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  • 1
    Keywords: Earth sciences ; Natural disasters ; Engineering geology ; Engineering ; Geology ; Foundations ; Hydraulics ; Sustainable development ; Earth Sciences ; Natural Hazards ; Geoengineering, Foundations, Hydraulics ; Sustainable Development
    Description / Table of Contents: ISDR-ICL Sendai Partnerships 2015-2025 --- The ISDR-ICL Sendai Partnerships 2015-2025: Background and Content --- Forum lectures --- Rupestrian world heritage sites: Instability investigation and sustainable mitigation --- Subaerial landslide-generated waves: Numerical and laboratory simulations --- Rockfall occurrence and fragmentation --- Contribution from signatory organizations of the Sendai Partnerships --- International Consortium on Landslides (ICL) --- International Consortium on Landslides (ICL) - The proposing organization of the ISDR-ICL Sendai partnerships 2015-2025 --- United Nations Office for Disaster Risk Reduction (UNISDR) --- UNISDR‘s Contribution to Science and Technology for Disaster Risk Reduction and the Role of the International Consortium on Landslides (ICL) --- United Nations Educational, Scientific and Cultural Organization (UNESCO) --- UNESCO’s Contribution to the Implementation of UNISDR’s Global Initiative and ICL --- United Nations University (UNU) --- The United Nations University: Research and Policy Support for Environmental Risk Reduction --- World Meteorological Organization (WMO) --- Concerted International Efforts for Advancing Multi-Hazard Early Warning Systems --- International Council for Science (ICSU) --- On Future Challenges for the Integration of Science into International Policy Development for Landslide Disaster Risk Reduction --- World Federation of Engineering Organizations (WFEO) --- World Federation of Engineering Organizations Activities in Disaster Risk Reduction --- Disaster Prevention Research Institute (DPRI), Kyoto University --- National Civil Protection Department, Italian Presidency of the Council of Ministers, Government of Italy --- Understanding and Reducing Landslide Disaster Risk: Challenges and Opportunities for Italian Civil Protection --- Landslide Dynamics: ISDR-ICL Landslide Interactive Teaching Tools (LITT) --- Progress of the World Report on Landslides --- International Programme on Landslides (IPL): Objectives, History and List of World Centres of Excellence and IPL Projects --- UNESCO-KU-ICL UNITWIN Cooperation Programme for Landslides and Water-Related Disaster Risk Management. Landslides: Journal of the International Consortium on Landslides --- IPL Activities --- Advanced Technologies for Landslides (WCoE 2014-2017, IPL-196, IPL-198) --- Mechanisms of Landslides and Creep in Over-Consolidated Clays and Flysch (WCoE 2014-2017 --- Research on Heavy-Rainfall-Induced and Hydraulic-Driven Geological Hazards in China (WCoE 2014-2017). Landslide Risk Reduction in Croatia: Scientific research in the framework of the WCoE 2014-2017, IPL-173, IPL-184, ICL ABN --- Shapes and Mechanisms of Large-scale Landslides in Japan: Forecasting Analysis from an Inventory (WCoE 2014–2017 --- Retrospective and Prospects for Cold Regions Landslide Research (2012-2016) (WCoE 2014-2017, IPL-132, IPL-167, IPL-203, CRLN --- Large-scale Rockslide Inventories: from the Kokomeren River Basin to the Entire Central Asia Region (WCoE 2014-2017, IPL-106-2) --- Interventions for Promoting Knowledge, Innovations and Landslide Risk Management Practices within South and Southeast Asia (WCoE 2014-2017) --- Promoting a Global Standard for Community-based Landslide Early Warning Systems (WCoE 2014-2017, IPL-158, IPL-165) --- Model Policy Frameworks, Standards and Guidelines on Landslide Disaster Reduction (WCoE 2014-2017) --- Landslide Hazard and Risk Management (WCoE 2014-2017) --- Mitigation of Landslide Hazards in Ukraine under the Guidance of ICL: 2009–2016 (IPL-153, IPL-191) --- Development of a Hazard Evaluation Technique for Earthquake-Induced Landslides Based on an Analytic Hierarchy Process (AHP) (IPL-154) --- The Croatian-Japanese SATREPS Joint Research Project on Landslides (IPL-161)
    Pages: Online-Ressource (XXVI, 586 pages) , 372 illustrations, 350 illustrations in color
    ISBN: 9783319594699
    Language: English
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  • 2
    Unknown
    Berlin, Heidelberg : Springer Vieweg
    Keywords: Engineering ; Humanities ; Digital libraries ; Educational technology ; Electrical engineering ; Engineering ; Communications Engineering, Networks ; Digital Humanities ; Technology and Digital Education
    Description / Table of Contents: Vorwort --- Einleitung --- Bürger --- Wenn Bots sich unter Leute mischen: Social Bots in den Sozialen Medien --- Digitale Partizipation in Wissenschaft und Wirtschaft --- Entwicklung einer soziodigitalen Souveränität --- Unternehmen --- Digitale Souveränität – ein mehrdimensionales Handlungskonzept für die deutsche Wirtschaft --- Privatheit und digitale Souveränität in der Arbeitswelt 4.0 --- Staat --- Mehr Daten, weniger Vertrauen in Statistik – freie Fahrt für ‚alternative Fakten‘? --- Internationale Perspektiven auf digitale Souveränität --- Digitalisierung der Bildung als staatliche Aufgabe --- Ausblick
    Pages: Online-Ressource (IX, 187 Seiten) , 40 Abbildungen in Farbe
    ISBN: 9783662557969
    Language: German
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  • 3
    Unknown
    Berlin, Heidelberg : Springer Vieweg
    Keywords: Engineering ; Robotics ; Automation ; Industrial engineering ; Production engineering ; Engineering economics ; Engineering economy ; Manufacturing industries ; Machines ; Tools ; Engineering ; Industrial and Production Engineering ; Robotics and Automation ; Engineering Economics, Organization, Logistics, Marketing ; Manufacturing, Machines, Tools ; Information Systems Applications (incl. Internet)
    Description / Table of Contents: Einordnung und Hintergründe --- Positionen der Sozialpartner --- Erfahrungen und Herausforderungen in der Industrie --- Forschungsfragen und Entwicklungsstrategien --- Ausblick
    Pages: Online-Ressource (VIII, 167 Seiten) , 38 Abbildungen
    ISBN: 9783662459157
    Language: German
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  • 4
    Unknown
    Berlin, Heidelberg : Springer Vieweg
    Keywords: Engineering ; Humanities ; Digital libraries ; Computers ; Educational technology ; Electrical engineering ; Engineering ; Communications Engineering, Networks ; Information Systems and Communication Service ; Digital Humanities ; Technology and Digital Education
    Description / Table of Contents: Seit Jahren wird unser Alltag geprägt von zunehmender Automation und Vernetzung, die Digitalisierung genannt wird. Sensoren erfassen immer mehr unterschiedliche Daten und werden von intelligenten Algorithmen zunehmend präzisier analysiert. Dies führt nicht nur zu einem anderen Verhältnis im Umgang und bei der Nutzung von Daten durch Menschen und Maschinen, sondern wird auch dramatisch Aufgaben und Prozesse verändern. Die damit verbundenen Arbeitsanforderungen werden zum massiven Wandel von Berufsbildern führen, in dem einfache Tätigkeiten automatisiert und komplexe Tätigkeiten vereinfacht werden. Nicht nur das Arbeiten sondern auch das Lernen, Lehren und Forschen verändert sich durch die Digitalisierung. Die technischen Möglichkeiten wandeln die Lebenswelten mit ihren urbanen Versorgungs- und Infrastrukturen und eröffnen den Wirtschaftsräumen neue Geschäftsmodelle. Diese parallel einsetzenden Entwicklungen führen zu radikalen Umbrüchen, die in den kommenden Jahren sämtliche Aspekte der Gesellschaft verändern werden
    Pages: Online-Ressource (IX, 199 Seiten)
    ISBN: 9783662528549
    Language: German
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  • 5
    Keywords: Engineering ; Commercial law ; Automotive engineering ; Robotics ; Automation ; Community psychology ; Environmental psychology ; Engineering ; Automotive Engineering ; Robotics and Automation ; Community and Environmental Psychology ; Commercial Law
    Description / Table of Contents: Teil I Human and Machine --- Teil II Mobilität --- Teil III Verkehr --- Teil IV Sicherheit --- Teil V Recht und Haftung --- Teil VI Akzeptanz
    Pages: Online-Ressource (XIV, 732 Seiten)
    ISBN: 9783662458549
    Language: German
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  • 6
    Unknown
    Berlin, Heidelberg : Springer Vieweg
    Keywords: Engineering ; Humanities ; Digital libraries ; Educational technology ; Electrical engineering ; Engineering ; Communications Engineering, Networks ; Digital Humanities ; Technology and Digital Education
    Description / Table of Contents: Vorwort --- Einleitung --- Bürger --- Wenn Bots sich unter Leute mischen: Social Bots in den Sozialen Medien --- Digitale Partizipation in Wissenschaft und Wirtschaft --- Entwicklung einer soziodigitalen Souveränität --- Unternehmen --- Digitale Souveränität – ein mehrdimensionales Handlungskonzept für die deutsche Wirtschaft --- Privatheit und digitale Souveränität in der Arbeitswelt 4.0 --- Staat --- Mehr Daten, weniger Vertrauen in Statistik – freie Fahrt für ‚alternative Fakten‘? --- Internationale Perspektiven auf digitale Souveränität --- Digitalisierung der Bildung als staatliche Aufgabe --- Ausblick
    Pages: Online-Ressource (IX, 187 Seiten) , 40 Abbildungen in Farbe
    ISBN: 9783662557969
    Language: German
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  • 7
    Unknown
    Berlin, Heidelberg : Springer Vieweg
    Keywords: Engineering ; Robotics ; Automation ; Industrial engineering ; Production engineering ; Economic sociology ; Engineering ; Industrial and Production Engineering ; Organizational Studies, Economic Sociology ; Robotics and Automation
    Description / Table of Contents: Einleitung --- Prognostizierte Veränderungen der gestaltbaren Arbeitssystemdimensionen --- Systeme zur Assistenz und Effizienzsteigerung in manuellen Produktionsprozessen der Industrie auf Basis von Projektion und Tiefendatenerkennung --- Betriebliche Auswirkungen industrieller Servicerobotik am Beispiel der Kleinteilemontage --- Erweiterte Horizonte – Ein technischer Blick in die Zukunft der Arbeit --- Soziotechnische Assistenzsysteme für die Produktionsarbeit in der Textilbranche --- Lernförderliche Arbeitssysteme für die Arbeitswelt von morgen --- Assistenz und Wissensvermittlung am Beispiel von Montage- und Instandhaltungstätigkeiten --- Der Mensch in Interaktion mit autonomen Planungs- und Steuerungssystemen für Cyber-Physische Produktionssysteme --- ReApp – Wiederverwendbare Roboterapplikationen für flexible Roboteranlagen - Auswirkungen der Ergebnisse aus ReApp auf betriebliche Funktionen am Beispiel eines Anwendungsfalls in der Elektroindustrie --- Modellierungsansatz für ein arbeitsplatznahes Beschreibungsmodell der »Arbeitswelt Industrie 4.0 --- Die Zukunft der Arbeit im demografischen Wandel --- “Social Manufacturing and Logistics“ – Arbeit in der digitalisierten Produktion --- Lernförderliche Arbeitsorganisation in der Industrie 4.0 --- Decision Support Pipelines – Durchgängige Datenverarbeitungsinfrastrukturen für die Entscheidungen von morgen --- Gerechtigkeit in flexiblen Arbeits- und Managementprozessen --- Technologie, Organisation, Qualifikation
    Pages: Online-Ressource (XI, 246 Seiten) , 62 Abbildungen, 56 Abbildungen in Farbe
    ISBN: 9783662492666
    Language: German
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  • 8
    Unknown
    Berlin, Heidelberg : Springer Vieweg
    Keywords: Engineering ; Humanities ; Digital libraries ; Computers ; Educational technology ; Electrical engineering ; Engineering ; Communications Engineering, Networks ; Information Systems and Communication Service ; Digital Humanities ; Technology and Digital Education
    Description / Table of Contents: Seit Jahren wird unser Alltag geprägt von zunehmender Automation und Vernetzung, die Digitalisierung genannt wird. Sensoren erfassen immer mehr unterschiedliche Daten und werden von intelligenten Algorithmen zunehmend präzisier analysiert. Dies führt nicht nur zu einem anderen Verhältnis im Umgang und bei der Nutzung von Daten durch Menschen und Maschinen, sondern wird auch dramatisch Aufgaben und Prozesse verändern. Die damit verbundenen Arbeitsanforderungen werden zum massiven Wandel von Berufsbildern führen, in dem einfache Tätigkeiten automatisiert und komplexe Tätigkeiten vereinfacht werden. Nicht nur das Arbeiten sondern auch das Lernen, Lehren und Forschen verändert sich durch die Digitalisierung. Die technischen Möglichkeiten wandeln die Lebenswelten mit ihren urbanen Versorgungs- und Infrastrukturen und eröffnen den Wirtschaftsräumen neue Geschäftsmodelle. Diese parallel einsetzenden Entwicklungen führen zu radikalen Umbrüchen, die in den kommenden Jahren sämtliche Aspekte der Gesellschaft verändern werden
    Pages: Online-Ressource (IX, 199 Seiten)
    ISBN: 9783662528549
    Language: German
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  • 9
    Keywords: Earth sciences ; Natural disasters ; Engineering geology ; Engineering ; Geology ; Foundations ; Hydraulics ; Sustainable development ; Earth Sciences ; Natural Hazards ; Geoengineering, Foundations, Hydraulics ; Sustainable Development
    Description / Table of Contents: ISDR-ICL Sendai Partnerships 2015-2025 --- The ISDR-ICL Sendai Partnerships 2015-2025: Background and Content --- Forum lectures --- Rupestrian world heritage sites: Instability investigation and sustainable mitigation --- Subaerial landslide-generated waves: Numerical and laboratory simulations --- Rockfall occurrence and fragmentation --- Contribution from signatory organizations of the Sendai Partnerships --- International Consortium on Landslides (ICL) --- International Consortium on Landslides (ICL) - The proposing organization of the ISDR-ICL Sendai partnerships 2015-2025 --- United Nations Office for Disaster Risk Reduction (UNISDR) --- UNISDR‘s Contribution to Science and Technology for Disaster Risk Reduction and the Role of the International Consortium on Landslides (ICL) --- United Nations Educational, Scientific and Cultural Organization (UNESCO) --- UNESCO’s Contribution to the Implementation of UNISDR’s Global Initiative and ICL --- United Nations University (UNU) --- The United Nations University: Research and Policy Support for Environmental Risk Reduction --- World Meteorological Organization (WMO) --- Concerted International Efforts for Advancing Multi-Hazard Early Warning Systems --- International Council for Science (ICSU) --- On Future Challenges for the Integration of Science into International Policy Development for Landslide Disaster Risk Reduction --- World Federation of Engineering Organizations (WFEO) --- World Federation of Engineering Organizations Activities in Disaster Risk Reduction --- Disaster Prevention Research Institute (DPRI), Kyoto University --- National Civil Protection Department, Italian Presidency of the Council of Ministers, Government of Italy --- Understanding and Reducing Landslide Disaster Risk: Challenges and Opportunities for Italian Civil Protection --- Landslide Dynamics: ISDR-ICL Landslide Interactive Teaching Tools (LITT) --- Progress of the World Report on Landslides --- International Programme on Landslides (IPL): Objectives, History and List of World Centres of Excellence and IPL Projects --- UNESCO-KU-ICL UNITWIN Cooperation Programme for Landslides and Water-Related Disaster Risk Management. Landslides: Journal of the International Consortium on Landslides --- IPL Activities --- Advanced Technologies for Landslides (WCoE 2014-2017, IPL-196, IPL-198) --- Mechanisms of Landslides and Creep in Over-Consolidated Clays and Flysch (WCoE 2014-2017 --- Research on Heavy-Rainfall-Induced and Hydraulic-Driven Geological Hazards in China (WCoE 2014-2017). Landslide Risk Reduction in Croatia: Scientific research in the framework of the WCoE 2014-2017, IPL-173, IPL-184, ICL ABN --- Shapes and Mechanisms of Large-scale Landslides in Japan: Forecasting Analysis from an Inventory (WCoE 2014–2017 --- Retrospective and Prospects for Cold Regions Landslide Research (2012-2016) (WCoE 2014-2017, IPL-132, IPL-167, IPL-203, CRLN --- Large-scale Rockslide Inventories: from the Kokomeren River Basin to the Entire Central Asia Region (WCoE 2014-2017, IPL-106-2) --- Interventions for Promoting Knowledge, Innovations and Landslide Risk Management Practices within South and Southeast Asia (WCoE 2014-2017) --- Promoting a Global Standard for Community-based Landslide Early Warning Systems (WCoE 2014-2017, IPL-158, IPL-165) --- Model Policy Frameworks, Standards and Guidelines on Landslide Disaster Reduction (WCoE 2014-2017) --- Landslide Hazard and Risk Management (WCoE 2014-2017) --- Mitigation of Landslide Hazards in Ukraine under the Guidance of ICL: 2009–2016 (IPL-153, IPL-191) --- Development of a Hazard Evaluation Technique for Earthquake-Induced Landslides Based on an Analytic Hierarchy Process (AHP) (IPL-154) --- The Croatian-Japanese SATREPS Joint Research Project on Landslides (IPL-161)
    Pages: Online-Ressource (XXVI, 586 pages) , 372 illustrations, 350 illustrations in color
    ISBN: 9783319594699
    Language: English
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  • 10
    Keywords: Engineering ; Computer simulation ; Economic theory ; Data-driven Science, Modeling and Theory Building ; Complexity ; Simulation and Modeling ; Applications of Graph Theory and Complex Networks ; Economic Theory/Quantitative Economics/Mathematical Methods
    Description / Table of Contents: Chapter 1 Financial Market --- Influence Networks in the Foreign Exchange Market --- Entropy and Transfer Entropy: The Dow Jones and the build up to the 1997 Asian Crisis --- Execution and Cancellation Lifetimes in Foreign Currency Market --- Signs of market orders and human dynamics --- Damped oscillatory behaviors in the ratios of stock market indices --- Exploring Market Making Strategy for High Frequency Trading: an Agent-based Approach --- Effect of Cancel Order on Simple Stochastic Order-Book Model --- Chapter 2 Robustness and Fragility --- Cascading failures in interdependent economic networks --- Do connections make systems robust?: a new scenario for the complexity-stability relation --- Simulation of Gross Domestic Product in International Trade Networks: Linear Gravity Transportation Model --- Analysis of Network Robustness for a Japanese Business Relation Network by Percolation Simulation.- Detectability threshold of the spectral method for graph partitioning.- Spread of Infectious Diseases with a Latent Period.-Chapter 3 Interaction and Distribution --- Geographic Dependency of Population Distribution- Spatiotemporal Analysis of Influenza Epidemics in Japan --- A Universal Lifetime Distribution for Multi-Species Systems --- Firm Age Distributions and the Decay Rate of Firm Activities --- Empirical Analysis of Firm-Dynamics on Japanese Inter-firm trade Network --- Direct participants’ behavior through the lens of transactional analysis: the case of SPEI --- Chapter 4 Traffic and Pedestrian --- Pedestrian Dynamics in Jamology --- Qualitative Methods of Validating Evacuation Behaviors --- Collective dynamics of pedestrians with no fixed destination --- Traffic Simulation of Kobe-city --- MOSAIIC: city-level agent-based traffic simulation adapted to emergency situations --- GUI for Agent Based Modeling --- Chapter 5 Social Media --- Emotional Changes in Japanese Blog Space Resulting from the 3.11 Earthquake --- Modeling of ENJYO via process of consensus formation on SNS --- A network structure of emotional interactions in an electronic bulletin board --- Scale-free network topologies with clustering similar to online social networks --- Identifying Colors of Products and Associated Personalized Recommendation Engine in e-Fashion Business
    Pages: Online-Ressource (IX, 346 pages)
    ISBN: 9783319205915
    Language: English
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  • 11
    Keywords: Engineering ; Project management ; Engineering design ; Automotive Engineering ; Project Management ; Engineering Design
    Description / Table of Contents: A - Die Entwicklung: Drei Erfolgsstories --- Die StreetScooter-Gründer-Story --- Die StreetScooter-Meilensteine 2008-2017 --- Die StreetScooter-Entwicklungsstory --- Die StreetScooter-Protagonisten-Story --- B - Die Lösung: Return on Engineering: Die StreetScooter-Lösungsbausteine. C - Die Perspektive: Die StreetScooter-Netzwerk-Story --- Die StreetScooter-Produktions-Story --- Die StreetScooter-Post-Story --- Die StreetScooter-Mobilitätslösung --- Die StreetScooter-Vision. A - The Development: Three Stories of Success --- The StreetScooter Founder Story --- The StreetScooter Milestones 2008-2017 --- The StreetScooter Development Story --- The StreetScooter Protagonists Story --- B - The Solution: Return on Engineering: The StreetScooter Building Blocks --- C - The Perspective: The StreetScooter Network Story --- The StreetScooter Production Story --- The StreetScooter Post Story --- The StreetScooter Mobility Solution --- The StreetScooter Vision
    Pages: Online-Ressource (VII, 213 Seiten)
    ISBN: 9783662549971
    Language: German
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  • 12
    Publication Date: 2021-05-19
    Description: Наряду с исследованиями по определению сырьевой базы Азово-Черноморского бассейна, при создании института АзЧерНИРО в 1933 г. была сразу организована научно-исследовательская лаборатория техники лова рыбы. За все время функционирования этого подразделения такие специалисты, как С.С. Виннов, О.И. Саковец, С.Я. Наместников, Е.Е. Шапунов, В.М. Кириллов, В.Г. Герасимов, В.С. Долбиш, Н.Г. Думин, В.Г. Васильев, А.А. Яковлев, Е.С. Деньгин, В.И. Абакаров, В.Н. Миронов, В.В. Стрельцов, А.С. Вайнерман, В.К. Яшкин, Ю.В. Шишов, А.М. Стафикопуло в течение многих лет вносили огромный вклад в развитие рыболовства в Азово-Черноморском бассейне и Мировом океане. До 1950 г. траловый промысел в Черном море отсутствовал, хотя были известны попытки внедрить этот вид лова в черноморское рыболовство. Так, в начале 1909 г. в северо-западной части Черного моря работал траулер «Федя». К концу 1911 г. количество траулеров, которые работали в данном регионе моря, увеличилось до 9 судов. Уловы состояли на 98-99 % из осетровых и на 1-2 % из камбалы. Ввиду очень большого вылова молоди осетровых рыб траловый промысел вскоре был запрещен. В 1932 г. из Мурманска для выяснения эффективности тралового лова в Черном море был послан рыболовный траулер «Абрек». Почти у всего черноморского побережья пробовали ловить отечественным промысловым тралом, применяемым в Баренцевом море для добычи трески. При этом отмечалось, что уловы камбалы были очень низкими. Очевидно, одной из причин была неприспособленность самой конструкции трала для лова этого вида рыб. В конце 1933 г. траулер вернулся в Мурманск. В 1949 г. Черноморская научно-промысловая экспедиция возобновила работы по освоению тралового лова в Черном море. Перед экспедицией стояла задача всесторонне изучить ихтиофауну моря и выяснить возможности применения ряда поисковых орудий лова, в том числе донного трала. С этой целью было разработано и испытано несколько типов донных тралов. С конца 1949 г. были начаты исследования по разработке конструкции разноглубинного трала для Черного моря. К тому времени инженерами М.К. Кокоревым, В.Ф. Шушпановым и А.Н. Потехиным была разработана специальная подъемно-распорная система. В соответствии с ее техническими данными в дальнейшем проектировались сетные части трала. Первый проект опытного рыболовного разноглубинного морского трала разрабатывался для лова мелких черноморских пелагических рыб в толще воды, на глубинах от 0 до 100 м, с одного судна. Большой вклад в развитие тралового промысла в Черном море внес А.Н. Самарянов.
    Description: Published
    Keywords: Engineering ; Fishing gear ; Fishing fleet ; Fishing vessels ; Trawlers ; Anchovy fisheries ; Sprat fisheries ; Purse fishing ; Commercial species ; Mullets
    Repository Name: AquaDocs
    Type: Conference Material , Non Refereed
    Format: pp.247-254
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  • 13
    Publication Date: 2021-05-19
    Description: Aleksey Sergeevich Vinnov (25.05.1958 – 04.06.2019) was a Candidate of Sciences (Engineering), an Associate Professor, a talented lecturer, a rector of the Kerch Maritime Technological Institute (KMTI) in 2000–2005, a Senior Researcher in the FSBSI “Southern Scientific Research Institute of Marine Fisheries and Oceanography” (YugNIRO), and a Deputy Head for Operation and Quality of the Limited Liability Company under the Laws of Russian Federation “Aquamarine”. A.S. Vinnov made a great contribution into the development of education and science in the field of fisheries. Aleksey Sergeevich began his professional life as a Junior Researcher in the Astrakhan Technical Institute of Fishing Industry and Economy and defended his Candidate's Thesis in 1988. He dedicated the major part of his working career to the Kerch State Maritime Technological University, where he had been employed for 21 years, taking positions from a senior lecturer of the Department of Fish Processing Technology, an Associate Professor, the Dean of the Technological Faculty, the vice-rector for academic affairs, to the rector of the University. A.S. Vinnov was known for his rational thinking and professional integrity; he was diplomatic and considerate, and proved to be a competent leader. Vinnov's research works were dedicated to the issues of development of production technology for canned fish and fish protein mass, of kinetics of enzymatic hydrolysis, and many other subjects. A.S. Vinnov was honored with several badges of distinction due to his high professional expertise and personal contribution to the development of fisheries field, particularly education.
    Description: Алексей Сергеевич Виннов (25.05.1958 – 04.06.2019 гг.) — кандидат технических наук, доцент, талантливый преподаватель, ректор Керченского морского технологического института с 2000 по 2005 г. (КМТИ), старший научный сотрудник ФГБНУ «Южный научно-исследовательский институт рыбного хозяйства и океанографии» (ЮгНИРО), заместитель директора по производству и качеству ООО «Аквамарин». А.С. Виннов внес огромный вклад в развитие образования и науки рыбной отрасли. Свою трудовую деятельность Алексей Сергеевич начал в должности младшего научного сотрудника Астраханского технического института рыбной промышленности и хозяйства, успешно защитив в 1988 г. кандидатскую диссертацию. Большую часть своей трудовой деятельности он посвятил Керченскому государственному морскому технологическому университету, проработав здесь 21 год в должностях от старшего преподавателя кафедры технологии рыбных продуктов, доцента, декана технологического факультета, проректора по учебной работе до ректора университета. А.С. Виннов обладал рациональным мышлением, был очень грамотным, тактичным человеком, умелым руководителем. Научная деятельность Алексея Сергеевича была посвящена изучению вопросов усовершенствования технологии рыбных консервов, рыбных белковых масс, кинетики ферментативного гидролиза, а также многим другим. За личный вклад в развитие образования и рыбной отрасли, за высокий профессионализм А.С. Виннов был удостоен ряда почетных знаков отличия.
    Description: Published
    Keywords: Researchers ; Engineering ; Fish processing ; Canned food ; Rector ; Proteins ; Hydrolysis
    Repository Name: AquaDocs
    Type: Journal Contribution , Refereed
    Format: pp.91-95
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-07-08
    Description: The Internet connects billions of computational platforms of various sizes, from supercomputers to smart phones. However, the same types of data transmission can connect computational resources to much simpler sensors “at the edge of the net” that collect, analyze, and transmit data, as well as controllers that receive instructions. Devices deployed in the environment, homes and offices, and even our bodies would expand the number of connected devices to the trillions. This “Internet of Things” (IoT) underlies the vision of smart homes and buildings that could sense and transmit their status and respond appropriately (1), or track and report on the state of objects (vehicles, goods, or even animals) in the environment. However, the practical implementation of the IoT has been relatively slow, in part because all of these edge devices must draw electrical power from their local environment. We analyze the use of photovoltaics (PV) to power devices and help bring the IoT to fruition. Authors: Richard Haight, Wilfried Haensch, Daniel Friedman
    Keywords: Engineering
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-07-08
    Description: Author: Phil Szuromi
    Keywords: Organic Chemistry
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-07-08
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-05-27
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-07-15
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-07-22
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-06-24
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-07-01
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-06-10
    Description: Transition metal–catalyzed arylation of C–H bonds has been intensively studied for forming C–C bonds in complex-molecule synthesis (1). An acidic C–H bond (for example, one near a double bond or an O atom) is cleaved to form a carbon–metal bond, which then couples to arene. Many of these organometallic species can be generated catalytically. Much less research has dealt with unreactive nonacidic sp3 C–H bond functionalization (3). On page 1304 of this issue, Shaw et al. (3) report an efficient and general method that focuses on arylation of sp3 C–H bonds at carbon atoms adjacent to amines and to cyclic ethers by combining nickel, visible-light photoredox, and hydrogen-atom transfer (HAT) catalysis. Author: Corinne Fruit
    Keywords: Organic Chemistry
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-06-10
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-09-09
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-09-07
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-08-17
    Keywords: Engineering
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-08-17
    Description: Polyamide thickness and roughness have been identified as critical properties that affect thin-film composite membrane performance for reverse osmosis. Conventional formation methodologies lack the ability to control these properties independently with high resolution or precision. An additive approach is presented that uses electrospraying to deposit monomers directly onto a substrate, where they react to form polyamide. The small droplet size coupled with low monomer concentrations result in polyamide films that are smoother and thinner than conventional polyamides, while the additive nature of the approach allows for control of thickness and roughness. Polyamide films are formed with a thickness that is controllable down to 4-nanometer increments and a roughness as low as 2 nanometers while still exhibiting good permselectivity relative to a commercial benchmarking membrane.
    Keywords: Engineering
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    Publication Date: 2018-09-07
    Description: Zeolitic imidazolate framework (ZIF) membranes are emerging as a promising energy-efficient separation technology. However, their reliable and scalable manufacturing remains a challenge. We demonstrate the fabrication of ZIF nanocomposite membranes by means of an all-vapor-phase processing method based on atomic layer deposition (ALD) of ZnO in a porous support followed by ligand-vapor treatment. After ALD, the obtained nanocomposite exhibits low flux and is not selective, whereas after ligand-vapor (2-methylimidazole) treatment, it is partially transformed to ZIF and shows stable performance with high mixture separation factor for propylene over propane (an energy-intensive high-volume separation) and high propylene flux. Membrane synthesis through ligand-induced permselectivation of a nonselective and impermeable deposit is shown to be simple and highly reproducible and holds promise for scalability.
    Keywords: Engineering
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-09-14
    Keywords: Engineering
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  • 30
    Publication Date: 2018-09-14
    Description: Insects are among the most agile natural flyers. Hypotheses on their flight control cannot always be validated by experiments with animals or tethered robots. To this end, we developed a programmable and agile autonomous free-flying robot controlled through bio-inspired motion changes of its flapping wings. Despite being 55 times the size of a fruit fly, the robot can accurately mimic the rapid escape maneuvers of flies, including a correcting yaw rotation toward the escape heading. Because the robot’s yaw control was turned off, we showed that these yaw rotations result from passive, translation-induced aerodynamic coupling between the yaw torque and the roll and pitch torques produced throughout the maneuver. The robot enables new methods for studying animal flight, and its flight characteristics allow for real-world flight missions.
    Keywords: Engineering
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-05-20
    Description: Antibiotics have been taking it on the chin lately. Not only has resistance to the anti-infective medications been growing, but drug companies have been dropping antibiotic research programs, because the drugs are difficult and expensive to make. Now, new help is on the way. Researchers report this week that they've found a way to churn out new members of one of the most widely used classes of antibiotics. These drugs, called macrolides, were first developed in the 1950s and now represent a major bulwark against infections. A bevy of possible new drugs in this class could lead to new weapons against antibiotic-resistant infections, and possibly save millions of lives. Author: Robert F. Service
    Keywords: Organic Chemistry
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-04-22
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-04-29
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-05-13
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-04-22
    Description: So prized by the ancient Romans were Egyptian obelisks that, at one time, more of them stood in Rome than in Egypt. In the 19th century, France, Britain, and the United States—inspired by Napoleon Bonaparte's expedition to Egypt in 1798— acquired their own major obelisks from Alexandria and Luxor. Cleopatra's Needles, by Egyptologist Bob Brier, explores the engineering challenges associated with building and erecting these massive monuments. Author: Andrew Robinson
    Keywords: Engineering
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-04-01
    Description: The SN2 nucleophilic substitution reaction, X− + RY → XR + Y−, is a paradigm reaction in organic chemistry (1). The modern understanding of the SN2 reaction mechanism is based on work of Hughes and Ingold (2), who proposed that the nucleophile (X−) approaches the carbon atom that bears the leaving group (Y−). As a result, the bond between the carbon atom and the leaving group becomes weakened. As this bond breaks and a new bond forms between the nucleophile and the carbon atom, the configuration of the carbon atom is inverted. Analyses of gas-phase reaction rates led to the suggestion of a potential energy surface (PES) with two wells connected by a central barrier transition state (3). Electronic structure calculations have confirmed this picture for some SN2 reactions (4), but recent studies have shown that the actual reaction dynamics may be considerably more complex (see the figure) (5–8). Authors: Jing Xie, William L. Hase
    Keywords: Organic Chemistry
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-04-01
    Description: Author: Julia Fahrenkamp-Uppenbrink
    Keywords: Organic Chemistry
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-04-27
    Keywords: Engineering
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-06-23
    Keywords: Engineering
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-06-23
    Keywords: Engineering
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-11-18
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-11-18
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-10-21
    Description: A physicist reveals the engineering marvels that underlie the modern metropolis Author: Sybil Derrible
    Keywords: Engineering
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-03-03
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-06-16
    Keywords: Engineering
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  • 46
    Publication Date: 2017-06-23
    Description: Exoskeletons and active prostheses promise to enhance human mobility, but few have succeeded. Optimizing device characteristics on the basis of measured human performance could lead to improved designs. We have developed a method for identifying the exoskeleton assistance that minimizes human energy cost during walking. Optimized torque patterns from an exoskeleton worn on one ankle reduced metabolic energy consumption by 24.2 ± 7.4% compared to no torque. The approach was effective with exoskeletons worn on one or both ankles, during a variety of walking conditions, during running, and when optimizing muscle activity. Finding a good generic assistance pattern, customizing it to individual needs, and helping users learn to take advantage of the device all contributed to improved economy. Optimization methods with these features can substantially improve performance.
    Keywords: Engineering
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1981-12-18
    Description: Women have made tremendous strides in educational attainment in science and engineering over the past decade, increasing their proportion of doctorate awards in these fields from 7 percent in 1965 to 23 percent in 1980. But they still have higher unemployment rates and lower salaries than men in all fields of science and engineering, at all degree levels, and at all levels of experience; and the disparities between men and women widen with higher degree levels and with years of experience. Graduate enrollments indicate continuing increases over at least the next several years in degree awards to women, but their access to equal employment and advancement opportunities is not assured.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Vetter, B M -- New York, N.Y. -- Science. 1981 Dec 18;214(4527):1313-21.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/7313688" target="_blank"〉PubMed〈/a〉
    Keywords: Education, Graduate ; Employment ; Engineering ; Female ; Humans ; Salaries and Fringe Benefits ; *Science ; *Women
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-11-24
    Keywords: Engineering
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-12-01
    Description: Kim et al . (Reports, 28 April 2017, p. 430) presented results for the solar-driven harvesting of water from air via metal-organic frameworks as a prodigious potential advance toward remedying global water shortages. Basic thermodynamics and a survey of multiple off-the-shelf technologies show that their approach is vastly inferior in efficiency (and thereby in feasibility) to available alternatives.
    Keywords: Engineering
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-12-01
    Keywords: Engineering
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  • 51
    Publication Date: 2017-12-01
    Description: In their comment, Bui et al . argue that the approach we described in our report is vastly inferior in efficiency to alternative off-the-shelf technologies. Their conclusion is invalid, as they compare efficiencies in completely different operating conditions. Here, using heat transfer and thermodynamics principles, we show how Bui et al .’s conclusions about the efficiencies of off-the-shelf technologies are fundamentally flawed and inaccurate for the operating conditions described in our study.
    Keywords: Engineering
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  • 52
    Publication Date: 2017-05-12
    Description: Bacteria within communities can interact to organize their behavior. It has been unclear whether such interactions can extend beyond a single community to coordinate the behavior of distant populations. We discovered that two Bacillus subtilis biofilm communities undergoing metabolic oscillations can become coupled through electrical signaling and synchronize their growth dynamics. Coupling increases competition by also synchronizing demand for limited nutrients. As predicted by mathematical modeling, we confirm that biofilms resolve this conflict by switching from in-phase to antiphase oscillations. This results in time-sharing behavior, where each community takes turns consuming nutrients. Time-sharing enables biofilms to counterintuitively increase growth under reduced nutrient supply. Distant biofilms can thus coordinate their behavior to resolve nutrient competition through time-sharing, a strategy used in engineered systems to allocate limited resources.
    Keywords: Engineering
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-05-12
    Keywords: Engineering
    Print ISSN: 0036-8075
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-12-09
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    Electronic ISSN: 1095-9203
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  • 55
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2016-10-21
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 56
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-04-14
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-04-14
    Description: The allotropes formed by carbon reflect differences in its bonding: single bonds in diamond, double bonds in graphite and graphene, and triple bonds in polyynes. Fashioning graphene sheets into bowls, monkey saddles, balls, and tubes has led to a number of molecular allotropes of carbon or carbon-rich quasi-allotropes with novel topologies and shapes. A simple ring of carbon can be reduced to practice in various forms (1): a cyclic array of carbon atoms, a “pearl necklace” of benzene rings, or a cylindrical hoop of flank-fused benzenes, just to name a few. On page 172 of this issue, Povie et al. (2) report on the synthesis of an angular-fused hoop structure, which has been a long-standing target. Author: Jay S. Siegel
    Keywords: Organic Chemistry
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  • 58
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-04-14
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-09-14
    Keywords: Engineering
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  • 60
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-03-03
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-02-17
    Description: Engineering has an image problem. The phrase "engineering disaster" rolls off the tongue, while great technical achievements are more often heralded as "scientific miracles." Enter Dream Big. Sponsored by the American Society of Civil Engineers with support from Bechtel Corporation, the film sets out to reframe engineering as a force for good and a profession in service to people and the planet. Author: Donna Riley
    Keywords: Engineering
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-03-09
    Keywords: Engineering
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-01-19
    Keywords: Engineering
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-07-21
    Keywords: Engineering
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-07-21
    Keywords: Engineering
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-04-01
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-05-26
    Keywords: Engineering
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-11-10
    Keywords: Engineering
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-01-13
    Description: Author: Jake Yeston
    Keywords: Organic Chemistry
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  • 70
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    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 478-485 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Synthesis and Polymerization Behaviour of 2-Aryl-5-methylene-1,3-dioxolan-4-ones and Arylbis(5-methylene-1,3-dioxolan-2-yl-4-on)esStarting from 2,6-di(hydroxymethyl)-4-methylphen-ol-Na-salt-1-hydrate (1) a synthesis of 2-alkoxy-5-methyliso-phthaldialdehydes (3a,b) is described via alkylation and oxidation. Condensation of aromatic aldehydes with 3-bromo-2-hydroxypropanoic acid (β-bromolactic acid) affords diastereoisomeric mixtures of new 2-aryl-5-bromomethyl-1,3-dioxolan-4-ones (6a-h) as well as the corresponding bisdioxolanones (6i-l). Dehydrobromination of 2-aryl-5-bromomethyl-1,3-dioxolan-4-ones (6a-d,i) with DBU leads to 2-aryl-5-methylene-1,3-dioxolan-4-ones (8a-e). Polymerization of compounds 8a,b,d and e proceed via opening of the dioxolanone ring.
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  • 71
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    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 496-503 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Studies on the Oxidation of α-Substituted Styrenes. I. Reactivity and Formation of Reaction Products During the Oxidation of Styrene DerivativesThe liquid phase oxidation of α-tert. -butyl-, α-bromo-, α-chloro-, and α-methyl styrene with pure oxygen was investigated in a closed apparatus in chlorobenzene solution and in presence of cumene and of cumene hydroperoxide in the temperature range 35-125°C. The product yields were determined gaschromatographically.The differences of the activation energies of the epoxide formation and the parallel reactions were calculated. They amount to 27-38 kJ/mol. The epoxide selectivity increases with increasing temperature and decreases with increasing concentration of cumene. Relative chain propagation constants related to the tertiary CH-bond of cumene were determined from cooxidation experiments.
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  • 72
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 73
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    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 534-537 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: New Cryptands with 1,3,5-Triazines as Ring Building BlocksThe synthesis and characterization of 10 new cryptands 5a-j, containing two 1,3,5-triazine rings as subunits are described. The general methodology used is based on the aminolysis of cyanuric chloride with α,ω-diamino compounds or diazacrowns.
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  • 74
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    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 529-533 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Trace-Matrix-Separation as Sample Pretreatment for the Determination of Chloride, Bromide and Iodide by Ion Chromatography in Salts, other Solid Samples and in Concentrated SolutionsChloride, bromide and iodide are collected from concentrated salt solutions on a column of Ag2CrO4. The excess of the collector is removed with acid and the silver halogenides dissolved with cyanide. The anions are separated on a PRP-X100 column using an eluent with p-hydroxybenzoic acid, p-hydroxobenzonitrile, methanol and cyanide. Detection limits are 0.2 ppm chloride, 0.04 ppm bromide and 0.2 ppm iodide, using conductivity detection and the Metrohm Ion Chromatograph 690.
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  • 75
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    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 239-241 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Tab.
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  • 76
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    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 266-268 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Karl-Fischer-Reaction in Dimethyl SulfoxideThe water equivalent (titer) of methanolic Karl-Fischer-reagents rises if dimethyl sulfoxide (DMSO) is used as an additional solvent. It is shown that the probable reason for this observation is the formation of iodine by the reaction between DMSO, iodide and sulfur trioxide.
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  • 77
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    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 283-291 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Investigations on the Chemistry of 3-Chloromethyl-3-methyl-2,3-dihydro-1,4-benzoxathiinesA series of 3-chloromethyl-2,3-dihydro-1,4-benzoxathiines 3 were prepared by the reaction of several β-methallylphenylethers 1 with sulfur dichloride. In some cases intermediate sulfenyl chlorides 2 were isolated and characterized as substituted thiazolidin-2-ones. The thermal regioisomerization of selected sulfenyl chlorides and one of the thiazolidinone products was achieved. Starting from 3-chloromethyl-2,3-dihydro-1,4-benzoxathiine 3o several derivatives were obtained by nucleophilic displacement at the 3-chloromethyl position, activated by S-3-neighboring group partizipation. The structure of the 3-acetoxymethyl derivative was determined by x-ray crystal structure analysis. Further special derivation with selected chiral reagents led to diastereomeric compounds. The separation of the diastereomers by crystallization and chromatography was attempted. HPLC-separation was achieved in one case.
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  • 78
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    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 472-477 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Amino-thieno[2,3-c]pyrazoles and Amino-thieno[2,3-b]pyrrolesThe synthesis of thieno[2,3-c]pyrazoles and thieno[2,3-b]pyrroles is described. From the dithioliumsalt (1) and potassium hydroxide the potassium-(2,2-dicyan-1-methylthio-ethen-1-yl)-thiolate (2) is formed. This reacts with hydrazine hydrate to form the 3-amino-5-thioxo-pyrazol-4-carbonitrile (3) S-Alkylation with α-chlorocarbonyl compounds yielding (6a-c) leads via Thorpe-Ziegler-cyclization to 3,4-diamino-thieno[2,3-c]pyrazoles (9) if the position 1 is alkylated (8). Acetyl acetone yields 2-mercapto-pyrazolo[1,5-a]pyrimidine (5). After S-alkylation (10a-d) are immediately cyclized to thieno [2′,3′:3,4]pyrazolo[1,5-a]pyrimidine (11a-d). The ketone (6a) can be cyclized to the pyrazolo [5,1-b]thiazole (12). 3 reacts with oxalyl chloride to form the 2,3-dioxo-6-thioxo-imidazo[1,2-b]pyrazole (13) of which S-phenacyl derivative (14) because the NH-proton cannot be cyclized. The 5-amino-3,4-dicyano-pyrrol-2-thiolate (16) shows the analogous behaviour. The S-alkylation is followed by cyclization, and 3,5-diamino-thieno[2,3-b]pyrroles (18a-b) arise. Reaction of 5-amino-2-alkylthio-pyrrol-3,5-dicarbonitrile (17) with acetyl acetone provides pyrrolo[1,2-a]pyrimidine (20a-c) which can be cyclized to form thieno[3′,2′:4,6]pyrimidines (21a-c) very easily.
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  • 79
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    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 379-384 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Synthesis of Benzo[b]thioxanthenesBenzo[b]thioxanthenes, heterocyclic compounds related to tetracenes and tetracyclines can be obtained by the reaction of 2H-benzo[b]thiete (1) and 1,4-naphthoquinones (3a-g). The primary cycloadducts 4a-g undergo an autoxidation process leading to the quinones 6a-g. The dihydroxy compound 4e shows an additional isomerization by a tetrafold H transfer (4e → 5e′). Another preparative route to benzo[b]thioxanthenes makes use of the cycloadditon reaction of 1 and 1,4-epoxynaphthalenes (7a-d). The primary adducts can be transformed to the title compounds by catalytic dehydration processes (8a-d → 9a-d). An alternate regioselective opening of the oxygen bridge can be performed by the action of trimethyliodosilane (8a → 10a). Methylation of 9a furnishes the sulfonium salt 14a which rearranges in a strongly alkaline medium to 16a; in the presence of oxygen ketone 17a is generated.
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  • 80
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    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 401-404 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: New Azacyclophanes from Cyanuric Chloride and Diamines
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    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 416-417 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 424-424 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 83
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Hydroformylation with Water- and Methanol-soluble Rhodium Carbonyl/phenyl-sulfonatoalkyl-phosphine Catalyst Systems - A New Concept for the Hydroformylation of Higher Molecular OlefinsThe heterogenization of the homogeneous hydroformylating catalyst system enables the recovery of the catalyst from the reaction products by a simple phase separation but it is unfavourable that many advantages of the homogeneous catalysis are given up by this procedure. To avoid this drawback we used rhodium carbonyl/tert. phosphine catalyst systems soluble as good in methanol as in water for the homogeneously catalyzed hydroformylation of the olefin in methanolic solution. Only after reaction the product mixture is heterogenized by adding water forming an aqueous phase containing the catalyst system. It was shown by the hydroformylation of n-tetradecene-1 with rhodium carbonyl/phenyl-sulfonatoalkyl-phosphine catalyst systems that this new conception is very useful for the oxo reaction of high-molecular olefins.
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    Journal für Praktische Chemie/Chemiker-Zeitung 338 (1996), S. 16-22 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Expert Systems to Assist Analytical Chemistry: Intelligent User Counseling in ICP-Mass SpectrometryBecause ICP-mass spectrometry is a sensitive and rather new technique, some operators may lack the required thorough expertise. An intelligent system is presented which at first helps to identify any problems originating from the components of the actual sample. By demand of the user an experimental strategy to acquire any lacking information is provided. Based on this knowledge possible interferences are prognosticated. An appropriate operating procedure is then proposed, including suitable details of sample preparation. After the analytical measurement a scanned mass spectrum may be automatically checked for plausibility and for evidence of unexpected sources of error. The system is strictly organized in separated modules. It is open for easy introduction of additional knowledge and for the cooperation with the software of the spectrometer. The expert system shell Nexpert has been used as a building tool.
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  • 85
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Geminal Substituent Effects. VIII. Enthalpies of Formation of AcetalsThe standard enthalpies of combustion ΔHc° (1 or c) of the α-phenyl-substituted acetals (1) and diacetals (2) were measured calorimetrically. The enthalpies of vaporisation or sublimation ΔHvap or ΔHsub of 1-2 were obtained from the temperature function of the vapor pressure measured in a flow system, and the standard enthalpies of formation are obtained thereof: ΔH°f (1 or c) and ΔHf° (g) (in kJ mol-1) for 1a = -308.40 ± 0.52(1), -248.94 ± 0.88; 1b = -343.48 ± 0.72 (1), -288.5 ± 1.5; 1c = -267.4 ± 1.3 (1), -205.3 ± 1.3; 1d = -343.8 ± 2.1 (c), -261.9 ± 2.2; 1e = -397.02 ± 0.86 (c), -311.3 ± 1.2; 1f = -414.52 ± 0.80 (1), -350.68 ± 0.86; 2a = -564.8 ± 2.4 (c), -467.1 ± 2.5; 2b = -547.6 ± 1.6 (c), -414.9 ± 2.7; 2c = -717.1 ± 7.5 (c), -587.0 ± 8.0. The results are combined into values of two strain free group increments CH[20, CPh] = -59.7 and C[20, CPh, C] = -71.3 kJ mol-1; and compared to the aliphatic series of acetals.
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  • 86
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Synthesis of Spirocyclic Isothiazolium Salts and their Base Catalysed Reaction to ThianthrenesN-Phenyl-substituted isothiazolium salts 1 with active 7-methylene group react under the influence of bases to the spirocyclic isothiazolium salts rac-cis- and rac-trans-4; the salts trans-4 are not stable and react to the thianthrene derivatives rac-trans-6. Thus, a very simple separation of diastereoisomeric salts rac-cis- and rac-trans-4 is possible. The influence of donor and acceptor substituents in the phenyl group of 1 on the diastereoselective synthesis of 4 and 6 was studied. The structure of rac-cis-4 and rac-trans-6 was confirmed by X-ray analysis.
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    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 203-208 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Cyanine dyes (1a-d) with the 5,5′,6,6′-tetrachloro-1,1′-dialkyl-3,3′-di-(3-carboxypropyl)-benzimidocarbocyanine chromophore differing only in the chain length of their alkyl groups in 1,1′-position have been synthesized, spectroscopically characterized, and compared with 5,5′6,6′-tetrachloro-1,1′-diethyl-3,3′-di-(4-sulfobutyl)-benzimidocarbocyanine(TDBC). In aqueous solution the dyes form J-aggregates which, depending on the alkyl group chain length, exhibit J-bands differing in spectral positions, bandwidth, and in the number of peaks.
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    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 222-230 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ring Cleavage of 4-(4-Nitrophenylazo)-substituted Pyrazolidine-3,5-diones to α-(4-Nitrophenylhydrazono)semicarbazides with Consecutive ReactionsThe reaction of 1 and 2 with ammonia, methylamine and dimethylamine in aprotic solvents, e. g. diethyl ether, yields the compounds 3 - 8 which can exist in two isomeric forms (form a/b). On conditions which are usually chosen for spectroscopic investigations only form a could be detected. Nevertheless, under the influence of bases like KOH or ammonia in water or alcohol these compounds are mainly converted to semicarbazides (11-15) which means that this reaction must run via form b. Those semicarbazides which are unsubstituted at the N-4 of their semicarbazide-moiety show great tendency to cyclize, thus forming the triazolederivatives 16-18. In contrast to these products, in the case of the N-4-monomethylated semicarbazide 14 the six-membered heterocyclus 19 was obtained. In comparison with 1 and 2, stable intermediates such as 3-8 in the reaction with 21 could not be isolated.
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  • 89
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    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 242-244 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Tab.
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  • 90
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Selectivity is such an intellectually, economically, and ecologically important matter in organic synthesis that it is highly desirable to know all the factors, both kinetic and thermodynamic, which influence it. We were surprised by the high selectivity obtained in an equilibration of isomeric β-thioalkyl trifluoroacetates, because the thermodynamic difference implied by this and other, similar, rearrangements did not appear to have been explained.It now appears that this difference is due to the thermochemical effect whereby polar substituents bind more strongly to alkyl groups of complementary polarity; in other words electronegative atoms prefer more „procationic“ tertiary and secondary alkyl groups, electropositive ones prefer the more „proanionic“ primary alkyl and methyl groups. This small but significant (1 to 7 kcal·mol-1) effect is well documented by thermochemical data, and has been described several times; it can be predicted qualitatively by Pauling's formula relating bond energy, bond polarisation, and electronegativity.We first describe how the electronegativity effect explains our observations: they are due to the higher electronegativity of oxygen and chlorine relative to that of sulfur. We then go on to show that it is useful for the interpretation of many other literature reports, ranging from the acid-catalysed isomerization of alkyl halides, to the carbocyclization of organozinc reagents, and the isomerization of alkyltransition metal complexes (a key step for the selectivity of important industrial processes such as alkene hydroformylation).
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  • 91
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    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 504-507 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The Assignment of the 13C-NMR Chemical Shifts of Substituted Naphthalenes from Charge Density with an Artificial Neural NetworkNeuronal networks are a new possibility to work with blurred data and informations. In this article, the use of a multilayer network with backpropagation of errors for the prediction of the 13C-chemical shifts of a series of substituted naphthalenes from the σ- and π- charge density of the corresponding carbon atoms (calculated by means of the PIMM program) will be described. The average uncertainty for the estimation of the 13C-chemical shifts of monosubstituted naphthalenes is only 2.1 ppm, for naphthalenes with more than one substituent about 4 ppm.
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  • 92
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    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 548-557 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Binucleophilic biogenic α-aminoacids 1 such as cysteine, penicillamine, serine, and threonine react with lactam acetals 2 by condensation to bridged α-amidinoacids 3 or by condensation/ring transformation to 2-(ω-aminoalkyl)-1,3-azoline-4-carboxylic acids 6. Corresponding reactions with lactim ethers 7 afford analogous α-amidinoacids 8, condensed imidazolones 10 as their derivatives, ω-aminoalkyl-1,3-azolines 13 and, by further reaction with lactim ether 7, modified ω-amidinoalkyl-1,3-azolines 14.
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  • 93
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    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 576-581 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Modification of Copolyamides via Polymeranalogous Reaction with Glycidyl EthersThe reaction of copolyamides with phenyl glycidyl ether (PGE) and glycidyl oxypropyl-3-triethoxy silane (GPTS) in the presence of anionic catalysts leads to the formation of grafted polyamides. Octanoic acid octylamide (OOA) and a copolyamide of polyamides 6, 66 and 11 were used as polyamide model compounds. The anionic centres were introduced by reaction of the amides with sodium methoxide in boiling toluene. About 15% of the amide groups react with PGE and GPTS. In the presence of GPTS, polycondensation reactions occur and crosslinked products are formed.
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  • 94
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    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 596-598 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Carbon Analogous Structures of Brasilin and Hematoxylin of the Indeno[1,2-α]indan-type
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  • 95
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    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 609-611 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 96
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    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 614-614 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 97
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    Journal für Praktische Chemie/Chemiker-Zeitung 338 (1996), S. 654-659 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Three perylene tetracarboxylic bisimide chromophores have been attached to a benzene ring in m-position (3). In this way steric and through-bond interactions of the chromophores are minimized and their through-space-interactions can be studied for which an unusually high bathochromic shift has been found. This indicates a destabilization. No exciton coupling has been observed in the trichromophoric dyes.
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  • 98
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    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 441-445 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The regioselective sulfation of a Lex-trisaccharide having free hydroxyl groups in 2-, 3- and 4- position of the galactose elucidated their different reactivities and gave mono- and disulfated Lex derivatives.
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  • 99
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    Journal für Praktische Chemie/Chemiker-Zeitung 338 (1996) 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 100
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Two new synthons, Fmoc-L-Arg(biphenyl-4-sulphonyl)-OH (8) and Fmoc-Arg(4-methoxy-3-t-butylbenzenesulphonyl)-OH (14), are prepared for the synthesis of arginine-containing peptides. These groups are cleaved by commonly employed trifluoroacetic acid and methanesulphonic acid. Kinetic studies reveal that extended bicyclic aromatic conjugation, as in biphenyl, slightly improves the acid lability compared to the electron-donating t-butyl group.
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