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  • Chromatographie, Gas  (67)
  • 42.55  (64)
  • oxidation  (57)
  • Springer  (188)
  • Periodicals Archive Online (PAO)
  • 1975-1979  (188)
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  • Springer  (188)
  • Periodicals Archive Online (PAO)
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  • 1
    ISSN: 1432-0630
    Keywords: 42.55
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Lasing in atomic lines of noble gases and fluorine, prior to excimer radiation, was observed in an electric discharge ArF/XeF excimer laser. Some Ar/Xe lines end at metastable levels, which are very important for the formation of ArF/XeF excimer molecules. Five new lasing lines of atomic fluorine have been obtained. Consideration is given to the use of lasing in atomic and molecular lines, that occurs in one burst, in investigations of the excitation kinetics of excimer states under the conditions of a high-pressure electric discharge.
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  • 2
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    Applied physics 14 (1977), S. 277-282 
    ISSN: 1432-0630
    Keywords: 42.55 ; 52
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The paper deals with the properties andI-V characteristics of discharges in narrow capillaries used, for example, for He−Ne waveguide lasers. It has been observed that discharges in He−Ne waveguide lasers are unstable because of the strongly falling characteristic. A theory is presented which assumes that at low currents wall charges restrict the positive column to a narrow plasma channel and are the main reason for the observed falling characteristic. A numerical evaluation for helium gives results which agree well with experimental data.
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  • 3
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    Applied physics 18 (1979), S. 333-338 
    ISSN: 1432-0630
    Keywords: 87 ; 42.55
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Energy transfer in DNA-dye-complexes after excitation in the UV down to 220 nm by means of a tunable laser was investigated. DNA of different base composition and polynucleotides were compared. The dyes proflavine, acridine orange and ethidium bromide were used. The energy transfer from DNA-bases to dye molecules was measured in dependence of the excitation wavelength and the base composition of the DNA. Models of the energy transfer from DNA to dye and of the molecular structures of the DNA-dye-complex (intercalation) could be deduced.
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  • 4
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    Applied physics 19 (1979), S. 47-51 
    ISSN: 1432-0630
    Keywords: 42.55 ; 42.80
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The possibility of building free-electron lasers and masers with quasi-circular undulators is considered. The two-mirror cavity is replaced by a suitable waveguide. The magnetic field along the orbit has a continuous component superimposed on the alternating one. Besides allowing large freedom for electron guiding and focusing, the structure allows effective negative mass conditions, which may enhance the electron beam modulation when space charge effect are important. Furthermore the radiation frequency can be higher than that in a linear undulator with the same electron energy, and long interaction times are possible in a compact structure.
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  • 5
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    Applied physics 19 (1979), S. 345-351 
    ISSN: 1432-0630
    Keywords: 78.55 ; 42.55
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract PrP5O14, PrxLa1−xP5O14, and PrxY1−xP5O14 (0≦x≦1) single crystals of laser quality were synthesized and their crystallographic and optical parameters measured. Laser emissions in the visible (λ=637.4 nm) with no mirrors in place (superradiance) and also in various optical resonators have been observed.
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  • 6
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    Applied physics 13 (1977), S. 97-99 
    ISSN: 1432-0630
    Keywords: 42.55 ; 82.50
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract First cw laser oscillation with thresholds below 1 mW was observed for various B1Пu → X1 ∑ g + transitions of diatomic molecular sodium excited by different argon laser lines in the range of 454–488 nm. For pump powers of 0.5 W output powers up to 3 mW and single-pass gain up to 0.1 cm−1 were obtained. Some properties of the heat pipe laser system are discussed.
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  • 7
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    Applied physics 13 (1977), S. 383-385 
    ISSN: 1432-0630
    Keywords: 42.55 ; 42.80
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract An optically pumped FIR laser was operated with a copper mesh Fabr-Perot output coupler. With this device a Gaussian output beam was obtained andthe degree of coupling could be varied continuously, thus allowing optimum coupling. From the measured properties of the wire mesches grains of two FIR laser lines are calculated and the saturation intensities estimated.
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  • 8
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    Applied physics 14 (1977), S. 25-28 
    ISSN: 1432-0630
    Keywords: 42.55 ; 42.80
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract A new device for magnetically displacing the output mirror of a laser resonator and synchronously tilting an etalon in order to obtain single-mode tuning of a dye laser over a tuning range of at least 10 GHz is described. Comparatively large displacements with good linearity of a coil mounted on a membrane and placed inside the strong magnetic field of a ring magnet are obtained for currents in the order of several hundred milliamperes. Together with etalon flats of appropriate thickness and reflection mounted in the resonator of the laser a versatile instrument for application in intra and extra cavity spectroscopy has been developed.
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  • 9
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    Applied physics 14 (1977), S. 393-398 
    ISSN: 1432-0630
    Keywords: 34 ; 42.55
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract A flowing afterglow method has been used to study a number of reactions of importance in KrF lasers using NF3 as the fluorine donor. Total rate constants are reported for Kr*(3 P 2)+NF3 and Kr++NF3. The thermal energy attachment coefficient has been measured for NF3 and the cross section for the electron excitation process Kr*(3 P 2) +e→Kr*(3 P 1)+e has been estimated. The relevance of these results to discharge pumped KrF lasers is discussed.
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  • 10
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    Applied physics 14 (1977), S. 193-197 
    ISSN: 1432-0630
    Keywords: 42.55 ; 52
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Planar and cylindrical discharges for argon lasers are compared by plasmatheoretical calculations. The maximum laser output power available in the two arrangements is computed in dependence of various parameters neglecting saturation mechanisms. A transverse discharge arrangement confining the positive column by two parallel walls is described and experimental laser threshold values for the current and pressure are reported.
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  • 11
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    Applied physics 14 (1977), S. 255-268 
    ISSN: 1432-0630
    Keywords: 42.80 ; 42.55 ; 85.60
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract GaAs double heterostructure semiconductor injection lasers which now exhibit more than 25000 h cw room temperature lifetime are of great interest for future use as directly modulated transmitters for high bit-rate fiber optical communications. The effects limiting this application are modulation distortions, spectral width and additional spectral broadening in the case of modulation and spontaneous fluctuations of the output power. The dynamic and spectral behavior of injection lasers, the methods of high bit-rate modulation and the improvement of the high bit-rate modulation capability by coupling two lasers are discussed.
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  • 12
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    Applied physics 15 (1978), S. 185-190 
    ISSN: 1432-0630
    Keywords: 42.55
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Electron energy loss studies of POPOP andp-terphenyl in the vapor phase at an incident electron energy of 25 eV have been performed. The spectra covering an energy loss between 0 and 9 eV revealed a considerable initial triplet population under electron impact excitation. The implications for electron-beam pumped vapor phase dye lasers are discussed.
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  • 13
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    Applied physics 15 (1978), S. 229-232 
    ISSN: 1432-0630
    Keywords: 42.55
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract A new type of discharge tube for high-power argon-ion lasers constructed of a segmented metal-ceramic compound system is described. Up to date, the system has been operating for 1500 h without failure. The maximum cw output is 140 W, limited by the destruction of the mirrors.
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  • 14
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    Applied physics 15 (1978), S. 439-450 
    ISSN: 1432-0630
    Keywords: 42.55 ; 42.65
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract A theoretical model for the ultrashort-pulse (USP) generation by lasers with saturable absorbers is presented. The gain medium is assumed to be a two-level system whereas the absorber is described by a four-level system which is characterized by a two-stage absorption process and the pertinent relaxation times. Laser dynamical equations are developed in the rate-equation approximation and boundary conditions appropriate for an unidirectional ring cavity are established. Evolution of USP is investigated for different combinations of parameter values appropriate for solid-state laser systems by computer simulation, employing a finite difference approximation for the dynamical equations. It is shown that USP output is attainable even if the cross-section of the excited-state absorption isgreater than that of the ground-state absorption and the laser is operating just above threshold. In fact, it is found that through the participation of a strong excited-state absorption the discrimination against satellite pulses is enhanced so that single-pulse output is more achievable. Furthermore, it is proposed that single picosecond pulses may be obtainable from relatively broad initial peaks by utilizing the high pulse-selection and pulse-shortening efficiency of the absorber due to the contribution of the excited-state absorption. The applicability of the present model to singlet-triplet crossing and photoisomer formation is also discussed.
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  • 15
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    Applied physics 16 (1978), S. 297-301 
    ISSN: 1432-0630
    Keywords: 42.55
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract A grating-tuned cw dye laser with an emission bandwidth of less than 1 GHz and output power in excess of 400 mW has been constructed. This was accomplished using a newly developed holographic grating with sinusoidal groove profile, which resulted in an enhanced spectral efficiency up to 94%. The low losses and the broad spectral working range (more than 1000 Å) which can be easily covered by simple rotation make these gratings an attractive single-stage tuning element for low-gain cw lasers.
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  • 16
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    Applied physics 16 (1978), S. 151-154 
    ISSN: 1432-0630
    Keywords: 42.65 ; 42.55 ; 33
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract We observed tunable UV radiation down to 175 nm by SRS of the output of a frequency-doubled dye laser in H2. The high power output of the 4th anti-Stokes to 5th Stokes line generated by the frequency doubled dye laser and the 8th anti-Stokes to 3rd Stokes line generated by the undoubled dye laser represents a broadly tunable coherent radiation source between 189 nm and 2064 nm.
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  • 17
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    Applied physics 13 (1977), S. 109-110 
    ISSN: 1432-0630
    Keywords: 42.55
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract A simple technique is described that allows the generation of a short pulses (1 ns) from dye lasers pumped by a much longer (7 ns) N2-laser pulse. Dye-laser pulses, either with a narrow bandwidth or a short duration, can thus be obtained with the same N2-laser pump.
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  • 18
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    Applied physics 17 (1978), S. 367-370 
    ISSN: 1432-0630
    Keywords: 42.55 ; 78.55
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract We report on room temperature quasi-cw laser action in K5Nd(MoO4)4 at a wavelength of 1.067 μm. The crystal was pumped with the 5140 Å line of an argon ion laser. Due to thermal effects actual cw lasing was not possible. Chopping the pump light with a low duty cycle of 1∶1000 leads to quasi-cw laser action and stable output power. We have determined the fundamental laser parameters: threshold pump powerA T=15 mW, slope efficiency η=22%, and internal lossesL=2.5%. In order to explain the measured relaxation oscillations, diffusion of the excited 4f-excitons is considered. According to a recently developed theory, a diffusion constant ofD=2×10−6cm2/s explains the observed results.
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  • 19
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    Applied physics 14 (1977), S. 121-122 
    ISSN: 1432-0630
    Keywords: 42.55
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Frequency-tunable generation by means of F 2 + and F 2 − colour centers in a LiF crystal is reported. Colour centers were created by illuminating LiF crystals with electrons of 3 meV energy at the electron current density of 1 μA/cm2. The pumping source was a ruby laser with a peak power of 20 MW, a pulse duration of 20 ns, and a repetition rate of 1 Hz. The frequency tuning is obtained in the range of 0.88–1.25 μm. Discussed are the ways of pumping of colour centers and the possibility of lasing in the spectral region of 0.85 to 2 μm in the type of colour centers under investigation.
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  • 20
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    Applied physics 18 (1979), S. 257-260 
    ISSN: 1432-0630
    Keywords: 32 ; 42.55
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract We have demonstrated the feasibility of Doppler-free polarization spectroscopy with a train of ultrashort pulses from a synchronously pumped mode-locked dye laser. The sensitivity of the method is compared with saturation spectroscopy with a single-mode laser.
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  • 21
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    Applied physics 15 (1978), S. 191-196 
    ISSN: 1432-0630
    Keywords: 42.55
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    Notes: Abstract A guideline for the optimum design of linear wall-ablation lamps is presented with a simple empirical formula which describes the luminescent characteristics of lamps. The absolute luminescent efficiency of the wall-ablation lamp was measured. A high-energy dye laser with a quadruple-elliptical cylindrical cavity was constructed using these lamps, and an output energy of 23.3 J (11.6 MW) was obtained with an overall efficiency of 0.31 %. The energy-flow diagram of this laser system was computed with a rate-equation analysis, and the conversion efficiency from electrical input to laser output was determined. One can expect an overall efficiency of about 2 %.
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  • 22
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    Applied physics 17 (1978), S. 181-187 
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    Keywords: 42.55
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract A complete theoretical model for optically pumped dye lasers is studied using the rate equation approach which includes excited singlet and triplet state absorption effects. Closed-form solutions under steady-state conditions reveal a novel nonlinear threshold phenomenon: partial reabsorption of the excited laser light can lead to a discontinuous onset of laser oscillation above laser threshold. Theoretical and experimental results for a transversely and longitudinally pumped rhodamine 6G laser are presented in terms of softmode and hardmode behavior at threshold.
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  • 23
    ISSN: 1432-0630
    Keywords: 33 ; 42.55
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The characteristics of a stable, external-resonator spin-flip Raman laser (SFRL), pumped by a cw carbon monoxide laser of controlled mode quality and spectral content, are determined using a combination of molecular spectroscopy, Raman amplifier and confocal Fabry-Perot interferometer measurements, and heterodyne detection. Single-frequency output of a free-running external-resonator is demonstrated with an inherent linewidth of 〈10 kHz and a short-term frequency jitter of ≃100 kHz. With the resonator length actively controlled to lock an axial mode frequency to the peak of the spontaneous gain, the linewidth of the SFRL output was maintained below 2 MHz. In this mode of operation, small variations in the output tuning rate, corresponding to the magnetic field dependence of the conduction-electrong-factor, were calibrated. Molecular absorption spectra obtained using gas cells both inside and outside the resonator have been used to illustrate the high resolution, wide-range tuning capability and sensitivity of the system. Lambda-doubling of the $$^2 \pi _{3/2} $$ of the Q-branch head of nitric oxide was measured for values ofJ down to 13/2, below which the splitting is less than the Doppler width. The splittings agreed with predictions using parameters obtained by conventional spectra for higherJ-values.
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  • 24
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    Applied physics 19 (1979), S. 241-242 
    ISSN: 1432-0630
    Keywords: 33 ; 42.55
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Several new laser lines using optically pumped deuterated methanol molecules have been discovered. These not only increase the spectral coverage of pumped methanol isotopes but may assist in the assignment of a molecular structure.
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  • 25
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    Applied physics 19 (1979), S. 399-403 
    ISSN: 1432-0630
    Keywords: 42.55
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The selection of a single longitudinal mode of a dye laser can be achieved with double or triple Michelson reflectors instead of Fabry-Perot etalons inside the laser cavity. These systems can be adapted to commercial multimode dye lasers. They provide a high efficiency and a good geometrical quality of the output beam. With a 7 watt pump power (λ=514.5 nm line of the Ar+ laser), a tunable output power of 1 watt was obtained at the peak of R6G, in the main output beam; the total single-mode power, including the auxiliary output beams, exceeded 1.4 watt. These results correspond to efficiencies of 14% and 20%, respectively (24% and 30% slope efficiencies). We discuss in the text why these efficiencies are comparable to those of ring lasers. In the infrared, with a 4.5 watt pump power (red lines of a Kr+ laser), 250 mW of single-mode output power in the main output beam was obtained at 780 nm with Oxazine 750.
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  • 26
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    Applied physics 19 (1979), S. 427-429 
    ISSN: 1432-0630
    Keywords: 33 ; 35 ; 42.55
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    Notes: Abstract Spectral coincidences between CO-laser lines and NO fundamental absorption lines were reinvestigated in order to resolve discrepancies between recently published papers. The absorption of CO laser radiation by NO and NO/Ar mixtures was measured and fitted by calculations using a Voigt profile for the NO line shapes. A new coincidence with a frequency offset of less than the NO Doppler width was found.
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  • 27
    ISSN: 1432-0630
    Keywords: 07 ; 42.55
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    Notes: Abstract A liquid-nitrogen cooled12C16O laser was operated both Q-switched and cw. A total of 276 lasing transitions were observed in cw using an intracavity grating for line selection. In the Q-switch mode, 230 lines occurred without dispersive element in the cavity.
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  • 28
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    Applied physics 18 (1979), S. 235-241 
    ISSN: 1432-0630
    Keywords: 42.65C ; 42.55 ; 33.20
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    Notes: Abstract Design and performance characteristics of a tunable ir waveguide Raman laser pumped by a high power dye laser are described. Using SRS up to third Stokes order in compressed H2, the wavelength range from 0.7 to 7 μm has been covered without gaps. Taking advantage of a waveguide structure in the scattering chamber, energy conversion efficiencies better than 1% with power levels in excess of 80 kW for the third Stokes component have been achieved. The experimental results support the theoretical predictions that a 4-wave parametric process is responsible for the production of the third Stokes component.
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  • 29
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    Applied physics 20 (1979), S. 41-50 
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    Keywords: 41 ; 42.55 ; 95
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    Notes: Abstract The interaction of free electrons and free electromagnetic radiation, in the presence of a uniform magnetic field, can result in stimulated emission or absorption. We analyze the dynamics of single electrons by solving the classical, relativistic Lorentz force equations of motion in these combined fields. An electron may gain energy from, or lose energy to, the radiation field, depending crucially on the phase and oscillation frequency of the electron's helical motion within the superposed, circularly polarized light wave. To first order in the radiation field strength, electrons in a monoenergetic, uniformly distributed beam become spatially bunched, but there is no net energy change. To second order, however, the beam may experience a gain or loss of energy, corresponding to attenuation or amplification of radiation. We compare the bunching of this laser process to the bunching processes involved in 1) the Stanford free-electron laser and 2) the cyclotron maser, and find significant differences in each case. Our analytic results provide a clear, simple picture of the interaction process, and can be useful in exploring light amplification in astrophysical magnetic fields, the magnetosphere, or in laboratory devices.
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  • 30
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    Applied physics 20 (1979), S. 61-65 
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    Notes: Abstract We show that a laser can efficiently accelerate charged particles if a magnetic field is introduced to improve the coupling between the particle and the wave. Solving the relativistic equations of motion for an electron in a uniform magnetic field and superposed, circularly polarized electromagnetic wave, we find that in energy-position phase space an electron traces out a curtate cycloid: it alternately gains and loses energy. If, however, the parameters are chosen so that the electron's oscillations in the two fields are resonant, it will continually accelerate or decelerate depending on its initial position within a wavelength of light. A laboratory accelerator operating under these resonant conditions appears attractive: in a magnetic field of 105 Gauss, and the fields of a 5×1012 W, 10 μm wavelength laser, an optimally positioned electron would accelerate to 700 MeV in only 10m.
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  • 31
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    Applied physics 20 (1979), S. 97-99 
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    Notes: Abstract A narrow-band tunable double-wavelength dye laser with a bandwidth of 0.1 cm−1 is described. The output at one of the wavelengths is found to be completely linearly polarized in the plane of incidence.
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  • 32
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    Applied physics 13 (1977), S. 107-108 
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    Notes: Abstract Intense laser oscillation has been observed from ArF molecules at 1933 Å. Excitation of the gas mixture NF3:Ar:He=1:55:630 at total pressures above 2.1 atm was produced by a transverse electric discharge. The range of fine tuning was from 1927 Å to 1936 Å. An output energy of 0.8 mJ was measured from a laser pulse 15 ns in duration.
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  • 33
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    Applied physics 17 (1978), S. 257-267 
    ISSN: 1432-0630
    Keywords: 42.55 ; 32.60
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    Notes: Abstract The effect of transversally applied magnetic fields on the polarization behavior of a single-mode gas laser is theoretically investigated, stressing the importance of the additivity of respective contributions influencing the time evolution of polarization parameters. By adding a new element to the existing theory, namely the contribution of magnetic-field-free regions in the active medium, and by considering the relatively large effects that small cavity anisotropies can cause, several apparent discrepancies between experiments and existing theory are resolved.
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    Applied physics 15 (1978), S. 59-63 
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    Notes: Abstract Feedback controlled self-excitation of optical pulses of nanosecond duration has been observed to occur rather reliably in a CW dye ring laser, oscillating in a traveling mode. These observations are described analytically by means of a direct time domain approach. It is shown that a steady-state Gaussian pulse whose time duration determined from the self consistency condition in terms of system characteristics describes accurately the observed pulse behaviors.
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  • 35
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    Applied physics 19 (1979), S. 39-41 
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    Notes: Abstract It is shown that when a distributed feedback dye laser is used to generate a train of picosecond pulses, the narrow lines observed in the spectrum are not longitudinal modes, but are due to the intrapulse refractive index changes caused by the heating effect of the pumping pulse.
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  • 36
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    Applied physics 18 (1979), S. 415-419 
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    Notes: Abstract Remarkable intensity fluctuations were observed in the LiNdP4O12 (LNP) laser by placing a moving ground-glass plate across the ouput beam. Resonance-like behaviors were also observed by tuning the moving velocity of the ground-glass plate, with respect to relaxation oscillations. Classical rate equations including the modulation term were given to explain the observed phenomena. Similar intensity fluctuations corresponding to relaxation oscillations were observed when the LNP laser light beam was coupled to an optical fiber.
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  • 37
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    Applied physics 19 (1979), S. 35-37 
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    Notes: Abstract Results of an investigation of 19 organic dyes pumped by a 1.7 MW discharge-pumped XeCl excimer laser are reported. The dye-laser emission covered a wide wavelength range from 340 nm to 710 nm.P-terphenyl shows efficient laser action. The highest energy conversion efficiency exceeds 40% in visible region. In comparison with 250 kW nitrogen laser pumping, higher efficiencies are obtained for most of these dyes in the same dye-laser configuration.
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  • 38
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    Applied physics 19 (1979), S. 185-189 
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    Notes: Abstract We have studied the interaction of stimulated spin-flip Raman scattering and stimulated recombination radiation in n-InSb using a CW CO pump laser. A change in linewidth and output power of second Stokes spin-flip radiation is observed when the tuning curve of the first Stokes stimulated spin-flip radiation and the stimulated recombination radiation cross. The observations are explained using a simple rate equation model.
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  • 39
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    Applied physics 18 (1979), S. 77-80 
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    Notes: Abstract We report, for the first time, on room temperature cw laser action of NdP5O14 and NdAl3(BO3)4 at 1.3 μm wavelength. The emission cross sections of the transition4 F 3/2→4 I 13/2 are 0.24·10−19 cm2 and 1.74·10−19 cm2, respectively. The lowest observed threshold was 45 mW and the slope efficiency was nearly 10%. The minimum threshold is expected to be about 5 mW of absorbed pump light for both materials.
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  • 40
    ISSN: 1432-0630
    Keywords: 32 ; 34 ; 42.55
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    Notes: Abstract Laser induced nonlinear absorption profiles in a three-level system have been recorded to study the effect of elastic collisions upon optical coherences. In our particular system, the signal is due to a pure double-quantum term, where we have separated the effect of phase-interrupting collisions from the effect of velocity-changing collisions. Experimental results show that the effect of velocity-changing collisions is very small, and that broadening of the signal is due to phase-interrupting collisions mainly. We are able to determine the increase of the decay rate of the coherent superposition (the “coherence”) of two levels of same parity [Dγ 13/dp=(6.5±1) MHz/Torr] and an upper limit for the mean velocity change (ũ≲5m/s).
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  • 41
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    Applied physics 19 (1979), S. 165-170 
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    Keywords: 33 ; 42.55
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    Notes: Abstract Computer calculations of ETDL performance indicate that dye laser output can be manipulated by an appropriate choice of a donor (absorber)-acceptor (dye) couple. Studies of relevant laser induced inter- and intramolecular energy transfer processes are presented.
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  • 42
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    Applied physics 19 (1979), S. 221-224 
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    Keywords: 42.10 ; 42.55 ; 42.65
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    Notes: Abstract Wave front of a light pulse is shown to be unstable as it propagates through a resonant saturable absorber, if its frequency is higher than the resonance frequency of the absorber. When ΔωT 2∼1, a small-scale transverse instability with the dimension of (λl abs)1/2 grows rapidly. Its growth-rate is of the order of the small-signal-absorption length of the medium.
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  • 43
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    Applied physics 19 (1979), S. 257-264 
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    Notes: Abstract Employing injection-locking techniques an oscillator configuration was found comprising in a simple way all the features required for fusion directed high-power CO2 laser systems. The oscillator provides emission in single axial modes on rotational transitions which can be freely selected by feeding fluencies of a few mW/cm2 at the particular transition into the oscillator cavity. In the same way simultaneous emission on selectable lines can be achieved. By the same principle the oscillator can be forced to emit in any orientation of polarization. The set up is relatively simple, the alignment rather uncritical, and the operation reliable. Gaussian-shaped nanosecond pulses with low forepulse power are produced with the help of a pulse cutter and saturable multiline absorber. The set up is described and its features are demonstrated by measurements.
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  • 44
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    Applied physics 13 (1977), S. 1-3 
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    Notes: Abstract Disappearance of NF3 and appearance of NF2 and N2F2 in an excimer laser is followed quantitatively with a mass spectrometer. A model for the kinetics is presented.
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  • 45
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    Applied physics 13 (1977), S. 55-58 
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    Keywords: 42.55 ; 78.60
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    Notes: Abstract NdxLa1−xP5O14 (0.25≦x≦1) single crystals, placed within a confocal optical resonator, were pumped with ruby laser fundamental and second-harmonic nanosecond pulses. In both cases laser oscillations at 1.05 μm exceeding in duration many times the pumping pulse were obtained.
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  • 46
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    Applied physics 14 (1977), S. 343-350 
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    Keywords: 33 ; 42.55
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    Notes: Abstract By means of nonlinear absorption spectroscopy data necessary for the interpretation of molecular spectra can be obtained in such spectral regions, where conventional spectroscopic methods yield only a quasi-continuous absorption curve. Using a Zeeman-tuned He−Ne laser at the wavelength of 3.39μm we have measured significant differences in the intensity and temperature behaviour for several ethane absorption lines, the analysis of which made possible a preliminary qualitative assignment of these lines.
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  • 47
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    Applied physics 14 (1977), S. 377-380 
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    Notes: Abstract Due to spatial hole burning, standing-wave dye lasers require a large amount of selectivity inside the cavity for single-mode operation. The output power of these lasers is limited by losses caused by the frequency selecting elements. In a travelling-wave laser, on the other hand, spatial hole burning does not exist, thereby eliminating the need for high selectivity. A travelling-wave cw dye laser was realized by unidirectional operation of a ring laser, yielding single mode output powers of 1.2 W at 595 nm and of 55 mW in the UV-region with intracavity frequency doubling.
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  • 48
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    Applied physics 15 (1978), S. 265-270 
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    Notes: Abstract For a homogeneously broadened two-level ring laser model the stability of the cw laser oscillation in the presence of a passive medium is investigated. The passive material is treated similar to the active material, but without an external pumping mechanism. Stable and unstable regions are shown for various parameters. The stability region of the cw solution becomes extremly small for certain parameters.
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  • 49
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    Applied physics 16 (1978), S. 155-158 
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    Keywords: 42.55 ; 78.60 ; 85.60
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    Notes: Abstract Dynamic characteristics of laser diodes are numerically calculated on multi-mode rate equations, including spatial relaxing interaction causing mode competitions or jumps. It is revealed that the interaction effect is classified into three cases [“independent (or inhomogeneous)”, “competition (or intermediate)”, and “monopoly (or ideally homogeneous)”], that an optimum relaxing coefficient value exists to minimize relaxation oscillations in rise and decay transients, and that the optimum value is related to the relaxation period. Calculated results are discussed in comparison with the experimental results.
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  • 50
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    Notes: Abstract The room temperature cw oscillation at 1.05 and 1.32 μm of lithium neodymium tetraphosphate [LiNd(PO3)4, LNP] lasers in an external resonator and, for the first time, also in a Fabry-Perot resonator with directly applied mirrors is reported. The growth and fluorescence properties of the LNP crystals are briefly described. Laser parameters such as threshold pump power, output power, differential efficiency, optical gain, emission cross section and laser modes are both measured and calculated. Laser experiments show the threshold pump power to be lower for 1.05 μm than for 1.32 μm emission because of the smaller emission cross section; the pump power density is lower for the external resonator than for the Fabry-Perot resonator because of its higher mode losses.
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  • 51
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    Applied physics 14 (1977), S. 199-203 
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    Keywords: 42.55 ; 82.50
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    Notes: Abstract Loss of gain in a dye medium as a result of decomposition by pump photons is considered in terms of disappearance of dye molecules and the appearance of a new, single chemical product having absorption in the fluorescence band. The cases of small signal gain and saturated gain are applied to a single pass through a transversely excited amplifier. Loss of output, defined as “quantum yield of laser deterioration”,Q L , is related to the true quantum yield of molecular destruction of the dye,Q M , and other known parameters. For the experimentally common, saturated gain condition, the smallestQ L can be isQ M , which requires a photochemically bleachable dye with high gain, preferably at high concentration, in a long cavity, operating at high injection and pumping fluxes. Reversing these conditions, the highest valueQ L can be, compared withQ M , is unrestricted.
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  • 52
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    Applied physics 17 (1978), S. 303-307 
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    Notes: Abstract A new and simple technique for measuring the effective diameter of a laser beam used in material processing is described. The time for the temperature of a spot heated by the laser beam to rise to 90% of equilibrium is compared with that predicted theoretically for a Gaussian TEM00 laser beam. A Gaussian beam diameter equivalent is thus deduced. This calculated diameter is of particular relevance to applications where the laser is used as a heat source.
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  • 53
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    Applied physics 17 (1978), S. 393-400 
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    Notes: Abstract Stimulated Raman scattering by polaritons when employing a nonlinear crystal inside the cavity of the laser with Q-switching and locked to fundamental frequency was theoretically studied. The equations were formulated describing the dynamics of the fundamental, Stokes and polariton waves under the assumption of instant Q-switching and uniformity of radiation except in the longitudinal direction. Numerical solutions of the equations were found and analysed. We demonstrate the influence, on generation characteristics, of the most important parameters, such as the effective nonlinearity, the initial level of population inversion, the feedback of the Stokes wave and the group mismatch between a Stokes and a pump wave. Optimum generation conditions are determined. Possibilities of the method are discussed for the generation of a) giant pulses which are controllable with regard to carrier frequency and duration but are unachievable with other methods, b) Stokes pulses of very small duration and high energy having sharp trailing edges, and c) analogous polariton pulses in the middle and far infrared range. The generation using a number of polariton branches in LiNbO3 was considered as an example. Calculations are in qualitative agreement with experimental data.
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  • 54
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    Applied physics 17 (1978), S. 211-232 
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    Notes: Abstract Physical principles, new ways and means of creation, schemes, characteristics and features of efficient high-power tunable pulse Raman lasers, operating in the near and middle ir are reviewed. The paper includes: tunable dye and Nd lasers as pump sources; promising active media and their optimal excitation methods; optical systems for producing spatially homogeneous pumping; the physics of Raman oscillators and their practical schemes, efficient high pulse energy liquid N2 and compressed H2 Raman oscillators, covering several bands in the range between 1.4 and 9.2 μm; the physics and construction of efficient tunable Raman amplifiers-convertors, amplifying in the saturation regime of spontaneously scattered or beforehand produced and collimated external Stokes signals, obtained in the spectral range between 0.83 μm and 18 μm. Raman laser using a, so-called, broadband pump where the linewidth of pumping light is broader than the spontaneous scattering linewidth, are also discussed. Features of both amplification and oscillation regimes of such broadband pumped Raman lasers are reported, and conditions for the efficient frequency conversion are determined.
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  • 55
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    Notes: Abstract Design and operating caracteristics of high pulse repetition rate NH3 laser producing up to 20 W of average output power are described. The NH3 laser, operating in the 12–13 μm region was optically pumped with a high pulse repetition rate TEA CO2 laser. Dependences of the NH3 laser output on the pump energy, ammonia and buffer gas pressures and pulse repetition rate have been studied. The conversion efficiency of up to 16% has been received.
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  • 56
    ISSN: 1432-0630
    Keywords: 35 ; 42.55 ; 42.68
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    Notes: Abstract We report the first accurate measurements of the transition strengths and linewidths of the 00o2 9.4 μm sequence lines of CO2. This sequence band is found to be very similar to the regular 00o1 laser band, except for an experimentally determined factor of 1.89±0.12 increase in transition strength (if the CO2 molecule is treated as a simple harmonic oscillator the theoretical increase in transition strength is 2.0). The laser absorption spectrometer used for these measurements can detect absorption coefficients in CO2 of ≈10−7 m−1, and we discuss the feasibility of using this sensitivity to monitor rare isotopic forms of CO2.
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  • 57
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    Applied physics 19 (1979), S. 243-245 
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    Notes: Abstract Stable step-tunable simultaneous double-wavelength emission from any branch combination of the 9.6 and 10.6 μm bands of a cw CO2 laser is reported in which the relative strengths of the two signals may be controlled.
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  • 58
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    Applied physics 18 (1979), S. 177-181 
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    Keywords: 42.55 ; 42.65 ; 33
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    Notes: Abstract We have studied experimentally stimulated Raman scattering and 4-wave-interaction processes occuring in hydrogen gas, which is excited by a Nd:YAG-pumped dye laser. The tuning ranges of the various Stokes and anti-Stokes lines, which are generated with high efficiency, cover the spectrum from 185 to 880 nm without a gap.
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  • 59
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    Applied physics 20 (1979), S. 129-134 
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    Keywords: 42.55 ; 33 ; 82.50
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    Notes: Abstract Collisional coupling between theB, C, andD states of KrF is measured in a discharge pumped KrF laser. Detection of the time resolved populations in the three states via measurement of the side fluorescence in theB→X, C→A, andD→X bands is used to record the collisional relaxation from theC andD state to theB state during laser emission. The experimentally determined limits for the collisional coupling times are τB-C≦1 ns and τB-D,τC-D〈20 ns at total pressures of 2 bar. Investigation of theB→X fluorescence band shows that the vibrational manifold of theB state is not thermalized during laser emission. TheV-V,T coupling time is estimated to be τV-V,T=4±2 ns. The influence of collisional coupling on energy extraction in the KrF laser is discussed.
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    Notes: Abstract An analytical treatment of the ultrashort-pulse generation in a solid-state laser is given taking into account gain saturation. The probability for the breakdown of the picosecond-pulse evolution caused by the amplification depletion is calculated. The influence of the active medium saturation on the satellite-pulse probability is investigated. Both probabilities characterize the mode-locking behaviour of the laser system and are calculated for various laser parameters to find an optimum laser regime.
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    Applied physics 19 (1979), S. 127-130 
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    Notes: Abstract The possibility of using stimulated emission from the recombination of electron-positron pairs for obtaining coherent γ-rays is considered. The critical number of pairs needed for the process is calculated.
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    Applied physics 19 (1979), S. 359-361 
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    Notes: Abstract This paper describes a 1 m-long CW HCN discharge laser with a hollow dielectric rectangular discharge tube of 5×20 cm2 cross-section. For optimum working conditions, the characteristics of the amplifying medium have been made constant over the cross-section, by using an additional magnetic field. Then, the unsaturated gain for the 337 μm line is 6.8% m−1. It is shown to be dependent on the smaller dimension of the cross-section rather than on the other dimension. By using the tube as a waveguide, laser output power of 1 Watt might be obtained with a discharge length of 4 m, instead of the 12m-long discharge required to get the same output power from a cylindrical waveguide laser.
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    Applied physics 20 (1979), S. 257-259 
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    Keywords: 87 ; 42.55
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    Notes: Abstract Selective electronic excitation of single kinds of DNA bases were performed with dye lasers. Different DNA-dye-complexes were used and the selective excitation could be proved by the varying strength of the interaction between the bases and the dye molecules.
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    Applied physics 20 (1979), S. 261-264 
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    Notes: Abstract The method of Stimulated Mandelshtam-Brillouin Scattering (SMBS) is utilized in a powerful laser to obtain better transverse beam quality by phase conjugation. The principle is explained, and the conclusions are substantiated by experimental results.
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  • 65
    ISSN: 1573-4889
    Keywords: oxidation ; nickel-chromium alloys ; Group III–V elements ; reactive minor additions
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    Notes: Abstract The corrosion of a number of experimental ternary Ni-15 wt. % Cr-0.5wt. %X alloys (where X= Y, La, Ce, Sm, Th, U, Zr, or V) has been assessed in pure oxygen at 900° C for periods of exposure up to 450 hr, and compared with the behavior of an Ni-15% Cr control alloy. It has been established that while all of the alloys oxidize in accordance with a protective, approximately parabolic regime, considerable differences in oxidation rates are exhibited. In particular, additions of La, Ce, and Th bring about progressively enhanced rates of oxidation relative to the binary alloy, whereas Y, Sm, V, U, and Zr effect increasingly reduced rates of oxidation in the order given. The rate constant for the Th-bearing alloy is about two orders of magnitude larger than that for the alloy containing Zr. Such differences in behavior seem to be associated with subtle variations in the morphology/composition of the corrosion products from alloy to alloy. The observations are considered in the light of earlier published literature concerning the effects of rare-earth and other reactive elements on the oxidation behavior of Ni/Cr alloys.
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    Oxidation of metals 10 (1976), S. 189-223 
    ISSN: 1573-4889
    Keywords: oxidation ; platinum ; platinum-aluminum alloys ; alumina (Al2O3) ; oxide-scale adhesion
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    Notes: Abstract The development, growth, and adhesion of α-Al2O3 scales on platinum-aluminum alloys containing between 0.5 and 6 wt.% aluminum have been studied at temperatures in the interval between 1000 and 1450° C. The morphologies and microstructures of the α-Al2O3 scales were found to be influenced by the temperature, oxygen pressure, and the microstructures of the alloys. The oxidation rates of the alloys appeared to be controlled by transport of oxygen along grain boundaries in the α-Al2O3 scales. The α-Al2O3 scales adhered to the platinum-aluminum substrates even after extensive periods of cyclic oxidation. The good adhesion of the α-Al2O3 may result from mechanical keying of the oxide to the alloys due to the development of irregular oxide-alloy interfaces.
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    Oxidation of metals 10 (1976), S. 277-289 
    ISSN: 1573-4889
    Keywords: alloy ; iron ; aluminum ; silicon ; oxidation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Silicon or chromium can be used as an oxygen getter in iron-aluminum alloys to prevent the internal oxidation of aluminum. This suppresses the formation of the iron oxide nodules that tend to destroy binary iron-aluminum alloys during high-temperature oxidation. Alloys of iron containing aluminum and silicon in varying proportions were heated in flowing air for 50 hr at 1093°C. Of the alloys tested, one containing 6% aluminum and 1 % silicon was the most resistant to oxidation.
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    Oxidation of metals 10 (1976), S. 311-327 
    ISSN: 1573-4889
    Keywords: defect structure ; CoO ; oxidation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The total concentration of point defects and deviation from stoichiometry in Co1-yO have been determined experimentally as functions of temperature and equilibrium oxygen pressure in the temperature range 1000–1250°C and oxygen pressure range 10−3-1 atm. This total concentration of defects has also been calculated from known values of the coefficients of chemical diffusion and tracer self-diffusion of cobalt. The results of the two methods agree well. It has been found in the investigated range of temperature and oxygen pressure that the defect structure of cobaltous oxide is composed not only of defects due to deviation from stoichiometry, singly ionized cation vacancies, and an equivalent amount of electron holes, but also of intrinsic defects, probably of the Frenkel type.
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    Oxidation of metals 10 (1976), S. 341-345 
    ISSN: 1573-4889
    Keywords: α-Al2O3 ; platinum ; oxidation ; adhesion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The influence of externally located platinum on the isothermal stability of α-Al2O3 scales formed at high temperatures has been examined. It has been observed that a nickel-base alloy forms an external scale of α-Al2O3 during oxidation at 1200°C, but this scale breaks down isothermally, enabling a faster-growing Cr2O3-rich scale to develop. However, in the presence of platinum metal alongside the specimen in the furnace hot zone, the breakdown of the α-Al2O3 scale is postponed for a substantial period of time. It appears that platinum, as the volatile species PtO2, is incorporated into the growing α-Al2O3 scale where it either influences the stress relief mechanism at temperature or reduces oxidation growth stress generation and thus significantly enhances the isothermal stability of the scale.
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    Oxidation of metals 10 (1976), S. 377-401 
    ISSN: 1573-4889
    Keywords: oxidation ; iron ; Mössbauer ; electron re-emission ; ERM spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The results of an electron re-emission Mössbauer (ERM) spectroscopy study of the oxidation of metallic Fe at temperatures from 150 to 500°C in pure oxygen ( $${\text{p}}_{{\text{O}}_{\text{2}} } \approx {\text{ }}10$$ Torr) are presented. The oxidized samples were prepared from a metallic Fe sample enriched to 70% in the Mössbauer isotope Fe57 and the oxidation kinetics were determined volumetrically. Scanning electron microscopy was employed to characterize the morphology of the oxide films. The hematite, magnetite, and total-oxide thicknesses were determined from the ERM spectra using a theory recently developed in this laboratory, and the results were found to agree well with the measured oxygen content of the oxide films. For Fe and Fe-base alloys it is shown that the ERM technique is most useful in the oxide-thickness range of approximately 20–3000 Å within that range, oxide-phase identifications and thickness determinations are perhaps more readily determined by ERM spectroscopy than by any competing technique. In particular, the ERM measurement is nondestructive, and no supplementary measurements (such as surface-roughness determinations) or special sample preparations (such as oxide-film stripping) are required
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    Oxidation of metals 11 (1977), S. 57-62 
    ISSN: 1573-4889
    Keywords: oxidation ; scale growth
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Equations are presented to modify the classical theoretical expressions for the parabolic rate constant for the case in which the scale has a large composition range and a large variation in molar volume. The modifications appear as simple averages, together with a factor f.Evaluation of f for some hypothetical cases shows that it is near unity unless the composition gradient has an extreme deviation from linearity.
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  • 72
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    Oxidation of metals 11 (1977), S. 193-198 
    ISSN: 1573-4889
    Keywords: oxidation ; scaling ; wustite ; magnetite ; iron
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The theory of the growth of two oxide layers by Yurek et al. has been applied to the oxidation of iron at 1100° C. The theoretical parabolic rate constants for the simultaneous growth of the two oxide layers were calculated from radioactive tracer diffusion coefficients for wustite and magnetite. Good agreement was found between the theoretical and experimental values of the ratio of scale thicknesses.
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    Oxidation of metals 12 (1978), S. 227-245 
    ISSN: 1573-4889
    Keywords: oxidation ; sulfidation ; iron-chromium-nickel alloy ; thermochemical diagram ; parabolic rate constant
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Oxidation-sulfidation studies of Fe-Cr-8Ni alloys with 4, 12, and 22 wt. % Cr were conducted at 750 and 875°C in multicomponent gas mixtures that contained CO, CO2, CH4, H2, and H2S. The reaction processes resulted in parabolic kinetics. A chromium concentration in the range 0–12 wt. % in the alloy had a negligible effect on the parabolic rate constant; however, the rate constant for the alloy with 22 wt. % Cr was significantly lower. For a given sulfur partial pressure, the oxygen partial pressures required for the formation of a continuous oxide layer in an Fe-22Cr-8Ni alloy were ∼102 to 103 times those calculated for Cr-Cr2O3 equilibrium at temperatures of 875 and 750° C, respectively.
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    Oxidation of metals 12 (1978), S. 451-471 
    ISSN: 1573-4889
    Keywords: HCl gas ; H2O vapor ; Ni-Cr-Al alloy ; oxidation ; hot corrosion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Moist air containing HCl gas caused the oxide formed on a Ni-Cr-Al alloy at 850°C to crack during the early stages of growth, and extensive blistering and spalling occurred on cooling. In dry air containing HCl gas no oxide cracking was observed at temperature although the oxide blistered and spalled on cooling. In dry or moist air free from HCl an adherent protective oxide formed which did not spall on cooling. The oxide cracking at temperature has been attributed to the production of hydrogen by reaction of Cr and Al in the alloy with water vapor and the removal of NiO as NiCl2 by reaction with HCl gas. Hydrogen produced by reaction of water vapor or HCl with Cr or Al dissolved in the alloy at temperature, but on cooling the hydrogen was released, causing the oxide to blister and spall. Preoxidation of the alloy in HCl-free atmospheres eliminated these effects of HCl gas in short-term isothermal tests.
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    Oxidation of metals 9 (1975), S. 45-67 
    ISSN: 1573-4889
    Keywords: oxidation ; hot corrosion ; nickel alloys ; composites
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The oxidation and hot corrosion behavior of a tungsten-fiber, reinforced Ni~ 20Cr alloy has been examined under the following exposure conditions: (a) pure oxygen at 1 atm pressure; (b) sulfidation in H2–10 %H2S; (c) presulfidation in H2–10 %H2S followed by oxidation in oxygen; and (d) oxidation in 1 atm oxygen after precoating with approximately 1 mg/cm2 of Na2SO4. Rapid oxidation of the tungsten fibers causes considerable distortion of the matrix and catastrophic degradation of the matrix follows. Inter diffusion between the matrix and the fibers is also important. During sulfidation, only the matrix forms sulfides, the fibers remaining unaffected. Consequently, presulfidation, although having a dramatic effect on the oxidation of the matrix does not have a damaging effect on the fibres. Equally, the presence of sodium sulfate is not critical, although severe oxidation of the exposed tungsten fibers is still observed.
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    Oxidation of metals 9 (1975), S. 275-305 
    ISSN: 1573-4889
    Keywords: oxidation ; Ni-Cr alloys ; rare-earth oxide dispersion ; dispersion-strengthened alloys
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The oxidation behavior of Ni-20%Cr alloys containing approximately 3 vol.% Y2O3, ThO2, and A12O3 as dispersed particles has been examined in the temperature range 900 to 1200° C in slowly flowing oxygen at 100 Torr. The results show that the oxidation behavior of the Y2O3-, ThO2-, Al2O3-, and Ce02-containing alloys is very similar and that some anomalies in the behavior of the ThO2-containing alloy might be explained by the slower rate of chromium diffusion in this coarse-grained alloy. Two Al2O3-containing alloys were studied. One with a relatively coarse dispersoid size behaved in a manner analogous to a dispersion-free Ni-30% Cr alloy at 1100°C. The other alloy contained a dispersion of fine Al2O3 particles and behaved exactly like the Y2O3-containing alloy at 1000 and 1100°C, but at 1200° C oxidized at a faster rate. It has been shown that the adherent scales on dispersion-containing alloys have a stabilized fine grain size, whereas the nonadherent scales on dispersion-free alloys undergo grain growth.
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    Oxidation of metals 9 (1975), S. 415-425 
    ISSN: 1573-4889
    Keywords: vanadium carbide ; vanadium oxycarbide ; oxidation ; parabolic rate law ; cubic rate law ; chemisorption
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The oxidation of an oxycarbide of vanadium, VO0.6C0.7, and of a vanadium carbide, VC0.98, was studied athermally up to temperatures of 800° C and isothermally between 400 and 580° C at oxygen pressures ranging from 10−2 to 1 atm. The oxycarbide followed the parabolic rate law below 450° C with V2O5 forming as the only reaction product. The activation energy was 49 kcal/mole. VC0.98 did not form an oxide in this temperature range, but rather dissolved oxygen, the activation energy being 26.6 kcal/mole. No oxygen pressure dependence on the kinetics was found for either sample in this temperature range. Both samples followed the cubic rate law during oxidation in the range of 500–580° C during which V2O5 formed. There was a P1/3 dependence and the activation energy was the same for both materials, 51 kcal/mole. The cubic rate law and the positive pressure dependency (rather than an anticipated negative dependency) were attributed to an electric field associated with oxygen ions chemisorbed on a thin layer of V2O5.
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    Oxidation of metals 9 (1975), S. 459-472 
    ISSN: 1573-4889
    Keywords: Cr ; oxidation ; kinetics ; Cr2O3 grain size ; short-circuit diffusion ; surface ; preparation ; Fe-Cr
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Cr was oxidized in 1 aim O2 at 980, 1090, and 1200°C. ElectropolishedCr and some orientations of etched Cr oxidize rapidly and develop compressive stress in the growing Cr2O3; other orientations oxidize slowly, apparently free of stress. SEM examination of fracture sections shows that the thick oxide is polycrystalline whereas the thin oxide on etched Cr is monocrystalline. It is deduced that the monocrystalline oxide grows by lattice diffusion of cations outward, and the polycrystalline layer by the two-way transport of cation diffusion outward and anion diffusion inward along oxide grain boundaries. The consequent formation of oxide within the body of the polycrystalline layer generates compressive stress and leads to wrinkling by plastic deformation. The activation energy for oxidation of Cr by cation lattice transport is 58 kcal/mole. Polycrystalline Cr2O3 forms on Fe-26Cr alloy, whether electropolished or etched; oxidation is accordingly rapid and accompanied by compressive stress.
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    Oxidation of metals 10 (1976), S. 85-95 
    ISSN: 1573-4889
    Keywords: boron carbide ; oxidation ; kinetics ; chromatography method
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Thermogravimetry and gas-adsorption chromatography were used to study the kinetics of formation of solid and gaseous products during the hightemperature oxidation of compact boron carbide in oxygen at 740 Torr. Oxidation resistance was observed at temperatures up to 1200°C. The main oxidation products were B2O3 and CO2. Oxidation was paralinear; the carbon consumption exceeded the consumption of boron as compared to the ratio of these elements in the compound B4C. This difference resulted in carbon depletion of the carbide layer in the substrate near the scale〉.
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    Oxidation of metals 10 (1976), S. 255-276 
    ISSN: 1573-4889
    Keywords: Zircaloy-4 ; zirconium ; alloy ; oxidation ; microstructure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The ZrO 2 scales formed on Zircaloy-4 PWR tubes during corrosion in steam in the temperature range of 1000–1300°C have been found to contain a metallic phase that is relatively rich in Sn. The precise composition of the metallic phase has not been determined. Most of the metallic phase is located in a line of metallic particles, which is oriented parallel to the alloy-scale interface and located near the center of the scale. The exact morphology of the scale on either side of the particle line has not been identified. The oxide between the metallic particles and the scale-steam interface contains very little Sn, except for a narrow zone adjacent to the scale-steam interface, which was formed in the beginning of the reaction. It appears that the scale between the metallic particles and the alloy-scale interface consists of thin columnar grains of ZrO 2 with a very fine metallic phase probably located at the ZrO 2 grain boundaries. The experimental evidence presently available indicates that the metallic phase exists in the scales at the reaction temperature. If the metallic particles were rich enough in Sn, then a liquid metallic phase would exist in the oxide during the reaction. Kinetic studies demonstrate that these particles move with respect to the scale-steam interface toward the center of the alloy during the course of the oxidation reaction. It appears that the presence of the line of metallic particles could, under certain conditions, markedly influence the mechanical properties of the oxide scales formed on Zircaloy-4.
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    Oxidation of metals 11 (1977), S. 23-56 
    ISSN: 1573-4889
    Keywords: oxidation ; carburization ; carbonaceous gases ; superalloys ; stainless steels ; film formation ; structure of oxide scales ; preoxidation ; metal dusting
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Formation and deterioration of oxide films on several contemporary high-temperature alloys was studied in various carbonaceous gas atmospheres. Scanning electron microscopy and metallographic examination were applied to films on Fe-Cr-Ni and Ni-Cr-Al type alloy compositions exposed in CH 4/H2 and CO/CO2 atmospheres at temperatures up to 900° C and pressures up to 900 psi (6.2 × 106 N/m2). The effects of various preoxidation treatments were evaluated. Reduction of certain oxide phases is observed to promote catalytic gas decomposition. Al2O3 components in the films are observed to be stable under the reducing conditions experienced. Carbon uptake by various alloys is found to be quite sensitive to surface finish, with an observed increase in penetration with surface roughness.
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    Oxidation of metals 11 (1977), S. 225-239 
    ISSN: 1573-4889
    Keywords: tantalum ; oxidation ; high temperature ; kinetics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The oxidation of tantalum in oxygen-nitrogen and oxygen-inert gas mixtures at925°C has been studied. The oxygen pressure was close to 0.5 atm in all experiments, and partial pressures of the second component of from 0 to 180 Torr were employed. Spherical specimens were used to provide quantitatively significant kinetic data. A model has been proposed which suggests that the oxygen pressure at the reaction interface close to the metal surface is lower than the external pressure because of the finite permeability of the porous outer oxide layer, and that the inert gas effectively reduces the permeability. The model gives good quantitative agreement with the experimental results.
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    Oxidation of metals 12 (1978), S. 1-22 
    ISSN: 1573-4889
    Keywords: NaCl vapor ; Ni-Cr-Al alloy ; oxidation ; hot-salt corrosion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A thin protective oxide formed on a Ni-19.7 Cr-2.4 Al alloy in air at 850°C. Microstructural examination of stripped films showed that the oxide was duplex with an inner chromium-rich layer of NiCr2O4 + Cr2O3 with probably some NiAl2O4 + Al2O3, and an outer nickel-rich layer, principally NiO. The oxide grew faster in the presence of NaCl and it differed significantly in microstructure and composition from a very early stage. The thicker regions of the oxide assumed regular polyhedral shapes in air + NaCl, rather than the irregular nodular shape exhibited in clean air, as well as becoming richer in chromium. The results suggest that chloride vapor increases cationic mobility in the oxide. It is proposed that Cl− ions are incorporated in the oxygen close-packed lattice, thereby increasing ionic mobility in Cr2O3.
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    Oxidation of metals 12 (1978), S. 83-110 
    ISSN: 1573-4889
    Keywords: oxidation ; iron ; chromium ; Fe-9% Cr alloy ; Auger electron spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The oxidation or general corrosion behavior of metals at pressures of 1 atm or more is usually investigated by oxidizing samples under prescribed conditions and then subsequently characterizing the surface produced using one or more of the experimental methods available. This article describes a method which obviates the necessity of transferring samples from the oxidizing environment to the instrument for analysis, is nondestructive, and monitors the oxidizing surface in situ. The oxidation of iron, chromium, and a 9% chromium-iron alloy in carbon dioxide at atmospheric pressure and at 773°K is described. The surfaces of these materials were analyzed by Auger electron spectroscopy during exposure to the gas. Spectra and diagrams illustrating the variation in surface composition as oxidation proceeded are shown and possible mechanisms for the oxidation reactions are briefly discussed. The formation of the surface oxide on iron and on the 9% Cr-Fe alloy appears to follow very similar paths under the conditions of oxidation used. In all the materials studied trace impurities such as sulfur participated in the oxidation reactions.
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    Oxidation of metals 13 (1979), S. 181-195 
    ISSN: 1573-4889
    Keywords: copper-manganese alloys ; oxidation ; scale composition
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The oxidation behavior of copper-manganese alloys (2–35 wt. % Mn) in pure oxygen at 760 Torr was investigated at 100° intervals between 550 and 850°C. Gravimetric measurements of the oxidation kinetics have been combined with microstructural studies of the reacted samples in order to evaluate the reaction mechanisms. The scales formed on Cu-2Mn, Cu-5Mn, Cu-10Mn are always composed of three different layers; in any case manganese is present only in the inner layer. The scales formed on Cu-20Mn and Cu-35Mn are composed of two layers, both containing manganese, with a more Cu-rich outer layer. In all the samples internal oxidation in combination with external scale formation is observed.
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  • 86
    ISSN: 1573-4889
    Keywords: Cu-Si alloys ; oxidation ; kinetics ; silica
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    Notes: Abstract The oxidation of Cu-Si alloys (containing up to 4.75 wt. % Si) in $${\text{p}}_{O_2 } $$ =0.01 atm from 800 to 1000°C has been investigated using thermogravimetry and other techniques. A 0.04% Si alloy followed a parabolic oxidation law with a rate similar to that of pure Cu. As the Si concentration increased the rate decreased and became irregular owing to SiO2 particles or flakes at the alloy-scale interface. It is considered that sintering of SiO2 particles and rupture of the sinter because of contraction during sintering are responsible for the irregular kinetics. A SiO2 layer forms directly on the 4.75% Si alloy which oxidizes uniformly. The SiO2 was always amorphous. In pure CO2 a similar pattern of amorphous SiO2 particles, flakes, and layers occurs.
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    Oxidation of metals 13 (1979), S. 283-298 
    ISSN: 1573-4889
    Keywords: oxidation ; surface alloys ; Fe-Cr alloys ; iron ; kinetics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The oxidation behavior of several surface and bulk Fe-Cr alloys and iron at 300°C and 4×10−6 Torr oxygen was studied. The surface alloys were fabricated by implantation of 25 keV Cr ions into the outermost 300Å of polycrystalline iron samples. The oxide thickness as a function of oxygen exposure was obtained using proton-excited X-ray analysis, and composition profiles of oxide films were obtained using Auger electron spectroscopy and ion sputtering. The addition of Cr to Fe by surface and bulk alloying caused the oxidation rate to decrease and changed the oxidation kinetics from parabolic (for Fe) to logarithmic (for Cr concentrations ≥4.7at.%). Interpretation of the data in terms of simple oxidation theories indicates that the Cr additions may reduce the oxidation rate by altering the electronic properties of the metal-oxide interface.
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    Oxidation of metals 13 (1979), S. 311-330 
    ISSN: 1573-4889
    Keywords: oxidation ; oxide maps ; alloying additives ; Fe-Ni-Al alloys
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The oxidation behavior of iron-nickel-aluminum alloys containing 0–40 wt.% nickel and 0–30 wt.% aluminum has been investigated at 600 and 800° C. Through the construction of “oxide maps” it can be shown that three possible oxide morphologies may exist: Alloys containing less than approximately 5 wt.% aluminum form scales consisting of predominantly Fe2O3 and spinel; alloys with between 5 and 10 wt.% aluminum form Al2O3 scales interspersed by Fe2O3 nodules, and alloys with greater than 10 wt.% aluminum form predominantly γ-Al2O3 scales.
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    Oxidation of metals 13 (1979), S. 223-236 
    ISSN: 1573-4889
    Keywords: nickel ; oxidation ; surface reactions ; X-ray photoelectron spectroscopy
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract X-ray photoelectron spectroscopy has been used to study the oxidation of polycrystalline nickel metal. The results indicate that the oxidation process takes place in three stages; associative adsorption of molecular oxygen, followed by the combination of oxygen atoms with surface nickel atoms and, ultimately, the formation of bulk oxide. At room temperature only the first two stages can be detected. For exposures below 1 L the O 1s photoelectron spectrum is considered to be characteristic of an associatively adsorbed oxygen species, but for exposures above this value evidence for the formation of a monolayer of “NiO” is suggested by the development of an O 1s peak at 529.9 eV. Incorporation of oxygen into the nickel lattice is observed at temperatures 〉500°K. The activation energy for this place-exchange process was estimated at 1.80±0.06 eV.
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    Oxidation of metals 13 (1979), S. 255-272 
    ISSN: 1573-4889
    Keywords: oxidation ; Fe-C ; graphite deposition ; nonadherent oxide ; kinetics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The oxidation of Fe-C alloys containing 0.5 and 1.0% C was studied in 1 atm O2 at 700° C. The oxidation rate is considerably slower than for pure Fe. The oxide scale formed is detached, multilayered, and overoxidized, containing little or no FeO. A thin film of graphite was identified at the metal-oxide interface by electron diffraction. It is proposed that the slow oxidation and abnormal scale are caused by a residue of graphite left at the metal surface from the oxidation of Fe3C. This inhibition of the oxidation of Fe by carbon at 700°C is in contrast to the stimulation observed at 500°C.
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    Oxidation of metals 9 (1975), S. 69-97 
    ISSN: 1573-4889
    Keywords: oxidation ; decarburization ; Fe-C alloys ; effect of humidity ; effect of microstructure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Isothermal oxidation treatments were carried out on an Fe-C alloy (0.4 % C): (a) in almost dry air around A1, and also with an Fe-C alloy (0.5% C) and IRSID pure iron; (b) in dry air ( $${\text{P}}_{H_2 O} \simeq 10^{ - 5} $$ nm Hg); (c) in almost dry air(1–2% water vapor) at 700° C; and (d) in moist air (31% water vapor). Theresults are as follows: The rate of oxidation at a temperature below A1depends chiefly on alloy structure, i.e., on thermal history of the sample.The water vapor content of the air strongly influences the scale adherenceas well as the rate of oxidation of the Fe-C alloys below A1, but has virtuallyno effect on the rate of oxidation of pure iron. Under the same conditions, avery light decarburization of metal occurs in air, whereas no decarburizationoccurred in air with 13% water vapor.
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    Oxidation of metals 9 (1975), S. 225-257 
    ISSN: 1573-4889
    Keywords: oxidation ; eutectic alloys ; refractory metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The oxidation behavior of the directionally aligned eutectic alloy, TaC-Co50B, has been examined between 600 and 1155°C. Parabolic oxidation behavior, isotropic in nature, is found to 800°C. Above 800°C, the oxidation behavior is no longer either parabolic or isotropic. The interaction between the Co matrix alloy and the TaC fibers adjacent to the oxidizing interface is reported as a function of temperature in oxidation.
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    Oxidation of metals 9 (1975), S. 215-223 
    ISSN: 1573-4889
    Keywords: cation diffusion ; oxidation ; metal partition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract An alternative mass balance at the alloy-scale interface is proposed for the Wagner theory of binary alloy oxidation. A simple relation between the bulk composition of the alloy and the scale composition at the alloy-scale interface, ξ′, is derived in terms of the transport properties of the scale and the limit of application of the relation defined. There is good agreement between calculated and measured values of ξ′.
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    Oxidation of metals 9 (1975), S. 427-440 
    ISSN: 1573-4889
    Keywords: cobalt ; cobalt-aluminum alloys ; oxidation ; thermal cycling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Most Ni and Co-base alloys used for high-temperature service rely on the production of a compact, stable Cr2O3 scale for their oxidation resistance. However, as operating temperatures have risen above 900–950° C, the loss of Cr2O3 as the volatile CrO3 has led to an inadequate life span of these alloys, particularly in rapidly flowing, turbulent gas streams. As a result of this, it has been necessary to examine the possibility of using Al2O3 as the protective scale. Al2O3 has a lower growth rate than Cr2O3, it is nonvolatile, and, unlike Cr-containing systems, it is less likely to form compound oxides such as spinels. In this study, the amount of Al which must be present in the Co-Al system to form a continuous layer of Al2O3 in the temperature range 800–1000° C has been determined. The quantity was found to rise from about 7–10 wt. % at 800° C to 10–13 wt. % at 900° C and 13 wt. % at 1000° C. Notice has also been taken of the abilities of the alumina-forming alloys to re-form a protective oxide in the event of spalling, blistering, or any other disruptions of the scale, and some “cyclic-oxidation” checks have been conducted on the Co13Al alloy at 900 and 1000° C.
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  • 95
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    Oxidation of metals 10 (1976), S. 97-103 
    ISSN: 1573-4889
    Keywords: silicon carbide ; oxidation ; molecular oxygen ; glow-discharge oxygen plasma ; kinetics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The oxidation kinetics and structure of the oxide scales formed on high-density SiC were studied in molecular oxygen at 740 Torr and in a glow-discharge oxygen plasma at 0.1 Torr at temperatures of 1000, 1100, and 1200°C. The monatomic oxygen formed by the glow discharge markedly increased the reaction rate and the vaporization of some of the oxidation products. The marked differences in kinetics suggest that the rate-controlling step during oxidation in molecular oxygen is the dissociation of adsorbed diatomic oxygen to the monatomic species. Films formed in molecular oxygen were mostly amorphous SiO2 with small inclusions of SiC and graphite, whereas films formed in dissociated oxygen were primarily amorphous SiO2 containing SiO, S2O3, and the coesite form of SiO2.
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  • 96
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    Oxidation of metals 11 (1977), S. 91-106 
    ISSN: 1573-4889
    Keywords: oxidation ; cyclic ; spallation ; stress
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Several alloys (one iron base and five nickel base) were cyclically oxidized in a series of tests in which the higher temperature (1100 or 1200° C) of the cycle was fixed at a level to allow ample oxidation in reasonable time and the lower temperature was variable to allow cycle temperature differences (ΔT s ) of up to 1400°C. The alloys oxidized included those which formed simple oxides such as Al2O3 or Cr2O3, as well as those which formed complex scales. Cooling rates were relatively low to minimize thermal shock effects. Each cycle consisted of 1 hr at the higher temperature and 1/2 hr at the lower temperature. Samples were tested up to 370 cycles. The extent of attack was determined by specific weight change which was continuously monitored. For all nickel alloys, as ΔT increased the extent of spallation increased. This effect was attributed to thermal expansion mismatches between the oxide and the nickel substrate. The FeCrAl alloy was not sensitive to ΔTand resisted spalling at ΔT levels to 1400°C. FeCrAl, and the Al2O3 scale which forms on it, have thermal expansion coefficients which are substantially more alike than any of the other oxide-metal combinations tested.
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  • 97
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    Oxidation of metals 12 (1978), S. 215-225 
    ISSN: 1573-4889
    Keywords: oxidation ; Fe-Ni alloys ; kinetics ; scale morphology ; EPMA
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The oxidation of an Fe—19.34 wt. % Ni alloy in dry CO2 has been studied at 700—1000°C using thermogravimetry, metallography, and EPMA. Weight gains for oxygen consumption followed a linear-parabolic-linear sequence at all temperatures. During the initial linear stage the scale consisted mainly of magnetite and the activation energy of 133±25 kJ · mole−1 is considered to be due to dissociation of CO2 into CO and adsorbed oxygen on the outer magnetite surface. During the parabolic oxidation stage a continuous Ni-rich layer containing ∼ 70% Ni forms a barrier to the diffusion which has an activation energy of 192±79 kJ · mole−1. The breakdown of the barrier layer causes a return to linear kinetics with an activation energy of 138±42 kJ · mole−1 for dissociation of CO2 on the outer surface. During the final linear stage there is pronounced general and intergranular subscale formation. Detailed information is presented of the Ni redistribution and concentrations during oxidation and its correlation with the kinetics and morphology.
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  • 98
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    Oxidation of metals 12 (1978), S. 35-66 
    ISSN: 1573-4889
    Keywords: CoCrAl ; oxidation ; oxide scale adherence ; rare-earth effect ; hafnium ; yttrium
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The effect of small amounts of yttrium (up to 1 wt. %) and hafnium (up to 1.5 wt.%) on the oxidation behavior of Co-Cr-Al alloys in the temperature range 1000–1200°C for times up to 1000 hr in air has been studied. The major portion of the study has been concerned with Co-10Cr-11Al base alloys. Both isothermal and cyclic tests have been carried out; the cycle used consisted of 20 hr at temperature, followed by cooling to room temperature. Both additions reduce the overall oxidation, Hf somewhat more so than Y. In part, this is due to the improved adhesion between scale and alloy reducing scale spallation at temperature, and in part due to possible modification of the Al2O3 grain size. The former factor is far more critical under thermal cycling conditions. Under isothermal conditions the oxidation rate increases with increasing Hf content with all but the 1.5 wt.% alloy oxidizing more slowly than the Hf-free alloy; increase in Y content has the reverse effect. Under thermal cycling conditions the 0.3 and 1.0 wt.% Hf alloys show the lowest overall weight gain. Metallographic evidence suggests that the improved scale adhesion is due principally to a pegging mechanism; the active elements promote the growth of intrusions of Al2O3 into the alloy. However, if the intrusions are too large, they can act as initiators of scale failure.
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  • 99
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    Oxidation of metals 12 (1978), S. 139-156 
    ISSN: 1573-4889
    Keywords: Rosenburg method ; oxidation ; CoO
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The Rosenburg continuous kinetic method is proposed for the determination of the parabolic rate constants of metal oxidation as a function of temperature and oxidant pressure. Using this method, it is possible to make numerous measurements in a continuous manner on a single metal sample left in situ in the furnace, thus eliminating systematic errors due to differences between samples. Moreover, using this method it is possible to determine directly from a given kinetic curve such important parameters as the coefficients of chemical diffusion and self-diffusion of the more mobile species in the studied compound and the total equilibrium defect concentration. The latter parameter has been inaccessible up to now by the experimental method. The limits of applicability of this method are given in the paper. As an example of this method, the kinetics of cobalt oxidation are investigated in the range of temperature 1000–1250°C and oxygen pressure 10−3−1 atm; the results compare favorably with those obtained by other authors. The method is, however, applicable to certain other systems, namely, metal oxides and sulfides.
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  • 100
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    Oxidation of metals 12 (1978), S. 173-181 
    ISSN: 1573-4889
    Keywords: oxidation ; hot corrosion ; sulfidation ; preoxidation ; scale penetration
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The transport of sulfur through growing scales may occur by chemical (solution and diffusion) or physical (gas molecule permeation) mechanisms. Both possibilities are examined theoretically for the case of NiO growing on nickel. Experiments are designed and carried out to establish which mechanism plays the major role in sulfur transport. The results indicate that the physical mechanism is likely to be predominant.
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