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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 16 (1992), S. 159-167 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An investigation has been carried out of the limiting oxygen index (LOI) test. A review of the literature shows that, although there is abundant information on the test, it is not clear that its results correlate well with those of any other test, or indeed with those of real fires. Theoretical considerations indicate that the test could be improved by using it with bottom ignition rather than with the standard top ignition. A number of materials were tested in the cone calorimeter and in the LOI, and various correlations were attempted. In general, correlations between some of the cone calorimeter properties measured and the inverse of the LOI made sense. These correlations were not, however, sufficiently sensitive, even when investigating small effects on a single base polymer system, to justify using the LOI as a proxy for the cone in any way. The LOI is likely to continue to be used extensively. This work suggests that quality control and, possibly, mechanistic or other flame-retardant additive studies, are its only applications where the results can be justified.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 18 (1994), S. 1-7 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Phospham is an iminophosphazene polymer of unusually high thermal stability. We have found that phospham imparts a substantial level of flame retardancy to nylon-4,6, a high-melting crystalline engineering thermoplastic. It did not appear to produce degradation of the polyamide in the processing temperature range. The flame retardant efficacy of phospham in nylon-4,6 was similar to that of stabilized red phosphorus, when compared on an equal phosphorus basis. In nylon-4,6, it did not display nitrogen-phosphorus synergism. Limited evidence from TGA suggested a condensed phase mode of action in nylon-4,6. Phospham showed orders-of-magnitude better hydrolytic stability than did ammonium polyphosphate, and did not produce detectable phosphine on processing as did red phosphorus.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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