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  • Inorganic Chemistry  (1,628)
  • Industrial Chemistry  (1,307)
  • Aerodynamics
  • Seismology
  • 2020-2024  (23)
  • 1950-1954  (3,056)
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  • 1
    Publication Date: 2024-04-05
    Description: This article has been accepted for publication in Geophysical Journal International ©:The Author(s) 2023. Published by Oxford University Press on behalf of the Royal Astronomical Society. All rights reserved.Uploaded in accordance with the publisher's self-archiving policy. All rights reserved.
    Description: We implemented an automatic procedure to download the hypocentral data of the online Bulletin of the International Seismological Centre (ISC) in order to produce in near real-time a homogeneous catalogue of the Global and EuroMediterranean instrumental seismicity to be used for forecasting experiments and other statistical analyses. For the interval covered by the reviewed ISC Bulletin, we adopt the ISC locations and convert the surface wave magnitude (Ms) and short-period body-wave magnitude (mb) as computed by the ISC to moment magnitude (Mw), using empirical relations. We merge the so obtained proxies with real Mw provided by global and EuroMediterranean moment tensor catalogues. For the most recent time interval (about 2 yr) for which the reviewed ISC Bulletin is not available, we do the same but using the preferred (prime) location provided by the ISC Bulletin and converting to Mw the Ms and mb provided by some authoritative agencies. For computing magnitude conversion equations, we use curvilinear relations defined in a previous work and the chi-square regression method that accounts for the uncertainties of both x and y variables.
    Description: H2020 EU project RISE contract n. 821115
    Description: Published
    Description: 1771-1785
    Description: OST2 Deformazione e Hazard sismico e da maremoto
    Description: JCR Journal
    Keywords: Statistical methods ; Statistical seismology ; Earthquake source observations ; Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
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    MDPI - Multidisciplinary Digital Publishing Institute
    Publication Date: 2023-11-30
    Description: Active flow control (AFC) utilizes local active perturbations to induce changes in global flow behavior that result in aero/hydrodynamic performance improvement. It has been a vibrant research area with potential applications in a wide range of engineering fields. This Special Issue is a collection of 11 excellent research papers published in Actuators, showcasing and discussing new advances in both fundamental and applied AFC technologies.
    Keywords: Active flow control ; Actuators ; Aerodynamics ; Synthetic jets&nbsp ; bic Book Industry Communication::T Technology, engineering, agriculture::TB Technology: general issues
    Language: English
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  • 3
    Publication Date: 2023-02-20
    Description: Several regions around the globe are characterized by a seismically active lower crust, at depths where litho­logical and thermal conditions suggest stress release by ductile flow. The Gargano Promontory (GP, southern Italy) is an example where a recently installed seismic network has recorded an intense seismic activity at depths between 20 and 30 km, i.e. in the lower crust. The GP is located in proximity of the Gargano-Dubrovnik line­ament, a seismogenic zone separating the central and southern Adriatic basins. These two basins constitute sites of sediments accumulation since Tertiary times. Another important basin in the region is represented by the Apennine foredeep, that includes the Candelaro area. We analyze the possible mechanisms controlling the dis­tribution of seismicity in the GP to identify the factors that make the lower crust seismically active. To this aim, we construct a thermo-rheological model of a layered continental crust, calibrated on the basis of geometrical, lithological and thermal constraints. The model takes into account various crustal lithologies, the presence of fluids in the crystalline basement, lateral variations of geotherm and stress field. The numerical simulations show that the presence of fluids is a key factor controlling the cluster of seismicity in the lower crust. Moreover, the presence of water in the upper crystalline basement and sedimentary cover provides a plausible explanation for upper crustal seismicity in a zone of very high heat flow SW of the GP. The distribution of the seismicity is probably affected by the composition of the crystalline basement, with mafic bodies injected into the crust during the Paleocene magmatic phase that affected the Mediterranean region. In addition, fluid accumulation and overpressure may occur along detachment levels in the lower crust, leading to clustering of the earthquakes. Based on our findings, we hypothesize that the presence of hydrous diapiric upwelling(s) in the upper mantle can feed a deep fluid circulation system, inducing lower crustal seismicity.
    Description: Published
    Description: 103929
    Description: 4T. Sismicità dell'Italia
    Description: JCR Journal
    Keywords: Lower crust ; Rheology ; Seismology ; Geotherm ; Numerical modeling ; Gargano Promontory (southern Italy)
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
    Publication Date: 2024-04-23
    Description: The National Institute of Geophysics and Volcanology (INGV, Istituto Nazionale di Geofisica e Vulcanologia), is an italian public research institute established in 1999. Since its inception, the mission of INGV included seismic surveillance and earthquake monitoring in Italy. INGV is part of the Civil Defence system (Margheriti et al., 2021). INGV has offices in different parts of Italy and operates the Italian National Seismic Network (Rete Sismica Nazionale—RSN; INGV Seismological Data Centre, 2006) and other networks at national scale (Michelini et al., 2017). INGV also operates a temporary seismic network infrastructure, a pool of instruments used to densify seismic networks for scientific experiments or in response to damaging earthquakes and to increase monitoring capabilities during seismic sequences. SISMIKO is the operational task force of INGV whose core purpose is to rapidly deploy temporary seismic stations in response to moderate—large magnitude earthquakes or in areas where a seismic sequence is causing concerns and/or scientific interest (Moretti et al., 2016). By reducing the spatial distance between the seismic stations, temporary deployments can improve the RSN detection capability and the accuracy of the earthquake locations. SISMIKO was established in 2015 by Lucia Margheriti and Milena Moretti, so they became responsible for INGV emergency deployments of the temporary networks. SISMIKO involves INGV technicians and researchers from all over Italy, from Milano to Catania (see acknowledgments), grouped together by common interest technical and scientific issues. SISMIKO coordinates all INGV groups working on seismic emergencies (Figure 1). The data acquired by the SISMIKO temporary networks, are made available to the scientific community, without any restrictions, via italian node of the European Integrated Data Archive portal (EIDA1; Danecek et al., 2021). Datasets are archived in near real-time in the “Standard for the Exchange of Earthquake Data (SEED)” format and have an associated Digital Object Identifier (DOI). The data are used for monitoring, surveillance and for scientific research. Since its establishment, SISMIKO has installed seven temporary seismic networks, including the one used to monitor the 2016–2018 seismic sequence in central Italy (Moretti et al., 2016). The most recent activations of SISMIKO were in May and November 2022: Chianti-Fiorentino (Piccinini et al., 2022; 2023) and North Marche coast (D’Alema et al., 2022b), respectively. The following section briefly describes the history of the INGV emergency mobile network.
    Description: Published
    Description: 1146579
    Description: OST5 Verso un nuovo Monitoraggio
    Description: JCR Journal
    Keywords: SISMIKO ; Seismic emergency ; Temporary seismic network ; Real time transmission ; Seismology ; 05.04. Instrumentation and techniques of general interest
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
    Publication Date: 2023-09-01
    Description: Abstract
    Description: We present a new, consistently processed seismicity catalogue for the Eastern and Southern Alps, based on the temporary dense Swath-D monitoring network. The final catalogue includes 6,053 earthquakes for the time period 2017-2019 and has a magnitude of completeness of −1.0ML. The smallest detected and located events have a magnitude of −1.7ML. Aimed at the low to moderate seismicity in the study region, we generated a multi-level, mostly automatic workflow which combines a priori information from local catalogues and waveform-based event detection, subsequent efficient GPU-based event search by template matching, P & S arrival time pick refinement and location in a regional 3-D velocity model. The resulting seismicity distribution generally confirms the previously identified main seismically active domains, but provides increased resolution of the fault activity at depth. In particular, the high number of small events additionally detected by the template search contributes to a more dense catalogue, providing an important basis for future geological and tectonic studies in this complex part of the Alpine orogen.
    Description: TableOfContents
    Description: Seismicity catalogue Python codes & metadata Seismicity cross-sections
    Keywords: Seismology ; Seismic Waveform Analysis ; Eastern Alps ; Earthquake ; Geophysics ; Template matching ; 4DMB ; 4D Mountain Building ; EARTH SCIENCE ; EARTH SCIENCE 〉 SOLID EARTH ; EARTH SCIENCE 〉 SOLID EARTH 〉 TECTONICS ; EARTH SCIENCE 〉 SOLID EARTH 〉 TECTONICS 〉 EARTHQUAKES ; EARTH SCIENCE 〉 SOLID EARTH 〉 TECTONICS 〉 EARTHQUAKES 〉 EARTHQUAKE MAGNITUDE/INTENSITY ; EARTH SCIENCE 〉 SOLID EARTH 〉 TECTONICS 〉 EARTHQUAKES 〉 EARTHQUAKE OCCURRENCES ; geophysics ; seismology ; surface processes ; tectonics
    Type: Dataset , Dataset
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  • 6
    Publication Date: 2023-10-18
    Description: Abstract
    Description: This data publication contains (i) a slab model of the Cascadia subduction zone, derived from receiver functions, parameterized as depth to the three interfaces: t (top), c (central) and m (Moho), in NetCDF format; (ii) the station measurements of all parameters in the model in tabular and Raysum model file format; (iii) the raw receiver functions in SAC format; and (iv) auxiliary scripts for loading and plotting the data. A total of 45,601 individual receiver functions recorded at 298 seismic stations distributed across the Cascadia forearc contributed to the slab model. For each station, 100 s recordings symmetric about the P -wave arrival (i.e. 50 s noise and 50 s signal) of earthquakes with magnitudes between 5.5 and 8, in the distance range between 30 and 100 degree, were downloaded from the Incorporated Research Institutions for Seismology (IRIS) data center, the Northern California Earthquake Data Center (NCEDC), and the Natural Resources Canada Data Center (NRCAN). After quality control, radial and transverse receiver functions were computed through frequency-domain simultaneous deconvolution, with an optimal damping factor found through generalized cross validation. The continental forearc and subducting slab were parameterized as three layers over a mantle half-space, with the subduction stratigraphy bounding interfaces labeled as t (top), c (central) and m (Moho). Synthetic receiver functions were calculated through ray-theoretical modeling of plane-wave scattering at the model interfaces. The thickness, S -wave velocity (VS) and P - to S -wave velocity ratio (VP/VS) of each layer, as well as the common strike and dip of the bottom two layers and the top of the half space (in total 11 parameters) were optimized simultaneously through a simulated annealing global parameter search scheme. The misfit was defined as the anti-correlation (1 minus the cross-correlation coefficient) between the observed and predicted receiver functions, bandpass filtered between 2 and 20 s period duration. In total, 171, 143 and 137 quality A nodes were determined to constrain the t, c and m interfaces, respectively. At the trench, 105 nodes at 3 km below the local bathymetry were inserted to constrain the t and c interfaces, and at 6.5 km deeper to constrain the m interface, representing typical sediment and igneous crustal thicknesses. A spline surface was fitted to these nodes to yield margin-wide depth models. The spline coefficients were found using singular value decomposition, with the nominal depth uncertainties supplied as weights. The solution was damped by retaining the 116, 117, and 116 largest singular values for the t, c and m interfaces, respectively, based on analysis of L-curves and the Akaike information criterion. The data set is the supplemental material to Bloch, W., Bostock, M. G., Audet, P. (2023) A Cascadia Slab Model from Receiver Functions. Geochemistry, Geophysics, Geosystems.
    Keywords: Seismology ; Cascadia ; North America ; Reveiver Functions ; Subduction ; EARTH SCIENCE 〉 SOLID EARTH 〉 TECTONICS 〉 PLATE TECTONICS ; EARTH SCIENCE 〉 SOLID EARTH 〉 TECTONICS 〉 PLATE TECTONICS 〉 PLATE BOUNDARIES ; lithosphere ; The Present
    Type: Dataset , Dataset
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  • 7
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-11
    Description: Some sixty years after the experimental flights of the North American X-15 hypersonic rocket-powered aircraft, sustained hypervelocity travel is still the next frontier in high-speed transportation. Today, there is much excitement and interest regarding hypersonic vehicles. In fact, many aerospace agencies, large industries, and several start-ups are involved in design activities and experimental campaigns both in wind tunnels and in-flight with full-scale experimental flying test beds and prototypes to make hypersonic travel almost as easy and convenient as airliner travel. Achieving this goal will radically revolutionize the future of civil transportation. This book contains valuable contributions that focus on various design issues related to hypersonic aircraft.
    Keywords: Aerodynamics ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGM Materials science::TGMF Engineering: Mechanics of fluids::TGMF1 Aerodynamics
    Language: English
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  • 8
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    Frontiers Media SA
    Publication Date: 2024-04-04
    Description: The Frontiers in Chemistry Editorial Office team are delighted to present the inaugural “Frontiers in Chemistry: Rising Stars” article collection, showcasing the high-quality work of internationally recognized researchers in the early stages of their independent careers. All Rising Star researchers featured within this collection were individually nominated by the Journal’s Chief Editors in recognition of their potential to influence the future directions in their respective fields. The work presented here highlights the diversity of research performed across the entire breadth of the chemical sciences, and presents advances in theory, experiment and methodology with applications to compelling problems. This Editorial features the corresponding author(s) of each paper published within this important collection, ordered by section alphabetically, highlighting them as the great researchers of the future. The Frontiers in Chemistry Editorial Office team would like to thank each researcher who contributed their work to this collection. We would also like to personally thank our Chief Editors for their exemplary leadership of this article collection; their strong support and passion for this important, community-driven collection has ensured its success and global impact.
    Keywords: Green and Sustainable Chemistry ; Analytical Chemistry ; Theoretical and Computational Chemistry ; Polymer Chemistry ; Medicinal and Pharmaceutical Chemistry ; Organic Chemistry ; Nanoscience ; Catalysis and Photocatalysis ; Supramolecular Chemistry ; Electrochemistry ; Inorganic Chemistry ; Chemical Biology ; thema EDItEUR::P Mathematics and Science::PD Science: general issues
    Language: English
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  • 9
    Publication Date: 2023-12-20
    Description: Giulia Parola’s Environmental Democracy at the Global Level: Rights and Duties for a New Citizenship can be seen as a manifesto that is both traditional and revolutionary at the same time. It calls for the construction of a new civilisation centred on the environment, while drawing on the traditional notions of democratic government. It adopts an approach that is focused on the power of individuals rather than governments, as ways to protect and improve the environment. It proposes that environmental rights and ecological duties are self-evident and inalienable, and should be treated as the cornerstones of a new democracy. Parola’s book is a thought provoking and intriguing work that will be of interest to scholars of environmental studies as well as to legal practitioners and non-specialists. Giulia Parola has studied Environmental Law at the University of Torino, at the University of René Descartes in Paris, (where she obtained PhD in Public Law) and at the University of Iceland ( LLM in Natural Resources Law and International Environmental Law). In 2011, she was appointed by the University of Laval (Canada, Quebec) as a researcher and a lecturer in Environmental Law.
    Keywords: GE1-350 ; K ; International Law ; Materials Science ; Industrial Chemistry ; Law ; Comparative Law ; Foreign Law ; Environment ; Natural Sciences ; German Civil Code ; Pollution Control ; bic Book Industry Communication::K Economics, finance, business & management::KC Economics::KCN Environmental economics
    Language: English
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  • 10
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-11
    Description: Aerodynamics, the study of air motion around solid objects, allows us to understand and measure the dominating forces acting on aircrafts, buildings, bridges, automobiles, and other structures. The forces that result in an aircraft overcoming gravity and drag are called thrust and lift. Various parameters such as geometrical configurations of objects, as well as physical properties of air, which may be functions of position and time, affect those forces. This book covers some of the latest studies regarding the application of the principles of aerodynamics to the design of many different engineered objects. This book will be of interest to mechanical and aerospace engineering students, academics, and researchers who are looking for new insights into this fascinating branch of fluid mechanics.
    Keywords: Aerodynamics ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGM Materials science
    Language: English
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  • 11
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    Taylor & Francis | CRC Press
    Publication Date: 2024-03-31
    Description: Because of many misconceptions, the biological drug manufacturing industry does not fully utilize disposable components, despite their wide availability. These misconceptions include concerns for the quality of materials, running costs, scalability, the level of automation possible, and the training of staff needed to include these components in existing bioprocessing systems. Not fully realizing the long-term benefits, many manufacturers are unwilling to discard investments made in fixed equipment and traditional stainless steel systems. Regulatory and environmental concerns, however, will eventually compel manufacturers to adopt disposable systems. Making a strong case for disposables, Disposable Bioprocessing Systems demonstrates the true potential of these systems. Written by a researcher and professor with hands-on experience in designing, establishing, and validating biological manufacturing facilities worldwide, and creating model facilities using maximum disposable technology, this book is the first comprehensive introduction to understanding disposable systems. It gives an overview of the current state of the disposable bioprocessing industry, resolves all controversial issues, and guides readers in choosing disposable components that meet their needs. An important chapter on safety addresses facts and myths about the use of plastics and elastomers—including the issue of leaching—and how to ensure regulatory compliance. Helping readers understand their choices, the book describes the equipment and systems available to prepare the starting materials for the manufacturing of biological drugs—from disposable containers to filters. The author also discusses costs, regulations, and concerns about waste disposal, and shares his predictions for the future of the disposable bioprocessing industry. A practical manual for those interested in the transition to disposable systems, this book will also interest students of bioprocessing. It offers a timely view of disposable bioprocessing technology as a "game changer" that will facilitate developing new drugs and conducting research in the emerging field of stem cells and gene therapy.
    Keywords: Biotechnology ; Pharmaceutical Science ; Industrial Chemistry ; PHARMACEUTICAL ; BIOSCIENCE ; CHEMLIB ; SCI-TECH ; BIOMEDICALSCIENCE ; CHEMICALENGINEERING ; STM ; bags ; bioreactors ; cleaning ; disposal ; downstream ; single ; stainless ; steel ; use ; validation ; thema EDItEUR::M Medicine and Nursing::MF Pre-clinical medicine: basic sciences ; thema EDItEUR::M Medicine and Nursing::MK Medical specialties, branches of medicine::MKG Pharmacology ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TD Industrial chemistry and manufacturing technologies::TDC Industrial chemistry and chemical engineering ; thema EDItEUR::M Medicine and Nursing::MQ Nursing and ancillary services::MQW Biomedical engineering
    Language: English
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  • 12
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-11
    Description: Aerodynamics, from a modern point of view, is a branch of physics that study physical laws and their applications, regarding the displacement of a body into a fluid, such concept could be applied to any body moving in a fluid at rest or any fluid moving around a body at rest. This Book covers a small part of the numerous cases of stationary and non stationary aerodynamics; wave generation and propagation; wind energy; flow control techniques and, also, sports aerodynamics. It's not an undergraduate text but is thought to be useful for those teachers and/or researchers which work in the several branches of applied aerodynamics and/or applied fluid dynamics, from experiments procedures to computational methods.
    Keywords: Aerodynamics ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGM Materials science
    Language: English
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  • 13
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-11
    Description: This book is intended to be a valuable addition to students, engineers, scientists, industrialists, consultants and others providing greater insight into wind tunnel designs and their enormous research potential. It is a compilation of works from world experts on subsonic and supersonic wind tunnel designs, applicable to a diverse range of disciplines. The book is organised in two sections. The first section comprises of three chapters on various aspects of stationary and portable subsonic wind tunnel designs, followed by one chapter on supersonic wind tunnel and the final chapter discusses a method to address unsteadiness effects of fan blade rotation. The second section contains four chapters regarding wind tunnel applications across a multitude of engineering fields including civil, mechanical, chemical and environmental engineering.
    Keywords: Aerodynamics ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGM Materials science
    Language: English
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  • 14
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-11
    Description: This book reports the latest development and trends in the low Re number aerodynamics, transition from laminar to turbulence, unsteady low Reynolds number flows, experimental studies, numerical transition modelling, control of low Re number flows, and MAV wing aerodynamics. The contributors to each chapter are fluid mechanics and aerodynamics scientists and engineers with strong expertise in their respective fields. As a whole, the studies presented here reveal important new directions toward the realization of applications of MAV and wind turbine blades.
    Keywords: Aerodynamics ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGM Materials science
    Language: English
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  • 15
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    IntechOpen
    Publication Date: 2024-04-04
    Description: Spacecraft attitude maneuvers comply with Euler's moment equations, a set of three nonlinear, coupled differential equations. Nonlinearities complicate the mathematical treatment of the seemingly simple action of rotating, and these complications lead to a robust lineage of research. This book is meant for basic scientifically inclined readers, and commences with a chapter on the basics of spaceflight and leverages this remediation to reveal very advanced topics to new spaceflight enthusiasts. The topics learned from reading this text will prepare students and faculties to investigate interesting spaceflight problems in an era where cube satellites have made such investigations attainable by even small universities. It is the fondest hope of the editor and authors that readers enjoy this book.
    Keywords: Science ; Mechanics ; Aerodynamics ; bic Book Industry Communication::P Mathematics & science::PH Physics::PHD Classical mechanics::PHDF Fluid mechanics ; thema EDItEUR::P Mathematics and Science::PH Physics::PHD Classical mechanics::PHDF Physics: Fluid mechanics
    Language: English
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  • 16
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    Taylor & Francis | CRC Press
    Publication Date: 2024-04-11
    Description: Suitable for practicing engineers and engineers in training, this book covers the most important operations involving particulate solids. Through clear explanations of theoretical principles and practical laboratory exercises, the text provides an understanding of the behavior of powders and pulverized systems. It also helps readers develop skills for operating, optimizing, and innovating particle processing technologies and machinery in order to carry out industrial operations. The author explores common bulk solids processing operations, including milling, agglomeration, fluidization, mixing, and solid-fluid separation.
    Keywords: Industrial Chemistry ; Food Chemistry ; FOOD ; CHEMLIB ; SCI-TECH ; CHEMICALENGINEERING ; CHEMISTRY ; STM ; bed ; distribution ; fluidized ; industry ; mass ; material ; particle-size ; processing ; technology ; transfer ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TD Industrial chemistry and manufacturing technologies::TDC Industrial chemistry and chemical engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TD Industrial chemistry and manufacturing technologies::TDC Industrial chemistry and chemical engineering::TDCT Food and beverage technology ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGM Materials science
    Language: English
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  • 17
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-11
    Description: Although great advances in computational methods have been made in recent years, wind tunnel tests remain essential for obtaining the full range of data required to guide detailed design decisions for various practical engineering problems. This book collects original and innovative research studies on recent applications in wind tunnel tests, exhibiting various investigation directions and providing a bird’s eye view on this broad subject area. It is composed of seven chapters that have been grouped in two major parts. The first part of the book (chapters 1–4) deals with wind tunnel technologies and devices. The second part (chapters 5–7) deals with the latest applications of wind tunnel testing. The text is addressed not only to researchers but also to professional engineers, engineering lecturers, and students seeking to gain better understanding of the current status of wind tunnels. Through its seven chapters, the reader will have an access to a wide range of works related to wind tunnel testing.
    Keywords: Aerodynamics ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGM Materials science
    Language: English
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  • 18
    Publication Date: 2024-04-04
    Description: The Earth is an heterogeneous complex media from the mineral composition scale (10−6m) to the global scale ( 106m). The reconstruction of its structure is a quite challenging problem because sampling methodologies are mainly indirect as potential methods (Günther et al., 2006; Rücker et al., 2006), diffusive methods (Cognon, 1971; Druskin & Knizhnerman, 1988; Goldman & Stover, 1983; Hohmann, 1988; Kuo & Cho, 1980; Oristaglio & Hohmann, 1984) or propagation methods (Alterman & Karal, 1968; Bolt & Smith, 1976; Dablain, 1986; Kelly et al., 1976; Levander, 1988; Marfurt, 1984; Virieux, 1986). Seismic waves belong to the last category. We shall concentrate in this chapter on the forward problem which will be at the heart of any inverse problem for imaging the Earth. The forward problem is dedicated to the estimation of seismic wavefields when one knows the medium properties while the inverse problem is devoted to the estimation of medium properties from recorded seismic wavefields.
    Keywords: seismic wave ; geophysical imaging ; seismic wave ; geophysical imaging ; Boundary value problem ; Finite element method ; Free surface ; Frequency domain ; Seismology ; Time domain ; Velocity ; thema EDItEUR::P Mathematics and Science::PD Science: general issues
    Language: English
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  • 19
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-11
    Description: Spacecraft attitude maneuvers comply with Euler's moment equations, a set of three nonlinear, coupled differential equations. Nonlinearities complicate the mathematical treatment of the seemingly simple action of rotating, and these complications lead to a robust lineage of research. This book is meant for basic scientifically inclined readers, and commences with a chapter on the basics of spaceflight and leverages this remediation to reveal very advanced topics to new spaceflight enthusiasts. The topics learned from reading this text will prepare students and faculties to investigate interesting spaceflight problems in an era where cube satellites have made such investigations attainable by even small universities. It is the fondest hope of the editor and authors that readers enjoy this book.
    Keywords: Aerodynamics ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGM Materials science
    Language: English
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  • 20
    Publication Date: 2023-06-12
    Description: Seismic events produced by block rotations about vertical axis occur in many geodynamic contexts. In this study, we show that these rotations can be accounted for using the proper theory, namely micropolar theory, and a new asymmetric moment tensor can be derived. We then apply this new theory to the Kaikōura earthquake (2016/11/14), Mw 7.8, one of the most complex earthquakes ever recorded with modern instrumental techniques. Using advanced numerical techniques, we compute synthetic seismograms including a full asymmetric moment tensor and we show that it induces measurable differences in the waveforms proving that seismic data can record the effects of the block rotations observed in the field. Therefore, the theory developed in this work provides a full framework for future dynamic source inversions of asymmetric moment tensors.
    Description: Westfälische Wilhelms-Universität Münster (1056)
    Keywords: ddc:551.22 ; Seismology ; asymmetric moment tensor ; micropolar theory ; Kaikōura earthquake
    Language: English
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  • 21
    Publication Date: 2024-02-28
    Description: The AlpArray experiment and the deployment of Swath-D together with the dense permanent network in Italy allow for detailed imaging of the spatio-temporal imaging complexity of seismic wave-fields within the greater Alpine region. The distance of any point within the area to the nearest station is less than 30 km, resulting in an average inter-station distance of about 45 km. With a much denser deployment in a smaller region of the Alps (320 km in length and 140 km wide), the Swath-D network possesses an average inter-station distance of about 15 km. We show that seismogram sections with a spatial sampling of less than 5 km can be obtained using recordings of these regional arrays for just a single event. Multiply reflected body waves can be observed for up to 2 h after source time. In addition, we provide and describe animations of long-period seismic wave-fields using recordings of about 1300–1600 broadband stations for six representative earthquakes. These illustrate the considerable spatio-temporal variability of the wave-field’s properties at a high lateral resolution. Within denser station distributions like those provided by Swath-D, even shorter period body and surface wave features can be recovered. The decrease of the horizontal wavelength from P to S to surface waves, deviations from spherically symmetric wavefronts, and the capability to detect multi-orbit arrivals are demonstrated qualitatively by the presented wave-field animations, which are a valuable tool for educational, quality control, and research purposes. We note that the information content of the acquired datasets can only be adequately explored by application of appropriate quantitative methods accounting for the considerable complexity of the seismic wave-fields as revealed by the now available station configuration.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Christian-Albrechts-Universität zu Kiel (3094)
    Keywords: ddc:551.22 ; Seismology ; Wave-fields ; Animations ; Alps ; AlpArray ; Swath-D
    Language: English
    Type: doc-type:article
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  • 22
    Publication Date: 2024-02-23
    Description: Abstract
    Description: Continuous passive seismic monitoring is carried out between September 2017 and December 2021 around the Theistareykir geothermal area located at the intersection between the active Northern Rift Zone and the active Tjörnes Fracture Zone in NE Iceland. This experiment, in addition to an extensive gravimetric monitoring survey, was conducted in the framework of the MicroGraviMoTiS project for a better understanding of the structures and behavior of the local geothermal system under exploitation and for further development of local and regional geothermal resources. 14 broadband stations (Trillium C-120s) recording at 200 Hz comprise the temporary network, that is installed to complement stations of the national seismological network of IMO and stations of Landsvirkjun, the National Power Company of Iceland. The stations were placed in and around the producing zone to primarily retrieve local natural and/or induced seismicity associated to the injection and production operations. The retrieved seismic data is also used for obtaining a representative 1D velocity model of the region, for computing a seismic ambient noise tomography, and for monitoring the system using coda wave interferometry techniques. Funding for this project is provided by the German Federal Ministry for Education and Research (MicroGraviMoTiS , BMBF, grant: 03G0858A), the Helmholtz Centre Potsdam GFZ German Research Centre for Geosciences and Landsvirkjun. Waveform data are available from the GEOFON data center, under network code 3P, and are embargoed until December 2025.
    Keywords: Broadband seismic waveforms ; Seismology ; temporary local seismic experiment ; Monitoring system ; EARTH SCIENCE 〉 SOLID EARTH ; In Situ/Laboratory Instruments 〉 Magnetic/Motion Sensors 〉 Seismometers ; In Situ Land-based Platforms 〉 GEOPHYSICAL STATIONS/NETWORKS ; In Situ Land-based Platforms 〉 GEOPHYSICAL STATIONS/NETWORKS 〉 SEISMOLOGICAL STATIONS
    Type: Dataset , Seismic Network
    Format: ~1T
    Format: .mseed
    Format: XML
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  • 23
    Publication Date: 2024-02-23
    Description: Abstract
    Description: The main aim of this project is to investigate the crustal and mantle structure beneath the Longmenshan fault zone in China, based on a very dense passive seismology profile. The Longmenshan fault zone hosted the Wenchuan earthquake of May 2008 with a magnitude (Mw) of 7.9 and the Lushan earthquake of June 2013 with a magnitude (Mw) of 6.6. It is planned to mainly use the receiver-function method, to investigate the crustal and mantle structure beneath the Longmenshan fault zone. Waveform data are available from the GEOFON data center, under network code 4O, and are embargoed until February 2024.
    Keywords: Broadband seismic waveforms ; Seismology ; temporary local seismic experiment ; Earthquake ; Receiver functions ; Crustal and mantle structure ; China ; Monitoring system ; EARTH SCIENCE 〉 SOLID EARTH ; In Situ/Laboratory Instruments 〉 Magnetic/Motion Sensors 〉 Seismometers ; In Situ Land-based Platforms 〉 GEOPHYSICAL STATIONS/NETWORKS ; In Situ Land-based Platforms 〉 GEOPHYSICAL STATIONS/NETWORKS 〉 SEISMOLOGICAL STATIONS
    Type: Dataset , Seismic Network
    Format: ~1T
    Format: .mseed
    Format: XML
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  • 24
    facet.materialart.
    Unknown
    In:  Geofisica Pura e Applicata, Los Angeles California, 1 p., California Institute of Technology Pasadena, vol. 28, no. 6, pp. 1-10, pp. L24306, (ISBN: 0534351875, 2nd edition)
    Publication Date: 1954
    Keywords: Low velocity layer ; Seismology
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  • 25
    facet.materialart.
    Unknown
    In:  Bull. Geol. Soc. Am., Los Angeles California, 1 p., California Institute of Technology Pasadena, vol. 65, no. 6, pp. 1342, pp. L24306, (ISBN: 0534351875, 2nd edition)
    Publication Date: 1954
    Keywords: Seismology ; Source parameters ; Shear waves ; Polarization
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  • 26
    facet.materialart.
    Unknown
    California Institute of Technology Pasadena
    In:  Seismological Laboratory Bulletin, Los Angeles California, 1 p., California Institute of Technology Pasadena, vol. 1953, no. 6, pp. 98, pp. L24306, (ISBN: 0534351875, 2nd edition)
    Publication Date: 1954
    Keywords: Earthquake catalog ; Seismology ; Seismicity
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  • 27
    facet.materialart.
    Unknown
    In:  Bull. Geol. Soc. Am., Los Angeles California, 1 p., California Institute of Technology Pasadena, vol. 65, no. 6, pp. 337-347, pp. L24306, (ISBN: 0534351875, 2nd edition)
    Publication Date: 1954
    Keywords: Low velocity layer ; Seismology
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  • 28
    facet.materialart.
    Unknown
    In:  Bull. California Division of Mines San Francisco, Luxembourg, National Academy of Sciences of the USA, vol. 170, no. 3-5, pp. 19-25, pp. B05311, (ISSN: 1340-4202)
    Publication Date: 1954
    Keywords: Seismicity ; Seismology
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  • 29
    facet.materialart.
    Unknown
    In:  Trans. Am. Geophys. Union, Beijing, Pergamon, vol. 35, no. 3-4, pp. 979-987, pp. 1246
    Publication Date: 1954
    Keywords: Seismology ; Project report/description ; EOS
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  • 30
    facet.materialart.
    Unknown
    In:  Bull. Seism. Soc. Am., Tokyo, Railway Tech. Res. Inst., vol. 44, no. 4, pp. 39-56, pp. L06615, (ISSN: 1340-4202)
    Publication Date: 1954
    Keywords: Waves ; Seismology ; earth Core ; Travel time ; BSSA
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  • 31
    facet.materialart.
    Unknown
    Princeton Univ. Press
    In:  Princeton, New Jersey, 9 + 310 pp., Princeton Univ. Press, vol. 7, no. XVI:, pp. 385-389, (ISBN 0-12-305355-2)
    Publication Date: 1954
    Keywords: Textbook of geophysics ; Seismology ; Seismicity
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  • 32
    Publication Date: 2019-06-28
    Description: No abstract available
    Keywords: Aerodynamics
    Type: NACA-RM-SL54F28
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  • 33
    Publication Date: 2019-07-11
    Description: An investigation has been made in the Langley low-turbulence pressure tunnel of the aerodynamic characteristics of the NACA 0012, 64(sub 2)-015, and 64(sub 3)-018 airfoil sections. Data were obtained at Mach numbers from 0.3 to that for tunnel choke, at angles of attack from -2deg to 30deg, and with the surface. of each airfoil smooth-and with roughness applied at the leading edge.The Reynolds numbers of the tests ranged from 0.8 x 10(exp 6) to 4.4 x 10(exp 6). The results are presented as variations of lift, drag, and quarter-chord pitching-moment coefficients with Mach number.
    Keywords: Aerodynamics
    Type: NACA-RM-L54H06a
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  • 34
    Publication Date: 2019-07-12
    Description: The effects of deflecting full-span, constant-chord, leading-edge flaps, having either round or sharp leading edges, upon the lift, drag,. and pitching moment characteristics of a model of an interceptor-type aircraft have been determined experimentally at subsonic and supersonic speeds. Results indicate that the variations of lift with angle of attack and of pitching moment with lift were unaffected by either the shape of the flap leading edge or flap deflection. Deflection of the flaps having either a round or sharp leading edge increased the drag at zero lift at both subsonic and supersonic speeds. In spite of the increase in the drag at zero lift, however, deflection of the flaps increased the maximum lift-drag ratio at subsonic speeds and had no deleterious effect at supersonic speeds.
    Keywords: Aerodynamics
    Type: NACA-RM-SA54B16
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  • 35
    Publication Date: 2019-07-12
    Description: An investigation to determine the altitude performance of the J57-P-1 turbojet engine and components was conducted at the NACA Lewis altitude wind tunnel. Data were obtained over a corrected inboard rotor speed range from 56 to 106 percent of rated speed, with intercompressor bleeds both open and closed, at altitudes from 15,000 to 50,000 feet and at a flight Mach number of 0.81. The corresponding range of Reynolds number indices was from 0.858 to 0.213. All data presented were obtained with a fixed-area exhaust nozzle sized according to the manufacturer's specification. Over-all engine performance parameters are presented as functions of inboard rotor speed corrected on the basis of engine inlet temperature. Component parameters are presented as functions of their respective corrected rotor speeds. A tabulation of all performance data is included in addition to the graphical presentation. Corrected net thrust is unusually sensitive to changes in corrected inboard rotor speed in the high speed region. A change of 1 percent in speed, at sated speed, produced a change of 6 percent in corrected net thrust . At rated engine speed, increasing the altitude from 15,000 to 50,000 feet at a constant flight Mach number of 0.81 increased the specific fuel consumption 13 percent but did not affect corrected net thrust.
    Keywords: Aerodynamics
    Type: NACA-RM-SE54D30
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  • 36
    Publication Date: 2019-07-11
    Description: The effect on drag of positioning symmetrically mounted Douglas Aircraft Company, Inc. stores in pairs on a parabolic fuselage of fineness ratio 10.0 has been determined by flight tests of rocket-propelled, zero-lift models through a range of Mach number from 0.9 to 1.8. The stores were mounted in half-submerged positions and on pylons and were tested in three longitudinal locations on the fuselage with the forward position being located at the maximum diameter of the fuselage. The effects on drag of removing the half-submerged stores or extending them outward on pylons also was investigated by tests of models with half-submerged-store cavities on the fuselage. Two pylons differing in airfoil section and thickness were tested at the forward position of the stores on the fuselage with cavities. The half-submerged stores gave the smallest drag increments, which were approximately equal regardless of their respective longitudinal locations. Removing the half-submerged stores to expose the cavities increased the drag increments from two to three times. For the pylon-mounted stores, the store in the midposition had less drag than in the forward or rear positions at supersonic speeds. Adding the half-submerged-store cavities to the pylon-mounted-store configurations reduced the drag at the rear position between Mach numbers 0.95 and 1.50 and increased the drag at the midposition throughout the speed range. Changing from the 6-percent-thick flat pylon to the 10-percent-thick airfoil pylon increased the total drag slightly above Mach number 1.10. Good agreement was obtain& between the experimental and theoretical interference drag coefficients for the pylon-mounted stores (without fuselage cavities} in the three longitudinal locations tested at Mach numbers 1.2 and 1.5.
    Keywords: Aerodynamics
    Type: NACA-RM-L54E26
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  • 37
    Publication Date: 2019-08-14
    Description: The lift, pitching-moment, and drag characteristics of a missile configuration having a body of fineness ratio 9.33 and a cruciform triangular wing and tail of aspect ratio 4 were measured at a Mach number of 1.99 and a Reynolds number of 6.0 million, based on the body length. The tests were performed through an angle-of-attack range of -5 deg to 28 deg to investigate the effects on the aerodynamic characteristics of roll angle, wing-tail interdigitation, wing deflection, and interference among the components (body, wing, and tail). Theoretical lift and moment characteristics of the configuration and its components were calculated by the use of existing theoretical methods which have been modified for application to high angles of attack, and these characteristics are compared with experiment. The lift and drag characteristics of all combinations of the body, wing, and tail were independent of roll angle throughout the angle-of-attack range. The pitching-moment characteristics of the body-wing and body-wing-tail combinations, however, were influenced significantly by the roll angle at large angles of attack (greater than 10 deg). A roll from 0 deg (one pair of wing panels horizontal) to 45 deg caused a forward shift in the center of pressure which was of the same magnitude for both of these combinations, indicating that this shift originated from body-wing interference effects. A favorable lift-interference effect (lift of the combination greater than the sum of the lifts of the components) and a rearward shift in the center of pressure from a position corresponding to that for the components occurred at small angles of attack when the body was combined with either the exposed wing or tail surfaces. These lift and center-of-pressure interference effects were gradually reduced to zero as the angle of attack was increased to large values. The effect of wing-tail interference, which influenced primarily the pitching-moment characteristics, is dependent on the distance between the wing trailing vortex wake and the tail surfaces and thus was a function of angle of attack, angle of roll, and wing-tail interdigitation. Although the configuration at zero roll with the wing and tail in line exhibited the least center-of-pressure travel, the configuration with the wing and tail interdigitated had the least change in wing-tail interference over the angle-of-attack range. The lift effectiveness of the variable-incidence wing was reduced by more than 70 percent as a result of an increase in the combined angle of attack and wing incidence from 0 deg to 40 deg. The wing-tail interference (effective downwash at the tail) due to wing deflection was nearly zero as a result of a region of negative vorticity shed from the inboard portion of the wing. The lift characteristics of the configuration and its components were satisfactorily predicted by the calculated results, but the pitching moments at large angles of attack were not because of the influence of factors for which no adequate theory is available, such as the variation of the crossflow drag coefficient along the body and the effect of the wing downwash field on the afterbody loading.
    Keywords: Aerodynamics
    Type: NACA-RM-A54H27
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  • 38
    Publication Date: 2019-07-11
    Description: A flight test has been conducted to determine the longitudinal stability and control,characteristics of a 0.133-scale model of the Consolidated Vultee XFY-1 airplane without propellers for the Mach number range between 0.73 and 1.19.
    Keywords: Aerodynamics
    Type: NACA-RM-SL54B03A
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  • 39
    Publication Date: 2019-07-11
    Description: An investigation was conducted in the Langley high-speed 7- by 10-foot tunnel to determine effects of modifications to a bomb model (particularly with regard to drag) when mounted on a wing-fuselage model and tested at Mach numbers from 0.70 to 1.10. In addition, the static longitudinal stability characteristics of several configurations of a larger scale model of the bomb alone were obtained over a Mach number range from 0.50 to 0.95. The results obtained for the wing-fuselage-bomb model indicate that large reductions in installation drag were obtained for the wing-fuselage-bomb model when the flat nose of the basic bomb was replaced by rounded or pointed noses of various calibers. Shortening the mounting pylon gave further decreases in the installation drag. The tests of the bomb alone indicated that only the flat-nose configurations were stable over the greater part of the Mach number range. Nose-shape modifications which improved the drag also caused the bombs to become unstable at low angles of attack. The stability of the low-drag bomb configurations could be improved by lengthening the cylindrical portion of the body behind the center of gravity.
    Keywords: Aerodynamics
    Type: NACA-RM-SL54D30
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  • 40
    Publication Date: 2019-07-11
    Description: An investigation has been conducted in the Langley 8-foot transonic tunnel to determine the effects of several fuselage modifications on the transonic drag-rise characteristics of a 1/20-scale model of the Convair F-102 airplane. Tests covered an angle-of-attack range from 0deg to about 10deg and a Mach number range from 0.60 to 1.14. Results indicated that the transonic drag rise .for the basic F-102 airplane could be substantially reduced by extending the fuselage after-body approximately 8 percent of the fuselage length. Tests of other bodies indicated that a shorter (4-percent) afterbody extension may have a similar effect on the drag rise. Further improvement of the axial cross-sectional-area distribution of the 8-percent extended configuration through the addition of fuselage volume resulted in additional reductions in the drag rise at a Mach number of 1.0 and caused no or only slight drag penalties at the higher Mach numbers. The results of the present tests generally substantiate the area-rule concept with respect to the prediction of the transonic drag rise through the use of an equivalent-area body of revolution for a practical delta-wing airplane configuration.
    Keywords: Aerodynamics
    Type: NACA-RM-SL54K18a
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  • 41
    Publication Date: 2019-07-11
    Description: A low-speed wind-tunnel investigation has been made of some aspects of the aerodynamic problems associated with the use of air-to-air missiles when carried externally on aircraft. Measurements of the forces and moments on a missile model for a range of positions under the mid-semispan location of a 45deg sweptback wing indicated longitudinal and lateral forces with regard to both carriage and release of the missiles. Surveys of the characteristics of the flow field in the region likely to be traversed by the missiles showed abrupt gradients in both flow angularity and in local dynamic pressure. Through the use of aerodynamic data on the isolated missile and the measured flow-field characteristics, the longitudinal forces and moments acting on the missile while in the presence of the wing-fuselage combination could be estimated with fair accuracy. Although the lateral forces and moments predicted were qualitatively correct, there existed some large discrepancies in absolute magnitude.
    Keywords: Aerodynamics
    Type: NACA-RM-L54J20
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  • 42
    Publication Date: 2019-07-12
    Description: Experimental results showing the static longitudinal-stability and control characteristics of a model of a fighter airplane employing a low-aspect-ratio unswept wing and an all-movable horizontal tail are presented. The investigation was made over a Mach number range from 0.60 to 0.90 and from 1.35 to 1.90 at a constant Reynolds number of 2.40 million, based on the wing mean aerodynamic chord. Because of the location of the horizontal tail at the tip of the vertical tail, interference was noted between the vertical tail and the horizontal tail and between the wing and the horizontal tail. This interference produced a positive pitching-moment coefficient at zero lift throughout the Mach number range of the tests, reduced the change in stability with increasing lift coefficient of the wing at moderate lift coefficients in the subsonic speed range, and reduced the stability at low lift coefficients at high supersonic speeds. The lift and pitching-moment effectiveness of the all movable tail was unaffected by the interference effects and was constant throughout the lift-coefficient range of the tests at each Mach number except 1.90.
    Keywords: Aerodynamics
    Type: NACA-RM-SA54D05
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  • 43
    Publication Date: 2019-07-12
    Description: An investigation has been conducted in the Langley 4- by 4-foot supersonic pressure tunnel at a Mach number of 1.41 to determine the static stability and control and drag characteristics of a l/l5-scale model of the Grunman F9F-9 airplane. The effects of alternate fuselage shapes, wing camber, wing fences, and fuselage dive brakes on the aerodynamic characteristics were also investigated. These tests were made at a Reynolds number of 1.96 x l0 (exp 6) based on the wing mean aerodynamic chord of 0.545 foot. The basic configuration had a static margin of stability of 38.4 percent of the mean aerodynamic chord and a minimum drag coefficient of 0.049. For the maximum horizontal tail deflection investigated (-l0 deg), the maximum trim lift coefficient was 0.338. The basic configuration had positive static lateral stability at zero angle of attack and positive directional control throughout the angle-of-attack range investigated up to ll deg.
    Keywords: Aerodynamics
    Type: NACA-RM-SL54G08
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  • 44
    Publication Date: 2019-07-12
    Description: The longitudinal stability and control characteristics of a 1/30-scale model of the Republic XF-103 airplane were investigated in the Langley 8-foot transonic tunnel. The effect of speed brakes located at the end of the fuselage was also investigated. The main part of the investigation was made with internal flow in the model, but some data were obtained with no internal flow. The longitudinal stability and control at transonic-speeds appeared satisfactory. The transonic drag rise was small. The speed brakes had no adverse effects on longitudinal stability.
    Keywords: Aerodynamics
    Type: NACA-RM-SL54H24
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  • 45
    Publication Date: 2019-07-12
    Description: A 1/5-scale, rocket-propelled model of the Convair F-102 configuration was tested in free flight to determine zero-lift drag at Mach numbers up to 1.34 and at Reynolds numbers comparable to those of the full-scale airplane. This large-scale model corresponded to the prototype airplane and had air flow through the duct. Additional zero-lift drag tests involved a series of small equivalent bodies of revolution which were launched by means of a helium gun. The several small-scale models tested corresponded to: the basic configuration, the 1/5-scale rocket-propelled model configuration, a 2-foot (full-scale) fuselage-extension configuration, and a 7-foot (full-scale) fuselage-extension configuration. Models designed to correspond to the area distribution at a Mach number of 1.0 were flown for each of these 'shapes and, in addition, models designed to correspond to the area distribution at a Mach number of 1.2 were flown for the 1/5-scale rocket-propelled model and the 7-foot-fuselage-extension configuration. The value of external pressure drag coefficient (including base drag) obtained from the large-scale rocket model was 0.0190 at a Mach number of 1..05 and the corresponding values from the equivalent-body tests varied from 0.0183 for the rocket-propelled model shape to 0.0137 for the 7-foot-fuselage-extension configuration. From the results of tests of equivalent bodies designed to correspond to the area distribution at a Mach number of 1.0, it is evident that the small changes in shape incorporated in the basic and 2-foot-fuselage-extension configurations from that of the rocket-propelled model configuration will provide no significant change in pressure drag. On the other hand, the data from the 7-foot-fuselage-extension model indicate a substantial reduction in pressure drag at transonic speeds.
    Keywords: Aerodynamics
    Type: NACA-RM-SL54DO9b
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  • 46
    Publication Date: 2019-07-12
    Description: The transonic longitudinal aerodynamic characteristics of a 0.0858-scale model of the Lockheed XF-104 airplane have been obtained from tests at the Langley 16-foot transonic tunnel. The results of the investigation provide some general information applicable to the transonic properties of thin, low-aspect-ratio, unswept wing configurations utilizing a high horizontal tail . The model employs a horizontal tail mounted at the top of the vertical tail and a wing with an aspect ratio of 2.5, a taper ratio of 0.385, and 3.4-percent-thick airfoil sections. The lift, drag, and static longitudinal pitching moment were measured at Mach numbers from 0.80 t o 1.09 and angles of attack from -2.5 deg to 22.5 deg. Some of the dynamic longitudinal stability properties of the airplane have been predicted from the test results. In addition, some visual flow studies on the wing surfaces obtained at Mach numbers of 0.80 and 1.00 are included. Results of the investigation show that the transonic rise in drag coefficient at zero lift is about 0.030. At high angles of attack, the model becomes longitudinally unstable at Mach numbers from 0.80 t o 0.90, whereas a reduction in static stability is experienced when very high angles of attack are reached at Mach numbers above 0.90. Longitudinal dynamic stability calculations show that the longitudinal control is good at angles of attack below the unstable break in the static pitching-moment curves, but a typical corrective control applied after the occurrence of neutral stability has little effect in averting pitch-up.
    Keywords: Aerodynamics
    Type: NACA-RM-SL54K19a
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  • 47
    Publication Date: 2019-07-12
    Description: The effects of elevator deflections from 0deg to -20deg on the force and moment characteristics of a 1/20-scale model of the Convair F-102 airplane with chordwise fences have been determined a t Mach numbers from 0.6 to 1.1 for angles of attack up to 20deg in the Langley 8-foot transonic tunnel. The configuration exhibited static longitudinal stability throughout the range tested, although a mild pitch-up tendency was indicated a t Mach numbers from 0.85 to 0.95. Elevator pitch effectiveness decreased rapidly between the Mach numbers of 0.9 and 1.0, however, no complete loss or reversal was indicated for all conditions tested. Because of the type of longitudinal control used, trimming the configuration from the zero elevator condition resulted in substantial decreases in lift-curve slope and maximum lift-drag ratio and increases in drag due to lift. The drag at zero lift, drag due to lift, and trim drag were high for this configuration.
    Keywords: Aerodynamics
    Type: NACA-RM-SL54G15
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  • 48
    Publication Date: 2019-07-12
    Description: A 1/10-scale rocket model of the Lockheed XF-104 with faired inlets has been flown over a Mach number range from 0.80 to 1.45 to determine low-lift drag and a limited amount of stability data. The center-of-gravity locations were 4.0 and 1.5 percent of the mean aerodynamic chord before and after sustainer firing, respectively. Oscillations induced by pulse rockets were used to determine stability data. The external transonic drag coefficient increased from a value of 0.0160 at Mach number 0.80 to a maximum of 0.0432 near Mach number 1-13, with a drag rise Mach number of about 0.93. At Mach numbers where it could be determined, the model exhibited stable dynamic and static stability characteristics at low lift.
    Keywords: Aerodynamics
    Type: NACA-RM-SL54E14
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  • 49
    Publication Date: 2019-07-12
    Description: A flight test has been conducted to determine the longitudinal stability and control characteristics of a 0.133-scale model of the Consolidated Vultee XFY-1 airplane with windmilling propellers for the Mach number range between 0.70 and 1.13. The variation of lift-curve slope C(sub L(sub alpha) with Mach number was gradual with a maximum value of 0.074 occurring at a Mach number of 0.97. Propellers had little effect upon the values of lift-curve slope or the linearity of lift coefficient with angle of attack. At lift coefficients between approximately 0.25 and 0.45 with an elevon angle of approximately -l0 deg, there was a region of neutral longitudinal stability at Mach numbers below 0.93 introduced by the addition of windmilling propellers. Below a lift coefficient of 0.10 and above a lift coefficient of 0.45, the model was longitudinally stable throughout the Mach number range of the test. There was a forward shift in the aerodynamic center of about 3-percent mean aerodynamic chord introduced by the addition of propellers. The aerodynamic center as determined at low lift moved gradually from a value of 28.5-percent mean aerodynamic chord at a Mach number of 0.75 to a value of 47-percent mean aerodynamic chord at a Mach number of 1.10. There was an abrupt decrease in pitch damping between Mach numbers of 0.88 and 0.99 followed by a rapid increase in damping to a Mach number of 1.06. The propellers had little effect upon the pitch damping characteristics . The transonic trim change was a large pitching-down tendency with and without windmilling propellers. The elevons were effective pitch controls throughout the speed range; however, their effectiveness was reduced about 50 percent at supersonic speeds. The propellers had no appreciable effect upon the control effectiveness.
    Keywords: Aerodynamics
    Type: NACA-RM-SL54F11
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  • 50
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 87 (1954) 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 51
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Vitamin D2 konnte durch Behandlung mit Bortrifluorid-ätherat unter Verschiebung des gesamten Trien-Systems in ein neues Isomeres umgelagert werden, das als iso-Tachysterin bezeichnet wird.Weiterhin konnte ein iso-Vitamin D2 partialsynthetisch gewonnen werden, wobei der aus Vitamin D2 durch Abbau erhaltene C21-Aldehyd Verwendung fand.Durch Oxydation von iso-Tachysterin sowie durch Umlagerung und Oxydation von iso-Vitamin D2 wurden schließlich identische Trien-ketone erhalten. Die Konfiguration der beiden neuen Isomeren wird im Zusammenhang mit den Ultraviolett-Absorptionsspektren diskutiert.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 993-997 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Literaturangabe, nach der 1.2-Diphenyl-inden bei der Ozonisierung in anomaler Reaktion o-Benzoyl-benzoin liefert, hat sich als irrtümlich erwiesen; es bildet vielmehr das normale Ozonid.
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  • 53
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1007-1010 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus den Blättern von Sol. acaule wurde ein neues Glykoalkaloid, Solacaulin, isoliert. Solacaulin liefert bei der Hydrolyse 1 Mol. Solanidin, 1 Mol. d-Glucose und 2 Moll. d-Xylose.
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  • 54
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1011-1018 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird eine Methode zur Darstellung der ersten Glieder von vinylenhomologen Pyrrolaldehyden beschrieben. Diese Verbindungen wurden u.a. charakterisiert durch ihre 2.4-Dinitro-phenylhydrazone. Außerdem konnten mit Hilfe dieser Aldehyde neue unsymmetrische Polymethinfarbstoffe dargestellt werden.
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  • 55
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    Keywords: Chemistry ; Inorganic Chemistry
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    Topics: Chemistry and Pharmacology
    Notes: Es werden unsymmetrische Methinfarbstoffe beschrieben, die durch Kondensation von α-Furyl-polyenalen mit Pyrrolen bzw. mit α-Phenyl-indol entstehen. Die Absorptionsspektren wurden qualitativ und z.Tl. quantitativ vermessen.
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  • 56
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1051-1056 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Neun bi-homologe Reihen, teilweise bis zu einer Alkylkettenlänge von zweimal 20 Kohlenstoff-Atomen, wurden synthetisiert. Der Verlauf der Schmelzpunktskurven dieser bihomologen Reihen wird besprochen.
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  • 57
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die symmetrischen 1.3-Dioxy-3.3-dialkyl-propane wurden durch Reduktion der in der VIII. Mitteil. beschriebenen 3-Oxy-3.3-dialkyl-propionsäuren mit LiAlH4 dargestellt.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954) 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1082-1083 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus den Samen von Lunaria biennis wird neben Lunarin, C25H31O4N3, ein mit diesem isomeres Alkaloid Lunaridin isoliert.
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  • 60
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1093-1098 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Reaktion von α-Amino-acyl-thiophenolen mit Schwefel-wasserstoff entstehen die den α-Aminosäuren analogen α-Amino-thiosäuren. Die kristallisierten Analogen des Glycins, Alanins, Valins, Isoleucins und Methionins sind Zwitterionen mit charakteristischen UV-Spektren. Die höheren α-Amino-thiosäuren vermögen mit ihren schwefelfreien Stammsubstanzen Mischkristalle zu bilden.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1119-1123 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Kondensation von o-Phenylendiamin-hydrochlorid mit Dimethyl-alloxan führt zum 1.3-Dimethyl-alloxazin. Bei der alkalischen Spaltung entsteht als Endprodukt die 3-Methylamino-chinoxalin-carbonsäure-(2).Die entsprechende neutrale Kondensation liefert 3-Oxy-chinoxalin carbonsäure (2) N-methyl-amid, aus dem mit Alkali die 3-Oxychinoxalin-carbonsäure-(2) hervorgeht.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1138-1141 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In 4-Stellung substituierte N-Acetyl-glucosamine geben die Morgan-Elson-Reaktion nicht.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1162-1163 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Das Produkt der alkalischen Verseifung von Vinylacetat in Wasser unter 15°, C8H14O4, wird als Acetyl-aldoxan erkannt; bei entsprechender alkalischer Verseifung von Vinylpropionat entsteht Propicnyl-aldoxan.
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  • 64
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    Keywords: Chemistry ; Inorganic Chemistry
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    Topics: Chemistry and Pharmacology
    Notes: Bei der Umsetzung von Acyl-aryl-acetonitrilen mit Guanidin bildeten sich nicht die erwarteten Pyrimidinderivate, sondern 1.3.5-Triazine. Auch wenn man die Anilinverbindung des α-Formyl-α-p-chlorphenyl-acetonitrils mit Guanidin reagieren lieβ, erhielt man ein Triazin; aus den Anilinderivaten der homologen Acyl-Verbindungen bildeten sich die entsprechenden Pyrimidine. Andere Reaktionsprodukte der Ketogruppe der Acyl-aryl-acetonitrile, wie das Oxim, das Semicarbazon und das Phenylhydrazon konnten nicht isoliert werden, weil sofort ein Ringschluß mit der Nitrilgruppe eintrat, wie durch die Aufnahme der UR-Spektren nachgewiesen wurde.Die Umsetzung der Nitrile mit Hydroxylamin führte zu den Amino-bzw. Imino-isoxazolen, die durch Säuren zu 5-Oxy-isoxazolen verseift wurden.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1197-1200 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ausgehend von der Furylvaleriansäure wurde über das Furocycloheptenon ein Oxy-furo-tropolon synthetisch gewonnen.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1201-1205 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Während Alkylhydroperoxyde bei der katalytischen Zersetzung mit CoII-Salzen symmetrische Dialkyl-peroxyde geben, setzen sie sich i. Ggw. von Cycloalkenen und Hydroaromaten bei der gleichen Behandlung zu gemischten Dialkyl-peroxyden um.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1219-1225 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Umsetzung von Acetylen-Kohlenwasserstoffen R-C≡C-R' mit Peressigsäure erfolgt neben der oxydativen Spaltung zu R-CO2H+R'-CO2H eine mit Oxydation verknüpfte Umlagerung des Kohlenstoff-Gerüstes zu disubstituierten Essigsäuren RR'CH·CO2H. Aus Di-acetylen-Verbindungen erhält man α,α'-di-substituierte Dicarbonsäuren. Diese Reaktion, die vermutlich über die Ketene RR'C=C=O verläuft und in ihrem Wesen der Schröterschen und der Buckleyschen Umlagerung verwandt erscheint, ist ein neuer Weg zur Darstellung α-verzweigter Fettsäuren.
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    Notes: Die bi-homologe Reihe der symmetrischen Phenyl-dialkyl-methanole wurde bis zum Phenyl-di-eikosyl-methanol durch Kondensation von Phenyl-magnesiumbromid mit symmetrischen Dialkyl-ketonen hergestellt.
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    Keywords: Chemistry ; Inorganic Chemistry
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    Topics: Chemistry and Pharmacology
    Notes: Die Kondensation von 3-Chlor-butanon-(2) bzw.α-Brom-propanal mit Thiosemicarbazid führt in schwach saurem Medium zu den entsprechenden Thiosemicarbazonen Ia und Ib, die sich in alkoholischer Lösung zum 2-Amino-5.6-dimethyl- (IIa) bzw. 2-Amino-6-methyl-1.3.4-thiodiazin (IIb) cyclisieren. Letztere lagern sich beim Erhitzen mit starker Salzsäure in das 3-Amino-4.5-dimethyl (IVa) bzw. 3-Amino-5-methyl-thiazolon-(2)-imid (IVb) um. Beide Verbindungen werden durch Salpetrige Säure desaminiert. Der Nachweis der hierbei gebildeten, substituierten 2-Amino-thiazole erfolgt durch Diazotierung und Kupplung zu Azofarbstoffen. Bei Einwirkung von Benzaldehyd gehen die beiden obengenannten Thiodiazine in die Benzalverbindungen des 4.5-Dimethyl- (Va) bzw. 5-Methyl-thiazolyl-(2)-hydrazins (Vb) über. Auch diese lagern sich unter dem Einfluß von H-Ionen in die entsprechenden Thiazolon-(2)-imide um.Zum Strukturbeweis der bei den einzelnen intramolekularen Umlagerungen auftretenden Endprodukte werden diese auf anderem Wege synthetisch dargestellt. Ferner wird eine Synthese des 5.5'-Dimethyl-azothiazols beschrieben.Als brauchbarer Nachweis für Thiazolyl-(2)-hydrazine hat sich deren Dehydrierung mit Quecksilberoxyd unter Bildung der entsprechenden Thiazolderivate erwiesen.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1179-1183 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird ein technisch anwendbares Verfahren zur Darstellung von Chinolinaldehyden durch katalytische Oxydation der entsprechenden Methylchinoline beschrieben.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1184-1186 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Versuchsbedingungen für die Bildung der einzelnen bei der Einwirkung von Schwefelsäure auf 2-Acetylamino-thiophen entstehenden Sulfonsäuren wurden ausgearbeitet und diese in Form der freien Säuren isoliert. Aus 2-Amino-thiophen-disulfonsäure-(3.5) wurde über die Diazoverbindung Thiophen-disulfonsäure-(3.5), aus 2-Acetylamino-sulfonsäure-(5) die 2-Amino-thiophen-sulfonsäure-(5) dargestellt. Diese unterscheidet sich in ihren chemischen Eigenschaften deutlich von der Sulfanilsäure, dem entsprechenden Benzolderivat.
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    Keywords: Chemistry ; Inorganic Chemistry
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    Topics: Chemistry and Pharmacology
    Notes: Aus der 2-Acetylamino-thiophen-sulfonsäure-(5) wurde das Sulfonsäurechlorid dargestellt, aus dem das Sulfonamid, das Sulfanilid, das Sulfonamidopyridin-Derivat und der Sulfonsäure-äthylester erhalten wurden.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1449-1460 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reine geminale Chlor-nitroso-Verbindungen sowie durch Radikal-Reaktionen erzeugte Gemische dieser Stoffe werden durch katalytische Hydrierung, Lithiumaluminiumhydrid, Natriumborhydrid oder durch rotes Licht mit zum Teil sehr guten Ausbeuten zu den entsprechenden Ketoximen reduziert.
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurden die Additionsprodukte von Phenanthrenchinon an d-Xylal und an Cellobial hergestellt.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1511-1512 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Herstellung des Diphenylena mit verbesserter Ausbeute wird beschrieben.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1513-1540 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Enolisierbare β-Diketone zeigen, [amphotere Halochromie], d. h. das Absorptions-Maximum der Enolform wird sowohl in alkalischer Lösung wie auch in starker Schwefelsäure nach längeren Wellen verschoben (aci- bzw. Onium-Halochromie). Bei trans-fixierten β-Diketonen geben die Absorptionskurven im pH-Bereich zwischen etwa +15 und -10 durch einen mehr oder weniger ausgeprägten isosbestischen Punkt; bei offenkettigen und, [cis-fixierten] β-Diketonen überlagert das Keto-Enol-Gleichgewicht die amphoteren Neutralisierungs-Gleichgewichte. Durch Isolierung und Analyse kristalliner Perchlorate und Sulfate lieβ sich erweisen, daβ sich mit den genannten Säuren Enol-Oxonium-Salze bilden. Diese besitzen ein ähnliches mesomeres Chromophor-System wie die Enolate, was die Ähnlichkeit der Absorptions-Kurven erklärt.Die, Onium-[Halochromie] von enolisierbaren β-Benzoyl-ketonen führt zu einer größeren bathochromen Verschiebung und Intensitäts-Erhöhung des Absorptions-Maximums als die, aci-[Halochromie] der gleichen β-Diketone; als Grund dafür wird angesehen, daβ sich nur im ersten Falle die Phenylringe am Zustandekommen des neuen Chromophors beteiligen.Aus den optischen Daten in Schwefelsäuren verschiedener Konzentration wird die, [Basizität] der β-Diketone berechnet.Beim Stehenlassen der stark sauren Lösungen der β-Diketone treten Änderungen der Spektren ein, die auf einer Säure-Spaltung in je eine Molekel Mono-Keton und Carbonsäure beruhen.
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Bromessigester-Kondensation läβt sich mit 1.3-Dioxo-8.10-dimethyl-dekalin ähnlich wie mit Dimedon ausführen. Sie führt zu einer C-substituierten Diketo-dekalin-essigsäure, die der Santonin-Reihe nahesteht. Deren Reduktion zu der wichtigen Monoketosäure gelingt katalytisch über die Enol-Acetate. Weiter wird gefunden, daβ sich auch die Enol-Äther cyclischer 1.3-Diketone katalytisch zu Monoketonen reduzieren lassen.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1373-1377 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Anlagerung von Chlorjod an 1.2-Dialkoxy-äthene werden 1.2-Dichlor-1.2-dialkoxy-äthane und elementares Jod erhalten. In Gegenwart von Pyridin bilden sich äquimolare Mengen N,N'-[1.2-Dialkoxy-äthylen]-bis-pyridiniumchloride und -bis-pyridiniumjodide.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1711-1713 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die in der Literatur als „Dinaphthol“ bezeichnete, durch Schmelzen von 2-Oxy-naphthaldehyd-(1) mit Kaliumhydroxyd bzw. durch Erhitzen von 1-Diazo-naphthol (2) mit methanolischer Kalilauge erhältliche Substanz ist in Wirklichkeit Bis-[2-oxy-naphthyl-(1)]-methan.
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Für die Enthalogenierung der vicinalen Dibromide mit Jodid-Ion wird ein kationischer Mechanismus vorgeschlagen. Die erhaltenen Versuchsergebnisse sprechen dafür, daß α,β-Dibrom-propyl-phenol-äther mit Jodid-Ionen unter Abspaltung des α-ständigen Brom-Atoms Carbenium-β-bromo-jodo-jodide ergeben, die z. Tl. intramolekular den Polyhaloid-Komplex abspalten und in die entsprechenden Olefine übergehen, z.Tl. sich aber einem Propenylphenoläther-Molekül unter Bildung von Dimeren anlagern. Das im letztgenannten Fall zuerst entstehende Verkettungsprodukt ergibt erst bei Berührung mit Wasser das entsprechende halogenfreie 2-Methyl-3-äthyl-1-phenyl-indan.
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    Keywords: Chemistry ; Inorganic Chemistry
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    Topics: Chemistry and Pharmacology
    Notes: Die Enthalogenierung der α,β-Dibrom-propylphenoläther mit Kupfer verläuft anscheinend über das Radikal Ar-CH-CHBr-CH3 und führt teils zu dem entsprechenden Propenylphenoläther, teils zu einem 3α-brom-substituierten Methronol.Aus dem α,β-Dibromid des Isoeugenol-benzyläthers wurde mit Kupfer 3α-Brom-diisoeugenol-dibenzyläther (Va) erhalten, aus wel-chem das trans-cis-Racemat des Diisoeugenols (VIIa) hergestellt wurde.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1752-1759 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird gezeigt, daß in der aus Cyclopentadien-kalium (bzw. Cyclopentadienyl-magnesiumbromid) und Kohlendioxyd hergestellten Cyclopentadien-carbonsäure die Carboxygruppe nicht, wie bisher angenommen, in 5- sondern in 1-Stellung haftet.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1547-1552 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch katalytische Hydrierung von Lactosazon erhält man nebeneinander Lactosamin (2-Desoxy-2-amino-lactose) und Isolactosamin (1-Desoxy-1-amino-lactulose). Nach Peracetylierung und anschließender Ammonolyse wurden N-Acetyl-lactosamin (2-Acetamino-lactose) und N-Acetyl isolactosamin (1 Acetamino-lactulose) chromatographisch getrennt. Die so synthetisch gewonnene 2-Acetamino-lactose ist in allen Eigenschaften identisch mit dem durch partielle Hydrolyse von Blutgruppen-Substanzen erhaltener Disaccharid.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 1600-1604 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Unter Verwendung von Methylanilino-magnesiumbromid als Kondensationsmittel wurde aus Korksäure-dinitril das 1-Cyan-cycloheptanon-(2) in 75-proz. Ausbeute gewonnen, das u. a. durch Hydrazinhydrat in 5-Amino-3.4-pentamethylen-pyrazol, durch Monobromaceton cyclisierend in 5-Methyl-2.3-pentamethylen-furan übergeführt wurde.
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  • 85
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 35-37 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Natriumverbindung anmethylierter Saccharose reagiert in ätherischer Lösung mit Dimethylsulfat schnell und vollständig unter Bildung von Oktamethyl-saccharose.
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  • 86
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die bei der Reaktion von [Co(CO)4]2 mit Aminen und Alkoholen beobachtete Valenzdisproportionierung des Carbonylmetalls: \documentclass{article}\pagestyle{empty}\begin{document}$$ 3{\rm{Co}}^0 \to {\rm{Co}}^{ \oplus \oplus } + 2{\rm{Co}}^ \odot $$\end{document} tritt sinngemäß beim tetrameren Kobalt-tricarbonyl ein. Entsprechend: \documentclass{article}\pagestyle{empty}\begin{document}$$ 3\left[ {{\rm{Co}}\left( {{\rm{CO}}} \right)_3 } \right]_4 + 24{\rm{B}} \to 4\left[ {{\rm{CoB}}_6 } \right]\left[ {{\rm{Co}}\left( {{\rm{CO}}} \right)_4 } \right]_2 + 4{\rm{CO}}\left( {{\rm{B}} = {\rm{N - oder O - Base}}} \right) $$\end{document}Außer Aminen und Alkoholen sind andere N- und O-Basen, wie z. B. Nitrile, Säureamide, Ketone und cyclische Äther zu dieser Umsetzung befähigt. Zwischenstufen der Reaktion mit CO-haltigen Kationen konnten nicht nachgewiesen werden. Stärker basische Amine, wie z. B. Methylamin, Dimethylamin und Piperidin, werden durch das bei der Umsetzung entbundene CO carbonyliert.Der Chemismus der Reaktion wird mit der Struktur der mehrkernigen Carbonyle in Zusammenhang gebracht.
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  • 87
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 38-45 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In der Tetramethyl-d-glucose und Tetramethyl-d-fructose konnte der Wasserstoff des Lactolhydroxyls durch Alkalimetall ersetzt werden. Konfiguration und Reaktionsfähigkeit der Alkalimetallverbindungen wurden durch Umsetzung mit Methyljodid und Dimethylsulfat, die zu den entsprechenden Glykosiden führte, ermittelt. Die Kalium-Verbindung der 2.3.4.6-Tetramethyl-d-glucose reagierte mit α-1-Tosyl-, α-1-Brom- und β-1-Chlor-2.3.4.6-Tetramethyl-d-glucose unter Bildung von Disacchariden des Trehalosetypus.
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  • 88
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird eine allgemeine Methode zur Darstellung der 5-Amino-1.2.4-thiodiazole beschrieben, die sich auf die Umsetzung von N-Halogen-amidinen mit Rhodaniden gründet. Auf die Eigenschaften dieser Stoffe, einige Derivate - darunter die Sulfanilamide - und Abbaureaktionen wird näher eingegangen.
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  • 89
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Umsetzung der 5-Amino-1.2.4-thiodiazole mit Methyljodid oder durch Ringschluß-Synthesen werden die im Kern methylierten Imino-thiodiazoline erhalten. Die exocyclisch methylierten Amine sind über die 5-Chlor-Verbindung zugänglich, gelegentlich auch durch Umlagerung aus dem entsprechenden Thiodiazolin. Beide Klassen, von deren Hauptvertretern eine Anzahl Substitutions- und Abbauprodukte hergestellt wurden, unterscheiden sich charakteristisch in ihren Basizitäten, UV-Spektren und Polarogrammen. Aus den Befunden wird geschlossen, daß die tautomeren 5-Amino-thiodiazole als Amine vorliegen.
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  • 90
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Darstellung des 2-[d-gluco-Pentaoxy-pentyl]-4-phenyl-thiazols beschrieben.Aus der Literatur sind zahlreiche Verbindungen bekannt, bei denen der Einbau einer Zuckerkette in heterocyclische Ringsysteme in der Weise erfolgte, daß ein, zwei oder auch drei Kohlenstoffatome des Zuckermoleküls dem Heterocyclus angehören. Wir verweisen in diesem Zusammenhang auf das kürzlich erschienene Referat „Heterocyclische Verbindungen aus Zuckern“ von H. Vogel1). Danach und nach unserer Kenntnis ist es bisher nicht gelungen, einfache Zucker in den Thiazolkern einzubauen. Lediglich in einem Fall war es durch Kondensation von einfachen Zuckern mit Cystein möglich, zu Zuckerabkömmlingen der Thiazolidin-carbonsäure (4)2) zu kommen.Für die von uns geplanten Untersuchungen war die Arbeit von C. Neuberg und H. Wolff3) von Interesse, wonach bei der Einwirkung von Phenyl- bzw. Allyl-senföl auf d-Glucosamin in glatter Reaktion 1-Phenyl (bzw. Allyl)-2-mercapto-4-[d-arabo-tetraoxy-butyl]-imidazol entsteht. Als Zwischenprodukt bildet sich hierbei N-[Anilino-thioformyl]-[bzw. N-(Allylamino-thioformyl])-d-glucosamin, das anschließend unter Wasseraustritt in das Imidazolderivat übergeht. Demnach reagiert bei gleichzeitiger Anwesenheit einer Sulfhydryl- und einer sekundaren Aminogruppe bevorzugt die letztere. Würde sich die SH-Gruppe an der Wasserabspaltung beteiligen, so müßte ein Thiazolylzucker entstehen, in dem die C-Atome 1 und 2 des Glucosemoleküls dem Thiazolring angehören. Eine derartige Kondensation ließ sich bisher nicht realisieren. Ein weiteres Beispiel dafür, daß das lactolische Hydroxyl des Zuckers vornehmlich mit einer Aminogruppe reagiert, ist die Bildung des d-Glucose-thioharnstoffs4) aus der d-Glucose und Thioharnstoff in Gegenwart von Salzsäure.
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  • 91
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die drei stereoisomeren Dihydro-santene werden dargestellt und optisch untersucht. Ein durch katalytische Hydrierung von Santen erhaltenes Dihydro-santen erweist sich in bezug auf die Methylgruppen als endo-cis-Verbindung. Die Anlagerung von Wasserstoff erfolgt sterisch “von der Brücke her” und stellt einen weiteren Fall von “exo-Addition” vor.
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  • 92
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 179-186 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Während bisher ausschließlich die synthetisch schwer zugängliche 4-Nitro-salicylsäure als Ausgangsmaterial zur Herstellung von Dialkylaminoalkyl-estern der 4-Amino- und 4-Alkamino-2-alkoxybenzoesäuren diente, wird jetzt die Herstellung dieser Verbindungen ausgehend von der Stammsubstanz, der heute leicht erhältlichen 4-Amino-salicylsäure (PAS), beschrieben.
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  • 93
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Das noch nicht näher charakterisierte Proazulen der Schafgarbe (“M-Proazulen”) läßt sich durch alkalische Verseifung über eine Zwischenstufe in eine intensiv blaue, unbeständige Cham-Azulencarbonsäure überführen, die einen gut kristallsierenden, tiefblauen, stabilen Methylester gibt, dessen Analyse zeigte daß dem zugrundeliegenden Cham-Azulen - in Übereinstimmung mit einer kürzlich erschienen Arbeit von A. Meisels und A. Weizmann1) - die Formel C14H16 zukommt. Die Cham-Azulencarbonsäure geht unter den Bedingungen der Wasserdampfdestillation leicht in Cham-Azulen über.
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  • 94
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Orthoesterbildung mit cis-Phloroglucit können Carboxygruppen vorübergehend gegen den Angriff von metallorganischen Verbindungen geschützt werden. Am Beispiel eines Halb-Orthoesters der Bernsteinsäure wird die präparative Bedeutung dieser Maskierung gezeigt.
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  • 95
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die p-Nitro-homohydratropasäure wird sowohl durch Umlagerung des 1-[p-Nitro-phenyl] -3-diazo-butanons-(2), als auch durch Verseifung und Decarboxylierung des α-[p-Nitro-benzyl]-α eyan-propion, säureesters, der durch Kondensation von p-Nitro-benzylchlorid mit Natrium-α-cyan-propionsäure-ester gut zugänglich ist, gewonnen. Für die m-Verbindung wird nur der zweite Weg beschrieben.
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  • 96
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 211-215 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 2.3.4.6-Tetraacetyl-β-d-glucose läßt sich nach der Trifluoressigsäure-anhydrid-Methode von Stacey mit Benzoesäure zu einem Gemisch von α- und β-2.3.4.6-Tetraacetyl-benzoyl-d-glucose benzoylieren. Das Verhältnis α:β-Verbindung hängt von den Versuchsbedingungen ab. Aus Benzyl-β-d-glucosid ist durch Umsetzung mit Trifluoressigsäure-anhydrid und Natriumtrifluoracetat das 2.3.4.6- Tetrakis-trifluoracetyl-benzyl-β-d-glucosid vomSchmp. 102° leicht darstellbar; die Benzyl-Gruppe konnte aber durch katalytische Hydrierung nicht entfernt werden. Falls dies gelänge, wäre es durch Veresterung mit Carbonsäuren in 1-Stellung nach Stacey und Umesterung durch Erwärmen mit Methanol möglich gewesen, in 1-Stellung beliebig veresterte Glucosen (und andere Zucker) herzustellen. Schließlich wird die Pentakis-trifluoracetyl-β-d-glucose beschrieben.
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  • 97
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 209-211 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung von 3.3-Dimethyl-1.5-diphenyl-pentan-dion-(1.5) aus β.β-Dimethyl-glutarsäure auf zwei verschiedenen Wegen wird beschrieben.
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  • 98
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Spaltung der p-Nitro-hydratropasäure in die optischen Antipoden beschrieben. Weiter werden sowohl die racemischen als auch die optisch-aktiven p-Amino-, p-Oxy- und p-Chlor-hydratropasäuren gewonnen.
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  • 99
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 221-222 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung des α-[m-Nitro-phenyl]-äthylamins und seine Spaltung in optische Antipoden wird beschrieben. Die Rotationsdispersion des Hydrochlorids und der Acetylverbindung wird mitgeteilt.
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  • 100
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 232-233 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die katalytische Hydrierung des 1-Cyanäthyl-naphthols-(2) (I) führt zu 1.2.3.4-Tetrahydro-5.6-benzochinolin (III).
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