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  • 2020-2023  (649)
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  • 1
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    Seasonal Differences in the Attenuation of Polar Trace Organics in the Hyporheic Zone of an Urban Stream (2022)
    Details
    Publication Date: 2022-04-04
    Description: Attenuation of trace organic compounds (TrOCs) in a river occurs to a large extent in its hyporheic zone. A major part of the attenuation of polar TrOCs is of microbial origin. As microbial activity depends on temperature and redox conditions, seasonal differences in TrOC attenuation are likely. We investigated TrOC attenuation at a river influenced by treated wastewater during two sampling campaigns, one in summer and one in winter. In addition to redox conditions and temperature, we also determined residence times of porewater in sediment using three methods: (a) non‐parametric deconvolution of electrical conductivity time series, (b) the model VFLUX 2.0 based on temperature time series (only summer), and (c) applying Darcy's law to differences in hydraulic heads (only summer). Contrary to our expectations, we found higher attenuation for 12 out of 18 TrOCs in winter, while three TrOCs were better attenuated in summer. Sediment conditions varied between seasons as more of the top sandy layer with a higher hydraulic permeability accumulated on the river bed in summer. As a result, residence times in the sediment were shorter in summer. In winter, longer residence times, lower temperatures, and a steeper oxygen gradient in sediment coincided with higher TrOC attenuation. Further research is needed to understand our unexpected findings and underlying mechanisms.
    Description: Key Points: The attenuation of 12 out of 18 trace organic compounds (TrOCs) in the hyporheic zone was higher in winter while three TrOCs were attenuated better in summer. Residence times in sediment were longer and more diverse in winter. The extent of the oxic sediment was similar between seasons but the gradient from the oxic to anoxic zone was steeper in winter.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: EC | H2020 | H2020 Priority Excellent Science | H2020 Marie Skłodowska‐Curie Actions (MSCA) http://dx.doi.org/10.13039/100010665
    Description: University of Western Australia ‐ University Postgraduate Award
    Description: Australian Government Research Training Program Scholarship
    Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347
    Description: https://doi.org/10.18728/igb-fred-578.0
    Keywords: ddc:628.162
    Language: English
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  • 2
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    Iron Exports From Catchments Are Constrained by Redox Status and Topography (2022)
    Details
    Publication Date: 2022-04-04
    Description: Fe(III) hydroxides stabilize organic carbon (OC) and P in soils. Observations of rising stream Fe concentrations are controversially posited to result from a flushing of iron‐rich deeper soil layers or a decrease of competing electron acceptors inhibiting Fe reduction (NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ and SO42− $\mathrm{S}{{\mathrm{O}}_{4}}^{2-}$). Here, we argue that catchment topography constrains the release of Fe, OC, and P to streams. We therefore incubated organic topsoil and mineral subsoil and modified the availability of NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$. We found that Fe leaching was highest in topsoil. Fe, OC, and P released at quantities proportional to their ratios in the source soil. Supply of NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ reduced Fe leaching to 18% and increased pore water OC:Fe and P:Fe ratios. Subsoil, however, was an insignificant Fe source (〈0.5%). Here, the leached quantities of Fe, OC and P were highly disproportionate to the soil source with an excess of released OC and P. We tested if experimental findings scale up using data from 88 German catchments representing gradients in NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ concentration and topography. Average stream Fe concentrations increased with decreasing NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ and were high in catchments with shallow topography where high groundwater levels support reductive processes and topsoils are hydrologically connected to streams; but Fe concentrations were low in catchments with steep topography where flow occurs primarily through subsoils. OC:Fe and P:Fe ratios in the streams similarly varied by NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ and topography. This corroborates the findings from the laboratory experiment and suggests that catchment topography and competing electron acceptors constrain the formation of Fe‐reducing conditions and control the release of Fe, OC, and P to streams.
    Description: Plain Language Summary: Iron is the second most abundant metal in the crust; its cycle is tightly connected to those of carbon, oxygen, and sulfur. The oxidized form (FeIII) is almost insoluble, but Fe can be mobilized by complexation or microbial Fe reduction. Both processes depend on availability of organic C. We found that Fe concentrations in streams were constrained by the topography of catchments and NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ abundance. Shallower catchments are characterized by higher groundwater tables connecting the organic topsoils efficiently to streams. NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ suppresses Fe reduction as a competing electron acceptor to Fe. We conclude that trends in soil wetness or atmospheric N deposition can change the stability of Fe and thus the release of PO43− $\mathrm{P}{{\mathrm{O}}_{4}}^{3-}$ and harmful metals to surface waters.
    Description: Key Points: Organic topsoils leach substantial amounts of Fe when incubated in the absence of NO3, a competing electron acceptor that inhibits Fe reduction. Shallow catchments with fluvially coupled topsoils and low NO3 availability release 200 fold more Fe than steep ones with high NO3 abundance. Catchment topography and NO3 availability explain 62%–64% of the variability of Fe concentration and OC:Fe and P:Fe ratios across 88 streams.
    Description: EFRE‐Europe
    Description: https://doi.org/10.4211/hs.43601618877945c5a46b715aa98db729
    Keywords: ddc:551.9
    Language: English
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  • 3
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    Feasibility of pXRF to evaluate chosen heavy metals in soil highly influenced by municipal waste disposal—A monitoring study of a former sewage farm (2022)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2022-04-04
    Description: Sewage disposal onto agricultural land may result in the high accumulation of organic wastes, which questions the applicability of typical elemental analysis used for the soil components. To monitor the contamination status of agricultural soils at a former sedimentation basin, after the long‐term cessation of wastewater irrigation, 110 locations (15–20 cm depth) and 4 boreholes (up to 100 cm depth) were sampled to determine pH, loss on ignition, and concentration of Ni, Cu, Pb, Zn, and Cr. Additionally, the applicability of portable X‐ray fluorescence (pXRF) for the soil samples highly influenced by the organic wastes was evaluated. The study revealed the presence of a relatively homogenous sewage waste layer (depth of 20 cm), characterized by slightly acidic to neutral pH (6.3–7.5), high organic matter (OM) accumulation (up to 49%), and elevated concentration (mg kg −1) ranges between: Pb (5–321), Cu (31–2828), Ni (10–193), Cr (14–966), and Zn (76–6639). The pXRF analysis revealed metal concentration increase in mineral samples (up to 50%). The regression models and correction factors demonstrated high correlation and significance of pXRF measurement with response to increasing OM content, with the lowest r 2 = 0.86 obtained for Ni. Correlation of pXRF and AES measurement illustrated element‐dependent response for soils high in organics. Zn, Cu, and Cr pXRF analysis led to a slight underestimation in lower values, but overall good correlations (0.87; 0.89; and 0.88 respectively). Pb and Ni pXRF measurement revealed higher deviation from the reference in both lower and higher concentrations (0.74 and 0.70, respectively).
    Description: German Federation of Industrial Research Associations http://dx.doi.org/10.13039/501100002723
    Description: Federal Ministry for Economic Affairs and Energy http://dx.doi.org/10.13039/501100006360
    Keywords: ddc:577.14
    Language: English
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  • 4
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    The Goldilocks Zone in Cooling Demand: What Can We Do Better? (2022)
    Details
    Publication Date: 2022-04-07
    Description: The higher frequency and intensity of sustained heat events have increased the demand for cooling energy across the globe. Current estimates of summer‐time energy demand are primarily based on Cooling Degree Days (CDD), representing the number of degrees a day's average temperature exceeds a predetermined comfort zone temperature. Through a comprehensive analysis of the historical energy demand data across the USA, we show that the commonly used CDD estimates fall significantly short (±25%) of capturing regional thermal comfort levels. Moreover, given the increasingly compelling evidence that air temperature alone is not sufficient for characterizing human thermal comfort, we extend the widely used CDD calculation to heat index, which accounts for both air temperature and humidity. Our results indicate significant mis‐estimation of regional thermal comfort when humidity is ignored. Our findings have significant implications for the security, sustainability, and resilience of the grid under climate change.
    Description: Plain Language Summary: Hotter summer days and more frequent and intense heatwaves are causing a sharp rise in demand for air conditioning across the globe. Accurate estimation of demand for space cooling is an integral component of resilient planning, operation, and management of the grid. One widely used metric for characterizing this demand is the Cooling Degree Days (CDD), which is calculated by measuring the difference between the mean daily temperature and a pre‐defined base temperature that represents a “comfort zone.” In this study, we analyze historical data on climate and energy demand and find that the most frequently used base temperature of 65°F in CDD calculations leads to mis‐characterizing comfort zones across different geographic areas in the United States. This can cause significant under‐ or over‐estimations of cooling energy demand. Moreover, we extend the temperature‐based CDD calculations to also account for the role of humidity and demonstrate the cost of ignoring humidity in CDD calculations under present and future climate conditions.
    Description: Key Points: Analysis of electricity demand shows that the widely used Cooling Degree Days (CDD) estimates fall short of capturing regional thermal comfort zones. Estimates of air conditioning penetration and affordability based on traditional calculation of CDD can lead to significant misestimation. Extending CDD calculations to include humidity improves the characterization of climate‐demand nexus under present and future climate.
    Description: National Science Foundation (NSF) http://dx.doi.org/10.13039/100000001
    Keywords: ddc:333.79
    Language: English
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  • 5
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    Vertically Divergent Responses of SOC Decomposition to Soil Moisture in a Changing Climate (2022)
    Details
    Publication Date: 2022-04-07
    Description: The role of soil moisture for organic matter decomposition rates remains poorly understood and underrepresented in Earth System Models (ESMs). We apply the Dual Arrhenius Michaelis‐Menten (DAMM) model to a selection of ESM soil temperature and moisture outputs to investigate their effects on decomposition rates, at different soil depths, for a historical period and a future climate period. Our key finding is that the inclusion of soil moisture controls has diverging effects on both the speed and direction of projected decomposition rates (up to ±20%), compared to a temperature‐only approach. In the top soil, the majority of these changes is driven by substrate availability. In deeper soil layers, oxygen availability plays a relatively stronger role. Owing to these different moisture controls along the soil depth, our study highlights the need for depth‐resolved inclusion of soil moisture effects on decomposition rates within ESMs. This is particularly important for C‐rich soils in regions which may be subject to strong future warming and vertically opposing moisture changes, such as the peat soils at northern high latitudes.
    Description: Plain Language Summary: Soils contain a lot of carbon (C). Earth System Models (ESMs) predict that the amount of C released from soils into the atmosphere as CO2 will increase in response to increased warming and microbial activity. Soil moisture also controls microbial C decomposition, but most ESMs do not yet describe this process very well. In this study we apply a simple equation to different ESMs, to see how both temperature and soil moisture change microbial decomposition under future climate. First, we show that the speed of C released into the atmosphere changes when we include soil moisture changes, compared to what is expected due to warming alone. Second, we found that the future speed at which carbon that can be decomposed in the topsoil mainly depends on how much carbon microbes have access to, but that in the deeper soil this process becomes much more affected by the absence/presence of oxygen. Including these soil moisture interactions in ESMs for different soil depths is important to predict whether soils will store more or less C in the future. Our findings are particularly relevant for high latitude soils which store large amounts of C, will warm fast, and experience frequent (re)wetting and drying.
    Description: Key Points: Considering soil moisture effects can change modeled decomposition rates by up to ±20% compared to considering only temperature effects. The majority of these changes are driven by substrate availability, in particular in the top soil. In the subsoil, oxygen availability becomes an increasingly important factor.
    Description: Norwegian Research Council
    Description: https://doi.org/10.5281/zenodo.5654554
    Keywords: ddc:631.4
    Language: English
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  • 6
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    Uncertainty in Aerosol Optical Depth From Modern Aerosol‐Climate Models, Reanalyses, and Satellite Products (2022)
    Details
    Publication Date: 2022-04-01
    Description: Despite the implication of aerosols for the radiation budget, there are persistent differences in data for the aerosol optical depth (τ) for 1998–2019. This study presents a comprehensive evaluation of the large‐scale spatio‐temporal patterns of mid‐visible τ from modern data sets. In total, we assessed 94 different global data sets from eight satellite retrievals, four aerosol‐climate model ensembles, one operational ensemble product, two reanalyses, one climatology and one merged satellite product. We include the new satellite data SLSTR and aerosol‐climate simulations from the Coupled Model Intercomparison Project Phase 6 (CMIP6) and the Aerosol Comparisons between Observations and Models Phase 3 (AeroCom‐III). Our intercomparison highlights model differences and observational uncertainty. Spatial mean τ for 60°N – 60°S ranges from 0.124 to 0.164 for individual satellites, with a mean of 0.14. Averaged τ from aerosol‐climate model ensembles fall within this satellite range, but individual models do not. Our assessment suggests no systematic improvement compared to CMIP5 and AeroCom‐I. Although some regional biases have been reduced, τ from both CMIP6 and AeroCom‐III are for instance substantially larger along extra‐tropical storm tracks compared to the satellite products. The considerable uncertainty in observed τ implies that a model evaluation based on a single satellite product might draw biased conclusions. This underlines the need for continued efforts to improve both model and satellite estimates of τ, for example, through measurement campaigns in areas of particularly uncertain satellite estimates identified in this study, to facilitate a better understanding of aerosol effects in the Earth system.
    Description: Plain Language Summary: Aerosols are known to affect atmospheric processes. For instance, particles emitted during dust storms, biomass burning and anthropogenic activities affect air quality and influence the climate through effects on solar radiation and clouds. Although many studies address such aerosol effects, there is a persistent difference in current estimates of the amount of aerosols in the atmosphere across observations and complex climate models. This study documents the data differences for aerosol amounts, including new estimates from climate‐model simulations and satellite products. We quantify considerable differences across aerosol amount estimates as well as regional and seasonal variations of extended and new data. Further, this study addresses the question to what extent complex climate models have improved over the past decades in light of observational uncertainty.
    Description: Key Points: Present‐day patterns in aerosol optical depth differ substantially between 94 modern global data sets. The range in spatial means from individual satellites is −11% to +17% of the multi‐satellite mean. Spatial means from climate model intercomparison projects fall within the satellite range but strong regional differences are identified.
    Description: Hans‐Ertel‐Center for Weather Research
    Description: Collaborative Research Centre 1211
    Description: Max‐Planck‐Institute for Meteorology
    Keywords: ddc:551.5
    Language: English
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  • 7
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    Assessing Volcanic Controls on Miocene Climate Change (2022)
    Details
    Publication Date: 2022-03-25
    Description: The Miocene period saw substantially warmer Earth surface temperatures than today, particularly during a period of global warming called the Mid Miocene Climatic Optimum (MMCO; ∼17–15 Ma). However, the long‐term drivers of Miocene climate remain poorly understood. By using a new continuous climate‐biogeochemical model (SCION), we can investigate the interaction between volcanism, climate and biogeochemical cycles through the Miocene. We identify high tectonic CO2 degassing rates and further emissions associated with the emplacement of the Columbia River Basalt Group as the primary driver of the background warmth and the MMCO respectively. We also find that enhanced weathering of the basaltic terrane and input of explosive volcanic ash to the oceans are not sufficient to drive the immediate cooling following the MMCO and suggest that another mechanism, perhaps the change in ocean chemistry due to massive evaporite deposition, was responsible.
    Description: Plain Language Summary: The Miocene period was much warmer than today, with the Mid Miocene Climatic Optimum (MMCO, roughly 17–15 million years ago) especially warm. Due to the high surface temperatures, comparisons to projected climatic conditions as a result of anthropogenic climate change have been drawn. However, the drivers of climate during the Miocene are not well understood. By using a new type of climate model, we investigate the impact volcanic eruptions had on the period, and link the extreme warmth of the MMCO with greenhouse gas release from the eruption of the Columbia River Basalts Group (CRBG). We find weathering of the CRBG does not explain the cooling at the end of the MMCO, and so discuss other potential explanations such as evaporite deposition.
    Description: Key Points: A new climate‐biogeochemical model allows investigation of drivers of climate change in the Miocene. Columbia River Basalt Group (CRBG) degassing is sufficient to have caused the Mid Miocene Climatic Optimum (MMCO). Weathering of CRBG insufficient to drive cooling after the MMCO. This may be linked to evaporite deposition and changes to marine chemistry.
    Description: UK Natural Environment Research Council
    Description: French Research Agency (ANR)
    Keywords: ddc:551
    Language: English
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  • 8
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    An Image Segmentation Approach for the Detection of Small-scale Magnetic Anomalies (2022)
    Details
    Publication Date: 2022-03-25
    Description: Due to the still enormous burden of unexploded ordnance (UXO) in the subsurface worldwide, the safe recovery of a wide variety of buried weapons and ammunition requires efficient and reliable detection methods. Using a deep learning approach applied to magnetic field data distributed areal along the surface, we aim to achieve a more accurate localization of UXO and small magnetically effective objects in general by detecting the specific signature of their magnetic anomaly. To investigate the applicability of this approach, we developed a deep convolutional neural network that performs image segmentation in different potential measurement scenarios. In this process, the sought small-scale target signals should be distinguished from different background fields containing, e.g., several types of noise. For this purpose, extensive synthetic data sets were generated first using numerical simulations of the magnetic dipole fields of multiple objects. The resulting multi-dipole scenarios and corresponding masks are then passed to the network, which is trained on a test and validation set to produce a representative model for the trained simulation examples. At the end of the training process, this model is supposed to be able to predict yet unknown examples from an evaluation set. Subsequently, the prediction quality of the resulting model needs to be analyzed to fine-tune the parameters of the assumed network architecture or even the architecture itself. The poster we present deals with the generation and preprocessing of appropriate training data, the applied network architecture, and preliminary results of the first evaluation stages.
    Description: poster
    Language: English
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  • 9
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    Faulting and Magmatic Accretion Across the Overlapping Spreading Center Between Vance Segment and Axial South Rift, Juan de Fuca Ridge (2022)
    Details
    Publication Date: 2022-03-24
    Description: Plate divergence along mid‐ocean ridges is accommodated through faulting and magmatic accretion, and, at overlapping spreading centers (OSC), is distributed across two curvilinear overlapping ridge axes. One‐meter resolution bathymetry acquired by autonomous underwater vehicles, combined with distribution and ages of lava flows, is used to: (a) analyze the spatial and temporal distribution of flows, faults, and fissures in the OSC between the distal south rift zone of Axial Seamount and the Vance Segment, (b) locate spreading axes, (c) calculate extension, and (d) determine the proportion of extension accommodated at the surface by faults and fissures versus volcanic extrusion over a period of ∼1300–1450 years. Our study reveals that in the recent history of the ridges, extension over a distance of 14 km across the Axial/Vance OSC was asymmetric in proportion and style: faults and fissures across 1–2 km of the Vance axial valley accommodated ∼3/4 of the spreading, whereas dike‐fed eruptions contributed ∼1/4 of the extension and occurred across 4 km of the south rift of Axial Seamount.
    Description: Plain Language Summary: Along mid‐ocean ridges, oceanic plates separate through the formation and growth of faults and the emplacement of dikes supplying lava flows. Where segments overlap in a zone of separation, these processes are distributed along two spreading axes separated by 2–30 km kilometers. We combine 1‐m resolution bathymetry collected by autonomous underwater vehicles and the age of large lava flows to (a) analyze the distribution of faults and lava flows where Axial Seamount overlaps with the Vance Segment, (b) define the current plate boundary, (c) calculate the speed of plate separation, and (d) determine the proportion and locations of fault extension versus flow emplacement. Our study shows that during the last ∼1300–1450 years, fault formation and growth along the Vance Segment are the main contributor to plate separation. In contrast, the emplacement of dikes and lava flows along Axial Seamount account only for ∼1/4 of the plate separation.
    Description: Key Points: Autonomous underwater vehicle mapping of an overlapping spreading center reveals the proportion of faulting and eruptions that occurred during the last ∼1300–1450 years. Faulting at the Vance Segment accommodates ∼3/4 of the spreading and magmatic accretion along Axial Seamount south rift accounts for ∼1/4. The spreading axis is 〈250 m wide along the Vance Segment but ∼4 km wide along the south rift of Axial Seamount.
    Description: David and Lucile Packard Foundation (PF) http://dx.doi.org/10.13039/100000008
    Keywords: ddc:551.8 ; ddc:551.13
    Language: English
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  • 10
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    Rock Glacier Characteristics Under Semiarid Climate Conditions in the Western Nyainqêntanglha Range, Tibetan Plateau (2022)
    Details
    Publication Date: 2022-03-24
    Description: Rock glaciers are receiving increased attention as a potential source of water and indicator of climate change in periglacial landscapes. They consist of an ice‐debris mixture, which creeps downslope. Although rock glaciers are a wide‐spread feature on the Tibetan Plateau, characteristics such as its ice fraction are unknown as a superficial debris layer inhibits remote assessments. We investigate one rock glacier in the semiarid western Nyainqêntanglha range (WNR) with a multi‐method approach, which combines geophysical, geological and geomorphological field investigations with remote sensing techniques. Long‐term kinematics of the rock glacier are detected by 4‐year InSAR time series analysis. The ice content and the active layer are examined by electrical resistivity tomography, ground penetrating radar, and environmental seismology. Short‐term activity (11‐days) is captured by a seismic network. Clast analysis shows a sorting of the rock glacier's debris. The rock glacier has three zones, which are defined by the following characteristics: (a) Two predominant lithology types are preserved separately in the superficial debris patterns, (b) heterogeneous kinematics and seismic activity, and (c) distinct ice fractions. Conceptually, the studied rock glacier is discussed as an endmember of the glacier—debris‐covered glacier—rock glacier continuum. This, in turn, can be linked to its location on the semiarid lee‐side of the mountain range against the Indian summer monsoon. Geologically preconditioned and glacially overprinted, the studied rock glacier is suggested to be a recurring example for similar rock glaciers in the WNR. This study highlights how geology, topography and climate influence rock glacier characteristics and development.
    Description: Plain Language Summary: Climate change has begun to impact all regions of our planet. In cold regions, such as high‐mountain areas, rising temperatures lead to massive melting of glaciers. Besides this evident loss of ice, permafrost, a long‐term ice resource hidden in the subsurface, has started to thaw. Rock glaciers as visible permafrost‐related landforms consist of an ice‐debris mixture, which makes them creep downslope. Due to this movement and their recognizable shape, rock glaciers are permafrost indicators in high‐mountain areas. We investigate one rock glacier in the western Nyaingêntanglha Range (Tibetan Plateau) using field and remote sensing methods to understand its development and to know the current state of its ice core. Our main outcome is, that the heterogeneous creeping behavior, the properties of the debris cover as well as the internal distribution of ice are the results of a continuous development from a glacier into today's rock glacier. In particular, the high ice content in particular sections points to such a glacial precondition. The debris layer covering the internal ice attenuates the effect of climate warming. This makes the rock glacier and similar rock glaciers found in the northern part of the mountain range important future water resources for the semiarid region.
    Description: Key Points: Geophysical and remote sensing methods in concert reveal the morphostructure, ice fraction, and kinematics of the studied rock glacier. Rock glacier characteristics are controlled by geology, topography and climate on the Tibetan Plateau. The studied rock glacier is conceptually interpreted as the endmember of a glacier—debris‐covered glacier—rock glacier continuum.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.31 ; ddc:555
    Language: English
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  • 11
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    Effects of CO2 and Ocean Mixing on Miocene and Pliocene Temperature Gradients (2022)
    Details
    Publication Date: 2022-03-28
    Description: Cenozoic climate changes have been linked to tectonic activity and variations in atmospheric CO2 concentrations. Here, we present Miocene and Pliocene sensitivity experiments performed with the climate model COSMOS. The experiments contain changes with respect to paleogeography, ocean gateway configuration, and atmospheric CO2 concentrations, as well as a range of vertical mixing coefficients in the ocean. For the mid‐Miocene, we show that the impact of ocean mixing on surface temperature is comparable to the effect of the possible range in reconstructed CO2 concentrations. In combination with stronger vertical mixing, relatively moderate CO2 concentrations of 450 ppmv enable global‐mean surface, deep‐water, and meridional temperature characteristics representative of mid‐Miocene Climatic Optimum (MMCO) reconstructions. The Miocene climate shows a reduced meridional temperature gradient and reduced seasonality. In the case of enhanced mixing, surface and deep ocean temperatures show significant warming of up to 5–10°C and an Arctic temperature anomaly of 〉12°C. In the Pliocene simulations, the impact of vertical mixing and CO2 is less important for the deep ocean, which we interpret as a different sensitivity dependence on the background state and mixed layer dynamics. We find a significant reduction in surface albedo and effective emissivity for either a high level of atmospheric CO2 or increased vertical mixing. Our mixing sensitivity experiments provide a warm deep ocean via ocean heat uptake. We propose that the mixing hypothesis can be tested by reconstructions of the thermocline and seasonal paleoclimate data indicating a lower seasonality relative to today.
    Description: Plain Language Summary: Cenozoic climate changes have been associated with tectonic changes and altered atmospheric CO2 concentrations. Here, we present Miocene and Pliocene computer simulations where we changed paleogeography, ocean gateways, and atmospheric CO2 concentrations as well as vertical mixing in the ocean. We show that the effect of ocean mixing on temperature is comparable to the respective effect of a possible range of CO2 concentrations. In combination with stronger vertical mixing, relatively moderate CO2 concentrations of 450 ppmv allow surface and deep‐water temperatures representative for reconstructions of the climate optimum of the mid‐Miocene. In the Pliocene simulations, the influence of vertical mixing and CO2 is less important than in the Miocene. We provide a possible mechanism of ocean heat absorption, albedo, and emissivity changes including a deeper oceanic mixing layer and a lower seasonality in the Miocene compared to today.
    Description: Key Points: Miocene experiment with standard mixing and atmospheric CO2 of 600 ppm captures large‐scale temperature characteristics of the mid‐Miocene. With enhanced ocean mixing the temperature characteristics and meridional temperature gradient can be reproduced with a CO2 level of 450 ppm. Miocene shows a strong warming at polar latitudes and reduced seasonality, vertical mixing, and CO2 are less important for the Pliocene.
    Description: Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research (AWI) http://dx.doi.org/10.13039/501100003207
    Description: Helmholtz Association (亥姆霍兹联合会致力) http://dx.doi.org/10.13039/501100009318
    Description: Helmholtz Climate Initiative RE‐KLIM
    Keywords: ddc:550.78
    Language: English
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  • 12
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    Blaubeuren, Cloppenburg, and Machtenstein—Three recently recognized H‐group chondrite finds in Germany with distinct terrestrial ages and weathering effects (2022)
    Details
    Publication Date: 2022-03-29
    Description: In the last 7 years, three meteorites (Blaubeuren, Cloppenburg, and Machtenstein) found in Germany were identified as chondrites. Two of these rocks had been recovered from the impact sites decades ago but were not considered to be meteorites. The aim of this study is to fully characterize these three meteorites. Based on the compositional data on the silicates, namely olivine and low‐Ca pyroxene, these meteorites fit nicely within the H‐group ordinary chondrites. The brecciated texture of Blaubeuren and Cloppenburg (both H4‐5) is perfectly visible, whereas that of Machtenstein, officially classified as an H5 chondrite, is less obvious but was detected and described in this study. Considering chondrites in general, brecciated rocks are very common rather than an exception. The bulk rock degree of shock is S2 for Blaubeuren and Machtenstein and S3 for Cloppenburg. All samples show significant features of weathering. They have lost their original fusion crust and more than half (W3) or about half (W2‐3) of their original metal abundances. The oxygen isotope compositions of the three chondrites are consistent with those of other H chondrites; however, the Cloppenburg values are heavily disturbed and influenced by terrestrial weathering. This is supported by the occurrence of the very rare hydrated iron phosphate mineral vivianite (Fe2+Fe2+2[PO4]2·8H2O), which indicates that the chondrite was weathered in a very wet environment. The terrestrial ages of Blaubeuren (~9.2 ka), Cloppenburg (~5.4 ka), and Machtenstein (~1.8 ka) show that these chondrites are very similar in their degree of alteration and terrestrial age compared to meteorite finds from relatively wet terrestrial environments. They still contain abundant metal, although, as noted, the oxygen isotope data indicate substantial weathering of Cloppenburg. The bulk compositions of the three meteorites are typical for H chondrites, although terrestrial alteration has slightly modified the concentrations, leading in general to a loss of Fe, Co, and Ni due to preferential alteration of metals and sulfides. As exceptions, Co and Ni concentrations in Machtenstein, which has the shortest terrestrial age, are typical for H chondrites. The chemical data show no enrichments in Ba and Sr, as is often observed in different meteorite groups of desert finds.
    Description: European Regional Development Fund http://dx.doi.org/10.13039/501100008530
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:549.112
    Language: English
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    Investigating the Basal Shear Zone of the Submarine Tuaheni Landslide Complex, New Zealand: A Core‐Log‐Seismic Integration Study (2022)
    Details
    Publication Date: 2022-03-29
    Description: Although submarine landslides have been studied for decades, a persistent challenge is the integration of diverse geoscientific datasets to characterize failure processes. We present a core‐log‐seismic integration study of the Tuaheni Landslide Complex to investigate intact sediments beneath the undeformed seafloor as well as post‐failure landslide deposits. Beneath the undeformed seafloor are coherent reflections underlain by a weakly‐reflective and chaotic seismic unit. This chaotic unit is characterized by variable shear strength that correlates with density fluctuations. The basal shear zone of the Tuaheni landslide likely exploited one (or more) of the low shear strength intervals. Within the landslide deposits is a widespread “Intra‐debris Reflector”, previously interpreted as the landslide's basal shear zone. This reflector is a subtle impedance drop around the boundary between upper and lower landslide units. However, there is no pronounced shear strength change across this horizon. Rather, there is a pronounced reduction in shear strength ∼10–15 m above the Intra‐debris Reflector that presumably represents an induced weak layer that developed during failure. Free gas accumulates beneath some regions of the landslide and is widespread deeper in the sedimentary sequence, suggesting that free gas may have played a role in pre‐conditioning the slope to failure. Additional pre‐conditioning or failure triggers could have been seismic shaking and associated transient fluid pressure. Our study underscores the importance of detailed core‐log‐seismic integration approaches for investigating basal shear zone development in submarine landslides.
    Description: Plain Language Summary: Submarine landslides move enormous amounts of sediment across the seafloor and have the potential to generate damaging tsunamis. To understand how submarine landslides develop, we need to be able to image and sample beneath the seafloor in regions where landslides have occurred. To image beneath the seafloor we generate sound waves in the ocean and record reflections from those waves, enabling us to produce “seismic images” of sediment layers and structures beneath the seafloor. We then use scientific drilling to sample the sediment layers and measure physical properties. In this study, we combine seismic images and drilling results to investigate a submarine landslide east of New Zealand's North Island. Drilling next to the landslide revealed a ∼25 m‐thick layer of sediment (from ∼75–95 m below the seafloor) that has strong variations in sediment strength and density. We infer that intervals of relatively low strength within this layer developed into the main sliding surface of the landslide. Additionally, results from within the landslide suggest that the process of landslide emplacement has induced a zone of weak sediments closer to the seafloor. Our study demonstrates how combining seismic images and drilling data helps to understand submarine landslide processes.
    Description: Key Points: We integrate scientific drilling data with seismic reflection data to investigate the submarine Tuaheni Landslide Complex. Basal shear zone of the landslide likely exploited a relatively low shear strength interval within an older (buried) mass transport deposit. Landslide emplacement seems to have induced an additional weak zone that is shallower than the interpreted base of the landslide deposit.
    Description: Marsden Fund (Royal Society of New Zealand Marsden Fund) http://dx.doi.org/10.13039/501100009193
    Description: European Consortium for Ocean Research Drilling
    Description: International Ocean Drilling Program, Science Support Program
    Description: New Zealand Ministry for Business Innovation and Employment
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: https://doi.pangaea.de/10.1594/PANGAEA.928073
    Keywords: ddc:622.15 ; ddc:551
    Language: English
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  • 14
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    Probability Distributions of Radiocarbon in Open Linear Compartmental Systems at Steady‐State (2022)
    Details
    Publication Date: 2022-06-26
    Description: Radiocarbon (14C) is commonly used as a tracer of the carbon cycle to determine how fast carbon moves between different reservoirs such as plants, soils, rivers, or oceans. However such studies mostly emphasize the mean value (as Δ14C) of an unknown probability distribution. We introduce a novel algorithm to compute Δ14C distributions from knowledge of the age distribution of carbon in linear compartmental systems at steady‐state. Our results demonstrate that the shape of the distributions might differ according to the speed of cycling of ecosystem compartments and their connectivity within the system, and might contain multiple peaks and long tails. The distributions are also sensitive to the variations of Δ14C in the atmosphere over time, as influenced by the counteracting anthropogenic effects of fossil‐fuel emissions (14C‐free) and nuclear weapons testing (excess 14C). Lastly, we discuss insights that such distributions can offer for sampling and design of experiments aiming to capture the precise variance of Δ14C values present in the multi‐compartmental ecosystems.
    Description: Plain Language Summary: Radiocarbon (14C) is a radioactive isotope of carbon prominent in environmental sciences for tracing the dynamics of ecosystems, especially as recent changes in atmospheric radiocarbon allow tracking excess 14C created by nuclear weapons testing in the atmosphere on timescales shorter than what can be determined using radioactive decay. For climate change mitigation, a crucial uncertainty is the time carbon captured through photosynthesis spends in ecosystems before being released. For this purpose, radiocarbon can be valuable as a biological tracer; however, it is necessary to accurately link the real age of carbon and its radiocarbon age, as they usually differ. Forests and soils are open systems, connecting components with intrinsically different cycling timescales, so that the mean age comes from an age distribution that is usually unknown. Here, we developed an algorithm to compute the 14C contents for models consisting of multiple interconnected carbon pools. Our approach offers more accurate estimations of the mean 14C content of the system and computations of the distribution of 14C within the system at different points in time. Results obtained from this method can provide additional insights on the dynamics of the carbon cycle in multiple compartments, and can help to better interpret observations.
    Description: Key Points: Probability distributions of radiocarbon in ecosystem compartments can be derived from carbon age distributions. The shape of these distributions vary according to the speed of carbon cycling and the year of observation. Probability distributions of radiocarbon provide insights to study carbon dynamics and to interpret radiocarbon data.
    Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347
    Description: Max‐Planck‐Gesellschaft (MPG) http://dx.doi.org/10.13039/501100004189
    Description: https://doi.org/10.5281/zenodo.6373329
    Keywords: ddc:551.9
    Language: English
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    A Combined Cosmogenic Nuclides Approach for Determining the Temperature‐Dependence of Erosion (2022)
    Details
    Publication Date: 2022-06-26
    Description: Physical weathering in cold, steep bedrock hillslopes occurs at rates that are thought to depend on temperature, but our ability to quantify the temperature‐dependence of erosion remains limited when integrating over geomorphic timescales. Here, we present results from a 1D numerical model of in‐situ cosmogenic 10Be, 14C, and 3He concentrations that evolve as a function of erosion rate, erosion style, and ground surface temperature. We used the model to explore the suitability of these nuclides for quantifying erosion rates in areas undergoing non‐steady state erosion, as well as the relationship between bedrock temperature, erosion rate, and erosional stochasticity. Our results suggest that even in stochastically eroding settings, 10Be‐derived erosion rates of amalgamated samples can be used to estimate long‐term erosion rates, but infrequent large events can lead to bias. The ratio of 14C to 10Be can be used to evaluate erosional stochasticity, and to determine the offset between an apparent 10Be‐derived erosion rate and the long‐term rate. Finally, the concentration of 3He relative to that of 10Be, and the paleothermometric interpretations derived from it, are unaffected by erosional stochasticity. These findings, discussed in the context of bedrock hillslopes in mountainous regions, indicate that the 10Be‐14C‐3He system in quartz offers a method to evaluate the temperature‐sensitivity of bedrock erosion rates in cold, high‐alpine environments.
    Description: Plain Language Summary: All mountains erode, but not all mountains erode in the same way and at the same rate. In cold mountainous landscapes, temperature is thought to be an important control on erosion. Previous research suggests that rocks fracture by frost most effectively at temperatures between −3°C and −8°C, and that the warming and thawing of permanently frozen ground (permafrost) destabilizes hillslopes and leads to more and larger rockfalls. However, our ability to test these hypotheses is limited, due to difficulties in measuring or estimating erosion rates and linking them with the temperatures that rocks experience. In this paper we present the results of a computer modeling study that tests the suitability of geochemical tools as measures of erosion rate, erosion style, and long‐term bedrock temperature. We find that these geochemical tracers, called cosmogenic nuclides, can be used to determine erosion rates, even in places that are prone to rare rockfalls, together with the long‐term bedrock temperature. They are therefore uniquely suitable for evaluating the link between temperatures and erosion rates in cold bedrock hillslopes over long timescales.
    Description: Key Points: Cosmogenic 10Be, 14C, and 3He is used to determine erosion rates, erosion styles, and bedrock temperatures in cold regions. 14C/10Be ratios of surface samples reflect the depth at which material was previously eroded, allowing for determination of erosion style. 14C/10Be ratios combined with 10Be‐derived erosion rates improve erosion rate estimates in stochastically eroding environments.
    Description: European Research Council Horizon 2020
    Description: https://doi.org/10.5880/GFZ.3.3.2022.001
    Keywords: ddc:551
    Language: English
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    An Adaptive Hybrid Vertical Equilibrium/Full‐Dimensional Model for Compositional Multiphase Flow (2022)
    Details
    Publication Date: 2022-06-26
    Description: Efficient compositional models are required to simulate underground gas storage in porous formations where, for example, gas quality (such as purity) and loss of gas due to dissolution are of interest. We first extend the concept of vertical equilibrium (VE) to compositional flow, and derive a compositional VE model by vertical integration. Second, we present a hybrid model that couples the efficient compositional VE model to a compositional full‐dimensional model. Subdomains, where the compositional VE model is valid, are identified during simulation based on a VE criterion that compares the vertical profiles of relative permeability at equilibrium to the ones simulated by the full‐dimensional model. We demonstrate the applicability of the hybrid model by simulating hydrogen storage in a radially symmetric, heterogeneous porous aquifer. The hybrid model shows excellent adaptivity over space and time for different permeability values in the heterogeneous region, and compares well to the full‐dimensional model while being computationally efficient, resulting in a runtime of roughly one‐third of the full‐dimensional model. Based on the results, we assume that for larger simulation scales, the efficiency of this new model will increase even more.
    Description: Key Points: A compositional vertical equilibrium model is coupled to its full‐dimensional counterpart. A criterion is developed to adaptively identify and assign regions where the vertical equilibrium model is applicable during simulation. A test case of hydrogen storage in a heterogeneous porous aquifer demonstrates efficiency and accuracy of the hybrid model.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: https://git.iws.uni-stuttgart.de/dumux-pub/Becker2021b.git
    Keywords: ddc:551.49 ; ddc:550
    Language: English
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    On Timescales and Reversibility of the Ocean's Response to Enhanced Greenland Ice Sheet Melting in Comprehensive Climate Models (2022)
    Details
    Publication Date: 2022-06-26
    Description: Warming of the North Atlantic region in climate history often was associated with massive melting of the Greenland Ice Sheet. To identify the meltwater's impacts and isolate these from internal variability and other global warming factors, we run single‐forcing simulations including small ensembles using three complex climate models differing only in their ocean components. In 200‐year‐long preindustrial climate simulations, we identify robust consequences of abruptly increasing Greenland runoff by 0.05 Sv: sea level rise of 44 ± 10 cm, subpolar North Atlantic surface cooling of 0.7°C, and a moderate AMOC decline of 1.1–2.0 Sv. The latter two emerge in under three decades—and reverse on the same timescale after the perturbation ends in year 100. The ocean translates the step‐change perturbation into a multidecadal‐to‐centennial signature in the deep overturning circulation. In all simulations, internal variability creates notable uncertainty in estimating trends, time of emergence, and duration of the response.
    Description: Plain Language Summary: Enhanced melting of Greenland's glaciers is considered to be a major player in past rapid climate transitions and anticipated to soon impact ocean circulation under current global warming. Global warming triggers complex processes and feedbacks, of which greater amounts of meltwater slowing the large‐scale ocean circulation is only one. To better understand the sensitivity of the real but also the model ocean to just this meltwater, we run idealized experiments with up‐to‐date climate models, which use the same atmosphere and land but different ocean components. We find that sea level rise, cooling of the North Atlantic region, and slowing of the ocean circulation are responses common to all models while regional magnitudes of these responses differ considerably. Once we stop adding freshwater, all three models show that surface temperature and ocean circulation recover as quickly (or slowly) as they changed at the beginning of the experiment. Sea level rise is a lasting impact though.
    Description: Key Points: Sudden increase in Greenland freshwater release is turned into century scale change by deep ocean dynamics. Upper ocean responses to moderately enhanced freshwater release from Greenland reverse on the same timescale once release ceases. Ocean model formulation affects regional expressions but basin‐scale responses are robust, so is the timing on decadal to centennial scales.
    Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347
    Keywords: ddc:551.6
    Language: English
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    Attribution of Observed Recent Decrease in Low Clouds Over the Northeastern Pacific to Cloud‐Controlling Factors (2022)
    Details
    Publication Date: 2022-06-26
    Description: Marine low clouds cool the Earth's climate, with their coverage (LCC) being controlled by their environment. Here, an observed significant decrease of LCC in the northeastern Pacific over the past two decades is linked quantitatively to changes in cloud‐controlling factors. In a comparison of different statistical and machine learning methods, a decrease in the inversion strength and near‐surface winds, and an increase in sea surface temperatures (SSTs) are unanimously shown to be the main causes of the LCC decrease. While the decreased inversion strength leads to more entrainment of dry free‐tropospheric air, the increasing SSTs are shown to lead to an increased vertical moisture gradient that enhances evaporation when entrainment takes place. While the LCC trend is likely driven by natural variability, the trend‐attribution framework developed here can be used with any method in future analyses. We find the choice of predictors is more important than the method.
    Description: Plain Language Summary: Marine low clouds efficiently cool the Earth's climate, and their prevalence is controlled by environmental factors. Here, a decrease of the cover of marine low clouds in the northeastern Pacific over the past 20 years is analyzed to attribute the trend to changes in environmental factors known to be important for low clouds. A decrease in the strength of the temperature inversion and an increase in sea surface temperatures (SSTs) are shown to be the main causes of the low‐cloud trend. The decreased inversion strength leads to more mixing in of dry air from above the clouds, leading to cloud evaporation. The increasing SSTs increase the atmospheric moisture levels near the surface more than above the cloud, enhancing evaporation when the mixing takes place. While the trend in low clouds is likely driven by natural variability rather than climate change, the analytical framework developed here can be deployed to attribute causes for trends with any statistical or machine learning method in the future. The analysis shows that the choice of environmental factors used for the analysis has a larger impact on the results than the method.
    Description: Key Points: Significant decrease of low cloud cover in northeastern Pacific in last two decades. Increased vertical moisture gradient, decreased inversion strength, and winds drive low cloud trend. Good agreement between statistical and machine‐learning methods, predictor choice more important.
    Description: Horizon 2020 research and innovation program
    Description: https://doi.org/10.24381/cds.f17050d7
    Description: https://doi.org/10.24381/cds.6860a573
    Description: https://dx.doi.org/10.5067/MODIS/MOD08_M3.061
    Description: http://dx.doi.org/10.5067/MODIS/MYD08_M3.061
    Description: https://doi.org/10.5067/TERRA-AQUA/CERES/EBAF-TOA_L3B004.1
    Description: https://doi.org/10.5281/zenodo.5747221
    Keywords: ddc:551.5
    Language: English
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    Evolution of Rift Systems and Their Fault Networks in Response to Surface Processes (2022)
    Details
    Publication Date: 2022-06-26
    Description: Continental rifting is responsible for the generation of major sedimentary basins, both during rift inception and during the formation of rifted continental margins. Geophysical and field studies revealed that rifts feature complex networks of normal faults but the factors controlling fault network properties and their evolution are still matter of debate. Here, we employ high‐resolution 2D geodynamic models (ASPECT) including two‐way coupling to a surface processes (SP) code (FastScape) to conduct 12 models of major rift types that are exposed to various degrees of erosion and sedimentation. We further present a novel quantitative fault analysis toolbox (Fatbox), which allows us to isolate fault growth patterns, the number of faults, and their length and displacement throughout rift history. Our analysis reveals that rift fault networks may evolve through five major phases: (a) distributed deformation and coalescence, (b) fault system growth, (c) fault system decline and basinward localization, (d) rift migration, and (e) breakup. These phases can be correlated to distinct rifted margin domains. Models of asymmetric rifting suggest rift migration is facilitated through both ductile and brittle deformation within a weak exhumation channel that rotates subhorizontally and remains active at low angles. In sedimentation‐starved settings, this channel satisfies the conditions for serpentinization. We find that SP are not only able to enhance strain localization and to increase fault longevity but that they also reduce the total length of the fault system, prolong rift phases and delay continental breakup.
    Description: Plain Language Summary: Continental rifting is responsible for breaking apart continents and forming new oceans. Rifts generally evolve according to three types: wide rift, symmetric rift, and asymmetric rifts, which also shape the final geometry of the continental rifted margin. Geophysical data shows that the evolution of rifts depends on a multitude of factors including the complex interactions between fault networks that accommodate extension and the processes of erosion and sediment deposition. Here we run 2D computer simulations to investigate fault network evolution during active rifting that include changes to the surface through erosion and sedimentation. By using a new python tool box, we extract the fault network from the simulation and determine individual fault properties like the number of faults, displacement, age, and length through time. We find that regardless of the rift type, rifts evolve according to five phases that can be assessed through the evolution of the fault network properties. Additionally, we find that greater erosion and sedimentation can prolong rift phases and delay the breakup of continents.
    Description: Key Points: We apply a new fault analysis toolbox to coupled numerical models of tectonics and surface processes. Fault network evolution of the major symmetric, asymmetric, narrow, and wide rift types can be described in five distinct phases. Surface processes reduce fault network complexity and delay breakup by enhancing strain localization and increasing fault longevity.
    Description: Helmholtz Young Investigators
    Description: National Science Foundation
    Description: Deutsche Forschungsgemeinschaft (DFG)
    Description: https://doi.org/10.5281/zenodo.5753144
    Keywords: ddc:551.8
    Language: English
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    Investigation of subsurface connectivity and subsurface stormflow in low mountain ranges—Findings from the two research catchments Obere Brachtpe and Bohlmicke (Germany) (2022)
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-06-26
    Description: The two small research catchments Obere Brachtpe (2.6 km2; 50.989986, 7.752013) and Bohlmicke (1 km2, 51.079319, 7.892988) are located in the Rhenish Massif, a low mountain range in Germany. Land use in both catchments is dominated by pasture land, spruce stands and mixed forests. Mean annual temperature is 9.1°C, and mean annual total precipitation is 1250 mm, with 15%–20% of the annual precipitation falling as snow. The geology is characterized by sandy silty clay shale from the Lower and Middle Devonian. Loamy Cambisols derived from periglacial slope deposits, complemented by Leptosols and Stagnosols, are the most prominent soils in the catchments. Long‐term hydrological datasets of precipitation, throughfall, discharge, groundwater levels and soil moisture (at different soil depths) in a high temporal and spatial resolution are available for further scientific analysis. Both catchments were monitored within the time period 1999 and 2009, in order to understand how the antecedent soil moisture, stratified soils (periglacial cover beds) and topography (slope form) impacted the subsurface connectivity, and the subsurface stormflow generation ‐ a dominant runoff generation process in humid mountainous catchments. Detailed physically based investigations on runoff processes were carried out, and the obtained results helped to better understand subsurface stormflow generation and subsurface connectivity dynamics. The process knowledge gained, which was presented at several conferences, as well as publications, was the basis for the discussion of open questions within the scientific network ‘Subsurface Stormflow ‐ A well‐recognized, but still challenging process in Catchment Hydrology’ (2016–2021), and the research unit ‘Fast and invisible: conquering subsurface stormflow through an interdisciplinary multisite approach’ (2022–2025), both financed by the German Research Foundation (DFG).
    Description: Long‐term hydrological datasets of precipitation, throughfall, discharge, groundwater levels and soil moisture (at different soil depths) in a high temporal and spatial resolution are available of the two small catchments Obere Brachtpe (2.6 km²) and Bohlmicke (1 km²) (Germany). Both catchments have been monitored in order to understand how the antecedent soil moisture, stratified soils (periglacial cover beds) and topography (slope form) impacted the subsurface connectivity and the subsurface stormflow generation in humid mountainous catchments.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.48
    Language: English
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    Multi‐Band Raman Analysis of Radiation Damage in Zircon for Thermochronology: Partial Annealing and Mixed Signals (2022)
    Details
    Publication Date: 2022-06-24
    Description: Four zircon Raman bands were previously calibrated to give consistent estimates of the accumulated self‐irradiation α‐dose in unannealed volcanic samples. Partial annealing of radiation damage produces inconsistent values because of differences in the relative annealing sensitivities. The damage estimates based on the external rotation band (DER) at ∼356 cm−1 and that based on the ν2(SiO4) band (D2) at ∼438 cm−1 are the most and least sensitive to damage annealing. The D2/DER‐ratio thus provides a numerical estimate of the extent of geologic annealing that a zircon sample has experienced. This ratio characterizes the thermal history of a zircon sample but also its state of radiation damage during the course of its geologic history, and thus the manner in which this state influences other thermochronologic methods. Meaningful interpretation of the zircon Raman age requires that the spectra are free of measurement artifacts. The major artifacts result from micrometer‐scale gradients of the damage densities within a zircon grain due to uranium and thorium zoning. The micrometer‐sized sampled volume may span different densities, producing overlapping spectra, causing apparent peak broadening, overestimated damage densities, and zircon Raman ages. The D3/D2‐ratio of the damage densities calculated from the ν3(SiO4) and ν2(SiO4) bands, most and least affected by overlap, is an efficient indicator of a meaningless signal. It reveals overlap in annealed and unannealed samples, because the used bands have similar responses to annealing. Multi‐band Raman maps can be converted to damage‐ratio maps for screening zircon mounts, and selecting spots for thermochronologic investigations.
    Description: Plain Language Summary: Radioactive processes cause damage to the lattice of zircon crystals. This damage can be measured with a Raman instrument. Such measurements are important for methods determining the ages and thermal histories of zircon grains in rocks. Thus, the Raman measurements must be reliable and meaningful. This work proposes tools for detecting effects that hinder the interpretation of zircon Raman data. These effects are mixed signals and loss of damage due to exposure to elevated temperatures in the geologic environment. Zircon Raman spectra have different bands that respond differently to mixed signals and temperature. The ratio of the damage estimates from the least and most temperature‐sensitive bands thus indicates partial annealing. Raman spectra of zoned zircons often straddle areas with different lattice damage. Their overlapping signals cause artificial band broadening, and a damage overestimation. The ratio of the damage estimated from the least and the most affected bands identifies mixed signals and allows to reject unsuitable samples. The damage ratios can also be plotted in maps for damage screening and for selecting optimal spots for measurements.
    Description: Key Points: Annealing and inhomogeneous damage are two main factors hindering radiation‐damage estimation for zircon Raman dating. Comparison of internal and external Raman bandwidths allows to detect partial annealing of radiation damage in zircon. Comparison of internal Raman bandwidths allows to detect artifactual broadening in zoned zircon.
    Description: Studienstiftung des Deutschen Volkes (Studienstiftung) http://dx.doi.org/10.13039/501100004350
    Description: http://dx.doi.org/10.25532/OPARA-155
    Keywords: ddc:549 ; ddc:551.9
    Language: English
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  • 22
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    The Subducting Slab as a Chromatographic Column: Regimes of Sub‐Solidus Mass Transport as a Function of Lithospheric Hydration State, With Special Reference to the Fate of Carbonate (2022)
    Details
    Publication Date: 2022-06-24
    Description: We investigate the chemical budget of subduction zones at sub‐solidus conditions using a thermodynamic‐numerical simulation in which all major rock components are treated as soluble and potentially mobile in aqueous fluids. This new strategy significantly improves the accuracy of predicted fluid‐rock equilibrium compositions in open petrological systems. We show that all slabs release volatiles and nonvolatiles to the mantle wedge, contributing to its refertilization. But some mobile constituents, such as alkali and alumina, may be trapped along layer boundaries or traverse without interaction depending on chemical contrasts between adjacent lithologies. The accumulation of igneous alumina and silica in the limestones of the central‐eastern Pacific slabs drives their decarbonation and is marked by metasomatic garnet growth. Those slabs are also predicted to lose much of their alkalis before sub‐arc depth. Even when they are produced in the altered mafic and ultramafic layers, fluids reach the slab/mantle wedge interface with distinct compositional signatures that are typical of the sedimentary cover. We distinguished supply and transport limited regimes of element subduction by testing the sensitivity of our mass balance to changes in slab hydration state (HS). Transport limited slabs sensitive to HS include notably a hotspot of carbon release to the mantle wedge (e.g., Costa Rica). Finally, we show that the quantitative budgets do depend on the geometry of fluid flows, and on assuming that slabs are mechanically continuous structures, which is questionable. Taken together, these insights will help better constrain the long‐term chemical evolution of the shallow planetary interior, and the thermomechanical behavior of the subduction interface.
    Description: Plain Language Summary: Subduction zones return chemical elements from the surface to the deep Earth. But quantifying this transfer has been challenging. Here, we present a model where all major elements are partly mobile in the fluid phase, enabling us to compile a chemical budget for subduction zones in which only fluids mediate mass transport. We identify transport and supply regimes of element subduction as a function of lithospheric hydration state, rock compositions, and slab temperature. We show that the transport of many rock‐forming elements such as SiO2, CaO, and Al2O3, within and out of the slab, modifies rock composition and contributes to the efficiency of slab decarbonation. Our model of subduction fluid and rock compositions has important implications to understand the role of slab‐derived metasomatic fluid in modifying the composition of the mantle wedge over time, the mechanical properties of deeply subducted rocks, and it will inform future investigations for the high‐pressure petrology of rocky planets in general.
    Description: Key Points. Inter dependence of element transfers in subduction zones. Thermodynamics of intra‐slab metasomatism of major elements. Transport‐ and supply limited regimes of carbonate subduction.
    Description: Alexander von Humboldt‐Stiftung (Humboldt‐Stiftung) http://dx.doi.org/10.13039/100005156
    Description: Branco Weiss Fellowship—Society in Science
    Description: Swiss National Science Foundation
    Description: https://osf.io/y84d2/
    Keywords: ddc:551
    Language: English
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    Sub‐micrometer focusing setup for high‐pressure crystallography at the Extreme Conditions beamline at PETRA III (2022)
    International Union of Crystallography | 5 Abbey Square, Chester, Cheshire CH1 2HU, England
    Details
    Publication Date: 2022-06-24
    Description: Scientific tasks aimed at decoding and characterizing complex systems and processes at high pressures set new challenges for modern X‐ray diffraction instrumentation in terms of X‐ray flux, focal spot size and sample positioning. Presented here are new developments at the Extreme Conditions beamline (P02.2, PETRA III, DESY, Germany) that enable considerable improvements in data collection at very high pressures and small scattering volumes. In particular, the focusing of the X‐ray beam to the sub‐micrometer level is described, and control of the aberrations of the focusing compound refractive lenses is made possible with the implementation of a correcting phase plate. This device provides a significant enhancement of the signal‐to‐noise ratio by conditioning the beam shape profile at the focal spot. A new sample alignment system with a small sphere of confusion enables single‐crystal data collection from grains of micrometer to sub‐micrometer dimensions subjected to pressures as high as 200 GPa. The combination of the technical development of the optical path and the sample alignment system contributes to research and gives benefits on various levels, including rapid and accurate diffraction mapping of samples with sub‐micrometer resolution at multimegabar pressures.
    Description: Facing the challenges of X‐ray diffraction from tiny samples subjected to multimegabar pressures, instrumentation developments are presented that enable, among other studies, single‐crystal data collection from micrometer‐ to sub‐micrometer‐sized grains. The developments are based on a sub‐micrometer beam capability employing compound refractive lenses operating with a phase correcting plate and a precise motorization solution.
    Keywords: ddc:548
    Language: English
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    The Vertical Structure and Entrainment of Subglacial Melt Water Plumes (2022)
    Details
    Publication Date: 2022-06-22
    Description: Basal melting of marine‐terminating glaciers, through its impact on the forces that control the flow of the glaciers, is one of the major factors determining sea level rise in a world of global warming. Detailed quantitative understanding of dynamic and thermodynamic processes in melt‐water plumes underneath the ice‐ocean interface is essential for calculating the subglacial melt rate. The aim of this study is therefore to develop a numerical model of high spatial and process resolution to consistently reproduce the transports of heat and salt from the ambient water across the plume into the glacial ice. Based on boundary layer relations for momentum and tracers, stationary analytical solutions for the vertical structure of subglacial non‐rotational plumes are derived, including entrainment at the plume base. These solutions are used to develop and test convergent numerical formulations for the momentum and tracer fluxes across the ice‐ocean interface. After implementation of these formulations into a water‐column model coupled to a second‐moment turbulence closure model, simulations of a transient rotational subglacial plume are performed. The simulated entrainment rate of ambient water entering the plume at its base is compared to existing entrainment parameterizations based on bulk properties of the plume. A sensitivity study with variations of interfacial slope, interfacial roughness and ambient water temperature reveals substantial performance differences between these bulk formulations. An existing entrainment parameterization based on the Froude number and the Ekman number proves to have the highest predictive skill. Recalibration to subglacial plumes using a variable drag coefficient further improves its performance.
    Description: Plain Language Summary: In a world of global warming, the melting of glaciers terminating as floating ice tongues into the oceans of Arctic and Antarctic regions allows those glaciers to flow faster and hence to make a considerable contribution to global mean sea‐level rise. Underneath the ice‐ocean interface, turbulent currents of the order of 10 m thickness (so‐called plumes) develop that transport the melt water from the grounding line where the glacier enters the ocean toward the calving front that marks the seaward end of the glacier. At its base, ambient relatively warm and salty ocean water is mixed into the plumes and is vertically transported toward the ice‐ocean interface, where the melting is increased due to the additional heat supply. Understanding these processes is essential for their incorporation into computer models for the prediction of such melt processes. In this study, an accurate simulation model for the water column is constructed that is able to consistently reproduce these processes. The algorithms developed here are proven to provide reliable results also for models with only a few grid points across the plume and can therefore be implemented into climate models with surface‐following coordinates to more accurately simulate future scenarios of sea level rise.
    Description: Key Points: A vertically resolving model with second‐moment turbulence closure has been constructed for subglacial plumes. Convergent numerical formulations for the ocean‐to‐ice fluxes of momentum, freshwater and heat have been derived from an analytical model. Model results are consistent with bulk parameterizations for the entrainment of ambient water.
    Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347
    Description: https://doi.org/10.5281/zenodo.6203838
    Keywords: ddc:550
    Language: English
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    Electrochemical Properties of Peat Particulate Organic Matter on a Global Scale: Relation to Peat Chemistry and Degree of Decomposition (2022)
    Details
    Publication Date: 2022-06-22
    Description: Methane production in peatlands is controlled by the availability of electron acceptors for microbial respiration, including peat dissolved organic matter (DOM) and particulate organic matter (POM). Despite the much larger mass of POM in peat, knowledge on the ranges of its electron transfer capacities—electron accepting capacity (EAC), and electron donating capacity (EDC)—is scarce in comparison to DOM and humic and fulvic acids. Moreover, it is unclear how peat POM chemistry and decomposition relate to its EAC and EDC. To address these knowledge gaps, we compiled peat samples with varying carbon contents from mid to high latitude peatlands and analyzed their EACPOM and EDCPOM, element ratios, decomposition indicators, and relative amounts of molecular structures as derived from mid infrared spectra. Peat EACPOM and EDCPOM are smaller (per gram carbon) than EAC and EDC of DOM and terrestrial and aquatic humic and fulvic acids and are highly variable within and between sites. Both are small in highly decomposed peat, unless it has larger amounts of quinones and phenols. Element ratio‐based models failed to predict EACPOM and EDCPOM, while mid infrared spectra‐based models can predict peat EACPOM to a large extent, but not EDCPOM. We suggest a conceptual model that describes how vegetation chemistry and decomposition control polymeric phenol and quinone contents as drivers of peat EDCPOM and EACPOM. The conceptual model implies that we need mechanistic models or spatially resolved measurements to understand the variability in peat EDCPOM and EACPOM and thus its role in controlling methane formation.
    Description: Plain Language Summary: Peatlands accumulated large amounts of carbon via photosynthesis and slow decomposition of senesced plant material. Microorganisms within the peat form methane. For this reason, peatlands are important global sources of the greenhouse gas methane and therefore can contribute to climate change. In order to produce methane, the microorganisms have to transfer electrons between compounds in respiration processes. Only recently, it has been found that the peat itself can reversibly transfer electrons and that its capacities to reversibly accept electron accepting capacity (EAC) and reversibly donate electron donating capacity (EDC) electrons are large. We investigated which conditions favor large or small EAC and EDC of peat so that we can better explain methane formation. We argue that vegetation and decomposition control the amount of phenols and quinones—molecules in the peat that presumably are responsible for most of the peat's EAC and EDC. The EAC and EDC probably are largest for peat formed from vegetation rich in quinones and phenols, such as shrubs, and smaller for other vegetation types, for example, certain mosses. Intense decomposition may reduce both the EAC and EDC.
    Description: Key Points: Peat particulate organic matter electron accepting and donating capacities per grams of carbon are smaller than for humic and fulvic acids. Both capacities are small in highly decomposed peat, unless it has larger amounts of quinones and phenols. We explain these patterns with parent vegetation chemistry and conditions during decomposition.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: CAS | Youth Innovation Promotion Association (YIPA) http://dx.doi.org/10.13039/501100012492
    Description: https://github.com/henningte/redoxpeat
    Keywords: ddc:551.9
    Language: English
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    Impact of Spreading Rate and Age‐Offset on Oceanic Transform Fault Morphology (2022)
    Details
    Publication Date: 2022-06-22
    Description: Oceanic transform faults (OTFs) are an inherent part of seafloor spreading and plate tectonics, whereas the process controlling their morphology remains enigmatic. Here, we systematically quantify variations in transform morphology and their dependence on spreading rate and age‐offset, based on a compilation of shipborne bathymetric data from 94 OTFs at ultraslow‐ to intermediate‐spreading ridges. In general, the length, width and depth of OTFs scale systematically better with age‐offset rather than spreading rate. This observation supports recent geodynamic models proposing that cross‐transform extension scaling with age‐offset, is a key process of transform dynamics. On the global scale, OTFs with larger age‐offsets tend to have longer, wider, and deeper valleys. However, at small age‐offsets (〈5 Myr), scatters in the depth and width of OTFs increase, indicating that small age‐offset OTFs with weak lithospheric strength are easily affected by secondary tectonic processes.
    Description: Plain Language Summary: In the past 5 decades, studies on oceanic transform faults (OTFs) have revealed significant complexity in their morphology, which calls for detailed quantitative analysis to study the processes controlling the morphology of OTFs. Using the most complete and advanced compilation of bathymetric data from ultraslow‐ to intermediate‐spreading ridges, we parameterized the morphological characteristics of OTFs and extracted length, width and depth for each transform fault from the compiled bathymetric data. Moreover, correlations between these morphological parameters and related tectonic factors (e.g., spreading rate, age‐offset) were investigated in this study. We find that correlations between morphological features and spreading rate are rather weak. Comparison of correlations suggests that age‐offset scales better with the morphological parameters, along with scatters mostly at small age‐offsets, indicating small‐age‐offset OTFs are unstable due to their weak lithospheric strength. Our observation evidences extensional tectonics at OTFs.
    Description: Key Points: We compiled multibeam bathymetric data of 94 oceanic transform faults (OTFs) to quantify their morphological characteristics. Morphology of OTFs is dominated by age‐offset rather than spreading rate. Transform valleys get systematically deeper and wider with increasing age‐offset, implying extensional tectonics at OTFs.
    Description: China Scholarship Council
    Description: http://doi.org/10.5281/zenodo.4774185
    Keywords: ddc:551
    Language: English
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    Rupture Heterogeneity and Directivity Effects in Back‐Projection Analysis (2022)
    Details
    Publication Date: 2022-06-21
    Description: The back projection method is a tremendously powerful technique for investigating the time dependent earthquake source, but its physical interpretation is elusive. We investigate how earthquake rupture heterogeneity and directivity can affect back‐projection results (imaged location and beam power) using synthetic earthquake models. Rather than attempting to model the dynamics of any specific real earthquake, we use idealized kinematic rupture models, with constant or varying rupture velocity, peak slip rate, and fault‐local strike orientation along unilateral or bilateral rupturing faults, and perform back‐projection with the resultant synthetic seismograms. Our experiments show back‐projection can track only heterogeneous rupture processes; homogeneous rupture is not resolved in our synthetic experiments. The amplitude of beam power does not necessarily correlate with the amplitude of any specific rupture parameter (e.g., slip rate or rupture velocity) at the back‐projected location. Rather, it depends on the spatial heterogeneity around the back‐projected rupture front, and is affected by the rupture directivity. A shorter characteristic wavelength of the source heterogeneity or rupture directivity toward the array results in strong beam power in higher frequency. We derive an equation based on Doppler theory to relate the wavelength of heterogeneity with synthetic seismogram frequency. This theoretical relation can explain the frequency‐ and array‐dependent back‐projection results not only in our synthetic experiments but also to analyze the 2019 M7.6 bilaterally rupturing New Ireland earthquake. Our study provides a novel perspective to physically interpret back‐projection results and to retrieve information about earthquake rupture characteristics.
    Description: Plain Language Summary: With the deployment of continental scale seismic arrays, seismologists can quickly locate the high‐frequency seismic radiation sources and track the earthquake rupture propagation using a technique called back‐projection. It is a signal beamforming technique application in seismology, and similar applications can be found in fields such as radar, wireless communication, and radio astronomy. Recent studies have proposed multiple advancements in improving the back‐projection location. However, the physical interpretation of the amplitude of stacked high‐frequency source radiations, which is commonly referred to as beam power, is still challenging since the analysis is not based on a forward model. In this article, we conduct a set of synthetic experiments to investigate the physical significance of back‐projection beam power. We find that beam power is mainly controlled by the spatial heterogeneity wavelength near the rupture front, rupture directivity, and the seismogram frequency. It is in contrast with some previous studies that link the beam power to the maximum slip rate (acceleration) amplitude near the rupture front. Based on the results, we develop a novel theoretical framework that can quantitatively interpret the frequency‐ and array‐dependent back‐projection results not only in our synthetic experiments, but also the 2019 bilateral rupture M7.6 New Ireland earthquake.
    Description: Key Points: We use kinematic forward models to investigate the relation between back‐projection beam location, power and earthquake source properties. Frequency‐dependent back‐projection peak beam power depends on the spatial heterogeneity near the rupture front, and rupture directivity. We develop a novel framework to analyze frequency‐ and array‐dependent back‐projection results, including the 2019 M7.6 New Ireland Event.
    Description: European Union's Horizon 2020 (ChEESE)
    Description: European Research Council (ERC)
    Description: German Research Foundation (DGF)
    Description: KAUST‐CRG
    Description: Leon and Joann V.C. Knopoff
    Description: NSF EAR
    Description: https://doi.org/10.7914/SN/AK
    Description: https://doi.org/10.7914/SN/AT
    Description: https://doi.org/10.7914/SN/AV
    Description: https://doi.org/10.7914/SN/BW
    Description: https://doi.org/10.7914/SN/CC
    Description: https://doi.org/10.7914/SN/CI
    Description: https://doi.org/10.7914/SN/CN
    Description: https://doi.org/10.7914/SN/II
    Description: https://doi.org/10.7914/SN/IU
    Description: https://doi.org/10.7914/SN/TA
    Description: https://doi.org/10.7914/SN/UW
    Keywords: ddc:551.22
    Language: English
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    BEST PRACTICE GUIDELINE Measurement of carbon dioxide, methane and nitrous oxide fluxes between soil-vegetation-systems and the atmosphere using non-steady state chambers (2022)
    Arbeitsgruppe Bodengase, Deutsche Bodenkundliche Gesellschaft | Göttingen
    Details
    Publication Date: 2022-06-23
    Description: This Best Practice Guideline was been initiated by the Working Group Soil Gases (AG Bodengase) of the German Soil Science Society (Deutsche Bodenkundliche Gesellschaft). Our intention was to collect and aggregate the expertise of different working groups in our field. As a compendium, this guideline may help both beginners and experts to meet the practical and theoretical challenges of measuring soil gas fluxes with non-steady state chamber systems.
    Description: German Soil Science Society, Working Group Soil Gases
    Description: manual
    Keywords: ddc:631.4
    Language: English
    Type: doc-type:book
    Format: 70
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    Thermolab: A Thermodynamics Laboratory for Nonlinear Transport Processes in Open Systems (2022)
    Details
    Publication Date: 2022-06-28
    Description: We developed a numerical thermodynamics laboratory called “Thermolab” to study the effects of the thermodynamic behavior of nonideal solution models on reactive transport processes in open systems. The equations of the state of internally consistent thermodynamic data sets are implemented in MATLAB functions and form the basis for calculating Gibbs energy. A linear algebraic approach is used in Thermolab to compute Gibbs energy of mixing for multicomponent phases to study the impact of the nonideality of solution models on transport processes. The Gibbs energies are benchmarked with experimental data, phase diagrams, and other thermodynamic software. Constrained Gibbs minimization is exemplified with MATLAB codes and iterative refinement of composition of mixtures may be used to increase precision and accuracy. All needed transport variables such as densities, phase compositions, and chemical potentials are obtained from Gibbs energy of the stable phases after the minimization in Thermolab. We demonstrate the use of precomputed local equilibrium data obtained with Thermolab in reactive transport models. In reactive fluid flow the shape and the velocity of the reaction front vary depending on the nonlinearity of the partitioning of a component in fluid and solid. We argue that nonideality of solution models has to be taken into account and further explored in reactive transport models. Thermolab Gibbs energies can be used in Cahn‐Hilliard models for nonlinear diffusion and phase growth. This presents a transient process toward equilibrium and avoids computational problems arising during precomputing of equilibrium data.
    Description: Plain Language Summary: The behavior of Earth materials, rocks, minerals, melts, fluids, and gases is important to predict physical processes in the Earth with computer models. The purpose of this is to study how the changes of variables such as fluid and solid composition influence the diffusion, fluid flow, and reaction in rocks. Here, we present a set of computer codes, called Thermolab, to calculate important physical properties such as density and chemical composition of solids, fluids, and melts in chemical equilibrium. The calculations are based on the Gibbs energy that exists for every material. We use computer codes, written in MATLAB/OCTAVE language, to show how this Gibbs energy is calculated and used to compute chemical equilibrium and find the physical properties such as density and chemical composition. We discuss techniques for accurate calculation of chemical equilibrium and physical properties in real rocks. Finally, we use Thermolab to formulate a computer model of fluids reacting with rocks. We find that chemical composition of the fluid and rock strongly affects the speed and shape of the boundary between reacted and unreacted rock. Thermolab can be used in phase growth models to investigate the way in which rocks develop toward equilibrium.
    Description: Key Points: Thermolab: a set of MATLAB codes is presented to perform equilibrium and nonequilibrium thermodynamic calculations. Local thermodynamic equilibrium is used to study effects of nonideality of solution models on nonlinear transport processes. Nonlinear diffusion processes are investigated with Thermolab providing a transient natural physical process toward equilibrium.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: Russian Ministry of Science and Higher Education
    Description: https://hansjcv.github.io/Thermolab/
    Description: https://doi.org/10.5281/zenodo.6383253
    Keywords: ddc:551.9 ; ddc:541.36
    Language: English
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    Toward Reconciling Radiocarbon Production Rates With Carbon Cycle Changes of the Last 55,000 Years (2022)
    Details
    Publication Date: 2022-06-28
    Description: Since it is currently not understood how changes in 14C production rate (Q), and in the carbon cycle, can be combined to explain the reconstructed atmospheric Δ14C record, we discuss possible reasons for this knowledge gap. Reviewing the literature, we exclude that changes in the content of atoms in the atmosphere, which produce cosmogenic 14C after being hit by galactic cosmic rays, might be responsible for parts of the observed differences. When combining Q with carbon cycle changes, one needs to understand the changes in the atmospheric 14C inventory, which are partially counterintuitive. For example, during the Last Glacial Maximum, Δ14C was ∼400‰ higher compared with preindustrial times, but the 14C inventory was 10% smaller. Some pronounced changes in atmospheric Δ14C do not correspond to any significant changes in the atmospheric 14C inventory, since CO2 was changing simultaneously. Using two conceptually different models (BICYCLE‐SE and LSG‐OGCM), we derive hypothetical Qs by forcing the models with identical atmospheric CO2 and Δ14C data. Results are compared with the most recent data‐based estimates of Q derived from cosmogenic isotopes. Millennial‐scale climate change connected to the bipolar seesaw is missing in the applied models, which might explain some, but probably not all, of the apparent model‐data disagreement in Q. Furthermore, Q based on either data from marine sediments or ice cores contains offsets, suggesting an interpretation deficit in the current data‐based approaches.
    Description: Key Points: No important change found in the level of precursor material, which produces cosmogenic radiocarbon after being hit by galactic cosmic rays. Transient changes in the bipolar seesaw are needed in applied carbon cycle models to improve interpretation of the radiocarbon cycle. Sediment core‐ and ice core‐based radiocarbon production rates differ systematically, suggesting missing processes.
    Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347
    Description: Swedish Research Concil
    Description: Helmholtz Association (亥姆霍兹联合会致力) http://dx.doi.org/10.13039/501100009318
    Description: https://doi.org/10.1594/PANGAEA.871273
    Description: https://www.ncdc.noaa.gov/paleo-search/study/31772
    Description: https://doi.org/10.1594/PANGAEA.914500
    Description: https://www.iceandclimate.nbi.ku.dk/data/
    Description: https://doi.org/10.1594/PANGAEA.932965
    Keywords: ddc:551.9
    Language: English
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    Spatio‐temporal patterns in degradation and restoration of gravel bars along Alpine rivers (2022)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2022-06-28
    Description: Braided reaches were common along near‐natural Alpine rivers, and the associated habitat dynamics supported plant and animal species specialized on early‐successional stages. The extensive riparian zones could mitigate climate change by absorbing floods and by retaining water during droughts. Human impacts largely reduced active river corridors through altered discharge and construction of dykes, while recent restoration projects aim at increasing river dynamics. The causes and consequences of Alpine river degradation are well understood, but there are only few quantitative studies on floodplain degradation and restoration. Thus, we have reconstructed historical changes of gravel bars along five Alpine rivers (Iller, Inn, Isar, Lech, and Wertach) in Southern Germany in the period 1808–2009, based on historical maps and aerial images. We found losses of 〉90% in gravel bar area along these rivers since the mid‐19th century. The decline was caused by a reduction of the active river corridor and by ongoing succession of the remaining open habitats. Within the past 30 years, at the Isar River, restoration measures were realized with the aim to widen the active river corridor and to recreate gravel bars. In four restored reaches, we found that 5% of the historical gravel bar area recovered, and that the proportion of restored gravel bar area was highest after intermediate flooding. We conclude that the active river corridors of German Alpine rivers are almost completely lost, and that more extensive restoration needs to be done to preserve the habitat dynamics and biodiversity of these systems, and to adapt Alpine rivers to climate change.
    Description: Deutsche Bundesstiftung Umwelt http://dx.doi.org/10.13039/100007636
    Keywords: ddc:551.35
    Language: English
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    Variation in the predictability of lake plankton metric types (2022)
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-06-28
    Description: Statistical and climate models are frequently used for biodiversity projections under future climatic changes, but their predictive capacity for freshwater plankton may vary among different species and community metrics. Here, we used random forests to model plankton species and community metrics as a function of biological, climatic, physical, and chemical data from long‐term (2000–2017) monitoring data collected from Lake Müggelsee Berlin, Germany. We (1) compared the predictability of well‐known lake plankton metric types (biomass, abundance, taxonomic diversity, Shannon diversity, Simpson diversity, evenness, taxonomic distinctness, and taxonomic richness) and (2) assessed how the relative influence of different environmental drivers varies across lake plankton metric models. Overall, the metric predictability was highest for biomass and abundance followed by taxonomic richness. The biomass of dominant phytoplankton taxonomic groups such as cyanobacteria (adjusted‐R2 = 0.53) and the abundance of dominant zooplankton taxonomic groups such as rotifers (adjusted‐R2 = 0.59) and daphnids (adjusted‐R2 = 0.51) were more predictable than other metric types. The plankton metric predictability increased when grouping phytoplankton species according to their functional traits (adjusted‐R2 = 0.37 ± 0.14, mean ± SD, n = 36 functional groups) compared to higher taxonomic units (adjusted‐R2 = 0.25 ± 0.15, n = 22 taxonomic groups). Light, nutrients, water temperature, and seasonality for phytoplankton and food resources for zooplankton were the main drivers of both taxonomic and functional groups, giving confidence that our models captured the expected major environmental drivers. Our quantitative analyses highlight the multidimensionality of lake planktonic responses to environmental drivers and have implications for our capacity to select appropriate metrics for forecasting the future of lake ecosystems under global change scenarios.
    Description: European Union's Horizon 2020 Research and Innovation Programme
    Description: Belmont Forum
    Description: BiodivERsA
    Description: LimnoSCenES
    Keywords: ddc:579.17
    Language: English
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    Precipitation and Lake Water Evaporation Recorded by Terrestrial and Aquatic n‐Alkane δ2H Isotopes in Lake Khar Nuur, Mongolia (2022)
    Details
    Publication Date: 2022-06-28
    Description: The compound‐specific hydrogen isotopic composition (δ2H) of n‐alkanes is a valuable proxy to investigate hydrological conditions in lake sediments. While terrestrial n‐alkanes reflect the isotopic signal of the local precipitation, aquatic n‐alkanes incorporate the isotopic signal of the lake's water, which can be strongly modulated by evaporative enrichment. So far, the spatial distribution of the terrestrial and aquatic δ2H signal within lakes have not systematically been investigated. Here, we present compound‐specific δ2H results of terrestrial (δ2HC31) and aquatic (δ2HC23) n‐alkanes of surface sediment samples from Lake Khar Nuur, a semi‐arid and high‐altitude lake in the Mongolian Altai, and additionally investigate the δ2H signal of topsoils from the catchment. Our results show that the majority of the n‐alkane δ2H values from the catchment topsoils correspond well with modeled local growing season precipitation (JJAS). However, few samples in the northern catchment show more positive δ2H values possibly due to increased evapo(transpi)ration by southward exposition and shallower soils there. The only small variability of δ2HC31 in the surface sediments is in the range of most topsoils δ2H from the catchment, and thus, well reflects local growing season precipitation. δ2HC23 in surface sediment samples from the central and deepest parts of the lake, that is, the lake's sediment accumulation zones, shows distinctly more positive δ2HC23 values due to evaporative lake water enrichment. Consequently, Δaq‐terr, which is the isotopic offset between δ2HC23 and δ2HC31, indicates distinct lake water enrichment in the lake's accumulation zones and is a valuable proxy to investigate past hydrological changes.
    Description: Key Points: The hydrogen isotopic composition of terrestrial C31 n‐alkanes reflects the local growing season precipitation at Lake Khar Nuur. Aquatic C23 n‐alkanes incorporate the isotopic signal of the lake's water, which is strongly modulated by evaporative enrichment. The isotopic offset between C23 and C31 is a valuable proxy for evaporation in the lake and past hydrological changes in the catchment.
    Description: https://doi.pangaea.de/10.1594/PANGAEA.940115
    Keywords: ddc:551.9
    Language: English
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    Joint Effects of Fragmentation and Mercury Contamination on Marsh Periwinkle (Littoraria irrorata) Movement (2022)
    Details
    Publication Date: 2022-10-07
    Description: There are different ways contaminants can interact and enhance the effects of habitat fragmentation, such as modifying the movement of organisms. The present study tested the hypothesis that mercury exacerbates the effects of fragmentation by affecting the movement of the marsh periwinkle Littoraria irrorata and reducing the probability of snails crossing fragmented microlandscape experimental systems. How these changes could affect the search efficiency of organisms in the long term was assessed using hidden Markov models and random walks simulations. Bayesian nonlinear models were used to analyze the effects of fragmentation and contamination on the mean speed and mean directional change of organisms. Snail movement for control and two mercury‐exposure treatments were recorded in microlandscapes with six different levels of habitat cover and three landscape replicates. The results indicated that exposed organisms had lower probabilities of crossing the landscape, reduced speed, and shifts in step length distributions. Both mercury exposure and habitat fragmentation affected the movement of the marsh periwinkle. Mercury exacerbated the effects of habitat fragmentation by affecting the cognition (e.g., route planning, orientation, and spatial learning) and movement of L. irrorata. Hence, the interaction of these stressors could further reduce the functional connectivity of landscapes and reduce the search efficiency of organisms. Environ Toxicol Chem 2022;41:1742–1753. © 2022 The Authors. Environmental Toxicology and Chemistry published by Wiley Periodicals LLC on behalf of SETAC.
    Description: Coordenação de Aperfeiçoamento de Pessoal de Nível Superior http://dx.doi.org/10.13039/501100002322
    Keywords: ddc:577.2
    Language: English
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    Chronic and Acute Effects of Imidacloprid on a Simulated BEEHAVE Honeybee Colony (2022)
    Details
    Publication Date: 2022-10-07
    Description: Honeybees (Apis mellifera) are important pollinators for wild plants as well as for crops, but honeybee performance is threatened by several stressors including varroa mites, gaps in foraging supply, and pesticides. The consequences of bee colony longtime exposure to multiple stressors are not well understood. The vast number of possible stressor combinations and necessary study duration require research comprising field, laboratory, and simulation experiments. We simulated long‐term exposure of a honeybee colony to the insecticide imidacloprid and to varroa mites carrying the deformed wing virus in landscapes with different temporal gaps in resource availability as single stressors and in combinations. Furthermore, we put a strong emphasis on chronic lethal, acute sublethal, and acute lethal effects of imidacloprid on honeybees. We have chosen conservative published values to parameterize our model (e.g., highest reported imidacloprid contamination). As expected, combinations of stressors had a stronger negative effect on bee performance than each single stressor alone, and effect sizes were larger after 3 years of exposure than after the first year. Imidacloprid‐caused reduction in bee performance was almost exclusively due to chronic lethal effects because the thresholds for acute effects were rarely met in simulations. In addition, honeybee colony extinctions were observed by the last day of the first year but more pronounced on the last days of the second and third simulation year. In conclusion, our study highlights the need for more long‐term studies on chronic lethal effects of pesticides on honeybees. Environ Toxicol Chem 2022;41:2318–2327. © 2022 The Authors. Environmental Toxicology and Chemistry published by Wiley Periodicals LLC on behalf of SETAC.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.5281/zenodo.6567312
    Keywords: ddc:577.2
    Language: English
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    Clockwise hysteresis of diatoms in response to nutrient dynamics during eutrophication and recovery (2022)
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-10-08
    Description: Many lake ecosystems that have been severely disturbed by eutrophication, have also experienced large human efforts to restore “natural” conditions. However, the trajectories and the extent of recovery of these lake ecosystems are still poorly understood. In many shallow lakes, recovery was often delayed and counter‐clockwise hysteretic. Here, we study recovery and ecosystem trajectories in a large and deep lake using diatom remains in sediment cores and time series of phosphorus concentrations. We identified four periods of diatom community change: slow change during early eutrophication, thereafter a short period of rapid change after the 1950s, followed by community stability from the 1960s to the mid‐1980s, and finally a recovery phase until 2010. Diatom community structure responded quickly and in a saturating way to increasing phosphorus concentrations, but also fast to phosphorus decline. Hence, diatom community dynamics did not show counter‐clockwise hysteresis but was characterized by a high degree of recovery and clock‐wise hysteresis (CWH). We suggest that CWH in response to eutrophication and recovery is a typical and previously overlooked feature of deep lakes, which results from a more rapid change of average nutrient concentrations and thus productivity in the epilimnion compared to average nutrient concentrations across the entire water column. Such nonlinear and hysteretic responses to changing nutrients need to be considered when analyzing the effects of other stressors such as climate warming on ecosystem dynamics to prevent erroneous attribution of ecosystem change to other stressors instead of nutrient change.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: European Regional Development Fund http://dx.doi.org/10.13039/501100008530
    Keywords: ddc:577.63
    Language: English
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    Increased phosphorus availability from sewage sludge ashes to maize in a crop rotation with clover (2022)
    Details
    Publication Date: 2022-10-08
    Description: A recycling of Phosphorus (P) from the human food chain is mandatory to secure the future P supply for food production. However, many available recycled P fertilizers from sewage sludge do not have an adequate P bioavailability and, thus, are not suitable for their application in soils with pH 〉5.5–6.0, unless being combined with efficient mobilization measures. The aim of the study was to test the P mobilization ability of red clover (Trifolium pratense L.) from two thermally recycled P fertilizers for a subsequently grown maize. Two sewage sludge ashes (SSA) were investigated in a pot experiment at soil pH 7.5 with red clover differing in its nitrogen (N) supply (added N fertilizer or biological N2 fixation (BNF)), followed by maize (Zea maize L.). Shoot dry matter of maize was almost doubled when N supply of previous grown clover was covered by BNF, instead of receiving added N fertilizer. Similarly, shoot P removal of maize following clover with BNF was significantly increased. It is suggested that the P mobilization is related to the BNF, and a proton release of N2 fixing clover roots led to the measured decrease in soil pH and thereby increased P availability of the tested fertilizers.
    Description: CORE Organic II
    Keywords: ddc:333.7
    Language: English
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    Do image resolution and classifier choice impact island biogeographical parameters of terrestrial islands? (2022)
    Details
    Publication Date: 2022-10-08
    Description: Island biogeography provides concepts for conservation management as fragmented habitats are comparable to ocean islands. Remote sensing can help to extract terrestrial habitat islands on the landscape scale. However, little is known about the effects of image resolution and classification algorithms on resulting island size and related parameters. We study the combined effect of three image resolutions (2, 10, and 30 m) and three classification algorithms (Artificial Neural Network, Random Forest, Support Vector Machine) by extracting quartz islands from WorldView‐2 imagery using image segmentation. We compared four island parameters (i.e., area, distance, shape index, and perimeter–area ratio between resolutions and classifiers). We found that in all cases, image resolution and classification algorithms had a strong effect. However, image resolution was more important for area and shape. Artificial Neural Network always provided the best performance as a classifier (OA: 0.880, kappa: 0.801, F1: 0.912). Hence, conservation strategies could lead to different results when different pattern extraction strategies are applied. Future studies which aim at extracting terrestrial habitat islands from image datasets should aim for the highest possible resolution and compare the outcomes of different classifiers to ensure the best possible results.
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:526.0285
    Language: English
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    Comparing the performance of high‐resolution global precipitation products across topographic and climatic gradients of Central Asia (2022)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2022-10-13
    Description: Accurate and reliable precipitation data with high spatial and temporal resolution are essential in studying climate variability, water resources management, and hydrological forecasting. A range of global precipitation data are available to this end, but how well these capture actual precipitation remains unknown, particularly for mountain regions where ground stations are sparse. We examined the performance of three global high‐resolution precipitation products for capturing precipitation over Central Asia, a hotspot of climate change, where reliable precipitation data are particularly scarce. Specifically, we evaluated MSWEP, CHIRPS, and GSMAP against independent gauging stations for the period 1985–2015. Our results show that MSWEP and CHIRPS outperformed GSMAP for wetter periods (i.e., winter and spring) and wetter locations (150–600 mm·year−1), lowlands, and mid‐altitudes (0–3,000 m), and regions dominated by winter and spring precipitation. MSWEP performed best in representing temporal precipitation dynamics and CHIRPS excelled in capturing the volume and distribution of precipitation. All precipitation products poorly estimated precipitation at higher elevations (〉3,000 m), in drier areas (〈150 mm), and in regions characterized by summer precipitation. All products accurately detected dry spells, but their performance decreased for wet spells with increasing precipitation intensity. In sum, we find that CHIRPS and MSWEP provide the most reliable high‐resolution precipitation estimates for Central Asia. However, the high spatial and temporal heterogeneity of the performance call for a careful selection of a suitable product for local applications considering the prevailing precipitation dynamics, climatic, and topographic conditions.
    Description: We present the first quantitative evaluation of global high‐resolution (below 12 km) precipitation products against independent ground observations over Central Asia. Our results show that MSWEP was best at representing temporal precipitation dynamics, and CHIRPS was most prominent in representing the volume and distribution of precipitation. This is especially the case of wet seasons, altitudes below 3,000 m, and regions dominated by spring and winter precipitation. Our analysis provides key insights on the precipitation products' suitability for local hydrological applications.
    Description: Leibniz‐Institut für Agrarentwicklung in Transformationsökonomien
    Description: Volkswagen Foundation http://dx.doi.org/10.13039/501100001663
    Keywords: ddc:551.6
    Language: English
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    Climate Change and Weather Extremes in the Eastern Mediterranean and Middle East (2022)
    Details
    Publication Date: 2022-10-13
    Description: Observation‐based and modeling studies have identified the Eastern Mediterranean and Middle East (EMME) region as a prominent climate change hotspot. While several initiatives have addressed the impacts of climate change in parts of the EMME, here we present an updated assessment, covering a wide range of timescales, phenomena and future pathways. Our assessment is based on a revised analysis of recent observations and projections and an extensive overview of the recent scientific literature on the causes and effects of regional climate change. Greenhouse gas emissions in the EMME are growing rapidly, surpassing those of the European Union, hence contributing significantly to climate change. Over the past half‐century and especially during recent decades, the EMME has warmed significantly faster than other inhabited regions. At the same time, changes in the hydrological cycle have become evident. The observed recent temperature increase of about 0.45°C per decade is projected to continue, although strong global greenhouse gas emission reductions could moderate this trend. In addition to projected changes in mean climate conditions, we call attention to extreme weather events with potentially disruptive societal impacts. These include the strongly increasing severity and duration of heatwaves, droughts and dust storms, as well as torrential rain events that can trigger flash floods. Our review is complemented by a discussion of atmospheric pollution and land‐use change in the region, including urbanization, desertification and forest fires. Finally, we identify sectors that may be critically affected and formulate adaptation and research recommendations toward greater resilience of the EMME region to climate change.
    Description: Key Points: The Eastern Mediterranean and Middle East is warming almost two times faster than the global average and other inhabited parts of the world. Climate projections indicate a future warming, strongest in summers. Precipitation will likely decrease, particularly in the Mediterranean. Virtually all socio‐economic sectors will be critically affected by the projected changes.
    Description: European Union Horizon 2020
    Description: https://esg-dn1.nsc.liu.se/search/esgf-liu/
    Keywords: ddc:551.6
    Language: English
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    Formation of fused aggregates under long‐term microgravity conditions aboard the ISS with implications for early solar system particle aggregation (2022)
    Koch, Tamara E. ; Spahr, Dominik ; Tkalcec, Beverley J. ; [et al.]
    Details
    Publication Date: 2022-10-13
    Description: In order to gain further insights into early solar system aggregation processes, we carried out an experiment on board the International Space Station, which allowed us to study the behavior of dust particles exposed to electric arc discharges under long‐term microgravity. The experiment led to the formation of robust, elongated, fluffy aggregates, which were studied by scanning electron microscopy, electron backscatter diffraction, and synchrotron micro‐computed tomography. The morphologies of these aggregates strongly resemble the typical shapes of fractal fluffy‐type calcium‐aluminum‐rich inclusions (CAIs). We conclude that a small amount of melting could have supplied the required stability for such fractal structures to have survived transportation and aggregation to and compaction within planetesimals. Other aggregates produced in our experiment have a massy morphology and contain relict grains, likely resulting from the collision of grains with different degrees of melting, also observed in some natural CAIs. Some particles are surrounded by igneous rims, which remind in thickness and crystal orientation of Wark–Lovering rims; another aggregate shows similarities to disk‐shaped CAIs. These results imply that a (flash‐)heating event with subsequent aggregation could have been involved in the formation of different morphological CAI characteristics.
    Description: BIOVIA
    Description: Nordlicht GmbH
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Bundesministerium für Wirtschaft und Energie http://dx.doi.org/10.13039/501100006360
    Description: NanoRacks LLC
    Description: Dr. Rolf M. Schwiete Stiftung http://dx.doi.org/10.13039/501100020027
    Description: Deutsches Zentrum für Luft‐ und Raumfahrt http://dx.doi.org/10.13039/501100002946
    Description: DreamUp
    Description: Carl Zeiss Meditec AG http://dx.doi.org/10.13039/501100002806
    Keywords: ddc:550.78
    Language: English
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    Microbially promoted calcite precipitation in the pelagic redoxcline: Elucidating the formation of the turbid layer (2022)
    Details
    Publication Date: 2022-10-12
    Description: Large bell‐shaped calcite formations called “Hells Bells” were discovered underwater in the stratified cenote El Zapote on the Yucatán Peninsula, Mexico. Together with these extraordinary speleothems, divers found a white, cloudy turbid layer into which some Hells Bells partially extend. Here, we address the central question if the formation of the turbid layer could be based on microbial activity, more specifically, on microbially induced calcite precipitation. Metagenomic and metatranscriptomic profiling of the microbial community in the turbid layer, which overlaps with the pelagic redoxcline in the cenote, revealed chemolithoautotrophic Hydrogenophilales and unclassified β‐Proteobacteria as the metabolic key players. Bioinformatic and hydrogeochemical data suggest chemolithoautotrophic oxidation of sulfide to zero‐valent sulfur catalyzed by denitrifying organisms due to oxygen deficiency. Incomplete sulfide oxidation via nitrate reduction and chemolithoautotrophy are both proton‐consuming processes, which increase the pH in the redoxcline favoring authigenic calcite precipitation and may contribute to Hells Bells growth. The observed mechanism of microbially induced calcite precipitation is potentially applicable to many other stagnant sulfate‐rich water bodies.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: CONACYT‐FONCICYT‐DADC
    Description: https://doi.org/10.11588/data/TMYLWS
    Description: https://doi.org/10.11588/data/GYLDH5
    Keywords: ddc:551.9
    Language: English
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    Location choice for large‐scale battery manufacturing plants: Exploring the role of clean energy, costs, and knowledge on location decisions in Europe (2022)
    Details
    Publication Date: 2022-10-15
    Description: Driven by an increase in the demand for battery electric vehicles, the location of large‐scale battery manufacturing plants, that is, gigafactories, has become a substantial and burgeoning topic in academia, policy, and industry. This study contributes to this debate by examining how a country's specific battery manufacturing costs and knowledge and the environmental impact of its energy mix affect the choice of location for gigafactories in the European Union. We found that France, Latvia, and Germany are suitable locations when equally balancing costs, knowledge, and energy. However, our results also showed that no country leads in all three dimensions, suggesting that there is no single best location to set up gigafactories. Instead, the choice will depend on the battery manufacturer's requirements. Here, we contribute an analysis of various combinations of costs, knowledge, and energy to identify suitable locations. Moreover, we provide a sensitivity analysis to test the robustness of our framework and to explore whether countries with a clean energy mix, such as Sweden, become suitable locations. The findings of our study will assist battery producers in identifying a suitable location for their gigafactories and will provide the basis for policymakers to attract battery manufacturing by directing investments into clean energy.
    Description: https://doi.org/10.1016/j.jclepro.2020.121428
    Description: https://www.iea.org/data-and-statistics/data-product/emissions-factors-2021
    Keywords: ddc:333.7
    Language: English
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    Near‐surface three‐dimensional multicomponent source and receiver S‐wave survey in the Tannwald Basin, Germany: Acquisition and data processing (2022)
    Details
    Publication Date: 2022-10-17
    Description: Shallow 3‐D reflection seismic surveys using S‐waves have rarely been carried out, even though S‐waves can provide higher resolution subsurface images than P‐waves. We conducted a 3‐D near‐surface multicomponent source and receiver survey in Quaternary sediments. We employed a small electrodynamic seismic source with a horizontal shaking unit operated in two orientations. Three‐component geophones in an orthogonal layout covering an area of 117×99 m2 were used for recording. Changes in weather and ground conditions, including freezing and thawing during acquisition, directly influenced the data quality and resulted in discernible relative time shifts in the data. Our seismic processing flow included a four‐component rotation of the data from the Cartesian acquisition geometry into the ‘natural’ coordinate frame to orient sources and receivers in radial or transverse orientation to separate different S‐wave polarizations. The rotation increased the signal strength and helped, for example, to improve the quality of the images of the basin base. The irregular offset distribution in the common midpoint gathers impedes filtering to suppress surface waves in the f–k domain. We, therefore, applied a common‐reflection surface processing flow. After regularization, we could better remove the energy of the surface waves. Both stacked 3‐D S‐wave volumes of vertical and horizontal polarizations provide images of the Quaternary overdeepened Tannwald Basin that was partly known from previous P‐ and S‐wave 2‐D surveys. Compared to a P‐wave profile adjacent to the volume, however, the S‐wave volumes provide higher resolution images of the basin base and internal structure. The basin base is well mapped in three dimensions and shows undulations that were not obvious from the P‐wave data. Comparing the S‐wave volumes of different polarizations, we find only minor differences in the stacks and interpretations.
    Keywords: ddc:622.1592
    Language: English
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    Modeling Subsurface Hydrogen Storage With Transport Properties From Entropy Scaling Using the PC‐SAFT Equation of State (2022)
    Details
    Publication Date: 2022-10-17
    Description: Hydrogen is a promising alternative to carbon based energy carriers and may be stored in large quantities in subsurface storage deposits. This work assesses the impact of static (density and phase equilibria) and dynamic (viscosity and diffusion coefficients) properties on the pressure field during the injection and extraction of hydrogen in the porous subsurface. In a first step, we derive transport properties for water, hydrogen and their mixture using the Perturbed‐Chain Statistical Associating Fluid Theory equation of state in combination with an entropy scaling approach and compare model predictions to alternative models from the literature. Our model compares excellently to experimental transport coefficients and models from literature with a higher number of adjustable parameters, such as GERG2008, and shows a clear improvement over empirical correlations for transport coefficients of hydrogen. In a second step, we determine the effect of further model reduction by comparing our against a much simpler model applying empirical transport coefficients from the literature. For this purpose, hydrogen is periodically injected into and extracted out of a dome‐shaped porous aquifer under a caprock. Our results show that density and viscosity of hydrogen have the highest impact on the pressure field, and that a thermodynamic model like the new model presented here is essential for modeling the storage aquifer, while keeping the number of coefficients at a minimum. In diffusion‐dominated settings such as the diffusion of hydrogen through the caprock, our developed diffusion coefficients show a much improved dependence on temperature and pressure, leading to a more accurate approximation of the diffusive fluxes.
    Description: Key Points: We model the phase behavior of pure hydrogen and the binary hydrogen‐water mixture using the Perturbed‐Chain Statistical Associating Fluid Theory equation of state. New entropy scaling relations for the transport properties of hydrogen and water and diffusion coefficients of their mixture are derived. The impact of the newly derived fluid properties is analyzed for a scenario of hydrogen storage in a porous aquifer.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: https://git.iws.uni-stuttgart.de/dumux-pub/sauerborn2020a
    Keywords: ddc:550
    Language: English
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    Noah‐MP With the Generic Crop Growth Model Gecros in the WRF Model: Effects of Dynamic Crop Growth on Land‐Atmosphere Interaction (2022)
    Warrach‐Sagi, K. ; Ingwersen, J. ; Schwitalla, T. ; [et al.]
    Details
    Publication Date: 2022-10-17
    Description: In this paper we coupled a crop growth model to the Weather Research and Forecasting model with its land surface model Noah‐MP and demonstrated the influence of the weather driven crop growth on land‐atmosphere (L‐A) feedback. An impact study was performed at the convection permitting scale of 3 km over Germany. While the leaf area index (LAI) in the control simulation was the same for all cropland grid cells, the inclusion of the crop growth model resulted in heterogeneous crop development with higher LAI and stronger seasonality. For the analyses of L‐A coupling, a two‐legged metric was applied based on soil moisture, latent heat flux and convective available potential energy. Weak atmospheric coupling is enhanced by the crop model, the terrestrial coupling determines the regions with the L‐A feedback. The inclusion of the crop model turns regions with no L‐A feedback on this path into regions with strong positive coupling. The number of non‐atmospherically controlled days between April and August is increased by 10–15 days in more than 50% of Germany. Our work shows that this impact results in a reduction of both cold bias and warm biases and thus improves the metrics of distributed added value of the monthly mean temperatures. The study confirms that the simulation of the weather driven annual phenological development of croplands for the regional climate simulations in mid‐latitudes is crucial due to the L‐A feedback processes and the currently observed and expected future change in phenological phases.
    Description: Key Points: Coupling a crop growth model with the Weather and Research Forecasting model significantly improves the simulation of the leaf area index. Land‐atmosphere coupling strength is enhanced by weather dependent crop growth simulation. The distributed added value metric shows a reduction in temperature biases of up to 80% in croplands throughout the season in Germany.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://opendata.dwd.de/climate_environment/CDC/grids_germany/daily/Project_TRY/air_temperature_mean/
    Description: https://doi.org/10.5281/zenodo.6501984
    Description: http://land.copernicus.eu/pan-european/corine-land-cover/clc-2006/view
    Description: https://doi.org/10.1594/WDCC/WRF_NOAH_HWSD_world_TOP_SOILTYP
    Keywords: ddc:551.6
    Language: English
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    Gradual warming prior to the end‐Permian mass extinction (2022)
    Gliwa, Jana ; Wiedenbeck, Michael ; Schobben, Martin ; [et al.]
    Details
    Publication Date: 2022-10-18
    Description: The biggest known mass extinction in the history of animal life occurred at the Permian–Triassic boundary and has often been linked to global warming. Previous studies have suggested that a geologically rapid (〈40 kyr) temperature increase of more than 10°C occurred simultaneously with the main extinction pulse. This hypothesis is challenged by geochemical and palaeontological data indicating profound environmental perturbations and a temperature rise prior to the main extinction. Using secondary ion mass spectrometry (SIMS), we measured oxygen isotope ratios from Changhsingian (late Permian) ostracods of north‐western Iran. Our data show that ambient seawater temperature began to rise at least 300 kyr prior to the main extinction event. Gradual warming by approximately 12°C was probably responsible for initial environmental degradation that eventually culminated in the global end‐Permian mass extinction.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:560
    Language: English
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    Initial Response of Nightside Auroral Currents to a Sudden Commencement: Observations of Electrojet and Substorm Onset (2022)
    Details
    Publication Date: 2022-10-18
    Description: Storm sudden commencements (SSC) often precede geomagnetic storms. Commonly, it takes some hours from the step‐like change that marks the SSC to the start of the magnetic storm activity. In a subset of cases, however, auroral activity starts almost instantaneously after the SSC. To the authors knowledge, the conditions that enable this rapid activation have not been investigated in detail before. Here we consider all the sudden commencements (SC) during the years 2000–2020. Our focus is on the initial response of the auroral currents on the nightside. For that purpose, we make use of the IMAGE Magnetometer Network in Fennoscandia. In about 30% of SC events an initial activation of the westward electrojet is observed. Magnetic deflections of the northward component, surpassing frequently 1,000 nT, are observed only 4 min after the SC. These intense westward currents, flowing typically in narrow channels of 1°–2° latitudinal width, last some 10 min. The electrojets are conjugate to regions in the magnetosphere near geostationary orbits. In several cases geomagnetic substorm onsets are observed about 30 min after the SC. These start typically at fairly high latitude, around 71° magnetic latitude. This is an indication for rather quiet conditions preceding the onset. The magnetic pulse of the SC seems to play an important role in initiating the strong electrojets and the substorms. These initial activities are of relevance for space weather effects because of their strong and rapid variations. This paper provides detailed observations of the initial auroral activity following some SCs.
    Description: Key Points: First detailed study of intense electrojet activity at auroral latitudes on the nightside following immediately a sudden commencement (SC). Precondition for intense auroral activity is a southward interplanetary magnetic field Bz and a sufficiently large magnetic pulse caused by the SC. In a subset of events also an isolated substorm is initiated at relatively high magnetic latitudes shortly after the SC.
    Description: National Nature Science Foundation of China
    Description: https://spdf.gsfc.nasa.gov/pub/data/omni/high_res_omni/
    Keywords: ddc:538.7
    Language: English
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    From Dynamic Groundwater Level Measurements to Regional Aquifer Parameters— Assessing the Power of Spectral Analysis (2022)
    Details
    Publication Date: 2022-10-18
    Description: Large‐scale groundwater models are required to estimate groundwater availability and to inform water management strategies on the national scale. However, parameterization of large‐scale groundwater models covering areas of major river basins and more is challenging due to the lack of observational data and the mismatch between the scales of modeling and measurements. In this work, we propose to bridge the scale gap and derive regional hydraulic parameters by spectral analysis of groundwater level fluctuations. We hypothesize that specific locations in aquifers can reveal regional parameters of the hydraulic system. We first generate ensembles of synthetic but realistic aquifers which systematically differ in complexity. Applying Liang and Zhang’s (2013), https://doi.org/10.1016/j.jhydrol.2012.11.044, semi‐analytical solution for the spectrum of hydraulic head time series, we identify for each ensemble member and at different locations representative aquifer parameters. Next, we extend our study to investigate the use of spectral analysis in more complex numerical models and in real settings. Our analyses indicate that the variance of inferred effective transmissivity and storativity values for stochastic aquifer ensembles is small for observation points which are far away from the Dirichlet boundary. Moreover, the head time series has to cover a period which is roughly 10 times as long as the characteristic time of the aquifer. In deterministic aquifer models we infer equivalent, regionally valid parameters. A sensitivity analysis further reveals that as long as the aquifer length and the position of the groundwater measurement location is roughly known, the parameters can be robustly estimated.
    Description: Plain Language Summary: We build large‐scale (regional) computer models of the subsurface flow conditions in order to quantify the long‐term shift in groundwater storage and response on the national level under changing climatic conditions and increasing human water demands. These models must be fed with hydrogeological parameters obtained from subsurface observation wells, drilling logs, and hydraulic tests in conjunction with (hydro)geological and geostatistical methods. In some regions these wells are sparsely distributed and derived parameters are representative only for small areas. We hypothesize that groundwater level records can reveal regional aquifer information when analyzed in the spectral domain. In order to bridge that scale gap and because groundwater level time series are generally available, we propose to infer regional parameters by analyzing the frequency content (spectrum) of long groundwater level time series. The required parameters were determined using mathematical formulations of the theoretical spectrum for simplified settings. We tested the methodology in computer models with limited complexity and found that the groundwater level time series indeed contain regional information if the time of observation is sufficiently long. Lastly, we apply the spectral analysis to real groundwater data to test the capability of the method to infer regional aquifer parameters in real aquifers.
    Description: Key Points: We successfully tested the spectral analysis of groundwater level fluctuations in numerical models and obtained regional aquifer parameters. In a sensitivity analysis of the spectral analysis using field data, the storativity and the response times could be robustly estimated. The application of the suggested methodology to the field data from a catchment in central Germany produced plausible results.
    Description: Helmholtz Centre for Environmental Research (UFZ)
    Description: Global Resource Water
    Description: German Federal Ministry of Education and Research (BMBF)
    Description: IDAEA‐CSIC
    Description: Barcelona City Council
    Description: https://github.com/ufz/ogs5
    Description: https://geostat-framework.github.io/
    Keywords: ddc:551.49
    Language: English
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    Geostandards and Geoanalytical Research Bibliographic Review 2020 (2022)
    Weis, Ulrike ; Stoll, Brigitte ; Förster, Michael W. ; [et al.]
    Details
    Publication Date: 2022-10-19
    Description: Key Points: Literature review of 7200 geoanalytical publications for the year 2020. 628 selected articles with summaries of target analytes, relevant reference materials and producers. Selected publications include data obtained by new analytical developments and improved analytical protocols for established RMs, and identifies recently developed RMs for specific scientific topics. image
    Description: This bibliographic review gives an overview of scientific publications in 2020 that contribute important data for geoanalytical reference materials (RMs).
    Keywords: ddc:551.9
    Language: English
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    A storyline attribution of the 2011/2012 drought in Southeastern South America (2022)
    John Wiley & Sons, Ltd. | Chichester, UK
    Details
    Publication Date: 2022-08-04
    Description: The 2011/2012 summer drought in Southeastern South America (SESA) was a short but devastating event. What would this event have looked like under pre‐industrial conditions, or in a +2 degC world? We find that climate change causes the region to be at a higher risk of drought. However, we found no large‐scale changes in the half‐month water budgets. We show that the climate change induced positive precipitation trend in the region outweighs the increased temperatures and potential evapotranspiration during the 2011/2012 drought. image
    Keywords: ddc:551.5
    Language: English
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    Long‐term sulfamethazine leaching simulation in two different soils using the MACRO model (2022)
    Details
    Publication Date: 2022-08-04
    Description: Physically based models have been part of many risk assessment studies concerning pesticide or nutrient transport within (sub)catchments or at plot scale, but they are only poorly validated for simulating the transport of veterinary medicinal products. Veterinary medicinal products not only pose a risk to the quality of our waters but also tend to accumulate in soils, where they are associated with the appearance of resistant bacteria and long‐term leaching. In this study, the physically based leaching model MACRO 5.2 was applied for simulating sulfamethazine (SMZ) transport over a period of more than 10 yr. The model was set up using reversible kinetic adsorption and equilibrium adsorption forming non‐extractable residues. Two different calibration periods were used to estimate uncertainties in predicted SMZ leaching associated with calibration based on short‐term data. Using the whole period for model calibration, SMZ leaching could be simulated adequately, but parameter ranges were wide due to correlation between the parameters. When using only the first period for calibration, the quality of the prediction strongly depended on the information content of the data set. The calculation of temporal sensitivity indices revealed that the effect of complex sorption parameters on the model output increased with time. Thus, parameters that appeared insensitive in a short‐term calibration were required for reliable long‐term simulations. In conclusion, a temporal sensitivity analysis beyond the calibration period might identify parameters that were not constrained enough by the calibration procedure. This could help to confirm leaching predictions even for periods without sampling data.
    Description: Core Ideas: The MACRO model was successfully used to simulate long‐term SMZ leaching. A high information content of short‐term SMZ leaching data was key to successful long‐term simulations. The effect of environmental fate parameters (sorption, degradation) on the model outcome may change over time. Implementing complex sorption processes was mandatory for SMZ long‐term simulation. Temporal sensitivity analysis beyond the calibration span may detect parameters required for long‐term simulation.
    Keywords: ddc:363.7396
    Language: English
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    A Triad Photoanode for Visible Light‐Driven Water Oxidation via Immobilization of Molecular Polyoxometalate on Polymeric Carbon Nitride (2022)
    Details
    Publication Date: 2022-08-04
    Description: Due to their availability, low cost, nontoxicity, and tunability, polymeric carbon nitrides (CNx) represent one of the most attractive materials classes for the development of fully sustainable photo(electro)catalytic systems for solar‐driven water splitting. However, the development of CNx‐based photoanodes for visible light‐driven water oxidation to dioxygen is rather challenging, particularly due to issues related to photoelectrode stability and effective coupling of the light absorber with water oxidation catalysts. Herein, a triadic photoanode comprising a porous TiO2 electron collector scaffold sensitized by CNx coupled to a molecular cobalt polyoxometalate (CoPOM = [Co4(H2O)2(PW9O34)2]10) catalyst is reported. Complete water oxidation to dioxygen under visible (λ 〉 420 nm) light irradiation is demonstrated, with photocurrents down to relatively low bias potentials (0.2 V vs RHE). Furthermore, polyethyleneimine (PEI), a cationic polymer is shown to act as an effective and non‐sacrificial electrostatic linker for immobilization of the anionic CoPOM onto the negatively charged surface of CNx. The optimized deposition of CoPOM using the PEI linker translates directly into improved efficiency of the transfer of photogenerated holes to water molecules and to enhanced oxygen evolution. This work thus provides important design rules for effective immobilization of POM‐based catalysts into soft‐matter photoelectrocatalytic architectures for light‐driven water oxidation.
    Description: A triadic photoanode comprised of a porous TiO2 electron collector scaffold sensitized by polymeric carbon nitride and coupled to a molecular cobalt polyoxometalate (CoPOM) catalyst exhibits visible (λ 〉 420 nm) light‐driven water oxidation to dioxygen. The beneficial role of the cationic polyethyleneimine polymer as an effective electrostatic linker for immobilization of CoPOM onto carbon nitride is highlighted.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Vector Stiftung http://dx.doi.org/10.13039/501100013912
    Keywords: ddc:551.9
    Language: English
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    Thickness of Fluvial Deposits Records Climate Oscillations (2022)
    Details
    Publication Date: 2022-08-04
    Description: Fluvial deposits offer Earth’s best‐preserved geomorphic record of past climate change over geological timescales. However, quantitatively extracting this information remains challenging in part due to the complexity of erosion, sediment transport and deposition processes and how each of them responds to climate. Furthermore, sedimentary basins have the potential to temporarily store sediments, and rivers subsequently rework those sediments. This may introduce time lags into sedimentary signals and obscure any direct correlation with climate forcing. Here, using a numerical model that combines all three processes—and a new analytical solution—we show that the thickness of fluvial deposits at the outlet of a mountain river can be linked to the amplitude and period of rainfall oscillations but is modulated by the mountain uplift rate. For typical uplift rates of a few mm/yr, climate oscillations at Milankovitch periods lead to alluvial sediment thickness of tens of meters as observed in nature. We also explain the time lag of the order of 20%–25% of the forcing period that is commonly observed between the timing of maximum rainfall and erosion. By comparing to field datasets, our predictions for the thickness and time lag of fluvial deposits are broadly consistent with observations despite the simplicity of our modeling approach. These findings provide a new theoretical framework for quantitatively extracting information on past rainfall variations from fluvial deposits.
    Description: Plain Language Summary: Climate influences the evolution of terrestrial landscapes through the amount of precipitation, which provides water to erode rocks and transport sediment in rivers. At the outlets of mountain ranges, rivers can deposit part of their sediment load; the shape of the deposits is influenced by the amount of flow in the rivers. If the climate changes such that the precipitation rate increases, rivers can cut into their own previous deposits. The remaining deposits are then abandoned above the riverbed. On the contrary, if precipitation decreases, rivers tend to deposit more sediment, leading to increases in the thickness of sediments at the outlets of mountain rivers. Thus, there is a relationship between the amount of precipitations and the thickness of sediments deposited at river outlets. We study this with a computer model that allows us to relate the variations in precipitation rates to variations in thickness of fluvial terrace deposits. This work can be used to better understand how rivers respond to climatic changes, and also to reconstruct climatic variations of the past from observed river deposits.
    Description: Key Points: We use a numerical model and a new analytical solution to quantify a physical link between fluvial deposits and climate oscillations. Our method provides a theoretical framework for extracting information on past climate variations from fluvial terrace deposits. Our results explain time lag of 20%–25% of forcing period commonly observed between the timing of maximum rainfall and erosion.
    Description: TOTAL
    Description: Marie Sklodowska‐Curie grant
    Description: https://doi.org/10.5281/zenodo.3833983
    Keywords: ddc:550.724
    Language: English
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    An Energy Conserving Vlasov Solver That Tolerates Coarse Velocity Space Resolutions: Simulation of MMS Reconnection Events (2022)
    Details
    Publication Date: 2022-08-05
    Description: Vlasov solvers that operate on a phase‐space grid are highly accurate but also numerically demanding. Coarse velocity space resolutions, which are largely unproblematic in particle‐in‐cell (PIC) simulations, can lead to numerical heating or oscillations in continuum Vlasov methods. To address this issue, we present a new dual Vlasov solver which is based on an established positivity preserving advection scheme for the update of the distribution function and an energy conserving partial differential equation solver for the kinetic update of mean velocity and temperature. The solvers work together via moment fitting during which the maximum entropy part of the distribution function is replaced by the solution from the partial differential equation solver. This numerical scheme makes continuum Vlasov methods competitive with PIC methods concerning computational cost and enables us to model large scale reconnection in Earth's magnetosphere with a fully kinetic continuum method. The simulation results agree well with measurements by the MMS spacecraft.
    Description: Key Points: A moment fitting continuum Vlasov solver is presented that preserves positivity of the distribution function and conserves total energy. The method behaves well at low velocity space resolutions, making it competitive with PIC methods concerning computational cost. There is good agreement of the simulations with measurements of magnetic reconnection by the MMS spacecraft.
    Description: Helmholtz Association (亥姆霍兹联合会致力) http://dx.doi.org/10.13039/501100009318
    Description: https://vlasov.tp1.ruhr-uni-bochum.de/data/paper-JGR-2021
    Keywords: ddc:550 ; ddc:538.7
    Language: English
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    Melting Behavior of Rimed and Unrimed Snowflakes Investigated With Statistics of Triple‐Frequency Doppler Radar Observations (2022)
    Details
    Publication Date: 2022-08-05
    Description: Comparing the reflectivity flux at the top and bottom of the melting layer (ML) reveals the overall effect of the microphysical processes occurring within the ML on the particle population. If melting is the only process taking place and all particles scatter in the Rayleigh regime, the reflectivity flux increases in the ML by a constant factor given by the ratio of the dielectric factors. Deviations from this constant factor can indicate that either growth or shrinking processes (breakup, sublimation, and evaporation) dominate. However, inference of growth or shrinking dominance from the increase in reflectivity flux is only possible if other influences (e.g., vertical wind speed) are negligible or corrected. By analyzing radar Doppler spectra and multi‐frequency observations, we correct the reflectivity fluxes for vertical wind and categorize the height profiles by the riming degree at the ML top. We apply this reflectivity flux ratio (ZFR) approach to a multi‐month mid‐latitude winter data set that contains mostly stratiform clouds. The profiles of radar variables in the ML are found to be surprisingly similar for both unrimed and rimed profiles with slight differences, for example, in the absolute values of the reflectivity flux. Statistical analysis of the ZFR suggests that either microphysical processes other than melting are not important or strongly compensate for each other. The results seem to confirm that at least for moderately precipitating stratiform clouds, the melting‐only assumption applied in several retrievals and microphysical schemes is reasonable.
    Description: Plain Language Summary: To better predict precipitation by numerical models and quantify precipitation by observations, it is important to improve the understanding of processes in the melting layer (ML). The ML is the part of clouds where ice particles melt and become rain. We use an approach that assesses whether a tendency toward either growth or shrinking processes is evident in the ML. We assess the uncertainty of the approach, correct for different factors, and apply it to a large data set to derive robust statistics separately for profiles with different characteristic ice particle shapes above the ML. These statistics are surprisingly similar for the different characteristic ice particle shapes and suggest that either growth and shrinking processes are not important in the ML or strongly compensate for each other.
    Description: Key Points: We investigated the growth or shrinking of snowflakes in the melting layer using statistics of multi‐frequency Doppler radar observations. Reflectivity flux analysis indicates only slight differences for unrimed or rimed particles. Growth or shrinking processes either compensate each other or have, on average, only a small impact on the reflectivity flux.
    Description: German Research Foundation http://dx.doi.org/10.13039/501100001659
    Description: University of Cologne
    Description: https://github.com/markuskarrer/ZFR_riming
    Description: http://cpex-lab.de/cpex-lab/EN/Home/JOYCE-CF/JOYCE-CF_node.html
    Description: https://doi.org/10.5281/zenodo.6341509
    Description: https://doi.org/10.5281/zenodo.5959906
    Keywords: ddc:551.57
    Language: English
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    On the evaluation of climate change impact models (2022)
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-08-05
    Description: In‐depth understanding of the potential implications of climate change is required to guide decision‐ and policy‐makers when developing adaptation strategies and designing infrastructure suitable for future conditions. Impact models that translate potential future climate conditions into variables of interest are needed to create the causal connection between a changing climate and its impact for different sectors. Recent surveys suggest that the primary strategy for validating such models (and hence for justifying their use) heavily relies on assessing the accuracy of model simulations by comparing them against historical observations. We argue that such a comparison is necessary and valuable, but not sufficient to achieve a comprehensive evaluation of climate change impact models. We believe that a complementary, largely observation‐independent, step of model evaluation is needed to ensure more transparency of model behavior and greater robustness of scenario‐based analyses. This step should address the following four questions: (1) Do modeled dominant process controls match our system perception? (2) Is my model's sensitivity to changing forcing as expected? (3) Do modeled decision levers show adequate influence? (4) Can we attribute uncertainty sources throughout the projection horizon? We believe that global sensitivity analysis, with its ability to investigate a model's response to joint variations of multiple inputs in a structured way, offers a coherent approach to address all four questions comprehensively. Such additional model evaluation would strengthen stakeholder confidence in model projections and, therefore, into the adaptation strategies derived with the help of impact models.
    Description: A comprehensive evaluation of climate change impact models combining both observation‐based and response‐based strategies.
    Description: This article is categorized under: Climate Models and Modeling 〉 Knowledge Generation with Models Assessing Impacts of Climate Change 〉 Evaluating Future Impacts of Climate Change
    Description: Alexander von Humboldt‐Stiftung http://dx.doi.org/10.13039/100005156
    Description: Engineering and Physical Sciences Research Council http://dx.doi.org/10.13039/501100000266
    Keywords: ddc:551.6
    Language: English
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    The ICON Earth System Model Version 1.0 (2022)
    Details
    Publication Date: 2022-08-05
    Description: This work documents the ICON‐Earth System Model (ICON‐ESM V1.0), the first coupled model based on the ICON (ICOsahedral Non‐hydrostatic) framework with its unstructured, icosahedral grid concept. The ICON‐A atmosphere uses a nonhydrostatic dynamical core and the ocean model ICON‐O builds on the same ICON infrastructure, but applies the Boussinesq and hydrostatic approximation and includes a sea‐ice model. The ICON‐Land module provides a new framework for the modeling of land processes and the terrestrial carbon cycle. The oceanic carbon cycle and biogeochemistry are represented by the Hamburg Ocean Carbon Cycle module. We describe the tuning and spin‐up of a base‐line version at a resolution typical for models participating in the Coupled Model Intercomparison Project (CMIP). The performance of ICON‐ESM is assessed by means of a set of standard CMIP6 simulations. Achievements are well‐balanced top‐of‐atmosphere radiation, stable key climate quantities in the control simulation, and a good representation of the historical surface temperature evolution. The model has overall biases, which are comparable to those of other CMIP models, but ICON‐ESM performs less well than its predecessor, the Max Planck Institute Earth System Model. Problematic biases are diagnosed in ICON‐ESM in the vertical cloud distribution and the mean zonal wind field. In the ocean, sub‐surface temperature and salinity biases are of concern as is a too strong seasonal cycle of the sea‐ice cover in both hemispheres. ICON‐ESM V1.0 serves as a basis for further developments that will take advantage of ICON‐specific properties such as spatially varying resolution, and configurations at very high resolution.
    Description: Plain Language Summary: ICON‐ESM is a completely new coupled climate and earth system model that applies novel design principles and numerical techniques. The atmosphere model applies a non‐hydrostatic dynamical core, both atmosphere and ocean models apply unstructured meshes, and the model is adapted for high‐performance computing systems. This article describes how the component models for atmosphere, land, and ocean are coupled together and how we achieve a stable climate by setting certain tuning parameters and performing sensitivity experiments. We evaluate the performance of our new model by running a set of experiments under pre‐industrial and historical climate conditions as well as a set of idealized greenhouse‐gas‐increase experiments. These experiments were designed by the Coupled Model Intercomparison Project (CMIP) and allow us to compare the results to those from other CMIP models and the predecessor of our model, the Max Planck Institute for Meteorology Earth System Model. While we diagnose overall satisfactory performance, we find that ICON‐ESM features somewhat larger biases in several quantities compared to its predecessor at comparable grid resolution. We emphasize that the present configuration serves as a basis from where future development steps will open up new perspectives in earth system modeling.
    Description: Key Points: This work documents ICON‐ESM 1.0, the first version of a coupled model based on the ICON framework. Performance of ICON‐ESM is assessed by means of CMIP6 Diagnosis, Evaluation, and Characterization of Klima experiments at standard CMIP‐type resolution. ICON‐ESM reproduces the observed temperature evolution. Biases in clouds, winds, sea‐ice, and ocean properties are larger than in MPI‐ESM.
    Description: European Union H2020 ESM2025
    Description: European Union H2020 COMFORT
    Description: European Union H2020ESiWACE2
    Description: Deutsche Forschungsgemeinschaft TRR181
    Description: Deutsche Forschungsgemeinschaft EXC 2037
    Description: European Union H2020
    Description: Deutscher Wetterdienst
    Description: Bundesministerium fuer Bildung und Forschung
    Description: http://esgf-data.dkrz.de/search/cmip6-dkrz/
    Description: https://mpimet.mpg.de/en/science/modeling-with-icon/code-availability
    Description: http://cera-www.dkrz.de/WDCC/ui/Compact.jsp?acronym=RUBY-0_ICON-_ESM_V1.0_Model
    Keywords: ddc:550.285 ; ddc:551.63
    Language: English
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    Olivine aggregates reveal a complex collisional history of the main group pallasite parent body (2022)
    Details
    Publication Date: 2022-08-05
    Description: Olivine aggregates, bodies found in pallasites that consist of olivines with coherent grain boundaries and minor amounts of Fe‐Ni and troilite, likely represent well‐preserved samples of different mantle regions of pallasite parent bodies (PPBs). We investigated olivine aggregates from the main group pallasites Fukang, Esquel, Imilac, and Seymchan and compare their textures with results from deformation experiments. Our measurements reveal an inverse relationship between the grain size of olivines and the primary metal fraction inside olivine aggregates, which is explained by simultaneous grain growth retarded by Zener pinning in different mantle regions. Textural evidence indicates that the mantle has remained at high temperatures before initial cooling occurred shortly after pallasite formation that was likely caused by an impact. Different degrees of annealing of the deformation textures suggest that the postcollisional cooling occurred in the order Seymchan, Imilac, Esquel, and Fukang. We interpret this observation with an increasing burial depth after the collision. We also demonstrate that the mantle has not been convecting before the impact despite being at high temperature. Using the minimum critical Rayleigh number, we estimate PPB radii assuming different core radii. Our results question the recent ferromagmatism hypothesis for pallasite formation and support a multistage formation process that includes one or several impacts.
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Keywords: ddc:549.1
    Language: English
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    Plate corner subduction and rapid localized exhumation: Insights from 3D coupled geodynamic and geomorphological modelling (2022)
    Details
    Publication Date: 2022-08-05
    Description: Rapid, localized exhumation has been reported at many plate corners between adjacent subduction/collision segments. Here we use a fully‐coupled geodynamic and geomorphological modelling approach to investigate overriding plate deformation and resulting rock uplift patterns in these narrow, cuspate regions. In this study, we focus on the effects of internal deformation within a subducting convex‐upward‐shaped indenter and the strength of the interface between the upper and downgoing plate. The strongest localization of high rock uplift rates in the region above the indenter apex is predicted in experiments with a deformable lower plate, a weak interface layer and lateral shortening accommodated only by subduction (i.e., without an upper plate advance component). Our results suggest that bull’s eye shaped structures characterized by young thermochronological ages can, in principle, be reproduced numerically when taking into account a non‐rigid subducting plate together with complex brittle‐ductile rheology and stratification of the overriding lithosphere and realistically implemented fluvial erosion at its surface.
    Description: Alexander von Humboldt‐Stiftung http://dx.doi.org/10.13039/100005156
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: European Research Council http://dx.doi.org/10.13039/100010663
    Keywords: ddc:551.1
    Language: English
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    Strengths and limitations of in situ U–Pb titanite petrochronology in polymetamorphic rocks: An example from western Maine, USA (2022)
    Details
    Publication Date: 2022-09-27
    Description: Titanite is a potentially powerful U–Pb petrochronometer that may record metamorphism, metasomatism, and deformation. Titanite may also incorporate significant inherited Pb, which may lead to inaccurate and geologically ambiguous U–Pb dates if a proper correction is not or cannot be applied. Here, we present laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS)‐derived titanite U–Pb dates and trace element concentrations for two banded calcsilicate gneisses from south‐central Maine, USA (SSP18‐1A and SSP18‐1B). Single spot common Pb‐corrected dates range from 400 to 280 Ma with ±12–20 Ma propagated 2SE. Titanite grains in sample SSP18‐1B exhibit regular core‐to‐rim variations in texture, composition, and date. We identify four titanite populations: (1) 397 ± 5 Ma (95% CL) low Y + HREE cores and mottled grains, (2) 370 ± 7 Ma high Y + REE mantles and cores, (3) 342 ± 6 Ma cores with high Y + REE and no Eu anomaly, and (4) 295 ± 6 Ma LREE‐depleted rims. We interpret the increase in titanite Y + HREE between ca. 397 and ca. 370 Ma to constrain the timing of diopside fracturing and recrystallization and amphibole breakdown. Apparent Zr‐in‐titanite temperatures (803 ± 36°C at 0.5 ± 0.2 GPa) and increased XDi suggest a thermal maximum at ca. 370 Ma. Population 3 domains dated to ca. 342 Ma exhibit no Eu anomaly and are observed only in compositional bands dominated by diopside (〉80 vol%), suggesting limited equilibrium between titanite and plagioclase. Finally, low LREE and high U/Th in Population 4 titanite dates the formation of hydrous phases, such as allanite, during high XH2O fluid infiltration at ca. 295 Ma. In contrast to the well‐defined date–composition–texture relationships observed for titanite from SSP18‐1B, titanite grains from sample SSP18‐1A exhibit complex zoning patterns and little correlation between texture, composition, and date. We hypothesize that the incorporation of variable amounts of radiogenic Pb from dissolved titanite into recrystallized domains resulted in mixed dates spanning 380–330 Ma. Although titanite may reliably record multiple phases of metamorphism, these data highlight the importance of considering U–Pb data along with chemical and textural data to screen for inherited radiogenic Pb.
    Description: The University of Maine
    Description: US‐DE Fulbright Komission
    Keywords: ddc:552.4
    Language: English
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    Mesocrystalline Architecture in Hyaline Foraminifer Shells Indicates a Non‐Classical Crystallisation Pathway (2022)
    Details
    Publication Date: 2022-09-27
    Description: Calcareous foraminifer shells (tests) represent one of the most important archives for paleoenvironmental and paleoclimatic reconstruction. To develop a mechanistic understanding of the relationship between environmental parameters and proxy signals, knowledge of the fundamental processes operating during foraminiferal biomineralization is essential. Here, we apply microscopic and diffraction‐based methods to address the crystallographic and hierarchical structure of the test wall of different hyaline foraminifer species. Our results show that the tests are constructed from micrometer‐scale oriented mesocrystals built of nanometer‐scale entities. Based on these observations, we propose a mechanistic extension to the biomineralization model for hyaline foraminifers, centered on the formation and assembly of units of metastable carbonate phases to the final mesocrystal via a non‐classical particle attachment process, possibly facilitated by organic matter. This implies the presence of metastable precursors such as vaterite or amorphous calcium carbonate, along with phase transitions to calcite, which is relevant for the mechanistic understanding of proxy incorporation in the hyaline foraminifers.
    Description: Plain Language Summary: Foraminifers are single celled marine organisms typically half a millimeter in size, which form shells made of calcium carbonate. During their life, the chemical composition of their shells records environmental conditions. By analyzing fossil shells, past conditions can be reconstructed to understand ancient oceans and climate change. To do that correctly, we need to know exactly how foraminifers form their shell. We find that foraminifers build micrometer‐sized mesocrystals which are made of smaller building blocks. This means that the smallest building blocks form first and assemble to form a larger grain, which is oriented in a specific direction. To align all the building blocks, it is possible that they are first unstable and undergo transformation on assembly, during which their composition may change. By understanding and quantifying this process, the composition of the final fossil shell may be understood, ultimately leading to more reliable reconstructions of past environmental change.
    Description: Key Points: Hyaline foraminiferal shells are built of micrometer sized mesocrystalline units. Biomineralization likely includes the formation and assembly of nanoparticles. Nanometer sized units suggest non‐classical crystal growth.
    Description: https://doi.org/10.17617/3.D7HN3I
    Keywords: ddc:561.9 ; ddc:549
    Language: English
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    Lagrangian Analysis of Moisture Sources of Precipitation in the Tianshan Mountains, Central Asia (2022)
    Details
    Publication Date: 2022-09-27
    Description: The moisture sources of precipitation in the Tianshan Mountains, one of the regions with the highest precipitation in Central Asia during 1979–2017 are comprehensively and quantitatively summarized by using a Lagrangian moisture source detection technique. Continental sources provide about 93.2% of the moisture for precipitation in the Tianshan Mountain, while moisture directly from the ocean is very limited, averaging only 6.8%. Central Asia plays a dominant role in providing moisture for all sub‐regions of the Tianshan Mountains. For the Western Tianshan, moisture from April to October comes mainly from Central Asia (41.4%), while moisture from November to March is derived primarily from Western Asia (45.7%). Nearly 13.0% of moisture to precipitation for Eastern Tianshan in summer originates from East and South Asia, and the Siberia region. There is a significant decreasing trend in the moisture contribution of local evaporation and Central Asia in the Eastern Tianshan during winter. The contribution of moisture from Europe to summer precipitation in the Central and Eastern Tianshan and the contribution of the North Atlantic Ocean to summer precipitation in the Northern, Central, and Eastern Tianshan also exhibit a decreasing trend. The largest increase in moisture in Western Tianshan stems from West Asia during extreme winter precipitation months. Europe is also an important contributor to extreme precipitation in the Northern Tianshan. The moisture from East and South Asia and Siberia during extreme precipitation months in both winter and summer is significantly enhanced in the Eastern Tianshan.
    Description: Key Points: Local evaporation and Central Asia play a leading role in providing moisture for all sub‐regions of the Tianshan Mountains. The largest moisture component during the months of extreme winter precipitation for Western Tianshan derives from western Asia. Moisture from East and South Asia and Siberia during extreme precipitation months is significantly enhanced in the Eastern Tianshan.
    Description: China Scholarship Council
    Description: Humboldt‐Universität zu Berlin
    Description: https://zenodo.org/record/6451656#.YrrfbqhBwuU
    Keywords: ddc:551.6
    Language: English
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    Late Quaternary paleoenvironmental reconstructions from sediments of Lake Emanda (Verkhoyansk Mountains, East Siberia) (2022)
    Andreev, Andrei A. ; Nazarova, Larisa B. ; Lenz, Marlene M. ; [et al.]
    Details
    Publication Date: 2022-09-27
    Description: Continuous pollen and chironomid records from Lake Emanda (65°17′N, 135°45′E) provide new insights into the Late Quaternary environmental history of the Yana Highlands (Yakutia). Larch forest with shrubs (alders, pines, birches) dominated during the deposition of the lowermost sediments suggesting its Early Weichselian [Marine Isotope Stage (MIS) 5] age. Pollen‐ and chironomid‐based climate reconstructions suggest July temperatures (TJuly) slightly lower than modern. Gradually increasing amounts of herb pollen and cold stenotherm chironomid head capsules reflect cooler and drier environments, probably during the termination of MIS 5. TJuly dropped to 8 °C. Mostly treeless vegetation is reconstructed during MIS 3. Tundra and steppe communities dominated during MIS 2. Shrubs became common after ~14.5 ka bp but herb‐dominated habitats remained until the onset of the Holocene. Larch forests with shrub alder and dwarf birch dominated after the Holocene onset, ca. 11.7 ka bp. Decreasing amounts of shrub pollen during the Lateglacial are assigned to the Older Dryas and Younger Dryas with TJuly ~ 7.5 °C. TJuly increased up to 13 °C. Shrub stone pine was present after ~7.5 ka bp. The vegetation has been similar to modern since ca. 5.8 ka bp. Chironomid diversity and concentration in the sediments increased towards the present day, indicating the development of richer hydrobiological communities in response to the Holocene thermal maximum.
    Description: Russian Scientific Foundation
    Description: German Federal Ministry of Education and Research
    Description: European Research Council http://dx.doi.org/10.13039/501100000781
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: RSF
    Description: Russian Ministry of Education and Science
    Description: Federal Ministry of Education and Research
    Description: BMBF
    Keywords: ddc:560
    Language: English
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    Inspecting the Reliability of Geochemical Facies Identified for the Waterworks' Capture Zone in Germany (2022)
    Blackwell Publishing Ltd | Malden, US
    Details
    Publication Date: 2022-09-27
    Description: Little research attention has been given to validating clusters obtained from the groundwater geochemistry of the waterworks' capture zone with a prevailing lake‐groundwater exchange. To address this knowledge gap, we proposed a new scheme whereby Gaussian finite mixture modeling (GFMM) and Spike‐and‐Slab Bayesian (SSB) algorithms were utilized to cluster the groundwater geochemistry while quantifying the probability of the resulting cluster membership against each other. We applied GFMM and SSB to 13 geochemical parameters collected during different sampling periods at 13 observation points across the Barnim Highlands plateau located in the northeast of Berlin, Germany; this included 10 observation wells, two lakes, and a gallery of drinking production wells. The cluster analysis of GFMM yielded nine clusters, either with a probability ≥0.8, while the SSB produced three hierarchical clusters with a probability of cluster membership varying from 〈0.2 to 〉0.8. The findings demonstrated that the clustering results of GFMM were in good agreement with the classification as per the principal component analysis and Piper diagram. By superimposing the parameter clustering onto the observation clustering, we could identify discrepancies that exist among the parameters of a certain cluster. This enables the identification of different factors that may control the geochemistry of a certain cluster, although parameters of that cluster share a strong similarity. The GFMM results have shown that from 2002, there has been active groundwater inflow from the lakes towards the capture zone. This means that it is necessary to adopt appropriate measures to reverse the inflow towards the lakes.
    Description: Article impact statement: The probability of cluster membership quantified using an algorithm should be validated against another probabilistic‐based classifier.
    Description: Federal Ministry of Education and Research http://dx.doi.org/10.13039/501100002347
    Keywords: ddc:551.9 ; ddc:551.49
    Language: English
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    Stratospheric Moistening After 2000 (2022)
    Details
    Publication Date: 2022-09-27
    Description: The significant climate feedback of stratospheric water vapor (SWV) necessitates quantitative estimates of SWV budget changes. Model simulations driven by the newest European Centre for Medium‐Range Weather Forecast reanalysis ERA5, satellite observations from the Stratospheric Water and OzOne Satellite Homogenized data set, Microwave Limb Sounder, and in situ frost point hygrometer observations from Boulder all show substantial and persistent stratospheric moistening after a sharp drop in water vapor at the turn of the millennium. This moistening occurred mainly during 2000–2006 and SWV abundances then remained high over the last decade. We find strong positive trends in the Northern Hemisphere and weak negative trends over the South Pole, mainly during austral winter. Moistening of the tropical stratosphere after 2000 occurred during late boreal winter/spring, reached values of ∼0.2 ppm/decade, was well correlated with a warming of the cold point tropopause by ∼0.4 K/decade and can only be partially attributed to El Nino‐Southern Oscillation and volcanic eruptions.
    Description: Plain Language Summary: Water vapor is an effective greenhouse gas. Human‐induced climate change has led to warmer air in the troposphere, which consequently can hold more moisture, thus enhancing the greenhouse effect. The long‐term change in stratospheric water vapor (SWV) is less clear and currently under debate. Using satellite observations, balloon soundings and model simulations, we find an increase of SWV after 2000. This moistening occurred mainly during 2000–2006 and the stratospheric moisture content then remained high over the last decade. The increase of SWV is stronger in the Northern than in the Southern Hemisphere. Over the South Pole, a weak decrease was found. Moistening of the tropical stratosphere occurred mainly during late winter and spring, and was in line with warming of the tropical tropopause, the coldest region that separates the troposphere and stratosphere. Natural causes such as volcanic eruptions cannot completely explain this stratospheric moistening.
    Description: Key Points: Stratospheric moistening after 2000 is clearly detectable in ERA5‐driven simulations, satellite and in situ observations. Hemispheric asymmetry is found with strong positive trends in the Northern Hemisphere and weak negative trends over the South Pole. Moistening of the lower tropical stratosphere is only partially caused by El Nino‐Southern Oscillation and volcanic eruptions.
    Description: https://doi.org/10.5067/Aura/MLS/DATA2508
    Description: https://doi.org/10.5067/GLOSSAC-L3-V2.0
    Description: https://doi.org/10.5067/GLOSSAC-L3-V2.0
    Keywords: ddc:551.6
    Language: English
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    Geomagnetic Detection of the Atmospheric Acoustic Resonance at 3.8 mHz During the Hunga Tonga Eruption Event on 15 January 2022 (2022)
    Details
    Publication Date: 2022-09-29
    Description: Modeling studies have predicted that the acoustic resonance of the atmosphere during geophysical events such as earthquakes and volcanos can lead to an oscillation of the geomagnetic field with a frequency of about 4 mHz. However, observational evidence is still limited due to scarcity of suitable events. On 15 January 2022, the submarine volcano Hunga Tonga‐Hunga Ha'apai (20.5°S, 175.4°W, Tonga) erupted in the Pacific Ocean and caused severe atmospheric disturbance, providing an opportunity to investigate geomagnetic effects associated with acoustic resonance. Following the eruption, geomagnetic oscillation is observed at Apia, approximately 835 km from Hunga Tonga, mainly in the Pc 5 band (150–600 s, or 1.7–6.7 mHz) lasting for about 2 hr. The dominant frequency of the oscillation is 3.8 mHz, which is consistent with the frequency of the atmospheric oscillation due to acoustic resonance. The oscillation is most prominent in the eastward (Y) component, with an amplitude of ∼3 nT, which is much larger than those previously reported for other events (〈1 nT). Comparably large oscillation is not found at other stations located further away (〉2700 km). However, geomagnetic oscillation with a much smaller amplitude (∼0.3 nT) is observed at Honolulu, which is located near the magnetic conjugate point of Hunga Tonga, in a similar wave form as at Apia, indicating interhemispheric coupling. This is the first time that geomagnetic oscillations due to the atmospheric acoustic resonance are simultaneously detected at magnetic conjugate points.
    Description: Key Points: The effect of the January 2022 Hunga Tonga‐Hunga Ha’apai volcano eruption on the geomagnetic field is examined. Geomagnetic oscillation with a frequency of ∼3.8 mHz is observed simultaneously near the volcano and its magnetic conjugate point. The oscillation is attributed to the acoustic resonance of the atmosphere.
    Description: Coordenação de Aperfeiçoamento de Pessoal de Nível Superior http://dx.doi.org/10.13039/501100002322
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://www.intermagnet.org/data-donnee/download-eng.php
    Keywords: ddc:538.7 ; ddc:551.5
    Language: English
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    Role of Poroelasticity During the Early Postseismic Deformation of the 2010 Maule Megathrust Earthquake (2022)
    Peña, Carlos ; Metzger, Sabrina ; Heidbach, Oliver ; [et al.]
    Details
    Publication Date: 2022-09-29
    Description: Megathrust earthquakes impose changes of differential stress and pore pressure in the lithosphere‐asthenosphere system that are transiently relaxed during the postseismic period primarily due to afterslip, viscoelastic and poroelastic processes. Especially during the early postseismic phase, however, the relative contribution of these processes to the observed surface deformation is unclear. To investigate this, we use geodetic data collected in the first 48 days following the 2010 Maule earthquake and a poro‐viscoelastic forward model combined with an afterslip inversion. This model approach fits the geodetic data 14% better than a pure elastic model. Particularly near the region of maximum coseismic slip, the predicted surface poroelastic uplift pattern explains well the observations. If poroelasticity is neglected, the spatial afterslip distribution is locally altered by up to ±40%. Moreover, we find that shallow crustal aftershocks mostly occur in regions of increased postseismic pore‐pressure changes, indicating that both processes might be mechanically coupled.
    Description: Plain Language Summary: Large earthquakes modify the state of stress and pore pressure in the upper crust and mantle. These changes induce stress relaxation processes and pore pressure diffusion in the postseismic phase. The two main stress relaxation processes are postseismic slip along the rupture plane of the earthquake and viscoelastic deformation in the rock volume. These processes decay with time, but can sustain over several years or decades, respectively. The other process that results in volumetric crustal deformation is poroelasticity due to pore pressure diffusion, which has not been investigated in detail. Using postseismic surface displacement data acquired by radar satellites after the 2010 Maule earthquake, we show that poroelastic deformation may considerably affect the vertical component of the observed geodetic signal during the first months. Poroelastic deformation also has an impact on the estimation of the postseismic slip, which in turn affects the energy stored at the fault plane that is available for the next event. In addition, shallow aftershocks within the continental crust show a good, positive spatial correlation with regions of increased postseismic pore‐pressure changes, suggesting they are linked. These findings are thus important to assess the potential seismic hazard of the segment.
    Description: Key Points: A poro‐viscoelastic deformation model improves the geodetic data misfit by 14% compared to an elastic model that only accounts for afterslip. Poroelastic deformation mainly produces surface uplift and landward displacement patterns on the coastal forearc region. Neglecting poroelastic effects may locally alter the afterslip amplitude by up to ±40% near the region of maximum coseismic slip.
    Description: Helmholtz Association (亥姆霍兹联合会致力) http://dx.doi.org/10.13039/501100009318
    Keywords: ddc:551
    Language: English
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    The detection of bacterial exometabolites in marine dissolved organic matter through ultrahigh‐resolution mass spectrometry (2022)
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-10-01
    Description: Bacteria play a key role in sustaining the chemodiversity of marine dissolved organic matter (DOM), yet there is limited direct evidence of a major contribution of bacterial exometabolites to the DOM pool. This study tests whether molecular formulae of intact exometabolites can be detected in natural DOM via untargeted Fourier‐transform ion cyclotron resonance mass spectrometry (FT‐ICR‐MS). We analyzed a series of quantitative mixtures of solid‐phase extracted DOM from the deep ocean, of a natural microbial community and selected model strains of marine bacteria. Under standard instrument settings (200 broadband scans, mass range 92–1000 Da), 77% of molecular formulae were shared between the mesocosm and marine DOM. However, there was 〈 10% overlap between pure bacterial exometabolome with marine DOM, and in mixing ratios closest to mimicking natural environments (1% bacterial DOM, 99% marine DOM), only 4% of the unique bacterial exometabolites remained detectable. Further experiments with the bacterial exometabolome DOM mixtures using enhanced instrument settings resulted in increased detection of the exometabolites at low concentrations. At 1000 and 10,000 accumulated scans, 23% and 29% of the unique molecular formulae were detectable at low concentrations, respectively. Moreover, windowing a specific mass range encompassing a representative fraction of exometabolites tripled the number of unique detected formulae at low concentrations. Routine FT‐ICR‐MS settings are thus not always sufficient to distinguish bacterial exometabolome patterns from a seawater DOM background. To observe these patterns at higher sensitivity, we recommend a high scan number coupled with windowing a characteristic region of the molecular fingerprint.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.46 ; ddc:579.3 ; ddc:
    Language: English
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    Application of mixed‐effects modelling and rule‐based models to explain copper variation in soil profiles of southern Germany (2022)
    Blackwell Publishing Ltd | Oxford, UK
    Details
    Publication Date: 2022-10-01
    Description: Copper (Cu) is an essential element for plants and microorganisms and at larger concentrations a toxic pollutant. A number of factors controlling Cu dynamics have been reported, but information on quantitative relationships is scarce. We aimed to (i) quantitatively describe and predict soil Cu concentrations (CuAR) in aqua regia considering site‐specific effects and effects of pH, soil organic carbon (SOC) and cation exchange capacity (CEC), and (ii) study the suitability of mixed‐effects modelling and rule‐based models for the analysis of long‐term soil monitoring data. Thirteen uncontaminated long‐term monitoring soil profiles in southern Germany were analysed. Since there was no measurable trend of increasing CuAR concentrations with time in the respective depth ranges of the sites, data from different sampling dates were combined and horizon‐specific regression analyses including model simplifications were carried out for 10 horizons. Fixed‐ and mixed‐effects models with the site as a random effect were useful for the different horizons and significant contributions (either of main effects or interactions) of SOC, CEC and pH were present for 9, 8 and 7 horizons, respectively. Horizon‐specific rule‐based cubist models described the CuAR data similarly well. Validations of cubist models and mixed‐effects models for the CuAR concentrations in A horizons were successful for the given population after random splitting into calibration and validation samples, but not after independent validations with random splitting according to sites. Overall, site, CEC, SOC and pH provide important information for a description of CuAR concentrations using the different regression approaches. Highlights: Information on quantitative relationships for factors controlling Cu dynamics is scarce. Site, CEC, SOC and pH provide important information for a description of Cu concentrations. Validations of cubist models and mixed‐effects models for A horizons were successful for a closed population of sites.
    Description: Bavarian State Ministry of the Environment and Consumer Protection http://dx.doi.org/10.13039/501100010219
    Description: Ministry of Agriculture and Environment Mecklenburg‐Western Pomerania
    Keywords: ddc:631.4
    Language: English
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    Tides, Stratification, and Counter Rotation: The German Bight ROFI in Comparison to Other Regions of Freshwater Influence (2022)
    Details
    Publication Date: 2022-10-01
    Description: The characteristics of tidal velocity profiles and their relation to stratification are investigated based on high‐resolution field data collected at four locations in the German Bight Region of Freshwater Influence (ROFI) in the North Sea. The deployments each include two to three tidal cycles and were conducted during field campaigns in August 2016 and May 2018. The depth‐averaged semidiurnal tidal motion is dominated by a standing wave directed toward the coast, but modified by a smaller, coast‐parallel progressive wave contribution. The time series of the tidal velocity profiles consistently show tidal asymmetries with higher flood than ebb velocities near the surface and counter‐clockwise rotation of the velocity trajectories at depth. Near the surface, phase‐locked periodic changes in the sense of rotation within the tidal cycle are evident for three deployments, resulting in periodic counter‐rotation of the upper and lower layer. During these episodes, stratification of the water column is observed. Counter‐rotation is initiated after a sudden decoupling developing from the surface downward, with subsequent rapid development of stratification and velocity shear. The observed decoupling is most likely triggered by advection of the plume‐induced lateral surface density gradient by weakly sheared ebb currents toward the study site. Due to the dominance of the standing wave in the German Bight ROFI, the observed intra‐tidal variations of stratification are more similar to the Liverpool Bay and differ significantly from the Rhine ROFI, where the tidal dynamics are controlled by a progressive Kelvin wave.
    Description: Plain Language Summary; The water velocities in the German Bight are strongly influenced by river freshwater input and semidiurnal tides. While the freshwater input from the rivers has a stratifying effect, tidal motion as well as wind and waves induce mixing. These forces compete in controlling the state of the water column in a complex manner. In theory, tidal motion should describe elliptical paths. However, in reality, these ellipses can be modified for example, by periodically occurring stratification. To assess the characteristics of the semidiurnal tidal velocity profile and its variability, four instruments to measure current velocity profiles were deployed in the German Bight during August 2016 and May 2018. Measurements were carried out for the duration of up to three tidal cycles, accompanied by parallel profiles of water temperature and salinity taken from the anchored ship nearby. Results show that periodic stratification related to the river freshwater plume is associated with periodically counter‐rotating tidal currents during the tidal cycle. The measurement position relative to the location of the density front of the plume appears to be critical for the occurrence of counter‐rotation. The observed dynamics are qualitatively compared to two other well‐studied coastal ocean regions of freshwater influence.
    Description: Key Points: High‐resolution velocity and density data from the German Bight Region of Freshwater Influence are used to assess M2 tidal properties and intra‐tidal variability. M2 tidal motion is a hybrid of standing and progressive waves, with the standing wave contribution dominating. Periodic counter‐rotation of upper‐ and lower‐layer current trajectories during the tidal cycle is related to water column stratification.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.1594/PANGAEA.919168
    Description: https://doi.pangaea.de/10.1594/PANGAEA.943958
    Description: https://doi.pangaea.de/10.1594/PANGAEA.943955
    Description: https://doi.org/10.1594/PANGAEA.897214
    Keywords: ddc:551.46
    Language: English
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    The Hidden Giant: How a rift pulse triggered a cascade of sector collapses and voluminous secondary mass‐transport events in the early evolution of Santorini (2022)
    Details
    Publication Date: 2022-10-01
    Description: Volcanic island sector collapses have the potential to trigger devastating tsunamis and volcanic eruptions that threaten coastal communities and infrastructure. Considered one of the most hazardous volcano‐tectonic regions in the world, the Christiana‐Santorini‐Kolumbo Volcanic Field (CSKVF) lies in the South Aegean Sea in an active rift zone. Previous studies identified an enigmatic voluminous mass‐transport deposit west and east of Santorini emplaced during the early evolution of the edifice. However, the distribution and volume as well as the nature and emplacement dynamics of this deposit remained unknown up to now. In this study, we use an extensive dataset of high‐resolution seismic profiles to unravel the distribution and internal architecture of this deposit. We show that it is located in all basins surrounding Santorini and has a bulk volume of up to 125 km3, thus representing the largest known volcanic island mass‐transport deposit in the entire Mediterranean Sea. We propose that the deposit is the result of a complex geohazard cascade that was initiated by an intensive rift pulse. This rifting event triggered a series of smaller precursory mass‐transport events before large‐scale sector collapses occurred on the northeastern flank of the extinct Christiana Volcano and on the southeastern flank of the nascent Santorini. This was followed by the emplacement of large‐scale secondary sediment failures on the slopes of Santorini, which transitioned into debris and turbidity flows that traveled far into the neighboring rift basins. Following this cascade, a distinct change in the volcanic behaviour of the CSKVF occurred, suggesting a close relationship between crustal extension, mass transport and volcanism. Cascading geohazards seem to be more common in the evolution of marine volcanic systems than previously appreciated. Wider awareness and a better understanding of cascading effects are crucial for more holistic hazard assessments.
    Description: Schematic Reconstruction of the Santorini Mass‐Transport Cascade (SMTC): After a phase of volcanic quiescence (A), a rift pulse (B) triggered precursory mass‐wasting events (C), large‐scale sector collapses (D) and secondary sediment failures (E), which culminated in a change in the volcanic behaviour of the system (F).
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.21
    Language: English
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    Analytical Artefacts Preclude Reliable Isotope Ratio Measurement of Internal Water in Coral Skeletons (2022)
    de Graaf, Stefan ; Vonhof, Hubert B. ; Reijmer, John J. G. ; [et al.]
    Details
    Publication Date: 2022-10-01
    Description: Internal water in cold‐water and tropical coral skeletons was extracted and measured for its oxygen and hydrogen isotope ratios. Water was extracted by crushing pieces of coral hard tissue in a percussion device connected to either a cavity ring‐down spectroscopy (CRDS) system or an isotope ratio mass spectrometry (IRMS) system. Despite most samples yielding sufficient water, each analytical system produces distinct isotope patterns. Experiments show that several characteristics specific to biominerals give rise to discrepancies and analytical artefacts that preclude the acquisition of reproducible isotope data. The main complication is that internal water in biogenic carbonates is distributed in an open interconnected micro‐network that readily exchanges with external water and potentially facilitates interaction with hydration water in the finely dispersed organic matrix in the coral skeleton. Furthermore, only an isotopically fractionated part of the internal water is released from the coral skeletons upon crushing. Altogether, isotope ratio measurement of internal water in corals with bulk crushing techniques does not give primary fluid isotope ratios useful for (palaeo‐)environmental or microbiological studies. As the resulting isotope patterns can show systematic behaviour per technique, isotope data may be erroneously interpreted to reflect the original calcifying fluid when using only a single technique to isotopically characterise internal fluids in coral skeletons.
    Description: Key Points: Free water trapped inside coral skeletons was extracted and isotopically analyzed on two commonly used techniques for fluid inclusion isotope analysis. Measured oxygen and hydrogen isotope ratios do not reproduce between the techniques due to several analytical artefacts. The water extracted from coral skeletons is not of primary origin.
    Description: Nederlandse Organisatie voor Wetenschappelijk Onderzoek http://dx.doi.org/10.13039/501100003246
    Description: Western Indian Ocean Marine Science Association http://dx.doi.org/10.13039/501100009106
    Keywords: ddc:551.9
    Language: English
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    Greigite (Fe3S4) Formation in Artificial Sediments via Solid‐State Transformation of Lepidocrocite (2022)
    Details
    Publication Date: 2022-09-30
    Description: Greigite (Fe3S4) is a ferrimagnetic iron‐sulfide mineral that forms in sediments during diagenesis. Greigite growth can occur diachronously within a stratigraphic profile, complicating or overprinting environmental and paleomagnetic records. An important objective for paleo‐ and rock‐magnetic studies is to identify the presence of greigite and to discern its formation conditions. Greigite detection remains, however, challenging and its magnetic properties obscure due to the lack of pure, stable material of well‐defined grain size. To overcome these limitations, we report a new method to selectively transform lepidocrocite to greigite via the intermediate phase mackinawite (FeS). In‐situ magnetic characterization was performed on discrete samples with different sediment substrates. Susceptibility and chemical remanent magnetization increased proportionally over time, defining two distinct greigite growth regimes. Temperature dependent and constant initial growth rates indicate a solid‐state FeS to greigite transformation with an activation energy of 78–90 kJ/mol. Low and room temperature magnetic remanence and coercivity ratios match with calculated mixing curves for superparamagnetic (SP) and single domain (SD) greigite and suggest ∼25% and ∼50% SD proportions at 300 and 100 K, respectively. The mixing trend coincides with empirical data reported for natural greigite‐bearing sediments, suggesting a common SP endmember size of 5–10 nm that is likely inherited from mackinawite crystallites. The average particle size of 20–50 nm determined by X‐ray powder diffraction and electron microscopy accords with theoretical predictions of the SP/SD threshold size in greigite. The method constitutes a novel approach to synthesize greigite and to investigate its formation in sediments.
    Description: Plain Language Summary: Sediments provide continuous records of Earth's ancient magnetic field, which lend insights into the workings of the geodynamo and help to establish the geologic time scale through global magnetostratigraphic correlation. Greigite is a magnetic iron sulfide mineral that commonly forms after deposition, thereby remagnetizing the sediment and complicating interpretation of the magnetic record. Understanding greigite formation and detecting its presence is fundamental for obtaining reliable records of the paleomagnetic field, yet knowledge of how greigite grows and how its magnetic properties evolve during growth remains limited. This article outlines a novel approach to form greigite in sediments and to monitor its growth kinetics, grain size and magnetic remanence acquisition. The magnetic properties of the synthetic sediments resemble those of natural greigite‐bearing sediments and match well with theoretical calculations, which can help quantify grain sizes in sedimentary greigite. The reported method and our results contribute to a better understanding of greigite formation and chemical magnetic remanence acquisition in sediments.
    Description: Key Points: We present a new method to grow greigite in aqueous sediments and create a chemical remanent magnetization under controlled conditions. Greigite grain sizes of 20–50 nm span the superparamagnetic to single domain threshold, consistent with theoretical predictions. Our experimental hysteresis data coincide with calculated mixing curves allowing better quantification of greigite particle sizes in nature.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.5281/zenodo.6521653
    Keywords: ddc:549
    Language: English
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    A New Population of Ultra‐Relativistic Electrons in the Outer Radiation Zone (2022)
    Details
    Publication Date: 2022-09-30
    Description: Van Allen Probes measurements revealed the presence of the most unusual structures in the ultra‐relativistic radiation belts. Detailed modeling, analysis of pitch angle distributions, analysis of the difference between relativistic and ultra‐realistic electron evolution, along with theoretical studies of the scattering and wave growth, all indicate that electromagnetic ion cyclotron (EMIC) waves can produce a very efficient loss of the ultra‐relativistic electrons in the heart of the radiation belts. Moreover, a detailed analysis of the profiles of phase space densities provides direct evidence for localized loss by EMIC waves. The evolution of multi‐MeV fluxes shows dramatic and very sudden enhancements of electrons for selected storms. Analysis of phase space density profiles reveals that growing peaks at different values of the first invariant are formed at approximately the same radial distance from the Earth and show the sequential formation of the peaks from lower to higher energies, indicating that local energy diffusion is the dominant source of the acceleration from MeV to multi‐MeV energies. Further simultaneous analysis of the background density and ultra‐relativistic electron fluxes shows that the acceleration to multi‐MeV energies only occurs when plasma density is significantly depleted outside of the plasmasphere, which is consistent with the modeling of acceleration due to chorus waves.
    Description: Plain Language Summary: The most energetic electrons in the Earth Van Allen radiation belts have not been accurately measured in the past. Observations for a recent NASA's Van Allen Probes missions reviled new unique structures, such as narrow rings, and posed further scientific questions. This review shows that, unlike relativistic electrons, ultra‐relativistic electrons can be very effectively locally scattered by plasma waves produced by ions, so‐called electromagnetic ion cyclotron waves. Observations also show that acceleration from MeV to multi‐MeV occurs locally by taking energy from another type of plasma wave. These waves are called whistler‐mode waves and can accelerate particles to such high energy when total plasma density is low. The difference between the relativistic and ultra‐relativistic particles justifies the classification of these particles into a different population from the bulk population of the outer radiation belt.
    Description: Key Points: Electromagnetic ion cyclotron waves effectively scatter ultra‐relativistic electrons in the radiation belts. The local acceleration produces acceleration from MeV to multi‐MeV in the regions of low density. The difference between MeV and multi‐MeV electrons justifies the classification of these particles into a new population.
    Description: EC, H2020, H2020 Priority Excellent Science, H2020 European Research Council http://dx.doi.org/10.13039/100010663
    Description: NASA
    Description: https://rbspgway.jhuapl.edu/
    Keywords: ddc:538.7
    Language: English
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    Asteroid 2008 TC3, not a polymict ureilitic but a polymict C1 chondrite parent body? Survey of 249 Almahata Sitta fragments (2022)
    Details
    Publication Date: 2022-09-30
    Description: On October 7, 2008, the asteroid 2008 TC3 exploded as it entered the Earth’s atmosphere, producing significant dust (in the atmosphere) and delivering thousands of stones in a strewn field in Sudan, collectively known as the Almahata Sitta (AhS) stones. About 600 fragments were officially recovered in 2008 and 2009. Further rocks were collected since the fall event by local people. From these stones, 249 were classified at the Institut für Planetologie in Münster (MS) known as MS‐xxx or MS‐MU‐xxx AhS subsamples. Most of these rocks are ureilitic in origin (168; 67%): 87 coarse‐grained ureilites, 60 fine‐grained ureilites, 15 ureilites with variable texture/mineralogy, four trachyandesites, and two polymict breccias. We identified 81 non‐ureilitic fragments, corresponding to 33% of the recovered samples studied in Münster. These included chondrites, namely 65 enstatite chondrites (43 EL; 22 EH), 11 ordinary chondrites (OC), one carbonaceous chondrite, and one unique R‐like chondrite. Furthermore, three samples represent a unique type of enstatite achondrite. Since all AhS stones must be regarded as individual specimens independent from each other, the number of fresh ureilite and enstatite chondrite falls in our meteorite collections has been increased by several hundred percent. Overall, the samples weigh between 〈1 and 250 g and have a mean mass of ~15 g. If we consider—almost 15 years after the fall—the mass calculations, observations during and after the asteroid entered the atmosphere, the mineralogy of the C1 stones AhS 91A and AhS 671, and the experimental work on fitting the asteroid spectrum (e.g., Goodrich et al., 2019; Jenniskens et al., 2010; Shaddad et al., 2010), the main portion of the meteoroid was likely made of the fine‐grained (carbonaceous) dust and was mostly lost in the atmosphere. In particular, the fact that C1 materials were found has important implications for interpreting asteroid 2008 TC3's early spectroscopic results. Goodrich et al. (2019) correctly suggested that if scientists had not recovered the “water‐free” samples (e.g., ureilites, enstatites, and OC) from the AhS strewn field, 2008 TC3 would have been assumed to be a carbonaceous chondrite meteoroid. Considering that the dominating mass of the exploding meteoroid consisted of carbonaceous materials, asteroid 2008 TC3 cannot be classified as a polymict ureilite; consequently, we state that the asteroid was a polymict carbonaceous chondrite breccia, specifically a polymict C1 object that may have formed by late accretion at least 50–100 Ma after calcium–aluminum‐rich inclusions.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Alexander von Humboldt Foundation http://dx.doi.org/10.13039/100005156
    Keywords: ddc:549.112 ; ddc:523
    Language: English
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    Algorithmic Differentiation for Sensitivity Analysis in Cloud Microphysics (2022)
    Details
    Publication Date: 2022-10-04
    Description: The role of clouds for radiative transfer, precipitation formation, and their interaction with atmospheric dynamics depends strongly on cloud microphysics. The parameterization of cloud microphysical processes in weather and climate models is a well‐known source of uncertainties. Hence, robust quantification of this uncertainty is mandatory. Sensitivity analysis to date has typically investigated only a few model parameters. We propose algorithmic differentiation (AD) as a tool to detect the magnitude and timing at which a model state variable is sensitive to any of the hundreds of uncertain model parameters in the cloud microphysics parameterization. AD increases the computational cost by roughly a third in our simulations. We explore this methodology as the example of warm conveyor belt trajectories, that is, air parcels rising rapidly from the planetary boundary layer to the upper troposphere in the vicinity of an extratropical cyclone. Based on the information of derivatives with respect to the uncertain parameters, the ten parameters contributing most to uncertainty are selected. These uncertain parameters are mostly related to the representation of hydrometeor diameter and fall velocity, the activation of cloud condensation nuclei, and heterogeneous freezing. We demonstrate the meaningfulness of the AD‐estimated sensitivities by comparing the AD results with ensemble simulations spawned at different points along the trajectories, where different parameter settings are used in the various ensemble members. The ranking of the most important parameters from these ensemble simulations is consistent with the results from AD. Thus, AD is a helpful tool for selecting parameters contributing most to cloud microphysics uncertainty.
    Description: Plain Language Summary: The formation of clouds is determined by processes that act on smaller scales than weather prediction models can resolve. Consequently, a parameterization with typically hundreds of parameters is constructed to determine the effects of these processes on the resolved larger scales. These parameters are a well‐known source of uncertainty in weather and climate models. Classical attempts to quantify this uncertainty are typically limited to a few parameters. We propose algorithmic differentiation (AD) as a tool to detect parameters with the largest impact for any of the hundreds of parameters on multiple model state variables at every time step in our simulation. This increases the computational cost by roughly a third. The relevance of the AD‐estimated impact is demonstrated by comparing the AD results with ensemble simulations, where different parameter settings are used in the various ensemble members. The ranking of the most important parameters from these ensemble simulations is consistent with the results from AD. Thus, AD is a helpful tool to identify parameters objectively that contribute most to uncertainty in cloud parameterizations.
    Description: Key Points: Quantification of multi‐parameter uncertainty of cloud microphysical evolution of WCB trajectories using algorithmic differentiation. Uncertainty at every time step derived with algorithmic differentiation representative for key uncertainty over at least 30 min intervals. Parameterization of CCN activation, diameter size, and fall velocity of hydrometeors have the largest mean impact on water vapor contents.
    Description: Deutsch Forschungsgemeinschaft DFG
    Keywords: ddc:551.5
    Language: English
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    Representation of hydrological processes in a rural lowland catchment in Northern Germany using SWAT and SWAT+ (2022)
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-10-04
    Description: The latest version of the Soil and Water Assessment Tool (SWAT+) features several improvements compared with previous versions of the model, for example, the definition of landscape units that allow for a better representation of spatio‐temporal dynamics. To evaluate the new model capabilities in lowland catchments characterized by near‐surface groundwater tables and extensive tile drainage, we assess the performance of two SWAT+ model setups in comparison to a setup based on a previous SWAT model version (SWAT3S with a modified three groundwater storage model) in the Kielstau catchment in Northern Germany. The Kielstau catchment has an area of about 50 km2, is dominated by agricultural land use, and has been thoroughly monitored since 2005. In both SWAT+ setups, the catchment is divided into upland areas and floodplains, but in the first SWAT+ model setup, runoff from the hydrologic response units is summed up at landscape unit level and added directly to the stream. In the second SWAT+ model setup, runoff is routed across the landscape before it reaches the streams. Model results are compared with regard to (i) model performance for stream flow at the outlet of the catchment and (ii) aggregated as well as temporally and spatially distributed water balance components. All three model setups show a very good performance at the catchment outlet. In comparison to a previous version of the SWAT model that produced more groundwater flow, the SWAT+ model produced more tile drainage flow and surface runoff. Results from the new SWAT+ model confirm that the representation of routing processes from uplands to floodplains in the model further improved the representation of hydrological processes. Particularly, the stronger spatial heterogeneity that can be related to characteristics of the landscape, is very promising for a better understanding and model representation of hydrological fluxes in lowland areas. The outcomes of this study are expected to further prove the applicability of SWAT+ and provide useful information for future model development.
    Description: The model performance of all three model setups was very good, but the SWAT+ model setup with runoff routing between landscape units performed best. Moreover, the SWAT+ model applications predicted a greater spatial heterogeneity of the water balance components. The representation of hydrological fluxes particularly with regard to groundwater flow, surface runoff, and tile drainage flow differed considerably between the SWAT and SWAT+ model setups.
    Keywords: ddc:551.48
    Language: English
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    Air‐Sea Interactions and Water Mass Transformation During a Katabatic Storm in the Irminger Sea (2022)
    Details
    Publication Date: 2022-10-04
    Description: We use a global 5‐km resolution model to analyze the air‐sea interactions during a katabatic storm in the Irminger Sea originating from the Ammassalik valleys. Katabatic storms have not yet been resolved in global climate models, raising the question of whether and how they modify water masses in the Irminger Sea. Our results show that dense water forms along the boundary current and on the shelf during the katabatic storm due to the heat loss caused by the high wind speeds and the strong temperature contrast. The dense water contributes to the lightest upper North Atlantic Deep Water as upper Irminger Sea Intermediate Water and thus to the lower limb of the Atlantic Meridional Overturning Circulation (AMOC). The katabatic storm triggers a polar low, which in turn amplifies the near‐surface wind speed due to the superimposed pressure gradient, in addition to acceleration from a breaking mountain wave. Overall, katabatic storms account for up to 25% of the total heat loss (20 January 2020 to 30 September 2021) over the Irminger shelf of the Ammassalik area. Resolving katabatic storms in global models is therefore important for the formation of dense water in the western boundary current of the Irminger Sea, which is relevant to the AMOC, and for the large‐scale atmospheric circulation by triggering polar lows.
    Description: Plain Language Summary: Katabatic storms are outbursts of cold air associated with strong winds from coastal valleys of Greenland, in particular from the Ammassalik valleys in southeast Greenland. These storms are not resolved in global climate models because of their small spatial extent. However, they are important for the formation of dense water on the Irminger Sea shelf, because they induce a substantial heat loss from the coastal water. In this study, we resolve katabatic storms for the first time in a global climate model and analyze the water transformation caused by a single storm before quantifying the importance of katabatic storms for the entire simulation period. We find that a water mass is formed during the katabatic storm that is dense enough to contribute to the cooling and sinking of the global conveyor belt in the subpolar North Atlantic. Overall, katabatic storms account for up to 25% of the heat loss over the Irminger shelf of the Ammassalik area.
    Description: Key Points: For the first time, the direct effect of a katabatic storm on the Irminger Sea has been simulated in a global climate model. The katabatic storm induces strong heat loss and dense water formation over the Irminger shelf (Sermilik Trough) and in the boundary current. Dense water forming in the western boundary current during katabatic storms contributes to the lightest upper North Atlantic Deep Water.
    Description: Collaborative Research Centre TRR181 funded by DFG
    Description: Max Planck Society for Advancement of Science
    Description: NextGEMS
    Description: European Union’s Horizon 2020
    Description: https://hdl.handle.net/21.11116/0000-0008-ECF1-E
    Description: https://cera-www.dkrz.de/WDCC/ui/Compact.jsp?acronym=DKRZ_LTA_033_ds00010
    Description: https://mpimet.mpg.de/en/science/modeling-with-icon/code-availability
    Keywords: ddc:551.5
    Language: English
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    Robust approaches for model‐free small‐angle scattering data analysis (2022)
    Bender, Philipp ; Honecker, Dirk ; Bersweiler, Mathias ; [et al.]
    International Union of Crystallography | 5 Abbey Square, Chester, Cheshire CH1 2HU, England
    Details
    Publication Date: 2022-10-04
    Description: The small‐angle neutron scattering data of nanostructured magnetic samples contain information regarding their chemical and magnetic properties. Often, the first step to access characteristic magnetic and structural length scales is a model‐free investigation. However, due to measurement uncertainties and a restricted q range, a direct Fourier transform usually fails and results in ambiguous distributions. To circumvent these problems, different methods have been introduced to derive regularized, more stable correlation functions, with the indirect Fourier transform being the most prominent approach. Here, the indirect Fourier transform is compared with the singular value decomposition and an iterative algorithm. These approaches are used to determine the correlation function from magnetic small‐angle neutron scattering data of a powder sample of iron oxide nanoparticles; it is shown that with all three methods, in principle, the same correlation function can be derived. Each method has certain advantages and disadvantages, and thus the recommendation is to combine these three approaches to obtain robust results.
    Description: Three different approaches are compared for determination of the correlation function from the small‐angle neutron scattering data of a powder sample of iron oxide nanoparticles.
    Keywords: ddc:548
    Language: English
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    Temporal evolution of headwall erosion rates derived from cosmogenic nuclide concentrations in the medial moraines of Glacier d'Otemma, Switzerland (2022)
    Details
    Publication Date: 2022-10-04
    Description: Climate change affects the stability and erosion of high‐alpine rock walls above glaciers (headwalls) that deliver debris to glacier surfaces. Since supraglacial debris in the ablation zone alters the melt behaviour of the underlying ice, the responses of debris‐covered glaciers and of headwalls to climate change may be coupled. In this study, we analyse the beryllium‐10 (10Be)‐cosmogenic nuclide concentration history of glacial headwalls delivering debris to the Glacier d'Otemma in Switzerland. By systematic downglacier‐profile‐sampling of two parallel medial moraines, we assess changes in headwall erosion through time for small, well‐defined debris source areas. We compute apparent headwall erosion rates from 10Be concentrations ([10Be]), measured in 15 amalgamated medial moraine debris samples. To estimate both the additional 10Be production during glacial debris transport and the age of our samples we combine our field‐based data with a simple model that simulates downglacier debris trajectories. Furthermore, we evaluate additional grain size fractions for eight samples to test for stochastic mass wasting effects on [10Be]. Our results indicate that [10Be] along the medial moraines vary systematically with time and consistently for different grain sizes. [10Be] are higher for older debris, closer to the glacier terminus, and lower for younger debris, closer to the glacier head. Computed apparent headwall erosion rates vary between ~0.6 and 10.8 mm yr−1, increasing over a maximum time span of ~200 years towards the present. As ice cover retreats, newly exposed headwall surfaces may become susceptible to enhanced weathering and erosion, expand to lower elevations, and contribute formerly shielded bedrock of likely different [10Be]. Hence, we suggest that recently lower [10Be] reflect the deglaciation of the debris source areas since the end of the Little Ice Age.
    Description: In glacial landscapes, systematic downglacier‐sampling of medial moraine debris holds the potential to assess changes in headwall erosion through time. Cosmogenic beryllium‐10 (10Be) concentrations within the medial moraines of Glacier d'Otemma, Switzerland, broadly increase downglacier and translate into increasing headwall erosion rates towards the present. These trends may reflect processes associated with the exposure of new bedrock surfaces across recently deglaciating source headwalls.
    Description: European Research Council (ERC) H2020‐EU.1.1.
    Description: https://doi.org/10.5880/GFZ.3.3.2021.007
    Keywords: ddc:551
    Language: English
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    Palaeoecological signals for Mesolithic land use in a Central European landscape? (2022)
    Heidgen, Shaddai ; Marinova, Elena ; Nelle, Oliver ; [et al.]
    Details
    Publication Date: 2022-10-04
    Description: During the Early Holocene, climate was the major factor causing fires, but whether during the Mesolithic (~11.5–7.4 cal ka BP) people co‐shaped their environment by means of fire remains of debate. Few studies have tackled this question by linking high‐resolution multi‐proxy palaeoecological studies from near Mesolithic occupation sites. An Early Holocene sediment record from the Ammer Valley palaeo‐wetland in south‐west Germany was studied using pollen, micro‐ and macrocharcoal, and plant macroremains. Archaeological evidence from Early and Late Mesolithic sites of Rottenburg‐Siebenlinden allowed us to link this palaeoecological record with Mesolithic land use in the same catchment. Between 11.6 and 10.6 cal kabp,intensive wildfires reinforced the persistence of open and pioneer vegetation. A transition from a river‐dominated landscape towards a wetland with open stagnant waters at 10.6–9.5 cal ka bpmade the region attractive to hunter‐gatherers, providing various plant resources (incl. hazel). From 10.1 cal ka bponwards, Mesolithic communities may have shaped their environment by using fire as a tool to expand open areas, which were important for the implementation of their subsistence strategies. After 9.5 cal ka bp, human control over fires cannot be excluded as Mesolithic occupation phases chronologically coincide with frequent low‐intensity fires and vegetation disturbance.
    Keywords: ddc:561
    Language: English
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    Benthic Carbon Remineralization and Iron Cycling in Relation to Sea Ice Cover Along the Eastern Continental Shelf of the Antarctic Peninsula (2022)
    Details
    Publication Date: 2022-10-04
    Description: Rapid and profound climatic and environmental changes have been predicted for the Antarctic Peninsula with so far unknown impact on the biogeochemistry of the continental shelves. In this study, we investigate benthic carbon sedimentation, remineralization and iron cycling using sediment cores retrieved on a 400 mile transect with contrasting sea ice conditions along the eastern shelf of the Antarctic Peninsula. Sediments at comparable water depths of 330–450 m showed sedimentation and remineralization rates of organic carbon, ranging from 2.5 to 13 and 1.8–7.2 mmol C m−2 d−1, respectively. Both rates were positively correlated with the occurrence of marginal sea ice conditions (5%–35% ice cover) along the transect, suggesting a favorable influence of the corresponding light regime and water column stratification on algae growth and sedimentation rates. From south to north, the burial efficiency of organic carbon decreased from 58% to 27%, while bottom water temperatures increased from −1.9 to −0.1°C. Net iron reduction rates, as estimated from pore‐water profiles of dissolved iron, were significantly correlated with carbon degradation rates and contributed 0.7%–1.2% to the total organic carbon remineralization. Tightly coupled phosphate‐iron recycling was indicated by significant covariation of dissolved iron and phosphate concentrations, which almost consistently exhibited P/Fe flux ratios of 0.26. Iron efflux into bottom waters of 0.6–4.5 μmol Fe m−2 d−1 was estimated from an empirical model. Despite the deep shelf waters, a clear bentho‐pelagic coupling is indicated, shaped by the extent and duration of marginal sea ice conditions during summer, and likely to be affected by future climate change.
    Description: Plain Language Summary: The seafloor of the shallow shelf seas plays a significant role in the recycling of organic carbon and acts as a nutrient source for algae growth in the upper water layers. In Antarctic waters, the change in sea ice cover has a great impact on the growth of algae and the subsequent sinking of organic carbon to the seafloor. With global warming, profound changes in sea ice cover are expected for the Antarctic Peninsula. To better understand its imprint on the seafloor, we collected sediment samples from different locations along the eastern shelf of the Antarctic Peninsula and measured how changes in sea ice cover influence the accumulation and recycling of organic carbon. We found that moderate sea ice cover of 5%–35% increases the amount of organic carbon received by the seafloor and that the fraction that is buried in the sediments decreases from south (58%) to north (27%). We further measured that more iron, an important micro‐nutrient for algae growth, can be released from the seafloor the more organic carbon accumulates. Thus, sea ice conditions determine the organic carbon accumulation, turnover, and nutrient release at the seafloor, which are likely to be affected by future climate change.
    Description: Key Points: Antarctic shelf sediments underlying marginal sea ice cover exhibit high sedimentation and remineralization rates of organic carbon. A high degree of sedimentary Fe‐recycling is found which scales with organic carbon remineralization rates. Coupling between P and Fe recycling is observed with a constant P/Fe flux ratio of 0.26 for sediments with high Fe and P recycling rates.
    Description: Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research http://dx.doi.org/10.13039/501100003207
    Description: https://doi.org/10.1594/PANGAEA.942455
    Keywords: ddc:551.9
    Language: English
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    Sound Velocity Measurements of B2‐Fe‐Ni‐Si Alloy Under High Pressure by Inelastic X‐Ray Scattering: Implications for the Composition of Earth's Core (2022)
    Details
    Publication Date: 2022-10-04
    Description: Elastic properties of B2‐Fe0.67Ni0.06Si0.27 (15 wt.% Si) alloy have been investigated by combined high‐resolution inelastic X‐ray scattering and powder X‐ray diffraction in diamond anvil cells up to 100 GPa at room temperature. Densities (ρ), compressional (VP) and shear (VS) wave velocities were extrapolated to inner core conditions to enable comparison with the preliminary reference Earth model. The modeled aggregate compressional and shear wave velocities and densities of the two‐phase mixture of B2‐Fe0.67Ni0.06Si0.27 and hcp‐Fe‐Ni are consistent with inner core PREM values of VP, VS, and ρ based on a linear mixing model with 30(5) vol % B2‐Fe0.67Ni0.06Si0.27 and 70(5) vol % hcp Fe‐Ni, which corresponds to ∼3–5 wt.% Si and ∼5–12 wt.% Ni.
    Description: Plain Language Summary: The composition of the inner core holds key information about how Earth evolved and how current processes such as the geomagnetic field work. Because the core cannot be directly sampled, our best estimates of its composition are based on the comparison of geophysical data with laboratory measurements of candidate materials. Decades of study have shown the inner core to be composed mainly of iron (with a minor amount of nickel) alloyed with one or more light elements, such as silicon. However, the effect of Si on the geophysical properties of Fe‐Ni alloys is not well established. In this study, we performed laboratory experiments to determine the density and sound velocity of Fe‐Ni‐Si alloy under extreme pressure conditions. We compared our results with seismological determinations and found that Earth's inner core can be accounted for by a mechanical mixture of cubic Fe‐Ni‐Si and hexagonal Fe‐Ni alloys. This mixture has a bulk composition of ∼3–5 weight % Si and ∼5–12 weight % Ni and is consistent with geophysical constraints.
    Description: Key Points: Sound velocities and densities of B2‐Fe‐Ni‐Si alloy are determined at high pressure, up to 100 GPa, using inelastic X‐ray scattering and X‐ray diffraction. Seismologically observed compressional and shear wave velocities and density of Earth's inner core can be accounted for by a two‐phase mixture of 30 vol % B2‐Fe‐Ni‐Si and 70 vol % hcp Fe‐Ni alloys. Extrapolated results at inner core boundary conditions are consistent with an inner core composition containing ∼3–5 wt.% Si and ∼5–12 wt.% Ni.
    Description: Japan Society for the Promotion of Science http://dx.doi.org/10.13039/501100001691
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: JSPS Japanese‐German graduate externship
    Description: https://doi.org/10.6084/m9.figshare.13370795.v1
    Description: https://doi.org/10.6084/m9.figshare.13370792.v1
    Keywords: ddc:551.112
    Language: English
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    Spatio‐Temporal Level Variations of the Martian Seasonal South Polar Cap From Co‐Registration of MOLA Profiles (2022)
    Details
    Publication Date: 2022-10-04
    Description: The seasonal deposition and sublimation of CO2 represents a major element in the Martian volatile cycle. Here, co‐registration strategies are applied to Mars Orbiter Laser Altimeter profiles to obtain spatio‐temporal variations in snow/ice level of the Seasonal South Polar Cap (SSPC), in grid elements of 0.5° in latitude from 60° to 87°S and 10° in longitude. The maximum snow/ice level in the range of 2–2.5 m is observed over the Residual South Polar Cap. Peak level at the Residual South Polar Cap in Martian Year 25 (MY25) are found to be typically ∼0.5 m higher than those in MY24. The total volume is estimated to peak at approximately 9.4 × 1012 m3. In addition, a map of average bulk density of the SSPC during its recession is derived. It implies much more snowfall‐like precipitation at the Residual South Polar Cap and its surroundings than elsewhere on Mars.
    Description: Plain Language Summary: Each Martian year, up to one third of the atmosphere's CO2 is transported from pole to pole, being deposited and sublimated depending on the season. Accurate measurements of snow level and volume variations of the resulting seasonal polar caps can serve as crucial constraints on the Martian volatile cycles. In this study, we apply new approaches of analyzing the Mars Orbiter Laser Altimeter profiles, which lead to spatially and temporally resolved measurements of snow/ice level of the Seasonal South Polar Cap (SSPC). Based on that, the maximum snow level, interannual maximum level change from Martian Year 24 (MY24) to MY25, and how the volume of the SSPC changes with time are measured. We also estimate the bulk density of the snow/ice deposition during southern winter. It is inferred that there is much more snowfall at the Residual South Polar Cap and its surroundings than elsewhere on the planet.
    Description: Key Points: Using co‐registration of Mars Orbiter Laser Altimeter profiles, spatio‐temporal level variations of the seasonal snow/ice deposits at the Martian south pole are obtained. Maximum level can be up to 2.5 m; Peak level increased by ∼0.5 m at the Residual South Polar Cap from Martian Year 24 (MY24) to MY25. Obtained bulk density map of the seasonal deposits implies that snowfall concentrates at the Residual South Polar Cap and its surroundings.
    Description: China Scholarship Council
    Description: Deutsche Forschungsgemeinschaft
    Description: Institut National des Sciences de l’Univers
    Description: Centre National de la Recherche Scientifique
    Description: Centre National d’Etudes Spatiales
    Description: https://pds-geosciences.wustl.edu/missions/mgs/pedr.html
    Description: https://naif.jpl.nasa.gov/pub/naif/pds/data/mgs-m-spice-6-v1.0/mgsp_1000/data/
    Description: https://doi.org/10.17632/z59b9nd6s9.2
    Description: https://doi.org/10.14768/8cba4407-d6a0-4d16-aeaf-d0ebfd2b480a
    Keywords: ddc:523
    Language: English
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    Greenhouse Gas Mitigation Potential of Alternate Wetting and Drying for Rice Production at National Scale—A Modeling Case Study for the Philippines (2022)
    Kraus, David ; Werner, Christian ; Janz, Baldur ; [et al.]
    Details
    Publication Date: 2022-10-04
    Description: Worldwide, rice production contributes about 10% of total greenhouse gas (GHG) emissions from the agricultural sector, mainly due to CH4 emissions from continuously flooded fields. Alternate Wetting and Drying (AWD) is a promising crop technology for mitigating CH4 emissions and reducing the irrigation water currently being applied in many of the world's top rice‐producing countries. However, decreased emissions of CH4 may be partially counterbalanced by increased N2O emissions. In this case study for the Philippines, the national mitigation potential of AWD is explored using the process‐based biogeochemical model LandscapeDNDC. Simulated mean annual CH4 emissions under conventional rice production for the time period 2000–2011 are estimated as 1,180 ± 163 Gg CH4 yr−1. During the cropping season, this is about +16% higher than a former estimate using emission factors. Scenario simulations of nationwide introduction of AWD in irrigated landscapes suggest a considerable decrease in CH4 emissions by −23%, while N2O emissions are only increased by +8%. Irrespective of field management, at national scale, the radiative forcing of irrigated rice production is always dominated by CH4 (〉95%). The reduction potential of GHG emissions depends on, for example, number of crops per year, residue management, amount of applied irrigation water, and sand content. Seasonal weather conditions also play an important role since the mitigation potential of AWD is almost double as high in dry as compared to wet seasons. Furthermore, this study demonstrates the importance of temporal continuity, considering off‐season emissions and the long‐term development of GHG emissions across multiple years.
    Description: Plain Language Summary: Worldwide, rice production contributes to about 10% of total greenhouse gas emissions of the agricultural sector mainly due to CH4 emissions from fields that are continuously flooded. Alternate Wetting and Drying (AWD) is an alternative cropping practice where fields are irrigated a few days after the disappearance of the ponded water. This study explores the mitigation potential of nationwide introduction of AWD in the Philippines. Results from the application of a process‐based model suggest a considerable decrease in CH4 emissions by −23%. Compared to N2O, CH4 is responsible for more than 95% of the total radiative forcing under conventional or AWD field management.
    Description: Key Points: Nationwide, Alternate Wetting and Drying (AWD) reduces CH4 emissions by −23%. N2O emissions contribute to less than 5% to the total radiative forcing under conventional or AWD field management. Mitigation of AWD depends on, for example, seasonal weather conditions, cropping intensity, irrigation, residue management, and soil texture.
    Description: DFG
    Description: https://doi.org/10.35097/588
    Keywords: ddc:551.6 ; ddc:581.7
    Language: English
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    Simultaneously tracing the fate of seven metals at a global level with MaTrace‐multi (2022)
    Details
    Publication Date: 2022-10-04
    Description: Keeping materials in use for a long time is key to reducing primary material demand and environmental impacts of resource use. Recycling yields of metals should only be limited by thermodynamically unavoidable losses of the remelting processes for well‐defined scraps. In practice, however, additional dissipative losses for metals occur due to incomplete collection of end‐of‐life products, insufficient waste sorting, remelting of contaminated or diluted scrap, and the downcycling of secondary materials. Here we simultaneously trace the fate of Al, Cr, Fe, Ni, Cu, Zn, and Pb in MaTrace‐multi, a planetary dynamic material flow system. Metals pass the processes mining, fabrication, use‐phase, collection, sorting, scrap allocation, remelting, and secondary material allocation. We calculate the circularity and longevity of the cohort of metal requirements for the final demand of 1 year. Nickel is found to have the best longevity at 116 (78 to 205) years, whereas zinc only has a longevity of 47 (37 to 61) years. While nickel, on average, is used in 5.13 (3.45 to 8.78) applications before dissipation, zinc is used only in 1.94 (1.52 to 2.47) applications. Our study results can be used to model the impacts of circular economy policies and technological developments on global metal cycles beyond the scope of studies modeling one metal at a time. This article met the requirements for a Gold–Gold JIE data openness badge described at http://jie.click/badges
    Description: https://doi.org/10.17605/OSF.IO/R54C6
    Keywords: ddc:363.7282
    Language: English
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    Flexible habitat choice of pelagic bacteria increases system stability and energy flow through the microbial loop (2022)
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-10-04
    Description: Pelagic bacteria can be classified into free‐living and particle‐attached life modes, which either dwell in the water column or attach to suspended particles. Bacteria with a generalist life style, however, can actively shift between these two habitats. Globally increasing densities of natural and artificial particles enhance habitat heterogeneity, with potential consequences for system stability and trophic transfer through aquatic food webs. To better decipher the dynamics of microbial communities, we investigated the influence of adaptive vs. fixed habitat choice on species coexistence for a simplified bacterial community by analyzing a corresponding food web model, consisting of two specialist bacterial prey species (free and attached), a generalist bacterial prey species with the ability to shift between both habitats, and two protist predators, specialized on either water or particle compartment. For simplicity we assume a shared resource pool, considering particles only for colonization but not as a source for nutrients or carbon, that is, inert particles like microplastics or inorganic sediments. The model predicts coexistence on a cyclic attractor between fixed and flexible bacteria, if the costs for adaptive habitat choice can be balanced by adaptation speed. The presence of adaptive prey dampens predator–prey cycle amplitudes, contributing to system stabilization resulting in higher mean predator biomass compared to specialist prey only. Thus, in pelagic microbial systems, flexible habitat choice at the prey level has important implications for system stability and magnitude of energy flow through the microbial loop.
    Description: German Ministry of Education and Science
    Description: German Science Foundation (DFG)
    Keywords: ddc:579.3
    Language: English
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    Basin‐scale estimates of greenhouse gas emissions from the Mara River, Kenya: Importance of discharge, stream size, and land use/land cover (2022)
    Mwanake, Ricky M. ; Gettel, Gretchen M. ; Ishimwe, Clarisse ; [et al.]
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-10-04
    Description: Greenhouse gas fluxes (CO2, CH4, and N2O) from African streams and rivers are under‐represented in global datasets, resulting in uncertainties in their contributions to regional and global budgets. We conducted year‐long sampling of 59 sites in a nested‐catchment design in the Mara River, Kenya in which fluxes were quantified and their underlying controls assessed. We estimated annual basin‐scale greenhouse gas emissions from measured in‐stream gas concentrations, modeled gas transfer velocities, and determined the sensitivity of up‐scaling to discharge. Based on the total annual CO2‐equivalent emissions calculated from global warming potentials (GWP), the Mara basin was a net greenhouse gas source (294 ± 35 Gg CO2 eq yr−1). Lower‐order streams (1–3) contributed 81% of the total fluxes, and higher stream orders (4–8) contributed 19%. Cropland‐draining streams also exhibited higher fluxes compared to forested streams. Seasonality in stream discharge affected stream widths (and stream area) and gas exchange rates, strongly influencing the basin‐wide annual flux, which was 10 times higher during the high and medium discharge periods than the low discharge period. The basin‐wide estimate was underestimated by up to 36% if discharge was ignored, and up to 37% for lower stream orders. Future research should therefore include seasonality in stream surface areas in upscaling procedures to better constrain basin‐wide fluxes. Given that agricultural activities are a major factor increasing riverine greenhouse gas fluxes in the study region, increased conversion of forests and agricultural intensification has the possibility of increasing the contribution of the African continent to global greenhouse gas sources.
    Description: Deutscher Akademischer Austauschdienst http://dx.doi.org/10.13039/501100001655
    Description: IHE Delft Institute for Water Education
    Description: Federal Ministry of Education and Research http://dx.doi.org/10.13039/501100002347
    Description: Helmholtz Association http://dx.doi.org/10.13039/501100009318
    Description: TERENO Bavarian Alps/ Pre‐Alps Observatory
    Keywords: ddc:551
    Language: English
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    Deepening the Late Quaternary's Deep Ocean Carbon Mysteries (2022)
    Details
    Publication Date: 2022-10-04
    Description: Changes to the carbon content of the deep ocean, the largest reservoir in the surficial carbon cycle, are capable of altering atmospheric carbon dioxide concentrations and thereby Earth's climate. While the role of the deep ocean's carbon inventory in the last ice age has been thoroughly investigated, comparatively little is known about whether the deep ocean contributed to the change in the pacing and intensity of ice ages around 1 million years ago during the Mid‐Pleistocene Transition (MPT). Qin et al. (2022, https://doi.org/10.1029/2021GL097121) provide new reconstructions of deep ocean carbonate ion saturation, a proxy for carbon content, from the deep Pacific Ocean across the MPT. Intriguingly, their results show that a reduction in deep Pacific carbonate ion saturation across the MPT occurred at different intervals from carbonate ion saturation decline in the deep Atlantic Ocean. These results suggest a more nuanced contribution of whole‐ocean carbon sequestration to the climate changes reconstructed across the MPT.
    Description: Plain Language Summary: Earth's periodic ice ages became longer and more intense around 1 million years ago. While the underlying reasons for this climate change remain debated, it is widely understood that the deep ocean may have played an important role by storing the potent greenhouse gas carbon dioxide away from the atmosphere. New research by Qin et al. (2022, https://doi.org/10.1029/2021gl097121) shows that the deep Pacific Ocean did indeed accumulate additional carbon around the time of this million‐year old climate transition. However, the new results also show that Pacific Ocean accumulated carbon over different intervals than the Atlantic Ocean, deepening the mystery around how and why this carbon uptake occurred.
    Description: Key Points: The deep Atlantic and Pacific Oceans accumulated carbon at different intervals during the mid‐Pleistocene transition.
    Description: National Science Foundation http://dx.doi.org/10.13039/100000001
    Description: https://doi.org/10.1029/2021GL097121
    Keywords: ddc:551
    Language: English
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    Effective buoyancy and CAPE: Some implications for tropical cyclones (2022)
    John Wiley & Sons, Ltd | Chichester, UK
    Details
    Publication Date: 2022-10-04
    Description: We review the widely used concepts of “buoyancy” and “convective available potential energy” (CAPE) in relation to deep convection in tropical cyclones and discuss their limitations. A fact easily forgotten in applying these concepts is that the buoyancy force of an air parcel, as often defined, is non‐unique because it depends on the arbitrary definition of a reference density field. However, when calculating CAPE, the buoyancy of a lifted air parcel is related to the specific reference density field along a vertical column passing through that parcel. Both concepts can be generalized for a vortical flow and to slantwise ascent of a lifted air parcel in such a flow. In all cases, the air parcel is assumed to have infinitely small dimensions. In this article, we explore the consequences of generalizing buoyancy and CAPE for buoyant regions of finite size that perturb the pressure field in their immediate environment. Quantitative calculations of effective buoyancy, defined as the sum of the conventional buoyancy and the static vertical perturbation pressure gradient force induced by it, are shown for buoyant regions of finite width. For a judicious choice of reference density, the effective buoyancy per unit mass is essentially a unique force, independent of the reference density, but its distribution depends on the horizontal scale of the buoyant region. A corresponding concept of “effective CAPE” is introduced and its relevance to deep convection in tropical cyclones is discussed. The study is conceived as a first step to understanding the decreasing ability of inner‐core deep convection in tropical cyclones to ventilate the mass of air converging in the frictional boundary layer as the vortex matures and decays.
    Description: The buoyancy force of an infinitesimally small air parcel is non‐unique, depending on the arbitrary definition of a reference density field. When calculating the “convective available potential energy” (CAPE), the buoyancy of a lifted air parcel is related to the reference density field along a vertical column passing through that parcel. We generalize buoyancy and CAPE for buoyant regions of finite size that perturb the pressure field in their immediate environment and discuss the relevance to deep convection in tropical cyclones.
    Keywords: ddc:551.5
    Language: English
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    Performance of a Rotational Sensor to Decipher Volcano Seismic Signals on Etna, Italy (2022)
    Eibl, Eva P. S. ; Rosskopf, Martina ; Sciotto, Mariangela ; [et al.]
    Details
    Publication Date: 2022-10-04
    Description: Volcano‐seismic signals such as long‐period events and tremor are important indicators for volcanic activity and unrest. However, their wavefield is complex and characterization and location using traditional seismological instrumentation is often difficult. In 2019 we recorded the full seismic wavefield using a newly developed 3C rotational sensor co‐located with a 3C traditional seismometer on Etna, Italy. We compare the performance of the rotational sensor, the seismometer and the Istituto Nazionale di Geofisica e Vulcanologia‐Osservatorio Etneo (INGV‐OE) seismic network with respect to the analysis of complex volcano‐seismic signals. We create event catalogs for volcano‐tectonic (VT) and long‐period (LP) events combining a STA/LTA algorithm and cross‐correlations. The event detection based on the rotational sensor is as reliable as the seismometer‐based detection. The LP events are dominated by SH‐type waves. Derived SH phase velocities range from 500 to 1,000 m/s for LP events and 300–400 m/s for volcanic tremor. SH‐waves compose the tremor during weak volcanic activity and SH‐ and SV‐waves during sustained strombolian activity. We derive back azimuths using (a) horizontal rotational components and (b) vertical rotation rate and transverse acceleration. The estimated back azimuths are consistent with the INGV‐OE event location for (a) VT events with an epicentral distance larger than 3 km and some closer events, (b) LP events and tremor in the main crater area. Measuring the full wavefield we can reliably analyze the back azimuths, phase velocities and wavefield composition for VT, LP events and tremor in regions that are difficult to access such as volcanoes.
    Description: Plain Language Summary: Traditional seismographs usually include mass and spring systems which measure vibrations constrained to up‐down, north‐south and east‐west directions. We compare the traditional seismometer to a rotational sensor which measures ground rotation around the same three directions. We installed a rotational sensor on Etna volcano in 2019 to test these new sensors in a volcanic environment. We compare the performance of the rotational sensor, a traditional seismometer and the Istituto Nazionale di Geofisica e Vulcanologia‐Osservatorio Etneo (INGV‐OE) seismometer network. We detect two types of a few second long earthquakes and find that the rotational sensor performs as good as the seismometer. We use the rotational sensor to calculate directions of the earthquake locations and find that most directions agree with the INGV‐OE network location and the area of the active craters. We find that for some earthquakes the ground only moved horizontally while for others it also moved up and down. Using a rotational sensor on a volcano we can easily and reliably estimate the ground motion, the speed of the earthquake waves in the ground and understand better how these earthquakes are generated.
    Description: Key Points: We tested the performance of a rotational sensor compared to a seismometer and a seismic network using long‐period (LP), volcano‐tectonic (VT) events and tremor on Etna. LP and VT events are dominated by SH‐ and SV‐waves, respectively. Tremor changed from SH‐ to a mixed wavefield during strombolian eruptions. LP event and tremor back azimuths point to the main craters consistent with the Istituto Nazionale di Geofisica e Vulcanologia location; VT event back azimuths are at times consistent.
    Description: Eurovolc
    Description: Daimler Benz Foundation
    Description: https://doi.org/10.14470/ME7564062119
    Keywords: ddc:551.2
    Language: English
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    New impact diagnostics for cross‐validation of different observation types (2022)
    John Wiley & Sons, Ltd | Chichester, UK
    Details
    Publication Date: 2022-10-04
    Description: New cross‐validation diagnostics have been derived by further partitioning well‐established impact diagnostics. They are related to consistency relations, the most prominent of which indicates whether the first‐guess departures of a given observation type pull the model state into the direction of the verifying data (when processed with the ensemble estimated model error covariances). Alternatively, this can be regarded as cross‐validation between model error covariance estimates from the ensemble (which are used in the data assimilation system) and estimates diagnosed directly from the observations. A statistical cross‐validation tool has been developed that includes an indicator of statistical significance as well as a normalization that makes the statistical comparison largely independent from the total number of data and the closeness of their collocation. We also present a version of these diagnostics related to single‐observation experiments that exploits the same consistency relations but is easier to compute. Diagnostics computed within the Deutscher Wetterdienst's localized ensemble transform Kalman filter (LETKF) are presented for various kinds of bins. Results from well‐established in‐situ measurements are taken as a benchmark for more complex observations. Good agreement is found for radio‐occultation bending angle measurements, whereas atmospheric motion vectors are generally also beneficial but substantially less optimal than the corresponding in‐situ measurements. This is consistent with reported atmospheric motion vector height assignment problems. To illustrate its potential, a recent example is given where the method allowed identifying bias problems of a subgroup of aircraft measurements. Another diagnostic relationship compares the information content of the analysis increments with a theoretical optimum. From this, the information content of the LETKF increments is found to be considerably lower than those of the deterministic hybrid ensemble–variational system, which is consistent with the LETKF's limitation to the comparably low‐dimensional ensemble space for finding the optimal analysis.
    Description: New cross‐validation diagnostics are presented, allowing to test the consistent use of different observation types in the data assimilation system. The figure gives an example in which these new diagnostics allowed identification of the detrimental impact of a group of aircraft measurements (which as a consequence has now been blacklisted in the Deutscher Wetterdienst's operational system). More precisely, brown colors in this plot indicate regions where these aircraft measurements pulled the analysis state away from radiosonde observations.
    Keywords: ddc:551.5
    Language: English
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    Millimetre scale aeration of the rhizosphere and drilosphere (2022)
    Blackwell Publishing Ltd | Oxford, UK
    Details
    Publication Date: 2022-10-04
    Description: Soil aeration is a critical factor for oxygen‐limited subsoil processes, as transport by diffusion and advection is restricted by the long distance to the free atmosphere. Oxygen transport into the soil matrix is highly dependent on its connectivity to larger pore channels like earthworm and root colonised biopores. Here we hypothesize that the soil matrix around biopores represents different connectivity depending on biopore genesis and actual coloniser. We analysed the soil pore system of undisturbed soil core samples around biopores generated or colonised by roots and earthworms and compared them with the pore system of soil, not in the immediacy of a biopore. Oxygen partial pressure profiles and gas relative diffusion was measured in the rhizosphere and drilosphere from the biopore wall into the bulk soil with microelectrodes. The measurements were linked with structural features such as porosity and connectivity obtained from X‐ray tomography and image analysis. Aeration was enhanced in the soil matrix surrounding biopores in comparison to the bulk soil, shown by higher oxygen concentrations and higher relative diffusion coefficients. Biopores colonised by roots presented more connected lateral pores than earthworm colonised ones, which resulted in enhanced aeration of the rhizosphere compared to the drilosphere. This has influenced biotic processes (microbial turnover/mineralization or root respiration) at biopore interfaces and highlights the importance of microstructural features for soil processes and their dependency on the biopore's coloniser.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:631.4
    Language: English
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    Variability in the Concentration of Lithium in the Indo‐Pacific Ocean (2022)
    Details
    Publication Date: 2022-10-04
    Description: Lithium has limited biological activity and can readily replace aluminium, magnesium and iron ions in aluminosilicates, making it a proxy for the inorganic silicate cycle and its potential link to the carbon cycle. Data from the North Pacific Ocean, tropical Indian Ocean, Southern Ocean and Red Sea suggest that salinity normalized dissolved lithium concentrations vary by up to 2%–3% in the Indo‐Pacific Ocean. The highest lithium concentrations were measured in surface waters of remote North Pacific and Indian Ocean stations that receive relatively high fluxes of dust. The lowest dissolved lithium concentrations were measured just below the surface mixed layer of the stations with highest surface water concentrations, consistent with removal into freshly forming aluminium rich phases and manganese oxides. In the North Pacific, water from depths 〉2,000 m is slightly depleted in lithium compared to the initial composition of Antarctic Bottom Water, likely due to uptake of lithium by authigenically forming aluminosilicates. The results of this study suggest that the residence time of lithium in the ocean may be significantly shorter than calculated from riverine and hydrothermal fluxes.
    Description: Key Points: Li/Na ratios vary by up to 2%–3% in the Indian and Pacific Oceans. Authigenic formation of aluminosilicates slightly deplete deep‐water lithium concentrations in the North Pacific. The residence time of lithium in the ocean is 240,000 ± 70,000 years, based on removal from North Pacific deep‐water.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: MoES, Indian National Centre for Ocean Information Services http://dx.doi.org/10.13039/501100004814
    Description: National Science Foundation USA
    Description: https://doi.pangaea.de/10.1594/PANGAEA.941888
    Keywords: ddc:551
    Language: English
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    Reassessing evidence of Moon–Earth dynamics from tidal bundles at 3.2 Ga (Moodies Group, Barberton Greenstone Belt, South Africa) (2022)
    Details
    Publication Date: 2022-10-04
    Description: Past orbital parameters of the Moon are difficult to reconstruct from geological records because relevant data sets of tidal strata are scarce or incomplete. The sole Archean data point is from the Moodies Group (ca 3.22 Ga) of the Barberton Greenstone Belt, South Africa. From the time‐series analysis of tidal bundles from a well‐exposed subaqueous sand wave of this unit, Eriksson and Simpson (Geology, 28, 831) suggested that the Moon’s anomalistic month at 3.2 Ga was closer to 20 days than the present 27.5 days. This is in apparent accordance with models of orbital mechanics which place the Archean Moon in a closer orbit with a shorter period, resulting in stronger tidal action. Although this study’s detailed geological mapping and section measuring of the site confirmed that the sandstone bed in question is likely a migrating dune, the presence of angular mud clasts, channel‐margin slumps, laterally aggrading channel fills and bidirectional paleocurrents in overlying and underlying beds suggests that this bedform was likely located in a nearshore channel near lower‐intertidal flats and subtidal estuarine bars; it thus carries risk of incomplete preservation. Repeated measurements of foreset thicknesses along the published traverse, measured perpendicular to bedding, failed to show consistent spectral peaks. Larger data sets acquired along traverses measured parallel to bedding along the 20.5 m wide exposure are affected by minor faulting, uneven outcrop weathering, changing illumination, weather, observer bias and show a low reproducibility. The most robust measurements herein confirm the periodicity peak of approximately 14 in the original data of Eriksson and Simpson (Geology, 28, 831). Because laminae may have been eroded, the measurements may represent a lower bound of about 28 lunar days per synodic month. This estimate agrees well with Earth–Moon dynamic models which consider the conservation of angular momentum and place the Archaean Moon in a lower orbit around a faster‐spinning Earth.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.3 ; ddc:556
    Language: English
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    Arctic – Atlantic Exchange of the Dissolved Micronutrients Iron, Manganese, Cobalt, Nickel, Copper and Zinc With a Focus on Fram Strait (2022)
    Details
    Publication Date: 2022-10-04
    Description: The Arctic Ocean is considered a source of micronutrients to the Nordic Seas and the North Atlantic Ocean through the gateway of Fram Strait (FS). However, there is a paucity of trace element data from across the Arctic Ocean gateways, and so it remains unclear how Arctic and North Atlantic exchange shapes micronutrient availability in the two ocean basins. In 2015 and 2016, GEOTRACES cruises sampled the Barents Sea Opening (GN04, 2015) and FS (GN05, 2016) for dissolved iron (dFe), manganese (dMn), cobalt (dCo), nickel (dNi), copper (dCu) and zinc (dZn). Together with the most recent synopsis of Arctic‐Atlantic volume fluxes, the observed trace element distributions suggest that FS is the most important gateway for Arctic‐Atlantic dissolved micronutrient exchange as a consequence of Intermediate and Deep Water transport. Combining fluxes from FS and the Barents Sea Opening with estimates for Davis Strait (GN02, 2015) suggests an annual net southward flux of 2.7 ± 2.4 Gg·a−1 dFe, 0.3 ± 0.3 Gg·a−1 dCo, 15.0 ± 12.5 Gg·a−1 dNi and 14.2 ± 6.9 Gg·a−1 dCu from the Arctic toward the North Atlantic Ocean. Arctic‐Atlantic exchange of dMn and dZn were more balanced, with a net southbound flux of 2.8 ± 4.7 Gg·a−1 dMn and a net northbound flux of 3.0 ± 7.3 Gg·a−1 dZn. Our results suggest that ongoing changes to shelf inputs and sea ice dynamics in the Arctic, especially in Siberian shelf regions, affect micronutrient availability in FS and the high latitude North Atlantic Ocean.
    Description: Plain Language Summary: Recent studies have proposed that the Arctic Ocean is a source of micronutrients such as dissolved iron (dFe), manganese (dMn), cobalt (dCo), nickel (dNi), copper (dCu) and zinc (dZn) to the North Atlantic Ocean. However, data at the Arctic Ocean gateways including Fram Strait and the Barents Sea Opening have been missing to date and so the extent of Arctic micronutrient transport toward the Atlantic Ocean remains unquantified. Here, we show that Fram Strait is the most important gateway for Arctic‐Atlantic micronutrient exchange which is a result of deep water transport at depths 〉500 m. Combined with a flux estimate for Davis Strait, this study suggests that the Arctic Ocean is a net source of dFe, dNi and dCu, and possibly also dCo, toward the North Atlantic Ocean. Arctic‐Atlantic dMn and dZn exchange seems more balanced. Properties in the East Greenland Current showed substantial similarities to observations in the upstream Central Arctic Ocean, indicating that Fram Strait may export micronutrients from Siberian riverine discharge and shelf sediments 〉3,000 km away. Increasing Arctic river discharge, permafrost thaw and coastal erosion, all consequences of ongoing climate change, may therefore alter future Arctic Ocean micronutrient transport to the North Atlantic Ocean.
    Description: Key Points: Fram Strait is the major gateway for Arctic‐Atlantic exchange of the dissolved micronutrients Fe, Mn, Co, Ni, Cu and Zn. The Arctic is a net source of dissolved Fe, Co, Ni and Cu to the Nordic Seas and toward the North Atlantic; Mn and Zn exchange are balanced. Waters of the Central Arctic Ocean, including the Transpolar Drift, are the main drivers of gross Arctic micronutrient export.
    Description: German Research Foundation
    Description: Netherlands Organization for Scientific Research
    Description: https://doi.pangaea.de/10.1594/PANGAEA.859558
    Description: https://doi.pangaea.de/10.1594/PANGAEA.871030
    Description: https://doi.pangaea.de/10.1594/PANGAEA.868396
    Description: https://doi.pangaea.de/10.1594/PANGAEA.905347
    Description: https://dataportal.nioz.nl/doi/10.25850/nioz/7b.b.jc
    Description: https://doi.pangaea.de/10.1594/PANGAEA.933431
    Description: https://www.bco-dmo.org/dataset/718440
    Description: https://doi.org/10.1594/PANGAEA.936029
    Description: https://doi.org/10.1594/PANGAEA.936027
    Description: https://doi.pangaea.de/10.1594/PANGAEA.927429
    Keywords: ddc:551.9
    Language: English
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    Contrasting State‐Dependent Effects of Natural Forcing on Global and Local Climate Variability (2022)
    Details
    Publication Date: 2022-10-04
    Description: Natural forcing from solar and volcanic activity contributes significantly to climate variability. The post‐eruption cooling of strong volcanic eruptions was hypothesized to have led to millennial‐scale variability during Glacials. Cooling induced by volcanic eruption is potentially weaker in the warmer climate. The underlying question is whether the climatic response to natural forcing is state‐dependent. Here, we quantify the response to natural forcing under Last Glacial and Pre‐Industrial conditions in an ensemble of climate model simulations. We evaluate internal and forced variability on annual to multicentennial scales. The global temperature response reveals no state dependency. Small local differences result mainly from state‐dependent sea ice changes. Variability in forced simulations matches paleoclimate reconstructions significantly better than in unforced scenarios. Considering natural forcing is therefore important for model‐data comparison and future projections.
    Description: Plain Language Summary: Climate variability describes the spatial and temporal variations of Earth's climate. Understanding these variations is important for estimating the occurrence of extreme climate events such as droughts. Yet, it is unclear whether climate variability depends on the mean surface temperature of the Earth or not. Here, we investigate the effects of natural forcing from volcanic eruptions and solar activity changes on climate variability. We compare simulations of a past (cold) and present (warm) climate with and without volcanism and solar changes. We find that overall, the climate system responds similarly to natural forcing in the cold and warm state. Small local differences mainly occur where ice can form. To evaluate the simulated variability, we use data from paleoclimate archives, including trees, ice‐cores, and marine sediments. Climate variability from forced simulations agrees better with the temperature variability obtained from data. Natural forcing is therefore critical for reliable simulation of variability in past and future climates.
    Description: Key Points: We present Glacial/Interglacial climate simulations and quantify effects of time‐varying volcanic and solar forcing on climate variability. The mean global and local response to these forcings is similar in Glacial and Interglacial climate, suggesting low state dependency. In both climate states, modeled temperature variance agrees better with palaeoclimate data when volcanic and solar forcing is included.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Heinrich Böll Stiftung (Heinrich Böll Foundation) http://dx.doi.org/10.13039/100009379
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: https://doi.org/10.5281/zenodo.6074747
    Description: https://github.com/paleovar/StateDependency
    Description: https://doi.org/10.5281/zenodo.6474769
    Keywords: ddc:551.6
    Language: English
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    Climates of democracy: Skeptical, rational, and radical imaginaries (2022)
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-10-05
    Description: How will the theories and practices of democracy fare in a climate changing world? Are conventional democratic institutions ultimately doomed or are they able to become more responsive to a changing climate? Is there a need to reimagine democracy and how might it be reimagined? This article reviews the different responses to these questions by distinguishing between three “political imaginaries” in which the relationship between climate change and democracy takes distinct forms. I start by showing how the concept of “political imaginaries” can facilitate the comparison of the different ways in which the relation between democracy and climate change is constructed, before reviewing three such imaginaries. The skeptical imaginary, found in the “eco‐authoritarianism” of the 1970s that is echoed by much sociopolitical analysis today, casts doubt on the possibilities of democratic mechanisms to respond adequately and swiftly to the problem of climate change. Those who resist such skepticism often defend democracy by arguing that institutions and processes of democracy can be made more “ecologically rational”—the rational imaginary of climate democracy involves improvements in political representation and participation. Finally, I present the alternative radical democratic imaginary, in which the crisis of climate change provides a moment for the rupture of existing sociopolitical structures and the formation of alternatives. The article concludes that although none of these imaginaries is able to capture the entirety of climate change politics around the world, the radical democratic imaginary is responsive to the inevitable and valuable plurality around the issue of climate change. This article is categorized under: Climate, Nature, and Ethics 〉 Ethics and Climate Change Policy and Governance 〉 Multilevel and Transnational Climate Change Governance
    Description: Climate protests may mobilise new political subjects.
    Keywords: ddc:363.70561
    Language: English
    Type: doc-type:article
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    Spatial Markov Model for the Prediction of Travel‐Time‐Based Solute Dispersion in Three‐Dimensional Heterogeneous Media (2022)
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    Publication Date: 2022-10-05
    Description: In recent years, Spatial Markov Models have gained popularity in simulating solute transport in heterogeneous formations. They describe the transition times of particles between equidistant observation planes by statistical distributions, assuming correlation of the transit times of individual particles between subsequent steps. By this, the approach naturally captures preasymptotic solute dispersion. In this study, we analyze Spatial Markov Models assuming bivariate log‐normal distributions of the particle slowness (i.e., the inverse velocity) in subsequent transitions. The model is fully parameterized by the mean Eulerian velocity, the variance of the log‐slowness, and the correlation coefficient of log‐slowness in subsequent steps. We derive closed‐form expressions for distance‐dependent ensemble dispersion, which is defined in terms of the second‐central moments of the solute breakthrough curves. We relate the coefficients to the properties of the underlying log‐hydraulic conductivity field assuming second‐order stationarity. The results are consistent with linear stochastic theory in the limit of small log‐conductivity variances, while the approach naturally extends to high‐variance cases. We demonstrate the validity of the approach by comparison to three‐dimensional particle‐tracking simulations of advective transport in heterogeneous media with isotropic, exponential correlation structure for log‐conductivity variances up to five. This study contributes to relating solute dispersion to metrics of the porous‐medium structure in cases of strong heterogeneity.
    Description: Key Points: We derive closed‐form expressions of ensemble dispersion in the spatial‐Markov framework of solute transport. The expressions are consistent with linear theory in the limit of small log‐conductivity variances, but extend to high‐variance cases. Comparison to particle‐tracking simulations of advective transport in 3‐D heterogeneous domains show excellent agreement.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.5281/zenodo.6554308
    Description: https://www.hsl.rl.ac.uk/catalogue/hsl_mi20.html
    Keywords: ddc:550
    Language: English
    Type: doc-type:article
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