ALBERT

Note: Contents: Contributors. - Foreword by Paul J. Crutzen. - Preface by David Schimel. - Introduction. - 1 Uncertainties of Global Biogeochemical Predictions / E. D. Schulze, D. S. S. Schimel. - 1.1 Introduction. - 1.2 The IGBP Transect Approach. - 1.2.1 The Patagonian Transect. - 1.2.2 The Australian Transect. - 1.2.3 The European Transect. - 1.3 Variability in Processes. - 1.4 Biome Approach and Functional Types. - 1.5 New Approaches to Functional Diversity. - 1.6 Conclusions. - References. - 2 Uncertainties of Global Climate Predictions / L. Bengtsson. - 2.1 Introduction. - 2.2 Observational Evidence. - 2.3 Physical Rationale. - 2.3.1 Stochastic Forcing. - 2.3.2 Solar irradiation Changes. - 2.3.3 Volcanic Effects. - 2.3.4 Anthropogenic Effects. - 2.4 Response to Forcing of the Climate System. - 2.5 Results from Climate Change Prediction Experiments. - 2.6 Summary and Conclusions. - References. - 3 Uncertainties in the Atmospheric Chemical System / G. P. Brasseur, E. A. H. Holland. - 3.1 Introduction. - 3.2 Synthetic View of Chemical Processes in the Troposphere. - 3.3 The IMAGES Model. - 3.4 Changes in the Chemical Composition of the Global Troposphere. - 3.5 Concluding Remarks. - References. - 4 Inferring Biogeochemical Sources and Sinks from Atmospheric Concentrations: General Consideration and Applications in Vegetation Canopies / M. Raupach. - 4.1 Introduction. - 4.2 Scalar and Isotopic Molar Balances. - 4.2.1 General Principles. - 4.2.2 Single-Point Eulerian Equations. - 4.2.3 Source Terms for CO2. - 4.2.4 Single-Point Lagrangian Equations. - 4.3 Inverse Methods for Inferring Scalar Sources and Sinks in Canopies. - 4.3.1 General Principles. - 4.3.2 Localized Near Field Theory. - 4.3.3 The Dispersion Matrix. - 4.3.4 Turbulent Velocity Field. - 4.3.5 Solutions for Forward, Inverse and Implicit Problems. - 4.3.6 Field Tests. - 4.4 Inverse Methods and Isotopes in Canopies. - 4.4.1 Path Integrals and Keeling Plots. - 4.4.2 Inverse Lagrangian Analysis of Isotopic Composition. - 4.5 Summary and Conclusions. - Appendix A. - Appendix B. - References. - 5 Biogeophysical Feedbacks and the Dynamics of Climate / M. Claussen. - 5.1 Introduction. - 5.2 Synergisms. - 5.2.1 High Northern Latitudes. - 5.2.2 Subtropics. - 5.3 Multiple Equilibria. - 5.4 Transient Interaction. - 5.5 Perspectives. - References. - 6 Land-Ocean-Atmosphere Interactions and Monsoon Climate Change: A Paleo-Perspective / J. E. Kutzbach, Michael T. Coe, S. P. Harrison and M. T. Coe. - 6.1 Introduction. - 6.2 Response of the Monsoon to Orbital Forcing. - 6.3 Ocean Feedbacks on the Monsoon. - 6.4 Land-Surface Feedbacks on the Monsoon. - 6.5 Synergies between the Land, Ocean and Atmosphere. - 6.6 The Role of Climate Variability. - 6.7 Final Remarks. - References. - 7 Paleobiogeochemistry / I. C. Prentice, D. Raynaud. - 7.1 Introduction. - 7.2 Methane. - 7.3 Carbon Dioxide. - 7.4 Mineral Dust Aerosol. - 7.5 Scientific Challenges Posed by the Ice-Core Records. - 7.5.1 Methane. - 7.5.2 Carbon Dioxide. - 7.5.3 Mineral Dust Aerosol. - 7.6 Towards an Integrated Research Strategy for Palaeobiogeochemistry. - References. - 8 Should Phosphorus Availability Be Constraining Moist Tropical Forest Responses to Increasing CO2 Concentrations / J. Lloyd, M. I. Bird, E. M. Veenendaal and B. Kruijt. - 8.1 Introduction. - 8.2 Phosphorus in the Soils of the Moist Tropics. - 8.2.1 Soil Organic Phosphorus. - 8.2.2 Soil Inorganic Phosphorus. - 8.2.3 Soil Carbon/Phosphorus Interactions. - 8.3 States and Fluxes of Phosphorus in Moist Tropical Forests. - 8.3.1 Inputs and Losses of Phosphorus Through Rainfall, Dry Deposition and Weathering: Losses Via Leaching. - 8.3.2 Internal Phosphorus Flows in Moist Tropical Forests. - 8.3.3 Mechanisms for Enhanced Phosphorus Uptake in Low P Soils. - 8.4 Linking the Phosphorus and Carbon Cycles. - 8.4.1 To What Extent Does Phosphorus Availability Really Limit Moist Tropical Forest Productivity?. - 8.4.2 Tropical Plant Responses to Increases in Atmospheric CO2 Concentrations. - 8.4.3 Using a Simple Model to Examine CO2/Phosphorus Interactions in Tropical Forests. - References. - 9 Trees in Grasslands: Biogeochemical Consequences of Woody Plant Expansion / S. Archer, T. W. Boutton and K. A. Hibbard. - 9.1 Introduction. - 9.2 Woody Plant Encroachment in Grasslands and Savannas. - 9.3 The La Copita Case Study. - 9.3.1 Biogeographical and Historal Context. - 9.3.2 Herbaceous Retrogression and Soil Carbon Losses. - 9.3.3 Woody Plant Encroachment and Ecosystem Biogeochemistry. - 9.4 Degradation: Ecological Versus Socioeconomic. - 9.5 Implications for Ecosystem and Natural Resources Management. - 9.6 Summary. - References. - 10 Biogeochemistry in the Arctic: Patterns, Processes and Controls / S. Jonasson, F.S. Chapin, III and G. R. Shaver. - 10.1 Introduction. - 10.2 Tundra Organic Matter. - 10.2.1 Distribution of Organic Matter. - 10.2.2 Patterns and Controls of Organic Matter Turnover between Ecosystem Types. - 10.3 Tundra Nutrients. - 10.3.1 Nutrient Distribution and Controls of Nutrient Cycling. - 10.3.2 Nutrient Mineralization and Plant Nutrient Uptake. - 10.3.3 Are there Unaccounted Plant Sources of Limiting Nutrients?. - 10.4 Biogeochemical Responses to Experimental Ecosystem Manipulations. - 10.4.1 Applicability of Experimental Manipulations. - 10.4.2 Responses to Water Applications. - 10.4.3 Response to Nutrient Addition and Warming. - 10.4.4 Responses in Ecosystem Carbon Balance. - 10.5 Summary. - References. - 11 Evaporation in the Boreal Zone During Summer - Physics and Vegetation / F. M. Kelliher, I. Lloyd, C. Rebmann, C. Wirth and E. D. Schulze, D. D. Baldocchi. - 11.1 Introduction. - 11.2 Climate and Soil Water. - 11.3 Evaporation Theory. - 11.4 Evaporation During Summer and Rainfall. - 11.5 Forest Evaporation, Tree Life Form and Nitrogen. - 11.6 Conclusions. - References. - 12 Past and Future Forest Response to Rapid Climate Change / M.B. Davis. - 12.1 Introduction. - 12.2 Long-Distance Dispersal. - 12.3 Estimating Jump Distances. - 12.4 Interactions with Resident Vegetation - Constraints on Establishment. - 12.5 Interactions with Resident Vegetation - Competition for Light and Resulting Constraints on Population Growth. - 12.6 Conclusions. - References. - 13 Biogeochemical Models: Implicit vs. Explicit Microbiology / J. Schimel. - 13.1 Introduction. - 13.2 Microbiology in Biogeochemical Models. - 13.3 Dealing with Microbial Diversity in Models. - 13.4 Kinetic Effects of Microbial Population Size. - 13.5 Microbial Recovery from Stress. - 13.6 Conclusions. - References. - 14 The Global Soil Organic Carbon Pool / M. I. Bird, H. Santruckova, J. Lloyd and E. M. Veenendaal. - 14.1 Introduction: the Soil Carbon Pool and Global Change. - 14.2 Factors Affecting the Distribution of Soil Organic Carbon. - 14.3 Global Variations in the SOC Pool. - 14.4 The Limitations of Available Observational SOC Data. - 14.5 A Stratified Sampling Approach. - 14.6 Conclusions: Sandworld and Clayworld. - References. - 15 Plant Compounds and Their Turnover and Stability as Soil Organic Matter / G. Gleixner, C. Czimczik, C. Kramer, B. M. Lühker and M. W. I. Schmidt. - 15.1 Introduction. - 15.2 Pathways of Soil Organic Matter Formation. - 15.2.1 Formation and Decomposition of Biomass. - 15.2.2 The Influence of Environmental Conditions on SOM Formation. - 15.2.3 For

Note: Contents: Preface. - Acknowledgments. - 1 How the Ocean-Atmosphere System Is Driven. - 1.1 Introduction. - 1.2 The Amount of Energy Received by the Earth. - 1.3 Radiative Equilibrium Models. - 1.4 The Greenhouse Effect. - 1.5 Effects of Convection. - 1.6 Effects of Horizontal Gradients. - 1.7 Variability in Radiative Driving of the Earth. - 2 Transfer of Properties between Atmosphere and Ocean. - 2.1 Introduction. - 2.2 Contrasts in Properties of Ocean and Atmosphere. - 2.3 Momentum Transfer between Air and Sea, and the Atmosphere's Angular Momentum Balance. - 2.4 Dependence of Exchange Rates on Air-Sea Velocity, Temperature, and Humidity Differences. - 2.5 The Hydrological Cycle. - 2.6 The Heat Balance of the Ocean. - 2.7 Surface Density Changes and the Thermohaline Circulation of the Ocean. - 3 Properties of a Fluid at Rest. - 3.1 The Equation of State. - 3.2 Thermodynamic Variables. - 3.3 Values of Thermodynamic Quantities for the Ocean and Atmosphere. - 3.4 Phase Changes. - 3.5 Balance of Forces in a Fluid at Rest. - 3.6 Static Stability. - 3.7 Quantities Associated with Stability. - 3.8 Stability of a Saturated Atmosphere. - 3.9 Graphical Representation of Vertical Soundings. - 4 Equations Satisfied by a Moving Fluid. - 4.1 Properties of a Material Element. - 4.2 Mass Conservation Equation. - 4.3 Balance for a Scalar Quantity like Salinity. - 4.4 The Internal Energy (or Heat) Equation. - 4.5 The Equation of Motion. - 4.6 Mechanical Energy Equation. - 4.7 Total Energy Equation. - 4.8 Bernoulli's Equation. - 4.9 Systematic Effects of Diffusion. - 4.10 Summary List of the Governing Equations. - 4.11 Boundary Conditions. - 4.12 A Coordinate System for Planetary Scale Motions. - 5 Adjustment under Gravity in a Nonrotating System. - 5.1 Introduction: Adjustment to Equilibrium. - 5.2 Perturbations from the Rest State for a Homogenous Inviscid Fluid. - 5.3 Surface Gravity Waves. - 5.4 Dispersion. - 5.5 Short-Wave and Long-Wave Approximations. - 5.6 Shallow-Water Equations Derived Using the Hydrostatic Approximation. - 5.7 Energetics of Shallow-Water Motion. - 5.8 Seiches and Tides in Channels and Gulfs. - 6 Adjustment under Gravity of a Density-Stratified Fluid. - 6.1 Introduction. - 6.2 The Case of Two Superposed Fluids of Different Density. - 6.3 The Baroclinic Mode and the Rigid Lid Approximation. - 6.4 Adjustments within a Continuously Stratified Incompressible Fluid. - 6.5 Internal Gravity Waves. - 6.6 Dispersion Effects. - 6.7 Energetics of internal waves. - 6.8 Internal Waves Generated at a Horizontal Boundary. - 6.9 Effects on Boundary-Generated Waves of Variations of Buoyancy Frequency with Height. - 6.10 Free Waves in the Presence of Boundaries. - 6.11 Waves of Large Horizontal Scale: Normal Modes. - 6.12 An Example of Adjustment to Equilibrium in a Stratified Fluid. - 6.13 Resolution into Normal Modes for the Ocean. - 6.14 Adjustment to Equilibrium in a Stratified Compressible Fluid. - 6.15 Examples of Adjustment in a Compressible Atmosphere. - 6.16 Weak Dispersion of a Pulse. - 6.17 Isobaric Coordinates. - 6.18 The Vertically Integrated Perturbation Energy Equation in Isobaric Coordinates. - 7 Effects of Rotation. - 7.1 Introduction. - 7.2 The Rossby Adjustment Problem. - 7.3 The Transients. - 7.4 Applicability, to the Rotating Earth. - 7.5 The Rossby Radius of Deformation. - 7.6 The Geostrophic Balance. - 7.7 Relative Geostrophic Currents: The Thermal Wind. - 7.8 Available Potential Energy. - 7.9 Circulation and Vorticity. - 7.10 Conservation of Potential Vorticity for a Shallow Homogeneous Layer. - 7.11 Circulation in a Stratified Fluid and Ertel's Potential Vorticity. - 7.12 Perturbation Forms of the Vorticity Equations in a Uniformly Rotating Fluid. - 7.13 Initialization of Fields for Numerical Prediction Schemes. - 8 Gravity Waves in a Rotating Fluid. - 8.1 Introduction. - 8.2 Effect of Rotation on Surface Gravity Waves: Poincare Waves. - 8.3 Dispersion Properties and Energetics of Poincare Waves. - 8.4 Vertically Propagating Internal Waves in a Rotating Fluid. - 8.5 Polarization Relations. - 8.6 Energetics. - 8.7 Waves Generated at a Horizontal Boundary. - 8.8 Mountain Waves. - 8.9 Effects of Variation of Properties with Height. - 8.10 Finite-Amplitude Topographic Effects. - 8.11 Dissipative Effects in the Upper Atmosphere. - 8.12 The Liouville-Green or WKBJ Approximation. - 8.13 Wave Interactions. - 8.14 The Internal Wave Spectrum in the Ocean. - 8.15 Wave Transport and Effects on the Mean Flow. - 8.16 Quasi-geostrophic Flow (f Plane): The Isallobaric Wind. - 9 Forced Motion. - 9.1 Introduction. - 9.2 Forcing Due to Surface Stress: Ekman Transport. - 9.3 Wind-Generated Inertial Oscillations in the Ocean Mixed Layer. - 9.4 Ekman Pumping. - 9.5 Bottom Friction: Velocity Structure of the Boundary Layer. - 9.6 The Laminar Ekman Layer. - 9.7 The Nocturnal Jet. - 9.8 Tide-Producing Forces. - 9.9 Effect of Atmospheric Pressure Variations and Wind on Barotropic Motion in the Sea: The Forced Shallow-Water Equation. - 9.10 Baroclinic Response of the Ocean to Wind Forcing: Use of Normal Modes. - 9.11 Response of the Ocean to a Moving Storm or Hurricane. - 9.12 Spin-Down by Bottom Friction. - 9.13 Buoyancy Forcing. - 9.14 Response to Stationary Forcing: A Barotropic Example. - 9.15 A Forced Baroclinic Vortex. - 9.16 Equilibration through Dissipative Effects. - 10 Effects of Side Boundaries. - 10.1 Introduction. - 10.2 Effects of Rotation on Seiches and Tides in Narrow Channels and Gulfs. - 10.3 Poincare Waves in a Uniform Channel of Arbitrary Width. - 10.4 Kelvin Waves. - 10.5 The Full Set of Modes for an Infinite Channel of Uniform Width. - 10.6 End Effects: Seiches and Tides in a Gulf That Is Not Narrow. - 10.7 Adjustment to Equilibrium in a Channel. - 10.8 Tides. - 10.9 Storm Surges on an Open Coastline: The Local Solution. - 10.10 Surges Moving along the Coast: Forced Kelvin Waves. - 10.11 Coastal Upwelling. - 10.12 Continental Shelf Waves. - 10.13 Coastally Trapped Waves. - 10.14 Eastern Boundary Currents. - 11. The Tropics. - 11.1 Introduction. - 11.2 Effects of Earth's Curvature: Shallow-Water Equations on the Sphere. - 11.3 Potential Vorticity for a Shallow Homogeneous Layer. - 11.4 The Equatorial Beta Plane. - 11.5 The Equatorial Kelvin Wave. - 11.6 Other Equatorially Trapped Waves. - 11.7 The Equatorial Waveguide: Gravity Waves. - 11.8 Planetary Waves and Quasi-geostrophic Motion. - 11.9 Baroclinic Motion near the Equator. - 11.10 Vertically Propagating Equatorial Waves. - 11.11 Adjustment under Gravity near the Equator. - 11.12 Transient Forced Motion. - 11.13 Potential Vorticity for Baroclinic Motion: The Steady Limit. - 11.14 Steady Forced Motion. - 11.15 The Tropical Circulation of the Atmosphere. - 11.16 Tropical Ocean Currents. - 12 Mid-latitudes. - 12.1 Introduction. - 12.2 The Mid-latitude Beta Plane. - 12.3 Planetary Waves. - 12.4 Spin-Up of the Ocean by an Applied Wind Stress. - 12.5 Steady Ocean Circulation. - 12.6 Western Boundary Currents. - 12.7 Vertical Propagation of Planetary Waves in a Medium at Rest. - 12.8 Nonlinear Quasi-geostrophic Flow in Three Dimensions. - 12.9 Small Disturbances on a Zonal Flow Varying with Latitude and Height. - 12.10 Deductions about Vertical Motion from the Quasi-geostrophic Equations. - 13 Instabilities, Fronts, and the General Circulation. - 13.1 Introduction. - 13.2 Free Waves in the Presence of a Horizontal Temperature Gradient. - 13.3 Baroclinic Instability: The Eady Problem. - 13.4 Baroclinic Instability: The Charney Problem. - 13.5 Necessary Conditions for Instability. - 13.6 Barotropic Instability. - 13.7 Eddies in the Ocean. - 13.8 Fronts. - 13.9 The Life Cycle of a Baroclinic Disturbance. - 13.10 General Circulation of the Atmosphere. - Appendix One Units and Their SI Equivalents. - Appendix Two Useful

Note: Contents Foreword Preface Summary for Policymakers Synthesis Report Question 1 Question 2 Question 3 Question 4 Question 5 Question 6 Question 7 Question 8 Question 9 Working Group Summaries Working Group I: The Scientific Basis Working Group II: Impacts, Adaptation, and Vulnerability Working Group III: Mitigation Annexes A. Authors and Expert Reviewers B. Glossary of Terms C. Acronyms, Abbreviations, and Units D. Scientific, Technical, and Socio-Economic Questions Selected by the Panel E. List of Major IPCC Reports

Note: Contents: Contributors. - Preface. - Introduction and Scientific Background / J.C.R. Hunt, J. Norbury and I. Roulstone. - 1. A view of the equations of meteorological dynamics and various approximations / A. A. White. - 2. Extended-geostrophic Euler-Poincare models for mesoscale oceanographic flow / J. S. Allen, D. D. Holm and P. A. Newberger. - 3. Fast singular oscillating limits of stably-stratified 3D Euler and Navier-Stokes equations and ageostrophic wave fronts / A. Babin, A. Mahalov and B. Nicolaenko. - 4. New mathematical developments in atmosphere and ocean dynamics, and their application to computer simulations / M. J. P. Cullen. - 5. Rearrangements of functions with applications to meteorology and ideal fluid flow / R. J. Douglas. - 6. Statistical methods in atmospheric dynamics: probability metrics and discrepancy measures as a means of defining balance / S. Baigent and J. Norbury.

Note: Chapter 1. Structure and chemistry of zircon and zircon-group minerals by Robert J. Finch and John M. Hanchar, p. 1 - 26 Chapter 2. The composition of zircon and igneous and metamorphic petrogenesis by Paul W. O. Hoskin and Urs Schaltegger, p. 27 - 62 Chapter 3. Melt inclusions in zircon by J. B. Thomas, Robert J. Bodnar, Nobumichi Shimizu, and Craig A. Chesner, p. 63 - 88 Chapter 4. Zircon saturation thermometry by John M. Hanchar and E. Bruce Watson, p. 89 - 112 Chapter 5. Diffusion in zircon by Daniele J. Cherniak and E. Bruce Watson, p. 113 - 144 Chapter 6. Historical development of zircon geochronology by Donald W. Davis, Ian S. Williams, and Thomas E. Krogh, p. 145 - 182 Chapter 7. Zircon U-Th-Pb geochronology by isotope dilution—thermal ionization mass spectrometry (ID-TIMS) by Randall R. Parrish and Stephen R. Noble, p. 183 - 214 Chapter 8. Considerations in zircon geochronology by SIMS by Trevor R. Ireland and Ian S. Williams, p. 215 - 242 Chapter 9. Present trends and the future of zircon in geochronology: laser ablation ICPMS by Jan Kosler and Paul J. Sylvester, p. 243 - 276 Chapter 10. Detrital zircon analysis of the sedimentary record by Christopher M. Fedo, Keith N. Sircombe, and Robert H. Rainbird, p. 277 - 304 Chapter 11. High-precision U-Pb zircon geochronology and the stratigraphic record by Samuel A. Bowring and Mark D. Schmitz, p. 305 - 326 Chapter 12. Lu-Hf and Sm-Nd isotope systems in zircon by Peter D. Kinny and Roland Maas, p. 327 - 342 Chapter 13. Oxygen isotopes in zircon by John W. Valley, p. 343 - 386 Chapter 14. Radiation effects in zircon by Rodney C. Ewing, Alkiviathes Meldrum, LuMin Wang, William J. Weber, and L. René Corrales, p. 387 - 426 Chapter 15. Spectroscopic methods applied to zircon by Lutz Nasdala, Ming Zhang, Ulf Kempe, Gérard Panczer, Michael Gaft, Michael Andrut, and Michael Plotze, p. 427 - 468 Chapter 16. Atlas of zircon textures by Fernando Corfu, John M. Hanchar, Paul W.O. Hoskin, and Peter Kinny, p. 469 - 500

Note: Chapter 1. An Overview of Biomineralization Processes and the Problem of the Vital Effect by Steve Weiner and Patricia M. Dove, p. 1 - 30 Chapter 2. Principles of Molecular Biology and Biomacromolecular Chemistry by John S. Evans, p. 31 - 56 Chapter 3. Principles of Crystal Nucleation and Growth by James J. De Yoreo and Peter G. Vekilov, p. 57 - 94 Chapter 4. Biologically Induced Mineralization by Bacteria by Richard B. Frankel and Dennis A. Bazylinskn, p. 95 - 114 Chapter 5. The Source of Ions for Biomineralization in Foraminifera and Their Implications for Paleoceanographic Proxies by Jonathan Erez, p. 115 - 150 Chapter 6. Geochemical Perspectives on Coral Mineralization by Anne L. Cohen and Ted A. McConnaughey, p. 151 - 188 Chapter 7. Biomineralization Within Vesicles: The Calcite of Coccoliths by Jeremy R. Young and Karen Henriksen, p. 189 - 216 Chapter 8. Biologically Controlled Mineralization in Prokaryotes by Dennis A. Bazylinski and Richard B. Frankel, p. 217 - 248 Chapter 9. Mineralization in Organic Matrix Frameworks by Arthur Veis, p. 249 - 290 Chapter 10. Silicification: The Processes by Which Organisms Capture and Mineralize Silica by Carole C. Perry, p. 291 - 328 Chapter 11. Biomineralization and Evolutionary History by Andrew H Knoll, p. 329 - 356 Chapter 12. Biomineralization and Global Biogeochemical Cycles by Philippe Van Cappellen, p. 357 -381

Note: Contents Prologue Acknowledgments List of Symbols PART I Foundations 1 INTRODUCTION: The Basic Challenge 1.1 The Climate System 1.2 Some Basic Observations 1.3 External Forcing 1.3.1 Astronomical Forcing 1.3.2 Tectonic Forcing 1.4 The Ice-Age Problem 2 TECHNIQUES FOR CLIMATE RECONSTRUCTION 2.1 Historical Methods 2.1.1 Direct Quantitative Measurements 2.1.2 Descriptive Accounts of General Environmental Conditions 2.2 Surficial Biogeologic Proxy Evidence 2.2.1 Annually Layered Life Forms 2.2.2 Surface Geomorphic Evidence 2.3 Conventional Nonisotopic Stratigraphic Analyses of Sedimentary Rock and Ice 2.3.1 Physical Indicators 2.3.2 Paleobiological Indicators (Fossil Faunal Types and Abundances) 2.4 Isotopic Methods 2.4.1 Oxygen Isotopes 2.4.2 Deuterium and Beryllium in Ice Cores 2.4.3 Stable Carbon Isotopes 2.4.4 Strontium and Osmium Isotopes 2.5 Nonisotopic Geochemical Methods 2.5.1 Cadmium Analysis 2.5.2 Greenhouse Gas Analysis of Trapped Air in Ice Cores 2.5.3 Chemical and Biological Constituents and Dust Layers in Ice Cores 2.6 Dating the Proxy Evidence (Geochronometry) 3 A SURVEY OF GLOBAL PALEOCLIMATIC VARIATIONS 3.1 The Phanerozoic Eon (Past 600 My) 3.2 The Cenozoic Era (Past 65 My) 3.3 The Plio-Pleistocene (Past 5 My) 3.4 Variations during the Last Ice Age: IRD Events 3.5 The Last Glacial Maximum (20 ka) 3.6 Postglacial Changes: The Past 20 ky 3.7 The Past 100 Years 3.8 The Generalized Spectrum of Climatic Variance 3.9 A Qualitative Discussion of Causes 4 GENERAL THEORETICAL CONSIDERATIONS 4.1 The Fundamental Equations 4.2 Time Averaging and Stochastic Forcing 4.3 Response Times and Equilibrium 4.4 Spatial Averaging 4.5 Climatic-Mean Mass and Energy Balance Equations 4.5.1 The Water Mass Balance 4.5.2 Energy Balance 5 SPECIAL THEORETICAL CONSIDERATIONS FOR PALEOCLIMATE: Structuring a Dynamical Approach 5.1 A Basic Problem: Noncalculable Levels of Energy and Mass Flow 5.2 An Overall Strategy 5.3 Notational Simplifications for Resolving Total Climate Variability 5.4 A Structured Dynamical Approach 5.5 The External Forcing Function, F 5.5.1 Astronomical/Cosmic Forcing 5.5.2 Tectonic Forcing 6 BASIC CONCEPTS OF DYNAMICAL SYSTEMS ANALYSIS: Prototypical Climatic Applications 6.1 Local (or Internal) Stability 6.2 The Generic Cubic Nonlinearity 6.3 Structural (or External) Stability: Elements of Bifurcation Theory 6.4 Multivariable Systems 6.4.1 The Two-Variable Phase Plane 6.5 A Prototype Two-Variable Model 6.5.1 Sensitivity of Equilibria to Changes in Parameters: Prediction of the Second Kind 6.5.2 Structural Stability 6.6 The Prototype Two-Variable System as a Stochastic-Dynamical System: Effects of Random Forcing 6.6.1 The Stochastic Amplitude 6.6.2 Structural Stochastic Stability 6.7 More Than Two-Variable Systems: Deterministic Chaos PART II Physics of the Separate Domains 7 MODELING THE ATMOSPHERE AND SURFACE STATE AS FAST-RESPONSE COMPONENTS 7.1 The General Circulation Model 7.2 Lower Resolution Models: Statistical-Dynamical Models and the Energy Balance Model 7.2.1 A Zonal-Average SDM 7.2.2 Axially Asymmetric SDMs 7.2.3 The Complete Time-Average State 7.3 Thermodynamic Models 7.3.1 Radiative-Convective Models 7.3.2 Vertically Averaged Models (the EBM) 7.4 The Basic Energy Balance Model 7.5 Equilibria and Dynamical Properties of the Zero-Dimensional (Global Average) EBM 7.6 Stochastic Resonance 7.7 The One-Dimensional (Latitude-Dependent) EBM 7.8 Transitivity Properties of the Atmospheric and Surface Climatic State: Inferences from a GCM 7.9 Closure Relationships Based on GCM Sensitivity Experiments 7.9.1 Surface Temperature Sensitivity 7.10 Formal Feedback Analysis of the Fast-Response Equilibrium State 7.11 Paleoclimatic Simulations 8 THE SLOW-RESPONSE "CONTROL" VARIABLES: An Overview 8.1 The Ice Sheets 8.1.1 Key Variables 8.1.2 Observations 8.2 Greenhouse Gases: Carbon Dioxide 8.3 The Thermohaline Ocean State 8.4 A Three-Dimensional Phase-Space Trajectory 9 GLOBAL DYNAMICS OF THE ICE SHEETS 9.1 Basic Equations and Boundary Conditions 9.2 A Scale Analysis 9.3 The Vertically Integrated Ice-Sheet Model 9.4 The Surface Mass Balance 9.5 Basal Temperature and Melting 9.6 Deformable Basal Regolith 9.7 Ice Streams and Ice Shelves 9.8 Bedrock Depression 9.9 Sea Level Change and the Ice Sheets: The Depression-Calving Hypothesis 9.10 Paleoclimatic Applications of the Vertically Integrated Model 9.11 A Global Dynamical Equation for Ice Mass 10 DYNAMICS OF ATMOSPHERIC CO2 10.1 The Air-Sea Flux, Q↑ 10.1.1 Qualitative Analysis of the Factors Affecting Q↑ 10.1.2 Mathematical Formulation of the Ocean Carbon Balance 10.1.3 A Parameterization for Q↑ 10.2 Terrestrial Organic Carbon Exchange, W↑G 10.2.1 Sea Level Change Effects 10.2.2 Thermal Effects 10.2.3 Ice Cover Effects 10.2.4 Long-Term Terrestrial Organic Burial, W↓G 10.2.5 The Global Mass Balance of Organic Carbon 10.3 Outgassing Processes, V↑ 10.4 Rock Weathering Downdraw, W↓ 10.5 A Global Dynamical Equation for Atmospheric CO2 10.6 Modeling the Tectonically Forced CO2 Variations, µˆ : Long-Term Rock Processes 10.6.1 The Long-Term Oceanic Carbon Balance 10.6.2 The GEOCARB Model 10.7 Overview of the Full Global Carbon Cycle 11 SIMPLIFIED DYNAMICS OF THE THERMOHALINE OCEAN STATE 11.1 General Equations 11.1.1 Boundary Conditions 11.2 A Prototype Four-Box Ocean Model 11.3 The Wind-Driven, Local-Convective, and Baroclinic Eddy Circulations 11.3.1 The Wind-Driven Circulation: Gyres and Upwelling 11.3.2 Local Convective Overturnings and Baroclinic Eddy Circulations 11.4 The Two-Box Thermohaline Circulation Model: Possible Bimodality of the Ocean State 11.4.1 The Two-Box System 11.4.2 A Simple Model of the TH Circulation 11.4.3 Meridional Fluxes 11.4.4 Dynamical Analysis of the Two-Box Model 11.5 Integral Equations for the Deep Ocean State 11.5.1 The Deep Ocean Temperature 11.5.2 The Deep Ocean Salinity 11.6 Global Dynamical Equations for the Thermohaline State: θ and Sφ PART III Unified Dynamical Theory 12 THE COUPLED FAST- AND SLOW-RESPONSE VARIABLES AS A GLOBAL DYNAMICAL SYSTEM: Outline of a Theory of Paleoclimatic Variation 12.1 The Unified Model: A Paleoclimate Dynamics Model 12.2 Feedback-Loop Representation 12.3 Elimination of the Fast-Response Variables: The Center Manifold 12.4 Sources of Instability: The Dissipative Rate Constants 12.5 Formal Separation into Tectonic Equilibrium and Departure Equations 13 FORCED EVOLUTION OF THE TECTONIC-MEAN CLIMATIC STATE 13.1 Effects of Changing Solar Luminosity and Rotation Rate 13.1.1 Solar Luminosity (S) 13.1.2 Rotation Rate (Ω) 13.2 General Effects of Changing Land-Ocean Distribution and Topography (h) 13.3 Effects of Long-Term Variations of Volcanic and Cosmic Dust and Bolides 13.4 Multimillion-Year Evolution of CO2 13.4.1 The GEOCARB Solution 13.4.2 First-Order Response of Global Ice Mass and Deep Ocean Temperature to Tectonic CO2 Variations 13.5 Possible Role of Salinity-Driven Instability of the Tectonic-Mean State 13.6 Snapshot Atmospheric and Surficial Equilibrium Responses to Prescribed y-Fields Using GCMs 14 THE LATE CENOZOIC ICE-AGE DEPARTURES: An Overview of Previous Ideas and Models 14.1 General Review: Forced vs. Free Models 14.1.1 Models in Which Earth-Orbital Forcing Is Necessary 14.1.2 Instability-Driven (Auto-oscillatory) Models 14.1.3 Hierarchical Classification in Terms of Increasing Physical Complexity 14.2 Forced Ice-Line Models (Box 1, Fig. 14-1) 14.3 Ice-Sheet Inertia Models 14.3.1 The Simplest Forms (Box 2) 14.3.2 More Physically Based Ice-Sheet Models: First Applications 14.3.3 Direct Bedrock Effects (Box 3) 14.3.4 Bedrock-Calving Effects (Box 4) 14.3.5 Basal Meltwater and Sliding (Box 5) 14.3.6 Ice Streams and Ice Shelf Effects 14.3.7 Continental Ice-Sheet Movement (Box 6) 14.3.8 Three-Dimensional (λ, φ, hI) Ice-Sheet Models 14.4 The Need for Enhancement of the Coupled Ice-Sheet/Atmospheric Climate Models 14.5 Ice-Sheet Variables Coupled with Additional Slow-Response Variables 14.5.1 Regolith Mass, mr (Box 7) 14.5.2 The Deep Ocean Te

Note: Contents Acknowledgements Executive Summary with Key Findings and Recommendations Current State of the Art Key Scientific Challenges and Recommendations Major New Synthesis Initiative Required Implementation of Arctic-CHAMP Policy Implications Summary 1. Introduction Rationale for Pan-Arctic Hydrologic Synthesis Report Framework 2. A Strategy for Detecting and Understanding Arctic Hydrological Change: Arctic-CHAMP Arctic-CHAMP Basic Long-Term Monitoring Arctic-CHAMP Field-Based Process Studies Arctic-CHAMP Synthesis Modeling Execution of Arctic-CHAMP 3. Role and Importance of Water in the Arctic System The Integrated Water Cycle of the Pan-Arctic Land Atmosphere Ocean Importance of Arctic Hydrology to the Arctic System Importance of the Arctic to the Earth System 4. Unprecedented Change to Arctic Hydrological Systems Changes to the Land-Based Hydrologic Cycle Changes to the Atmosphere The Changing Arctic Ocean and its Regional Seas 5. Impacts and Feedbacks Associated with Arctic Hydrological Change Direct Impacts on Ecosystems Arctic Water Cycle Change and Humans Land-Atmosphere-Ocean Feedbacks Land-Atmosphere-Ocean-Human Feedbacks 6. Implementation of Arctic-CHAMP References Appendix 1. NSF-ARCSS Arctic Hydrology Workshop Participants Appendix 2. Current Gaps in Understanding the Pan-Arctic Hydrological Cycle Appendix 3. Integration of Arctic-CHAMP with NSF and Other Federal Agency Initiatives Appendix 4. International Collaborations

Note: Chapter 1. Classification and Structures of the Micas by S. W. Bailey, p. 1 - 12 Chapter 2. Crystal Chemistry of the True Micas by S. W. Bailey, p. 13 - 60 Chapter 3. The Brittle Micas by Stephen Guggenheim, p. 61 - 104 Chapter 4. Electrostatic Energy Models of Micas by R. F. Giese, Jr., p. 105 - 144 Chapter 5. Spectroscopy of Micas by George R. Rossman. p. 145 - 182 Chapter 6. Optical Properties of Mica Under the Polarizing Microscope by Ray E. Wilcox, p. 183 - 200 Chapter 7. Experimental Phase Relations of the Micas by David A. Hewitt and David R. Wones, p. 201 - 256 Chapter 8. Paragenesis, Crystallochemical Characteristics, and Geochemical Evolution of Micas in Granitic Pegmatites by Petr Cerny and Donald M. Burt, p. 257 - 298 Chapter 9. Micas in Igneous Rocks by J. Alexander Speer, p. 299 - 356 Chapter 10. Micas in Metamorphic Rocks by Charles V. Guidotti, p. 257 - 468 Chapter 11. F-OH and Cl-OH Exchange in Micas with Applications to Hydrothermal Ore Deposits by James L. Munoz, p. 469 - 494 Chapter 12. Illite by Jan Sordori and Dennis D. Eberl, p. 495 - 544 Chapter 13. Glauconite and Celadonite Minerals by I. Edgar Odom, p. 545 - 572 Appendix: X-Ray Power Patterns of Micas p. 573 - 584

Note: Mainland Europe --- K. Weber: Variscan events: early Palaeozoic continental rift metamorphism and late Palaeozoic crustal shortening / Geological Society, London, Special Publications, 14:3-22, doi:10.1144/GSL.SP.1984.014.01.02 --- R. Meissner, M. Springer, and E. Flüh: Tectonics of the Variscides in North-Western Germany based on seismic reflection measurements / Geological Society, London, Special Publications, 14:23-32, doi:10.1144/GSL.SP.1984.014.01.03 --- Wolfgang Franke: Late events in the tectonic history of the Saxothuringian zone / Geological Society, London, Special Publications, 14:33-45, doi:10.1144/GSL.SP.1984.014.01.04 --- J. P. Burg, Ph. Matte, A. Leyreloup, and J. Marchand: Inverted metamorphic zonation and large-scale thrusting in the Variscan Belt: an example in the French Massif Central / Geological Society, London, Special Publications, 14:47-61, doi:10.1144/GSL.SP.1984.014.01.05 --- Jean-Michel Quenardel and Patrick Rolin: Palaeozoic evolution of the Plateau d’Aigurande (NW Massif Central, France) / Geological Society, London, Special Publications, 14:63-70, doi:10.1144/GSL.SP.1984.014.01.06 --- S. C. Matthews: Northern margins of the Variscides in the North Atlantic region: comments on the tectonic context of the problem / Geological Society, London, Special Publications, 14:71-85, doi:10.1144/GSL.SP.1984.014.01.07 --- Britain --- M. P. Coward and S. Smallwood: An interpretation of the Variscan tectonics of SW Britain / Geological Society, London, Special Publications, 14:89-102, doi:10.1144/GSL.SP.1984.014.01.08 --- B. E. Leveridge, M. T. Holder, and G. A. Day: Thrust nappe tectonics in the Devonian of south Cornwall and the western English Channel / Geological Society, London, Special Publications, 14:103-112, doi:10.1144/GSL.SP.1984.014.01.09 --- T. J. Chapman, R. L. Fry, and P. T. Heavey: A structural cross-section through SW Devon / Geological Society, London, Special Publications, 14:113-118, doi:10.1144/GSL.SP.1984.014.01.10 --- J. W. F. Edwards: Interpretations of seismic and gravity surveys over the eastern part of the Cornubian platform / Geological Society, London, Special Publications, 14:119-124, doi:10.1144/GSL.SP.1984.014.01.11 --- Robert M. Shackleton: Thin-skinned tectonics, basement control and the Variscan front / Geological Society, London, Special Publications, 14:125-129, doi:10.1144/GSL.SP.1984.014.01.12 --- Russell S. Arthurton: The Ribblesdale fold belt, NW England—a Dinantian-early Namurian dextral shear zone / Geological Society, London, Special Publications, 14:131-138, doi:10.1144/GSL.SP.1984.014.01.13 --- M. F. Critchley: Variscan tectonics of the Alston block, northern England / Geological Society, London, Special Publications, 14:139-146, doi:10.1144/GSL.SP.1984.014.01.14 --- Ireland --- David J. Sanderson: Structural variation across the northern margin of the Variscides in NW Europe / Geological Society, London, Special Publications, 14:149-165, doi:10.1144/GSL.SP.1984.014.01.15 --- M. A. Cooper, D. Collins, M. Ford, F. X. Murphy, and P. M. Trayner: Structural style, shortening estimates and the thrust front of the Irish Variscides / Geological Society, London, Special Publications, 14:167-175, doi:10.1144/GSL.SP.1984.014.01.16 --- M. D. Max and J. P. Lefort: Does the Variscan front in Ireland follow a dextral shear zone? / Geological Society, London, Special Publications, 14:177-183, doi:10.1144/GSL.SP.1984.014.01.17 --- D. W. Coller: Variscan structures in the Upper Palaeozoic rocks of west central Ireland / Geological Society, London, Special Publications, 14:185-194, doi:10.1144/GSL.SP.1984.014.01.18 --- North America --- N. Rast: The Alleghenian orogeny in eastern North America / Geological Society, London, Special Publications, 14:197-217, doi:10.1144/GSL.SP.1984.014.01.19 --- Jean-Pierre Lefort and Richard T. Haworth: Geophysical evidence for the extension of the Variscan front on to the Canadian continental margin: geodynamic and palaeogeographic consequences / Geological Society, London, Special Publications, 14:219-231, doi:10.1144/GSL.SP.1984.014.01.20 --- Sharon Mosher and Nicholas Rast: The deformation and metamorphism of Carboniferous rocks in Maritime Canada and New England / Geological Society, London, Special Publications, 14:233-243, doi:10.1144/GSL.SP.1984.014.01.21 --- R. P. Wintsch and J.-P. Lefort: A clockwise rotation of Variscan strain orientation in SE New England and regional implications / Geological Society, London, Special Publications, 14:245-251, doi:10.1144/GSL.SP.1984.014.01.22 --- J. A. Brewer: Clues to the deep structure of the European Variscides from crustal seismic profiling in North America / Geological Society, London, Special Publications, 14:253-263, doi:10.1144/GSL.SP.1984.014.01.23

Note: Chapter 1. Molecular Modeling in Mineralogy and Geochemistry by Randall T. Cygan, p. 1 - 36 Chapter 2. Simulating the Crystal Structures and Properties of Ionic Materials From Interatomic Potentials by Julian D. Gale, p. 37 - 62 Chapter 3. Application of Lattice Dynamics and Molecular Dynamics Techniques to Minerals and Their Surfaces by Steve C. Parker, Nora H. de Leeuw, Ekatarina Bourova, and David J. Cooke, p. 63 - 82 Chapter 4. Molecular Simulations of Liquid and Supercritical Water: Thermodynamics, Structure, and Hydrogen Bonding by Andrey G. Kalinichev, p. 83 - 130 Chapter 5. Molecular Dynamics Simulations of Silicate Glasses and Glass Surfaces by Stephen H. Garofalini, p. 131 - 168 Chapter 6. Molecular Models of Surface Relaxation, Hydroxylation, and Surface Charging at Oxide-Water Interfaces by James R. Rustad, p. 169 - 198 Chapter 7. Structure and Reactivity of Semiconducting Mineral Surfaces: Convergence of Molecular Modeling and Experiment by Kevin M. Rosso, p. 199 - 272 Chapter 8. Quantum Chemistry and Classical Simulations of Metal Complexes in Aqueous Solutions by David M. Sherman, p. 273 - 318 Chapter 9. First Principles Theory of Mantle and Core Phases by Lars Stixrude, p. 319 - 344 Chapter 10. A Computational Quantum Chemical Study of the Bonded Interactions in Earth Materials and Structurally and Chemically Related Molecules by G. V. Gibbs, Monte B. Boisen, Jr., Lesa L. Beverly, and Kevin M. Rosso, p. 345 - 382 Chapter 11. Modeling the Kinetics and Mechanisms of Petroleum and Natural Gas Generation: A First Principles Approach by Yitian Xiao, p. 383 - 436 Chapter 12. Calculating the NMR Properties of Minerals, Glasses, and Aqueous Species by John D. Tossell, p. 437 - 458 Chapter 13. Interpretation of Vibrational Spectra Using Molecular Orbital Theory Calculations by James D. Kubicki, p. 459 - 484 Chapter 14. Molecular Orbital Modeling and Transition State Theory in Geochemistry by Mihali A. Felipe, Yitian Xiao, and James D. Kubicki, p. 485 - 531