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  • 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry  (27)
  • 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques  (21)
  • American Geophysical Union  (40)
  • Blackwell Publishing Ltd  (4)
  • Copernicus
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  • 1
    Publikationsdatum: 2021-03-01
    Beschreibung: A new period of eruptive activity started at Turrialba volcano, Costa Rica, in 2010 after almost 150 years of quiescence. This activity has been characterized by sporadic explosions whose frequency clearly increased since October 2014. This study aimed to identify the mechanisms that triggered the resumption of this eruptive activity and characterize the evolution of the phenomena over the past 2 years. We integrate 3He/4He data available on fumarole gases collected in the summit area of Turrialba between 1999 and 2011 with new measurements made on samples collected between September 2014 and February 2016. The results of a petrological investigation of the products that erupted between October 2014 and May 2015 are also presented. We infer that the resumption of eruptive activity in 2010 was triggered by a replenishment of the plumbing system of Turrialba by a new batch of magma. This is supported by the increase in 3He/4He values observed since 2005 at the crater fumaroles and by comparable high values in September 2014, just before the onset of the new eruptive phase. The presence of a number of fresh and juvenile glassy shards in the erupted products increased between October 2014 and May 2015, suggesting the involvement of new magma with a composition similar to that erupted in 1864–1866. We conclude that the increase in 3He/4He at the summit fumaroles since October 2015 represents strong evidence of a new phase of magma replenishment, which implies that the level of activity remains high at the volcano.
    Beschreibung: Published
    Beschreibung: 3V. Proprietà dei magmi e dei prodotti vulcanici
    Beschreibung: 4V. Dinamica dei processi pre-eruttivi
    Beschreibung: 5V. Dinamica dei processi eruttivi e post-eruttivi
    Beschreibung: JCR Journal
    Schlagwort(e): Turrialba volcano ; eruptive activity ; 3He/4He ; fumarole gases ; glassy shards ; juvenile component ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.08. Volcanic arcs ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Publikationsdatum: 2017-04-04
    Beschreibung: Piton de la Fournaise (PdF) is recognised as one of the world’s most active volcanoes in terms of eruptive frequency and the substantial quantity of lava produced. Yet, with the sole exception of rather modest intracrateric fumarole activity, this seems to be in contrast with an apparent absence of any type of natural fluid emission during periods of quiescence. Measurement campaigns were undertaken during a long-lasting quiescent period (2012-2014) and just after a short lived summit eruption (June 2014) in order to identify potential degassing areas in relation to the main structural features of the volcano (ex. rift zones) with the aim of developing a broader understanding of the geometry of the plumbing and degassing system. In order to assess the possible existence of anomalous soil CO2 flux, 513 measurements were taken along transects roughly orthogonal to the known tectonic lineaments crossing PdF edifice. In addition, 53 samples of gas for C isotope analysis were taken at measurement points that showed a relatively high CO2 concentration in the soil. CO2 flux values range from 10 to 1300 g m-2 d-1 while 13C are between -26.6 to -8‰. The results of our investigation clearly indicate that there is a strong spatial correlation between the anomalous high values of diffusive soil emissions and the main rift zones cutting the PdF massif and, moreover, that generally high soil CO2 fluxes show a d13C signature clearly related to a magmatic origin.
    Beschreibung: INSU (CNRS) and La Réunion Préfecture (Projet pour la quantification de l’aléa volcanique à La Réunion)
    Beschreibung: Published
    Beschreibung: 4388–4404
    Beschreibung: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): CO2 soil degassing anomalies at Piton de la Fournaise ; d13C magmatic signature ; Close link between anomalous CO2 degassing and the main seismotectonic structures ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Publikationsdatum: 2017-04-04
    Beschreibung: This paper focuses on the chemical composition changes in soil gases through both a theoretical model and laboratory experiments. The model describes the one-dimensional mass transfer process, which is triggered by changes in the flux parameters of the system, and the time-dependent evolution of the composition of the soil gases as a function of i) the pristine gas mixture, ii) the diffusivity of the chemicals, and iii) the thickness of the transited medium. Carbon dioxide (CO2), hydrogen (H2), and helium (He) were used in a laboratory-scale flux simulator to investigate the evolution of the gas composition profile in an artificial soil of constant thickness. The agreement between the theoretical calculations and the experimental results supports the validity of the model. Our results indicate a good reproducibility of the transient changes in the concentrations of CO2, He, and H2 in CO2-rich gas mixtures that contain He and H2 as trace gases. Finally, the theoretical results were used to analyze the H2 and CO2 continuous monitoring data collected at Etna volcano in 2010
    Beschreibung: Published
    Beschreibung: 1565–1583
    Beschreibung: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Beschreibung: 5V. Sorveglianza vulcanica ed emergenze
    Beschreibung: 1IT. Reti di monitoraggio e Osservazioni
    Beschreibung: JCR Journal
    Beschreibung: open
    Schlagwort(e): Soil gases ; Volcanic gas composition ; Hydrogen ; Carbon dioxide ; CO2 ; Helium ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Publikationsdatum: 2017-04-04
    Beschreibung: In seismically active areas, tectonic stress deforms and breaks the rocks of the crust. Ongoing deformation produces detectable modifications in the shallower portions of the crust, resulting in a wide variety of changes in several parameters. In this paper, we report the results of a large-scale spatial (across an area of 15,000 km2) and temporal (up to 3 years) investigation of the relationship between active crustal stress and soil CO2 flux. We deployed a network of 10 automatic stations in most of the seismically active districts of southern Italy to monitor the soil CO2 fluxes, and we used seismicity data to track crustal stress. The results of the investigation show that the CO2 flux signals varied independently in the districts with low and sporadic seismicity. Conversely, in the only district with nearly continuous seismic activity, almost all of the CO2 flux signals were well correlated with each other, and we recorded a clear synchronous sharp increase of the seismicity and signals recorded by several stations. The high spatial and temporal correlation between seismicity and gas discharge evidenced in this study prove that the crustal stress associated with the seismogenic process is able to effectively modulate the gas release in a seismically active area.
    Beschreibung: Published
    Beschreibung: 7071–7085
    Beschreibung: 2T. Tettonica attiva
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Soil CO2 flux ; Crustal stress ; seismotectonic process ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Publikationsdatum: 2024-05-09
    Beschreibung: Here we report on the first assessment of volatile fluxes from the hyperacid crater lake hosted within the summit crater of Copahue, a very active volcano on the Argentina-Chile border. Our observations were performed using a variety of in situ and remote sensing techniques during field campaigns in March 2013, when the crater hosted an active fumarole field, and in March 2014, when an acidic volcanic lake covered the fumarole field. In the latter campaign, we found that 566 to 1373 t d−1 of SO2 were being emitted from the lake in a plume that appeared largely invisible. This, combined with our derived bulk plume composition, was converted into flux of other volcanic species (H2O ~ 10989 t d−1, CO2 ~ 638 t d−1, HCl ~ 66 t d−1, H2 ~ 3.3 t d−1, and HBr ~ 0.05 t d−1). These levels of degassing, comparable to those seen at many open-vent degassing arc volcanoes, were surprisingly high for a volcano hosting a crater lake. Copahue's unusual degassing regime was also confirmed by the chemical composition of the plume that, although issuing from a hot (65°C) lake, preserves a close-to-magmatic signature. EQ3/6 models of gas-water-rock interaction in the lake were able to match observed compositions and demonstrated that magmatic gases emitted to the atmosphere were virtually unaffected by scrubbing of soluble (S and Cl) species. Finally, the derived large H2O flux (10,988 t d−1) suggested a mechanism in which magmatic gas stripping drove enhanced lake water evaporation, a process likely common to many degassing volcanic lakes worldwide.
    Beschreibung: Published
    Beschreibung: 6071–6084
    Beschreibung: 3V. Dinamiche e scenari eruttivi
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): water/rock interaction ; volcanic lakes ; volcanic/hydrothermal gases ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.02. Exploration geophysics::04.02.07. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Publikationsdatum: 2020-12-14
    Beschreibung: Explosive volcanic eruptions are defined as the violent ejection of gas and hot fragments from a vent in the Earth's crust. Knowledge of ejection velocity is crucial for understanding and modeling relevant physical processes of an eruption, and yet direct measurements are still a difficult task with largely variable results. Here we apply pioneering high-speed imaging to measure the ejection velocity of pyroclasts from Strombolian explosive eruptions with an unparalleled temporal resolution. Measured supersonic velocities, up to 405 m/s, are twice higher than previously reported for such eruptions. Individual Strombolian explosions include multiple, sub-second-lasting ejection pulses characterized by an exponential decay of velocity. When fitted with an empirical model from shock-tube experiments literature, this decay allows constraining the length of the pressurized gas pockets responsible for the ejection pulses. These results directly impact eruption modeling and related hazard assessment, as well as the interpretation of geophysical signals from monitoring networks.
    Beschreibung: INGV-DPC “V2” and “Paroxysm”, FIRB-MIUR “Research and Development of New Technologies for Protection and Defense of Territory from Natural Risks”, and FP7-PEOPLE-IEF-2008 – 235328 Projects
    Beschreibung: Published
    Beschreibung: L02301
    Beschreibung: 3V. Dinamiche e scenari eruttivi
    Beschreibung: JCR Journal
    Beschreibung: open
    Schlagwort(e): strombolian ; ejection velocity ; explosive eruption ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Publikationsdatum: 2021-06-25
    Beschreibung: Beside anthropogenic influences, mercury in the environment can also be of natural origin. Among geologic sources, volcanic activity has been of main interest so far. Modern estimations of global natural emissions are between 2000 and 5200 tonnes per year. However, these estimates are very uncertain, thus more detailed and systematic research on natural sources of mercury is necessary. Tectonic activity is connected to certain phenomena such as degassing of Hg and other gases from active faults, geothermal activity, volcanoes, etc., especially on tectonic plate margins. Elemental mercury concentrations in air, soil gases and fluxes, as well as its speciation, in connection to tectonic activity, were studied in different environments such are karst cave (Postojna Cave), active volcano areas (Mt. Etna, Italy), and active tectonic areas in the Mediterranean Basin on Africa-Adriatic tectonic plate margin. Postojna Cave is characterized by elevated Hg (up to 150 ng m-3) air concentrations at certain areas in vicinity of active faults; however the concentrations showed also strong seasonal variations. Mt. Etna on Sicily is the largest and most active Mediterranean volcano. Concentrations of mercury in air in the vicinity of the volcano are relatively high (between 4 and 30 ng m-3) and rise towards the summit crater (65 to 130 ng m-3). Concentrations in sulphatare and fumaroles gases on the summit of the volcano can reach very high values (even up to 60 μg m-3). The Mediterranean Basin is characterized by strong tectonic activity as a consequence of subduction of African plate under the Eurasian plate. A possible source of DGM (dissolved gaseous mercury in sea water) in deeper and bottom waters could be intensive tectonic activity of the seafloor, since higher concentrations and portions of DGM were found near the bottom at locations with strong tectonic activity (Alboran Sea, Strait of Sicily, Tyrrhenian Sea, Ionian Sea). Distribution of different mercury species in sediment and water of the Mediterranean Sea showed that the main source of mercury is geotectonic activity and its accompanying phenomena.
    Beschreibung: Published
    Beschreibung: San Francisco
    Beschreibung: 6A. Monitoraggio ambientale, sicurezza e territorio
    Beschreibung: restricted
    Schlagwort(e): Mercury ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: Conference paper
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Publikationsdatum: 2017-04-04
    Beschreibung: We investigated the carbon isotope composition of mantle source beneath the Hyblean Plateau (southeast Sicily, Italy) by studying CO2 in fluid inclusions from ultramafic xenoliths recovered in some Miocene diatremes. In order to constrain the processes influencing the isotopic marker of carbon we combined d13CCO2 results with information about noble gases (He and Ar) obtained in a previous investigation of the same products. Although Ar/CO2 and He/Ar ratios provide evidence of Rayleigh-type fractional degassing, the isotopic geochemistry of carbon is poorly influenced by this process. Mixing related to metasomatic processes where MORB-type pyroxenitic melts permeate a peridotite mantle probably contaminated by crustal fluids inherited from a fossil subduction can explain the measured d13C and CO2/3He variations, ranging from 24&to 22& and from 109 to 1010, respectively. Simple mass-balance calculations highlighted that the Hyblean peridotite source was mainly contaminated by the carbonate source, being carbonate and organic matter present at a ratio that varied within the range from 7:1 to 4:1.
    Beschreibung: Published
    Beschreibung: 600-611
    Beschreibung: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): xenoliths ; mantle heterogeneity ; Hyblean Plateau ; fluid inclusions ; isotopic carbon ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Publikationsdatum: 2017-04-04
    Beschreibung: Gas from mud volcanoes, dry mofettes, springs, and wells were sampled in a region of active tectonics and high seismicity in the southern Apennines (Italy), where there is a long history of disastrous earthquakes, with the latest (Ms = 6.9) occurring in 1980. The fluids consist of a mixture of mantle-derived and crust-derived volatiles, with a low atmosphere-derived contribution, as identified by the He isotope signature and He/Ne ratio measurements. One year of monthly monitoring of the He concentrations and He isotopes revealed no seasonal modifications or variations induced by low seismicity. There are extraordinary high outputs of 4He produced in the crust in the area (up to 2.5 × 1028 atoms yr 1). These outputs cannot be solely due to the whole-rock production rate and a long-lasting diffusion degassing through the crust of the produced 4He. This study explored the relation between the volume of fractured rock and the related release of He. The results support that crustal degassing can be controlled by tectonic events resulting in earthquakes. The high seismicity in this sector of the Apennines provides the conditions necessary for a massive release of He that has accumulated in the rock over a long time period. We identified that the assessed high crustal 4He output can be attributed to an intense fracturing of a calculable volume of rock, which gives new constraints on the volume of rock involved in high-magnitude earthquakes in the region.
    Beschreibung: Published
    Beschreibung: 2200-2211
    Beschreibung: 2T. Tettonica attiva
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): xtraordinary high radiogenic helium flux in continental region ; Release of crustal 4He due to rock fracturing ; Relationship between rock involved in earthquake and radiogenic He flux ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Publikationsdatum: 2017-04-04
    Beschreibung: High-speed imaging of explosive eruptions at Stromboli (Italy), Fuego (Guatemala), and Yasur (Vanuatu) volcanoes allowed visualization of pressure waves from seconds-long explosions. From the explosion jets, waves radiate with variable geometry, timing, and apparent direction and velocity. Both the explosion jets and their wave fields are replicated well by numerical simulations of supersonic jets impulsively released from a pressurized vessel. The scaled acoustic signal from one explosion at Stromboli displays a frequency pattern with an excellent match to those from the simulated jets. We conclude that both the observed waves and the audible sound from the explosions are jet noise, i.e., the typical acoustic field radiating from high-velocity jets. Volcanic jet noise was previously quantified only in the infrasonic emissions from large, sub-Plinian to Plinian eruptions. Our combined approach allows us to define the spatial and temporal evolution of audible jet noise from supersonic jets in small-scale volcanic eruptions.
    Beschreibung: INGV-DPC “V2” and “Paroxysm,” FIRB-MIUR “Research and Development of New Technologies for Protection and Defense of Territory from Natural Risks,” and FP7-PEOPLE-IEF-2008–235328 “NEMOH” ITN projects
    Beschreibung: Published
    Beschreibung: 3096–3102
    Beschreibung: 3V. Dinamiche e scenari eruttivi
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): jet noise ; volcano acoustics ; Stromboli ; Yasur ; Fuego ; strombolian eruption ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 11
    Publikationsdatum: 2017-04-04
    Beschreibung: The fumarolic gas output has not been quantified for any of the currently deforming calderas worldwide, due to the lack of suitable gas flux sensing techniques. In view of resumption of ground uplift (since 2005) and the associated variations in gas chemistry, Campi Flegrei, in southern Italy, is one of the restless calderas where gas flux observations are especially necessary. Here we report the first ever obtained estimate of the Campi Flegrei fumarolic gas output, based on a set of MultiGAS surveys (performed in 2012 and 2013) with an ad-hoc-designed measurement setup. We estimate that the current Campi Flegrei fumarolic sulphur (S) flux is low, on the order of 1.5–2.2 tons/day, suggesting substantial scrubbing of magmatic S by the hydrothermal system. However, the fumarolic carbon dioxide (CO2) output is ∼460±160 tons/day (mean±SD), which is surprisingly high for a dormant volcano in the hydrothermal stage of activity, and results in a combined (fumaroles + soil) CO2 output of ∼1560 tons/day. Assuming magma to be the predominant source, we propose that the current CO2 output can be supplied by either (i) a large (0.6–4.6 km3), deeply stored (〉7 km) magmatic source with low CO2 contents (0.05–0.1 wt%) or (ii) by a small to medium-sized (∼0.01–0.1 km3) but CO2-rich (2 wt%) magma, possibly stored at pressures of ∼100 to 120 MPa. Independent geophysical evidence (e.g., inferred from geodetic and gravity data) is needed to distinguish between these two possibilities.
    Beschreibung: Published
    Beschreibung: 4153–4169
    Beschreibung: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): Campi Flegrei ; calderas ; gas output ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 12
    Publikationsdatum: 2021-03-24
    Beschreibung: On 24 August 2013 a sudden gas eruption from the ground occurred in the Tiber river delta, nearby Rome's international airport of Fiumicino. We assessed that this gas, analogous to other minor vents in the area, is dominantly composed of deep, partially mantle-derived CO2, as in the geothermal gas of the surrounding Roman Comagmatic Province. Increased amounts of thermogenic CH4 are likely sourced from Meso-Cenozoic petroleum systems, overlying the deep magmatic fluids. We hypothesize that the intersection of NE-SW and N-S fault systems, which at regional scale controls the location of the Roman volcanic edifices, favors gas uprising through the impermeable Pliocene and deltaic Holocene covers. Pressurized gas may temporarily be stored below these covers or within shallower sandy, permeable layers. The eruption, regardless the triggering cause—natural or man-made, reveals the potential hazard of gas-charged sediments in the delta, even at distances far from the volcanic edifices.
    Beschreibung: Published
    Beschreibung: 5632–5636
    Beschreibung: 2.2. Laboratorio di paleomagnetismo
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): geothermal gas ; deep CO2 ; Tiber river delta ; thermogenic CH4 ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 13
    Publikationsdatum: 2020-02-24
    Beschreibung: We present unprecedented data of real-time measurements of the concentration and isotope composition of CO2 in air and in fumarole-plume gases collected in 2013 during two campaigns at Mount Etna volcano, which were made using a laser-based isotope ratio infrared spectrometer. We performed approximately 360 measurements/h, which allowed calculation of the δ13C values of volcanic CO2. The fumarole gases of Torre del Filosofo (2900mabove sea level) range from 3.24 ± 0.06‰to 3.71 ± 0.09‰, comparable to isotope ratio mass spectrometry (IRMS) measurements of discrete samples collected on the same dates. Plume gases sampled more than 1 km from the craters show a δ13C= 2.2 ± 0.4‰, in agreement with the crater fumarole gases analyzed by IRMS. Measurements performed along ~17km driving track from Catania to Mount Etna show more negative δ13C values when passing through populated centers due to anthropogenic-derived CO2 inputs (e.g., car exhaust). The reported results demonstrate that this technique may represent an important advancement for volcanic and environmental monitoring.
    Beschreibung: Published
    Beschreibung: 2382–2389
    Beschreibung: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): Real-time data of CO2 content and δ13C in atmospheric/volcanic gases ; This study opens new perspective for the community for volcanic surveillance ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 14
    Publikationsdatum: 2017-04-04
    Beschreibung: We report on the first geochemical investigation of the Monticchio maar lakes (Mt. Vulture volcano, southern Italy) covering an annual cycle that aimed at understanding the characteristic features of the physical structures and dynamics of the two lakes. We provide the first detailed description of the lakes based on high-resolution CTD profiles, chemical and isotopic (H and O) compositions of the water, and the amounts of dissolved gases (e.g., He, Ar, CH4 and CO2). The combined data set reveals that the two lakes, which are separated by less than 200 m, exhibit different dynamics: one is a meromictic lake, where the waters are rich in biogenic and mantle-derived gases, while the other is a monomictic lake, which exhibits complete turnover of the water in winter and the release of dissolved gases. Our data strongly suggest that the differences in the dynamics of the two lakes are due to different density profiles affected by dissolved solutes, mainly Fe, which is strongly enriched in the deep water of the meromictic lake. A conceptual model of water balance was constructed based on the correlation between the chemical composition of the water and the hydrogen isotopic signature. Gas-rich groundwaters that feed both of the lakes and evaporation processes subsequently modify the water chemistry of the lakes. Our data highlight that no further potential hazardous accumulation of lethal gases is expected at the Monticchio lakes. Nevertheless, geochemical monitoring is needed to prevent the possibility of vigorous gas releases that have previously occurred in historical time.
    Beschreibung: Published
    Beschreibung: 1411–1434
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): geochemistry ; noble gases ; maar lake ; lake dynamics ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 15
    Publikationsdatum: 2017-04-04
    Beschreibung: Despite the advance in our understanding of the carbon exchange between terrestrial ecosystems and the atmosphere, semiarid ecosystems have been poorly investigated and little is known about their role in the global carbon balance. We used eddy covariance measurements to determine the exchange of CO2 between a semiarid steppe and the atmosphere over 3 years. The vegetation is a perennial grassland of Stipa tenacissima L. located in the SE of Spain. We examined diurnal, seasonal and interannual variations in the net ecosystem carbon balance (NECB) in relation to biophysical variables. Cumulative NECB was a net source of 65.7, 143.6 and 92.1 g C mˉ2 yrˉ1 for the 3 years studied, respectively. We separated the year into two distinctive periods: dry period and growing season. The ecosystem was a net source of CO2 to the atmosphere, particularly during the dry period when large CO2 positive fluxes of up to 15 μmol mˉ2 sˉ1 were observed in concomitance with large wind speeds. Over the growing season, the ecosystem was a slight sink or neutral with maximum rates of -2.3 μmol mˉ2 sˉ1. Rainfall events caused large fluxes of CO2 to the atmosphere and determined the length of the growing season. In this season, photosynthetic photon flux density controlled day-time NECB just below 1000 μmol mˉ2 sˉ1. The analyses of the diurnal and seasonal data and preliminary geological and gas-geochemical evaluations, including C isotopic analyses, suggest that the CO2 released was not only biogenic but most likely included a component of geothermal origin, presumably related to deep fluids occurring in the area. These results highlight the importance of considering geological carbon sources, as well as the need to carefully interpret the results of eddy covariance partitioning techniques when applied in geologically active areas potentially affected by CO2-rich geofluid circulation.
    Beschreibung: Published
    Beschreibung: 539–554
    Beschreibung: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): alpha grass ; carbon sequestration ; ecosystem respiration ; eddy covariance ; geogas ; geothermal activity ; grasslands ; net ecosystem carbon balance ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 16
    Publikationsdatum: 2017-04-03
    Beschreibung: Here we report new data on the sulfur isotopic compositions (d34S) of fumarolic and plume gases collected at Mount Etna volcano during 2008–2009. While low-temperature fumaroles are affected by postmagmatic processes that modify the pristine isotopic signature, high-temperature and plume gases allow establishment of a d34S range of 0 1‰ for magmatic SO2. We compared our data with those from S dissolved in primitive melt inclusions from 2002 lava and in whole rocks that erupted during the past two thousand years. Such a comparison revealed that d34S is systematically lower for magmatic gases than for sulfur dissolved in the melt. We modeled how isotopic fractionation due to magma degassing process may vary d34S value in both the melt and gaseous phases. This modeling required assessment of the fractionation factor (agas-melt). The most recent measurements on the oxidation state of sulfur in basaltic melt inclusions indicate that nearly all S is dissolved as sulfate (S6+), which would be possible in oxidized magmatic systems (DNNO ≥ 1). Under these conditions the exsolved gaseous phase is depleted with respect to the melt and the proposed model fits both gas and melt data, and constrains the Etnean magmatic d34S to 1.0 1.5‰. It is remarkable that the assessed redox conditions—which are significantly more oxidizing than previously thought—are able to explain why the dominant sulfur species measured in the Etnean plume is SO2.
    Beschreibung: Published
    Beschreibung: Q05015
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): Mount Etna ; SO2 ; degassing ; fumarole ; plume ; sulfur isotope ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 17
    Publikationsdatum: 2017-04-04
    Beschreibung: Volcanic rift zones, characterized by repeated dike emplacements, are expected to delimit the upper portion of unstable flanks at basaltic edifices. We use nearly two decades of InSAR observations excluding wintertime acquisitions, to analyze the relationships between rift zones, dike emplacement and flank instability at Etna. The results highlight a general eastward shift of the volcano summit, including the northeast and south rifts. This steadystate eastward movement (1-2 cm/yr) is interrupted or even reversed during transient dike injections. Detailed analysis of the northeast rift shows that only during phases of dike injection, as in 2002, does the rift transiently becomes the upper border of the unstable flank. The flank's steady-state eastward movement is inferred to result from the interplay between magmatic activity, asymmetric topographic unbuttressing, and east-dipping detachment geometry at its base. This study documents the first evidence of steady-state volcano rift instability interrupted by transient dike injection at basaltic edifices.
    Beschreibung: Partially funded by INGV and the Italian DPC (DPC-INGV project V4 “Flank”). ERS and ENVISAT SAR data were provided by ESA through the Cat-1 project no. 4532 and the GEO Supersite initiative. The DEM was obtained from the SRTM archive. ERS-1/2 orbits are courtesy of the TU-Delft, The Netherlands. SAR data processing has been done at IREACNR, partially carried out under contract “Volcanic Risk System (SRV)” funded by the Italian Space Agency (ASI).
    Beschreibung: Published
    Beschreibung: L20311
    Beschreibung: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Beschreibung: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Beschreibung: 1.10. TTC - Telerilevamento
    Beschreibung: 3.2. Tettonica attiva
    Beschreibung: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Beschreibung: 3.6. Fisica del vulcanismo
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): flank instability ; rift zones ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.03. Geodesy::04.03.09. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 18
    Publikationsdatum: 2023-01-16
    Beschreibung: The April–May 2010 eruption of the Eyjafjallajökull volcano (Iceland) was characterized by a nearly continuous injection of tephra into the atmosphere that affected various economic sectors in Iceland and caused a global interruption of air traffic. Eruptive activity during 4–8 May 2010 was characterized based on short-duration physical parameters in order to capture transient eruptive behavior of a long-lasting eruption (i.e., total grain-size distribution, erupted mass, and mass eruption rate averaged over 30 min activity). The resulting 30 min total grain-size distribution based on both ground and Meteosat Second Generation-Spinning Enhanced Visible and Infrared Imager (MSG-SEVIRI) satellite measurements is characterized by Mdphi of about 2 and a fine-ash content of about 30 wt %. The accumulation rate varied by 2 orders of magnitude with an exponential decay away from the vent, whereas Mdphi shows a linear increase until about 18 km from the vent, reaching a plateau of about 4.5 between 20 and 56 km. The associated mass eruption rate is between 0.6 and 1.2 × 105 kg s−1. In situ sampling showed how fine ash mainly fell as aggregates of various typologies. About 5 to 9 wt % of the erupted mass remained in the cloud up to 1000 km from the vent, suggesting that nearly half of the ash 〉7 settled as aggregates within the first 60 km. Particle sphericity and shape factor varied between 0.4 and 1 with no clear correlation to the size and distance from vent. Our experiments also demonstrate how satellite retrievals and Doppler radar grain-size detection can provide a real-time description of the source term but for a limited particle-size range.
    Beschreibung: Published
    Beschreibung: B12202
    Beschreibung: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): MSG-SEVIRI, PLUDIX ; particle aggregation ; settling velocity ; tephra deposits ; weak plumes ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 19
    Publikationsdatum: 2012-02-03
    Beschreibung: A simple linear relation can be used to link time averaged discharge rate (TADR) and lava flow area (A). The relation applies to given insulation conditions, as described by the characteristic flow surface temperature (Te), and will vary from case-to-case depending on rheological and topographic influences on flow spreading. Most flows have insulation conditions that change through time, modifying the relationship between TADR and area as insulation conditions evolve. Using lidar data we can define TADR, the flow area that the discharge feeds and Te, allowing generation of a case-specific relation to convert satellite-data-derived flow areas to TADR. For Etna's 2006 lava flow field we obtain a relation whereby TADR = 5.6 × 10−6 A for well insulated conditions (Te = 100°C) and TADR = 1.5 × 10−4 A for poorly insulated conditions (Te = 600°C).
    Beschreibung: Published
    Beschreibung: L20308
    Beschreibung: 1.10. TTC - Telerilevamento
    Beschreibung: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Beschreibung: 3.6. Fisica del vulcanismo
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): lava flow ; discharge rate ; area ; surface temperature ; lidar ; Etna. ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 20
    Publikationsdatum: 2017-04-04
    Beschreibung: Methane soil flux measurements have been made in 38 sites at the geothermal system of Sousaki (Greece) with the closed chamber method. Fluxes range from –47.6 to 29,150 mg m-2 d-1 and the diffuse CH4 output of the system has been estimated at 19 t a-1. Contemporaneous CO2 flux measurements showed a moderate positive correlation between CO2 and CH4 fluxes. Comparison of the CO2/CH4 soil flux ratios with the CO2/CH4 ratio of the gases of the main gas manifestations provided evidence for methanotrophic activity within the soil. Laboratory CH4 consumption experiments confirmed the presence of methanotrophic microorganisms in soil samples collected at Sousaki. Consumption was generally in the range from –4.9 to –38.9 pmolCH4 h-1 g-1 but could sometimes reach extremely high values (–33,000 pmolCH4 h-1 g-1.). These results are consistent with recent studies on other geothermal systems that revealed the existence of thermoacidophilic bacteria exerting methanotrophic activity in hot, acid soils, thereby reducing methane emissions to the atmosphere.
    Beschreibung: Published
    Beschreibung: 97–107
    Beschreibung: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Sousaki ; accumulation chamber ; soil degassing ; hydrothermal systems ; methane output ; methanotrophic activity ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 21
    Publikationsdatum: 2017-04-04
    Beschreibung: Assessment of the hazard from lava flow inundation at the active volcano of Mount Etna, Italy, was performed by calculating the probability of lava flow inundation at each position on the volcano. A probability distribution for the formation of new vents was calculated using geological and volcanological data from past eruptions. The simulated lava flows from these vents were emplaced using a maximum expected flow length derived from geological data on previous lava flows. Simulations were run using DOWNFLOW, a digital-elevation-model-based model designed to predict lava flow paths. Different eruptive scenarios were simulated by varying the elevation and probability distribution of eruptive points. Inundation maps show that the city of Catania and the coastal zone may only be impacted by flows erupted from low-altitude vents (〈1500 m elevation) and that flank eruptions at elevations 〉2000 m preferentially inundate the northeast and southern sectors of the volcano as well as the Valle del Bove. Eruptions occurring in the summit area (〉3000 m elevation) pose no threat to the local population. Discrepancies between the results of simple, hydrological models and those of the DOWNFLOW model show that hydrological approaches are inappropriate when dealing with Etnean lava flows. Because hydrological approaches are not designed to reproduce the full complexity of lava flow spreading, they underestimate the catchment basins when the fluid has a complex rheology.
    Beschreibung: Published
    Beschreibung: F01019
    Beschreibung: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Beschreibung: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): volcanic hazard ; lava flow ; Mount Etna ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 22
    Publikationsdatum: 2017-04-04
    Beschreibung: Long duration time-series of the chemical composition of fumaroles and of soil CO2 flux reveal that important variations in the activity of the Solfatara fumarolic field, the most important hydrothermal site of Campi Flegrei, occurred in the 2000-2008 period. A continuous increase of the CO2 concentrations, and a general decrease of the CH4 concentrations are interpreted as the consequence of the increment of the relative amount of magmatic fluids, rich in CO2 and poor in CH4, hosted by the hydrothermal system. Contemporaneously, the H2O-CO2-He-N2 gas system shows remarkable compositional variations in the samples collected after July 2000 with respect to the previous ones, indicating the progressive arrival at the surface of a magmatic component different from that involved in the 1983-84 episode of volcanic unrest (1983-1984 bradyseism). The change starts in 2000 concurrently with the occurrence of relatively deep, long-period seismic events which were the indicator of the opening of an easy-ascent pathway for the transfer of magmatic fluids towards the shallower, brittle domain hosting the hydrothermal system. Since 2000, this magmatic gas source is active and causes ground deformations, seismicity as well as the expansion of the area affected by soil degassing of deeply derived CO2. Even though the activity will most probably be limited to the expulsion of large amounts of gases and thermal energy, as observed in other volcanoes and in the past activity of Campi Flegrei, the behavior of the system in the future is, at the moment, unpredictable.
    Beschreibung: Published
    Beschreibung: B03205
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: 2.4. TTC - Laboratori di geochimica dei fluidi
    Beschreibung: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Campi Flegrei ; CO2 ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 23
    Publikationsdatum: 2012-02-03
    Beschreibung: An edited version of this paper was published by AGU. Copyright (2010) American Geophysical Union
    Beschreibung: Seismic, deformation, and volcanic gas observations offer independent and complementary information on the activity state and dynamics of quiescent and eruptive volcanoes and thus all contribute to volcanic risk assessment. In spite of their wide use, there have been only a few efforts to systematically integrate and compare the results of these different monitoring techniques. Here we combine seismic (volcanic tremor and long‐period seismicity), deformation (GPS), and geochemical (volcanic gas plume CO2/SO2 ratios) measurements in an attempt to interpret trends in the recent (2007–2008) activity of Etna volcano. We show that each eruptive episode occurring at the Southeast Crater (SEC) was preceded by a cyclic phase of increase‐decrease of plume CO2/SO2 ratios and by inflation of the volcano’s summit captured by the GPS network. These observations are interpreted as reflecting the persistent supply of CO2‐rich gas bubbles (and eventually more primitive magmas) to a shallow (depth of 1–2.8 km asl) magma storage zone below the volcano’s central craters (CCs). Overpressuring of the resident magma stored in the upper CCs’ conduit triggers further magma ascent and finally eruption at SEC, a process which we capture as an abrupt increase in tremor amplitude, an upward (〉2800 m asl) and eastward migration of the source location of seismic tremor, and a rapid contraction of the volcano’s summit. Resumption of volcanic activity at SEC was also systematically anticipated by declining plume CO2/SO2 ratios, consistent with magma degassing being diverted from the central conduit area (toward SEC).
    Beschreibung: Published
    Beschreibung: Q09008
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Beschreibung: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): volcano monitoring ; Mt. Etna volcano ; geochemistry and geophysics ; volcanic tremor ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 24
    Publikationsdatum: 2017-04-04
    Beschreibung: Long time series of fumarolic compositions at Campi Flegrei (Italy), Mammoth Mountain (California), Panarea (Italy) and Nisyros (Greece) show rapid increases, up to orders of magnitude, of the CO2/CH4 ratio systematically with the occurrence of volcanic unrest periods. These easily detected anomalies originate with the arrival of CH4-poor magmatic fluids in the shallower levels of the volcanoes. The data suggest that volcanoes are characterized by magmatic activity at depth also in periods of apparent quiescence. The activity is constituted by the pulsing release of large amount of fluids which either cause unrest periods (seismicity and ground deformation) or possibly could precede volcanic eruption. This type of volcanic activity can be monitored trough the classical geophysical techniques together with the systematic sampling and analysis of fumaroles.
    Beschreibung: Published
    Beschreibung: L02302
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: 2.4. TTC - Laboratori di geochimica dei fluidi
    Beschreibung: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): CO2/CH4 ; magma degassing ; quiescent volcanoes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 25
    Publikationsdatum: 2017-04-04
    Beschreibung: This thematic issue of Geofluids includes 11 papers representing the three main topics discussed in the 10th edition of the International Conference on Gas Geochemistry (ICGG-10): (i) gas in petroleum systems and seepage, (ii) gas in geothermal systems and volcanoes and (iii) gas, seismicity and geohazards. ICGG-10 was held in 2009 in Romania, a country extraordinarily rich in surface gas manifestations, that offers innumerable opportunities for innovative studies on gas geochemistry. We briefly describe the present knowledge on gases occurring both in petroliferous sedimentary basins and geothermal areas of Romania. The 11 contributions of this special issue, which include data from eight countries, are then summarised. Based on these papers and other works presented at the ICGG-10, we find that significant advances in analytical capabilities, data treating and interpretation have led to innovative insights into the origin, distribution and environmental impact of gases migrating to the Earth’s surface. It is increasingly clear, in particular, that gas geochemistry can be more effective for petroleum exploration, volcano-tectonic, geodynamic and environmental studies, if multiparametric studies are performed and the data are interpreted in the geological context.
    Beschreibung: Published
    Beschreibung: 457-462
    Beschreibung: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): geothermal gas ; international conference on gas geochemistry ; natural gas ; romania ; seeps ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 26
    Publikationsdatum: 2017-04-04
    Beschreibung: Natural gas seeps in the Alpine region are poorly investigated. However, they can provide useful information regarding the hydrocarbon potential of sedimentary Alpine units and related geofluid migration, typically controlled by pressurized gas accumulations and tectonics. A gas seep located near Giswil, in the Swiss Northern Alps, was investigated, for the first time, for molecular and isotopic gas composition, methane flux to the atmosphere, and gas flux variations over time. The analyses indicated that the gas was thermogenic (CH4 〉 96%; d13C1: )35.5& to )40.2&) and showed evidence of subsurface petroleum biodegradation (13C-enriched CO2, and very low C3+ concentrations). The source rock in the region is marine Type II kerogen, which is likely the same as that providing thermogenic gas in the nearby Wilen shallow well, close to Lake Sarnen. However, the lack of d13CCO2 and d13C3 data for that well prevented us from determining whether the Wilen and Giswil seeps are fed by the same reservoir and seepage system. Gas fluxes from the Giswil seep, measured using a closedchamber system, were significant and mainly from two major vents. However, a substantial gas exhalation from the soil occurs diffusely in an area of at least 115 m2, leading to a total CH4 output conservatively estimated to be at least 16 tonnes per year. Gas flux variations, monitored over a 1-month period by a special tent and flowmeter, showed not only daily meteorological oscillations, but also an intrinsic ‘pulsation’ with periods of enhanced flux that lasted 2–6 h each, occurring every few days. The pulses are likely related to episodes of gas pressure build-up and discharge along the seepage system. However, to date, no relationship to seismicity in the active Sarnen strike-slip fault system has been established.
    Beschreibung: Published
    Beschreibung: 476-485
    Beschreibung: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): Alps ; isotopes ; methane ; organic geochemistry ; seeps ; Switzerland ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 27
    Publikationsdatum: 2017-04-04
    Beschreibung: Flank instability is common at volcanoes, even though the subsurface structures, including the depth to a detachment fault, remain poorly constrained. Here, we use a multidisciplinary approach, applicable to most volcanoes, to evaluate the detachment depth of the unstable NE flank of Mt. Etna. InSAR observations of Mount Etna during 1995–2008 show a trapdoor subsidence of the upper NE flank, with a maximum deformation against the NE Rift. The trapdoor tilt was highest in magnitude in 2002–2004, contemporaneous with the maximum rates of eastward slip along the east flank. We explain this deformation as due to a general eastward displacement of the flank, activating a rotational detachment and forming a rollover anticline, the head of which is against the NE Rift. Established 2D rollover construction models, constrained by morphological and structural data, suggest that the east‐dipping detachment below the upper NE flank lies at around 4 km below the surface. This depth is consistent with seismicity that clusters above 2–3 km below sea level. Therefore, the episodically unstable NE flank lies above an east‐dipping rotational detachment confined by the NE Rift and Pernicana Fault. Our approach, which combines short‐term (InSAR) and long‐term (geological) observations, constrains the 3D geometry and kinematics of part of the unstable flank of Etna and may be applicable and effective to understand the deeper structure of volcanoes undergoing flank instability or unrest.
    Beschreibung: This work was partially funded by INGV and the DPC‐INGV project “Flank”, and partially by the ASI (SRV project).
    Beschreibung: Published
    Beschreibung: L16304
    Beschreibung: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Beschreibung: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Beschreibung: 1.10. TTC - Telerilevamento
    Beschreibung: 3.2. Tettonica attiva
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): flank instability ; fault ; InSAR ; Etna ; rollover ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 28
    Publikationsdatum: 2017-04-04
    Beschreibung: Volcanoes deform as a consequence of the rise and storage of magma; once magma reaches a critical pressure, an eruption occurs. However, how the edifice deformation relates to its eruptive behavior is poorly known. Here, we produce a joint interpretation of spaceborne InSAR deformation measurements and volcanic activity at Mt. Etna (Italy), between 1992 and 2006. We distinguish two volcano-tectonic behaviors. Between 1993 and 2000, Etna inflated with a starting deformation rate of 1 cm yr 1 that progressively reduced with time, nearly vanishing between 1998 and 2000; moreover, low-eruptive rate summit eruptions occurred, punctuated by lava fountains. Between 2001 and 2005, Etna deflated, feeding higher-eruptive rate flank eruptions, along with large displacements of the entire East-flank. These two behaviors, we suggest, result from the higher rate of magma stored between 1993 and June 2001, which triggered the emplacement of the dike responsible for the 2001 and 2002–2003 eruptions. Our results clearly show that the joint interpretation of volcano deformation and stored magma rates may be crucial in identifying impending volcanic eruptions.
    Beschreibung: This work was partly funded by INGV and the Italian DPC and was supported by ASI, the Preview Project and CRdC-AMRA. DPC-INGV Flank project providing the funds for the publication fees.
    Beschreibung: Published
    Beschreibung: L02309
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Beschreibung: 1.10. TTC - Telerilevamento
    Beschreibung: 3.6. Fisica del vulcanismo
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: 4.5. Degassamento naturale
    Beschreibung: JCR Journal
    Beschreibung: partially_open
    Schlagwort(e): deformation ; eruptions ; Mt. Etna ; eruptive cycle ; InSAR ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 29
    Publikationsdatum: 2017-04-04
    Beschreibung: The soil CO2 flux on Mt. Etna as recorded by the ETNAGAS network (an automatic system for measuring soil CO2 flux and meteorological parameters) started to increase strongly about 5 months prior to the onset of the 2004–2005 eruption and decreased a few months before the end of the eruption. Time delays in the occurrences of anomalies in soil CO2 flux at different sites in the geochemical network constrain the relationship between soil CO2 flux distributions and the tectonic framework of Etna volcano. The anomalies observed before the 2004–2005 eruption support the intrusion of new undegassed magma into the upper feeding system of the volcano (〈20 km below sea level). Magma subsequently rose slowly in the volcano conduits, thereby triggering the onset of the 2004–2005 eruption. The time delays in the occurrences of anomalies in combination with spectral analysis indicate the importance of tectonic and volcanotectonic structures in driving the ascent of deep gases within the crust. Moreover, greatest amplitude pulsations of the low-frequency components of the CO2 flux signals were correlated with the paroxystic activities of the 2004–2005 eruption. This study confirms that CO2 flux variation is a useful indicator for volcanic activity in the surveillance of the Mt. Etna and similar basaltic volcanoes.
    Beschreibung: Dipartimento Protezione Civile Ministero degli Interni
    Beschreibung: Published
    Beschreibung: B09206
    Beschreibung: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): CO2 flux ; Continuous monitoring of soil CO2 flux ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 30
    Publikationsdatum: 2017-04-04
    Beschreibung: Repeated phenomena of flank instability accompanied the 28 December 2002 to 21 July 2003 eruption of Stromboli volcano. The major episodes were two tsunamigenic landslides on 30 December 2002, 2 d after the volcano unrest. After 30 December, sliding processes remodeled the area affected by slope instability.We propose analyses of 565 sliding episodes taking place from December 2002 to February 2003.We try to shed light on their main seismic features and links with the ongoing seismic and volcanic activity using variogram analysis as well. A characterization of the seismic signals in the time and frequency domains is presented for 185 sliding episodes. Their frequency content is between 1 Hz and 7 Hz. On the basis of the dominant peaks and shape of the spectrum, we identify three subclasses of signals, one of which has significant energy below 2 Hz. Low-frequency signatures were also found in the seismic records of the landslides of 30 December, which affected the aerial and submarine northwestern flank of the volcano. Accordingly, we surmise that spectral analysis might provide evidence of sliding phenomena with submarine runouts.We find no evidence of sliding processes induced by earthquakes. Additionally, a negative statistical correlation between sliding episodes and explosion quakes is highlighted by variogram analysis. Variograms indicate a persistent behavior, memory, of the flank instability from 5 to 10 d.We interpret the climax in the occurrence rate of the sliding processes between 24 and 29 January 2003 as the result of favorable conditions to slope instability due to the emplacement of NW-SE aligned, dike-fed vents located near the scarp of the landslide area. Afterward, the stabilizing effect of the lava flows over the northwestern flank of the volcano limited erosive phenomena to the unstable, loose slope not covered by lava.
    Beschreibung: This work was supported financially by Istituto Nazionale di Geofisica e Vulcanologia and Dipartimento per la Protezione Civile, project INGV-DPC V4/02.
    Beschreibung: Published
    Beschreibung: Q04022
    Beschreibung: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Beschreibung: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Beschreibung: 3.6. Fisica del vulcanismo
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): rockfalls ; seismicity ; volcanoes ; volcano collapses ; Stromboli ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 31
    Publikationsdatum: 2017-04-04
    Beschreibung: We report the first measurements of volcanic gases with an unmanned aerial vehicle (UAV). The data were collected at La Fossa crater, Vulcano, Italy, during April 2007, with a helicopter UAV of 3 kg payload, carrying an ultraviolet spectrometer for remotely sensing the SO2 flux (8.5 Mg d 1), and an infrared spectrometer, and electrochemical sensor assembly for measuring the plume CO2/SO2 ratio; by multiplying these data we compute a CO2 flux of 170 Mg d 1. Given the deeper exsolution of carbon dioxide from magma, and its lower solubility in hydro-thermal systems, relative to SO2, the ability to remotely measure CO2 fluxes is significant, with promise to provide more profound geochemical insights, and earlier eruption forecasts, than possible with SO2 fluxes alone: the most ubiquitous current source of remotely sensed volcanic gas data.
    Beschreibung: Published
    Beschreibung: L06303
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Plume measurements ; carbon dioxide fluxes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 32
    Publikationsdatum: 2017-04-04
    Beschreibung: Long time series of fumarolic compositions at Campi Flegrei (Italy), Mammoth Mountain (California), Panarea (Italy) and Nisyros (Greece) show rapid increases, up to orders of magnitude, of the CO2/CH4 ratio systematically with the occurrence of volcanic unrest periods. These easily detected anomalies originate with the arrival of CH4-poor magmatic fluids in the shallower levels of the volcanoes. The data suggest that volcanoes are characterized by magmatic activity at depth also in periods of apparent quiescence. The activity is constituted by the pulsing release of large amount of fluids which either cause unrest periods (seismicity and ground deformation) or possibly could precede volcanic eruption. This type of volcanic activity can be monitored trough the classical geophysical techniques together with the systematic sampling and analysis of fumaroles.
    Beschreibung: In press
    Beschreibung: 4.5. Degassamento naturale
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): fumarole ; magma degassing ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 33
    Publikationsdatum: 2017-04-04
    Beschreibung: Two-dimensional cross sections of the sulphur dioxide (SO2) distribution in the volcanic gas plume of Mt. Etna were reconstructed using tomographic techniques. The data for these projections were generated by a network of five automated scanning spectrometers, positioned on the flanks of the volcano. These measure slant-column amounts of SO2 at 105 different angles, every four minutes. Stable wind conditions allow the plume to be monitored on 82% of days. A time-series of plume cross sections was computed, revealing the potential of this method to track variations in plume position and structure on timescales of minutes to hours, a result of potential importance for air traffic and civil defence in case of eruption, when copious amounts of fine ash can be transported.
    Beschreibung: Published
    Beschreibung: L17811
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): tomography ; SO2 ; DOAS ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 34
    Publikationsdatum: 2017-04-04
    Beschreibung: Soil temperature and total dissolved gas pressure(TDGP) data were recorded by two continuous monitoring stations on the volcano of Stromboli (Italy) between March and October 2006. During this period several TDGP and soil temperature anomalies, unrelated to external causes and characterized by a similar shape and occurrence time, were recorded. These anomalies were interpreted as transients due to changes in the degassing regime of the volcano,which was in turn related to changes in the partition ratio of the volcanic fluidsbetweenthe conduitandthe soil. In thesame period Stromboli experienced an anomalous phase of volcanic and tectonic activity. The close correlation found between volcano-tectonic activity and variations in anomalousmonitored parameters suggests that their continuous monitoring may be a useful tool for the surveillance of volcanic activity on the island.
    Beschreibung: Published
    Beschreibung: L08301
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Dissolved gases ; Soil temperature ; Total dissolved gas pressure ; Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 35
    Publikationsdatum: 2017-04-04
    Beschreibung: An application of light detection and ranging (lidar) intensity for the identification and mapping of different lava flows from the Mount Etna (Italy) active volcano is described. In September 2004 an airborne lidar survey was flown over summit sectors of Mount Etna. The information derived from lidar intensity values was used to compare the lava flows with respect to their age of emplacement. Analyzed lava flows vary in age between those dating prior to A.D. 1610 and those active during the survey (2004–2005 eruptions). The target-emitter distance, as well as surface roughness and texture at the lidar footprint scale, is the main parameter controlling the intensity response of lava flows. Variations in the roughness and texture of surfaces at a meter scale result from two main processes, initial lava cooling and subsequent surface weathering; both lead to variations in the original surface roughness of the flow. In summary: (1) initially, from the time of emplacement, the lidar intensity of lava flow surfaces decreases and (2) about 6 years after emplacement the lidar intensity of lava surfaces starts to increase with the age of flows. Lidar capability in terms of geometric (accuracy of ∼1 m in plan position and less than 1 m in elevation) and spectral (lidar intensity depends on surface reflection at λ = 1.064 μm) information can thus be effectively used to map lava flows and to define a relative chronology of lava emplacement.
    Beschreibung: Published
    Beschreibung: B02201
    Beschreibung: 3.6. Fisica del vulcanismo
    Beschreibung: 3.5. Geologia e storia dei sistemi vulcanici
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): lava flows ; mapping ; lidar ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 36
    Publikationsdatum: 2017-04-04
    Beschreibung: Sulphur speciation in volcanic gases acts as a major redox buffer, and H2S/SO2 ratios represent a valuable indicator of magmatic conditions and interactions between magmatic and hydrothermal fluids. However, measurement of H2S/SO2 even by direct sampling techniques, is not straightforward. We report here on application of a small ultraviolet spectrometer for real-time field measurement of H2S and SO2 concentrations, using open-path and extractive configurations. The device was tested at fumaroles on Solfatara and Vulcano, Italy, in November 2002. H2S concentrations of up to 220ppmm(400 ppmv) were measured directly above the Bocca Grande fumarole at Solfatara, and H2S/SO2 molar ratios of 2 and 2.4, respectively, were determined for the ‘F11’ and ‘F0’ fumaroles at Vulcano. In comparison with other optical techniques capable of multiple volcanic gas measurements, such as laser and FTIR spectroscopy, this approach is considerably simpler and cheaper, with the potential for autonomous, sustained hightime resolution operation.
    Beschreibung: Published
    Beschreibung: 1652
    Beschreibung: partially_open
    Schlagwort(e): Remote monitoring ; Plume chemistry ; sulphur species ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 37
    Publikationsdatum: 2017-04-04
    Beschreibung: The recent eruption of Mount Etna (July 2001) offered the opportunity to analyze magma-derived volatiles emitted during preand syn-eruptive phases, and to verify whether their composition is affected by changes in volcanic dynamics. This paper presents the results of analyses of F, Cl and S in the volcanic plume collected by filter-packs, and interprets variations in the composition based on contrasting solubility in magmas. A Rayleigh-type degassing mechanism was used to fit the acquired data and to estimate Henryâ s solubility constant ratios in Etnean basalt. This model provided insights into the dynamics of the volcano. Abundances of sulfur and halogens in eruptive plumes may help predict the temporal evolution of an ongoing effusive eruption.
    Beschreibung: -Gruppo Nazionale per la Vulcanologia.
    Beschreibung: Published
    Beschreibung: 1559
    Beschreibung: partially_open
    Schlagwort(e): magmatic degassing ; acidic gases ; plume chemistry ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 38
    Publikationsdatum: 2017-04-04
    Beschreibung: Volcanic gas emissions from fumaroles on the rim of La Fossa crater, Vulcano Island, Italy, were measured simultaneously using direct sampling (for H2O, CO2, total sulfur, HCl and HF), filter packs (for SO2, HCl, HF) and short-path active-mode FTIR measurements (for H2O, CO2,SO2, HCl and HF) in an intercomparison study in May 2002. The results show that Cl/F ratios were in good agreement between all three methods, and that FTIR and direct sampling determined comparable proportions of CO2 and H2O. Amounts of total S observed in direct sampling data were approximately double the amounts of SO2 measured with filter packs and FTIR. This difference could be attributed either to the fact FTIR and filter packs do not measure reduced sulfur species (e.g., H2S) or to sublimation of elemental S upon exit from the fumarole, after collection by direct sampling but before detection with FTIR and filter packs.
    Beschreibung: Published
    Beschreibung: L02610
    Beschreibung: partially_open
    Schlagwort(e): volcanic gas techniques ; gas geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 39
    Publikationsdatum: 2017-04-04
    Beschreibung: A new method for extracting dissolved gases in natural waters has been developed and tested, both in the laboratory and in the field. The sampling device consists of a polytetrafluroethylene (PTFE) tube (waterproof and gas permeable) sealed at one end and connected to a glass sample holder at the other end. The device is pre-evacuated and subsequently dipped in water, where the dissolved gases permeate through the PTFE tube until the pressure inside the system reaches equilibrium. A theoretical model describing the time variation in partial gas pressure inside a sampling device has been elaborated, combining the mass balance and ‘‘Solution-Diffusion Model’’ which describes the gas permeation process through a PTFE membrane). This theoretical model was used to predict the temporal evolution of the partial pressure of each gas species in the sampling device. The model was validated by numerous laboratory tests. The method was applied to the groundwater of Vulcano Island (southern Italy). The results suggest that the new sampling device could easily extract the dissolved gases from water in order to determine their chemical and isotopic composition.
    Beschreibung: - European Social Fund.
    Beschreibung: Published
    Beschreibung: Q09005
    Beschreibung: partially_open
    Schlagwort(e): dissolved gases ; helium isotope ; PTFE membrane ; Vulcano Island ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.02. Hydrology::03.02.07. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 40
    Publikationsdatum: 2017-04-04
    Beschreibung: Ground-based measurements of volcanic sulfur dioxide fluxes are important indicators of volcanic activity, with application in hazard assessment, and understanding the impacts of volcanic emissions upon the environment and climate. These data are obtained by making traverses underneath the volcanic plume a few kilometers from source with an ultraviolet spectrometer, measuring integrated SO2 concentrations across the plume’s cross section, and multiplying by the plume’s transport speed. However, plume velocities are usually derived from ground-based anemometers, located many kilometers from the traverse route and hundreds of meters below plume altitude, complicating the experimental design and introducing large flux (can be 〉100%) errors. Here we present the first report of a single instrument capable of (accurate) volcanic SO2 flux measurements. This device records integrated SO2 concentrations and plume heights during traverses. Between traverses, two in-plume SO2 time series are measured from underneath the plume with the instrument, corresponding to zenith and inclined (user-specified angle from vertical in the direction of the volcano) fields of view, respectively. The distance between the points of intersection of the two views with the plume is found on the basis of the determined plume height, and the two signals are cross-correlated to determine the lag between them, enabling accurate derivation of the wind speed. We present flux data (with errors ±12%) obtained in this way at Mt. Etna during July 2004.
    Beschreibung: Published
    Beschreibung: Q02003
    Beschreibung: partially_open
    Schlagwort(e): DOAS ; volcanic SO2 emissions. ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 41
    Publikationsdatum: 2017-04-04
    Beschreibung: The performance of a newly-developed portable gas analyzer, capable of real-time measurement of CO2, SO2 and H2S concentrations in volcanic gases, was tested at La Fossa Crater, Vulcano Island. The gas analyzer was used to acquire about 3000 determinations over the fumarolic field, allowing the definition of its chemical structure and heterogeneity. Our high-resolution analysis reveals that, in December 2004, the La Fossa fumarolic field was characterized by an oxidized inner core (SO2/H2S ratios of 3), and by more reducing conditions on its northern edge (SO2/H2S ratios of 1; range: 0.2–3.3). CO2/(SO2+H2S) molar ratios averaged 35 ± 21, with overlapping compositions for rim and inner crater fumaroles. S-poor compositions (CO2/(SO2+H2S) 50) characterized the field margins, probably due to deposition of native sulfur. Based on the above data and an SO2 flux of 18 ± 3 t.d-1, we estimate CO2 and H2S output rates from the volcano of 420 ± 250 and 4 ± 2 t.d-1, respectively.
    Beschreibung: Published
    Beschreibung: L13309
    Beschreibung: partially_open
    Schlagwort(e): electrochemical sensors ; fumarolic gases ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 42
    Publikationsdatum: 2017-04-04
    Beschreibung: We present the first regional map of CO2 Earth degassing from a large area (most of central and south Italy) derived from the carbon of deep provenance dissolved in the main springs of the region. The investigation shows that a globally significant amount of deeply derived CO2 (10% of the estimated global CO2 emitted from subaerial volcanoes) is released by two large areas located in western Italy. The anomalous flux of CO2 suddenly disappears in the Apennine in correspondence to a narrow band where most of seismicity concentrates. Here, at depth, the gas accumulates in crustal traps generating CO2 overpressurized reservoirs which induce seismicity.
    Beschreibung: Published
    Beschreibung: 1-4
    Beschreibung: partially_open
    Schlagwort(e): Carbon dioxide ; Central Italy ; Southern Italy ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 43
    Publikationsdatum: 2017-04-04
    Beschreibung: Five gas discharges in the area of Mount Etna volcano (Italy) and in the near Hyblean plateau have been monitored since 1996. All the emissions displayed low contributions from crustal fluids, whereas magmatic gases were the main component. Selective dissolution of these gases into hydrothermal aquifers has been recognized and modeled, allowing us to calculate the original composition of the magma-released gases. The inferred composition of the magmatic gases exhibits synchronous variations of He/Ne and He/CO2 ratios, which are coherent with the magma degassing process. On the basis of numerical simulations of volatile degassing from Etnean basalts we have computed the initial and final pressures of the magma batches feeding the emissions. We thus can define the levels of the Etna plumbing system where magmas are stored. Pressure values were around 360 and 160 MPa for initial and final stages, respectively, meaning related depths of about 10 and 3 km below sea level, matching those obtained by geophysical investigations for the deep and shallow magma reservoirs. In addition, we have been able to recognize episodes of magma migration from the deeper reservoir toward the shallow one. An important magma injection into the shallow storage volume was detected during the onset of the 2001 eruption (17 July). No further injection had taken place during this period until September 2001, providing a possible reason for the quick exhaustion of the eruption. In view of this we suggest that the sampled emissions are a powerful geochemical tool to investigate the Etna’s plumbing system and its magma dynamics, as well as the development of eruptive events.
    Beschreibung: Published
    Beschreibung: 2463
    Beschreibung: partially_open
    Schlagwort(e): gas geochemistry ; magma degassing ; modeling ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 44
    Publikationsdatum: 2017-04-04
    Beschreibung: We report results on the measured high 3He/4He isotope ratio in western Sicily, interpreted together with the heat data. The study of this sector of the Europe-Africa interaction is crucial to a better understanding of the tectonics and the geodynamical evolution of the central Mediterranean area. The estimated mantle-derived helium fluxes in the investigated areas are up to 2–3 orders of magnitude greater than those of a stable continental area. The highest flux, found in the southernmost area near the Sicily Channel, where recent eruptions of the Ferdinandea Island occurred 20 miles out to sea off Sciacca, has been associated with a clear excess of heat flow. Our results indicate that there is an accumulation of magma below the continental crust of western Sicily that is possibly intruding and out-gassing through roughly N-S trending deep fault systems linked to the mantle, that have an extensional component. Although the identification of these faults is not sufficiently constrained by our data, they could possibly be linked to the pre-existing faults that originated during the Mesozoic extensional-transtensional tectonic phases.
    Beschreibung: Published
    Beschreibung: L04312
    Beschreibung: partially_open
    Schlagwort(e): helium isotopes ; heat production ; tectonics ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.03. Heat flow ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.03. Heat generation and transport ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Format: 503 bytes
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