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  • phosphorus  (681)
  • Currents
  • Springer  (686)
  • American Meteorological Society  (36)
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  • Elsevier B.V.  (1)
  • 1
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    Response to a steady poleward outflow. Part I : the linear, quasigeostrophic problem (2010)
    American Meteorological Society
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2009. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 39 (2009): 1541-1550, doi:10.1175/2008JPO3999.1.
    Description: The response of a zonal channel to a uniform, switched-on but subsequently steady poleward outflow is presented. An eastward coastal current with a Kelvin wave’s cross-shore structure is found to be generated instantly upon initiation of the outflow. The current is essentially in geostrophic balance everywhere except for the vicinity of the outflow channel mouth, where the streamlines must cross planetary vorticity contours to feed the current. The adjustment of this region generates a plume that propagates westward at Rossby wave speeds. The cross-shore structure of the plume varies with longitude, and at any given longitude it evolves with time. The authors show that the plume evolution can be understood both conceptually and quantitatively as the westward propagation of the Kelvin current’s meridional spectrum, with each spectral element propagating at its own Rossby wave group velocity.
    Description: This work was completed at Woods Hole Oceanographic Institution while T.S. Durland was supported by the Ocean and Climate Change Institute. M.A. Spall was supported by NSF Grant OCE-0423975, and J. Pedlosky by NSF Grant OCE-0451086. T.S. Durland acknowledges additional report preparation support from NASA Grant NNG05GN98G.
    Keywords: Coastal flows ; Estuaries ; Currents ; Vorticity ; Plumes
    Repository Name: Woods Hole Open Access Server
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  • 2
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    Performance of a new generation of acoustic current meters (2010)
    American Meteorological Society
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2007. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 37 (2007): 148–161, doi:10.1175/JPO3003.1.
    Description: As part of a program aimed at developing a long-duration, subsurface mooring, known as Ultramoor, several modern acoustic current meters were tested. The instruments with which the authors have the most experience are the Aanderaa RCM11 and the Nortek Aquadopp, which measure currents using the Doppler shift of backscattered acoustic signals, and the Falmouth Scientific ACM, which measures changes in travel time of acoustic signals between pairs of transducers. Some results from the Doppler-based Sontek Argonaut and the travel-time-based Nobska MAVS are also reported. This paper concentrates on the fidelity of the speed measurement but also presents some results related to the accuracy of the direction measurement. Two procedures were used to compare the instruments. In one, different instruments were placed close to one another on three different deep-ocean moorings. These tests showed that the RCM11 measures consistently lower speeds than either a vector averaging current meter or a vector measuring current meter, both more traditional instruments with mechanical velocity sensors. The Aquadopp in use at the time, but since updated to address accuracy problems in low scattering environments, was biased high. A second means of testing involved comparing the appropriate velocity component of each instrument with the rate of change of pressure when they were lowered from a ship. Results from this procedure revealed no depth dependence or measurable bias in the RCM11 data, but did show biases in both the Aquadopp and Argonaut Doppler-based instruments that resulted from low signal-to-noise ratios in the clear, low scattering conditions beneath the thermocline. Improvements in the design of the latest Aquadopp have reduced this bias to a level that is not significant.
    Description: This material is based upon work supported by the National Science Foundation under Grant 9810641.
    Keywords: Currents ; Acoustic measurements ; In situ sensors
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  • 3
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    Shelf circulation and cross-shelf transport out of a bay driven by eddies from an open-ocean current. Part I : interaction between a barotropic vortex and a steplike topography (2011)
    American Meteorological Society
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2011. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 41 (2011): 889–910, doi:10.1175/2010JPO4496.1.
    Description: This paper examines interaction between a barotropic point vortex and a steplike topography with a bay-shaped shelf. The interaction is governed by two mechanisms: propagation of topographic Rossby waves and advection by the forcing vortex. Topographic waves are supported by the potential vorticity (PV) jump across the topography and propagate along the step only in one direction, having higher PV on the right. Near one side boundary of the bay, which is in the wave propagation direction and has a narrow shelf, waves are blocked by the boundary, inducing strong out-of-bay transport in the form of detached crests. The wave–boundary interaction as well as out-of-bay transport is strengthened as the minimum shelf width is decreased. The two control mechanisms are related differently in anticyclone- and cyclone-induced interactions. In anticyclone-induced interactions, the PV front deformations are moved in opposite directions by the point vortex and topographic waves; a topographic cyclone forms out of the balance between the two opposing mechanisms and is advected by the forcing vortex into the deep ocean. In cyclone-induced interactions, the PV front deformations are moved in the same direction by the two mechanisms; a topographic cyclone forms out of the wave–boundary interaction but is confined to the coast. Therefore, anticyclonic vortices are more capable of driving water off the topography. The anticyclone-induced transport is enhanced for smaller vortex–step distance or smaller topography when the vortex advection is relatively strong compared to the wave propagation mechanism.
    Description: Y. Zhang acknowledges the support of theMIT-WHOI Joint Programin Physical Oceanography, NSF OCE-9901654 and OCE-0451086. J. Pedlosky acknowledges the support of NSF OCE- 9901654 and OCE-0451086.
    Keywords: Transport ; Eddies ; Barotropic flow ; Topographic effects ; Vortices ; Currents ; Potential vorticity ; Rossby waves
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  • 4
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    Improving HF radar estimates of surface currents using signal quality metrics, with application to the MVCO high-resolution radar system (2012)
    American Meteorological Society
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Atmospheric and Oceanic Technology 29 (2012): 1377–1390, doi:10.1175/JTECH-D-11-00160.1.
    Description: Estimates of surface currents over the continental shelf are now regularly made using high-frequency radar (HFR) systems along much of the U.S. coastline. The recently deployed HFR system at the Martha’s Vineyard Coastal Observatory (MVCO) is a unique addition to these systems, focusing on high spatial resolution over a relatively small coastal ocean domain with high accuracy. However, initial results from the system showed sizable errors and biased estimates of M2 tidal currents, prompting an examination of new methods to improve the quality of radar-based velocity data. The analysis described here utilizes the radial metric output of CODAR Ocean Systems’ version 7 release of the SeaSonde Radial Site Software Suite to examine both the characteristics of the received signal and the output of the direction-finding algorithm to provide data quality controls on the estimated radial currents that are independent of the estimated velocity. Additionally, the effect of weighting spatial averages of radials falling within the same range and azimuthal bin is examined to account for differences in signal quality. Applied to two month-long datasets from the MVCO high-resolution system, these new methods are found to improve the rms difference comparisons with in situ current measurements by up to 2 cm s−1, as well as reduce or eliminate observed biases of tidal ellipses estimated using standard methods.
    Description: 2013-03-01
    Keywords: Coastal flows ; Currents ; Data processing ; Data quality control ; In situ atmospheric observations ; Remote sensing
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  • 5
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    Wind-driven cross-equatorial flow in the Indian Ocean (2013)
    American Meteorological Society
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 42 (2012): 2234–2253, doi:10.1175/JPO-D-12-033.1.
    Description: Meridional velocity, mass, and heat transport in the equatorial oceans are difficult to estimate because of the nonapplicability of the geostrophic balance. For this purpose a steady-state model is utilized in the equatorial Indian Ocean using NCEP wind stress and temperature and salinity data from the World Ocean Atlas 2005 (WOA05) and Argo. The results show a Somali Current flowing to the south during the winter monsoon carrying −11.5 ± 1.3 Sv (1 Sv ≡ 106 m3 s−1) and −12.3 ± 0.3 Sv from WOA05 and Argo, respectively. In the summer monsoon the Somali Current reverses to the north transporting 16.8 ± 1.2 Sv and 19.8 ± 0.6 Sv in the WOA05 and Argo results. Transitional periods are considered together and in consequence, there is not a clear Somali Current present in this period. Model results fit with in situ measurements made around the region, although Argo data results are quite more realistic than WOA05 data results.
    Description: This study has been partly funded by the MOC Project (CTM 2008- 06438) and the Spanish contribution to the Argo network (AC2009 ACI2009-0998), financed by the Spanish Government and Feder.
    Description: 2013-06-01
    Keywords: Indian Ocean ; Subtropics ; Currents ; Ocean circulation ; Transport ; Wind stress
    Repository Name: Woods Hole Open Access Server
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  • 6
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    Coral reef drag coefficients—surface gravity wave enhancement (2018)
    American Meteorological Society
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2018. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 48 (2018): 1555-1566, doi:10.1175/JPO-D-17-0231.1.
    Description: A primary challenge in modeling flow over shallow coral reefs is accurately characterizing the bottom drag. Previous studies over continental shelves and sandy beaches suggest surface gravity waves should enhance the drag on the circulation over coral reefs. The influence of surface gravity waves on drag over four platform reefs in the Red Sea is examined using observations from 6-month deployments of current and pressure sensors burst sampling at 1Hz for 4–5min. Depth-average current fluctuations U0 within each burst are dominated by wave orbital velocities uw that account for 80%–90%of the burst variance and have a magnitude of order 10 cm s21, similar to the lower-frequency depth-average current Uavg. Previous studies have shown that the cross-reef bottom stress balances the pressure gradient over these reefs. A bottom stress estimate that neglects the waves (rCdaUavgjUavgj, where r is water density and Cda is a drag coefficient) balances the observed pressure gradient when uw is smaller than Uavg but underestimates the pressure gradient when uw is larger than Uavg (by a factor of 3–5 when uw 5 2Uavg), indicating the neglected waves enhance the bottom stress. In contrast, a bottom stress estimate that includes the waves [rCda(Uavg 1 U0)jUavg 1 U0j)] balances the observed pressure gradient independent of the relative size of uw and Uavg, indicating that this estimate accounts for the wave enhancement of the bottom stress. A parameterization proposed by Wright and Thompson provides a reasonable estimate of the total bottom stress (including the waves) given the burst-averaged current and the wave orbital velocity.
    Description: The Red Sea field program was supported by Awards USA 00002 and KSA 00011 made by KAUST. S. Lentz was supported for the analysis by NSF Award OCE-1558343.
    Description: 2019-01-13
    Keywords: Coastal flows ; Currents ; Dynamics ; Gravity waves ; Turbulence
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  • 7
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    Laboratory experiments on the interaction of a buoyant coastal current with a canyon : application to the East Greenland Current (2010)
    American Meteorological Society
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2009. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 39 (2009): 1258-1271, doi:10.1175/2008JPO4028.1.
    Description: This paper presents a set of laboratory experiments focused on how a buoyant coastal current flowing over a sloping bottom interacts with a canyon and what controls the separation, if any, of the current from the upstream canyon bend. The results show that the separation of a buoyant coastal current depends on the current width W relative to the radius of curvature of the bathymetry ρc. The flow moved across the mouth of the canyon (i.e., separated) for W/ρc 〉 1, in agreement with previous results. The present study extends previous work by examining both slope-controlled and surface-trapped currents, and using a geometry specific to investigating buoyant current–canyon interaction. The authors find that, although bottom friction is important in setting the position of the buoyant front, the separation process driven by the inertia of the flow could overcome even the strongest bathymetric influence. Application of the laboratory results to the East Greenland Current (EGC), an Arctic-origin buoyant current that is observed to flow in two branches south of Denmark Strait, suggests that the path of the EGC is influenced by the large canyons cutting across the shelf, as the range of W/ρc in the ocean spans those observed in the laboratory. What causes the formation of a two-branched EGC structure downstream of the Kangerdlugssuaq Canyon (68°N, 32°W) is still unclear, but potential mechanisms are discussed.
    Description: This work was partially funded by NSF Grant OCE-0450658. DS also received support from the Academic Programs Office of the Woods Hole Oceanographic Institution, while CC had partial support from NSF OCE-0350891.
    Keywords: Coastal flows ; Buoyancy ; Currents ; Experimental design ; Topographic effects
    Repository Name: Woods Hole Open Access Server
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  • 8
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    Interannual variability in the pathways of the North Atlantic Current over the Mid-Atlantic Ridge and the impact of topography (2010)
    American Meteorological Society
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2008. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 38 (2008): 104–120, doi:10.1175/2007JPO3686.1.
    Description: Recent studies have indicated that the North Atlantic Ocean subpolar gyre circulation undergoes significant interannual-to-decadal changes in response to variability in atmospheric forcing. There are also observations, however, suggesting that the southern limb of the subpolar gyre, namely, the eastward-flowing North Atlantic Current (NAC), may be quasi-locked to particular latitudes in the central North Atlantic by fracture zones (gaps) in the Mid-Atlantic Ridge. This could constrain the current’s ability to respond to variability in forcing. In the present study, subsurface float trajectories at 100–1000 m collected during 1997–99 and satellite-derived surface geostrophic velocities from 1992 to 2006 are used to provide an improved description of the detailed pathways of the NAC over the ridge and their relationship to bathymetry. Both the float and satellite observations indicate that in 1997–99, the northern branch of the NAC was split into two branches as it crossed the ridge, one quasi-locked to the Charlie–Gibbs Fracture Zone (CGFZ; 52°–53°N) and the other to the Faraday Fracture Zone (50°–51°N). The longer satellite time series shows, however, that this pattern did not persist outside the float sampling period and that other branching modes persisted for one or more years, including an approximately 12-month time period in 2002–03 when the strongest eastward flow over the ridge was at 49°N. Schott et al. showed how northward excursions of the NAC can temporarily block the westward flow of the Iceland–Scotland Overflow Water through the CGFZ. From the 13-yr time series of surface geostrophic velocity, it is estimated that such blocking may occur on average 6% of the time, although estimates for any given 12-month period range from 0% to 35%.
    Description: This research was supported by National Science Foundation Grants OCE-9531877 to the Woods Hole Oceanographic Institution (WHOI) and OCE-9906775 to the University of Rhode Island, by the WHOI Summer Student Fellowship Program, and by the Lawrence J. Pratt and Melinda M. Hall Endowed Fund for Interdisciplinary Research at the Woods Hole Oceanographic Institution.
    Keywords: Currents ; Topographic effects ; Interannual variability ; Forcing ; Gyres
    Repository Name: Woods Hole Open Access Server
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  • 9
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    Observations and a model of the mean circulation over the Middle Atlantic Bight continental shelf (2010)
    American Meteorological Society
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2008. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 38 (2008): 1203–1221, doi:10.1175/2007JPO3768.1.
    Description: Analyses of current time series longer than 200 days from 33 sites over the Middle Atlantic Bight continental shelf reveal a consistent mean circulation pattern. The mean depth-averaged flow is equatorward, alongshelf, and increases with increasing water depth from 3 cm s−1 at the 15-m isobath to 10 cm s−1 at the 100-m isobath. The mean cross-shelf circulation exhibits a consistent cross-shelf and vertical structure. The near-surface flow is typically offshore (positive, range −3 to 6 cm s−1). The interior flow is onshore and remarkably constant (−0.2 to −1.4 cm s−1). The near-bottom flow increases linearly with increasing water depth from −1 cm s−1 (onshore) in shallow water to 4 cm s−1 (offshore) at the 250-m isobath over the slope, with the direction reversal near the 50-m isobath. A steady, two-dimensional model (no along-isobath variations in the flow) reproduces the main features of the observed circulation pattern. The depth-averaged alongshelf flow is primarily driven by an alongshelf pressure gradient (sea surface slope of 3.7 × 10−8 increasing to the north) and an opposing mean wind stress that also drives the near-surface offshore flow. The alongshelf pressure gradient accounts for both the increase in the alongshelf flow with water depth and the geostrophic balance onshore flow in the interior. The increase in the near-bottom offshore flow with water depth is due to the change in the relative magnitude of the contributions from the geostrophic onshore flow that dominates in shallow water and the offshore flow driven by the bottom stress that dominates in deeper water.
    Description: This research was funded by Ocean Sciences Division of the National Science Foundation under Grants OCE-820773, OCE-841292, and OCE-848961.
    Keywords: Ocean models ; Ocean circulation ; Continental shelf ; Currents ; In situ observations
    Repository Name: Woods Hole Open Access Server
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  • 10
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    Western Arctic shelfbreak eddies : formation and transport (2010)
    American Meteorological Society
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2008. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 38 (2008): 1644-1668, doi:10.1175/2007JPO3829.1.
    Description: The mean structure and time-dependent behavior of the shelfbreak jet along the southern Beaufort Sea, and its ability to transport properties into the basin interior via eddies are explored using high-resolution mooring data and an idealized numerical model. The analysis focuses on springtime, when weakly stratified winter-transformed Pacific water is being advected out of the Chukchi Sea. When winds are weak, the observed jet is bottom trapped with a low potential vorticity core and has maximum mean velocities of O(25 cm s−1) and an eastward transport of 0.42 Sv (1 Sv ≡ 106 m3 s−1). Despite the absence of winds, the current is highly time dependent, with relative vorticity and twisting vorticity often important components of the Ertel potential vorticity. An idealized primitive equation model forced by dense, weakly stratified waters flowing off a shelf produces a mean middepth boundary current similar in structure to that observed at the mooring site. The model boundary current is also highly variable, and produces numerous strong, small anticyclonic eddies that transport the shelf water into the basin interior. Analysis of the energy conversion terms in both the mooring data and the numerical model indicates that the eddies are formed via baroclinic instability of the boundary current. The structure of the eddies in the basin interior compares well with observations from drifting ice platforms. The results suggest that eddies shed from the shelfbreak jet contribute significantly to the offshore flux of heat, salt, and other properties, and are likely important for the ventilation of the halocline in the western Arctic Ocean. Interaction with an anticyclonic basin-scale circulation, meant to represent the Beaufort gyre, enhances the offshore transport of shelf water and results in a loss of mass transport from the shelfbreak jet.
    Description: This study was supported by the National Science Foundation Office of Polar Programs under Grants 0421904 and 035268 (MS), and by the Office of Naval Research Grant N00014-02-1-0317 (RP and PF). Analysis by AJP was supported by the Office of Naval Research under Grant N00014-97-1-0135 and by the National Science Foundation under Grant OPP-9815303.
    Keywords: Arctic ; Eddies ; Transport ; Currents ; Jets
    Repository Name: Woods Hole Open Access Server
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  • 11
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    The western North Atlantic shelfbreak current system in summer (2010)
    American Meteorological Society
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    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2007. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography. 37 (2007): 2509-2533, doi:10.1175/JPO3123.1.
    Description: Twelve years of historical hydrographic data, spanning the period 1990–2001, are analyzed to examine the along-stream evolution of the western North Atlantic Ocean shelfbreak front and current, following its path between the west coast of Greenland and the Middle Atlantic Bight. Over 700 synoptic sections are used to construct a mean three-dimensional description of the summer shelfbreak front and to quantify the along-stream evolution in properties, including frontal strength and grounding position. Results show that there are actually two fronts in the northern part of the domain—a shallow front located near the shelf break and a deeper front centered in the core of Irminger Water over the upper slope. The properties of the deeper Irminger front erode gradually to the south, and the front disappears entirely near the Grand Banks of Newfoundland. The shallow shelfbreak front is identifiable throughout the domain, and its properties exhibit large variations from north to south, with the largest changes occurring near the Tail of the Grand Banks. Despite these structural changes, and large variations in topography, the foot of the shelfbreak front remains within 20 km of the shelf break. The hydrographic sections are also used to examine the evolution of the baroclinic velocity field and its associated volume transport. The baroclinic velocity structure consists of a single velocity core that is stronger and penetrates deeper where the Irminger front is present. The baroclinic volume transport decreases by equal amounts at the southern end of the Labrador Shelf and at the Tail of the Grand Banks. Overall, the results suggest that the Grand Banks is a geographically critical location in the North Atlantic shelfbreak system.
    Description: This work was supported by the National Science Foundation under Grants OCE00- 95261 (PF) and OCE-0450658 (RP).
    Keywords: Continental shelf ; Currents ; Atlantic Ocean ; Fronts ; Transport
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  • 12
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    Strengthening of the Pacific Equatorial Undercurrent in the SODA reanalysis : mechanisms, ocean dynamics, and implications (2014)
    American Meteorological Society
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2014. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 27 (2014): 2405–2416, doi:10.1175/JCLI-D-13-00359.1.
    Description: Several recent studies utilizing global climate models predict that the Pacific Equatorial Undercurrent (EUC) will strengthen over the twenty-first century. Here, historical changes in the tropical Pacific are investigated using the Simple Ocean Data Assimilation (SODA) reanalysis toward understanding the dynamics and mechanisms that may dictate such a change. Although SODA does not assimilate velocity observations, the seasonal-to-interannual variability of the EUC estimated by SODA corresponds well with moored observations over a ~20-yr common period. Long-term trends in SODA indicate that the EUC core velocity has increased by 16% century−1 and as much as 47% century−1 at fixed locations since the mid-1800s. Diagnosis of the zonal momentum budget in the equatorial Pacific reveals two distinct seasonal mechanisms that explain the EUC strengthening. The first is characterized by strengthening of the western Pacific trade winds and hence oceanic zonal pressure gradient during boreal spring. The second entails weakening of eastern Pacific trade winds during boreal summer, which weakens the surface current and reduces EUC deceleration through vertical friction. EUC strengthening has important ecological implications as upwelling affects the thermal and biogeochemical environment. Furthermore, given the potential large-scale influence of EUC strength and depth on the heat budget in the eastern Pacific, the seasonal strengthening of the EUC may help reconcile paradoxical observations of Walker circulation slowdown and zonal SST gradient strengthening. Such a process would represent a new dynamical “thermostat” on CO2-forced warming of the tropical Pacific Ocean, emphasizing the importance of ocean dynamics and seasonality in understanding climate change projections.
    Description: EJDis supported by NSFGrantsOCE-1031971 and OCE-1233282. KBK is supported by NSF Grant OCE-1233282.
    Description: 2014-09-15
    Keywords: Tropics ; Currents ; Ocean dynamics ; Atmosphere-ocean interaction ; Climate variability ; Reanalysis data
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  • 13
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    The Equatorial Undercurrent and TAO sampling bias from a decade at SEA (2014)
    American Meteorological Society
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2014. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Atmospheric and Oceanic Technology 21 (2014): 2015–2025, doi:10.1175/JTECH-D-13-00262.1.
    Description: The NOAA Tropical Atmosphere Ocean (TAO) moored array has, for three decades, been a valuable resource for monitoring and forecasting El Niño–Southern Oscillation and understanding physical oceanographic as well as coupled processes in the tropical Pacific influencing global climate. Acoustic Doppler current profiler (ADCP) measurements by TAO moorings provide benchmarks for evaluating numerical simulations of subsurface circulation including the Equatorial Undercurrent (EUC). Meanwhile, the Sea Education Association (SEA) has been collecting data during repeat cruises to the central equatorial Pacific Ocean (160°–126°W) throughout the past decade that provide useful cross validation and quantitative insight into the potential for stationary observing platforms such as TAO to incur sampling biases related to the strength of the EUC. This paper describes some essential sampling characteristics of the SEA dataset, compares SEA and TAO velocity measurements in the vicinity of the EUC, shares new insight into EUC characteristics and behavior only observable in repeat cross-equatorial sections, and estimates the sampling bias incurred by equatorial TAO moorings in their estimates of the velocity and transport of the EUC. The SEA high-resolution ADCP dataset compares well with concurrent TAO measurements (RMSE = 0.05 m s−1; R2 = 0.98), suggests that the EUC core meanders sinusoidally about the equator between ±0.4° latitude, and reveals a mean sampling bias of equatorial measurements (e.g., TAO) of the EUC’s zonal velocity of −0.14 ± 0.03 m s−1 as well as a ~10% underestimation of EUC volume transport. A bias-corrected monthly record and climatology of EUC strength at 140°W for 1990–2010 is presented.
    Description: The authors thank the NSF Physical Oceanography program (OCE-1233282) and the WHOI Academic Programs Office for funding.
    Description: 2015-03-01
    Keywords: Pacific Ocean ; Tropics ; Currents ; Ocean dynamics ; Buoy observations ; Sampling
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  • 14
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    Absolute velocity estimates from autonomous underwater gliders equipped with Doppler current profilers (2017)
    American Meteorological Society
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    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2017. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Atmospheric and Oceanic Technology 34 (2017): 309-333, doi:10.1175/JTECH-D-16-0156.1.
    Description: Doppler current profilers on autonomous underwater gliders measure water velocity relative to the moving glider over vertical ranges of O(10) m. Measurements obtained with 1-MHz Nortek acoustic Doppler dual current profilers (AD2CPs) on Spray gliders deployed off Southern California, west of the Galápagos Archipelago, and in the Gulf Stream are used to demonstrate methods of estimating absolute horizontal velocities in the upper 1000 m of the ocean. Relative velocity measurements nearest to a glider are used to infer dive-dependent flight parameters, which are then used to correct estimates of absolute vertically averaged currents to account for the accumulation of biofouling during months-long glider missions. The inverse method for combining Doppler profiler measurements of relative velocity with absolute references to estimate profiles of absolute horizontal velocity is reviewed and expanded to include additional constraints on the velocity solutions. Errors arising from both instrumental bias and decreased abundance of acoustic scatterers at depth are considered. Though demonstrated with measurements from a particular combination of platform and instrument, these techniques should be applicable to other combinations of gliders and Doppler current profilers.
    Description: Spray glider missions were supported by the National Science Foundation (OCE-1232971, OCE-1233282), the National Oceanic and Atmospheric Administration (NA10OAR4320156, NA15OAR4320071), Eastman Chemical Company, the Oceans and Climate Change Institute at WHOI, and the W. Van Alan Clark Jr. Chair for Excellence in Oceanography at WHOI. RET acknowledges additional support for analysis and publication from the National Science Foundation (OCE-1633911).
    Description: 2017-07-31
    Keywords: Currents ; Acoustic measurements/effects ; Data processing ; Data quality control ; Profilers ; Inverse methods
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  • 15
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    The occurrence, drivers, and implications of submesoscale eddies on the Martha’s Vineyard Inner Shelf (2016)
    American Meteorological Society
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2016. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 46 (2016): 2645-2662, doi:10.1175/JPO-D-15-0191.1.
    Description: The occurrence, drivers, and implications of small-scale O(2–5) km diameter coherent vortices, referred to as submesoscale eddies, over the inner shelf south of Martha’s Vineyard, Massachusetts, are examined using high-frequency (HF), radar-based, high-resolution (400 m) observations of surface currents. Within the 300 km2 study area, eddies occurred at rates of 1 and 4 day−1 in winter and summer, respectively. Most were less than 5 h in duration, smaller than 4 km in diameter, and rotated less than once over their lifespan; 60% of the eddies formed along the eastern edge of study area, adjacent to Wasque Shoal, and moved westward into the interior, often with relative vorticity greater than f. Eddy generation was linked to vortex stretching on the ebb and flood tide as well as the interaction of the spatially variable tide and the wind-driven currents; however, these features had complex patterns of surface divergence and stretching. Eddies located away from Wasque Shoal were related to the movement of wind-driven surface currents, as wind direction controlled where eddies formed as well as density effects. Using an analysis of particles advected within the radar-based surface currents, the observed eddies were found to be generally leaky, losing 60%–80% of particles over their lifespan, but still more retentive than the background flow. As a result, the combined translation and rotational effects of the observed eddies were an important source of lateral exchange for surface waters over the inner shelf.
    Description: The HF radar data utilized here were obtained using internal funding from the Woods Hole Oceanographic Institution. The analysis was supported by NSF OCE Grant 1332646.
    Description: 2017-02-19
    Keywords: Geographic location/entity ; Continental shelf/slope ; Circulation/ Dynamics ; Currents ; Eddies ; Observational techniques and algorithms ; Radars/Radar observations
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  • 16
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    Observing the Galápagos–EUC interaction : insights and challenges (2011)
    American Meteorological Society
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2010. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 40 (2010): 2768–2777, doi:10.1175/2010JPO4461.1.
    Description: Although sustained observations yield a description of the mean equatorial current system from the western Pacific to the eastern terminus of the Tropical Atmosphere Ocean (TAO) array, a comprehensive observational dataset suitable for describing the structure and pathways of the Equatorial Undercurrent (EUC) east of 95°W does not exist and therefore climate models are unconstrained in a region that plays a critical role in ocean–atmosphere coupling. Furthermore, ocean models suggest that the interaction between the EUC and the Galápagos Islands (92°W) has a striking effect on the basic state and coupled variability of the tropical Pacific. To this end, the authors interpret historical measurements beginning with those made in conjunction with the discovery of the Pacific EUC in the 1950s, analyze velocity measurements from an equatorial TAO mooring at 85°W, and analyze a new dataset from archived shipboard ADCP measurements. Together, the observations yield a possible composite description of the EUC structure and pathways in the eastern equatorial Pacific that may be useful for model validation and guiding future observation.
    Description: Karnauskas acknowledges the WHOI Penzance Endowed Fund in Support of Assistant Scientists.
    Keywords: Atmosphere-ocean interaction ; Currents ; In situ observations ; Model evaluation/performance ; Pacific Ocean ; Tropics
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    Anisotropic material transport by eddies and eddy-driven currents in a model of the North Atlantic (2010)
    American Meteorological Society
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2009. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 39 (2009): 3162-3175, doi:10.1175/2009JPO4239.1.
    Description: This study analyzes anisotropic properties of the material transport by eddies and eddy-driven zonal jets in a general circulation model of the North Atlantic through the analysis of Lagrangian particle trajectories. Spreading rates—defined here as half the rate of change in the particle dispersion—in the zonal direction systematically exceed the meridional rates by an order of magnitude. Area-averaged values for the upper-ocean zonal and meridional spreading rates are approximately 8100 and 1400 m2 s−1, respectively, and in the deep ocean they are 2400 and 200 m2 s−1. The results demonstrate that this anisotropy is mainly due to the action of the transient eddies and not to the shear dispersion associated with the time-mean jets. This property is consistent with the fact that eddies in this study have zonally elongated shapes. With the exception of the upper-ocean subpolar gyre, eddies also cause the superdiffusive zonal spreading, significant variations in the spreading rate in the vertical and meridional directions, and the difference between the westward and eastward spreading.
    Description: Funding for IK was provided by NSF Grants OCE 0346178, 0749722, and 0842834. Funding for PB was provided by NSF Grants OCE 0344094 and OCE 0725796 and by the research grant from the Newton Trust of the University of Cambridge. For JP the acknowledgement is to NSF OCE-0451086.
    Keywords: Eddies ; Transport ; Currents ; North Atlantic Ocean
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    An oceanic current against the wind : how does Taiwan island steer warm water into the East China Sea? (2010)
    American Meteorological Society
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2007. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 37 (2007): 2563-2569, doi:10.1175/JPO3134.1.
    Description: Along the Taiwan Strait (〈100 m in depth) a northeastward flow persists in all seasons despite the annually averaged wind stress that is strongly southwestward. The forcing mechanism of this countercurrent is examined by using a simple ocean model. The results from a suite of experiments demonstrate that it is the Kuroshio that plays the deciding role for setting the flow direction along the Taiwan Strait. The momentum balance along the strait is mainly between the wind stress, friction, and pressure gradient. Since both wind stress and friction act against the northward flow, it is most likely the pressure gradient that forces the northward flow, as noted in some previous studies. What remains unknown is why there is a considerable pressure difference between the southern and northern strait. The Kuroshio flows along the east coast of Taiwan, and thus the western boundary current layer dynamics applies there. Integrating the momentum equation along Taiwan’s east coast shows that there must be a pressure difference between the southern and the northern tip of Taiwan to counter a considerable friction exerted by the mighty Kuroshio. This same pressure difference is also felt on the other side of the island where it forces the northward flow through Taiwan Strait. The model shows that the local wind stress acts to dampen this northward flow. This mechanism can be illustrated by an integral constraint for flow around an island.
    Description: This study has been supported by National Science Foundation through Grant OCE-0351055.
    Keywords: Ocean circulation ; Wind ; Currents
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  • 19
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    Transport and dynamics of the Panay Sill overflow in the Philippine Seas (2011)
    American Meteorological Society
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2010. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 40 (2010): 2679–2695, doi:10.1175/2010JPO4395.1.
    Description: Observations of stratification and currents between June 2007 and March 2009 reveal a strong overflow between 400- and 570-m depth from the Panay Strait into the Sulu Sea. The overflow water is derived from approximately 400 m deep in the South China Sea. Temporal mean velocity is greater than 0.75 m s−1 at 50 m above the 570-m Panay Sill. Empirical orthogonal function analysis of a mooring time series shows that the flow is dominated by the bottom overflow current with little seasonal variance. The overflow does not descend below 1250 m in the Sulu Sea but rather settles above high-salinity deep water derived from the Sulawesi Sea. The mean observed overflow transport at the sill is 0.32 × 106 m3 s−1. The observed transport was used to calculate a bulk diapycnal diffusivity of 4.4 × 10−4 m2 s−1 within the Sulu Sea slab (575–1250 m) ventilated from Panay Strait. Analysis of Froude number variation across the sill shows that the flow is hydraulically controlled. A suitable hydraulic control model shows overflow transport equivalent to the observed overflow. Thorpe-scale estimates show turbulent dissipation rates up to 5 × 10−7 W kg−1 just downstream of the supercritical to subcritical flow transition, suggesting a hydraulic jump downstream of the sill.
    Description: This work was supported by the Office of Naval Research Grant N00014-09-1-0582 to Lamont-Doherty Earth Observatory of Columbia University; Grants ONR-13759000 and N00014-09-1-0582 to the Woods Hole Oceanographic Institution; Grant ONR-N00014-06-1-0690 to Scripps Institute of Oceanography; and a National Defense Science and Engineering Graduate Fellowship.
    Keywords: Transport ; Dynamics ; Topographic effects ; Currents ; Empirical orthogonal functions
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  • 20
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    Near-surface transport pathways in the north Atlantic Ocean : looking for throughput from the subtropical to the subpolar gyre (2011)
    American Meteorological Society
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2011. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 41 (2011): 911–925, doi:10.1175/2011JPO4498.1.
    Description: Motivated by discrepancies between Eulerian transport estimates and the behavior of Lagrangian surface drifters, near-surface transport pathways and processes in the North Atlantic are studied using a combination of data, altimetric surface heights, statistical analysis of trajectories, and dynamical systems techniques. Particular attention is paid to the issue of the subtropical-to-subpolar intergyre fluid exchange. The velocity field used in this study is composed of a steady drifter-derived background flow, upon which a time-dependent altimeter-based perturbation is superimposed. This analysis suggests that most of the fluid entering the subpolar gyre from the subtropical gyre within two years comes from a narrow region lying inshore of the Gulf Stream core, whereas fluid on the offshore side of the Gulf Stream is largely prevented from doing so by the Gulf Stream core, which acts as a strong transport barrier, in agreement with past studies. The transport barrier near the Gulf Stream core is robust and persistent from 1992 until 2008. The qualitative behavior is found to be largely independent of the Ekman drift.
    Description: This work was supported by the National Science Foundation Grants CMG-82469600 and CMG-82579600 and by the Office of Naval Research Grant ONR-13108700.
    Keywords: Atlantic Ocean ; Transport ; Gyres ; Lagrangian circulation/transport ; Tracers ; Currents ; Meridional overturning circulation
    Repository Name: Woods Hole Open Access Server
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  • 21
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    Coral reef drag coefficients – water depth dependence (2017)
    American Meteorological Society
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2017. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 47 (2017): 1061-1075, doi:10.1175/JPO-D-16-0248.1.
    Description: A major challenge in modeling the circulation over coral reefs is uncertainty in the drag coefficient because existing estimates span two orders of magnitude. Current and pressure measurements from five coral reefs are used to estimate drag coefficients based on depth-average flow, assuming a balance between the cross-reef pressure gradient and the bottom stress. At two sites wind stress is a significant term in the cross-reef momentum balance and is included in estimating the drag coefficient. For the five coral reef sites and a previous laboratory study, estimated drag coefficients increase as the water depth decreases consistent with open channel flow theory. For example, for a typical coral reef hydrodynamic roughness of 5 cm, observational estimates, and the theory indicate that the drag coefficient decreases from 0.4 in 20 cm of water to 0.005 in 10 m of water. Synthesis of results from the new field observations with estimates from previous field and laboratory studies indicate that coral reef drag coefficients range from 0.2 to 0.005 and hydrodynamic roughnesses generally range from 2 to 8 cm. While coral reef drag coefficients depend on factors such as physical roughness and surface waves, a substantial fraction of the scatter in estimates of coral reef drag coefficients is due to variations in water depth.
    Description: The Red Sea field program was supported by Awards USA 00002 and KSA 00011 made by KAUST to S. Lentz and J. Churchill. The Palau field program was funded by NSF Award OCE-1220529.
    Keywords: Ocean ; Currents ; Wind stress ; Boundary layer ; Sea level ; Tides
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    Deep eddies in the Gulf of Mexico observed with floats (2018)
    American Meteorological Society
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Meteorological Society, 2018. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 48 (2018): 2703-2719, doi:10.1175/JPO-D-17-0245.1.
    Description: A new set of deep float trajectory data collected in the Gulf of Mexico from 2011 to 2015 at 1500- and 2500-m depths is analyzed to describe mesoscale processes, with particular attention paid to the western Gulf. Wavelet analysis is used to identify coherent eddies in the float trajectories, leading to a census of the basinwide coherent eddy population and statistics of the eddies’ kinematic properties. The eddy census reveals a new formation region for anticyclones off the Campeche Escarpment, located northwest of the Yucatan Peninsula. These eddies appear to form locally, with no apparent direct connection to the upper layer. Once formed, the eddies drift westward along the northern edge of the Sigsbee Abyssal Gyre, located in the southwestern Gulf of Mexico over the abyssal plain. The formation mechanism and upstream sources for the Campeche Escarpment eddies are explored: the observational data suggest that eddy formation may be linked to the collision of a Loop Current eddy with the western boundary of the Gulf. Specifically, the disintegration of a deep dipole traveling under the Loop Current eddy Kraken, caused by the interaction with the northwestern continental slope, may lead to the acceleration of the abyssal gyre and the boundary current in the Bay of Campeche region.
    Description: The authors were supported by the Department of the Interior, Bureau of Ocean Energy Management (BOEM), Contract M10PC00112 to Leidos, Inc., Raleigh, North Carolina.
    Description: 2019-05-07
    Keywords: Abyssal circulation ; Currents ; Eddies ; Mesoscale processes ; Trajectories ; In situ oceanic observations
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  • 23
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    Influence of the meridional shifts of the Kuroshio and the Oyashio Extensions on the atmospheric circulation (2011)
    American Meteorological Society
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2011. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 24 (2011): 762-777, doi:10.1175/2010JCLI3731.1.
    Description: The meridional shifts of the Oyashio Extension (OE) and of the Kuroshio Extension (KE), as derived from high-resolution monthly sea surface temperature (SST) anomalies in 1982–2008 and historical temperature profiles in 1979–2007, respectively, are shown based on lagged regression analysis to significantly influence the large-scale atmospheric circulation. The signals are independent from the ENSO teleconnections, which were removed by seasonally varying, asymmetric regression onto the first three principal components of the tropical Pacific SST anomalies. The response to the meridional shifts of the OE front is equivalent barotropic and broadly resembles the North Pacific Oscillation/western Pacific pattern in a positive phase for a northward frontal displacement. The response may reach 35 m at 250 hPa for a typical OE shift, a strong sensitivity since the associated SST anomaly is 0.5 K. However, the amplitude, but not the pattern or statistical significance, strongly depends on the lag and an assumed 2-month atmospheric response time. The response is stronger during fall and winter and when the front is displaced southward. The response to the northward KE shifts primarily consists of a high centered in the northwestern North Pacific and hemispheric teleconnections. The response is also equivalent barotropic, except near Kamchatka, where it tilts slightly westward with height. The typical amplitude is half as large as that associated with OE shifts.
    Description: This work was supported in part by the L’Institut universitaire de France (CF), the WHOI Heyman fellowship, and the NASAGrant withAwardNNX09AF35G(Y.-O. K), and grants through NOAA’s Climate Variability and Predictability Program (MAA).
    Keywords: Atmospheric circulation ; Currents
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    Four current meter models compared in strong currents in Drake Passage (2014)
    American Meteorological Society
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2013. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Atmospheric and Oceanic Technology 30 (2013): 2465–2477, doi:10.1175/JTECH-D-13-00032.1.
    Description: Seven current meters representing four models on a stiffly buoyed mooring were placed for an 11-month deployment to intercompare their velocity measurements: two vector-measuring current meters (VMCMs), two Aanderaa recording current meter (RCM) 11s, two Aanderaa SEAGUARDs, and a Nortek Aquadopp. The current meters were placed 6-m apart from each other at about 4000-m depth in an area of Drake Passage expected to have strong currents, nearly independent of depth near the bottom. Two high-current events occurred in bursts of semidiurnal pulses lasting several days, one with peak speeds up to 67 cm s−1 and the other above 35 cm s−1. The current-speed measurements all agreed within 7% of the median value when vector averaged over simultaneous time intervals. The VMCMs, chosen as the reference measurements, were found to measure the median of the mean-current magnitudes. The RCM11 and SEAGUARD current speeds agreed within 2% of the median at higher speeds (35–67 cm s−1), whereas in lower speed ranges (0–35 cm s−1) the vector-averaged speeds for the RCM11 and SEAGUARD were 4%–5% lower and 3%–5% higher than the median, respectively. The shorter-record Aquadopp current speeds were about 6% higher than the VMCMs over the range (0–40 cm s−1) encountered.
    Description: This work was supported by U.S. National Science Foundation Grants ANT-0635437 and ANT-0636493.
    Description: 2014-04-01
    Keywords: Currents ; Acoustic measurements/effects ; In situ oceanic observations ; Instrumentation/sensors
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    Eulerian and Lagrangian correspondence of high-frequency radar and surface drifter data : effects of radar resolution and flow components (2014)
    American Meteorological Society
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2014. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Atmospheric and Oceanic Technology 31 (2014): 945–966, doi:10.1175/JTECH-D-13-00146.1.
    Description: This study investigated the correspondence between the near-surface drifters from a mass drifter deployment near Martha’s Vineyard, Massachusetts, and the surface current observations from a network of three high-resolution, high-frequency radars to understand the effects of the radar temporal and spatial resolution on the resulting Eulerian current velocities and Lagrangian trajectories and their predictability. The radar-based surface currents were found to be unbiased in direction but biased in magnitude with respect to drifter velocities. The radar systematically underestimated velocities by approximately 2 cm s−1 due to the smoothing effects of spatial and temporal averaging. The radar accuracy, quantified by the domain-averaged rms difference between instantaneous radar and drifter velocities, was found to be about 3.8 cm s−1. A Lagrangian comparison between the real and simulated drifters resulted in the separation distances of roughly 1 km over the course of 10 h, or an equivalent separation speed of approximately 2.8 cm s−1. The effects of the temporal and spatial radar resolution were examined by degrading the radar fields to coarser resolutions, revealing the existence of critical scales (1.5–2 km and 3 h) beyond which the ability of the radar to reproduce drifter trajectories decreased more rapidly. Finally, the importance of the different flow components present during the experiment—mean, tidal, locally wind-driven currents, and the residual velocities—was analyzed, finding that, during the study period, a combination of tidal, locally wind-driven, and mean currents were insufficient to reliably reproduce, with minimal degradation, the trajectories of real drifters. Instead, a minimum combination of the tidal and residual currents was required.
    Description: I.R. was supported by the WHOI Coastal Ocean Institute Project 27040148 and by the WHOI Access to the Sea Program 27500036. I.R. and A.K. acknowledge support fromthe NSF project 83264600. A.K. acknowledges support from the Massachusetts Clean Energy Center (MassCEC) via the New England Marine Renewable Energy Center (MREC).
    Description: 2014-10-01
    Keywords: Coastal flows ; Currents ; Lagrangian circulation/transport ; Trajectories ; Radars/Radar observations
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  • 26
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    Wave-driven along-channel subtidal flows in a well-mixed ocean inlet (2014)
    John Wiley & Sons
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2014. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 119 (2014): 2987–3001, doi:10.1002/2014JC009839.
    Description: Observations of waves, flows, and water levels collected for a month in and near a long, narrow, shallow (∼ 3000 m long, 1000 m wide, and 5 m deep), well-mixed ocean inlet are used to evaluate the subtidal (periods 〉 30 h) along-inlet momentum balance. Maximum tidal flows in the inlet were about 1.5 m/s and offshore significant wave heights ranged from about 0.5 to 2.5 m. The dominant terms in the local (across the km-wide ebb shoal) along-inlet momentum balance are the along-inlet pressure gradient, the bottom stress, and the wave radiation-stress gradient. Estimated nonlinear advective acceleration terms roughly balance in the channel. Onshore radiation-stress gradients owing to breaking waves enhance the flood flows into the inlet, especially during storms.
    Description: Funding was provided by the Office of Naval Research, the Office of the Assistant Secretary of Defense for Research and Engineering, and a National Defense Science and Engineering Graduate Fellowship.
    Description: 2014-11-20
    Keywords: Inlet ; Wind waves ; Currents ; Radiation stress
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    The equatorial current system west of the Galapagos Islands during the 2014-16 El Niño as observed by underwater gliders (2021)
    American Meteorological Society
    Details
    Publication Date: 2022-05-27
    Description: Author Posting. © American Meteorological Society, 2021. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 51(1),(2021): 3-17, https://doi.org/10.1175/JPO-D-20-0064.1.
    Description: The strong El Niño of 2014–16 was observed west of the Galápagos Islands through sustained deployment of underwater gliders. Three years of observations began in October 2013 and ended in October 2016, with observations at longitudes 93° and 95°W between latitudes 2°N and 2°S. In total, there were over 3000 glider-days of data, covering over 50 000 km with over 12 000 profiles. Coverage was superior closer to the Galápagos on 93°W, where gliders were equipped with sensors to measure velocity as well as temperature, salinity, and pressure. The repeated glider transects are analyzed to produce highly resolved mean sections and maps of observed variables as functions of time, latitude, and depth. The mean sections reveal the structure of the Equatorial Undercurrent (EUC), the South Equatorial Current, and the equatorial front. The mean fields are used to calculate potential vorticity Q and Richardson number Ri. Gradients in the mean are strong enough to make the sign of Q opposite to that of planetary vorticity and to have Ri near unity, suggestive of mixing. Temporal variability is dominated by the 2014–16 El Niño, with the arrival of depressed isopycnals documented in 2014 and 2015. Increases in eastward velocity advect anomalously salty water and are uncorrelated with warm temperatures and deep isopycnals. Thus, vertical advection is important to changes in heat, and horizontal advection is relevant to changes in salt. Implications of this work include possibilities for future research, model assessment and improvement, and sustained observations across the equatorial Pacific.
    Description: We gratefully acknowledge the support of the National Science Foundation (OCE-1232971, OCE-1233282) and the Ocean Observing and Monitoring Division of the National Oceanographic and Atmospheric Administration (NA13OAR4830216).
    Keywords: Ocean ; Tropics ; Currents ; El Nino ; In situ oceanic observations
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    On the predictability of sea surface height around Palau (2021)
    American Meteorological Society
    Details
    Publication Date: 2022-05-27
    Description: Author Posting. © American Meteorological Society, 2020. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 50(11), (2020): 3267–3294, https://doi.org/10.1175/JPO-D-19-0310.1.
    Description: As part of the Flow Encountering Abrupt Topography (FLEAT) program, an array of pressure-sensor equipped inverted echo sounders (PIESs) was deployed north of Palau where the westward-flowing North Equatorial Current encounters the southern end of the Kyushu–Palau Ridge in the tropical North Pacific. Capitalizing on concurrent observations from satellite altimetry, FLEAT Spray gliders, and shipboard hydrography, the PIESs’ 10-month duration hourly bottom pressure p and round-trip acoustic travel time τ records are used to examine the magnitude and predictability of sea level and pycnocline depth changes and to track signal propagations through the array. Sea level and pycnocline depth are found to vary in response to a range of ocean processes, with their magnitude and predictability strongly process dependent. Signals characterized here comprise the barotropic tides, semidiurnal and diurnal internal tides, southeastward-propagating superinertial waves, westward-propagating mesoscale eddies, and a strong signature of sea level increase and pycnocline deepening associated with the region’s relaxation from El Niño to La Niña conditions. The presence of a broad band of superinertial waves just above the inertial frequency was unexpected and the FLEAT observations and output from a numerical model suggest that these waves detected near Palau are forced by remote winds east of the Philippines. The PIES-based estimates of pycnocline displacement are found to have large uncertainties relative to overall variability in pycnocline depth, as localized deep current variations arising from interactions of the large-scale currents with the abrupt topography around Palau have significant travel time variability.
    Description: Support for this research was provided by Office of Naval Research Grants N00014-16-1-2668, N00014-18-1-2406, N00014-15-1-2488, and N00014-15-1-2622. R.C.M. was additionally supported by the Postdoctoral Scholar Program at the Woods Hole Oceanographic Institution, with funding provided by the Weston Howland Jr. Postdoctoral Scholarship.
    Keywords: Tropics ; Currents ; Eddies ; ENSO ; Internal waves ; Mesoscale processes
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    Kinematic structure and dynamics of the Denmark Strait Overflow from ship-based observations (2021)
    American Meteorological Society
    Details
    Publication Date: 2022-05-27
    Description: Author Posting. © American Meteorological Society, 2020. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 50(11), (2020): 3235–3251, https://doi.org/10.1175/JPO-D-20-0095.1.
    Description: The dense outflow through Denmark Strait is the largest contributor to the lower limb of the Atlantic meridional overturning circulation, yet a description of the full velocity field across the strait remains incomplete. Here we analyze a set of 22 shipboard hydrographic–velocity sections occupied along the Látrabjarg transect at the Denmark Strait sill, obtained over the time period 1993–2018. The sections provide the first complete view of the kinematic components at the sill: the shelfbreak East Greenland Current (EGC), the combined flow of the separated EGC, and the North Icelandic Jet (NIJ), and the northward-flowing North Icelandic Irminger Current (NIIC). The total mean transport of overflow water is 3.54 ± 0.29 Sv (1 Sv ≡ 106 m3 s−1), comparable to previous estimates. The dense overflow is partitioned in terms of water mass constituents and flow components. The mean transports of the two types of overflow water—Atlantic-origin Overflow Water and Arctic-origin Overflow Water—are comparable in Denmark Strait, while the merged NIJ–separated EGC transports 55% more water than the shelfbreak EGC. A significant degree of water mass exchange takes place between the branches as they converge in Denmark Strait. There are two dominant time-varying configurations of the flow that are characterized as a cyclonic state and a noncyclonic state. These appear to be wind-driven. A potential vorticity analysis indicates that the flow through Denmark Strait is subject to symmetric instability. This occurs at the top of the overflow layer, implying that the mixing/entrainment process that modifies the overflow water begins at the sill.
    Description: Funding for the study was provided by National Science Foundation (NSF) Grants OCE-1259618, OCE-1756361, and OCE-1558742. The German research cruises were financially supported through various EU Projects (e.g. THOR, NACLIM) and national projects (most recently TRR 181 “Energy Transfer in Atmosphere and Ocean” funded by the German Research Foundation and RACE II “Regional Atlantic Circulation and Global Change” funded by the German Federal Ministry for Education and Research). GWKM acknowledges the support of the Natural Sciences and Engineering Research Council of Canada. LP was supported by NSF Grant OCE-1657870.
    Keywords: Currents ; Instability ; Ocean circulation ; Ocean dynamics ; Potential vorticity
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    Role of the Gulf Stream and Kuroshio–Oyashio systems in large-scale atmosphere–ocean interaction : a review (2010)
    American Meteorological Society
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2010. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 23 (2010): 3249-3281, doi:10.1175/2010JCLI3343.1.
    Description: Ocean–atmosphere interaction over the Northern Hemisphere western boundary current (WBC) regions (i.e., the Gulf Stream, Kuroshio, Oyashio, and their extensions) is reviewed with an emphasis on their role in basin-scale climate variability. SST anomalies exhibit considerable variance on interannual to decadal time scales in these regions. Low-frequency SST variability is primarily driven by basin-scale wind stress curl variability via the oceanic Rossby wave adjustment of the gyre-scale circulation that modulates the latitude and strength of the WBC-related oceanic fronts. Rectification of the variability by mesoscale eddies, reemergence of the anomalies from the preceding winter, and tropical remote forcing also play important roles in driving and maintaining the low-frequency variability in these regions. In the Gulf Stream region, interaction with the deep western boundary current also likely influences the low-frequency variability. Surface heat fluxes damp the low-frequency SST anomalies over the WBC regions; thus, heat fluxes originate with heat anomalies in the ocean and have the potential to drive the overlying atmospheric circulation. While recent observational studies demonstrate a local atmospheric boundary layer response to WBC changes, the latter’s influence on the large-scale atmospheric circulation is still unclear. Nevertheless, heat and moisture fluxes from the WBCs into the atmosphere influence the mean state of the atmospheric circulation, including anchoring the latitude of the storm tracks to the WBCs. Furthermore, many climate models suggest that the large-scale atmospheric response to SST anomalies driven by ocean dynamics in WBC regions can be important in generating decadal climate variability. As a step toward bridging climate model results and observations, the degree of realism of the WBC in current climate model simulations is assessed. Finally, outstanding issues concerning ocean–atmosphere interaction in WBC regions and its impact on climate variability are discussed.
    Description: Funding for LT was provided by the NASA-sponsored Ocean Surface Topography Science Team, under Contract 1267196 with the University of Washington, administered by the Jet Propulsion Laboratory. HN was supported in part by the Grant-in-Aid 18204044 by the Japan Society for Promotion for Science (JSPS) and the Global Environment Research Fund (S-5) of the Japanese Ministry of Environment. YK was supported by the Kerr Endowed Fund and Penzance Endowed Fund.
    Keywords: Currents ; Sea surface temperature ; Anomalies ; Large-scale motions ; Oceanic mixed layer ; Northern Hemisphere
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    Diapycnal mixing in the Antarctic Circumpolar Current (2011)
    American Meteorological Society
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2011. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 41 (2011): 241-246, doi:10.1175/2010JPO4557.1.
    Description: The vertical dispersion of a tracer released on a density surface near 1500-m depth in the Antarctic Circumpolar Current west of Drake Passage indicates that the diapycnal diffusivity, averaged over 1 yr and over tens of thousands of square kilometers, is (1.3 ± 0.2) × 10−5 m2 s−1. Diapycnal diffusivity estimated from turbulent kinetic energy dissipation measurements about the area occupied by the tracer in austral summer 2010 was somewhat less, but still within a factor of 2, at (0.75 ± 0.07) × 10−5 m2 s−1. Turbulent diapycnal mixing of this intensity is characteristic of the midlatitude ocean interior, where the energy for mixing is believed to derive from internal wave breaking. Indeed, despite the frequent and intense atmospheric forcing experienced by the Southern Ocean, the amplitude of finescale velocity shear sampled about the tracer was similar to background amplitudes in the midlatitude ocean, with levels elevated to only 20%–50% above the Garrett–Munk reference spectrum. These results add to a long line of evidence that diapycnal mixing in the interior middepth ocean is weak and is likely too small to dictate the middepth meridional overturning circulation of the ocean.
    Description: This material is based upon work supported by the National Science Foundation Grants OCE-0622825,OCE-0622670, OCE-0622630, and OCE-0623177.
    Keywords: Diapycnal mixing ; Currents ; Antarctica ; Ocean circulation ; Meridional overturning circulation
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  • 32
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    The use (and misuse) of sediment traps in coral reef environments : theory, observations, and suggested protocols (2011)
    Springer
    Details
    Publication Date: 2022-05-26
    Description: © The Authors, 2010. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Coral Reefs 30 (2011): 23-38, doi:10.1007/s00338-010-0705-3.
    Description: Sediment traps are commonly used as standard tools for monitoring “sedimentation” in coral reef environments. In much of the literature where sediment traps were used to measure the effects of “sedimentation” on corals, it is clear from deployment descriptions and interpretations of the resulting data that information derived from sediment traps has frequently been misinterpreted or misapplied. Despite their widespread use in this setting, sediment traps do not provide quantitative information about “sedimentation” on coral surfaces. Traps can provide useful information about the relative magnitude of sediment dynamics if trap deployment standards are used. This conclusion is based first on a brief review of the state of knowledge of sediment trap dynamics, which has primarily focused on traps deployed high above the seabed in relatively deep water, followed by our understanding of near-bed sediment dynamics in shallow-water environments that characterize coral reefs. This overview is followed by the first synthesis of near-bed sediment trap data collected with concurrent hydrodynamic information in coral reef environments. This collective information is utilized to develop nine protocols for using sediment traps in coral reef environments, which focus on trap parameters that researchers can control such as trap height (H), trap mouth diameter (D), the height of the trap mouth above the substrate (z o ), and the spacing between traps. The hydrodynamic behavior of sediment traps and the limitations of data derived from these traps should be forefront when interpreting sediment trap data to infer sediment transport processes in coral reef environments.
    Keywords: Sediment trap ; Coral reefs ; Sedimentation ; Waves ; Currents ; Shear stress
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    3D structure of striations in the North Pacific (2022)
    American Meteorological Society
    Details
    Publication Date: 2022-06-06
    Description: Author Posting. © American Meteorological Society, 2021. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 51(12),(2021): 3651–3662, https://doi.org/10.1175/JPO-D-21-0076.1.
    Description: Ocean striations are composed of alternating quasi-zonal band-like flows; this kind of organized structure of currents can be found in all the world’s oceans and seas. Previous studies have mainly been focused on the mechanisms of their generation and propagation. This study uses the spatial high-pass filtering to obtain the three-dimensional structure of ocean striations in the North Pacific in both the z coordinate and σ coordinate based on 10-yr averaged Simple Ocean Data Assimilation version 3 (SODA3) data. First, we identify an ideal-fluid potential density domain where the striations are undisturbed by the surface forcing and boundary effects. Second, using the isopycnal layer analysis, we show that on isopycnal surfaces the orientations of striations nearly follow the potential vorticity (PV) contours, while in the meridional–vertical plane the central positions of striations are generally aligned with the latitude of zero gradient of the relative PV. Our analysis provides a simple dynamical interpretation and better understanding for the role of ocean striations.
    Description: This work is supported by the National Natural Science Foundation of China (42076025, 41676021), the Key Special Project for introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) (GML2019ZD0306), the National Basic Research Program (973 Program) of China (2013CB956201). The numerical simulation is supported by the High Performance Computing Division in the South China Sea Institute of Oceanography. The authors thank Tingjin Guan for the help in enhancing drawing quality.
    Keywords: Currents ; Jets ; Mesoscale processes ; Potential vorticity ; Isopycnal coordinates
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  • 34
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    Whither the Chukchi Slope Current? (2021)
    American Meteorological Society
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2020. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 50(6),(2020): 1717-1732, doi:10.1175/JPO-D-19-0273.1.
    Description: Recent measurements and modeling indicate that roughly half of the Pacific-origin water exiting the Chukchi Sea shelf through Barrow Canyon forms a westward-flowing current known as the Chukchi Slope Current (CSC), yet the trajectory and fate of this current is presently unknown. In this study, through the combined use of shipboard velocity data and information from five profiling floats deployed as quasi-Lagrangian particles, we delve further into the trajectory and the fate of the CSC. During the period of observation, from early September to early October 2018, the CSC progressed far to the north into the Chukchi Borderland. The northward excursion is believed to result from the current negotiating Hanna Canyon on the Chukchi slope, consistent with potential vorticity dynamics. The volume transport of the CSC, calculated using a set of shipboard transects, decreased from approximately 2 Sv (1 Sv ≡ 106 m3 s−1) to near zero over a period of 4 days. This variation can be explained by a concomitant change in the wind stress curl over the Chukchi shelf from positive to negative. After turning northward, the CSC was disrupted and four of the five floats veered offshore, with one of the floats permanently leaving the current. It is hypothesized that the observed disruption was due to an anticyclonic eddy interacting with the CSC, which has been observed previously. These results demonstrate that, at times, the CSC can get entrained into the Beaufort Gyre.
    Description: This work was principally supported by the Stratified Ocean Dynamics of the Arctic (SODA) program under ONR Grant N000141612450. S.B. wants to thank Labex iMust for supporting his research. R.S.P. acknowledges U.S. National Science Foundation Grants OPP-1702371, OPP-1733564, and PLR-1303617. P.L. acknowledges National Oceanic and Atmospheric Administration Grant NA14-OAR4320158. M.L. acknowledges National Natural Science Foundation of China Grants 41706025 and 41506018. T.P. thanks ENS de Lyon for travel support funding. The authors gratefully acknowledge the support of Steve Jayne, Pelle Robins, and Alex Ekholm at the Woods Hole Oceanographic Institution for preparation, deployment, and data provision for the ALTO floats. Chanhyung Jeon assisted in preparing and deploying the floats. The invaluable support of the crew of the R/V Sikuliaq is also gratefully acknowledged.
    Keywords: Arctic ; Continental shelf/slope ; Currents ; Mixing
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    Structure and variability of the shelfbreak East Greenland Current north of Denmark Strait (2017)
    American Meteorological Society
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2017. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 47 (2017): 2631-2646, doi:10.1175/JPO-D-17-0062.1.
    Description: Data from a mooring array deployed north of Denmark Strait from September 2011 to August 2012 are used to investigate the structure and variability of the shelfbreak East Greenland Current (EGC). The shelfbreak EGC is a surface-intensified current situated just offshore of the east Greenland shelf break flowing southward through Denmark Strait. This study identified two dominant spatial modes of variability within the current: a pulsing mode and a meandering mode, both of which were most pronounced in fall and winter. A particularly energetic event in November 2011 was related to a reversal of the current for nearly a month. In addition to the seasonal signal, the current was associated with periods of enhanced eddy kinetic energy and increased variability on shorter time scales. The data indicate that the current is, for the most part, barotropically stable but subject to baroclinic instability from September to March. By contrast, in summer the current is mainly confined to the shelf break with decreased eddy kinetic energy and minimal baroclinic conversion. No other region of the Nordic Seas displays higher levels of eddy kinetic energy than the shelfbreak EGC north of Denmark Strait during fall. This appears to be due to the large velocity variability on mesoscale time scales generated by the instabilities. The mesoscale variability documented here may be a source of the variability observed at the Denmark Strait sill.
    Description: Support for this work was provided by the Norwegian Research Council under Grant Agreement 231647 (LH and KV) and the Bergen Research Foundation under Grant BFS2016REK01 (KV). Additional funding was provided by the National Science Foundation under Grants OCE-0959381 and OCE-1558742 (RP).
    Keywords: Ocean ; Arctic ; Boundary currents ; Currents ; Stability ; Oceanic variability
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  • 36
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    Iceland-Scotland Overflow Water transport variability through the Charlie-Gibbs Fracture Zone and the impact of the North Atlantic Current (2017)
    John Wiley & Sons
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 122 (2017): 6989–7012, doi:10.1002/2017JC012698.
    Description: The Charlie-Gibbs Fracture Zone (CGFZ), a deep and wide gap in the Mid-Atlantic Ridge near 52°N, is a gateway between the eastern and western subpolar regions for the Atlantic Meridional Overturning Circulation (AMOC). In 2010–2012, an eight-mooring array of current meters and temperature/salinity sensors was installed across the CGFZ between 500 m and the sea floor to measure the mean transport of westward-flowing Iceland-Scotland Overflow Water (ISOW) and investigate the impact of the eastward-flowing North Atlantic Current (NAC) on ISOW transport variability. The 22 month record mean ISOW transport through the CGFZ, −1.7 ± 0.5 Sv (95% confidence interval), is 30% lower than the previously published estimate based on 13 months of current-only measurements, −2.4 ± 1.2 Sv. The latter mean estimate may have been biased high due to the lack of continuous salinity measurements, although the two estimates are not statistically different due to strong mesoscale variability in both data sets. Empirical Orthogonal Function analysis and maps of satellite-derived absolute dynamic topography show that weak westward ISOW transport events and eastward reversals are caused by northward meanders of the NAC, with its deep-reaching eastward velocities. These results add to growing evidence that a significant fraction of ISOW exits the Iceland Basin by routes other than the CGFZ.
    Description: U.S. National Science Foundation Grant Number: OCE-0926656; Woods Hole Oceanographic Institution
    Description: 2018-03-01
    Keywords: Currents ; Eddies and mesoscale processes ; Topographic/bathymetric interactions
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  • 37
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    Sedimentation processes in a coral reef embayment : Hanalei Bay, Kauai (2009)
    Elsevier B.V.
    Details
    Publication Date: 2022-05-26
    Description: This paper is not subject to U.S. copyright. The definitive version was published in Marine Geology 264 (2009): 140-151, doi:10.1016/j.margeo.2009.05.002.
    Description: Oceanographic measurements and sediment samples were collected during the summer of 2006 as part of a multi-year study of coastal circulation and the fate of terrigenous sediment on coral reefs in Hanalei Bay, Kauai. The goal of this study was to better understand sediment dynamics in a coral reef-lined embayment where winds, ocean surface waves, and river floods are important processes. During a summer period that was marked by two wave events and one river flood, we documented significant differences in sediment trap collection rates and the composition, grain size, and magnitude of sediment transported in the bay. Sediment trap collection rates were well correlated with combined wave-current near-bed shear stresses during the non-flood periods but were not correlated during the flood. The flood's delivery of fine-grained sediment to the bay initially caused high turbidity and sediment collection rates off the river mouth but the plume dispersed relatively quickly. Over the next month, the flood deposit was reworked by mild waves and currents and the fine-grained terrestrial sediment was advected around the bay and collected in sediment traps away from the river mouth, long after the turbid surface plume was gone. The reworked flood deposits, due to their longer duration of influence and proximity to the seabed, appear to pose a greater long-term impact to benthic coral reef communities than the flood plumes themselves. The results presented here display how spatial and temporal differences in hydrodynamic processes, which result from variations in reef morphology and orientation, cause substantial variations in the deposition, residence time, resuspension, and advection of both reef-derived and fluvial sediment over relatively short spatial scales in a coral reef embayment.
    Keywords: Coral reefs ; Winds ; Waves ; Currents ; Sediment traps ; Sedimentation ; USA ; Hawaii ; Kauai
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  • 38
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    Hurricane Sally (2020) shifts the ocean thermal structure across the inner core during rapid intensification over the shelf (2023)
    American Meteorological Society
    Details
    Publication Date: 2023-02-25
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(11), (2022): 2841–2852, https://doi.org/10.1175/jpo-d-22-0025.1.
    Description: Prediction of rapid intensification in tropical cyclones prior to landfall is a major societal issue. While air–sea interactions are clearly linked to storm intensity, the connections between the underlying thermal conditions over continental shelves and rapid intensification are limited. Here, an exceptional set of in situ and satellite data are used to identify spatial heterogeneity in sea surface temperatures across the inner core of Hurricane Sally (2020), a storm that rapidly intensified over the shelf. A leftward shift in the region of maximum cooling was observed as the hurricane transited from the open gulf to the shelf. This shift was generated, in part, by the surface heat flux in conjunction with the along- and across-shelf transport of heat from storm-generated coastal circulation. The spatial differences in the sea surface temperatures were large enough to potentially influence rapid intensification processes suggesting that coastal thermal features need to be accounted for to improve storm forecasting as well as to better understand how climate change will modify interactions between tropical cyclones and the coastal ocean.
    Description: This research was made possible by the NOAA RESTORE Science Program (NA17NOS4510101 and NA19NOS4510194) and the NASA Physical Oceanography program (80NSSC21K0553 and WBS 281945.02.25.04.67) and NOAA IOOS program via GCOOS (NA16NOS0120018). The authors declare that they have no competing interests.
    Keywords: Seas/gulfs/bays ; Atmosphere–ocean interaction ; Currents ; Tropical cyclones ; Buoy observations ; In situ oceanic observations
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    Turbulent thermal-wind driven coastal upwelling: current observations and dynamics (2022)
    American Meteorological Society
    Details
    Publication Date: 2022-12-21
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(12), (2022): 2909-2921, https://doi.org/10.1175/jpo-d-22-0063.1.
    Description: A remarkably consistent Lagrangian upwelling circulation at monthly and longer time scales is observed in a 17-yr time series of current profiles in 12 m of water on the southern New England inner shelf. The upwelling circulation is strongest in summer, with a current magnitude of ∼1 cm s−1, which flushes the inner shelf in ∼2.5 days. The average winter upwelling circulation is about one-half of the average summer upwelling circulation, but with larger month-to-month variations driven, in part, by cross-shelf wind stresses. The persistent upwelling circulation is not wind-driven; it is driven by a cross-shelf buoyancy force associated with less-dense water near the coast. The cross-shelf density gradient is primarily due to temperature in summer, when strong surface heating warms shallower nearshore water more than deeper offshore water, and to salinity in winter, caused by fresher water near the coast. In the absence of turbulent stresses, the cross-shelf density gradient would be in a geostrophic, thermal-wind balance with the vertical shear in the along-shelf current. However, turbulent stresses over the inner shelf attributable to strong tidal currents and wind stress cause a partial breakdown of the thermal-wind balance that releases the buoyancy force, which drives the observed upwelling circulation. The presence of a cross-shelf density gradient has a profound impact on exchange across this inner shelf. Many inner shelves are characterized by turbulent stresses and cross-shelf density gradients with lighter water near the coast, suggesting turbulent thermal-wind-driven coastal upwelling may be a broadly important cross-shelf exchange mechanism.
    Description: The National Science Foundation, Woods Hole Oceanographic Institution, the Massachusetts Technology Collaborative, and the Office of Naval Research have supported the construction and maintenance of MVCO. The analysis presented here was partially funded by the National Science Foundation under Grants OCE 1558874 and OCE 1655686.
    Keywords: Buoyancy ; Coastal flows ; Currents ; Dynamics ; Lagrangian circulation/transport ; Upwelling/downwelling
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  • 40
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    Potential Vorticity and Instability in the Pacific Equatorial Undercurrent West of the Galápagos Archipelago (2022)
    American Meteorological Society
    Details
    Publication Date: 2023-02-01
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(8), (2022): 1927-1943, https://doi.org/10.1175/jpo-d-21-0124.1.
    Description: The Galápagos Archipelago lies on the equator in the path of the eastward flowing Pacific Equatorial Undercurrent (EUC). When the EUC reaches the archipelago, it upwells and bifurcates into a north and south branch around the archipelago at a latitude determined by topography. Since the Coriolis parameter (f) equals zero at the equator, strong velocity gradients associated with the EUC can result in Ertel potential vorticity (Q) having sign opposite that of planetary vorticity near the equator. Observations collected by underwater gliders deployed just west of the Galápagos Archipelago during 2013–16 are used to estimate Q and to diagnose associated instabilities that may impact the Galápagos Cold Pool. Estimates of Q are qualitatively conserved along streamlines, consistent with the 2.5-layer, inertial model of the EUC by Pedlosky. The Q with sign opposite of f is advected south of the Galápagos Archipelago when the EUC core is located south of the bifurcation latitude. The horizontal gradient of Q suggests that the region between 2°S and 2°N above 100 m is barotropically unstable, while limited regions are baroclinically unstable. Conditions conducive to symmetric instability are observed between the EUC core and the equator and within the southern branch of the undercurrent. Using 2-month and 3-yr averages, e-folding time scales are 2–11 days, suggesting that symmetric instability can persist on those time scales.
    Description: This work was supported by the National Science Foundation (Grants OCE-1232971 and OCE-1233282), the NASA Earth and Space Science Fellowship Program (Grant 80NSSC17K0443), and the Global Ocean Monitoring and Observing Program of the National Oceanographic and Atmospheric Administration (NA13OAR4830216). Color maps are from Thyng et al. (2016).
    Description: 2023-02-01
    Keywords: Currents ; In situ oceanic observations ; Instability ; Mixing ; Ocean dynamics ; Pacific Ocean ; Potential vorticity ; Tropics
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  • 41
    Electronic Resource
    Electronic Resource
    Ni–Zn–P alloy deposition from sulfate bath: inhibitory effect of zinc (1999)
    Springer
    Journal of applied electrochemistry 29 (1999), S. 1171-1176 
    Details
    ISSN: 1572-8838
    Keywords: alloys ; cyclic voltammetry ; electrodeposition ; electroless deposition ; nickel ; phosphorus ; zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Electroless Ni–Zn–P alloy deposition from a sulphate bath, containing sodium hypophosphite as reducer, was investigated. To increase the plating rate, the deposition parameters were optimized. The effect of process parameters (T, pH and [Zn2+]) on the plating rate and deposit composition was examined and it was found that the presence of zinc in the bath has an inhibitory effect on the alloy deposition. As a consequence, the percentage of zinc in the electroless Ni–Zn–P alloys never reaches high values. Using cyclic voltammetry the electrodeposition mechanism of Ni–Zn–P alloys was investigated. It was observed that the zinc deposition inhibits the nickel discharge and, as a consequence, its catalytic activity on hypophosphite oxidation. It was also found that increase in temperature or pH leads to the deposition of nickel rich alloys.
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    URL: http://dx.doi.org/10.1023/A:1003426904395
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    Structure of (meso-5,10,15,20-tetraphenylporphyrinato) dichlorophosphorus(V) chloride, [P(tpp)Cl2]+Cl− (1995)
    Springer
    Journal of chemical crystallography 25 (1995), S. 231-235 
    Details
    ISSN: 1572-8854
    Keywords: Octahedral ; phosphorus ; chloride
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The title compound [P(tpp)Cl2]+Cl− crystallizes in the space group P21/n witha=10.701(2),b=24.860(2),c=14.799(2), β=94.24(2)°,Z=4. The phosphorus atom has an octahedral coordination geometry formed by the four nitrogen atoms (Np) of the porphyrinato group and the two chloride ions. The average phosphorus-chloride distance is 2.150(1) Å, with phosphorus situated 0.006 Å below the porphyrin ring.
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    URL: http://dx.doi.org/10.1007/BF01665175
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    Electrochemical characterization of Fe-Ni-P alloy electrodeposition (1997)
    Springer
    Journal of applied electrochemistry 27 (1997), S. 1198-1206 
    Details
    ISSN: 1572-8838
    Keywords: alloy ; amorphous ; anomalous ; hydrogen ; iron ; nickel ; phosphorus ; plating
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract In this study we have investigated the electrodeposition of amorphous iron–nickel–phosphorus alloys from a sulfate electrolyte. Fe-Ni alloys are known to exhibit an ’anomalous‘ type of plating behaviour in which deposition of the less noble metal is favoured. We have found that the codeposition of phosphorus from hypophosphite in the electrolyte led to a reversal to a ’normal‘ behaviour. This reversal was due both to the suppression of iron and enhancement of nickel partial currents. The overall deposition process is dominated by the hydrogen evolution reaction. This is exacerbated by the low pH needed to codeposit sufficient phosphorus to achieve an amorphous structure.
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    URL: http://dx.doi.org/10.1023/A:1018475718629
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    Microstructural characterization and corrosion resistance of Ni–Zn–P alloys electrolessly deposited from a sulphate bath (1999)
    Springer
    Journal of applied electrochemistry 29 (1999), S. 637-645 
    Details
    ISSN: 1572-8838
    Keywords: alloys ; electroless ; microstructure ; morphology ; nickel ; phosphorus ; zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Electroless Ni–Zn–P alloy coatings were obtained on an iron substrate from a sulfate bath at various pH values. The effects of changes in bath pH on alloy composition, morphology, microstructure and corrosion resistance were studied. Scanning electron microscopy was performed to observe the morphological change of the deposits with bath pH. Coating crystallinity was investigated by grazing incidence asymmetric Bragg X-ray diffraction and transmission electron microscopy. A transition from an amorphous to polycrystalline structure was observed on increasing the bath alkalinity, and thus decreasing the phosphorus content of the alloys. A single crystalline phase corresponding to face-centred-cubic nickel was identified in the alloys obtained from a strong alkaline solution. An increase in zinc percentage up to 23% in the deposits does not change the f.c.c. nickel crystalline structure. Corrosion potential and polarization resistance measurements indicated that the corrosion resistance of electroless Ni–Zn–P alloys depends strongly on the microstructure and chemical composition. The deposits obtained at pH 9.0–9.5 and with 11.4–12.5% zinc and 11.8–11.2% phosphorous exhibited the best corrosion resistance.
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    Surface acid property and its relation to SCR activity of phosphorus added to commercial V2O5(WO3)/TiO2 catalyst (1998)
    Springer
    Catalysis letters 53 (1998), S. 65-71 
    Details
    ISSN: 1572-879X
    Keywords: selective catalytic reduction ; nitric oxide reduction ; phosphorus ; acid property
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract To examine the influence of phosphorus on the commercial V2O5(WO3)/TiO2 SCR catalyst, measurements were carried out by means of infrared and Raman spectroscopy, XPS, and NO reduction measurement as a function of phosphorus loading. Phosphorus added to the catalyst was found to disperse well over the catalyst without a significant agglomeration up to 5 wt% P2O5 addition. The number of the hydroxyl groups bonded to the vanadium and titanium species decreased readily with increasing amount of phosphorus. Correspondingly, the hydroxyl groups bonded to the phosphorus species were formed. NH3 adsorbed on both hydroxyl groups bonded to vanadium and phosphorus as ammonium ions, implying that the P–OH groups formed are also responsible for the Brønsted acidity. The NO reduction activity was found to be decreased with increasing amount of phosphorus; however, the influence of phosphorus was relatively small irrespective of the large amount of phosphorus addition. The deactivation might be caused by the change in the nature of the surface hydroxyl groups as Brønsted acid sites. Phosphorus species might partially wrap the surface V=O and W=O groups, which might also contribute to the deactivation.
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    URL: http://dx.doi.org/10.1023/A:1019020931117
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    The ecosystem of a mesotrophic lake-II. Interactions among nutrient load, river flow, and epilimnion depth (1991)
    Springer
    Aquatic sciences 53 (1991), S. 263-272 
    Details
    ISSN: 1420-9055
    Keywords: Lake ecosystem ; chl-a ; phosphorus ; nitrogen ; river flow ; thermocline ; simulation model ; multiple regression
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The management variables which primarily affect phytoplankton biomass (as chl-a) in Lake Mjøsa, Norway, are total phosphorus loading (TP) and the timing and volume of water through flow (by active storage reservoirs). The response of the lake to changes in these factors is studied using a simulation model of the lake ecosystem. Chl-a responses from both observed data and the simulated results are extracted by multiple regression. Results show that decreasing TP load decreases chl-a, but less at low TP levels (〈 10 mg TP · m−3). There is also a certain time period for peak river flow which gives the least yield of chl-a per unit TP. This time period occurs in early summer (i.e., around June 10) if the total phosphorus load is low, and later if the load is high. Both observations and simulation results show that a high water flow increases chl-a at low epilimnion depths (〈 15 m), but that the same high water flow decreases chl-a when epilmnion is deep.
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    URL: http://dx.doi.org/10.1007/BF00877062
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    The short term response to eutrophication abatement (1990)
    Springer
    Aquatic sciences 52 (1990), S. 199-220 
    Details
    ISSN: 1420-9055
    Keywords: Eutrophication ; lake management ; phosphorus ; ecosystem ; chlorophyll-a ; mathematical modelling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract We compare results of a new model for predicting the short term inter annual changes in chlorophyll-a (chl-a) in lakes after reductions in total phosphorus (TP) to predictions made by least squares regression models. In the new method, slopes of chl-a/TP graphs (both axes in mg · m−3) are depicted in frequency diagrams and used to extract information on the expected, short term chl-a/TP response. The short term response for nine shallow (〈 10 m deep) and nutrient rich lakes to changes in TP was found to be: Chl-a = 0.49 · TP + 17.3, and for nine deep, P-limited lakes: Chl-a = 0.08 · TP + 3.5. If the TP-reduction is known to be greater than 10 mg · m−3, the expected slope increases to 0.58 for shallow lakes and to 0.26 for deep lakes. The slope, 0.58, is 8% lower than the slope for the long term response calculated by regression for the shallow lakes. For deep lakes the slope, 0.26, is 2 to 3 times higher than that calculated by regression, indicating that reductions in TP for deep lakes give greater effects than least squares regression equations suggest. We have also calculated the reduction in TP which will give about 80% probability that a reduction in chl-a will be observed next year. For shallow, P-limited lakes this reduction is about 30 mg · m−3 (5% of average initial in-lake TP concentration), and for deep lakes about 14 mg · m−3 (35% of average initial in-lake TP concentration).
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    URL: http://dx.doi.org/10.1007/BF00877280
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    Vertical mixing in Überlinger See, western part of Lake Constance (1990)
    Springer
    Aquatic sciences 52 (1990), S. 256-268 
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    ISSN: 1420-9055
    Keywords: Vertical mixing ; stratification ; phosphorus ; Lake Constance
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Depth variable vertical eddy diffusion coefficients for heat (K z) were calculated from continuously measured temperature profiles in Überlinger See (western part of Lake Constance). The temperatures were averaged over vertical intervals of 10 m yielding 14 discrete values (maximum depth of Überlinger See: 147 m). A linear fit from 10 June to 29 September 1987 was used to smooth the significant temperature fluctuations caused by internal seiches of Lake Constance. Assuming horizontal homogeneity for the smoothed data the Gradient-Flux-Method was applied to compute vertical diffusion coefficientsK z at different depths using the depth variable volumes and surfaces of the 14 layers. The resulting mean diffusion coefficients for the period from June to September are 0.04 cm2/s near the thermocline and up to 0.8 cm2/s in deeper strata (accuracy: ± 50%). It is shown that horizontal mixing between Überlinger See and Obersee (main lake) alters the computation ofK z by less than 50%. A relationship betweenK z and stability (Brunt-Väisälä) frequencyN is found which corresponds well to the theory of internal wave induced turbulence. Combining the diffusion coefficients with measured phosphorus profiles, a phosphorus flux from the hypolimnion to the epilimnion of (0.7 ± 0.4) mg P m−2 d−1 was calculated, corresponding to about 20% of the average external loading per area of Lake Constance in 1986.
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    Measurement of total dissolved phosphorus in small volumes of iron rich interstitial water (1992)
    Springer
    Aquatic sciences 54 (1992), S. 1-9 
    Details
    ISSN: 1420-9055
    Keywords: Sediment ; interstitial water ; phosphorus ; iron ; persulfate digestion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract It is shown that sorption of orthophosphate to iron compounds, formed during persulfate digestion, can cause a significant underestimation of total dissolved phosphorus in interstitial waters rich in iron and poor in phosphorus. Labelling the samples with carrier free32PO4 before digestion allows to correct for these losses.
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    Effects of repeated manure and fertilizer phosphorus additions on soil phosphorus dynamics under a soybean-wheat rotation (1999)
    Springer
    Biology and fertility of soils 28 (1999), S. 150-155 
    Details
    ISSN: 1432-0789
    Keywords: Key words Phosphorus dynamics ; Olsen ; phosphorus ; Soil phosphorus fractions ; Manure ; Soybean-wheat rotation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract  Soil P availability and efficiency of applied P may be improved through an understanding of soil P dynamics in relation to management practices in a cropping system. Our objectives in this study were to evaluate changes in plant-available (Olsen) P and in different inorganic P (Pi) and organic P (P0) fractions in soil as related to repeated additions of manure and fertilizer P under a soybean-wheat rotation. A field experiment on a Typic Haplustert was conducted from 1992 to 1995 wherein the annual treatments included four rates of fertilizer P (0, 11, 22 and 44 kg ha–1 applied to both soybean and wheat) in the absence and presence of 16 t ha–1 of manure (applied to soybean only). With regular application of fertilizer P to each crop the level of Olsen P increased significantly and linearly through the years in both manured and unmanured plots. The mean P balance required to raise Olsen P by 1 mg kg–1 was 17.9 kg ha–1 of fertilizer P in unmanured plots and 5.6 kg ha–1 of manure plus fertilizer P in manured plots. The relative sizes of labile [NaHCO3-extractable Pi (NaHCO3-Pi) and NaHCO3-extractable P0 (NaHCO3-P0)], moderately labile [NaOH-extractable Pi (NaOH-Pi) and NaOH-extractable P0 (NaOH-P0)] and stable [HCl-extractable P (HCl-P) and H2SO4/H2O2-extractable P (resisual-P)] P pools were in a 1 : 2.9 : 7.6 ratio. Application of fertilizer P and manure significantly increased NaHCO3-Pi and -P0 and NaOH-Pi, and -P0 fractions and also total P. However, HCl-P and residual-P were not affected. The changes in NaHCO3-Pi, NaOH-Pi and NaOH-P0 fractions were significantly correlated with the apparent P balance and were thought to represent biologically dynamic soil P and act as major sources and sinks of plant-available P.
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    Physical processes in an Indian Ocean atoll (1998)
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    Coral reefs 17 (1998), S. 155-168 
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    ISSN: 1432-0975
    Keywords: Key words Atoll hydrodynamics ; Lagoon ciculation ; Wave transformation ; Currents ; Physical processes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract  Detailed measurements of water levels, and tide and wave-induced currents were undertaken to examine physical processes and their relationship with morphology in the Cocos (Keeling) Islands, a medium sized atoll in the Indian Ocean. Results indicate that the atoll structure controls both lagoon circulation and the spatial pattern of energy distribution. Lagoon circulation is tide dominated (currents 16–31 cms-1) with flushing (2–5 days) of the lagoon occurring through the deep leeward passages. Wave- and tide-driven unidirectional flows through shallow passages (26–65 cms-1) are important mechanisms of ocean to lagoon water exchange and contribute up to 24% of the lagoon neap tide prism. Reef flats are dominated by wave energy (maximum velocity 140 cms-1, east) with measurements of the attenuation of wave energy between reef flats and shallow lagoon (80–90%) conforming to measurements from fringing and barrier reefs. Spectral analysis shows that the characteristics of wave energy vary on different sectors of the atoll, with gravity wave energy dominating the east, and infragravity wave energy dominating the southern reef flat and passages. Wave setup at the reef crest is considered to be responsible for an identified 0.1 m higher water level in the southern as opposed to eastern and northern atoll, which promotes higher reef flat growth. Transmission of gravity waves across reef flats requires threshold water depths of 0.65 (east) and 0.70 m (south). The higher southern reef is an effective filter of gravity wave energy for most tidal elevations. Differences in the type and magnitude of physical processes within the atoll are discussed with relation to geomorphic development on Cocos.
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    Determination of P/Al ratio in phosphorus-doped aluminium oxide thin films by XRF, RBS and FTIR (1995)
    Springer
    Microchimica acta 119 (1995), S. 13-22 
    Details
    ISSN: 1436-5073
    Keywords: aluminium oxide ; phosphorus ; XRF ; RBS ; FTIR
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Phosphorus-doped aluminium oxide thin films were deposited in a flow-type ALE reactor from AlCl3, H2O and from either P2O5 or trimethyl-phosphate. Structural information of the films was obtained from Fourier transform infrared (FTIR) spectra. Rutherford backscattering spectroscopy (RBS) was used to quantitatively determine the composition of the films. The P/Al intensity ratios calculated from X-ray fluorescence (XRF) results were in a linear relation with the P/Al concentration ratios calculated from RBS results. For comparison, the intensity ratios of the phosphorus peak (P=O) at about 1250 cm−1 and the aluminium peak (Al-O) at about 950 cm−1 were determined from the IR absorption spectra. The calibration of FTIR peak intensities was done by plotting the intensity ratios of phosphorus and aluminium peaks against the P/Al concentration ratios measured by RBS. FTIR gave also a linear calibration curve with RBS but the method is less suitable for routine analysis of P/Al ratio than XRF.
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    Determination of phosphorus, sulfur and chlorine in high-purity aluminium (1990)
    Springer
    Microchimica acta 101 (1990), S. 273-279 
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    ISSN: 1436-5073
    Keywords: aluminium analysis ; phosphorus ; sulfur ; chlorine
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Multi-step procedures for the determination of phosphorus, sulfur and chlorine are described and tested against established methods and on reference materials. Phosphorus is separated as hydrogen phosphide, extracted as phosphomolybdic acid, reduced to molydenum blue and measured photometrically (detection limit 0.05 μg/g). Sulfur is separated after reduction as hydrogen sulfide or by means of pyrohydrolysis and measured by ICP-OES (detection limit 0.1 μg/g). Chloride can be measured by ion chromatography after pyrohydrolytic separation (detection limit 0.1 μg/g). The determination of sulfur was also successfully tested on copper and steel samples.
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    Extraction inductively coupled plasma-optical emission spectrometry (ICP-OES) determination of traces of phosphorus in tungsten (1989)
    Springer
    Microchimica acta 99 (1989), S. 399-412 
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    ISSN: 1436-5073
    Keywords: phosphorus ; tungsten ; preconcentration ; ICP-OES
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A method for the separation and preconcentration of traces of phosphorus from tungsten was developed. Solid phase extraction of the phosphovanadomolybdate complex performed on a micro-column was applied. Phosphorus was determined by optical emission spectroscopy (OES) with inductively coupled plasma (ICP) excitation. A limit of detection of 0.4 μg/g P with respect to the solid phase is obtained. By directly coupling the extraction/elution step to the ICP instrument a detection limit of 0.06 μg/g P in W was achieved. Besides, the complexity of spectral evaluation in ICP-OES determinations of traces in spectralline-rich matrices is discussed.
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    Elemental analysis of organic phosphorus compounds X. Schöniger-flask method for phosphorus (1986)
    Springer
    Microchimica acta 88 (1986), S. 245-247 
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    ISSN: 1436-5073
    Keywords: Schöniger-flask method ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract By use of a fused-silica hook for holding the sample packet in a Schöniger combustion flask, even difficultly combustible phosphorus compounds can be completely decomposed.
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    The determination of phosphonate base scale inhibitors in brines by plasma spectrometry (1992)
    Springer
    Microchimica acta 109 (1992), S. 201-209 
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    ISSN: 1436-5073
    Keywords: phosphonate base scale inhibitor ; brine ; direct current plasma ; inductively coupled plasma atomic emission spectrometry ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The determination of phosphonate base scale inhibitors in brines by direct current plasma (DCP) and inductively coupled plasma atomic emission spectrometry (ICP-AES) is described. The first method is based on a direct nebulization of the brine samples and plasma using the phosphorus line at 213.618 nm. The second method involves extraction of phosphorus as phospho-antimonyl molybdate complex into methylisobutyl ketone (MIBK) phase and analysis of the extract for molybdenum using the Mo 313.260 nm line. Comparison between the proposed methods and an established recommended method [1] shows excellent agreement between the results in addition to the sensitivity and ease of automation provided by AES.
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    Historical changes in sediments of Pyramid Lake, Nevada, USA: consequences of changes in the water balance of a terminal desert lake (1994)
    Springer
    Journal of paleolimnology 12 (1994), S. 87-101 
    Details
    ISSN: 1573-0417
    Keywords: Great Basin ; climatic variations ; productivity ; organic matter ; nitrogen ; phosphorus ; hardwater lake
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Sediment cores from the shallow and deep basins of Pyramid Lake, Nevada, revealed variations in composition with depth reflecting changes in lake level, river inflow, and lake productivity. Recent sediments from the period of historical record indicate: (1) CaCO3 and organic content of sediment in the shallow basin decrease at lower lake level, (2) CaCO3 content of deep basin sediments increases when lake level decreases rapidly, and (3) the inorganic P content of sediments increases with decreasing lake volume. Variations in sediment composition also indicate several periods for which productivity in Pyramid Lake may have been elevated over the past 1000 years. Our data provide strong evidence for increased productivity during the first half of the 20th Century, although the typical pattern for cultural eutrophication was not observed. The organic content of sediments also suggests periods of increased productivity in the lake prior to the discovery and development of the region by white settlers. Indeed, a broad peak in organic fractions during the 1800's originates as an increase starting around 1600. However, periods of changing organic content of sediments also correspond to periods when inflow to the lake was probably at extremes (e.g. drought or flood) indicating that fluctuations in river inflow may be an important factor affecting sediment composition in Pyramid Lake.
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    An expanded weighted-averaging model for inferring past total phosphorus concentrations from diatom assemblages in eutrophic British Columbia (Canada) lakes (1995)
    Springer
    Journal of paleolimnology 14 (1995), S. 49-67 
    Details
    ISSN: 1573-0417
    Keywords: diatoms ; eutrophication ; lake management ; paleolimnology ; British Columbia ; lakes ; phosphorus ; training sets
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Eighteen lakes were added to a published training set of 46 British Columbia (BC) lakes in order to expand the original range of total phosphorus (TP) concentrations. Canonical correspondence analysis (CCA) was used to analyze the relationship between diatom assemblages and environmental variables. Specific conductivity and [TP] each explained significant (P≤0.05) directions of variance in the distribution of the diatoms. The relationship between diatom assemblages and [TP] was sufficiently strong to warrant the development of a weighted-averaging (WA) regression and calibration model that can be used to infer past trophic status from fossil diatom assemblages. The relationship between observed and inferred [TP] was not improved by the addition of more eutrophic lakes, however the [TP] range and the number of taxa used in the transfer function are now superior to the original model. Diatom species assemblages changed very little in lakes with TP concentrations greater than 85 µg 1−1, so we document the development of a model containing lakes with TP≤85 µg 1−1. The updated model uses 59 training lakes and covers a range of species optima from 6 to 41.9 µg 1−1 TP, and a total of 150 diatom taxa. The updated inference model provided a more realistic reconstruction of the anthropogenic history of a highly eutrophic BC lake. The model can now be used to infer past nutrient conditions in other BC lakes in order to assess changes in trophic status.
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    Variability of diatom-inferred phosphorus profiles in a small lake basin and its implications for histories of lake eutrophication (1998)
    Springer
    Journal of paleolimnology 20 (1998), S. 47-55 
    Details
    ISSN: 1573-0417
    Keywords: diatoms ; spatial variability ; canonical correspondence analysis ; lake eutrophication ; transfer functions ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Diatom analyses were undertaken of sediment cores covering a range of water depths in a small eutrophic lake (Lough Augher, Co. Tyrone, N. Ireland). The significance of between-core variability in diatom relative frequency stratigraphy was assessed by Canonical Correspondence Analysis (CCA) where the ordination axes were constrained to external environmental variables (sediment depth, core location coordinates, water depth, effective fetch, distance-from-shore and distance-from-inflow). After the removal of the effect of sediment age by partialling it out, the resultant first two axes from the partial-CCA were significantly correlated with water depth and distance-from-shore, indicating non-uniform diatom stratigraphies across the lake. Despite this variability, all cores show the same succession of species and, therefore, record the eutrophication of the lake. Diatom-inferred total phosphorus (DI-TP) was inferred for six cores using weighted averaging regression and calibration. Apart from considerable differences of DI-TP in surficial sediment samples, there was good between-core repeatability of DI-TP profiles. These data support the use of DI-TP for establishing background nutrient concentrations for lakes, and associated implications for lake restoration schemes using single cores. Comparisons of DI-TP profiles and total diatom accumulation rate data for the individual cores indicate that diatom production peaked prior to the maximum TP concentrations in the lake.
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    Stable isotope (δ13C and δ15N) signatures of sedimented organic matter as indicators of historic lake trophic state (1999)
    Springer
    Journal of paleolimnology 22 (1999), S. 205-221 
    Details
    ISSN: 1573-0417
    Keywords: carbon isotopes ; diatoms ; lake management ; nitrogen isotopes ; phosphorus ; radium-226 ; sediments ; trophic state
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract We explored the use of carbon and nitrogen isotopes (δ13C and δ15N) in sedimented organic matter (OM) as proxy indicators of trophic state change in Florida lakes. Stable isotope data from four 210Pb-dated sediment cores were compared stratigraphically with established proxies for historical trophic state (diatom-inferred limnetic total phosphorus, sediment C/N ratio) and indicators of cultural disturbance (sediment total P and 226Ra activity). Diatom-based limnetic total P inferences indicate a transition from oligo-mesotrophy to meso-eutrophy in Clear Lake, and from eutrophy to hypereutrophy in Lakes Parker, Hollingsworth and Griffin. In cores from all four lakes, the carbon isotopic signature of accumulated OM generally tracks trophic state inferences and cultural impact assessments based on other variables. Oldest sediments in the records yield lower diatom-inferred total limnetic P concentrations and display relatively low δ13C values. In the Clear, Hollingsworth and Parker records, diatom-inferred nutrient concentrations increase after ca. AD 1900, and are associated stratigraphically with higher δ13C values in sediment OM. In the Lake Griffin core, both proxies display slight increases before ~1900, but highest values occur over the last ~100 years. As Lakes Clear, Hollingsworth and Parker became increasingly nutrient-enriched over the past century, the δ15N of sedimented organic matter decreased. This reflects, in part, the increasing relative contribution of nitrogen-fixing cyanobacteria to sedimented organic matter as primary productivity increased in these waterbodies. The Lake Griffin core displays a narrow range of both δ13C and δ15N values. Despite the complexity of carbon and nitrogen cycles in lakes, stratigraphic agreement between diatom-inferred changes in limnetic total P and the stable isotope signatures of sedimented OM suggests that δ13C and δ15N reflect shifts in historic lake trophic state.
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    URL: http://dx.doi.org/10.1023/A:1008078222806
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    Calibration of diatoms along a nutrient gradient in Florida Everglades Water Conservation Area-2A, USA (1999)
    Springer
    Journal of paleolimnology 22 (1999), S. 413-437 
    Details
    ISSN: 1573-0417
    Keywords: diatoms ; Everglades ; phosphorus ; wetland ; calibration ; multivariate ; Florida
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract The relationship between diatom taxa preserved in surface soils and environmental variables at 31 sites in Water Conservation Area 2A (WCA-2A) of the Florida Everglades was explored using multivariate analyses. Surface soils were collected along a phosphorus (P) gradient and analyzed for diatoms, total P, % nitrogen (N), %carbon (C), calcium (Ca), and biogenic silica (BSi). Phosphorus varied from 315-1781 μg g-1, and was not found to be correlated with the other geochemical variables. Canonical correspondence analysis (CCA) was used to examine which environmental variables correlated most closely with the distributions in diatom taxa. Canonical correspondence analysis with forward selection, constrained and partial CCA, and Monte Carlo permutation tests of significance show the most significant changes in diatom assemblages along the P gradient (p 〈 0.01), with additional species differences correlated with soil C, N, Ca, and BSi. Weighted-averaging (WA) regression and calibration models of diatom assemblages to P and BSi were developed. The diatom-based inference model for soil [P] had a high apparent r2 (0.86) with RMSEboot = 218 μg g-1. Indicator diatom species identified by assessing species WA optima and WA tolerance to [P], such as Nitzschia amphibia and N. palea for high [P] (~1300-1400 μ g-1) and Achnanthes minutissima var. scotica and Mastogloia smithii for low [P] (~400-600 μg g-1), may be useful as monitoring tools for eutrophication in WCA-2A as well as other areas of the Everglades. Diatom assemblages analyzed by cluster analysis were related to location within WCA-2A, and dominant taxa within clusters are discussed in relation to the geochemical variables measured as well as hydrology and pH. Diversity of diatom assemblages and a ‘Disturbance Index’ based on diatom data are discussed in relation to the historically P-limited Everglades ecosystem. Diatom assemblages should be very useful for reconstructions of [P] through time in the Florida Everglades, provided diatoms are well preserved in soil cores.
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    URL: http://dx.doi.org/10.1023/A:1008049224045
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    Modern and historic accumulation rates of phosphorus in Lake Okeechobee, Florida (1998)
    Springer
    Journal of paleolimnology 20 (1998), S. 31-46 
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    ISSN: 1573-0417
    Keywords: phosphorus ; Lake Okeechobee ; lead-210 dating ; eutrophication ; phosphorus loading
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Phosphorus accumulation rates in depositional zone sediments of Lake Okeechobee were determined in 11 mud-zone cores and two peat-zone cores dated by 210Pb. Although difficulties were encountered in interpreting 210Pb data from some sites, reliable dating of sediments from the mud zone of this shallow lake is possible. Sediment accumulation rates in this zone have increased during the present century by an average of about twofold, and accumulation of organic sediments in the lake during pre-settlement times apparently was much slower than during the past century. Concentrations of all forms of sedimentary P but especially nonapatite inorganic-P and organic-P also have increased since pre-settlement times and especially since about 1940. Annual P accumulation rates in the lake's sediments have increased about fourfold during the 1900s, with most of the increase occurring in the past 40–50 years. The recent accumulation rate of sedimentary P (past ~ 10 years) agrees within a factor of 1.5 with the net retention of P in the lake calculated from published input-output mass balances.
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    URL: http://dx.doi.org/10.1023/A:1007939714301
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    Fertilizer regime and changes in the phosphate and potash status of a silty marine clay soil during 25 years (1980)
    Springer
    Nutrient cycling in agroecosystems 1 (1980), S. 95-101 
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    ISSN: 1573-0867
    Keywords: soil fertility ; phosphorus ; potassium ; green manure ; crop rotation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Changes in the soil phosphorus and potassium status on three farming systems in the Northeast Polder during 25 years are related to the fertilizer regime over this period. The changes in the nutrient status of the soil are reflected in fertilizer policy. High rates of phosphate dressings markedly increased the phosphate status of the soil and built up a reserve of phosphate. In contrast, the potassium status decreased by about half, because only potatoes in the rotation were dressed with potassium. Methods of fertilization are discussed and suggestions are made with regard to possible improvements.
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    URL: http://dx.doi.org/10.1007/BF01073181
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    The variation of element contents in triticale during vegetative growth (1987)
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    Nutrient cycling in agroecosystems 13 (1987), S. 155-159 
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    ISSN: 1573-0867
    Keywords: triticale ; contents of nitrogen ; phosphorus ; potassium ; calcium ; magnesium ; trace elements ; heavy metals ; stage of growth
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Description / Table of Contents: Zusammenfassung Es wurden die Schwankungen in den Konzentration von N, P, K, Ca, Mg, Fe, Mn, Zn, Cu, B, Ba, Be, Bi, Sn, Sr, Sb, Ti, Te, V, Se, As und Hg in Triticale unter Feldbedingungen untersucht. Von der Bestockung bis zur Vollreife wurden alle 10 Tage von je 0.5 m2 pro Parzelle Pflanzenproben genommen. In allgemeinen haben die Konzentrationen von Frühjar bis zur Ernte abgenommen. Der elementengehalt in Triticale war demjenigen der übrigen Getreidearten verschieden, aber der Trend der Änderungen war ähnlich.
    Notes: Abstract The variation of N, P, K, Ca, Mg, Fe, Mn, Zn, Cu, B, Ba, Be, Bi, Sn, Sr, Sb, Ti, Te, V, Se, As and Hg concentrations was studied under field conditions in triticale. The samples were collected every 10 days from tillering to full ripening stage using plant material from 0.5 m2 per plot. The concentrations generally decreased from early growth to harvest. The elemental concentrations in triticale differed from the other cereals, but the variation's trend was similar.
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    Effect of nitrogen, phosphorus and soil and crop residues management practices on maize (Zea mays L.) yield in ultisol of eastern Cameroon (1987)
    Springer
    Nutrient cycling in agroecosystems 14 (1987), S. 135-142 
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    ISSN: 1573-0867
    Keywords: nitrogen ; phosphorus ; soil and crop residues management practices ; maize yield ; Plinthudult ; Cameroon
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The shortening of fallow period in several areas in tropical Africa has reduced soil fertility and exposed soils to erosion and run-off. Fertilizer application and crop conservation practices are needeed to sustain high crop yield and to conserve the natural resource base for upland crop production in the continent. Field trials were carried out to evaluate the effect of fertilizer application and soil and crop residues management practices on yield of maize (Zea mays L.) planted on a Plinthudult soil at Bertoua, Eastern Cameroon. Maize yields increased significantly with nitrogen and phosphorus fertilizer application. Under the rainfall pattern prevailing in the area, the amount of nitrogen required for maximum yield was higher in the second season. On the other hand, the amount of phosphorus required for maximum yield appeared to decrease with time. The burning of crop residues and weeds prior to planting together with no-till practive gave higher yield of maize than other soil and crop residues management practices.
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    Africa — how much fertilizer needed: Case study of Sierra Leone (1988)
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    Nutrient cycling in agroecosystems 17 (1988), S. 101-118 
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    ISSN: 1573-0867
    Keywords: Nitrogen ; phosphorus ; potassium ; organic matter ; fallow ; forecasting ; fertilizer requirement ; Sierra Leone
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The quantities of nitrogen, phosphorus and potassium supplied by an ‘average’ African soil cleared from bush fallow, assuming no losses, were approximated. Values ranged from 23 to 120 Kg N ha−1, 1.8 to 12 Kg P ha−1, 47 to 187 Kg K ha−1, depending on type of fallow, length of fallow, drainage and extent of depletion of native supplies. Additional amounts of 4 to 5 Kg N ha−1, 4 to 6 Kg P ha−1 and 14 to 20 Kg K ha−1 are obtained from the ash. Using crop nutrient removal data and approximate efficiencies of native and fertilizer N, P and K, fertilizer requirements at the reconnaissance level were estimated for selected target yields. For newly cleared uplands at cropping/fallow ratio of 2:7, N fertilizer requirements for cassava (30 t ha−1), maize (4 t ha−1), and sweet potato (16 t ha−1), were 138, 98, 42 kg ha−1 respectively. Wetland rice (4 t ha−1) required 55 kg N ha−1. Corresponding P fertilizer requirements for cassava, maize, sweet potato, upland rice (1.5 t ha−1) and ground-nut (1 t ha−1) were 190, 80, 30, 30 and 16 kg P ha−1 respectively. Wetland rice required 83 kg P ha−1. Substantial residual values of applied P are to be expected. Cassava required 60 kg ha−1 of K on newly cleared land. In soils of lowered nutrient status higher N, P, and K fertilizer requirements were indicated for all crops. Land use data from Sierra Leone were used to illustrate how the total quantities of N, P and K fertilizers in a country in the forest zone of Africa can be approximated. Fertilizer needs in Sierra Leone were in decreasing order P 〉 N ≫ K. N, P and K requirements were estimated to be 10,000 t, 20,000 t and 4,000 t respectively. The nutrient balance sheet method described in this paper is a useful tool to estimate the order of magnitude of fertilizer requirement at selected target yields for countries in Africa.
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    URL: http://dx.doi.org/10.1007/BF01050271
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    Fertilizer requirement of rice-wheat and maize-wheat rotations on coarse-textured soils amended with farmyard manure (1988)
    Springer
    Nutrient cycling in agroecosystems 17 (1988), S. 153-164 
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    ISSN: 1573-0867
    Keywords: farmyard manure ; maize ; nitrogen ; phosphorus ; rice ; wheat
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Field experiments with rice-wheat rotation were conducted during five consecutive years on a coarse-textured low organic matter soil. By amending the soil with 12t FYM ha−1, the yield of wetland rice in the absence of fertilizers was increased by 32 per cent. Application of 80 kg N ha−1 as urea could increase the grain yield of rice equivalent to 120 kg N ha−1 on the unamended soil. Although the soil under test was low in Olsen's P, rice did not respond to the application of phosphorus on both amended and unamended soils. For producing equivalent grain yield, fertilizer requirement of maize grown on soils amended with 6 and 12 t FYM ha−1 could be reduced, respectively to 50 and 25 per cent of the dose recommended for unamended soil (120 kg N + 26.2 kg P + 25 kg K ha−1). Grain yield of wheat grown after rice on soils amended with FYM was significantly higher than that obtained on unamended soil. In contrast, grain yield of wheat which followed maize did not differ significantly on amended or unamended soils.
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    Phosphorus management of a rice-wheat cropping system (1989)
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    Nutrient cycling in agroecosystems 20 (1989), S. 27-32 
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    ISSN: 1573-0867
    Keywords: Cropping system ; phosphorus ; rice ; wheat
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A long term field experiment was conducted on a sandy loam soil from 1983 to 1987 to determine how to best apply phosphorus fertilizer in a rice-wheat cropping system. The treatments included 9 combinations of phosphorus application either to both rice and wheat or to rice or wheat alone. Direct application of phosphorus at 13 kg/ha to both the crops resulted in significantly higher total productivity of the rice-wheat cropping system as compared with 26 kg P/ha applied either to rice or wheat alone. Phosphorus at 13 kg/ha for rice and 26 kg/ha for wheat was as efficient as 13 kg P/ha for rice and 13 kg P/ha for wheat. The higher rate of P (26 kg/ha) applied to both rice and wheat resulted a decline in the total productivity. The residual effects of phosphorus applied to either rice or wheat were significant to the succeeding crop but was inferior to its direct application. Phosphorus increased the leaf area index, chlorophyll content of leaves, and interception of more photosynthetically active radiation (PAR) which resulted in increased grain yield of rice and wheat. Phosphorus status of the surface soil declined markedly, in the absence of P application from 15.4 to 6.4 kg P/ha. Phosphorus applied at 26 kg P/ha to both the crops resulted a build up of the available P status of soil. Phosphorus application at 13 kg/ha to both rice and wheat maintained the phosphorus status of the soil at original level.
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    Hydrology of the Peel-Harvey estuary catchment (1993)
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    Nutrient cycling in agroecosystems 36 (1993), S. 127-133 
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    ISSN: 1573-0867
    Keywords: hydrology ; water balance ; phosphorus ; Streamflow ; Peel-Harvey
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract This paper discusses the land types, hydrologic characteristics and processes, and the major modification of these, in relation to mechanisms and magnitude of phosphorus losses to drains and riverine systems which discharge to the Peel-Harvey estuary. About 75% of the coastal plain part of the catchment is cleared of native vegetation and used for dryland, dairy and beef grazing. There are small areas devoted to irrigated pasture and commercial horticulture. Seventy-five percent of the soils of the catchment are sandy surfaced with a poor capacity to retain phosphorus. Though the area is flat, catchment water yields are high because of a large winter rainfall excess and low soil storage capacity. Drainage schemes have been constructed in much of the catchment to remove excess water quickly. This was required initially to allow agricultural expansion and is now important for protecting a growing infrastructure which serves the most populous region of Western Australia.
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    Phosphorus and mycorrhizal interaction on uptake of P and trace elements by maize (1989)
    Springer
    Nutrient cycling in agroecosystems 21 (1989), S. 19-22 
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    ISSN: 1573-0867
    Keywords: VAM fungi ; phosphorus ; molybdenum ; interaction ; maize
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Vesicular arbuscular mycorrhizal fungi (VAM) when applied to soils can result in marked increases in plant growth and P uptake. Application of molybdenum can also result in a synergistic interaction with phosphorus, with reslutant increases in plant dry matter production. The current investigation was designed to evaluate P X Mo X VAM interactions on yield and P uptake of sweet corn (Zea mays L.) The experiment was conducted in the greenhouse using soils from Missouri and Jamaica (West Indies) which were very low in available soil P. Corn was grown in pots amended with P and VAM, with and without Mo. Colonizing Jamaican soil amended with P withGlomus etunicatum increased shoot dry matter weights significantly. Greatest P uptake occured in treatments receiving the highest application of P and mycorrhizal inoculation. There was a significant difference between the two soils with respect to treatment effects on micronutrient accumulation of the test crop. The decreases in Cu, Zn, Mn, and Mo concentration of corn leaves between control and the treated pots, is attributed to dry matter dilution effect. The results indicated that mycorrhizal inoculation increased the dry matter significantly in Jamaican soil amended with P, however not in Missouri soil.
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    URL: http://dx.doi.org/10.1007/BF01054731
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    Environmental impact of fertilizing soils by using sewage and animal wastes (1994)
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    Nutrient cycling in agroecosystems 37 (1994), S. 1-22 
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    ISSN: 1573-0867
    Keywords: animal slurries and manures ; applications to soils ; carbon- ; nitrogen- ; phosphorus ; contamination ; crop production ; dissemination ; hazardous organics ; heavy metals ; inputs ; macro- and micronutrients ; pathogens ; sewage sludges ; survival- ; transfer- ; transport and adsorption rates in soils
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The European Community is producing annually about 300 × 106 tons of sewage sludges as well as about 150, 950,160 and 200 tons of domestic, agricultural, industrial and other wastes (street litter, dead leaves etc.). About 20–25% of the German sewage sludges, which contain in average about 3.8,1.6, 0.4, 0.6, 5.3% DM−1 N, P, K, Mg and Ca, 202, 5, 131, 349, 53, 3 and 1446 mg kg−1 DM Pb, Cd, Cr, Cu, Ni, Hg, Zn as well as ca. 37 and 5 mg kg−1 Dm polychlorinated hydrocarbons and biphenyls, are recycled annually as fertilizer. In addition environmental impacts on the arable land of Germany may derive from 76,19.2, 64.7, 33.6, 7.8 and 0.1 kg ha−1 a−1 of N, P, K, Ca, Mg and Cu added as animal manures. Besides heavy metals and hazardous organics pathogens are disseminated with organic wastes. Crop production and soil fertility generally profit from the considerable amounts of plant nutrients and carbon in sewage sludges, animal slurries and manures, but the physicochemical soil properties, the composition of microbial, faunal and plant communities as well as the metabolic processes in the soil-, rhizo- and phyllosphere are changed by organic manuring. Consequences for the soil carbon-, nitrogen-and phosphorus-cycle are discussed. Impacts of heavy metals and hazardous organics on the soil biomass and its habitat as well as on transport mechanisms and surival times of disseminated pathogens in soils are reviewed with emphasis on the German situation. A proposal for future strategies (landscape recycling) is made.
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    Results and experiences from fertilization experiments in The Netherlands (1991)
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    Nutrient cycling in agroecosystems 27 (1991), S. 107-111 
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    ISSN: 1573-0867
    Keywords: Liming ; phosphorus ; heathland ; copper ; fertilization ; forest
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Forest fertilization in the Netherlands has played an important role in the phase of afforestation of former heathlands. Research started in the early fifties, but results were not applied in practical forestry. A review is presented on forest fertilization in practice, and on the main results of the activities of De Dorschkamp on NPK fertilization, liming and micronutrients application. Attention is paid to problems which have developed during the past ten years.
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    URL: http://dx.doi.org/10.1007/BF01048613
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    Share of agriculture in nitrogen and phosphorus emissions into the surface waters of Western Europe against the background of their eutrophication (1990)
    Springer
    Nutrient cycling in agroecosystems 26 (1990), S. 253-269 
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    ISSN: 1573-0867
    Keywords: Nitrogen ; phosphorus ; sulphur ; nutrient balances ; surface waters ; North Sea ; Baltic Sea ; eutrophication ; hypertrophication ; primary production
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Dissolved inorganic nitrogen and phosphorus, their relationship to each other (DIN/DIP) as predisposing (nutrient) factors, as well as prevailing weather as a triggering factor all work together to induce the primary production and hence the eutrophication (hypertrophication) process in surface waters. Sulfate likewise is a decisive predisposing factor influencing the eutrophication process by reducing N availability but increasing P availability and thus acting towards an N limitation of the primary production. This is one of the reasons why marine (coastal) waters and estuaries often exhibit N limitation with respect to primary production, while freshwater ecosystems often tend to exhibit P limitation. Within the N and P balance of agriculture of some countries of Western Europe (Netherlands, Denmark, Switzerland, FRG, UK and Sweden for N, resp. Netherlands, FRG and GDR for P) more the level than the efficiency of the N and P applications indicates the extent of the nutrient surplus. Despite 59–73% N utilization in plant production, the rate of 13–23% for agriculture as a whole equals to the 12–21% efficiency of N use in animal production. The varying N surplus in agriculture in the separate countries of 124 to 465 kg N ha−1 a−1 is determined almost exclusively by the level of the N application and not by its efficiency. The situation is similar for P: In spite of P utilization in plant production of 59–76%, P utilization in total agriculture is only 11–38%, or comparable to the P efficiency within animal production of 10–34%. The differing P excess balance of 55 to 88 kg P2O5 ha−1 a−1 is influenced by the level of the P application. The N and P efficacy of total agriculture hence is determined almost completely by that of animal production, since 83–95% (N basis) and 76–94% (P basis) of the total plant production (on top of the nationally varying levels of N and P use via imported feeds) are fed to animals — with the low N and P utilization cited above. Agriculture's share of the N and P emissions into surface water of several countries/regions in Western Europe (FRG, Netherlands, Italy, Denmark, Switzerland, Norway) ranges from 37 to 82% resp. 27 to 38%. Its share in the flus into the North Sea catchment basin will be about 60% for N and 25% for P related only to the anthropogenic material carried by the rivers. Agriculture's share in the atmospheric N emissions into the North and Baltic Seas can be estimated at about 65% or 55%, resp. while the remaining approx. 35% or 45%, resp. are traceable primarily to anthropogenic burning processes. For agriculture the priority lies in limiting N emissions into surface water caused by leaching, erosion and NH3 emissions, and reducing P emissions mainly through soil conservation (protection against erosion) and water protection. As regards N this means a demand for comprehensive protection of groundwater and atmosphere differentiated according to the potential for losses or the risk of losses on a site, also outside the protection zones. As regards P only those areas can be included in the demand for reduction of emissions that are actually threatened by erosion or surface runoff. Plenty of short-term and long-term measures are available to agriculture to reduce N and P emissions. Especially the long-range measures (such as creating nutrient balances on farms and fields, the integration of animal and plant production, maintaining maximum livestock densities according to the ability of areas to absorb nutrients, altered feeding programs in animal nutrition, changes in livestock keeping (slurry→deep litter), increasing the internal and external recycling of N and P) are capable of bringing about a satisfactory degree of success within the next 20 to 30 years.
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    Land application of poultry litter and water quality in Oklahoma, U.S.A. (1994)
    Springer
    Nutrient cycling in agroecosystems 40 (1994), S. 165-173 
    Details
    ISSN: 1573-0867
    Keywords: Animal manure ; eutrophication ; ground water ; nitrogen ; phosphorus ; surface runoff
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract With the rapid growth of the poultry industry in Oklahoma, U.S.A., more litter is applied to farm land. Thus, information is required on the impact of applications on regional soil and water resources. The effect of soil and poultry litter management on nitrogen (N) and phosphorus (P) loss in runoff and subsurface flow from four 16 m2 plots (Ruston fine sandy loam, 6 to 8% slope) was investigated under natural rainfall. Plots under Bermudagrass (Cynodon dactylon) received 11 Mg litter ha−1, which amounts to contributions of approximately 410 kg N and 140 kg P ha−1 yr−1. In spring, litter was broadcast on 3 of the plots; the upper half of one and total area of the other two. One of the total-area broadcast plots was tilled to 6 cm, the other remained as no till. The fourth plot served as a control. Relative to the control, litter application increased mean concentrations of total N and total P in runoff during the 16-week study for no-till (15.4 and 5.8 mg L−1) and tilled treatments (16.7 and 6.1 mg L−1). However, values for the half-area application (5.6 and 2.0 mg L−1) were similar to the control (5.7 and 1.3 mg L−1). Interflow (subsurface lateral flow at 70 cm depth) P was not affected by litter application; however, nitrate-N concentrations increased from 0.6 (control) to 2.9 mg L−1 (no till). In all cases, 〈 2 % litter N and P was lost in runoff and interflow, maintaining acceptable water quality concentrations. Although litter increased grass yield (8518 kg ha−1) compared to the control (3501 kg ha−1), yields were not affected by litter management. An 8-fold increase in the plant available P content of surface soil indicates long-term litter management and application rates will be critical to the environmentally sound use of this nutrient resource.
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    Future directions for agricultural phosphorus research (1995)
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    Nutrient cycling in agroecosystems 41 (1995), S. 167-178 
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    ISSN: 1573-0867
    Keywords: phosphorus ; workshop ; environment ; review
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A workshop was held in 1990 in Muscle Shoals, Alabama to discuss current and future research on phosphorus in agriculture. Twenty four presentations were given in areas ranging from basic to applied research. For five of the research areas presented at the workshop, this paper presents a literature review, a review of presentations at the workshop, and a discussion of future research ideas.
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    Coordinated phosphorus research within a network of six European institutions (1995)
    Springer
    Nutrient cycling in agroecosystems 43 (1995), S. 109-115 
    Details
    ISSN: 1573-0867
    Keywords: phosphorus ; European network ; maintenance fertilization ; fixation capacity ; comparison of methods
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract After three years of a research network project on mineral phosphorus fertilization including five experimental fields located in Europe the first results are discussed. Crop response was very significant to TSP application in the alluvial calcareous polder soil of Netherlands, and in the brown silty acid soil of Scotland, both having a low level of P availability and a high fixation capacity. In the alluvial sandy loam on chalk in England, a response was observed to the first fertilization level equal to the previous crop export of phosphorus. In the brown sandy-silty soil on sand in Germany the highest rate of TSP led to a response in the third year. No effect on the final yields was observed in the brown silt loam of Belgium characterised by a textural B horizon with a high P fixation capacity. The critical values for phosphorus fertilization are discussed as the amount of P needed to maintain a target value of soil phosphorus. Concerning the supply of the different soils, no balance was reached in the Dutch and Scottish soils, a steady state was reached in the English soil with the return of the previous crop removal and the critical value for P was lower than the return of the previous crop export in the German and Belgian soils. According to the eight methods of P determination compared in the network, the P contents in the plow layer were raised in the soils of Netherlands, England and Scotland. They remained at the same level or fluctuated depending on the soil testing methods in Germany and in Belgium. High correlations exist between the different methods used in routine analysis, except for the calcium cloride and calcium acetate lactate method. Annual fluctuations in the soil P were detected at different depths depending on analytical methods and need further research.
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    URL: http://dx.doi.org/10.1007/BF00747689
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    Plant biomass and fruit yield induction by Ti(IV) in P-stressed pepper crops (1995)
    Springer
    Nutrient cycling in agroecosystems 43 (1995), S. 131-136 
    Details
    ISSN: 1573-0867
    Keywords: phosphorus ; titanium ; fertilizer efficiency ; plant nutrition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract To study the titanium effect on P nutrition, a greenhouse experiment withCapsicum annuum L., cv. Bunejo plants growing under differential P fertilization was conducted. All the plants were grown under identical conditions and they only differred in the P fertilization and in Ti supply. Plant biomass production of the Ti-untreated plants was affected by the diminution of the P-feed, but the plants growing under the lowest P supply did not showed any deficiency symptom during the crop cycle. All the Ti-treated plots showed a significative increase of the plant biomass against their corresponding untreated references. The biomass enhancement was mainly caused by the increase of the fruit yield with an absolute enhancement of 62% in the plants growing under the lowest P feed, and of 45% in the plants with a complete P support.
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    URL: http://dx.doi.org/10.1007/BF00747692
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    Phosphate enrichment in the sandy loam soils of West-Flanders, Belgium (1995)
    Springer
    Nutrient cycling in agroecosystems 43 (1995), S. 209-215 
    Details
    ISSN: 1573-0867
    Keywords: phosphorus ; saturation ; inventory ; leaching ; eutrophication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The last three decades, pig breeding has evolved towards a specialised, large scaled, land independent bio-industry in the province of West-Flanders. Subsequently, in certain regions, very high amounts of liquid pig manure are produced each year. This pig slurry is used as a fertilizer at a rate which very often exceeds normal agricultural practices. Because of the nonequilibrium between the phosphorus crop requirements and the P-inputs, phosphates accumulate in the soil. However, the phosphate sorption capacity of a soil is limited. Once the sorption capacity is exceeded, phosphates will start leaching through the soil profile. Since, during winter, in these areas, the groundwater table is situated at a depth of less than 1.0 m, phosphate breakthrough might take place. In the sandy loam soil region (± 1000 km2) of the province, an inventory of the P status of the soil was made. The region was sampled according to a regular grid with 2 km intervals. At random, some sample points were only 500 m apart. This resulted in a total of 296 samplings. In view of fertilizer recommendations, lactate extractable P of the plough layer (0-30 cm) was determined. A maximum value of 101 mg P 100 g−1 of air dry soil, a minimum value of 6 mg P 100 g−1 and a median value of 31 mg P 100 g−1 were found, indicating that for half of the spots monitored, the P status of the soil is high to very high. An oxalate extraction was done to investigate the phosphate saturation of the soil profile (0-90 cm). Based on a critical phosphate saturation degree of 30%, more than half of the soil profiles are phosphate saturated. Phosphate leaching at a rate higher than 0.1 mg ortho-P 1−1 at a depth of 90 cm can be expected. Therefore, a restriction of the P fertilization should be highly recommended. The geostatistical processing of the data using block kriging resulted in a spatial continuous estimate of the phosphate saturation degree. A good agreement was found between the pig density and the phosphate saturation degree of the soil profile.
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    URL: http://dx.doi.org/10.1007/BF00747704
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    Response of ensete (Ensete ventricosum W.) to mineral fertilizers in southwest Ethiopia (1994)
    Springer
    Nutrient cycling in agroecosystems 37 (1994), S. 107-113 
    Details
    ISSN: 1573-0867
    Keywords: Ensete ventricosum ; fertilizer response ; nitrogen ; phosphorus ; potassium ; sulphur ; starch
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Ensete (Ensete ventricosum W. Cheesm.) is a root crop which stores starch in the root and in the lower part of the stem. It is grown in the southwest of Ethiopia and due to its drought resistance, it is of outstanding importance for the supply of food to the local population. Until now virtually nothing is known about the response of Ensete to fertilizer application. Field trials carried out on three representative soils in Ethiopia showed that Ensete biomass yields were increased significantly on all three soils by nitrogen and phosphorus application. Potassium had only marginal effect on biomass growth but favourably influenced starch production. Sulfate application had no major impact on growth and starch yield. The yield response was well related to the level of available nutrients in the soil, as determined by electroultrafiltration (EUF). Leaf analysis provided preliminary evidence that optimum levels of N, P, and K may be 3.8%, 0.3%, and 4.8%, respectively.
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    URL: http://dx.doi.org/10.1007/BF00748551
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    Estimating nutrient surplus and nutrient use efficiency from farm characteristics (1995)
    Springer
    Nutrient cycling in agroecosystems 45 (1995), S. 221-233 
    Details
    ISSN: 1573-0867
    Keywords: fertilizer recovery ; modelling ; nitrogen ; nutrient efficiency ; nutrient surplus ; phosphorus ; Poland
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Research on nutrient losses from agricultural systems should try to relate these losses to farm characteristics. This was done for private farms in two districts in Poland. Using data from a farm survey, nutrient surpluses and Nutrient Use Efficiency (NUE, defined as the ratio of outgoing and incoming nutrients) were calculated for nitrogen and phosphorus. Both nutrient surplus and NUE are relatively high. A model was developed to estimate surpluses and NUE from farm characteristics like location, farm size, fertilizer application level, animal density, grass production and sugar beet or potato area. The results of the model are satisfying for nutrient surplus (R2=0.9) and nitrogen NUE (R2=0.4). Estimation of phosphorus NUE was not satisfactory. High surpluses are associated with high fertilizer applications, high animal density and high grass production while an increasing share of sugar beets leads to lower surpluses. A high nitrogen NUE is associated with low fertilizer applications, low animal density and little grass production, and with a high sugar beet area share. Results suggest that, with exception of sugar beet, fertilizer recovery in Poland is very low. Sugar beet, however, combines high fertilizer applications with low surpluses and high NUE. The outcome of the model can be used in the design of environmental policies. The paper ends with some remarks on the type of measures that can be taken, and the effects these will have on private farms in Poland.
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    URL: http://dx.doi.org/10.1007/BF00748593
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    Influence of co-granulated nutrients and granule size on plant responses to elemental sulfur in compound fertilizers (1996)
    Springer
    Nutrient cycling in agroecosystems 46 (1996), S. 81-90 
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    ISSN: 1573-0867
    Keywords: elemental sulfur ; granule size ; nitrogen ; phosphorus ; potassium ; S oxidation ; sulfur fertilizers
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Experiments were undertaken to determine the effect of granule size and nutrients in granulated compound fertilizers fortified with finely divided elemental sulfur (So) on the rate of So oxidation. In one experiment, So was banded together with or apart from triple superphosphate (TSP) while in two others, So was granulated with nutrient and inert carriers. A fourth experiment examined response to S in an So-fortified TSP from a range of granule sizes. Response and, in some cases, So recovery (using 35S labels) by test crops (maize, wheat, upland rice) was measured. In all experiments, P mixed with So increased plant growth and S recovery above treatments in which P and So were physically separated. There was however, no effect of distance of separation on S recovery. In one experiment, N as urea and N and P as diammonium phosphate (DAP) were also found to enhance response to So although to a lesser degree than P alone. These observations were attributed to a nutritional requirement of So-oxidizing microorganisms for P and N. Granulation of So with carriers also influenced oxidation rate, as inferred from the fertilizer S recovery. For a given So concentration, the effect was inversely proportional to the mean diameter of granules. It is shown that this relationship can be explained if one assumes that So particles in granules collapse into a fixed number of aggregates per granule irrespective of granule size when the soluble nutrient carrier dissolves and diffuses away from the point of application.
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    URL: http://dx.doi.org/10.1007/BF00210226
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    Fertilizer inputs, nutrient balance and soil nutrient supplying power in intensive, irrigated rice system. III. Phosphorus (1996)
    Springer
    Nutrient cycling in agroecosystems 46 (1996), S. 111-125 
    Details
    ISSN: 1573-0867
    Keywords: long-term experiments ; phosphorus ; rice ; nutrient balance ; phosphorus uptake ; fertilizer P response ; soil testing ; ion-exchange resin ; phosphorus supplying capacity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Data from long-term experiments at 11 sites in Asia with a wide range of nutrient input treatments and yield levels were used to quantify crop P requirements of rice (Oryza sativa L.) and the P balance in intensive, irrigated rice systems. Uptake of 1.8–4.2 kg P was required to produce one ton of grain yield. Physiological P use efficiency varied between 220 to 900 kg grain kg P-1. Without added P, there was a net loss of 7 to 8 kg P ha-1 per crop; with added P there was a net gain of 4 to 5 kg P ha-1 per crop. Phosphorus adsorption kinetics on mixed-bed ion-exchange resin capsules provided an integrative measure of soil P status, P diffusion, and acid-induced P solubilization. The resin capsule was a sensitive tool to characterize buildup or depletion of soil P as a result of different P balances. Both Olsen-P and the resin capsule were suitable methods to predict P uptake of tropical lowland rice. It is hypothesized that both methods measure a similar soil P pool which is soluble under alkaline, aerobic conditions but transformed into acid-soluble P froms as a result of submergence and reduction. Present recommendations for P fertilizer use on rice of 20–25 kg P ha-1 are adequate to maintain yields of 5–6 t ha-1, but sustaining higher yields of 7–8 t ha-1 will require farm-specific management strategies based on knowledge of the long-term P balance and soil P-supplying capacity.
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    URL: http://dx.doi.org/10.1007/BF00704311
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    Characterization of soil-fertilizer P reaction products and their evaluation as sources of P for gram (Cicer arietinum L.) (1996)
    Springer
    Nutrient cycling in agroecosystems 46 (1996), S. 71-79 
    Details
    ISSN: 1573-0867
    Keywords: ammonium poly-phosphate ; diammonium orthophosphate ; fertilizer reaction ; gram ; Indian soils ; phosphorus ; P uptake ; single superphosphate ; triple superphosphate ; yield
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Laboratory studies on the characterization of soil-fertilizer P reaction products were carried out by reacting three-soils occurring in a toposequence in the plateau region of Bihar (India) with saturated solutions of diammonium orthophosphate (DAP), triple superphosphate (TSP) and ammonium polyphosphate (APP) for 1 hour and 24 hours. The reaction products (precipitates) formed in the solutions after 120 days of incubation were isolated and identified through X-ray diffraction technique. Results indicate the formation of Brushite [CaHPO4 · 2H2O, Strengite (FePO4 · 2H2O), Variscite (AIPO4 · 2H2O) and Fe4(P2O7)3 as major soil-fertilizer P reaction products in these soils with ortho-and polyphosphates as source of phosphorus. Pot cultures were used to evaluate the relative efficiency of reaction products (Struvite, Brushite, Variscite and Strengite), orthophosphates (DAP and SSP) and polyphosphate (APP) as sources of P for gram (Cicer arietinum L.) in a typical acid soil. Results indicate significant response of gram to different sources and level of added P. The dry weight and P uptake at 0, 6 and 12 mg P kg-1 soil were 0.406, 0.519 and 0.609 (g pot-1); and 0.289, 0.428 and 0.575 (mg P pot-1), respectively. Among the sources , struvite proved to be superior or equally effective as APP, DAP or SSP as sources of P for gram. Uptake of P also varied significantly with different P sources and levels of P application. Strengite was least effective in enhancing yield and P uptake by the crop.
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    Comparison of resin beads and resin membranes for extracting soil phosphate (1995)
    Springer
    Nutrient cycling in agroecosystems 44 (1995), S. 1-8 
    Details
    ISSN: 1573-0867
    Keywords: aerobic incubation ; cation-anion-exchange resin ; phosphorus ; resin beads ; resin membranes ; suspension incubation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Six Portuguese soils of varying P sorption capacity were incubated aerobically at 30° C without and with added P in order to give 0.1.mg P L−1 in the soil solution. Two methods of measuring extractable P were compared: (i) mixed-bed cation-anion-resin beads in bags and (ii) a simpler method with anion-resin membrane only. The bag method extracted about twice and 1.5 times as much as the strip method, respectively, without and with added P. The relationships were much closer after one extraction for 2 hours (r = 0.982, p 〈 0.01) instead of the cumulative extraction of 24 hours (r = 0.635,p 〉 0.05.). P recovery after incubation was inversely related to some soil properties as organic matter, buffer capacity, selective dissolution Al forms (Alox and Ald) and P sorption. It is suggested that the simpler resin membrane method is more adequate to assess P for many studies of P reaction with soil. A simpler incubation method was tried, consisting of incubation as a soil suspension in water at a high temperature (50° C). The results suggested that this method gave similar results to aerobic incubation, with the advantage that there was no need to measure the required and final water contents of incubated soil.
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    URL: http://dx.doi.org/10.1007/BF00750686
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    Effects of temperature on nutrient release from slow-release fertilizers (1996)
    Springer
    Nutrient cycling in agroecosystems 46 (1996), S. 179-187 
    Details
    ISSN: 1573-0867
    Keywords: electrical conductivity ; leaching ; nitrogen ; pH ; phosphorus ; potassium ; release pattern ; slow-release fertilizers ; temperature
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract We studied the effect of temperature on the release of N, P, and K from slow-release fertilizers (SRF). The study was conducted in micro-lysimeters filled with moist peat medium. Increasing the temperature from 4 to 12°C slightly increased N release from three different slow-release N (SRN) carriers with different particle sizes and coating thicknesses. At 21°C the rate of release was significantly different than the other two temperatures. Urea formaldehyde (UF), sulphur coated urea (SCU) and coated calcium nitrate (CCN), incubated in sphagnum moss peat, released between 3 and 20% of the applied N in six weeks. For eight synthetic and organic NPK carriers, the release pattern was similar to UF and SCU. However, the leaching losses of N from the NPK fertilizers were up to twenty times more than for the SRN products. Except for Osmocote® and Duna, which released 30–40% of the applied N as mineral-N within six weeks, all other slow-release and slowly mineralized NPK carriers acted like readily water-soluble compound NPK. Temperature did not affect the nutrient release from NPK fertilizers.
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    URL: http://dx.doi.org/10.1007/BF00420552
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    Leaching of nitrogen and phosphorus from rural areas to surface waters in the Netherlands (1998)
    Springer
    Nutrient cycling in agroecosystems 50 (1998), S. 321-324 
    Details
    ISSN: 1573-0867
    Keywords: nutrient modelling ; leaching ; nitrogen ; phosphorus ; schematization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract In context of preparing the Fourth National Policy Document on Water Management in the Netherlands effects of different scenarios of fertilizer management on nitrogen (N) and phosphorus (P) leaching from rural areas into Dutch surface waters were analyzed. The manuscript offers insight into the model instrument that is used to simulate the different scenarios. Main parts of the modelinstrument are: a procedure to schematize the Netherlands in horizontal areal units, field scale mechanistic models for water and nutrient behaviour in the soil and an empirical model for fertilizer additions.
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    URL: http://dx.doi.org/10.1023/A:1009773202654
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    Changes in fertilizer and manurial practices during 1960–1990: implications for N and P inputs to the Ythan catchment, N.E. Scotland (1998)
    Springer
    Nutrient cycling in agroecosystems 52 (1998), S. 19-29 
    Details
    ISSN: 1573-0867
    Keywords: agriculture ; catchment ; fertilizer ; historical ; manure ; nitrate ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A suggested increase in the growth of macrophytic algae within the Ythan estuary (N.E. Scotland) over recent years has been linked to the increased amounts of nitrogen in the form of NO3–N entering the estuary from the river. The increased NO3 concentration in the river has been associated with recent changes in farming practices in this predominantly agricultural catchment. Terrestrially derived phosphorus is also considered to contribute increasingly to eutrophication of fresh waters. Historical agricultural census data together with appropriate surveys of fertilizer practice were used to calculate the total quantities of fertilizer and manure derived N and P applied annually over the wholeYthan catchment during the period 1960 – 1990. While the total agricultural land area has remained similar, significant changes in cropping practice have occurred. In particular, a greater proportion of land is given to autumn sown crops while the area of grassland has declined. These changes in farming practice are associated with differences in both the total amounts and timing of fertilizer applied. The use of inorganic N in the catchment has trebled since 1960 and is currently approximately 6400 tonnes (104 kg N/ha). The use of P has decreased by more than a quarter to 1274 tonnes (21 kg P/ha) over a similar time period. There has been no obvious change in total quantity of N and P derived from animal manures, estimated to be 44 and 11 kg per ha, respectively, when averaged over the area of agricultural land. Cattle and sheep numbers have remained relatively constant and together account for approximately 80% of the manure N and 70% of the manure P produced annually. However, poultry have declined by 70% since 1960 while pig numbers have increased six-fold. The average annual application rate of manure derived N over the whole catchment (44 kg/ha) is considerably below that proposed at the farm scale in the EC Nitrate Directive (210–170 kg/ha). However, on a local scale difficulties may arise for large manure producing concerns such as dairy or pig units.
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    URL: http://dx.doi.org/10.1023/A:1009787618943
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    Controlling soil water content in fertiliser dissolution experiments (1999)
    Springer
    Nutrient cycling in agroecosystems 55 (1999), S. 7-14 
    Details
    ISSN: 1573-0867
    Keywords: fertiliser formulation ; nutrients ; phosphorus ; relative humidity ; soil moisture
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Phosphorus lost in runoff from agricultural land leads to the enrichment of surface waters and contributes to algal blooms. Fertilisers are one source of this P. To compare the water available P of different fertiliser formulations in the laboratory it is necessary to control environmental conditions, temperature, relative humidity and soil water content, prior to simulating rainfall. Two chambers were designed in which relative humidity and soil water content were controlled using salt solutions. An initial design comprising a sealed chamber with three layers of soil samples over a salt bath was found to be inferior to a single layer design. The changes in water content of soil samples were used to test the single layer chamber in a constant temperature environment (15 °C) using a saturated KCl solution (90% relative humidity). Based on the final soil water content of the samples, the spatial variation within the chamber was within tolerable limits. The single layer chamber was used for a simulation experiment comparing the water available P of two commercial fertilisers. Using a saturated resorcinol solution (95% relative humidity) soil samples were equilibrated at 15 °C for 21 days, fertiliser added, and the water available P measured up to 600 h after fertiliser application. The results indicate that the amount of water available P was related to the fertiliser compound and exponentially related to the time since fertiliser application. It was concluded that the single layer chamber is suitable for controlling relative humidity and soil water content in trials such as these where the water available P of fertilisers are being compared.
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    URL: http://dx.doi.org/10.1023/A:1009816716466
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    Transfers of phosphorus within three dairy farming systems receiving varying inputs in feeds and fertilizers (1999)
    Springer
    Nutrient cycling in agroecosystems 55 (1999), S. 63-75 
    Details
    ISSN: 1573-0867
    Keywords: dairy systems ; feeds ; fertilizers ; phosphorus ; P surplus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Inputs of phosphorus (P) above requirements for production on dairy farms lead to surplus P with increased risk of P transfer in land run-off to surface waters causing eutrophication. The impact of reducing surplus P inputs in purchased feeds and fertilizers on milk and forage production was investigated in a comparison of three dairy farm systems on chalkland soils in southern England over a 3-year period. In accordance with current commercial practice, no attempt was made to regulate P inputs in system 1, which accumulated an average annual surplus of 23 kg P ha-1. Progressive reductions in purchased feed and/or fertilizer inputs into systems 2 and 3 decreased surplus P to 17 and 3 kg ha-1, respectively, without apparently limiting either milk or herbage dry matter production. The estimated reduction in faecal P output from system 3 cows fed a low P diet compared to system 1 cows fed a high P diet was 26%. Milk P concentrations significantly (P 〈0.001) increased in systems 2 and 3 which included maize in the diet. Output of P in milk and meat products, as a proportion of the total dietary P inputs, increased from 28% in system 1 to 36% in system 3. Surplus P was greatest in continuous maize fields receiving both dairy manure and starter P fertilizer. Withholding P fertilizer in system 3 did not reduce P offtake in cut herbage on soils of moderate P fertility. Total annual losses of P in storm run-off and leaching were no greater than annual inputs of P from the atmosphere (0.5 kg ha-1). The results indicate there is scope to reduce surplus P on commercial dairy farms without sacrificing production targets at least in the short term. Purchased feeds are the largest of the P inputs on intensive dairy farms, yet these are rarely quantified on commercial holdings.
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    URL: http://dx.doi.org/10.1023/A:1009860915462
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    Applications of poultry litter and triple superphosphate fertilizer to a sandy soil: effects on soil phosphorus status and profile distribution (1999)
    Springer
    Nutrient cycling in agroecosystems 54 (1999), S. 233-242 
    Details
    ISSN: 1573-0867
    Keywords: leaching ; phosphorus ; poultry litter ; soil
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract To determine P loadings, added through poultry litter, sufficient to cause downward movement of P from the cultivated layer of a sandy soil, six rates of poultry litter were applied annually for four years to a site in central England. (total loading 0 – 1119 kg P ha-1). A single extra plot also received an extra 1000 kg ha-1 as triple superphosphate (TSP; total loading 2119 kg P ha-1) and three other treatments received 200 – 800 kg ha-1 P as TSP only. Annual soil sampling in 30-cm increments to 1.5-m depth provided information on P build-up in the topsoil and P movement to depth. There were strong linear trends between P balance (P applied – P removed in crops) and total P, Olsen bicarbonate extractable P and water-soluble P in the topsoil. Phosphorus from TSP and poultry litter fell on the same regression lines, suggesting that both would be equally effective as fertilizer sources. We calculated that 100 kg ha-1 surplus total P would increase the Olsen extractable P content by c. 6 mg kg-1 and the water-soluble P by c. 5 mg kg-1. Thus, relatively large amounts of P would need to be applied to raise soil P status. We found some evidence of P movement into the soil layers immediately below cultivation depth. However, neither soil sampling nor soil solution extracted through Teflon water samplers showed evidence of movement into the deep subsoil (1 m) despite large P loadings.
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    Inorganic phosphorus and manure effects on bahiagrass production on a Spodosol (1999)
    Springer
    Nutrient cycling in agroecosystems 54 (1999), S. 259-266 
    Details
    ISSN: 1573-0867
    Keywords: bahiagrass ; manure ; pasture fertilization ; phosphorus ; phosphorus cycling ; Spodosol
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Bahiagrass (Paspalum notatum Flugge) pasture fertilization recommendations have traditionally been based upon clipping studies. Inclusion of P from manure, not originally considered when P recommendations were developed for pastures, may minimize the need for P fertilization without reducing bahiagrass production or P uptake. The objective of this research was to determine if manure contributes greatly to the P crop nutrient requirement. A 2-year field study utilized a factorial arrangement of 0 and 6.9 Mg air-dried manure ha-1 with 0, 17, 34, 51, and 68 kg inorganic P ha-1 from triple superphosphate to evaluate bahiagrass yield, root distribution, and P uptake response on a Myakka fine sand (sandy, siliceous, hyperthermic Aeric Alaquod). Because air-dried manure was used in the field study, a greenhouse study was employed to confirm that there were no differences in bahiagrass yield or P uptake from either air-dried or fresh cattle (Bos spp.) manure sources. There were no manure or manure by P interaction effects on yield or P uptake of bahiagrass indicating that manure source did not effect grass production in the greenhouse. In the field study, bahiagrass roots were distributed into the Bh horizon, and the Bh horizon had at least four times more Mehlich-1 extractable P than that of the Ap horizon. This horizon was most likely acting as a main source for P-uptake by the grass. This observation was further confirmed by no yield response to levels of inorganic P application in 1989. A linear-response-and-plateau (R2=0.196) relationship with a critical point of 15.4 kg P ha-1 was found in 1990. Bahiagrass yield and P uptake were not dependent on P fertilization, either from manure or inorganic P, due to the availability of P from the Bh horizon.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1009831011649
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  • 92
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    Effect of P fertilizer on alleviating chloride toxicity in wheat (1985)
    Springer
    Nutrient cycling in agroecosystems 6 (1985), S. 171-176 
    Details
    ISSN: 1573-0867
    Keywords: Chloride ; phosphorus ; salinity ; wheat
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A pot study with four levels each P (control, 6.5, 13.0, 19.5 mg kg−1) and Cl− in irrigation water (control, 30, 60, 90me l−1) was carried out to test Cl− and P interaction on wheat. It has been found that optimum P nutrition alleviates the toxic effect of excess Cl−. Highest P rate resulted in a significant yield increase upto a Cl− level of 60me l−1. Cl− depressed P content in the plant only at a Cl− level of 90me l−1, while P rates had no major impact on the Cl− concentration in the plant. Lower Cl− concentration at higher P rates are rather a dilution effect than an antagonistic one. With optimum P supply higher Cl− contents in the plants were tolerated than with a low P supply.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01051011
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  • 93
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    Tracking phosphorus patterns in mango (Mangifera indica L) and possible relations to floral induction (1985)
    Springer
    Nutrient cycling in agroecosystems 6 (1985), S. 225-234 
    Details
    ISSN: 1573-0867
    Keywords: bark ; floral induction ; leaves ; mango ; phosphorus ; shoots ; stems
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Phosphorus concentration was tracked in four types of mango shoots. The mean phosphorus concentration was highest in laterals existing on shoots which had either flowered or fruited in the preceding season, followed by young flush arising in July, laterals existing on shoots which did not flower or fruit in the preceding season and shoots which did not flower or fruit in the preceding season and having further extension of growth. A higher percentage of floral induction was noted in the laterals on shoots which had either flowered or fruited in the preceding season. The study clearly showed the association of availability of phosphorus with floral induction.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01048797
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  • 94
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    Response of two okra (Abelmoschus esculentus L. Moench) varieties to fertilizers: Yield and yield components as influenced by nitrogen and phosphorus application (1985)
    Springer
    Nutrient cycling in agroecosystems 6 (1985), S. 257-267 
    Details
    ISSN: 1573-0867
    Keywords: nitrogen ; okra (Abelmoschus esculentus L. Moench) ; phosphorus ; yield ; yield components
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The response of two okra (Abelmoschus esculentus L. Moench) varieties (‘White velvet’ and ‘NHAE 47-4’) to fertilization in northern Nigeria was examined using four rates of nitrogen (0, 25, 50 and 100 kg ha−1) and three rates of phosphorus (0, 13 and 26 kg ha−1). Nitrogen application significantly increased green pod yield, pod diameter, number of fruits per plant, number of seeds per pod and pod weight. Application of phosphorus also significantly increased green pod yield, pod number and number of seeds per pod. The two varieties responded to nitrogen application differentially with respect to green pod yield. For optimum green pod yield of ‘White velvet’ 35 kg N ha−1 is suggested while for variety ‘NHAE 47-4’, N fertilization can be increased to 70 kg ha−1. There was no differential response of varieties to phosphorus fertilization for green pod yield; however, the application of 13 kg ha−1 enhanced the performance of both varieties.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01048799
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  • 95
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    A conceptual model for initial and residual responses to phosphorus fertilizers (1985)
    Springer
    Nutrient cycling in agroecosystems 6 (1985), S. 131-138 
    Details
    ISSN: 1573-0867
    Keywords: modelling ; phosphorus ; residual value
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A model is formulated to describe the amount of effective phosphorus in soil. For a source that is immediately fully effective only three parameters are required — the amount of effective phosphorus initially present, the proportion of phosphorus remaining effective after each year, and a parameter which determines the lower limit for the amount of effective phosphorus. An extension of the model to sources that release their phosphorus slowly requires one further parameter — the fraction of such phosphorus released each year. The effective phosphorus in soil is then related to yield using the Mitscherlich equation. The model gave a good description of the growth response ofStylosanthes humilis to superphosphate and calcined Christmas Island C-grade phosphate (CCICP) over three years on a red earth at Katherine, N.T. Furthermore, it enabled a quantitative assessment to be made of the residual value of the CCICP that was not achieved in an earlier analysis of the data.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01051007
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  • 96
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    Fertilizer and liming value of lime-treated sewage sludge (1986)
    Springer
    Nutrient cycling in agroecosystems 8 (1986), S. 313-328 
    Details
    ISSN: 1573-0867
    Keywords: fertilizers ; lime ; lucerne ; nitrogen ; phosphorus ; sewage sludge
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A field experiment was conducted with lucerne on a strongly acidic and phosphorus deficient soil to determine the liming and phosphorus and nitrogen fertilizer value of an undigested, lime-treated sewage sludge. The results are presented in terms of calculated combinations of lime, nitrogen and phosphorus fertilizer required to obtain the same lucerne yield (or soil pH or extractable phosphorus level) as achieved with 5 or 10 t ha−1 of dried sludge. The sludge was a good source of lime, phosphorus and nitrogen. The sludge phosphorus was 49% as effective as the fertilizer phosphorus in raising extractable phosphorus in the soil to the level required for crop growth. The calcium carbonate of the sludge raised soil pH more effectively than agricultural lime, probably because of finer particle size in the former. It was not possible to achieve the yield obtained with 25 t ha−1 of sludge with combinations of agricultural lime, and nitrogen and phosphorus fertilizers at high rates of application. This was attributed to the effects of the sludge on improving soil physical properties.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01048634
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  • 97
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    Comparisons of the fertilizing and liming properties of lime-treated sewage sludge with its incinerated ash (1986)
    Springer
    Nutrient cycling in agroecosystems 9 (1986), S. 187-197 
    Details
    ISSN: 1573-0867
    Keywords: lime ; lucerne ; nitrogen ; phosphorus ; ryecorn ; ryegrass ; sewage sludge ; sewage ash
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Two field experiments were conducted to compare the fertilizing and liming properties of dried lime-treated sewage sludge with its incineration product (ash). One experiment used a mixture of ryecorn and ryegrass on a relatively fertile soil and the other lucerne on a strongly acidic and phosphorus deficient soil. The first harvest of the ryecorn-ryegrass experiment showed small but significant linear responses in dry matter yield to both ash and sludge. Ash applications did not affect foliage nitrogen and phosphorus concentrations, or uptakes, but sludge applications increased these significantly. Sludge also increased the concentrations of K, S, Mg, Cu and Zn but ash only increased the concentrations of S and Mg. At the second harvest (ryegrass) 5 t ha−1 of sludge increased dry matter yield and foliage nitrogen and phosphorus concentrations whereas ash had no effect. Levels of phosphorus extracted from the soil were increased by both amendments but the sludge was much more effective than the ash. Both ash and sludge raised soil pH. In the lucerne experiment comparisons between sludge and ash were calculated from response surfaces fitted to the data which showed marked increased in soil pH and dry matter yield. Sludge markedly increased extractable phosphorus whereas ash had no effect. The sludge was 22% as effective as ash in raising soil pH to 6.5. The amounts of ash required to obtain the same yield as 10 t ha−1 of sludge were 5.78, 12.78 and 6.39 t ha−1 respectively for three successive harvests. These results and those for foliage concentrations of nitrogen and phosphorus were also ascribed to the much greater availability of the sludge phosphorus than the ash phosphorus, and the presence of nitrogen in the sludge but not in the ash.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01050345
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  • 98
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    Fertilization of tropical rice: A case study on Bangkok plain (1986)
    Springer
    Nutrient cycling in agroecosystems 10 (1986), S. 97-112 
    Details
    ISSN: 1573-0867
    Keywords: fertilizer ; nitrogen ; phosphorus ; plant analysis ; nutritional status
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract This study consisted of a survey on the nutritional status of rice plants in relation to nutrient application and yield in 70 farmers' fields in four provinces of Bangkok plain during the 1977 wet season. In addition a series of fertilizer experiments were carried out on rice experimental stations in the same provinces to study yield response to N and P fertilization and to develop a fertilizer recommendation system based on plant analysis. The average grain yield in the survey was 3.2 t ha−1 and the early (high yielding varieties), medium (local) and late maturity (local) types yielded 3.3, 2.8 and 3.0 t ha−1, respectively. The average amount of fertilizers applied to these maturity types were 33, 15 and 7 kg N ha−1 and 15, 8 and 6 kg P ha−1, respectively. Regression analysis indicated only a slight correlation between yield and any level of fertilizer application. On experimental stations yields over 6 t ha−1 were obtained with applications of N over 100 kg ha−1 and P over 22 kg ha−1. Evaluation of nutritional status of plants based on plant analysis showed that in all provinces there were strong and widespread nutrient deficiences primarily of N and secondarily of P, and possibly of some other nutrients. Fertilizer application based on plant analysis gave high yield responses. It was concluded that the major constraints of yield on Bangkok plain are too low fertilizer application especially of N, and unbalanced fertilization of N and P.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01074365
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  • 99
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    Mathematical algorithm for effective phosphorus determination in a rice based cropping system (1988)
    Springer
    Nutrient cycling in agroecosystems 18 (1988), S. 57-61 
    Details
    ISSN: 1573-0867
    Keywords: Cropping system ; modelling ; phosphorus ; residual value ; rice based ; sources of P
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A mathematical model similar to the one suggested by Probert [3] is used to calculate effective phosphorus in two rice crops followed by green gram. The effective phosphorus values are then related to dry matter yield, grain yield and phosphorus uptake in the three crops using linear and Mitscherlich equations.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01064178
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  • 100
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    Fertilization of millet cv. Souna III in Senegal: dry matter production and nutrient uptake (1993)
    Springer
    Nutrient cycling in agroecosystems 35 (1993), S. 217-226 
    Details
    ISSN: 1573-0867
    Keywords: calcium ; dry matter distribution ; fertilizer ; harvest index ; magnesium ; manure ; millet ; nitrogen ; nutrient uptake ; phosphorus ; potassium ; Senegal
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract In a fertilizer and manure experiment, millet was grown under four treatments (no fertilizer or manure, farmyard manure, chemical fertilizer, and both). Grain yield and total aboveground biomass production of the unfertilized plot were relatively high. The observed differences in total dry matter production must be attributed to differences in nutrient availability, as amount of rainfall and its distribution were favourable. Results show only small differences in distribution of dry matter among the various plant organs between the best and the non-fertilized treatments. Nutrient supply from natural sources, defined as crop content of N, P, and K at maturity without fertilizer application, amounted to 104, 16 and 103 kg ha−1, respectively, which are very high values. Total uptake of calcium and magnesium is related to that of potassium, as the combined content of these three elements is linearly related to total aboveground biomass production. Minimum removal of nitrogen and phosphorus per ton grain dry matter amounts to 29 and 4kg, respectively, and 9 kg potassium per ton total aboveground dry matter. A possible double function of phosphorus as element of structural biomass and for maintenance of electro-neutrality is discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00750640
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