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  • Articles  (530)
  • John Wiley & Sons
  • 2015-2019  (530)
  • 101
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 123 (2018): 6779-6799, doi:10.1029/2017JC013625.
    Description: Observations of water levels, waves, currents, and bathymetry collected for a month at an unstratified tidal inlet with a shallow (1 to 2 m deep) ebb shoal are used to evaluate the asymmetry in flows and dynamics owing to inertia and waves. Along‐channel currents ranged from −1.5 to 0.6 m/s (positive inland) inside the main (3 to 5 m deep) channel crossing the ebb shoal. Net discharge is negligible, and ebb dominance of the channel flows is owing to inflow and outflow asymmetries near the inlet mouth. Offshore wave heights ranged from 0.5 to 2.5 m. During moderate to large wave events (offshore significant wave heights 〉1.2 m), wave forcing enhanced onshore mass flux near the shoal edge and inside the inlet, leading to reduced ebb flow dominance. Momentum balances estimated with the water depths, currents, and waves simulated with a quasi 3‐D numerical model reproduce the momentum balances estimated from the observations reasonably well. Both observations and simulations suggest that ebb‐dominant bottom stresses are balanced by the ebb‐dominant pressure gradient and the tidally asymmetric inertia, which is a sink (source) of momentum on flood (ebb). Simulations with and without waves suggest that waves drive local and nonlocal changes in the water levels and flows. Specifically, breaking waves at the offshore edge of the ebb shoal induce setup and partially block the ebb jet (local effects), which leads to a more onshore‐directed mass flux, changes to the advection across the ebb shoal, and increased water levels inside the inlet mouth (nonlocal effects).
    Description: WHOI Coastal Ocean Institute Student Research; Office of the Assistant Secretary of Defense for Research and Engineering; National Defense Science and Engineering; National Science Foundation; Office of Naval Research
    Description: 2019-03-22
    Keywords: Inlets ; Waves ; Inertia ; Tidal asymmetry ; Ebb shoal
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  • 102
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2014. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 119 (2014): 8195–8220, doi:10.1002/2014JC010111.
    Description: Eddies can influence biogeochemical cycles through a variety of mechanisms, including the excitation of vertical velocities and the horizontal advection of nutrients and ecosystems, both around the eddy periphery by rotational currents and by the trapping of fluid and subsequent transport by the eddy. In this study, we present an analysis of the influence of mesoscale ocean eddies on near-surface chlorophyll (CHL) estimated from satellite measurements of ocean color. The influences of horizontal advection, trapping, and upwelling/downwelling on CHL are analyzed in an eddy-centric frame of reference by collocating satellite observations to eddy interiors, as defined by their sea surface height signatures. The influence of mesoscale eddies on CHL varies regionally. In most boundary current regions, cyclonic eddies exhibit positive CHL anomalies and anticyclonic eddies contain negative CHL anomalies. In the interior of the South Indian Ocean, however, the opposite occurs. The various mechanisms by which eddies can influence phytoplankton communities are summarized and regions where the observed CHL response to eddies is consistent with one or more of the mechanisms are discussed. This study does not attempt to link the observed regional variability definitively to any particular mechanism but provides a global overview of how eddies influence CHL anomalies.
    Description: This work was funded by NASA grants NNX08AI80G, NNX08AR37G, and NNX10AO98G. DJM gratefully acknowledges NASA grant NNX13AE47G and NSF grant OCE-1048897.
    Description: 2015-06-01
    Keywords: Mesoscale eddies ; Satellite observations ; Physical-biological interaction
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  • 103
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2014. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 15 (2014): 4445–4467, doi:10.1002/2014GC005473.
    Description: Mangaia hosts the most radiogenic Pb-isotopic compositions observed in ocean island basalts and represents the HIMU (high µ = 238U/204Pb) mantle end-member, thought to result from recycled oceanic crust. Complete geochemical characterization of the HIMU mantle end-member has been inhibited due to a lack of deep submarine glass samples from HIMU localities. We homogenized olivine-hosted melt inclusions separated from Mangaia lavas and the resulting glassy inclusions made possible the first volatile abundances to be obtained from the HIMU mantle end-member. We also report major and trace element abundances and Pb-isotopic ratios on the inclusions, which have HIMU isotopic fingerprints. We evaluate the samples for processes that could modify the volatile and trace element abundances postmantle melting, including diffusive Fe and H2O loss, degassing, and assimilation. H2O/Ce ratios vary from 119 to 245 in the most pristine Mangaia inclusions; excluding an inclusion that shows evidence for assimilation, the primary magmatic H2O/Ce ratios vary up to ∼200, and are consistent with significant dehydration of oceanic crust during subduction and long-term storage in the mantle. CO2 concentrations range up to 2346 ppm CO2 in the inclusions. Relatively high CO2 in the inclusions, combined with previous observations of carbonate blebs in other Mangaia melt inclusions, highlight the importance of CO2 for the generation of the HIMU mantle. F/Nd ratios in the inclusions (30 ± 9; 2σ standard deviation) are higher than the canonical ratio observed in oceanic lavas, and Cl/K ratios (0.079 ± 0.028) fall in the range of pristine mantle (0.02–0.08).
    Description: M.J. acknowledges NSF grants EAR-1145202, EAR-1348082, EAR-1347377, and OCE-1153894 that supported this work. E.F.R.-K. thanks the European Synthesys FP7 “Capacities” Specific Program for financing part of the analytical cost of this research. K.T.K. acknowledges French ANR grant ANR-09-BLAN-038 (project SlabFlux) that supported this work. The Nordsim facility is funded and operated as a joint Nordic research infrastructure under an agreement with NOS-N.
    Description: 2015-05-28
    Keywords: Volatiles ; Mantle geochemistry ; Melt inclusions ; HIMU ; Cook Islands ; Mangaia ; Hot spot
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  • 104
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2014. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 119 (2014): 8162–8176, doi:10.1002/2014JC010256.
    Description: The surface layer of the southeast Pacific Ocean (SEP) requires an input of cold, fresh water to balance heat gain, and evaporation from air-sea fluxes. Models typically fail to reproduce the cool sea surface temperatures (SST) of the SEP, limiting our ability to understand the variability of this climatically important region. We estimate the annual heat budget of the SEP for the period 2004–2009, using data from the upper 250 m of the Stratus mooring, located at 85°W 20°S, and from Argo floats. The surface buoy measures meteorological conditions and air-sea fluxes; the mooring line is heavily instrumented, measuring temperature, salinity, and velocity at more than 15 depth levels. We use a new method for estimating the advective component of the heat budget that combines Argo profiles and mooring velocity data, allowing us to calculate monthly profiles of heat advection. Averaged over the 6 year study period, we estimate a cooling advective heat flux of −41 ± 29 W m−2, accomplished by a combination of the mean gyre circulation, Ekman transport, and eddies. This compensates for warming fluxes of 32 ± 4 W m−2 due to air-sea fluxes and 7 ± 9 W m−2 due to vertical mixing and Ekman pumping. A salinity budget exhibits a similar balance, with advection of freshwater (−60 psu m) replenishing the freshwater lost through evaporation (47 psu m) and Ekman pumping (14 psu m).
    Description: This work was supported by NOAA's Climate Program Office and by NSF grant OCE-0745508.
    Description: 2015-05-28
    Keywords: Southeast Pacific ; Heat budget ; Argo ; Stratus mooring
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  • 105
    Publication Date: 2022-05-25
    Description: © The Author(s), 2014. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in MicrobiologyOpen 3 (2014): 860–874, doi:10.1002/mbo3.209.
    Description: Microbial source tracking is an area of research in which multiple approaches are used to identify the sources of elevated bacterial concentrations in recreational lakes and beaches. At our study location in Darwin, northern Australia, water quality in the harbor is generally good, however dry-season beach closures due to elevated Escherichia coli and enterococci counts are a cause for concern. The sources of these high bacteria counts are currently unknown. To address this, we sampled sewage outfalls, other potential inputs, such as urban rivers and drains, and surrounding beaches, and used genetic fingerprints from E. coli and enterococci communities, fecal markers and 454 pyrosequencing to track contamination sources. A sewage effluent outfall (Larrakeyah discharge) was a source of bacteria, including fecal bacteria that impacted nearby beaches. Two other treated effluent discharges did not appear to influence sites other than those directly adjacent. Several beaches contained fecal indicator bacteria that likely originated from urban rivers and creeks within the catchment. Generally, connectivity between the sites was observed within distinct geographical locations and it appeared that most of the bacterial contamination on Darwin beaches was confined to local sources.
    Keywords: 454 Pyrosequencing ; Australia ; Bacteria ; DGGE ; Fecal ; Sewage ; Tracking ; Tropical
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  • 106
    Publication Date: 2022-05-25
    Description: © The Author(s), 2014. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Geophysical Research Letters 41 (2014): 8987–8993, doi:10.1002/2014GL062274.
    Description: Observations at the Columbia River plume show that wave breaking is an important source of turbulence at the offshore front, which may contribute to plume mixing. The lateral gradient of current associated with the plume front is sufficient to block (and break) shorter waves. The intense whitecapping that then occurs at the front is a significant source of turbulence, which diffuses downward from the surface according to a scaling determined by the wave height and the gradient of wave energy flux. This process is distinct from the shear-driven mixing that occurs at the interface of river water and ocean water. Observations with and without short waves are examined, especially in two cases in which the background conditions (i.e., tidal flows and river discharge) are otherwise identical.
    Description: This work was supported by the Office of Naval Research, as part of the Data Assimilation and Remote Sensing for Littoral Applications (DARLA) project and in coordination with the Rivers and Inlets (RIVET) program.
    Keywords: Wave breaking ; Turbulence ; Mixing ; Wave-current interaction ; River plume
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  • 107
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2014. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 41 (2014): 8935–8943, doi:10.1002/2014GL061357.
    Description: Superstorm Sandy was a massive storm that impacted the U.S. East Coast on 22–31 October 2012, generating large waves, record storm surges, and major damage. The Coupled Ocean-Atmosphere-Wave-Sediment Transport modeling system was applied to hindcast this storm. Sensitivity experiments with increasing complexity of air-sea-wave coupling were used to depict characteristics of this immense storm as it underwent tropical to extratropical transition. Regardless of coupling complexity, model-simulated tracks were all similar to the observations, suggesting the storm track was largely determined by large-scale synoptic atmospheric circulation, rather than by local processes resolved through model coupling. Analyses of the sea surface temperature, ocean heat content, and upper atmospheric shear parameters showed that as a result of the extratropical transition and despite the storm encountering much cooler shelf water, its intensity and strength were not significantly impacted. Ocean coupling was not as important as originally thought for Sandy.
    Description: Research support provided by USGS Coastal Process Project, NOAA grant NA11NOS0120033, and NASA grant NNX13AD80G is much appreciated.
    Description: 2015-06-16
    Keywords: Hurricane Sandy ; Landfall ; Air-sea-wave coupling
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  • 108
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Ecology and Evolution 5 (2015): 1278–1290, doi:10.1002/ece3.1437.
    Description: Compound-specific stable isotope analysis (CSIA) of amino acids (AA) has rapidly become a powerful tool in studies of food web architecture, resource use, and biogeochemical cycling. However, applications to avian ecology have been limited because no controlled studies have examined the patterns in AA isotope fractionation in birds. We conducted a controlled CSIA feeding experiment on an avian species, the gentoo penguin (Pygoscelis papua), to examine patterns in individual AA carbon and nitrogen stable isotope fractionation between diet (D) and consumer (C) (Δ13CC-D and Δ15NC-D, respectively). We found that essential AA δ13C values and source AA δ15N values in feathers showed minimal trophic fractionation between diet and consumer, providing independent but complimentary archival proxies for primary producers and nitrogen sources respectively, at the base of food webs supporting penguins. Variations in nonessential AA Δ13CC-D values reflected differences in macromolecule sources used for biosynthesis (e.g., protein vs. lipids) and provided a metric to assess resource utilization. The avian-specific nitrogen trophic discrimination factor (TDFGlu-Phe = 3.5 ± 0.4‰) that we calculated from the difference in trophic fractionation (Δ15NC-D) of glutamic acid and phenylalanine was significantly lower than the conventional literature value of 7.6‰. Trophic positions of five species of wild penguins calculated using a multi-TDFGlu-Phe equation with the avian-specific TDFGlu-Phe value from our experiment provided estimates that were more ecologically realistic than estimates using a single TDFGlu-Phe of 7.6‰ from the previous literature. Our results provide a quantitative, mechanistic framework for the use of CSIA in nonlethal, archival feathers to study the movement and foraging ecology of avian consumers.
    Description: This research was funded by National Science Foundation Office of Polar Programs [grants ANT-0125098, ANT-0739575] and the 2013 Antarctic Science Bursaries.
    Keywords: Amino acid ; Avian ; Compound-specific stable isotope analysis ; Diet ; Fractionation ; Penguin ; Trophic position
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  • 109
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Earth's Future 3 (2015): 49–65, doi:10.1002/2014EF000274.
    Description: How climate controls hurricane variability has critical implications for society is not well understood. In part, our understanding is hampered by the short and incomplete observational hurricane record. Here we present a synthesis of intense-hurricane activity from the western North Atlantic over the past two millennia, which is supported by a new, exceptionally well-resolved record from Salt Pond, Massachusetts (USA). At Salt Pond, three coarse grained event beds deposited in the historical interval are consistent with severe hurricanes in 1991 (Bob), 1675, and 1635 C.E., and provide modern analogs for 32 other prehistoric event beds. Two intervals of heightened frequency of event bed deposition between 1400 and 1675 C.E. (10 events) and 150 and 1150 C.E. (23 events), represent the local expression of coherent regional patterns in intense-hurricane–induced event beds. Our synthesis indicates that much of the western North Atlantic appears to have been active between 250 and 1150 C.E., with high levels of activity persisting in the Caribbean and Gulf of Mexico until 1400 C.E. This interval was one with relatively warm sea surface temperatures (SSTs) in the main development region (MDR). A shift in activity to the North American east coast occurred ca. 1400 C.E., with more frequent severe hurricane strikes recorded from The Bahamas to New England between 1400 and 1675 C.E. A warm SST anomaly along the western North Atlantic, rather than within the MDR, likely contributed to the later active interval being restricted to the east coast.
    Description: Funding was provided by US National Science Foundation (awards 0903020 and 1356708), the Risk Prediction Initiative at the Bermuda Institute for Ocean Sciences (BIOS), US Department of Energy National Institute for Climate Change Research, National Oceanic and Atmospheric Administration (award NA11OAR431010), and the Dalio Explore Fund.
    Keywords: Tropical cyclones ; Climate change ; Holocene ; Common era ; Sea surface temperature
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  • 110
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 16 (2015): 126–147, doi:10.1002/2014GC005517.
    Description: Here we present volatile, major, and trace element concentrations of 64 olivine-hosted melt inclusions from the Lucky Strike segment on the mid-Atlantic ridge. Lucky Strike is one of two locations where a crustal melt lens has been seismically imaged on a slow-spreading ridge. Vapor-saturation pressures, calculated from CO2 and H2O contents of Lucky Strike melt inclusions, range from approximately 300–3000 bars, corresponding to depths of 0.5–9.9 km below the seafloor. Approximately 50% of the melt inclusions record crystallization depths of 3–4 km, corresponding to the seismically imaged melt lens depth, while an additional ∼35% crystallize at depths 〉 4 km. This indicates that while crystallization is focused within the melt lens, significant crystallization also occurs in the lower crust and/or upper mantle. The melt inclusions span a range of major and trace element concentrations from normal to enriched basalts. Trace element ratios at all depths are heterogeneous, suggesting that melts are not efficiently homogenized in the mantle or crust, despite the presence of a melt lens. This is consistent with the transient nature of magma chambers proposed for slower-spreading ridges. To investigate the petrogenesis of the melt inclusion compositions, we compare the measured trace element compositions to theoretical melting calculations that consider variations in the melting geometry and heterogeneities in the mantle source. The full range of compositions can be produced by slight variations in the proportion of an Azores plume and depleted upper mantle components and changes in the total extent of melting.
    Description: thanked for his help with sample preparation. The GRAVILUCK'06 and Bathyluck'08 cruises where financed by the French Ministry of Research. This work was supported by NSF grant OCE-0926422 to A.M.S., OCE-PRF-1226130 to V.D.W., OCE-1333492 to S.A.S., and EAR-09-48666 to M.D.B., and by ANR (France) Mothseim Project NT05-342213 to J.E.
    Description: 2015-07-20
    Keywords: Slow-spreading ridge ; Lucky Strike ; Melt inclusions ; Volatiles ; Melt lens
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  • 111
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Journal of Geophysical Research: Oceans 120 (2015): 2096–2111, doi:10.1002/2014JC010573.
    Description: In this study, we address the question whether eddy-driven transports in the Argentine Basin can be held responsible for enhanced sediment accumulation over the Zapiola Rise, hence accounting for the existence and growth of this sediment drift. To address this question, we perform a 6 year simulation with a strongly eddying ocean model. We release two passive tracers, with settling velocities that are consistent with silt and clay size particles. Our experiments show contrasting behavior between the silt fraction and the lighter clay. Due to its larger settling velocity, the silt fraction reaches a quasisteady state within a few years, with abyssal sedimentation rates that match net input. In contrast, clay settles only slowly, and its distribution is heavily stratified, being transported mainly along isopycnals. Yet, both size classes display a significant and persistent concentration minimum over the Zapiola Rise. We show that the Zapiola Anticyclone, a strong eddy-driven vortex that circulates around the Zapiola Rise, is a barrier to sediment transport, and hence prevents significant accumulation of sediments on the Rise. We conclude that sediment transport by the turbulent circulation in the Argentine Basin alone cannot account for the preferred sediment accumulation over the Rise. We speculate that resuspension is a critical process in the formation and maintenance of the Zapiola Rise.
    Description: This research was supported by the Regional and Global Climate Modeling Program of the US Department of Energy Office of Science (WW). Los Alamos National Laboratory is operated by the Los Alamos National Security, LLC for the National Nuclear Security Administration of the U.S. Department of Energy under contract DE-AC52-06NA25396.
    Keywords: Zapiola Rise ; Zapiola anticyclone ; Argentine Basin ; Sedimentation
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  • 112
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Paleoceanography 30 (2015): 353–368, doi:10.1002/2014PA002667.
    Description: Approximately synchronous with the onset of Heinrich Stadial 1 (HS1), δ13C decreased throughout most of the upper (~1000–2500 m) Atlantic, and at some deeper North Atlantic sites. This early deglacial δ13C decrease has been alternatively attributed to a reduced fraction of high-δ13C North Atlantic Deep Water (NADW) or to a decrease in the NADW δ13C source value. Here we present new benthic δ18O and δ13C records from three relatively shallow (~1450–1650 m) subpolar Northeast Atlantic cores. With published data from other cores, these data form a depth transect (~1200–3900 m) in the subpolar Northeast Atlantic. We compare Last Glacial Maximum (LGM) and HS1 data from this transect with data from a depth transect of cores from the Brazil Margin. The largest LGM-to-HS1 decreases in both benthic δ13C and δ18O occurred in upper waters containing the highest NADW fraction during the LGM. We show that the δ13C decrease can be explained entirely by a lower NADW δ13C source value, entirely by a decrease in the proportion of NADW relative to Southern Ocean Water, or by a combination of these mechanisms. However, building on insights from model simulations, we hypothesize that reduced ventilation due to a weakened but still active Atlantic Meridional Overturning Circulation also contributed to the low δ13C values in the upper North Atlantic. We suggest that the benthic δ18O gradients above ~2300 m at both core transects indicate the depth to which heat and North Atlantic deglacial freshwater had mixed into the subsurface ocean by early HS1.
    Description: The work was supported by NSF grants OCE13-35191, OCE07-50880, and OCE05-84911 to the Woods Hole Oceanographic Institution.
    Keywords: Heinrich Stadial 1 ; Deglacial d13C minimum ; Atlantic Circulation ; Benthic d18O ; Benthic d13C
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  • 113
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 42 (2015): 3431–3441, doi:10.1002/2015GL063494.
    Description: The impact on the upper ocean of the passage of a short, intense storm over a Southern Ocean site, in proximity to an Antarctic Circumpolar Current front, is characterized. The storm causes a wind-induced deepening of the mixed layer and generates an inertial current. Immediate poststorm observations indicate a mixed layer extending to approximately 50 m depth. Subsequent measurements show the upper ocean to have restratified, injecting near-inertial shear in stratified waters within 1 day of the storm's passage. This time scale for the development of near-inertial shear is 1 order of magnitude shorter than that predicted by the β dispersion paradigm. The observed rapid changes in upper ocean stratification point to the existence of an as yet undocumented, efficient mechanism for injection of near-inertial shear into the stratified ocean that is in turn associated with enhanced turbulence and mixing.
    Description: The SOFine project is funded by the UK Natural Environmental Research Council (NERC) (grant NE/G001510/1).
    Description: 2015-11-07
    Keywords: Upper ocean ; Restratification ; Near-inertial shear
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  • 114
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 30 (2015): 510–526, doi:10.1002/2014PA002741.
    Description: Global warming lowers the solubility of gases in the ocean and drives an enhanced hydrological cycle with increased nutrient loads delivered to the oceans, leading to increases in organic production, the degradation of which causes a further decrease in dissolved oxygen. In extreme cases in the geological past, this trajectory has led to catastrophic marine oxygen depletion during the so-called oceanic anoxic events (OAEs). How the water column oscillated between generally oxic conditions and local/global anoxia remains a challenging question, exacerbated by a lack of sensitive redox proxies, especially for the suboxic window. To address this problem, we use bulk carbonate I/Ca to reconstruct subtle redox changes in the upper ocean water column at seven sites recording the Cretaceous OAE 2. In general, I/Ca ratios were relatively low preceding and during the OAE interval, indicating deep suboxic or anoxic waters exchanging directly with near-surface waters. However, individual sites display a wide range of initial values and excursions in I/Ca through the OAE interval, reflecting the importance of local controls and suggesting a high spatial variability in redox state. Both I/Ca and an Earth System Model suggest that the northeast proto-Atlantic had notably higher oxygen levels in the upper water column than the rest of the North Atlantic, indicating that anoxia was not global during OAE 2 and that important regional differences in redox conditions existed. A lack of correlation with calcium, lithium, and carbon isotope records suggests that neither enhanced global weathering nor carbon burial was a dominant control on the I/Ca proxy during OAE 2.
    Description: Z.L. thanks NSF OCE 1232620. J.D.O. is supported by an Agouron Postdoctoral Fellowship. T.W.L. acknowledges support from the NSF-EAR and NASA-NAI. A.R. thanks the support of NERC via NE/J01043X/1.
    Description: 2015-11-13
    Keywords: I/Ca ; OAE 2 ; Oxygenation
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  • 115
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 120 (2015): 2555–2570, doi:10.1002/2014JC010564.
    Description: We tested the hypothesis that humpback whales aggregate at the southern flank of Stellwagen Bank (SB) in response to internal waves (IWs) generated semidiurnally at Race Point (RP) channel because of the presence of their preferred prey, planktivorous fish, which in turn respond to zooplankton concentrated by the predictable IWs. Analysis of synthetic aperture radar (SAR) images indicates that RP IWs approach the southern flank of SB frequently (∼62% of the images). Published reports of whale sighting data and archived SAR images point to a coarse spatial coincidence between whales and Race Point IWs at SB's southern flank. The responses of whales to IWs were evaluated via sightings and behavior of humpback whales, and IWs were observed in situ by acoustic backscatter and temperature measurements. Modeling of IWs complemented the observations, and results indicate a change of ∼0.4 m/s in current velocity, and ∼1.5 Pa in dynamic pressure near the bottom, which may be sufficient for bottom fish to detect the IWs. However, fish were rare in our acoustic observations, and fish response to the IWs could not be evaluated. RP IWs do not represent the leading edge of the internal tide, and they may have less mass-transport potential than typical coastal IWs. There was large interannual variability in whale sightings at SB's southern flank, with decreases in both numbers of sightings and proportion of sightings where feeding was observed from 2008 to 2013. Coincidence of whales and IWs was inconsistent, and results do not support the hypothesis.
    Description: We would also like to acknowledge funding from the National Oceanic and Atmospheric Administration Sea Grant (Woods Hole), the Woods Hole Oceanographic Institution, the ESA, and the German Aerospace Center.
    Description: 2015-10-02
    Keywords: Humpback whales ; Nonlinear internal waves ; Shallow temperate bank ; Ecological hotspots
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  • 116
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 120 (2015): 3624–3639, doi:10.1002/2014JC010352.
    Description: The net ecosystem metabolism of the seagrass Thalassia testudinum was studied across a nutrient and productivity gradient in Florida Bay, Florida, using the Eulerian control volume, eddy covariance, and biomass addition techniques. In situ oxygen fluxes were determined by a triangular Eulerian control volume with sides 250 m long and by eddy covariance instrumentation at its center. The biomass addition technique evaluated the aboveground seagrass productivity through the net biomass added. The spatial and temporal resolutions, accuracies, and applicability of each method were compared. The eddy covariance technique better resolved the short-term flux rates and the productivity gradient across the bay, which was consistent with the long-term measurements from the biomass addition technique. The net primary production rates from the biomass addition technique, which were expected to show greater autotrophy due to the exclusion of sediment metabolism and belowground production, were 71, 53, and 30 mmol carbon m−2 d−1 at 3 sites across the bay. The net ecosystem metabolism was 35, 25, and 11 mmol oxygen m−2 d−1 from the eddy covariance technique and 10, −103, and 14 mmol oxygen m−2 d−1 from the Eulerian control volume across the same sites, respectively. The low-flow conditions in the shallow bays allowed for periodic stratification and long residence times within the Eulerian control volume that likely reduced its precision. Overall, the eddy covariance technique had the highest temporal resolution while producing accurate long-term flux rates that surpassed the capabilities of the biomass addition and Eulerian control volume techniques in these shallow coastal bays.
    Description: This research was conducted under Everglades National Park permit # EVER-2011-SCI-0057. This study received financial support from the Jones Environmental and Barley Scholars Program at the University of Virginia and the National Science Foundation (Chemical Oceanography grant OCE-0536431).
    Description: 2015-11-22
    Keywords: Eddy covariance ; Eulerian ; Metabolism ; Seagrass ; Eddy correlation
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  • 117
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 120 (2015): 4324–4339, doi:10.1002/2014JC010547.
    Description: In the coastal ocean off the Northeast U.S., the sea surface temperature (SST) in the first half of 2012 was the highest on the record for the past roughly 150 years of recorded observations. The underlying dynamical processes responsible for this extreme event are examined using a numerical model, and the relative contributions of air-sea heat flux versus lateral ocean advective heat flux are quantified. The model accurately reproduces the observed vertical structure and the spatiotemporal characteristics of the thermohaline condition of the Gulf of Maine and the Middle Atlantic Bight waters during the anomalous warming period. Analysis of the model results show that the warming event was primarily driven by the anomalous air-sea heat flux, while the smaller contribution by the ocean advection worked against this flux by acting to cool the shelf. The anomalous air-sea heat flux exhibited a shelf-wide coherence, consistent with the shelf-wide warming pattern, while the ocean advective heat flux was dominated by localized, relatively smaller-scale processes. The anomalous cooling due to advection primarily resulted from the along-shelf heat flux divergence in the Gulf of Maine, while in the Middle Atlantic Bight the advective contribution from the along-shelf and cross-shelf heat flux divergences was comparable. The modeling results confirm the conclusion of the recent analysis of in situ data by Chen et al. (2014a) that the changes in the large-scale atmospheric circulation in the winter of 2011–2012 primarily caused the extreme warm anomaly in the spring of 2012. The effect of along-shelf or cross-shelf ocean advection on the warm anomalies from either the Scotian Shelf or adjacent continental slope was secondary.
    Description: K.C. was supported by the Woods Hole Oceanographic Institution Postdoctoral Scholar program, the Coastal Ocean Institute, and the National Science Foundation (NSF) under grant OCE-1435602. G.G.G. was supported by NSF grants OCE-1435602 and OCE-1129125. Y.-O.K. was supported by the NSF grant OCE-1435602. W.G.Z. was supported by the NSF grant OCE-1129125.
    Description: 2015-12-15
    Keywords: Extreme temperature ; Heat budget ; Northeast U.S. coastal ocean ; Numerical modeling ; Air-sea interaction ; Climate change
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  • 118
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Journal of Field Robotics 32 (2015): 632–654, doi:10.1002/rob.21572.
    Description: We report the derivation and experimental evaluation of a stable adaptive identifier to estimate rigid body rotations using rotors in Geometric Algebra (GA). This work is motivated by the need for in situ estimation of the alignment between sensors commonly used in underwater vehicle navigation. Here we derive an adaptive identifier using a geometric interpretation of the error to drive first-order rotor kinematics. We prove that it is Lyapunov stable, and we show that it is asymptotically stable in the presence of persistent excitation. We use the identifier to estimate the alignment between the Doppler velocity log sonar and the fiber optic gyrocompass used by underwater vehicles for dead reckoning (DR). We evaluate this method in the laboratory with a remotely operated vehicle (ROV), and then with an autonomous underwater vehicle (AUV) operating in the field at 1,200 m depth. Our results show that this technique reduces dead reckoning navigation errors on these platforms and provides comparable performance to previously reported SO(3) constrained Linear Algebra (LA) approaches. The rotor identifier has a number of advantages over these previously reported methods, including a more straightforward derivation, simpler gain tuning, increased computational efficiency, and reduced data manipulation.
    Description: This work was supported in part by the National Defense Science and Engineering Graduate Program (MJS), the Edwin A. Link Foundation (MJS), the WHOI Academic Programs Office (MJS), The Jessie B. Cox Endowed Fund in Support of Scientific Staff (JCK), and The Penzance Endowed Fund in Support of Assistant Scientists (JCK).
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  • 119
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Geophysical Research Letters 42 (2015): 4032–4039, doi:10.1002/2015GL063065.
    Description: Using autonomous underwater gliders, we quantified diurnal periodicity in dissolved oxygen, chlorophyll, and temperature in the subtropical North Pacific near the Hawaii Ocean Time-series (HOT) Station ALOHA during summer 2012. Oxygen optodes provided sufficient stability and precision to quantify diel cycles of average amplitude of 0.6 µmol kg−1. A theoretical diel curve was fit to daily observations to infer an average mixed layer gross primary productivity (GPP) of 1.8 mmol O2 m−3 d−1. Cumulative net community production (NCP) over 110 days was 500 mmol O2 m−2 for the mixed layer, which averaged 57 m in depth. Both GPP and NCP estimates indicated a significant period of below-average productivity at Station ALOHA in 2012, an observation confirmed by 14C productivity incubations and O2/Ar ratios. Given our success in an oligotrophic gyre where biological signals are small, our diel GPP approach holds promise for remote characterization of productivity across the spectrum of marine environments.
    Description: The authors acknowledge support from the National Science Foundation (NSF) through an NSF Science and Technology Center, the Center for Microbial Oceanography Research and Education (C-MORE; NSF EF-0424599). D.N. also was supported by NSF (OCE-1129644) and an Independent Study Award from the Woods Hole Oceanographic Institution (WHOI). D.M.K. was also supported by the Gordon and Betty Moore Foundation. WHOI Summer Student Fellow Cole Stites-Clayton, Stanford University, contributed to early stages of Seaglider data analysis and was supported by an NSF REU grant to WHOI (OCE-1156952).
    Keywords: Primary productivity ; Glider ; Diel ; Oxygen ; Net community production ; Hawaii
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  • 120
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    John Wiley & Sons
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 42 (2015): 4301-4308, doi:10.1002/2015GL064480.
    Description: Continents on Earth periodically assemble to form supercontinents and then break up again into smaller continental blocks (the Wilson cycle). Previous highly developed numerical models incorporate fixed continents while others indicate that continent movement modulates flow. Our simplified numerical model suggests that continental drift is fundamental. A thermally insulating continent is anchored at its center to mantle flow on an otherwise stress-free surface for infinite Prandtl number cellular convection with constant material properties. Rayleigh numbers exceed 107, while continent widths and chamber lengths approach Earth's values. The Wilson cycle is reproduced by a unique, rugged monopolar “continental drift convection cell.” Subduction occurs at the cell's upstream end with cold slabs dipping at an angle beneath the moving continent (as found in many continent/subduction regions on Earth). Drift enhances vertical heat transport up to 30%, especially at the core-mantle boundary, and greatly decreases lateral mantle temperature differences.
    Description: Funding was provided by NSF grants EAR-1010432 and EAR-1316333.
    Description: 2015-12-02
    Keywords: Cellular convection ; Wilson cycle ; Continental drift ; Oscillation ; Subduction
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  • 121
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Geophysical Research Letters 42 (2015): 4931–4939, doi:10.1002/2015GL064431.
    Description: The oceans absorb anthropogenic CO2 from the atmosphere, lowering surface ocean pH, a concern for calcifying marine organisms. The impact of ocean acidification is challenging to predict as each species appears to respond differently and because our knowledge of natural changes to ocean pH is limited in both time and space. Here we reconstruct 222 years of biennial seawater pH variability in the Sargasso Sea from a brain coral, Diploria labyrinthiformis. Using hydrographic data from the Bermuda Atlantic Time-series Study and the coral-derived pH record, we are able to differentiate pH changes due to surface temperature versus those from ocean circulation and biogeochemical changes. We find that ocean pH does not simply reflect atmospheric CO2 trends but rather that circulation/biogeochemical changes account for 〉90% of pH variability in the Sargasso Sea and more variability in the last century than would be predicted from anthropogenic uptake of CO2 alone.
    Description: Funding to N.F.G. was provided by the University of Hong Kong and the National Research Foundation Singapore under its Singapore NRF Fellowship scheme (National Research Fellow Award NRF-RF2012-03), as administered by the Earth Observatory of Singapore and the Singapore Ministry of Education under the Research Centres of Excellence initiative. S.C.D. and K.A.H. acknowledge support from the National Science Foundation and Woods Hole Oceanographic Institution.
    Keywords: AMO ; NAO ; Coral del11B proxy ; pH
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  • 122
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 120 (2015): 4205–4225, doi:10.1002/2015JC010790.
    Description: The Intertropical Convergence Zone (ITCZ) is a major source of the surface freshwater input to the tropical open ocean. Under the ITCZ, sea-surface salinity (SSS) fronts that extend zonally across the basins are observed by the Aquarius/SAC-D mission and Argo floats. This study examined the evolution and forcing mechanisms of the SSS fronts. It is found that, although the SSS fronts are sourced from the ITCZ-freshened surface waters, the formation, structure, and propagation of these fronts are governed by the trade wind driven Ekman processes. Three features characterize the governing role of Ekman forcing. First, the SSS fronts are associated with near-surface salinity-minimum zones (SMZs) of 50–80 m deep. The SMZs are formed during December–March when the near-equatorial Ekman convergence zone concurs with an equatorward displaced ITCZ. Second, after the formation, the SMZs are carried poleward away at a speed of ∼3.5 km d−1 by Ekman transport. The monotonic poleward propagation is a sharp contrast to the seasonal north/south oscillation of the ITCZ. Lastly, each SMZ lasts about 12–15 months until dissipated at latitudes beyond 10°N/S. The persistence of more than 1 calendar year allows two SMZs to coexist during the formation season (December–March), with the newly formed SMZ located near the equator while the SMZ that is formed in the previous year located near the latitudes of 10–15° poleward after 1 year's propagation. The contrast between the ITCZ and SMZ highlights the dominance of Ekman dynamics on the relationship between the SSS and the ocean water cycle.
    Description: The study was supported by the NASA Ocean Salinity Science Team (OSST) under grant NNX12AG93G. Support from the NOAA Office of Climate Observation (OCO) under grant NA09OAR4320129 and NASA Ocean Vector Wind Science Team (OVWST) under grant NNA10AO86G in developing OAFlux evaporation and surface wind stress used in the study is gratefully acknowledged.
    Description: 2015-12-08
    Keywords: Sea-surface salinity fronts ; Salinity-minimum zones ; Tropical water cycle and salinity ; Aquarius salinity observations
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  • 123
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 16 (2015): 2303-2321, doi:10.1002/2015GC005797.
    Description: We reconstruct the history of the mode of accretion of an area of the Mid-Atlantic Ridge south of the Kane fracture zone using bathymetric morphology. The area includes 200 km of the spreading axis and reaches to 10 Ma on either side. We distinguish three tectonic styles: (1) volcanic construction with eruption and intrusion of magma coupled with minor faulting, (2) extended terrain with abundant large-offset faults, (3) detachment faulting marked by extension on single long-lived faults. Over 40% of the seafloor is made of extended terrain and detachment faults. The area includes products of seven spreading segments. The spreading axis has had detachment faulting or extended terrain on one or both sides for 70% of the last 10 Ma. In some parts of the area, regions of detachment faulting and extended terrain lie close to segment boundaries. Regions of detachment faulting initiated at 10 Ma close to the adjacent fracture zones to the north and south, and then expanded away from them. We discuss the complex evidence from gravity, seismic surveys, and bathymetry for the role of magma supply in generating tectonic style. Overall, we conclude that input of magma at the spreading axis has a general control on the development of detachment faulting, but the relationship is not strong. Other factors may include a positive feedback that stabilizes detachment faulting at the expense of volcanic extension, perhaps through the lubrication of active detachment faults by the formation of low friction materials (talc, serpentine) on detachment fault surfaces.
    Description: 2016-01-22
    Keywords: Slow spreading ridges ; Mid-Atlantic Ridge ; Detachment faults
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  • 124
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Advanced Science 2 (2015): 1500025, doi:10.1002/advs.201500025.
    Description: Clofazimine is an orally administered drug that massively bioaccumulates in macrophages, forming membrane-bound intracellular structures possessing nanoscale supramolecular features. Here, a library of phenazine compounds derived from clofazimine is synthesized and tested for ability to accumulate and form ordered molecular aggregates inside cells. Regardless of chemical structure or physicochemical properties, bioaccumulation is consistently greater in macrophages than in epithelial cells. Microscopically, some self-assembled structures exhibit a pronounced, diattenuation anisotropy signal, evident by the differential absorption of linearly polarized light, at the peak absorbance wavelength of the phenazine core. The measured anisotropy is well above the background anisotropy of endogenous cellular components, reflecting the self-assembly of condensed, insoluble complexes of ordered phenazine molecules. Chemical variations introduced at the R-imino position of the phenazine core lead to idiosyncratic effects on the compounds' bioaccumulation behavior as well as on the morphology and organization of the resulting intracellular structures. Beyond clofazimine, these results demonstrate how the self-assembly of membrane permeant, orally bioavailable small molecule building blocks can endow cells with unnatural structural elements possessing chemical, physical, and functional characteristics unlike those of other natural cellular components.
    Description: The authors acknowledge financial support from NIH (Grant R01GM078200 to G.R.R. and R01EB002583 to R.O.), a Rackham Predoctoral Fellowship Award to K.A.M., and University of Michigan M-Cubed funds awarded to K.A.S. and G.R.R.
    Keywords: Aggregation ; Biocrystals ; Chromophores ; Clofazimine ; Medicinal chemistry
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  • 125
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 16 (2015): 2582–2597, doi:10.1002/2015GC005927.
    Description: The portion of the Central American margin that encompasses Nicaragua is considered to represent an end-member system where multiple lines of evidence point to a substantial flux of subducted fluids. The seafloor spreading fabric of the incoming Cocos plate is oriented parallel to the trench such that flexural bending at the outer rise optimally reactivates a dense network of normal faults that extend several kilometers into the upper mantle. Bending faults are thought to provide fluid pathways that lead to serpentinization of the upper mantle. While geophysical anomalies detected beneath the outer rise have been interpreted as broad crustal and upper mantle hydration, no observational evidence exists to confirm that bending faults behave as fluid pathways. Here we use seafloor electromagnetic data collected across the Middle America Trench (MAT) offshore of Nicaragua to create a comprehensive electrical resistivity image that illuminates the infiltration of seawater along bending faults. We quantify porosity from the resistivity with Archie's law and find that our estimates for the abyssal plain oceanic crust are in good agreement with independent observations. As the Cocos crust traverses the outer rise, the porosity of the dikes and gabbros progressively increase from 2.7% and 0.7% to 4.8% and 1.7%, peaking within 20 km of the trench axis. We conclude that the intrusive crust subducts twice as much pore water as previously thought, significantly raising the flux of fluid to the seismogenic zone and the mantle wedge.
    Description: This work was supported by National Science Foundation grants OCE-0841114 and OCE-0840894, and the Seafloor Electromagnetic Methods Consortium at Scripps Institution of Oceanography.
    Description: 2016-02-16
    Keywords: Subduction zones ; Fluids ; Oceanic crust ; Bending faults
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  • 126
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 42 (2015): 7705–7713, doi:10.1002/2015GL065003.
    Description: We present the first noble gas observations in a proglacial fjord in Greenland, providing an unprecedented view of surface and submarine melt pathways into the ocean. Using Optimum Multiparameter Analysis, noble gas concentrations remove large uncertainties inherent in previous studies of meltwater in Greenland fjords. We find glacially modified waters with submarine melt concentrations up to 0.66 ± 0.09% and runoff 3.9 ± 0.29%. Radiogenic enrichment of Helium enables identification of ice sheet near-bed melt (0.48 ± 0.08%). We identify distinct regions of meltwater export reflecting heterogeneous melt processes: a surface layer of both runoff and submarine melt and an intermediate layer composed primarily of submarine melt. Intermediate ocean waters carry the majority of heat to the fjords' glaciers, and warmer deep waters are isolated from the ice edge. The average entrainment ratio implies that ocean water masses are upwelled at a rate 30 times the combined glacial meltwater volume flux.
    Description: We gratefully acknowledge funding from WHOI's Ocean and Climate Change Institute, the Doherty Postdoctoral Scholarship, and ship time from the Advanced Climate Dynamics Summer School (SiU grant NNA-2012/10151).
    Description: 2016-03-30
    Keywords: Glacial melt ; Noble gases ; Tracers ; Meltwater ; Greenland ; Fjord
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  • 127
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 42 (2015): 7589–7597, doi:10.1002/2015GL065284.
    Description: Broadband seismic stations were deployed across the Ross Ice Shelf (RIS) in November 2014 to study ocean gravity wave-induced vibrations. Initial data from three stations 100 km from the RIS front and within 10 km of each other show both dispersed infragravity (IG) wave and ocean swell-generated signals resulting from waves that originate in the North Pacific. Spectral levels from 0.001 to 10 Hz have the highest accelerations in the IG band (0.0025–0.03 Hz). Polarization analyses indicate complex frequency-dependent particle motions, with energy in several frequency bands having distinctly different propagation characteristics. The dominant IG band signals exhibit predominantly horizontal propagation from the north. Particle motion analyses indicate retrograde elliptical particle motions in the IG band, consistent with these signals propagating as Rayleigh-Lamb (flexural) waves in the ice shelf/water cavity system that are excited by ocean wave interactions nearer the shelf front.
    Description: Bromirski, Diez, and Gerstoft were supported by NSF grant PLR 1246151. Stephen and Bolmer were supported by NSF grant PLR-1246416. Wiens, Aster, and Nyblade were supported under NSF grants PLR-1142518, 1141916, and 1142126, respectively. Bromirski also received support from the California Department of Parks and Recreation, Division of Boating and Waterways under contract 11-106-107. The NIB data were collected under NSF grant OPP-0229546 and were downloaded from the IRIS DMC archives.
    Description: 2016-03-16
    Keywords: Ocean wave-ice shelf interactions ; Infragravity waves ; Dispersed gravity wave arrivals ; Polarization analysis ; Rayleigh-Lamb waves ; Flexural waves
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  • 128
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Geophysical Research Letters 42 (2015): 7639–7647, doi:10.1002/2015GL065043.
    Description: Oceanic internal waves are closely linked to turbulence. Here a relationship between vertical wave number (kz) spectra of fine-scale vertical kinetic energy (VKE) and turbulent dissipation ε is presented using more than 250 joint profiles from five diverse dynamic regimes, spanning latitudes between the equator and 60°. In the majority of the spectra VKE varies as inline image. Scaling VKE with inline image collapses the off-equatorial spectra to within inline image but underestimates the equatorial spectrum. The simple empirical relationship between VKE and ε fits the data better than a common shear-and-strain fine-scale parameterization, which significantly underestimates ε in the two data sets that are least consistent with the Garrett-Munk (GM) model. The new relationship between fine-scale VKE and dissipation rate can be interpreted as an alternative, single-parameter scaling for turbulent dissipation in terms of fine-scale internal wave vertical velocity that requires no reference to the GM model spectrum.
    Description: National Science Foundation Grant Numbers: OCE-0728766, OCE-0425361, OCE-0424953, OCE-1029722, OCE-0622630, OCE-1030309, OCE-1232962, and Office of Naval Research Grant Number: N00014-10-10315
    Keywords: Internal waves ; Turbulence ; Mixing ; Vertical kinetic energy ; Finestructure parameterization
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  • 129
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Geophysical Research Letters 42 (2015): 7687–7695, doi:10.1002/2015GL065530.
    Description: Onshore intrusions of offshore waters onto the Mid-Atlantic Bight shelf can greatly affect shelf circulation, biogeochemistry, and fisheries. Previous studies have concentrated on onshore intrusions of slope water. Here we present a direct intrusion of Gulf Stream warm-core ring water onto the shelf representing a previously unknown exchange process at the shelfbreak. Impingement of warm-core rings at the shelfbreak generates along-isobath intrusions that grow like Pinocchio's nose, extending hundreds of kilometers to the southwest. By combining satellite and Ocean Observatory Initiative Pioneer Array data and idealized numerical simulations, we discover that the intrusion results from topographically induced vorticity variation of the ring water, rather than from entrainment of the shelfbreak frontal jet. This intrusion of the Gulf Stream ring water has important biogeochemical implications and could facilitate migration of marine species across the shelfbreak barrier and transport low-nutrient surface Gulf Stream ring water to the otherwise productive shelfbreak region.
    Description: National Science Foundation Grant Number: OCE-1129125
    Keywords: Mid-Atlantic Bight ; Cross-shelf exchange ; Onshore intrusion ; Warm-core ring ; OOI Pioneer Array ; Vorticity dynamics
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  • 130
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 120 (2015): 6542–6563, doi:10.1002/2015JC010751.
    Description: Hydrographic data, chlorofluorocarbon-12 (CFC-12) and sulfur hexafluoride (SF6) measurements collected in March 2010 and September–October 2011 in the Red Sea, as well as an idealized numerical experiment are used to study the formation and spreading of Red Sea Outflow Water (RSOW) in the Red Sea. Analysis of inert tracers, potential vorticity distributions, and model results confirm that RSOW is formed through mixed-layer deepening caused by sea surface buoyancy loss in winter in the northern Red Sea and reveal more details on RSOW spreading rates, pathways, and vertical structure. The southward spreading of RSOW after its formation is identified as a layer with minimum potential vorticity and maximum CFC-12 and SF6. Ventilation ages of seawater within the RSOW layer, calculated from the partial pressure of SF6 (pSF6), range from 2 years in the northern Red Sea to 15 years at 17°N. The distribution of the tracer ages is in agreement with the model circulation field which shows a rapid transport of RSOW from its formation region to the southern Red Sea where there are longer circulation pathways and hence longer residence time due to basin wide eddies. The mean residence time of RSOW within the Red Sea estimated from the pSF6 age is 4.7 years. This time scale is very close to the mean transit time (4.8 years) for particles from the RSOW formation region to reach the exit at the Strait of Bab el Mandeb in the numerical experiment.
    Description: King Abdullah University of Science and Technology (KAUST) Grant Numbers: USA 00002, KSA 00011, KSA 00011/02; National Science Foundation; WHOI Academic Program Office Grant Number: OCE0927017
    Description: 2016-03-29
    Keywords: Anthropogenic tracers ; Red Sea Outflow Water ; Transit time ; Formation ; Spreading ; Residence time
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  • 131
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 16 (2015): 3414–3435, doi:10.1002/2015GC005947.
    Description: Overflow of Northern Component Water, the precursor of North Atlantic Deep Water, appears to have varied during Neogene times. It has been suggested that this variation is moderated by transient behavior of the Icelandic mantle plume, which has influenced North Atlantic bathymetry through time. Thus pathways and intensities of bottom currents that control deposition of contourite drifts could be affected by mantle processes. Here, we present regional seismic reflection profiles that cross sedimentary accumulations (Björn, Gardar, Eirik, and Hatton Drifts). Prominent reflections were mapped and calibrated using a combination of boreholes and legacy seismic profiles. Interpreted seismic profiles were used to reconstruct solid sedimentation rates. Björn Drift began to accumulate in late Miocene times. Its average sedimentation rate decreased at ∼2.5 Ma and increased again at ∼0.75 Ma. In contrast, Eirik Drift started to accumulate in early Miocene times. Its average sedimentation rate increased at ∼5.5 Ma and decreased at ∼2.2 Ma. In both cases, there is a good correlation between sedimentation rates, inferred Northern Component Water overflow, and the variation of Icelandic plume temperature independently obtained from the geometry of diachronous V-shaped ridges. Between 5.5 and 2.5 Ma, the plume cooled, which probably caused subsidence of the Greenland-Iceland-Scotland Ridge, allowing drift accumulation to increase. When the plume became hotter at 2.5 Ma, drift accumulation rate fell. We infer that deep-water current strength is modulated by fluctuating dynamic support of the Greenland-Scotland Ridge. Our results highlight the potential link between mantle convective processes and ocean circulation.
    Description: Natural Environment Research Council Grant Number: NE/G007632/1; The University of Cambridge Girdler Fund; BP Exploration
    Description: 2016-04-15
    Keywords: Contourite ; Drift ; Iceland ; Plume
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  • 132
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Ecosphere 6, no. 11 (2015): 1-18, doi:10.1890/ES14-00503.1.
    Description: We develop a coupled economic-metacommunity model to investigate the trade-off between diversity and profit for multispecies systems. The model keeps track of the presence or absence of species in habitat patches. With this approach, it becomes (relatively) simple to include more species than can typically be included in models that track species population density. We use this patch-occupancy framework to understand how profit and biodiversity are impacted by (1) community assembly, (2) pricing structures that value species equally or unequally, and (3) the implementation of marine reserves. We find that when local communities assemble slowly as a result of facilitative colonization, there are lower profits and optimal harvest rates, but the trade-off with diversity may be either large or small. The trade-off is diminished if later colonizing species are more highly valued than early colonizers. When the cost of harvesting is low, maximizing profits tends to sharply reduce biodiversity and maximizing diversity entails a large harvesting opportunity cost. In the models we analyze, marine reserves are never economically optimal for a profit-maximizing owner. However, management using marine reserves may provide low-cost biodiversity protection if the community is over-harvested.
    Description: This research was supported by The Seaver Institute and the National Science Foundation (OCE-1031256) through grants awarded to J. B. Kellner and M. G. Neubert. E. A. Moberg was funded by NSF GRFP number 1122374 and MIT's Ida Green Fellowship.
    Keywords: Ecosystem-based management ; Fisheries management ; Marine reserves ; Metacommunity ; Multispecies interactions
    Repository Name: Woods Hole Open Access Server
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  • 133
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 31 (2016): 472–490, doi:10.1002/2015PA002917.
    Description: Compilations of paleoceanographic observations for the deep sea now contain a few hundred points along the oceanic margins, mid-ocean ridges, and bathymetric highs, where seawater conditions are indirectly recorded in the chemistry of buried benthic foraminiferal shells. Here we design an idealized experiment to test our predictive ability to reconstruct modern-day seawater properties by considering paleoceanographic-like data. We attempt to reconstruct the known, modern-day global distributions by using a state estimation method that combines a kinematic tracer transport model with observations that have paleoceanographic characteristics. When a modern-like suite of observations (Θ, practical salinity, seawater δ18O, inline image, PO4, NO3, and O2) is used from the sparse paleolocations, the state estimate is consistent with the withheld data at all depths below 1500 m, suggesting that the observational sparsity can be overcome. Physical features, such as the interbasin gradients in deep inline image and the vertical structure of Atlantic inline image, are accurately reconstructed. The state estimation method extracts useful information from the pointwise observations to infer distributions at the largest oceanic scales (at least 10,000 km horizontally and 1500 m vertically) and outperforms a standard optimal interpolation technique even though neither dynamical constraints nor constraints from surface boundary fluxes are used. When the sparse observations are more realistically restricted to the paleoceanographic proxy observations of δ13C, δ18O, and Cd/Ca, however, the large-scale property distributions are no longer recovered coherently. At least three more water mass tracers are likely needed at the core sites in order to accurately reconstruct the large-scale property distributions of the Last Glacial Maximum.
    Description: NSF Grant Numbers: 1124880, 1125422
    Description: 2016-10-08
    Keywords: Water mass geometry ; Tracer distributions ; Inverse methods ; Last Glacial Maximum ; Identical twin experiment ; Isotope records
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  • 134
    Publication Date: 2022-05-25
    Description: Author Posting. © Ecological Society of America, 2016. This article is posted here by permission of Ecological Society of America for personal use, not for redistribution. The definitive version was published in Frontiers in Ecology and the Environment 14 (2016): 200-208, doi:10.1002/fee.1262.
    Description: In addition to their important effects on nitrogen (N) cycling via excretion and assimilation (by macrofauna and macroflora, respectively), many macrobiota also host or facilitate microbial taxa responsible for N transformations. Interest in this topic is expanding, especially as it applies to coastal marine systems where N is a limiting nutrient. Our understanding of the diversity of microbes associated with coastal marine macrofauna (invertebrate and vertebrate animals) and macrophytes (seaweeds and marine plants) is improving, and recent studies indicate that the collection of microbes living in direct association with macrobiota (the microbiome) may directly contribute to N cycling. Here, we review the roles that macrobiota play in coastal N cycling, review current knowledge of macrobial–microbial associations in terms of N processing, and suggest implications for coastal ecosystem function as animals are harvested and as foundational habitat is lost or degraded. Given the biodiversity of microbial associates of macrobiota, we advocate for more research into the functional consequences of these associations for the coastal N cycle.
    Description: University of Chicago-Marine Biological Laboratories (MBL)
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  • 135
    Publication Date: 2022-05-25
    Description: © The Author(s), 2016. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Ecology and Evolution 6 (2016): 6855–6879, doi:10.1002/ece3.2202.
    Description: Mothers that experience different individual or environmental conditions may produce different proportions of male to female offspring. The Trivers-Willard hypothesis, for instance, suggests that mothers with different qualities (size, health, etc.) will use different sex ratios if maternal quality differentially affects sex-specific reproductive success. Condition-dependent, or facultative, sex ratio strategies like these allow multiple sex ratios to coexist within a population. They also create complex population structure due to the presence of multiple maternal conditions. As a result, modeling facultative sex ratio evolution requires not only sex ratio strategies with multiple components, but also two-sex population models with explicit stage structure. To this end, we combine nonlinear, frequency-dependent matrix models and multidimensional adaptive dynamics to create a new framework for studying sex ratio evolution. We illustrate the applications of this framework with two case studies where the sex ratios depend one of two possible maternal conditions (age or quality). In these cases, we identify evolutionarily singular sex ratio strategies, find instances where one maternal condition produces exclusively male or female offspring, and show that sex ratio biases depend on the relative reproductive value ratios for each sex.
    Description: National Science Foundation Graduate Research Fellowship Grant Number: 1122374; National Science Foundation Grant Numbers: DEB1145017, DEB1257545; European Research Council Grant Number: 322989; Woods Hole Oceanographic Institution Academic Programs Office
    Keywords: Adaptive dynamics ; Facultative sex ratios ; Maternal condition ; Matrix population models ; Sex ratio evolution ; Trivers-Willard hypothesis
    Repository Name: Woods Hole Open Access Server
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  • 136
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 121 (2016): 6635–6649, doi:10.1002/2016JC011714.
    Description: We investigate the role of mesoscale eddies in modulating air-sea CO2 flux and associated biogeochemical fields in Drake Passage using in situ observations and an eddy-resolving numerical model. Both observations and model show a negative correlation between temperature and partial pressure of CO2 (pCO2) anomalies at the sea surface in austral summer, indicating that warm/cold anticyclonic/cyclonic eddies take up more/less CO2. In austral winter, in contrast, relationships are reversed: warm/cold anticyclonic/cyclonic eddies are characterized by a positive/negative pCO2 anomaly and more/less CO2 outgassing. It is argued that DIC-driven effects on pCO2 are greater than temperature effects in austral summer, leading to a negative correlation. In austral winter, however, the reverse is true. An eddy-centric analysis of the model solution reveals that nitrate and iron respond differently to the same vertical mixing: vertical mixing has a greater impact on iron because its normalized vertical gradient at the base of the surface mixed layer is an order of magnitude greater than that of nitrate.
    Description: NASA High-End Computing (HEC) Program through the NASA Advanced Supercomputing (NAS) Division at Ames Research Center Grant Number: SMD-15-5752; NSF MOBY project Grant Numbers: (OCE-1048926), OCE-1259388, PLR-1341647, AOAS-0944761, and AOAS-066975; NOAA Climate Program Office Grant Number: (NA12OAR4310058)
    Description: 2017-03-10
    Keywords: CO2 flux ; Mesoscale eddy ; Southern Ocean ; Vertical mixing ; Nutrient fluxes
    Repository Name: Woods Hole Open Access Server
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  • 137
    Publication Date: 2022-05-25
    Description: Author Posting. © Association for the Sciences of Limnology and Oceanography, 2016. This article is posted here by permission of Association for the Sciences of Limnology and Oceanography for personal use, not for redistribution. The definitive version was published in Limnology and Oceanography 61 (2016): 2243–2260, doi:10.1002/lno.10372.
    Description: A numerical circulation model with a very simple representation of dissolved oxygen dynamics is used to simulate hypoxia in Chesapeake Bay for the 30-yr period 1984–2013. The model assumes that the biological utilization of dissolved oxygen is constant in both time and space in an attempt to isolate the role that physical processes play in modulating oxygen dynamics. Despite the simplicity of the model it demonstrates skill in simulating the observed inter-annual variability of hypoxic volume, capturing 50% of the observed variability in hypoxic volume (〈2 mg L−1) for the month of July and 58% of the observed variability for the month of August, over the 30-yr period. Model skill increases throughout the summer suggesting that physical processes play a more important role in modulating hypoxia later in the summer. Model skill is better for hypoxic volumes than for anoxic volumes. In fact, a simple regression based on the integrated January–June Susquehanna River nitrogen load can explain more of the variability in the observed anoxic volumes than the model presented here. Model results suggest that the mean summer (June–August) wind speed is the single-most important physical variable contributing to variations in hypoxic volumes. Previous studies have failed to document the importance of summer wind speed because they have relied on winds measured at Patuxent Naval Air Station, which does not capture the observed inter-annual variations in wind speed that are observed by stations that directly measure wind over the waters of Chesapeake Bay.
    Description: National Science Foundation Grant Number: OCE-1338518; National Oceanic and Atmospheric Association NOAA via the IOOS Office Award Grant Numbers: NA10NOS0120063, NA11NOS01201441
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  • 138
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Earth Surface 121 (2016): 664–683, doi:10.1002/2015JF003780.
    Description: River mouths, shoreline locations where fluvial and coastal sediments are partitioned via erosion, trapping, and redistribution, are responsible for the ultimate sedimentary architecture of deltas and, because of their dynamic nature, also pose great management and engineering challenges. To investigate the interaction between fluvial and littoral processes at wave-dominated river mouths, we modeled their morphologic evolution using the coupled hydrodynamic and morphodynamic model Delft3D-SWAN. Model experiments replicate alongshore migration of river mouths, river mouth spit development, and eventual spit breaching, suggesting that these are emergent phenomena that can develop even under constant fluvial and wave conditions. Furthermore, we find that sediment bypassing of a river mouth develops though feedbacks between waves and river mouth morphology, resulting in either continuous bypassing pathways or episodic bar bypassing pathways. Model results demonstrate that waves refracting into the river mouth bar create a zone of low alongshore sediment transport updrift of the river mouth, which reduces sediment bypassing. Sediment bypassing, in turn, controls the river mouth migration rate and the size of the river mouth spit. As a result, an intermediate amount of river discharge maximizes river mouth migration. The fraction of alongshore sediment bypassing can be predicted from the balance between the jet and the wave momentum flux. Quantitative comparisons show a match between our modeled predictions of river mouth bypassing and migration rates observed in natural settings.
    Description: NSF Grant Number: EAR-0952146
    Description: 2016-10-21
    Keywords: River mouth ; Bypassing ; Alongshore sediment transport ; Delft3D ; River mouth migration ; River mouth spit
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  • 139
    Publication Date: 2022-05-25
    Description: Author Posting. © Society for Marine Mammalogy, 2016. This article is posted here by permission of Society for Marine Mammalogy for personal use, not for redistribution. The definitive version was published in Marine Mammal Science 32 (2016):1510–1515, doi:10.1111/mms.12328.
    Description: Baleen whales are the largest animals ever to live on earth, and many populations were hunted close to extinction in the 20th century (Clapham et al. 1999). Their recovery is now a key international conservation goal, and they are important in marine ecosystems as massive consumers that can promote primary production through nutrient cycling (Roman et al. 2014). However, although abundance has been assessed to monitor the recovery of some large whale populations (e.g., Barlow et al. 2011, Laake et al. 2012) many populations are wide-ranging and pelagic, and this inaccessibility has generally impeded quantitative assessments of recovery (Peel et al. 2015). To augment traditional abundance monitoring, we suggest that photogrammetric measures of individual growth and body condition can also inform about population status, enabling assessment of individual health as well as population numbers. Photogrammetry from manned aircraft has used photographs taken from directly above whales to estimate individual lengths (Gilpatrick and Perryman 2008) and monitor growth trends (Fearnbach et al. 2011), and shape profiles can be measured to assess body condition to infer reproductive and nutritional status (e.g., Perryman and Lynn 2002, Miller et al. 2012). Recently, Durban et al. (2015) demonstrated the utility of an unmanned hexacopter for collecting aerial photogrammetry images of killer whales (Orcinus orca); this provided a noninvasive, cost-effective, and safe platform that could be deployed from a boat to obtain vertical images of whales. Here we describe the use of this small, unmanned aerial system (UAS) to measure length and condition of blue whales (Balaenoptera musculus), the largest of all whales.
    Description: María Francisca Cortés Solari; Rafaela Landea Briones; MERI Foundation; Woods Hole Oceanographic Institution Access
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  • 140
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 121 (2016): 7795–7803, doi:10.1002/2016JC011742.
    Description: An uplift of the ocean bottom caused by a submarine earthquake can trigger acoustic-gravity waves that travel at near the speed of sound in water and thus may act as early tsunami precursors. We study the spatiotemporal evolution of the pressure field induced by acoustic-gravity modes during submarine earthquakes, analytically. We show that these modes may all induce comparable temporal variations in pressure at different water depths in regions far from the epicenter, though the pressure field depends on the presence of a leading acoustic-gravity wave mode. Practically, this can assist in the implementation of an early tsunami detection system by identifying the pressure and frequency ranges of measurement equipment and appropriate installation locations.
    Description: 2017-04-24
    Keywords: Acoustic-gravity waves ; Submarine earthquake ; Early tsunami detection system
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  • 141
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 31 (2016): 1302–1314, doi:10.1002/2016PA002975.
    Description: Antarctic Intermediate Water is an essential limb of the Atlantic meridional overturning circulation that redistributes heat and nutrients within the Atlantic Ocean. Existing reconstructions have yielded conflicting results on the history of Antarctic Intermediate Water penetration into the Atlantic across the most recent glacial termination. In this study we present leachate, foraminiferal, and detrital neodymium isotope data from three intermediate-depth cores collected from the southern Brazil margin in the South Atlantic covering the past 25 kyr. These results reveal that strong chemical leaching following decarbonation does not extract past seawater neodymium composition in this location. The new foraminiferal records reveal no changes in seawater Nd isotopes during abrupt Northern Hemisphere cold events at these sites. We therefore conclude that there is no evidence for greater incursion of Antarctic Intermediate Water into the South Atlantic during either the Younger Dryas or Heinrich Stadial 1. We do, however, observe more radiogenic Nd isotope values in the intermediate-depth South Atlantic during the mid-Holocene. This radiogenic excursion coincides with evidence for a southward shift in the Southern Hemisphere westerlies that may have resulted in a greater entrainment of radiogenic Pacific-sourced water during intermediate water production in the Atlantic sector of the Southern Ocean. Our intermediate-depth records show similar values to a deglacial foraminiferal Nd isotope record from the deep South Atlantic during the Younger Dryas but are clearly distinct during the Last Glacial Maximum and Heinrich Stadial 1, demonstrating that the South Atlantic remained chemically stratified during Heinrich Stadial 1.
    Description: NERC Grant Numbers: NE/K005235/1, NE/F006047/1; NSF Grant Number: OCE -1335191; FAPESP Grant Number: 2012/17517-3; CAPES Grant Numbers: 1976/2014, 564/2015
    Description: 2017-04-05
    Keywords: Antarctic Intermediate Water ; Neodymium isotopes ; Degalciation ; South Atlantic
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  • 142
    Publication Date: 2022-05-25
    Description: © The Author(s), 2016. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Journal of Geophysical Research: Oceans 121 (2016): 7819–7844, doi:10.1002/2016JC011922.
    Description: A 9 km long tracer plume was created by continuously releasing Rhodamine WT dye for 2.2 h during ebb tide within the southern edge of the main tidal channel at New River Inlet, NC on 7 May 2012, with highly obliquely incident waves and alongshore winds. Over 6 h from release, COAWST (coupled ROMS and SWAN, including wave, wind, and tidal forcing) modeled dye compares well with (aerial hyperspectral and in situ) observed dye concentration. Dye first was transported rapidly seaward along the main channel and partially advected across the ebb-tidal shoal until reaching the offshore edge of the shoal. Dye did not eject offshore in an ebb-tidal jet because the obliquely incident breaking waves retarded the inlet-mouth ebb-tidal flow and forced currents along the ebb shoal. The dye plume largely was confined to 〈4 m depth. Dye was then transported downcoast in the narrow (few 100 m wide) surfzone of the beach bordering the inlet at 0.3 inline image driven by wave breaking. Over 6 h, the dye plume is not significantly affected by buoyancy. Observed dye mass balances close indicating all released dye is accounted for. Modeled and observed dye behaviors are qualitatively similar. The model simulates well the evolution of the dye center of mass, lateral spreading, surface area, and maximum concentration, as well as regional (“inlet” and “ocean”) dye mass balances. This indicates that the model represents well the dynamics of the ebb-tidal dye plume. Details of the dye transport pathways across the ebb shoal are modeled poorly perhaps owing to low-resolution and smoothed model bathymetry. Wave forcing effects have a large impact on the dye transport.
    Description: Littoral Geosciences and Optics Division of the Office of Naval Research as part of the Tidal Inlets and River Mouths Directed Research Initiative
    Keywords: Tidal inlet ; Tracer transport ; Ebb-tidal plume
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  • 143
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 18 (2017): 445–456, doi:10.1002/2016GC006686.
    Description: MeltMigrator is a MATLAB®-based melt migration software developed to process three-dimensional mantle temperature and velocity data from user-supplied numerical models of mid-ocean ridges, calculate melt production and melt migration trajectories in the mantle, estimate melt flux along plate boundaries, and predict crustal thickness distribution on the seafloor. MeltMigrator is also capable of calculating compositional evolution depending on the choice of petrologic melting model. Programmed in modules, MeltMigrator is highly customizable and can be expanded to a wide range of applications. We have applied it to complex mid-ocean ridge model settings, including transform faults, oblique segments, ridge migration, asymmetrical spreading, background mantle flow, and ridge-plume interaction. In this technical report, we include an example application to a segmented mid-ocean ridge. MeltMigrator is available as a supplement to this paper, and it is also available from GitHub and the University of Maryland Geodynamics Group website.
    Description: National Science Foundation Grant Number: OCE-0937277 and OCE-1458201
    Description: 2017-07-22
    Keywords: Mid-ocean ridges ; Melt migration ; Crustal thickness
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  • 144
    Publication Date: 2022-05-25
    Description: © The Author(s), 2016. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Limnology and Oceanography: Methods 15 (2017): 94–102, doi:10.1002/lom3.10145.
    Description: Recent advances in plankton ecology have brought to light the importance of variability within populations and have suggested that cell-to-cell differences may influence ecosystem-level processes such as species succession and bloom dynamics. Flow cytometric cell sorting has been used to capture individual plankton cells from natural water samples to investigate variability at the single cell level, but the crude taxonomic resolution afforded by the fluorescence and light scattering measurements of conventional flow cytometers necessitates sorting and analyzing many cells that may not be of interest. Addition of imaging to flow cytometry improves classification capability considerably: Imaging FlowCytobot, which has been deployed at the Martha's Vineyard Coastal Observatory since 2006, allows classification of many kinds of nano- and microplankton to the genus or even species level. We present in this paper a modified bench-top Imaging FlowCytobot (IFCB-Sorter) with the capability to sort both single cells and colonies of phytoplankton and microzooplankton from seawater samples. The cells (or subsets selected based on their images) can then be cultured for further manipulation or processed for analyses such as nucleic acid sequencing. The sorting is carried out in two steps: a fluorescence signal triggers imaging and diversion of the sample flow into a commercially available “catcher tube,” and then a solenoid-based flow control system isolates each sorted cell along with 20 μL of fluid.
    Description: NSF Grant Number: OCE-11300140; WHOI internal support; NSERC through a Post-Graduate Masters award
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  • 145
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 18 (2017): 75–92, doi:10.1002/2016GC006537.
    Description: Tidal oscillations of venting temperature and chlorinity have been observed in the long-term time series data recorded by the Benthic and Resistivity Sensors (BARS) at the Grotto mound on the Juan de Fuca Ridge. In this study, we use a one-dimensional two-layer poroelastic model to conduct a preliminary investigation of three hypothetical scenarios in which seafloor tidal loading can modulate the venting temperature and chlorinity at Grotto through the mechanisms of subsurface tidal mixing and/or subsurface tidal pumping. For the first scenario, our results demonstrate that it is unlikely for subsurface tidal mixing to cause coupled tidal oscillations in venting temperature and chlorinity of the observed amplitudes. For the second scenario, the model results suggest that it is plausible that the tidal oscillations in venting temperature and chlorinity are decoupled with the former caused by subsurface tidal pumping and the latter caused by subsurface tidal mixing, although the mixing depth is not well constrained. For the third scenario, our results suggest that it is plausible for subsurface tidal pumping to cause coupled tidal oscillations in venting temperature and chlorinity. In this case, the observed tidal phase lag between venting temperature and chlorinity is close to the poroelastic model prediction if brine storage occurs throughout the upflow zone under the premise that layers 2A and 2B have similar crustal permeabilities. However, the predicted phase lag is poorly constrained if brine storage is limited to layer 2B as would be expected when its crustal permeability is much smaller than that of layer 2A.
    Description: Woods Hole Oceanographic Institution; NOAA; National Science Foundation Grant Numbers: 9820105 , 0120392 , 0701196 , 0751868 , 0819004
    Description: 2017-07-18
    Keywords: Hydrothermal vent ; Temperature ; Chlorinity ; Brine ; Tide ; Poroelastic model
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  • 146
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 32 (2017): 146–160, doi:10.1002/2016PA002976.
    Description: Coral skeletons are valuable archives of past ocean conditions. However, interpretation of coral paleotemperature records is confounded by uncertainties associated with single-element ratio thermometers, including Sr/Ca. A new approach, Sr-U, uses U/Ca to constrain the influence of Rayleigh fractionation on Sr/Ca. Here we build on the initial Pacific Porites Sr-U calibration to include multiple Atlantic and Pacific coral genera from multiple coral reef locations spanning a temperature range of 23.15–30.12°C. Accounting for the wintertime growth cessation of one Bermuda coral, we show that Sr-U is strongly correlated with the average water temperature at each location (r2 = 0.91, P 〈 0.001, n = 19). We applied the multispecies spatial calibration between Sr-U and temperature to reconstruct a 96 year long temperature record at Mona Island, Puerto Rico, using a coral not included in the calibration. Average Sr-U derived temperature for the period 1900–1996 is within 0.12°C of the average instrumental temperature at this site and captures the twentieth century warming trend of 0.06°C per decade. Sr-U also captures the timing of multiyear variability but with higher amplitude than implied by the instrumental data. Mean Sr-U temperatures and patterns of multiyear variability were replicated in a second coral in the same grid box. Conversely, Sr/Ca records from the same two corals were inconsistent with each other and failed to capture absolute sea temperatures, timing of multiyear variability, or the twentieth century warming trend. Our results suggest that coral Sr-U paleothermometry is a promising new tool for reconstruction of past ocean temperatures.
    Description: NSF Graduate Research Fellowships Grant Numbers: NSF-OCE-1338320, NSF-OCE-1031971, NSF-OCE-0926986; WHOI Access to the Sea Grant Numbers: 27500056, 0734826; NSF HRD; UPR Central Administration to EAHD through the Center for Applied Tropical Ecology and Conservation of UPR
    Description: 2017-08-16
    Keywords: Coral ; Temperature ; Paleoceangraphy ; Paleothermometry ; Global warming ; Biomineralization
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  • 147
    Publication Date: 2022-05-25
    Description: Author Posting. © Ecological Society of America, 2017. This article is posted here by permission of Ecological Society of America for personal use, not for redistribution. The definitive version was published in Ecology 98 (2017): 940-951, doi:10.1002/ecy.1749.
    Description: Evidence of climate-change-driven shifts in plant and animal phenology have raised concerns that certain trophic interactions may be increasingly mismatched in time, resulting in declines in reproductive success. Given the constraints imposed by extreme seasonality at high latitudes and the rapid shifts in phenology seen in the Arctic, we would also expect Antarctic species to be highly vulnerable to climate-change-driven phenological mismatches with their environment. However, few studies have assessed the impacts of phenological change in Antarctica. Using the largest database of phytoplankton phenology, sea-ice phenology, and Adélie Penguin breeding phenology and breeding success assembled to date, we find that, while a temporal match between Penguin breeding phenology and optimal environmental conditions sets an upper limit on breeding success, only a weak relationship to the mean exists. Despite previous work suggesting that divergent trends in Adélie Penguin breeding phenology are apparent across the Antarctic continent, we find no such trends. Furthermore, we find no trend in the magnitude of phenological mismatch, suggesting that mismatch is driven by interannual variability in environmental conditions rather than climate-change-driven trends, as observed in other systems. We propose several criteria necessary for a species to experience a strong climate-change-driven phenological mismatch, of which several may be violated by this system.
    Description: Funding to H. J. Lynch and C. Youngflesh was provided by the National Science Foundation Grant OPP/GSS 1255058, to S. Jenouvrier, H. J. Lynch, C. Youngflesh, Y. Li, and R. Ji by the National Science Foundation Grant 1341474, to S. Jenouvrier, Y. Li, and R. Ji by NASA grant NNX14AH74G, to D. G. Ainley, G. Ballard, and K. M. Dugger by the National Science Foundation Grants OPP 9526865, 9814882, 0125608, 0944411 and 0440643, to P. O’B. Lyver by New Zealand’s Ministry of Business, Innovation, and Employment Grants C09X0510 and C01X1001, and Ministry of Primary Industry grants with logistic support from Antarctica New Zealand.
    Keywords: Anna Karenina Principle ; Antarctica ; Asynchrony ; Bayesian hierarchical model ; Climate change ; Phenology ; Pygoscelis adeliae ; Quantile regression
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  • 148
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    John Wiley & Sons
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 122 (2017): 941–954, doi:10.1002/2016JC012201.
    Description: The Cold Pool is a 20–60 m thick band of cold, near-bottom water that persists from spring to fall over the midshelf and outer shelf of the Middle Atlantic Bight (MAB) and Southern Flank of Georges Bank. The Cold Pool is remnant winter water bounded above by the seasonal thermocline and offshore by warmer slope water. Historical temperature profiles are used to characterize the average annual evolution and spatial structure of the Cold Pool. The Cold Pool gradually warms from spring to summer at a rate of order 1°C month−1. The warming rate is faster in shallower water where the Cold Pool is thinner, consistent with a vertical turbulent heat flux from the thermocline to the Cold Pool. The Cold Pool warming rate also varies along the shelf; it is larger over Georges Bank and smaller in the southern MAB. The mean turbulent diffusivities at the top of the Cold Pool, estimated from the spring to summer mean heat balance, are an order of magnitude larger over Georges Bank than in the southern MAB, consistent with much stronger tidal mixing over Georges Bank than in the southern MAB. The stronger tidal mixing causes the Cold Pool to warm more rapidly over Georges Bank and the eastern New England shelf than in the New York Bight or southern MAB. Consequently, the coldest Cold Pool water is located in the New York Bight from late spring to summer.
    Description: NSF Grant Number: OCE-1332666
    Description: 2017-08-02
    Keywords: Continental shelf circulation ; Cold Pool ; Middle Atlantic Bight ; Seasonal cycle
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  • 149
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 122 (2017): 1901–1926, doi:10.1002/2016JC012306.
    Description: Photosynthetic conversion of inline image to organic carbon and the transport of this carbon from the surface to the deep ocean is an important regulator of atmospheric inline image. To understand the controls on carbon fluxes in a productive region impacted by upwelling, we measured biological productivity via multiple methods during a cruise in Monterey Bay, California. We quantified net community production and gross primary production from measurements of inline image/Ar and inline image triple isotopes ( inline image), respectively. We simultaneously conducted incubations measuring the uptake of 14C, inline image, and inline image, and nitrification, and deployed sediment traps. At the start of the cruise (Phase 1) the carbon cycle was at steady state and the estimated net community production was 35(10) and 35(8) mmol C m−2 d−1 from inline image/Ar and 15N incubations, respectively, a remarkably good agreement. During Phase 1, net primary production was 96(27) mmol C m−2 d−1 from C uptake, and gross primary production was 209(17) mmol C m−2 d−1 from inline image. Later in the cruise (Phase 2), recently upwelled water with higher nutrient concentrations entered the study area, causing 14C and inline image uptake to increase substantially. Continuous inline image/Ar measurements revealed submesoscale variability in water mass structure and likely productivity in Phase 2 that was not evident from the incubations. These data demonstrate that inline image/Ar and inline image incubation-based NCP estimates can give equivalent results in an N-limited, coastal system, when the nonsteady state inline image fluxes are negligible or can be quantified.
    Description: Funding for this work was provided by NSF awards OCE-1060840 to R.H.R. Stanley, OCE-1129644 to D.P. Nicholson, OCE-1357042 to F.P. Chavez, NASA award NNX14AI06G to M.R. Fewings, the David and Lucile Packard Foundation through their generous annual donation to the Monterey Bay Aquarium Research Institute, an Ocean Ventures Fund award from the WHOI Academic Programs Office to CC Manning, and graduate scholarships from NSERC and CMOS to CC Manning.
    Description: 2017-09-11
    Keywords: Marine productivity ; Carbon cycle ; Dissolved gases
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  • 150
    Publication Date: 2022-05-25
    Description: © The Author(s), 2016. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in MicrobiologyOpen 5 (2016): 846–855, doi:10.1002/mbo3.374.
    Description: By taking advantage of the ballistoconidium-forming capabilities of members of the genus Sporobolomyces, we recovered ten isolates from deciduous tree leaves collected from Vermont and Washington, USA. Analysis of the small subunit ribosomal RNA gene and the D1/D2 domain of the large subunit ribosomal RNA gene indicate that all isolates are closely related. Further analysis of their physiological attributes shows that all were similarly pigmented yeasts capable of growth under aerobic and microaerophilic conditions, all were tolerant of repeated freezing and thawing, minimally tolerant to elevated temperature and desiccation, and capable of growth in liquid or on solid media containing pectin or galacturonic acid. The scientific literature on ballistoconidium-forming yeasts indicates that they are a polyphyletic group. Isolates of Sporobolomyces from two geographically separated sites show almost identical phenotypic and physiological characteristics and a monophyly with a broad group of differently named Sporobolomyces/Sporidiobolus species based on both small subunit ribosomal RNA (SSU rRNA) and D1/D2 domains of the LSU rRNA gene sequences.
    Keywords: Ballistospore ; D1/D2 ; Phylogeny ; Physiology ; rRNA ; Sporobolomyces
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  • 151
    Publication Date: 2022-05-25
    Description: © The Author(s), 2016. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Journal of Phycology 52 (2016): 716–731, doi:10.1111/jpy.12441.
    Description: Diatoms are highly productive single-celled algae that form an intricately patterned silica cell wall after every cell division. They take up and utilize silicic acid from seawater via silicon transporter (SIT) proteins. This study examined the evolution of the SIT gene family to identify potential genetic adaptations that enable diatoms to thrive in the modern ocean. By searching for sequence homologs in available databases, the diversity of organisms found to encode SITs increased substantially and included all major diatom lineages and other algal protists. A bacterial-encoded gene with homology to SIT sequences was also identified, suggesting that a lateral gene transfer event occurred between bacterial and protist lineages. In diatoms, the SIT genes diverged and diversified to produce five distinct clades. The most basal SIT clades were widely distributed across diatom lineages, while the more derived clades were lineage-specific, which together produced a distinct repertoire of SIT types among major diatom lineages. Differences in the predicted protein functional domains encoded among SIT clades suggest that the divergence of clades resulted in functional diversification among SITs. Both laboratory cultures and natural communities changed transcription of each SIT clade in response to experimental or environmental growth conditions, with distinct transcriptional patterns observed among clades. Together, these data suggest that the diversification of SITs within diatoms led to specialized adaptations among diatoms lineages, and perhaps their dominant ability to take up silicic acid from seawater in diverse environmental conditions.
    Description: Gordon and Betty Moore Foundation Grant Numbers: GBMF2637, GBMF3776; University of Washington; National Science Foundation Grant Number: OCE-1205233
    Keywords: Diatoms ; Gene family ; Molecular evolution ; Nutrients ; Silicon ; Transporter
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  • 152
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 43 (2016): 8645–8653, doi:10.1002/2016GL070226.
    Description: Estimates of primary and export production (PP and EP) based on satellite remote sensing algorithms and global biogeochemical models are widely used to provide year-round global coverage not available from direct observations. However, observational data to validate these approaches are limited. We find that no single satellite algorithm or model can reproduce seasonal and annual geochemically determined PP, export efficiency (EP/PP), and EP rates throughout the North Pacific basin, based on comparisons throughout the full annual cycle at time series stations in the subarctic and subtropical gyres and basin-wide regions sampled by container ship transects. The high-latitude regions show large PP discrepancies in winter and spring and strong effects of deep winter mixed layers on annual EP that cannot be accounted for in current satellite-based approaches. These results underscore the need to evaluate satellite- and model-based estimates using multiple productivity parameters measured over broad ocean regions throughout the annual cycle.
    Description: NDSEG Fellowship from the Office of Naval Research; NSF Graduate Research Fellowship; ARCS Foundation Fellowship
    Description: 2017-02-28
    Keywords: North Pacific ; Productivity ; Biological pump ; Carbon cycle
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  • 153
    Publication Date: 2022-05-25
    Description: This paper is not subject to U.S. copyright. The definitive version was published in Journal of Geophysical Research: Oceans 122 (2017): 3505–3518, doi:10.1002/2017JC012727.
    Description: A 3-D variational ocean data assimilation adjoint approach is used to examine the impact of ocean observations on coupled tropical cyclone (TC) model forecast error for three recent hurricanes: Isaac (2012), Hilda (2015), and Matthew (2016). In addition, this methodology is applied to develop an innovative ocean observation targeting tool validated using TC model simulations that assimilate ocean temperature observed by Airborne eXpendable Bathy Thermographs and Air-Launched Autonomous Micro-Observer floats. Comparison between the simulated targeted and real observation data assimilation impacts reveals a positive maximum mean linear correlation of 0.53 at 400–500 m, which implies some skill in the targeting application. Targeted ocean observation regions from these three hurricanes, however, show that the largest positive impacts in reducing the TC model forecast errors are sensitive to the initial prestorm ocean conditions such as the location and magnitude of preexisting ocean eddies, storm-induced ocean cold wake, and model track errors.
    Description: ONR Grant Numbers: N0001416WX01949, N0001416WX01384, N0001416WX01262; NOAA Grant Number: NA13OAR4830233
    Keywords: Tropical cyclone ; Ocean data assimilation ; Ocean sampling ; Air-sea interaction
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  • 154
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 122 (2017): 3519–3542, doi:10.1002/2016JC012519.
    Description: Observations from two companion field programs—Origins of the Kuroshio and Mindanao Current (OKMC) and Observations of Kuroshio Transport Variability (OKTV)—are used here to examine the Kuroshio's temporal and spatial evolution. Kuroshio strength and velocity structure were measured between June 2012 and November 2014 with pressure-sensor equipped inverted echo sounders (PIESs) and upward-looking acoustic Doppler current profilers (ADCPs) deployed across the current northeast of Luzon, Philippines, and east of Taiwan with an 8 month overlap in the two arrays' deployment periods. The time-mean net (i.e., integrated from the surface to the bottom) absolute transport increases downstream from 7.3 Sv (±4.4 Sv standard error) northeast of Luzon to 13.7 Sv (±3.6 Sv) east of Taiwan. The observed downstream increase is consistent with the return flow predicted by the simple Sverdrup relation and the mean wind stress curl field over the North Pacific (despite the complicated bathymetry and gaps along the North Pacific western boundary). Northeast of Luzon, the Kuroshio—bounded by the 0 m s−1 isotach—is shallower than 750 dbar, while east of Taiwan areas of positive flow reach to the seafloor (3000 m). Both arrays indicate a deep counterflow beneath the poleward-flowing Kuroshio (–10.3 ± 2.3 Sv by Luzon and −12.5 ± 1.2 Sv east of Taiwan). Time-varying transports and velocities indicate the strong influence at both sections of westward propagating eddies from the ocean interior. Topography associated with the ridges east of Taiwan also influences the mean and time-varying velocity structure there.
    Description: Office of Naval Research (ONR) Grant Numbers: N00014-15-12593 , N00014-16-13069; Taiwan's Ministry of Science and Technology Grant Numbers: NSC 101-2611-M-002-018-MY3 , MOST 103-2611-M-002-011 , MOST 105-2119-M-002-042; ONR Grant Numbers: N00014-10-1-0308 , N00015-10-1-0469
    Description: 2017-11-02
    Keywords: Kuroshio ; PIES ; ADCP ; Eddies ; Western boundary current ; Altimetry
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  • 155
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 31 (2017): 922–940, doi:10.1002/2016GB005615.
    Description: A coupled global numerical simulation (conducted with the Community Earth System Model) is used in conjunction with satellite remote sensing observations to examine the role of top-down (grazing pressure) and bottom-up (light, nutrients) controls on marine phytoplankton bloom dynamics in the Southern Ocean. Phytoplankton seasonal phenology is evaluated in the context of the recently proposed “disturbance-recovery” hypothesis relative to more traditional, exclusively “bottom-up” frameworks. All blooms occur when phytoplankton division rates exceed loss rates to permit sustained net population growth; however, the nature of this decoupling period varies regionally in Community Earth System Model. Regional case studies illustrate how unique pathways allow blooms to emerge despite very poor division rates or very strong grazing rates. In the Subantarctic, southeast Pacific small spring blooms initiate early cooccurring with deep mixing and low division rates, consistent with the disturbance-recovery hypothesis. Similar systematics are present in the Subantarctic, southwest Atlantic during the spring but are eclipsed by a subsequent, larger summer bloom that is coincident with shallow mixing and the annual maximum in division rates, consistent with a bottom-up, light limited framework. In the model simulation, increased iron stress prevents a similar summer bloom in the southeast Pacific. In the simulated Antarctic zone (70°S–65°S) seasonal sea ice acts as a dominant phytoplankton-zooplankton decoupling agent, triggering a delayed but substantial bloom as ice recedes. Satellite ocean color remote sensing and ocean physical reanalysis products do not precisely match model-predicted phenology, but observed patterns do indicate regional variability in mechanism across the Atlantic and Pacific.
    Description: NDSEG Graduate Fellowship; National Aeronautics and Space Administration Ocean Biology and Biogeochemistry Program Grant Number: NNX14L86G; NSF Poloar Programs Award Grant Number: 1440435; National Aeronautics and Space Administration Grant Number: NNX14AL86G; NDSEG; National Science Foundation Grant Number: 1440435
    Description: 2017-11-30
    Keywords: Southern Ocean ; Phytoplankton ; Bloom phenology ; Top-down controls ; Bottom-up controls ; Modeling
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  • 156
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 44 (2017): 5627–5636, doi:10.1002/2017GL073814.
    Description: Variability and change in the ocean sink of anthropogenic carbon dioxide (CO2) have implications for future climate and ocean acidification. Measurements of surface seawater CO2 partial pressure (pCO2) and wind speed from moored platforms are used to calculate high-resolution CO2 flux time series. Here we use the moored CO2 fluxes to examine variability and its drivers over a range of time scales at four locations in the Pacific Ocean. There are significant surface seawater pCO2, salinity, and wind speed trends in the North Pacific subtropical gyre, especially during winter and spring, which reduce CO2 uptake over the 10 year record of this study. Starting in late 2013, elevated seawater pCO2 values driven by warm anomalies cause this region to be a net annual CO2 source for the first time in the observational record, demonstrating how climate forcing can influence the timing of an ocean region shift from CO2 sink to source.
    Description: NOAA, OAR, CPO, OOMD Grant Number: 100007298; NOAA, OAR, CPO, OOMD Grant Number: NA09OAR4320129; Ocean Observation and Monitoring Division (OOMD) Grant Number: NA09OAR4320129; National Oceanic and Atmospheric Administration (NOAA) Grant Number: 100007298
    Description: 2017-12-12
    Keywords: Sea-air CO2 flux ; Surface ocean pCO2 ; Ocean carbon ; Anthropogenic change
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  • 157
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 18 (2017): 676–696, doi:10.1002/2016GC006667.
    Description: Tectonic plate motion and mantle dynamics processes are heavily influenced by the characteristics of the lithosphere-asthenosphere boundary (LAB), yet this boundary remains enigmatic regarding its properties and geometry. The processes involved in rifting at passive margins result in substantial alteration of the lithosphere through the transition from continental to oceanic lithologies. Here we employ marine magnetotelluric (MT) data acquired along a ∼135 km long profile, offshore Martha's Vineyard, New England, USA, to image the electrical conductivity structure beneath the New England continental margin for the first time. We invert the data using two different MT 2-D inversion algorithms and present a series of models that are obtained using three different parameterizations: fully unconstrained, unconstrained with an imposed LAB discontinuity and a priori constrained lithosphere resistivity. This suite of models infers variability in the depth of the LAB, with an average depth of 115 km at the eastern North America passive margin. Models robustly detect a ∼350 Ωm lithospheric anomalous conductivity zone (LACZ) that extends vertically through the entire lithosphere. Our preferred conductivity model is consistent with regional P-to-S receiver function data, shear-wave velocity, gravity anomalies, and prominent geological features. We propose that the LACZ is indicative of paleolithospheric thinning, either resulting from kimberlite intrusions associated with rifting and the New England Great Meteor hot spot track, or from shear-driven localized deformation related to rifting.
    Description: NSF Grant Number: OCE-0958878, OCE-1459035, OCE-1458392, and OCE-1536161
    Description: 2017-08-25
    Keywords: Lithosphere-asthensphere boundary (LAB) ; Magnetotelluric (MT) ; 2-D MT inversion ; Conductivity structure ; Kimberlite intrusion ; Shear-driven deformation
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  • 158
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 32 (2017): 512–530, doi:10.1002/2016PA003072.
    Description: The carbon isotope composition (δ13C) of seawater provides valuable insight on ocean circulation, air-sea exchange, the biological pump, and the global carbon cycle and is reflected by the δ13C of foraminifera tests. Here more than 1700 δ13C observations of the benthic foraminifera genus Cibicides from late Holocene sediments (δ13CCibnat) are compiled and compared with newly updated estimates of the natural (preindustrial) water column δ13C of dissolved inorganic carbon (δ13CDICnat) as part of the international Ocean Circulation and Carbon Cycling (OC3) project. Using selection criteria based on the spatial distance between samples, we find high correlation between δ13CCibnat and δ13CDICnat, confirming earlier work. Regression analyses indicate significant carbonate ion (−2.6 ± 0.4) × 10−3‰/(μmol kg−1) [CO32−] and pressure (−4.9 ± 1.7) × 10−5‰ m−1 (depth) effects, which we use to propose a new global calibration for predicting δ13CDICnat from δ13CCibnat. This calibration is shown to remove some systematic regional biases and decrease errors compared with the one-to-one relationship (δ13CDICnat = δ13CCibnat). However, these effects and the error reductions are relatively small, which suggests that most conclusions from previous studies using a one-to-one relationship remain robust. The remaining standard error of the regression is generally σ ≅ 0.25‰, with larger values found in the southeast Atlantic and Antarctic (σ ≅ 0.4‰) and for species other than Cibicides wuellerstorfi. Discussion of species effects and possible sources of the remaining errors may aid future attempts to improve the use of the benthic δ13C record.
    Description: U.S. National Science Foundation Grant Numbers: 1634719, 0926735, 1125181; Swiss National Science Foundation Grant Numbers: PP00P2_144811, 200021_163003; Canadian Institute for Advanced Research (CIFAR); Canadian Foundation for Innovation (CFI); Natural Sciences and Engineering Research Council (NSERC)
    Description: 2017-12-03
    Keywords: Carbon ; Isotopes ; Benthic ; Foraminifera ; Calibration
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  • 159
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 122 (2017): 4743–4760, doi:10.1002/2016JC012455.
    Description: Estuarine mixing is often intensified in regions where topographic forcing leads to hydraulic transitions. Observations in the salt-wedge estuary of the Connecticut River indicate that intense mixing occurs during the ebb tide in regions of supercritical flow that is accelerated by lateral expansion of the channel. The zones of mixing are readily identifiable based on echo-sounding images of large-amplitude shear instabilities. The gradient Richardson number (Ri) averaged across the mixing layer decreases to a value very close to 0.25 during most of the active mixing phase. The along-estuary variation in internal Froude number and interface elevation are roughly consistent with a steady, inviscid, two-layer hydraulic representation, and the fit is improved when a parameterization for interfacial stress is included. The analysis indicates that the mixing results from lateral straining of the shear layer, and that the rapid development of instabilities maintains the overall flow near the mixing threshold value of Ri = 0.25, even with continuous, active mixing. The entrainment coefficient can be estimated from salt conservation within the interfacial layer, based on the finding that the mixing maintains Ri = 0.25. This approach leads to a scaling estimate for the interfacial mixing coefficient based on the lateral spreading rate and the aspect ratio of the flow, yielding estimates of turbulent dissipation within the pycnocline that are consistent with estimates based on turbulence-resolving measurements.
    Description: NSF Grant Number: OCE 0926427; Devonshire Scholars program
    Description: 2017-12-12
    Keywords: Internal hydraulics ; Mixing ; Gradient Richardson number ; Estuary
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  • 160
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 122 (2017): 1425–1438, doi:10.1002/2016JC012162.
    Description: Understanding the physical and biogeochemical processes that control CO2 and dissolved oxygen (DO) dynamics in the Arctic Ocean (AO) is crucial for predicting future air-sea CO2 fluxes and ocean acidification. Past studies have primarily been conducted on the AO continental shelves during low-ice periods and we lack information on gas dynamics in the deep AO basins where ice typically inhibits contact with the atmosphere. To study these gas dynamics, in situ time-series data have been collected in the Canada Basin during late summer to autumn of 2012. Partial pressure of CO2 (pCO2), DO concentration, temperature, salinity, and chlorophyll-a fluorescence (Chl-a) were measured in the upper ocean in a range of sea ice states by two drifting instrument systems. Although the two systems were on average only 222 km apart, they experienced considerably different ice cover and external forcings during the 40–50 day periods when data were collected. The pCO2 levels at both locations were well below atmospheric saturation whereas DO was almost always slightly supersaturated. Modeling results suggest that air-sea gas exchange, net community production (NCP), and horizontal gradients were the main sources of pCO2 and DO variability in the sparsely ice-covered AO. In areas more densely covered by sea ice, horizontal gradients were the dominant source of variability, with no significant NCP in the surface mixed layer. If the AO reaches equilibrium with atmospheric CO2 as ice cover continues to decrease, aragonite saturation will drop from a present mean of 1.00 ± 0.02 to 0.86 ± 0.01.
    Description: U.S. National Science Foundation Arctic Observing Network Grant Number: ARC-1107346 and ARC-0856479
    Description: 2017-08-25
    Keywords: Arctic Ocean ; CO2 ; O2 ; Biogeochemistry ; Dynamics ; Carbon cycle
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  • 161
    Publication Date: 2022-05-25
    Description: © The Author(s), 2017. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in MicrobiologyOpen 6 (2017): e467, doi:10.1002/mbo3.467.
    Description: Fueled by seasonal phytoplankton blooms, the Columbia River estuary is a natural bioreactor for organic matter transformations. Prior metagenome analyses indicated high abundances of diverse Bacteroidetes taxa in estuarine samples containing phytoplankton. To examine the hypothesis that Bacteroidetes taxa have important roles in phytoplankton turnover, we further analyzed metagenomes from water collected along a salinity gradient at 0, 5, 15, 25, and 33 PSU during bloom events. Size fractions were obtained by using a 3-μm prefilter and 0.2-μm collection filter. Although this approach targeted bacteria by removing comparatively large eukaryotic cells, the metagenome from the ES-5 sample (5 PSU) nevertheless contained an abundance of diatom DNA. Biogeochemical measurements and prior studies indicated that this finding resulted from the leakage of cellular material due to freshwater diatom lysis at low salinity. Relative to the other metagenomes, the bacterial fraction of ES-5 was dramatically depleted of genes annotated as Bacteroidetes and lysogenic bacteriophages, but was overrepresented in DNA of protists and Myxococcales bacterivores. We suggest the following equally plausible scenarios for the microbial response to phytoplankton lysis: (1) Bacteroidetes depletion in the free-living fraction may at least in part be caused by their attachment to fluvial diatoms as the latter are lysed upon contact with low-salinity estuarine waters; (2) diatom particle colonization is likely followed by rapid bacterial growth and lytic phage infection, resulting in depletion of lysogenic bacteriophages and host bacteria; and (3) the subsequent availability of labile organic matter attracted both grazers and predators to feed in this estuarine biogeochemical “hotspot,” which may have additionally depleted Bacteroidetes populations. These results represent the first detailed molecular analysis of the microbial response to phytoplankton lysis at the freshwater–brackish water interface in the fast-flowing Columbia River estuary.
    Description: National Science Foundation Grant Numbers: OCE 0424602, MCB 0644468
    Keywords: Bacteroidetes ; Metagenome analysis ; Phytoplankton bloom degradation
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  • 162
    Publication Date: 2022-05-25
    Description: © The Author(s), 2017. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Journal of Geophysical Research: Biogeosciences 122 (2017): 1529–1548, doi:10.1002/2016JG003668.
    Description: During the Norwegian young sea ICE expedition (N-ICE2015) from January to June 2015 the pack ice in the Arctic Ocean north of Svalbard was studied during four drifts between 83° and 80°N. This pack ice consisted of a mix of second year, first year, and young ice. The physical properties and ice algal community composition was investigated in the three different ice types during the winter-spring-summer transition. Our results indicate that algae remaining in sea ice that survived the summer melt season are subsequently trapped in the upper layers of the ice column during winter and may function as an algal seed repository. Once the connectivity in the entire ice column is established, as a result of temperature-driven increase in ice porosity during spring, algae in the upper parts of the ice are able to migrate toward the bottom and initiate the ice algal spring bloom. Furthermore, this algal repository might seed the bloom in younger ice formed in adjacent leads. This mechanism was studied in detail for the dominant ice diatom Nitzschia frigida. The proposed seeding mechanism may be compromised due to the disappearance of older ice in the anticipated regime shift toward a seasonally ice-free Arctic Ocean.
    Description: Norwegian Research Council Grant Number: 244646; Norwegian Ministry of Climate and Environment Grant Number: N-ICE; Norwegian Research Council Grant Number: 221961; Norwegian Ministry of Foreign Affairs Grant Number: ID Arctic; Norwegian Ministry of Foreign Affairs and Ministry of Climate and Environment, Norway; Polish-Norwegian Research Program Grant Number: Pol-Nor/197511/40/2013; Research Council of Norway project STASIS Grant Number: 221961; Natural Sciences and Engineering Research Council of Canada (NSERC) Discovery Grant Canada Foundation for Innovation Investment in Science Fund; Research Council of Norway project Boom or Bust Grant Number: 244646; Centre of Ice, Climate and Ecosystems
    Keywords: Ice algae ; Arctic ; Sea ice ; N-ICE ; Multiyear ice ; Seeding
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  • 163
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 32 (2018): 389-416, doi:10.1002/2017GB005790.
    Description: Carbon cycling in the coastal zone affects global carbon budgets and is critical for understanding the urgent issues of hypoxia, acidification, and tidal wetland loss. However, there are no regional carbon budgets spanning the three main ecosystems in coastal waters: tidal wetlands, estuaries, and shelf waters. Here we construct such a budget for eastern North America using historical data, empirical models, remote sensing algorithms, and process‐based models. Considering the net fluxes of total carbon at the domain boundaries, 59 ± 12% (± 2 standard errors) of the carbon entering is from rivers and 41 ± 12% is from the atmosphere, while 80 ± 9% of the carbon leaving is exported to the open ocean and 20 ± 9% is buried. Net lateral carbon transfers between the three main ecosystem types are comparable to fluxes at the domain boundaries. Each ecosystem type contributes substantially to exchange with the atmosphere, with CO2 uptake split evenly between tidal wetlands and shelf waters, and estuarine CO2 outgassing offsetting half of the uptake. Similarly, burial is about equal in tidal wetlands and shelf waters, while estuaries play a smaller but still substantial role. The importance of tidal wetlands and estuaries in the overall budget is remarkable given that they, respectively, make up only 2.4 and 8.9% of the study domain area. This study shows that coastal carbon budgets should explicitly include tidal wetlands, estuaries, shelf waters, and the linkages between them; ignoring any of them may produce a biased picture of coastal carbon cycling.
    Description: NASA Interdisciplinary Science program Grant Number: NNX14AF93G; NASA Carbon Cycle Science Program Grant Number: NNX14AM37G; NASA Ocean Biology and Biogeochemistry Program Grant Number: NNX11AD47G; National Science Foundation's Chemical Oceanography Program Grant Number: OCE‐1260574
    Description: 2018-10-04
    Keywords: Carbon cycle ; Coastal zone ; Tidal wetlands ; Estuaries ; Shelf waters
    Repository Name: Woods Hole Open Access Server
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  • 164
    Publication Date: 2022-05-25
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Global Biogeochemical Cycles 32 (2018): 594-616, doi:10.1002/2017GB005830.
    Description: Cobalt is an important micronutrient for ocean microbes as it is present in vitamin B12 and is a co‐factor in various metalloenzymes that catalyze cellular processes. Moreover, when seawater availability of cobalt is compared to biological demands, cobalt emerges as being depleted in seawater, pointing to a potentially important limiting role. To properly account for the potential biological role for cobalt, there is therefore a need to understand the processes driving the biogeochemical cycling of cobalt and, in particular, the balance between external inputs and internal cycling. To do so, we developed the first cobalt model within a state‐of‐the‐art three‐dimensional global ocean biogeochemical model. Overall, our model does a good job in reproducing measurements with a correlation coefficient of 〉0.7 in the surface and 〉0.5 at depth. We find that continental margins are the dominant source of cobalt, with a crucial role played by supply under low bottom‐water oxygen conditions. The basin‐scale distribution of cobalt supplied from margins is facilitated by the activity of manganese‐oxidizing bacteria being suppressed under low oxygen and low temperatures, which extends the residence time of cobalt. Overall, we find a residence time of 7 and 250 years in the upper 250 m and global ocean, respectively. Importantly, we find that the dominant internal resupply process switches from regeneration and recycling of particulate cobalt to dissolution of scavenged cobalt between the upper ocean and the ocean interior. Our model highlights key regions of the ocean where biological activity may be most sensitive to cobalt availability.
    Description: EC | H2020 | H2020 Priority Excellent Science | H2020 European Research Council (ERC) Grant Number: 724289; Natural Environment Research Council (NERC) Grant Number: NE/N001079/1; Gordon and Betty Moore Foundation Grant Number: 3738; NSF OCE Grant Numbers: 0929919, 0752832, 0649639, 0223378, 1658030, 1736599; NERC Grant Number: NE/N001079/1; European Research Council Grant Number: 724289
    Keywords: Biogeochemistry ; Trace elements ; Modeling
    Repository Name: Woods Hole Open Access Server
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  • 165
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 45 (2018): 3203-3211, doi:10.1002/2017GL075361.
    Description: To assess phytoplankton nutritional status in seasonally oligotrophic waters of the southern Mid‐Atlantic Bight, and the potential for rain to stimulate primary production in this region during summer, shipboard bioassay experiments were performed using natural seawater and phytoplankton collected north and south of the Gulf Stream. Bioassay treatments comprised iron, nitrate, iron + nitrate, iron + nitrate + phosphate, and rainwater. Phytoplankton growth was inferred from changes in chlorophyll a, inorganic nitrogen, and carbon‐13 uptake, relative to unamended control treatments. Results indicated the greatest growth stimulation by iron + nitrate + phosphate, intermediate growth stimulation by rainwater, modest growth stimulation by nitrate and iron + nitrate, and no growth stimulation by iron. Based on these data and analysis of seawater and atmospheric samples, nitrogen was the proximate limiting nutrient, with a secondary limitation imposed by phosphorus. Our results imply that summer rain events increase new production in these waters by contributing nitrogen and phosphorus, with the availability of the latter setting the upper limit on rain‐stimulated new production.
    Description: US National Science Foundation Grant Numbers: OCE‐1260454, OCE‐1260454, OCE‐1260574
    Description: 2018-09-12
    Keywords: Nutrients ; Phytoplankton ; Atmospheric deposition ; Iron ; Primary production ; Rainwater
    Repository Name: Woods Hole Open Access Server
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  • 166
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 45 (2018): 4933-4943, doi:10.1029/2018GL078056.
    Description: Seagrasses are marine flowering plants that strongly impact their physical and biological surroundings and are therefore frequently referred to as ecological engineers. The effect of seagrasses on coastal bay resilience and sediment transport dynamics is understudied. Here we use six historical maps of seagrass distribution in Barnegat Bay, USA, to investigate the role of these vegetated surfaces on the sediment storage capacity of shallow bays. Analyses are carried out by means of the Coupled‐Ocean‐Atmosphere‐Wave‐Sediment Transport (COAWST) numerical modeling framework. Results show that a decline in the extent of seagrass meadows reduces the sediment mass potentially stored within bay systems. The presence of seagrass reduces shear stress values across the entire bay, including unvegetated areas, and promotes sediment deposition on tidal flats. On the other hand, the presence of seagrasses decreases suspended sediment concentrations, which in turn reduces the delivery of sediment to marsh platforms. Results highlight the relevance of seagrasses for the long‐term survival of coastal ecosystems, and the complex dynamics regulating the interaction between subtidal and intertidal landscapes.
    Description: 2018-10-30
    Keywords: Seagrass ; Sediment transport ; COAWST ; Salt marsh ; Ecosystems
    Repository Name: Woods Hole Open Access Server
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  • 167
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 45 (2018): 3221-3227, doi:10.1002/2017GL076821.
    Description: Global mean sea surface temperature ((T) over bar) is a variable of primary interest in studies of climate variability and change. The temporal evolution of (T) over bar) can be influenced by surface heat fluxes ((F) over bar)) and by diffusion ((D) over bar)) and advection ((A) over bar)) processes internal to the ocean, but quantifying the contribution of these different factors from data alone is prone to substantial uncertainties. Here we derive a closed (T) over bar) budget for the period 1993-2015 based on a global ocean state estimate, which is an exact solution of a general circulation model constrained to most extant ocean observations through advanced optimization methods. The estimated average temperature of the top (10-m thick) level in the model, taken to represent (T) over bar), shows relatively small variability at most time scales compared to (F) over bar), (D) over bar), or (A) over bar), reflecting the tendency for largely balancing effects from all the latter terms. The seasonal cycle in (T) over bar) is mostly determined by small imbalances between (F) over bar) and (D) over bar), with negligible contributions from (A) over bar). While (D) over bar) seems to simply damp (F) over bar) at the annual period, a different dynamical role for (D) over bar) at semiannual period is suggested by it being larger than (F) over bar). At periods longer than annual, (A) over bar) contributes importantly to (T) over bar) variability, pointing to the direct influence of the variable ocean circulation on (T) over bar) and mean surface climate. Plain Language Summary Global mean sea surface temperature (T) over bar) is a key metric when defining the Earth's climate. Determining what controls the evolution of (T) over bar )T is thus vital for understanding past climate variability and predicting its future evolution. Processes that control (T) over bar) involve forcing surface heat fluxes, as well as advection and diffusion of heat internal to the ocean, but their relative contributions are poorly known and difficult to assess from observations alone. Here we use advanced methods to combine models and data and derive a closed budget for (T) over bar) variability in terms of the forcing, advection, and diffusion processes. The estimated (T) over bar) shows relatively small variability compared to surface forcing, advection, or diffusion, reflecting the tendency for largely balancing effects from all the latter terms. The seasonal cycle in (T) over bar) is mostly determined by small imbalances between forcing and diffusion, with negligible contributions from advection. Diffusion does not always act as a simple damping of forcing surface fluxes, however. In addition, at periods longer than annual, advection contributes importantly to (T) over bar) variability. The results point to the direct influence of the variable ocean circulation on (T) over bar) and the Earth's surface climate.
    Description: NSF Grant Number: PLR-1513396
    Description: 2018-09-25
    Keywords: Sea surface temperature
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  • 168
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 123 (2018): 2615-2634, doi:10.1002/2017JC013536.
    Description: In this work, we use realistic isopycnal velocities with a 3-D eddy diffusivity to advect and diffuse a tracer in the Antarctic Circumpolar Current, beginning in the Southeast Pacific and progressing through Drake Passage. We prescribe a diapycnal diffusivity which takes one value in the SE Pacific west of 678W and another value in Drake Passage east of that longitude, and optimize the diffusivities using a cost function to give a best fit to experimental data from the DIMES (Diapycnal and Isopycnal Mixing Experiment in the Southern Ocean) tracer, released near the boundary between the Upper and Lower Circumpolar Deep Water. We find that diapycnal diffusivity is enhanced 20-fold in Drake Passage compared with the SE Pacific, consistent with previous estimates obtained using a simpler advection-diffusion model with constant, but different, zonal velocities east and west of 678W. Our result shows that diapycnal mixing in the ACC plays a significant role in transferring buoyancy within the Meridional Overturning Circulation.
    Description: UK Natural Environment Research Council Grant Numbers: NE/F020252/1 , NE/N018028/1 , NE/J007757/1; US National Science Foundation Grant Numbers: OCE 0622825 , OCE 1232962
    Description: 2018-09-26
    Keywords: Diapycnal mixing ; Ocean circulation ; Tracer experiment ; Ocean model
    Repository Name: Woods Hole Open Access Server
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  • 169
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 123 (2018): 3832-3843, doi:10.1029/2017JC013722.
    Description: Observations of currents, water levels, winds, and bathymetry collected for a month at an unstratified, narrow (150 m), shallow (8 m), 90° tidal inlet bend are used to evaluate an analytical model for curvature‐driven flow and the effects of local wind on the cross‐channel circulation. Along‐channel flows ranged from −1.0 to 1.4 m/s (positive is inland), and the magnitudes of cross‐channel flows were roughly 0.1–0.2 m/s near the outer bank of the bend. Cross‐channel observations suggest the lateral sea‐surface gradients and along‐channel flows are tidally asymmetric and spatially variable. The depth‐averaged along‐channel dynamics are consistent with a balance between the surface tilt and centrifugal acceleration. The vertical structure and magnitude of cross‐channel flows during weak winds are consistent with a one‐dimensional depth‐varying balance between centrifugal acceleration, bottom stress, and diffusion. Low‐passed (to remove tides) surface and bottom cross‐channel flows are correlated (r2 = 0.5–0.7) with cross‐channel wind velocity, suggesting that winds can enhance or degrade the local‐curvature‐induced, two‐layer flow and can drive three‐layer flow. The observed flow response to the wind is larger than that expected from a one‐dimensional balance, suggesting that two‐dimensional and three‐dimensional processes may be important.
    Description: Funding was provided by the Office of Naval Research, a National Defense Science and Engineering Graduate award, and a Vannevar Bush Faculty Fellowship from the Office of the Assistant Secretary of Defense for Research and Engineering.
    Description: 2018-10-19
    Keywords: Cross‐channel flows ; Curvature ; Wind ; Tidal inlet ; Channel bend
    Repository Name: Woods Hole Open Access Server
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  • 170
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 123 (2018): 4110–4131, doi:10.1029/2017JC013414.
    Description: The relationship between North Pacific variability and sea surface temperature (SST) of the Northwest Atlantic continental shelf is examined over interannual time scale in 1982–2014. Statistically significant negative correlations exist between Pacific Decadal Oscillation (PDO) index and SST in the Gulf of Maine (GoM) in spring and summer. Cross‐correlation analysis further suggests significant negative lead‐lag correlations, with the spring PDO leading the GoM SST by 0–3 months while the summer PDO lags by 1–3 months. These correlations are dominated by the interannual component of the PDO. Statistical relationships are placed in context by further investigating the physical processes controlling the upper ocean mixed layer temperature budget in the GoM. The results reveal contrasting roles between the atmosphere and the ocean in spring and summer, respectively. Local atmospheric forcings, in particular the radiative air‐sea fluxes, are the dominant driver for the interannual variability of springtime SST over the Northwest Atlantic shelf. In contrast, oceanic terms are important in controlling the interannual variability of summertime SST. As a result, reconstructed SST using atmospheric forcings successfully reproduces the statistical relationship with PDO in spring, but not in summer. Furthermore, it is shown that the SST anomalies in the central and eastern North Pacific play a key role in these relationships.
    Description: National Science Foundation Ocean Science Division Grant Numbers: OCE‐1435602 , OCE‐1558960 , OCE‐1634094; National Oceanic and Atmospheric Administration Climate Program Office MAPP program Grant Number: NA170AR4310111
    Description: 2018-12-28
    Keywords: Continental shelf temperature variability ; Atmosphere‐ocean interaction ; Mixed layer temperature ; Coastal to large‐scale connections ; Pacific Decadal Oscillation
    Repository Name: Woods Hole Open Access Server
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  • 171
    Publication Date: 2022-05-25
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Journal of Geophysical Research: Oceans 123 (2018): 4853-4873, doi:10.1029/2018JC013888.
    Description: The first full transarctic section of 228Ra in surface waters measured during GEOTRACES cruises PS94 and HLY1502 (2015) shows a consistent distribution with maximum activities in the transpolar drift. Activities in the central Arctic have increased from 2007 through 2011 to 2015. The increased 228Ra input is attributed to stronger wave action on shelves resulting from a longer ice‐free season. A concomitant decrease in the 228Th/228Ra ratio likely results from more rapid transit of surface waters depleted in 228Th by scavenging over the shelf. The 228Ra activities observed in intermediate waters (〈1,500 m) in the Amundsen Basin are explained by ventilation with shelf water on a time scale of about 15–18 years, in good agreement with estimates based on SF6 and 129I/236U. The 228Th excess below the mixed layer up to 1,500 m depth can complement 234Th and 210Po as tracers of export production, after correction for the inherent excess resulting from the similarity of 228Ra and 228Th decay times. We show with a Th/Ra profile model that the 228Th/228Ra ratio below 1,500 m is inappropriate for this purpose because it is a delicate balance between horizontal supply of 228Ra and vertical flux of particulate 228Th. The accumulation of 226Ra in the deep Makarov Basin is not associated with an accumulation of Ba and can therefore be attributed to supply from decay of 230Th in the bottom sediment. We estimate a ventilation time of 480 years for the deep Makarov‐Canada Basin, in good agreement with previous estimates using other tracers.
    Description: U.S. National Science Foundation Grant Numbers: OCE‐1458305, OCE‐1458424; US NSF Grant Number: OCE‐1433922
    Keywords: Radium‐228 ; Thorium‐228 ; Arctic Ocean ; Transpolar drift ; GEOTRACES
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  • 172
    Publication Date: 2022-05-25
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in MicrobiologyOpen 7 (2018): e00586, doi:10.1002/mbo3.586.
    Description: Chemoautotrophic bacteria belonging to the genus Sulfurimonas in the class Campylobacteria are widespread in many marine environments characterized by redox interfaces, yet little is known about their physiological adaptations to different environmental conditions. Here, we used liquid chromatography coupled with tandem mass spectrometry (LC-MS/ MS) in a targeted metabolomics approach to study the adaptations of Sulfurimonas denitrificans to varying salt concentrations that are found in its natural habitat of tidal mudflats. Proline was identified as one of the most abundant internal metabolites and its concentration showed a strong positive correlation with ionic strength, suggesting that it acts as an important osmolyte in S. denitrificans. 2,3-dihydroxypropane- 1- sulfonate was also positively correlated with ionic strength, indicating it might play a previously unrecognized role in osmoregulation. Furthermore, the detection of metabolites from the reductive tricarboxylic acid cycle at high internal concentrations reinforces the importance of this pathway for carbon fixation in Campylobacteria and as a hub for biosynthesis. As the first report of metabolomic data for an campylobacterial chemolithoautotroph, this study provides data that will be useful to understand the adaptations of Campylobacteria to their natural habitat at redox interfaces.
    Description: NSF, Grant/Award Number: OCE- 1136727 and OCE-1154320; Woods Hole Oceanographic Institution; U.S. Geological Survey
    Keywords: Environmental stress ; Metabolism ; Metabolomics ; Microbial ecology ; Osmoregulation ; Sulfurimonas
    Repository Name: Woods Hole Open Access Server
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  • 173
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 123 (2018): 5571-5586, doi:10.1029/2018JC014096.
    Description: The Arctic ice cover influences the generation, propagation, and dissipation of internal waves, which in turn may affect vertical mixing in the ocean interior. The Arctic internal wavefield and its relationship to the ice cover is investigated using observations from Ice‐Tethered Profilers with Velocity and Seaglider sampling during the 2014 Marginal Ice Zone experiment in the Canada Basin. Ice roughness, ice concentration, and wind forcing all influenced the daily to seasonal changes in the internal wavefield. Three different ice concentration thresholds appeared to determine the evolution of internal wave spectral energy levels: (1) the initial decrease from 100% ice concentration after which dissipation during the surface reflection was inferred to increase, (2) the transition to 70–80% ice concentration when the local generation of internal waves increased, and (3) the transition to open water that was associated with larger‐amplitude internal waves. Ice roughness influenced internal wave properties for ice concentrations greater than approximately 70–80%: smoother ice was associated with reduced local internal wave generation. Richardson numbers were rarely supercritical, consistent with weak vertical mixing under all ice concentrations. On decadal timescales, smoother ice may counteract the effects of lower ice concentration on the internal wavefield complicating future predictions of internal wave activity and vertical mixing.
    Description: Seagliders Grant Number: N00014‐12‐10180; Deployment and subsequent analysis efforts of the ITP‐Vs Grant Numbers: N00014‐12‐10799, N00014‐12‐10140; Joint Ocean Ice Studies cruise; Beaufort Gyre Observing System
    Description: 2019-02-14
    Keywords: Internal waves ; Arctic ; Near‐inertial ; Ice roughness ; Ice concentration
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  • 174
    Publication Date: 2022-05-25
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Journal of Geophysical Research: Oceans 123 (2018): 6373-6391, doi:10.1029/2018JC013814.
    Description: We quantify Atlantic Water heat loss north of Svalbard using year‐long hydrographic and current records from three moorings deployed across the Svalbard Branch of the Atlantic Water boundary current in 2012–2013. The boundary current loses annually on average 16 W m−2 during the eastward propagation along the upper continental slope. The largest vertical fluxes of 〉100 W m−2 occur episodically in autumn and early winter. Episodes of sea ice imported from the north in November 2012 and February 2013 coincided with large ocean‐to‐ice heat fluxes, which effectively melted the ice and sustained open water conditions in the middle of the Arctic winter. Between March and early July 2013, a persistent ice cover‐modulated air‐sea fluxes. Melting sea ice at the start of the winter initiates a cold, up to 100‐m‐deep halocline separating the ice cover from the warm Atlantic Water. Semidiurnal tides dominate the energy over the upper part of the slope. The vertical tidal structure depends on stratification and varies seasonally, with the potential to contribute to vertical fluxes with shear‐driven mixing. Further processes impacting the heat budget include lateral heat loss due to mesoscale eddies, and modest and negligible contributions of Ekman pumping and shelf break upwelling, respectively. The continental slope north of Svalbard is a key example regarding the role of ocean heat for the sea ice cover. Our study underlines the complexity of the ocean's heat budget that is sensitive to the balance between oceanic heat advection, vertical fluxes, air‐sea interaction, and the sea ice cover.
    Description: Arctic Ocean program at the FRAM-High North Research Centre for Climate and the environment; National Science Foundation (NSF) Grant Number: ARC-1264098; Polish-Norwegian Research Programme Grant Number: POL-NOR/202006/10/2013; Research Council of Norway Grant Number: 276730; Steven Grossman Family Foundation
    Keywords: Atlantic Water ; Arctic Ocean ; Heat flux ; Nansen Basin ; Boundary current ; A‐TWAIN
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  • 175
    Publication Date: 2022-05-25
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Paleoceanography and Paleoclimatology 33 (2018): 1013-1034, doi:10.1029/2018PA003408.
    Description: The chemical composition of benthic foraminifera from marine sediment cores provides information on how glacial subsurface water properties differed from modern, but separating the influence of changes in the origin and end‐member properties of subsurface water from changes in flows and mixing is challenging. Spatial gaps in coverage of glacial data add to the uncertainty. Here we present new data from cores collected from the Demerara Rise in the western tropical North Atlantic, including cores from the modern tropical phosphate maximum at Antarctic Intermediate Water (AAIW) depths. The results suggest lower phosphate concentration and higher carbonate saturation state within the phosphate maximum than modern despite similar carbon isotope values, consistent with less accumulation of respired nutrients and carbon, and reduced air‐sea gas exchange in source waters to the region. An inversion of new and published glacial data confirms these inferences and further suggests that lower preformed nutrients in AAIW, and partial replacement of this still relatively high‐nutrient AAIW with nutrient‐depleted, carbonate‐rich waters sourced from the region of the modern‐day northern subtropics, also contributed to the observed changes. The results suggest that glacial preformed and remineralized phosphate were lower throughout the upper Atlantic, but deep phosphate concentration was higher. The inversion, which relies on the fidelity of the paleoceanographic data, suggests that the partial replacement of North Atlantic sourced deep water by Southern Ocean Water was largely responsible for the apparent deep North Atlantic phosphate increase, rather than greater remineralization.
    Description: National Science Foundation (NSF) Grant Numbers: OCE‐0750880, OCE‐1335191, OCE‐1558341, OCE‐1536380; Woods Hole Oceanographic Institution (WHOI) Grant Numbers: 27007592, 27000808
    Keywords: Glacial Atlantic circulation ; Preformed phosphate ; Remineralized phosphate ; Antarctic Intermediate Water ; Nutrient redistribution ; Tropical phosphate maximum
    Repository Name: Woods Hole Open Access Server
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  • 176
    Publication Date: 2022-05-25
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Journal of Geophysical Research: Oceans 123 (2018): 6392-6407, doi:10.1029/2018JC014129.
    Description: Low levels of dissolved oxygen (DO) occur in many embayments throughout the world and have numerous detrimental effects on biota. Although measurement of in situ DO is straightforward with modern instrumentation, quantifying the volume of water in a given embayment that is hypoxic (hypoxic volume (HV)) is a more difficult task; however, this information is critical for determining whether management efforts to increase DO are having an overall impact. This paper uses output from a three‐dimensional numerical model to demonstrate that HV in Chesapeake Bay can be estimated well with as few as two vertical profiles. In addition, the cumulative hypoxic volume (HVC; the total amount of hypoxia in a given year) can be calculated with relatively low uncertainty (〈10%) if continuous DO data are available from two strategically positioned vertical profiles. This is because HV in the Chesapeake Bay is strongly constrained by the geometry of the embayment. A simple Geometric HV calculation method is presented and numerical model results are used to illustrate that for calculating HVC, the results using two daily‐averaged profiles are typically more accurate than those of the standard method that interpolates bimonthly cruise data. Bimonthly data produce less accurate estimates of HVC because high‐frequency changes in oxygen concentration, for example, due to regional‐weather‐ or storm‐induced changes in wind direction and magnitude, are not resolved. The advantages of supplementing cruise‐based sampling with continuous vertical profiles to estimate HVC should be applicable to other systems where hypoxic water is constrained to a specific area by bathymetry.
    Description: NOAA Grant Number: NA13NOS0120139
    Keywords: Chesapeake Bay ; Oxygen ; Dead zone ; Hypoxia ; Observing systems ; Estuary
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  • 177
    Publication Date: 2022-05-25
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Journal of Geophysical Research: Oceans 123 (2018): 3563-3576, doi:10.1029/2017JC013329.
    Description: We investigate the characteristics of the sinking of dense waters in the North Atlantic Ocean that constitute the downwelling limb of the Atlantic Meridional Overturning Circulation (AMOC) as simulated by two global ocean models: an eddy‐permitting model at 1/4° resolution and its coarser 1° counterpart. In line with simple geostrophic considerations, it is shown that the sinking predominantly occurs in a narrow region close to the continental boundary in both model simulations. That is, the regions where convection is deepest do not coincide with regions where most dense waters sink. The amount of near‐boundary sinking that occurs varies regionally. For the 1/4° resolution model, these variations are in quantitative agreement with a relation based on geostrophy and a thermodynamic balance between buoyancy loss and alongshore advection of density, which links the amount of sinking to changes in density along the edge of the North Atlantic Ocean. In the 1° model, the amount and location of sinking appears not to be governed by this simple relation, possibly due to the large impact of overflows and nonnegligible cross‐shore density advection. If this poor representation of the processes governing the sinking of dense waters in the North Atlantic Ocean is a generic feature of such low‐resolution models, the response of the AMOC to changes in climate simulated by this type of models needs to be evaluated with care.
    Description: NWO (Netherlands Scientific Research foundation) VIDI Grant Number: 864.13.011; National Science Foundation Grant Numbers: OCE‐1534618, OCE‐1558742
    Keywords: Ocean circulation ; Climate
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  • 178
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 19 (2018): 3208-3223, doi:10.1029/2018GC007659.
    Description: We performed a detrital zircon (DZ) U‐Pb geochronologic survey of the lower parts of the Danube River approaching its Danube delta, Black Sea sink, and a few large tributaries (Tisza, Jiu, Olt, and Siret) originating in the nearby Carpathian Mountains. Samples are modern sediments. DZ age spectra reflect the geology and specifically the crustal age formation of the source area, which in this case is primarily the Romanian Carpathians and their foreland with contributions from the Balkan Mountains to the south of Danube and the East European Craton. The zircon cargo of these rivers suggests a source area that formed during the latest Proterozoic and mostly into the Cambrian and Ordovician as island arcs and back‐arc basins in a Peri‐Gondwanan subduction setting (~600–440 Ma). The Inner Carpathian units are dominated by a U‐Pb DZ peak in the Ordovician (460–470 Ma) and little inheritance from the nearby continental masses, whereas the Outer Carpathian units and the foreland have two main peaks, one Ediacaran (570–610 Ma) and one in the earliest Permian (290–300 Ma), corresponding to granitic rocks known regionally. A prominent igneous Variscan peak (320–350 Ma) in the Danube's and tributaries DZ zircon record is difficult to explain and points out to either an extra Carpathian source or major unknown gaps in our understanding of Carpathian geology. Younger peaks corresponding to arc magmatism during the Alpine period make up as much as about 10% of the DZ archive, consistent with the magnitude and surface exposure of Mesozoic and Cenozoic arcs.
    Description: Unitatea Executiva pentru Finantarea Invatamantului Superior, a Cercetarii, Dezvoltarii si Inovarii (UEFISCDI); Romanian Executive Agency for Higher Education, Research, Development and Innovation Funding Grant Number: PN‐III‐P4‐ID‐PCE‐2016‐0127; U.S. National Science Foundation. Grant Number: EAR 1725002
    Description: 2019-03-14
    Keywords: Danube ; Carpathians ; Detrital zircon ; U‐Pb geochronology ; Continental crust
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  • 179
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 45 (2018): 10,509-10,519, doi:10.1029/2018GL079180.
    Description: Autonomous underwater glider observations collected during and after 2017 Hurricanes Irma, Jose, and Maria show two types of transient response within the Gulf Stream. First, anomalously fresh water observed near the surface and within the core of the Gulf Stream offshore of the Carolinas likely resulted from Irma's rainfall being entrained into the Loop Current‐Gulf Stream system. Second, Gulf Stream volume transport was reduced by as much as 40% for about 2 weeks following Jose and Maria. The transport reduction had both barotropic and depth‐dependent characteristics. Correlations between transport through the Florida Straits and reanalysis winds suggest that both local winds in the Florida Straits and winds over the Gulf Stream farther downstream may have contributed to the transport reduction. To clarify the underlying dynamics, additional analyses using numerical models that capture the Gulf Stream's transient response to multiple tropical cyclones passing nearby in a short period are needed.
    Description: DOC | NOAA | Climate Program Office (CPO) Grant Number: NA14OAR4320158; DOD | United States Navy | Office of Naval Research (ONR) Grant Number: N000141713040; Eastman Chemical Company; National Science Foundation (NSF) Grant Numbers: OCE-0220769, OCE-1633911; Woods Hole Oceanographic Institution (WHOI)
    Description: 2019-04-04
    Keywords: Gulf Stream ; Hurricane ; Underwater glider
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  • 180
    Publication Date: 2022-05-25
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Geophysical Research Letters 45 (2018): 11,257-11,264, doi:10.1029/2018GL079336.
    Description: The Gulf Stream plays an important role in North Atlantic climate variability on a range of timescales. The North Atlantic is notable for large decadal variability in sea surface temperatures (SST). Whether this variability is driven by atmospheric or oceanic influences is a disputed point. Long time series of atmospheric and ocean variables, in particular long time series of Gulf Stream position, reveal differing sources of SST variability on quasi‐decadal and multidecadal timescales. On quasi‐decadal timescales, an oscillatory signal identified in the North Atlantic Oscillation (NAO) controls SST evolution directly via air‐sea heat fluxes. However, on multidecadal timescales, this relationship between the NAO and SST changes, while the relationship between the NAO and Gulf Stream position remains consistent in phase and resonant in amplitude. Recent changes in the Gulf Stream Extension show a weakening and broadening of the current, consistent with increased instability. We consider these changes in the context of a weakening Atlantic overturning circulation.
    Description: European Commission (EC) Grant Number: 727852
    Keywords: Atlantic Ocean ; Atlantic multidecadal variability ; Gulf Stream ; Atlantic meridional overturning circulation ; Air‐sea heat fluxes
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  • 181
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 45 (2018): 9909-9918, doi:10.1029/2018GL080135.
    Description: It is well known that the wintertime time‐mean surface wind convergence patterns over the Kuroshio Extension and Gulf Stream show significant imprints of the underlying oceanic fronts. Previous studies have suggested that this collocation results from a time‐mean response to sea level pressure forcing from sea surface temperature gradients. However, more recent work has illustrated this phenomenon is heavily influenced by extratropical cyclones, although exact mechanisms are still debated. The purpose of this study is to introduce a new framework that explicitly distinguishes between two separate components in their contribution to the time‐mean surface wind convergence, that associated with and without atmospheric fronts. It is then argued that this distinction can help better explain the mechanisms driving the Kuroshio Extension and Gulf Stream influence on the atmosphere.
    Description: National Science Foundation (NSF); NSF Physical Oceanography program Grant Numbers: AGS‐1355339, OCE‐1419235
    Description: 2019-03-29
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  • 182
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 123 (2018): 7351-7365, doi:10.1029/2018JC014306.
    Description: A differentiable function whose contours are orthogonal to potential density (σ) contours does not exist. However, such a function, called potential spicity (π), can be defined in the least square sense; these two functions form a practically orthogonal coordinate system in potential temperature‐salinity (θ‐S) space. Thus, in addition to the classical potential temperature‐salinity (θ‐S) diagram, seawater properties can be studied in the potential density‐potential spicity (σ − π) diagram.
    Description: Guangzhou Science and Technology Program key projects. Grant Number: 201804020056 National Natural Science Foundation of China. Grant Numbers: 41476167, 91752108 National Natural Science Foundation of Guangdong Province, China Grant Number: 2016A030311042; Strategic Priority Research Program of the Chinese Academy of Sciences Grant Number: XDA11030302; Guangzhou Science and Technology Program; NSF of Guangdong Province, China
    Description: 2019-04-16
    Keywords: Potential spicity ; Potential density ; The least square method ; Orthogonal coordinate system
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  • 183
    Publication Date: 2022-05-25
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Journal of Geophysical Research: Oceans 123 (2018): 7237-7263, doi:10.1029/2018JC013950.
    Description: Resuspension affects water quality in coastal environments by entraining seabed organic matter into the water column, which can increase remineralization, alter seabed fluxes, decrease water clarity, and affect oxygen and nutrient dynamics. Nearly all numerical models of water column biogeochemistry, however, simplify seabed and bottom boundary layer processes and neglect resuspension. Here we implemented HydroBioSed, a coupled hydrodynamic‐sediment transport‐biogeochemical model to examine the role of resuspension in regulating oxygen and nitrogen dynamics on timescales of a day to a month. The model was implemented for the northern Gulf of Mexico, where the extent of summertime hypoxia is sensitive to seabed and bottom boundary layer processes. Results indicated that particulate organic matter remineralization in the bottom water column increased by an order of magnitude during resuspension events. This increased sediment oxygen consumption and ammonium production, which were defined as the sum of seabed fluxes of oxygen and ammonium, plus oxygen consumption and ammonium production in the water column due to resuspended organic matter. The increases in remineralization impacted biogeochemical dynamics to a greater extent than resuspension‐induced seabed fluxes and oxidation of reduced chemical species. The effect of resuspension on bottom water biogeochemistry increased with particulate organic matter availability, which was modulated by sediment transport patterns. Overall, when averaged over the shelf and on timescales of a month in the numerical model, cycles of erosion and deposition accounted for about two thirds of sediment oxygen consumption and almost all of the sediment ammonium production.
    Description: DOC | National Oceanic and Atmospheric Administration (NOAA); U.S. National Oceanic and Atmospheric Administration's National Centers for Coastal Ocean Science Center for Sponsored Coastal Ocean Research Grant Numbers: NA09NOS4780231, NA09NOS4780229
    Keywords: Regional Ocean Modeling System (ROMS) ; Northern Gulf of Mexico continental shelf hypoxia ; Sediment transport and resuspension ; Particulate organic carbon (POC) ; Nitrogen ; Oxygen
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  • 184
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 19 (2018): 2463-2477, doi:10.1029/2017GC007339.
    Description: We examine the paleoceanographic record over the last ∼400 kyr derived from major, trace, and rare earth elements in bulk sediment from two sites in the East China Sea drilled during Integrated Ocean Drilling Program Expedition 346. We use multivariate statistical partitioning techniques (Q‐mode factor analysis, multiple linear regression) to identify and quantify five crustal source components (Upper Continental Crust (UCC), Luochuan Loess, Xiashu Loess, Southern Japanese Islands, Kyushu Volcanics), and model their mass accumulation rates (MARs). UCC (35–79% of terrigenous contribution) and Luochuan Loess (16–55% contribution) are the most abundant end‐members through time, while Xiashu Loess, Southern Japanese Islands, and Kyushu Volcanics (1–22% contribution) are the lowest in abundance when present. Cycles in UCC and Luochuan Loess MARs may indicate continental and loess‐like material transported by major rivers into the Okinawa Trough. Increases in sea level and grain size proxy (e.g., SiO2/Al2O3) are coincident with increased flux of Southern Japanese Islands, indicating localized sediment supply from Japan. Increases in total terrigenous MAR precede minimum relative sea levels by several thousand years and may indicate remobilization of continental shelf material. Changes in the relative contribution of these end‐members are decoupled from total MAR, indicating compositional changes in the sediment are distinct from accumulation rate changes but may be linked to variations in sea level, riverine and eolian fluxes, and shelf‐bypass processes over glacial‐interglacials, complicating accurate monsoon reconstructions from fluvial dominated sediment.
    Description: U.S. National Science Foundation Grant Numbers: NSF‐EAR1434175, NSF‐EAR1433665, NSF‐EAR1434138
    Keywords: East China Sea ; Bulk sediment ; Provenance ; Multivariate statistics ; East Asian Monsoon ; Loess
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  • 185
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2014. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 41 (2014): 7584–7590, doi:10.1002/2014GL061637.
    Description: Two near-surface dye releases were mapped on scales of minutes to hours temporally, meters to order 1 km horizontally, and 1–20 m vertically using a scanning, depth-resolving airborne lidar. In both cases, dye evolved into a series of rolls with their major axes approximately aligned with the wind and/or near-surface current. In both cases, roll spacing was also of order 5–10 times the mixed layer depth, considerably larger than the 1–2 aspect ratio expected for Langmuir cells. Numerical large-eddy simulations under similar forcing showed similar features, even without Stokes drift forcing. In one case, inertial shear driven by light winds induced large aspect ratio large-eddy circulation. In the second, a preexisting lateral mixed layer density gradient provided the dominant forcing. In both cases, the growth of the large-eddy structures and the strength of the resulting dispersion were highly dependent on the type of forcing.
    Description: Support for the 2004 field experiment was provided by the Cecil H. and Ida M. Green Technology Innovation Fund and Coastal Ocean Institute grant 27001545, both through Woods Hole Oceanographic Institution, and by Office of Naval Research grant N00014-01-1-0984. Support for the 2011 field experiments was provided by ONR grants N00014-09-1-0194, N00014-09-1-0175, N00014-11-WX-21010, N00014-12-WX-21031, and N00014-09-1-0460 and NSF grants OCE-0751734 and OCE-0751653. Simulations were supported under grant N00014-09-1-0268.
    Description: 2015-05-06
    Keywords: Large-eddy circulation ; Ocean surface mixed layer ; Lidar ; Fluorescent dye ; Numerical model
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  • 186
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2014. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 29 (2014): 1072–1093, doi:10.1002/2014PA002674.
    Description: The last deglaciation was characterized by a series of millennial-scale climate events that have been linked to deep ocean variability. While often implied in interpretations, few direct constraints exist on circulation changes at mid-depths. Here we provide new constraints on the variability of deglacial mid-depth circulation using combined radiocarbon and neodymium isotopes in 24 North Atlantic deep-sea corals. Their aragonite skeletons have been dated by uranium-series, providing absolute ages and the resolution to record centennial-scale changes, while transects spanning the lifetime of a single coral allow subcentennial tracer reconstruction. Our results reveal that rapid fluctuations of water mass sourcing and radiocarbon affected the mid-depth water column (1.7–2.5 km) on timescales of less than 100 years during the latter half of Heinrich Stadial 1. The neodymium isotopic variability (−14.5 to −11.0) ranges from the composition of the modern northern-sourced waters towards more radiogenic compositions, suggesting the presence of a greater southern-sourced component at some times. However, in detail, simple two-component mixing between well-ventilated northern-sourced and radiocarbon-depleted southern-sourced water masses cannot explain all our data. Instead, corals from ~15.0 ka and ~15.8 ka may record variability between southern-sourced intermediate waters and radiocarbon-depleted northern-sourced waters, unless there was a major shift in the neodymium isotopic composition of the northern end-member. In order to explain the rapid shift towards the most depleted radiocarbon values at ~15.4 ka, we suggest a different mixing scenario involving either radiocarbon-depleted deep water from the Greenland-Iceland-Norwegian Seas or a southern-sourced deep water mass. Since these mid-depth changes preceded the Bolling-Allerod warming and were apparently unaccompanied by changes in the deep Atlantic, they may indicate an important role for the intermediate ocean in the early deglacial climate evolution.
    Description: This study was supported by Natural Environment Research Council grant NE/F016751/1, Marie Curie International Reintegration grant IRG 230828, and Leverhulme Trust grant RPG-398 to TvdF, as well as a Phillip Leverhulme Prize, Marie Curie International Reintegration Grant, and European Research Council grant to L.F.R.
    Description: 2015-05-20
    Keywords: Heinrich stadial ; Deglaciation ; Atlantic meridional overturning circulation ; Neodymium isotopes ; Radiocarbon ; Deep sea corals
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  • 187
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 120 (2015): 608–633, doi:10.1002/2014JC010254.
    Description: The coastal waters of the northern portion of the California Current System experience a seasonal decline in oxygen concentrations and hypoxia over the summer upwelling season that results in negative impacts on habitat for many organisms. Using a regional model extending from 43°N to 50°N, with an oxygen component developed in this study, drivers of seasonal and regional oxygen variability are identified. The model includes two pools of detritus, which was an essential addition in order to achieve good agreement with the observations. The model was validated using an extensive array of hydrographic and moored observations. The model captures the observed seasonal decline as well as spatial trends in bottom oxygen. Spatially, three regions of high respiration are identified as locations where hypoxia develops each modeled year. Two of the regions are previously identified recirculation regions. The third region is off of the Washington coast. Sediment oxygen demand causes the region on the Washington coast to be susceptible to hypoxia and is correlated to the broad area of shallow shelf (〈60 m) in the region. Respiration and circulation-driven divergence contribute similar (60, 40%, respectively) amounts to the integrated oxygen budget on the Washington coast while respiration dominates the Oregon coast. Divergence, or circulation, contributes to the oxygen dynamics on the shelf in two ways: first, through the generation of retention features, and second, by determining variability.
    Description: This work was supported by a postdoctoral fellowship to Samantha Siedlecki from JISAO and the Program on Climate Change at the University of Washington, and grants from the Coastal Ocean Program of the National Oceanic and Atmospheric Administration (NOAA) (NA09NOS4780180) and the National Science Foundation (NSF) (OCE0942675) as part of the Pacific Northwest Toxins (PNWTOX) project.
    Description: 2015-08-05
    Keywords: Hypoxia ; Oxygen ; Respiration ; Upwelling
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  • 188
    Publication Date: 2022-05-25
    Description: © The Author(s), 2014. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Environmental Microbiology 17 (2015): 1510–1519, doi:10.1111/1462-2920.12571.
    Description: Here we investigated whether there is evidence of local adaptation in strains of an ancestrally marine dinoflagellate to the lacustrine environment they now inhabit (optimal genotypes) and/or if they have evolved phenotypic plasticity (a range of phenotypes). Eleven strains of Polarella glacialis were isolated and cultured from three different environments: the polar seas, a hyposaline and a hypersaline Antarctic lake. Local adaptation was tested by comparing growth rates of lacustrine and marine strains at their own and reciprocal site conditions. To determine phenotypic plasticity, we measured the reaction norm for salinity. We found evidence of both, limited local adaptation and higher phenotypic plasticity in lacustrine strains when compared with marine ancestors. At extreme high salinities, local lake strains outperformed other strains, and at extreme low salinities, strains from the hyposaline lake outperformed all other strains. The data suggest that lake populations may have evolved higher phenotypic plasticity in the lake habitats compared with the sea, presumably due to the high temporal variability in salinity in the lacustrine systems. Moreover, the interval of salinity tolerance differed between strains from the hyposaline and hypersaline lakes, indicating local adaptation promoted by different salinity.
    Description: This work was supported by a grant from the Australian Antarctic Research Assessment Committee to J.L-P and KR and by The Swedish Research Council (621-2009-5324) to KR. RL has been financed by a Marie Curie Intra-European Fellowship (PIEF-GA-2009–235365, EU) and a Juan de la Cierva fellowship (JCI-2010–06594, Ministry of Science and Innovation, Spain).
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  • 189
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Geochemistry, Geophysics, Geosystems 16 (2015): 925–946, doi:10.1002/2014GC005692.
    Description: Grain size is an important control on mantle viscosity and permeability, but is difficult or impossible to measure in situ. We construct a two-dimensional, single phase model for the steady state mean grain size beneath a mid-ocean ridge. The mantle rheology is modeled as a composite of diffusion creep, dislocation creep, dislocation accommodated grain boundary sliding, and a plastic stress limiter. The mean grain size is calculated by the paleowattmeter relationship of Austin and Evans (2007). We investigate the sensitivity of our model to global variations in grain growth exponent, potential temperature, spreading-rate, and mantle hydration. We interpret the mean grain-size field in terms of its permeability to melt transport. The permeability structure due to mean grain size may be approximated as a high permeability region beneath a low permeability region. The transition between high and low permeability regions occurs across a boundary that is steeply inclined toward the ridge axis. We hypothesize that such a permeability structure generated from the variability of the mean grain size may focus melt toward the ridge axis, analogous to Sparks and Parmentier (1991)-type focusing. This focusing may, in turn, constrain the region where significant melt fractions are observed by seismic or magnetotelluric surveys. This interpretation of melt focusing via the grain-size permeability structure is consistent with MT observation of the asthenosphere beneath the East Pacific Rise.
    Description: European Research Council under the European Union's Seventh Framework Programme . Grant Number: FP7/2007–2013
    Keywords: Mid-ocean ridge ; Permeability ; Grain size ; Simulation
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  • 190
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 16 (2015): 579–599, doi:10.1002/2014GC005576.
    Description: The three-dimensional velocity and temperature fields surrounding an isolated thermal plume in a fluid with temperature-dependent viscosity are measured using Particle-Image Velocimetry and thermochromatic liquid crystals, respectively. The experimental conditions are relevant to a plume rising through the mantle. It is shown that while the velocity and the isotherm surrounding the plume can be used to visualize the plume, they do not reveal the finer details of its structure. However, by computing the Finite-Time Lyapunov Exponent fields from the velocity measurements, the material lines of the flow can be found, which clearly identify the shape of the plume head and characterize the behavior of the flow along the plume stem. It is shown that the vast majority of the material in the plume head has undergone significant stretching and originates from a wide region very low in the fluid domain, which is proposed as a contributing factor to the small-scale isotopic variability observed in ocean-island basalt regions. Lastly, the Finite-Time Lyapunov Exponent fields are used to calculate the steady state rise velocity of the thermal plume, which is found to scale linearly with the Rayleigh number, in contrast to some previous work. The possible cause and the significance of these conflicting results are discussed, and it is suggested that the scaling relationship may be affected by the temperature-dependence of the fluid viscosity in the current work.
    Description: This work was funded by the National Science Foundation (grant EAR-055199) and the MAPS Dean's Office at UCL.
    Description: 2015-09-04
    Keywords: Mantle plumes ; Hot spots ; Mantle flow ; Mantle processes ; Fluid dynamics
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  • 191
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 42 (2015): 2326–2332, doi:10.1002/2014GL062759.
    Description: Results from three hydrographic surveys across the East Greenland Current between 2011 and 2013 are presented with focus on the freshwater sources. End-member analysis using salinity, δ18O, and nutrient data shows that while meteoric water dominated the freshwater content, a significant amount of Pacific freshwater was present near Denmark Strait with a maximum in August 2013. While in 2011 and 2012 the net sea ice melt was dominated by brine, in 2013 it became close to zero. The amount of Pacific freshwater observed near Denmark Strait in 2013 is as large as the previous maximum in 1998. This, together with the decrease in meteoric water and brine, suggests a larger contribution from the Canadian Basin. We hypothesize that the increase of Pacific freshwater is the result of enhanced flux through Bering Strait and a shorter pathway of Pacific water through the interior Arctic to Fram Strait.
    Description: The research leading to these results has received funding from the European Union Seventh Framework Programme (FP7 2007–2013) under grant agreement 308299, NACLIM Project, and from the U.S. National Science Foundation under grant OCE-085041.
    Description: 2015-10-01
    Keywords: East Greenland Current ; Freshwater ; Pacific Water ; Sea-ice melt ; Nordic Seas
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  • 192
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 120 (2015): 2370-2384, doi:10.1002/2014JC010516.
    Description: Expendable bathythermographs (XBTs) have been launched along a repeat track from New Jersey to Bermuda from the CMV Oleander through the NOAA/NEFSC Ship of Opportunity Program about 14 times per year since 1977. The XBT temperatures on the Middle Atlantic Bight shelf are binned with 10 km horizontal and 5 m vertical resolution to produce monthly, seasonally, and annually averaged cross-shelf temperature sections. The depth-averaged shelf temperature, Ts, calculated from annually averaged sections that are spatially averaged across the shelf, increases at 0.026 ± 0.001°C yr−1 from 1977 to 2013, with the recent trend substantially larger than the overall 37 year trend (0.11 ± 0.02°C yr−1 since 2002). The Oleander temperature sections suggest that the recent acceleration in warming on the shelf is not confined to the surface, but occurs throughout the water column with some contribution from interactions between the shelf and the adjacent Slope Sea reflected in cross-shelf motions of the shelfbreak front. The local warming on the shelf cannot explain the region's amplified rate of sea level rise relative to the global mean. Additionally, Ts exhibits significant interannual variability with the warmest anomalies increasing in intensity over the 37 year record even as the cold anomalies remain relatively uniform throughout the record. Ts anomalies are not correlated with annually averaged coastal sea level anomalies at zero lag. However, positive correlation is found between 2 year lagged Ts anomalies and coastal sea level anomalies, suggesting that the region's sea level anomalies may serve as a predictor of shelf temperature.
    Description: J.F. was supported as a Woods Hole Oceanographic Institution Summer Student Fellow by the National Science Foundation's Research Experiences for Undergraduates through OCE-0649139. M.A. received support through OCE-1332667 and G.G. through OCE-1435602.
    Description: 2015-09-27
    Keywords: Oleander ; Ocean heat content ; Expendable bathythermograph ; Shelfbreak front ; Sea level ; Middle Atlantic Bight
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  • 193
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Solid Earth 120 (2015): 2119–2142, doi:10.1002/2014JB011501.
    Description: We use high-resolution multibeam bathymetry, shipboard gravity, side-scan sonar images, and magnetic anomaly data collected on conjugate flanks of the Mid-Atlantic Ridge at 25°N–27°30′N and out to ~27 Ma crust to investigate the crustal evolution of the ridge. Substantial variations in crustal structure and thickness are observed both along and across isochrons. Along isochrons within spreading segments, there are distinct differences in seafloor morphology and gravity-derived crustal thickness between inside and outside corners. Inside corners are associated with shallow depths, thin crust, and enhanced normal faulting while outside corners have greater depths, thicker crust, and more limited faulting. Across-isochrons, systematic variations in crustal thickness are observed at two different timescales, one at ~2–3 Myr and another at 〉10 Myr, and these are attributed to temporal changes in melt supply at the ridge axis. The shorter-term variations mostly are in-phase between conjugate ridge flanks, although the actual crustal thickness can be significantly different on the two flanks at any given time. We observe no correlation between crustal thickness and spreading rate. Thus, during periods of low melt supply, tectonic extension must increase to accommodate the full plate separation rate. This extension commonly is concentrated in long-lived faults on only one side of the axial valley, resulting in strong across-axis asymmetries in crustal thickness and seafloor morphology. The thin-crust flank has few volcanic features and exhibits elevated, blocky topography with large-offset, often irregular faults, while the conjugate thicker-crust flank shows shorter-offset, regular faulting, and common volcanic features. The variations in melt supply at the ridge axis most likely are caused either by episodic convection in the subaxial mantle or by variable melting of chemically heterogeneous mantle.
    Description: This study was funded by Chinese Natural Science Foundation grant 41206034 and Chinese Postdoc Scholarship award 2012M511130 (T.W.), by Ministry of Science and Technology 973 Project award 2012CB417303, and by the WHOI Henry Bryant Bigelow Chair (J.L.). ARSRP and MAREAST data acquisition was funded by Office of Naval Research grant N00014-90-J-6121 and by U.S. National Science Foundation grant OCE-9503561, respectively.
    Description: 2015-10-21
    Keywords: Crustal thickness ; Seafloor morphology ; Mid-Atlantic Ridge
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  • 194
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 29 (2015): 656–676, doi:10.1002/2015GB005120.
    Description: The formation of the toxic and bioaccumulating monomethylmercury (MMHg) in marine systems is poorly understood, due in part to sparse data from many ocean regions. We present dissolved mercury (Hg) speciation data from 10 stations in the North and South Equatorial Pacific spanning large water mass differences and gradients in oxygen utilization. We also compare the mercury content in suspended particles from six stations and sinking particles from three stations to constrain local Hg sources and sinks. Concentrations of total Hg (THg) and methylated Hg in the surface and intermediate waters of the Equatorial and South Pacific suggest Hg cycling distinct from that of the North Pacific gyre. Maximum concentrations of 180 fM for both MMHg and dimethylmercury (DMHg) are observed in the Equatorial Pacific. South of the equator, concentrations of MMHg and DMHg are less than 100 fM. Sinking fluxes of particulate THg can reasonably explain the shape of dissolved THg profiles, but those of MMHg are too low to account for dissolved MMHg profiles. However, methylated Hg species are lower than predicted from remineralization rates based on North Pacific data, consistent with limitation of methylation in Equatorial and South Pacific waters. Full water column depth profiles were also measured for the first time in these regions. Concentrations of THg are elevated in deep waters of the North Pacific, compared to those in the intermediate and surface waters, and taper off in the South Pacific. Comparisons with previous measurements from nearby regions suggest little enrichment of THg or MMHg over the past 20 years.
    Description: Financial support for this study was provided by the National Science Foundation in a grant from the Chemical Oceanography Program (OCE-1031271) to C.H. Lamborg and M.A. Saito and a Graduate Student Fellowship to K.M. Munson.
    Description: 2015-11-25
    Keywords: Mercury ; Speciation ; Sinking fluxes ; Oxygen minimum zone
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  • 195
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 120 (2015): 3522–3541, doi:10.1002/2014JC010492.
    Description: A data assimilative ocean circulation model is used to hindcast the Gulf of Maine [GOM) circulation in spring and summer 2010. Using the recently developed incremental strong constraint 4D Variational data assimilation algorithm, the model assimilates satellite sea surface temperature and in situ temperature and salinity profiles measured by expendable bathythermograph, Argo floats, and shipboard CTD casts. Validation against independent observations shows that the model skill is significantly improved after data assimilation. The data-assimilative model hindcast reproduces the temporal and spatial evolution of the ocean state, showing that a sea level depression southwest of the Scotian Shelf played a critical role in shaping the gulf-wide circulation. Heat budget analysis further demonstrates that both advection and surface heat flux contribute to temperature variability. The estimated time scale for coastal water to travel from the Scotian Shelf to the Jordan Basin is around 60 days, which is consistent with previous estimates based on in situ observations. Our study highlights the importance of resolving upstream and offshore forcing conditions in predicting the coastal circulation in the GOM.
    Description: Research support was provided by National Oceanic and Atmospheric Administration (NOAA) grant NA06NOS4780245 for the Gulf of Maine Toxicity (GOMTOX) program. RH and DJM were also supported by NOAA grant NA11NOS4780023 under the PCMHAB program. YL was partly supported by Postdoctoral Scholar Program at the Woods Hole Oceanographic Institution, with funding provided by the George D. Grice Postdoctoral Scholarship.
    Description: 2015-11-19
    Keywords: Gulf of Maine ; Circulation modeling ; Data assimilation
    Repository Name: Woods Hole Open Access Server
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  • 196
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 29 (2015): 793-811, doi:10.1002/2014GB005001.
    Description: Mesoscale eddies in Oxygen Minimum Zones (OMZs) have been identified as important fixed nitrogen (N) loss hotspots that may significantly impact both the global rate of N-loss as well as the ocean's N isotope budget. They also represent “natural tracer experiments” with intensified biogeochemical signals that can be exploited to understand the large-scale processes that control N-loss and associated isotope effects (ε; the ‰ deviation from 1 in the ratio of reaction rate constants for the light versus heavy isotopologues). We observed large ranges in the concentrations and N and O isotopic compositions of nitrate (NO3−), nitrite (NO2−), and biogenic N2 associated with an anticyclonic mode-water eddy in the Peru OMZ during two cruises in November and December 2012. In the eddy's center where NO3− was nearly exhausted, we measured the highest δ15N values for both NO3− and NO2− (up to ~70‰ and 50‰) ever reported for an OMZ. Correspondingly, N deficit and biogenic N2-N concentrations were also the highest near the eddy's center (up to ~40 µmol L−1). δ15N-N2 also varied with biogenic N2 production, following kinetic isotopic fractionation during NO2− reduction to N2 and, for the first time, provided an independent assessment of N isotope fractionation during OMZ N-loss. We found apparent variable ε for NO3− reduction (up to ~30‰ in the presence of NO2−). However, the overall ε for N-loss was calculated to be only ~13–14‰ (as compared to canonical values of ~20–30‰) assuming a closed system and only slightly higher assuming an open system (16–19‰). Our results were similar whether calculated from the disappearance of DIN (NO3− + NO2−) or from the appearance of N2 and changes in isotopic composition. Further, we calculated the separate ε values for NO3− reduction to NO2− and NO2− reduction to N2 of ~16–21‰ and ~12‰, respectively, when the effect of NO2− oxidation could be removed. These results, together with the relationship between N and O of NO3− isotopes and the difference in δ15N between NO3− and NO2−, confirm a role for NO2− oxidation in increasing the apparent ε associated with NO3− reduction. The lower ε for N-loss calculated in this study could help reconcile the current imbalance in the global N budget if representative of global OMZ N-loss.
    Description: This work was supported by the Deutsche Forschungsgemeinschaft- project SFB-754 (www.sfb754.de), SOPRAN II (grant FKZ 03F0611A; www.sopran.pangaea.de), NSF grants OCE 0851092 and OCE 1154741 to M.A.A., and a NSERC Postdoctoral Fellowship to A.B.
    Description: 2015-12-06
    Keywords: Mesoscale eddy ; Isotope effects ; N-loss
    Repository Name: Woods Hole Open Access Server
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  • 197
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 42 (2015): 4309–4317, doi:10.1002/2015GL063917.
    Description: We investigate the mechanisms of normal fault initiation and evolution in the subducting Pacific Plate near the Mariana Trench, through bathymetry analysis and geodynamic modeling. We model the subducting plate as an elastoplastic slab subjected to tectonic forcing at the trench, including vertical load, bending moment, and horizontal tensional force. In our simulations, normal faults initiate within the outer rise region and reach maximum throw toward the trench. This result holds over a wide range of tectonic forcing and is consistent with observations of the Challenger Deep region, where multibeam bathymetry data indicate faults initiate near the outer rise at 70–110 km from the trench and reach maximum throw at 10–35 km from the trench. However, models require a horizontal tensional force with magnitude comparable to axial vertical load to jointly explain the observed seafloor bathymetry, location of maximum normal fault throw, and prevalence of normal faults dipping toward the trench.
    Description: This work was supported by the Mariana Trench Project of the South China Sea Institute of Oceanology of Chinese Academy of Sciences, Chinese National 985 project 1350141509, Ministry of Science and Technology 973 project award 2012CB417303, and Chinese Scholarship Council 201406260134.
    Description: 2015-12-02
    Keywords: Normal faulting ; Subducting plate ; Mariana Trench ; Slab pull
    Repository Name: Woods Hole Open Access Server
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  • 198
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Earth Surface 120 (2015): 1082–1106, doi:10.1002/2014JF003398.
    Description: We analyzed geophone and GPS measurements collected within the ablation zone of the western Greenland Ice Sheet during a ~35 day period of the 2011 melt season to study changes in ice deformation before, during, and after a supraglacial lake drainage event. During rapid lake drainage, ice flow speeds increased to ~400% of winter values, and icequake activity peaked. At times 〉7 days after drainage, this seismicity developed variability over both diurnal and longer periods (~10 days), while coincident ice speeds fell to ~150% of winter values and showed nightly peaks in spatial variability. Approximately 95% of all detected seismicity in the lake basin and its immediate vicinity was triggered by fracture propagation within near-surface ice (〈330 m deep) that generated Rayleigh waves. Icequakes occurring before and during drainage frequently were collocated with the down flow (west) end of the primary hydrofracture through which the lake drained but shifted farther west and outside the lake basin after the drainage. We interpret these results to reveal vertical hydrofracture opening and local uplift during the drainage, followed by enhanced seismicity and ice flow on the downstream side of the lake basin. This region collocates with interferometric synthetic aperture radar-measured speedup in previous years and could reflect the migration path of the meltwater supplied to the bed by the lake. The diurnal seismic signal can be associated with nightly reductions in surface melt input that increase effective basal pressure and traction, thereby promoting elevated strain in the surficial ice.
    Description: Research by J. Carmichael was supported by a NASA NESSF Fellowship grant NNX08AU82H and NSF grant ANT-0424589. The fieldwork and additional analyses were supported by the National Science Foundation's Office of Polar Programs (NSF-OPP) through ARC-1023382, awarded to I. Joughin, and ARC-1023364, awarded to S. B. Das and M. D. Behn. Matt King is a recipient of an Australian Research Council Future Fellowship (project number FT110100207).
    Description: 2015-12-25
    Keywords: Western Greenland Ice Sheet ; Icequakes ; Statistical signal processing ; GPS ; Supraglacial lakes ; Seismic threshold monitoring
    Repository Name: Woods Hole Open Access Server
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  • 199
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Limnology and Oceanography 60 (2015): 1332–1343, doi:10.1002/lno.10098.
    Description: Understanding the behavior of larval invertebrates during planktonic and settlement phases remains an open and intriguing problem in larval ecology. Larvae modify their vertical swimming behavior in response to water column cues to feed, avoid predators, and search for settlement sites. The larval eastern oyster (Crassostrea virginica) can descend in the water column via active downward swimming, sinking, or “diving,” which is a flick and retraction of the ciliated velum to propel a transient downward acceleration. Diving may play an important role in active settlement, as diving larvae move rapidly downward in the water column and may regulate their proximity to suitable settlement sites. Alternatively, it may function as a predator-avoidance escape mechanism. We examined potential hydrodynamic triggers to this behavior by observing larval oysters in a grid-stirred turbulence tank. Larval swimming was recorded for two turbulence intensities and flow properties around each larva were measured using particle image velocimetry. The statistics of flow properties likely to be sensed by larvae (fluid acceleration, deformation, vorticity, and angular acceleration) were compared between diving and non-diving larvae. Our analyses showed that diving larvae experienced high average flow accelerations in short time intervals (approximately 1–2 s) prior to dive onset, while accelerations experienced by non-diving larvae were significantly lower. Further, the probability that larvae dove increased with the fluid acceleration they experienced. These results indicate that oyster larvae actively respond to hydrodynamic signals in the local flow field, which has ecological implications for settlement and predator avoidance.
    Description: This work was supported by NSF grant OCE-0850419, NOAA Sea Grant NA14OAR4170074, grants from the WHOI Coastal Ocean Institute, discretionary WHOI funds, a WHOI Ocean Life Fellowship to LM, and a Grove City College Swezey Fellowship to EA.
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  • 200
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 120 (2015): 5766–5789, doi:10.1002/2014JC010490.
    Description: Impacts of the multichannel river network on plume dynamics in the Pearl River estuary were examined using a high-resolution 3-D circulation model. The results showed that during the dry season the plume was a distinct feature along the western coast of the estuary. The plume was defined as three water masses: (a) riverine water (〈5 psu), (b) estuarine water (12–20 psu), and (c) diluted water (〉22 psu), respectively. A significant amount of low-salinity water from Hengmen and Hongqimen was transported through a narrow channel between the QiAo Island and the mainland of the Pearl River delta during the ebb tide and formed a local salinity-gradient feature (hereafter referred to as a discharge plume). This discharge plume was a typical small-scale river plume with a Kelvin number K = 0.24 and a strong frontal boundary on its offshore side. With evidence of a significant impact on the distribution and variability of the salinity and flow over the West Shoal, this plume was thought to be a major feature of the Pearl River plume during the dry season. The upstream multichannel river network not only were the freshwater discharge sources but also played a role in establishing an estuarine-scale subtidal pressure gradient. This pressure gradient was one of the key dynamical processes controlling the water exchange between discharge and river plumes in the Pearl River estuary. This study clearly showed the role of the river network and estuary interaction on river plume dynamics.
    Description: The research work was supported by the National Natural Science Foundation of China (grant 41206005), the Ocean Public Welfare Scientific Research Project, State Oceanic Administration of the People's Republic of China (grant 201305019-3) and the CAS Strategic Pilot Science and Technology (XDA11020205). Changsheng Chen's participation was supported by the International Center for Marine Studies, Shanghai Ocean University.
    Description: 2016-02-21
    Keywords: River plume ; Multichannel river network ; River and estuary interaction ; Pearl River estuary
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