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  • Articles  (938)
  • Wiley-Blackwell  (938)
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  • Architecture, Civil Engineering, Surveying  (938)
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  • Articles  (938)
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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 17 (1993), S. 185-190 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Different types of floor coverings were tested using three different methods: the Cone Calorimeter (ISO 5660), the Nordtest floor covering test NT FIRE 007 and the German Radiant Panel Method (DIN 4102 Teil 14). The results of the comparisons between both flame spread and smoke production are given. Some correlation is found between the results of the Cone Calorimeter and the NT FIRE 007. Between other methods, no correlations seem to exist.
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  • 2
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 17 (1993), S. 249-254 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: External radiation in enclosure fires can significantly enhance flame spread and fire growth. One of the effects of external radiation is to increase the mass loss rate of the fuel, which in turn produces larger flames. In this work, a measurement of mass loss with and without applied radiation was made as a function of time for three types of materials: a plastic (polymethylmethacrylate), wood-based products (particle board and hardboard), and a paper-based product (cardboard). The levels of applied radiation ranged from 0 to nearly 12 kWm-2. The purpose of the investigation was to (1) quantitatively determine the effect of external radiation on the mass loss of various materials,(2) measure various parameters which may be used to characterize the mass loss rate history of the materials and (3) determine a method for expressing the mass loss rate as a function of time for input into numerical models. Higher levels of external radiation resulted in higher peak mass loss rates and quicker consumption of the material. Quantities which are useful for ranking the flammability of materials have been measured for the samples tested and are tabulated.
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  • 3
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 17 (1993) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 4
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 17 (1993), S. 259-263 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A new Intermediate Scale Heat Release Rate Test Method is being developed primarily for testing assemblies in the vertical mode. Using the oxygen consumption calorimetry methodology and exhaust collection systems that already exist in many laboratories in the US and around the world, the apparatus is very economical to install. The sample size lends itself to reptitive testing in a short period of time. Sample preparation is generally quick and easy. Further development of the method should progress now that the method has been introduced at ASTM and will be introduced formally into ISO in the near future. There has been a favorable response by several laboratories who are considering construction of the apparatus. Additional assemblies tests are already underway and additional data will be presented in the near future.
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  • 5
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 17 (1993), S. 271-277 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In the study of smoke suppressants the measurement of gross amount of smoke from a given sample is essential. However, smoke being a complex phenomenon, its measurement with optical methods presents practical problems. The paper describes a flow system for the measurement of smoke production. Effectiveness of smoke-suppressant formulations for poly(vinyl chloride) as assessed in a flow system is reported. Results of experiments conducted to probe and establish the capability of smoke measurement in a flow system using a helium-neon laser are discussed.
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  • 6
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 18 (1994), S. 231-241 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper extends previously reported work 1,2 and describes the influence that a range of selected flame retardants have on the burning behaviour and pyrolyses of homo-and copolymers of acrylonitrile. Various inorganic and organic phosphorus and nitrogen- or sulphur-containing, halogen-containing (in the absence and presence of halogen or antimony (III) oxide) and nitrogen-containing flame retardants and red phosphorus were studied using LOI, TGA, DSC and residual char measuring techniques. Flame retardancy relates directly to char-forming tendency for all retardants and their ability to reduce the dominance of flammable volatiles formed during the first stage of acrylic polymer pyrolysis. Ammonium phosphates are particularly effective flame retardants for the selected copolymers. Possible mechanisms of retardant activity are discussed, including the char-forming tendency of antimony-bromine combiniations.
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  • 7
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 18 (1994), S. 263-265 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 8
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 5 (1981), S. 6-13 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Measured Critical Oxygen Index values at 40°C for Opal polymethylmethacrylate (Perspex) sheet have been found to be remarkably dependent on the gas velocity within the column of the Hot Flammability Test Apparatus. Investigation of the atmosphere present in the column has indicated that the effect is almost solely attributable to varying quantities of ambient air entering the column as the flow rate is altered. A modification to the apparatus is proposed that successfully prevents this entrainment of air at normal testing flow rates.
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  • 9
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    Fire and Materials 5 (1981), S. 14-23 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper reports a set of modeling studies that were undertaken to acquire a more detailed knowledge of combustion inhibition mechanisms. Mixtures of H2/O2/Ar reacting in the idealized perfectly stirred reactor were investigated. Three H2/O2 kinetic mechanisms were considered, differing from one another by the number of HO2 reactions included. Two physical inhibitors, Ar and N2, and one chemical inhibitor, HBr, were investigated. Additional parameters considered were pressure, equivalence ratio, inhibitor concentration and rate coefficient variation. The most effective inhibitor was HBr which acted chemically and caused substantial reduction in radical concentrations in the mixtures considered. The molecules Ar and N2 acted as physical diluents with N2, the more effective of the two due to its larger heat capacity.
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  • 10
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    Fire and Materials 5 (1981), S. 24-32 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A test device consisting of an asbestos covered wooden cylinder was developed to study the burning behaviour of textiles relative to transmitted thermal energy and heat flux registered at 20 sensor points on the cylinder. In order to simulate a ‘line situation’ a reproducible procedure was used for igniting the fabrics at the hem edge by open flames. By linking known tolerance thresholds for second degree burn injuries in humans to the measured time patterns of transmitted thermal energy, the burning behaviour of a pure cotton twill, a 35/65% polyester-cotton twill and a 65/35% polyester-cotton twill was compared. All fabrics, which had no fire-retardant finishes, were also tested in combination with cotton underwear and in some of the experiments they were soaked with an inflammable solvent before ignited. In contrast to customary opinions it could be shown that in apparel burn accidents without inflammable solvents fabrics made from polyester-cotton blends are more advantageous with regard to the thermal energy transmitted to the skin of the wearer than fabrics made from cotton. Even when the burning clothes are soaked with an inflammable solvent, polyester-cotton blends are practically not more disadvantageous than 100% cotton fabrics.
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  • 11
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 5 (1981), S. 77-84 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: For building control purposes of wall-lining and flooring materials in Europe several empirical reaction to fire tests are used. This paper examines the correlation between a number of different tests looking at some 42 different materials, and comments thereon.
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  • 12
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    Fire and Materials 5 (1981), S. 85-85 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 13
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    Fire and Materials 5 (1981), S. i 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 14
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    Fire and Materials 5 (1981) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 15
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    Fire and Materials 5 (1981), S. iii 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 16
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 5 (1981), S. 112-122 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The characteristics of fire resistance test furnaces are examined. It is shown that the efficiency of a furnace, as measured in terms of the heat load it imposes on a test specimen, depends markedly on the size of the furnace and the nature of the furnace gas. Only with large furnaces heated by gases of high radiation potential (near-black gases) can the test results be regarded as meaningful and reproducible. Reling a defective furnace with a material of very low thermal inertia, though helpful, is unlikely to bring its performance up to the required level. Methods of determining the efficiency of test furnaces are outlined. The theorem of uniformity heat load is recognized as a succinct descriptor of fires with respect to their destructive potential. As such, it forms the basis for correlating real-world fires with standard test fires.
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  • 17
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    Fire and Materials 5 (1981), S. 128-130 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 18
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    Fire and Materials 5 (1981), S. 123-127 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This investigation examines the influence of sample dimensions on the Critical Oxygen Index, as determined on a Stanton Redcoft Hot Flammability Test Apparatus instrument. The materials used were polypropylene films in a range of thicknesses from 40 μm up to 300 μm and polymethylmethacrylate of 1600 μm thickness. Both the Critical Oxygen Index and the rate of spared of burn in the samples were determined. It is concluded that, for polypropylene, the sample dimensions were important in determining the Critical Oxygen Index and the rate of spread of burn and, further, that the ratio of the volume of material burned in unit time to the volume flow of oxygen in the same time remains constant, the value of the constant being 2.5 × 10 -4. For polymethlmethacrylate, in confirmation of the work of Fenimore and Jones, the sample dimensions were unimportant when investigating the Critical Oxygen Index, although the rate of burn by volume showed a significant increase with sample width. The volume ratio showed a corresponding increase.
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  • 19
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    Fire and Materials 5 (1981), S. 131-131 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 20
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    Fire and Materials 5 (1981) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 21
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    Fire and Materials 5 (1981), S. iii 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 22
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    Fire and Materials 5 (1981), S. 142-148 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Results of a study of time-dependent deformation of concrete over a period of five hours at room and elevated temperatures (22 to 649°C) are described. The influences of load, temperature and material variables are examined and data compared with several mathematical models commonly used to describe concrete creep behavior. Information obtained from this study will help in evaluation of the design of concrete structures to withstand fire and other high temperature environments.
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  • 23
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    Fire and Materials 5 (1981), S. 133-141 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The thermal decomposition of a number of TDI- and MDI-based biscarbamates (model compounds for polyurethane foams) between 200°C and 1000°C showed that the urethane linkage undergoes an O-acyl fission at about 300°C to generate the free isocyanate and alcohol. In the case of the flexible foam analogues, the newly generated TDI reacts further to generate volatile polyureas, termed ‘yellow smoke’. The MDI residues generated in the decomposition of a rigid foams react to yield non-volatile polycarbodiimides. Both the yellow smokes and the polycarbodiimides decompose above 600°C to give a mixture of nitriles (including HCN) as well as a number of olefinic and aromatic compounds. The use of 13C labeling indicated that HCN and all the other nitriles generated during the high temperature decompositions originate in the thermal fission of the aromatic ring, the nitrile carbon being the 2-, 4- or 6- carbon of MDI.
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  • 24
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    Fire and Materials 5 (1981), S. 149-152 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Gas chromatography using a column with a molecular sieve was applied to the determination of carbon monoxide in thermal degradation of polymeric materials. Attention was paid to the variance of individual determinations and conclusions were drawn regarding reproducibility of the processes studies. The carbon monoxide content in pyrolysis and thermooxidation products of the commonest polymeric materials and the effect of temperature on the amount of carbon monoxide formed were determined.
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  • 25
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    Fire and Materials 5 (1981), S. 153-162 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Ignitability, one of the new fire test methods for building materials developing within the International Standards Organization is compared with the national fire test methods in Austria, Britain, France, Germany and Scandinavia. Different commercial wood-based panels have been tested, including fire retardant treated panels. The International Standards Organization ignitability test measures the time to ignition at radiation intensities from 1 to 5 Wm -2; it seems to be able to distinguish between different materials in an intelligible way. An evaluation of the results of this ignitability test is discussed. One possibility which is proposed here is to calculate the mean time to ignition at different fixed radiation intensities; such a mean value simplifies the evaluation and takes into account all the test data. Agreement with the national fire test methods is rather low, since they partly measure other fire parameters; agreement with the Austrian Schlyter method, which also evaluated ignitability, is somewhat better and agreement between the national fire test methods is relatively good for wood-based panels. This is consistent with earlier experience, which has shown that mainly new types of materials behave differently according to different national test methods.
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  • 26
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    Fire and Materials 5 (1981), S. 177-178 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 27
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    Fire and Materials 5 (1981), S. 175-176 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 28
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    Fire and Materials 5 (1981), S. 179-179 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 29
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    Fire and Materials 5 (1981), S. 163-174 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The results of applying the tentative, high temperature, International Standards Organization test methods DP 5925 Part 3, which was developed to measure smoke leakage of door assemblies during the course of a standard fire endurance test, are reported. A critical analysis reveals that the basic objective of the test method is limited in its utility in that fire scenarios in high-rise buildings may not be adequately simulated. Independent of this limitation, the analysis then identifies certain theoretical problems with the test method and its procedures. These lead to a conclusion that the test method is not generally reliable. An alternative test concept which appears to remove this limitation and all of its problems is described, and its development is advocated.
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  • 30
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    Fire and Materials 5 (1981), S. 180-181 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 31
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    Fire and Materials 6 (1982), S. 54-58 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Owing to their low cost phosphorus fire-retardants find vast application in making fire-retardant cellulosic compostions. They have been used both as a physical additive as well as part of the polymer structure. Acid forming phosphorus compounds are generally effective in cotton and other cellulosic. Acidic retardants produce char via a dehydration process and this brings about the final fire-retardancy in phosphate-containing composition. High efficiency of phosphorus fire retardants in polyurethane foam has also been suggested to be the result of stable char formation. The char affects the flammability in the three following ways: reduction of flammable fuel, insulation by the char and coating by the non-volatile thermally stable phosphorous acids which screen the hot carbon from the oxygen. Nitrogen-phosphorus synergism in cellulose in controversial and evidence indicates that it is non existent in polymers.
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  • 32
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In recent year, increased attention, linked to the use of new structural design criteria and materials, has been given to maintaining the integrity of buildings and structures exposed to fire. Structures are now designed using lighter structural shapes and consequently differ from earlier, more traditional buildings, in terms of their resistance to the effects of the high temperature of fire. Contemporary structures are less expensive. Advance in building construction technology also result in faster erection.
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  • 33
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    Fire and Materials 6 (1982), S. 59-64 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The theromo-oxidative decomposition, flash ignition and burning of high-impact polystyrene containing the flame-retardant system decabromodiphenyl oxide + antimony trioxide was investigated using the Setchkin apparatus combined with mass spectrometry. The time dependences of the release rate of the main products into the gas phase during decomposition and burning showed that the flame-retardants markedly influence these processes. It was found that the retardants used exhibit an acceleration of the polymer degradation and that the efficiency of inhibition in the gas phase depends on the atomic ratio antimony: bromine.
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  • 34
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    Fire and Materials 6 (1982), S. 65-67 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Estimates of the errors in light extinction measurements of smoke resulting from forward scattered light entering the detector and from the spectral width of the light source are presented. It is shown for specific examples that each of these effects can lead to an error of about 25% in typical applications. A potential method for calibrating extinction instruments is described.
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    Fire and Materials 6 (1982), S. 68-71 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The development, construction, and testing of a gas-fired radiant heat source for use as part of a fire test method is described. The unit has been shown capable of operation over extended periods at surface temperatures yielding radiance corresponding to that of a black body at 935 °C. This permits a 60% increase of specimen irradiance over that possible with a burner previously used, without modifying the specimen-burner configuration factor. One such application of this burner allows operation with specimen irradiance levels at 5 W cm-2 or for short periods at levels approaching 7 W cm-2 at higher temperatures. This performance is achieved while maintaining effective spatial separation between specimen and heat source. This assists in avoiding imposition of vitiated air near the surface of a burning specimen. Some performance data are provided on its behavior when supplied with natural gas. The unit can burn propane but only with a significant reduction of thermal output.
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  • 36
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    Fire and Materials 6 (1982), S. 76-79 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In making fire safety decisions the designer often finds that some input variables concerning his problems are chance variables. As detailed statistical data are rarely available the designer must rely largely on his expert judgment. With the application of the Delphi method such decisions can be optimized and formalized. The essence of the Delphi method is described and its use illustrated through an example related to the assessment of fire resistance requirements.
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    Fire and Materials 6 (1982), S. 72-75 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A study of the 1979 UK fire statistics and the Annual Report of the Office of Population Censuses and Surveys shows that only 1 death per 1000 is attributable to toxic gases from combustion. However, of the ‘deaths by violence’ it rises to 30 (3%). As 37% of all fires in occupied buildings were confined to the first item ignited and 53% to the area of origin it is postulated that such fires (and the consequent deaths) largely concerned substances which will burn on their own. From experience these are largely materials with limiting oxygen indices below 22 or 22-28 for restricted burning only. Those with limiting oxygen indices 〉28 cannot on their own sustain combustion. These considerations suggest the mode in which toxic gas tests should be conducted, i.e., horizontally or vertically and vertically only for the first two groups, respectively, and in the presence of a fire sustainer for the limiting oxygen index 〉28 group. Wood in the form of a wooden crib is suggested as suitable. To this end some experiments are described with PVC placed on top of a No. 5 crib (PSA). These latter show that, making the best assumption possible from the existing data, the wood contributes about 63% to the toxicity and the PVC 37%. On the large scale, other work has shown that wooden cribs alone will give lethal concentrations of carbon monoxide for significant periods. Thus difficult-to-burn substances need to evolve gases of exceptional toxicity for their contribution to be worth considering.
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  • 38
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    Fire and Materials 6 (1982), S. 80-95 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: NBS burned eleven mattresses made up with bedding in two different rooms, typical of a residential bedroom and a nursing home patient room, respectively. Seven of the mattresses flamed and burned vigorously, the other four were of a construction or so heavily flame-inhibited that they only smoldered. The burning behavior of the seven that flamed was modeled with the Harvard Mark V fire simulation. The experimental burn behavior for tests conducted in one room was well reproduced using only total weight of combustible, surface area and heat of combustion. Smoke production values were found to have little effect on the predicted behavior except for the smoke production itself. Fires in a second room, whose ventilation was intentionally restricted by the configuration of the adjoining space, could not be as well reproduced by the present, single-room fire model. During this study several changes were made to the simulation. The most significant change was the inclusion of mixing of the hot exiting fire gases with the cold incoming air. As a part of this, the inter-layer radiation exchange was reformulated to include the effect of smoke contamination of the lower layer. The reformulation of the radiation model has a marked effect on the predicted upper layer gas temperatures, generally improving the quality of the simulation.
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    Fire and Materials 6 (1982), S. 98-98 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 6 (1982) 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 6 (1982), S. 119-121 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Melamine orthophosphate crystals vary in shape and formula according to their method of production. The types vary widely in their behaviour when incorporated into an epoxy resin intumescent coating for trials in a small scale fire test. Heat treatment of melamine phosphate crystals at 210 °C, a process designed to reduce their solubility, profoundly affects the performance of any crystal type in a fire test. In such cases crystal shape alone appears to determine performance, whereas the shape, formula, and state of agglomeration affect performance in coatings produced with untreated melamine phosphate. Small plates of side 20 μm heat treated at 210 °C, are the preferred type for optimum performance and weathering characteristics.
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    Fire and Materials 6 (1982), S. 111-118 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A fire test device suitable for small-scale, comparative testing as a first step in investigating the performance of fire retardant materials is described. The procedure developed is not intended to predict the performance of a given material in a real fire, since the local conditions can be extremely variable. However, the parameters in the device can be varied over a wide range to screen the performance of various materials in given situation. Typical results for an intumescent mastic consisting of epoxy resin, hardener and melamine phosphate are quoted, together with appropriate calibration curves. A method of estimating the thermal resistance of the developing char is also discussed.
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    Fire and Materials 6 (1982), S. 122-126 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A study has been made of the effect of antimony and molybdenum oxides on the temperature-critical oxygen index relationship of halogenated polyester thermosets. The polyesters were prepared from maleic anhydride, phthalic anhydride and propylene glycol, using either tetrachlorophthalic anhydride, tetrabromophthalic anhydride or chlorendic anhydride as the halogen source. Marked differences were observed in the effect of the two oxides. The critical oxygen index values of the halogenated polyesters containing maoybdenum (VI)oxide decreased with increase in timperature, which is in accordance with what is normally found for organic polymers, with and without additives. In contrast to this, the critical oxygen index values of the formulations containing antimony(II)oxide increased with increased with increase in temperature to reach a maximum value at around 100-150 °C. These results indicate that antimony(II)oxide is a better flame retardant than molybdenum(VI)oxide, since not only is it superior at the primary ignition stage but it shows enhanced activity at the higher temperatures which would be experienced by polymeric material in the early stages of a fire. It is concluded that higher temperature critical oxygen index studies provide a better guide to the flame retardant activity of additives than do ambient critical oxygen index determinations alone.
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    Fire and Materials 7 (1983), S. 38-40 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 7 (1983), S. 132-149 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: To assess the utility of a laboratory test for smoke and fume emission from overheated materials, six materials were heated to 500°C in larger amounts in three locations in an air-conditioned aircraft fuselage on the ground. Smoke, acidic or alkaline gases and carbon monoxide were monitored. It was shown that the laboratory test results could be a basis for predicting the smoke- and fume-emission behaviour of materials subjected to overheating, e. g. in aircraft in flight.
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    Fire and Materials 7 (1983), S. 128-131 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Smoke toxicity test methods which determine only lethal toxicological potency under ‘worst case’ conditions do not satisfactorily address the critical issue of relative hazard, including time-to-escape and tenability limits resulting from the fire performance of materials under comparable conditions. Since threats to escape from a fire are largely time-dependent, toxic insults produced by burning materials should also be considered as rate processes. Assessment of time thresholds exhibited by burning materials under test conditions to effect performance impairment (incapacitation) of an animal model would appear to be more relevant than lethal toxicological potencies in estimating probability of successful escape from fires. A model is advanced in which intoxication rate thresholds for materials are obtained using a rodent exposure test method. Concentration-time curves, obtained from experimentally derived concentration-time-response surfaces, are the basis for estimating rate thresholds which are distinctively different for each material and which vary as a function of test conditions. it is this performance impairment response surface which is potentially a key to the modeling of toxic hazards of smoke in perspective with other hazards presented by fire.
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    Fire and Materials 7 (1983), S. 157-162 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The term ‘bed’ has a variety of meanings in different countries. In central Europe, ‘bed’ is used for a bedstead with a mattress, a duvet and a pillow, Following clear definitions of the components of a ‘bed’ the author considers methods for testing the burning characteristics of beds and reports on experiences with model beds in fire tests.
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    Fire and Materials 7 (1983), S. 150-156 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A device constructed and used to determine the flammability limits of pyrolysate-air mixtures as a function of percentage weight loss on pyrolysis has been employed to investigate the pyrolysate gases generated from poly (ethylene terephthalate) both in the presence and absence of chemical flame retardants. The chemicals tripropyl phosphate (TPP), dibromopropanol (DBP) and tris (2, 3 dibromopropyl) phosphate (TRIS) all influenced both the lower and upper flammability limits, with the largest effects being obtained when both phosphorus and bromine were present, followed by bromine only and then phosphorus only. The results indicate TPP has negligible condensed phase activity with only small gas phase action. DBP has no condensed phase activity but is a very active gas phase inhibitor. In contrast, TRIS has a detrimental effect upon the condensed phase reactions in that it is responsible for the formation of a more flammable pyrolysate gas mixture. Fortunately, its gas phase inhibition reaction is capable of reducing the overall flammability.
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    Fire and Materials 7 (1983), S. 180-184 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Flammability tests are difficult because of the complexity of burning processes and of safety considerations. Experimental fires only give a partial view of the combustion process. Owing to the dynamic processes occurring in the flame, tests are very sensitive to external influences. Use, therefore, of flammability test methods should be made only with a clear understanding of what is being tested. Only officially standardized and recognized test methods should be sued.
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    Fire and Materials 7 (1983), S. 173-179 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Polymeric Dielectrics are usually chemically complex, and it is attractive to establish techniques capable of providing a general assessment of material composition and thermal behaviour. Simultaneous thermal analysis (STA) is capable of providing such an assessment and complementing flammability studies. The use of STA in both of these roles is demonstrated for a number of polymer materials used in high-voltage cables. The materials investigated include various polyethylenes, ethylene-copolymers and filled polyvinylchloride formulations. Fingerprint identification of materials and the influence of chemical structure and additives on thermal behaviour is discussed. In particular the influence of antimony trioxide-chlorinated hydrocarbon flame retardants is examined. The application of STA information in guiding flammability studies is shown by example, and some potential routes for further development are also discussed.
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    Fire and Materials 7 (1983), S. 185-192 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Detailed quantitative studies are reported on the kinetics of acetonitrile pyrolysis using an isothermal quartz tubular flow reactor at 720-1033 K and 1 atm. Pressure using flow rates, in nitrogen, of 2-200 ml min-1. The pyrolysis of several other nitriles (acrylonitrile, propionitrile, methacrylonitrile and benzonitrile) has also been investigated qualitatively by pyrolysis-gas chromatography.
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    Fire and Materials 7 (1983), S. 193-201 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Fire retardants improve reaction to fire characteristics such as ignitability and flame propagation. This paper presents the toxicological results of tests performed on eleven pairs of untreated and treated materials, including woods, synthetic materials and textiles (both natural and synthetic). It is shown that the effects of fire retardants on toxicity results can be variable. In addition, the problem of the use of toxicity results is discussed more generally.
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    Fire and Materials 7 (1983), S. 210-215 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A Preliminary study of the thermal degradation of wool fabric was carried out under a wide range of oxidative degradation conditions including flaming combustion. Product collection methods and analysis conditions were designed to minimize secondary reactions. The degradation products obtained included a variety of organic nitriles and heterocyclic compounds as well as the usual aromatic and oxygenated products. Variations in moisture content and fire retardant level in the wool had little effect on the organic volatiles produced form the fabrics.
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    Fire and Materials 7 (1983), S. 202-209 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: There is widespread concern at present about the fire risk form the use of modern materials in upholstery and other domestic articles. One of the main characteristics of fires in dwellings which start with the ignition of textiles or furniture is that they have a high casualty rate compared with other kinds of domestic fires. Most of the casualties form such fires occur in fires which start in upholstery or bedding, often accidentally ignited by smokers' materials. Asphyxiations by smoke is the commonest cause of death in ‘textile’ and ‘upholstery’ fires. This paper presents relevant statistical information on fires in dwellings attended by local authority fire brigades which result from the ignition of upholstery, bedding, other textiles or furniture and the casualties which these fires cause.
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    Fire and Materials 7 (1983), S. 216-218 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 8 (1984) 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 8 (1984), S. 6-9 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 8 (1984), S. 1-5 
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    Notes: The application of the results of any fire toxicity test is extremely difficult because of the complexity of the problem and the limitations of the test. This paper will discuss the potential use of test data in the decision-making process.
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    Fire and Materials 8 (1984), S. 10-16 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: The mechanisms of incapacitation resulting from exposures to the thermal decomposition products of flexible and rigid polyurethane foams (PUF) were studied over a range of different temperatures under pyrolytic or non-flaming oxidative decomposition conditions. Individual cynomolgus monkeys were exposed to atmospheres increasing in separate experiments from very low concentrations until early physiological signs of incapacitation were detected. When flexible PUF was pyrolysed at 900°C and rigid PUF was oxidized at 600°C, clear atmospheres containing CO and HCN were produced and the signs of toxicity were very similar to those produced by HCN gas alone, consisting of an episode of hyperventilation followed by a semi-conscious state. Pyrolysis of flexible PUF at 600°C and 300°C produced a dense yellow smoke but no HCN. The signs, consisting of hyperventilation throughout exposure and dyspnoea afterwards, were consistent with pulmonary irritation, Since TDI monmer is not present at 6000 C it is concluded that some as-yet unidentified but highly irritant chemical species is present in smoke from flexible PUF.
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    Fire and Materials 8 (1984), S. 17-19 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Flame-retardant paints have been developed which can considerably upgrade the performance of combustible substrates in surface spread of flame test, but there is uncertainty as to their benefit in a real fire situation. This is partly owing to the lack of agreement on laboratory test methods and even of their value. Flame-retardant paints commercially available in the United Kingdom are of two types, the intumescent type and the antimony oxide type, and their mechanism of action is discussed.
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    Fire and Materials 8 (1984), S. 20-27 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The Swedisn box apparatus was modified to include an oxygen analysis of the exhaust gases to be compared with the conventional exhaust gas temperature measurement. A slow-burning material shows good correlation between the temperature measurement and the rate of heat release. A fast-burning material, however, consumes all the available oxygen, and the temperature measurement becomes a measure of only the thermal properties of the material.
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    Fire and Materials 8 (1984), S. 28-39 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A theoretical and experimental study of buoyant, axisymmetric, turbulent, diffusion flames is described. Measurements included profiles of mean velocity, mean temperature and mean concentrations of major species for flames having heat release rates of 1.67 and 8.51 kW. An integral model was developed and calibrated with both present and earlier measurements. Empirical constants account for flow entrainment and rates of fuel consumption. Overall, the integral model provided satisfactory predictions of bulk velocity, temperature and concentrations in both combusting and non-combusting plumes.
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    Fire and Materials 8 (1984), S. 40-48 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Progress in the field of theoretical prediction of fire resistance has been rapid in recent years. A procedure has been developed at the National Research Council of Canada for calculation of the fire resistance of structural members. The various steps in the construction of a mathematical model to calculate temperatures, deformations and strength are shown using as an example the calculation of the fire resistance of a cylindrical tubular steel column filled with concrete. A comparison of results calculated using the model with those of a fire test is also discussed.
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    Fire and Materials 8 (1984), S. 55-56 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 8 (1984), S. 49-53 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The Fire Precautions Act 1971, in contrast with previous legislation, is directed exclusively to the provision of fire precautions in buildings after occupation. The system of control is by fire certificate and can be applied to a class of premise (listed in Section 1) by means of a designating order. In the case of any particular use of premise, the Secretary of State, under Section 12, may by Regulation, make provision as to precautions which are to be taken in relation to the risk to persons in case of fire.
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    Fire and Materials 8 (1984), S. 54-55 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
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    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 8 (1984) 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 8 (1984), S. 64-68 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: More than 700 standardized rules for fire testing are used round the world in order to assess the fire safety of materials, products and constructions in different technical fields. This article discusses the reasons for this variety of test methods and evaluation systems and the attempts to create systematic models in this special field of material testing, including new suggestions and developments in ISO and CIB for future approaches.
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    Fire and Materials 8 (1984), S. 57-63 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Laboratory tests have been developed that evaluate realistically the protective performance of clothing materials and garments. Test conditions are chosen to stress the high temperature resistance of materials in the same manner as in an industrial flash fire exposure. A second degree burn in human tissue is used as the criteria to ate performance of materials. Test results have been correlated between the small-scale lab swatch test and a full-scale instrumented manikin garment test, and these results related to industrial experience. The TPP lab test has been found useful in evaluating the performance of candidate materials as replacement for existing materials with known acceptable protective performance. It can be used to specify the level of protection needed in a garment when the intensity of the exposure hazard is known. Also, the test is especially useful for developing new materials and selecting candidates for additional field testing.
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    Fire and Materials 8 (1984), S. 77-80 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Normalized heart load, obtained by dividing heat absorption by thermal inertia, is a quantity useful in building design for relating fire severity in fully developed compartment fires to fire severity in standard fire resistance tests. Harmathy has shown how normalized heat load may be used for determining required fire resistance in projected buildings. The present work describes how effective values of thermal inertia can be calculated for such important materials as brick and concrete, both normal and lightweight, for which thermal properties depend strongly upon temperature.
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    Fire and Materials 8 (1984), S. 69-76 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Some examples of the application of fire tests to hazard and risk assessment and some of the problems to be encountered are described. Reference is made to theoretical studies designed to show how to obtain basic data on material properties from ignitability and flame spread tests, and recent correlations of the rate of heat release required to cause flashover are presented. Progress in predicting fire growth from theory for certain idealized conditions will increasingly condition the choice of which processes shall be the subject of tests.
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    Fire and Materials 8 (1984) 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 75
    ISSN: 0308-0501
    Keywords: Combustion of plastics ; combustion properties ; fire tests ; heat of combustion ; ignitability ; oxygen consumption ; rate of heat release ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A new bench-scale rate of heat release calorimeter utilizing the oxygen consumption principle has been developed for use in fire testing and research. Specimens may be of uniform or composite construction and may be tested in a horizontal, face-up orientation, or, for those which do not melt, in a vertical orientation. An external irradiance of zero to over 100 kW m-2 may be imposed by means of a temperature-controlled radiant heater. The rate of heat release is determined by measuring combustion product gas flow and oxygen depletion, while the mass loss is also recorded simultaneously. The instrument has been designed to be capable of higher accuracy than existing instruments and yet to be simple to operate and moderate in construction cost. The instrument is thermed a ‘cone calorimeter’ because of the geometric arrangement of the electric heater.
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    Fire and Materials 8 (1984), S. 96-104 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: ‘Normalized heat load’ is a quantifier of the destructive potential of fires, real-world compartment fires and test fires alike. For real-world fires it is subject to some uncertainties owing to the random nature of two of the variables it depends on: ventilation and fire load. For test fires also it is subject to uncertainties owing to a moderate degree of randomness that characterizes the results of test fires. A procedure is described for predicting the failure probability in fire of the boundaries of a compartment designed for fire resistance on the basis of information concerning the characteristics of the compartment and the design value of the fire load. The procedure is essentially deterministic, employing statistical considerations only as far as required by the nature of some of the input variables. With the aid of second-moment analysis, it is possible, furthermore, to design the compartment boundaries for appropriate target failure probabilities.
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    Fire and Materials 8 (1984), S. 105-111 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An interactive computer program for simulating the early fire growth in an enclosure is described. The enclosure is assumed to be divided into distinct homogeneous zones. The rate of heat release is defined for the fire and the conservation equations are solved for the zones, yielding the temperature and radiant heat conditions in the fire room. The purpose of the work was to develop a computer program to be used by people working with fire engineering applications and having little experience in computer calculations. The user converses with the program via a terminal connected to the computer. The dialogue is governed by commands adapted to the concepts of the user. Results of the computer model are compared with measured data of the burning of wood and plastic cribs in an enclosure, showing a good agreement between measured and calculated results.
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    Fire and Materials 8 (1984), S. 113-124 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The general nature of fire problems on energy-conservative passenger trains is described, including a description of vehicle structures and lightweight design. Effects of high energy demand, tunnels and high maximum speeds on fire safety are outlined. The considerations used in design analysis are described, beginning with the development of a ‘worst-case fire scenario’. Typical combustible materials are considered and some of the reasons for choices are given. Notes on cavity and chimney effects emphasize the importance of clear objectives. Structural fire resistance is examined, and the basis of conventional recommendations analysed. The application of British Standard 6336 guidelines on fire tests and hazard assessment is examined. Limitation of fire load density is described, and some problems of calorific value determination outlined. Sources of ignition and hazards from passengers are defined. Flammability and flame-spread control are discussed, and rate of heat release is referred to in the context of fire behaviour. Problems of passenger escape linked to flashover, smoke and combustion gases are dealt with briefly.
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    Fire and Materials 8 (1984), S. 137-147 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Measurements of the limits of flaming and smoldering combustion and relative rates of burning under elevated temperatures and oxygen-depleted conditions have been used to characterize the fire behaviour of polymeric materials using a semi-empicical approach (based on scientific theory) in terms of Power Law Indices. The work was based on modified current tests; namely the Limiting Oxygen Index (ASTM D2863) at elevated temperatures and the Setchkin Flash and Self-Ignition Test (ASTM D1929) modified to operate in oxygen-depleted atmospheres and to record rate of weight loss. Results show that the relative flammability and rate of burning of materials can change markedly with fire environment, and confirms the need to test materials lunder conditions representative of those of the anticipated end-use hazard.
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    Fire and Materials 8 (1984), S. 224-226 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The vague meaning of the word ‘burning’ has long created communication difficulties among fire scientists, and has to unwarranted conclusions. It is suggested that the word ‘burning’ be used as an umbrella term, covering up to three dissimilar types of reactions: pyrolysis or gasification, (gas-phase) combustion, and char-oxidation.
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    Fire and Materials 8 (1984), S. 206-216 
    ISSN: 0308-0501
    Keywords: building materials ; fire tests ; heat release rate ; oxygen consumption ; spectral energy distribution ; weight measurement ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Equipment has been developed for measuring the rate of heat release from building materials in an open test arrangement. The method is based on an oxygen consumption technique. A vertical sample is placed under an open hood in which the combustion gases and a certain amount of air are collected. The decrease in oxygen concentration and the mass flow of the gases are measured in the exhaust duct. The rate of heat release is then calculated. The equipment has been calibrated with good agreement between input and measured effects. The total response time for the system is 10s. The method has been used for testing building materials at radiation intensities up to 5W Cm-2. It is able to distinguish between different board materials, and the repeatability is good, The paper describes the equipment, including the weighing of a burning sample and the selection of test condition. Smoke and gas analysis can be added when desirable. Some test results with building materials are also presented.
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    Fire and Materials 15 (1991), S. 47-49 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 15 (1991), S. 43-46 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Three small-scale flammability tests were evaluated for potential use in quality control. The small-scale flame test produced excessive scatter of data, the hot-plate ignition test gave reasonably reproducible data, but the critical oxygen index yielded superior results and is recommended for quality control testing.
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    Fire and Materials 15 (1991), S. 37-42 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The fire-retardant effectiveness of mixtures of hexabromocyclododecane (HBCD) and artimony oxide (Sb2O3) in polyethylene (PE) was examined utilizing differential thermal analysis (DTA), gas chromatography/mass spectroscopy (GC/MS) and limited oxygen index (LOI) techniques. It was determined that the normal practice of mixing Sb2O3 with HBCD induced a synergistic chemical reaction at 250°C whose main product, SbBr3, was responsible for enhanced fire retardancy. The mixing of SbBr3 directly into the PE produces a superior fire-retardant polyethylene.
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    Fire and Materials 15 (1991) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 15 (1991), S. 51-51 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 15 (1991), S. 65-84 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An evaluation of the cone calorimeter by the Association of Plastic Manufacturers in Europe (APME) involved testing of 25 plastic materials together with two natural polymers. Specimen preparation is identified as having an important influence on the results, especially for certain types of material. Ignition time, rate of heat release (RHR) and smoke results are presented to show the influence of external heat flux. The dynamic smoke results (which should be measured from the time of exposure) are only relevant to well-ventilated fires unless the cone calorimeter is specially modified. For a complete evaluation a cumulative smoke measurement may be needed in addition. Although the cone calorimeter is a valuable research tool, and may be used frequently in industry, it needs to be made more robust and user friendly to avoid excessive downtime and to reduce calibration time. If the instrument is to be used for routine development and quality assurance, only one or two heat flux levels should be selected. These could represent a developing and a developed fire and should depend on the product application.
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    Fire and Materials 15 (1991), S. 93-96 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Combustible dusts, based on tests conducted in the Setchkin Furnace on five representative dusts, are shown to have two distinct layer minimum ignition temperatures, designated MITnon-flaming and MITflaming. The MITnon-flaming is the one usually reported in the literature; the MITflaming is determined by starting at a much higher temperature and working downwards. MITflaming can yield a different ranking of dust flammability than MITnon-flaming. The MITflaming appears to be more closely correlated to the MIT of dust clouds and to the test prescribed for flammable solids in the US Code of Federal Regulations than the MITnon-flaming.
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    Fire and Materials 15 (1991), S. 127-130 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The flammability and ignitability of polyethylene using antimony trihalide compounds as fire retardants was evaluated by standard methods to determine retardant effectiveness. Compared with other retardants, the antimony trihalide compounds, antimony tribromide and antimony trichloride, substantially reduced both the flammability and the ignitability of the polyethylene. The influence of retardant concentration, heat flux and type of polyethylene was also studied.
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    Fire and Materials 15 (1991), S. 117-125 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A study of the behaviour of aluminium building products in bushfires was carried out to test the validity of assertions that they perform poorly under bushfire conditions. The work was conducted in two parts: an examination of data from bushfire damage surveys and laboratory experiments in which window assemblies were exposed to radiant heat from a furnace. Data from surveys conducted after major bushfires were augmented with information from a questionnaire related specifically to this work. Analysis of these data did not provide any support for the belief that houses incorporating aluminium building products are at greater risk of being destroyed. The laboratory experiments on both timber- and aluminium-framed windows showed their performance under simulated bushfire conditions to be similar. It was found that bending of glass through distortion of the frames was not a factor in crack initiation.
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    Fire and Materials 15 (1991), S. 105-115 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A study of the fire behaviour of polypropylene plastics trays being considered for letter handling has been carried out. Various ignition sources and configurations of trays (both empty and filled with letters) were examined. In particular, stacks of trays contained in large steel-mesh unit load devices (ULDs), protected by automatic sprinklers, were ignited and the progress of the fires, release of heat and smoke, and sprinkler activation recorded. It was found that, when examined singly or in stacks in scenarios which might be encountered in sorting areas and post offices, the trays made from fire-retardant plastics were more difficult to ignite and took longer to become involved in fire than those made from standard grade plastics. The benefits of this slower build-up fire with the retarded plastics formulation were reduced to some extent by the greater amounts of smoke released by the burning of the retarded plastics. For stacks of ULDs filled with trays, typical of a scenario in a mail exchange, the fire-retardant plastics gave significant benefits in terms of life safety and fire damage to the trays and mail.
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    Fire and Materials 15 (1991), S. 131-136 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Until the 1960s ASTM E136 and CAN/ULC-S114 test methods were adequate for determination of non-combustibility in materials being used to construct most buildings. However, since then there has been a very large increase in the use of products that are considered safe for construction of buildings required to be noncombustible but which are classified as combustible by these simple pass/fail tests. Therefore, Forintek Canada Corp. have developed an approach to define the combustibility of these new materials, based upon their release of heat when tested using the ASTM E1354 cone calorimeter.
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    Fire and Materials 15 (1991), S. 147-147 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 15 (1991), S. 149-149 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 15 (1991), S. 137-143 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper describes a comprehensive experimental investigation of the fire performance of nailed gusset connections between large glue-laminated timber members. Both plywood and steel gusset plates were investigated with a range of loaded and unloaded test methods. The principal conclusions are that unprotected gussets have poor fire performance, but that a layer of solid wood or gypsum plasterboard will provide at least one hour of fire protection to typical joints.
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    Fire and Materials 15 (1991), S. 145-146 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The thermal behaviour of cellulose obtained from both the pith and rind of papyrus was studied and the flammability properties of paper produced from papyrus and other papers were measured. The use of flame retardants did not significantly alter the flammability properties of the papyrus paper.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 97
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 16 (1992), S. 29-35 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The post-cooling properties of reinforced concrete constituents are of great relevance in the assessment of a structure for re-use after fire. The expansive rehydration of dissociated calcium hydroxide on post-cooling exposure to air can cause a total loss in strength if cement paste specimens are heated to and maintained at 400°C or above. The use of cement replacement agents can mitigate this effect. The strength and ductility of hot-rolled mild steel and cold twisted steel on gradual cooling or quenching from various temperatures can be correlated with microstructural phenomena. There is a significant increase in strength and loss of ductility when both types of steel are quenched from temperatures above 723°C. Some practical implications of these properties are described, using examples of fire-damaged structures.
    Additional Material: 7 Ill.
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  • 98
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 16 (1992), S. 159-167 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An investigation has been carried out of the limiting oxygen index (LOI) test. A review of the literature shows that, although there is abundant information on the test, it is not clear that its results correlate well with those of any other test, or indeed with those of real fires. Theoretical considerations indicate that the test could be improved by using it with bottom ignition rather than with the standard top ignition. A number of materials were tested in the cone calorimeter and in the LOI, and various correlations were attempted. In general, correlations between some of the cone calorimeter properties measured and the inverse of the LOI made sense. These correlations were not, however, sufficiently sensitive, even when investigating small effects on a single base polymer system, to justify using the LOI as a proxy for the cone in any way. The LOI is likely to continue to be used extensively. This work suggests that quality control and, possibly, mechanistic or other flame-retardant additive studies, are its only applications where the results can be justified.
    Additional Material: 9 Ill.
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  • 99
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 16 (1992), S. 181-186 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The authors have conducted a laboratory-scale gallery fire test on eight different samples of electric cable in a horizontal airflow. The number of speciments and the distances between them on the trestle were varied for each test. As a result, it was found that both ignitability and flame-propagation properties depended on the distance between the specimens as well as on their number. Such flammability properties obtained for each cable sample were also found to be considerably consistent with the critical oxygen index. In addition, it is proposed that the flammability should be classified largely into five categories in this laboratory-scale gallery fire test for fire-retardance evaluation of solid combustible materials such as electric cables.
    Additional Material: 8 Ill.
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  • 100
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 16 (1992), S. 187-196 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Wood fiberboard-based, cellulose ceiling tiles have been used for many years. While various fire-retardant technologies have been developed to reduce the surface flammability of these products to acceptable levels, questions of their suitability for use due to their intrinsic fuel value and the impact of attachment methods used on fire performance have been raised from time to time. This paper reviews the history of these products from a fire-performance perspective and presents materials property data on surface flamespread, thermal conductivity and ignition phenomena. In addition, large-scale room fire test results are presented including compartment tests conducted on a variety of assemblies (including those installed with mastic construction adhesives) according to ASTM E 603 - Standard Guide for Room Fire Experiments.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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