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  • 1
    ISSN: 1432-0495
    Keywords: Key words Tourist cave ; Human impact ; Speleothem degradation ; Biological weathering
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Human intrusion on the Cave of Marvels (southwestern Spain) has produced a series of effects on the water (fall in the level of the pools due to pumping from nearby wells), the air (increased temperature and CO2 concentration as well as decreased relative humidity) and the rock. In addition, plant colonization, favored by the lighting system, has irreversibly altered numerous speleothems. The processes of degradation are especially intense in the sectors with less air volume and limited ventilation. The analysis of the cave deposits by scanning electron microscopy and thin section analysis revealed that floral pollution constitutes one of the most aggressive agents against the calcite and aragonite precipitates, being responsible for biochemical and biophysical degradation of the first order.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 119 (2000), S. 191-207 
    ISSN: 1573-2932
    Keywords: bricks ; decay tests ; firing temperature ; particulate matter ; polluted atmosphere ; SO2 ; weathering
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The weathering of different brick samples ina range of aggressive environments has been studied.Brick samples were prepared using two clay types (fromGranada, Spain), different additives, and a range offiring temperatures (850–1100 °C). The brickscompositional and textural characteristics wereevaluated using XRD, SEM, hydric tests and mercuryintrusion porosimetry (MIP). The samples weresubjected to accelerate aging, including wet-dry,freeze-thaw and salt crystallization cycles. The decayof the bricks in polluted atmospheres was simulated ina static chamber containing sulfur dioxide (SO2)at 25 °C and 50% relative humidity. Samplesfired at 1000 °C proved to be the most durable,with better hydric behavior (fast drying and slowwater absorption) and fewer micropores. However, theywere not suitable for salt-rich environments (badperformance in the salt decay test). Samples fired at850 °C turned out to be more resistant to saltdecay, but they showed a poor hydric behavior (slowdrying and rapid water absorption) and littleresistance to freeze-thaw and wet-dry cycles. Samplesfired at 1100 °C had good hydric behavior, theyperformed well in the salt decay test, but they didnot perform as well as the samples fired at1000 °C in most accelerated aging tests. Gypsumformed on all the brick samples submitted to SO2atmosphere regardless exposure time (e.g. gypsumappears following just 24 h of exposure),composition, or firing temperature. Samples withdeposited particulate matter collected from vehicleexhausts (diesel, as well as leaded and non-leadedgasoline motor cars) resulted in the fastest gypsumdevelopment and greater abundance. On the other hand,the blank samples, and the samples withpollution-derived dust collected from historicalbuildings showed little gypsum development. Theimplications of these results in historicalbrick-building preservation in a range of aggressiveenvironments, and in polluted atmospheres inparticular, are discussed.
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 2010-03-29
    Description: The effects of borax on the crystallization of sodium and magnesium sulphate, two of the most damaging salts affecting porous stones, have been studied. Borax promotes the crystallization of mirabilite and inhibits epsomite crystallization in open glass beakers. The additive is preferentially adsorbed onto {140}mirabilite and {111}epsomite faces, thus acting as an effective habit modifier. In contrast, in the presence of a calcitic support (either Iceland spar single crystals or a porous limestone - a biocalcarenite) crystallization is promoted in the presence of borax, irrespective of the salt tested. Apparently, this is due to a high stereochemical affinity between borate molecules adsorbed (and/or co-precipitated) onto calcite, and mirabilite and epsomite crystals. Salt weathering tests using a biocalcarenite show a significant damage reduction upon borax addition to the saline solutions. Borax promotes the crystallization of both mirabilite and epsomite within the pores of the stone, reducing its porosity. Crystallization promotion favours nucleation at a low supersaturation, thereby resulting in very low crystallization pressure and minimal damage. Application of borax to porous limestones affected by mirabilite and/or epsomite crystallization could be a new means of suppressing salt weathering.
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  • 4
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    Mineralogical Society of America
    In: Elements
    Publication Date: 2013-06-13
    Description: The survival of important pieces of our architectural and sculptural heritage is challenged by irreparable damage due to crystallization of soluble salts. Mineral precipitation is also a problem in many industrial processes, leading to costly scale formation. Most of the mechanisms that control these crystallization reactions can be modified or slowed down by using specific additives. Recent advances in elucidating the mechanisms of mineral nucleation and growth and molecular-level mineral–additive interactions have led to the development of novel treatments for the prevention of mineral scale and salt damage.
    Print ISSN: 1811-5209
    Electronic ISSN: 1811-5217
    Topics: Geosciences
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  • 5
    Publication Date: 2010-03-16
    Print ISSN: 0743-7463
    Electronic ISSN: 1520-5827
    Topics: Chemistry and Pharmacology
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  • 6
    Publication Date: 2016-06-30
    Description: The mechanism of surface coating formation (the so-called surface altered layers [SALs] or leached layers) during weathering of silicate minerals is controversial and hinges on understanding the saturation state of the fluid at the dissolving mineral surface. Here we present in-situ data on the evolution of the interfacial fluid composition during dissolution of wollastonite (CaSiO 3 ), obtained using interferometry and micro pH and ion-selective electrodes. Steep concentration gradients develop at the mineral interface as soon as it makes contact with the solution. This interfacial fluid becomes supersaturated with respect to amorphous silica that forms a surface coating, limiting fluid access to the mineral surface and hence affecting the dissolution rate. The thickness of the supersaturated zone and the precipitated layer depends on the relative rates of mass transport and surface reaction in the system; this effect could contribute to the discrepancy between dissolution rates measured in the field and in the laboratory. As well, our results have implications for predictions of silicate weathering rates and hence climate evolution, as different assumptions on dissolution mechanisms affect calculations on CO 2 drawdown during weathering and consequent effects on estimates of global mean temperatures.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
    Topics: Geosciences
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  • 7
    Publication Date: 2012-10-01
    Description: The dissolution of most common multicomponent silicate minerals and glasses is typically incongruent, as shown by the nonstoichiometric release of the solid phase components. This results in the formation of so-called surface leached layers. Due to the important effects these leached layers may have on mineral dissolution rates and secondary mineral formation, they have attracted a great deal of research. However, the mechanism of leached layer formation is a matter of vigorous debate. Here we report on an in situ atomic force microscopy (AFM) study of the dissolution of wollastonite, CaSiO 3 , as an example of leached layer formation during dissolution. Our in situ AFM results provide, for the first time, clear direct experimental evidence that leached layers are formed in a tight interface-coupled two-step process: stoichiometric dissolution of the pristine mineral surfaces and subsequent precipitation of a secondary phase (most likely amorphous silica) from a supersaturated boundary layer of fluid in contact with the mineral surface. This occurs despite the fact that the bulk solution is undersaturated with respect to the secondary phase. Our results differ significantly from the concept of preferential leaching of cations, as postulated by most currently accepted incongruent dissolution models. This interface-coupled dissolution-precipitation model has important implications in understanding and evaluating dissolution kinetics of major rock-forming minerals.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
    Topics: Geosciences
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  • 8
    Publication Date: 2014-06-12
    Description: Serpentinites from Sierra Nevada (Granada, south of Spain) have traditionally been used as ornamental elements in historical buildings, both indoors and outdoors. The cathedral, the Palace of Charles V, the Royal Chancellery in Granada and some others are good examples of their use. Outside Granada, the serpentinites are seen at the monastery of El Escorial, The Royal Palace and the convent of Las Salesas Reales, all of them part of Madrid's architectural heritage, although there are much more examples to be found across the country. There are two quarries located in Sierra Nevada that supplied all the material to make the different elements in the above buildings. In this work, we report a thorough characterization of the main characteristics of the serpentinites from Sierra Nevada in order to propose this stone as a possible candidate as a ‘Global Heritage Stone Resource’. This work is important for duly recognizing a natural stone that has been profusely used in the past in the construction of a magnificent heritage of important cities, and historical quarries should be protected so that they can provide original material if required to do so in the future.
    Print ISSN: 0305-8719
    Electronic ISSN: 2041-4927
    Topics: Geosciences
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  • 9
    Publication Date: 2017-02-01
    Print ISSN: 0264-1275
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Published by Elsevier
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  • 10
    Publication Date: 2008-05-27
    Print ISSN: 0943-0105
    Electronic ISSN: 1432-0495
    Topics: Geosciences
    Published by Springer
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