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  • 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry  (31)
  • 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism  (31)
  • Elsevier  (60)
  • Chinese Geoscience Union  (2)
  • Essen : Verl. Glückauf
  • Krefeld : Geologischer Dienst Nordhein-Westfalen
  • Oxford University Press
  • 2005-2009  (62)
Collection
Years
Year
  • 1
    Publication Date: 2021-06-25
    Description: We present the first helium isotope data for thermal waters and gas emissions on the islands of Terceira, Graciosa, Faial, Pico and Flores, as well as new data for Sao Miguel. The results allow us to track current mantle degassing associated with the Azores hot spot, to delineate its spatial distribution and to discuss its possible origin. As a general rule, we find that free gases tend to display somewhat higher 3He/4He ratio than groundwaters.We argue that this difference is likely due to radiogenic helium inputs to aquifers duringwater– rock interactions and, therefore, that gas phases are the fluid carriers with the most representative of mantle source signature. The measured 3He/4He ratios (normalized to the air ratio, Ra) range from lower-than-MORB values (5.23–6.07 Ra) on central Sao Miguel, to MORB values on Faial (8.53 Ra) and Flores (8.04 Ra) – located on either side of the Mid-Atlantic Ridge – and to plume-type values on Graciosa (11.2 Ra) and Terceira (13.5 Ra) where free gases also display ten times higher-than-MORB CO2/3He ratios (1.8–2.6×1010). Such a wide He isotopic range and its spatial distribution corroborate with available data for volcanic rocks, indicating that plume's head presently underlies the central part of the archipelago. The plume-type 3He/4He ratios on Terceira and Graciosa agree with geochemical and seismic evidence of a deep-rooted mantle plume feeding the Azores hot spot. Our finding that high 3He/4He ratios correspond to low 3He concentrations and high (arctype) CO2/3He values exclude a simple plume supply of 3He-rich primitive mantle. Instead, the simultaneity of both elevated CO2/3He and 3He/4He ratios is best explained by a 3He-rich contribution from the lower mantle diluted in a CO2-rich feeding plume that contains a recycled altered oceanic plate component. The alternative possibility of an enhanced time-integrated 3He/(U+Th) ratio in the Azores plume due to a greater compatibility of helium relative to U and Th during melting events is difficult to reconcile with the enriched pattern of volcanic rocks from the central islands. In any case, the Azores plume should derive from a mantle reservoir that could escape convective homogenization for a very long period of time, in agreement with subchondritic osmium isotopic ratios in volcanic rocks from the central islands of the archipelago.
    Description: Published
    Description: 70−80
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: hydrothemal fluids ; helium isotopes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2021-07-14
    Description: A quantitative analysis of planktonic foraminifera, coupled with petrophysical and paleomagnetic measurements and 14C AMS calibrations, was carried out on a deep core recovered in the Sardinia Channel (Western Mediterranean Sea), during the CIESM Sub2 survey, providing an integrated stratigraphic time-framework over the last 80 kyr. Significant changes in the quantitative distribution of planktonic foraminifera allowed the identification of several eco-bioevents useful to accurately mark the boundaries of the eco-biozones widely recognised in the Western Mediterranean records and used for large scale correlations. Namely, 10 eco-biozones were identified based on the relative abundance of selected climate sensitive planktonic foraminiferal species. Sixteen codified eco-bioevents were correlated with the Alboran Sea planktonic foraminiferal data and four climatic global events (Sapropel S1, Younger Dryas, Greenland Isotope Interstadial 1, Greenland Isotope Stadial 2, Heinrich event H1-H6) were recognized. The eco-bioevents together with the 14C AMS calibrations allowed us to define an accurate age model, spanning between 2 and 83 kyr. The reliability of the age model was confirmed by comparing the colour reflectance (550 nm%) data of the studied record with the astronomically tuned record from the Ionian sea (ODP-Site 964). A mean sedimentation rate of about 7 cm/kyr included three turbidite event beds that were chronologically constrained within the relative low stand and lowering sea level phases of the MIS 4 and 3. The deep-sea sedimentary record includes a distinct tephra occurring at the base of the core which dates 78 ka cal. BP. The paleomagnetic data provide a well-defined record of the characteristic remanent magnetization that may be used to reconstruct the geomagnetic paleosecular variation for the Mediterranean back to 83 kyr.
    Description: Published
    Description: 725 - 737
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Integrated stratigraphy ; Late Neogene marine record ; Eco-bio-events ; Reflectance 550 nm % ; Sardinia Channel ; Western Mediterranean ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2017-04-04
    Description: Quantifying the contribution of volcanism to global mercury (Hg) emissions is important to understand the pathways and the mechanisms of Hg cycling through the Earth's geochemical reservoirs and to assess its environmental impacts. While previous studies have suggested that degassing volcanoes might contribute importantly to the atmospheric budget of mercury, little is known about the amount and behaviour of Hg in volcanic aquifers. Here we report on detailed investigations of both the content and the speciation of mercury in aquifers of active volcanoes in Italy and Guadeloupe Island (Lesser Antilles). In the studied groundwaters, total Hg (THg) concentrations range from 10 to 500 ng/l and are lower than the 1000 ng/l threshold value for human health protection fixed by the World Health Organization [WHO (1993): WHO Guidelines for Drinking Water Quality- http://www.who.int/water_sanitation_health/GDWQ/index.htlm]. Positive co-variations of (THg) with sulphate indicate that Hg-SO4-rich acid groundwaters receive a direct input of magmatic/hydrothermal gases carrying mercury as Hg0 (gas). Increasing THg in a volcanic aquifer could thus be a sensitive tracer of magmatic gas input prior to an eruption. Since the complex behaviour and toxicity of mercury in waters depend on its chemical speciation, we carefully determined the different aqueous forms of this element in our samples.We find that dissolved elemental Hg0 (aq) and particulate-bound Hg (HgP) widely prevail in volcanic aquifers, in proportions that highlight the efficiency of Hg adsorption onto colloidal particles. Moreover, we observe that dissolved Hg0 aq and Hg(II) forms coexist in comparable amount in most of the waters, in stark contrast to the results of thermodynamic equilibrium modelling. Therefore, chemical equilibrium between dissolved mercury species in volcanic waters is either prevented by natural kinetic effects or not preserved in collected waters due to sampling/storage artefacts. Finally, we provide a first quantitative comparison of the relative intensity of aqueous transport and atmospheric emissions of mercury at Mount Etna, a very active basaltic volcano.
    Description: Published
    Description: 96-106
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: speciation ; volcanic aquifers ; total and dissolved mercury ; mercury cycling ; volatile budget ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2017-04-04
    Description: The geochemical monitoring carried out on fluids released in the Central Apennines (Umbria region) evidenced seismically-induced modifications of the physic-chemical parameters in all the released fluids, including some cold waters circulating in certain carbonate rocks that are exploited for drinking purposes. The results allowed us to recognize the presence of components of diverse origin that changed the chemical composition of the water. These components, potentially dangerous for human consumption, can be considered as being “secondary effects” on local aquifers, induced by crustal deformation. We would also stress the relationship between the circulating fluids and active tectonic structures, as we detected modifications in some springs that were apparently not located anywhere near the local faults. The temporal variations in the geochemical features of the investigated cold waters are related to the local faulting activity that occurs during seismogenesis. The geochemical monitoring that provided information on fault movements during the seismic crisis, is also able to give us information regarding faulting activity in its earlier stages.
    Description: Published
    Description: 709-729
    Description: 3.2. Tettonica attiva
    Description: N/A or not JCR
    Description: reserved
    Keywords: cold waters ; earthquakes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2017-04-04
    Description: Dynamic accumulation chamber methods have been extensively used to estimate the total output of CO2 released from active volcanic area. In order to asses the performance and reliability of a closed dynamic system several tests were carried out with different soil permeabilities and soil CO2 fluxes. A special device was used to create a constant one-dimensional CO2 flux through a soil column with a known permeability. Three permeabilities were investigated, ranging between 3.6 × 10− 2 and 3.5 × 10 μm2, as were several CO2 fluxes (ranging between 1.1 × 10− 6 and 6.3 × 10− 5 kg m− 2 s− 1). The results highlight that the accuracy of soil CO2 flux measurements strictly depends on the soil gas permeability and the soil CO2 flux regimen. Generally chamber measurements underestimate CO2 fluxes at low soil permeability and low soil CO2 fluxes, whereas appreciable overestimations occur for high permeability soil, especially for high soil CO2 fluxes. Other tests carried out with different settings for the measurement device, such as the chamber volume and the flux of the pump used to recirculate air through the chamber and the gas analyzer (recirculation flux), revealed a strong dependence of the closed dynamic chamber measurements on the recirculation flux. Low recirculation fluxes (0.2–0.4 l min− 1) decreased the performance of the measurement system, causing underestimations of the actual soil CO2 flux, whereas higher values (0.6–1.0 l min− 1) resulted in overestimations, especially for elevated soil CO2 fluxes. An empirical equation was deduced to allow accumulation chamber fluxes to be calculated very accurately based on soil gas permeabilities measured in the field.
    Description: Published
    Description: 387-393
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Soil CO2 flux measuraments ; Closed dynamic chamber ; soil gas permeability ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
    Publication Date: 2017-04-04
    Description: A quantitative analysis of planktonic foraminifera, coupled with petrophysical and paleomagnetic measurements and 14C AMS calibrations, was carried out on a deep core recovered in the Sardinia Channel (Western Mediterranean Sea), during the CIESM Sub2 survey, providing an integrated stratigraphic time-framework over the last 80 kyr. Significant changes in the quantitative distribution of planktonic foraminifera allowed the identification of several eco-bioevents useful to accurately mark the boundaries of the eco-biozones widely recognised in the Western Mediterranean records and used for large scale correlations. Namely, 10 eco-biozones were identified based on the relative abundance of selected climate sensitive planktonic foraminiferal species. Sixteen codified eco-bioevents were correlated with the Alboran Sea planktonic foraminiferal data and four climatic global events (Sapropel S1, Younger Dryas, Greenland Isotope Interstadial 1, Greenland Isotope Stadial 2, Heinrich event H1-H6) were recognized. The eco-bioevents together with the 14C AMS calibrations concurred to define an accurate age model, spanning between 2 and 83 kyr cal. BP. The reliability of the age model was confirmed by comparing the colour reflectance (550 nm%) data of the studied record with the astronomically tuned one of the Ionian sea (ODP-Site 964). A mean sedimentation rate of about 7 cm/kyr was evaluated including three turbidite event beds that were chronologically constrained within the relative low stand and lowering sea level phases of the MIS 4 and MIS 3. The deep sea sedimentary record includes a distinct tephra occurring at the base of the core which dates 79 ka. The paleomagnetic data provide a well-defined record of the characteristic remanent magnetization that may be used to reconstruct the geomagnetic paleosecular variation for the Mediterranean back to 83 kyr cal. BP.
    Description: In press
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: open
    Keywords: integrated stratigraphy, late Neogene marine record, eco-bio-events, reflectance 550 nm %, Sardinia ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
    Publication Date: 2017-04-04
    Description: Methane, the most abundant hydrocarbon in the atmosphere, plays an important role in the Earth’s atmospheric chemistry and radiative balance being the second most important greenhouse gas after CO2. Methane is released to the atmosphere by a wide number of sources, both natural and anthropogenic, with the latter being twice as large as the former (Kvenvolden and Rogers, 2005). It has recently been established that significant amounts of geological methane, produced within the Earth’s crust, are currently released naturally into the atmosphere (Etiope, 2004). Among natural sources the volcanic/geothermal emissions are probably the least constrained. Recent estimations for volcanic and geothermal systems in Europe (Etiope et al. 2007) gave a rather large provisional range (4-16 kt/a) that claims for much more field measurements in order to widen the current database and decrease the present uncertainties. Pantelleria is an active volcanic complex, at present in quiescent status, hosting a high enthalpy geothermal system. Explorative geothermal wells tapped an exploitable water-dominated reservoir at 600-800 m depth with maximum measured temperatures of 250 °C. While some data are available on diffuse CO2 fluxes, data on CH4 are available only for fumarolic fluids. In the present study we measured CH4 fluxes in the area of Favara Grande characterized by intense diffuse degassing and widespread signs of geothermal activity (fumaroles, steaming grounds and large zones devoid of vegetation). Values range from negative (-43 to 0 mgCH4 m2 day), typical of soils with methanotrophic activity, up to 3500 mgCH4 m2 day in the most thermalized area. The preliminary estimate of the methane release from the area of Favara Grande is about 2.5 t/a. Extrapolation to the whole volcanic/geothermal system of Pantelleria gives about 10 t/a.
    Description: Published
    Description: Davos, Switzerland
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: soil gases ; methane output ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 8
    Publication Date: 2017-04-04
    Description: The island of Vulcano (Aeolian arc, Southern Italy) has displayed several periods of volcanic unrest since the end of the last eruption (1890). We report here results obtained from a long-term survey concerning variations of both the steam output and the exhaling surface area at the sun~mit crater fumarolic field of La Fossa. The field measurements analysed in a Geographiciil Information System (GIS: show a highly dynamic volcanic system in which deep variations in the geochemishy and the temperature of the released fluids were accompanied by fluctuations in the mass output of steam and the topography of the crater field. The use of a GIS facilitated digitized reconstructions of maps of the crater field in addition to analysis (of the steam flux data. The furnarolic field expanded its surface area from 50 m2 in 1983 to more than 2400 m* in 1995, accompanied by an increase in steam output from 152 to about 1400 tonnes per day. The possibility that the observed phenomena are related to volcano-tectonic activity and to magma uprising is taken into consideration.
    Description: Published
    Description: 253-263
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: volcanic surveillance ; Steam output ; tectonic lines ; flux ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
    Publication Date: 2017-04-04
    Description: On February 27, 2007 a new eruption started at Stromboli that lasted until April 2 and included a paroxysmal explosion on March 15. Geochemical monitoring carried out over several years revealed some appreciable variations that preceded both the eruption onset and the explosion. The carbon dioxide (CO2) flux from the soil at Pizzo Sopra La Fossa markedly increased a few days before the eruption onset, and continued during lava effusion to reach its maximum value (at 90,000 g m−2 d−1) a few days before the paroxysm. Almost contemporarily, the δ13CCO2 of the SC5 fumarole located in the summit area increased markedly, peaking just before the explosion (δ13CCO2~−1.8‰). Following the paroxysm, helium (He) isotopes measured in the gases dissolved in the basal thermal aquifer sharply increased. Almost contemporarily, the automatic station of CO2 flux recorded an anomalous degassing rate. Also temperatures and the vertical thermal gradient, which had been measured since November 2006 in the soil at Pizzo Sopra La Fossa, showed appreciable variabilities that lasted until the end of the eruption. The geochemical variations indicated the degassing of a new batch of volatile-rich magma that preceded and probably fed the paroxysm. The anomalous 3He/4He ratio suggested that the ascent of a second batch of volatile-rich magma toward the surface was probably responsible of the resumption of the ordinary activity. A comparison with the geochemical variations observed during the 2002–2003 eruption indicated that the 2007 eruption was less energetic.
    Description: Published
    Description: 246-254
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: geochemistry ; eruption ; dissolved gases ; Stromboli ; volcanic activity ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 10
    Publication Date: 2017-04-04
    Description: The Pleistocene history of climate control on sedimentation in the Southern Alps-Po Plain system, northern Italy, was reconstructed using an integrated magnetostratigraphic, palynological, and petrographical approach on a 47-m-deep core. The core mainly consists of lacustrine sediments pertaining to the Bagaggera sequence, deposited at the foothills of the Southern Alps during the late Matuyama subchron (0.99–0.78 Ma). At that time, climate worsened globally and locally it caused the progradation of an alluvial fan unit onto the nearby Po Plain, triggering lake formation by damming of a tributary valley. These new data are used in conjunction with data from the literature to highlight and track the effects of climate forcing on sedimentation during the late Matuyama subchron in different orographic and geodynamic settings of the Southern Alps-Po Plain system as part of the greater Alpine area. We found that the episodes of alluvial fan and braidplain progradation observed in the southern foreland of the Alps during the late Matuyama global cooling seem broadly synchronous with the deposition of most of the so-called Günz and Älterer Deckenschotter deposits in the northern forelands of the Alps as well as with the first major waxing of the Alpine valley glaciers, possibly around the Marine Isotope Stage 22 (~0.87 Ma).
    Description: In press
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: Pleistocene ; magnetostratigraphy ; pollen analysis ; sand petrography ; Alps ; Po Plain ; lacustrine sequence ; alluvial fan ; 02. Cryosphere::02.03. Ice cores::02.03.05. Paleoclimate ; 04. Solid Earth::04.04. Geology::04.04.02. Geochronology ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 11
    Publication Date: 2017-04-04
    Description: The Early/Middle Eocene (Ypresian/Lutetian) transition is represented by a hiatus in many North European sections, including those in which the classic stratotypes were originally defined. However, the Global Stratotype Section and Point of the Lutetian Stage, which is still pending definition, should be placed at a globally correlatable event included within that unrepresented interval. The Pyrenean Eocene outcrops display sedimentary successions that offer the rare opportunity to analyse the Ypresian/Lutetian boundary interval in almost continuous sections and in very different settings. Seven reference stratigraphic sections were selected on the basis of their quality and correlated by means of biomagnetostratigraphic data. This correlation framework casts light on the sequence of chronostratigraphic events that characterize the Ypresian/Lutetian boundary interval, which may prove useful in defining the main correlation criterion of the base of the Lutetian. All of the Pyrenean sections show a similar sedimentary evolution, despite being up to 350 km apart from each other, containing deposits of different origins (intrabasinal carbonate sediments, siliciclastic sediments sourced from the Iberian plate, and terrigenous sediments sourced from the uplifting Pyrenees) and despite having been accumulated in different sedimentary environments (from continental to deep marine) and in different geodynamic settings (piggy-back basin, foreland basin and cratonic margin). This common evolution can be readily interpreted in terms of a sea-level driven depositional sequence whose lowstand and transgressive systems tracts are included within the Ypresian/Lutetian boundary interval. The Pyrenean Ypresian/Lutetian depositional sequence can reasonably be correlated with depositional sequences from classic North European areas, shedding light on the palaeoenvironmental history which in those areas has not been recorded. Furthermore, these depositional sequences may possibly correlate with others from the Antarctic Ocean and from New Jersey, as well as with oceanic temperature variations, suggesting that they might be the result of climatically-driven glacioeustatic sea-level changes. Should this hypothesis prove correct, it would confirm previous suggestions that the onset of Antarctic glaciations needs to be backshifted to the late Ypresian at least.
    Description: Published
    Description: 313-332
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Eocene ; Lutetian ; Chronostratigraphy ; Sequence stratigraphy ; Climate ; Pyrenees ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.02. Geomagnetic field variations and reversals ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 12
    Publication Date: 2017-04-04
    Description: Chemical and isotopic analyses of the main gas manifestations of the island of Pantelleria (Italy) were used to gain insight on the origin of the released methane. Results indicate that the most probable origin is through abiogenic reactions within the hydrothermal system. Methane and CO2 flux measurements from the soils were made with the accumulation chamber method in an area of about 0.015 km2 within the main fumarolic area of the island (Favara Grande). The 23 measurements range from –34 to 3550 mg m-2 d-1 for CH4 and from 0.6 to 379 g m-2 d-1 for CO2. The relationships between CH4 and CO2 fluxes and the CH4/CO2 ratios in the gases collected between 25 and 100 cm depth provide evidence for methanotrophic processes within the soils. Methane output for the surveyed area was calculated in 2.5 t a-1 and extrapolated to about 5-10 t a-1 for the entire volcanic/hydrothermal system of the island. Previous higher estimates of the CH4 output at Pantelleria (Etiope et al., 2007 - J. Volcanol. Geotherm. Res., 165, 76 – 86) were based on soil CO2 output and CH4/CO2 ratios in fumarolic gases; the present work provides the first direct CH4 flux data and it suggests that methanotrophic activity in the soil could be substantial in reducing the CH4 emission to the atmosphere.
    Description: Published
    Description: 147-157
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: hydrothermal systems ; gas geochemistry ; isotope composition ; methane output ; methanotrophic consumption ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 13
    Publication Date: 2020-11-19
    Description: We report on structural and anisotropy of magnetic susceptibility (AMS) results from the Upper Miocene sediments of the Amantea basin, located on the Tyrrhenian coast of the Calabrian Arc (Southern Italy). The stratigraphic succession of the basin is organized in three depositional sequences, separated by two major angular unconformities. Detailed geologica1 mapping and structural analysis demonstrate that the stratigraphic evolution of the Amantea basin is strongly controlled by a synsedimentary extensional tectonic regime. Severa1 NNE-SSW-trending norma1 fault arrays with large scatter in inclination values have been interpreted as due to a domino faulting mechanism, consistent with a WNW-ESE stretching direction. AMS data have been obtained for 13 sites, both in the not constrained in age first depositional sequence (3 sites), and in the upper Tortonian-lower Messinian clays from the second depositional sequence (10 sites). Al1 the sites show a strong magnetic foliation parallel to the bedding planes, and a well defined magnetic lineation subparallel to the local bedding dip directions. The magnetic lineations cluster around a WNW-ESE trend and are parallel to the stretching directions inferred by fault-slip analysis and basin architecture. These new data then confirm the possibility to use the magnetic lineation to map the strain trajectory in weakly deformed extensional sedimentary basins. Paleomagnetic data (from previous studies) show that the whole Calabrian block underwent a 15°-20° clockwise rotation probably in the Pleistocene, postdating the extensional tectonic events which controlled the Amantea basin geometry. Therefore we suggest for the Amantea basin an original E-W-oriented stretching direction, which may be considered as the older extensional direction characterizing the Late Miocene evolution of the southern Tyrrhenian Sea domain.
    Description: Published
    Description: 33-49
    Description: JCR Journal
    Description: reserved
    Keywords: magnetic fabric ; extentional tectonics ; Miocene ; Calabrian Arc ; Italy ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 14
    Publication Date: 2021-01-07
    Description: The CO2 degassing process from a large area on the Tyrrhenian side of central Italy, probably related to the input into the upper crust of mantle fluids, was investigated in detail through the geochemical study of gas emissions and groundwater. Mass-balance calculations and carbon isotopes show that over 50% of the inorganic carbon in regional groundwater is derived from a deep source highlighting gas−liquid separation processes at depth. The deep carbonate−evaporite regional aquifer acts as the main CO2 reservoir and when total pressure of the reservoir fluid exceeds hydrostatic pressure, a free gas phase separates from the parent liquid and escapes toward the surface generating gas emissions which characterise the study area. The distribution of the CO2 flux anomalies and the location of high PCO2 springs and gas emissions suggest that the storage and the expulsion of the CO2 toward the atmosphere are controlled by the geological and structural setting of the shallow crust. The average CO2 flux and the total amount of CO2 discharged by the study area were computed using surface heat flow, enthalpy and CO2 molality of the liquid phase circulating in the deep carbonate−evaporite aquifer. The results show that the CO2 flux varies from 1×104 mol y−1 km−2 to 5×107 mol y−1 km−2, with an average value of 4.8×106 mol y−1 km−2, about five times higher than the value of 1×106 mol y−1 derived by Kerrick et al. [Kerrick, D.M., McKibben, M.A., Seward, T.M., Caldeira, K., 1995. Convective hydrothermal CO2 emission from high heat flow regions. Chem. Geol. 121, 285–293] as baseline for terrestrial CO2 emissions. The total CO2 discharged from the study area is 0.9×1011 mol y−1, confirming that Earth degassing from Tyrrhenian central Italy is a globally relevant carbon source
    Description: Published
    Description: 89–102
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Earth degassing ; carbon dioxide ; CO2 flux ; groundwater ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 15
    Publication Date: 2020-12-14
    Description: This paper presents a new methodology for studying the evolution of curved mountain belts by means of paleomagnetic analyses performed on analogue models. Eleven models were designed aimed at reproducing various tectonic settings in thin-skinned tectonics. Our models analyze in particular those features reported in the literature as possible causes for peculiar rotational patterns in the outermost as well as in the more internal fronts. In all the models the sedimentary cover was reproduced by frictional low-cohesion materials (sand and glass micro-beads), which detached either on frictional or on viscous layers. These latter were reproduced in the models by silicone. The sand forming the models has been previously mixed with magnetite-dominated powder. Before deformation, the models were magnetized by means of two permanent magnets generating within each model a quasi-linear magnetic field of intensity variable between 20 and 100 mT. After deformation, the models were cut into closely spaced vertical sections and sampled by means of 1x1-cm Plexiglas cylinders at several locations along curved fronts. Care was taken to collect paleomagnetic samples only within virtually undeformed thrust sheets, avoiding zones affected by pervasive shear. Afterwards, the natural remanent magnetization of these samples was measured, and alternating field demagnetization was used to isolate the principal components. The characteristic components of magnetization isolated were used to estimate the vertical-axis rotations occurring during model deformation. We find that indenters pushing into deforming belts from behind form non-rotational curved outer fronts. The more internal fronts show oroclinal-type rotations of a smaller magnitude than that expected for a perfect orocline. Lateral symmetrical obstacles in the foreland colliding with forward propagating belts produce non-rotational outer curved fronts as well, whereas in between and inside the obstacles a perfect orocline forms only when the ratio between obstacles’ distance and thickness of the cover is greater than 10. Finally, when a belt collides with an obstacle in the foreland oblique to the shortening direction the outer front displays rotations opposite in sign to oroclinal-type rotations, whereas the internal fronts seem to assume an "oroclinal type" rotational pattern. Furthermore rotation is easier in laterally unconfined models, i.e. when the wedge can "escape" laterally. The results from our models may be useful when compared to paleomagnetic rotations detected in natural arcs. In these cases, our results may allow for better understanding the tectonic setting controlling the genesis of curved mountain fronts, as is the case of the Gela Nappe of Sicily we compare with some of our models.
    Description: Published
    Description: 633-654
    Description: JCR Journal
    Description: reserved
    Keywords: paleomagnetism ; tectonic rotations ; physical models ; arcuate belts ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 16
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    Elsevier
    In:  Tanguy, J.C., Principe, C., Arrighi, S., 2005. Comment on “Historical measurements of the Earth’s magnetic field compared with remanence directions from lava flows in Italy over the last four centuries”. In: Lanza, R., Meloni, A., Tema, E. (Eds.), Phys Earth Planet. Inter. 152, 116–120.
    Publication Date: 2017-04-04
    Description: A comparison of the geomagnetic directions derived from lava flows of Italian volcanoes with those derived from direct historical measurements of the Earth’s magnetic field (Lanza et al., 2005) yielded two main results: (1) The general agreement between the two data sets already noted by previous authors (Rolph et al., 1987; Incoronato et al., 2002; Tanguy et al., 2003) was better substantiated. (2) The thermal remanent magnetization (TRM) direction of most flows was shown to deviate from the corresponding historical direction by a small angle θ. In most cases, this angle was larger than the experimental error on the TRM direction as given by the α95 semi-angle of confidence of Fisher’s statistics, i.e. θ 〉 α95. The conclusion drawn from these results was straightforward: a better understanding of the causes of the TRM deviation is required if we are to fully exploit the precision of TRM data from Italian volcanoes when their α95 value is less than 2.5–3.0◦.
    Description: Published
    Description: 121-124
    Description: 1.6. Osservazioni di geomagnetismo
    Description: 2.6. TTC - Laboratorio di gravimetria, magnetismo ed elettromagnetismo in aree attive
    Description: 3.4. Geomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Secular variation ; Historical magnetic measurements ; Thermal remanent magnetization ; Volcanic rocks ; 04. Solid Earth::04.05. Geomagnetism::04.05.02. Geomagnetic field variations and reversals ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 17
    Publication Date: 2017-04-04
    Description: The age of spreading of the Liguro–Provençal Basin is still poorly constrained due to the lack of boreholes penetrating the whole sedimentary sequence above the oceanic crust and the lack of a clear magnetic anomaly pattern. In the past, a consensus developed over a fast (20.5–19 Ma) spreading event, relying on old paleomagnetic data from Oligo–Miocene Sardinian volcanics showing a drift-related 30° counterclockwise (CCW) rotation. Here we report new paleomagnetic data from a 10-mthick lower–middle Miocene marine sedimentary sequence from southwestern Sardinia. Ar/Ar dating of two volcanoclastic levels in the lower part of the sequence yields ages of 18.94±0.13 and 19.20±0.12 Ma (lower–mid Burdigalian). Sedimentary strata below the upper volcanic level document a 23.3±4.6° CCW rotation with respect to Europe, while younger strata rapidly evolve to null rotation values. A recent magnetic overprint can be excluded by several lines of evidence, particularly by the significant difference between the in situ paleomagnetic and geocentric axial dipole (GAD) field directions. In both the rotated and unrotated part of the section, only normal polarity directions were obtained. As the global magnetic polarity time scale (MPTS) documents several geomagnetic reversals in the Burdigalian, a continuous sedimentary record would imply that (unrealistically) the whole documented rotation occurred in few thousands years only. We conclude that the section contains one (or more) hiatus(es), and that the minimum age of the unrotated sediments above the volcanic levels is unconstrained. Typical back-arc basin spreading rates translate to a duration ≥3 Ma for the opening of the Liguro–Provençal Basin. Thus, spreading and rotation of Corsica–Sardinia ended no earlier than 16 Ma (early Langhian). A 16–19 Ma, spreading is corroborated by other evidences, such as the age of the breakup unconformity in Sardinia, the age of igneous rocks dredged west of Corsica, the heat flow in the Liguro–Provençal Basin, and recent paleomagnetic data from Sardinian sediments and volcanics. Since Corsica was still rotating/drifting eastward at 16 Ma, it presumably induced significant shortening to the east, in the Apennine belt. Therefore, the lower Miocene extensional basins in the northern Tyrrhenian Sea and margins can be interpreted as synorogenic "intra-wedge" basins due to the thickening and collapse of the northern Apennine wedge.
    Description: Published
    Description: 231-251
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Paleomagnetism ; Corsica-Sardinia ; Liguro-Provençal Basin ; Back-arc spreading ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 18
    Publication Date: 2017-04-04
    Description: We report on new paleomagnetic results obtained from 27 sites sampled in the Plio-Pleistocene sequences at the external front of the central-northern Apennines. Previous analyses of Miocene (Messinian) sediments indicated that the present shape of the northern Apenninic arc is due to the oroclinal bending of an originally straight belt oriented around N320° and that vertical axis rotations accompanied the migration of the thrust fronts toward the Adriatic foreland [F. Speranza et al., J. Geophys. Res. 102 (1997) 3153-3166]. We tried to provide new paleomagnetic constraints for the timing and rates of the oroclinal bending process during the Pliocene and the Pleistocene. The results suggest that CCW rotations observed in the northern part of the studied area are possibly younger than 3 Ma. No regional rotation is recorded in the Pliocene and Pleistocene sediments from the southern part of the study area, analogously to the Messinian sediments of the 'Acquasanta' domain of Speranza et al. [F. Speranza et al., J. Geophys. Res. 102 (1997) 3153-3166]. A local significant CCW rotation (23° ± 10°) is identified in the Early Pleistocene sediments that crop out along the Adriatic coast between Ascoli and Pescara, indicating differential motion of the thrust sheets. This rotation must be younger than 1.43 Ma.
    Description: Published
    Description: 243-257
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: open
    Keywords: paleomagnetism ; Apennines ; tectonics ; Pliocene ; Pleistocene ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 19
    Publication Date: 2017-04-03
    Description: Ocean Drilling Program holes 744Aand 748B represent key sections for calibration of Southern Ocean Eocene-Oligocene biostratigraphic zonations. Sites 744 and 748 were above the carbonate compensation depth throughout this time interval and contain good planktonic foraminiferal, calcareous nannofossil, and diatom biostratigraphic records. In particular, the Southern Ocean diatom biostratigraphic zonation for the Oligocene critically hinges on calibration of these two holes. Previous low-resolution magnetostratigraphic studies at these sites were hampered by limited sampling and technical difficulties, which prompted our high-resolution reinvestigation of the magnetostratigraphy. Magnetic polarity zonations for holes 744Aand 748B were constructed after inspection of vector component plots at 1-cm stratigraphic intervals from continuous u-channel measurements. The magnetizations are generally stable and a robust polarity stratigraphy has been obtained for both holes. The increased resolution of our study and identification of persistent secondary overprints, which were not recognised in previous studies, suggests that the previously published interpretations need to be revised. Our magnetostratigraphic interpretations for both holes are constrained by foraminiferal and calcareous nannofossil datums, as well as by Sr isotope ages. We have calibrated four diatom datums, which are synchronous at the two studied sites, to the geomagnetic polarity timescale, including the first occurrence (FO) of Lisitzinia ornata (27.8 Ma), the FO of Rocella vigilans var. B (27.8 Ma), the FO of Cavitatus jouseanus (30.9 Ma) and the FO of Rhizosolenia oligocaenica (33.8 Ma). The synchroneity of these datums suggests that diatom biostratigraphy has considerable potential for Palaeogene biostratigraphic correlation in the Southern Ocean. Although the ages of some datums are obscured by an unconformity in Hole 744A, our age model from Hole 748B suggests age estimates for the last common occurrence of Rocella vigilans var. A(~29.0 Ma), the FO of Rocella vigilans var. A(30.0 Ma) and the FO of Rhizosolenia antarctica (33.2 Ma). It should also be noted that the last occurrence of the calcareous nannofossil Chiasmolithus altus occurs in Chron C8r rather than C8n in our revised magnetostratigraphic interpretation, which indicates that this datum is not diachronous between low and mid latitudes as had previously been suggested. Significant unconformities are documented in both holes, in the middle Oligocene and in the middle late Oligocene, respectively, which probably resulted from periods of enhanced circumpolar deep-water circulation.
    Description: Published
    Description: 145-168
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Eocene ; Oligocene ; Ocean Drilling Program ; holes 744A and 748B ; Kerguelen Plateau ; Antarctica ; magnetostratigraphy ; biostratigraphy ; diatoms ; foraminifera ; calcareous nannofossils ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 20
    Publication Date: 2017-04-04
    Description: The Piànico-Sèllere is a lacustrine succession from northern Italy that records a sequence of climatic transitions across two Pleistocene glacial stages. The intervening interglacial stage is represented by well-preserved varves with calcitic (summer) and clastic (winter) laminae. There is a tight coupling between climate-driven lithologic changes and magnetic susceptibility variations, and stable paleomagnetic components were retrieved from all investigated lithologies including the largely diamagnetic calcite varves. These components were used to delineate a sequence of magnetic polarity reversals that was interpreted as a record of excursions of the Earth’s magnetic field. Comparison of the magnetostratigraphic results with previously published data allows discussion of two possible models which have generated controversy regarding the age of the Piànico Formation. The data indicates that the Piànico Formation magnetostratigraphy correlates to geomagnetic field excursions across the Brunhes/Matuyama transition, and consequently the Piànico interglacial correlates to marine isotope stage 19. This correlation option is substantially consistent with K-Ar radiometric age estimates recently obtained from a tepha layer interbedded in the Piànico Formation. The alternative option, considering the Piànico interglacial correlative to marine isotope stage 11 within the Brunhes Chron as supported by tephrochronological dating reported in the literature, is not supported by the magnetostratigraphic results.
    Description: In press
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: Piànico Formation ; Pleistocene ; magnetostratigraphy ; polarity excursions ; Brunhes Chron ; Southern Alps ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 21
    Publication Date: 2017-04-04
    Description: El Chichón volcano (Chiapas, Mexico) erupted violently in March–April 1982, breaching through the former volcano–hydrothermal system. Since then, the 1982 crater has hosted a shallow (1–3.3 m, acidic (pH ∼ 2.2) and warm (∼ 30 °C) crater lake with a strongly varying chemistry (Cl/SO4=0–79 molar ratio). The changes in crater lake chemistry and volume are not systematically related to the seasonal variation of rainfall, but rather to the activity of near-neutral geyser-like springs in the crater (Soap Pool). These Soap Pool springs are the only sources of Cl for the lake. Their geyser-like behaviour with a long-term (months to years) periodicity is due to a specific geometry of the shallow boiling aquifer beneath the lake, which is the remnant of the 1983 Cl-rich (24,000 mg/l) crater lake water. The Soap Pool springs decreased in Cl content over time. The zero-time extrapolation (1982, year of the eruption) approaches the Cl content in the initial crater lake,meanwhile the extrapolation towards the future indicates a zero-Cl content by 2009±1. This particular situation offers the opportunity to calculate mass balance and Cl budget to quantify the lake–spring system in the El Chichón crater. These calculations show that the water balance without the input of SP springs is negative, implying that the lake should disappear during the dry season. The isotopic composition of lake waters (δD and δ18O) coincide with this crater lake-SP dynamics, reflecting evaporation processes and mixing with SP geyser and meteoric water. Future dome growth, not observed yet in the post-1982 El Chichón crater, may be anticipated by changes in lake chemistry and dynamics.
    Description: Published
    Description: 237–248
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: El Chichón volcano ; crater lake–Spring dynamics ; fluid geochemistry ; stable isotopes ; monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 22
    Publication Date: 2017-04-04
    Description: El Chichón crater lake appeared immediately after the 1982 catastrophic eruption in a newly formed, 1-km wide, explosive crater. During the first 2 years after the eruption the lake transformed from hot and ultraacidic caused by dissolution of magmatic gases, to a warm and less acidic lake due to a rapid “magmatic-tohydrothermal transition” — input of hydrothermal fluids and oxidation of H2S to sulfate. Chemical composition of the lake water and other thermal fluids discharging in the crater, stable isotope composition (δD and δ18O) of lake water, gas condensates and thermal waters collected in 1995–2006 were used for the mass-balance calculations (Cl, SO4 and isotopic composition) of the thermal flux from the crater floor. The calculated fluxes of thermal fluid by different mass-balance approaches become of the same order of magnitude as those derived from the energy-budget model if values of 1.9 and 2 mmol/mol are taken for the catchment coefficient and the average H2S concentration in the hydrothermal vapors, respectively. The total heat power from the crater is estimated to be between 35 and 60 MW and the CO2 flux is not higher than 150 t/day or ~200 gm−2 day−1.
    Description: Published
    Description: 472-481
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: El Chichón ; crater lake ; mass-energy budget ; CO2 flux ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data
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  • 23
    Publication Date: 2017-04-04
    Description: Recent developments in paleomagnetism and environmental magnetism provide new tools for the detailed correlation of climatically induced magnetic mineralogy changes in sedimentary sequences. Studies of these changes contribute to the reconstruction of climate history for the glacial^interglacial cycles of the Late Pleistocene and to the delineation of the range of natural variability for global climate during the past hundred thousands years. Here we show that sharp coercivity minima observed in fine-grained sediments from the continental rise of the western Antarctic Peninsula correlate to the major rapid cooling events of the northern Atlantic (Heinrich layers). We interpret such an environmental magnetic signal in terms of variations in deep sea diagenetic processes of sulfide formation, which reflect changes in the input of detrital organic matter controlled by sea-ice extent. With the inherent uncertainties in age controls, the sedimentary paleoclimatic markers of the two hemispheres are almost contemporaneous, but interhemispheric time lags or leads of the order of 1-2 kyr (such as those recently reported from the Greenland and Antarctic ice cores) are also compatible with the data.
    Description: Published
    Description: 65-80
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: paleomagnetism ; paleointensity ; Antarctica ; Heinrich events ; climatic correlation ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 24
    Publication Date: 2017-04-04
    Description: Many of the mountain belts displaying a curved shape are "oroclines", i.e. are produced after progressive bending of an originally straight fold and thrust belt. The bending process was previously explained as a consequence of several possible events taking place in the crustal orogenic wedge, such as occurrence of obstacles, non-coaxial deformation, and mouvements on wrench faults. Recent paleomagnetic results from the northern Apenninic Arc document that this belt is properly an orocline and results from Late Messinian-Early Pliocene bending of a Messinian straight belt-foredeep system. Tomographic images in turn show the presence of a high-velocity body, interpreted as subducted slab, in the upper mantle beneath the northern Apennines, between 35 and 670 km depth. Down to 100 km, this body displays an arcuate shape which closely mirrors the geological outlines, while it appears to be straight (and parallel to the Messinian pre-rotated belt) at depth. We explore here the possibility that the arcuate shape of the northern Apennines is a consequence, closely following in time, on much deeper processes than previously suggested, i.e. the lateral bending of the subducting Adriatic plate.
    Description: Published
    Description: 53-64
    Description: JCR Journal
    Description: reserved
    Keywords: paleomagnetism ; seismic tomography ; Northern Apennines ; orocline ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 25
    Publication Date: 2017-04-04
    Description: We report on the anisotropy of magnetic susceptibility (AMS) analyses of fine-grained sediments deposited during the Messinian in foredeep basins at the front of the northern Apenninic chain. The data refer to 32 sampling sites, mostly distributed in the fine-grained intervals of the Laga and Colombacci formations, extending along the belt for a total length of about 300 km. Rock magnetism analyses indicate that the magnetic susceptibility and its anisotropy are in most cases dominated by the paramagnetic minerals of the clay matrix. In order to delineate the contribution of the ferrimagnetic fraction to the overall susceptibility fabric, the anisotropy of the anhysteretic remanent magnetisation was investigated at some representative sites. The magnetic fabric of the studied sediments mostly reflects the effects of compaction, showing a predominant magnetic foliation parallel to the bedding piane. At all the sites a well distinct magnetic lineation was also found, which is parallel to the fold axes and thrust fronts, both at local and regional scales. This feature is maintained in sequences that differ for sedimentological character and age, implying that the magnetic lineation was produced by a mild tectonic overprint of the primary sedimentary-compactional fabric. The relationship between the magnetic lineation trends and the vertical axis rotations detected by Speranza et al. [Speranza, F., Sagnotti, L.. Mattei, M., 1997. J. Geophys. Res. 102, 3153-3166] indicates that the magnetic lineation formed during the compressive phases of the Messinian-early Pliocene, when the Apenninic front was almost rectilinear and oriented N32O°.
    Description: Published
    Description: 73-93
    Description: JCR Journal
    Description: reserved
    Keywords: magnetic anisotropy ; rock strain ; northern Apennines ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 26
    Publication Date: 2017-04-04
    Description: A transect of three sites was drilled during Leg 188 of the Ocean Drilling Program (ODP), proximal to the East Antarctic Ice Sheet (EAIS) across the Prydz Bay continental shelf (Site 1166), slope (Site 1167), and rise (Site 1165). We present results of a palaeomagnetic and rock magnetic study of sediments recovered at sites 1165 and 1166. Magnetostratigraphic interpretations are presented for both holes and are mainly constrained by diatom and radiolarian biostratigraphies, interpreted in the light of recent refinements to Southern Ocean zonal schemes and datum calibrations for these microfossil groups. Site 1165 records a history of sedimentation on the continental rise extending back to earliest Miocene times (about 22 Ma). Several long-term changes characterise this record, including an overall trend of decreasing sedimentation rates from the bottom to the top of the hole. There is a progressive decrease in the sedimentation rate above about 308 mbsf (meters below sea floor), which is marked by a transition from dark-grey fissile claystones to greenish-grey diatom-bearing clays. At this transition, ice-rafted debris, sand grains, and total clay content also increase. The chronology presented here indicates a middle Miocene age (~14.3 Ma) for the lithological transition. Correlation to ODP Hole 747A from the Kerguelen Plateau suggests that this lithological transition coincides with the base of the Mi-3/3a δ18O event, which suggests palaeoclimatic control on middle Miocene sedimentation changes at Site 1165. Core recovery was poor at Site 1166. Consequently, the magnetostratigraphic data are of limited value. The deepest cores recovered at Site 1166 record brief intervals in the early history of the EAIS for the Prydz Bay region, extending back through the early stage of glaciation to pre-glacial times. An Early Cretaceous fluvio-lacustrine unit, lagoonal deposits and sandy fluvio-deltaic units of mid-late Eocene age contain a sporadic record of the transition from humid and mild conditions to cool temperate conditions.
    Description: Published
    Description: 69-100
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: magnetostratigraphy ; biostratigraphy ; Prydz Bay ; Antarctica ; Ocean Drilling Program ; sites 1165 and 1166 ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 27
    Publication Date: 2017-04-04
    Description: Four groups of thermal springs with temperatures from 50 to 80 °C are located on the S–SW–W slopes of El Chichón volcano, a composite dome-tephra edifice, which exploded in 1982 with a 1 km wide, 160 m deep crater left. Very dynamic thermal activity inside the crater (variations in chemistry and migration of pools and fumaroles, drastic changes in the crater lake volume and chemistry) contrasts with the stable behavior of the flank hot springs during the time of observations (1974–2005). All known groups of hot springs are located on the contact of the basement and volcanic edifice, and only on the W–SW–S slopes of the volcano at almost same elevations 600–650 m asl and less than 3 km of direct distance from the crater. Three groups of near-neutral (pH≈6) springs at SW–S slopes have the total thermal water outflow rate higher than 300 l/s and are similar in composition. The fourth and farthest group on the western slope discharges acidic (pH≈2) saline (10 g/kg of Cl) water with a much lower outflow rate (b10 l/s). Water–rock interaction modeling of main types of the El Chichón thermal waters using regular log Q/K graphs (saturation indices vs temperature) showed maximum equilibrium temperature slightly higher than 200 °C. Acidic waters are equilibrated with some clay minerals at about 120 °C. Three main sources of the salinity of thermal water are suggested on the basis of mixing plots and isotopic data: a magmatic source for CO2, boron, sulfur and a limited part of Cl; volcanic rock source for the major cations and trace elements; the oil-bearing evaporitic basement source (oil-field brine?) for NaCl, Br, a part of Ca and some trace elements. All flank thermal springs end up in the river Rio Magdalena that has a variable seasonal flow rates from 4 to 20 m3/s. Any changes in the chemistry of springs must notably change the composition of the streams draining hot springs and eventually, Rio Magdalena. A monthly geochemical monitoring of Rio Magdalena and streams draining main hot springs would be a useful tool for surveying the activity of the volcano.
    Description: Published
    Description: 224–236
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: volcano–hydrothermal system ; crater lake ; acidic water ; trace elements ; thermochemical modeling ; El Chichón volcano ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 28
    Publication Date: 2017-04-03
    Description: Direct measurements of the Earth’s magnetic field in Italy since 1640 a.d. have been used to check the remanence directions derived from historically dated volcanic rocks of Etna and Vesuvius. Direct measurements consist of the records of L’Aquila and Pola geomagnetic observatories, the repeat stations of the Italian Magnetic Network and the data base of the Historical Italian Geomagnetic Data Catalogue. All have been relocated to the same reference site (Viterbo — lat. 42.45◦N, long. 12.03◦E) in order to draw a reference secular variation (SV) curve. The direction of the Earth’s field at Viterbo has also been calculated from the historical records (2000–1600) of ref. [Jackson, A., Jonkers, A.R.T., Walker, M.R., 2000. Four centuries of geomagnetic secular variation from historical records. Phil. Trans. R. Soc. London, Ser. A 358, 957–990] database. The remanence directions from Etna show a general agreement with the trend of the SV curve, although their inclination is usually lower than that from the direct measurement. The directions from Vesuvius are more scattered. Large discrepancies occur at both volcanoes and in some cases have been ascribed in the literature to poor geographic information, making it difficult to identify the flows actually emplaced during the eruptions reported in the chronicles. Closer examination shows that the great majority of the best-defined remanence directions (semi-angle of confidence α95 〈 2.5◦) deviate significantly from the geomagnetic direction measured at the time of the emplacement, the angle between the two directions being larger than the α95 value. The value of 2.5–3.0◦ can thus be regarded as a conservative evaluation of the error when dealing with dating Etna and Vesuvius lava flows older than 17th century, even when the accuracy attained in remanence measurements is higher. In default of a SV curve for Italy derived from archaeological artefacts, a further error in dating is introduced when reference is made to SV curves of other countries, even if well-established, as these are from regions too far from Italy (〉600 km) to confidently relocate magnetic directions.
    Description: Published
    Description: 97-107
    Description: 1.6. Osservazioni di geomagnetismo
    Description: 2.6. TTC - Laboratorio di gravimetria, magnetismo ed elettromagnetismo in aree attive
    Description: 3.4. Geomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Secular variation ; Historical magnetic measurements ; Thermal remanent magnetization ; Volcanic rocks ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 04. Solid Earth::04.05. Geomagnetism::04.05.02. Geomagnetic field variations and reversals ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 29
    Publication Date: 2017-04-04
    Description: The analysis of the Messinian and Pliocene stratigraphy of the southern Bajo Segura Basin (Betic Cordillera, Spain) has revealed three highstand sedimentary phases (Messinian I, Messinian II, and Pliocene) bounded by two lowstand erosional surfaces (intra-Messinian and end-Messinian unconformities). The Messinian I highstand phase is characterized by the progradation of coastal and shallow marine sandstones (La Virgen Fm) over slope and pelagic-basin marls (Torremendo Fm). After this first phase, a fall in sea level brought about the intra-Messinian unconformity, a subaerial erosional surface with local accumulations of karstic breccias and caliche-like carbonate crusts. The Messinian II highstand phase is represented by sandy beaches and muddy lagoons (Garruchal Fm) correlative with shallow marine evaporites (San Miguel Fm); this second phase records the intra-Messinian reflooding of the basin, which characterizes the salinity crisis in the marginal basins of the Mediterranean. A new sea-level fall resulted in the end-Messinian unconformity, of which the most significant feature is the presence of a broad palaeovalley, c. 200 m deep, which, along its course, completely eroded the deposits of the Messinian II phase and part of the deposits of the Messinian I phase. The Pliocene highstand phase begins with coastal and shallow marine conglomerates and sandstones (La Pedrera Fm) which fill the deep part of the above-mentioned palaeovalley. These bottom deposits evolved gradually upwards towards pelagic marls (Hurchillo Fm), over which shallow marine and coastal sandstones prograded (Rojales Fm). This third phase records the flooding of the basin at the beginning of the Pliocene, when the salinity crisis ended in the marginal basins of the Mediterranean. The combination of calcareous nannoplankton biostratigraphy and magnetostratigraphy has confirmed that both the end of the sedimentation of the Messinian I phase, as well as the two lowstand erosional surfaces (intra- and end-Messinian unconformities) and also the onset of the Pliocene phase occurred in the chron C3r (c. 5.9–5.2 Ma). Under the assumption of the classical model of a desiccated deep basin, either of the two aforementioned erosional surfaces, or even both, could be correlative with the evaporites deposited in the abyssal parts of the Mediterranean.
    Description: Published
    Description: 267-288
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Stratigraphy ; Magnetobiostratigraphy ; Messinian ; Pliocene ; Salinity crisis ; Mediterranean region ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.07. Rock magnetism
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  • 30
    Publication Date: 2017-04-04
    Description: This work represents the first attempt to use anisotropy of magnetic susceptibility (AMS) analysis for the characterization of the magnetic fabric of Plio-Pleistocene sediments in the southern Apennines of Italy. The area examined, the Sant’Arcangelo basin, has undergone mild deformation during the Pleistocene. Analysis was carried out on 182 cores sampled at 15 sites in unmetamorphosed, weakly deformed clays and marly clays. The data identify a magnetic fabric of clearly depositional—compactional origin even though a partial contribution of tectonic deformation to the AMS is also recognizable at many sites. The results presented here are compared with the existing structural and sedimentary data. In particular, a close consistency is found between the overall orientation of magnetic lineations and the compressional directions indicated by previous meso-structural analysis. We suggest that the magnetic fabric detected here arises from a limited overprint of strain effects related to compressional episodes on a primary, sedimentary, fabric. This interpretation allowed us to resolve the bedding attitude where the clayey units appear homogeneous in the field, and hence to suggest the appropriate bedding correction in concomitant paleomagnetic analysis, and to estimate the orientation and the relative degree of deformation at each sampling site.
    Description: Published
    Description: 165-176
    Description: JCR Journal
    Description: reserved
    Keywords: magnetic anisotropy ; rock strain ; Sant'Arcangelo basin ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 31
    Publication Date: 2017-04-04
    Description: Piston core LC07, located west of the Sicily Strait in the Mediterranean Sea, unambiguously records the Matuyama/ Brunhes (M/B) and the upper Jaramillo polarity reversals, with similar average sediment accumulation rates (SARs) for the Brunhes Chron (2.29 cm/kyr) and late Matuyama Chron C1r.1r (2.19 cm/kyr). We report a relative paleointensity record for the interval spanning the M/B boundary down into the Jaramillo Subchron, which is unique in the Mediterranean because existing records from this basin cover only the last 80 kyr. The average SAR in core LC07 is used to translate the depth-related paleointensity record to the time domain; the ratio of anhysteretic remanent magnetization to low-field magnetic susceptibility is climatically sensitive and is used to tune the age model. This correlation produces a good fit to the global ice volume model derived for summer insolation at 65°N. With this age model, a paleointensity minimum in association with the M/B boundary has a duration of about 4-5 kyr, while the directional change has a duration of 〈3 kyr. A second paleointensity minimum of similar duration is found about 16 kyr below the M/B boundary. This feature (precursor or 'dip' in the literature) has previously been recognized at the same time interval in many marine records, which reinforces the validity of our age model. Other relative paleointensity minima are found within chron C1r.1r, and, within the uncertainties of the respective age models, these minima coincide with those observed from the few published coeval paleointensity records. In particular, there is good correspondence between the ages of minima at about 0.92 and 0.89 Ma, which probably correlate with two geomagnetic excursions (Santa Rosa and Kamikatsura, respectively) that have been recorded in lava flows and dated using the 40Ar/39Ar technique. In contrast, a recently dated excursion at 0.83 Ma from La Palma seems to correspond to a paleointensity maximum. This observation is opposite to that expected and this excursion needs to be confirmed. In contrast to some recently published paleointensity records, spectral analysis of the LC07 record does not reveal identification of significant power at the orbital obliquity frequency.
    Description: Published
    Description: 327-341
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: paleointensity ; magnetic field ; Matuyama Chron ; Jaramillo Subchron ; Brunhes Chron ; Mediterranean Sea ; 04. Solid Earth::04.05. Geomagnetism::04.05.02. Geomagnetic field variations and reversals ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 32
    Publication Date: 2017-04-04
    Description: Drilling offshore from Cape Roberts, Antarctica, has enabled recovery of a 1472-m cumulative record of late Eocene–early Miocene history of sedimentary basin development and climate change in the Western Ross Sea. In this paper, we synthesize the results of palaeomagnetic analyses carried out on the CRP-1, CRP-2 and CRP-3 sediment cores, and present a chronology for the recovered Eocene–Miocene succession. Stepwise demagnetization data demonstrate that secondary overprints have been successfully removed and that characteristic remanent magnetizations (ChRMs) have been clearly identified in most of the samples. A close sampling interval has allowed a detailed magnetic polarity stratigraphy to be established for the composite succession. Correlation with the geomagnetic polarity time scale (GPTS) has been constrained by a number of 40Ar/39Ar and 87Sr/86Sr ages, as well as by a recently developed Antarctic siliceous microfossil zonation, and by calcareous nannoplankton biostratigraphy. The basal sediments of the Eocene–Miocene succession rest unconformably on Devonian sandstones of the Beacon Supergroup. A basal sandstone breccia, which probably represents the onset of rifting in the Victoria Land Basin (VLB), is overlain by a succession of sandstones that are interbedded with thin conglomerate beds. These sediments give way to more clearly glacially influenced mudstones and diamictite facies in the mid Oligocene, and, by the Oligocene–Miocene boundary, coincident with the Mi-1 glaciation, a permanent glacial dominance was imprinted on the sedimentary record. Average sediment accumulation rates were initially rapid in the late Eocene–early Oligocene (up to 60 cm/k.y.), but reduced to only a few cm/k.y. in the early Miocene as basin subsidence slowed.
    Description: Published
    Description: 207-236
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: 3.8. Geofisica per l'ambiente
    Description: JCR Journal
    Description: reserved
    Keywords: Antarctica ; Cape Roberts Project ; Cenozoic ; Chronology ; Magnetostratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 33
    Publication Date: 2017-04-04
    Description: An extensive geochemical survey of the fluids released by the volcanic/geothermal system of Methana was undertaken. Gases were characterized based on the chemical and isotopic [helium (He) and carbon (C)] analysis of 27 samples. Carbon dioxide soil gas concentration and fluxes were measured at 179 sampling sites throughout the peninsula. Forty samples of thermal and cold groundwaters were also sampled and analysed to characterize the geochemistry of the aquifers. Gases of hydrothermal origin gave a preliminary geothermometric estimate of about 210 °C. The He-isotope composition indicated mantle contributions of up to 40%, and the C-isotope composition of CO2 indicated that it predominantly (〉90%) originated from limestone decomposition. The groundwater composition was suggestive of mixing between meteoric and hydrothermally modified sea-water endmembers and water–rock interaction processes limited to simple rock dissolution driven by an increased endogenous CO2 content. All of the thermal manifestations and anomalous degassing areas, although of limited extent, were spatially correlated with the main active tectonic system of the area. The total CO2 output of the volcanic system has been preliminary estimated to be less than 0.05 kg s–1. Although this value is very low compared to those of other volcanic systems, anomalous CO2 degassing at Methana – which is currently restricted to limited areas and at present is the only volcanic risk of the peninsula – is a potential gas hazard that warrants further assessment in future studies.
    Description: Published
    Description: 818-828
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Methana ; south Aegean volcanic arc ; fluids geochemistry ; soil gases ; groundwaters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 34
    Publication Date: 2017-04-04
    Description: Research article
    Description: Quantifying the contribution of volcanism to global mercury (Hg) emissions is important to understand the pathways and the mechanisms of Hg cycling through the Earth's geochemical reservoirs and to assess its environmental impacts. While previous studies have suggested that degassing volcanoes might contribute importantly to the atmospheric budget of mercury, little is known about the amount and behaviour of Hg in volcanic aquifers. Here we report on detailed investigations of both the content and the speciation of mercury in aquifers of active volcanoes in Italy and Guadeloupe Island (Lesser Antilles). In the studied groundwaters, total Hg (THg) concentrations range from 10 to 500 ng/l and are lower than the 1000 ng/l threshold value for human health protection fixed by the World Health Organization [WHO (1993): WHO Guidelines for Drinking Water Quality- http://www.who.int/water_sanitation_health/GDWQ/index.htlm]. Positive co-variations of (THg) with sulphate indicate that Hg-SO4-rich acid groundwaters receive a direct input of magmatic/hydrothermal gases carrying mercury as Hg0 (gas). Increasing THg in a volcanic aquifer could thus be a sensitive tracer of magmatic gas input prior to an eruption. Since the complex behaviour and toxicity of mercury in waters depend on its chemical speciation, we carefully determined the different aqueous forms of this element in our samples.We find that dissolved elemental Hg0 (aq) and particulate-bound Hg (HgP) widely prevail in volcanic aquifers, in proportions that highlight the efficiency of Hg adsorption onto colloidal particles. Moreover, we observe that dissolved Hg0 aq and Hg(II) forms coexist in comparable amount in most of the waters, in stark contrast to the results of thermodynamic equilibrium modelling. Therefore, chemical equilibrium between dissolved mercury species in volcanic waters is either prevented by natural kinetic effects or not preserved in collected waters due to sampling/storage artefacts. Finally, we provide a first quantitative comparison of the relative intensity of aqueous transport and atmospheric emissions of mercury at Mount Etna, a very active basaltic volcano.
    Description: In press
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: open
    Keywords: Fluid geochemistry ; volcanic mercury ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 35
    Publication Date: 2017-04-04
    Description: We present a high-resolution paleomagnetic record from 682 discrete samples from Eltanin 27–21 (69.03°S 179.83°E), a 16-meter long piston core recovered in 1968 at a water depth of 3456 m by the USNS Eltanin as part of Operation Deep Freeze. After removal of a low-coercivity overprint, most samples yield stable characteristic remanent magnetization directions. The downhole variation in the magnetic inclination provides a well-resolved magnetostratigraphy from the Brunhes Chron (0–0.781 Ma), through the Reunion Subchron (2.128–2.148 Ma), and into Chron C2r.2r. The sedimentation rates are sufficiently high that even short-term geomagnetic features, like the Cobb Mountain excursion, are resolved. The record from Eltanin 27–21 provides new insights into the behavior of the geomagnetic field at high latitudes, about which very little is currently known. Using the variability in the inclinations during stable polarity intervals, we estimate that the dispersion in the paleomagnetic pole position over the past ~2 Myr is 30.3°±4.3°, which is significantly greater than observed at low to mid latitude sites. The higher dispersion observed at Eltanin 27–21 is consistent with numerical modeling of the geodynamo. That modeling has shown that polar vortices can develop in the Earth's core within the tangent cylinder, defined as the cylinder coaxial with the Earth's rotation axis and tangent to the inner core/outer core boundary. The polar vortices produce vigorous fluid motion in the core, which creates greater geomagnetic field variability above the tangent cylinder at the surface of the Earth. The tangent cylinder intersects the Earth's surface in the polar regions at 79.1° latitude, which is relatively close to the latitude of Eltanin 27–21.
    Description: Published
    Description: 435-443
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: paleomagnetism ; geomagnetism ; magnetostratigraphy ; Eltanin ; Ross Sea ; Antarctica ; tangent cylinder ; geodynamo ; Cobb Mountain Subchron ; Reunion Subchron ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.07. Rock magnetism
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  • 36
    Publication Date: 2017-04-04
    Description: The Neogene Fortuna and Bajo Segura basins are located on the northeastern end of the Trans-Alborán Shear Zone (TASZ), on the eastern Betic cordillera. The stratigraphic study of the infilling of these basins has shown two major sedimentary discontinuities. The first one, represented by an erosive surface separating open marine marls from an overlying coastal conglomeratic unit, is linked to the onset of the activity along the TASZ, which in this area indicates the beginning of the Abanilla Thrust emplacement. In the Fortuna Basin, the Tortonian salinity crisis, registered over this older first discontinuity, was therefore related to tectonic processes of the eastern portion of the cordillera and consequently would not have an expression in the western basins. The age of the Tortonian Salinity Crisis has been established with nannofossil biostratigraphy as Latest Tortonian at a somewhat lower stratigraphic position than previously recognized. The second sedimentary discontinuity was developed in relation with the known Mediterranean-wide Messinian salinity crisis.
    Description: Published
    Description: 474-481
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Betic Cordillera ; Tortonian Salinity Crisis ; Messinian Salinity Crisis ; Trans-Alboran Shear Zone ; Fortuna Basin ; Spain ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 37
    Publication Date: 2017-04-04
    Description: A new magnetic polarity stratigraphy is reported from 214 sampling sites representing 265 m of fluviatile red beds of the Buntsandstein facies succession from the Catalan Coastal Ranges (Riera de Sant Jaume, RSJ section). The Buntsandstein constitutes the lowermost of the six lithostratigraphic units in which the Triassic from the CCR is subdivided (also grouped into the typical three-fold subdivision of the Germanic Facies from the Tethys Realm: Buntsandstein, Muschelkalk and Keuper). Magnetostratigraphic data from four sections though the uppermost Buntsandstein facies located in the Molina de Aragón area in the Iberian Ranges (Rey, D., Turner, P., Ramos, A., 1996. Palaeomagnetism and Magnetostratigraphy of the Middle Triassic in the Iberian Ranges (Central Spain). In: Morris, A., Tarling, D.R. (Eds.), Palaeomagnetism and Tectonics of the Mediterranean Region, Geol. Soc. Sp. Pub. 105, 59–82) are also discussed in the light of a new biostratigraphic reappraisal of the palynoflora content presented herein. Characteristic magnetizations are carried mostly by hematite with minor contributions by magnetite for the Buntsandstein red beds. The magnetic polarity sequence at the RSJ section consists of 9 magnetozones (and one additional less reliable magnetozone) that are represented by more than two samples. A detailed study along a magnetic reversal indicates that the nature of the remanence in the studied red beds is partially controlled by a chemical magnetization process (delayed remanence acquisition), in addition to a detrital signature (the characteristic primary direction). Chronostratigraphic constraints are provided by conodont fauna from the overlying Muschelkalk facies that indicates a middle–late Pelsonian to late Illyrian age (middle–late Anisian) (Marquez-Aliaga, A., Valenzuela-Rios, J.I., Calvet, F., Budurov, K., 2000. Middle Triassic conodonts from northeastern Spain; biostratigraphic implications. Terra Nova 12, 77–83) and a few palynostratigraphic determinations in the Buntsandstein red beds. These biostratigraphic constraints and the magnetic polarity pattern allow an unambiguous correlation of the RSJ magnetostratigraphy to the conodont-ammonoid-calibrated magnetostratigraphy from the Tethys realm (Muttoni, G., Kent, D.V., Meco, S., Balini, M., Nicora, A., Rettori, R. Gaetani, M., Krystine, L., 1998. Towards a better definition of the Middle Triassic magnetostratigraphy and biostratigraphy of the Tethyan realm. Earth Planet. Sci. Lett. 164, 285–302; Muttoni, G., Gaetani, M., Budurov, K., Zagorchev, I., Trifonova, E., Ivanova, D., Petrounova, L., Lowrie, W., 2000. Middle Triassic paleomagnetic data from northern Bulgaria; constraints on Tethyan magnetostratigraphy and paleogeography. Palaeogeogr. Palaeoclimatol. Palaeoecol. 160, 223–237; Muttoni, G., Nicora, A., Brack, P., Kent, D.V., 2004a. Integrated Anisian–Ladinian boundary chronology. Palaeogeogr. Palaeoclimatol. Palaeoecol. 208, 85–102; Muttoni, G., Kent, D.V., Olsen, P.E., Di Stefano, P., Lowrie, W., Bernasconi, S., Hernandez, F.M., 2004b. Tethyan magnetostratigraphy from Pizzo Mondello (Sicily) and correlation to the Late Triassic Newark astrochronological polarity time scale. Geol. Soc. Amer. Bull. 116, 1043–1058). The proposed correlation identifies for the first time in the Triassic from Iberia the Olenekian (Scythian)–Anisian stage boundary (245 Ma) within magnetozone N3 in the Riera de Sant Jaume units. Likewise, the new palynostratigraphic reconsideration allows the identification of the Anisian–Ladian stage (Illyrian–Fassanian substage) boundary (taken the option at the base of the Curionii ammonoid Zone favored by Muttoni et al. (2004a) [Muttoni, G., Nicora, A., Brack, P., Kent, D.V., 2004. Integrated Anisian–Ladinian boundary chronology. Palaeogeogr. Palaeoclimatol. Palaeoecol. 208, 85–102] for this boundary within the upper part of the Rillo Mudstone and Sandstones Formation (RMS Formation) and the Fassanian–Longobardian substage boundary (Ladinian) within the Torete Multicoloured Mudstone and Sandstone Formation (TMMS Formation). Our data are consistent with the notion that the lower Muschelkalk transgression progressed from east to west (i.e., the Buntsandstein/Muschelkalk boundary is younger in the Iberian Ranges with respect to the Catalan Coastal Ranges). The Early/Middle Triassic paleopole for the Catalan Coastal Ranges is located at 55.18N 172.4E (Dp=1.4, Dm=2.7).and the Middle/Late Triassic paleopole for the Iberian Ranges is 558N 201E (Dp=1.7, Dm=3.1). These paleopoles are compatible with the general trend of the Iberian apparent polar wander path which indicates a northward motion during the Triassic related to the general northward translation of Pangea.
    Description: Published
    Description: 158-177
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Buntsandstein ; Olenekian–Anisian boundary ; Anisian–Ladinian boundary ; Palynostratigraphy ; Conodonts ; Catalan Coastal Ranges ; Iberian Ranges ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 38
    Publication Date: 2017-04-04
    Description: In curved orogenic systems where thrusting and vertical-axis rotations have been documented, it is possible to determine whether the curvature is secondary or progressive based on the timing between the two motions. The South-Central Unit of the Southern Pyrenees provides an opportunity to investigate relationships between thrusting, folding, and vertical-axis rotation because of unusual preservation of Tertiary synorogenic sedimentary strata. Paleomagnetic samples were collected from 51 sites in the upper Eocene-lower Oligocene continental synorogenic strata of the Oliana anticline, a foreland fold along the eastern margin of the South-Central Unit. Site-mean characteristic remanent magnetization directions were determined from 17 sites through thermal demagnetization and principal component analysis. In addition, 72 samples were collected from 39 stratigraphic levels spanning the Upper Eocene marine marls and treated with thermal and alternating field demagnetization techniques. Of these, 53 samples yielded demagnetization trajectories that further constrained the rotation. Comparison of the observed mean paleomagnetic direction from the Oliana anticline with the expected direction indicates a counterclockwise rotation (R ± ΔR) of 20.3° ± 10.9°. Based on the stratigraphic horizons recording the rotation, the age of the rotation is younger than ~34 Ma (after deposition of Unit 3). Data covering the Upper Eocene-Lower Oligocene time interval indicate a similar magnitude of rotation, suggesting that late stage emplacement of thrust sheets hinterlandward of the Oliana anticline controlled the rotation, with rotation accommodated along regionally extensive evaporites. The well-constrained timing relationships between thrusting and rotation and the regional and local transport directions, suggest that the South-Central Unit is a progressive curve that formed through distributed shortening.
    Description: Published
    Description: 435-449
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Pyrenees ; Oliana anticline ; synorogenic strata ; paleomagnetism ; salients ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 39
    Publication Date: 2017-04-04
    Description: Neogene intermontane basins in Almería Province, SE Spain, display excellent exposures of Messinian (Late Miocene) sequences. The Sorbas, Almería-Níjar and Vera basins maintained connection with the Mediterranean throughout the Messinian, except during the major desiccation phase leading to the formation of salt in the deep centre of the Western Mediterranean. These basins were part of the Western Mediterranean with no separate link to the Atlantic Ocean. The presence of normal marine sediments in these basins reflects the Western Mediterranean watermass. Messinian pre-evaporitic sediments in the basins of southeastern Almería do not show gradual change towards evaporite deposits. Instead they contain stenohaline invertebrates right up to a major erosion surface that separates them from overlying gypsum deposits. This contradicts suggestion of progressive salinity increase in this part of the Western Mediterranean prior to the Messinian Salinity Crisis (MSC); it also indicates that initiation of evaporite precipitation was not synchronous throughout the Mediterranean Basin. There is no major erosion surface within or at the top of the evaporites in these Almería basins, and the gypsum beds exhibit upward transition to siliciclastic and carbonate deposits. This is inconsistent with a model of Messinian Mediterranean evaporite formation whereby deposition of marginal evaporites was followed by their erosion during drawdown that resulted in formation of evaporites in the centre of the Western Mediterranean. The presence of stenohaline biotas in siliciclastic deposits interbedded with the gypsum and in the Messinian post-evaporitic sediments, challenges the view that a long-standing large body of brackish water (the Lago Mare) filled the Western Mediterranean following the MSC and prior to Early Pliocene flooding. It also contradicts the concept of many relatively small brackish basins spread across an otherwise desiccated Western Mediterranean basin. The basins of southeastern Almería record normal marine Early Messinian sedimentation that was abruptly interrupted by sealevel fall. This drawdown most likely resulted in precipitation of evaporites in the central deep Western Mediterranean basin. Following this episode, final marine reflooding of the Western Mediterranean took place during the Late Messinian, and the Mediterranean Sea rose to a level similar to, or higher than, that preceding the Salinity Crisis.
    Description: Published
    Description: 131-154
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Almería ; Evaporites ; Messinian Salinity Crisis ; Palaeoenvironments ; Western Mediterranean ; Spain ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 40
    Publication Date: 2017-04-04
    Description: A new method combining measurements of soil CO2 flux and determinations of the carbon isotopic composition of soil CO2 efflux was developed in order to qualitatively and quantitatively characterise the CO2 source feeding the soil CO2 diffuse degassing. The method was tested in March 2007 at the Solfatara of Pozzuoli volcano degassing area (Naples, Italy) where more than 300 measurements of soil CO2 flux and determinations of the carbon isotopic composition of soil CO2 efflux were performed, surveying Solfatara crater and its surroundings. The wide range of CO2 flux and CO2 isotopic composition values (from 8.4 g m−2 d−1 to 28,834 g m−2 d−1, and from 0.73‰ to −33.54‰, respectively), together with their statistical distributions suggests the occurrence of multiple CO2 sources feeding soil degassing. The combined interpretation of flux and isotopic data allows us to identify and characterise two distinct gas sources: a hydrothermal and a biogenic source. The soil CO2 from the hydrothermal source is characterised by a mean δ13CCO2 of −2.3‰±0.9‰, hence close to the isotopic composition of the fumarolic CO2 (δ13CCO2=−1.48‰± 0.22‰) and by a mean CO2 flux of 2875 g m−2 d−1. The CO2 from the biogenic source is characterised by a mean δ13CCO2 of −19.4‰±2.1‰, and by a mean CO2 flux of 26 g m−2 d−1, which are both in the range of the typical values for biologic CO2 soil degassing. This reliable characterisation of the biogenic CO2 flux would not have been possible by solely applying a statistical analysis of the CO2 flux values, which is commonly applied in volcanological studies for the partitioning between background fluxes and anomalous CO2 fluxes. A map of the Solfatara diffuse degassing structure was derived from the estimated threshold for the biogenic CO2 flux, highlighting that soil degassing of hydrothermal CO2 mixed in different proportion with biogenic CO2 occurs over a large area (~0.8 km2), which extends over the inner part of the Solfatara crater as well as the eastern periphery, corresponding with a NW–SE fault system. The presented method and data analysis are important means of surveillance of the volcanic activity.
    Description: Published
    Description: 372–379
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: CO2 soil degassing ; CO2 flux ; carbon dioxide ; carbon isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 41
    Publication Date: 2017-04-04
    Description: Lake Averno is situated in the homonymous crater in the northwestern sector of the Campi Flegrei active volcanic system in Campania region, Italy. In February 2005 a fish kill event was observed in the lake, prompting a geochemical survey to ascertain the possible cause. In February 2005 a geochemical survey revealed that the lake water was unstratified chemically and isotopically, presumably, as a result of lake overturn. This fish kill phenomenon was recorded at least two other times in the past. In contrast to the February 2005 results, data collected in October 2005, shows the Lake Averno to be stratified, with an oxic epilimnion (surface to 6 m) and an anoxic hypolimnion (6 m to lake bottom at about 33 m). Chemical and isotopic compositions of Lake Averno waters suggest an origin by mixing of shallow waters with a Na–Cl hydrothermal component coupled with an active evaporation process. The isotopic composition of Dissolved Inorganic Carbon, as well as the composition of the non-reactive dissolved gas species again supports the occurrence of this mixing process. Decreasing levels of SO4 and increasing levels of H2S and CH4 contents in lake water with depth, strongly suggests anaerobic bacterial processes are occurring through decomposition of organic matter under anoxic conditions in the sediment and in the water column. Sulfate reduction and methanogenesis processes coexist and play a pivotal role in the anaerobic environment of the Lake Averno. The sulfate reducing bacterial activity has been estimated in the range of 14–22 μmol m−2 day−1. Total gas pressure of dissolved gases ranges between 800 and 1400 mbar, well below the hydrostatic pressure throughout the water column, excluding the possibility, at least at the survey time, of a limnic eruption. Vertical changes in the density of lake waters indicate that overturn may be triggered by cooling of epilimnetic waters below 7 °C. This is a possible phenomenon in winter periods if atmospheric temperatures remain frosty for enough time, as occurred in February 2005. The bulk of these results strongly support the hypothesis that fish kill was caused by a series of events that began with the cooling of the epilimnetic waters with breaking of the thermal stratification, followed by lake overturn and the rise of toxic levels of H2S from the reduced waters near the lake bottom.
    Description: Published
    Description: 305–316
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: lake Averno ; dissolved gases ; stable isotopes ; stable isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 42
    Publication Date: 2021-09-08
    Description: The Gran Sasso range is a striking salient formed by two roughly rectilinear E–W and N–S limbs. In the past ∼90° counterclockwise (CCW) rotations from the eastern Gran Sasso were reported [Tectonophysics 215 (1992) 335], suggesting west–east increase of rotation-related northward shortening along the E–W limb. In this paper, we report on paleomagnetic data from Meso-Cenozoic sedimentary dykes and strata cropping out at Corno Grande (central part of the E–W Gran Sasso limb), the highest summit of the Apennine belt. Predominant northwestward paleomagnetic declinations (in the normal polarity state) from both sedimentary dykes and strata are observed. When compared to the expected declination values for the Adriatic foreland, our data document no thrusting-related rotation at Corno Grande. The overall paleomagnetic data set coupled with the available geological information shows that the Gran Sasso arc is in fact a composite structure, formed by an unrotated-low shortening western (E–W trending) limb and a strongly CCW rotated eastern salient. Late Messinian and post-early Pliocene shortening episodes documented along the Gran Sasso front indicate that belt building and arc formation occurred during two distinct episodes. We suggest that the southern part of a late Messinian N–S front was reactivated during early–middle Pliocene time, forming a tight range salient due to CCW rotations and differential along-front shortening rates. The formation of a northward displacing bulge in an overall NW–SE chain is likely a consequence of the collision between the Latium-Abruzzi and Apulian carbonate platforms during northeastward propagation of the Apennine wedge, inducing lateral northward extrusion of Latium-Abruzzi carbonates towards ductile basinal sediment areas.
    Description: Published
    Description: 183-197
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Gran Sasso range ; Mountain front ; Central Apennines ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 43
    Publication Date: 2022-05-30
    Description: We report on new palaeomagnetic and magnetic fabric analyses of mainly Upper Miocene sedimentary sequences from the external central Apennine fold and thrust belt (Molise area), where the principal compressive structures are clearly non-coaxial. The sampling was carried out on the E–W-oriented Matese–Frosolone thrust sheet, that for its geographical position and structural setting (superposition of thrusting, strike-slip and extensional tectonics since Late Miocene to present-day) represents a key structure for the comprehension of the Neogene–Quaternary evolution of the entire Molise area. Palaeomagnetic results suggest that the Matese–Frosolone thrust sheet counterclockwise rotated at least 35° after Messinian times. These data confirm that the present-day trend variability observed in the main compressional structures in the Apennine chain can be related to rotations about vertical axes rather than to changes in the stress field orientation, at least since Late Miocene times. Magnetic fabric analyses indicate that the studied sediments were subjected to very mild deformation, suggesting that the surface emergence of the thrust front of the Matese–Frosolone unit is located farther north, far from the studied area. Well-defined magnetic lineations of tectonic origin were only observed in sites close to localised belts of strike-slip deformation.
    Description: Published
    Description: 143-157
    Description: JCR Journal
    Description: reserved
    Keywords: Apennines ; palaeomagnetism ; anisotropy of magnetic susceptibility ; structural geology ; Neogene ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 44
    Publication Date: 2024-05-09
    Description: A geochemical survey of thermal waters collected from submarine vents at Panarea Island (Aeolian Islands, southern Italy) was carried out from December 2002 to March 2007, in order to investigate i) the geochemical processes controlling the chemical composition of the hydrothermal fluids and ii) the possible relations between the chemical features of the hydrothermal reservoir and the activity of the magmatic system. Compositional data of the thermal water samples were integrated in a hydrological conceptual model, which describes the formation of the vent fluid by mixing of seawater, seawater concentrated by boiling, and a deep, highly-saline end-member, whose composition is regulated by water-rock interactions at relatively high temperature and shows clear clues of magmatic-related inputs. The chemical composition of concentrated seawater was assumed to be represented by that of the water sample having the highest Mg content. The composition of the deep end-member was instead calculated by extrapolation assuming a zero-Mg end-member. The Na–K–Ca geothermometer, when applied to the thermal end-member composition, indicated an equilibrium temperature of approximately 300 °C, a temperature in agreement with the results obtained by gas-geothermometry.
    Description: Published
    Description: 246-254
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: low-pH waters; shallow submarine hydrothermal springs; Panarea Island ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 45
    Publication Date: 2017-04-04
    Description: The Deep Western Boundary Current (DWBC) inflow to the SW Pacific is one of the largest, transporting ~40% of the total input of deep water to the world’s oceans. Here we use a sedimentary record from the giant piston core MD97-2114 collected on the northern flank of the Chatham Rise located at 1935 m water depth, east of New Zealand, to investigate DWBC variability during the Pleistocene epoch when the period of glacial cycles changed progressively from a 41 kyr to 100 kyr rhythm. Magnetic grain-size may be directly related to orbitally forced fluctuations in the strength of the upper circumpolar deep water (UCDW) through its interaction with terrigenous sediments supplied from the south and west. The long-term trends in magnetic properties are characterized by two main perturbations centered at 870 ka (Marine Isotope Stage, MIS 22) 450 ka (MIS 12), which is broadly consistent with the inferred perturbation during the mid-Pleistocene climate transition based on sedimentological paleocurrent reconstruction from Ocean Drilling Program Site 1123 located at 3290 m water depth in the main core of the DWBC flow on the North Chatham Drift. This similarity suggests that both the upper and middle CDW are modulated by similar processes and fluctuations of Antarctic Bottom Water production could be directly responsible for this deep Pacific Ocean inflow variability over the past 1.2 Ma.
    Description: Published
    Description: 107-118
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: DWBC ; Chatham Rise ; New Zealand; ; Pleistocene; ; magnetostratigraphy; ; environmental magnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 46
    Publication Date: 2017-04-04
    Description: The sustained and uninterrupted plume degassing at Mount Etna volcano, Southern Italy, represents the troposphere’s most prominent natural source of fluorine. Of the ~ 200 Mg of fluorine (as HFg) emitted daily by the volcano, 1.6±2.7 Mg are deposited by wet and dry deposition. Fluorine-deposition via volcanic ash, here characterised for the first time, can be quite significant during volcanic eruptions (i.e. 60 Mg of fluorine were deposited during the 2001 eruption through volcanic ash, corresponding to ~ 85% of the total fluorine deposition). Despite the fact that these depositions are huge, the fate of the deposited fluorine and its impact on the environment are poorly understood. We herein present original data on fluorine abundance in vegetation (Castanea Sativa and Pinus Nigra) and andosoils from the volcano’s flank, in the attempt to reveal the potential impact of volcanogenic fluorine emissions. Fluorine contents in chestnut leaves and pine needles are in the range 1.8-35 µg/g and 2.1-74 µg/g respectively; they exceed the typical background concentrations in plants growing in rural areas, but fall within the lower range of typical concentrations in plants growing near high fluorine anthropogenic emission sources. The rare plume fumigations on the lower flanks of Mt Etna (distance 〉 4 km from summit craters) are probably the cause of the “undisturbed” nature of Etnean vegetation: climatic conditions, which limit the growth of vegetation on the upper regione deserta, are a natural limit to the development of more severe impacts. High fluorine contents, associated with visible symptoms, were only measured in pine needles at three sites, located near recently-active (2001 to 2003) lateral eruptive fractures. Total fluorine contents (FTOT) in the Etnean soils have a range of 112-341 µg/g, and fall within the typical range of undisturbed soils; fluorine extracted with distilled water (FH2O) have a range of 5.1 to 61 µg/g and accounts for 2-40 % of FTOT. FH2O is higher in topsoils from the eastern flank (downwind), while it decreases with depth in soil profiles and on increasing soil grain size (thereby testifying to its association with clay-mineral-rich, fine soil fractions). The fluorine adsorption capacity of the andosoils acts as a natural barrier that protects the groundwater system.
    Description: Published
    Description: 87-101
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Mt. Etna ; Fluorine ; environmental volcanology ; impact of volcanic F ; soils ; vegetation ; volcanic ash ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 47
    Publication Date: 2017-04-04
    Description: Introduction of a special issue of the journal
    Description: no abstract
    Description: Published
    Description: 1-4
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Earth's degassing ; volcanic areas ; seismic areas ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 48
    Publication Date: 2017-04-04
    Description: We report on a high-resolution magnetostratigraphic analysis of a continuous 97.5 m thick upper Sinemurian–Pliensbachian pelagic limestone section (“Corniola” formation) exposed at Bosso Stirpeto (Marche, Italy), where detailed ammonite and calcareous nannofossil biozonation is available. The early Pliensbachian (Carixian) is notably expanded (74.35 m excluding few slumps), implying an average sedimentation rate of 28.6 m/Myr. Both the Carixian boundaries and three additional intra-Carixian ammonite zone boundaries are tied up with polarity magnetozones. We find that a normal polarity characterizes the latest Sinemurian and Sinemurian/Carixian boundary, while a reverse polarity (punctuated by three short normal polarity magnetozones) dominates the Carixian. In the lower Carixian sediments, two 3.39–4.65 m thick (excluding the slumps) intervals are characterized by persistent transitional (between 45°N and 45°S) virtual geomagnetic pole (VGP) latitudes, but this seems not to be the result of mineral magnetic artefacts, antipodal polarity averaging, or sedimentary layer disturbance. Thus we suggest that in two ∼120 and 160 kyr-long time intervals during the early Carixian, the VGPs were predominantly confined at tropical–equatorial latitudes of the Earth. Such geomagnetic feature has never been documented before elsewhere in other time intervals, and requires further paleomagnetic investigation of other expanded Carixian section to be confirmed. The magnetic polarity profile (including the transitional direction intervals) of Bosso Stirpeto may compare with that from similarly expanded Carixian sections (Breggia, Switzerland), and cores (Montcornet, Paris basin). However, the matching of magnetic polarity zones requires a significant aging of some parts of the magnetostratigraphic profile at both Breggia and Montcornet.
    Description: Published
    Description: 344-359
    Description: 3.4. Geomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: magnetostratigraphy ; Pliensbachian ; Carixian ; Corniola formation ; geomagnetic field ; Bosso valley ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 49
    Publication Date: 2017-04-04
    Description: Metamorphic and magmatic garnets are known to fractionate REE, with generally HREE-enriched patterns, and high Lu/ Hf and Sm/Nd ratios, making them very useful as geochemical tracers and in geochronological studies. However, these garnets are typically Al-rich (pyrope, almandine, spessartine, and grossular) and little is known about garnets with a more andraditic (Fe3+) composition, as frequently found in skarn systems. This paper presents LA-ICP-MS data for garnets from the Crown Jewel Au-skarn deposit (USA), discusses the factors controlling incorporation of REE into garnets, and strengthens the potential of garnet REE geochemistry as a tool to help understand the evolution of metasomatic fluids. Garnets from the Crown Jewel deposit range from Adr30Grs70 to almost pure andradite (Adr〉99). Fe-rich garnets (Adr〉90) are isotropic, whereas Al-rich garnets deviate from cubic symmetry and are anisotropic, often showing sectorial dodecahedral twinning. All garnets are extremely LILE-depleted, Ta, Hf, and Th and reveal a positive correlation of RREE3+ with Al content. The Al-rich garnets are relatively enriched in Y, Zr, and Sc and show ‘‘typical’’ HREE-enriched and LREE-depleted patterns with small Eu anomalies. Fe-rich garnets (Adr〉90) have much lower RREE and exhibit LREE-enriched and HREE-depleted patterns, with a strong positive Eu anomaly. Incorporation of REE into garnet is in part controlled by its crystal chemistry, with REE3+ following a coupled, YAG-type substitution mechanism ð½ X2þ VIII 1 ½REE3þ VIII þ1 ½ Si4þ IV 1½Z3þ IV þ1Þ, whereas Eu2+ substitutes for X2+ cations. Thermodynamic data (e.g., Hmixing) in grossular– andradite mixtures suggest preferential incorporation of HREE in grossular and LREE in more andraditic compositions. Variations in textural and optical features and in garnet geochemistry are largely controlled by external factors, such as fluid composition, W/R ratios, mineral growth kinetics, and metasomatism dynamics, suggesting an overall system that shifts dynamically between internally and externally buffered fluid chemistry driven by fracturing. Al-rich garnets formed by diffusive metasomatism, at low W/R ratios, from host-rock buffered metasomatic fluids. Fe-rich garnets grow rapidly by advective metasomatism, at higher W/R ratios, from magmatic-derived fluids, consistent with an increase in porosity by fracturing.
    Description: Published
    Description: 185-205
    Description: 3.6. Fisica del vulcanismo
    Description: 3.8. Geofisica per l'ambiente
    Description: JCR Journal
    Description: reserved
    Keywords: A LA-ICP-MS ; Crown Jewel ; 04. Solid Earth::04.01. Earth Interior::04.01.04. Mineral physics and properties of rocks ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 50
    Publication Date: 2017-04-04
    Description: A physical model based on the advective–diffusion theory was developed in order to describe the mixing between a deep gas source and the atmosphere. The model was used to predict the isotopic fractionation of carbon in soil CO2. Gas samples were collected at different depths in areas characterized by different geological settings and CO2 fluxes. The relative theoretical and experimental isotopic profiles were compared and a good agreement was found. These profiles show how the isotopic composition of CO2 changes through the upper few decimeters of soil and how the amount of the isotopic fractionation is strongly influenced by soil CO2 flux. Finally, the model was used to derive the carbon isotopic composition of unfractioned deep CO2 source for all the investigated sites
    Description: Published
    Description: 3016–3027
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Carbon isotope fractionation ; soil degassing ; gas transport ; D13C(CO2) ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 51
    Publication Date: 2017-04-04
    Description: The analysis of gaseous compositions from Solfatara (Campi Flegrei, South Italy) fumaroles since the early 1980s, clearly reveals a double thermobarometric signature. A first signature at temperatures of about 360 C was inferred by methanebased chemical–isotopic geoindicators and by the H2/Ar geothermometer. These high temperatures, close to the critical point of water, are representative of a deep zone where magmatic gases flash the hydrothermal liquid, forming a gas plume. A second signature was found to be at around 200–240 C. At these temperatures, the kinetically fast reactive species (H2 and CO) re-equilibrate in a pure vapor phase during the rise of the plume. A combination of these observations with an original interpretation of the oxygen isotopic composition of the two dominant species, i.e. H2O and CO2, shed light on the origin of fumarolic fluids by showing that effluents are mixture between fluids degassed from a magma body and the vapor generated at about 360 C by the vaporization of hydrothermal liquids. A typical ‘andesitic’ water type (dD 20&, d18O 10&) and a CO2-rich composition ðXCO2 0:4Þ has been inferred for the magmatic fluids, while for the hydrothermal component a meteoric origin and a CO2 fugacity fixed by fluid-rock reaction at high temperatures have been estimated. In the time the fraction of magmatic fluids in the fumaroles increased (up to 0.5) at each seismic and ground uplift crisis (bradyseism) which occurred at Campi Flegrei, suggesting that bradyseismic crises are triggered by periodic injections of CO2-rich magmatic fluids at the bottom of the hydrothermal system
    Description: Published
    Description: 3040-3055
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: origin of the fumaroles ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 52
    Publication Date: 2017-04-04
    Description: A new high-resolution Apparent Polar Wander Path (APWP) segment has been obtained from the magnetostratigraphy of four Kimmeridgian to Lower Aptian sections in the Northern Apennines (Italy). The use of paleomagnetic data for determination of the Adria APWP was hampered by the large local rotations linked to Apennine tectonics, characterized by folds and thrusts developed during the Neogene. To overcome this problem, we have computed relative rotations between time overlapping sections and realigned them in a common declination reference frame (namely the Bosso section). We synthesized a new high-resolution 150 to 125 Ma APWP for Adria, which has a similar shape to the time-equivalent segment of the synthetic APWP of Africa of Besse and Courtillot [J., Besse, V., Courtillot, Apparent and true polar wander and the geometry of the geomagnetic field over the last 200 Myr, J. Geophys. Res. 107(B11) (2002), doi:10.1029/200JB000050]. A 26° clockwise rotation of our combined Adria APWP places it in almost perfect overlap with African data of same age, confirming that the Adria promontory moved coherently with Africa during this time span, whereas the counterclockwise rotation of Adria with respect to Africa was introduced later, most probably during Apennines orogenesis. Finally, we discuss in relation with worldwide plate evolution the peculiar shape of our APWP, which displays a hairpin turn during Berriasian time, and dates the main Late Jurassic/Early Cretaceous change in plate motion at around anomaly M16.
    Description: Published
    Description: 329-342
    Description: 3.4. Geomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: paleomagnetism ; Apparent Polar Wander Path ; magnetostratigraphy ; Adria ; Italy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
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  • 53
    Publication Date: 2022-06-08
    Description: An integrated sedimentological, magnetostratigraphic, and paleontological study of the Vallcebre section (south eastern Pyrenees, Spain) is carried out in order to define and portray the transition from the Cretaceous to the Tertiary in a continental setting. A robust magnetostratigraphy is correlated to the standard polarity scale in light of known biochronological constraints (charophyte, marine invertebrates, eggshells and other dinosaur remains). Our results show that this section is among the thickest stratigraphic records for the continental Maastrichtian in the Old World. Sedimentology indicates a progressive regression from marine through lagoonal to entirely continental environments. The section is dominated by mudstones deposited under low energy conditions. Exceptionally, a basin-wide regression maximum is recorded some time before the Cretaceous–Tertiary boundary (K/T). This regression maximum is marked by the input of coarse-grained (alluvial) sediments that record a dramatic change in the landscape (quiet mud plains changed to sandy floodplains deposited by high-energy currents). After a period of renewed quiescence following the regression maximum, a Cenozoic flooding took place. Such terminal Cretaceous sequence of events has been recorded in shorter sections in several other basins from southwestern Europe. This energetic sediment input suggests that some time before the K/T event, a sudden paleoenvironmental reorganization took place in the continental basins of south western Europe.
    Description: Published
    Description: 35-47
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: K/T boundary ; magnetostratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 54
    Publication Date: 2017-04-04
    Description: Despite its impact in understanding oceanic crust formation and eruptive styles of related volcanism, magma dynamics at midocean ridges are poorly known. Here, we propose a new method to assess ascent rates of mid-ocean ridge basalt (MORB) magmas,as well as their pre- and sin-eruptive dynamics. It is based on the idea that a rising magma can reach a variable degree of both CO2 supersaturation in melt and kinetic fractionation among noble gases in vesicles in relation to its ascent rate through the crust. To quantify the relationship, we have used a model of multicomponent bubble growth in MORB melts, developed by extending the single-component model of Proussevitch and Sahagian [A.A. Proussevitch, D.L. Sahagian, Dynamics and energetics of bubble growth in magmas: analytical formulation and numerical modeling, J. Geophys. Res. 103 (1998), 18223–18251.] to CO2–He–Ar gas mixtures. After proper parameterization, we have applied it to published suites of data having the required features (glasses from Pito Seamount and mid-Atlantic ridges). Our results highlight that the investigated MORB magmas display very different ranges of ascent rates: slow rises of popping rock forming-magmas that cross the crust (0.01–0.5 m/s), slightly faster rates of energetic effusions (0.1–1 m/s), up to rates of 1–10 m/s which fall on the edge between lava effusion and Hawaiian activity. Inside a single plumbing system, very dissimilar magma dynamics highlight the large differences in compressive stress of the oceanic crust on a small scale. Constraints on how the systems of ridges work, as well as the characteristics of the magmatic source, can also be obtained. Our model shows how measurements of both the dissolved gas concentration in melt and the volatile composition of vesicles in the same sample are crucial in recognizing the kinetic effects and definitively assessing magma dynamics. An effort should be made to correctly set the studied samples in the sequence of volcanic submarine deposits where they are collected. Enhanced knowledge of a number of physical properties of gas-bearing MOR magmas is also required, mainly noble gas diffusivities, to describe multicomponent bubble growth at a higher confidence level.
    Description: Published
    Description: 138-158
    Description: partially_open
    Keywords: Bubble growth ; MORB ; Noble gas ; Kinetic fractionation ; Modeling ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics
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  • 55
    Publication Date: 2017-04-03
    Description: Several types of natural gas emissions (soil gas, low temperature fumaroles, gas bubbling in mud pools) were collected monthly on Mt. Etna volcano between July 2000 and July 2003 both from its summit and its flanks. Samples were analysed for the determination of the concentrations of CO2, CH4, He, H2, CO as well as the isotopic ratios of 13 14 C/ C of CO2 (δ13C) and He (R/Ra). The analysed gases were chemically divided into two groups: air-contaminated (from sites closer to the summit vents of Mt. Etna) and CO2 - rich. Among the latter, samples from the lower SW flank of the volcano showed high contents of biogenic thermogenic and/or microbial CH4. Isotopic shift in the δ13C values is caused by input of organic CO2 and/or by interaction between magmatic CO2 and shallow ground water as a function of water temperature and CO2 flux from depth. Based on a graphic method applied to δ13 TDIC C of some ground water, the inferred isotopic composition of the pristine magmatic gas at Mt. Etna is characterised by δ13C values ranging from -2 to -1 0 00 . During the period July 2000 - July 2003 significant variations were observed in many of the investigated parameters almost at all monitored sites. Seasonal influences were generally found to be negligible, with only a limited effect of air temperature changes on soil CO2 and ground temperature in only two of the air-contaminated sites. The largest chemical anomalies were observed in the air-contaminated sites, probably because of the strong buffering power of local ground water on gases released through the most peripheral areas where the CO2-rich sites are located. The anomalous changes observed during the study period can be explained in terms of progressive gas release from separate batches of magma that ascend towards the surface in a step-wise manner. Data relevant to the period following the 2002-03 eruption suggest that magma kept accumulating beneath the volcano, thus increasing the probability of a new large eruption at Mt. Etna.
    Description: Istituto Nazionale di Geofisica e Vulcanologia, Sezione di Palermo
    Description: Published
    Description: 805-841
    Description: open
    Keywords: Mt. Etna ; Geochemistry ; Gases ; Eruptive activity ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 56
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    Elsevier
    In:  Taran Y. A., Inguaggiato S., Marin M., and Yurova L. M. (2002) Geochemistry of fluids from submarine hot springs at Punta de Mita, Nayarit, Mexico. J. Volcanol. Geoth. Res. 115, 329-338.
    Publication Date: 2017-04-04
    Description: We thank R.M. Prol-Ledesma for her comment on the paper by Taran et al. (2002a) and the new data presented on the water composition of the Punta de Mita (PM) submarine springs. Prol-Ledesma (2003) comments refer to a supposedly wrong citation, superficial description of the geological background, incorrect method of water sampling, wrong approach for the estimation of the end-member composition, irrelevant discussion on the origin of fluids and, lastly, the using of someone else’s ideas and conclusions. In addition, she claims that our data on the fluid chemistry of the springs are not the first (original)ones. The Comment is supported by numerous references to publications by Prol-Ledesma et al. The text below follows the rubrics in the Comment.
    Description: Published
    Description: 319-322
    Description: partially_open
    Keywords: submarine springs ; hydrothermal systems ; geothermometry ; He-isotopes ; formation waters ; Jalisco Block ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 57
    Publication Date: 2017-04-04
    Description: The northwestern flank of the Colli Albani, a Quaternary volcanic complex near Rome, is characterised by high CO2 values and Rn activities in the groundwater and by the presence of zones with strong emission of gas from the soil. The most significant of these zones is Cava dei Selci where many houses are located very near to the gas emission site. The emitted gas consists mainly of CO2 (up to 98 vol) with an appreciable content of H2S (0.8). The He and C isotopic composition indicates, as for all fluids associated with the Quaternary Roman and Tuscany volcanic provinces, the presence of an upper mantle component contaminated by crustal fluids associated with subducted sediments and carbonates. An advective CO2 flux of 37 tons/day has been estimated from the gas bubbles rising to the surface in a small drainage ditch and through a stagnant water pool, present in the rainy season in a topographically low central part of the area. A CO2 soil flux survey with an accumulation chamber, carried out in February-March 2000 over a 12 000 m2 surface with 242 measurement points, gave a total (mostly conductive) flux of 61 tons/day. CO2 soil flux values vary by four orders of magnitude over a 160-m distance and by one order of magnitude over several metres. A fixed network of 114 points over 6350 m2 has been installed in order to investigate temporal flux variations. Six surveys carried out from May 2000 to June 2001 have shown large variations of the total CO2 soil flux (8/25 tons/day). The strong emission of CO2 and H2S, which are gases denser than air, produces dangerous accumulations in low areas which have caused a series of lethal accidents to animals and one to a man. The gas hazard near the houses has been assessed by continuously monitoring the CO2 and H2S concentration in the air at 75 cm from the ground by means of two automatic stations. Certain environmental parameters (wind direction and speed; atm P, T, humidity and rainfall) were also continuously recorded. At both stations, H2S and CO2 exceeded by several times the recommended concentration thresholds. The highest CO2 and H2S values were recorded always with wind speeds less than 1.5 m/s, mostly in the night hours. Our results indicate that there is a severe gas hazard for people living near the gas emission site of Cava dei Selci, and appropriate precautionary and prevention measures have been recommended both to residents and local authorities.
    Description: - GNV funded research project Gas Hazard of Colli Albani
    Description: Published
    Description: 81^94
    Description: partially_open
    Keywords: Colli Albani ; CO2 flux ; H2S ; gas hazard ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 58
    Publication Date: 2017-04-04
    Description: Chlorine- and sulphur-bearing compounds in fumarole discharges of the La Fossa crater at Vulcano Island (Italy) can be modelled by a mixing process between magmatic gases and vapour from a boiling hydrothermal system. This allows estimating the compounds in both endmembers. Magma degassing cannot explain the time variation of sulphur and HCl concentrations in the deep endmember, which are more probably linked to reactions of solid phases at depth, before mixing with the hydrothermal vapours. Based on the P^T conditions and speciation of the boiling hydrothermal system below La Fossa, the HCl and Stot contents in the hydrothermal vapours were used to compute the redox conditions and pH of the aqueous solution. The results suggest that the haematite magnetite buffer controls the hydrothermal fO2 values, while the pH has increased since the end of the 1970s. The main processes affecting pH values may be linked to Na^Ca exchanges between evolved seawater, feeding the boiling hydrothermal system, and local rocks. While Na is removed from water, calcium enters the solution, undergoes hydrolysis and produces HCl,lowering the pH of the water. The increasing water^rock ratio within the hydrothermal system lowers the Ca availability, so the aqueous solution becomes less acidic. Seawater flowing towards the boiling hydrothermal brine dissolves a large quantity of pyrite along its path. In the boiling hydrothermal system, dissolved sulphur precipitates as pyrite and anhydrite, and becomes partitioned in vapour phase as H2S and SO2. These results are in agreement with the paragenesis of hydrothermal alteration minerals recovered in drilled wells at Vulcano and are also in agreement with the isotopic composition of sulphur emitted by the crater fumaroles.
    Description: Published
    Description: 137-150
    Description: partially_open
    Keywords: chlorine ; sulphur ; hydrothermal system ; genetic processes ; Vulcano Island ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 59
    Publication Date: 2017-04-04
    Description: This work addresses the study of fluid circulation of the Stromboli island using a dense coverage of self-potential (SP) and soil CO2 data. A marked difference exists between the northern flank and the other flanks of the island. The northern flank exhibits (1) a typical negative SP/altitude gradient not observed on the other flanks, and (2) higher levels of CO2. The general SP pattern suggests that the northern flank is composed of porous layers through which vadose water flows down to a basal water table, in contrast to the other flanks where impermeable layers impede the vertical flow of vadose water. In the Sciara del Fuoco and Rina Grande-Le Schicciole landslide complexes, breccias of shallow gliding planes may constitute such impermeable layers whereas elsewhere, poorly permeable, fine-grained pyroclastites or altered lava flows may be present. This general model of the flanks also explains the main CO2 patterns: concentration of CO2 at the surface is high on the porous north flank and lower on the other flanks where impermeable layers can block the upward CO2 flux. The active upper part of the island is underlain by a well-defined hydrothermal system bounded by short-wavelength negative SP anomalies and high peaks of CO2. These boundaries coincide with faults limiting ancient collapses of calderas, craters and flank landslides. The hydrothermal system is not homogeneous but composed of three main subsystems and of a fourth minor one and is not centered on the active craters. The latter are located near its border. This divergence between the location of the active craters and the extent of the hydrothermal system suggests that the internal heat sources may not be limited to sources below the active craters. If the heat source strictly corresponds to intrusions at depth around the active conduits, the geometry of the hydrothermal subsystems must be strongly controlled by heterogeneities within the edifice such as craters, caldera walls or gliding planes of flank collapse, as suggested by the correspondence between SP^CO2 anomalies and structural limits. The inner zone of the hydrothermal subsystems is characterized by positive SP anomalies, indicating upward movements of fluids, and by very low values of CO2 emanation. This pattern suggests that the hydrothermal zone becomes self-sealed at depth, thus creating a barrier to the CO2 flux. In this hypothesis, the observed hydrothermal system is a shallow one and it involves mostly convection of infiltrated meteoric water above the sealed zone. Finally, on the base of CO2 degassing measurements, we present evidence for the presence of two regional faults, oriented N41‡ and N64‡, and decoupled from the volcanic structures.
    Description: Published
    Description: 1^18
    Description: partially_open
    Keywords: Stromboli ; hydrothermal system ; self-potential ; soil gas ; carbon dioxide ; Aeolian islands ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 60
    Publication Date: 2017-04-04
    Description: Geochemical research was carried out on cold and hot springs at Popocatepetl (Popo) volcano (Mexico) in 1999 to identify a possible relationship with magmatic activity. The chemical and isotopic composition of the fluids is compatible with strong gas–water interaction between deep and shallow fluids. In fact, the isotopic composition of He and dissolved carbon species is consistent with a magmatic origin. The presence of a geothermal system having a temperature of 80–1008 C was estimated on the basis of liquid geothermometers. A large amount of dissolved CO2 in the springs was also detected and associated with high CO2 degassing.
    Description: Published
    Description: 91– 108
    Description: partially_open
    Keywords: Popocatepetl volcano ; helium isotope composition ; carbon isotope composition ; dissolved gases ; gas–water interaction ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 61
    Publication Date: 2017-04-04
    Description: We have developed a quantitative model of CO2 and H2O isotopic mixing between magmatic and hydrothermal gases for the fumarolic emissions of the La Fossa crater (Vulcano Island, Italy). On the basis of isotope balance equations, the model takes into account the isotope equilibrium between H2O and CO2 and extends the recent model of chemical and energy two-end-member mixing by Nuccio et al. (1999). As a result,the H2O and CO2 content and the dD, d18O, and d13C isotope compositions for both magmatic and hydrothermal end-members have been assessed. Low contributions of meteoric steam, added at a shallow depth, have been also recognized and quantified in the fumaroles throughout the period from 1988 to 1998. Nonequilibrium oxygen isotope exchange also seems to be occurring between ascending gases and wall rocks along some fumarolic conduits. The d13CCO2 of the magmatic gases varies around -3 to 1‰ vs. Peedee belemnite (PDB), following a perfect synchronism with the variations of the CO2 concentration in the magmatic gases. This suggests a process of isotope fractionation because of vapor exsolution caused by magma depressurization. The hydrogen isotopes in the magmatic gases (-1 to -35‰ vs. standard mean ocean water [SMOW]), as well as the above d13CCO2 value, are coherent with a convergent tectonic setting of magma generation, where the local mantle is widely contaminated by fluids released from the subducted slab. Magma contamination in the crust probably amplifies this effect. The computed isotope composition of carbon and hydrogen in the hydrothermal vapors has been used to calculate the dD and d13C of the entire hydrothermal system, including mixed H2O-CO2 vapor, liquid water, and dissolved carbon. We have computed values of about 10‰ vs. SMOW for water and -2 to -6.5‰ vs. PDB for CO2. On these grounds, we think that Mediterranean marine water (dDH2O 10‰) feeds the hydrothermal system. It infiltrates at depth throughout the local rocks, reaching oxygen isotope equilibrium at high temperatures. Interaction processes between magmatic gases and the evolving seawater also seem to occur, causing the dissolution of isotopically fractionated aqueous CO2 and providing the source for hydrothermal carbon. These results have important implications concerning fluid circulation beneath Vulcano and address the more convenient routine of geochemical surveillance.
    Description: Published
    Description: 759–772
    Description: partially_open
    Keywords: isotope geochemistry ; volcanic gases ; mixing modeling ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 62
    Publication Date: 2017-04-04
    Description: The results of the 7 years (1994-2000) of monthly monitoring of spring water before and during eruptions show response to volcanic activity. Low salinity and temperature characterize most of the springs, which are located on the flanks of Popocatepetl Volcano. The pH ranges from 5.8 to 7.8 and temperature from 3 to 36 jC. Oxygen and hydrogen isotopic data show that the water is of meteoric origin, but SO4 2 , Cl , F , HCO3 , B, and SO4 2- /Cl- variations precede main eruptive activity, which is considered linked to influx of magmatic gases and acid fluids that react with sublimates and host rock and mix with the large water system. Na +, Ca2 + , SiO2 and Mg2 + concentrations in the water also increased before eruptive activity. The computed partial pressure of CO2 in equilibrium with spring waters shows values higher than air-saturated water (ASW), with the highest values up to 0.73 bar of pCO2. Boron is detected in the water only preceding the larger eruptions. When present, boron concentration is normally under health standard limits, but in two cases the concentration was slightly above. Other components are within health standard limits, except for F- in one spring.
    Description: Published
    Description: 207– 229
    Description: partially_open
    Keywords: Volcano monitoring ; Spring water chemistry ; Popocatepetl ; Mexico ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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