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  • 1
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    A comparative study of the diagenesis in diapir-influenced reef atolls and a fault block reef platform in the Late Albian of the Vasco-Cantabrian Basin (2018)
    Springer | Berlin [u.a.]
    Details
    Publication Date: 2021-04-25
    Keywords: 551 ; VKB 350 ; 38.20
    Language: English
    Type: anthologyArticle , publishedVersion
    Format: 186-209
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  • 2
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    Fluid/rock interaction and mass transfer in continental subduction zones: constraints from trace elements and isotopes (Li, B, O, Sr, Nd, Pb) in UHP rocks from the Chinese Continental Scientific Drilling Program, Sulu, East China (2018)
    Springer-Verlag | Berlin/Heidelberg
    Details
    Publication Date: 2021-03-29
    Description: In order to better understand the role of fluids during subduction and subsequent exhumation, we have investigated whole-rock and mineral chemistry (major and trace elements) and Li, B as well as O, Sr, Nd, Pb isotopes on selected continuous drill-core profiles through contrasting lithological boundaries from the Chinese Continental Scientific Drilling Program (CCSD) in Sulu, China. Four carefully selected sample sets have been chosen to investigate geochemical changes as a result of fluid mobilization during dehydration, peak metamorphism, and exhumation of deeply subducted continental crust. Our data reveal that while O and Sr-Nd-Pb isotopic compositions remain more or less unchanged, significant Li and/or B isotope fractionations occur between different lithologies that are in close contact during various metamorphic stages. Samples that are supposed to represent prograde dehydration as indicated by veins formed at high pressures (HP) are characterized by element patterns of highly fluid-mobile elements in the veins that are complementary to those of the host eclogite. A second sample set represents a UHP metamorphic crustal eclogite that is separated from a garnet peridotite by a thin transitional interface. Garnet peridotite and eclogite are characterized by a 〉10% difference in MgO, which, together with the presence of abundant hydroxyl-bearing minerals and compositionally different clinopyroxene grains demonstrate that both rocks have been derived from different sources that have been tectonically juxtaposed during subduction, and that hydrous silicate-rich fluids have been added from the subducting slab to the mantle. Two additional sample sets, comprising retrograde amphibolite and relatively fresh eclogite, demonstrate that besides external fluids, internal fluids can be responsible for the formation of amphibolite. Li and B concentrations and isotopic compositions point to losses and isotopic fractionation during progressive dehydration. On the other hand, fluids with isotopically heavier Li and B are added during retrogression. On a small scale, mantle-derived rocks may be significantly metasomatized by fluids derived from the subducted slab. Our study indicates that during high-grade metamorphism, Li and B may show different patterns of enrichment and of isotopic fractionation.
    Keywords: Fluid/rock interaction; Elemental transfer; Isotopic fractionation; Subduction and exhumation; Sulu ; 551 ; Earth Sciences; Mineralogy; Mineral Resources; Geology
    Language: English
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  • 3
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    The Itajaí foreland basin: a tectono-sedimentary record of the Ediacaran period, Southern Brazil (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: The Itajaí Basin located in the southern border of the Luís Alves Microplate is considered as a peripheral foreland basin related to the Dom Feliciano Belt. It presents an excellent record of the Ediacaran period, and its upper parts display the best Brazilian example of Precambrian turbiditic deposits. The basal succession of Itajaí Group is represented by sandstones and conglomerates (Baú Formation) deposited in alluvial and deltaic-fan systems. The marine upper sequences correspond to the Ribeirão Carvalho (channelized and non-channelized proximal silty-argillaceous rhythmic turbidites), Ribeirão Neisse (arkosic sandstones and siltites), and Ribeirão do Bode (distal silty turbidites) formations. The Apiúna Formation felsic volcanic rocks crosscut the sedimentary succession. The Cambrian Subida leucosyenogranite represents the last felsic magmatic activity to affect the Itajaí Basin. The Brusque Group and the Florianópolis Batholith are proposed as source areas for the sediments of the upper sequence. For the lower continental units the source areas are the Santa Catarina, São Miguel and Camboriú complexes. The lack of any oceanic crust in the Itajaí Basin suggests that the marine units were deposited in a restricted, internal sea. The sedimentation started around 600 Ma and ended before 560 Ma as indicated by the emplacement of rhyolitic domes. The Itajaí Basin is temporally and tectonically correlated with the Camaquã Basin in Rio Grande do Sul and the Arroyo del Soldado/Piriápolis Basin in Uruguay. It also has several tectono-sedimentary characteristics in common with the African-equivalent Nama Basin.
    Keywords: Dom Feliciano Belt; Ediacaran; Foreland basin; U–Pb SHRIMP ages; Provenance ; 551 ; Earth Sciences; Geophysics/Geodesy; Geology
    Language: English
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  • 4
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    Petrographical and petrophysical properties of sandstones: statistical analysis as an approach to predict material behaviour and construction suitability (2018)
    Springer-Verlag | Berlin/Heidelberg
    Details
    Publication Date: 2021-03-29
    Description: Most studies dealing with material properties of sandstones are based on a small data set. The present study utilizes petrographical and petrophysical data from 22 selected sandstones and ~300 sandstones from the literature to estimate/predict the material and weathering behaviour of characteristic sandstones. Composition and fabric properties were determined from detailed thin section analyses. Statistical methods applied consist of data distributions with whisker plots and linear regression with confidence regions for the petrophysical and weathering properties. To identify similarities between individual sandstones and to define groups of specific sandstone types, principal component and cluster analyses were applied. The results confirm an interaction between the composition, depositional environment, stratigraphic association and diagenesis, which leads to a particular material behaviour of sandstones. Three different types of pore radii distributions are observed, whereby each is derived from different pore space modifications during diagenesis and is associated with specific sandstone types: (1) bimodal with a maximum in capillary and micropores, (2) unimodal unequal with a maximum in smaller capillary pores and (3) unimodal equable with a maximum in larger capillary pores. Each distribution shows specific dependencies to water absorption, salt loading and hygric dilatation. The strength–porosity relationship shows dependence on the content of unstable lithic fragments, grain contact and type of pore radii distribution, cementation and degree of alteration. Sandstones showing a maximum of capillary pores and micropores (bimodal) exhibit a distinct hygric dilatation and low salt resistance. These sandstones are highly immature sublitharenites–litharenites, characterized by altered unstable rock fragments, which show pointed-elongated grain contacts, and some pseudomatrix. Quartz arenites and sublitharenites–litharenites which are strongly compacted and cemented, show unimodal unequal pore radii distributions, low porosity, high strength and a high salt resistance. The presence of swellable clay minerals in sublitharenites–litharenites leads to a medium to high hygric dilatation, whereas quartz arenites show little hygric dilatation. Sandstones with unimodal equal pore radii distribution mostly belong to weakly compacted and cemented mature quartz arenites. These are characterized by high water absorption and high porosity, low to medium strength and a low salt resistance. The data compiled in this study are used to create a sandstone quality catalogue. Since material properties are dependent on many different parameters of influence, the transition between different lithotypes is fluent.
    Keywords: Sandstones; Pore space; Prediction; Weathering behavior; Compressive strength ; 551 ; Earth Sciences; Geology
    Language: English
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  • 5
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    Lattice-preferred orientations of late-Variscan granitoids derived from neutron diffraction data: implications for magma emplacement mechanisms (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: The lattice-preferred orientation (LPOs) of two late-Variscan granitoids, the Meissen monzonite and the Podlesí dyke granite, were determined from high-resolution time-of-flight neutron diffraction patterns gained at the diffractometer SKAT in Dubna, Russia. The results demonstrate that the method is suitable for the LPO analysis of polyphase, relatively coarse-grained (0.1–6 mm) rocks. The Meissen monzonite has a prominent shape-preferred orientation (SPO) of the non-equidimensional minerals feldspar, mica and amphibole, whereas SPO of the Podlesí granite is unapparent at the hand-specimen scale. The neutron diffraction data revealed distinct LPOs in both granitoids. The LPO of the non-equidimensional minerals feldspar, mica and amphibole developed mainly during magmatic flow. In the case of the Meissen monzonite, the magmatic flow was superimposed by regional shear tectonics, which, however, had no significant effect on the LPOs. In both samples, quartz shows a weak but distinct LPO, which is atypical for plastic deformation and different in the syn-kinematic Meissen monzonite and the post-kinematic Podlesí granite. We suggest that, first of all, the quartz LPO of the Meissen monzonite is the result of oriented growth in an anisotropic stress field. The quartz LPO of the Podlesí granite, which more or less resembles a deformational LPO in the flattening field of the local strain field, developed during magmatic flow, whereby the rhombohedral faces of the quartz crystals adhered to the (010) faces of aligned albite and to the (001) faces of zinnwaldite. Due to shape anisotropy of their attachments, the quartz crystals were passively aligned by magmatic flow. Thus, magmatic flow and oriented crystal growth are the major LPO-forming processes in both granitoids. For the Meissen monzonite, the solid-state flow was too weak to cause significant crystallographic re-orientation of the minerals aligned by magmatic flow. Finally, the significance of our results for the evaluation of the regional tectonic environment during magma emplacement is discussed. The discussion on the regional implications of the more methodologically oriented results provides the basis for future, more regionally aimed studies in view of the fabric characteristics of such plutons and their developing mechanisms.
    Keywords: Neutron diffraction; Lattice-preferred orientation; Shape-preferred orientation; Magmatic flow; Podlesí granite; Meissen Massif ; 551 ; Earth Sciences; Geology; Geophysics/Geodesy
    Language: English
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  • 6
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    The Neoproterozoic-early Paleozoic metamorphic and magmatic evolution of the Eastern Sierras Pampeanas: an overview (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: The Eastern Sierras Pampeanas were structured by three main events: the Ediacaran to early Cambrian (580–510 Ma) Pampean, the late Cambrian–Ordovician (500–440 Ma) Famatinian and the Devonian-Carboniferous (400–350 Ma) Achalian orogenies. Geochronological and Sm–Nd isotopic evidence combined with petrological and structural features allow to speculate for a major rift event (Ediacaran) dividing into two Mesoproterozoic major crustal blocks (source of the Grenvillian age peaks in the metaclastic rocks).This event would be coeval with the development of arc magmatism along the eastern margin of the eastern block. Closure of this eastern margin led to a Cambrian active margin (Sierra Norte arc) along the western margin of the eastern block in which magmatism reworked the same crustal block. Consumption of a ridge segment (input of OIB signature mafic magmas) which controlled granulite-facies metamorphism led to a final collision (Pampean orogeny) with the western Mesoprotrozoic block. Sm–Nd results for the metamorphic basement suggest that the TDM age interval of 1.8–1.7 Ga, which is associated with the less radiogenic values of εNd(540) (−6 to −8), can be considered as the mean average crustal composition for the Eastern Sierras Pampeanas. Increasing metamorphic grade in rocks with similar detrital sources and metamorphic ages like in the Sierras de Córdoba is associated with a younger TDM age and a more positive εNd(540) value. Pampean pre-540 Ma granitoids form two clusters, one with TDM ages between 2.0 and 1.75 Ga and another between 1.6 and 1.5 Ga. Pampean post-540 Ma granitoids exhibit more homogenous TDM ages ranging from 2.0 to 1.75 Ga. Ordovician re-activation of active margin along the western part of the block that collided in the Cambrian led to arc magmatism (Famatinian orogeny) and related ensialic back-arc basin in which high-grade metamorphism is related to mid-crustal felsic plutonism and mafic magmatism with significant contamination of continental crust. TDM values for the Ordovician Famatinian granitoids define a main interval of 1.8–1.6, except for the Ordovician TTG suites of the Sierras de Córdoba, which show younger TDM ages ranging from 1.3 to 1.0 Ga. In Devonian times (Achalian orogeny), a new subduction regime installed west of the Eastern Sierras Pampeanas. Devonian magmatism in the Sierras exhibit process of mixing/assimilation of depleted mantle signature melts and continental crust. Achalian magmatism exhibits more radiogenic εNd(540) values that range between 0.5 and −4 and TDM ages younger than 1.3 Ga. In pre-Devonian times, crustal reworking is dominant, whereas processes during Devonian times involved different geochemical and isotopic signatures that reflect a major input of juvenile magmatism.
    Keywords: Magmatism-metamorphism; Sm–Nd systematics; Tectonic evolution; Neoproterozoic-early Paleozoic orogenies; Eastern Sierras Pampeanas ; 551 ; Earth Sciences; Geophysics/Geodesy; Geology
    Language: English
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  • 7
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    Moisture expansion as a deterioration factor for sandstone used in buildings (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: The expansion processes that develop in building stones upon changes of moisture content may be an important contributing factor for their deteriorations. Until recently, few data could be found in the literature concerning this parameter and weathering processes. Moreover, the processes that may be responsible for the moisture related expansion of natural building stones are not yet completely understood. To further elucidate this process, extensive mineralogical, petrophysical and fabric investigations were performed on eight German sandstones in order to obtain more information regarding the weathering process and its dependence on the rock fabric. The analysed sandstones show a wide range of pore size distributions and porosities. A positive correlation with the fabric and the pore space can be found for all studied petrophysical parameters. The intensity of the expansion and related swelling pressure cannot be attributed only to the swelling of clay minerals. The investigations suggest that the micropores and the resulting disjoining pressure during wet/dry cycles also play an important role. The results obtained suggest that the mechanism is related to the presence of liquid water within the porous material.
    Keywords: Sandstone weathering; Moisture expansion; Hygric and hydric wetting; Swelling clay minerals ; 551 ; Earth Sciences; Geology
    Language: English
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  • 8
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    Optimized extraction of dimension stone blocks (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: The profitable production of dimension stone mainly depends on the extractable block size. The regularity and volume of the blocks are of critical importance, and are controlled by the three-dimensional pattern of the discontinuity system. Therefore, optimization of block size has to be the aim when quarrying for natural stone. This is mainly connected to the quantification of joints and fractures, i.e., their spacing and orientation. The problem of finding unfractured blocks within arbitrarily oriented and distributed planes can be solved effectively by a numerical algorithm. The main effects of joint orientations on block sizes and shapes will be presented in this article. Quantification of unfractured blocks with the aim of optimization is illustrated by detailed studies on several quarries. The algorithm used in this study can be applied as a powerful tool in the planning of a quarry and the future exploitation of dimension stone. Application of the described approach is demonstrated on practical examples of quarrying natural stones, namely, sandstone, granite, rhyolite, etc. Block quarrying can be optimized by using the new 3D-BlockExpert approach. The quantification of unfractured rock masses is also shown to contribute to a more ecological protection and the sustainable use of natural resources.
    Keywords: Production of dimension stones; Joints and fractures; Block sizes; Optimization ; 551 ; Earth Sciences; Geology
    Language: English
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  • 9
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    Physical weathering of building stones induced by freeze–thaw action: a laboratory long-term study (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: Damages to natural building stones induced by the action of frost are considered to be of great importance. Commonly, the frost resistance of building stones is checked by standardised freeze–thaw tests before using. Corresponding tests normally involve 30–50 freeze–thaw action cycles. In order to verify the significance of such measurements, we performed long-term tests on four selected rocks over 1,400 freeze–thaw action cycles. Additionally, numerous petrophysical parameters were analysed to compare the behaviour of rocks in the weathering tests according to the current explanatory models of stress formation by growing ice crystals in the pore space. The long-term tests yield more information about the real frost sensibility of the rocks. A clear deterioration cannot be determined in most cases until 50 weathering cycles have been completed. In the freeze–thaw tests, the samples are also stressed by changing temperature and moisture, indicating that different decay mechanisms can interfere with each other. Thus, thermohygric and moisture expansion are important damage processes.
    Keywords: Freeze–thaw action; Natural building stones; Microfabric; Pore space properties ; 551 ; Earth Sciences; Geology
    Language: English
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  • 10
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    Quality assessment of replacement stones for the Cologne Cathedral: mineralogical and petrophysical requirements (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: Owing to its long building history, different types of building stones comprised the construction of the Cologne Cathedral. Severe damage is observed on the different stones, e.g., sandstones, carbonate, and volcanic rocks, especially when the different stone materials neighbor the medieval “Drachenfels trachyte” from the “Siebengebirge”. The question arises, “Is the insufficient compatibility of the implemented building materials causatively related to the strong decay of the Drachenfels trachyte?” The present investigations focus on the petrography and mineralogical composition of eight different stones from the Cologne Cathedral. Petrophysical data, i.e., phase content, moisture and thermal characteristics as well as strength properties are determined and discussed in correlation to each other, showing that not only in terms of lithology great differences exist, but also the petrophysical properties strongly diverge. The ascertained parameters are discussed in view of the deterioration behavior and decay mechanisms of the different stones. To evaluate the compatibility of original, replacement and modern building materials, the properties of the investigated stones are compared to those of Drachenfels trachyte by means of constraints given in the literature. Besides optical properties, petrophysical criteria are also defined as well as strength values. It could be shown that primarily moisture properties, i.e., capillary and sorptive water uptake, water saturation, drying processes and moisture dilatation can be addressed to the deterioration processes.
    Keywords: Stone decay; Cologne Cathedral; Compatibility of building materials; Requirements for replacement stones ; 551 ; Earth Sciences; Geology
    Language: English
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  • 11
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    Traces of the bone-eating annelid Osedax in Oligocene whale teeth and fish bones (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-04-27
    Description: The range of substrates that the bone-eating marine worm Osedax is able to consume has important implications for its evolutionary history, especially its potential link to the rise of whales. Once considered a whale specialist, recent work indicates that Osedax consumes a wide range of vertebrate remains, including whale soft tissue and the bones of mammals, birds and fishes. Traces resembling those produced by living Osedax have now been recognized for the first time in Oligocene whale teeth and fish bones from deep-water strata of the Makah, Pysht and Lincoln Creek formations in western Washington State, USA. The specimens were acid etched from concretions, and details of the borehole morphology were investigated using micro-computed tomography. Together with previously published Osedax traces from this area, our results show that by Oligocene time Osedax was able to colonize the same range of vertebrate remains that it consumes today and had a similar diversity of root morphologies. This supports the view that a generalist ability to exploit vertebrate bones may be an ancestral trait of Osedax.
    Keywords: Deep-sea; Trace fossil; Osedax; Whale; Fish; Micro-CT; Tiefsee; Spurenfossil; Osedax; Wal; Fisch; Micro-CT ; 551 ; Earth Sciences; Paleontology
    Language: English
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  • 12
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    Propagation, linkage, and interaction of caldera ring-faults: comparison between analogue experiments and caldera collapse at Miyakejima, Japan, in 2000 (2018)
    Springer-Verlag | Springer-Verlag
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    Publication Date: 2021-03-29
    Description: The formation of ring faults yields important implications for understanding the structural and dynamic evolution of collapse calderas and potentially associated ash-flow eruptions. Caldera collapse occurred in 2000 at Miyakejima Island (Japan) in response to a lateral intrusion. Based on geophysical data it is inferred that a set of caldera ring faults was propagating upward. To understand the kinematics of ring-fault propagation, linkage, and interaction, we describe new laboratory sand-box experiments that were analyzed through Digital Image Correlation (DIC) and post-processed using 2D strain analysis. The results help us gain a better understanding of the processes occurring during caldera subsidence at Miyakejima. We show that magma chamber evacuation induces strain localization at the lateral chamber margin in the form of a set of reverse faults that sequentially develops and propagates upwards. Then a set of normal faults initiates from tension fractures at the surface, propagating downwards to link with the reverse faults at depth. With increasing amounts of subsidence, interaction between the reverse- and normal-fault segments results in a deactivation of the reverse faults, while displacement becomes focused on the outer normal faults. Modeling results show that the area of faulting and collapse migrates successively outward, as peak displacement transfers from the inner ring faults to later developed outer ring faults. The final structural architecture of the faults bounding the subsiding piston-like block is hence a consequence of the amount of subsidence, in agreement with other caldera structures observed in nature. The experimental simulations provide an analogy to the observations and seismic records of caldera collapse at Miyakejima volcano, but are also applicable to caldera collapse in general.
    Keywords: Collapse calderas; Ring faults; Analogue modeling; Fault kinematics; Digital image correlation ; 551 ; Earth Sciences; Sedimentology ; Mineralogy ; Geophysics/Geodesy ; Geology
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  • 13
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    Proximate causes of deforestation in the Bolivian lowlands: an analysis of spatial dynamics (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: Forests in lowland Bolivia suffer from severe deforestation caused by different types of agents and land use activities. We identify three major proximate causes of deforestation. The largest share of deforestation is attributable to the expansion of mechanized agriculture, followed by cattle ranching and small-scale agriculture. We utilize a spatially explicit multinomial logit model to analyze the determinants of each of these proximate causes of deforestation between 1992 and 2004. We substantiate the quantitative insights with a qualitative analysis of historical processes that have shaped land use patterns in the Bolivian lowlands to date. Our results suggest that the expansion of mechanized agriculture occurs mainly in response to good access to export markets, fertile soil, and intermediate rainfall conditions. Increases in small-scale agriculture are mainly associated with a humid climate, fertile soil, and proximity to local markets. Forest conversion into pastures for cattle ranching occurs mostly irrespective of environmental determinants and can mainly be explained by access to local markets. Land use restrictions, such as protected areas, seem to prevent the expansion of mechanized agriculture but have little impact on the expansion of small-scale agriculture and cattle ranching. The analysis of future deforestation trends reveals possible hotspots of future expansion for each proximate cause and specifically highlights the possible opening of new frontiers for deforestation due to mechanized agriculture. Whereas the quantitative analysis effectively elucidates the spatial patterns of recent agricultural expansion, the interpretation of long-term historic drivers reveals that the timing and quantity of forest conversion are often triggered by political interventions and historical legacies.
    Keywords: Bolivia; Amazon; Deforestation; Proximate causes; Spatial analysis; Multinomial logistic regression ; 551 ; Environment; Geology; Geography (general); Regional/Spatial Science; Climate Change; Nature Conservation; Oceanography
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  • 14
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    Calcifying extracellular mucus substances (EMS) of Madrepora oculata (2018)
    Springer | Berlin [u.a.]
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    Publication Date: 2021-04-25
    Description: Colonial non-zooxanthellate corals from deep-water coral reefs, Lophelia pertusa and Madrepora oculata, produce large amounts of extracellular mucus (EMS). This mucus has various functions, e.g., an antifouling capability protecting the coral skeleton from attacks of endolithic and boring organisms. Both corals show thick epithecal and exothecal skeletal parts with a clear lamellar growth pattern. The formation of the epitheca is unclear. It is supposed that the EMS play a central role during the calcification process of the epithecal skeletal parts. Staining with the fluorochrome tetracycline has shown an enrichment of Ca2+ ions in the mucus. In order to investigate this hypothesis, the protein content of the mucus and the intracrystalline organic matter from newly formed epithecal aragonite of Madrepora oculata was determined via sodium dodecyl sulfate (SDS) gel electrophoresis. Identical band patterns within both substances could be detected, one around 45 kDa molecular weight and a cluster around 30-35 kDa molecular weight. The occurrence of identical protein patterns within the mucus and in the newly formed aragonite confirms the idea that the mucus plays an important role during the organomineralization of the coral epitheca.
    Keywords: 551 ; VU 000 ; 38.20
    Language: English
    Type: anthologyArticle , publishedVersion
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  • 15
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    Monument futures: climate change, air pollution, decay and conservation—the Wolf-Dieter Grimm-volume (2018)
    Springer-Verlag | Springer-Verlag
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    Publication Date: 2021-03-29
    Keywords: 551 ; Geosciences; Geology
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  • 16
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    Major shear zones of southern Brazil and Uruguay: escape tectonics in the eastern border of Rio de La plata and Paranapanema cratons during the Western Gondwana amalgamation (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: The Mantiqueira Province represents a series of supracrustal segments of the South-American counterpart formed during the Gondwana Supercontinent agglutination. In this crustal domain, the process of escape tectonics played a conspicuous role, generating important NE–N–S-trending lineaments. The oblique component of the motions of the colliding tectonic blocks defined the transpressional character of the main suture zones: Lancinha-Itariri, Cubatão-Arcádia-Areal, Serrinha-Rio Palmital in the Ribeira Belt and Sierra Ballena-Major Gercino in the Dom Feliciano Belt. The process as a whole lasted for ca. 60 Ma, since the initial collision phase until the lateral escape phase predominantly marked by dextral and subordinate sinistral transpressional shear zones. In the Dom Feliciano Belt, southern Brazil and Uruguay, transpressional event at 630–600 Ma is recognized and in the Ribeira Belt, despite less coevally, the transpressional event occurred between 590 and 560 Ma in its northern-central portion and between ca. 625 and 595 Ma in its central-southern portion. The kinematics of several shear zones with simultaneous movement in opposite directions at their terminations is explained by the sinuosity of these lineaments in relation to a predominantly continuous westward compression.
    Keywords: Mantiqueira Province; Gondwana agglutination; Suture zones; Escape tectonics; Metamorphic-deformational events ; 551 ; Earth Sciences; Geophysics/Geodesy; Geology
    Language: English
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  • 17
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    Extreme precipitation events in the Mediterranean: Spatiotemporal characteristics and connection to large‐scale atmospheric flow patterns (2021)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2021-07-01
    Description: The Mediterranean region is strongly affected by extreme precipitation events (EPEs), sometimes leading to severe negative impacts on society, economy, and the environment. Understanding such natural hazards and their drivers is essential to mitigate related risks. Here, EPEs over the Mediterranean between 1979 and 2019 are analysed, using ERA5, the latest reanalysis dataset from ECMWF. EPEs are determined based on the 99th percentile of their daily distribution (P99). The different EPE characteristics are assessed, based on seasonality and spatiotemporal dependencies. To better understand their connection to large‐scale atmospheric flow patterns, Empirical Orthogonal Function analysis and subsequent non‐hierarchical K‐means clustering are used to quantify the importance of weather regimes to EPE frequency. The analysis is performed for different variables, depicting atmospheric variability in the lower and middle troposphere. Results show a clear spatial division in EPE occurrence, with winter and autumn being the seasons of highest EPE frequency for the eastern and western Mediterranean, respectively. There is a high degree of temporal dependencies with 20% of the EPEs (median value based on all studied grid cells), occurring up to 1 week after a preceding P99 event at the same location. Local orography is a key modulator of the spatiotemporal connections and substantially enhances the probability of co‐occurrence of EPEs even for distant locations. The clustering clearly demonstrates the prevalence of distinct synoptic‐scale atmospheric conditions during the occurrence of EPEs for different locations within the region. Results indicate that clustering, based on a combination of sea level pressure (SLP) and geopotential height at 500 hPa (Z500), can increase the conditional probability of EPEs by more than three (3) times (median value for all grid cells) from the nominal probability of 1% for the P99 EPEs. Such strong spatiotemporal dependencies and connections to large‐scale patterns can support extended‐range forecasts.
    Description: This study analyses the spatiotemporal characteristics of extreme precipitation events over the Mediterranean, and their connection to large‐scale atmospheric flow patterns. It is shown that by conditioning the extremes based on the atmospheric variability in the low‐ and mid‐troposphere, their probability increases more than threefold, when using nine clusters to group all the synoptic daily patterns. This finding can support extended‐range forecasts, as for such lead times the NWP models are more skillful in predicting large‐scale patterns than localized extremes.
    Description: Marie Skłodowska‐Curie
    Description: European Union's Horizon 2020
    Keywords: 551.6 ; extreme precipitation ; large‐scale/circulation patterns ; Mediterranean ; weather regimes
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    Exhumation and uplift of the Sierras Pampeanas: preliminary implications from K–Ar fault gouge dating and low-T thermochronology in the Sierra de Comechingones (Argentina) (2018)
    Springer-Verlag | Berlin/Heidelberg
    Details
    Publication Date: 2021-03-29
    Description: The Sierras Pampeanas in central and north-western Argentina constitute a distinct morphotectonic feature between 27°S and 33°S. The last stage of uplift and deformation in this area are interpreted to be closely related to the Andean flat-slab subduction of the Nazca plate beneath the South American plate. K–Ar fault gouge dating and low-temperature thermochronology along two transects within the Sierra de Comechingones reveal a minimum age for the onset of brittle deformation about 340 Ma, very low exhumation rates since Late Paleozoic time, as well as a total exhumation of about 2.3 km since the Late Cretaceous. New Ar–Ar ages (7.54–1.91 Ma) of volcanic rocks from the San Luis volcanic belt support the eastward propagation of the flat-slab magmatic front, confirming the onset of flat-slab related deformation in this region at 11.2 Ma. Although low-temperature thermochronology does not clearly constrain the signal of the Andean uplift, it is understood that the current structural relief related to the Comechingones range has been achieved after the exhumation of both fault walls (circa 80–70 Ma).
    Keywords: Sierras Pampeanas; K–Ar dating; Fault gouge dating; Low thermal geochronology; Andean uplift ; 551 ; Earth Sciences; Geophysics/Geodesy; Geology
    Language: English
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    Hydrogen incorporation in enstatite in the system MgO-SiO2-H2O-NaCl (2018)
    Springer
    Details
    Publication Date: 2021-03-29
    Description: The incorporation of hydrogen in enstatite in a hydrous system containing various amounts of NaCl was investigated at 25 kbar. The hydrogen content in enstatite shows a clear negative correlation to the NaCl-concentration in the system. The most favourable explanation is the reduction of water fugacity due to dilution. Other reasons for the limited hydrogen incorporation at high NaCl levels, such as a significant influence of Na+ on the defect chemistry or an exchange between OH- and Cl-in enstatite, appear much less important. A partition coefficient D Na En/Fluid = 0.0013 could be determined, demonstrating that Na is less incompatible in enstatite than H. The new results support the idea that dissolved components have to be considered when the total hydrogen storage capacity in nominally anhydrous minerals is estimated, especially in geological settings with high levels of halogens, such as subduction zones.
    Keywords: KEnstatite; Hydrogen incorporation;Water activity; Sodium; Chlorine ; 551
    Language: English
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    Mechanism of uranium fixation by zero valent iron: the importance of co-precipitation (2018)
    Springer | Berlin
    Details
    Publication Date: 2021-03-29
    Description: The coprecipitation of U (VI) with iron corrosion products from aqueous solutions by zero valent iron was investigated. The evidence of coprecipitation was demonstrated by conducting experiments with well characterized scrap iron,pyrite and a mixture of both materials with experimental durations of up to four months. Results indicate that under anoxic conditions only less than one tenth of the immobilized U(VI) was associated with the surface of scrap iron, whereas theremaining amount is entrapped in aging corrosion products.
    Keywords: 551
    Language: English
    Type: anthologyArticle , acceptedVersion
    Format: 577-586
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    Short-term fluctuations in vegetation and phytoplankton during the Middle Eocene greenhouse climate: a 640-kyr record from the Messel oil shale (Germany) (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: The Palaeogene was the most recent greenhouse period on Earth. Especially for the Late Palaeocene and Early Eocene, several superimposed short-term hyperthermal events have been described, including extremes such as the Palaeocene–Eocene Thermal Maximum. Major faunal and floral turnovers in the marine and terrestrial realms were recorded in association with these events. High-resolution palynological analysis of the early Middle Eocene maar lake sediments at Messel, near Darmstadt, Germany, provides an insight into the dynamics of a climax vegetation during the Middle Eocene greenhouse climate in a time span without significant climatic excursions. Numerical techniques like detrended correspondence analysis and wavelet analysis have been applied to recognize cyclic fluctuations and long-term trends in the vegetation through a time interval of approximately 640 kyr. Based on the numerical zoning of the pollen diagram, three phases in the development of the vegetation may be distinguished. Throughout these phases, the climax vegetation did not change substantially in qualitative composition, but a trend towards noticeably less humid conditions probably in combination with a drop of the water level in the lake may be recognized. A shift in algal population from the freshwater dinoflagellate cyst Messelodinium thielepfeifferae to a dominance of Botryococcus in the uppermost part of the core is interpreted as a response to changes in acidity and nutrient availability within the lake. Time series analyses of pollen assemblages show that variations in the Milankovitch range of eccentricity, obliquity and precession can be distinguished. In addition, fluctuations in the sub-Milankovitch range are indicated. This demonstrates that floral changes during steady depositional conditions in the Middle Eocene of Messel were controlled by orbital forcing.
    Keywords: Middle Eocene; Maar lake; Palynology; Climate variability; Milankovitch cycles; Multivariate statistics; Time series analysis ; 551 ; Earth Sciences; Geology; Geophysics/Geodesy
    Language: English
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    Microbial diversity on a marble monument: a case study (2018)
    Springer-Verlag | Berlin/Heidelberg
    Details
    Publication Date: 2021-03-29
    Description: In the presented case study, ascomycete fungi and green algae on a marble monument were identified by comparisons of the 18S rRNA gene sequences, which were obtained from DNA either from environmental samples or from enrichment cultures. The organisms were found to be responsible for either black or green surface coverings on different areas of the monument surface. Most fungi were related to plant-inhabiting genera, corresponding to a heavy soiling of the marble surface with honeydew. Whereas green algae of the genera Stichococcus, Chloroidium and Apatococcus were found to be dominant in all samples, isolates of two additional genera were recovered only from enrichment cultures. A reference strain of Apatococcus lobatus and an isolate of Prasiolopsis sp. were investigated with respect to putative surface adhesive structures of the cell envelope. The Prasiolopsis cell walls were covered with a thin adhesive exopolysaccharide layer involved in biofilm formation.
    Keywords: Marble monument; Biofilm; Ascomycete fungi; Green algae; Cell wall; Exopolysaccharide ; 551 ; Earth Sciences; Geology
    Language: English
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    Bowing of dimensional granitic stones (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: Bowing is a well-known phenomenon seen in marbles used as building veneers. This form of rock weathering occurs as a result of external factors such as temperature, humidity, the system for anchoring the marble slabs or the panel dimensions. Under the same external conditions, many factors will determine the degree of deformation including petrography, thermal properties and residual locked stresses. The usual way to solve the problem of bowed marble slabs is to replace them with other materials, such as granites, in which the deformation still exists but is less common. In this study, eight ornamental granites with different mineralogy, grain size, grain shape, porosity and fabric were tested in a laboratory to assess their susceptibility to bowing. Three slabs of granite, each cut with a different orientation, were studied under different conditions of temperature (90 and 120°C) and water saturation (dry and wet) to investigate the influence of these factors together with that of anisotropy. At 90°C, only the granite with the coarsest grain size and low porosity exhibited deformation under wet conditions. At 120°C and wet conditions, three of the granites showed evident signs of bowing. Again, the granite with the coarsest grain size was the most deformed. It was concluded that the wide grain size distribution influences microcracking more than other expected factors, such as the quartz content of the rock. Also, mineral shape-preferred orientation and porosity play an important role in the bowing of the studied granites.
    Keywords: Granitoids; Bowing; Texture; Thermal expansion ; 551 ; Earth Sciences; Geology
    Language: English
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    Multi-stage emplacement of the Götemar Pluton, SE Sweden: new evidence inferred from field observations and microfabric analysis, including cathodoluminescence microscopy (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: The emplacement of the Mesoproterozoic Götemar Pluton into Paleoproterozoic granitoid host rocks of the Transscandinavian Igneous Belt is re-examined by microfabric analysis, including cathodoluminescence microscopy. Field data on the pluton-host rock system are used to strengthen the model. The Götemar Pluton, situated on the Baltic Shield of SE Sweden, is a horizontally zoned tabular structure that was constructed by the intrusion of successive pulses of magma with different crystal/melt ratios, at an estimated crustal depth of 4–8 km. Initial pluton formation involved magma ascent along a vertical dike, which was arrested at a mechanical discontinuity within the granitoid host rocks; this led to the formation of an initial sill. Subsequent sill stacking and their constant inflation resulted in deformation and reheating of existing magma bodies, which also raised the pluton roof. This multi-stage emplacement scenario is indicated by complex dike relationships and the occurrence of several generations of quartz (Si-metasomatism). The sills were charged by different domains of a heterogeneous magma chamber with varying crystal/melt ratios. Ascent or emplacement of magma with a high crystal/melt ratio is indicated by syn-magmatic deformation of phenocrysts. Complex crystallization fabrics (e.g. oscillatory growth zoning caused by high crystal defect density, overgrowth and replacement features, resorbed and corroded crystal cores, rapakivi structure) are mostly related to processes within the main chamber, that is repeated magma mixing or water influx.
    Keywords: Pluton emplacement; Microfabrics; Cathodoluminescence; Mesoproterozoic; Götemar; SE Sweden ; 551 ; Earth Sciences; Geophysics/Geodesy; Geology
    Language: English
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    Provenance of Pleistocene Rhine River Middle Terrace sands between the Swiss–German border and Cologne based on U–Pb detrital zircon ages (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Keywords: Provenance; Heavy minerals; Detrital zircon; U–Pb dating; Rhine River; Alps ; 551 ; Earth Sciences; Geology; Geophysics/Geodesy
    Language: English
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    Localisation and temporal variability of groundwater discharge into the Dead Sea using thermal satellite data (2018)
    Springer-Verlag | Berlin/Heidelberg
    Details
    Publication Date: 2021-03-29
    Keywords: Landsat ETM+; Sea surface temperature; Submarine groundwater discharge; Groundwater resource ; 551 ; Earth Sciences; Geology
    Language: English
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    Dolomitic slates from Uruguay: petrophysical and petromechanical characterization and deposit evaluation (2018)
    Springer-Verlag | Berlin/Heidelberg
    Details
    Publication Date: 2021-03-29
    Description: Slates are internationally known as roof and façade-cladding material since prehistoric times. The methods required to mine and manufacture these dimensional stones are relatively simple in comparison to those utilized in granitic dimensional stones. This has led to a worldwide rentable commercialization of slate in the last centuries and also to the development of characteristic cultural landscapes. In Uruguay several slates are mined and used in architecture, especially as façade cladding and floor slabs. The most important slates regarding their production and utilization are the dolomitic slates. These dolomitic slates are associated with the Neoproterozoic thrust and fold belt of the Dom Feliciano belt. Representative samples have been geochemically and petrographically characterized, as well as petrophysically and petromechanically analyzed. The petrophysical and petromechanical properties were investigated in a very systematic way with respect to the new European standards, showing values comparable to those registered for internationally known slates. Detailed structural and deposit analysis were carried out in Uruguay in order to evaluate the dolomitic slate deposits. The slates are linked to calc-silicate strata in a greenschist facies volcano-sedimentary sequence and the deposits are located in the limb of a regional fold, where bedding and cleavage are parallel. The main lithotype is a layered and fine-grained dolomitic slate with a quite diverse palette of colors: light and dark green, gray, dark gray, reddish and black. The mined slate is split into slabs 0.5–2 cm thick. In the past, the average production in Uruguay was around 4,000 tons/year and a historical maximum of 13,000 tons was reached in 1993 (Oyhantçabal et al. in Z dt Ges Geowiss 158(3):417–428, 2007). The oscillations in the regional demand were the cause of several flourishing and decay cycles in the activity, but our investigation shows a considerable volume of indicated resources and therefore a very good potential.
    Keywords: Slates; Dimensional stones; Petrophysical properties; Petrography; Uruguay ; 551 ; Earth Sciences; Geology
    Language: English
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    Microcracking in calcite and dolomite marble: microstructural influences and effects on properties (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: Microstructure‐based finite-element analysis with a microcracking algorithm was used to simulate an actual degradation phenomenon of marble structures, i.e., microcracking. Both microcrack initiation and crack propagation were characterized, as were their dependence on lattice preferred orientation (LPO), grain shape preferred orientation (SPO), grain size, marble composition (calcite and dolomite) and grain‐boundary fracture toughness. Two LPOs were analyzed: a random orientation distribution function and an orientation distribution function with strong directional crystalline texture generated from a March–Dollase distribution. Three SPOs were considered: equiaxed grains; elongated grains and a mixture of equiaxed and elongated grains. Three different grain sizes were considered: fine grains of order 200 μm (only calcitic marble); medium size grains of order 1 mm (calcitic and dolomitic marbles); and large grains of order 2 mm (only dolomitic marble). The fracture surface energy for the grain boundaries, γig, was chosen to be 20 and 40 % of the fracture surface energy of a grain, γxtal, so that both intergranular and transgranular fracture were possible. Studies were performed on these idealized marble microstructures to elucidate the range of microcracking responses. Simulations were performed for both heating and cooling by 50 °C in steps of 1 °C. Microcracking results were correlated with the thermoelastic responses, which are indicators related to degradation. The results indicate that certain combinations of LPO, SPO, grain size, grain‐boundary fracture toughness and marble composition have a significant influence on the thermal-elastic response of marble. Microstructure with the smallest grain size and the highest degree of SPO and LPO had less of a tendency to microcrack. Additionally, with increasing SPO and LPO microcracking becomes more spatially anisotropic. A significant observation for all microstructures was an asymmetry in microcracking upon heating and cooling: more microcracking was observed upon cooling than upon heating. Given an identical microstructure and crystallographic texture, calcite showed larger thermal stresses than dolomite, had an earlier onset of microcracking upon heating and cooling, and a greater microcracked area at a given temperature differential. Thermal expansion coefficients with and without microcracking were also determined.
    Keywords: Marble; Microcracking; Finite-element modeling; Lattice preferred orientation; Shape preferred orientation; Strain energy density; Maximum principal stress; Thermal expansion coefficient; Thermal expansion anisotropy ; 551 ; Earth Sciences; Geology
    Language: English
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    Granitic dimensional stones in Uruguay: evaluation and assessment of potential resources (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: In Uruguay commercial granite varieties comprise mafic rocks, granitoids, and syenitoids. There is a long tradition in Uruguay, as well as worldwide, of using dimensional stones in architecture and art, specially granitic ones. Some of the present applications of these dimensional stones are as façade cladding, countertops, and outdoor and indoor floor slabs. The color spectrum of the Uruguayan granitic dimensional stones varies from black to light gray, covering a wide variety of red and pink and minor greenish-gray. The décor of these granitic dimensional stones is mainly determined by their fabric, fundamentally the grain size and the color distribution between the different minerals that compose the rocks. In the present research the most important commercial granites were sampled to analyze their petrography and petrophysical properties. A detailed structural analysis has been performed in several deposits, as well as the application of the software 3D Block Expert for modeling the possible raw block size distribution. Other factors controlling the mining viability of the deposits were also studied (e.g., homogeneity/heterogeneity of color and décor) and the possible reserves were calculated.
    Keywords: Granitic dimensional stones; Petrophysical properties; Petrography; Deposit characterization; Uruguay ; 551 ; Earth Sciences; Geology
    Language: English
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    Moisture expansion associated to secondary porosity: an example of the Loseros Tuff of Guanajuato, Mexico (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: The old mining city of Guanajuato in middle Mexico preserves one of the most important historical legacies in colonial buildings, the UNESCO declared the city World Heritage Site in 1988. Practically all the colonial constructions were built with natural stones from the neighbourhood, of which stands a greenish to reddish vulcanite, called Loseros Tuff. Although the Loseros Tuff is widely used in historical buildings in the city. It shows significant deterioration and weathering effects, principally in the parts where the tuff shows a coarse grain size. The petrographic, petrophysical, mineralogical and geochemical properties of the Loseros Tuff were analysed in order to determine the causes, effects, behaviour and response to deterioration of this volcanic rock. The results of the investigations suggest that in addition to the parameters like the grain size and the porosity properties, the pore radii distribution is decisive for the effectiveness of porosity and the water transport into the rock. It is recognized that once the liquid water invades the rock the dissolution of the matrix occurs, which is accompanied by a sudden moisture expansion favoured by the newly formed secondary porosity and the high content of expandable clay minerals.
    Keywords: Tuff; Moisture expansion; Porosity; Guanajuato ; 551 ; Earth Sciences; Geology
    Language: English
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    Bestimmung der Schadstofffrachten an Kontrollebenen mithilfe von Punktkonzentrationsmessungen und Immissionspumpversuchen – ein Vergleich (2018)
    Springer-Verlag
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    Publication Date: 2021-03-29
    Description: Kurzfassung Die Quantifizierung der Schadstofffrachten an Kontrollebenen ist eine entscheidende Voraussetzung zur Bewertung von Grundwasserschadensfällen und zum Nachweis von Natural Attenuation. Hierzu können zwei verschiedene Erkundungsansätze, die Frachtbestimmung basierend auf der Interpolation von Punktkonzentrationsmessungen sowie Immissionspumpversuche, verwendet werden. Punktkonzentrationsmessungen haben den entscheidenden Nachteil, dass in der Regel nur eine ausreichend große Anzahl sicher stellen kann, dass die gesamte Abstromfahne erfasst wird. Immissionspumpversuche können wiederum relativ hohe Grundwasseraufbereitungs- und Entsorgungskosten verursachen und nur in ausreichend durchlässigen Grundwasserleitern durchgeführt werden. Ein Vergleich der Ergebnisse aus der Anwendung beider Erkundungsansätze kann eine Hilfestellung bei der Konzipierung von Erkundungsmaßnahmen bieten. Daher wurden die Resultate von vier Immissionspumpversuchen mit Messungen in 13, in kurzem Abstand zueinander errichteten, Direct-Push-Messstellen auf dem Gelände eines ehemaligen Gaswerks verglichen. Es konnte festgestellt werden, dass die Vergleichbarkeit der Erkundungsergebnisse je nach Standortsituation stark von der Heterogenität der Verteilung der Schadstoffe im Grundwasserleiter abhängt. Die Studie legt nahe, dass insbesondere bei stark heterogenen Verhältnissen im Grundwasserleiter Immissionspumpversuche bei der Wahl der Erkundungsmethode bevorzugt werden sollten, da die Interpolation von Punktkonzentrationsmessungen selbst im Falle eines relativ engmaschigen Messstellennetzes zu einer großen Erkundungsunsicherheit führen kann.
    Description: The quantification of contaminant mass flow rates at control planes is an essential prerequisite for assessing contaminated sites and for providing evidence of natural attenuation. Two different investigation approaches are usually implemented: mass flow estimation based on interpolation of point scale concentration measurements, and integral pumping tests. Point scale concentration measurements have the crucial disadvantage that in general, only a sufficiently dense monitoring network can ensure that the plume is completely covered. On the other hand, integral pumping tests may require expensive groundwater treatment and disposal and are only applicable in sufficiently conductive aquifers. A comparison of results from the application of both approaches can help with respect to the selection of a subsurface investigation method. A former gasworks site was chosen to compare the results of four integral pumping tests and measurements obtained from 13 direct-push-wells, which were installed at a relatively close spacing. The comparison shows that the correlation of the two methods depends strongly on the heterogeneity of the contaminant distribution within the aquifer. The study suggests that especially in the case of heterogeneous settings, integral pumping tests should be chosen for subsurface investigations, as interpolated point scale concentration measurements, even if densely spaced, can still bear a prohibitively high degree of uncertainty.
    Keywords: contaminant mass flow rate; integral pumping tests; point scale concentration measurements; remediation optimization ; 551 ; Geosciences; Geoecology/Natural Processes; Soil Science & Conservation ; Applied Geosciences ; Waste Water Technology / Water Pollution Control / Water Management / Aquatic Pollution; Hydrogeology
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    Stability assessment of marble statuaries of the Schlossbrücke (Berlin, Germany) based on rock strength measurements and ultrasonic wave velocities (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: The degree of weathering in natural stones on buildings and sculptures has been determined for many years in numerous cases by means of ultrasonic measurements. Conclusions concerning the strength of the rock and the type of weathering can thus be drawn. This relationship has not been established for all rock types. Most of the progress utilizing this method has been made in the analysis of marbles, where an increasing degree of weathering shows lower ultrasonic velocities. In the present study, four Carrara marble samples showing similar rock fabrics, but with respect to weathering exhibit considerable differences are investigated. Porosity varies between 0.2 vol. % and ca. 2.4 vol. %, whereby with increasing porosity the pore radii changes as well. Parallel to this the ultrasonic velocities change in dry samples from about 5.5 to 1.6 km/s, respectively. Model calculations reveal that the velocity reduction is caused by cracks with an extremely small aspect ratio of about 0.005 or even less. After a specific loss of strength, however, solution processes can become active, which modify the microcracks and generate an opposite trend. In the process a strong porosity increase correlates to a relatively small velocity reduction. With the presence of water the Vp porosity weathering relationship experiences a considerable modification. Parallel to the reduction of the ultrasonic velocities, it was determined that the mechanical strength (compressive strength, flexural strength, etc.) as well as the static Young’s modulus is reduced almost equally by a progressive advancement of the weathering front. In one case study dealing with tensile strengths, it was clearly documented how tensile cracks develop and propagate in dependence of the rock fabric. The rock mechanical and ultrasonic velocity data were used for stability assessments applied to the marble statuaries from the Schlossbrücke in Berlin. Stability assessments of the sculpture group 4 reveal that some critical parts must be replaced due to safety reasons.
    Keywords: Marble waethering; Mechanical properties; Ultrasonic wave velocites; Stability assessment; Cultural heritage ; 551 ; Earth Sciences; Geology
    Language: English
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    Cambrian sedimentary dykes in the Proterozoic basement of the Västervik area (southeast Sweden): episodic formation inferred from macro- and microfabrics (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: Fabrics of Cambrian sedimentary dykes formed in Proterozoic granites of the Västervik area (Southeast Sweden) evidence repeated opening/filling and mineralisation/cementation events under varying conditions. Diagnostic features include (1) wall-parallel boundaries between epiclastic fillings and (2) early formed dyke sediments that appear as lithoclasts in subsequently formed sedimentary fillings. The psammitic components mostly consist of well-rounded quartz grains related to a coastal environment and fragments from the granitic host rock. Platy calcitic fragments embedded in the epiclastic matrix originally formed as microveins within already-lithified dyke sediments and the adjacent host rock. Convex downward-pointing, internal sagging structures, together with the preferred orientation of compositional boundaries and long axes of grains/rock fragments parallel to the dyke walls, are interpreted as the result of suction-controlled flow of unconsolidated fillings during episodes of downward dyke growth. Pressure solution of quartz grains are evidence of extensional phases with dyke propagation that were interrupted by phases of horizontal compression normal to the dyke walls. The N–S and NE–SW striking sedimentary dykes formed by opening of a pre-existing joint set during NW–SE oriented rifting during the Cambrian.
    Keywords: Sedimentary dykes; Proterozoic; Southeast Sweden; Microfabrics; Passive infill; Cambrian geodynamics ; 551 ; Earth Sciences; Geology; Geophysics/Geodesy
    Language: English
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    Weathering of volcanic tuff rocks caused by moisture expansion (2018)
    Springer-Verlag | Berlin/Heidelberg
    Details
    Publication Date: 2021-03-29
    Description: Moisture expansion in natural building stones is considered one of the most important factors affecting their weathering and deterioration. The processes that may be responsible for the expansion under determinate relative humidity (hygric dilatation) and water-saturated conditions (hydric dilatation) are generally attributed to the presence of swellable clay minerals. In contrast to this assumption, our investigations show that moisture expansion also takes place in volcanic tuff building stones almost free from clay minerals. To provide a deeper understanding of the processes, swelling and deterioration were performed on 14 volcanic tuffs used as important building stones of different ages, compositions and weathering stages from Mexico, Germany and Hungary. The investigations undertaken include extensive chemical, petrophysical and fabric analyses. The samples show a wide range of effective porosity, microporosity, capillary water absorption, moisture expansion, and CEC values. High moisture expansion does not seem to depend on clay mineral content alone. We also observed that there is no significant effect on dilatation if clay minerals are present but only form a thin coat on the outer shell of bigger pores. Moreover, we identified a correlation between microporosity, average pore radius and moisture expansion. The investigations highlight the fact that moisture expansion cannot only be attributed to swellable clay minerals, and suggest that the presence and accumulation of micropores and their average radius and distribution play an important role for non-clay associated swelling intensity, which can most probably be attributed to the disjoining pressure.
    Keywords: Weathering of tuffs; Hygric expansion; Hydric expansion; Clay mineralogy; Microporosity; Disjoining pressure ; 551 ; Earth Sciences; Geology
    Language: English
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    Discrimination of TiO2 polymorphs in sedimentary and metamorphic rocks (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: Investigation by Raman spectroscopy of samples from different geological settings shows that the occurrence of TiO2 polymorphs other than rutile can hardly be predicted, and furthermore, the occurrence of anatase is more widespread than previously thought. Metamorphic pressure and temperature, together with whole rock chemistry, control the occurrence of anatase, whereas variation of mineral assemblage characteristics and/or fluid occurrence or composition takes influence on anatase trace element characteristics and re-equilibration of relict rutiles. Evaluation of trace element contents obtained by electron microprobe in anatase, brookite, and rutile shows that these vary significantly between the three TiO2 phases. Therefore, on the one hand, an appropriation to source rock type according to Nb and Cr contents, but as well application of thermometry on the basis of Zr contents, would lead to erroneous results if no phase specification is done beforehand. For the elements Cr, V, Fe, and Nb, variation between the polymorphs is systematic and can be used for discrimination on the basis of a linear discriminant analysis. Using phase group means and coefficients of linear discriminants obtained from a compilation of analyses from samples with well-defined phase information together with prior probabilities of groupings from a natural sample compilation, one is able to calculate phase grouping probabilities of any TiO2 analysis containing at least the critical elements Cr, V, Fe, and Nb. An application of this calculation shows that for the appropriation to the phase rutile, a correct-classification rate of 99.5% is obtained. Hence, phase specification by trace elements proves to be a valuable tool besides Raman spectroscopy.
    Keywords: TiO2 polymorph discrimination; Phase classification; Anatase; Brookite; Rutile; Erzgebirge; Zr-in-rutile thermometry ; 551 ; Earth Sciences; Mineral Resources; Mineralogy; Geology
    Language: English
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    The transpressional connection between Dom Feliciano and Kaoko Belts at 580–550 Ma (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: A new U–Pb SHRIMP age of 551 ± 4 Ma on a mylonitic porphyry that intruded into the Sierra Ballena Shear Zone (Southernmost Dom Feliciano Belt, Uruguay) and a review of relevant published data make possible a more refined correlation and reconstruction of Brasiliano/Pan-African transpressional events. Paleogeographic reconstruction, kinematics and timing of events indicate a connection between the shear systems of the Dom Feliciano and Kaoko Belts at 580–550 Ma. Sinistral transpression recorded in shear zones accommodates deformation subsequent to collision between the Congo and Río de la Plata Cratons. The correlation is strengthened by the similarity of magmatic and metamorphic ages in the Coastal Terrane of the Kaoko Belt and the Punta del Este Terrane of the Dom Feliciano Belt. This post-collisional sinistral transpression brought these units near to their final position in Gondwana and explains the different evolution at 550–530 Ma. While in the Kaoko Belt, an extensional episode resulted in exhumation as a consequence of collision in the Damara Belt, in the Dom Feliciano Belt, sinistral transpression occurred associated with the closure of the southern Adamastor Ocean due to Kalahari-Río de la Plata collision.
    Keywords: Dom Feliciano Belt; Kaoko Belt; Brasiliano; Pan-African; Transpressional deformation; Shear Zones ; 551 ; Earth Sciences; Geophysics/Geodesy; Geology
    Language: English
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    Geodynamic evolution of the Eastern Sierras Pampeanas (Central Argentina) based on geochemical, Sm–Nd, Pb–Pb and SHRIMP data (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Keywords: Eastern Sierras Pampeanas; Provenance; Tectonic setting; Gondwana margin; Geodynamic evolution ; 551 ; Earth Sciences; Geophysics/Geodesy; Geology
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    Zircon texture and chemical composition as a guide to magmatic processes and mixing in a granitic environment and coeval volcanic system (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: This study documents the chemical and textural responses of zircon in the Elba igneous complex, with particular reference to the 7- to 7.8-Ma-old Monte Capanne pluton in relation to its coeval volcanic counterpart (Capraia), using BSE imaging and quantitative electron microprobe analyses. The Monte Capanne pluton displays multiple field and geochemical evidence for magma mixing. The samples we have investigated (including monzogranitic, mafic enclave and dyke samples) display similar zircon textures and are associated with an extremely large range of trace and minor element (Hf, Y, HREE, Th, U) compositions, which contrast with relatively simple textures and zoning patterns in zircons from a Capraia dacite. We have used a relatively simple textural classification (patchy zoning, homogenous cores, oscillatory zoning and unzoned zircon) as the basis for discussing the chemical composition and chemical variation within zircons from the Monte Capanne pluton. Based on these data and other works (Dini et al. 2004 in Lithos 78:101–118, 2004) , it is inferred that mixing between metaluminous and peraluminous melts occurred early in the evolution of the Monte Capanne magma chamber. In particular, mixing was responsible for the development of the patchy-zoning texture in the zircon cores, which was associated with reactions between other accessory phases (including monazite, apatite, allanite), which we infer to have significantly affected the Th distribution in zircon. Zircons from the MC pluton displaying “homogeneous cores” have chemical affinities with zircons in the coeval Capraia volcanic system, consistent with the participation of a Capraia-like mantle end-member during mixing. Further zircon growth in the MC pluton produced the oscillatory zoning texture, which records both long-term (crystal fractionation) and transient (recharge with both silicic and mafic magmas) events in a hybrid magma chamber. It is inferred that Hf and the Th/U ratio cannot be used alone to infer magmatic processes due to their dependency on temperature, nor are they a diagnostic feature of xenocrystic grains. This study shows that zircon chemistry coupled with detailed textural analysis can provide a powerful tool to elucidate the complex evolution of a magma system.
    Keywords: Granite petrology; Zircon; Elba; Capraia; Electron microprobe; Magma mixing ; 551 ; Earth Sciences; Mineralogy ; Mineral Resources ; Geology
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    The bowing potential of granitic rocks: rock fabrics, thermal properties and residual strain (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: The bowing of natural stone panels is especially known for marble slabs. The bowing of granite is mainly known from tombstones in subtropical humid climate. Field inspections in combination with laboratory investigations with respect to the thermal expansion and the bowing potential was performed on two different granitoids (Cezlak granodiorite and Flossenbürg granite) which differ in the composition and rock fabrics. In addition, to describe and explain the effect of bowing of granitoid facade panels, neutron time-of-flight diffraction was applied to determine residual macro- and microstrain. The measurements were combined with investigations of the crystallographic preferred orientation of quartz and biotite. Both samples show a significant bowing as a function of panel thickness and destination temperature. In comparison to marbles the effect of bowing is more pronounced in granitoids at temperatures of 120°C. The bowing as well as the thermal expansion of the Cezlak sample is also anisotropic with respect to the rock fabrics. A quantitative estimate was performed based on the observed textures. The effect of the locked-in stresses may also have a control on the bowing together with the thermal stresses related to the different volume expansion of the rock-forming minerals.
    Keywords: Granitoids; Bowing; Residual strain; Texture; Thermal expansion ; 551 ; Geosciences; Geology
    Language: English
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    Nd–Sr–Hf–O isotope provinciality in the northernmost Arabian–Nubian Shield: implications for crustal evolution (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: Multi-isotope study including whole-rock Nd–Sr, single zircon Hf, and SIMS δ18O analyses of zircons sheds light on magma sources in the northernmost Arabian–Nubian Shield (ANS) during ~820–570 Ma. Reconnaissance initial Nd and Sr isotope data for the older rocks (~820–740 Ma) reaffirms previous estimates that early crustal evolution in this part of the shield involved some crustal contamination by pre-ANS material. Prominent isotope provinciality is displayed by post-collisional calc-alkaline and alkaline igneous rocks of ~635–570 Ma across a NW-SE transect across basement of the Sinai Peninsula (Egypt) and southern Israel. Silicic rocks of the NW-region are characterized by lower εNd(T)–εHf(T) and higher Sri and δ18O compared with rocks of the SE-region, and the transition between the regions is gradual. Within each region isotope ratios are independent of the extent of magma fractionation, and zircon cores and rims yield similar δ18O values. Comparison with southern segments of the ANS shows that the source for most ~635–570 Ma rocks can be modeled as the isotopically aged lower-intermediate crust in the ANS core (SE-region) and its northern, more contaminated ANS margins (NW-region). Nevertheless, Nd–Sr isotope enrichment of the lithospheric mantle is indicated by some basic magmas of the NW-region displaying the most enriched Nd–Sr isotope compositions. Comparison of Nd and Hf depleted mantle model ages for rocks of the SE-region may indicate that crustal formation events in the ANS geographical core took place at 1.1–1.2 Ga and were followed by crustal differentiation starting at ~0.9 Ga.
    Keywords: Nd–Sr–Hf–O; Arabian–Nubian Shield; Magma-sources; Zircon ; 551 ; Earth Sciences; Mineralogy ; Mineral Resources ; Geology
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    The replacement of plagioclase feldspars by albite: observations from hydrothermal experiments (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: Oligoclase and labradorite crystals have been experimentally replaced by albite in an aqueous sodium silicate solution at 600°C and 2 kbars. The replacement is pseudomorphic and is characterised by a sharp chemical interface which progresses through the feldspar while preserving the crystallographic orientation. Reaction rims of albite, up to 50 μm thick, can be readily achieved within 14 days. Re-equilibration of plagioclase in an 18O-enriched sodium- and silica-bearing solution results in oxygen isotope redistribution within the feldspar framework structure. The observed characteristics of the reaction products are similar to naturally albitised plagioclase and are indicative of an interface-coupled dissolution–reprecipitation mechanism. Chemical analyses demonstrate that the albitisation is accompanied by the mobilisation of major, minor and trace elements also including elements such as Al and Ti which are commonly regarded as immobile during hydrothermal alteration. The results contribute to developing our understanding of the close association between large-scale albitisation and secondary ore mineralisation which is common in nature.
    Keywords: Plagioclase albitisation; Fluid–mineral interaction; Interface-coupled dissolution–reprecipitation; Hydrothermal experiments; Element mobility ; 551 ; Earth Sciences; Mineralogy ; Mineral Resources ; Geology
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    The tectonic significance of K/Ar illite fine-fraction ages from the San Luis Formation (Eastern Sierras Pampeanas, Argentina) (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: The Sierra de San Luis forms the southern tip of the Eastern Sierras Pampeanas in central Argentina. Two narrow belts of low-grade phyllites and quartz arenites, i.e. the San Luis Formation, have accommodated part of the strain-related differential exhumation of the medium- to high-grade metamorphic domains that constitute to the basement complex of the sierra. Eleven phyllite samples were subjected to the K/Ar fine-fraction dating technique. Results are interpreted in relation to the Kübler index of the illites, which indicate epimetamorphic conditions for the majority of the samples. Obtained ages between 330 and 290 Ma cover a period of compressional tectonics in the late Mississippian (Visean/Serpukhovian boundary) followed by the subsidence during the formation of the Paganzo Basin in the provinces of La Rioja and San Luis. These tectonic movements are coincident with the Toco orogeny in northern Chile and southern Bolivia. This suggests that the older K/Ar ages document the compressional stage and that younger ages record the cooling of the basement during the subsequent extensional uplift of the basement.
    Keywords: Eastern Sierras Pampeanas; San Luis Formation; Paganzo Basin; K/Ar; Illite fine fractions ; 551 ; Earth Sciences; Geophysics/Geodesy; Geology
    Language: English
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    The Río de la Plata Craton: a review of units, boundaries, ages and isotopic signature (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: A review of the lithostratigraphic units in the Río de la Plata Craton and of new and previously published geochronological, isotopic and geophysical data is presented. Sm–Nd TDM model ages between 2.6 and 2.2 Ga characterize the Piedra Alta Terrane of this craton. Crystallization ages between 2.2 and 2.1 Ga for the metamorphic protoliths and 2.1–2.0 Ga for the post-orogenic granitoids indicate juvenile crust, followed by a short period of crustal recycling. Cratonization of this terrane occurred during the late Paleoproterozoic. Younger overprinting is not observed, suggesting it had a thick and strong lithosphere in the Neoproterozoic. A similar scenario is indicated for the Tandilia Belt of Argentina. Sm–Nd TDM model ages for the Nico Pérez Terrane show two main events of crustal growth (3.0–2.6 and 2.3–1.6 Ga). The crystallization ages on zircon ranges between 3.1 and 0.57 Ga, which is evidence for long-lived crustal reworking. The age for cratonization is still uncertain. In the Taquarembó Block, which is considered the prolongation of the Nico Pérez Terrane in southern Brazil, a similar scenario can be observed. These differences together with contrasting geophysical signatures support the redefinition of the Río de la Plata Craton comprising only the Piedra Alta Terrane and the Tandilia Belt. The Sarandí del Yí Shear Zone is regarded as the eastern margin of this Craton.
    Keywords: Precambrian; Transamazonian cycle; South American platform; Río de la Plata Craton ; 551 ; Earth Sciences; Geophysics/Geodesy; Geology
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    Micro-framework reconstruction from peloidal-dominated mud mounds (Viséan, SW Spain) (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Keywords: Mud mound; Peloids; Automicrites; Micro-framework; Carboniferous; Spain ; 551 ; Earth Sciences; Ecology; Paleontology; Geochemistry ; Biogeosciences; Sedimentology
    Language: English
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    Magma chamber evolution prior to the Campanian Ignimbrite and Neapolitan Yellow Tuff eruptions (Campi Flegrei, Italy) (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Keywords: Campi Flegrei; Phlegraean fields; Campanian Ignimbrite; Neapolitan Yellow Tuff; Geochemistry; Sr and Nd isotopes; Magma batches; Precursor activity ; 551 ; Geosciences; Sedimentology ; Mineralogy ; Geophysics/Geodesy ; Geology
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    Petrology, magnetostratigraphy and geochronology of the Miocene volcaniclastic Tepoztlán Formation: implications for the initiation of the Transmexican Volcanic Belt (Central Mexico) (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: The volcaniclastic Tepoztlán Formation (TF) represents an important rock record to unravel the early evolution of the Transmexican Volcanic Belt (TMVB). Here, a depositional model together with a chronostratigraphy of this Formation is presented, based on detailed field observations together with new geochronological, paleomagnetic, and petrological data. The TF consists predominantly of deposits from pyroclastic density currents and extensive epiclastic products such as tuffaceous sandstones, conglomerates and breccias, originating from fluvial and mass flow processes, respectively. Within these sediments fall deposits and lavas are sparsely intercalated. The clastic material is almost exclusively of volcanic origin, ranging in composition from andesite to rhyolite. Thick gravity-driven deposits and large-scale alluvial fan environments document the buildup of steep volcanic edifices. K-Ar and Ar-Ar dates, in addition to eight magnetostratigraphic sections and lithological correlations served to construct a chronostratigraphy for the entire Tepoztlán Formation. Correlation of the 577 m composite magnetostratigraphic section with the Cande and Kent (1995) Geomagnetic Polarity Time Scale (GPTS) suggests that this section represents the time intervall 22.8–18.8 Ma (6Bn.1n-5Er; Aquitanian-Burdigalian, Lower Miocene). This correlation implies a deposition of the TF predating the extensive effusive activity in the TMVB at 12 Ma and is therefore interpreted to represent its initial phase with predominantly explosive activity. Additionally, three subdivisions of the TF were established, according to the dominant mode of deposition: (1) the fluvial dominated Malinalco Member (22.8–22.2 Ma), (2) the volcanic dominated San Andrés Member (22.2–21.3 Ma) and (3) the mass flow dominated Tepozteco Member (21.3–18.8 Ma).
    Keywords: Magnetostratigraphy; K-Ar Geochronology; Volcaniclastics; Miocene; Tepoztlán Formation; Transmexican Volcanic Belt; Central Mexico ; 551 ; Earth Sciences; Sedimentology; Mineralogy; Geophysics/Geodesy; Geology
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    The Sierra Ballena Shear Zone in the southernmost Dom Feliciano Belt (Uruguay): evolution, kinematics, and deformation conditions (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: The Sierra Ballena Shear Zone (SBSZ) is part of a high-strain transcurrent system that divides the Neoproterozoic Dom Feliciano Belt of South America into two different domains. The basement on both sides of the SBSZ shows a deformation stage preceding that of the transcurrent deformation recognized as a high temperature mylonitic foliation associated with migmatization. Grain boundary migration and fluid-assisted grain boundary diffusion enhanced by partial melting were the main deformation mechanisms associated with this foliation. Age estimate of this episode is 〉658 Ma. The second stage corresponds to the start of transpressional deformation and the nucleation and development of the SBSZ. During this stage, pure shear dominates the deformation, and is characterized by the development of conjugate dextral and sinistral shear zones and the emplacement of syntectonic granites. This event dates to 658–600 Ma based on the age of these intrusions. The third stage was a second transpressional event at about 586 to 〈560 Ma that was associated with the emplacement of porphyry dikes and granites that show evidence of flattening. Deformation in the SBSZ took place, during the late stages, under regional low-grade conditions, as indicated by the metamorphic paragenesis in the supracrustals of the country rocks. Granitic mylonites show plastic deformation of quartz and brittle behavior of feldspar. A transition from magmatic to solid-state microstructures is also frequently observed in syntectonic granites. Mylonitic porphyries and quartz mylonites resulted from the deformation of alkaline porphyries and quartz veins emplaced in the shear zone. Quartz veins reflect the release of silica associated with the breakdown of feldspar to white mica during the evolution of the granitic mylonites to phyllonites, which resulted in shear zone weakening. Quartz microstructures characteristic of the transition between regime 2 and regime 3, grain boundary migration and incipient recrystallization in feldspar indicate deformation under lower amphibolite to upper greenschist conditions (550–400°C). On the other hand, the mylonitic porphyries display evidence of feldspar recrystallization suggesting magmatic or high-T solid-state deformation during cooling of the dikes.
    Keywords: Brasiliano; Pan-African; Shear zone; Dom Feliciano Belt; Uruguay; Kinematic analysis ; 551 ; Earth Sciences; Geology ; Geophysics/Geodesy
    Language: English
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    Age constraints on faulting and fault reactivation: a multi-chronological approach (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: Movement within the Earth’s upper crust is commonly accommodated by faults or shear zones, ranging in scale from micro-displacements to regional tectonic lineaments. Since faults are active on different time scales and can be repeatedly reactivated, their displacement chronology is difficult to reconstruct. This study represents a multi-geochronological approach to unravel the evolution of an intracontinental fault zone locality along the Danube Fault, central Europe. At the investigated fault locality, ancient motion has produced a cataclastic deformation zone in which the cataclastic material was subjected to hydrothermal alteration and K-feldspar was almost completely replaced by illite and other phyllosilicates. Five different geochronological techniques (zircon Pb-evaporation, K–Ar and Rb–Sr illite, apatite fission track and fluorite (U-Th)/He) have been applied to explore the temporal fault activity. The upper time limit for initiation of faulting is constrained by the crystallization age of the primary rock type (known as “Kristallgranit”) at 325 ± 7 Ma, whereas the K–Ar and Rb–Sr ages of two illite fractions 〈2 μm (266–255 Ma) are interpreted to date fluid infiltration events during the final stage of the cataclastic deformation period. During this time, the “Kristallgranit” was already at or near the Earth’s surface as indicated by the sedimentary record and thermal modelling results of apatite fission track data. (U–Th)/He thermochronology of two single fluorite grains from a fluorite–quartz vein within the fault zone yield Cretaceous ages that clearly postdate their Late-Variscan mineralization age. We propose that later reactivation of the fault caused loss of helium in the fluorites. This assertion is supported by geological evidence, i.e. offsets of Jurassic and Cretaceous sediments along the fault and apatite fission track thermal modelling results are consistent with the prevalence of elevated temperatures (50–80°C) in the fault zone during the Cretaceous.
    Keywords: Argillic alteration; Fault zone; K–Ar illite; Apatite fission track; (U–Th)/He thermochronology ; 551 ; Earth Sciences; Geology ; Geophysics/Geodesy
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    Community forestry management and livelihood development in northwest China: integration of governance, project design, and community participation (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Keywords: Community-based co-management; Community forestry; Livelihood; Governance; Policy; Mechanism; Participation ; 551 ; Environment; Climate Change; Geology; Oceanography; Geography (general); Regional/Spatial Science; Nature Conservation
    Language: English
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    Time constraints on the tectonic evolution of the Eastern Sierras Pampeanas (Central Argentina) (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: The application of the SHRIMP U/Pb dating technique to zircon and monazite of different rock types of the Sierras de Córdoba provides an important insight into the metamorphic history of the basement domains. Additional constraints on the Pampean metamorphic episode were gained by Pb/Pb stepwise leaching (PbSL) experiments on two titanite and garnet separates. Results indicate that the metamorphic history recorded by Crd-free gneisses (M2) started in the latest Neoproterozoic/earliest Cambrian (553 and 543 Ma) followed by the M4 metamorphism at ~530 Ma that is documented in the diatexites. Zircon ages of 492 Ma in the San Carlos Massif correlate partly with rather low Th/U ratios (〈0.1) suggesting their growth by metamorphic fluids. This age is even younger than the PbSL titanite ages of 506 Ma. It is suggested that the fluid alteration relates to the beginning of the Famatinien metamorphic cycle in the neighbouring Sierra de San Luis and has not affected the titanite ages. The PTt evolution can be correlated with the plate tectonic processes responsible for the formation of the Pampean orogene, i.e., the accretion of the Pampean basement to the Río de La Plata craton (M2) and the later collision of the Western Pampean basement with the Pampean basement.
    Keywords: Eastern Sierras Pampeanas; Sierras de Córdoba; Pampean and Famatinian cycles; Geodynamic evolution; SHRIMP dating; Titanite and Garnet Pb–Pb step-wise leaching ; 551 ; Earth Sciences; Geology ; Geophysics/Geodesy
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    Indicator Kriging without Order Relation Violations (2018)
    Springer-Verlag | Springer-Verlag
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    Publication Date: 2021-03-29
    Description: Indicator kriging (IK) is a spatial interpolation technique aimed at estimating the conditional cumulative distribution function (ccdf) of a variable at an unsampled location. Obtained results form a discrete approximation to this ccdf, and its corresponding discrete probability density function (cpdf) should be a vector, where each component gives the probability of an occurrence of a class. Therefore, this vector must have positive components summing up to one, like in a composition in the simplex. This suggests a simplicial approach to IK, based on the algebraic-geometric structure of this sample space: simplicial IK actually works with log-odds. Interpolated log-odds can afterwards be easily re-expressed as the desired cpdf or ccdf. An alternative but equivalent approach may also be based on log-likelihoods. Both versions of the method avoid by construction all conventional IK standard drawbacks: estimates are always within the (0,1) interval and present no order-relation problems (either with kriging or co-kriging). Even the modeling of indicator structural functions is clarified.
    Keywords: Aitchison geometry; Ilr coordinates; Indicator variogram; Logistic regression ; 551 ; Geosciences; Hydrogeology ; Geotechnical Engineering; Statistics for Engineering, Physics, Computer Science, Chemistry & Geosciences; Math. Applications in Geosciences
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    Continuum-mechanical, Anisotropic Flow model for polar ice masses, based on an anisotropic Flow Enhancement factor (2018)
    Springer-Verlag | Springer-Verlag
    Details
    Publication Date: 2021-03-29
    Description: A complete theoretical presentation of the Continuum-mechanical, Anisotropic Flow model, based on an anisotropic Flow Enhancement factor (CAFFE model) is given. The CAFFE model is an application of the theory of mixtures with continuous diversity for the case of large polar ice masses in which induced anisotropy occurs. The anisotropic response of the polycrystalline ice is described by a generalization of Glen’s flow law, based on a scalar anisotropic enhancement factor. The enhancement factor depends on the orientation mass density, which is closely related to the orientation distribution function and describes the distribution of grain orientations (fabric). Fabric evolution is governed by the orientation mass balance, which depends on four distinct effects, interpreted as local rigid body rotation, grain rotation, rotation recrystallization (polygonization) and grain boundary migration (migration recrystallization), respectively. It is proven that the flow law of the CAFFE model is truly anisotropic despite the collinearity between the stress deviator and stretching tensors.
    Keywords: Continuum mechanics; Anisotropy; Ice; Mixtures; Recrystallization ; 551 ; Physics; Theoretical and Applied Mechanics; Structural Materials; Engineering Thermodynamics, Heat and Mass Transfer; Classical Continuum Physics
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    Mafic Late Miocene–Quaternary volcanic rocks in the Kamchatka back arc region: implications for subduction geometry and slab history at the Pacific–Aleutian junction (2018)
    Springer-Verlag | Springer-Verlag
    Details
    Publication Date: 2021-03-29
    Description: New 40Ar/39Ar and published 14C ages constrain voluminous mafic volcanism of the Kamchatka back-arc to Miocene (3–6 Ma) and Late Pleistocene to Holocene (〈1 Ma) times. Trace elements and isotopic compositions show that older rocks derived from a depleted mantle through subduction fluid-flux melting (〉20%). Younger rocks form in a back arc by lower melting degrees involving enriched mantle components. The arc front and Central Kamchatka Depression are also underlain by plateau lavas and shield volcanoes of Late Pleistocene age. The focus of these voluminous eruptions thus migrated in time and may be the result of a high fluid flux in a setting where the Emperor seamount subducts and the slab steepens during rollback during terrain accretions. The northern termination of Holocene volcanism locates the edge of the subducting Pacific plate below Kamchatka, a “slab-edge-effect” is not observed in the back arc region.
    Keywords: Kamchatka; Back-arc; Plateau-basalts; Subduction; Trace elements; Isotopes ; 551 ; Earth Sciences; Mineralogy ; Mineral Resources ; Geology
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    The oldest synallactid sea cucumber (Echinodermata: Holothuroidea: Aspidochirotida) (2018)
    Springer-Verlag | Berlin/Heidelberg
    Details
    Publication Date: 2021-04-25
    Description: Aspidochirote holothurian ossicles were discovered in Upper Ordovician-aged Öjlemyr cherts from Gotland, Sweden. The well-preserved material allows definitive assignment to the family Synallactidae, a deep-sea sea cucumber group that is distributed worldwide today. The new taxon Tribrachiodemas ordovicicus gen. et sp. nov. is described, representing the oldest member of the Aspidochirotida. The further fossil record of Synallactidae and evolutionary implications are also discussed.
    Keywords: Echinodermata; Holothuroidea; Ordovician; Sweden; Baltic Sea; Echinodermata; Holothuroidea; Ordovizium; Schweden; Ostsee ; 551 ; Earth Sciences; Paleontology
    Language: English
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    Shear modulus, heat capacity, viscosity and structural relaxation time of Na2O–Al2O3–SiO2 and Na2O–Fe2O3–Al2O3–SiO2 melts (2018)
    Springer-Verlag | Berlin/Heidelberg
    Details
    Publication Date: 2021-03-29
    Description: The configurational heat capacity, shear modulus and shear viscosity of a series of Na2O–Fe2O3–Al2O3–SiO2 melts have been determined as a function of composition. A change in composition dependence of each of the physical properties is observed as Na2O/(Na2O + Al2O3) is decreased, and the peralkaline melts become peraluminous and a new charge-balanced Al-structure appears in the melts. Of special interest are the frequency dependent (1 mHz–1 Hz) measurements of the shear modulus. These forced oscillation measurements determine the lifetimes of Si–O bonds and Na–O bonds in the melt. The lifetime of the Al–O bonds could not, however, be resolved from the mechanical spectrum. Therefore, it appears that the lifetime of Al–O bonds in these melts is similar to that of Si–O bonds with the Al–O relaxation peak being subsumed by the Si–O relaxation peak. The appearance of a new Al-structure in the peraluminous melts also cannot be resolved from the mechanical spectra, although a change in elastic shear modulus is determined as a function of composition. The structural shear-relaxation time of some of these melts is not that which is predicted by the Maxwell equation, but up to 1.5 orders of magnitude faster. Although the configurational heat capacity, density and shear modulus of the melts show a change in trend as a function of composition at the boundary between peralkaline and peraluminous, the deviation in relaxation time from the Maxwell equation occurs in the peralkaline regime. The measured relaxation times for both the very peralkaline melts and the peraluminous melts are identical with the calculated Maxwell relaxation time. As the Maxwell equation was created to describe the timescale of flow of a mono-structure material, a deviation from the prediction would indicate that the structure of the melt is too complex to be described by this simple flow equation. One possibility is that Al-rich channels form and then disappear with decreasing Si/Al, and that the flow is dominated by the lifetime of Si–O bonds in the Al-poor peralkaline melts, and by the lifetime of Al–O bonds in the relatively Si-poor peralkaline and peraluminous melts with a complex flow mechanism occurring in the mid-compositions. This anomalous deviation from the calculated relaxation time appears to be independent of the change in structure expected to occur at the peralkaline/peraluminous boundary due to the lack of charge-balancing cations for the Al-tetrahedra.
    Keywords: Frequency dependent; Shear modulus; Heat capacity; Silicate melts; Relaxation time ; 551 ; Earth Sciences; Mineral Resources ; Geochemistry ; Mineralogy ; Crystallography
    Language: English
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    Grain-Size Control on Petrographic Composition of Sediments: Compositional Regression and Rounded Zeros (2018)
    Springer-Verlag | Springer-Verlag
    Details
    Publication Date: 2021-03-29
    Description: It is well-known that sediment composition strongly depends on grain size. A number of studies have tried to quantify this relationship focusing on the sand fraction, but only very limited data exists covering wider grain size ranges. Geologists have a clear conceptual model of the relation between grain size and sediment petrograpic composition, typically displayed in evolution diagrams. We chose a classical model covering grain sizes from fine gravel to clay, and distinguishing five types of grains (rock fragments, poly- and mono crystalline quartz, feldspar and mica/clay). A compositional linear process is fitted here to a digitized version of this model, by (i) applying classical regression to the set of all pairwise log-ratios of the 5-part composition against grain size, and (ii) looking for the compositions that best approximate the set of estimated parameters, one acting as slope and one as intercept. The method is useful even in the presence of several missing values. The linear fit suggests that the relative influence of the processes controlling the relationship between grain size and sediment composition is constant along most of the grain size spectrum.
    Keywords: Censored data; Compositional Data Analysis; Moore–Penrose generalized inverse; Sedimentary petrography ; 551 ; Earth Sciences; Hydrogeology ; Geotechnical Engineering; Statistics for Engineering, Physics, Computer Science, Chemistry and Earth Sciences; Mathematical Applications in Earth Sciences
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    Prioritizing reaches for restoration in a regulated Alpine river: Locally driven versus hydro‐morphologically based actions (2021)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2021-06-27
    Description: We discuss the prioritization of river reaches to be selected for restoration measures under the constraints of financial resource limitation. We propose and apply a simple approach based on the quantification of major hydro‐morphological alterations and the critical comparison with locally proposed restoration actions. The available hydro‐morphological and ecological data for the approach do not go beyond the requirements posed by the implementation of the EU Water Framework and Floods Directives. We describe an example that refers to a heavily regulated Alpine river (Sarca River, NE Italy). The results indicate hydropower facilities as a key source of hydrological alteration, with sediment retention and grade control structures on lateral tributaries playing an additional relevant role in reducing sediment supply. The frequency and duration of sediment‐transporting floods have dramatically decreased, and the bed sediment composition has been markedly altered and become highly compacted. Habitat improvement has been achieved after the implementation of minimum environmental flows. The comparison between the results of the hydro‐morphological indicators and the locally proposed restoration actions highlights that reaches with lower degree of hydro‐morphological alterations do not coincide with the areas chosen for the locally planned actions, which often miss considerations of the relevant spatial scales. In a context of limited available financial resources and data compared to other flagship river restoration projects in the European Alps, the present work suggests viable options for the choice of target restoration reaches.
    Description: Consorzio dei Comuni BIM Sarca
    Description: Italian Ministry of Education, University and Research (MIUR)
    Description: Rete di Riserve della Sarca
    Keywords: 333.91 ; ecological flows ; hydropower ; regulated rivers ; sediment transport
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    Extreme precipitation events over northern Italy. Part II: Dynamical precursors (2021)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2021-07-20
    Description: The connection between weather extremes and Rossby wave packets (RWP) has been increasingly documented in recent years. RWP propagation and characteristics can modulate the midlatitude weather, setting the scene for temperature and precipitation extremes and controlling the geographical area affected. Several studies on extreme precipitation events (EPEs) in the Alpine area reported, as the main triggering factor, a meridionally elongated upper‐level trough as part of an incoming Rossby wave packet. In this work, we investigate a wide number of EPEs occurring between 1979 and 2015 in northern‐central Italy. The EPEs are subdivided into three categories (Cat1, Cat2, Cat3) according to thermodynamic conditions over the affected region. It is found that the three categories differ not only in terms of the local meteorological conditions, but also in terms of the evolution and properties of precursor RWPs. These differences cannot be solely explained by the apparent seasonality of the flow; therefore, the relevant physical processes in the RWP propagation of each case are further investigated. In particular, we show that RWPs associated with the strongest EPEs, namely the ones falling in Cat2, undergo a substantial amplification over the western North Atlantic due to anomalous ridge‐building 2 days before the event; arguably due to diabatic heating sources. This type of development induces a downstream trough which is highly effective in focusing water vapour transport toward the main orographic barriers of northern‐central Italy and favouring the occurrence of EPEs.
    Description: The EPEs are subdivided into three categories (Cat1, Cat2, Cat3) according to thermodynamic conditions over the affected region. The three categories not only differ locally but also in the evolution of precursor RWPs as visible in the composite Hovmöller plots. RWPs associated with the strongest EPEs, the ones falling in Cat2, undergo a substantial amplification over the west North Atlantic due to anomalous ridge‐building 2 days before the event. This type of development induces a downstream trough which is highly effective in focusing water vapour transport toward the Apennines and the Alps.
    Description: Ludwig‐Maximilians‐Universität München http://dx.doi.org/10.13039/501100005722
    Description: German Research Foundation (DFG)
    Description: Transregional Collaborative Research Centre
    Keywords: 551.6 ; atmospheric rivers ; extreme precipitation ; integrated water vapour transport ; large‐scale forcing ; potential vorticity ; Rossby wave packets
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    WRF‐based dynamical downscaling of ERA5 reanalysis data for High Mountain Asia: Towards a new version of the High Asia Refined analysis (2021)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2021-07-03
    Description: The High Asia Refined analysis (HAR) is a regional atmospheric data set generated by dynamical downscaling of the Final operational global analysis (FNL) using the Weather Research and Forecasting (WRF) model. It has been successfully and widely utilized. A new version (HAR v2) with longer temporal coverage and extended domains is currently under development. ERA5 reanalysis data is used as forcing data. This study aims to find the optimal set‐up for the production of the HAR v2 to provide similar or even better accuracy as the HAR. First, we conducted a sensitivity study, in which different cumulus, microphysics, planetary boundary layer, and land surface model schemes were compared and validated against in situ observations. The technique for order preference by similarity to the ideal solution (TOPSIS) method was applied to identify the best schemes. Snow depth in ERA5 is overestimated in High Mountain Asia (HMA) and causes a cold bias in the WRF output. Therefore, we used Japanese 55‐year Reanalysis (JRA‐55) to correct snow depth initialized from ERA5 based on the linear scaling approach. After applying the best schemes identified by the TOPSIS method and correcting the initial snow depth, the model performance improves. Finally, we applied the improved set‐up for the HAR v2 and computed a one‐year run for 2011. Compared to the HAR, the HAR v2 has a better representation of air temperature at 2 m. It produces slightly higher precipitation amounts, but the spatial distribution of seasonal mean precipitation is closer to observations.
    Description: German Federal Ministry of Education and Research (BMBF) http://dx.doi.org/10.13039/501100002347
    Keywords: 551.5 ; cold bias ; dynamical downscaling ; ERA5 ; HAR ; High Mountain Asia ; snow depth ; WRF
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    Hydro Explorer: An interactive web app to investigate changes in runoff timing and runoff seasonality all over the world (2021)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2021-06-27
    Description: Climatic changes and anthropogenic modifications of the river basin or river network have the potential to fundamentally alter river runoff. In the framework of this study, we aim to analyze and present historic changes in runoff timing and runoff seasonality observed at river gauges all over the world. In this regard, we develop the Hydro Explorer, an interactive web app, which enables the investigation of 〉7,000 daily resolution discharge time series from the Global Runoff Data Centre (GRDC). The interactive nature of the developed web app allows for a quick comparison of gauges, regions, methods, and time frames. We illustrate the available analytical tools by investigating changes in runoff timing and runoff seasonality in the Rhine River Basin. Since we provide the source code of the application, existing analytical approaches can be modified, new methods added, and the tool framework can be re‐used to visualize other data sets.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: WOA Institution: UNIVERSITAET POTSDAM Blended DEAL: ProjektDEAL
    Keywords: 551.488 ; global runoff database ; interactive web app ; R Shiny ; runoff seasonality ; runoff timing
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    The behaviour of consolidated volcanic tuffs: weathering mechanisms under simulated laboratory conditions (2018)
    Springer
    Details
    Publication Date: 2021-03-29
    Description: Five volcanic tuffs ranging from dacitic tuffs of Hungary to rhyolite, phonolite and basaltic tuffs of Germany were consolidated under laboratory conditions. Prior to consolidation an anti-hygro, a hydrous consolidant, which reduces the swelling ability of clay minerals, was applied. The three consolidants, a silicic acid ester (SAE), an elastic silicic acid ester (eSAE) and an acrylate resin (PMMA) were applied on test specimens under vacuum. Petrographic characterisation (polarizing microscopy, XRD, SEM) provided data for fabric analyses and the mineral composition of the tuffs. Changes in fabric, effective porosity, density, tensile strength, ultrasonic wave velocity were evaluated after the treatment. Weathering simulation tests such as hygric dilatation and thermal dilatation aimed to prove the effectiveness of consolidation and the durability of consolidated tuff samples. More than 500 samples were analysed. The tests showed that SAE caused the highest increase in indirect tensile strength. The water absorption and the pore size distribution of the tuffs were modified by consolidation. The PMMA reduced the water absorption the most, whereas SAE modified it the least. All the tested consolidants increased the thermal dilatation of the tuffs. The changes in hygric dilatation were not uniform: for most tuffs SAE increased and PMMA decreased the hygric dilatation, although the clay-rich Habichtswald tuff showed the opposite trend. The changes in hygric and thermal behaviour of consolidated tuff require special care when specific consolidants are chosen. These products modify the physical properties of consolidated tuffs and change the behaviour of weathering.
    Keywords: Strengthening agents; Tuff; Silicic acid ester; PMMA; Durability ; 551
    Language: English
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    Geochemical, isotopic and single crystal 40Ar/39Ar age constraints on the evolution of the Cerro Galán ignimbrites (2018)
    Springer-Verlag | Berlin/Heidelberg
    Details
    Publication Date: 2021-03-29
    Description: The giant ignimbrites that erupted from the Cerro Galán caldera complex in the southern Puna of the high Andean plateau are considered to be linked to crustal and mantle melting as a consequence of delamination of gravitationally unstable thickened crust and mantle lithosphere over a steepening subduction zone. Major and trace element analyses of Cerro Galán ignimbrites (68–71% SiO2) that include 75 new analyses can be interpreted as reflecting evolution at three crustal levels. AFC modeling and new fractionation corrected δ18O values from quartz (+7.63–8.85‰) are consistent with the ignimbrite magmas being near 50:50 mixtures of enriched mantle (87Sr/86Sr ~ 0.7055) and crustal melts (87Sr/86Sr near 0.715–0.735). Processes at lower crustal levels are predicated on steep heavy REE patterns (Sm/Yb = 4–7), high Sr contents (〉250 ppm) and very low Nb/Ta (9-5) ratios, which are attributed to amphibolite partial melts mixing with fractionating mantle basalts to produce hybrid melts that rise leaving a gravitationally unstable garnet-bearing residue. Processes at mid crustal levels create large negative Eu anomalies (Eu/Eu* = 0.45–0.70) and variable trace element enrichment in a crystallizing mush zone with a temperature near 800–850°C. The mush zone is repeatedly recharged from depth and partially evacuated into upper crustal magma chambers at times of regional contraction. Crystallinity differences in the ignimbrites are attributed to biotite, zoned plagioclase and other antecrysts entering higher level chambers where variable amounts of near-eutectic crystallization occurs at temperatures as low as 680°C just preceding eruption. 40Ar/39Ar single crystal sanidine weighted mean plateau and isochron ages combined with trace element patterns show that the Galán ignimbrite erupted in more than one batch including a ~ 2.13 Ma intracaldera flow and outflows to the west and north at near 2.09 and 2.06 Ma. Episodic delamination of gravitationally unstable lower crust and mantle lithosphere and injection of basaltic magmas, whose changing chemistry reflects their evolution over a steepening subduction zone, could trigger the eruptions of the Cerro Galán ignimbrites.
    Keywords: Cerro Galán; Puna ignimbrite chemistry; 40Ar/39Ar ages; Delamination; Plateau evolution ; 551 ; Earth Sciences; Sedimentology; Geophysics/Geodesy; Mineralogy; Geology
    Language: English
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    Weathering behaviour and construction suitability of dimension stones from the Drei Gleichen area (Thuringia, Germany) (2018)
    Springer-Verlag | Berlin/Heidelberg
    Details
    Publication Date: 2021-03-29
    Description: The construction suitability of a dimension stone depends on its weathering properties along with the petrology and the petrophysical properties. The aim of this study was to evaluate the suitability of the dimension stones from the “Drei Gleichen” area for construction and replacement purposes. In total, six sandstones (Ingersleben, Wachsenburg, Hindfelden, Seeberg, Röhnberg, Gleichenberg; Upper Triassic) as well as two carbonates (Wachsenburg sinter; Quaternary, Wandersleben dolomite; Middle Triassic) were analysed. The results from our laboratory and on-site studies of the dimension stones show that rocks from the same stratigraphic layer, like the sandstones from the upper Triassic, can show major differences in their petrophysical and weathering properties. These differences are attributed to their different diagenesis, resulting, e.g. in varying pore space, water balance and strength properties. The pore size distribution can be divided into four different groups based on their occurring maxima and micropore content. The determined water balance properties as well as moisture expansion and salt attack depend on these groups. Next to this, the mineralogical composition significantly influences the weathering resistance. Sandstones with a high content of altered lithoclasts show a high amount of moisture expansion, low strength and, in consequence, a low weathering resistance against salt attack. Based on the results of the present study, an evaluation of construction suitability could be accomplished. From the analysed sandstones, only the Seebergen sandstone is suitable for construction purposes due to its good availability, good strength properties (high compressive and tensile strength, low softening degree) as well as a low porosity. Furthermore, the Wachsenburg sandstone also shows good petrophysical and petrological properties, but exploitable deposits are too sparse to be of commercial interest. From the carbonates, the Wachsenburg sinter shows very suitable rock parameters, but only sparse outcrops occur, which are not appropriate for mining.
    Keywords: Dimension stones; Sandstones; Carbonates; Weathering ; 551 ; Earth Sciences; Geology
    Language: English
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    Monuments under threat: environmental impact, preservation strategies and natural stone recourses (2018)
    Springer-Verlag | Berlin/Heidelberg
    Details
    Publication Date: 2021-03-29
    Keywords: 551 ; Earth Sciences; Geology
    Language: English
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    Natural building stones of Mexico–Tenochtitlán: their use, weathering and rock properties at the Templo Mayor, Palace Heras Soto and the Metropolitan Cathedral (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: In the Aztec period and in colonial times different natural stones originating in the Valley of Mexico were used for building construction. Stone weathering was investigated onsite at various historical buildings within the old quarter of Mexico City. In this study, different aspects of weathering and deterioration at three significant historical buildings will be presented, the Aztec excavation site Templo Mayor, the Metropolitan Cathedral, and the colonial palace of the dukes of Heras Soto. Petrophysical properties of the main building stones of these structures were investigated like density, porosity, pore radii distribution, water uptake rate and coefficient, thermal and hygric expansion, and the mechanical properties of uniaxial compressive strength. A relationship between single critical property values, according to anisotropy fabric characteristics, and specific weathering forms could be deduced.
    Keywords: Stone weathering; Mexico-DF; Petrophysical properties; Isotropy–anisotropy; Critical values ; 551 ; Earth Sciences; Geology
    Language: English
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    Seasonal variability of Holocene climate: a palaeolimnological study on varved sediments in Lake Jues (Harz Mountains, Germany) (2018)
    Springer | Springer
    Details
    Publication Date: 2021-03-29
    Keywords: Albrecht-von-Haller-Institut für Pflanzenwissenschaften / Abteilung für Palynologie und Klimadynamik ; Palaeolimnology; Holocene climate; Diatoms; Green algae; Pollen; Karst ; 551
    Language: English
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    Characterizing uranium solubilization under natural near oxic conditions (2018)
    Springer | Berlin/Heidelberg
    Details
    Publication Date: 2021-03-29
    Description: A 782 d solubilization study using not shaken batch experiments and involving one uranium-bearing rock and three natural carbonate minerals was conducted to characterize uranium (U) leaching under oxic conditions. Results showed that aqueous U concentration increased continuously with a solubilization rate of 0.16 mgm-2h-1 for the first 564 d (1.5 y). After 1.5 y, U concentration reached a maximum value (saturation) and decreased afterwards. The saturation concentration of 54 mgL-1 (mean value) was influenced to various extent by the presence of carbonate minerals. Dissolution/precipitation, adsorption or ion exchange processes appear to control U solubilization.
    Keywords: 551
    Language: English
    Type: anthologyArticle , acceptedVersion
    Format: 425-435
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    Phylogenetic aspects and new descriptions of Spicule-Bearing, Hadromerid Sponges with a secondary calcareous skeleton (Tetractinomorpha, Demospongiae) (2018)
    Springer | Berlin [u.a.]
    Details
    Publication Date: 2021-04-25
    Keywords: 551 ; VU 000 ; 38.20
    Language: English
    Type: anthologyArticle , publishedVersion
    Format: 179-211
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    Late-stage volcano geomorphic evolution of the Pleistocene San Francisco Mountain, Arizona (USA), based on high-resolution DEM analysis and 40Ar/39Ar chronology (2018)
    Springer-Verlag
    Details
    Publication Date: 2021-03-29
    Description: The cone-building volcanic activity and subsequent erosion of San Francisco Mountain, AZ, USA, were studied by using high-resolution digital elevation model (DEM) analysis and new 40Ar/39Ar dating. By defining remnants or planèzes of the volcano flanks in DEM-derived images, the original edifice can be reconstructed. We propose a two-cone model with adjacent summit vents which were active in different times. The reconstructed cones were 4,460 and 4,350 m high a.s.l., corresponding to ∼2,160 and 2,050 m relative height, respectively. New 40Ar/39Ar data allow us to decipher the chronological details of the cone-building activity. We dated the Older and Younger Andesites of the volcano that, according to previous mapping, built the stage 2 and stage 3 stratocones, respectively. The new 40Ar/39Ar plateau ages yielded 589–556 ka for the Older and 514–505 ka for the Younger Andesites, supporting their distinct nature with a possible dormant period between. The obtained ages imply an intense final (≤100 ka long) cone-building activity, terminating ∼100 ka earlier than indicated by previous K-Ar ages. Moreover, 40Ar/39Ar dating constrains the formation of the Inner Basin, an elliptical depression in the center of the volcano initially created by flank collapse. A 530 ka age (with a ±58.4 ka 2σ error) for a post-depression dacite suggests that the collapse event is geochronologically indistinguishable from the termination of the andesitic cone-building activity. According to our DEM analysis, the original cone of San Francisco Mountain had a volume of about 80 km3. Of this volume, ∼7.5 km3 was removed by the flank collapse and subsequent glacial erosion, creating the present-day enlarged Inner Basin, and ∼2 km3 was removed from the outer valleys by erosion. Based on volumetric analysis and previous and new radiometric ages, the average long-term eruption rate of San Francisco Mountain was ∼0.2 km3/ka, which is a medium rate for long-lived stratovolcanoes. However, according to the new 40Ar/39Ar dates for the last ≤100 ka period, the final stratovolcanic activity was characterized by a greater ∼0.3 km3/ka rate.
    Keywords: San Francisco Mountain; DEM analysis; Volcanic geomorphology; 40Ar/39Ar geochronology; Stratovolcanic activity; Erosion; Colorado Plateau ; 551 ; Earth Sciences; Sedimentology; Mineralogy ; Geophysics/Geodesy ; Geology
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    Integrale Quantifizierung von Schadstoffmassenflüssen im Grundwasser – Konditionierung der numerischen Inversion der Konzentrationsganglinien von Immissionspumpversuchen (2018)
    Springer-Verlag | Springer-Verlag
    Details
    Publication Date: 2021-03-29
    Description: Kurzfassung Auf dem Gelände eines ehemaligen Gaswerks (Testfeld Süd) wurden Immissionspumpversuche (IPVs) zur Quantifizierung der Fracht und der mittleren Konzentration gaswerkstypischer Schadstoffe entlang von drei Kontrollquerschnitten durchgeführt. Die daraus resultierenden Konzentrationsganglinien wurden mithilfe des Inversionsprogramms CSTREAM und eines Strömungs- und Transportmodells des hydraulisch extrem heterogenen Grundwasserleiters numerisch ausgewertet. Die den gesamten Abstrombereich der Verdachtsfläche erfassenden Kontrollquerschnitte ermöglichen Aussagen über die Position und Ausbreitung der Schadstofffahne auf dem Gelände des Testfeldes Süd. Bisherige Auswertungen von IPVs konnten die Verteilung der Schadstofffahne um den IPV-Brunnen für genau drei Fälle berechnen: entweder befindet sich die Fahne links vom Brunnen, rechts davon oder ist symmetrisch um ihn verteilt. Um eine realistischere Vorstellung von der Fahnenposition zu ermöglichen, wurden in dieser Studie zusätzlich Direct-Push-Messstellen entlang einer Kontrollebene installiert. Die in diesen Messstellen gemessenen Konzentrationen wurden zur Konditionierung der numerischen Inversionslösung herangezogen. Die Ergebnisse ermöglichen eine genauere Eingrenzung des Fahnenzentrums sowie des Fahnenrandes, was insbesondere die Erarbeitung angepasster und optimierter Sanierungsstrategien unterstützt.
    Description: A series of integral pumping tests (IPTs) were conducted at a former gasworks site to quantify the contaminant mass flux and average concentration in groundwater along three control planes. The resulting concentration-time series were analysed numerically with the help of the inversion code CSTREAM and a flow and transport model representing the highly heterogeneous aquifer. Since the control planes cover the entire downstream width of the potentially contaminated area, they allow conclusions to be drawn about the current location and spread of the contaminant plume. Previous evaluations of integral pumping tests could calculate three scenarios concerning the spread of the plume around the IPT well: (i) the plume is located to the right of the well, (ii) to the left, or (iii) is distributed symmetrically around it. To create a more realistic picture of the plume position, a series of direct-push monitoring wells were installed along one control plane. The concentrations found in these wells were included in the numerical analysis to condition the inversion results, and resulted in a more pronounced plume centre and fringe, which supports the development of optimised remediation strategies.
    Keywords: integral pumping tests; conditioning; plume delineation; remediation optimisation ; 551 ; Geosciences; Geoecology/Natural Processes; Soil Science & Conservation ; Applied Geosciences ; Waste Water Technology / Water Pollution Control / Water Management / Aquatic Pollution; Hydrogeology
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    Structural characteristics of the halite fabric type ‘Kristallbrocken’ from the Zechstein Basin with regard to its development (2018)
    Springer-Verlag | Springer-Verlag
    Details
    Publication Date: 2021-03-29
    Description: The Kristallbrocken are a characteristic centimetre- to decimetre-sized, laminated halite fabric type occurring in the Stassfurt Formation in the Zechstein Basin. Up to now, the nature of the Kristallbrocken, i.e. if they are relics of fine-grained, polycrystalline halite beds or clasts of ‘single crystal-layers’, as well as the deformation mechanisms of this halite type, were not clear from the literature. Drill core material from the salt deposit Teutschenthal at the southern rim of the Zechstein Basin now allowed investigating less intensely deformed samples for the first time. The deformational behaviour of these Kristallbrocken ranges from brittle to ductile, which is evidenced by fractured Kristallbrocken on the one hand and weakly bent or even folded Kristallbrocken on the other hand. Local X-ray texture measurements demonstrated that the Kristallbrocken are definitely single crystals and that they can be regarded as relics of formerly larger ‘single crystal-layers’ of up to several dm2 in size. The folded Kristallbrocken clearly display by their single grain texture characteristics that their crystal lattice is bent, which was most likely enabled by a kind of flexural-shear folding, and did not develop after deformation from a fine-grained aggregate by recrystallisation. Due to their monocrystallinity, their originally large size, and the solid inclusions forming the internal lamination, the Kristallbrocken have clearly stronger rheological properties than the surrounding fine- to coarse-grained polycrystalline rock salt, and thus also deform by fracturing.
    Keywords: Halite; Zechstein salt; Kristallbrocken; X-ray texture goniometry; Deformation mechanism; Crystallography ; 551 ; Earth Sciences; Geology ; Geophysics/Geodesy
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    The fossil record of the Haplosclerid excavating sponge Aka de Laubenfels (2018)
    Springer | Berlin [u.a.]
    Details
    Publication Date: 2021-04-25
    Keywords: 551 ; VU 000 ; 38.20
    Language: English
    Type: anthologyArticle , publishedVersion
    Format: 102-120
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    Renewed study of the type material of Palaeospongilla chubutensis Ott and Volkheimer (1972) (2018)
    Springer | Berlin [u.a.]
    Details
    Publication Date: 2021-04-25
    Keywords: 551 ; VU 000 ; 38.20
    Language: English
    Type: anthologyArticle , publishedVersion
    Format: 121-133
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    Unusual appearance of mother‐of‐pearl clouds above El Calafate, Argentina (50°21′S, 72°16′W) (2021)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2021-04-29
    Description: Visual observations from the ground and from a glider soaring in the lowermost stratosphere revealed the existence of stratospheric mother‐of‐pearl clouds above El Calafate in the lee of the Andes on 11 September 2019. The appearance of these clouds is rather unusual considering the time – end of the austral winter – and the location at about 50°S, being far away from Antarctica. This paper presents the available observations and describes the overall meteorological situation that was related to the earliest sudden stratospheric warming recorded so far in the Southern Hemisphere. By using high‐resolution numerical simulations, we show evidence of mountain waves propagating up to the stratosphere that are responsible for generating the localised cold stratospheric temperature anomalies required for ice cloud formation. Snapshots of a mother‐of‐pearl cloud from the camera installed at the PERLAN 2 aircraft's tail wing. image
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: 551.5 ; Argentina ; ice cloud formation
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    A new approach to classification of 40 years of Antarctic sea ice concentration data (2021)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2021-07-04
    Description: In this paper, we present a characterization of Antarctic sea ice based on the classification of annual sea ice concentration (SIC) data from 1979 to 2018. A clustering algorithm was applied to provide a climatological description of significant annual cycles of SIC and their spatial distribution around the Southern Ocean. Based on these classification results, we investigate the variability of SIC cycles on decadal and inter‐annual time scales. First, we discuss significant spatial shifts of SIC cycles during 1979–1998 and 1999–2018. In the Weddell Sea and in large parts of the Ross Sea, we observed higher SIC during the summer season, and an extension of sea ice cover in winter compared to the long‐term average. Second, we introduce the Climatological Sea Ice Anomaly Index (CSIAI), which is an annual measure for year‐round sea ice anomalies of the Southern Ocean and its regional sub‐sectors. By relating selected years of significant sea ice conditions (1981, 2007 and 2014) with atmospheric influences, we demonstrate that the CSIAI is very useful for assessing inter‐annular Antarctic SIC variability. Positive and negative sea ice anomalies can be qualitatively explained by atmospheric circulation anomalies in the years 1981 and 2007. However, in 2014, the year with the largest observed sea ice extent in our time series, we found that this positive sea ice anomaly was surprisingly not associated with a stationary and inter‐seasonally persistent pattern of circulation anomaly. This suggests that sub‐seasonal to seasonal circulation anomalies and ocean‐related processes favoured the formation of the sea ice maximum in 2014. With this study we provide additional information on the long‐term annual SIC variability around Antarctica. Furthermore, our classification approach and its results have potential for application in the evaluation of sea ice model results.
    Description: In this paper, we present a characterization of Antarctic sea ice based on the classification of annual sea ice concentration cycles in the period 1979 to 2018. Furthermore, we discuss spatial shifts between 1979–1998 and 1999–2018 and are able to explain significant annual sea ice anomalies by atmospheric circulation anomalies.
    Description: DLR Management Board: Young Investigator Group Leader Program. F.R. was funded by the Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: 551.31 ; passive microwave data ; sea ice climatology ; sea ice trends ; sea ice variability
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    Severe thunderstorms with large hail across Germany in June 2019 (2021)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2021-04-21
    Description: From 10 to 12 June 2019, severe thunderstorms affected large parts of Germany. Hail larger than golf ball size caused considerable damage, especially in the Munich area where losses amount to EUR 1 billion. This event thus ranks among the ten most expensive hail events in Europe in the last 40 years. Atmospheric blocking in combination with a moist, unstably stratified air mass provided an excellent setting for the development of severe, hail‐producing thunderstorms across the country. image
    Description: German Research Foundation http://dx.doi.org/10.13039/501100001659
    Keywords: 551.5 ; Germany ; thunderstorms ; hailstorm
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    Pre‐instrumental summer precipitation variability in northwestern Greece from a high‐elevation Pinus heldreichii network (2021)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2021-07-04
    Description: The spatiotemporal variability of precipitation is of vital importance to Mediterranean ecology and economy, but pre‐instrumental changes are not well understood. Here, we present a millennial‐length June–July precipitation reconstruction derived from a network of 22 Pinus heldreichii high‐elevation sites in the Pindus Mountains of northwestern Greece. Tree‐ring width chronologies from these sites cohere exceptionally well over the past several hundred years (r1467–2015 = 0.64) revealing coherence at inter‐annual to centennial timescales across the network. The network mean calibrates significantly against instrumental June–July precipitation over the past 40 years (r1976–2015 = 0.71), even though no high‐elevation observational record is available representing the moist conditions at the treeline above 1,900 m a.s.l. For the final reconstruction, the instrumental target data are adjusted to provide realistic estimates of high‐elevation summer rainfall back to 729 CE. The reconstruction contains substantially more low‐frequency variability than other high‐resolution hydroclimate records from the eastern Mediterranean including extended dry periods from 1,350 to 1,379 CE (39 ± 4.5 mm) and 913 to 942 (40 ± 8.4 mm), and moist periods from 862 to 891 (86 ± 11 mm) and 1,522 to 1,551 (80 ± 3.5 mm), relative to the long‐term mean of 61 mm. The most recent 30‐year period from 1986 to 2015 is characterized by above average June–July precipitation (73 ± 2 mm). Low‐frequency changes in summer precipitation are likely related to variations in the position and persistence of storm tracks steering local depressions and causing extensive rainfall (or lack thereof) in high‐elevation environments of the Pindus Mountains.
    Description: Associated with a strengthening of circum‐global sub‐tropical high‐pressure belts, climate models unequivocally predict a decrease of Mediterranean precipitation, accompanied by an increase of extreme events in the upcoming decades. Long‐term desiccation will amplify evaporative demand challenging plant metabolism and foster an even greater need to irrigate Mediterranean crops. We place these recent hydroclimate dynamics into a long‐term context and explore the feasibility of reconstructing low‐frequency precipitation variability by employing a large network of high‐elevation Pinus heldreichii sites from northwestern Greece.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: 551.6 ; climate reconstruction ; Mediterranean ; Pindus Mountains ; pine ; tree‐rings ; Valia Calda
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    Grassland greening on the Mongolian Plateau despite higher grazing intensity (2021)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2021-06-28
    Description: Changes in land management and climate alter vegetation dynamics, but the determinants of vegetation changes often remain elusive, especially in global drylands. Here we assess the determinants of grassland greenness on the Mongolian Plateau, one of the world's largest grassland biomes, which covers Mongolia and the province of Inner Mongolia in China. We use spatial panel regressions to quantify the impact of precipitation, temperature, radiation, and the intensity of livestock grazing on the normalized difference vegetation indices (NDVI) during the growing seasons from 1982 to 2015 at the county level. The results suggest that the Mongolian Plateau experienced vegetation greening from 1982 to 2015. Precipitation and animal density were the most influential factors contributing to higher NDVI on the grasslands of Inner Mongolia and Mongolia. Our results highlight the dominant effect of climate variability, and especially of the precipitation variability, on the grassland greenness in Mongolian drylands. The findings challenge the common belief that higher grazing pressure is the key driver for land degradation. The analysis exemplifies how representative wall‐to‐wall results for large areas can be attained from exploring space–time data and adds empirical insights to the puzzling relationship between grazing intensity and vegetation growth in dryland areas.
    Description: European Union's Framework Programme for Research and Innovation ‐ Horizon 2020 (2014‐2020)
    Description: Alexander von Humboldt Foundation of Germany
    Keywords: 333.7 ; China ; climate change ; grassland ; livestock grazing ; NDVI ; spatial panel regression ; vegetation growth
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    Contextualizing land‐use and land‐cover change with local knowledge: A case study from Pokot Central, Kenya (2021)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2021-07-16
    Description: Rural communities in the drylands of sub‐Saharan Africa (SSA) derive their livelihoods primarily from their natural resource base. Unprecedented changes in these environments over the past few decades are likely to intensify in the future and land users need to develop sustainable adaptation strategies. This study aims to identify land‐use and land‐cover (LULC) changes and their drivers in a sub‐Saharan dryland, between 1986 and 2017, by integrating local knowledge and remote sensing. Local knowledge and environmental perception are used as the basis for defining LULC classes and for training and validation of change detection. This study detects significant LULC changes in 41% of the investigated area, and identifies bush encroachment into former pastures as the dominant LULC change with an increase of woodland by 39% and a decrease of grassland by 74%. This process is perceived as severe degradation by local respondents and is linked to changing management regimes and unreliable rainfall patterns. Deforestation and woodland thinning account for 44% of the detected changes, and can be traced back to increased habitation and farming, although the local community also identifies charcoal production as a driving factor. The integration of remote sensing and local knowledge provides a holistic view on LULC change in Pokot Central, Kenya and offers a solid base for site‐specific and actor‐centred management approaches necessary for sustainable pathways of drylands. Our results emphasize the need to include local actors in the development of adaptation strategies and management guidelines for drylands.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Heidelberg University, Graduiertenförderung
    Keywords: 631.37 ; Kenya ; LANDSAT ; land‐use and land‐cover change ; local knowledge ; Pokot Central ; remote sensing
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    Comprehensive evaluation of an improved large‐scale multi‐site weather generator for Germany (2021)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2021-06-29
    Description: In this work, we present a comprehensive evaluation of a stochastic multi‐site, multi‐variate weather generator at the scale of entire Germany and parts of the neighbouring countries covering the major German river basins Elbe, Upper Danube, Rhine, Weser and Ems with a total area of approximately 580,000 km2. The regional weather generator, which is based on a first‐order multi‐variate auto‐regressive model, is setup using 53‐year long daily observational data at 528 locations. The performance is evaluated by investigating the ability of the weather generator to replicate various important statistical properties of the observed variables including precipitation occurrence and dry/wet transition probabilities, mean daily and extreme precipitation, multi‐day precipitation sums, spatial correlation structure, areal precipitation, mean daily and extreme temperature and solar radiation. We explore two marginal distributions for daily precipitation amount: mixed Gamma‐Generalized Pareto and extended Generalized Pareto. Furthermore, we introduce a new procedure to estimate the spatial correlation matrix and model mean daily temperature and solar radiation. The extensive evaluation reveals that the weather generator is greatly capable of capturing most of the crucial properties of the weather variables, particularly of extreme precipitation at individual locations. Some deficiencies are detected in capturing spatial precipitation correlation structure that leads to an overestimation of areal precipitation extremes. Further improvement of the spatial correlation structure is envisaged for future research. The mixed marginal model found to outperform the extended Generalized Pareto in our case. The use of power transformation in combination with normal distribution significantly improves the performance for non‐precipitation variables. The weather generator can be used to generate synthetic event footprints for large‐scale trans‐basin flood risk assessment.
    Description: The regional weather generator is greatly capable of capturing most of the crucial statistical properties of weather events. Hence, it can be used to generate synthetic event footprints for large‐scale trans‐basin flood risk assessment. However, due to its deficiency in capturing spatial precipitation correlation structure leading to an overestimation of areal precipitation extremes, further improvement is envisaged for future research.
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: 551.6 ; correlation ; extreme ; flood ; large‐scale ; multi‐variate ; weather generator
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    Development of a 3D groundwater model based on scarce data: the Wadi Kafrein catchment/Jordan (2018)
    Springer-Verlag | Berlin/Heidelberg
    Details
    Publication Date: 2021-03-29
    Keywords: Wadi Kafrein; Groundwater modelling; Model calibration; Arid and semiarid areas ; 551 ; Earth Sciences; Geology
    Language: English
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    Vertebrate tracksites in the Obernkirchen Sandstone (late Berriasian, Early Cretaceous) of northwest Germany— their stratigraphical, palaeogeographical, palaeoecological, and historical context (2018)
    Springer-Verlag | Berlin/Heidelberg
    Details
    Publication Date: 2021-04-24
    Description: The northern German Lower Cretaceous Bückeberg Formation yields numerous dinosaur tracksites, some of which have produced material of impressive quality. Stratigraphically, the localities are concentrated in the Obernkirchen Sandstone, a thin subunit within this formation. The Obernkirchen Sandstone represents mainly a sandy barrier to back-barrier and lagoonal setting within a limnic deltaic facies complex, which was deposited during the late Berriasian (Cypridea alta formosa ostracod subzone) in the southeast of the Lower Saxony Basin, northwest Germany. A few tracksites occur more proximally in coeval fluvial deposits. Dinosaur footprint assemblages were left by ornithopods, theropods, sauropods, ankylosaurs, and small, bipedal ornithischians. Other vertebrate tracks are those of turtles and, possibly, crocodilians. Due to the decrease in sandstone quarrying in recent decades, many old tracksites are inaccessible today. Additionally, historical descriptions of the tracks were of highly variable quality and often published in remote and today nearly unobtainable sources. Here we provide a catalogue of 13 tracksites compiled from the literature and some new observations. Of these 13 tracksites, only five are still accessible and currently under study. Descriptions of each locality are provided, with a comprehensive compilation of existing data on lithofacies, stratigraphy, palaeogeography and palaeoecology of the Obernkirchen Sandstone and equivalent strata. A short review of the track-bearing lithofacies assemblage indicates that the outcrop areas have distinctly different facies and environments, and, therefore, track-bearing horizons can only be correlated stratigraphically between adjacent outcrops. For this reason, the identification of a megatracksite in the Obernkirchen Sandstone is currently regarded as premature and uncertain.
    Keywords: Vertebrate tracks; Dinosauria; Cretaceous; Berriasian; Obernkirchen; Münchehagen; Germany; Wirbeltier-Fährten; Dinosauria; Kreide; Berriasium; Obernkirchen; Münchehagen; Deutschland ; 551 ; Earth Sciences; Paleontology
    Language: English
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    Marble bowing: comparative studies of three different public building facades (2018)
    Springer
    Details
    Publication Date: 2021-03-29
    Description: The veneer cladding of the Oeconomicum (OEC, Göttingen), the State Theatre of Darmstadt (STD, Darmstadt) and of the State and University Library (SUB, Göttingen) is characterised by pronounced bowing after a short time of exposure. Direct comparison of bowing data related to measurements from 2000 to 2003 at the SUB clearly show that the amplitude in bowing had significantly increased. The bowing is different in intensity and orientation (concave, convex). The cladding material (Peccia marble, Rosa Estremoz marble and Carrara marble) are different in lattice preferred orientation, grain size distribution and grain interlocking. Depending on the bowing, panels may show cracks mostly initiated at the dowels. The percentage of visible cracks and breakouts increases with the amplitude of bowing except for the STD. Repetitive heatingcooling under dry conditions leads to considerable inelastic residual strain only after the first or second thermal cycle. The residual strain continuously increases again if water is present, whereby the moisture content after a thermal cycle has a certain impact on the decay rate. The water-enhanced thermal dilatation strongly correlates with the deterioration rate obtained from the laboratory bow test. Detailed petrophysical investigations provide evidence that with increasing bowing a decrease of mechanical properties (flexural strength or breaking load at dowel hole) occur. Marble degradation is also connected with the increase in porosity and a general shift of the maximum pore radii to larger pore sizes...
    Keywords: Bowing; Marble; Building mapping;Residual strain;Thermal expansion; Bowing potential ; 551
    Language: English
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    The bipolar bivalve Oxytoma (Palmoxytoma) cygnipes (Young & Bird, 1822) in the Upper Pliensbachian of Germany (2018)
    Springer-Verlag | Berlin/Heidelberg
    Details
    Publication Date: 2021-04-25
    Description: The morphologically conspicuous bivalve Oxytoma (Palmoxytoma) cygnipes (Young & Bird, 1822), known for its palaeogeographically bipolar distribution, from a limestone bed in the boundary “Belemniten–Schichten”/Amaltheenton formation, Lower Jurassic, in N Germany is described. The occurrence of this palaeoceanographically significant bivalve points to an influx of cool seawater from the Arctic to the North-German Basin at the base of the Upper Pliensbachian, just before the deposition of the Amaltheenton formation. A review of previously reported occurrences on the NW European Shelf indicates two distinct stratigraphic intervals of occurrence of this taxon: the Rhaetian–Hettangian boundary and the Upper Pliensbachian. Whereas the former interval of occurrence may be related to short-term cooling in the course of the end-Triassic extinction event, the latter is interpreted as reflecting the influx of a cool water current to the eastern part of the NW European Shelf, which continued southwards parallel to the coast of the Bohemian–Vindelician High.
    Keywords: Bivalvia; Germany; Triassic–Jurassic boundary; Pliensbachian; Boreal; Bivalvia; Deutschland; Trias–Jura-Grenze; Pliensbachium; Boreal ; 551 ; Earth Sciences; Paleontology
    Language: English
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    Ascomycete fungi on dimension stone of the “Burg Gleichen”, Thuringia (2018)
    Springer-Verlag | Berlin/Heidelberg
    Details
    Publication Date: 2021-03-29
    Description: In the present study, the diversity of ascomycete fungi was investigated on two wall areas of the “Burg Gleichen”, Thuringia (Germany), made of various types of sandstones, travertine and Grenzdolomit. From a W-exposed, shaded wall area, free-living ascomycetes (mainly “black fungi”) and green algae could be retrieved from sandstone lithologies. Sandstone from an ESE-exposed area was mainly colonized by lichen ascomycetes and the lichen alga Trebouxia. Both areas share a small number of generalist species, related to the ascomycete black fungi Sarcinomyces petricola, Phaeococcomyces chersonesos and Stichococcus mirabilis. Free-living black fungi were isolated and characterized with respect to cell wall morphology and melanin content. A remarkably rigid melanin layer, incorporated in the cell wall of a Cladosporium isolate is presented in detail.
    Keywords: Dimension stone; Biofilm; Ascomycete fungi; Green algae; Cell wall; Melanin ; 551 ; Earth Sciences; Geology
    Language: English
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    Influence of shape fabric and crystal texture on marble degradation phenomena: simulations (2018)
    Springer-Verlag | Berlin/Heidelberg
    Details
    Publication Date: 2021-03-29
    Description: Microstructure-based finite element simulations were used to study the influence of grain shape fabric and crystal texture on thermoelastic responses related to marble degradation phenomena. Calcite was used as an illustrative example for studying extremes of shape preferred orientation (SPO) in shape fabric and lattice preferred orientation (LPO) in crystal texture. Three SPOs were analyzed: equiaxed grains, elongated grains, and a mixture of equiaxed and elongated grains. Three LPOs were considered: a random orientation distribution function and two degrees of strong directional crystal texture. Finally, the correlation between the direction of the LPO with respect to that of the SPO was examined. Results show that certain combinations of SPO, LPO, and their directional relationship have significant influence on the thermomechanical behavior of marble. For instance, while there is no major dependence of the elastic strain energy density and the maximum principal stress on SPO for randomly textured microstructures, there is a strong synergy between LPO and its directional relationship with respect to the SPO direction. Microcracking precursors, elastic strain energy density, and maximum principal stress, decrease when the crystalline c-axes have fiber texture perpendicular to the SPO direction, but increase significantly when the c-axes have fiber texture parallel to the SPO direction. Moreover, the microstructural variability increases dramatically for these latter configurations. In general, the influence of LPO was as expected, namely, the strain energy density and the maximum principal stress decreased with more crystal texture, apart from for the exception noted above. Spatial variations of these precursors indicated regions in the microstructure with a propensity for microcracking. Unexpectedly, important variables were the microstructural standard deviations of the spatial distributions of the microcracking indicators. These microstructural standard deviations were as large as or larger than the variables themselves. The elastic misfit-strain contributions to the coefficients of thermal expansion were also calculated, but their dependence was as expected.
    Keywords: Shape fabric; Shape preferred orientation; Crystal texture; Lattice preferred orientation; Marble; Calcite; Finite element simulations; Thermal expansion anisotropy; Elastic strain energy density; Maximum principal stress; Orientation distribution function; Coefficient of thermal expansion ; 551 ; Earth Sciences; Geology
    Language: English
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    Development and assessment of protective winter covers for marble statuaries of the Schlossbrücke, Berlin (Germany) (2018)
    Springer-Verlag | Berlin/Heidelberg
    Details
    Publication Date: 2021-03-29
    Description: The present study documents the results of an inter-disciplinary model project that was planned with the aim of developing an innovative winter covering system for marble statuaries located on the Schlossbrücke (Berlin). Such a system would need to fulfil the various requirements for structural stability, aesthetics, climate and practical use. This applied research represents the first complex scientific study of the sustainability of a winter covering system. The study is characterised by the use of complex scientific instruments such as special laboratory analysis and numerical simulation tools. The interaction between the environment and the artefacts in connection with the innovative winter covering structures were studied by extensive climatic monitoring.
    Keywords: Marble sculptures; Marble weathering; Winter cover; Climate data; Numerical simulations ; 551 ; Earth Sciences; Geology
    Language: English
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    The effect of air pollution on stone decay: the decay of the Drachenfels trachyte in industrial, urban, and rural environments—a case study of the Cologne, Altenberg and Xanten cathedrals (2018)
    Springer-Verlag | Berlin/Heidelberg
    Details
    Publication Date: 2021-03-29
    Description: Severe stone deterioration is evident at the Cologne cathedral. In particular, the “Drachenfels” trachyte, which was the building material of the medieval construction period, shows significant structural deterioration as well as massive formation of gypsum crusts. The present article investigates crust formation on limestone, sandstone, and volcanic rock from the Cologne cathedral as well as from the Xanten and Altenberg cathedrals. These three buildings, showing varying degrees of deterioration, are located in different areas and exposed to varying industrial, urban, and rural pollution. Thin laminar and black framboidal crusts form on calcareous as well as silicate stone. The lack of a significant intrinsic calcium and sulfur source for the formation of the gypsum crusts on the Drachenfels trachyte indicates major extrinsic environmental impact: a sufficient offer of SOx from pollutant fluxes as well as external calcium sources (e.g., pollution, mortars, neighboring calcite stones). Chemical analyses reveal strong gypsum enrichment within the crusts as well as higher concentrations of lead and other pollutants (arsenic, antimony, bismuth, tin, etc.), which generally can be linked to traffic and industry. The formation of weathering crusts in an industrial environment is clearly distinguishable from that in rural areas. Scanning electron microscopy observations confirm that the total amount of pollution is less at the Altenberg cathedral than at the Cologne and Xanten cathedrals. XRF analyses show that the formation of gypsum occurs in lower amounts at Altenberg. This correlates well with the measured SO2 content and the intensity of the decay at the different locations. Furthermore, the different types of crusts, e.g., framboidal and laminar, can be differentiated and assigned to the different locations. The black weathering crusts on the silicate Drachenfels trachyte contribute to the degradation of the historic building material. They enhance mechanical moisture-related deterioration processes and the decay by chemical corrosion of rock-forming minerals. Although SO2 concentrations in air have shown a strong decrease over the past 30 years, degradation in connection with weathering crusts is still observed. This indicates that not only contemporary or recent emissions, but also past pollutant concentrations have to be considered.
    Keywords: Cologne cathedral; Xanten cathedral; Altenberg cathedral; Weathering crusts; Pollution impact; Stone decay processes; Drachenfels trachyte ; 551 ; Earth Sciences; Geology
    Language: English
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    Infiltration and groundwater flow into a fractured porous sandstone aquifer in the eastern Thuringian Basin (2018)
    Springer-Verlag | Springer-Verlag
    Details
    Publication Date: 2021-03-29
    Description: Kurzfassung Im Osten des Thüringer Beckens sind aufgrund der geringen Niederschläge von 585 mm/a die Grundwasserressourcen in den geklüfteten Buntsandsteingrundwasserleitern stark limitiert. Ziel der Untersuchung war es, für dieses Buntsandsteinfließsystem ein numerisches Grundwasserströmungsmodell zu erstellen, um die zukünftige Entwicklung der Grundwasserressourcen auf der Grundlage verschiedener Klimaszenarien prognostizieren zu können. Im vorliegenden Beitrag wurden Grundwasserganglinien mit dem Ziel analysiert, eine Inputfunktion für die Grundwasserneubildung am Grundwasserspiegel abzuleiten, welche ein wichtiger Eingangsparameter bei der numerischen Modellierung ist. Es konnte gezeigt werden, dass die Strömung im Buntsandsteingrundwasserleiter sowohl durch ein kluft- sowie ein matrixdominiertes Strömungsregime charakterisiert ist. Der überwiegende Anteil der Grundwasserneubildung infiltriert rasch durch das Kluftsystem. Dagegen bewirken die geringeren Matrixdurchlässigkeiten in der ungesättigten Zone, in Abhängigkeit vom Flurabstand, eine deutliche Verzögerung der Grundwasserneubildung von bis zu mehreren Jahren.
    Description: In the eastern Thuringian Basin, the low precipitation rate of 585 mm/y limits the groundwater resources in the sandstone aquifer system. The aim of this study was to develop a groundwater flow model for the region in order to forecast the impacts of different climate scenarios on the groundwater balance. Since recharge is of high relevance for the numerical model, a time series of groundwater levels were investigated to obtain the recharge input function. In the sandstone aquifer it could be shown that groundwater flow is characterised by flow in the fracture network as well as in the matrix. The largest fraction of recharge reaches the water table very quickly via the fracture network. However, both the thickness of the unsaturated zone and the low hydraulic conductivity of the sandstone matrix control the time lag of groundwater recharge. The time lag of the slow component to reach the water table is in the order of several years.
    Keywords: groundwater level; fractured porous sandstone aquifer; water table fluctuation; groundwater recharge; geostatistical estimation ; 551 ; Earth Sciences; Geoecology/Natural Processes; Soil Science & Conservation ; Applied Earth Sciences; Waste Water Technology / Water Pollution Control / Water Management / Aquatic Pollution; Hydrogeology
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    International Year of the Planet Earth (IYPE) und unsere FH-DGG-Tagung in Göttingen, Mai 2008 (2018)
    Springer-Verlag | Springer-Verlag
    Details
    Publication Date: 2021-03-29
    Keywords: 551 ; Geosciences; Geoecology/Natural Processes; Soil Science & Conservation ; Applied Geosciences ; Waste Water Technology / Water Pollution Control / Water Management / Aquatic Pollution; Hydrogeology
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  • 91
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    Stability assessment of sandstones from the St. Servatius Church in Quedlinburg (UNESCO’s World Heritage Site, Germany) (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: The St. Servatius Church in Quedlinburg (UNESCO’s World Heritage Site, Germany) is characterised by long-standing stability problems and structural damages, which have been known over the last several centuries. The monotonous Cretaceous sandstone with its poor lithification is considered to be the main factor. The sandstone is characterised by a high porosity of around 30 Vol.% (max. ca. 35 Vol.%) and a corresponding high w-value. The porosity and the degree of cementation are responsible for the very low compressive strength of around 8 MPa at maximum, whereas under moisture these values are significantly reduced up to 40%. The freeze–thaw tests indicate a very poor resistance to frost weathering, which may explain the near-surface softening of the sandstone. Direct shear experiments with an approximate 60° angle of friction on the sandstone clearly demonstrate the safety margins. Initial geotechnical modelling does not favour the hypothesis that a landslide of the hill parallel to the southward dipping bedding planes (i.e. shear failure along weak zones) can occur. A prominent clay layer (also with a southward dip) below the entire castle hill is monitored to determine the possible amount of movement with respect to the geological discontinuities (e.g. joints, fractures). At present, a combination of foundation problems are being considered for the stability situation at the church. These include construction deficiencies due to deformation or softening of the foundation of the forerunner churches and missing or faulty connections from building additions. Geological factors responsible for the stability problems include the softening of the sandstone by the influence of weathering and penetrating water as well as the presence of possible shear planes and joints.
    Keywords: Cretaceous sandstone; Lithology; Diagenetic processes; Weathering; Petrophysical properties; Stability assessment ; 551 ; Earth Sciences; Geology
    Language: English
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    Black dimensional stones: geology, technical properties and deposit characterization of the dolerites from Uruguay (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: Dimensional stones with a black color occupy a prominent place on the international market. Uruguayan dolerite dikes of andesitic and andesitic–basaltic composition are mined for commercial blocks of black dimensional stones. A total of 16 dikes of both compositions were studied and samples collected for geochemical and petrographical analysis. Color measurements were performed on different black dimensional stones in order to compare them with the Uruguayan dolerites. Samples of the two commercial varieties (Absolute Black and Moderate Black) were obtained for petrophysical analysis (e.g. density, porosity, uniaxial compressive strength, tensile strength, etc.). Detailed structural analyses were performed in several quarries. Geochemistry and petrography determines the intensity of the black color. The Uruguayan dolerite Absolute Black is the darkest black dimensional stone analyzed in this study. The petrophysical properties of Uruguayan dolerites make them one of the highest quality black dimensional stones. Structural analyses show that five joint sets have been recognized: two sub-vertical joints, one horizontal and two diagonal. These joint sets are one of the most important factors that control the deposits, since they control the block size distribution and the amount of waste material.
    Keywords: Dolerites; Black dimensional stones; Petrophysical properties; Structural analysis; Block size distribution; Uruguay ; 551 ; Earth Sciences; Geology
    Language: English
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    Direct observation of microcrack development in marble caused by thermal weathering (2018)
    Springer-Verlag | Berlin/Heidelberg
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    Publication Date: 2021-03-29
    Description: One of the properties that makes marble such an excellent construction and ornamental material is its low porosity. It is very difficult for water or decay agents to penetrate the internal structure of materials with no or few pores, so enhancing the durability of these materials. However, environmental temperature fluctuations bring about significant physical changes in marbles that result in an increase in porosity, due to the appearance of new microcracks and the expansion of existing ones. These cracks offer new paths into the marble which make it easier for solutions containing pollutants to penetrate the material. Thermal expansion tests were performed on three different types of marble known as White, Tranco, and Yellow Macael (Almeria, Spain), after which an increase in porosity (from 17 to 73% depending on marble type) was observed, mainly due to crack formation. The structural changes occurring during thermal expansion tests were more significant in the case of White Macael samples, a fact that is not only related to its mineralogical composition but also to the morphology of the grains, grain boundaries and crystal size. Our research suggests that thermally weathered White Macael marble could be more susceptible to decay by other contaminant agents than Tranco or Yellow Macael. The use of hot-stage environmental scanning electron microscopy is proposed as a valid tool for observing, both in situ and at high magnification, changes in the fracture system of building stones induced by thermal stress.
    Keywords: Marble; Microcracks; Thermal expansion anisotropy; Grain boundaries ; 551 ; Earth Sciences; Geology
    Language: English
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    Multi-accretional tectonics at the Rio de la Plata Craton margins: preface (2018)
    Springer-Verlag | Berlin/Heidelberg
    Details
    Publication Date: 2021-03-29
    Keywords: 551 ; Earth Sciences; Geophysics/Geodesy; Geology
    Language: English
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    The regional MiKlip decadal prediction system for Europe: Hindcast skill for extremes and user‐oriented variables (2021)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2021-07-03
    Description: Regional climate predictions for the next decade are gaining importance, as this period falls within the planning horizon of politics, economy, and society. The potential predictability of climate indices or extremes at the regional scale is of particular interest. The German MiKlip project (“mid‐term climate forecast”) developed the first regional decadal prediction system for Europe at 0.44° resolution, based on the regional model COSMO‐CLM using global MPI‐ESM simulations as boundary conditions. We analyse the skill of this regional system focussing on extremes and user‐oriented variables. The considered quantities are related to temperature extremes, heavy precipitation, wind impacts, and the agronomy sector. Variables related to temperature (e.g., frost days, heat wave days) show high predictive skill (anomaly correlation up to 0.9) with very little dependence on lead‐time, and the skill patterns are spatially robust. The skill patterns for precipitation‐related variables (e.g., heavy precipitation days) and wind‐based indices (like storm days) are less skilful and more heterogeneous, particularly for the latter. Quantities related to the agronomy sector (e.g., growing degree days) show high predictive skill, comparable to temperature. Overall, we provide evidence that decadal predictive skill can be generally found at the regional scale also for extremes and user‐oriented variables, demonstrating how the utility of decadal predictions can be substantially enhanced. This is a very promising first step towards impact‐related modelling at the regional scale and the development of individual user‐oriented products for stakeholders.
    Description: The skill of the regional MiKlip decadal prediction system is analysed focussing on extremes and user‐oriented variables. Variables related to temperature extremes and the agronomy sector show high predictive skill with very little dependence on lead‐time. Skill patterns for precipitation‐related variables and wind‐based indices are less skilful and more heterogeneous, especially for the latter.
    Description: The study was mainly funded by the Bundesministerium für Bildung und Forschung (BMBF) under project FONA MiKlip‐II http://dx.doi.org/10.13039/501100002347
    Description: AXA Research Fund http://dx.doi.org/10.13039/501100001961
    Keywords: 551.6 ; climate services ; Europe ; extremes ; MiKlip ; regional decadal predictions ; user needs
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    Assessing land use and flood management impacts on ecosystem services in a river landscape (Upper Danube, Germany) (2021)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2021-06-28
    Description: Rivers and floodplains provide many regulating, provisioning and cultural ecosystem services (ES) such as flood risk regulation, crop production or recreation. Intensive use of resources such as hydropower production, construction of detention basins and intensive agriculture substantially change ecosystems and may affect their capacity to provide ES. Legal frameworks such as the European Water Framework Directive, Bird and Habitats Directive and Floods Directive already address various uses and interests. However, management is still sectoral and often potential synergies or trade‐offs between sectors are not considered. The ES concept could support a joint and holistic evaluation of impacts and proactively suggest advantageous options. The river ecosystem service index (RESI) method evaluates the capacity of floodplains to provide ES by using a standardized five‐point scale for 1 km‐floodplain segments based on available spatial data. This scaling allows consistent scoring of all ES and their integration into a single index. The aim of this article is to assess ES impacts of different flood prevention scenarios on a 75 km section of the Danube river corridor in Germany. The RESI method was applied to evaluate scenario effects on 13 ES with the standardized five‐point scale. Synergies and trade‐offs were identified as well as ES bundles and dependencies on land use and connectivity. The ratio of actual and former floodplain has the strongest influence on the total ES provision: the higher the percentage and area of an active floodplain, the higher the sum of ES. The RESI method proved useful to support decision‐making in regional planning.
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Keywords: 333.91 ; assessment ; cultural ; floodplains ; index ; inter‐sectoral management ; regulating and provisioning ecosystem services ; stakeholders
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    Nonstationarity of the link between the Tropics and the summer East Atlantic pattern (2021)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2021-07-03
    Description: A 700‐year pre‐industrial control run with the MPI‐ESM‐LR model is used to investigate the link between the summer East Atlantic (SEA) pattern and the Pacific‐Caribbean rainfall dipole (PCD), a link that has previously been shown using ERA‐Interim reanalysis data. In the model, it is found that the link between the SEA and PCD is present in some multidecadal epochs but not in others. A simple statistical model reproduces this behaviour. In the statistical model, the SEA is represented by a white noise process plus a weak influence from the PCD based on the full 700 years of the model run. The statistical model is relevant to other extratropical modes of variability, for example, the winter North Atlantic Oscillation (NAO), that are weakly influenced by the Tropics. It follows that the link between the Tropics and the winter NAO is likely to undergo modulation on multidecadal time scales, as found in some previous studies. The results suggest that any predictability of the SEA, and by implication the NAO, based on tropical rainfall may not be robust and may, in fact, be modulated on multidecadal time scales, with implications for seasonal and decadal prediction systems.
    Description: The positive phase of the SEA is associated with warm summers in Europe. The figure shows the running correlation in 51 year windows between the SEA index and the corresponding tropical rainfall index in a long pre‐industrial model run. The link between tropical rainfall and the SEA exists only in some decadal epochs, shown by the green shading, implying that predictability of the SEA based on tropical rainfall can be expected to vary on multidecadal time scales.
    Keywords: 551.5 ; nonstationarity ; seasonal prediction ; summer East Atlantic pattern
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    Convective rain cell characteristics and scaling in climate projections for Germany (2021)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2021-07-03
    Description: Extreme convective precipitation is expected to increase with global warming. However, the rate of increase and the understanding of contributing processes remain highly uncertain. We investigated characteristics of convective rain cells like area, intensity, and lifetime as simulated by a convection‐permitting climate model in the area of Germany under historical (1976–2005) and future (end‐of‐century, RCP8.5 scenario) conditions. To this end, a tracking algorithm was applied to 5‐min precipitation output. While the number of convective cells is virtually similar under historical and future conditions, there are more intense and larger cells in the future. This yields an increase in hourly precipitation extremes, although mean precipitation decreases. The relative change in the frequency distributions of area, intensity, and precipitation sum per cell is highest for the most extreme percentiles, suggesting that extreme events intensify the most. Furthermore, we investigated the temperature and moisture scaling of cell characteristics. The temperature scaling drops off at high temperatures, with a shift in drop‐off towards higher temperatures in the future, allowing for higher peak values. In contrast, dew point temperature scaling shows consistent rates across the whole dew point range. Cell characteristics scale at varying rates, either below (mean intensity), at about (maximum intensity and area), or above (precipitation sum) the Clausius–Clapeyron rate. Thus, the widely investigated extreme precipitation scaling at fixed locations is a complex product of the scaling of different cell characteristics. The dew point scaling rates and absolute values of the scaling curves in historical and future conditions are closest for the highest percentiles. Therefore, near‐surface humidity provides a good predictor for the upper limit of for example, maximum intensity and total precipitation of individual convective cells. However, the frequency distribution of the number of cells depending on dew point temperature changes in the future, preventing statistical inference of extreme precipitation from near‐surface humidity.
    Description: We investigated characteristics of convective rain cells under historical and future conditions in convection‐permitting climate simulations using a tracking algorithm. There are more intense and larger cells in the future yielding an increase in hourly precipitation extremes. The temperature scaling curves of cell characteristics shift towards higher peak values at higher temperatures in the future. In contrast, cell characteristics scale consistently with dew point temperature. Therefore, near‐surface humidity provides a good predictor for the upper limit of for example, maximum intensity, and total precipitation of convective cells.
    Keywords: 551.6 ; Clausius–Clapeyron scaling ; convection‐permitting simulation ; convective storms ; COSMO‐CLM ; precipitation ; tracking
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    Feasibility of pXRF to evaluate chosen heavy metals in soil highly influenced by municipal waste disposal—A monitoring study of a former sewage farm (2022)
    John Wiley & Sons, Ltd. | Chichester, UK
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    Publication Date: 2022-04-04
    Description: Sewage disposal onto agricultural land may result in the high accumulation of organic wastes, which questions the applicability of typical elemental analysis used for the soil components. To monitor the contamination status of agricultural soils at a former sedimentation basin, after the long‐term cessation of wastewater irrigation, 110 locations (15–20 cm depth) and 4 boreholes (up to 100 cm depth) were sampled to determine pH, loss on ignition, and concentration of Ni, Cu, Pb, Zn, and Cr. Additionally, the applicability of portable X‐ray fluorescence (pXRF) for the soil samples highly influenced by the organic wastes was evaluated. The study revealed the presence of a relatively homogenous sewage waste layer (depth of 20 cm), characterized by slightly acidic to neutral pH (6.3–7.5), high organic matter (OM) accumulation (up to 49%), and elevated concentration (mg kg −1) ranges between: Pb (5–321), Cu (31–2828), Ni (10–193), Cr (14–966), and Zn (76–6639). The pXRF analysis revealed metal concentration increase in mineral samples (up to 50%). The regression models and correction factors demonstrated high correlation and significance of pXRF measurement with response to increasing OM content, with the lowest r 2 = 0.86 obtained for Ni. Correlation of pXRF and AES measurement illustrated element‐dependent response for soils high in organics. Zn, Cu, and Cr pXRF analysis led to a slight underestimation in lower values, but overall good correlations (0.87; 0.89; and 0.88 respectively). Pb and Ni pXRF measurement revealed higher deviation from the reference in both lower and higher concentrations (0.74 and 0.70, respectively).
    Description: German Federation of Industrial Research Associations http://dx.doi.org/10.13039/501100002723
    Description: Federal Ministry for Economic Affairs and Energy http://dx.doi.org/10.13039/501100006360
    Keywords: ddc:577.14
    Language: English
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    Habitat availability determines food chain length and interaction strength in food webs of a large lowland river (2021)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2022-04-07
    Description: Many large rivers used for navigation have lost their hydromorphological heterogeneity, which has led to the widespread loss of native biodiversity and the concurrent establishment of non‐native communities. While the effects on biodiversity are well‐described, we know little about how the loss of natural habitats and the restructuring of communities cumulate into effects on riverine food webs. We constructed binary and ingestion webs for benthic macroinvertebrates and their resources in the Elbe River (Germany) and compared if food chain length, food web complexity, robustness, ingestion rates, and consumer‐resource interaction strength differ among three shoreline engineering practices. Food webs at profoundly altered shorelines were significantly less complex and had significantly shorter food chains than the food web at the semi‐natural shoreline. However, food web robustness to a simulated loss of species was comparable at all shorelines. Total ingestion rates were up to eight times lower at highly altered shorelines due to significantly lower ingestion rates by native species. Predator–prey interaction strength was comparable among shorelines due to higher shares of non‐native predators, indicating that non‐native predators can be functionally equivalent to native predators. We attributed the observed food web differences to the absence of complex habitats at profoundly altered shorelines and the accompanied absence of specialized consumers. Our study provides empirical evidence that hydromorphological modifications reduce the efficiency of food webs to control organic matter dynamics and may ultimately affect the provisioning of riverine ecosystem services.
    Keywords: ddc:339.95 ; ddc:551.483
    Language: English
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