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  • Artikel  (278)
  • mercury
  • soil
  • Energietechnik  (150)
  • Biologie  (138)
  • 1
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Estuarine and Coastal Marine Science 12 (1981), S. 155-166 
    ISSN: 0302-3524
    Schlagwort(e): Massachusetts coast ; crabs ; marsh plants ; mercury ; metal uptake ; mussels ; salt marshes ; sewage disposal
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Biologie , Geographie , Geologie und Paläontologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Journal of Invertebrate Pathology 44 (1984), S. 121-127 
    ISSN: 0022-2011
    Schlagwort(e): Bacillus thuringiensis var. aizawai ; Galleria mellonella ; indigenous in soil ; loss of in soil ; microorganisms ; possible effect of presence on B. thruingiensis ; soil ; viability and potency
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Biologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Journal of Invertebrate Pathology 49 (1987), S. 130-132 
    ISSN: 0022-2011
    Schlagwort(e): Ivela auripes ; Nuclear polyhedrosis virus ; soil ; viral ecology
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Biologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Journal of Invertebrate Pathology 55 (1990), S. 401-406 
    ISSN: 0022-2011
    Schlagwort(e): Entomopathogenic nematode ; Steinernema carpocapsae ; Steinernema glaseri ; pathogenicity ; persistence ; soil ; survival
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Biologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Journal of Invertebrate Pathology 44 (1984), S. 128-133 
    ISSN: 0022-2011
    Schlagwort(e): Bacillus thuringiensis var aizawai ; Pieris brassicae ; indigenous in soil ; microorganisms ; parasporal crystal ; persistence of bacteria in ; possible effect of presence on crystal ; soil
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Biologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    ISSN: 0022-2011
    Schlagwort(e): Beauveria bassiana ; Blissus leucopterus leucopterus ; enzootic ; infection ; pathogenhost interaction ; soil
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Biologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Journal of Invertebrate Pathology 49 (1987), S. 265-272 
    ISSN: 0022-2011
    Schlagwort(e): Sunetta scripta ; bivalve ; copper ; end product ; environmental hypoxia ; hemolymph ; lactic acid ; mercury
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Biologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Journal of Invertebrate Pathology 43 (1984), S. 150-155 
    ISSN: 0022-2011
    Schlagwort(e): Bacillus thuringiensis ; detection by ; immunofluorescence ; parasporal crystals ; soil ; spores ; vegetative cells
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Biologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Journal of Invertebrate Pathology 47 (1986), S. 277-282 
    ISSN: 0022-2011
    Schlagwort(e): Bacillus thuringiensis ; H serotype ; distribution in ; parasporal-inclusion-forming bacteria ; soil
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Biologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Journal of Invertebrate Pathology 47 (1986), S. 12-20 
    ISSN: 0022-2011
    Schlagwort(e): Aedes aegypti ; Bacillus thuringiensis ; Bombyx mori ; Pyrrhalta tibialis ; insect toxicity ; parasporal inclusion ; soil
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Biologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 11
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Journal of Invertebrate Pathology 57 (1991), S. 242-249 
    ISSN: 0022-2011
    Schlagwort(e): Entomopathogenic nematode ; Steinernema carpocapsae ; Steinernema glaseri ; moisture ; pathogenicity ; persistence ; relative humidity ; soil ; steinernematid ; survival ; temperature
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Biologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 12
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Journal of Invertebrate Pathology 32 (1978), S. 303-309 
    ISSN: 0022-2011
    Schlagwort(e): Bacillus cereus ; Bacillus thuringiensis ; H serotype ; O antigen ; isolation ; serological identification ; silkworm litter ; soil
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Biologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 13
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Journal of Invertebrate Pathology 42 (1983), S. 17-32 
    ISSN: 0022-2011
    Schlagwort(e): Locusta migratoria ; cadmium ; glycoproteins ; histopathological effects ; mercury ; metallothioneins
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Biologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 14
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Phytochemistry 26 (1987), S. 973-974 
    ISSN: 0031-9422
    Schlagwort(e): Metrosideros ; Myrtaceae ; heavy metal ; mercury ; rate of emission. ; tree ; vapour release
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Biologie , Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 15
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Phytochemistry 26 (1987), S. 1343-1348 
    ISSN: 0031-9422
    Schlagwort(e): Asterionella glacialis ; cadmium. ; diatom ; fatty acids ; lipids ; mercury ; sterols
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Biologie , Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 16
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Biological Conservation 69 (1994), S. 107-114 
    ISSN: 0006-3207
    Schlagwort(e): Quercus ilex ; dissemination ; dissemination ; forest ; futaie ; seed ; semences ; soil ; sol
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Biologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 17
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Journal of Photochemistry and Photobiology B: Biology 5 (1990), S. 303-310 
    ISSN: 1011-1344
    Schlagwort(e): Dunaliella tertiolecta ; Photosystem II ; chlorophyll. ; fluorescence ; mercury ; water-splitting system
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Biologie , Chemie und Pharmazie , Medizin
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 18
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Environmental Pollution 85 (1994), S. 153-160 
    ISSN: 0269-7491
    Schlagwort(e): grey seal ; harbour seal ; harp seal ; mercury ; ringed seal ; selenium
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Energietechnik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 19
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Environmental Pollution 84 (1994), S. 159-166 
    ISSN: 0269-7491
    Schlagwort(e): children ; dust ; lead ; pollution ; soil
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Energietechnik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 20
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Estuarine, Coastal and Shelf Science 34 (1992), S. 23-36 
    ISSN: 0272-7714
    Schlagwort(e): Liverpool Bay ; North Wales ; aluminium ; arsenic ; iron ; mercury ; sediments ; sewage disposal
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Biologie , Geographie , Geologie und Paläontologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 21
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Environmental Pollution 83 (1994), S. 245-250 
    ISSN: 0269-7491
    Schlagwort(e): GIS ; climate change ; moisture ; soil
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Energietechnik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 22
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Estuarine, Coastal and Shelf Science 38 (1994), S. 625-642 
    ISSN: 0272-7714
    Schlagwort(e): Haifa Bay ; Pb^2^1^0 deposition flux ; bioturbation rate ; capping of pollutants ; mercury ; sedimentation rate
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Biologie , Geographie , Geologie und Paläontologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 23
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Biochemical Systematics and Ecology 15 (1987), S. 361-363 
    ISSN: 0305-1978
    Schlagwort(e): Sesquiterpene lactones ; allelopathy ; degradation ; isoalantolactone ; isohelenin ; persistence ; soil
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Biologie , Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 24
    ISSN: 1539-6924
    Schlagwort(e): Benchmark ; mercury ; risk assessment ; epidemiology
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract This paper presents benchmark (BMD) calculations and additional regression analyses of data from a study in which scores from 26 scholastic and psychological tests administered to 237 6- and 7-year-old New Zealand children were correlated with the mercury concentration in their mothers' hair during pregnancy. The original analyses of five test scores found an association between high prenatal mercury exposure and decreased test performance, using category variables for mercury exposure. Our regression analyses, which utilized the actual hair mercury level, did not find significant associations between mercury and children's test scores. However, this finding was highly influenced by a single child whose mother's mercury hair level (86 mg/kg) was more than four times that of any other mother. When that child was omitted, results were more indicative of a mercury effect and scores on six tests were significantly associated with the mothers' hair mercury level. BMDs calculated from five tests ranged from 32 to 73 mg/kg hair mercury, and corresponding BMDLs (95% lower limits on BMDs) ranged from 17 to 24 mg/kg. When the child with the highest mercury level was omitted, BMDs ranged from 13 to 21 mg/kg, and corresponding BMDLs ranged from 7.4 to 10 mg/kg.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 25
    Digitale Medien
    Digitale Medien
    Springer
    Journal of ornithology 139 (1998), S. 401-405 
    ISSN: 1439-0361
    Schlagwort(e): Biocides ; organochlorines ; mercury ; pollution ; river Rhine
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Beschreibung / Inhaltsverzeichnis: Zusammenfassung 1994/95 durchgeführte Vergleichsuntersuchungen zur Belastung von Binnenland- und Wattenmeerbrütern des Austernfischers mit den Bioziden DDT, DDE und HCH sowie den Industriechemikalien PCB, HCB und Hg ergaben in Austernfischer-Eiern vom Unteren Niederrhein signifikant höhere Konzentrationen chlororganischer Verbindungen als in Eiern der Wattenmeerinseln Griend (NL) und Mellum (D). Nur Hg wurde in niederrheinischen Eiern in hoch signifikant geringerer Konzentration gefunden als in Eiern von Brutvögel des Wattenmeeres. Austernfischer-Eier von Griend waren bezüglich der meisten analysierten Parameter geringer belastet als Eier von Mellum (Ausnahmen: pp'DDT, Σ PCB). Von den untersuchten Umweltchemikalien war die PCB-Konzentration in allen drei Untersuchungsgebieten am höchsten. Die hohe PCB-Kontamination am Unteren Niederrhein spiegelt die auch heute noch erhebliche Belastung des Flusses mit „Altlasten” wider. Weder die Konzentration der untersuchten Industriechemikalien noch die der Biozide dürften von embryotoxischer Wirkung gewesen sein.
    Notizen: Summary Due to the international importance of the Wadden Sea for waders and waterfowl a long-term programme to monitor contamination of birds breeding in the Wadden Sea has been established in the early 1980s. One of the species selected is the Oystercatcher. Comparatively little is known about contamination of birds breeding inland. Therefore, we collected eight eggs of Oystercatchers breeding at the Lower Rhine (district of Kleve) and analysed their contamination with biocides (DDT, DDE, HCH) and industrial chemicals (PCB, HCB, Hg) in comparison to birds breeding on the Wadden Sea islands of Griend (NL) and Mellum (D), where ten eggs were collected in 1994/95. We found distinctive differences between inland and Wadden Sea breeding Oystercatchers. Eggs from the Lower Rhine had significantly higher residues of all organochlorines, whereas concentration of mercury was significantly lower than in those from birds breeding on the Wadden Sea islands. In general, eggs collected on Griend held lower concentrations than those collected on Mellum island, except pp'-DDT and Σ PCB. The high PCB contamination in Ostercatcher eggs from the Lower Rhine nowadays reflects the extreme pollution in the past. However, concentrations of the parameters studied obviously had no embryotoxic effects in Oystercatchers.
    Materialart: Digitale Medien
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  • 26
    ISSN: 1570-7458
    Schlagwort(e): copper ; mercury ; chromatin supraorganization ; survival ; Triatoma infestans ; Hemiptera
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract The nuclear phenotypes and survival of the hemipteran,Triatoma infestans (Hemiptera, Reduviidae), were studied in specimens treated with copper sulfate and methylmercury. The objective was to determine whether changes in chromatin supraorganization and insect survival similar to those promoted by other stressing agents could also be induced by heavy metals. At the concentrations used, copper sulfate and methylmercury were toxic to the cells, mainly inducing nuclear degenrration in the Malpighian tubules and being lethal to a large part of the insect population. Although some individual resistance was found, especially in fasted specimens, heavy metals were found to be much more lethal than was, for instance, a thermal shock at 0°C for 12 h. The nuclear phenotypes detected after heavy metal treatment were similar to those reported under other stressing conditions. However, the frequency at which nuclei exhibited aspects of heterochromatin unraveling was much higher than that found in fasted and thermal-shocked specimens, and was independent of the heavy metal type used. If this phenotype represents an attempt to improve opportunities for extensive cell and insect survival, it was not sufficiently effective. In 5th instar nymphs, the effect of CuSO4 on chromatin supraorganization was detected at early steps of spermatogenesis but not in the cells which were at late spermiogenesis when the metal was administered. This is probably due to changes in nuclear protein composition and to the tightly packed state of the DNA-protein complexes occurring at spermiogenesis, which may protect chromatin from damages. However, when CuSO4 was supplied to 4th instar nymphs, it slowed down the spermiogenesis process, possibly due to several factors including Cu2+ binding to DNA phosphates.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 27
    Digitale Medien
    Digitale Medien
    Springer
    Entomologia experimentalis et applicata 85 (1997), S. 1-9 
    ISSN: 1570-7458
    Schlagwort(e): Hylobius abietis ; oviposition strategies ; root ; soil ; egg distribution ; egg predation ; larval orientation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract Spatial and temporal distributions of eggs laid by the pine weevil Hylobius abietis (L.) (Coleoptera: Curculionidae) were studied by taking root and soil samples around pine stumps on a clear-cutting in central Sweden. In addition, first-instar larvae migrating in the soil were sampled using traps baited with host-odour. Eggs were found in the soil rather than in the bark of stump roots, which previously has been regarded as the usual oviposition site. Based on an oviposition experiment and additional field observations we conclude that eggs are laid in the bark of roots only when the surrounding material is likely to dry out. We suggest two explanations for why weevils oviposit mainly in the soil, although they are known to show stereotypic behaviour when inserting eggs in stump roots: (1) egg predation by other arthropods or by conspecifics is avoided, and (2) newly hatched pine weevil larvae are better than ovipositing females at locating suitable sites for larval feeding.
    Materialart: Digitale Medien
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  • 28
    Digitale Medien
    Digitale Medien
    Springer
    Entomologia experimentalis et applicata 95 (2000), S. 53-61 
    ISSN: 1570-7458
    Schlagwort(e): Hylobius abietis ; movement ; habitat preference ; edge permeability ; soil ; seedling protection ; reforestation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract Pine weevil, Hylobius abietis (L.) (Coleoptera: Curculionidae), movement behaviour on different substrates was studied in an indoor arena using a video camera and digital image processing technique. We analysed individual variation in movement characteristics, i.e. turning angles, movement directions, and distance moved per unit time on the bare and level arena surface which consisted of mineral soil (sand) and/or humus sections in various spatial configurations. Pine weevils on humus did not turn back when they came to the border with the sand. However, most individuals moved faster on sand than on humus. Thus, the results suggest that interactions between substrate differences and individual movement behaviour may to some extent explain why pine weevils have been observed to feed less frequently on coniferous seedlings planted on mineral soil than on those planted on humus.
    Materialart: Digitale Medien
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  • 29
    ISSN: 1572-8900
    Schlagwort(e): Starch ; PHBV ; PHA ; plastic ; blends ; biodegradation ; soil ; compost
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Energietechnik , Maschinenbau
    Notizen: Abstract Injection molded specimens were prepared by blending poly (hydroxybutyrate-co-valerate) (PHBV) with cornstarch. Blended formulations incorporated 30% or 50% starch in the presence or absence of poly-(ethylene oxide) (PEO), which enhances the adherence of starch granules to PHBV. These formulations were evaluated for their biodegradability in natural compost by measuring changes in physical and chemical properties over a period of 125 days. The degradation of plastic material, as evidenced by weight loss and deterioration in tensile properties, correlated with the amount of starch present in the blends (neat PHBV 〈 30% starch 〈 50% starch). Incorporation of PEO into starch-PHBV blends had little or no effect on the rate of weight loss. Starch in blends degraded faster than PHBV and it accelerated PHBV degradation. Also, PHBV did not retard starch degradation. After 125 days of exposure to compost, neat PHBV lost 7% of its weight (0.056% weight loss/day), while the PHBV component of a 50% starch blend lost 41% of its weight (0.328% weight loss/day). PHB and PHV moieties within the copolymer degraded at similar rates, regardless of the presence of starch, as determined by 1H-NMR spectroscopy. GPC analyses revealed that, while the number average molecular weight (Mn) of PHBV in all exposed samples decreased, there was no significant difference in this decrease between neat PHBV as opposed to PHBV blended with starch. SEM showed homogeneously distributed starch granules embedded in a PHBV matrix, typical of a filler material. Starch granules were rapidly depleted during exposure to compost, increasing the surface area of the PHBV matrix.
    Materialart: Digitale Medien
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  • 30
    Digitale Medien
    Digitale Medien
    Springer
    Journal of polymers and the environment 3 (1995), S. 31-36 
    ISSN: 1572-8900
    Schlagwort(e): Biodegradation ; chitin ; chitosan ; film ; soil
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Energietechnik , Maschinenbau
    Notizen: Abstract The biodegradation of polyethylene-chitin (PE-chitin) and polyethylene-chitosan (PE-chitosan) films, containing 10% by weight chitin or chitosan, by pure microbial cultures and in a soil environment was studied. Three soil-inhabited organsims,Serratia marcescens, Pseudomonas aeruginosa, andBeauveria bassiana were able to utilize chitin and chitosan in prepared PE-chitin and PE-chitosan films after eight weeks of incubation at 25°C in a basal medium containing no source of carbon or nitrogen. In a soil environment, the biodegradation of those films was studied and compared with a commercial biodegradable film containing 6% by the weight of corn starch. In soil placed in the lab, 73.4% of the chitosan and 84.7% of the chitin in the films were degraded, while 46.5% of the starch in the commercial film was degraded after six months of incubation. In an open field, 100% of the chitin and 100% of the chitosan in the films were degraded, but only 85% of the starch in the commercial film was degraded after six months of incubation. The weight of controls, (polyethylene films), remained mainly stable during the incubation period. Both PE-chitin and PE-chitosan films degraded at a higher rate than the commercial starch-based film in a soil environment indicating the potential use of chitin-based films for the manufacturing of biodegradable packaging materials.
    Materialart: Digitale Medien
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  • 31
    ISSN: 1572-8773
    Schlagwort(e): cadmium ; cell culture ; culture medium ; ICP-MS ; K-562 ; mercury ; selenium
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract Effects of some metals on the growth of cultured human erythroleukemia K-562 cells were investigated when grown in two different types of media based upon RPMI-1640 or Ham's F-10. The study on proliferation, using RPMI-1640 supplemented with sodium selenite, selenomethionine, mercuric chloride, methylmercuric chloride and cadmium nitrate showed no inhibition of growth at concentrations of 2.5, 25, 25, 2.5 and 25 μM, while at 75, 250, 50, 5 and 50 μM toxicity was apparent. Selenite at 5–50 μM and selenomethionine at 50–100 μM inhibited the growth. In Ham's F-10 supplemented with the same compounds no inhibition was found at concentrations of 5, 10, 25, 1 and 50 μM, while at 50, 100, 50, 5 and 75 μM toxic effects were noted. Selenite 10 μM and selenomethionine 25-50 μM inhibited the proliferation. Measurements of trace element levels in pellets of K-562 cells grown in RPMI-1640 or Ham's F-10 unveiled higher cell contents of cadmium and selenium in cells grown in RPMI-1640, being consistent with higher concentrations of these elements in that medium. Manganese and mercury concentrations were higher in cells grown in Ham's F-10 correlating with a higher medium concentration of these elements. The growth responses and cellular uptake differed between the metals and the selenocompounds and although extrapolating the results to humans is difficult the selenium exposures were in approximately the same order of magnitude as in human exposures. The compounds could be ranked according to decreasing toxicity as: methylmercuric chloride 〉 mercuric chloride, cadmium nitrate, sodium selenite 〉 selenomethionine.
    Materialart: Digitale Medien
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  • 32
    ISSN: 1572-8773
    Schlagwort(e): energy transfer ; fluorescence ; mercury ; phycobilisome ; phycocyanin ; Spirulina platensis
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract We have shown that mercury affects energy transfer in Spirulina platensis. It inhibits energy transfer from phycocyanin to chlorophyll a by specifically bleaching the β-84 chromophore of the chromo protein, phycocyanin (PC), in the cyanobacterium. This effect is observed during short-term exposure of cells to Hg2+ ions. Upon long-term (12 h) exposure, mercury at low concentrations (1–2.5 μm) causes the gradual degradation of the β polypeptide (22 kDa) of the PC of phycobilisomes in this cyanobacterium. The effect of mercury on this polypeptide is significant compared with the other phycobiliproteins.
    Materialart: Digitale Medien
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  • 33
    ISSN: 1572-8773
    Schlagwort(e): mercury ; Na-K-ATPase ; rat liver ; signal transduction
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract Specific binding of Hg to ouabain-sensitive Na-K-ATPase of rat liver plasma membrane was demonstrated with a K of 2.64¥10 and B of 1.6nmole mg protein. The binding of mercury to the enzyme also causes significant inhibition of the enzyme, which is greater than its ouabain sensitivity. In the cytosol Hg binding to reduced glutathione (GSH) is stimulated by GSH-S-transferase (GST), the activity of which was found to be significantly enhanced by 15mM Na and 10mM Hg. It is proposed that the transport of Hg2 inside the cell takes place by increased dissociation of Hg from the membrane due to greater avidity of Hg towards cytosolar GSH binding. The GSH-Hg complex enters the nucleus where it dissociates to bind the metal response element (MRE) of the metallothionein (MT) gene to induce MT transcription.
    Materialart: Digitale Medien
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  • 34
    ISSN: 1572-8773
    Schlagwort(e): lead ; mercury ; metals ; nickel ; radiation effects ; selenium
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract Effects of Pb2+, Ni2+, Hg2+ and Se4+ on cultured human glioma U-343MG cells were investigated considering uptake, toxicity and, in combination with radiation, clonogenic cell survival. The cells were exposed to 0-100 μm of the metals for a week before the evaluation. The tests showed a tendency to toxicity with 10 μm nickel although not significant (P 〉 0.05). Selenium, lead and mercury exerted a significant toxicity (P 〈 0.05) at 2.5 μm, 10 μm and 1 μm, respectively. To challenge the clonogenic cell survival capacity, the cells were irradiated with60Co photons after being exposed to the highest nontoxic concentration of the different metals. The clonogenic cell survival tests, after irradiation, showed no significant change if the cells were exposed to 5 μm nickel, 0.5 μm selenium or 5 μm lead compared with those not exposed. Mercury, 0.1 μm, gave a relative reduction in survival compared with only irradiated cells of 58 ± 17%. Thus, only mercury affected the radiation-induced damage and/or repair. When exposed to the highest nontoxic concentrations of the different metals, the cultures did not display a significant uptake ratio (metal concentration ratio of exposed cells to control cells) of nickel (3.1 ± 3.3), only a small uptake ratio of selenium (4.0 ± 0.4), while there was a large uptake ratio of both lead (2.6 ± 1.7) x 102 and mercury (1.5 ± 0.2) x 101. The results indicated that nickel was neither especially toxic nor influenced the clonogenic cell survival after irradiation. Mercury was more toxic and also influenced the radiation sensitivity. Lead was taken up strongly but did not influence the radiation sensitivity. Selenium accumulated but gave no detectable effect on the radiation sensitivity.
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  • 35
    ISSN: 1572-8773
    Schlagwort(e): 3β-HSD ; fish oocyte ; mercury ; Na-K-ATPase ; steroidogenesis
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract Both in vitro and in vivo HgCl treatment demonstrated a remarkably high rate of progesterone synthesis accompanied by a low rate of conversion to 17β-estradiol in the oocyte of Channa punctatus. On depuration, however, there was a reversal of the steroidogenic scenario with a low progesterone and high estradiol level. The accumulation of progesterone was positively correlated with the significant increase in 3β-hydroxysteroid dehydrogenase activity in the Hg-treated fish. Thus, it was clear that at the early stage of intoxication Hg does play a role in the induction of 3β-hydroxysteroid dehydrogenase in the oocyte of fish at the spawning stage. The induction of this enzyme was found to be mediated by specific binding of Hg to the plasma membrane Na-K-ATPase (B: 14 nmoles mg protein; K 1.14 x 108 moles) and increase in the specific messenger RNA translating 3β-hydroxysteroid dehydrogenase. It is concluded that inorganic mercury is able to initiate translatable messenger RNA synthesis in fish oocyte at a low degree of intoxication.
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  • 36
    Digitale Medien
    Digitale Medien
    Springer
    BioMetals 10 (1997), S. 357-361 
    ISSN: 1572-8773
    Schlagwort(e): copper ; exposure ; mercury ; smoking ; zinc
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract The excretion of mercury, copper and zinc in urine, and mercury in whole blood andplasma, was determined in 40 chloralkali workers exposed to mercury vapour and 40age-matched referents. The Hg concentrations in whole blood, plasma and urine werehigher in the exposed group (35 nmol l, 30 nmol l,and 11.5 nmol mmol creatinine, respectively) in comparison with thereference group (15 nmol l, 6.3 nmol l, and 1.8nmol mmol creatinine, respectively). The urinary copper excretionwas similar in the two groups, while U-Zn excretion was significantly higher (P = 0.04)in the exposed group, median 0.83 mmol mmol creatinine versus 0.76mnmol mmol creatinine in the reference group. In a subgroup of exposedworkers with current U-Hg above 11.5 nmol lmmolcreatinine (20 mg g creatinine) the medianU-Zn was 1.1 mmol mmol creatinine. In both groups smokers had highU-Zn levels than non smokers. When both U-Hg and smoking were taken into account in alinear regression model, there was a significant association between U-Hg and U-Zn inthe combined group of exposed and referents (P = 0.002). This study indicates thatmercury exposure in humans, as in animals, causes increased urinary excretion of zinc.The mechanisms may be induced synthesis of metallothionein in the kidneys, displacementof Zn from preexisting metallothionein by Hg, or a decreased reabsorption of zinc in thekidneys owing to a slight tubular dysfunction.
    Materialart: Digitale Medien
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  • 37
    Digitale Medien
    Digitale Medien
    Springer
    BioMetals 11 (1998), S. 139-143 
    ISSN: 1572-8773
    Schlagwort(e): feathers ; pheasant ; mercury ; muscles
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract Mercury concentrations were determined in muscles and feathers of 58 cock pheasants. Birds were collected from seven different polluted sites in southern Poland in 1987. The mercury concentrations in the muscle ranged from 0.010 to 0.026 mug g dry mass. The significantly highest values were found in muscle samples from Przylasek and Przemysl. The levels found in the flight feathers were higher than in breast feathers. Average concentrations in flight feathers ranged from 0.050 mug g (Przemysl) to 0.240 mug g dry mass (Przylasek). © Rapid Science 1998
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  • 38
    ISSN: 1572-8773
    Schlagwort(e): capsule secondary structure ; exopolysaccharide ; bacterial cell surface ; copper ; mercury ; ytterbium
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract Escherichia coli K1 secretes a homopolymer capsular polysaccharide (CPS) consisting of alpha 2,8 linked N-acetylneuraminic acid (poly α2,8NeuNAc). Typically poly α2,8NeuNAc is arranged in low and high order alpha helices with carboxyl and hydroxyl groups extending from the helices. Several properties of CPS such as antigenicity and metal binding can be influenced by its structural conformation. We examined the influences of metal ions and temperature on the secondary structure of polyαa2,8NeuNAc. Conformation alteration was detected by ultraviolet (UV) spectroscopy and circular dichroism (CD). The majority of metal ions tested had no detectable influence on poly a2,8NeuNAc structure. In contrast, Yb3+., Hg2+, and Cu2+ ions greatly altered the UV and CD spectra, which suggests that these ions had disrupted the alpha helical structure of poly α2,8NeuNAc. These changes were influenced by the metal ion concentration. When poly α2,8NeuNAc was incubated at temperatures ranging from 20 - 60°C, alterations in its UV absorption spectra were also seen. The most significant change occurred between 35 and 40°C. In summary, this study suggests that the higher order structure and function of bacterial CPS may be influenced by environmental factors
    Materialart: Digitale Medien
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  • 39
    ISSN: 1572-8773
    Schlagwort(e): mercury ; trigeminal ganglion ; tooth pulp
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract An amalgam filling was inserted into the first upper molar of 12 rats and the animals were killed after 3–9 months. Tissue sections from the trigeminal ganglia and the brain stem were then investigated with a sensitive histochemical technique to trace mercury deposits. Within the trigeminal ganglia, nerve cells with mercury deposits were observed in seven out of 12 rats, whereas no mercury was detected in sections from the brain stem. The mechanism responsible for the accumulation of mercury in neurons of the trigeminal ganglia is discussed.
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  • 40
    ISSN: 1572-8773
    Schlagwort(e): mercury ; urine ; feces ; gastrointestinal absorption
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract The effects of long-term daily intake of mercury on its urinary and fecal excretion, whole-body retention, and blood concentration in male rats were observed. The animals were exposed to mercuric chloride labeled with 203Hg via drinking water for 8 weeks (5, 50 and 500 μ m Hg). 203Hg in urine, feces and blood was quantified. The blood mercury concentration did not keep a linear relationship with the increasing dose. The percentage of the total amount of mercury intake which is excreted by the fecal route in rats exposed to 500 μ m Hg was significantly lower than in those exposed to 5 and 50 μ m. The daily dose percentage of mercury excreted in urine increased with dose size. The results show that the absorption fraction of mercury through the gastrointestinal tract (30–40%) was higher than values previously reported.
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  • 41
    Digitale Medien
    Digitale Medien
    Springer
    BioMetals 9 (1996), S. 213-220 
    ISSN: 1572-8773
    Schlagwort(e): mercury ; kidney ; metallothionein ; oral exposure
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract The effects of long-term daily intake of low and high levels of mercury on its organ distribution and binding to renal metallothionein (MT) in male rats were studied. The animals were exposed to mercuric chloride labelled with203Hg via drinking water for 8 weeks (5, 50 and 500μ m Hg). The greatest concentration of mercury was found in the kidneys. Similar levels of radioactivity in the buccal cavity and oesophagus were also observed by whole-body autoradiography. In the kidneys, the mercury was accumulated in the outer stripe of the outer zone of the medulla and, to a minor degree, in the renal cortex. Almost 50% the total renal mercury was associated to MT. The binding capacity of the renal MT for mercury tends to saturate with increasing doses, thus this means that the capacity of the kidneys to accumulate mercury is limited.
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  • 42
    ISSN: 1572-8773
    Schlagwort(e): copper ; mercury ; rat ; tooth fillings ; zinc
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract The aim of this study was to measure the distribution of mercury, in tissues of rats exposed to amalgam over a two months period. Possible interaction of mercury with copper and zinc in organs was also evaluated. Rats were either exposed to mercury from 4 dental amalgams, or fed the diet containing powdered amalgam during two months. Mercury was measured in the kidney, liver and brain, copper in kidney and brain and zinc in kidney. The results showed significantly higher concentrations of mercury in the kidneys and the brains of rats in both exposed groups compared to control. Even after two months of exposure to mercury brain mercury concentration in rats with amalgam fillings was 8 times higher than in the control and 2 times higher than in rats exposed to amalgam supplemented diet. The highest mercury concentration in the latter group was found in the kidneys and it was 5 times higher than in the control group. We found no significant differences between mercury levels in exposed and control rat's liver. Exposure to mercury from dental amalgams did not alter the concentrations of copper and zinc in the tissues. Histopathological analyses of rats tissues did not show any pathological changes. These results support previously proposed nose-brain transport of mercury released from dental amalgam fillings.
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  • 43
    Digitale Medien
    Digitale Medien
    Springer
    BioMetals 5 (1992), S. 17-22 
    ISSN: 1572-8773
    Schlagwort(e): mercury ; zinc ; copper ; metallothionein
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract The effects of HgCl2 on urinary excretion of Zn, Cu and metallothionein at different time intervals were observed in male Wistar rats. The rats were given a daily intraperitoneal injection of203HgCl2 (0.5 or 1.0 mg Hg kg−1) for 2 days.203Hg, Zn, Cu and metallothionein in urine, kidney and liver were analyzed. Significant increases in urinary Zn and Cu concentrations were found in HgCl2-dosed groups. Elevated urinary Zn and Cu concentrations were accompanied by an increased metallothionein excretion in urine at different time periods. Zn concentration in urine remained elevated during the entire observation period of 7 days. There were also increased concentrations of Cu and Zn in the renal cortex in one of the two exposed groups. The results indicate that urinary Cu and Zn are related to the manifestation of renal toxicity and/or the synthesis of metallothionein in kidney induced by mercury.
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  • 44
    Digitale Medien
    Digitale Medien
    Springer
    BioMetals 5 (1992), S. 73-80 
    ISSN: 1572-8773
    Schlagwort(e): mercury ; arsenic ; cadmium ; plasmid ; restriction analysis ; curing ; conjugation ; transformation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract Pseudomonas sp isolated from the Bay of Bengal (Madras coast) contained a single large plasmid (pMR1) of 146 kb. Plasmid curing was not successful with mitomycin C, sodium dodecyl sulfate, acridine orange, nalidixic acid or heat. Transfer of mercury resistance from marinePseudomonas toEscherichia coli occurred during mixed culture incubation in liquid broth at 10−4 to 10−5 ml−1. However, transconjugants lacked the plasmid pMR1 and lost their ability to resist mercury. Transformation of pMR1 intoE. coli competent cells was successful; however, the efficiency of transformation (1.49×102 Hgr transformants μg−1 pMR1 DNA) was low.E. coli transformants containing the plasmid pMR1 conferred inducible resistance to mercury, arsenic and cadmium compounds similar to the parental strain, but with increased expression. The mercury resistant transformants exhibited mercury volatilization activity. A correlation existed between metal and antibiotic resistance in the plasmid pMR1.
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  • 45
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Enzyme and Microbial Technology 16 (1994), S. 802-807 
    ISSN: 0141-0229
    Schlagwort(e): Accumulation ; Chlorella ; agarose ; algae ; alginate ; immobilization ; mercury ; packed-bed reactor ; phosphate ; volatilization
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Biologie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
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  • 46
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Environmental and Experimental Botany 34 (1994), S. 385-391 
    ISSN: 0098-8472
    Schlagwort(e): CO"2 ; leaf ; photosynthesis ; radiation ; respiration ; soil ; temperature ; tree
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Biologie
    Materialart: Digitale Medien
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  • 47
    Digitale Medien
    Digitale Medien
    Springer
    Biodegradation 4 (1993), S. 141-153 
    ISSN: 1572-9729
    Schlagwort(e): bioavailability ; biodegradation ; sorption ; oil ; soil
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Energietechnik , Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Materialart: Digitale Medien
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  • 48
    Digitale Medien
    Digitale Medien
    Springer
    Journal of paleolimnology 13 (1995), S. 157-168 
    ISSN: 1573-0417
    Schlagwort(e): 210Pb ; 137Cs ; soil ; model-simulation ; migration ; mixing
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Geologie und Paläontologie
    Notizen: Abstract The γspectroscopic measurement of soil samples is described.210Pb data from a soil survey in western-Europe are briefly reviewed. The average210Pb flux from the atmosphere, as determined from210Pb exc soil inventories, is 90 Bq m−2a−1. A simple one-dimensional box-chain model is described. The model simulates the vertical, post depositional transport of natural and fall-out radionuclides in the soil. Simulation of measured210Pb exc ,134Cs,137Cs, and241Am soil profiles shows that mixing (bioturbation) is a very efficient transport mechanism. Lead seems to be strongly fixed to organic and clay particles. It is transported by the displacement of the organic and clay carrier substances. The mean residence time of lead, caesium, plutonium and americium in organic rich forest soils is in the order of 250–1000 years. An applicability study in investigate the use of210Pb in erosion problems showed erosion rates from 60–180 g m−2a−1 on organic rich forest and meadow sites with 10°–25° slopes.
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  • 49
    Digitale Medien
    Digitale Medien
    Springer
    Journal of paleolimnology 23 (2000), S. 213-221 
    ISSN: 1573-0417
    Schlagwort(e): geochemistry ; heavy metals ; palaeolimnology ; sediment ; soil ; X-ray fluorescence
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Geologie und Paläontologie
    Notizen: Abstract Energy dispersive isotope-source X-ray fluorescence (XRF) analysers are little used in academic environmental research, in spite of being ideally suited to a number of tasks. In this paper an XRF method is tested by measuring a wide range of environmental materials of known elemental composition. Precision, accuracy and detection limits are presented. Using isotope-source X-ray fluorescence analysis, the total concentrations of Si, Ti, Ca, K, Fe, Mn, Cl, S, Nb, Ni, Pb, Rb, Sr, Zn and Zr can be determined in soils and sediments at a rate of 〉70 samples per day. The combination of speed and accuracy makes the technique ideal for three classes of application within environmental research. First, in sediments and soils that are highly heterogeneous, reliable characterisation is more dependent upon the number of samples measured than on measurement precision or accuracy. Under these circumstances the method is sufficiently accurate to be used alone. This is also the case where there is high and wide ranging contamination of sediment or soil by Pb and Zn. Second, major elements (Si, Ti, Fe, Ca, K and S) can be measured with sufficient accuracy in sediments and soils to aid the interpretation of other sediment chemical analyses. Third, the technique is ideal for the rapid screening of sediment or soil, allowing effective targeting of samples for more time consuming or expensive analyses. The XRF method presented here offers rapid, non-destructive total elemental analysis of sediments and soils that is sufficiently accurate to be useful in environmental research.
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  • 50
    Digitale Medien
    Digitale Medien
    Springer
    Journal of paleolimnology 1 (1988), S. 133-140 
    ISSN: 1573-0417
    Schlagwort(e): mercury ; sediments ; waste waters ; dated cores ; Baltic Sea
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Geologie und Paläontologie
    Notizen: Abstract Several cores were compared to elucidate the grade of mercury retention in sediments of the Baltic Sea near Oulu, Finland. The known history of the mercury discharge to waste water from a chlor-alkali plant, the primary pollution source, was compared to that in the sedimentary record. One core was dated by lead-210 and varve counts. During the past thirty years, the rate of sedimentation was up to 10 mm per year corresponding to a dry matter accumulation rate of about 3 kg m−2a−1. Under these conditions, most of the mercury reaching the sediment was retained. Correspondingly, the mercury levels in fish were considerably lower, with a delay of some five years. The present mercury content of the upper layers is some 1/4 or 1/5 that of the late 1970's, but it is still some twentyfold compared to levels at the beginning of the century. The extent to which the present mercury level in the sediment represents the various phases of industrial emission remains unsolved due to the origin of mercury in this sea area from several other sources and due to difficulties in exact core correlations from different years.
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  • 51
    Digitale Medien
    Digitale Medien
    Springer
    Mycopathologia 146 (1999), S. 115-116 
    ISSN: 1573-0832
    Schlagwort(e): India ; keratinophilic fungi ; Mumbai ; soil
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Medizin
    Notizen: Abstract Eighty-seven soil samples were collected from various areas of Mumbai and its vicinity to determine the prevalence of keratinophilic fungi. From the 55 positive samples (63.21%), a total of four genera with nine species were isolated viz. Chrysosporium indicum (28.73%),C. lobatum (2.29 %), C. sp.I (1.14%), C. sp. II (1.14%),C. tropicum (1.14%),C. zonatum (2.29%),Ctenomyces serratus (2.29%) Malbranchea aurantiaca (2.29%) and Microsporum gypseum complex (21.83%).
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  • 52
    Digitale Medien
    Digitale Medien
    Springer
    Mycopathologia 147 (1999), S. 67-81 
    ISSN: 1573-0832
    Schlagwort(e): Grain ; mycotoxin ; ochratoxin ; Penicillium verrucosum ; soil ; survival
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Medizin
    Notizen: Abstract A field experiment was conducted to elucidate the survival of P. verrucosum in infested bulk soil(T1) and infested soil with waste grain (T2). The infested soil and reference soil (T3) was filled into steel cylinders, which were buried and sampled 13 times during a period from October 1994 to March 1996.The abundance of P. verrucosum and indigenous soil fungi were assessed by dilution plating on a selective and diagnostic medium (DYSG). Kernel infection was examined in T2. According to our results, P. verrucosum seems well adapted to survival in arable soil and little affected by indigenous fungi. During the first autumn and winter the grain caused a proliferation of P. verrucosum while its abundance in bulk soil was more constant except for a decrease in February 95, which is ascribed to frost/thaw alternations. In T2, P. verrucosum initially infected more than 50% of the kernels but during the first few months it was ousted by other fungi. A hypothesis regarding waste grain as the natural niche for the fungus in the field was therefore partly rejected. A gradual decrease in the abundance of P. verrucosum in soil during spring, a die-off in the dry summer and aproliferation during the second winter were found in both T1 and T2. Our results cannot provide the reason for the increase during the second winter. On an overall basis, however, they show that P. verrucosum can survive in the field, proliferate on soil organic matter and probably become an integral part of the soil ecosystem. This may constitute a risk of grain contamination when given appropriate environmental conditions.
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  • 53
    Digitale Medien
    Digitale Medien
    Springer
    Mycopathologia 125 (1994), S. 157-162 
    ISSN: 1573-0832
    Schlagwort(e): Aflatoxins ; Aspergillus parasiticus ; Aspergillus tamarii ; Aspergillus nomius ; soil ; fungal populations
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Medizin
    Notizen: Abstract Four agar media used to isolate aflatoxin producing fungi were compared for utility in isolating fungi in theAspergillus flavus group from agricultural soils collected in 15 fields and four states in the southern United States. The four media wereAspergillus flavus andparasiticus Agar (AFPA, 14), the rose bengal agar described by Bell and Crawford (BCRB; 3), a modified rose bengal agar (M-RB), and Czapek's-Dox Agar supplemented with the antibiotics in BC-RB (CZ-RB). M-RB was the most useful for studying the population biology of this group because it permitted both identification of the greatest number ofA. flavus group strains and growth of the fewest competing fungi. M-RB supported an average of 12% moreA. flavus group colonies than the original rose bengal medium while reducing the number of mucorales colonies and the number of total fungi by 99% and 70%, respectively. M-RB was successfully employed to isolate all three aflatoxin producing species,A. flavus, A. parasiticus andA. nomius, and both the S and L strains ofA. flavus. M-RB is a defined medium without complex nitrogen and carbon sources (e.g. peptone and yeast extract) present in BC-RB. M-RB should be useful for studies on the population biology of theA. flavus group.
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  • 54
    Digitale Medien
    Digitale Medien
    Springer
    Mycopathologia 106 (1989), S. 47-52 
    ISSN: 1573-0832
    Schlagwort(e): keratinophilic fungi ; soil ; antarctic
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Medizin
    Notizen: Abstract In the present study, 10 soil samples were collected aseptically from an equal number of areas of the Antarctic in the zone occupied by the 1986–1987 Italian expedition for research on keratinophilic fungi. Of particular interest was the isolation of a pathogenic fungus, Microsporum gypseum, from two sites in the base camp occupied by men and by skuas. Trichophyton terrestre was isolated from a site in which people worked and through which penguins and skuas passed. The most widespread fungal species were members of the genus Chrysosporium. Some of these species were isolated but not identified and this part of the study was still be completed. Another significant finding was the absence of fungi in one sample, while in another the widespread and abundant growth in all the seeded dishes of a single species of Chrysosporium. Other species in genera of general diffusion in many environments were also isolated : Aspergillus spp., Malbranchea sp., Mycelia sterilia spp., Paecilomyces sp., Penicillium spp. and Scopulariopsis spp.
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  • 55
    Digitale Medien
    Digitale Medien
    Springer
    Antonie van Leeuwenhoek 53 (1987), S. 253-259 
    ISSN: 1572-9699
    Schlagwort(e): P. aeruginosa ; mercury ; organomercurials ; pyocin types ; antibiotic resistance ; metal resistance
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract Susceptibility to inorganic mercuric ions and to organomercurials of 237 Pseudomonas aeruginosa clinical strains isolated in Mexico was determined by agar dilution tests. Resistant strains fell into two classes: i) narrow-spectrum resistant strains (27% of total isolates) resistant only to mercuric ions and to merbromin, and most grouped in pyocin type 1; and ii) broad-spectrum resistant strains (5%) with additional resistances to thimerosal, phenylmercury, methylmercury and p-hydroxymercuribenzoate, that belonged mostly to pyocin type 10. Mercurial resistant isolates showed a higher proportion of resistance to antibiotics and metals than did mercurial sensitive isolates, and broad-spectrum resistant strains had the highest frequency of resistance to antibiotics and to tellurite and arsenate.
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  • 56
    ISSN: 1572-9699
    Schlagwort(e): thermophilic actmonycetes in India ; Faenia rectivirgula ; Thermoactinomyces spp. ; Saccharomonospora viridis ; hay ; compost ; bagasse ; soil ; straw
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract Medically important thermophilic actinomycetes were isolated from 218 (64%) of 341 samples of vegetable substrates and soil examined from sites in north-western India. Thermoactinomyces vulgaris (T. candidus) was the commonest species, occurring in 56% of samples, followed by Saccharomonospora viridis in 29%, Thermoactinomyces thalpophilus in 27%, Faenia rectivirgula (Micropolyspora faeni) in 21% and Thermoactinomyces sacchari in 14%. T. vulgaris and T. thalpophilus were isolated from all types of substrate examined, with T. vulgaris always more common than T. thalpophilus. Of the other thermophilic actinomycetes, F. rectivirgula was isolated predominantly from hay (44%) and S. viridis (56%) and T. sacchari (44%) from sugarcane bagasse. The largest populations of T. vulgaris and T. thalpophilus were found in paddy straw, followed by T. sacchari, S. viridis and F. rectivirgula in sugar-cane bagasse. The widespread occurrence of these clinically important thermophilic actinomycetes suggests that exposure of humans and animals to them may be frequent in north-western India. Studies are required to determine the prevalence of extrinsic allergic alveolitis (hypersensitivity pneumonitis) caused by thermophilic actinomycetes in the local population.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 57
    Digitale Medien
    Digitale Medien
    Springer
    Biodegradation 7 (1996), S. 329-333 
    ISSN: 1572-9729
    Schlagwort(e): biodegradation ; modelling ; rubber ; soil
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Energietechnik , Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract The biodegradation of rubber particles in rubber-soil mixtures at different rubber contents was monitored by the carbon dioxide production. The cumulative carbon dioxide production was modelled according to a two parameter exponential function. The model provides an excellent fit (R2〉0.98) for the observed data. The two parameters yield a reliable estimate of the half-life for the process observed, but estimation of the true half-life of rubber in soil will need more research.
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  • 58
    ISSN: 1572-9729
    Schlagwort(e): bioavailability ; builders ; detergents ; kinetics ; mineralization ; sewage sludge ; soil
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Energietechnik , Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Tetradecenyl succinic acid (TSA) is the major component of a detergent builder (C12-C14 alkenyl succinic acid), which is inherently biodegradable. 14C-TSA was dosed as a component of sewage sludge into a soil with a history of sludge amendment at final added concentrations of 1.5 and 30 mg (kg soil)-1. In addition, it was dosed to the soil in an aqueous solution to a final added concentration of 30 mg (kg soil)-1. Dose and form were found to have a pronouced effect on the mineralization kinetics. When dosed in a realistic form and concentration (i.e. 1.5 mg (kg soil)-1 as a component of sludge), TSA was mineralized at its highest rate and to its greatest extent, and the mineralization half-life was 2.4 days. When dosed at 30 mg (kg soil)-1 as a component of sludge, mineralization began immediately, and the half-life was 23 days. In contrast, when dosed at this concentration in aqueous solution, the onset of mineralization was preceded by a 13 day lag period and the mineralization half-life was 69 days. Primary biodegradation and mineralization rates of TSA were very similar. Approximately, half the radioactivity was evolved as 14CO2, while the remaining radioactivity became non-extractable, having presumably been incorporated into biomass or natural soil organic matter (humics). This study demonstrated that TSA is effectively removed from sludge-amended soils as a result of biodegradation. Furthermore, it showed the effect that dose form and concentration have on the biodegradation kinetics and the importance of dosing a chemical not only at a relevant concentration but also in the environmental form in which it enters the soil environment.
    Materialart: Digitale Medien
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  • 59
    ISSN: 1572-9729
    Schlagwort(e): Desulfomonile tiedjei ; soil ; PCR ; reductive dechlorination
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Energietechnik , Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract The aim of this work was to test the feasibility ofintroducing an anaerobic microbial reductivedechlorination activity into non sterile soil slurrymicrocosms by inoculation with the pure anaerobicbacterial strain Desulfomonile tiedjei, which iscapable of dechlorinating 3-chlorobenzoate tobenzoate. To show that the bacterium was establishedin the microcosms we followed the expression of thereductive dechlorination activity and a molecularprobe based on PCR amplification of the 16S rDNA genewas developed. However, the success of PCRamplification of the 16S rDNA gene depends on the DNAextraction and purification methodologies applied, asshown through the use of several protocols. In thisstudy we report a DNA extraction and purificationmethod which generates sufficient and very clean DNAsuitable for PCR amplification of the D. tiedjei16S rDNA gene. The threshold of detection was about5.103 bacteria per gram of soil slurry.Introduction of D. tiedjei in soil slurrymicrocosms proved successful since 3-chlorobenzoatedechlorination activity was established with thisbacterium in microcosms normally devoid of thisdechlorination capacity. Indeed, the addition of D. tiedjei to microcosms supplemented with acetateplus formate as cosubstrate, at their respectiveconcentrations of 5 and 6 mM, led to a totalbiotransformation of 2.5 mM of 3-chlorobenzoate within12 days. After complete 3-chlorobenzoatedechlorination, the 16S rDNA gene of this bacteriumwas specifically detected only in the inoculatedmicrocosms as shown by PCR amplification followed byrestriction mapping confirmation.
    Materialart: Digitale Medien
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  • 60
    Digitale Medien
    Digitale Medien
    Springer
    Biodegradation 8 (1997), S. 349-356 
    ISSN: 1572-9729
    Schlagwort(e): biodegradation ; bioremediation ; acclimation ; Everglades ; mineralization ; nitrophenol ; soil
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Energietechnik , Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract The Everglades in South Florida are a unique ecologicalsystem. As a result of the widespread use of pesticides andherbicides in agricultural areas upstream from these wetlands,there is a serious potential for pollution problems in theEverglades. The purpose of this study was to evaluate theability of indigenous microbial populations to degradexenobiotic organic compounds introduced by agricultural andother activities. Such biodegradation may facilitate theremediation of contaminated soils and water in the Everglades.The model compound selected in this study is 4-nitrophenol, achemical commonly used in the manufacture of pesticides. Themineralization of 4-nitrophenol at various concentrations wasstudied in soils collected from the Everglades. Atconcentrations of 10 and 100 µg/g soil, considerablemineralization occurred within a week. At a higherconcentration, i.e., 10 mg/g soil, however, no mineralizationof 4-nitrophenol occurred over a 4-month period; such a highconcentration apparently produced an inhibitory effect. Therate and extent of 4-nitrophenol mineralization was enhancedon inoculation with previously isolated nitrophenol-degradingmicroorganisms. The maximum mineralization extent measured,however, was less than 30% suggesting conversion to biomassand/or unidentified intermediate products. These resultsindicate the potential for natural mechanisms to mitigate theadverse effects of xenobiotic pollutants in a complex systemsuch as the Everglades.
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  • 61
    Digitale Medien
    Digitale Medien
    Springer
    Landscape ecology 2 (1988), S. 45-61 
    ISSN: 1572-9761
    Schlagwort(e): Illinois ; geographic information system ; landscape ecology ; soil ; land use ; presettlement ; vegetation ; land-use change ; fractal dimension
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract The Illinois Geographic Information System was used to compare the soil and landscape attributes of the State with its historic vegetation, current land use, and patterns of land-use change over the past 160 years. Patch structural characteristics among land types in four geographic zones were also compared. The assessment of patch characteristics revealed a highly modified State with most land patches controlled by human influences and relatively few by topographic and hydrologic features. Correlation and regression analyses determined the relationships of land type and abundance within each of 50 general soil associations to properties of the soil associations - typically slope, texture, organic matter, productivity index, and available waterholding capacity. The distribution of the historic vegetation of the State and its current deciduous forests and nonforested wetlands related moderately (r2 ≥ 0.44) to various landscape attributes. Urban and other highly modified land types were less closely related.
    Materialart: Digitale Medien
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  • 62
    Digitale Medien
    Digitale Medien
    Springer
    Landscape ecology 6 (1991), S. 49-56 
    ISSN: 1572-9761
    Schlagwort(e): soil ; dune ; climate
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract Freely drained soils in humid climates are marked by rather rapid leaching, acidification and, eventually, podzolisation, because of of the high permeability and low acid buffering capacity of the sands. In cooler climates podzols may develop within a few centuries, whereas in warmer or less humid climates podzols require several milennia or longer periods to form. In dry climates soils contain little organic matter. Clay and soluble soil components accumulate and soil salinity may be high due to salt spray. If drainage is poor, organic matter tends to accumulate and in cooler climates peat formation becomes prominent. Soil salinity increases with increasing aridity. Effects of climatic changes can only be predicted in qualitative terms and concern changes in the pedogenic trends and in the rates of the processes described. It is suggested to execute comparative studies of well-dated soils in different climatic zones in order to quantify these effects.
    Materialart: Digitale Medien
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  • 63
    Digitale Medien
    Digitale Medien
    Springer
    Biodegradation 9 (1998), S. 327-336 
    ISSN: 1572-9729
    Schlagwort(e): fungi ; organophosphate insecticides ; phosphorus mineralization ; sulfur mineralization ; soil
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Energietechnik , Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Thirteen fungal species isolated from soil treated with pesticides were tested for their ability to mineralize and degrade three organophosphate insecticides currently used in Egypt (Cyolan®, Malathion® and Dursban®) in liquid media free from phosporus (P) and sulfur (S). All fungal species grew successfully on the culture media treated with the three used doses of insecticides (10, 50 and 100 ppm active ingredient) but the growth rate varied with the species, the insecticide and the doses. At 10 ppm level, insecticide degradation expressed in term of organic P mineralization (calculated as % of applied P) was the highest with all fungi tested. Organic P mineralization from pesticides was decreased by increasing the dose used to 50 and 100 ppm. The highest amount of P mineralized was observed with Cyolan® followed by Malathion® whilst P mineralization from Dursban® proceeded very slowly. Aspergillus terreus showed the greatest potential to mineralize organic P followed by A. tamarii, A. niger, Trichoderma harzianum and Penicillium brevicompactum whilst the remaining fungi only moderately mineralized the organic P component of the insecticides tested. Organic sulfur mineralization by the used fungal species paralleled, to some extent, organic P mineralization. The extracellular protein content of culture filtrates in the presence of various doses of insecticides was also decreased by increasing insecticide concentrations. The extracellular protein was significantly correlated with P and S mineralization (r = 0.89** and 0.64**, respectively) whilst correlation with cell dry mass was not significant (r = 0.03 and 0.003) suggesting a direct relationship between pesticide degradation and microbial protein production. The addition of P or S to the growth media enhanced extracellular protein excretion, and increased organic P and S mineralization by the most potent species tested (A. niger, A. tamarii, A. terreus and T. harzianum). This increment was significant in most cases, especially at the higher application rates. The relationship between extracellular protein excretion and organic P and S mineralization from insecticides was highly significant with the addition of inorganic phosphorus (r = 0.96** and 0.83**, respectively) or sulfur (r = 0.85** and 0.89**, respectively) to the growth media.
    Materialart: Digitale Medien
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  • 64
    Digitale Medien
    Digitale Medien
    Springer
    Cellular and molecular life sciences 43 (1987), S. 104-108 
    ISSN: 1420-9071
    Schlagwort(e): Abnormalities ; trace metals ; soil ; geology ; geography
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Medizin
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 65
    ISSN: 1420-9055
    Schlagwort(e): Particles ; phosphorus ; watersheds ; snow ; frost ; soil
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract Hydrological processes are known to have a considerable effect on nutrient transport from agricultural land to watercourses. In cold temperate regions peak discharges are caused not only by storm conditions but also by melting of snow and frost. The objective of this work was to investigate the effects of snow and frost melt on concentrations of phosphorus and suspended solids. The samples were taken using flowweighted automatic sampling techniques from two agricultural drainage basins. During the beginning of the snowmelt period the concentration of suspended solids was rather low by comparison with the total phosphorus concentration and the discharge. The different behaviour compared with the relationships found during storm conditions was probably caused by continuous extraction of the soil surface by low ionic concentration melt water, and to some extent by leaching from plant residues. The gradual decrease of total phosphorus concentration during the frost thawing period could be attributed to the gradually increasing proportion of the subsurface and ground water discharge in the runoff.
    Materialart: Digitale Medien
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  • 66
    Digitale Medien
    Digitale Medien
    Springer
    Cellular and molecular life sciences 42 (1986), S. 857-860 
    ISSN: 1420-9071
    Schlagwort(e): Wine quality ; soil ; climate ; vine culture ; enology ; malolactic fermentation ; genetic selection
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Medizin
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 67
    Digitale Medien
    Digitale Medien
    Springer
    Cellular and molecular life sciences 45 (1989), S. 567-570 
    ISSN: 1420-9071
    Schlagwort(e): C-reactive protein ; mercury ; cell necrosis
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Medizin
    Notizen: Summary The C-reactive proteins (CRP) from both rat andLimulus were found to bind mercury (Hg) in both in vivo and in vitro conditions. CRP has high-affinity binding sites for Hg as evidenced by the loss of free sulfhydryl groups, arrested mobility in polyacrylamide gel electrophoresis, and the consumption of CRP in the serum after Hg administration. The binding was tight as it could not be inhibited either by the addition of cysteine or EDTA. By using a direct titration method it was shown that binding of Hg to CRP was saturable at a molar ratio of Hg/CRP=13.11. The possibility that CRP may act as a scavenger for Hg is discussed.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 68
    ISSN: 1432-072X
    Schlagwort(e): Nitrobacter ; Nitrification ; Natural population ; soil ; freshwater ; sediments ; Restriction fragment length polymorphism ; Polymerase chain reaction ; Intergenic spacer ; ribosomal RNA
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract DNA sequences from the intergenic spacer (IGS) region of the ribosomal operon were amplified by the polymerase chain reaction (PCR) technique using two primers derived from 16S and 23S rRNA conserved sequences. The PCR products, cleaved by 4 base cutting restriction enzymes, were used to differentiate Nitrobacter strains. This method offered a convenient alternative to serological testing for characterization of Nitrobacter isolates and enabled a large number of strains to be genotypically characterized easily and rapidly. This method was successfully used to characterize natural populations of Nitrobacter from various soils and a lake. A diversity was demonstrated in various soils, and in a lake both in freshwater and in sediments. Strains closely related to both WL and LL were found in these eco-systems. It seems that the diversity of Nitrobacter populations was not associated with global environments but may be related to the presence of locally coexisting niches.
    Materialart: Digitale Medien
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  • 69
    Digitale Medien
    Digitale Medien
    Springer
    Journal of industrial microbiology and biotechnology 16 (1996), S. 79-101 
    ISSN: 1476-5535
    Schlagwort(e): alginate ; bacteria ; biodegradation ; bioremediation ; κ-carrageenan ; encapsulation ; immobilization ; microorganisms ; soil
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Abstract Immobilized microbial cells have been used extensively in various industrial and scientific endeavours. However, immobilized cells have not been used widely for environmental applications. This review examines many of the scientific and technical aspects involved in using immobilized microbial cells in environmental applications, with a particular focus on cells encapsulated in biopolymer gels. Some advantages and limitations of using immobilized cells in bioreactor studies are also discussed.
    Materialart: Digitale Medien
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  • 70
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 85 (1995), S. 1275-1280 
    ISSN: 1573-2932
    Schlagwort(e): Pinus radiata ; nutrient ; needle ; soil ; principal component analysis
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Nutrient status in Pinus radiata sites in the Basque Country (Spain) have been established. Current-year, 1-year-old needles, and soil samples were collected in 7 sites. Needle samples were analyzed for calcium (Ca), magnesium (Mg), potassium (K), phosphorus (P) and nitrogen (N). Soil samples were analyzed for pH (H2O), N, P, Ca, Mg, K and aluminium (Al). The results indicate differences between sites and needles of different ages. In general, nutrient concentrations in needles are sufficient for the nutritive requirements, but some low concentrations of Mg and P found in 1-year-old needles, indicate that some trees may show signs of deficiency in the near future. In turn, N concentrations are, in many cases, higher than those usually found in this species and may originate growth disorders. These concentrations may be related to NO3 − and NH4 + deposition. Soil nutrients are sufficient for trees requirements, but the levels of K and Mg are low. Soil pH values are not very acid, and the value of the Ca/Al ratio is, in general, near 1. An arrangement of sites and physiographical and nutritional parameters based on correlation and principal component analysis is also presented.
    Materialart: Digitale Medien
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  • 71
    Digitale Medien
    Digitale Medien
    Springer
    Molecular and cellular biochemistry 138 (1994), S. 221-226 
    ISSN: 1573-4919
    Schlagwort(e): ADP-ribosylation ; cysteine ; pertussis toxin ; mercury
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie , Medizin
    Notizen: Abstract Mono-ADP-ribosylation is a protein modification that occurs at a number of different amino acids, dictated by the specificity of the individual ADP-ribosyltransferases. A specific cysteine in several guanine nucleotide-binding regulatory proteins is ADP-ribosylated by the bacterial protein pertussis toxin. Recent purification of an ADP-ribosylcysteine hydrolase and NAD:cysteine ADP-ribosyltransferase, and detection of ADP-ribose-cysteine linkages in tissue samples has raised hope that an endogenous regulatory cysteine-specific ADP-ribosylation pathway exists. A current goal is the identification of such a pathway for ADP-ribosylation of cysteine within animal cells. Interpretation of the data in this field has been complicated by recent reports that revealed several unforeseen chemical reactions of NAD and its metabolites with free cysteine and cysteine in proteins. This mini-review covers the latest understanding of the ADP-ribosylation reactions associated with cysteine, and provides a set of criteria for future research to establish positively the existence of an endogenous cysteine-specific mono-ADP-ribosyltransferase.
    Materialart: Digitale Medien
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  • 72
    Digitale Medien
    Digitale Medien
    Springer
    Journal of chemical ecology 1 (1975), S. 41-58 
    ISSN: 1573-1561
    Schlagwort(e): ferulic acid metabolism ; vanillic acid ; soil ; microorganisms ; Rhodotorula rubra ; Cephalosporium curtipes
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract The suppression of plant growth by different phenolic acids is well known. This work was designed to determine if ferulic acid, a known phenolic inhibitor of plant growth, accumulates in the soil and if soil microorganisms could be isolated that metabolize it. Over 99% of the extractable ferulic acid was lost from decaying hackberry leaves in 300 days. During this time the amount in the top 15 cm of soil remained fairly constant at about 30 ppm, except for the March sample which was significantly higher than the rest. Addition of ferulic acid to soil caused an increase in CO2 evolution and in numbers of a select group of microorganisms.Rhodotorula rubra andCepnalosporium curtipes, which actively metabolize ferulic acid, were isolated, but the metabolic pathways employed appear to be different from the reported one. The reported pathway for ferulic acid breakdown is ferulic acid to vanillic acid to protocatechuic acid to β-keto-adipic acid.Rhodotorula Rubra was found to convert ferulic acid to vanillic acid, but no evidence was found for utilization of the rest of the pathway.Cephalosporium curtipes appears to use a different pathway or to metabolize intermediate compounds rapidly without accumulating them, because no phenolic compounds were found during the breakdown of ferulic acid. The presence in the soil of microorganisms that metabolize ferulic acid and other phenolic acids is ecologically significant because such organisms prevent long-term accumulations of these substances, which are toxic to many other microorganisms and higher plants.
    Materialart: Digitale Medien
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  • 73
    Digitale Medien
    Digitale Medien
    Springer
    Journal of chemical ecology 17 (1991), S. 147-160 
    ISSN: 1573-1561
    Schlagwort(e): Eucalyptus globulus ; allelopathy ; Lactuca sativa ; natural leachates ; soil ; litter
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract Natural leachates ofEucalyptus globulus (throughfall, stemflow, and soil percolates) were collected daily during rainy spells in the vegetative period (February–July), and their effects on the germination and radicle growth ofLactuca sativa were measured. Concurrently, the effects ofL. sativa of topsoil and leachates from decaying litter were determined. The results suggest that toxic allelochemicals released byEucalyptus globulus may influence the composition and structure of the understory of the plantation and that this effect is attributable mainly to the decomposition products of decaying litter rather than to aerial leachates. The soil may neutralize or dilute allelopathic agents, at least below the top few cms.
    Materialart: Digitale Medien
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  • 74
    Digitale Medien
    Digitale Medien
    Springer
    Journal of chemical ecology 26 (2000), S. 2111-2118 
    ISSN: 1573-1561
    Schlagwort(e): Allelopathy ; laboratory bioassays ; allelochemicals ; soil ; field settings
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract One concern often voiced by researchers of allelopathic interactions is that many laboratory bioassays do not adequately predict the responses observed in field situations. The questions that arise are: (1) What criteria should be implemented to design ecologically relevant bioassays? (2) What species (crops or weeds) are involved in the interaction? (3) Are we investigating allelopathy of debris/residues or interactions involving living plants? (4) Which plant indicator species are actually cohabiting with the species under investigation? and (5) What are appropriate experimental controls? It is difficult to design a bioassay that can be used to examine responses in all species. In fact, each bioassay must be designed specifically to assess species interactions after careful consideration of growth habit, biotic characteristics, and ecophysiological factors. The objective of this paper is to discuss the significance of bioassays designed to study a particular aspect of allelopathy. We conclude that through a laboratory bioassay we can not demonstrate that allelopathy is operational in natural settings. An investigator should consider allelopathy as one component in a multifaceted approach to ecology and address key questions to determine the relevance of a particular assay. Due to the complexity of field interactions and responses, one can only hope to predict and describe some of the cause-and-effect relationships observed in a field setting. An accurate assessment of these main effects will prove invaluable in directing the focus of future research emphasis.
    Materialart: Digitale Medien
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  • 75
    ISSN: 1573-2932
    Schlagwort(e): Heavy metals ; precipitation ; throughfall ; stemflow ; soil ; metabolic activity ; trees ; uptake
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Content of copper, manganese, lead, and zinc in samples of bulk precipitation, throughfall and stemflow has been studied in a forest area in central Bohemia. The sampling localities are situated on two types of bedrock, granite and cenomaniau sandstones. The content in bulk precipitation reflects the impact of fossil fuel emission sources and the vehicular sources of lead. The deposition rate of elements in throughfall, in comparison with that of the deposition on an open land, exhibits increased values in essential microelements (in Mn approx. 45 times, Zh-5 times, Cu and Cd-2 times), with significant seasonal fluctuations. The value of the same ratio for ecotoxic lead is 0.23. The enhanced flux of elements in throughfall is ascribed mainly to the metabolic processes of the trees. Differences in the chemical composition of throughfall and stemflow collected on stands with different kind of bedrock are ascribed to various degree of accessibility of the micronutrients and various intensity of their vegetation uptake.
    Materialart: Digitale Medien
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  • 76
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 85 (1995), S. 823-828 
    ISSN: 1573-2932
    Schlagwort(e): fish ; mercury ; lake chemistry ; biomagnification
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract We determined mercury in fish (perch Perca fluviatilis) from 26 Russian lakes in three regions over four years. The lakes ranged in size from 2 to 395,000 ha, in pH from 4.5 to 10.0, and in color from 3 to 190 hazen. Sixteen lakes were drainage lakes, with permanent outlets, and 10 were seepage lakes, with no permanent inlets or outlets. The lakes were generally located in forested regions with little or no human habitation in the watershed. The three regions were geologically distinct: Precambrian Shield granitic bedrock covered with thin soil; Triassic bedrock covered with thick glacial tills; and Triassic bedrock covered with thin sediments. At each lake water samples were collected and analyzed for pH, add neutralizing capacity (ANC), major cations, and anions. Dissolved mercury species were estimated with a thermodynamic equilibrium model (MINTEQA2). Mercury content of dorsal muscle varied from 0.04 to 1.0 μg/g wet weight, and was linearly related to calculated HgCH3Cl (r20.68, p〈0.001). Lake HgCH3Cl, in turn, was related to lake pH (r2=0.86, p〈0.001). Stepwise multiple regression selected lake HgCH3Cl and color as the factors most highly related to fish mercury content, with the model accounting for 75% of the variation.
    Materialart: Digitale Medien
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  • 77
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 76 (1994), S. 133-161 
    ISSN: 1573-2932
    Schlagwort(e): biome ; climate ; crop yield ; global data bases ; land cover ; potential vegetation ; simulation models ; soil
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract The terrestrial biosphere component of the Integrated Model to Assess the Greenhouse Effect (IMAGE 2.0) uses changes in land cover to compute dynamically the greenhouse gas fluxes between the terrestrial biosphere and the atmosphere. Potential land cover for both natural ecosystems and agrosystems, are determined with the Terrestrial Vegetation Model (TVM). TVM consists of separate submodels for the water-balance, global vegetation patterns, crop distribution and potential rain fed crop yield. All these submodels are based on local climatic, hydrological and soil characteristics and appropriate global data bases for those parameters are collected or compiled. The structure of all models, data bases and linkages between them and other modules of IMAGE 2.0 are described. Although computationally demanding, the models give an adequate description of the global vegetation and agricultural patterns. The only discrepancy occurs in regions where the vegetation and agricultural distribution depends on causes other than climatic, such as additional water storage and supply, anthropogenic influence and natural disturbance. Despite this discrepancy, we conclude that TVM simulates satisfactory global vegetation characteristics and that it can be adequately integrated with other models of IMAGE 2.0.
    Materialart: Digitale Medien
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  • 78
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 80 (1995), S. 325-335 
    ISSN: 1573-2932
    Schlagwort(e): Atmospheric chemistry ; mercury ; plume model
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract A reactive plume model that includes atmospheric chemical reactions of mercury was developed. The model simulates advective transport with the mean wind flow; horizontal and vertical turbulent diffusion; gas phase; aqueous-phase and particulate chemistry; cloud microphysics; wet deposition and dry deposition. The model was applied to the simulation of clear sky, non-precipitating cloud and precipitating cloud scenarios. No significant mercury chemistry occurs in the absence of droplets. In clouds, Hg(II) is reduced to Hg(0) with more reduction taking place in precipitating clouds than in non-precipitating clouds.
    Materialart: Digitale Medien
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  • 79
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 80 (1995), S. 1209-1216 
    ISSN: 1573-2932
    Schlagwort(e): gaseous ; particulate ; mercury ; sampling ; silver ; gold ; denuder
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract A denuder-based method for sampling and separating gaseous and participate mercury in the air is described. Two different denuder configurations developed in Vilnius, Lithuania (silver) and in Gothenburg, Sweden (gold) are compared. Data were acquired at different sampling locations around the cities of Vilnius and Gothenburg. The concentration of particulate Hg was found to be 0.04 to 0.40 ng m−3 in the Vilnius region, and 0.11 to 0.57 ng m−3 in the Gothenburg region. Intel-calibration results for the silver and gold denuders are presented. The results obtained by the two different denuder configurations and sampling set-ups display satisfactory agreement.
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  • 80
    ISSN: 1573-2932
    Schlagwort(e): acidification ; buffering ; groundwater ; monitoring ; precipitation ; seasalt ; soil ; soilwater ; throughfall
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Chemical time trends for precipitation, throughfall, and soilwater (1986–1992), and groundwater (1980–1993) at Birkenes, southern Norway, are compared to gain insights into possible causes for the recent increase in groundwater acidification there. Precipitation and throughfall trends do not show evidence for an increase in anthropogenic acids (e.g. sulphate), but seasalt deposition (e.g. chloride) has been marginally greater in 1990–1992 than in most previous years on record. Soilwater composition partly indicates increasing acidification in recent years (pH, Al and ANC), but hardness and sulphate content are decreasing. Soilwater ANC became negative in 1989, revealing a lasting deficit in its potential to buffer acidity. Groundwater shows clear signs of intensifying acidification (pH, Al, ANC, hardness and sulphate), and this may result partly from climatic conditions (mild winters, ‘seasalt episodes’) and partly from the deterioration of an acid buffering system within the soil cover. Acidification via sulphate deposition certainly is not a direct cause. The declining hardness of soilwater suggests that the ion-exchange buffer in the soil may have ceased to function properly. The necessity for obtaining long-term time-series of water chemistry is underscored by this study.
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  • 81
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 89 (1996), S. 1-22 
    ISSN: 1573-2932
    Schlagwort(e): biogeochemistry ; watershed ; watershed analysis ; model ; budget ; input-output ; base cations ; dynamics ; weathering ; forest floor ; nutrient cycles ; soil ; acidification ; depletion ; ecosystem
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Watershed ecosystem analysis has been used to study aspects of nutrient cycles in many regions of the US. Here we quantify watershed input-output budgets and intrasystem cycling of the base cations Ca, K and Mg in a montane Virginia ecosystem. The intrasystem fluxes of uptake, return, canopy leaching and mineralization were simulated over the period of forest aggradation. A forest-dynamics model, based on previous models, was created to model biotically-driven fluxes at this site; biomass nutrient concentrations were parameterized with a field study. A two-year watershed mass-balance study was then conducted to estimate geologic fluxes for comparison with modeled biotic fluxes. Results show the major biotic fluxes to be much greater, highlighting the importance of considering biomass dynamics in ecosystem nutrient-cycling studies. Mineralization from forest-floor biomass compartments proved to be an increasingly important avenue for internal recycling during aggradation. Accumulation of base cations in biomass also corresponded to a production of H+ in soil at three times the H+ levels in atmospheric deposition at this location. Such high levels of base removal in soils could exceed weathering rates and may result in a depletion of bases from the soil exchange complex.
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  • 82
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 89 (1996), S. 267-275 
    ISSN: 1573-2932
    Schlagwort(e): mercury ; forest trees ; biomonitors ; contaminants
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract The concentration of mercury has been determined in assimilation organs of forest trees from 10 main industrial regions of Slovakia, four mountain forests and one military area and compared with concentration of mercury from 1356 permanent monitoring plots of Slovakia. The mercury concentration ranges for 2 yr old needles of Picea abies Karst. were (in mg kg−1): 1.249–4.402 (Rudnany iron ore mines), 0.013–0.749 (nine other industrial regions), 0.021–0.737 (four mountain forests) and 0.053–0.538 (military area). The mercury content in the soil (0–5 cm) from a mercury smelting plant ranged from 9.9 to 130 mg kg−1, and the moss Pleurozium schreberi contained 3.8–9.1 mg kg−1. The values obtained were compared with the available literature data.
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  • 83
    ISSN: 1573-2932
    Schlagwort(e): petrochemicals ; adsorption ; soil ; multi-components ; fixed-column-reactor ; experiment ; breakthrough
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Present-day massive exploration, extraction, transport, and use of petrochemicals pose a real threat of continuous or occasional accidental contamination of precious groundwater. However, the knowledge of the pathways and mechanisms involved in the transport, retention, and degradation of such chemicals once they are within the soil matrix is very limited. One of the important means of petrochemical retention in the soil is through the process of chemical adsorption onto the soil. An investigation was conducted to observe the adsorption phenomena of several components of petrochemicals (benzene, toluene, and xylene) solved in hexane utilizing the columnar continuous plug-flow configuration of a fixed bed of sands. Three types of soils were investigated for the time variation of the adsorption of the organic chemicals. The results are the indicative values of the adsoption of the principal components of petrochemicals in paacked-soil-bed subjected to tortuous seepage flow conditions of the fluids. The adsorption results are presented in the form of breakthrough curves. The paper includes the analytical methodology of UV spectroscopy which was utilized to measure the concentrations of various chemical components of the petrochemical mixture.
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  • 84
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 96 (1997), S. 301-320 
    ISSN: 1573-2932
    Schlagwort(e): acid rain ; batch experiment ; Freundlich isotherm ; lysimeter experiment ; mercury ; simulation model
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Increasing mercury contents are reported from freshwater systems and fish in northern Europe and North America. Mercury input from soils is a major source with the leaching being affected by increased atmospheric mercury deposition compared to pre-industrial times and by other environmental conditions such as acid rain. The results of a mathematical model-calculation of vertical inorganic Hg(II) leaching in a Scandinavian iron-humus podzol under different atmospheric input rates of mercury are presented. Leaching under background rain conditions was calculated to be considerably stronger than under acid rain conditions. Increasing fractions of deposited soluble or solute atmospheric mercury were leached from the O f(h)-horizon with decreasing soil content of soluble mercury under acid rain conditions; this effect was less pronounced under background rain conditions. The steady state concentrations of soluble mercury of the upper soil horizons were calculated and compared with the actual concentrations of total (= soluble + insoluble mercury) and extractable (= estimate of soluble) mercury measured in these horizons. The results indicate that even if the deposition of airborne mercury to soil is strongly reduced, the total mercury content of the soil decreases only slowly. It may take decades or even centuries before a new steady state concentration of total mercury is established in the soil. The decrease of the mercury concentration in the O f(h)-horizon is probably largely dependent on the turnover of organic matter, binding most of the deposited airborne mercury in an insoluble form. Hence, present day mercury leaching is likely to be dominated by mercury deposited during former times and temporarily retained in an insoluble form in the organic matter.
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  • 85
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 90 (1996), S. 507-520 
    ISSN: 1573-2932
    Schlagwort(e): mercury ; foodplains ; humic substances ; complexation ; speciation ; mobilization ; risk assessment ; water solubility
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract The water-mobilizability of mercury from contaminated floodplain soils of the river Elbe in Northern Germany was evaluated by batch extraction experiments. It was shown that only a small amount of the total mercury present (about 1% per extraction) can be mobilized by water. This mercury is transported entirely in the form of a complex bound to humic acids (HA); particulates and fulvic acids (FA) did not seem to contribute to the process. It could not be removed from the HA even at pH 1, indicating an extremely strong complexation e.g. by sulfur-containing ligands. Furthermore, the influence of pH on the mobilization was investigated. It was found that in the range of natural pH-values, there was no observable effect of pH on the mobilization of either mercury or dissolved organic carbon (DOC). This surprising finding is explained by an unexpectedly high buffering capacity of the humics, both in the acidic and in the alkaline region. Only at extreme pH-values there was deviation from this behaviour. In contrast to other heavy metals, the amount of mobilized mercury decreases at pH 〈 3; and at pH 〉 12, an increased mobilization of mercury was observed because the humics are mobilized completely, accompanied by the total amount of mercury bound to them.
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  • 86
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 90 (1996), S. 543-556 
    ISSN: 1573-2932
    Schlagwort(e): heavy metals ; solubility ; redox potential ; pH ; soil
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract To assess the mobilities of Pb, Cd, and Zn from a contaminated soil, the effects of redox potential and pH value on metal solubilities were investigated. Both redox potential and pH were found to greatly affect heavy metal solubility in the soil. Results showed that the soil suspension under continuous oxygen aeration for 21 days resulted in increases of redox potential from 290 to 440 mV and pH value from 6.9 to 7.0, respectively. Soluble concentrations of Pb, Cd, and Zn varied with time, and were all lower than 1 mg kg−1. When the soil suspension was aerated with nitrogen, final redox potential was −140 mV and pH value of 7.1. The soluble metal concentrations were slightly higher than those aerated with oxygen. The equilibrium solubility experiments were conducted under three different pH values (3.3, 5.0, 8.0) and three redox potential (325, 0, −100 mV). Results showed that metals were sparingly soluble under alkaline conditions (pH = 8.0). Metal solubilities were higher when under slightly acidic conditions (pH = 5.0), and increased drastically when pH was kept at 3.3. When solubilities were compared under same pH values, it was observed that metal solubilities increased as redox potential decreased. Generally speaking, acidic and reducing conditions were most favorable for metal solubilization, and the effect of pH was more significant than that of redox potential. It was proposed that heavy metals were mostly adsorbed onto Fe-Mn oxyhydroxides. The pH-dependent metal adsorption reaction and the dissolution of Fe-Mn oxyhydroxides under reducing conditions was the mechanism controlling the release of heavy metals from soils.
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  • 87
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 97 (1997), S. 205-207 
    ISSN: 1573-2932
    Schlagwort(e): mercury ; gold mining ; ecosystems ; methyl-Hg ; cycling ; global sources
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract As described by Jemelov and Ramel (1995), the Scientific Committee on Problems of the Environment (SCOPE) sponsored an investigation of Hg in ecosystems with special emphasis on tropical regions. In these regions small-scale gold mining activities have occupied about 10 million people worldwide who use Hg for extracting gold.
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  • 88
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 97 (1997), S. 257-263 
    ISSN: 1573-2932
    Schlagwort(e): mercury ; atmosphere ; rainwater ; marine
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Total gaseous mercury (TGM) and rainwater were collected on board of two research vessels (F. S. ALKOR and R.V. BELGICA) positioned 200 km apart in the center of the North Sea during the North Sea Experiment, September 1991. On the F. S. ALKOR (up-wind ship) TGM concentrations ranged from 0.7 to 2.6 ng·m−3 with an average of 1.5 ng m−3 and on the R. V. BELGICA (down-wind ship) TGM ranged from 0.7 to 1.9 ng·m−3 with an average of 1.2 ng·m−3. An average 20% decrease is observed from the up-wind to the down wind ship. which may largely be affected by entrainment into the free troposphere. An overall removal (entrainment) velocity of 0.95 cm·s−1 was calculated for the whole experiment. The average removal velocity was 0.5 cm·s−1 for dry periods and varied between 1 to 5 cm·s−1 during rain events. Rainwater concentrations varied between 5 and 25 ng·1−1. Based on these data an annual wet deposition flux of 1.08 ng Hg cm−2 yr1− was estimated for the North Sea.
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  • 89
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 94 (1997), S. 85-98 
    ISSN: 1573-2932
    Schlagwort(e): soil ; pollution ; heavy metals ; smelters ; factoranalysis
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract A combined statistical and computergraphic approach is proposed for apportionment and attribution of soil contaminants in complex areas. The field test site lies north of Swansea, south Wales and contains two major pollutant sources, an active nickel refiner and (4 km away) the site of major base metal smelting in the nineteenth century (the Lower Swansea Valley reclamation study area). Soil samples (70 samples, 0–15 cm) were collected on a regular grid of 1000 m interval. They were extracted using 0.05 M diammonium EDTA and the extracts analysed for Cd, Co, Cu, Fe, Mn, Ni, Pb and Zn. Soil pH and %organic content were also determined. Factor analysis yielded three groups which explained 73.8% of the data variance (1: Cd, Cu, %OM, Pb, Zn, Ni; 2: Cd, Zn, Mn, pH; 3: Cu, Mn, Co, Ni, Fe). Isoline plots were classifiable into the same three groups. It was concluded that factor 3 contained those elements associated with smelter emissions, factor 1 with contamination from the Lower Swansea Valley and in factor 2 pedogenetic processes control the occurrence of the elements.
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  • 90
    ISSN: 1573-2932
    Schlagwort(e): mercury ; methylmercury ; sediment ; polychaete ; Nereis diversicolor ; methylation ; bioaccumulation ; Scheldt estuary
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Total mercury (Hg) and methylmercury (MeHg) concentrations were determined in sediments and in the polychaete worm Nereis diversicolor at 13 stations of a brackish water intertidal mudflat of the Scheldt estuary. Hg and MeHg concentrations in sediments ranged from 144 to 1192 ng g−1 dw and from 0.8 to 6 ng g−1 dw, respectively. Both Hg and MeHg concentrations increased with an increase of organic matter (OM) content and fine grain fraction. In contrast, Hg accumulation by N. diversicolor was significantly (p 〈 0.05) higher at stations with sandy sediments (mean value: 125 ng g−1 dw) than at stations with muddy sediments (mean value, 80 ng g−1), probably because Hg availability for bioaccumulation at muddy stations was reduced by high OM content of the muddy sediments. MeHg accounted for an average of 0.7% of the total Hg in sediments and 18% of the total Hg in N. diversicolor. Seasonal variations significantly affected Hg concentrations in sediments and MeHg in N. diversicolor. Total Hg concentrations in sediments were significantly (p 〈 0.05) higher in autumn and winter than in spring and summer whereas MeHg concentrations were lowest in winter compared to the other seasons. On the other hand, total Hg concentrations in the worms were lowest in spring whereas MeHg concentrations were significantly (p 〈 0.01) higher in spring and summer than in autumn and winter.
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  • 91
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 94 (1997), S. 163-180 
    ISSN: 1573-2932
    Schlagwort(e): acid deposition ; liming ; catchment ; lake ; water chemistry ; fish ; soil ; model
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract In June 1983 a whole-catchment liming experiment was conducted at Tjønnstrond, southernmost Norway, to test the utility of terrestrial liming as a technique to restore fish populations in remote lakes with short water-retention times. Tjønnstrond consists of 2 small ponds of 3.0 and 1.5 ha in area which drain a 25-ha catchment. The area is located at about 650–700 meters above sea-level in sparse and unproductive forests of spruce, pine and birch with abundant peatlands. A dose of 3 ton/ha of powdered limestone were spread by helicopter to the terrestrial area. No limestone was added to the ponds themselves. The ponds were subsequently stocked with brown and brook trout. Liming caused large and immediate changes in surface water chemistry; pH increased from 4.5 to 7.0, Ca increased from 40 to 200 μeq/L, ANC increased from –30 to +70 μeq/L, and reactive-Al decreased from about 10 to 3 μmol/L. During the subsequent 11 years the chemical composition of runoff has decreased gradually back towards the acidic pre-treatment situation. The major trends in concentrations of runoff Ca, ANC, pH, Al and NO3 in runoff are all well simulated by the acidification model MAGIC. Neither the measured data nor the MAGIC simulations indicate significant changes in any other major ion as a result of liming. The soils at Tjønnstrond in 1992 contained significantly higher amounts of exchangeable Ca relative to those at the untreated reference catchment Storgama. In 1992 about 75% of the added Ca remains in the soil as exchangeable Ca, 15% has been lost in runoff, and 10% is unaccounted for. The whole-catchment liming experiment at Tjønnstrond clearly demonstrates that this liming technique produces a long-term stable and favourable water quality for fish. Brown trout in both ponds in 1994 have good condition factors, which indicate that the fish are not stressed by marginal water quality due to re-acidification. The water quality is still adequate after 11 years and 〉20 water renewals. Concentrations of H+ and inorganic Al have gradually increased and approach levels toxic to trout, but the toxicity of these are offset by the continued elevated Ca concentrations. Reduced sulphate deposition during the last 4 years (1990–94) has also helped to slow and even reverse the rate of reacidification. The experiment at Tjønnstrond demonstrates that for this type of upland, remote terrain typical of large areas of southern Norway, terrestrial liming offers a suitable mitigation technique for treating acidified surface waters with short retention times.
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  • 92
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 99 (1997), S. 217-223 
    ISSN: 1573-2932
    Schlagwort(e): selective leach ; organic ; humic ; fulvic ; analysis ; mercury ; zinc
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract The international reference lake sediment, LKSD-4, was used to compare Hg, organic C and Zn extracted from its ‘soluble organic’ phase by two commonly used reagents: 0.1 M Na4P2O7 solution at pH 10 and 0.5 M NaOH solution at pH 12. While recoveries of Hg and Zn by 0.1 M Na4P2O7 are not affected by changes in sample weight to reagent volume ratio (W/V) or contact time, those by NaOH show a marked dependency. In general, the NaOH leach extracts more organic C and Hg from LKSD-4 but less Zn. Over the range of conditions studied, the NaOH-based method extracted 4.7–9.8% C, 27–103 ng g−1 Hg and 19–69 μg g−1 Zn from LKSD-4, compared to 2.3–2.8% C, 17–24 ng g−1 Hg and 64–72 μg g−1 Zn by the Na4P2O7 leach. Clearly, different groups of organic substances are being dissolved by these two reagents and therefore a comparison of data from different laboratories becomes meaningless. This paper suggests that more research is needed into the exactNature of metal-organic associations extracted by selective leaches and into associated artifacts of extraction such as readsorption phenomena.
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  • 93
    Digitale Medien
    Digitale Medien
    Springer
    Environmental monitoring and assessment 59 (1999), S. 191-209 
    ISSN: 1573-2959
    Schlagwort(e): estimation ; geostatistics ; interpolation ; radionuclides ; soil
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Many environmental surveys require the implementation of estimation techniques to determine the spatial distribution of the variable being investigated. Traditional methods of interpolation and estimation, for example, inverse distance squared and triangulation often ignore features of the data set such as anisotropy which may have a significant impact on the quality of the estimates produced. Geostatistical techniques may offer an improved method of estimation by modelling the spatial continuity of the variable using semi-variogram analysis. The theoretical model fitted to the semi-variogram is then used in the assignation of weighting factors to the samples surrounding the location to be estimated. This paper outlines the results of a comparison between three common estimation methods, polygonal, triangulation and inverse distance squared and a geostatistical method, in the estimation of soil radionuclide activities. The geostatistical estimation method known as kriging performed best over a range of parameters used to test the performance of the methods. Kriging exhibited the best correlation between actual and estimated values, the narrowest error distribution and the lowest overall estimation error. Polygonal estimation was best at reproducing the data set distribution. Conditional bias was evident in all the methods, low values being over-estimated and high values being under-estimated.
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  • 94
    Digitale Medien
    Digitale Medien
    Springer
    Environmental monitoring and assessment 60 (2000), S. 71-88 
    ISSN: 1573-2959
    Schlagwort(e): copper-nickel smelter ; ICP mass spectrometry ; Kola peninsula ; pollution ; soil ; trace elements ; vegetation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Concentrations of 34 elements determined by ICP mass spectrometry were studied in surface soil and vegetation along a north–south gradient through the ‘Pechenganickel’ smelter complex in Kola peninsula, northern Russia. Strong influence from the smelter was evident for Fe, Co, Ni, and Cu, mainly associated with dry deposition of large particles. Also for As, Se, Mo, Sb, Te, Bi, and Pb the smelter or associated sources appeared to be distinct contributors of contamination consisting presumably of smaller particles. Significant but less distinct effects leading to enhanced concentration levels were observed for P, S, V, Cr, Zn, and Tl. In the case of Mn, Rb, Sr, Cs, and Ba the concentrations in vegetation were generally lower near the source, which may be due to cation exchange with protons or heavy metal cations in the soil and subsequent leaching from the root zone. For Li, Be, B, Na, Mg, Al, Ca, Y, Cd, La, Th, and U no particular influence from the smelter complex was observed. Some characteristic differences observed in element concentrations in different plant species and between different years of Pinus sylvestris needles are discussed. The high concentrations observed for many trace elements in the humus horizon indicates that it acts as an active biogeochemical barrier against downward transport of these elements.
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  • 95
    Digitale Medien
    Digitale Medien
    Springer
    Environmental monitoring and assessment 64 (2000), S. 583-590 
    ISSN: 1573-2959
    Schlagwort(e): biological activity of soil ; constantpressure volumetric respirometer ; flow-through respirometer ; respirometry methods ; soil ; soil respiration
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Among commonly employed methods of fast estimation of the soil biological activity a method of the oxygen consumption determination is used. The main goal of this research was an estimation of a soil respiratory metabolism using the constant pressure volumetric respirometer and also using the flow-through respirometer UNI-RES10.Soil respiration measurements were done using both types of respirometers in temperatures 10, 15, 20, 25, 30 and 35 °C, keeping up the constant humidity. The investigated soil was a soil humus belonged to organic soils from the Dziekanów Leśny field. The soil respiration was also measured for 8 plant communities in Sudeten Mountains with various respiration intensity.After the experiments it was stated that both measuring instruments could be used for the soil metabolism evaluation. Readouts obtained from the UNI-RES10 respirometer are smaller then readouts when using the constant pressure volumetric respirometer. The flow-through respirometers have to be calibrated to obtain results comparable with these from volumetric ones. The volumetric and flow-through respirometry methods are useful for the comparative analysis of metabolism levels.
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  • 96
    Digitale Medien
    Digitale Medien
    Springer
    Environmental and ecological statistics 4 (1997), S. 49-64 
    ISSN: 1573-3009
    Schlagwort(e): soil ; pollution ; threshold ; geostatistics ; indicators ; kriging ; risk ; Swiss Jura
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract The probability that the concentrations of toxic substances in soil or other medium exceed tolerablemaxima at any unsampled place can be estimated by indicator geostatistics. The method is developed and used to estimate and map the risk of contamination by cadmium, copper and lead in the topsoil of a 14.5 km 2 region in the Swiss Jura. It combines both direct measurements of metal concentrations and thecalibration of a geological map, and it shows that the risk of toxicity is least on Argovian rocks. Two approaches are proposed to divide a region into safe' and 'hazardous' zones on the basis of probability maps. The first declares as contaminated all places where the risk of contamination exceeds a given threshold. The second approach first evaluates the financial costs that might result from a wrongdeclaration, after which the site is allocated to a class so as to minimize that cost. The risk of exposure for humans and animals is generally greater for contaminated agricultural land than for forest soil, and so land use is taken into account in both procedures.
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  • 97
    Digitale Medien
    Digitale Medien
    Springer
    Ecotoxicology 2 (1993), S. 33-40 
    ISSN: 1573-3017
    Schlagwort(e): mercury ; body distribution ; feather concentrations ; body burden ; tern chicks
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: We studied mercury concentrations and amounts in tissues of 19 starved young Common Tern chicks (median age 4 days) and in eggs from the same colony. Concentrations and burden were similar between eggs and newly hatched chicks. Mercury concentrations were highest in down, which contained at least 38% of the body mercury. The mercury burden of the whole body and of the tissues as well as the concentration in down increased with age and body mass, indicating the importance of down as an elimination pathway. Conversion ratios between mercury concentrations in tissues and the whole chick body varied according to the contamination level.
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  • 98
    ISSN: 1573-3017
    Schlagwort(e): fish ; mercury ; natural selection ; allozyme ; population
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Measurements of the differential tolerance between enzyme genotypes and shifts in allozyme frequencies in populations from contaminated habitats have prompted the use of allozymes as markers of population-level toxicant effects. However, such studies often do not consider other factors that influence allele frequencies, including natural clines, migration, the intensity and specificity of selection and toxicant-induced genetic bottlenecks. In addition, selection components other than survival are not included. Consequently, the associated conclusions remain speculative. To assess this approach rigorously, a simulation study was conducted with the mosquitofish (Gambusia holbrooki) GPI-2 locus. Laboratory studies have shown the GPI-238/38 homozygote at this locus to be less tolerant than other genotypes during acute exposure to mercury. The GPI-2100/100 genotype has also been shown to have a reproductive disadvantage at lower mercury concentrations. Simple and then more complex models were used to quantify the relative effects of viability selection, random genetic drift and migration on the GPI-238 allele frequency. Simulations were also performed to assess the contribution of sexual and fecundity selection. A simple population model suggested that viability selection plays a greater role than does mortality-driven, genetic drift in the decrease of the sensitive allele under the conditions of this study. A more complex, stochastic model indicated that no significant mortality-driven drift was taking place in this system. In both models, migration mitigated the effect of selection. Sexual and fecundity selection had little effect on the allele frequencies in these simulations. We conclude that, provided the system under study is clearly understood, shifts in allele frequency can indicate the population-level effects of pollutants.
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  • 99
    ISSN: 1573-3017
    Schlagwort(e): earthworm ; nickel ; soil ; toxicology ; eisenia veneta
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract The toxic effects of nickel on survival, growth, and reproduction of Eisenia veneta were investigated following 4 weeks of exposure to a nickel-chloride spiked loamy sand soil. The ability of a simple earthworm biomarker, the lysosomal membrane stability of coelomocytes, to reflect nickel exposure was also studied. Nickel caused a significant toxic effect on E.veneta at soil concentrations above 85 mg Ni/kg. Reproduction (cocoon production) was the most sensitive parameter being reduced at soil concentrations above 85 mg Ni/kg (EC10 = 85 mg Ni/kg). Survival of adults was only reduced at concentrations above 245 mg Ni/kg, while adult and cocoon wet weight were not affected by soil nickel concentrations up to 700 mg Ni/kg. The lysosomal membrane stability, measured as neutral-red retention time, was reduced at soil nickel concentrations similar to those that reduced reproduction, and demonstrated a dose-response relationship. The neutral-red retention time showed large individual variation for the earthworms within each exposure concentration. It was concluded that the lysosomal membrane stability, measured as neutral red retention time, has a potential role in risk assessment, but care should be taken conducting this test.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 100
    ISSN: 1573-4919
    Schlagwort(e): mercury ; rat kidney ; mitochondria ; oxidative phosphorylation ; FoF1-ATPase ; ATP synthesis ; ATP hydrolysis ; oxidative stress
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie , Medizin
    Notizen: Abstract The effects of Hg(II) on bioenergetic and oxidative status of rat renal cortex mitochondria were evaluated both in vitro, and in vivo 1 and 24 h after treatment of animals with 5 mg HgCl2/kg ip. The parameters assessed were mitochondrial respiration, ATP synthesis and hydrolysis, glutathione content, lipid peroxidation, protein oxidation, and activity of antioxidant enzymes. At low concentration (5 µM) and during a short incubation time, Hg(II) uncoupled oxidative phosphorylation while at slightly higher concentration or longer incubation time the ion impaired the respiratory chain. The rate of ATP synthesis and the phosphorylation potential of mitochondria were depressed, although inhibition of ATP synthesis did not exceed 50%. In vivo, respiration and ATP synthesis were not affected 1 h post-treatment, but were markedly depressed 24 h later. ATP hydrolysis by submitochondrial particle FoF1-ATPase was inhibited (also by no more than 50%) both in vitro, and in vivo 1 and 24 h post-treatment. Hg(II) induced maximum ATPase inhibition at about 1 uM concentration but did not have a strong inhibitory effect in the presence of Triton X-100. Oxidative stress was not observed in mitochondria 1 h post-treatment. However, 24 h later Hg(II) reduced the GSH/GSSG ratio and increased mitochondrial lipid peroxidation and protein oxidation, as well as inhibited GSH-peroxidase and GSSG-reductase activities. These results suggest that the following sequence of events may be involved in Hg(II) toxicity in the kidney: (1) inhibition of FoFl-ATPase, (2) uncoupling of oxidative phosphorylation, (3) oxidative stress-associated impairment of the respiratory chain, and (4) inhibition of ATP synthesis.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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