ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Publication Date: 2021-03-29
    Description: One of the properties that makes marble such an excellent construction and ornamental material is its low porosity. It is very difficult for water or decay agents to penetrate the internal structure of materials with no or few pores, so enhancing the durability of these materials. However, environmental temperature fluctuations bring about significant physical changes in marbles that result in an increase in porosity, due to the appearance of new microcracks and the expansion of existing ones. These cracks offer new paths into the marble which make it easier for solutions containing pollutants to penetrate the material. Thermal expansion tests were performed on three different types of marble known as White, Tranco, and Yellow Macael (Almeria, Spain), after which an increase in porosity (from 17 to 73% depending on marble type) was observed, mainly due to crack formation. The structural changes occurring during thermal expansion tests were more significant in the case of White Macael samples, a fact that is not only related to its mineralogical composition but also to the morphology of the grains, grain boundaries and crystal size. Our research suggests that thermally weathered White Macael marble could be more susceptible to decay by other contaminant agents than Tranco or Yellow Macael. The use of hot-stage environmental scanning electron microscopy is proposed as a valid tool for observing, both in situ and at high magnification, changes in the fracture system of building stones induced by thermal stress.
    Keywords: Marble; Microcracks; Thermal expansion anisotropy; Grain boundaries ; 551 ; Earth Sciences; Geology
    Language: English
    Type: article , publishedVersion
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Publication Date: 2010-03-29
    Description: The effects of borax on the crystallization of sodium and magnesium sulphate, two of the most damaging salts affecting porous stones, have been studied. Borax promotes the crystallization of mirabilite and inhibits epsomite crystallization in open glass beakers. The additive is preferentially adsorbed onto {140}mirabilite and {111}epsomite faces, thus acting as an effective habit modifier. In contrast, in the presence of a calcitic support (either Iceland spar single crystals or a porous limestone - a biocalcarenite) crystallization is promoted in the presence of borax, irrespective of the salt tested. Apparently, this is due to a high stereochemical affinity between borate molecules adsorbed (and/or co-precipitated) onto calcite, and mirabilite and epsomite crystals. Salt weathering tests using a biocalcarenite show a significant damage reduction upon borax addition to the saline solutions. Borax promotes the crystallization of both mirabilite and epsomite within the pores of the stone, reducing its porosity. Crystallization promotion favours nucleation at a low supersaturation, thereby resulting in very low crystallization pressure and minimal damage. Application of borax to porous limestones affected by mirabilite and/or epsomite crystallization could be a new means of suppressing salt weathering.
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    Publication Date: 2013-06-13
    Description: The reactions that occur at the mineral–water interface are central to all geochemical processes. They affect a wide range of important Earth processes, all of which involve geochemical element cycling. Examples include weathering and soil formation, nutrient availability, biomineralization, acid mine drainage, the fate of contaminants, nuclear waste disposal, and minor element incorporation and partitioning during mineral growth. Each of these processes, and its reaction rates, is ultimately controlled by reactions that occur at mineral surfaces. Through the development of advanced analytical methods, direct observations of mineral reactions at the nanoscale have enabled exciting new possibilities for clarifying the mechanisms governing mineral–fluid reactions.
    Print ISSN: 1811-5209
    Electronic ISSN: 1811-5217
    Topics: Geosciences
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    Publication Date: 2010-03-16
    Print ISSN: 0743-7463
    Electronic ISSN: 1520-5827
    Topics: Chemistry and Pharmacology
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    Publication Date: 2016-06-30
    Description: The mechanism of surface coating formation (the so-called surface altered layers [SALs] or leached layers) during weathering of silicate minerals is controversial and hinges on understanding the saturation state of the fluid at the dissolving mineral surface. Here we present in-situ data on the evolution of the interfacial fluid composition during dissolution of wollastonite (CaSiO 3 ), obtained using interferometry and micro pH and ion-selective electrodes. Steep concentration gradients develop at the mineral interface as soon as it makes contact with the solution. This interfacial fluid becomes supersaturated with respect to amorphous silica that forms a surface coating, limiting fluid access to the mineral surface and hence affecting the dissolution rate. The thickness of the supersaturated zone and the precipitated layer depends on the relative rates of mass transport and surface reaction in the system; this effect could contribute to the discrepancy between dissolution rates measured in the field and in the laboratory. As well, our results have implications for predictions of silicate weathering rates and hence climate evolution, as different assumptions on dissolution mechanisms affect calculations on CO 2 drawdown during weathering and consequent effects on estimates of global mean temperatures.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
    Topics: Geosciences
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    Publication Date: 2012-10-01
    Description: The dissolution of most common multicomponent silicate minerals and glasses is typically incongruent, as shown by the nonstoichiometric release of the solid phase components. This results in the formation of so-called surface leached layers. Due to the important effects these leached layers may have on mineral dissolution rates and secondary mineral formation, they have attracted a great deal of research. However, the mechanism of leached layer formation is a matter of vigorous debate. Here we report on an in situ atomic force microscopy (AFM) study of the dissolution of wollastonite, CaSiO 3 , as an example of leached layer formation during dissolution. Our in situ AFM results provide, for the first time, clear direct experimental evidence that leached layers are formed in a tight interface-coupled two-step process: stoichiometric dissolution of the pristine mineral surfaces and subsequent precipitation of a secondary phase (most likely amorphous silica) from a supersaturated boundary layer of fluid in contact with the mineral surface. This occurs despite the fact that the bulk solution is undersaturated with respect to the secondary phase. Our results differ significantly from the concept of preferential leaching of cations, as postulated by most currently accepted incongruent dissolution models. This interface-coupled dissolution-precipitation model has important implications in understanding and evaluating dissolution kinetics of major rock-forming minerals.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
    Topics: Geosciences
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    Publication Date: 2012-02-01
    Description: Atomic force microscopy (AFM) enables in situ observations of mineral–fluid reactions to be made at a nanoscale. During the past 20 years, the direct observation of mineral surfaces at molecular resolution during dissolution and growth has made significant contributions toward improvements in our understanding of the dynamics of mineral–fluid reactions at the atomic scale. Observations and kinetic measurements of dissolution and growth from AFM experiments give valuable evidence for crystal dissolution and growth mechanisms, either confirming existing models or revealing their limitations. Modifications to theories can be made in the light of experimental evidence generated by AFM. Significant changes in the kinetics and mechanisms of crystallization and dissolution processes occur when the chemical and physical parameters of solutions, including the presence of impurity molecules or background electrolytes, are altered. Calcite has received considerable attention in AFM studies due to its central role in geochemical and biomineralization processes. This review summarizes the extensive literature on the dissolution and growth of calcite that has been generated by AFM studies, including the influence of fluid characteristics such as supersaturation, solution stoichiometry, pH, temperature and the presence of impurities.
    Print ISSN: 0026-461X
    Electronic ISSN: 1471-8022
    Topics: Geosciences
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    Publication Date: 2017-02-01
    Print ISSN: 0264-1275
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Published by Elsevier
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    Publication Date: 2019
    Print ISSN: 0935-1221
    Electronic ISSN: 1617-4011
    Topics: Geosciences
    Published by Schweizerbart
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    Publication Date: 2019
    Print ISSN: 0935-1221
    Electronic ISSN: 1617-4011
    Topics: Geosciences
    Published by Schweizerbart
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...