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  • 04. Solid Earth::04.08. Volcanology::04.08.01. Gases  (11)
  • ddc:551  (11)
  • Adaptation
  • Springer Berlin Heidelberg  (21)
  • Blackwell  (3)
  • 1
    Publication Date: 2020-11-16
    Description: Geochemical investigations have shown that there is a considerable inflow of gas into both crater lakes of Monticchio, Southern Italy. These lakes are located in two maars that formed 140,000 years ago during Mt. Vulture volcano’s last eruptive activity. Isotopic analyses suggest that CO2 and helium are of magmatic origin; the latter displays 3He/4He isotope ratios similar to those measured in olivines of the maar ejecta. In spite of the fact that the amount of dissolved gases in the water is less than that found in Lake Nyos (Cameroon), both the results obtained and the historical reports studied indicate that these crater lakes could be highly hazardous sites, even if they are located in a region currently considered inactive. This could be of special significance in very popular tourist areas such as the Monticchio lakes, which are visited by about 30,000 people throughout the summer, for the most part on Sundays.
    Description: In press
    Description: 83-87
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Description: open
    Keywords: volcanic gases ; gas hazard ; crater lakes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2021-06-16
    Description: In Ecuador, magmatism results from the subduction of the Nazca Plate beneath the North Western part of South America. North of 2.5°S, the Ecuadorian Quaternary volcanic arc is characterized by about 60 volcanoes distributed along three different parallel NNE-striking chains. Many of these volcanoes are potentially active or currently in activity displaying associated geothermal fields. South of this latitude, no active arc is present in Ecuador. Few geochemical studies of the discharged fluids in this region have been attempted, mainly related to geothermal exploration. Nevertheless, a complete study of the fluids of the volcanic arc is lacking. The aim of this work is to present the first systematic geochemical characterization of discharged fluids from the entire Ecuadorian volcanic arc. In order to achieve this objective, 56 samples of thermal and cold waters, as well as 32 dissolved and 27 bubbling gases, were collected from North to South across the arc and analyzed for determination of the main geochemical parameters. A chemical study reflects the physical and chemical processes undergone by these cold and thermal waters during their circulation through the different host rocks. The chemistry of the dissolved gases, are characterized by He and CO2 contents, 2 to 3 orders of magnitude higher than the ASW values implies very active gas-water interaction processes. Moreover, both dissolved and bubbling gases isotopic signature shows a wide compositional range, with Helium ranging between 0.1 to 7.12 R/Ra and carbon ranging from -1.75 to -10.50 13C(TDIC) vs PDB standard. Such isotopic features may be related to the presence of at least two distinct end-members: mantle and crustal.. Helium, Nitrogen, Carbon, Oxygen and Deuterium isotopic signatures will help us to identify and characterize the main end-members of fluids involved in Ecuador’s continental arc-volcanism. Moreover, on the basis of the chemistry of thermal waters and associated bubbling gases the characteristics and the potential resources of the different geothermal fields are being investigated.
    Description: Published
    Description: 525-541
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: gases ; isotopes ; Helium ; Nitrogen ; 04. Solid Earth::04.07. Tectonophysics::04.07.08. Volcanic arcs ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
    Publication Date: 2017-04-04
    Description: We report the results of 16 months of continuous measurements of soil CO2 flux at a fumarole field in the summit area of Mt. Etna. The patterns of soil CO2 emissions suggest two contrasting degassing regimes. During the period of observation, volcanic activity at the summit craters displayed striking extremes, ranging from passive to explosive degassing, which culminated in lava fountains. These changes in activity coincided with fluctuation between the two degassing patterns. Building on the findings of previous studies, we propose an interpretative framework that explains the observed correlation in terms of a modification of the dynamics of magma supply. We argue that periods of higher CO2 flux are associated with deep open system degassing conditions, whereas low-level CO2 flux signals closed system degassing and less efficient discharge of deeply exsolved gas. An important implication of our study is that, in relation to the two degassing regimes, two types of activity are expected at the summit craters. Thus, our measurements represent a valuable tool for the evaluation of the evolution of volcanic activity
    Description: Published
    Description: 846
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Magma supply dynamics ; Soil CO2 emissions ; Lava fountain ; Mt. Etna ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
    Publication Date: 2020-02-24
    Description: Socorro Island is the exposed part of an approx. 4000-m-high volcanic edifice rising from the oceanic floor to approx. 1000 m asl at the northern part of the Mathematician Ridge, Western Pacific. The volcano is active, with the most recent basaltic eruption in 1993. Moderate fumarolic activity and diffuse degassing with a total CO2 flux of approx. 20 total day)1 are concentrated in the summit region of the volcano composed of a group of rhy- olite domes. Low-temperature, boiling point, fumaroles discharge gas with high H2 (up to 20 mol% in dry gas) and CH4 (up to 4 mol%). Both carbon and He isotopic ratios and abundances correspond to those in MORB flu- ids (d13CCO2 )5&; 3He ⁄ 4He = 7.6 Ra, CO2 ⁄ 3He = (2–3) · 109, where Ra is the atmospheric ratio 3He ⁄ 4He of 1.4 · 10)6. Light hydrocarbons (CH4, C2H6, C3H8, and C4H10) are characterized by a high C1 ⁄C2+ ratio of approx. 1000. Methane is enriched in 13C (d13CCH4 from )15 to )20&) and 2H (d2H from )80 to )120&), and hydrocarbons show an inverse isotopic trend in both d13C and d2H (ethane is isotopically lighter than methane). These isotopic and concentration features of light hydrocarbons are similar to those recently discovered in fluids from ultramafic-hosted spreading ridge vents and may be related to the serpentinization processes: H2 generation and reduction of CO2 to CH4 within high-temperature zone of volcano-seawater hydrothermal system hosted in basaltic and ultramafic rocks beneath a volcano edifice. The thermodynamic analysis of this unusual composition of the Socorro fluids and the assessment of endmember compositions are complicated by the near-surface cool- ing, condensation and mixing with meteoric water.
    Description: Published
    Description: 542-555
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: open
    Keywords: Geochemistry ; isotopes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
    Publication Date: 2017-04-04
    Description: Near-infrared room temperature tunable diode lasers(TDL) have recently found increased usage in atmospheric chemistry and air monitoring research, but applications in volcanology are still limited to a few examples. Here, we explored the potential of a commercial infrared laser unit (GasFinder 2.0 from Boreal Laser Ltd) for measurement of volcanic CO2 mixing ratios, and ultimately for estimating the volcanic CO2 flux. Our field tests were conducted at Campi Flegrei near Pozzuoli, Southern Italy, where the GasFinder was used during three campaigns in October 2012, January 2013 and May 2013 to repeatedly measure the path-integrated mixing ratios of CO2 along cross sections of the atmospheric plumes of two major fumarolic fields (Solfatara and Pisciarelli). By using a tomographic post-processing routine, we resolved, for each of the two fields, the contour maps of CO2 mixing ratios in the atmosphere, from the integration of which (and after multiplication by the plumes’ transport speeds) the CO2 fluxes were finally obtained. We evaluate a total CO2 output from the Campi Flegrei fumaroles of ∼490 Mg/day, in line with independent estimates based on in situ (Multi-GAS) observations. We conclude that TDL technique may enable CO2 flux quantification at other volcanoes worldwide.
    Description: 1- Progetto V2 “Precursori” DPC-INGV research agreement 2012-2013; 2- Miur (PRIN 2009; PI M.V.), and 3-European Research Council under the European Union’s Seventh Framework Programme (FP7/2007/2013)/ERC grant agreement n1305377 (PI, A.A).
    Description: Published
    Description: 812
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: Tunable diode lasers ; Atmospheric CO2 monitoring ; gas sensing ; spectroscopy ; Volcanic CO2 fluxes ; Campi Flegrei ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
    Publication Date: 2017-04-04
    Description: Between 1994 and 2010, we completed 16 thermal surveys of Vulcano’s Fossa fumarole field (Aeolian Islands, Italy). In each survey, between 400 and 1,200 vent temperatures were collected using a thermal infrared thermometer from distances of ∼1 m. The results show a general decrease in average vent temperature during 1994–2003, with the average for the entire field falling from ∼220°C in 1994 to ∼150°C by 2003. However, between 2004 and 2010, we witnessed heating, with the average increasing to ∼190°C by 2010. Alongside these annual-scale field-wide trends, we record a spatial re-organisation of the fumarole field, characterised by shut down of vent zones towards the crater floor, matched by rejuvenation of zones located towards the crater rim. Heating may be expected to be associated with deflation because increased amounts of vaporisation will remove volume from the hydrothermal system Gambino and Guglielmino (J Geophys Res 113: B07402, 2008). However, over the 2004–2010 heating period, no ground deformation was observed. Instead, the number of seismic events increased from a typical rate of 37 events per month during 1994–2000 to 195 events per month during 2004–2010. As part of this increase, we noticed a much greater number of high-frequency events associated with rock fracturing. We thus suggest that the heating event of 2004–2010 was the result of changed permeability conditions, rather than change in the heat supply from the deeper magmatic source. Within this scenario, cooling causes shut down of lower sectors and re-establishment of pathways located towards the crater rim, causing fracturing, increased seismicity and heat flow in these regions. This is consistent with the zone of rejuvenation (which lies towards and at the rim) being the most favourable location for fracturing given the stress field of the Fossa cone Schöpa et al. (J Volcanol Geotherm Res 203:133–145, 2011); it is also the most established zone, having been active at least since the early twentieth century. Our data show the value of deploying multi-disciplinary geophysical campaigns at degassing (fumarolic) hydrothermal systems. This allows more complete and constrained understanding of the true heat loss dynamics of the system. In the case study presented here, it allows us to distinguish true heating from apparent heating phases. While the former are triggered from the bottom-up, i.e. they are driven by increases in heat supply from the magmatic source, the latter are triggered from the top-down, i.e. by changing permeability conditions in the uppermost portion of the system to allow more efficient heat flow over zones predisposed to fracturing.
    Description: Published
    Description: 1293-1311
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: restricted
    Keywords: Fumaroles ; Vulcano ; Vent temperature ; Seismicity ; Ground Deformation ; Permeability ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
    Publication Date: 2017-04-04
    Description: Editor’s Note: The following comment and reply arise from an article published in Geophysical Research Letters by Voigt et al. (2014). The article addresses a volcanology topic, and the commenters take issue with some conclusions and offer an analysis of their own. Voigt and co-authors have responded. Why is this comment-and-reply being published in the Bulletin? It is because Geophysical Research Letters is one of a number of journals that do not offer any published forum for discussion of the papers they publish. This is a matter of editorial policy, and a decision for each journal. The Bulletin of Volcanology does provide a forum for discussion of articles published. When contacted by Marcello Liotta with the request that the Bulletin consider hosting a discussion of the Voigt et al. volcanology article in GRL, I agreed to do so if the GRL authors were willing to engage with the comment. Voigt and co-authors were willing to do so, and have been allowed a small amount of additional space to summarize for Bulletin readers the key points of the GRL paper under discussion before responding directly to the comment from Liotta and Rizzo. I hope that Bulletin readers find the discussion and reply of interest. James D.L. White Executive Editor, Bulletin of Volcanology
    Description: Published
    Description: 864
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: Evolution . Mt. Etna . Volcanic plumes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
    Publication Date: 2017-04-04
    Description: Editor’s Note: The following comment and reply arise from an article published in Geophysical Research Letters by Voigt et al. (2014). The article addresses a volcanology topic, and the commenters take issue with some conclusions and offer an analysis of their own. Voigt and co-authors have responded. Why is this comment-and-reply being published in the Bulletin? It is because Geophysical Research Letters is one of a number of journals that do not offer any published forum for discussion of the papers they publish. This is a matter of editorial policy and a decision for each journal. The Bulletin of Volcanology does provide a forum for discussion of articles published. When contacted by Marcello Liotta with the request that the Bulletin consider hosting a discussion of the Voigt et al. volcanology article in GRL, I agreed to do so if the GRL authors were willing to engage with the comment. Voigt and co-authors were willing to do so and have been allowed a small amount of additional space to summarize for Bulletin readers the key points of the GRL paper under discussion before responding directly to the comment from Liotta and Rizzo. I hope that Bulletin readers find the discussion and reply of interest.
    Description: Published
    Description: 865
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: open
    Keywords: Volcanic degassing ; Volcanic plume ; Etna ; Chemical evolution of trace gases ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
    Publication Date: 2022-05-25
    Description: The continuous measurement of molecular hydrogen (H2) emissions from passively degassing volcanoes has recently been made possible using a new generation of low-cost electrochemical sensors. We have used such sensors to measure H2, along with SO2, H2O and CO2, in the gas and aerosol plume emitted from the phonolite lava lake at Erebus volcano, Antarctica. The measurements were made at the crater rim between December 2010 and January 2011. Combined with measurements of the long-term SO2 emission rate for Erebus, they indicate a characteristic H2 flux of 0. 03 kg s-1 (2. 8 Mg day-1). The observed H2 content in the plume is consistent with previous estimates of redox conditions in the lava lake inferred from mineral compositions and the observed CO2/CO ratio in the gas plume (~0. 9 log units below the quartz-fayalite-magnetite buffer). These measurements suggest that H2 does not combust at the surface of the lake, and that H2 is kinetically inert in the gas/aerosol plume, retaining the signature of the high-temperature chemical equilibrium reached in the lava lake. We also observe a cyclical variation in the H2/SO2 ratio with a period of ~10 min. These cycles correspond to oscillatory patterns of surface motion of the lava lake that have been interpreted as signs of a pulsatory magma supply at the top of the magmatic conduit.
    Description: Published
    Description: 2109 – 2120
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: Erebus volcano; Hydrogen; Lava lake; Magma redox conditions; Volcanic degassing ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
    Publication Date: 2023-06-23
    Description: Die Ergebnisse regionaler Klimaprojektionen für Deutschland weisen auf eine Zunahme der mittleren Lufttemperatur und eine innerjährliche Verschiebung der Niederschläge – mit feuchteren Wintern und trockeneren Sommern – hin. Darüber hinaus werden sich regional die Häufigkeit, Intensität und Dauer von Hitzewellen, Trockenperioden und Starkregenereignissen weiter erhöhen. Durch diese Veränderungen wird sich auch der Jahresgang der Grundwasserneubildung ändern. Als Folge dessen können sich Änderungen bei den hohen, mittleren und tiefen Grundwasserständen, Grundwasserschwankungsbreiten und dem Grundwasserdargebot ergeben. Aber nicht nur die Ressource Grundwasser wird durch die Folgen des Klimawandels betroffen. Auch die gesamte Infrastruktur – von der Förderung bis zur Verteilungsleitung zum Kunden – kann beeinträchtigt werden. Neben den direkten Einflüssen sind auch indirekte Beeinflussungen durch Kaskadeneffekte – beispielsweise ausgehend vom Energiesektor – möglich. Darum gilt es integrative, ganzheitliche und systemische Lösungen zu erarbeiten, um die Funktionalität der kritischen Infrastruktur dauerhaft auch unter Berücksichtigung der Folgen des Klimawandels gewährleisten zu können.
    Description: Helmholtz-Zentrum Geesthacht - Zentrum für Material- und Küstenforschung GmbH (HZG) (4216)
    Description: Climate change impacts on groundwater use—impacts and action needs
    Keywords: ddc:304.28 ; Klimawandel ; Wasserversorgung ; Kritische Infrastruktur ; Anpassung ; Climate change ; Impacts ; Water supply ; Critical infrastructure ; Adaptation
    Language: German
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  • 11
    Publication Date: 2023-06-17
    Description: Paleo-shorelines on continental shelves give insights into the complex development of coastlines during sealevel cycles. This study investigates the geologic development of the Limpopo Shelf during the last sealevel cycle using multichannel seismic and acoustic datasets acquired on the shelf in front of the Limpopo River mouth. A detailed investigation of seismic facies, shelf bathymetry, and a correlation to sea level revealed the presence of numerous submerged shorelines on the shelf. These shorelines are characterized by distinct topographic ridges and are interpreted as coastal dune ridges that formed in periods of intermittent sealevel still-/slowstand during transgression. The shorelines are preserved due to periods of rapid sealevel rise (melt water pulses) that led to the overstepping of the dune ridges as well as due to early cementation of accumulated sediments that increased the erosive resistance of the ridges. The high along-shelf variability of the submerged dune ridges is interpreted as a result of pre-existing topography affecting shoreline positions during transgression. The pre-existing topography is controlled by the underlying sedimentary deposits that are linked to varying fluvial sediment input at different points on the shelf. The numerous prominent submerged dune ridges form barriers for the modern fluvial sediment from the Limpopo River and dam sediment on the inner shelf. They may also facilitate along-shelf current-induced sediment transport.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551 ; Limpopo Shelf ; Geology
    Language: English
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  • 12
    Publication Date: 2023-06-17
    Description: After the onset of plate collision in the Alps, at 32–34 Ma, the deep structure of the orogen is inferred to have changed dramatically: European plate break-offs in various places of the Alpine arc, as well as a possible reversal of subduction polarity in the eastern Alps have been proposed. We review different high-resolution tomographic studies of the upper mantle and combine shear- and body-wave models to assess the most reliable geometries of the slabs. Several hypotheses for the tectonic evolution are presented and tested against the tomographic model interpretations and constraints from geologic and geodetic observations. We favor the interpretation of a recent European slab break-off under the western Alps. In the eastern Alps, we review three published scenarios for the subduction structure and propose a fourth one to reconcile the results from tomography and geology. We suggest that the fast slab anomalies are mainly due to European subduction; Adriatic subduction plays no or only a minor role along the Tauern window sections, possibly increasing towards the Dinarides. The apparent northward dip of the slab under the eastern Alps may be caused by imaging a combination of Adriatic slab, from the Dinaric subduction system, and a deeper lying European one, as well as by an overturned, retreating European slab.
    Description: GRNE graduate school
    Description: Deutsche Forschungsgemeinschaft (DE)
    Description: H2020 Marie Skłodowska-Curie Actions ()
    Description: http://www.orfeus-eu.org/eida
    Keywords: ddc:551 ; Seismic tomography ; Subduction slabs ; Alpine subduction system ; Slab break-off ; Slab polarity reversal
    Language: English
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  • 13
    Publication Date: 2023-06-17
    Description: The Namibian Mesozoic successions may be remnant of a high dynamic sedimentary system that is characterized by multiple stages of sediment accumulation and erosion with contemporaneous homogenization starting with the deposition of the Permo-Carboniferous Dwyka Group strata and continues at least until the Lower Cretaceous. The Lower Cretaceous sedimentary system is interpreted to have involved at least an area covering the whole SW Gondwana, documenting the sedimentary history during the evolution from an ice house environment to an arid desert. To test the sediment homogenization hypothesis, we applied a combination of isotopic and morphometric data on detrital zircon grains, as well as whole-rock geochemical data of selected Mesozoic sandstones from Namibia. As a base for the interpretation of the detrital zircon age data we compiled a zircon age dataset with c. 44,000 analyses for the southern African region. All samples reveal a major detrital pan-African zircon age peak of c. 0.5–0.7 Ga sourced from the pan-African magmatic events occurring around the Kalahari Craton margin. The lowermost Triassic is characterized by the occurrence of additional Mesoproterozoic and Paleoproterozoic age peaks of c. 1.0–1.2 Ga and 1.8–2.0 Ga with a majority of zircon grains showing angular shapes. The protosource of these grains is interpreted to possibly be the Namaqua Metamorphic Complex and other Paleoproterozoic structural units deformed in course of the Namaqua orogeny. In contrast, other samples show a prominent Permo-Triassic age peak and completely rounded zircon grains, putatively derived from within the Gondwanides volcanic arc. The disparity in the zircon age pattern may point towards a change in provenance and also a change in the whole system of zircon recycling during the Mesozoic southern Gondwana. The Lower Triassic Neu Loore fm. are constrained to more local bedrock sources and short zircon transport distance. In contrast, zircon grains of the Middle Triassic Omingonde, the Jurassic Etjo und the Cretaceous Twyfelfontein formations are an expression for a major recycling and sediment homogenization system. The system was facilitated by an interplay between fluvial and eolian sedimentary transport systems.
    Keywords: ddc:551 ; Zircon U–pb ; Mesozoic ; Gondwana ; Karoo ; Namibia
    Language: English
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  • 14
    Publication Date: 2023-08-17
    Description: Samples and documentation of outcrops and drillings, facies analysis, whole rock geochemistry and radiometric ages have been employed to re-evaluate the Late Carboniferous Tharandt Forest caldera (TFC) and the co-genetic Niederbobritzsch granite (NBG) in the eastern Erzgebirge near Dresden, Germany. The c. 52 km2 TFC harbours strongly welded ignimbrites with a preserved minimum thickness of 550 m. Composition of initial fallout tephra at the base of the TFC fill, comprising lithics of rhyolitic and basic lava, and of silica-rich pyroclastic rocks, suggests a bimodal volcanic activity in the area prior to the climactic TFC eruption. The lower part of the TFC fill comprises quartz-poor ignimbrites, overlain by quartz-rich ignimbrites, apparently without a depositional break. Landslides originating from the collapse collar of the caldera plunged into the still hot TFC fill producing monolithic gneiss mesobreccia with clasts ≤ 1 m in a pyroclastic matrix. Aphanitic and porphyritic rhyolitic magma formed ring- and radial dykes, and subvolcanic bodies in the centre of TFC. Whole rock geochemical data indicate a high silica (most samples have 〉 73 wt% SiO2) rhyolitic composition of the TFC magma, and a similar granodiorite–granitic composition for the NBG. Based on drillings and caldera extent, a minimum volume of 22 km3 of TFC fill is preserved, the original fill is assumed at about 33 km3. This estimate translates into a denudation of at least c. 210 m during Late Paleozoic to pre-Cenomanian. Telescopic subsidence of the TFC took place in two, perhaps three stages. A possible TFC outflow facies has been completely eroded and distal TFC tuff has not been recognized in neighboring basins. New CA-ID-TIMS measurements on two TFC samples gave mean zircon ages of 313.4 ± 0.4 Ma and 311.9 ± 0.4 Ma; two samples from NBG resulted in 318.2 ± 0.5 Ma and 319.5 ± 0.4 Ma. In addition, for one sample of the ring dyke an age of ca. 314.5 ± 0.5 Ma has been obtained. These ages, together with field relations, allow for a model of a long-standing evolution of an upper crustal magmatic system (~ 5 Ma?), where pulses of magmatic injection and crustal doming alternate with magmatic quietness and erosion. Together with the Altenberg–Teplice Volcanic Complex, located some 10 km to the southeast, the TFC–NBG Complex represents an early post-Variscan magmatic activity in central Europe.
    Description: Technische Universität Bergakademie Freiberg (3135)
    Keywords: ddc:551 ; Single phase caldera evolution ; Caldera wall landslides ; Freiberg gneiss dome ; CA-ID-TIMS zircon dating
    Language: English
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  • 15
    Publication Date: 2023-08-17
    Description: This paper presents radon flux profiles from four regions in Schleswig–Holstein (Northern Germany). Three of these regions are located over deep-rooted tectonic faults or salt diapirs and one is in an area without any tectonic or halokinetic activity, but with steep topography. Contrary to recently published studies on spatial patterns of soil radon gas concentration we measured flux of radon from soil into the atmosphere. All radon devices of each profile were deployed simultaneously to avoid inconsistencies due to strong diurnal variations of radon exhalation. To compare data from different seasons, values had to be normalized. Observed radon flux patterns are apparently related to the mineralogical composition of the Quaternary strata (particularly to the abundance of reddish granite and porphyry), and its grain size (with a flux maximum in well-sorted sand/silt). Minimum radon flux occurs above non-permeable, clay-rich soil layers. Small amounts of water content in the pore space increase radon flux, whereas excessive water content lessens it. Peak flux values, however, are observed over a deep-rooted fault system on the eastern side of Lake Plön, i.e., at the boundary of the Eastholstein Platform and the Eastholstein Trough. Furthermore, high radon flux values are observed in two regions associated with salt diapirism and near-surface halokinetic faults. These regions show frequent local radon flux maxima, which indicate that the uppermost strata above salt diapirs are very inhomogeneous. Deep-rooted increased permeability (effective radon flux depth) or just the boundaries between permeable and impermeable strata appear to concentrate radon flux. In summary, our radon flux profiles are in accordance with the published evidence of low radon concentrations in the “normal” soils of Schleswig–Holstein. However, very high values of radon flux are likely to occur at distinct locations near salt diapirism at depth, boundaries between permeable and impermeable strata, and finally at the tectonically active flanks of the North German Basin.
    Description: Bundesministerium für Wirtschaft und Energie http://dx.doi.org/10.13039/501100006360
    Description: Johannes Gutenberg-Universität Mainz (1030)
    Keywords: ddc:551 ; Radon flux ; Local radon flux maxima ; Permeability ; Quaternary sediments ; Salt tectonics ; Schleswig–Holstein
    Language: English
    Type: doc-type:article
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  • 16
    Publication Date: 2023-07-20
    Description: Late Cenozoic was a period of large-scale extension in the Aegean. The extension is mainly recorded in the metamorphic core complexes with little data from the sedimentary sequences. The exception is the Thrace Basin in the northern Aegean, which has a continuous record of Middle Eocene to Oligocene marine sedimentation. In the Thrace Basin, the Late Oligocene–Early Miocene was characterized by north-northwest (N25°W) shortening leading to the termination of sedimentation and formation of large-scale folds. We studied the stratigraphy and structure of one of these folds, the Korudağ anticline. The Korudağ anticline has formed in the uppermost Eocene–Lower Oligocene siliciclastic turbidites with Early Oligocene (31.6 Ma zircon U–Pb age) acidic tuff beds. The turbidites are underlain by a thin sequence of Upper Eocene pelagic limestone. The Korudağ anticline is an east-northeast (N65°E) trending fault-propagation fold, 9 km wide and 22 km long and with a subhorizontal fold axis. It is asymmetric with shallowly-dipping northern and steeply-dipping southern limbs. Its geometry indicates about 1 km of shortening in a N25°W direction. The folded strata are unconformably overlain by Middle Miocene continental sandstones, which constrain the age of folding. The Korudağ anticline and other large folds in the Thrace Basin predate the inception of the North Anatolian Fault (NAF) by at least 12 myr. The Late Oligocene–Early Miocene (28–17 Ma) shortening in the Thrace Basin and elsewhere in the Balkans forms an interlude between two extensional periods, and is probably linked to changes in the subduction dynamics along the Hellenic trench.
    Description: TÜBİTAK
    Description: İTÜ-BAP
    Description: TÜBA
    Description: Freie Universität Berlin (1008)
    Keywords: ddc:551 ; Thrace Basin ; Shortening ; Oligocene ; Miocene ; Aegean
    Language: English
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  • 17
    Publication Date: 2023-07-20
    Description: New whole-rock geochemical and coupled U–Pb and Lu–Hf LA-ICP-MS zircon data of metasedimentary rocks of the Austroalpine, South Alpine and Penninic basement domains are presented, to disentangle the pre-Variscan tectonic evolution of the proto-Alps. The studied units seem to record distinct stages of protracted Late Ediacaran to Carboniferous tectonosedimentary processes prior to the Variscan collision. In the case of Austroalpine and South Alpine units, nevertheless, no major differences in terms of provenance are observed, since most detrital zircon samples are characterized by a major Pan-African peak. Their detrital zircon spectra record a provenance from the northeastern Saharan Metacraton and the Sinai basement at the northern Arabian-Nubian Shield, being thus located along the eastern Early Paleozoic northern Gondwana margin, whereas sources located further west are inferred for the Penninic Unit, which might have been placed close to the Moldanubian Unit of the Bohemian Massif. In any case, it is thus clear that the Alpine basement remained in a close position to the Gondwana mainland at least during the Early Paleozoic. The Late Ediacaran to Silurian tectonic evolution, which includes Cadomian and Cenerian tectonometamorphic and magmatic processes, seem thus to record a continuum related to a retreating-mode accretionary orogen, with diachronous back-arc basin opening and possibly discrete compressional/transpressional pulses linked to changes in subduction zone dynamics. On the other hand, it is inferred that the Alpine basement essentially comprises Pan-African metasedimentary and subordinate metaigneous rocks, possibly with very few Early Neoproterozoic relics. This basement was significantly reworked during the protracted Paleozoic orogenic evolution, due to anatexis and/or assimilation by mantle-derived juvenile magmatism.
    Description: Georg-August-Universität Göttingen (1018)
    Keywords: ddc:551 ; Alpine basement ; Cadomian orogeny ; Cenerian orogeny ; Retreating-mode accretionary orogen ; Sedimentary provenance ; Detrital zircons
    Language: English
    Type: doc-type:article
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  • 18
    Publication Date: 2023-08-08
    Description: Within the Ararat Valley (Armenia), a continuously growing water demand (for irrigation and fish farming) and a simultaneous decline in groundwater recharge (due to climate change) result in increasing stress on the local groundwater resources. This detrimental development is reflected by groundwater-level drops and an associated reduction of the area with artesian conditions in the valley centre. This situation calls for increasing efforts aimed at more sustainable water resources management. The aim of this baseline study was the collection of data that allows for study on the origin and age distribution of the Ararat Valley groundwater based on environmental tracers, namely stable (δ〈sup〉2〈/sup〉H, δ〈sup〉18〈/sup〉O) and radioactive (〈sup〉35〈/sup〉S, 〈sup〉3〈/sup〉H) isotopes, as well as physical-chemical indicators. The results show that the Ararat Valley receives modern recharge, despite its (semi-)arid climate. While subannual groundwater residence times could be disproved (〈sup〉35〈/sup〉S), the detected 〈sup〉3〈/sup〉H pattern suggests groundwater ages of several decades, with the oldest waters being recharged around 60 years ago. The differing groundwater ages are reflected by varying scatter of stable isotope and hydrochemical signatures. The presence of young groundwater (i.e., younger that the 1970s), some containing nitrate, indicates groundwater vulnerability and underscores the importance of increased efforts to achieve sustainable management of this natural resource. Since stable isotope signatures indicate the recharge areas to be located in the mountains surrounding the valley, these efforts must not be limited to the central part of the valley where most of the abstraction wells are located.
    Description: Technische Universität Darmstadt (3139)
    Keywords: ddc:551 ; Groundwater residence time ; Tritium ; Radiosulphur ; Stable isotopes ; Armenia
    Language: English
    Type: doc-type:article
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  • 19
    Publication Date: 2023-07-27
    Description: Extensive morphological and age studies on more than 4600 detrital zircon grains recovered from modern sands of Namibia reveal complex mechanisms of sediment transport. These data are further supplemented by a zircon age database containing more than 100,000 single grain analyses from the entire southern Africa and allow for hypothesising of a large Southern Namibian Sediment Vortex located between the Damara Orogen and the Orange River in southern Namibia. The results of this study also allow assuming a modified model of the Orange River sand highway, whose origin is likely located further south than previously expected. Moreover, studied samples from other parts of Namibia give first insights into sediment movements towards the interior of the continent and highlight the potential impact of very little spatial variations of erosion rates. Finally, this study points out the huge potential of detrital zircon morphology and large geo-databases as an easy-to-use additional tool for provenance analysis.
    Description: deutsche forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Senckenberg Naturhistorische Sammlungen Dresden (3507)
    Keywords: ddc:551 ; Namibia ; Zircon ; Mineral morphology ; Sediment transport ; Geochronology ; Database
    Language: English
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  • 20
    Publication Date: 2023-07-27
    Description: The Brenner normal fault bounds the Tauern Window to the west and accommodated a significant portion of the orogen-parallel extension in the Eastern Alps. Here, we use zircon (U–Th)/He, apatite fission track, and apatite (U–Th)/He dating, thermokinematic modeling, and a topographic analysis to constrain the exhumation history of the western Tauern Window in the footwall of the Brenner fault. ZHe ages from an E–W profile (parallel to the slip direction of the fault) decrease westwards from ~ 11 to ~ 8 Ma and suggest a fault-slip rate of 3.9 ± 0.9 km/Myr, whereas AFT and AHe ages show no spatial trends. ZHe and AFT ages from an elevation profile indicate apparent exhumation rates of 1.1 ± 0.7 and 1.0 ± 1.3 km/Myr, respectively, whereas the AHe ages are again spatially invariant. Most of the thermochronological ages are well predicted by a thermokinematic model with a normal fault that slips at a rate of 4.2 km/Myr between ~ 19 and ~ 9 Ma and produces 35 ± 10 km of extension. The modeling reveals that the spatially invariant AHe ages are caused by heat advection due to faulting and posttectonic thermal relaxation. The enigmatic increase of K–Ar phengite and biotite ages towards the Brenner fault is caused by heat conduction from the hot footwall to the cooler hanging wall. Topographic profiles across an N–S valley in the fault footwall indicate 1000 ± 300 m of erosion after faulting ceased, which agrees with the results of our thermokinematic model. Valley incision explains why the Brenner fault is located on the western valley shoulder and not at the valley bottom. We conclude that the ability of thermokinematic models to quantify heat transfer by rock advection and conduction is crucial for interpreting cooling ages from extensional fault systems.
    Description: Westfälische Wilhelms-Universität Münster (1056)
    Description: https://github.com/jeanbraun
    Keywords: ddc:551 ; European Alps ; Tauern Window ; Thermochronology ; Thermokinematic modeling
    Language: English
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  • 21
    Publication Date: 2023-07-21
    Description: Late Paleozoic (Variscan) magmatism is widespread in Central Europe. The Lusatian Block is located in the NE Bohemian Massif and it is part of the Saxothuringian Zone of the Variscan orogen. It is bordered by two major NW-trending shear zones, the Intra-Sudetic Fault Zone towards NE and the Elbe Fault Zone towards SW. The scarce Variscan igneous rocks of the Lusatian Block are situated close to these faults. We investigated 19 samples from Variscan plutonic and volcanic rocks of the Lusatian Block, considering all petrological varieties (biotite-bearing granites from the Koenigshain and Stolpen plutons, amphibole-bearing granites from three boreholes, several volcanic dykes, and two volcanites from the intramontane Weissig basin). We applied whole-rock geochemistry (18 samples) and zircon evaporation dating (19 samples). From the evaporation data, we selected six representative samples for additional zircon SHRIMP and CA–ID–TIMS dating. For the Koenigshain pluton, possible protoliths were identified using whole-rock Nd-isotopes, and zircon Hf- and O-isotopes. The new age data allow a subdivision of Variscan igneous rocks in the Lusatian Block into two distinct magmatic episodes. The spatial relation of the two age groups to either the Elbe Fault Zone (298–299 Ma) or the Intra-Sudetic Fault Zone (312–313 Ma) together with reports on the fault-bound character of the dated intrusions suggests an interpretation as two major post-collisional faulting episodes. This assumption of two distinct magmatic periods is confirmed by a compilation of recently published zircon U–Pb CA–ID–TIMS data on further Variscan igneous rocks from the Saxothuringian Zone. New geochemical data allow us to exclude a dominant sedimentary protolith for the Koenigshain pluton as supposed by previous investigations. This conclusion is mainly based on new O- and Hf-isotope data on zircon and the scarcity of inherited zircons. Instead, acid or intermediate igneous rocks are supposed as the main source for these I-type granitoids from the Koenigshain pluton.
    Description: Technische Universität Bergakademie Freiberg (3135)
    Keywords: ddc:551 ; Geochronology ; Zircon ; Variscan granites ; Lusatian block
    Language: English
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  • 22
    Publication Date: 2023-08-01
    Description: Cereal crop production in sub-Saharan Africa has not achieved the much-needed increase in yields to foster economic development and food security. Maize yields in the region’s semi-arid agroecosystems are constrained by highly variable rainfall, which may be worsened by climate change. Thus, the Tanzanian government has prioritized agriculture as an adaptation sector in its intended nationally determined contribution, and crop management adjustments as a key investment area in its Agricultural Sector Development Programme. In this study, we investigated how future changes in maize yields under different climate scenarios can be countered by regional adjusted crop management and cultivar adaptation strategies. A crop model was used to simulate maize yields in the Singida region of Tanzania for the baseline period 1980–2012 and under three future climate projections for 2020–2060 and 2061–2099. Adaptation strategies to improve yields were full irrigation, deficit irrigation, mulch and nitrogen addition and another cultivar. According to our model results, increase in temperature is the main driver of future maize yield decline. Increased respiration and phenological development were associated with lower maize yields of 16% in 2020–2060 and 20% in 2061–2099 compared to the 1980–2012 baseline. Surprisingly, none of the management strategies significantly improved yields; however, a different maize variety that was tested as an alternative coping strategy performed better. This study suggests that investment in accessibility of improved varieties and investigation of maize traits that have the potential to perform well in a warmer future are better suited for sustaining maize production in the semi-arid region than adjustments in crop management.
    Description: Leibniz Centre for Agricultural Landscape Research (ZALF)
    Description: Universität Hohenheim (3153)
    Keywords: ddc:631 ; Maize ; Climate change ; Adaptation ; Model ; Tanzania ; NDC
    Language: English
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  • 23
    Publication Date: 2023-01-27
    Description: One of the major objectives of volcanology remains relating variations in surface monitoring signals to the magmatic processes at depth that cause these variations. We present a method that enables compositional and temporal information stored in zoning of minerals (olivine in this case) to be linked to observations of real-time degassing data. The integrated record may reveal details of the dynamics of gradual evolution of a plumbing system during eruption. We illustrate our approach using the 2006 summit eruptive episodes of Mt. Etna. We find that the history tracked by olivine crystals, and hence, most likely the magma pathways within the shallow plumbing system of Mt. Etna, differed considerably between the July and October eruptions. The compositional and temporal record preserved in the olivine zoning patterns reveal two mafic recharge events within months of each other (June and September 2006), and each of these magma supplies may have triggered the initiation of different eruptive cycles (July 14–24 and August 31–December 14). Correlation of these observations with gas monitoring data shows that the systematic rise of the CO2/SO2gas values is associated with the gradual (preand syn-eruptive) supply of batches of gas-rich mafic magma into segments of Etna’s shallow plumbing system, where mixing with pre-existing and more evolved magma occurred.
    Description: This work was funded by the German Science Foundation as part of the collaborative research centre (SFB) on Rheology of the Crust—from the upper crust to the subduction zone (SFB 526).
    Description: Published
    Description: 692
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: 3V. Dinamiche e scenari eruttivi
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: Crystal zoning ; Plumbing system Mt. Etna ; Magma mixing ; Gas monitoring ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 24
    Publication Date: 2024-05-09
    Description: Abstract A geochemical survey of fumarolic and submerged gases from fluid discharges located in the Nea Kameni and Palea Kameni islets (Santorini Island, Greece) was carried out before, during, and after the unrest related to the anomalously high seismic and ground deformation activity that affected this volcanic system since January 2011. Our data show that from May 2011 to February 2012, the Nea Kameni fumaroles showed a significant increase of H2 concentrations. After this period, an abrupt decrease in the H2 contents, accompanied by decreasing seismic events, was recorded. A similar temporal pattern was shown by the F−, Cl−, SO4 2−, and NH4 + concentrations in the fumarolic condensates. During the sharp increase of H2 concentrations, when values up to 158 mmol/ mol were measured, the δ13C–CO2 values, which prior to January 2011 were consistent with a dominant CO2 thermometamorphic source, have shown a significant decrease, suggesting an increase of mantle CO2 contribution. Light hydrocarbons, including CH4, which are controlled by chemical reactions kinetically slower than H2 production from H2O dissociation, displayed a sharp increase in March 2012, under enhanced reducing conditions caused by the high H2 concentrations of May 2011–February 2012. The general increase in light hydrocarbons continued up to July 2012, notwithstanding the contemporaneous H2 decrease. The temporal patterns of CO2 concentrations and N2/Ar ratios increased similarly to that of H2, possibly due to sealing processes in the fumarolic conduits that diminished the contamination related to the entrance of atmospheric gases in the fumarolic conduits. The compositional evolution of the Nea Kameni fumaroles can be explained by a convective heat pulse from depth associated with the seismic activation of the NE–SW-oriented Kameni tectonic lineament, possibly triggered by either injection of new magma below Nea Kameni island, as apparently suggested by the evolution of the seismic and ground deformation activity, or increased permeability of the volcanic plumbing system resulting from the tectonic movements affecting the area. The results of the present study demonstrate that the geophysical and geochemical signals at Santorini are interrelated and may be precursory signals of renewed volcanic activity and encourage the development of interdisciplinary monitoring program to mitigate the volcanic risk in the most tourist-visited island of the Mediterranean Sea.
    Description: Published
    Description: 711
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Santorini Island . ; Fluid geochemistry ; Geochemical monitoring ; Seismic crisis ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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