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  • English  (10,171)
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  • 101
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    Offset approaches in existing compliance mechanisms : adding value and upholding environmental integrity? (2022)
    Dessau-Roßlau : Umweltbundesamt
    Details
    Publication Date: 2022-08-15
    Description: The objective of this report is to use historical analysis to identify conditions that determine when offsets add value to compliance schemes while upholding environmental integrity. The indicators of success include: increased acceptance of introducing compliance schemes; raising ambition in subsequent compliance periods; the possibility to drive emission reductions outside the compliance sectors; promoting investments in sustainable development; and avoiding perverse incentives that undermine the stringency of the compliance scheme or compliance actors’ efforts in reducing their own emissions. Through undertaking in-depth case study analyzes on the effects of offsets in the European Union, Alberta, Australia, Colombia and Japan, the report identifies common conditions that explain why offsets were successful (or not) in achieving individual indicators. The report further identifies two common conditions that can help explain when offsets achieve all five indicators of success. The first is that policymakers need to be willing to design the compliance scheme to set and maintain a strong compliance price signal that justifies the need for incorporating cost containment measures, such as offsets, to avert negative political and economic ramifications. Relatedly, the second condition requires institutions, processes and infrastructure that govern both the compliance scheme and offsets to be well developed so that they can ensure offsets uphold the principles of environmental integrity, achieve sustainable development benefits, and act as a reliable cost containment measure to high compliance prices. The findings also highlight how difficult it is to achieve both conditions, as both domestic and international political economy factors determine whether policymakers and voters are willing to introduce and maintain compliance schemes that deliver effective action on climate.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: report , doc-type:report
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  • 102
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    Sustainable transformation of energy systems in MENA countries : comparative report (2022)
    Amman : Friedrich-Ebert-Stiftung
    Details
    Publication Date: 2022-08-17
    Description: A clear understanding of socio-technical interdependencies and a structured vision are prerequisites for fostering and steering a transition to a fully renewables-based energy system. To facilitate such understanding, a phase model for the renewable energy (RE) transition in the Middle East and North Africa (MENA) countries has been developed and applied to ten countries: Algeria, Egypt, Iraq, Israel, Jordan, Lebanon, Morocco, Palestine, Tunisia, and Yemen. This report synthesises the results of these ten studies. The analysis shows that the state of the energy sector in the MENA region varies from country to country, but some underlying trends are present in all countries. In the majority of countries, energy prices are subsidised, and energy markets are mostly not liberalised. The energy demand in all analysed countries is growing and most grid systems are poorly interconnected across borders. Still, the expansion of RE in the MENA region can benefit from significant global progress and cost reductions in RE technologies. Reducing greenhouse gas (GHG) emissions is not the only key driver for energy transition. In fact, the main motives for transition are that RE can help to meet growing demand, reduce dependence on imports, increase energy security, and provide opportunities for economic development. All countries studied have RE targets. While some countries are on track to meet these targets, others need to increase their efforts to expand renewable electricity generation in order to meet their goals. Strong progress has been made in countries with limited fossil energy resources, while in some countries that produce and export large amounts of fossil energy resources, the energy transition is progressing rather slowly.
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: report , doc-type:report
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  • 103
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    Sustainable transformation of Yemen's energy system : development of a phase model (2022)
    Sana'a : Friedrich-Ebert-Stiftung
    Details
    Publication Date: 2022-08-17
    Description: A clear understanding of socio-technical interdependencies and a structured vision are prerequisites for fostering and steering a transition to a fully renewables-based energy system. To facilitate such understanding, a phase model for the renewable energy (RE) transition in MENA countries has been developed and applied to the country case of Yemen. It is designed to support the strategy development and governance of the energy transition and to serve as a guide for decision makers. The transition towards REs is still at a quite early stage in Yemen. The military conflict has prevented the implementation of most of the planned large-scale renewable projects. The political instability, the high dependence on fossil fuels, and poor administrative performance are the most pressing concerns for Yemen's electricity sector. At an operational level, Yemen requires a total retrofit of the electricity infrastructure and needs to expand its overall capacity while improving its efficiencies. Despite these challenges, rebuilding the energy system after the political turmoil and the subsequent violent conflicts could offer Yemen the capability to transition towards renewables. This will provide short-term and long-term opportunities and avoid stranded investments in fossil-fuel capacities. The priority is to improve the framework conditions for RE in Yemen, starting with the development of a long-term strategy up to 2030 and beyond. Also, an appropriate and transparent legislation must be created. Furthermore, based on the legislation, clear regulations for REs must be introduced, and a realistic timeframe for expansion must be established in order to promote acceptance and market development on a large scale. The results of the analysis along the transition phase model towards 100% RE are intended to stimulate and support the discussion on Yemen's future energy system by providing an over-arching guiding vision for the energy transition and the development of appropriate policies.
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 104
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    Sustainable transformation of Lebanon's energy system : development of a phase model (2022)
    Beirut : Friedrich-Ebert-Stiftung
    Details
    Publication Date: 2022-08-17
    Description: A clear understanding of socio-technical interdependencies and a structured vision are prerequisites for fostering and steering a transition to a fully renewables-based energy system. To facilitate such understanding, a phase model for the renewable energy (RE) transition in the Middle East and North Africa (MENA) countries has been developed and applied to the country case of Lebanon. It is designed to support the strategy development and governance of the energy transition and to serve as a guide for decision makers. Lebanon's energy transition towards REs stands at a very early stage of the first transformation phase. Although abundant solar and wind energy potential does exist, the pathway towards a 100% renewables energy seems very challenging for Lebanon, as a consequence of highly unstable political conditions. The most pressing concern for Lebanon's electricity sector is combating the country's fiscal imbalance, while providing secure and reliable electricity supply. At the operational level, Lebanon's grid network requires significant investments to rebuild, retrofit, and expand the overall capacity and energy efficiency improvements. The need to strengthen the energy system after the political turmoil of the civil war is likely to offer several long-term opportunities, such as developing the economy, reducing environmental pollution, and increasing the energy security. In order to move forward into the first phase, Lebanon needs to improve the framework conditions for REs and implement its visions. It needs to support the market development in a realistic timeframe, where structural reforms represent the highest priority. The results of the analysis along the transition phase model towards 100% renewables energy are intended to stimulate and support the discussion on Lebanon's future energy system by providing an overarching guiding vision for the energy transition and the development of appropriate policies.
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 105
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    Digital product passport : the ticket to achieving a climate neutral and circular European economy? (2022)
    Cambridge : University of Cambridge Institute for Sustainability Leadership
    Details
    Publication Date: 2022-10-10
    Description: The introduction of a Digital Product Passport (DPP) is an opportunity to create a system that can store and share all relevant information throughout a product's life cycle. This would provide industry stakeholders, businesses, public authorities and consumers with a better understanding of the materials used in the product as well as their embodied environmental impact. With the COVID-19 pandemic, the Russian invasion of Ukraine and the cost-of-living crisis, now is a critical moment to transform our economic and business models, while also addressing the huge scale of material emissions. DPPs can be a pivotal policy instrument in this goal. Furthermore, DPPs can accelerate the twin green and digital transitions as part of EU efforts to deliver positive climate action and sustainable economies. In 2020, the European Commission (EC) adopted a new Circular Economy Action Plan (CEAP), which emphasised the need for circular economy initiatives to consider the entire life cycle of products, from the production of basic materials to end-of-life disposal. The Circular Economy Package published in March 2022 includes a proposal for an Ecodesign for Sustainable Products Regulation (ESPR), which builds upon the Ecodesign Directive that covers energy-related products. A DPP will form a key regulatory element of the ESPR by enhancing the traceability of products and their components. This will provide consumers and manufacturers with the information needed to make better informed choices by taking their environmental impact into consideration. As discussed in the report, there is widespread agreement amongst business leaders that a well-designed DPP could have both short- and longer-term benefits, improving access to reliable and comparable product sustainability information for businesses, consumers and policymakers. A well-designed DPP can unify information, making it more readily accessible to all actors in the supply chain. This will support businesses to ensure an effective transformation towards a decarbonised industry. It could also create incentives for companies to make their products more sustainable, as improving access to reliable and consistent information across supply chains will make it easier for customers to make comparisons.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: report , doc-type:report
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  • 106
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    Joint Effects of Fragmentation and Mercury Contamination on Marsh Periwinkle (Littoraria irrorata) Movement (2022)
    Details
    Publication Date: 2022-10-07
    Description: There are different ways contaminants can interact and enhance the effects of habitat fragmentation, such as modifying the movement of organisms. The present study tested the hypothesis that mercury exacerbates the effects of fragmentation by affecting the movement of the marsh periwinkle Littoraria irrorata and reducing the probability of snails crossing fragmented microlandscape experimental systems. How these changes could affect the search efficiency of organisms in the long term was assessed using hidden Markov models and random walks simulations. Bayesian nonlinear models were used to analyze the effects of fragmentation and contamination on the mean speed and mean directional change of organisms. Snail movement for control and two mercury‐exposure treatments were recorded in microlandscapes with six different levels of habitat cover and three landscape replicates. The results indicated that exposed organisms had lower probabilities of crossing the landscape, reduced speed, and shifts in step length distributions. Both mercury exposure and habitat fragmentation affected the movement of the marsh periwinkle. Mercury exacerbated the effects of habitat fragmentation by affecting the cognition (e.g., route planning, orientation, and spatial learning) and movement of L. irrorata. Hence, the interaction of these stressors could further reduce the functional connectivity of landscapes and reduce the search efficiency of organisms. Environ Toxicol Chem 2022;41:1742–1753. © 2022 The Authors. Environmental Toxicology and Chemistry published by Wiley Periodicals LLC on behalf of SETAC.
    Description: Coordenação de Aperfeiçoamento de Pessoal de Nível Superior http://dx.doi.org/10.13039/501100002322
    Keywords: ddc:577.2
    Language: English
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  • 107
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    Chronic and Acute Effects of Imidacloprid on a Simulated BEEHAVE Honeybee Colony (2022)
    Details
    Publication Date: 2022-10-07
    Description: Honeybees (Apis mellifera) are important pollinators for wild plants as well as for crops, but honeybee performance is threatened by several stressors including varroa mites, gaps in foraging supply, and pesticides. The consequences of bee colony longtime exposure to multiple stressors are not well understood. The vast number of possible stressor combinations and necessary study duration require research comprising field, laboratory, and simulation experiments. We simulated long‐term exposure of a honeybee colony to the insecticide imidacloprid and to varroa mites carrying the deformed wing virus in landscapes with different temporal gaps in resource availability as single stressors and in combinations. Furthermore, we put a strong emphasis on chronic lethal, acute sublethal, and acute lethal effects of imidacloprid on honeybees. We have chosen conservative published values to parameterize our model (e.g., highest reported imidacloprid contamination). As expected, combinations of stressors had a stronger negative effect on bee performance than each single stressor alone, and effect sizes were larger after 3 years of exposure than after the first year. Imidacloprid‐caused reduction in bee performance was almost exclusively due to chronic lethal effects because the thresholds for acute effects were rarely met in simulations. In addition, honeybee colony extinctions were observed by the last day of the first year but more pronounced on the last days of the second and third simulation year. In conclusion, our study highlights the need for more long‐term studies on chronic lethal effects of pesticides on honeybees. Environ Toxicol Chem 2022;41:2318–2327. © 2022 The Authors. Environmental Toxicology and Chemistry published by Wiley Periodicals LLC on behalf of SETAC.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.5281/zenodo.6567312
    Keywords: ddc:577.2
    Language: English
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  • 108
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    Clockwise hysteresis of diatoms in response to nutrient dynamics during eutrophication and recovery (2022)
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-10-08
    Description: Many lake ecosystems that have been severely disturbed by eutrophication, have also experienced large human efforts to restore “natural” conditions. However, the trajectories and the extent of recovery of these lake ecosystems are still poorly understood. In many shallow lakes, recovery was often delayed and counter‐clockwise hysteretic. Here, we study recovery and ecosystem trajectories in a large and deep lake using diatom remains in sediment cores and time series of phosphorus concentrations. We identified four periods of diatom community change: slow change during early eutrophication, thereafter a short period of rapid change after the 1950s, followed by community stability from the 1960s to the mid‐1980s, and finally a recovery phase until 2010. Diatom community structure responded quickly and in a saturating way to increasing phosphorus concentrations, but also fast to phosphorus decline. Hence, diatom community dynamics did not show counter‐clockwise hysteresis but was characterized by a high degree of recovery and clock‐wise hysteresis (CWH). We suggest that CWH in response to eutrophication and recovery is a typical and previously overlooked feature of deep lakes, which results from a more rapid change of average nutrient concentrations and thus productivity in the epilimnion compared to average nutrient concentrations across the entire water column. Such nonlinear and hysteretic responses to changing nutrients need to be considered when analyzing the effects of other stressors such as climate warming on ecosystem dynamics to prevent erroneous attribution of ecosystem change to other stressors instead of nutrient change.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: European Regional Development Fund http://dx.doi.org/10.13039/501100008530
    Keywords: ddc:577.63
    Language: English
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  • 109
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    Increased phosphorus availability from sewage sludge ashes to maize in a crop rotation with clover (2022)
    Details
    Publication Date: 2022-10-08
    Description: A recycling of Phosphorus (P) from the human food chain is mandatory to secure the future P supply for food production. However, many available recycled P fertilizers from sewage sludge do not have an adequate P bioavailability and, thus, are not suitable for their application in soils with pH 〉5.5–6.0, unless being combined with efficient mobilization measures. The aim of the study was to test the P mobilization ability of red clover (Trifolium pratense L.) from two thermally recycled P fertilizers for a subsequently grown maize. Two sewage sludge ashes (SSA) were investigated in a pot experiment at soil pH 7.5 with red clover differing in its nitrogen (N) supply (added N fertilizer or biological N2 fixation (BNF)), followed by maize (Zea maize L.). Shoot dry matter of maize was almost doubled when N supply of previous grown clover was covered by BNF, instead of receiving added N fertilizer. Similarly, shoot P removal of maize following clover with BNF was significantly increased. It is suggested that the P mobilization is related to the BNF, and a proton release of N2 fixing clover roots led to the measured decrease in soil pH and thereby increased P availability of the tested fertilizers.
    Description: CORE Organic II
    Keywords: ddc:333.7
    Language: English
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  • 110
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    Do image resolution and classifier choice impact island biogeographical parameters of terrestrial islands? (2022)
    Details
    Publication Date: 2022-10-08
    Description: Island biogeography provides concepts for conservation management as fragmented habitats are comparable to ocean islands. Remote sensing can help to extract terrestrial habitat islands on the landscape scale. However, little is known about the effects of image resolution and classification algorithms on resulting island size and related parameters. We study the combined effect of three image resolutions (2, 10, and 30 m) and three classification algorithms (Artificial Neural Network, Random Forest, Support Vector Machine) by extracting quartz islands from WorldView‐2 imagery using image segmentation. We compared four island parameters (i.e., area, distance, shape index, and perimeter–area ratio between resolutions and classifiers). We found that in all cases, image resolution and classification algorithms had a strong effect. However, image resolution was more important for area and shape. Artificial Neural Network always provided the best performance as a classifier (OA: 0.880, kappa: 0.801, F1: 0.912). Hence, conservation strategies could lead to different results when different pattern extraction strategies are applied. Future studies which aim at extracting terrestrial habitat islands from image datasets should aim for the highest possible resolution and compare the outcomes of different classifiers to ensure the best possible results.
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:526.0285
    Language: English
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  • 111
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    Comparing the performance of high‐resolution global precipitation products across topographic and climatic gradients of Central Asia (2022)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2022-10-13
    Description: Accurate and reliable precipitation data with high spatial and temporal resolution are essential in studying climate variability, water resources management, and hydrological forecasting. A range of global precipitation data are available to this end, but how well these capture actual precipitation remains unknown, particularly for mountain regions where ground stations are sparse. We examined the performance of three global high‐resolution precipitation products for capturing precipitation over Central Asia, a hotspot of climate change, where reliable precipitation data are particularly scarce. Specifically, we evaluated MSWEP, CHIRPS, and GSMAP against independent gauging stations for the period 1985–2015. Our results show that MSWEP and CHIRPS outperformed GSMAP for wetter periods (i.e., winter and spring) and wetter locations (150–600 mm·year−1), lowlands, and mid‐altitudes (0–3,000 m), and regions dominated by winter and spring precipitation. MSWEP performed best in representing temporal precipitation dynamics and CHIRPS excelled in capturing the volume and distribution of precipitation. All precipitation products poorly estimated precipitation at higher elevations (〉3,000 m), in drier areas (〈150 mm), and in regions characterized by summer precipitation. All products accurately detected dry spells, but their performance decreased for wet spells with increasing precipitation intensity. In sum, we find that CHIRPS and MSWEP provide the most reliable high‐resolution precipitation estimates for Central Asia. However, the high spatial and temporal heterogeneity of the performance call for a careful selection of a suitable product for local applications considering the prevailing precipitation dynamics, climatic, and topographic conditions.
    Description: We present the first quantitative evaluation of global high‐resolution (below 12 km) precipitation products against independent ground observations over Central Asia. Our results show that MSWEP was best at representing temporal precipitation dynamics, and CHIRPS was most prominent in representing the volume and distribution of precipitation. This is especially the case of wet seasons, altitudes below 3,000 m, and regions dominated by spring and winter precipitation. Our analysis provides key insights on the precipitation products' suitability for local hydrological applications.
    Description: Leibniz‐Institut für Agrarentwicklung in Transformationsökonomien
    Description: Volkswagen Foundation http://dx.doi.org/10.13039/501100001663
    Keywords: ddc:551.6
    Language: English
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  • 112
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    Climate Change and Weather Extremes in the Eastern Mediterranean and Middle East (2022)
    Details
    Publication Date: 2022-10-13
    Description: Observation‐based and modeling studies have identified the Eastern Mediterranean and Middle East (EMME) region as a prominent climate change hotspot. While several initiatives have addressed the impacts of climate change in parts of the EMME, here we present an updated assessment, covering a wide range of timescales, phenomena and future pathways. Our assessment is based on a revised analysis of recent observations and projections and an extensive overview of the recent scientific literature on the causes and effects of regional climate change. Greenhouse gas emissions in the EMME are growing rapidly, surpassing those of the European Union, hence contributing significantly to climate change. Over the past half‐century and especially during recent decades, the EMME has warmed significantly faster than other inhabited regions. At the same time, changes in the hydrological cycle have become evident. The observed recent temperature increase of about 0.45°C per decade is projected to continue, although strong global greenhouse gas emission reductions could moderate this trend. In addition to projected changes in mean climate conditions, we call attention to extreme weather events with potentially disruptive societal impacts. These include the strongly increasing severity and duration of heatwaves, droughts and dust storms, as well as torrential rain events that can trigger flash floods. Our review is complemented by a discussion of atmospheric pollution and land‐use change in the region, including urbanization, desertification and forest fires. Finally, we identify sectors that may be critically affected and formulate adaptation and research recommendations toward greater resilience of the EMME region to climate change.
    Description: Key Points: The Eastern Mediterranean and Middle East is warming almost two times faster than the global average and other inhabited parts of the world. Climate projections indicate a future warming, strongest in summers. Precipitation will likely decrease, particularly in the Mediterranean. Virtually all socio‐economic sectors will be critically affected by the projected changes.
    Description: European Union Horizon 2020
    Description: https://esg-dn1.nsc.liu.se/search/esgf-liu/
    Keywords: ddc:551.6
    Language: English
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  • 113
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    Formation of fused aggregates under long‐term microgravity conditions aboard the ISS with implications for early solar system particle aggregation (2022)
    Koch, Tamara E. ; Spahr, Dominik ; Tkalcec, Beverley J. ; [et al.]
    Details
    Publication Date: 2022-10-13
    Description: In order to gain further insights into early solar system aggregation processes, we carried out an experiment on board the International Space Station, which allowed us to study the behavior of dust particles exposed to electric arc discharges under long‐term microgravity. The experiment led to the formation of robust, elongated, fluffy aggregates, which were studied by scanning electron microscopy, electron backscatter diffraction, and synchrotron micro‐computed tomography. The morphologies of these aggregates strongly resemble the typical shapes of fractal fluffy‐type calcium‐aluminum‐rich inclusions (CAIs). We conclude that a small amount of melting could have supplied the required stability for such fractal structures to have survived transportation and aggregation to and compaction within planetesimals. Other aggregates produced in our experiment have a massy morphology and contain relict grains, likely resulting from the collision of grains with different degrees of melting, also observed in some natural CAIs. Some particles are surrounded by igneous rims, which remind in thickness and crystal orientation of Wark–Lovering rims; another aggregate shows similarities to disk‐shaped CAIs. These results imply that a (flash‐)heating event with subsequent aggregation could have been involved in the formation of different morphological CAI characteristics.
    Description: BIOVIA
    Description: Nordlicht GmbH
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Bundesministerium für Wirtschaft und Energie http://dx.doi.org/10.13039/501100006360
    Description: NanoRacks LLC
    Description: Dr. Rolf M. Schwiete Stiftung http://dx.doi.org/10.13039/501100020027
    Description: Deutsches Zentrum für Luft‐ und Raumfahrt http://dx.doi.org/10.13039/501100002946
    Description: DreamUp
    Description: Carl Zeiss Meditec AG http://dx.doi.org/10.13039/501100002806
    Keywords: ddc:550.78
    Language: English
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  • 114
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    Microbially promoted calcite precipitation in the pelagic redoxcline: Elucidating the formation of the turbid layer (2022)
    Details
    Publication Date: 2022-10-12
    Description: Large bell‐shaped calcite formations called “Hells Bells” were discovered underwater in the stratified cenote El Zapote on the Yucatán Peninsula, Mexico. Together with these extraordinary speleothems, divers found a white, cloudy turbid layer into which some Hells Bells partially extend. Here, we address the central question if the formation of the turbid layer could be based on microbial activity, more specifically, on microbially induced calcite precipitation. Metagenomic and metatranscriptomic profiling of the microbial community in the turbid layer, which overlaps with the pelagic redoxcline in the cenote, revealed chemolithoautotrophic Hydrogenophilales and unclassified β‐Proteobacteria as the metabolic key players. Bioinformatic and hydrogeochemical data suggest chemolithoautotrophic oxidation of sulfide to zero‐valent sulfur catalyzed by denitrifying organisms due to oxygen deficiency. Incomplete sulfide oxidation via nitrate reduction and chemolithoautotrophy are both proton‐consuming processes, which increase the pH in the redoxcline favoring authigenic calcite precipitation and may contribute to Hells Bells growth. The observed mechanism of microbially induced calcite precipitation is potentially applicable to many other stagnant sulfate‐rich water bodies.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: CONACYT‐FONCICYT‐DADC
    Description: https://doi.org/10.11588/data/TMYLWS
    Description: https://doi.org/10.11588/data/GYLDH5
    Keywords: ddc:551.9
    Language: English
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  • 115
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    Location choice for large‐scale battery manufacturing plants: Exploring the role of clean energy, costs, and knowledge on location decisions in Europe (2022)
    Details
    Publication Date: 2022-10-15
    Description: Driven by an increase in the demand for battery electric vehicles, the location of large‐scale battery manufacturing plants, that is, gigafactories, has become a substantial and burgeoning topic in academia, policy, and industry. This study contributes to this debate by examining how a country's specific battery manufacturing costs and knowledge and the environmental impact of its energy mix affect the choice of location for gigafactories in the European Union. We found that France, Latvia, and Germany are suitable locations when equally balancing costs, knowledge, and energy. However, our results also showed that no country leads in all three dimensions, suggesting that there is no single best location to set up gigafactories. Instead, the choice will depend on the battery manufacturer's requirements. Here, we contribute an analysis of various combinations of costs, knowledge, and energy to identify suitable locations. Moreover, we provide a sensitivity analysis to test the robustness of our framework and to explore whether countries with a clean energy mix, such as Sweden, become suitable locations. The findings of our study will assist battery producers in identifying a suitable location for their gigafactories and will provide the basis for policymakers to attract battery manufacturing by directing investments into clean energy.
    Description: https://doi.org/10.1016/j.jclepro.2020.121428
    Description: https://www.iea.org/data-and-statistics/data-product/emissions-factors-2021
    Keywords: ddc:333.7
    Language: English
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  • 116
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    Near‐surface three‐dimensional multicomponent source and receiver S‐wave survey in the Tannwald Basin, Germany: Acquisition and data processing (2022)
    Details
    Publication Date: 2022-10-17
    Description: Shallow 3‐D reflection seismic surveys using S‐waves have rarely been carried out, even though S‐waves can provide higher resolution subsurface images than P‐waves. We conducted a 3‐D near‐surface multicomponent source and receiver survey in Quaternary sediments. We employed a small electrodynamic seismic source with a horizontal shaking unit operated in two orientations. Three‐component geophones in an orthogonal layout covering an area of 117×99 m2 were used for recording. Changes in weather and ground conditions, including freezing and thawing during acquisition, directly influenced the data quality and resulted in discernible relative time shifts in the data. Our seismic processing flow included a four‐component rotation of the data from the Cartesian acquisition geometry into the ‘natural’ coordinate frame to orient sources and receivers in radial or transverse orientation to separate different S‐wave polarizations. The rotation increased the signal strength and helped, for example, to improve the quality of the images of the basin base. The irregular offset distribution in the common midpoint gathers impedes filtering to suppress surface waves in the f–k domain. We, therefore, applied a common‐reflection surface processing flow. After regularization, we could better remove the energy of the surface waves. Both stacked 3‐D S‐wave volumes of vertical and horizontal polarizations provide images of the Quaternary overdeepened Tannwald Basin that was partly known from previous P‐ and S‐wave 2‐D surveys. Compared to a P‐wave profile adjacent to the volume, however, the S‐wave volumes provide higher resolution images of the basin base and internal structure. The basin base is well mapped in three dimensions and shows undulations that were not obvious from the P‐wave data. Comparing the S‐wave volumes of different polarizations, we find only minor differences in the stacks and interpretations.
    Keywords: ddc:622.1592
    Language: English
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    Modeling Subsurface Hydrogen Storage With Transport Properties From Entropy Scaling Using the PC‐SAFT Equation of State (2022)
    Details
    Publication Date: 2022-10-17
    Description: Hydrogen is a promising alternative to carbon based energy carriers and may be stored in large quantities in subsurface storage deposits. This work assesses the impact of static (density and phase equilibria) and dynamic (viscosity and diffusion coefficients) properties on the pressure field during the injection and extraction of hydrogen in the porous subsurface. In a first step, we derive transport properties for water, hydrogen and their mixture using the Perturbed‐Chain Statistical Associating Fluid Theory equation of state in combination with an entropy scaling approach and compare model predictions to alternative models from the literature. Our model compares excellently to experimental transport coefficients and models from literature with a higher number of adjustable parameters, such as GERG2008, and shows a clear improvement over empirical correlations for transport coefficients of hydrogen. In a second step, we determine the effect of further model reduction by comparing our against a much simpler model applying empirical transport coefficients from the literature. For this purpose, hydrogen is periodically injected into and extracted out of a dome‐shaped porous aquifer under a caprock. Our results show that density and viscosity of hydrogen have the highest impact on the pressure field, and that a thermodynamic model like the new model presented here is essential for modeling the storage aquifer, while keeping the number of coefficients at a minimum. In diffusion‐dominated settings such as the diffusion of hydrogen through the caprock, our developed diffusion coefficients show a much improved dependence on temperature and pressure, leading to a more accurate approximation of the diffusive fluxes.
    Description: Key Points: We model the phase behavior of pure hydrogen and the binary hydrogen‐water mixture using the Perturbed‐Chain Statistical Associating Fluid Theory equation of state. New entropy scaling relations for the transport properties of hydrogen and water and diffusion coefficients of their mixture are derived. The impact of the newly derived fluid properties is analyzed for a scenario of hydrogen storage in a porous aquifer.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: https://git.iws.uni-stuttgart.de/dumux-pub/sauerborn2020a
    Keywords: ddc:550
    Language: English
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    Noah‐MP With the Generic Crop Growth Model Gecros in the WRF Model: Effects of Dynamic Crop Growth on Land‐Atmosphere Interaction (2022)
    Warrach‐Sagi, K. ; Ingwersen, J. ; Schwitalla, T. ; [et al.]
    Details
    Publication Date: 2022-10-17
    Description: In this paper we coupled a crop growth model to the Weather Research and Forecasting model with its land surface model Noah‐MP and demonstrated the influence of the weather driven crop growth on land‐atmosphere (L‐A) feedback. An impact study was performed at the convection permitting scale of 3 km over Germany. While the leaf area index (LAI) in the control simulation was the same for all cropland grid cells, the inclusion of the crop growth model resulted in heterogeneous crop development with higher LAI and stronger seasonality. For the analyses of L‐A coupling, a two‐legged metric was applied based on soil moisture, latent heat flux and convective available potential energy. Weak atmospheric coupling is enhanced by the crop model, the terrestrial coupling determines the regions with the L‐A feedback. The inclusion of the crop model turns regions with no L‐A feedback on this path into regions with strong positive coupling. The number of non‐atmospherically controlled days between April and August is increased by 10–15 days in more than 50% of Germany. Our work shows that this impact results in a reduction of both cold bias and warm biases and thus improves the metrics of distributed added value of the monthly mean temperatures. The study confirms that the simulation of the weather driven annual phenological development of croplands for the regional climate simulations in mid‐latitudes is crucial due to the L‐A feedback processes and the currently observed and expected future change in phenological phases.
    Description: Key Points: Coupling a crop growth model with the Weather and Research Forecasting model significantly improves the simulation of the leaf area index. Land‐atmosphere coupling strength is enhanced by weather dependent crop growth simulation. The distributed added value metric shows a reduction in temperature biases of up to 80% in croplands throughout the season in Germany.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://opendata.dwd.de/climate_environment/CDC/grids_germany/daily/Project_TRY/air_temperature_mean/
    Description: https://doi.org/10.5281/zenodo.6501984
    Description: http://land.copernicus.eu/pan-european/corine-land-cover/clc-2006/view
    Description: https://doi.org/10.1594/WDCC/WRF_NOAH_HWSD_world_TOP_SOILTYP
    Keywords: ddc:551.6
    Language: English
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    Gradual warming prior to the end‐Permian mass extinction (2022)
    Gliwa, Jana ; Wiedenbeck, Michael ; Schobben, Martin ; [et al.]
    Details
    Publication Date: 2022-10-18
    Description: The biggest known mass extinction in the history of animal life occurred at the Permian–Triassic boundary and has often been linked to global warming. Previous studies have suggested that a geologically rapid (〈40 kyr) temperature increase of more than 10°C occurred simultaneously with the main extinction pulse. This hypothesis is challenged by geochemical and palaeontological data indicating profound environmental perturbations and a temperature rise prior to the main extinction. Using secondary ion mass spectrometry (SIMS), we measured oxygen isotope ratios from Changhsingian (late Permian) ostracods of north‐western Iran. Our data show that ambient seawater temperature began to rise at least 300 kyr prior to the main extinction event. Gradual warming by approximately 12°C was probably responsible for initial environmental degradation that eventually culminated in the global end‐Permian mass extinction.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:560
    Language: English
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    Initial Response of Nightside Auroral Currents to a Sudden Commencement: Observations of Electrojet and Substorm Onset (2022)
    Details
    Publication Date: 2022-10-18
    Description: Storm sudden commencements (SSC) often precede geomagnetic storms. Commonly, it takes some hours from the step‐like change that marks the SSC to the start of the magnetic storm activity. In a subset of cases, however, auroral activity starts almost instantaneously after the SSC. To the authors knowledge, the conditions that enable this rapid activation have not been investigated in detail before. Here we consider all the sudden commencements (SC) during the years 2000–2020. Our focus is on the initial response of the auroral currents on the nightside. For that purpose, we make use of the IMAGE Magnetometer Network in Fennoscandia. In about 30% of SC events an initial activation of the westward electrojet is observed. Magnetic deflections of the northward component, surpassing frequently 1,000 nT, are observed only 4 min after the SC. These intense westward currents, flowing typically in narrow channels of 1°–2° latitudinal width, last some 10 min. The electrojets are conjugate to regions in the magnetosphere near geostationary orbits. In several cases geomagnetic substorm onsets are observed about 30 min after the SC. These start typically at fairly high latitude, around 71° magnetic latitude. This is an indication for rather quiet conditions preceding the onset. The magnetic pulse of the SC seems to play an important role in initiating the strong electrojets and the substorms. These initial activities are of relevance for space weather effects because of their strong and rapid variations. This paper provides detailed observations of the initial auroral activity following some SCs.
    Description: Key Points: First detailed study of intense electrojet activity at auroral latitudes on the nightside following immediately a sudden commencement (SC). Precondition for intense auroral activity is a southward interplanetary magnetic field Bz and a sufficiently large magnetic pulse caused by the SC. In a subset of events also an isolated substorm is initiated at relatively high magnetic latitudes shortly after the SC.
    Description: National Nature Science Foundation of China
    Description: https://spdf.gsfc.nasa.gov/pub/data/omni/high_res_omni/
    Keywords: ddc:538.7
    Language: English
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    From Dynamic Groundwater Level Measurements to Regional Aquifer Parameters— Assessing the Power of Spectral Analysis (2022)
    Details
    Publication Date: 2022-10-18
    Description: Large‐scale groundwater models are required to estimate groundwater availability and to inform water management strategies on the national scale. However, parameterization of large‐scale groundwater models covering areas of major river basins and more is challenging due to the lack of observational data and the mismatch between the scales of modeling and measurements. In this work, we propose to bridge the scale gap and derive regional hydraulic parameters by spectral analysis of groundwater level fluctuations. We hypothesize that specific locations in aquifers can reveal regional parameters of the hydraulic system. We first generate ensembles of synthetic but realistic aquifers which systematically differ in complexity. Applying Liang and Zhang’s (2013), https://doi.org/10.1016/j.jhydrol.2012.11.044, semi‐analytical solution for the spectrum of hydraulic head time series, we identify for each ensemble member and at different locations representative aquifer parameters. Next, we extend our study to investigate the use of spectral analysis in more complex numerical models and in real settings. Our analyses indicate that the variance of inferred effective transmissivity and storativity values for stochastic aquifer ensembles is small for observation points which are far away from the Dirichlet boundary. Moreover, the head time series has to cover a period which is roughly 10 times as long as the characteristic time of the aquifer. In deterministic aquifer models we infer equivalent, regionally valid parameters. A sensitivity analysis further reveals that as long as the aquifer length and the position of the groundwater measurement location is roughly known, the parameters can be robustly estimated.
    Description: Plain Language Summary: We build large‐scale (regional) computer models of the subsurface flow conditions in order to quantify the long‐term shift in groundwater storage and response on the national level under changing climatic conditions and increasing human water demands. These models must be fed with hydrogeological parameters obtained from subsurface observation wells, drilling logs, and hydraulic tests in conjunction with (hydro)geological and geostatistical methods. In some regions these wells are sparsely distributed and derived parameters are representative only for small areas. We hypothesize that groundwater level records can reveal regional aquifer information when analyzed in the spectral domain. In order to bridge that scale gap and because groundwater level time series are generally available, we propose to infer regional parameters by analyzing the frequency content (spectrum) of long groundwater level time series. The required parameters were determined using mathematical formulations of the theoretical spectrum for simplified settings. We tested the methodology in computer models with limited complexity and found that the groundwater level time series indeed contain regional information if the time of observation is sufficiently long. Lastly, we apply the spectral analysis to real groundwater data to test the capability of the method to infer regional aquifer parameters in real aquifers.
    Description: Key Points: We successfully tested the spectral analysis of groundwater level fluctuations in numerical models and obtained regional aquifer parameters. In a sensitivity analysis of the spectral analysis using field data, the storativity and the response times could be robustly estimated. The application of the suggested methodology to the field data from a catchment in central Germany produced plausible results.
    Description: Helmholtz Centre for Environmental Research (UFZ)
    Description: Global Resource Water
    Description: German Federal Ministry of Education and Research (BMBF)
    Description: IDAEA‐CSIC
    Description: Barcelona City Council
    Description: https://github.com/ufz/ogs5
    Description: https://geostat-framework.github.io/
    Keywords: ddc:551.49
    Language: English
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    Geostandards and Geoanalytical Research Bibliographic Review 2020 (2022)
    Weis, Ulrike ; Stoll, Brigitte ; Förster, Michael W. ; [et al.]
    Details
    Publication Date: 2022-10-19
    Description: Key Points: Literature review of 7200 geoanalytical publications for the year 2020. 628 selected articles with summaries of target analytes, relevant reference materials and producers. Selected publications include data obtained by new analytical developments and improved analytical protocols for established RMs, and identifies recently developed RMs for specific scientific topics. image
    Description: This bibliographic review gives an overview of scientific publications in 2020 that contribute important data for geoanalytical reference materials (RMs).
    Keywords: ddc:551.9
    Language: English
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    Analysis to support the implementation of the energy efficiency first principle in decision-making : final report (2022)
    Luxembourg : Publications Office of the European Union
    Details
    Publication Date: 2022-10-24
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: report , doc-type:report
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    In between : from transdisciplinary, transformative science to evidence-based policy making (2022)
    Baden-Baden : Nomos
    Details
    Publication Date: 2022-10-24
    Description: When dealing with the Great Transformation towards a sustainable world (WBGU 2011), one defining factor is the stark contradiction in the availability of knowledge: While there is almost unlimited knowledge on many technical and economic aspects of the sustainability transformation, while in some way all the tools are available and we, in theory, know exactly how to use them, there is a lack of action at all levels. If we assume that in principle a majority of decision-makers has understood the necessity to act, this ultimately points to a lack of knowledge on how major transformations can be triggered. To use a common distinction, we have solid knowledge of the systems at play, we know the targets society should be heading for, and these targets have been globally and politically agreed to, but our knowledge on transformations, while growing, is obviously lacking. While this is true for all forms of knowledge to some extent, especially transformation knowledge requires more than just disciplinary or interdisciplinary research because it depends on transdisciplinary approaches that integrate the knowledge of practitioners from politics, administration, civil society and business.
    Keywords: ddc:300
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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    Overview report on definition and concept of the circular economy in a European perspective : CICERONE D1.1 (2022)
    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Details
    Publication Date: 2022-10-24
    Description: On the basis of a literature research, this subtask develops a conceptional framework for a common understanding of CE within the project team and for the following work packages and tasks. After a brief introduction into the objectives and the context of a circular economy, a more elaborated look into the necessity of an explicit understanding of CE, the objectives, the spatial perspective of CE and the specific challenges within the CICERONE context will be done, in order to develop a basis for a common understanding within the project context. Circular economy can and has to be understood as an (eco-)innovation agenda. Therefore, the paper investigates the role policy has to play to support innovation for a CE transition, for creating the framework conditions and why CE has also to be build from the ground up. Finally, the paper looks from two perspectives at emerging trends and business models in a CE to sketch next steps towards the transition in a selection of central sectors. Conclusions are drawn on the basis of the insights gained by the preceding chapters.
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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    Report on current state of the art & understanding of the circular economy : CICERONE D1.2 (2022)
    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Details
    Publication Date: 2022-10-24
    Description: The key objective of this deliverable is to gain insights on and assess how CE is being implemented and R&I is being funded at regional level, e.g., via the RIS3 strategy and Structural Funds. As such it sets the scope for the project and provides the background against which programmes and measures can be understood, assessed, developed and recommended in succinct tasks and work packages. The objective of this report is to provide a concise overview of the current R&I priorities, as expressed in running and newly introduced funding and legislative measures with respect to Circular Economy in European countries and regions.
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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    Fostering circular cities : a study on urban circularity hotspot frameworks for the Western Balkan region (2022)
    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Details
    Publication Date: 2022-10-24
    Description: A main goal of this study - which also functions as deliverable 210078-D07 of the Circular Economy Beacons (CEB) project - is to evaluate currently available frameworks that measure and operationalise Circular Economy (CE), with a particular focus on the urban context. The regional focus lies on the Western Balkan region, which is at the centre of the project. Such "Urban Circularity Hotspot Frameworks" (UCHF) aim at providing decision support for policy makers, companies, citizens etc. regarding the transition to CE within cities. Based on the analysis of different frameworks, suggestions are derived regarding UCHF suitable for the specific characteristics of Western Balkan municipalities, i.e. a Circular Economy Beacons Urban Circularity Hotspot Framework (CEB-UCHF) ready for short-term implementation.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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    Applying the energy efficiency first principle based on a decision-tree framework (2022)
    Details
    Publication Date: 2022-10-24
    Description: Energy Efficiency First (EEF) is an established principle for European Union (EU) energy policy design. It highlights the exploitation of demand-side resources and prioritizes cost-effective options from the demand-side over other options from a societal cost-benefit perspective. However, the involvement of multiple decision-makers makes it difficult to implement. Therefore, we propose a flexible decision-tree framework for applying the EEF principle based on a review of relevant areas and examples. In summary, this paper contributes to applying the EEF principle by defining and distinguishing different types of cases - (1) policy-making, and (2) system planning and investment - identifying the most common elements, and proposing a decision-tree framework that can be flexibly constructed based on the elements for different cases. Finally, we exemplify the application of this framework with two example cases: (1) planning for demand-response in the power sector, and (2) planning for a district heating system.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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    Key strategies to achieve deep decarbonisation of the industry sector : insights from a meta-analysis of recent climate neutrality scenarios for Germany (2022)
    Stockholm : European Council for an Energy Efficient Economy
    Details
    Publication Date: 2022-10-24
    Description: The EU aims to become the first climate neutral continent. To achieve this goal, the industry sector needs to reduce its GHG emissions to net zero or at least close to net zero. This is a particularly challenging task due to the high energy demand especially of primary materials production and the little potential to reduce this energy intensity when switching to other production processes based on electricity or hydrogen. In order to identify robust strategies for achieving a net-zero-compatible industry sector, the paper at hand analyses the transformation of the industry sector as described by a number of recent climate neutrality scenarios for Germany. Apart from overall industry, a focus is set on the sectors of steel, chemicals and cement. The analysed scenarios show very deep GHG emission reductions in industry and they appear to be techno-economically feasible by the mid of the century, without relying on offsets or on shifts from domestic production to imports. The scenarios agree on a suite of core strategies to achieve this, such as direct and indirect electrification, energy efficiency and recycling as well as new technological routes in steel making and cement. The scenarios differ, however, regarding the future mix of electricity, hydrogen and biomass and regarding the future relevance of domestic production of basic chemicals.
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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    Ensuring an effective global stocktake with a sectoral perspective (2022)
    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Details
    Publication Date: 2022-10-24
    Description: A sectoral perspective can help the Global Stocktake (GST) to effectively achieve its objective to inform Parties' in enhancing subsequent NDCs and in enhancing international cooperation. Specifically, granular and actionable sectoral lessons, grounded in country-driven assessments, should be identified and elaborated. To be effective, conversations on sectoral transformations need to synthesise key challenges and opportunities identified in the national analyses and link them to international enablers; focus on systemic interdependencies, involve diverse actors, and be thoroughly prepared including by pre-scoping points of convergences and divergence across transformations. We specifically recommend that: the co-facilitators of the Technical Dialogue use their (limited) mandate to facilitate an effective conversationon sectoral transformations e.g. by organising dedicated informal seminars in between formal negotiation sessions; key systemic transformations necessary toachieve net-zero by mid-century should be spelled out and included in the final decision or political declaration of the GST; and the political outcome of the GST should mandate follow-up processes at the regional level and encourage national-level conversations to translate the collective messages from GST into actionable and sector-specific policy recommendations.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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    Secondary school student participation in carbon footprint assessment for schools (2022)
    Stockholm : European Council for an Energy Efficient Economy
    Details
    Publication Date: 2022-10-24
    Description: More and more cities are setting themselves ambitious climate protection targets, including CO2 neutrality. Schools are important institutions of cities and therefore they have to play a central role in achieving this goal. With the investment backlog building up and pressure from the Friday for Future movement increasing, the Wuppertal Institute and Büro Ö-quadrat have initiated the project Schools4Future, aiming to support secondary schools to become climate-neutral. In cooperation with secondary school students and teachers, the project team evaluated the existing situation of the participating schools and developed GHG-balances and feasible climate protection concepts. For this purpose, an Excel-based carbon footprint (CF) assessment tool for schools has been developed which is freely available. The tool covers all important emission areas, including heating energy, electricity use, travel to and from schools, school trips, the school canteen and paper consumption. The students were found capable to conduct the CF assessment with the guidance of the teacher, information materials and support of the researchers. So far, six pilot schools have completed their CF assessment with emissions ranging between 335 and 944 kg CO2 per person. In this paper we present the tool and compare the CF assessment of some schools. We further elaborate on how the tool and project has increased the climate awareness and self-efficacy of students and even stimulated measures by the school board.
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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    Accelerating circular economy solutions to achieve the 2030 agenda for sustainable development goals (2022)
    Details
    Publication Date: 2022-10-24
    Description: Circular economy seems a vital enabler for sustainable use of natural resources which is also important for achieving the 2030 agenda for sustainable development goals. Therefore, a special session addressing issues of "sustainable solutions and remarkable practices in circular economy focusing materials downstream" was held at the 16th International Conference on Waste Management and Technology, where researchers and attendees worldwide were convened to share their experiences and visions. Presentations focusing on many key points such as new strategies, innovative technologies, management methods, and practical cases were discussed during the session. Accordingly, this article compiled all these distinctive presentations and gave insights into the pathway of circular economy towards the sustainable development goals. We summarized that the transition to circular economy can keep the value of resources and products at a high level and minimize waste production; the focus of governmental policies and plans with the involvement of public-private-partnership on 3Rs (reduce, reuse, and recycle) helps to improve the use of natural resources and take a step ahead to approach or achieve the sustainability.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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    Business model innovations for renewable energy prosumer development in Germany (2022)
    Details
    Publication Date: 2022-10-24
    Description: In Germany, the number of renewable energy prosumers has increased rapidly since 2000. However, the development of prosumers has faced and will continue to face various economic, social, and technological challenges, which have triggered the emergence of a number of innovative business models (BM). This paper enriches the empirical basis for prosumer-oriented BMs by investigating two BM innovations in Germany (P2P electricity trading and aggregation of small-size prosumers) drawing on business model and socio-technical transition theories. A mix of qualitative data collection methods, including document analysis and semi-structured expert interviews, was applied. We found that while both BMs can potentially address the challenges associated with renewable energy prosumer development in Germany, small-scale prosumers’ participation in both BMs has been limited so far. We identified various internal and external drivers and barriers for scaling up these BMs for prosumer development in Germany. Despite these barriers, both aggregation and centralized P2P targeting prosumers may potentially be also taken up by incumbent market actors such as utilities. Decentralized P2P on the other hand still faces significant internal and external barriers for upscaling. Based on the analysis, the paper provides policy recommendations with respect to the identified drivers and barriers. From a theoretical perspective, our findings provide further evidence to challenge the dichotomous understanding of niche actors and incumbents, the latter of which are often theorized to be resistant to radical innovations.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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    Harnessing energy performance certificates for deep energy renovation : policy recommendations and evidence from testing (2022)
    Stockholm : European Council for an Energy Efficient Economy
    Details
    Publication Date: 2022-10-24
    Description: To achieve the EU's energy efficiency targets, both the rate of building energy renovation and its depth, i.e., the amount of energy savings post renovation need to be improved. Energy Performance Certificates (EPCs) are key to make energy efficiency measures transparent for the building market and to promote the energy efficiency of buildings through renovation. The revision of the Energy Performance of Buildings Directive (EPBD) is seen as a pre-condition to meet the Renovation Wave objectives and to reach a highly energy efficient and decarbonized building stock by 2050. One focus of the current revision of the EPBD is therefore the improvement of EPCs. QualDeEPC - High-quality Energy Performance Assessment and Certification in Europe Accelerating Deep Energy Renovation, funded under the EU's Horizon 2020 programme, is a project that aims to improve EPCs. Following an EU-wide review of existing EPC schemes, and extensive stakeholder discussions in the seven partner countries, QualDeEPC found that EPCs and EPC schemes need to enhance particularly in the following three ways: 1. Establish a close link between EPCs and deep energy renovation 2. Improve the quality of EPC schemes, i.e., both the EPCs and their data, and the processes of assessment, certification, verification 3. Improve cross-EU convergence of EPC schemes.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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    Impact chains of energy sufficiency policies : a proposal for visualization and possibilities for integration into energy modeling (2022)
    Details
    Publication Date: 2022-10-24
    Description: Impact chains are used in many different fields of research to depict the various impacts of an activity and to visualize the system in which this activity is embedded. Research has not yet conceptualized impact chains specifically for energy sufficiency policies. We develop such a concept based on current evaluation approaches and extend these by adding qualitative elements such as success factors and barriers. Furthermore, we offer two case studies in which we test this concept with the responsible climate action managers. We also describe options for integrating these impact chains into different types of energy models, which are key tools in policy consulting.
    Keywords: ddc:300
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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    Overcoming information asymmetry in the plastics value chain with digital product passports : how decentralised identifiers and verifiable credentials can enable a circular economy for plastics (2022)
    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Details
    Publication Date: 2022-11-10
    Description: This paper analyses the potential of digital information technology to enable the reliable provision of product information along the plastics supply chain. The authors investigate the possible contribution of a product passport equipped with decentralised identifiers and verifiable credentials to overcome information deficits and information asymmetry in the circular plastics economy. Through this, high-quality plastics recycling could be enabled on a larger scale than currently possible.
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: workingpaper , doc-type:workingPaper
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    Current approaches to the digital product passport for a circular economy : an overview of projects and initiatives (2022)
    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Details
    Publication Date: 2022-11-10
    Description: A large number and variety of activities are being undertaken to introduce Digital Product Passports (DPPs). However, only a few DPPs have made it into practice so far, so there is some uncertainty about which impact DPPs will actually have. With this paper, we aim to provide a structured overview of the current development of DPPs. We provide insights of 76 current corporate, policy, and research activities that exist and their objectives. To allow for a structured assessment and discussion of the diverse approaches we defined 13 criteria for a comparable description, categorization and evaluation. We expect that this overview will not only encourage feedback and contributions from the DPP community, as well as valuable discussions with and among experts. It is also intended to help promote and facilitate the adoption of DPPs for the Circular Economy by facilitating collaborations and suggestions for ongoing activities.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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    Moving transport to net zero : what it takes to decarbonise the global transport sector (2022)
    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Details
    Publication Date: 2022-11-10
    Description: What is necessary to reach net zero emissions in the transport sector on a global level? To keep limiting global warming to 1.5° C within reach, the world has to decarbonise by mid-century, with every sector contributing as much as possible as soon as possible. This paper identifies what has to be done in road transport, aviation, and shipping to achieve net zero emission in the transport sector. For this purpose, it first sets the scene by providing an overview of the origins and impacts of the concept of net zero emissions in international climate policy as well as of the current state and future prospects of global transport emissions using currently available scenarios for low-emission and net zero transport. While for staying below 1.5° C, the basic approach to reducing transport emissions remains unchanged from what has been suggested in the past, the set, intensity and pace of actions as to shift fundamentally. Without first drastically reducing traffic volume and shifting transport demand to low-emission modes, reaching net zero transport will not be feasible: the amount of additional electricity required to fully electrify the sector with renewable energy is otherwise just too huge. After portraying key instruments for achieving net zero emissions in land transport, aviation, and shipping, this paper identifies key barriers for net zero transport. Based on this analysis, the authors recommend the following to be able to move transport to net zero: 1. Adapt Decarbonisation Strategies to Different Transport Sub-sectors 2. Prioritise and Significantly Increase Investment in Zero-/low-carbon Infrastructure 3. Massively Invest in the Development and Roll out of Zero-/low-emission Technologies 4. Focus on a Just Transition to Overcome Social and Political Barriers 5. Increase International Support and Cooperation
    Keywords: ddc:380
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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    Schools transitioning towards more climate awareness : a multi-level analysis of climate protection projects in the German school system (2022)
    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Details
    Publication Date: 2022-11-10
    Description: This thesis conceptualizes the school as a socio-technical system, in which change towards sustainable development and a transition towards more climate awareness are necessary. The multi-level perspective (MLP) framework is applied to the German school system and to climate protection projects (CPPs) as examples of niche activities integrating climate protection (CP) in the school. The thesis utilizes the analytical levels of the MLP (landscape, regime, and niche) and the concept of regulative, cognitive, and normative rules and addresses the question: How do actors in CPPs perceive drivers and barriers for transitioning towards more climate awareness in the German school system? The data were collected through expert interviews and analyzed by conducting a qualitative content analysis. The results show that the German school system is characterized by an inherent rigidity, deep-set normative role dynamics, and an unappreciated role of schools in society. They also highlight the importance of public pressure, strategic CP orientation, and hands-on approaches. CPPs can be a driving force for this in individual schools, but, overall, CP needs to be addressed more systematically in the school and more substantial efforts and reforms are necessary. Highly motivated niche actors play an important role and represent key drivers for such developments. This thesis reveals the complex and systemic nature of the challenges the German school system is faced with. It highlights the difficulties of integrating CP and the importance of substantial and transformative political action. The thesis demonstrates the crucial need to recognize the significance of schools and their actors for society and to integrate new methods and approaches into the school. This thesis also contributes to the body of literature on socio-technical systems and sustainability transitions. It offers an operationalization of the MLP and reveals strengths and limits as well as future research outlooks.
    Keywords: ddc:300
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: masterthesis , doc-type:masterThesis
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    A storyline attribution of the 2011/2012 drought in Southeastern South America (2022)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2022-08-04
    Description: The 2011/2012 summer drought in Southeastern South America (SESA) was a short but devastating event. What would this event have looked like under pre‐industrial conditions, or in a +2 degC world? We find that climate change causes the region to be at a higher risk of drought. However, we found no large‐scale changes in the half‐month water budgets. We show that the climate change induced positive precipitation trend in the region outweighs the increased temperatures and potential evapotranspiration during the 2011/2012 drought. image
    Keywords: ddc:551.5
    Language: English
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    Long‐term sulfamethazine leaching simulation in two different soils using the MACRO model (2022)
    Details
    Publication Date: 2022-08-04
    Description: Physically based models have been part of many risk assessment studies concerning pesticide or nutrient transport within (sub)catchments or at plot scale, but they are only poorly validated for simulating the transport of veterinary medicinal products. Veterinary medicinal products not only pose a risk to the quality of our waters but also tend to accumulate in soils, where they are associated with the appearance of resistant bacteria and long‐term leaching. In this study, the physically based leaching model MACRO 5.2 was applied for simulating sulfamethazine (SMZ) transport over a period of more than 10 yr. The model was set up using reversible kinetic adsorption and equilibrium adsorption forming non‐extractable residues. Two different calibration periods were used to estimate uncertainties in predicted SMZ leaching associated with calibration based on short‐term data. Using the whole period for model calibration, SMZ leaching could be simulated adequately, but parameter ranges were wide due to correlation between the parameters. When using only the first period for calibration, the quality of the prediction strongly depended on the information content of the data set. The calculation of temporal sensitivity indices revealed that the effect of complex sorption parameters on the model output increased with time. Thus, parameters that appeared insensitive in a short‐term calibration were required for reliable long‐term simulations. In conclusion, a temporal sensitivity analysis beyond the calibration period might identify parameters that were not constrained enough by the calibration procedure. This could help to confirm leaching predictions even for periods without sampling data.
    Description: Core Ideas: The MACRO model was successfully used to simulate long‐term SMZ leaching. A high information content of short‐term SMZ leaching data was key to successful long‐term simulations. The effect of environmental fate parameters (sorption, degradation) on the model outcome may change over time. Implementing complex sorption processes was mandatory for SMZ long‐term simulation. Temporal sensitivity analysis beyond the calibration span may detect parameters required for long‐term simulation.
    Keywords: ddc:363.7396
    Language: English
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    A Triad Photoanode for Visible Light‐Driven Water Oxidation via Immobilization of Molecular Polyoxometalate on Polymeric Carbon Nitride (2022)
    Details
    Publication Date: 2022-08-04
    Description: Due to their availability, low cost, nontoxicity, and tunability, polymeric carbon nitrides (CNx) represent one of the most attractive materials classes for the development of fully sustainable photo(electro)catalytic systems for solar‐driven water splitting. However, the development of CNx‐based photoanodes for visible light‐driven water oxidation to dioxygen is rather challenging, particularly due to issues related to photoelectrode stability and effective coupling of the light absorber with water oxidation catalysts. Herein, a triadic photoanode comprising a porous TiO2 electron collector scaffold sensitized by CNx coupled to a molecular cobalt polyoxometalate (CoPOM = [Co4(H2O)2(PW9O34)2]10) catalyst is reported. Complete water oxidation to dioxygen under visible (λ 〉 420 nm) light irradiation is demonstrated, with photocurrents down to relatively low bias potentials (0.2 V vs RHE). Furthermore, polyethyleneimine (PEI), a cationic polymer is shown to act as an effective and non‐sacrificial electrostatic linker for immobilization of the anionic CoPOM onto the negatively charged surface of CNx. The optimized deposition of CoPOM using the PEI linker translates directly into improved efficiency of the transfer of photogenerated holes to water molecules and to enhanced oxygen evolution. This work thus provides important design rules for effective immobilization of POM‐based catalysts into soft‐matter photoelectrocatalytic architectures for light‐driven water oxidation.
    Description: A triadic photoanode comprised of a porous TiO2 electron collector scaffold sensitized by polymeric carbon nitride and coupled to a molecular cobalt polyoxometalate (CoPOM) catalyst exhibits visible (λ 〉 420 nm) light‐driven water oxidation to dioxygen. The beneficial role of the cationic polyethyleneimine polymer as an effective electrostatic linker for immobilization of CoPOM onto carbon nitride is highlighted.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Vector Stiftung http://dx.doi.org/10.13039/501100013912
    Keywords: ddc:551.9
    Language: English
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    Thickness of Fluvial Deposits Records Climate Oscillations (2022)
    Details
    Publication Date: 2022-08-04
    Description: Fluvial deposits offer Earth’s best‐preserved geomorphic record of past climate change over geological timescales. However, quantitatively extracting this information remains challenging in part due to the complexity of erosion, sediment transport and deposition processes and how each of them responds to climate. Furthermore, sedimentary basins have the potential to temporarily store sediments, and rivers subsequently rework those sediments. This may introduce time lags into sedimentary signals and obscure any direct correlation with climate forcing. Here, using a numerical model that combines all three processes—and a new analytical solution—we show that the thickness of fluvial deposits at the outlet of a mountain river can be linked to the amplitude and period of rainfall oscillations but is modulated by the mountain uplift rate. For typical uplift rates of a few mm/yr, climate oscillations at Milankovitch periods lead to alluvial sediment thickness of tens of meters as observed in nature. We also explain the time lag of the order of 20%–25% of the forcing period that is commonly observed between the timing of maximum rainfall and erosion. By comparing to field datasets, our predictions for the thickness and time lag of fluvial deposits are broadly consistent with observations despite the simplicity of our modeling approach. These findings provide a new theoretical framework for quantitatively extracting information on past rainfall variations from fluvial deposits.
    Description: Plain Language Summary: Climate influences the evolution of terrestrial landscapes through the amount of precipitation, which provides water to erode rocks and transport sediment in rivers. At the outlets of mountain ranges, rivers can deposit part of their sediment load; the shape of the deposits is influenced by the amount of flow in the rivers. If the climate changes such that the precipitation rate increases, rivers can cut into their own previous deposits. The remaining deposits are then abandoned above the riverbed. On the contrary, if precipitation decreases, rivers tend to deposit more sediment, leading to increases in the thickness of sediments at the outlets of mountain rivers. Thus, there is a relationship between the amount of precipitations and the thickness of sediments deposited at river outlets. We study this with a computer model that allows us to relate the variations in precipitation rates to variations in thickness of fluvial terrace deposits. This work can be used to better understand how rivers respond to climatic changes, and also to reconstruct climatic variations of the past from observed river deposits.
    Description: Key Points: We use a numerical model and a new analytical solution to quantify a physical link between fluvial deposits and climate oscillations. Our method provides a theoretical framework for extracting information on past climate variations from fluvial terrace deposits. Our results explain time lag of 20%–25% of forcing period commonly observed between the timing of maximum rainfall and erosion.
    Description: TOTAL
    Description: Marie Sklodowska‐Curie grant
    Description: https://doi.org/10.5281/zenodo.3833983
    Keywords: ddc:550.724
    Language: English
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    Keeping promises? : The voluntary carbon market is faced with great expectations under uncertain conditions (2022)
    Details
    Publication Date: 2022-07-29
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: contributiontoperiodical , doc-type:contributionToPeriodical
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    An Energy Conserving Vlasov Solver That Tolerates Coarse Velocity Space Resolutions: Simulation of MMS Reconnection Events (2022)
    Details
    Publication Date: 2022-08-05
    Description: Vlasov solvers that operate on a phase‐space grid are highly accurate but also numerically demanding. Coarse velocity space resolutions, which are largely unproblematic in particle‐in‐cell (PIC) simulations, can lead to numerical heating or oscillations in continuum Vlasov methods. To address this issue, we present a new dual Vlasov solver which is based on an established positivity preserving advection scheme for the update of the distribution function and an energy conserving partial differential equation solver for the kinetic update of mean velocity and temperature. The solvers work together via moment fitting during which the maximum entropy part of the distribution function is replaced by the solution from the partial differential equation solver. This numerical scheme makes continuum Vlasov methods competitive with PIC methods concerning computational cost and enables us to model large scale reconnection in Earth's magnetosphere with a fully kinetic continuum method. The simulation results agree well with measurements by the MMS spacecraft.
    Description: Key Points: A moment fitting continuum Vlasov solver is presented that preserves positivity of the distribution function and conserves total energy. The method behaves well at low velocity space resolutions, making it competitive with PIC methods concerning computational cost. There is good agreement of the simulations with measurements of magnetic reconnection by the MMS spacecraft.
    Description: Helmholtz Association (亥姆霍兹联合会致力) http://dx.doi.org/10.13039/501100009318
    Description: https://vlasov.tp1.ruhr-uni-bochum.de/data/paper-JGR-2021
    Keywords: ddc:550 ; ddc:538.7
    Language: English
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    Melting Behavior of Rimed and Unrimed Snowflakes Investigated With Statistics of Triple‐Frequency Doppler Radar Observations (2022)
    Details
    Publication Date: 2022-08-05
    Description: Comparing the reflectivity flux at the top and bottom of the melting layer (ML) reveals the overall effect of the microphysical processes occurring within the ML on the particle population. If melting is the only process taking place and all particles scatter in the Rayleigh regime, the reflectivity flux increases in the ML by a constant factor given by the ratio of the dielectric factors. Deviations from this constant factor can indicate that either growth or shrinking processes (breakup, sublimation, and evaporation) dominate. However, inference of growth or shrinking dominance from the increase in reflectivity flux is only possible if other influences (e.g., vertical wind speed) are negligible or corrected. By analyzing radar Doppler spectra and multi‐frequency observations, we correct the reflectivity fluxes for vertical wind and categorize the height profiles by the riming degree at the ML top. We apply this reflectivity flux ratio (ZFR) approach to a multi‐month mid‐latitude winter data set that contains mostly stratiform clouds. The profiles of radar variables in the ML are found to be surprisingly similar for both unrimed and rimed profiles with slight differences, for example, in the absolute values of the reflectivity flux. Statistical analysis of the ZFR suggests that either microphysical processes other than melting are not important or strongly compensate for each other. The results seem to confirm that at least for moderately precipitating stratiform clouds, the melting‐only assumption applied in several retrievals and microphysical schemes is reasonable.
    Description: Plain Language Summary: To better predict precipitation by numerical models and quantify precipitation by observations, it is important to improve the understanding of processes in the melting layer (ML). The ML is the part of clouds where ice particles melt and become rain. We use an approach that assesses whether a tendency toward either growth or shrinking processes is evident in the ML. We assess the uncertainty of the approach, correct for different factors, and apply it to a large data set to derive robust statistics separately for profiles with different characteristic ice particle shapes above the ML. These statistics are surprisingly similar for the different characteristic ice particle shapes and suggest that either growth and shrinking processes are not important in the ML or strongly compensate for each other.
    Description: Key Points: We investigated the growth or shrinking of snowflakes in the melting layer using statistics of multi‐frequency Doppler radar observations. Reflectivity flux analysis indicates only slight differences for unrimed or rimed particles. Growth or shrinking processes either compensate each other or have, on average, only a small impact on the reflectivity flux.
    Description: German Research Foundation http://dx.doi.org/10.13039/501100001659
    Description: University of Cologne
    Description: https://github.com/markuskarrer/ZFR_riming
    Description: http://cpex-lab.de/cpex-lab/EN/Home/JOYCE-CF/JOYCE-CF_node.html
    Description: https://doi.org/10.5281/zenodo.6341509
    Description: https://doi.org/10.5281/zenodo.5959906
    Keywords: ddc:551.57
    Language: English
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    On the evaluation of climate change impact models (2022)
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-08-05
    Description: In‐depth understanding of the potential implications of climate change is required to guide decision‐ and policy‐makers when developing adaptation strategies and designing infrastructure suitable for future conditions. Impact models that translate potential future climate conditions into variables of interest are needed to create the causal connection between a changing climate and its impact for different sectors. Recent surveys suggest that the primary strategy for validating such models (and hence for justifying their use) heavily relies on assessing the accuracy of model simulations by comparing them against historical observations. We argue that such a comparison is necessary and valuable, but not sufficient to achieve a comprehensive evaluation of climate change impact models. We believe that a complementary, largely observation‐independent, step of model evaluation is needed to ensure more transparency of model behavior and greater robustness of scenario‐based analyses. This step should address the following four questions: (1) Do modeled dominant process controls match our system perception? (2) Is my model's sensitivity to changing forcing as expected? (3) Do modeled decision levers show adequate influence? (4) Can we attribute uncertainty sources throughout the projection horizon? We believe that global sensitivity analysis, with its ability to investigate a model's response to joint variations of multiple inputs in a structured way, offers a coherent approach to address all four questions comprehensively. Such additional model evaluation would strengthen stakeholder confidence in model projections and, therefore, into the adaptation strategies derived with the help of impact models.
    Description: A comprehensive evaluation of climate change impact models combining both observation‐based and response‐based strategies.
    Description: This article is categorized under: Climate Models and Modeling 〉 Knowledge Generation with Models Assessing Impacts of Climate Change 〉 Evaluating Future Impacts of Climate Change
    Description: Alexander von Humboldt‐Stiftung http://dx.doi.org/10.13039/100005156
    Description: Engineering and Physical Sciences Research Council http://dx.doi.org/10.13039/501100000266
    Keywords: ddc:551.6
    Language: English
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    The ICON Earth System Model Version 1.0 (2022)
    Details
    Publication Date: 2022-08-05
    Description: This work documents the ICON‐Earth System Model (ICON‐ESM V1.0), the first coupled model based on the ICON (ICOsahedral Non‐hydrostatic) framework with its unstructured, icosahedral grid concept. The ICON‐A atmosphere uses a nonhydrostatic dynamical core and the ocean model ICON‐O builds on the same ICON infrastructure, but applies the Boussinesq and hydrostatic approximation and includes a sea‐ice model. The ICON‐Land module provides a new framework for the modeling of land processes and the terrestrial carbon cycle. The oceanic carbon cycle and biogeochemistry are represented by the Hamburg Ocean Carbon Cycle module. We describe the tuning and spin‐up of a base‐line version at a resolution typical for models participating in the Coupled Model Intercomparison Project (CMIP). The performance of ICON‐ESM is assessed by means of a set of standard CMIP6 simulations. Achievements are well‐balanced top‐of‐atmosphere radiation, stable key climate quantities in the control simulation, and a good representation of the historical surface temperature evolution. The model has overall biases, which are comparable to those of other CMIP models, but ICON‐ESM performs less well than its predecessor, the Max Planck Institute Earth System Model. Problematic biases are diagnosed in ICON‐ESM in the vertical cloud distribution and the mean zonal wind field. In the ocean, sub‐surface temperature and salinity biases are of concern as is a too strong seasonal cycle of the sea‐ice cover in both hemispheres. ICON‐ESM V1.0 serves as a basis for further developments that will take advantage of ICON‐specific properties such as spatially varying resolution, and configurations at very high resolution.
    Description: Plain Language Summary: ICON‐ESM is a completely new coupled climate and earth system model that applies novel design principles and numerical techniques. The atmosphere model applies a non‐hydrostatic dynamical core, both atmosphere and ocean models apply unstructured meshes, and the model is adapted for high‐performance computing systems. This article describes how the component models for atmosphere, land, and ocean are coupled together and how we achieve a stable climate by setting certain tuning parameters and performing sensitivity experiments. We evaluate the performance of our new model by running a set of experiments under pre‐industrial and historical climate conditions as well as a set of idealized greenhouse‐gas‐increase experiments. These experiments were designed by the Coupled Model Intercomparison Project (CMIP) and allow us to compare the results to those from other CMIP models and the predecessor of our model, the Max Planck Institute for Meteorology Earth System Model. While we diagnose overall satisfactory performance, we find that ICON‐ESM features somewhat larger biases in several quantities compared to its predecessor at comparable grid resolution. We emphasize that the present configuration serves as a basis from where future development steps will open up new perspectives in earth system modeling.
    Description: Key Points: This work documents ICON‐ESM 1.0, the first version of a coupled model based on the ICON framework. Performance of ICON‐ESM is assessed by means of CMIP6 Diagnosis, Evaluation, and Characterization of Klima experiments at standard CMIP‐type resolution. ICON‐ESM reproduces the observed temperature evolution. Biases in clouds, winds, sea‐ice, and ocean properties are larger than in MPI‐ESM.
    Description: European Union H2020 ESM2025
    Description: European Union H2020 COMFORT
    Description: European Union H2020ESiWACE2
    Description: Deutsche Forschungsgemeinschaft TRR181
    Description: Deutsche Forschungsgemeinschaft EXC 2037
    Description: European Union H2020
    Description: Deutscher Wetterdienst
    Description: Bundesministerium fuer Bildung und Forschung
    Description: http://esgf-data.dkrz.de/search/cmip6-dkrz/
    Description: https://mpimet.mpg.de/en/science/modeling-with-icon/code-availability
    Description: http://cera-www.dkrz.de/WDCC/ui/Compact.jsp?acronym=RUBY-0_ICON-_ESM_V1.0_Model
    Keywords: ddc:550.285 ; ddc:551.63
    Language: English
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    Olivine aggregates reveal a complex collisional history of the main group pallasite parent body (2022)
    Details
    Publication Date: 2022-08-05
    Description: Olivine aggregates, bodies found in pallasites that consist of olivines with coherent grain boundaries and minor amounts of Fe‐Ni and troilite, likely represent well‐preserved samples of different mantle regions of pallasite parent bodies (PPBs). We investigated olivine aggregates from the main group pallasites Fukang, Esquel, Imilac, and Seymchan and compare their textures with results from deformation experiments. Our measurements reveal an inverse relationship between the grain size of olivines and the primary metal fraction inside olivine aggregates, which is explained by simultaneous grain growth retarded by Zener pinning in different mantle regions. Textural evidence indicates that the mantle has remained at high temperatures before initial cooling occurred shortly after pallasite formation that was likely caused by an impact. Different degrees of annealing of the deformation textures suggest that the postcollisional cooling occurred in the order Seymchan, Imilac, Esquel, and Fukang. We interpret this observation with an increasing burial depth after the collision. We also demonstrate that the mantle has not been convecting before the impact despite being at high temperature. Using the minimum critical Rayleigh number, we estimate PPB radii assuming different core radii. Our results question the recent ferromagmatism hypothesis for pallasite formation and support a multistage formation process that includes one or several impacts.
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Keywords: ddc:549.1
    Language: English
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    Plate corner subduction and rapid localized exhumation: Insights from 3D coupled geodynamic and geomorphological modelling (2022)
    Details
    Publication Date: 2022-08-05
    Description: Rapid, localized exhumation has been reported at many plate corners between adjacent subduction/collision segments. Here we use a fully‐coupled geodynamic and geomorphological modelling approach to investigate overriding plate deformation and resulting rock uplift patterns in these narrow, cuspate regions. In this study, we focus on the effects of internal deformation within a subducting convex‐upward‐shaped indenter and the strength of the interface between the upper and downgoing plate. The strongest localization of high rock uplift rates in the region above the indenter apex is predicted in experiments with a deformable lower plate, a weak interface layer and lateral shortening accommodated only by subduction (i.e., without an upper plate advance component). Our results suggest that bull’s eye shaped structures characterized by young thermochronological ages can, in principle, be reproduced numerically when taking into account a non‐rigid subducting plate together with complex brittle‐ductile rheology and stratification of the overriding lithosphere and realistically implemented fluvial erosion at its surface.
    Description: Alexander von Humboldt‐Stiftung http://dx.doi.org/10.13039/100005156
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: European Research Council http://dx.doi.org/10.13039/100010663
    Keywords: ddc:551.1
    Language: English
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    Strengths and limitations of in situ U–Pb titanite petrochronology in polymetamorphic rocks: An example from western Maine, USA (2022)
    Details
    Publication Date: 2022-09-27
    Description: Titanite is a potentially powerful U–Pb petrochronometer that may record metamorphism, metasomatism, and deformation. Titanite may also incorporate significant inherited Pb, which may lead to inaccurate and geologically ambiguous U–Pb dates if a proper correction is not or cannot be applied. Here, we present laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS)‐derived titanite U–Pb dates and trace element concentrations for two banded calcsilicate gneisses from south‐central Maine, USA (SSP18‐1A and SSP18‐1B). Single spot common Pb‐corrected dates range from 400 to 280 Ma with ±12–20 Ma propagated 2SE. Titanite grains in sample SSP18‐1B exhibit regular core‐to‐rim variations in texture, composition, and date. We identify four titanite populations: (1) 397 ± 5 Ma (95% CL) low Y + HREE cores and mottled grains, (2) 370 ± 7 Ma high Y + REE mantles and cores, (3) 342 ± 6 Ma cores with high Y + REE and no Eu anomaly, and (4) 295 ± 6 Ma LREE‐depleted rims. We interpret the increase in titanite Y + HREE between ca. 397 and ca. 370 Ma to constrain the timing of diopside fracturing and recrystallization and amphibole breakdown. Apparent Zr‐in‐titanite temperatures (803 ± 36°C at 0.5 ± 0.2 GPa) and increased XDi suggest a thermal maximum at ca. 370 Ma. Population 3 domains dated to ca. 342 Ma exhibit no Eu anomaly and are observed only in compositional bands dominated by diopside (〉80 vol%), suggesting limited equilibrium between titanite and plagioclase. Finally, low LREE and high U/Th in Population 4 titanite dates the formation of hydrous phases, such as allanite, during high XH2O fluid infiltration at ca. 295 Ma. In contrast to the well‐defined date–composition–texture relationships observed for titanite from SSP18‐1B, titanite grains from sample SSP18‐1A exhibit complex zoning patterns and little correlation between texture, composition, and date. We hypothesize that the incorporation of variable amounts of radiogenic Pb from dissolved titanite into recrystallized domains resulted in mixed dates spanning 380–330 Ma. Although titanite may reliably record multiple phases of metamorphism, these data highlight the importance of considering U–Pb data along with chemical and textural data to screen for inherited radiogenic Pb.
    Description: The University of Maine
    Description: US‐DE Fulbright Komission
    Keywords: ddc:552.4
    Language: English
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    Mesocrystalline Architecture in Hyaline Foraminifer Shells Indicates a Non‐Classical Crystallisation Pathway (2022)
    Details
    Publication Date: 2022-09-27
    Description: Calcareous foraminifer shells (tests) represent one of the most important archives for paleoenvironmental and paleoclimatic reconstruction. To develop a mechanistic understanding of the relationship between environmental parameters and proxy signals, knowledge of the fundamental processes operating during foraminiferal biomineralization is essential. Here, we apply microscopic and diffraction‐based methods to address the crystallographic and hierarchical structure of the test wall of different hyaline foraminifer species. Our results show that the tests are constructed from micrometer‐scale oriented mesocrystals built of nanometer‐scale entities. Based on these observations, we propose a mechanistic extension to the biomineralization model for hyaline foraminifers, centered on the formation and assembly of units of metastable carbonate phases to the final mesocrystal via a non‐classical particle attachment process, possibly facilitated by organic matter. This implies the presence of metastable precursors such as vaterite or amorphous calcium carbonate, along with phase transitions to calcite, which is relevant for the mechanistic understanding of proxy incorporation in the hyaline foraminifers.
    Description: Plain Language Summary: Foraminifers are single celled marine organisms typically half a millimeter in size, which form shells made of calcium carbonate. During their life, the chemical composition of their shells records environmental conditions. By analyzing fossil shells, past conditions can be reconstructed to understand ancient oceans and climate change. To do that correctly, we need to know exactly how foraminifers form their shell. We find that foraminifers build micrometer‐sized mesocrystals which are made of smaller building blocks. This means that the smallest building blocks form first and assemble to form a larger grain, which is oriented in a specific direction. To align all the building blocks, it is possible that they are first unstable and undergo transformation on assembly, during which their composition may change. By understanding and quantifying this process, the composition of the final fossil shell may be understood, ultimately leading to more reliable reconstructions of past environmental change.
    Description: Key Points: Hyaline foraminiferal shells are built of micrometer sized mesocrystalline units. Biomineralization likely includes the formation and assembly of nanoparticles. Nanometer sized units suggest non‐classical crystal growth.
    Description: https://doi.org/10.17617/3.D7HN3I
    Keywords: ddc:561.9 ; ddc:549
    Language: English
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    Lagrangian Analysis of Moisture Sources of Precipitation in the Tianshan Mountains, Central Asia (2022)
    Details
    Publication Date: 2022-09-27
    Description: The moisture sources of precipitation in the Tianshan Mountains, one of the regions with the highest precipitation in Central Asia during 1979–2017 are comprehensively and quantitatively summarized by using a Lagrangian moisture source detection technique. Continental sources provide about 93.2% of the moisture for precipitation in the Tianshan Mountain, while moisture directly from the ocean is very limited, averaging only 6.8%. Central Asia plays a dominant role in providing moisture for all sub‐regions of the Tianshan Mountains. For the Western Tianshan, moisture from April to October comes mainly from Central Asia (41.4%), while moisture from November to March is derived primarily from Western Asia (45.7%). Nearly 13.0% of moisture to precipitation for Eastern Tianshan in summer originates from East and South Asia, and the Siberia region. There is a significant decreasing trend in the moisture contribution of local evaporation and Central Asia in the Eastern Tianshan during winter. The contribution of moisture from Europe to summer precipitation in the Central and Eastern Tianshan and the contribution of the North Atlantic Ocean to summer precipitation in the Northern, Central, and Eastern Tianshan also exhibit a decreasing trend. The largest increase in moisture in Western Tianshan stems from West Asia during extreme winter precipitation months. Europe is also an important contributor to extreme precipitation in the Northern Tianshan. The moisture from East and South Asia and Siberia during extreme precipitation months in both winter and summer is significantly enhanced in the Eastern Tianshan.
    Description: Key Points: Local evaporation and Central Asia play a leading role in providing moisture for all sub‐regions of the Tianshan Mountains. The largest moisture component during the months of extreme winter precipitation for Western Tianshan derives from western Asia. Moisture from East and South Asia and Siberia during extreme precipitation months is significantly enhanced in the Eastern Tianshan.
    Description: China Scholarship Council
    Description: Humboldt‐Universität zu Berlin
    Description: https://zenodo.org/record/6451656#.YrrfbqhBwuU
    Keywords: ddc:551.6
    Language: English
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    Late Quaternary paleoenvironmental reconstructions from sediments of Lake Emanda (Verkhoyansk Mountains, East Siberia) (2022)
    Andreev, Andrei A. ; Nazarova, Larisa B. ; Lenz, Marlene M. ; [et al.]
    Details
    Publication Date: 2022-09-27
    Description: Continuous pollen and chironomid records from Lake Emanda (65°17′N, 135°45′E) provide new insights into the Late Quaternary environmental history of the Yana Highlands (Yakutia). Larch forest with shrubs (alders, pines, birches) dominated during the deposition of the lowermost sediments suggesting its Early Weichselian [Marine Isotope Stage (MIS) 5] age. Pollen‐ and chironomid‐based climate reconstructions suggest July temperatures (TJuly) slightly lower than modern. Gradually increasing amounts of herb pollen and cold stenotherm chironomid head capsules reflect cooler and drier environments, probably during the termination of MIS 5. TJuly dropped to 8 °C. Mostly treeless vegetation is reconstructed during MIS 3. Tundra and steppe communities dominated during MIS 2. Shrubs became common after ~14.5 ka bp but herb‐dominated habitats remained until the onset of the Holocene. Larch forests with shrub alder and dwarf birch dominated after the Holocene onset, ca. 11.7 ka bp. Decreasing amounts of shrub pollen during the Lateglacial are assigned to the Older Dryas and Younger Dryas with TJuly ~ 7.5 °C. TJuly increased up to 13 °C. Shrub stone pine was present after ~7.5 ka bp. The vegetation has been similar to modern since ca. 5.8 ka bp. Chironomid diversity and concentration in the sediments increased towards the present day, indicating the development of richer hydrobiological communities in response to the Holocene thermal maximum.
    Description: Russian Scientific Foundation
    Description: German Federal Ministry of Education and Research
    Description: European Research Council http://dx.doi.org/10.13039/501100000781
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: RSF
    Description: Russian Ministry of Education and Science
    Description: Federal Ministry of Education and Research
    Description: BMBF
    Keywords: ddc:560
    Language: English
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    Inspecting the Reliability of Geochemical Facies Identified for the Waterworks' Capture Zone in Germany (2022)
    Blackwell Publishing Ltd | Malden, US
    Details
    Publication Date: 2022-09-27
    Description: Little research attention has been given to validating clusters obtained from the groundwater geochemistry of the waterworks' capture zone with a prevailing lake‐groundwater exchange. To address this knowledge gap, we proposed a new scheme whereby Gaussian finite mixture modeling (GFMM) and Spike‐and‐Slab Bayesian (SSB) algorithms were utilized to cluster the groundwater geochemistry while quantifying the probability of the resulting cluster membership against each other. We applied GFMM and SSB to 13 geochemical parameters collected during different sampling periods at 13 observation points across the Barnim Highlands plateau located in the northeast of Berlin, Germany; this included 10 observation wells, two lakes, and a gallery of drinking production wells. The cluster analysis of GFMM yielded nine clusters, either with a probability ≥0.8, while the SSB produced three hierarchical clusters with a probability of cluster membership varying from 〈0.2 to 〉0.8. The findings demonstrated that the clustering results of GFMM were in good agreement with the classification as per the principal component analysis and Piper diagram. By superimposing the parameter clustering onto the observation clustering, we could identify discrepancies that exist among the parameters of a certain cluster. This enables the identification of different factors that may control the geochemistry of a certain cluster, although parameters of that cluster share a strong similarity. The GFMM results have shown that from 2002, there has been active groundwater inflow from the lakes towards the capture zone. This means that it is necessary to adopt appropriate measures to reverse the inflow towards the lakes.
    Description: Article impact statement: The probability of cluster membership quantified using an algorithm should be validated against another probabilistic‐based classifier.
    Description: Federal Ministry of Education and Research http://dx.doi.org/10.13039/501100002347
    Keywords: ddc:551.9 ; ddc:551.49
    Language: English
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    Stratospheric Moistening After 2000 (2022)
    Details
    Publication Date: 2022-09-27
    Description: The significant climate feedback of stratospheric water vapor (SWV) necessitates quantitative estimates of SWV budget changes. Model simulations driven by the newest European Centre for Medium‐Range Weather Forecast reanalysis ERA5, satellite observations from the Stratospheric Water and OzOne Satellite Homogenized data set, Microwave Limb Sounder, and in situ frost point hygrometer observations from Boulder all show substantial and persistent stratospheric moistening after a sharp drop in water vapor at the turn of the millennium. This moistening occurred mainly during 2000–2006 and SWV abundances then remained high over the last decade. We find strong positive trends in the Northern Hemisphere and weak negative trends over the South Pole, mainly during austral winter. Moistening of the tropical stratosphere after 2000 occurred during late boreal winter/spring, reached values of ∼0.2 ppm/decade, was well correlated with a warming of the cold point tropopause by ∼0.4 K/decade and can only be partially attributed to El Nino‐Southern Oscillation and volcanic eruptions.
    Description: Plain Language Summary: Water vapor is an effective greenhouse gas. Human‐induced climate change has led to warmer air in the troposphere, which consequently can hold more moisture, thus enhancing the greenhouse effect. The long‐term change in stratospheric water vapor (SWV) is less clear and currently under debate. Using satellite observations, balloon soundings and model simulations, we find an increase of SWV after 2000. This moistening occurred mainly during 2000–2006 and the stratospheric moisture content then remained high over the last decade. The increase of SWV is stronger in the Northern than in the Southern Hemisphere. Over the South Pole, a weak decrease was found. Moistening of the tropical stratosphere occurred mainly during late winter and spring, and was in line with warming of the tropical tropopause, the coldest region that separates the troposphere and stratosphere. Natural causes such as volcanic eruptions cannot completely explain this stratospheric moistening.
    Description: Key Points: Stratospheric moistening after 2000 is clearly detectable in ERA5‐driven simulations, satellite and in situ observations. Hemispheric asymmetry is found with strong positive trends in the Northern Hemisphere and weak negative trends over the South Pole. Moistening of the lower tropical stratosphere is only partially caused by El Nino‐Southern Oscillation and volcanic eruptions.
    Description: https://doi.org/10.5067/Aura/MLS/DATA2508
    Description: https://doi.org/10.5067/GLOSSAC-L3-V2.0
    Description: https://doi.org/10.5067/GLOSSAC-L3-V2.0
    Keywords: ddc:551.6
    Language: English
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    Geomagnetic Detection of the Atmospheric Acoustic Resonance at 3.8 mHz During the Hunga Tonga Eruption Event on 15 January 2022 (2022)
    Details
    Publication Date: 2022-09-29
    Description: Modeling studies have predicted that the acoustic resonance of the atmosphere during geophysical events such as earthquakes and volcanos can lead to an oscillation of the geomagnetic field with a frequency of about 4 mHz. However, observational evidence is still limited due to scarcity of suitable events. On 15 January 2022, the submarine volcano Hunga Tonga‐Hunga Ha'apai (20.5°S, 175.4°W, Tonga) erupted in the Pacific Ocean and caused severe atmospheric disturbance, providing an opportunity to investigate geomagnetic effects associated with acoustic resonance. Following the eruption, geomagnetic oscillation is observed at Apia, approximately 835 km from Hunga Tonga, mainly in the Pc 5 band (150–600 s, or 1.7–6.7 mHz) lasting for about 2 hr. The dominant frequency of the oscillation is 3.8 mHz, which is consistent with the frequency of the atmospheric oscillation due to acoustic resonance. The oscillation is most prominent in the eastward (Y) component, with an amplitude of ∼3 nT, which is much larger than those previously reported for other events (〈1 nT). Comparably large oscillation is not found at other stations located further away (〉2700 km). However, geomagnetic oscillation with a much smaller amplitude (∼0.3 nT) is observed at Honolulu, which is located near the magnetic conjugate point of Hunga Tonga, in a similar wave form as at Apia, indicating interhemispheric coupling. This is the first time that geomagnetic oscillations due to the atmospheric acoustic resonance are simultaneously detected at magnetic conjugate points.
    Description: Key Points: The effect of the January 2022 Hunga Tonga‐Hunga Ha’apai volcano eruption on the geomagnetic field is examined. Geomagnetic oscillation with a frequency of ∼3.8 mHz is observed simultaneously near the volcano and its magnetic conjugate point. The oscillation is attributed to the acoustic resonance of the atmosphere.
    Description: Coordenação de Aperfeiçoamento de Pessoal de Nível Superior http://dx.doi.org/10.13039/501100002322
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://www.intermagnet.org/data-donnee/download-eng.php
    Keywords: ddc:538.7 ; ddc:551.5
    Language: English
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    Role of Poroelasticity During the Early Postseismic Deformation of the 2010 Maule Megathrust Earthquake (2022)
    Peña, Carlos ; Metzger, Sabrina ; Heidbach, Oliver ; [et al.]
    Details
    Publication Date: 2022-09-29
    Description: Megathrust earthquakes impose changes of differential stress and pore pressure in the lithosphere‐asthenosphere system that are transiently relaxed during the postseismic period primarily due to afterslip, viscoelastic and poroelastic processes. Especially during the early postseismic phase, however, the relative contribution of these processes to the observed surface deformation is unclear. To investigate this, we use geodetic data collected in the first 48 days following the 2010 Maule earthquake and a poro‐viscoelastic forward model combined with an afterslip inversion. This model approach fits the geodetic data 14% better than a pure elastic model. Particularly near the region of maximum coseismic slip, the predicted surface poroelastic uplift pattern explains well the observations. If poroelasticity is neglected, the spatial afterslip distribution is locally altered by up to ±40%. Moreover, we find that shallow crustal aftershocks mostly occur in regions of increased postseismic pore‐pressure changes, indicating that both processes might be mechanically coupled.
    Description: Plain Language Summary: Large earthquakes modify the state of stress and pore pressure in the upper crust and mantle. These changes induce stress relaxation processes and pore pressure diffusion in the postseismic phase. The two main stress relaxation processes are postseismic slip along the rupture plane of the earthquake and viscoelastic deformation in the rock volume. These processes decay with time, but can sustain over several years or decades, respectively. The other process that results in volumetric crustal deformation is poroelasticity due to pore pressure diffusion, which has not been investigated in detail. Using postseismic surface displacement data acquired by radar satellites after the 2010 Maule earthquake, we show that poroelastic deformation may considerably affect the vertical component of the observed geodetic signal during the first months. Poroelastic deformation also has an impact on the estimation of the postseismic slip, which in turn affects the energy stored at the fault plane that is available for the next event. In addition, shallow aftershocks within the continental crust show a good, positive spatial correlation with regions of increased postseismic pore‐pressure changes, suggesting they are linked. These findings are thus important to assess the potential seismic hazard of the segment.
    Description: Key Points: A poro‐viscoelastic deformation model improves the geodetic data misfit by 14% compared to an elastic model that only accounts for afterslip. Poroelastic deformation mainly produces surface uplift and landward displacement patterns on the coastal forearc region. Neglecting poroelastic effects may locally alter the afterslip amplitude by up to ±40% near the region of maximum coseismic slip.
    Description: Helmholtz Association (亥姆霍兹联合会致力) http://dx.doi.org/10.13039/501100009318
    Keywords: ddc:551
    Language: English
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    The detection of bacterial exometabolites in marine dissolved organic matter through ultrahigh‐resolution mass spectrometry (2022)
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-10-01
    Description: Bacteria play a key role in sustaining the chemodiversity of marine dissolved organic matter (DOM), yet there is limited direct evidence of a major contribution of bacterial exometabolites to the DOM pool. This study tests whether molecular formulae of intact exometabolites can be detected in natural DOM via untargeted Fourier‐transform ion cyclotron resonance mass spectrometry (FT‐ICR‐MS). We analyzed a series of quantitative mixtures of solid‐phase extracted DOM from the deep ocean, of a natural microbial community and selected model strains of marine bacteria. Under standard instrument settings (200 broadband scans, mass range 92–1000 Da), 77% of molecular formulae were shared between the mesocosm and marine DOM. However, there was 〈 10% overlap between pure bacterial exometabolome with marine DOM, and in mixing ratios closest to mimicking natural environments (1% bacterial DOM, 99% marine DOM), only 4% of the unique bacterial exometabolites remained detectable. Further experiments with the bacterial exometabolome DOM mixtures using enhanced instrument settings resulted in increased detection of the exometabolites at low concentrations. At 1000 and 10,000 accumulated scans, 23% and 29% of the unique molecular formulae were detectable at low concentrations, respectively. Moreover, windowing a specific mass range encompassing a representative fraction of exometabolites tripled the number of unique detected formulae at low concentrations. Routine FT‐ICR‐MS settings are thus not always sufficient to distinguish bacterial exometabolome patterns from a seawater DOM background. To observe these patterns at higher sensitivity, we recommend a high scan number coupled with windowing a characteristic region of the molecular fingerprint.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.46 ; ddc:579.3 ; ddc:
    Language: English
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    Application of mixed‐effects modelling and rule‐based models to explain copper variation in soil profiles of southern Germany (2022)
    Blackwell Publishing Ltd | Oxford, UK
    Details
    Publication Date: 2022-10-01
    Description: Copper (Cu) is an essential element for plants and microorganisms and at larger concentrations a toxic pollutant. A number of factors controlling Cu dynamics have been reported, but information on quantitative relationships is scarce. We aimed to (i) quantitatively describe and predict soil Cu concentrations (CuAR) in aqua regia considering site‐specific effects and effects of pH, soil organic carbon (SOC) and cation exchange capacity (CEC), and (ii) study the suitability of mixed‐effects modelling and rule‐based models for the analysis of long‐term soil monitoring data. Thirteen uncontaminated long‐term monitoring soil profiles in southern Germany were analysed. Since there was no measurable trend of increasing CuAR concentrations with time in the respective depth ranges of the sites, data from different sampling dates were combined and horizon‐specific regression analyses including model simplifications were carried out for 10 horizons. Fixed‐ and mixed‐effects models with the site as a random effect were useful for the different horizons and significant contributions (either of main effects or interactions) of SOC, CEC and pH were present for 9, 8 and 7 horizons, respectively. Horizon‐specific rule‐based cubist models described the CuAR data similarly well. Validations of cubist models and mixed‐effects models for the CuAR concentrations in A horizons were successful for the given population after random splitting into calibration and validation samples, but not after independent validations with random splitting according to sites. Overall, site, CEC, SOC and pH provide important information for a description of CuAR concentrations using the different regression approaches. Highlights: Information on quantitative relationships for factors controlling Cu dynamics is scarce. Site, CEC, SOC and pH provide important information for a description of Cu concentrations. Validations of cubist models and mixed‐effects models for A horizons were successful for a closed population of sites.
    Description: Bavarian State Ministry of the Environment and Consumer Protection http://dx.doi.org/10.13039/501100010219
    Description: Ministry of Agriculture and Environment Mecklenburg‐Western Pomerania
    Keywords: ddc:631.4
    Language: English
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    Tides, Stratification, and Counter Rotation: The German Bight ROFI in Comparison to Other Regions of Freshwater Influence (2022)
    Details
    Publication Date: 2022-10-01
    Description: The characteristics of tidal velocity profiles and their relation to stratification are investigated based on high‐resolution field data collected at four locations in the German Bight Region of Freshwater Influence (ROFI) in the North Sea. The deployments each include two to three tidal cycles and were conducted during field campaigns in August 2016 and May 2018. The depth‐averaged semidiurnal tidal motion is dominated by a standing wave directed toward the coast, but modified by a smaller, coast‐parallel progressive wave contribution. The time series of the tidal velocity profiles consistently show tidal asymmetries with higher flood than ebb velocities near the surface and counter‐clockwise rotation of the velocity trajectories at depth. Near the surface, phase‐locked periodic changes in the sense of rotation within the tidal cycle are evident for three deployments, resulting in periodic counter‐rotation of the upper and lower layer. During these episodes, stratification of the water column is observed. Counter‐rotation is initiated after a sudden decoupling developing from the surface downward, with subsequent rapid development of stratification and velocity shear. The observed decoupling is most likely triggered by advection of the plume‐induced lateral surface density gradient by weakly sheared ebb currents toward the study site. Due to the dominance of the standing wave in the German Bight ROFI, the observed intra‐tidal variations of stratification are more similar to the Liverpool Bay and differ significantly from the Rhine ROFI, where the tidal dynamics are controlled by a progressive Kelvin wave.
    Description: Plain Language Summary; The water velocities in the German Bight are strongly influenced by river freshwater input and semidiurnal tides. While the freshwater input from the rivers has a stratifying effect, tidal motion as well as wind and waves induce mixing. These forces compete in controlling the state of the water column in a complex manner. In theory, tidal motion should describe elliptical paths. However, in reality, these ellipses can be modified for example, by periodically occurring stratification. To assess the characteristics of the semidiurnal tidal velocity profile and its variability, four instruments to measure current velocity profiles were deployed in the German Bight during August 2016 and May 2018. Measurements were carried out for the duration of up to three tidal cycles, accompanied by parallel profiles of water temperature and salinity taken from the anchored ship nearby. Results show that periodic stratification related to the river freshwater plume is associated with periodically counter‐rotating tidal currents during the tidal cycle. The measurement position relative to the location of the density front of the plume appears to be critical for the occurrence of counter‐rotation. The observed dynamics are qualitatively compared to two other well‐studied coastal ocean regions of freshwater influence.
    Description: Key Points: High‐resolution velocity and density data from the German Bight Region of Freshwater Influence are used to assess M2 tidal properties and intra‐tidal variability. M2 tidal motion is a hybrid of standing and progressive waves, with the standing wave contribution dominating. Periodic counter‐rotation of upper‐ and lower‐layer current trajectories during the tidal cycle is related to water column stratification.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.1594/PANGAEA.919168
    Description: https://doi.pangaea.de/10.1594/PANGAEA.943958
    Description: https://doi.pangaea.de/10.1594/PANGAEA.943955
    Description: https://doi.org/10.1594/PANGAEA.897214
    Keywords: ddc:551.46
    Language: English
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    The Hidden Giant: How a rift pulse triggered a cascade of sector collapses and voluminous secondary mass‐transport events in the early evolution of Santorini (2022)
    Details
    Publication Date: 2022-10-01
    Description: Volcanic island sector collapses have the potential to trigger devastating tsunamis and volcanic eruptions that threaten coastal communities and infrastructure. Considered one of the most hazardous volcano‐tectonic regions in the world, the Christiana‐Santorini‐Kolumbo Volcanic Field (CSKVF) lies in the South Aegean Sea in an active rift zone. Previous studies identified an enigmatic voluminous mass‐transport deposit west and east of Santorini emplaced during the early evolution of the edifice. However, the distribution and volume as well as the nature and emplacement dynamics of this deposit remained unknown up to now. In this study, we use an extensive dataset of high‐resolution seismic profiles to unravel the distribution and internal architecture of this deposit. We show that it is located in all basins surrounding Santorini and has a bulk volume of up to 125 km3, thus representing the largest known volcanic island mass‐transport deposit in the entire Mediterranean Sea. We propose that the deposit is the result of a complex geohazard cascade that was initiated by an intensive rift pulse. This rifting event triggered a series of smaller precursory mass‐transport events before large‐scale sector collapses occurred on the northeastern flank of the extinct Christiana Volcano and on the southeastern flank of the nascent Santorini. This was followed by the emplacement of large‐scale secondary sediment failures on the slopes of Santorini, which transitioned into debris and turbidity flows that traveled far into the neighboring rift basins. Following this cascade, a distinct change in the volcanic behaviour of the CSKVF occurred, suggesting a close relationship between crustal extension, mass transport and volcanism. Cascading geohazards seem to be more common in the evolution of marine volcanic systems than previously appreciated. Wider awareness and a better understanding of cascading effects are crucial for more holistic hazard assessments.
    Description: Schematic Reconstruction of the Santorini Mass‐Transport Cascade (SMTC): After a phase of volcanic quiescence (A), a rift pulse (B) triggered precursory mass‐wasting events (C), large‐scale sector collapses (D) and secondary sediment failures (E), which culminated in a change in the volcanic behaviour of the system (F).
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.21
    Language: English
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    Analytical Artefacts Preclude Reliable Isotope Ratio Measurement of Internal Water in Coral Skeletons (2022)
    de Graaf, Stefan ; Vonhof, Hubert B. ; Reijmer, John J. G. ; [et al.]
    Details
    Publication Date: 2022-10-01
    Description: Internal water in cold‐water and tropical coral skeletons was extracted and measured for its oxygen and hydrogen isotope ratios. Water was extracted by crushing pieces of coral hard tissue in a percussion device connected to either a cavity ring‐down spectroscopy (CRDS) system or an isotope ratio mass spectrometry (IRMS) system. Despite most samples yielding sufficient water, each analytical system produces distinct isotope patterns. Experiments show that several characteristics specific to biominerals give rise to discrepancies and analytical artefacts that preclude the acquisition of reproducible isotope data. The main complication is that internal water in biogenic carbonates is distributed in an open interconnected micro‐network that readily exchanges with external water and potentially facilitates interaction with hydration water in the finely dispersed organic matrix in the coral skeleton. Furthermore, only an isotopically fractionated part of the internal water is released from the coral skeletons upon crushing. Altogether, isotope ratio measurement of internal water in corals with bulk crushing techniques does not give primary fluid isotope ratios useful for (palaeo‐)environmental or microbiological studies. As the resulting isotope patterns can show systematic behaviour per technique, isotope data may be erroneously interpreted to reflect the original calcifying fluid when using only a single technique to isotopically characterise internal fluids in coral skeletons.
    Description: Key Points: Free water trapped inside coral skeletons was extracted and isotopically analyzed on two commonly used techniques for fluid inclusion isotope analysis. Measured oxygen and hydrogen isotope ratios do not reproduce between the techniques due to several analytical artefacts. The water extracted from coral skeletons is not of primary origin.
    Description: Nederlandse Organisatie voor Wetenschappelijk Onderzoek http://dx.doi.org/10.13039/501100003246
    Description: Western Indian Ocean Marine Science Association http://dx.doi.org/10.13039/501100009106
    Keywords: ddc:551.9
    Language: English
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    Greigite (Fe3S4) Formation in Artificial Sediments via Solid‐State Transformation of Lepidocrocite (2022)
    Details
    Publication Date: 2022-09-30
    Description: Greigite (Fe3S4) is a ferrimagnetic iron‐sulfide mineral that forms in sediments during diagenesis. Greigite growth can occur diachronously within a stratigraphic profile, complicating or overprinting environmental and paleomagnetic records. An important objective for paleo‐ and rock‐magnetic studies is to identify the presence of greigite and to discern its formation conditions. Greigite detection remains, however, challenging and its magnetic properties obscure due to the lack of pure, stable material of well‐defined grain size. To overcome these limitations, we report a new method to selectively transform lepidocrocite to greigite via the intermediate phase mackinawite (FeS). In‐situ magnetic characterization was performed on discrete samples with different sediment substrates. Susceptibility and chemical remanent magnetization increased proportionally over time, defining two distinct greigite growth regimes. Temperature dependent and constant initial growth rates indicate a solid‐state FeS to greigite transformation with an activation energy of 78–90 kJ/mol. Low and room temperature magnetic remanence and coercivity ratios match with calculated mixing curves for superparamagnetic (SP) and single domain (SD) greigite and suggest ∼25% and ∼50% SD proportions at 300 and 100 K, respectively. The mixing trend coincides with empirical data reported for natural greigite‐bearing sediments, suggesting a common SP endmember size of 5–10 nm that is likely inherited from mackinawite crystallites. The average particle size of 20–50 nm determined by X‐ray powder diffraction and electron microscopy accords with theoretical predictions of the SP/SD threshold size in greigite. The method constitutes a novel approach to synthesize greigite and to investigate its formation in sediments.
    Description: Plain Language Summary: Sediments provide continuous records of Earth's ancient magnetic field, which lend insights into the workings of the geodynamo and help to establish the geologic time scale through global magnetostratigraphic correlation. Greigite is a magnetic iron sulfide mineral that commonly forms after deposition, thereby remagnetizing the sediment and complicating interpretation of the magnetic record. Understanding greigite formation and detecting its presence is fundamental for obtaining reliable records of the paleomagnetic field, yet knowledge of how greigite grows and how its magnetic properties evolve during growth remains limited. This article outlines a novel approach to form greigite in sediments and to monitor its growth kinetics, grain size and magnetic remanence acquisition. The magnetic properties of the synthetic sediments resemble those of natural greigite‐bearing sediments and match well with theoretical calculations, which can help quantify grain sizes in sedimentary greigite. The reported method and our results contribute to a better understanding of greigite formation and chemical magnetic remanence acquisition in sediments.
    Description: Key Points: We present a new method to grow greigite in aqueous sediments and create a chemical remanent magnetization under controlled conditions. Greigite grain sizes of 20–50 nm span the superparamagnetic to single domain threshold, consistent with theoretical predictions. Our experimental hysteresis data coincide with calculated mixing curves allowing better quantification of greigite particle sizes in nature.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.5281/zenodo.6521653
    Keywords: ddc:549
    Language: English
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    A New Population of Ultra‐Relativistic Electrons in the Outer Radiation Zone (2022)
    Details
    Publication Date: 2022-09-30
    Description: Van Allen Probes measurements revealed the presence of the most unusual structures in the ultra‐relativistic radiation belts. Detailed modeling, analysis of pitch angle distributions, analysis of the difference between relativistic and ultra‐realistic electron evolution, along with theoretical studies of the scattering and wave growth, all indicate that electromagnetic ion cyclotron (EMIC) waves can produce a very efficient loss of the ultra‐relativistic electrons in the heart of the radiation belts. Moreover, a detailed analysis of the profiles of phase space densities provides direct evidence for localized loss by EMIC waves. The evolution of multi‐MeV fluxes shows dramatic and very sudden enhancements of electrons for selected storms. Analysis of phase space density profiles reveals that growing peaks at different values of the first invariant are formed at approximately the same radial distance from the Earth and show the sequential formation of the peaks from lower to higher energies, indicating that local energy diffusion is the dominant source of the acceleration from MeV to multi‐MeV energies. Further simultaneous analysis of the background density and ultra‐relativistic electron fluxes shows that the acceleration to multi‐MeV energies only occurs when plasma density is significantly depleted outside of the plasmasphere, which is consistent with the modeling of acceleration due to chorus waves.
    Description: Plain Language Summary: The most energetic electrons in the Earth Van Allen radiation belts have not been accurately measured in the past. Observations for a recent NASA's Van Allen Probes missions reviled new unique structures, such as narrow rings, and posed further scientific questions. This review shows that, unlike relativistic electrons, ultra‐relativistic electrons can be very effectively locally scattered by plasma waves produced by ions, so‐called electromagnetic ion cyclotron waves. Observations also show that acceleration from MeV to multi‐MeV occurs locally by taking energy from another type of plasma wave. These waves are called whistler‐mode waves and can accelerate particles to such high energy when total plasma density is low. The difference between the relativistic and ultra‐relativistic particles justifies the classification of these particles into a different population from the bulk population of the outer radiation belt.
    Description: Key Points: Electromagnetic ion cyclotron waves effectively scatter ultra‐relativistic electrons in the radiation belts. The local acceleration produces acceleration from MeV to multi‐MeV in the regions of low density. The difference between MeV and multi‐MeV electrons justifies the classification of these particles into a new population.
    Description: EC, H2020, H2020 Priority Excellent Science, H2020 European Research Council http://dx.doi.org/10.13039/100010663
    Description: NASA
    Description: https://rbspgway.jhuapl.edu/
    Keywords: ddc:538.7
    Language: English
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    Asteroid 2008 TC3, not a polymict ureilitic but a polymict C1 chondrite parent body? Survey of 249 Almahata Sitta fragments (2022)
    Details
    Publication Date: 2022-09-30
    Description: On October 7, 2008, the asteroid 2008 TC3 exploded as it entered the Earth’s atmosphere, producing significant dust (in the atmosphere) and delivering thousands of stones in a strewn field in Sudan, collectively known as the Almahata Sitta (AhS) stones. About 600 fragments were officially recovered in 2008 and 2009. Further rocks were collected since the fall event by local people. From these stones, 249 were classified at the Institut für Planetologie in Münster (MS) known as MS‐xxx or MS‐MU‐xxx AhS subsamples. Most of these rocks are ureilitic in origin (168; 67%): 87 coarse‐grained ureilites, 60 fine‐grained ureilites, 15 ureilites with variable texture/mineralogy, four trachyandesites, and two polymict breccias. We identified 81 non‐ureilitic fragments, corresponding to 33% of the recovered samples studied in Münster. These included chondrites, namely 65 enstatite chondrites (43 EL; 22 EH), 11 ordinary chondrites (OC), one carbonaceous chondrite, and one unique R‐like chondrite. Furthermore, three samples represent a unique type of enstatite achondrite. Since all AhS stones must be regarded as individual specimens independent from each other, the number of fresh ureilite and enstatite chondrite falls in our meteorite collections has been increased by several hundred percent. Overall, the samples weigh between 〈1 and 250 g and have a mean mass of ~15 g. If we consider—almost 15 years after the fall—the mass calculations, observations during and after the asteroid entered the atmosphere, the mineralogy of the C1 stones AhS 91A and AhS 671, and the experimental work on fitting the asteroid spectrum (e.g., Goodrich et al., 2019; Jenniskens et al., 2010; Shaddad et al., 2010), the main portion of the meteoroid was likely made of the fine‐grained (carbonaceous) dust and was mostly lost in the atmosphere. In particular, the fact that C1 materials were found has important implications for interpreting asteroid 2008 TC3's early spectroscopic results. Goodrich et al. (2019) correctly suggested that if scientists had not recovered the “water‐free” samples (e.g., ureilites, enstatites, and OC) from the AhS strewn field, 2008 TC3 would have been assumed to be a carbonaceous chondrite meteoroid. Considering that the dominating mass of the exploding meteoroid consisted of carbonaceous materials, asteroid 2008 TC3 cannot be classified as a polymict ureilite; consequently, we state that the asteroid was a polymict carbonaceous chondrite breccia, specifically a polymict C1 object that may have formed by late accretion at least 50–100 Ma after calcium–aluminum‐rich inclusions.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Alexander von Humboldt Foundation http://dx.doi.org/10.13039/100005156
    Keywords: ddc:549.112 ; ddc:523
    Language: English
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    Algorithmic Differentiation for Sensitivity Analysis in Cloud Microphysics (2022)
    Details
    Publication Date: 2022-10-04
    Description: The role of clouds for radiative transfer, precipitation formation, and their interaction with atmospheric dynamics depends strongly on cloud microphysics. The parameterization of cloud microphysical processes in weather and climate models is a well‐known source of uncertainties. Hence, robust quantification of this uncertainty is mandatory. Sensitivity analysis to date has typically investigated only a few model parameters. We propose algorithmic differentiation (AD) as a tool to detect the magnitude and timing at which a model state variable is sensitive to any of the hundreds of uncertain model parameters in the cloud microphysics parameterization. AD increases the computational cost by roughly a third in our simulations. We explore this methodology as the example of warm conveyor belt trajectories, that is, air parcels rising rapidly from the planetary boundary layer to the upper troposphere in the vicinity of an extratropical cyclone. Based on the information of derivatives with respect to the uncertain parameters, the ten parameters contributing most to uncertainty are selected. These uncertain parameters are mostly related to the representation of hydrometeor diameter and fall velocity, the activation of cloud condensation nuclei, and heterogeneous freezing. We demonstrate the meaningfulness of the AD‐estimated sensitivities by comparing the AD results with ensemble simulations spawned at different points along the trajectories, where different parameter settings are used in the various ensemble members. The ranking of the most important parameters from these ensemble simulations is consistent with the results from AD. Thus, AD is a helpful tool for selecting parameters contributing most to cloud microphysics uncertainty.
    Description: Plain Language Summary: The formation of clouds is determined by processes that act on smaller scales than weather prediction models can resolve. Consequently, a parameterization with typically hundreds of parameters is constructed to determine the effects of these processes on the resolved larger scales. These parameters are a well‐known source of uncertainty in weather and climate models. Classical attempts to quantify this uncertainty are typically limited to a few parameters. We propose algorithmic differentiation (AD) as a tool to detect parameters with the largest impact for any of the hundreds of parameters on multiple model state variables at every time step in our simulation. This increases the computational cost by roughly a third. The relevance of the AD‐estimated impact is demonstrated by comparing the AD results with ensemble simulations, where different parameter settings are used in the various ensemble members. The ranking of the most important parameters from these ensemble simulations is consistent with the results from AD. Thus, AD is a helpful tool to identify parameters objectively that contribute most to uncertainty in cloud parameterizations.
    Description: Key Points: Quantification of multi‐parameter uncertainty of cloud microphysical evolution of WCB trajectories using algorithmic differentiation. Uncertainty at every time step derived with algorithmic differentiation representative for key uncertainty over at least 30 min intervals. Parameterization of CCN activation, diameter size, and fall velocity of hydrometeors have the largest mean impact on water vapor contents.
    Description: Deutsch Forschungsgemeinschaft DFG
    Keywords: ddc:551.5
    Language: English
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    Representation of hydrological processes in a rural lowland catchment in Northern Germany using SWAT and SWAT+ (2022)
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-10-04
    Description: The latest version of the Soil and Water Assessment Tool (SWAT+) features several improvements compared with previous versions of the model, for example, the definition of landscape units that allow for a better representation of spatio‐temporal dynamics. To evaluate the new model capabilities in lowland catchments characterized by near‐surface groundwater tables and extensive tile drainage, we assess the performance of two SWAT+ model setups in comparison to a setup based on a previous SWAT model version (SWAT3S with a modified three groundwater storage model) in the Kielstau catchment in Northern Germany. The Kielstau catchment has an area of about 50 km2, is dominated by agricultural land use, and has been thoroughly monitored since 2005. In both SWAT+ setups, the catchment is divided into upland areas and floodplains, but in the first SWAT+ model setup, runoff from the hydrologic response units is summed up at landscape unit level and added directly to the stream. In the second SWAT+ model setup, runoff is routed across the landscape before it reaches the streams. Model results are compared with regard to (i) model performance for stream flow at the outlet of the catchment and (ii) aggregated as well as temporally and spatially distributed water balance components. All three model setups show a very good performance at the catchment outlet. In comparison to a previous version of the SWAT model that produced more groundwater flow, the SWAT+ model produced more tile drainage flow and surface runoff. Results from the new SWAT+ model confirm that the representation of routing processes from uplands to floodplains in the model further improved the representation of hydrological processes. Particularly, the stronger spatial heterogeneity that can be related to characteristics of the landscape, is very promising for a better understanding and model representation of hydrological fluxes in lowland areas. The outcomes of this study are expected to further prove the applicability of SWAT+ and provide useful information for future model development.
    Description: The model performance of all three model setups was very good, but the SWAT+ model setup with runoff routing between landscape units performed best. Moreover, the SWAT+ model applications predicted a greater spatial heterogeneity of the water balance components. The representation of hydrological fluxes particularly with regard to groundwater flow, surface runoff, and tile drainage flow differed considerably between the SWAT and SWAT+ model setups.
    Keywords: ddc:551.48
    Language: English
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    Air‐Sea Interactions and Water Mass Transformation During a Katabatic Storm in the Irminger Sea (2022)
    Details
    Publication Date: 2022-10-04
    Description: We use a global 5‐km resolution model to analyze the air‐sea interactions during a katabatic storm in the Irminger Sea originating from the Ammassalik valleys. Katabatic storms have not yet been resolved in global climate models, raising the question of whether and how they modify water masses in the Irminger Sea. Our results show that dense water forms along the boundary current and on the shelf during the katabatic storm due to the heat loss caused by the high wind speeds and the strong temperature contrast. The dense water contributes to the lightest upper North Atlantic Deep Water as upper Irminger Sea Intermediate Water and thus to the lower limb of the Atlantic Meridional Overturning Circulation (AMOC). The katabatic storm triggers a polar low, which in turn amplifies the near‐surface wind speed due to the superimposed pressure gradient, in addition to acceleration from a breaking mountain wave. Overall, katabatic storms account for up to 25% of the total heat loss (20 January 2020 to 30 September 2021) over the Irminger shelf of the Ammassalik area. Resolving katabatic storms in global models is therefore important for the formation of dense water in the western boundary current of the Irminger Sea, which is relevant to the AMOC, and for the large‐scale atmospheric circulation by triggering polar lows.
    Description: Plain Language Summary: Katabatic storms are outbursts of cold air associated with strong winds from coastal valleys of Greenland, in particular from the Ammassalik valleys in southeast Greenland. These storms are not resolved in global climate models because of their small spatial extent. However, they are important for the formation of dense water on the Irminger Sea shelf, because they induce a substantial heat loss from the coastal water. In this study, we resolve katabatic storms for the first time in a global climate model and analyze the water transformation caused by a single storm before quantifying the importance of katabatic storms for the entire simulation period. We find that a water mass is formed during the katabatic storm that is dense enough to contribute to the cooling and sinking of the global conveyor belt in the subpolar North Atlantic. Overall, katabatic storms account for up to 25% of the heat loss over the Irminger shelf of the Ammassalik area.
    Description: Key Points: For the first time, the direct effect of a katabatic storm on the Irminger Sea has been simulated in a global climate model. The katabatic storm induces strong heat loss and dense water formation over the Irminger shelf (Sermilik Trough) and in the boundary current. Dense water forming in the western boundary current during katabatic storms contributes to the lightest upper North Atlantic Deep Water.
    Description: Collaborative Research Centre TRR181 funded by DFG
    Description: Max Planck Society for Advancement of Science
    Description: NextGEMS
    Description: European Union’s Horizon 2020
    Description: https://hdl.handle.net/21.11116/0000-0008-ECF1-E
    Description: https://cera-www.dkrz.de/WDCC/ui/Compact.jsp?acronym=DKRZ_LTA_033_ds00010
    Description: https://mpimet.mpg.de/en/science/modeling-with-icon/code-availability
    Keywords: ddc:551.5
    Language: English
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    Robust approaches for model‐free small‐angle scattering data analysis (2022)
    Bender, Philipp ; Honecker, Dirk ; Bersweiler, Mathias ; [et al.]
    International Union of Crystallography | 5 Abbey Square, Chester, Cheshire CH1 2HU, England
    Details
    Publication Date: 2022-10-04
    Description: The small‐angle neutron scattering data of nanostructured magnetic samples contain information regarding their chemical and magnetic properties. Often, the first step to access characteristic magnetic and structural length scales is a model‐free investigation. However, due to measurement uncertainties and a restricted q range, a direct Fourier transform usually fails and results in ambiguous distributions. To circumvent these problems, different methods have been introduced to derive regularized, more stable correlation functions, with the indirect Fourier transform being the most prominent approach. Here, the indirect Fourier transform is compared with the singular value decomposition and an iterative algorithm. These approaches are used to determine the correlation function from magnetic small‐angle neutron scattering data of a powder sample of iron oxide nanoparticles; it is shown that with all three methods, in principle, the same correlation function can be derived. Each method has certain advantages and disadvantages, and thus the recommendation is to combine these three approaches to obtain robust results.
    Description: Three different approaches are compared for determination of the correlation function from the small‐angle neutron scattering data of a powder sample of iron oxide nanoparticles.
    Keywords: ddc:548
    Language: English
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    Temporal evolution of headwall erosion rates derived from cosmogenic nuclide concentrations in the medial moraines of Glacier d'Otemma, Switzerland (2022)
    Details
    Publication Date: 2022-10-04
    Description: Climate change affects the stability and erosion of high‐alpine rock walls above glaciers (headwalls) that deliver debris to glacier surfaces. Since supraglacial debris in the ablation zone alters the melt behaviour of the underlying ice, the responses of debris‐covered glaciers and of headwalls to climate change may be coupled. In this study, we analyse the beryllium‐10 (10Be)‐cosmogenic nuclide concentration history of glacial headwalls delivering debris to the Glacier d'Otemma in Switzerland. By systematic downglacier‐profile‐sampling of two parallel medial moraines, we assess changes in headwall erosion through time for small, well‐defined debris source areas. We compute apparent headwall erosion rates from 10Be concentrations ([10Be]), measured in 15 amalgamated medial moraine debris samples. To estimate both the additional 10Be production during glacial debris transport and the age of our samples we combine our field‐based data with a simple model that simulates downglacier debris trajectories. Furthermore, we evaluate additional grain size fractions for eight samples to test for stochastic mass wasting effects on [10Be]. Our results indicate that [10Be] along the medial moraines vary systematically with time and consistently for different grain sizes. [10Be] are higher for older debris, closer to the glacier terminus, and lower for younger debris, closer to the glacier head. Computed apparent headwall erosion rates vary between ~0.6 and 10.8 mm yr−1, increasing over a maximum time span of ~200 years towards the present. As ice cover retreats, newly exposed headwall surfaces may become susceptible to enhanced weathering and erosion, expand to lower elevations, and contribute formerly shielded bedrock of likely different [10Be]. Hence, we suggest that recently lower [10Be] reflect the deglaciation of the debris source areas since the end of the Little Ice Age.
    Description: In glacial landscapes, systematic downglacier‐sampling of medial moraine debris holds the potential to assess changes in headwall erosion through time. Cosmogenic beryllium‐10 (10Be) concentrations within the medial moraines of Glacier d'Otemma, Switzerland, broadly increase downglacier and translate into increasing headwall erosion rates towards the present. These trends may reflect processes associated with the exposure of new bedrock surfaces across recently deglaciating source headwalls.
    Description: European Research Council (ERC) H2020‐EU.1.1.
    Description: https://doi.org/10.5880/GFZ.3.3.2021.007
    Keywords: ddc:551
    Language: English
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    Palaeoecological signals for Mesolithic land use in a Central European landscape? (2022)
    Heidgen, Shaddai ; Marinova, Elena ; Nelle, Oliver ; [et al.]
    Details
    Publication Date: 2022-10-04
    Description: During the Early Holocene, climate was the major factor causing fires, but whether during the Mesolithic (~11.5–7.4 cal ka BP) people co‐shaped their environment by means of fire remains of debate. Few studies have tackled this question by linking high‐resolution multi‐proxy palaeoecological studies from near Mesolithic occupation sites. An Early Holocene sediment record from the Ammer Valley palaeo‐wetland in south‐west Germany was studied using pollen, micro‐ and macrocharcoal, and plant macroremains. Archaeological evidence from Early and Late Mesolithic sites of Rottenburg‐Siebenlinden allowed us to link this palaeoecological record with Mesolithic land use in the same catchment. Between 11.6 and 10.6 cal kabp,intensive wildfires reinforced the persistence of open and pioneer vegetation. A transition from a river‐dominated landscape towards a wetland with open stagnant waters at 10.6–9.5 cal ka bpmade the region attractive to hunter‐gatherers, providing various plant resources (incl. hazel). From 10.1 cal ka bponwards, Mesolithic communities may have shaped their environment by using fire as a tool to expand open areas, which were important for the implementation of their subsistence strategies. After 9.5 cal ka bp, human control over fires cannot be excluded as Mesolithic occupation phases chronologically coincide with frequent low‐intensity fires and vegetation disturbance.
    Keywords: ddc:561
    Language: English
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    Benthic Carbon Remineralization and Iron Cycling in Relation to Sea Ice Cover Along the Eastern Continental Shelf of the Antarctic Peninsula (2022)
    Details
    Publication Date: 2022-10-04
    Description: Rapid and profound climatic and environmental changes have been predicted for the Antarctic Peninsula with so far unknown impact on the biogeochemistry of the continental shelves. In this study, we investigate benthic carbon sedimentation, remineralization and iron cycling using sediment cores retrieved on a 400 mile transect with contrasting sea ice conditions along the eastern shelf of the Antarctic Peninsula. Sediments at comparable water depths of 330–450 m showed sedimentation and remineralization rates of organic carbon, ranging from 2.5 to 13 and 1.8–7.2 mmol C m−2 d−1, respectively. Both rates were positively correlated with the occurrence of marginal sea ice conditions (5%–35% ice cover) along the transect, suggesting a favorable influence of the corresponding light regime and water column stratification on algae growth and sedimentation rates. From south to north, the burial efficiency of organic carbon decreased from 58% to 27%, while bottom water temperatures increased from −1.9 to −0.1°C. Net iron reduction rates, as estimated from pore‐water profiles of dissolved iron, were significantly correlated with carbon degradation rates and contributed 0.7%–1.2% to the total organic carbon remineralization. Tightly coupled phosphate‐iron recycling was indicated by significant covariation of dissolved iron and phosphate concentrations, which almost consistently exhibited P/Fe flux ratios of 0.26. Iron efflux into bottom waters of 0.6–4.5 μmol Fe m−2 d−1 was estimated from an empirical model. Despite the deep shelf waters, a clear bentho‐pelagic coupling is indicated, shaped by the extent and duration of marginal sea ice conditions during summer, and likely to be affected by future climate change.
    Description: Plain Language Summary: The seafloor of the shallow shelf seas plays a significant role in the recycling of organic carbon and acts as a nutrient source for algae growth in the upper water layers. In Antarctic waters, the change in sea ice cover has a great impact on the growth of algae and the subsequent sinking of organic carbon to the seafloor. With global warming, profound changes in sea ice cover are expected for the Antarctic Peninsula. To better understand its imprint on the seafloor, we collected sediment samples from different locations along the eastern shelf of the Antarctic Peninsula and measured how changes in sea ice cover influence the accumulation and recycling of organic carbon. We found that moderate sea ice cover of 5%–35% increases the amount of organic carbon received by the seafloor and that the fraction that is buried in the sediments decreases from south (58%) to north (27%). We further measured that more iron, an important micro‐nutrient for algae growth, can be released from the seafloor the more organic carbon accumulates. Thus, sea ice conditions determine the organic carbon accumulation, turnover, and nutrient release at the seafloor, which are likely to be affected by future climate change.
    Description: Key Points: Antarctic shelf sediments underlying marginal sea ice cover exhibit high sedimentation and remineralization rates of organic carbon. A high degree of sedimentary Fe‐recycling is found which scales with organic carbon remineralization rates. Coupling between P and Fe recycling is observed with a constant P/Fe flux ratio of 0.26 for sediments with high Fe and P recycling rates.
    Description: Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research http://dx.doi.org/10.13039/501100003207
    Description: https://doi.org/10.1594/PANGAEA.942455
    Keywords: ddc:551.9
    Language: English
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    Sound Velocity Measurements of B2‐Fe‐Ni‐Si Alloy Under High Pressure by Inelastic X‐Ray Scattering: Implications for the Composition of Earth's Core (2022)
    Details
    Publication Date: 2022-10-04
    Description: Elastic properties of B2‐Fe0.67Ni0.06Si0.27 (15 wt.% Si) alloy have been investigated by combined high‐resolution inelastic X‐ray scattering and powder X‐ray diffraction in diamond anvil cells up to 100 GPa at room temperature. Densities (ρ), compressional (VP) and shear (VS) wave velocities were extrapolated to inner core conditions to enable comparison with the preliminary reference Earth model. The modeled aggregate compressional and shear wave velocities and densities of the two‐phase mixture of B2‐Fe0.67Ni0.06Si0.27 and hcp‐Fe‐Ni are consistent with inner core PREM values of VP, VS, and ρ based on a linear mixing model with 30(5) vol % B2‐Fe0.67Ni0.06Si0.27 and 70(5) vol % hcp Fe‐Ni, which corresponds to ∼3–5 wt.% Si and ∼5–12 wt.% Ni.
    Description: Plain Language Summary: The composition of the inner core holds key information about how Earth evolved and how current processes such as the geomagnetic field work. Because the core cannot be directly sampled, our best estimates of its composition are based on the comparison of geophysical data with laboratory measurements of candidate materials. Decades of study have shown the inner core to be composed mainly of iron (with a minor amount of nickel) alloyed with one or more light elements, such as silicon. However, the effect of Si on the geophysical properties of Fe‐Ni alloys is not well established. In this study, we performed laboratory experiments to determine the density and sound velocity of Fe‐Ni‐Si alloy under extreme pressure conditions. We compared our results with seismological determinations and found that Earth's inner core can be accounted for by a mechanical mixture of cubic Fe‐Ni‐Si and hexagonal Fe‐Ni alloys. This mixture has a bulk composition of ∼3–5 weight % Si and ∼5–12 weight % Ni and is consistent with geophysical constraints.
    Description: Key Points: Sound velocities and densities of B2‐Fe‐Ni‐Si alloy are determined at high pressure, up to 100 GPa, using inelastic X‐ray scattering and X‐ray diffraction. Seismologically observed compressional and shear wave velocities and density of Earth's inner core can be accounted for by a two‐phase mixture of 30 vol % B2‐Fe‐Ni‐Si and 70 vol % hcp Fe‐Ni alloys. Extrapolated results at inner core boundary conditions are consistent with an inner core composition containing ∼3–5 wt.% Si and ∼5–12 wt.% Ni.
    Description: Japan Society for the Promotion of Science http://dx.doi.org/10.13039/501100001691
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: JSPS Japanese‐German graduate externship
    Description: https://doi.org/10.6084/m9.figshare.13370795.v1
    Description: https://doi.org/10.6084/m9.figshare.13370792.v1
    Keywords: ddc:551.112
    Language: English
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    Spatio‐Temporal Level Variations of the Martian Seasonal South Polar Cap From Co‐Registration of MOLA Profiles (2022)
    Details
    Publication Date: 2022-10-04
    Description: The seasonal deposition and sublimation of CO2 represents a major element in the Martian volatile cycle. Here, co‐registration strategies are applied to Mars Orbiter Laser Altimeter profiles to obtain spatio‐temporal variations in snow/ice level of the Seasonal South Polar Cap (SSPC), in grid elements of 0.5° in latitude from 60° to 87°S and 10° in longitude. The maximum snow/ice level in the range of 2–2.5 m is observed over the Residual South Polar Cap. Peak level at the Residual South Polar Cap in Martian Year 25 (MY25) are found to be typically ∼0.5 m higher than those in MY24. The total volume is estimated to peak at approximately 9.4 × 1012 m3. In addition, a map of average bulk density of the SSPC during its recession is derived. It implies much more snowfall‐like precipitation at the Residual South Polar Cap and its surroundings than elsewhere on Mars.
    Description: Plain Language Summary: Each Martian year, up to one third of the atmosphere's CO2 is transported from pole to pole, being deposited and sublimated depending on the season. Accurate measurements of snow level and volume variations of the resulting seasonal polar caps can serve as crucial constraints on the Martian volatile cycles. In this study, we apply new approaches of analyzing the Mars Orbiter Laser Altimeter profiles, which lead to spatially and temporally resolved measurements of snow/ice level of the Seasonal South Polar Cap (SSPC). Based on that, the maximum snow level, interannual maximum level change from Martian Year 24 (MY24) to MY25, and how the volume of the SSPC changes with time are measured. We also estimate the bulk density of the snow/ice deposition during southern winter. It is inferred that there is much more snowfall at the Residual South Polar Cap and its surroundings than elsewhere on the planet.
    Description: Key Points: Using co‐registration of Mars Orbiter Laser Altimeter profiles, spatio‐temporal level variations of the seasonal snow/ice deposits at the Martian south pole are obtained. Maximum level can be up to 2.5 m; Peak level increased by ∼0.5 m at the Residual South Polar Cap from Martian Year 24 (MY24) to MY25. Obtained bulk density map of the seasonal deposits implies that snowfall concentrates at the Residual South Polar Cap and its surroundings.
    Description: China Scholarship Council
    Description: Deutsche Forschungsgemeinschaft
    Description: Institut National des Sciences de l’Univers
    Description: Centre National de la Recherche Scientifique
    Description: Centre National d’Etudes Spatiales
    Description: https://pds-geosciences.wustl.edu/missions/mgs/pedr.html
    Description: https://naif.jpl.nasa.gov/pub/naif/pds/data/mgs-m-spice-6-v1.0/mgsp_1000/data/
    Description: https://doi.org/10.17632/z59b9nd6s9.2
    Description: https://doi.org/10.14768/8cba4407-d6a0-4d16-aeaf-d0ebfd2b480a
    Keywords: ddc:523
    Language: English
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    Greenhouse Gas Mitigation Potential of Alternate Wetting and Drying for Rice Production at National Scale—A Modeling Case Study for the Philippines (2022)
    Kraus, David ; Werner, Christian ; Janz, Baldur ; [et al.]
    Details
    Publication Date: 2022-10-04
    Description: Worldwide, rice production contributes about 10% of total greenhouse gas (GHG) emissions from the agricultural sector, mainly due to CH4 emissions from continuously flooded fields. Alternate Wetting and Drying (AWD) is a promising crop technology for mitigating CH4 emissions and reducing the irrigation water currently being applied in many of the world's top rice‐producing countries. However, decreased emissions of CH4 may be partially counterbalanced by increased N2O emissions. In this case study for the Philippines, the national mitigation potential of AWD is explored using the process‐based biogeochemical model LandscapeDNDC. Simulated mean annual CH4 emissions under conventional rice production for the time period 2000–2011 are estimated as 1,180 ± 163 Gg CH4 yr−1. During the cropping season, this is about +16% higher than a former estimate using emission factors. Scenario simulations of nationwide introduction of AWD in irrigated landscapes suggest a considerable decrease in CH4 emissions by −23%, while N2O emissions are only increased by +8%. Irrespective of field management, at national scale, the radiative forcing of irrigated rice production is always dominated by CH4 (〉95%). The reduction potential of GHG emissions depends on, for example, number of crops per year, residue management, amount of applied irrigation water, and sand content. Seasonal weather conditions also play an important role since the mitigation potential of AWD is almost double as high in dry as compared to wet seasons. Furthermore, this study demonstrates the importance of temporal continuity, considering off‐season emissions and the long‐term development of GHG emissions across multiple years.
    Description: Plain Language Summary: Worldwide, rice production contributes to about 10% of total greenhouse gas emissions of the agricultural sector mainly due to CH4 emissions from fields that are continuously flooded. Alternate Wetting and Drying (AWD) is an alternative cropping practice where fields are irrigated a few days after the disappearance of the ponded water. This study explores the mitigation potential of nationwide introduction of AWD in the Philippines. Results from the application of a process‐based model suggest a considerable decrease in CH4 emissions by −23%. Compared to N2O, CH4 is responsible for more than 95% of the total radiative forcing under conventional or AWD field management.
    Description: Key Points: Nationwide, Alternate Wetting and Drying (AWD) reduces CH4 emissions by −23%. N2O emissions contribute to less than 5% to the total radiative forcing under conventional or AWD field management. Mitigation of AWD depends on, for example, seasonal weather conditions, cropping intensity, irrigation, residue management, and soil texture.
    Description: DFG
    Description: https://doi.org/10.35097/588
    Keywords: ddc:551.6 ; ddc:581.7
    Language: English
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    Simultaneously tracing the fate of seven metals at a global level with MaTrace‐multi (2022)
    Details
    Publication Date: 2022-10-04
    Description: Keeping materials in use for a long time is key to reducing primary material demand and environmental impacts of resource use. Recycling yields of metals should only be limited by thermodynamically unavoidable losses of the remelting processes for well‐defined scraps. In practice, however, additional dissipative losses for metals occur due to incomplete collection of end‐of‐life products, insufficient waste sorting, remelting of contaminated or diluted scrap, and the downcycling of secondary materials. Here we simultaneously trace the fate of Al, Cr, Fe, Ni, Cu, Zn, and Pb in MaTrace‐multi, a planetary dynamic material flow system. Metals pass the processes mining, fabrication, use‐phase, collection, sorting, scrap allocation, remelting, and secondary material allocation. We calculate the circularity and longevity of the cohort of metal requirements for the final demand of 1 year. Nickel is found to have the best longevity at 116 (78 to 205) years, whereas zinc only has a longevity of 47 (37 to 61) years. While nickel, on average, is used in 5.13 (3.45 to 8.78) applications before dissipation, zinc is used only in 1.94 (1.52 to 2.47) applications. Our study results can be used to model the impacts of circular economy policies and technological developments on global metal cycles beyond the scope of studies modeling one metal at a time. This article met the requirements for a Gold–Gold JIE data openness badge described at http://jie.click/badges
    Description: https://doi.org/10.17605/OSF.IO/R54C6
    Keywords: ddc:363.7282
    Language: English
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    Flexible habitat choice of pelagic bacteria increases system stability and energy flow through the microbial loop (2022)
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-10-04
    Description: Pelagic bacteria can be classified into free‐living and particle‐attached life modes, which either dwell in the water column or attach to suspended particles. Bacteria with a generalist life style, however, can actively shift between these two habitats. Globally increasing densities of natural and artificial particles enhance habitat heterogeneity, with potential consequences for system stability and trophic transfer through aquatic food webs. To better decipher the dynamics of microbial communities, we investigated the influence of adaptive vs. fixed habitat choice on species coexistence for a simplified bacterial community by analyzing a corresponding food web model, consisting of two specialist bacterial prey species (free and attached), a generalist bacterial prey species with the ability to shift between both habitats, and two protist predators, specialized on either water or particle compartment. For simplicity we assume a shared resource pool, considering particles only for colonization but not as a source for nutrients or carbon, that is, inert particles like microplastics or inorganic sediments. The model predicts coexistence on a cyclic attractor between fixed and flexible bacteria, if the costs for adaptive habitat choice can be balanced by adaptation speed. The presence of adaptive prey dampens predator–prey cycle amplitudes, contributing to system stabilization resulting in higher mean predator biomass compared to specialist prey only. Thus, in pelagic microbial systems, flexible habitat choice at the prey level has important implications for system stability and magnitude of energy flow through the microbial loop.
    Description: German Ministry of Education and Science
    Description: German Science Foundation (DFG)
    Keywords: ddc:579.3
    Language: English
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    Basin‐scale estimates of greenhouse gas emissions from the Mara River, Kenya: Importance of discharge, stream size, and land use/land cover (2022)
    Mwanake, Ricky M. ; Gettel, Gretchen M. ; Ishimwe, Clarisse ; [et al.]
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-10-04
    Description: Greenhouse gas fluxes (CO2, CH4, and N2O) from African streams and rivers are under‐represented in global datasets, resulting in uncertainties in their contributions to regional and global budgets. We conducted year‐long sampling of 59 sites in a nested‐catchment design in the Mara River, Kenya in which fluxes were quantified and their underlying controls assessed. We estimated annual basin‐scale greenhouse gas emissions from measured in‐stream gas concentrations, modeled gas transfer velocities, and determined the sensitivity of up‐scaling to discharge. Based on the total annual CO2‐equivalent emissions calculated from global warming potentials (GWP), the Mara basin was a net greenhouse gas source (294 ± 35 Gg CO2 eq yr−1). Lower‐order streams (1–3) contributed 81% of the total fluxes, and higher stream orders (4–8) contributed 19%. Cropland‐draining streams also exhibited higher fluxes compared to forested streams. Seasonality in stream discharge affected stream widths (and stream area) and gas exchange rates, strongly influencing the basin‐wide annual flux, which was 10 times higher during the high and medium discharge periods than the low discharge period. The basin‐wide estimate was underestimated by up to 36% if discharge was ignored, and up to 37% for lower stream orders. Future research should therefore include seasonality in stream surface areas in upscaling procedures to better constrain basin‐wide fluxes. Given that agricultural activities are a major factor increasing riverine greenhouse gas fluxes in the study region, increased conversion of forests and agricultural intensification has the possibility of increasing the contribution of the African continent to global greenhouse gas sources.
    Description: Deutscher Akademischer Austauschdienst http://dx.doi.org/10.13039/501100001655
    Description: IHE Delft Institute for Water Education
    Description: Federal Ministry of Education and Research http://dx.doi.org/10.13039/501100002347
    Description: Helmholtz Association http://dx.doi.org/10.13039/501100009318
    Description: TERENO Bavarian Alps/ Pre‐Alps Observatory
    Keywords: ddc:551
    Language: English
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    Deepening the Late Quaternary's Deep Ocean Carbon Mysteries (2022)
    Details
    Publication Date: 2022-10-04
    Description: Changes to the carbon content of the deep ocean, the largest reservoir in the surficial carbon cycle, are capable of altering atmospheric carbon dioxide concentrations and thereby Earth's climate. While the role of the deep ocean's carbon inventory in the last ice age has been thoroughly investigated, comparatively little is known about whether the deep ocean contributed to the change in the pacing and intensity of ice ages around 1 million years ago during the Mid‐Pleistocene Transition (MPT). Qin et al. (2022, https://doi.org/10.1029/2021GL097121) provide new reconstructions of deep ocean carbonate ion saturation, a proxy for carbon content, from the deep Pacific Ocean across the MPT. Intriguingly, their results show that a reduction in deep Pacific carbonate ion saturation across the MPT occurred at different intervals from carbonate ion saturation decline in the deep Atlantic Ocean. These results suggest a more nuanced contribution of whole‐ocean carbon sequestration to the climate changes reconstructed across the MPT.
    Description: Plain Language Summary: Earth's periodic ice ages became longer and more intense around 1 million years ago. While the underlying reasons for this climate change remain debated, it is widely understood that the deep ocean may have played an important role by storing the potent greenhouse gas carbon dioxide away from the atmosphere. New research by Qin et al. (2022, https://doi.org/10.1029/2021gl097121) shows that the deep Pacific Ocean did indeed accumulate additional carbon around the time of this million‐year old climate transition. However, the new results also show that Pacific Ocean accumulated carbon over different intervals than the Atlantic Ocean, deepening the mystery around how and why this carbon uptake occurred.
    Description: Key Points: The deep Atlantic and Pacific Oceans accumulated carbon at different intervals during the mid‐Pleistocene transition.
    Description: National Science Foundation http://dx.doi.org/10.13039/100000001
    Description: https://doi.org/10.1029/2021GL097121
    Keywords: ddc:551
    Language: English
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    Effective buoyancy and CAPE: Some implications for tropical cyclones (2022)
    John Wiley & Sons, Ltd | Chichester, UK
    Details
    Publication Date: 2022-10-04
    Description: We review the widely used concepts of “buoyancy” and “convective available potential energy” (CAPE) in relation to deep convection in tropical cyclones and discuss their limitations. A fact easily forgotten in applying these concepts is that the buoyancy force of an air parcel, as often defined, is non‐unique because it depends on the arbitrary definition of a reference density field. However, when calculating CAPE, the buoyancy of a lifted air parcel is related to the specific reference density field along a vertical column passing through that parcel. Both concepts can be generalized for a vortical flow and to slantwise ascent of a lifted air parcel in such a flow. In all cases, the air parcel is assumed to have infinitely small dimensions. In this article, we explore the consequences of generalizing buoyancy and CAPE for buoyant regions of finite size that perturb the pressure field in their immediate environment. Quantitative calculations of effective buoyancy, defined as the sum of the conventional buoyancy and the static vertical perturbation pressure gradient force induced by it, are shown for buoyant regions of finite width. For a judicious choice of reference density, the effective buoyancy per unit mass is essentially a unique force, independent of the reference density, but its distribution depends on the horizontal scale of the buoyant region. A corresponding concept of “effective CAPE” is introduced and its relevance to deep convection in tropical cyclones is discussed. The study is conceived as a first step to understanding the decreasing ability of inner‐core deep convection in tropical cyclones to ventilate the mass of air converging in the frictional boundary layer as the vortex matures and decays.
    Description: The buoyancy force of an infinitesimally small air parcel is non‐unique, depending on the arbitrary definition of a reference density field. When calculating the “convective available potential energy” (CAPE), the buoyancy of a lifted air parcel is related to the reference density field along a vertical column passing through that parcel. We generalize buoyancy and CAPE for buoyant regions of finite size that perturb the pressure field in their immediate environment and discuss the relevance to deep convection in tropical cyclones.
    Keywords: ddc:551.5
    Language: English
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    Performance of a Rotational Sensor to Decipher Volcano Seismic Signals on Etna, Italy (2022)
    Eibl, Eva P. S. ; Rosskopf, Martina ; Sciotto, Mariangela ; [et al.]
    Details
    Publication Date: 2022-10-04
    Description: Volcano‐seismic signals such as long‐period events and tremor are important indicators for volcanic activity and unrest. However, their wavefield is complex and characterization and location using traditional seismological instrumentation is often difficult. In 2019 we recorded the full seismic wavefield using a newly developed 3C rotational sensor co‐located with a 3C traditional seismometer on Etna, Italy. We compare the performance of the rotational sensor, the seismometer and the Istituto Nazionale di Geofisica e Vulcanologia‐Osservatorio Etneo (INGV‐OE) seismic network with respect to the analysis of complex volcano‐seismic signals. We create event catalogs for volcano‐tectonic (VT) and long‐period (LP) events combining a STA/LTA algorithm and cross‐correlations. The event detection based on the rotational sensor is as reliable as the seismometer‐based detection. The LP events are dominated by SH‐type waves. Derived SH phase velocities range from 500 to 1,000 m/s for LP events and 300–400 m/s for volcanic tremor. SH‐waves compose the tremor during weak volcanic activity and SH‐ and SV‐waves during sustained strombolian activity. We derive back azimuths using (a) horizontal rotational components and (b) vertical rotation rate and transverse acceleration. The estimated back azimuths are consistent with the INGV‐OE event location for (a) VT events with an epicentral distance larger than 3 km and some closer events, (b) LP events and tremor in the main crater area. Measuring the full wavefield we can reliably analyze the back azimuths, phase velocities and wavefield composition for VT, LP events and tremor in regions that are difficult to access such as volcanoes.
    Description: Plain Language Summary: Traditional seismographs usually include mass and spring systems which measure vibrations constrained to up‐down, north‐south and east‐west directions. We compare the traditional seismometer to a rotational sensor which measures ground rotation around the same three directions. We installed a rotational sensor on Etna volcano in 2019 to test these new sensors in a volcanic environment. We compare the performance of the rotational sensor, a traditional seismometer and the Istituto Nazionale di Geofisica e Vulcanologia‐Osservatorio Etneo (INGV‐OE) seismometer network. We detect two types of a few second long earthquakes and find that the rotational sensor performs as good as the seismometer. We use the rotational sensor to calculate directions of the earthquake locations and find that most directions agree with the INGV‐OE network location and the area of the active craters. We find that for some earthquakes the ground only moved horizontally while for others it also moved up and down. Using a rotational sensor on a volcano we can easily and reliably estimate the ground motion, the speed of the earthquake waves in the ground and understand better how these earthquakes are generated.
    Description: Key Points: We tested the performance of a rotational sensor compared to a seismometer and a seismic network using long‐period (LP), volcano‐tectonic (VT) events and tremor on Etna. LP and VT events are dominated by SH‐ and SV‐waves, respectively. Tremor changed from SH‐ to a mixed wavefield during strombolian eruptions. LP event and tremor back azimuths point to the main craters consistent with the Istituto Nazionale di Geofisica e Vulcanologia location; VT event back azimuths are at times consistent.
    Description: Eurovolc
    Description: Daimler Benz Foundation
    Description: https://doi.org/10.14470/ME7564062119
    Keywords: ddc:551.2
    Language: English
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    New impact diagnostics for cross‐validation of different observation types (2022)
    John Wiley & Sons, Ltd | Chichester, UK
    Details
    Publication Date: 2022-10-04
    Description: New cross‐validation diagnostics have been derived by further partitioning well‐established impact diagnostics. They are related to consistency relations, the most prominent of which indicates whether the first‐guess departures of a given observation type pull the model state into the direction of the verifying data (when processed with the ensemble estimated model error covariances). Alternatively, this can be regarded as cross‐validation between model error covariance estimates from the ensemble (which are used in the data assimilation system) and estimates diagnosed directly from the observations. A statistical cross‐validation tool has been developed that includes an indicator of statistical significance as well as a normalization that makes the statistical comparison largely independent from the total number of data and the closeness of their collocation. We also present a version of these diagnostics related to single‐observation experiments that exploits the same consistency relations but is easier to compute. Diagnostics computed within the Deutscher Wetterdienst's localized ensemble transform Kalman filter (LETKF) are presented for various kinds of bins. Results from well‐established in‐situ measurements are taken as a benchmark for more complex observations. Good agreement is found for radio‐occultation bending angle measurements, whereas atmospheric motion vectors are generally also beneficial but substantially less optimal than the corresponding in‐situ measurements. This is consistent with reported atmospheric motion vector height assignment problems. To illustrate its potential, a recent example is given where the method allowed identifying bias problems of a subgroup of aircraft measurements. Another diagnostic relationship compares the information content of the analysis increments with a theoretical optimum. From this, the information content of the LETKF increments is found to be considerably lower than those of the deterministic hybrid ensemble–variational system, which is consistent with the LETKF's limitation to the comparably low‐dimensional ensemble space for finding the optimal analysis.
    Description: New cross‐validation diagnostics are presented, allowing to test the consistent use of different observation types in the data assimilation system. The figure gives an example in which these new diagnostics allowed identification of the detrimental impact of a group of aircraft measurements (which as a consequence has now been blacklisted in the Deutscher Wetterdienst's operational system). More precisely, brown colors in this plot indicate regions where these aircraft measurements pulled the analysis state away from radiosonde observations.
    Keywords: ddc:551.5
    Language: English
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    Millimetre scale aeration of the rhizosphere and drilosphere (2022)
    Blackwell Publishing Ltd | Oxford, UK
    Details
    Publication Date: 2022-10-04
    Description: Soil aeration is a critical factor for oxygen‐limited subsoil processes, as transport by diffusion and advection is restricted by the long distance to the free atmosphere. Oxygen transport into the soil matrix is highly dependent on its connectivity to larger pore channels like earthworm and root colonised biopores. Here we hypothesize that the soil matrix around biopores represents different connectivity depending on biopore genesis and actual coloniser. We analysed the soil pore system of undisturbed soil core samples around biopores generated or colonised by roots and earthworms and compared them with the pore system of soil, not in the immediacy of a biopore. Oxygen partial pressure profiles and gas relative diffusion was measured in the rhizosphere and drilosphere from the biopore wall into the bulk soil with microelectrodes. The measurements were linked with structural features such as porosity and connectivity obtained from X‐ray tomography and image analysis. Aeration was enhanced in the soil matrix surrounding biopores in comparison to the bulk soil, shown by higher oxygen concentrations and higher relative diffusion coefficients. Biopores colonised by roots presented more connected lateral pores than earthworm colonised ones, which resulted in enhanced aeration of the rhizosphere compared to the drilosphere. This has influenced biotic processes (microbial turnover/mineralization or root respiration) at biopore interfaces and highlights the importance of microstructural features for soil processes and their dependency on the biopore's coloniser.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:631.4
    Language: English
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    Variability in the Concentration of Lithium in the Indo‐Pacific Ocean (2022)
    Details
    Publication Date: 2022-10-04
    Description: Lithium has limited biological activity and can readily replace aluminium, magnesium and iron ions in aluminosilicates, making it a proxy for the inorganic silicate cycle and its potential link to the carbon cycle. Data from the North Pacific Ocean, tropical Indian Ocean, Southern Ocean and Red Sea suggest that salinity normalized dissolved lithium concentrations vary by up to 2%–3% in the Indo‐Pacific Ocean. The highest lithium concentrations were measured in surface waters of remote North Pacific and Indian Ocean stations that receive relatively high fluxes of dust. The lowest dissolved lithium concentrations were measured just below the surface mixed layer of the stations with highest surface water concentrations, consistent with removal into freshly forming aluminium rich phases and manganese oxides. In the North Pacific, water from depths 〉2,000 m is slightly depleted in lithium compared to the initial composition of Antarctic Bottom Water, likely due to uptake of lithium by authigenically forming aluminosilicates. The results of this study suggest that the residence time of lithium in the ocean may be significantly shorter than calculated from riverine and hydrothermal fluxes.
    Description: Key Points: Li/Na ratios vary by up to 2%–3% in the Indian and Pacific Oceans. Authigenic formation of aluminosilicates slightly deplete deep‐water lithium concentrations in the North Pacific. The residence time of lithium in the ocean is 240,000 ± 70,000 years, based on removal from North Pacific deep‐water.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: MoES, Indian National Centre for Ocean Information Services http://dx.doi.org/10.13039/501100004814
    Description: National Science Foundation USA
    Description: https://doi.pangaea.de/10.1594/PANGAEA.941888
    Keywords: ddc:551
    Language: English
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    Reassessing evidence of Moon–Earth dynamics from tidal bundles at 3.2 Ga (Moodies Group, Barberton Greenstone Belt, South Africa) (2022)
    Details
    Publication Date: 2022-10-04
    Description: Past orbital parameters of the Moon are difficult to reconstruct from geological records because relevant data sets of tidal strata are scarce or incomplete. The sole Archean data point is from the Moodies Group (ca 3.22 Ga) of the Barberton Greenstone Belt, South Africa. From the time‐series analysis of tidal bundles from a well‐exposed subaqueous sand wave of this unit, Eriksson and Simpson (Geology, 28, 831) suggested that the Moon’s anomalistic month at 3.2 Ga was closer to 20 days than the present 27.5 days. This is in apparent accordance with models of orbital mechanics which place the Archean Moon in a closer orbit with a shorter period, resulting in stronger tidal action. Although this study’s detailed geological mapping and section measuring of the site confirmed that the sandstone bed in question is likely a migrating dune, the presence of angular mud clasts, channel‐margin slumps, laterally aggrading channel fills and bidirectional paleocurrents in overlying and underlying beds suggests that this bedform was likely located in a nearshore channel near lower‐intertidal flats and subtidal estuarine bars; it thus carries risk of incomplete preservation. Repeated measurements of foreset thicknesses along the published traverse, measured perpendicular to bedding, failed to show consistent spectral peaks. Larger data sets acquired along traverses measured parallel to bedding along the 20.5 m wide exposure are affected by minor faulting, uneven outcrop weathering, changing illumination, weather, observer bias and show a low reproducibility. The most robust measurements herein confirm the periodicity peak of approximately 14 in the original data of Eriksson and Simpson (Geology, 28, 831). Because laminae may have been eroded, the measurements may represent a lower bound of about 28 lunar days per synodic month. This estimate agrees well with Earth–Moon dynamic models which consider the conservation of angular momentum and place the Archaean Moon in a lower orbit around a faster‐spinning Earth.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.3 ; ddc:556
    Language: English
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    Arctic – Atlantic Exchange of the Dissolved Micronutrients Iron, Manganese, Cobalt, Nickel, Copper and Zinc With a Focus on Fram Strait (2022)
    Details
    Publication Date: 2022-10-04
    Description: The Arctic Ocean is considered a source of micronutrients to the Nordic Seas and the North Atlantic Ocean through the gateway of Fram Strait (FS). However, there is a paucity of trace element data from across the Arctic Ocean gateways, and so it remains unclear how Arctic and North Atlantic exchange shapes micronutrient availability in the two ocean basins. In 2015 and 2016, GEOTRACES cruises sampled the Barents Sea Opening (GN04, 2015) and FS (GN05, 2016) for dissolved iron (dFe), manganese (dMn), cobalt (dCo), nickel (dNi), copper (dCu) and zinc (dZn). Together with the most recent synopsis of Arctic‐Atlantic volume fluxes, the observed trace element distributions suggest that FS is the most important gateway for Arctic‐Atlantic dissolved micronutrient exchange as a consequence of Intermediate and Deep Water transport. Combining fluxes from FS and the Barents Sea Opening with estimates for Davis Strait (GN02, 2015) suggests an annual net southward flux of 2.7 ± 2.4 Gg·a−1 dFe, 0.3 ± 0.3 Gg·a−1 dCo, 15.0 ± 12.5 Gg·a−1 dNi and 14.2 ± 6.9 Gg·a−1 dCu from the Arctic toward the North Atlantic Ocean. Arctic‐Atlantic exchange of dMn and dZn were more balanced, with a net southbound flux of 2.8 ± 4.7 Gg·a−1 dMn and a net northbound flux of 3.0 ± 7.3 Gg·a−1 dZn. Our results suggest that ongoing changes to shelf inputs and sea ice dynamics in the Arctic, especially in Siberian shelf regions, affect micronutrient availability in FS and the high latitude North Atlantic Ocean.
    Description: Plain Language Summary: Recent studies have proposed that the Arctic Ocean is a source of micronutrients such as dissolved iron (dFe), manganese (dMn), cobalt (dCo), nickel (dNi), copper (dCu) and zinc (dZn) to the North Atlantic Ocean. However, data at the Arctic Ocean gateways including Fram Strait and the Barents Sea Opening have been missing to date and so the extent of Arctic micronutrient transport toward the Atlantic Ocean remains unquantified. Here, we show that Fram Strait is the most important gateway for Arctic‐Atlantic micronutrient exchange which is a result of deep water transport at depths 〉500 m. Combined with a flux estimate for Davis Strait, this study suggests that the Arctic Ocean is a net source of dFe, dNi and dCu, and possibly also dCo, toward the North Atlantic Ocean. Arctic‐Atlantic dMn and dZn exchange seems more balanced. Properties in the East Greenland Current showed substantial similarities to observations in the upstream Central Arctic Ocean, indicating that Fram Strait may export micronutrients from Siberian riverine discharge and shelf sediments 〉3,000 km away. Increasing Arctic river discharge, permafrost thaw and coastal erosion, all consequences of ongoing climate change, may therefore alter future Arctic Ocean micronutrient transport to the North Atlantic Ocean.
    Description: Key Points: Fram Strait is the major gateway for Arctic‐Atlantic exchange of the dissolved micronutrients Fe, Mn, Co, Ni, Cu and Zn. The Arctic is a net source of dissolved Fe, Co, Ni and Cu to the Nordic Seas and toward the North Atlantic; Mn and Zn exchange are balanced. Waters of the Central Arctic Ocean, including the Transpolar Drift, are the main drivers of gross Arctic micronutrient export.
    Description: German Research Foundation
    Description: Netherlands Organization for Scientific Research
    Description: https://doi.pangaea.de/10.1594/PANGAEA.859558
    Description: https://doi.pangaea.de/10.1594/PANGAEA.871030
    Description: https://doi.pangaea.de/10.1594/PANGAEA.868396
    Description: https://doi.pangaea.de/10.1594/PANGAEA.905347
    Description: https://dataportal.nioz.nl/doi/10.25850/nioz/7b.b.jc
    Description: https://doi.pangaea.de/10.1594/PANGAEA.933431
    Description: https://www.bco-dmo.org/dataset/718440
    Description: https://doi.org/10.1594/PANGAEA.936029
    Description: https://doi.org/10.1594/PANGAEA.936027
    Description: https://doi.pangaea.de/10.1594/PANGAEA.927429
    Keywords: ddc:551.9
    Language: English
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    Contrasting State‐Dependent Effects of Natural Forcing on Global and Local Climate Variability (2022)
    Details
    Publication Date: 2022-10-04
    Description: Natural forcing from solar and volcanic activity contributes significantly to climate variability. The post‐eruption cooling of strong volcanic eruptions was hypothesized to have led to millennial‐scale variability during Glacials. Cooling induced by volcanic eruption is potentially weaker in the warmer climate. The underlying question is whether the climatic response to natural forcing is state‐dependent. Here, we quantify the response to natural forcing under Last Glacial and Pre‐Industrial conditions in an ensemble of climate model simulations. We evaluate internal and forced variability on annual to multicentennial scales. The global temperature response reveals no state dependency. Small local differences result mainly from state‐dependent sea ice changes. Variability in forced simulations matches paleoclimate reconstructions significantly better than in unforced scenarios. Considering natural forcing is therefore important for model‐data comparison and future projections.
    Description: Plain Language Summary: Climate variability describes the spatial and temporal variations of Earth's climate. Understanding these variations is important for estimating the occurrence of extreme climate events such as droughts. Yet, it is unclear whether climate variability depends on the mean surface temperature of the Earth or not. Here, we investigate the effects of natural forcing from volcanic eruptions and solar activity changes on climate variability. We compare simulations of a past (cold) and present (warm) climate with and without volcanism and solar changes. We find that overall, the climate system responds similarly to natural forcing in the cold and warm state. Small local differences mainly occur where ice can form. To evaluate the simulated variability, we use data from paleoclimate archives, including trees, ice‐cores, and marine sediments. Climate variability from forced simulations agrees better with the temperature variability obtained from data. Natural forcing is therefore critical for reliable simulation of variability in past and future climates.
    Description: Key Points: We present Glacial/Interglacial climate simulations and quantify effects of time‐varying volcanic and solar forcing on climate variability. The mean global and local response to these forcings is similar in Glacial and Interglacial climate, suggesting low state dependency. In both climate states, modeled temperature variance agrees better with palaeoclimate data when volcanic and solar forcing is included.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Heinrich Böll Stiftung (Heinrich Böll Foundation) http://dx.doi.org/10.13039/100009379
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: https://doi.org/10.5281/zenodo.6074747
    Description: https://github.com/paleovar/StateDependency
    Description: https://doi.org/10.5281/zenodo.6474769
    Keywords: ddc:551.6
    Language: English
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    Climates of democracy: Skeptical, rational, and radical imaginaries (2022)
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-10-05
    Description: How will the theories and practices of democracy fare in a climate changing world? Are conventional democratic institutions ultimately doomed or are they able to become more responsive to a changing climate? Is there a need to reimagine democracy and how might it be reimagined? This article reviews the different responses to these questions by distinguishing between three “political imaginaries” in which the relationship between climate change and democracy takes distinct forms. I start by showing how the concept of “political imaginaries” can facilitate the comparison of the different ways in which the relation between democracy and climate change is constructed, before reviewing three such imaginaries. The skeptical imaginary, found in the “eco‐authoritarianism” of the 1970s that is echoed by much sociopolitical analysis today, casts doubt on the possibilities of democratic mechanisms to respond adequately and swiftly to the problem of climate change. Those who resist such skepticism often defend democracy by arguing that institutions and processes of democracy can be made more “ecologically rational”—the rational imaginary of climate democracy involves improvements in political representation and participation. Finally, I present the alternative radical democratic imaginary, in which the crisis of climate change provides a moment for the rupture of existing sociopolitical structures and the formation of alternatives. The article concludes that although none of these imaginaries is able to capture the entirety of climate change politics around the world, the radical democratic imaginary is responsive to the inevitable and valuable plurality around the issue of climate change. This article is categorized under: Climate, Nature, and Ethics 〉 Ethics and Climate Change Policy and Governance 〉 Multilevel and Transnational Climate Change Governance
    Description: Climate protests may mobilise new political subjects.
    Keywords: ddc:363.70561
    Language: English
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    Spatial Markov Model for the Prediction of Travel‐Time‐Based Solute Dispersion in Three‐Dimensional Heterogeneous Media (2022)
    Details
    Publication Date: 2022-10-05
    Description: In recent years, Spatial Markov Models have gained popularity in simulating solute transport in heterogeneous formations. They describe the transition times of particles between equidistant observation planes by statistical distributions, assuming correlation of the transit times of individual particles between subsequent steps. By this, the approach naturally captures preasymptotic solute dispersion. In this study, we analyze Spatial Markov Models assuming bivariate log‐normal distributions of the particle slowness (i.e., the inverse velocity) in subsequent transitions. The model is fully parameterized by the mean Eulerian velocity, the variance of the log‐slowness, and the correlation coefficient of log‐slowness in subsequent steps. We derive closed‐form expressions for distance‐dependent ensemble dispersion, which is defined in terms of the second‐central moments of the solute breakthrough curves. We relate the coefficients to the properties of the underlying log‐hydraulic conductivity field assuming second‐order stationarity. The results are consistent with linear stochastic theory in the limit of small log‐conductivity variances, while the approach naturally extends to high‐variance cases. We demonstrate the validity of the approach by comparison to three‐dimensional particle‐tracking simulations of advective transport in heterogeneous media with isotropic, exponential correlation structure for log‐conductivity variances up to five. This study contributes to relating solute dispersion to metrics of the porous‐medium structure in cases of strong heterogeneity.
    Description: Key Points: We derive closed‐form expressions of ensemble dispersion in the spatial‐Markov framework of solute transport. The expressions are consistent with linear theory in the limit of small log‐conductivity variances, but extend to high‐variance cases. Comparison to particle‐tracking simulations of advective transport in 3‐D heterogeneous domains show excellent agreement.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.5281/zenodo.6554308
    Description: https://www.hsl.rl.ac.uk/catalogue/hsl_mi20.html
    Keywords: ddc:550
    Language: English
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    MAGEMin, an Efficient Gibbs Energy Minimizer: Application to Igneous Systems (2022)
    Details
    Publication Date: 2022-10-05
    Description: Prediction of stable mineral equilibria in the Earth's lithosphere is critical to unravel the tectonomagmatic history of exposed geological sections. While the recent advances in geodynamic modeling allow us to explore the dynamics of magmatic transfer in solid mediums, there is to date no available thermodynamic package that can easily be linked and efficiently be accounted for the computation of phase equilibrium in magmatic systems. Moreover, none of the existing tools fully exploit single point calculation parallelization, which strongly hinders their applicability for direct geodynamic coupling or for thermodynamic database inversions. Here, we present a new Mineral Assemblage Gibbs Energy Minimizer (magemin). The package is written as a parallel C library, provides a direct Julia interface, and is callable from any petrological/geodynamic tool. For a given set of pressure, temperature, and bulk‐rock composition magemin uses a combination of linear programming, extended Partitioning Gibbs Energy and gradient‐based local minimization to compute the stable mineral assemblage. We apply our new minimization package to the igneous thermodynamic data set of Holland et al. (2018), https://doi.org/10.1093/petrology/egy048 and produce several phase diagrams at supra‐solidus conditions. The phase diagrams are then directly benchmarked against thermocalc and exhibit very good agreement. The high scalability of magemin on parallel computing facilities opens new horizons, for example, for modeling reactive magma flow, for thermodynamic data set inversion, and for petrological/geophysical applications.
    Description: Plain Language Summary: Understanding magmatic systems requires knowing how rocks melt. Because a single melting experiment can easily take weeks, it is impossible to do enough experiments to cover the whole range of pressure, temperature, and composition relevant for magmatic systems. We therefore need a way to interpolate in between conditions that are not directly covered by the experiments. It is long known that the best way to perform such interpolation is by using basic thermodynamic principles. For magmatic systems, this requires a well‐calibrated thermodynamic melting model. It also requires an efficient computational tool to predict the most stable configuration of minerals and melt. Since the 1980s, a number of such computational tools have been developed to perform a so‐called Gibbs energy minimization. These tools work very well for simpler systems but become very slow for recently developed, more realistic, melting models. Here, we describe a new method that combines some ideas of the previous methods with a new algorithm. Our method is faster and takes advantage of modern computer architectures. It can predict rock properties such as densities, seismic velocities, melt content, and chemistry. It can therefore be used to link physical observations with hard rock data of magmatic systems.
    Description: Key Points: A new, parallel, Gibbs energy minimization approach is presented to compute multiphase multicomponent equilibria. It predicts parameters like stable phases, melt content, or seismic velocities as a function of chemistry and temperature/pressure conditions. Examples and benchmark cases are presented that apply the approach to magmatic systems.
    Description: EC | H2020 | H2020 Priority Excellent Science | H2020 European Research Council (ERC) http://dx.doi.org/10.13039/100010663
    Description: https://doi.org/10.5281/zenodo.6347567
    Description: https://github.com/ComputationalThermodynamics/magemin.git
    Keywords: ddc:552
    Language: English
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    Holocene variability in sea‐ice conditions in the eastern Baffin Bay‐Labrador Sea – A north–south biomarker transect study (2022)
    Saini, Jeetendra ; Stein, Ruediger ; Fahl, Kirsten ; [et al.]
    Details
    Publication Date: 2022-10-05
    Description: Reconstructions of sea‐surface conditions during the Holocene were achieved using three sediment cores from northeastern Baffin Bay (GeoB19948‐3 and GeoB19927‐3) and the Labrador Sea (GeoB19905‐1) along a north–south transect based on sea‐ice IP25 and open‐water phytoplankton biomarkers (brassicasterol, dinosterol and HBI III). In Baffin Bay, sea‐surface conditions in the Early Holocene were characterized by extended (early) spring sea ice cover (SIC) prior to 7.6 ka BP. The conditions in the NE Labrador Sea, however, remained predominantly ice‐free in spring/autumn due to the enhanced influx of Atlantic Water (West Greenland Current, WGC) from 11.5 until ~9.1 ka BP, succeeded by a period of continued (spring–autumn) ice‐free conditions between 9.1 and 7.6 ka BP corresponding to the onset of Holocene Thermal Maximum (HTM)‐like conditions. A transition towards reoccurring ice‐edge and significantly reduced SIC conditions in Baffin Bay is evident in the Middle Holocene (~7.6–3 ka BP) probably caused by the variations in the WGC influence associated with the ice melting and can be characterized as HTM‐like conditions. These HTM‐like conditions are predominantly recorded in the NE Labrador Sea area shown by (spring–autumn) ice‐free conditions from 5.9–3 ka BP. In the Late Holocene (last ~3 ka), our combined proxy records from eastern Baffin Bay indicate low in‐situ ice algae production; however, enhanced multi‐year (drifted) sea ice in this area was possibly attributed to the increased influx of Polar Water mass influx and may correlate with the Neoglacial cooling. The conditions in the NE Labrador Sea during the last 3 ka, however, continued to remain (spring–autumn) ice‐free. Our data from the Baffin Bay–Labrador Sea transect suggest a dominant influence of meltwater influx on sea‐ice formation throughout the Holocene, in contrast to sea‐ice records from the Fram Strait area, which seem to follow predominantly the summer insolation trend.
    Description: image
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.46
    Language: English
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    Multiple Angle Observations Would Benefit Visible Band Remote Sensing Using Night Lights (2022)
    Details
    Publication Date: 2022-10-05
    Description: The spatial and angular emission patterns of artificial and natural light emitted, scattered, and reflected from the Earth at night are far more complex than those for scattered and reflected solar radiation during daytime. In this commentary, we use examples to show that there is additional information contained in the angular distribution of emitted light. We argue that this information could be used to improve existing remote sensing retrievals based on night lights, and in some cases could make entirely new remote sensing analyses possible. This work will be challenging, so we hope this article will encourage researchers and funding agencies to pursue further study of how multi‐angle views can be analyzed or acquired.
    Description: Plain Language Summary: When satellites take images of Earth, they usually do so from directly above (or as close to it as is reasonably possible). In this comment, we show that for studies that use imagery of Earth at night, it may be beneficial to take several images of the same area at different angles within a short period of time. For example, different types of lights shine in different directions (street lights usually shine down, while video advertisements shine sideways), and tall buildings can block the view of a street from some viewing angles. Additionally, since views from different directions pass through different amounts of air, imagery at multiple angles could be used to obtain information about Earth's atmosphere, and measure artificial and natural night sky brightness. The main point of the paper is to encourage researchers, funding agencies, and space agencies to think about what new possibilities could be achieved in the future with views of night lights at different angles.
    Description: Key Points: Remote sensing using the visible band at night is more complex than during the daytime, especially due to the variety of artificial lights. Views of night lights intentionally taken from multiple angles provide several advantages over near‐nadir or circumstantial view geometries. Night lights remote sensing would benefit from greater consideration of the role viewing geometry plays in the observed radiance.
    Description: EC H2020 H2020 Societal Challenges http://dx.doi.org/10.13039/100010676
    Description: Helmholtz Association http://dx.doi.org/10.13039/501100009318
    Description: Slovak Research and Development Agency
    Description: Xunta de Galicia (Regional Government of Galicia) http://dx.doi.org/10.13039/501100010801
    Description: National Aeronautics and Space Administration http://dx.doi.org/10.13039/100000104
    Description: University of Hong Kong http://dx.doi.org/10.13039/501100003803
    Description: Fonds de recherche du Québec
    Description: EC Emprego, Assuntos Sociais e Inclusão European Social Fund http://dx.doi.org/10.13039/501100004895
    Description: Natural Environment Research Council http://dx.doi.org/10.13039/501100000270
    Description: City of Cologne, Germany
    Keywords: ddc:551.5
    Language: English
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    The relationship between precipitation and its spatial pattern in the trades observed during EUREC4A (2022)
    John Wiley & Sons, Ltd | Chichester, UK
    Details
    Publication Date: 2022-10-06
    Description: Trade wind convection organises into a rich spectrum of spatial patterns, often in conjunction with precipitation development. Which role spatial organisation plays for precipitation and vice versa is not well understood. We analyse scenes of trade‐wind convection scanned by the C‐band radar Poldirad during the EUREC4A field campaign to investigate how trade‐wind precipitation fields are spatially organised, quantified by the cells' number, mean size, and spatial arrangement, and how this matters for precipitation characteristics. We find that the mean rain rate (i.e., the amount of precipitation in a scene) and the intensity of precipitation (mean conditional rain rate) relate differently to the spatial pattern of precipitation. Whereas the amount of precipitation increases with mean cell size or number, as it scales well with the precipitation fraction, the intensity increases predominantly with mean cell size. In dry scenes, the increase of precipitation intensity with mean cell size is stronger than in moist scenes. Dry scenes usually contain fewer cells with a higher degree of clustering than moist scenes do. High precipitation intensities hence typically occur in dry scenes with rather large, few, and strongly clustered cells, whereas high precipitation amounts typically occur in moist scenes with rather large, numerous, and weakly clustered cells. As cell size influences both the intensity and amount of precipitation, its importance is highlighted. Our analyses suggest that the cells' spatial arrangement, correlating mainly weakly with precipitation characteristics, is of second‐order importance for precipitation across all regimes, but it could be important for high precipitation intensities and to maintain precipitation amounts in dry environments.
    Description: We analyse scenes of trade‐wind convection scanned by the C‐band radar Poldirad during the EUREC4A field campaign to investigate how trade‐wind precipitation fields are spatially organised, quantified by the cells' number, mean size, and spatial arrangement, and how this matters for precipitation characteristics. We conclude that the cells' size is important for both the amount and intensity of precipitation, whereas the cells' spatial arrangement is of second‐order importance for precipitation across all regimes, but possibly important for precipitation in dry environments.
    Description: Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under Germany's Excellence Strategy—EXC 2037 'CLICCS—Climate, Climatic Change, and Society'
    Description: https://doi.org/10.25326/217
    Description: https://doi.org/10.25326/79
    Keywords: ddc:551.5
    Language: English
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    High groundwater levels: Processes, consequences, and management (2022)
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-10-06
    Description: In recent years, the issue of high groundwater levels has caught attention. Unfavorable consequences of high groundwater levels are especially damage to buildings, infrastructure, and the environment. Processes that lead to high groundwater levels are hydrological (heavy or extended rainfall and flood events), or anthropogenic (reduced groundwater extractions, interaction with sewer networks, hydraulic engineering measures, structural interventions in the water balance, and mining activities). Several different map products have been prepared for the information of inhabitants and for planning purposes, and also methods for damage and risk analysis related to high groundwater levels have been developed. Groundwater management measures and structural measures are available to reduce the risk related to high groundwater levels. An operational management system could be combined from existing components, but operational forecasting systems for high groundwater levels are—different to flood forecasting systems—not yet common practice. A better understanding of the processes and the development of integrated approaches for modeling, design, planning, forecasting, and warning, as well as improvement of interdisciplinary collaboration between different organizations, are recommendations for the future. This article is categorized under: Engineering Water 〉 Engineering Water Water and Life 〉 Conservation, Management, and Awareness Science of Water 〉 Hydrological Processes Science of Water 〉 Water Extremes
    Description: Pumping water from a basement during the Neiße flood 2010 in Saxony. The clear water indicates that the basement flooding originates from groundwater (photo: Reinhard Schinke).
    Keywords: ddc:551.49
    Language: English
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    Capturing complex star dune dynamics—repeated highly accurate surveys combining multitemporal 3D topographic measurements and local wind data (2022)
    Details
    Publication Date: 2022-10-06
    Description: Morphologies of highly complex star dunes are the result of aeolian dynamics in past and present times. These dynamics reflect climatic conditions and associated forces like sediment availability and vegetation cover, as well as feedbacks with adjacent environments. However, an understanding of aeolian dynamics on star dune morphometries is still lacking sufficient detail, and their influence on formation and evolution remains unclear. We therefore investigate the dynamics of a complex star dune (Erg Chebbi, Morocco) by analysing wind measurements compared to morphometric changes derived from multitemporal high‐accuracy 3D observations during two surveys (October 2018 and February 2020). Using real‐time kinematic global navigation satellite system (RTK‐GNSS) measurements and terrestrial laser scanning (TLS), the reaction of a star dune surface to an observed constant unimodal sand‐moving wind is presented. TLS point clouds are used for morphometric analysis as well as direct surface change analysis, which relates to sand transport. RTK‐GNSS measurements enable the assessment of horizontal crest movement. Observed surface changes lead to the identification of an overall shielding effect, resulting in sand accumulation mainly on windward slopes. Our results point to a self‐sustained dune growth, which has not yet been described in such spatial detail. Steep slopes, often found on star dunes around the globe, seem to partly hinder upslope sand transport. Though a comparatively short observation period, we therefore hypothesize that, besides wind intensity alone, slope angles are more decisive for sand transport than previously assumed. Our methodological approach of combining meteorological data and high‐resolution multitemporal 3D elevation models can be used for monitoring all dune forms and contributes to a general understanding of dune dynamics and evolution.
    Description: The accurate detection of altitudinal surface changes on a star dune compared to climatic data enables the identification of aeolian dynamics and new mechanisms where, besides wind intensity alone, slope angles are more decisive for sand transport than previously assumed. The methodological approach can be transferred to all dune forms, ranging from small barchans to complex and extensive star dunes.
    Description: https://doi.org/10.11588/data/ZAMGCL
    Keywords: ddc:551.37
    Language: English
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    The first belemnite of boreal ancestry from the Early Cretaceous (Valanginian) of the western Tethys: implications for belemnite ecology (2022)
    Details
    Publication Date: 2022-10-06
    Description: The first occurrence of the belemnite species Liobelus acrei (formerly Acroteuthis acrei) is reported from the Lower Cretaceous (Valanginian) of the Vocontian Basin (VB; south‐east France). This first record of the genus Liobelus (Family Cylindroteuthididae), which is commonly attributed to the latest Jurassic and Early Cretaceous of the Boreal Realm, revises the spatial distribution pattern of boreal belemnites significantly. The Valanginian belemnite assemblages of the VB are dominated by genera of Tethyan ancestry, including both Duvaliidae (Berriasibelus, Castellanibelus, Duvalia, Pseudobelus) and Belemnopseidae (Adiakritobelus, Hibolithes, Mirabelobelus, Vaunagites). These two groups of Tethyan taxa comprise more than 99.9% of the belemnite‐rich assemblages of the Valanginian of the VB. The occurrence of a boreal specimen documents an isolated immigration of belemnites from the north in the early Valanginian. At the same time most Tethyan belemnite taxa are absent from the Boreal Realm, only Duvalia, Pseudobelus and Hibolithes have been described from North‐East Greenland, and Hibolithes from Svalbard. Based on these diverging biogeographical patterns of the Tethyan belemnite genera we establish two taxonomically different belemnite faunas: Tethyan Fauna 1 (Duvalia, Pseudobelus, Hibolithes), which has a near global, Tethyan‐wide and even boreal distribution, and Tethyan Fauna 2 (Adiakritobelus, Berriasibelus, Castellanibelus, Mirabelobelus, Vaunagites), which is less widely distributed and is restricted to southern Europe. These different spatial distribution patterns shed light on the ecology, migration patterns and evolution of Early Cretaceous belemnites.
    Keywords: ddc:564.5
    Language: English
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    Ensemble Kalman filter based data assimilation for tropical waves in the MJO skeleton model (2022)
    John Wiley & Sons, Ltd | Chichester, UK
    Details
    Publication Date: 2022-10-06
    Description: The Madden–Julian oscillation (MJO) is the dominant component of tropical intraseasonal variability, with wide‐reaching impacts even on extratropical weather and climate patterns. However, predicting the MJO is challenging. One reason is the suboptimal state estimates obtained with standard data assimilation (DA) approaches. These are typically based on filtering methods with Gaussian approximations and do not take into account physical properties that are important specifically for the MJO. In this article, a constrained ensemble DA method is applied to study the impact of different physical constraints on the state estimation and prediction of the MJO. The quadratic programming ensemble (QPEns) algorithm utilized extends the standard stochastic ensemble Kalman filter (EnKF) with specifiable constraints on the updates of all ensemble members. This allows us to recover physically more consistent states and to respect possible associated non‐Gaussian statistics. The study is based on identical twin experiments with an adopted nonlinear model for tropical intraseasonal variability. This so‐called skeleton model succeeds in reproducing the main large‐scale features of the MJO and closely related tropical waves, while keeping adequate simplicity for fast experiments on intraseasonal time‐scales. Conservation laws and other crucial physical properties from the model are examined as constraints in the QPEns. Our results demonstrate an overall improvement in the filtering and forecast skill when the model's total energy is conserved in the initial conditions. The degree of benefit is found to be dependent on the observational setup and the strength of the model's nonlinear dynamics. It is also shown that, even in cases where the statistical error in some waves remains comparable with the stochastic EnKF during the DA stage, their prediction is improved remarkably when using the initial state resulting from the QPEns.
    Description: Unsatisfactory predictions of the MJO are partly due to DA methods that do not respect non‐Gaussian PDFs and the physical properties of the tropical atmosphere. Therefore the QPEns, an algorithm extending a stochastic EnKF with state constraints, is tested here on a simplified model for the MJO and associated tropical waves. Our series of identical twin experiments shows, in particular, that a constraint on the truth's nonlinear total energy improves forecasts statistically and can, in certain situations, even prevent filter divergence. image
    Description: Deutsche Forschungsgemeinschaft : Heisenberg Award (DFG JA1077/4‐1); Transregional Collaborative Research Center SFB / TRR 165 “Waves to Weather” http://dx.doi.org/10.13039/501100001659
    Description: Office of Naval Research (ONR) http://dx.doi.org/10.13039/100000006
    Keywords: ddc:551.6
    Language: English
    Type: doc-type:article
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    Modeling the Transport and Deposition of 10Be Produced by the Strongest Solar Proton Event During the Holocene (2022)
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    Publication Date: 2022-10-06
    Description: Prominent excursions in the number of cosmogenic nuclides (e.g., 10Be) around 774 CE/775 document the most severe solar proton event (SPE) throughout the Holocene. Its manifestation in ice cores is valuable for geochronology, but also for solar‐terrestrial physics and climate modeling. Using the ECHAM/MESSy Atmospheric Chemistry (EMAC) climate model in combination with the Warning System for Aviation Exposure to SEP (WASAVIES), we investigate the transport, mixing, and deposition of the cosmogenic nuclide 10Be produced by the 774 CE/775 SPE. By comparing the model results to the reconstructed 10Be time series from four ice core records, we study the atmospheric pathways of 10Be from its stratospheric source to its sink at Earth's surface. The reconstructed post‐SPE evolution of the 10Be surface fluxes at the ice core sites is well captured by the model. The downward transport of the 10Be atoms is controlled by the Brewer‐Dobson circulation in the stratosphere and cross‐tropopause transport via tropopause folds or large‐scale sinking. Clear hemispheric differences in the transport and deposition processes are identified. In both polar regions the 10Be surface fluxes peak in summertime, with a larger influence of wet deposition on the seasonal 10Be surface flux in Greenland than in Antarctica. Differences in the peak 10Be surface flux following the 774 CE/775 SPE at the drilling sites are explained by specific meteorological conditions depending on the geographic locations of the sites.
    Description: Plain Language Summary: During large solar storms, high energy particles are hurled with enormous force toward Earth by the Sun. As these particles collide with atmospheric constituents (such as oxygen or nitrogen) unique nuclides of cosmogenic origin are formed in the higher atmosphere. From there they are transported downwards and finally precipitate at the surface due to different sink processes. Their imprints can be conserved over thousands of years within natural archives, such as ice cores or tree rings. Analysis of these natural archives around the globe indicates that the strongest solar storm over the last 10.000 years happened around 774 CE/775. This event is estimated to have been up to two orders of magnitude stronger, than the strongest known events documented for the satellite era. In this study, we model and analyze the transport and deposition of the cosmogenic nuclides produced by the extreme 774 CE/775 event, by applying a new experimental setup. Our results might help to interpret the fingerprints of historical extreme events with respect to the prevailing atmospheric conditions.
    Description: Key Points: The modeled transport and deposition of the cosmogenic nuclide10Be produced by the 774/775 solar proton event was compared to 10Be ice core records. Hemispheric differences in stratospheric and cross‐tropopause transport, and deposition were identified, with polar summertime maxima of 10Be surface flux. Differences in reconstructed10Be surface fluxes are explained by the local ratio of wet to dry deposition maximizing in the summertime.
    Description: MEXT Japan Society for the Promotion of Science http://dx.doi.org/10.13039/501100001691
    Keywords: ddc:551.5
    Language: English
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    Nonmarine Ostracoda as proxies in (geo‐)archaeology — A review (2022)
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    Publication Date: 2022-10-06
    Description: Ostracods as bioindicators are extremely useful for reconstructing palaeoenvironment and palaeoclimate and can also indicate the provenance of sediments and materials, for example, in studies on ancient commercial networks. Ostracods are small crustaceans that live in almost all aquatic habitats, both natural and man‐made. Due to their calcitic carapace, they have high fossilization potential, and their use in geoarchaeology has been steadily increasing during the last decades. Their small size needs mean that only small volumes of sediment samples are needed, and species‐specific ecological tolerances and preferences allow detailed palaeoenvironmental reconstructions. Typical methods of their application are palaeoecological analyses of associations based on ecological information and taphonomy, morphometric variability and stable isotope and chemistry analyses of their shells. The present paper aims to present an overview of applications of non‐marine ostracods in (geo‐)archaeological research, recommending sampling and analytical techniques for addressing archaeological research questions on palaeoclimate, habitat and landscape changes, water availability and quality, land use and other anthropogenic impacts, the provenance of materials and commercial networks to promote the application of Ostracoda in geoarchaeology/environmental archaeology.
    Description: International Max Planck Research School for the Science of Human History
    Keywords: ddc:565.3
    Language: English
    Type: doc-type:article
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