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  • Inorganic Chemistry  (2,206)
  • Industrial Chemistry  (1,603)
  • AERODYNAMICS
  • Aircraft Design, Testing and Performance
  • Seismology
  • 2020-2024  (15)
  • 1950-1954  (3,064)
  • 1945-1949  (1,097)
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  • 1
    Publication Date: 2024-04-05
    Description: This article has been accepted for publication in Geophysical Journal International ©:The Author(s) 2023. Published by Oxford University Press on behalf of the Royal Astronomical Society. All rights reserved.Uploaded in accordance with the publisher's self-archiving policy. All rights reserved.
    Description: We implemented an automatic procedure to download the hypocentral data of the online Bulletin of the International Seismological Centre (ISC) in order to produce in near real-time a homogeneous catalogue of the Global and EuroMediterranean instrumental seismicity to be used for forecasting experiments and other statistical analyses. For the interval covered by the reviewed ISC Bulletin, we adopt the ISC locations and convert the surface wave magnitude (Ms) and short-period body-wave magnitude (mb) as computed by the ISC to moment magnitude (Mw), using empirical relations. We merge the so obtained proxies with real Mw provided by global and EuroMediterranean moment tensor catalogues. For the most recent time interval (about 2 yr) for which the reviewed ISC Bulletin is not available, we do the same but using the preferred (prime) location provided by the ISC Bulletin and converting to Mw the Ms and mb provided by some authoritative agencies. For computing magnitude conversion equations, we use curvilinear relations defined in a previous work and the chi-square regression method that accounts for the uncertainties of both x and y variables.
    Description: H2020 EU project RISE contract n. 821115
    Description: Published
    Description: 1771-1785
    Description: OST2 Deformazione e Hazard sismico e da maremoto
    Description: JCR Journal
    Keywords: Statistical methods ; Statistical seismology ; Earthquake source observations ; Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
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    transcript Verlag | transcript Verlag
    Publication Date: 2024-05-13
    Description: Die Novemberrevolution von 1918/19 erschütterte die Tiefenschichten der politischen und gesellschaftlichen Ordnung der Metropole Hamburg. Diese vielschichtige Transformation wird anhand ausgewählter Akteur*innen, Institutionen und Ereignisse mit Beiträgen aus der neueren Revolutions-, Konflikt- und Kriegsforschung sowie aus der Kulturwissenschaft, der Geschichts- und Sozialwissenschaft nachgezeichnet. Die Beiträger*innen des Bandes durchleuchten die Dynamiken des revolutionären Wandels im umfassenden Dispositiv der urbanen Machtverhältnisse in ihren diskursiven Formationen: im Geschlechterverhältnis, in den Klassenverhältnissen, in der Wirtschaft, im Bildungswesen, im Film, in den Utopien und Vorstellungen der Menschen der Zeit. Die Beschreibung der dynamischen Umbrüche schließt die Nachbarstadt Altona und die Region ein und verbindet somit Lokales mit Nationalem und Globalem.
    Keywords: Revolution 1918/19 ; Hamburg ; Politik ; Gesellschaft ; Norddeutschland ; Wahlen 1919 ; Film ; Weimarer Republik ; Globalgeschichte ; Deutsche Geschichte ; Bismarck ; Metropole ; Seismologie ; Kulturgeschichte ; Geschlecht ; Stadt ; Sozialgeschichte ; Europäische Geschichte ; Geschichte des 20. Jahrhunderts ; Geschichtswissenschaft ; Politics ; Society ; North Germany ; Elections 1919 ; Weimar Republic ; Global History ; German History ; Seismology ; Cultural History ; Gender ; City ; Social History ; European History ; History of the 20th Century ; History ; thema EDItEUR::N History and Archaeology::NH History::NHD European history ; thema EDItEUR::N History and Archaeology::NH History::NHT History: specific events and topics::NHTB Social and cultural history
    Language: German
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  • 3
    Publication Date: 2023-02-20
    Description: Several regions around the globe are characterized by a seismically active lower crust, at depths where litho­logical and thermal conditions suggest stress release by ductile flow. The Gargano Promontory (GP, southern Italy) is an example where a recently installed seismic network has recorded an intense seismic activity at depths between 20 and 30 km, i.e. in the lower crust. The GP is located in proximity of the Gargano-Dubrovnik line­ament, a seismogenic zone separating the central and southern Adriatic basins. These two basins constitute sites of sediments accumulation since Tertiary times. Another important basin in the region is represented by the Apennine foredeep, that includes the Candelaro area. We analyze the possible mechanisms controlling the dis­tribution of seismicity in the GP to identify the factors that make the lower crust seismically active. To this aim, we construct a thermo-rheological model of a layered continental crust, calibrated on the basis of geometrical, lithological and thermal constraints. The model takes into account various crustal lithologies, the presence of fluids in the crystalline basement, lateral variations of geotherm and stress field. The numerical simulations show that the presence of fluids is a key factor controlling the cluster of seismicity in the lower crust. Moreover, the presence of water in the upper crystalline basement and sedimentary cover provides a plausible explanation for upper crustal seismicity in a zone of very high heat flow SW of the GP. The distribution of the seismicity is probably affected by the composition of the crystalline basement, with mafic bodies injected into the crust during the Paleocene magmatic phase that affected the Mediterranean region. In addition, fluid accumulation and overpressure may occur along detachment levels in the lower crust, leading to clustering of the earthquakes. Based on our findings, we hypothesize that the presence of hydrous diapiric upwelling(s) in the upper mantle can feed a deep fluid circulation system, inducing lower crustal seismicity.
    Description: Published
    Description: 103929
    Description: 4T. Sismicità dell'Italia
    Description: JCR Journal
    Keywords: Lower crust ; Rheology ; Seismology ; Geotherm ; Numerical modeling ; Gargano Promontory (southern Italy)
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
    Publication Date: 2024-04-23
    Description: The National Institute of Geophysics and Volcanology (INGV, Istituto Nazionale di Geofisica e Vulcanologia), is an italian public research institute established in 1999. Since its inception, the mission of INGV included seismic surveillance and earthquake monitoring in Italy. INGV is part of the Civil Defence system (Margheriti et al., 2021). INGV has offices in different parts of Italy and operates the Italian National Seismic Network (Rete Sismica Nazionale—RSN; INGV Seismological Data Centre, 2006) and other networks at national scale (Michelini et al., 2017). INGV also operates a temporary seismic network infrastructure, a pool of instruments used to densify seismic networks for scientific experiments or in response to damaging earthquakes and to increase monitoring capabilities during seismic sequences. SISMIKO is the operational task force of INGV whose core purpose is to rapidly deploy temporary seismic stations in response to moderate—large magnitude earthquakes or in areas where a seismic sequence is causing concerns and/or scientific interest (Moretti et al., 2016). By reducing the spatial distance between the seismic stations, temporary deployments can improve the RSN detection capability and the accuracy of the earthquake locations. SISMIKO was established in 2015 by Lucia Margheriti and Milena Moretti, so they became responsible for INGV emergency deployments of the temporary networks. SISMIKO involves INGV technicians and researchers from all over Italy, from Milano to Catania (see acknowledgments), grouped together by common interest technical and scientific issues. SISMIKO coordinates all INGV groups working on seismic emergencies (Figure 1). The data acquired by the SISMIKO temporary networks, are made available to the scientific community, without any restrictions, via italian node of the European Integrated Data Archive portal (EIDA1; Danecek et al., 2021). Datasets are archived in near real-time in the “Standard for the Exchange of Earthquake Data (SEED)” format and have an associated Digital Object Identifier (DOI). The data are used for monitoring, surveillance and for scientific research. Since its establishment, SISMIKO has installed seven temporary seismic networks, including the one used to monitor the 2016–2018 seismic sequence in central Italy (Moretti et al., 2016). The most recent activations of SISMIKO were in May and November 2022: Chianti-Fiorentino (Piccinini et al., 2022; 2023) and North Marche coast (D’Alema et al., 2022b), respectively. The following section briefly describes the history of the INGV emergency mobile network.
    Description: Published
    Description: 1146579
    Description: OST5 Verso un nuovo Monitoraggio
    Description: JCR Journal
    Keywords: SISMIKO ; Seismic emergency ; Temporary seismic network ; Real time transmission ; Seismology ; 05.04. Instrumentation and techniques of general interest
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
    Publication Date: 2023-09-01
    Description: Abstract
    Description: We present a new, consistently processed seismicity catalogue for the Eastern and Southern Alps, based on the temporary dense Swath-D monitoring network. The final catalogue includes 6,053 earthquakes for the time period 2017-2019 and has a magnitude of completeness of −1.0ML. The smallest detected and located events have a magnitude of −1.7ML. Aimed at the low to moderate seismicity in the study region, we generated a multi-level, mostly automatic workflow which combines a priori information from local catalogues and waveform-based event detection, subsequent efficient GPU-based event search by template matching, P & S arrival time pick refinement and location in a regional 3-D velocity model. The resulting seismicity distribution generally confirms the previously identified main seismically active domains, but provides increased resolution of the fault activity at depth. In particular, the high number of small events additionally detected by the template search contributes to a more dense catalogue, providing an important basis for future geological and tectonic studies in this complex part of the Alpine orogen.
    Description: TableOfContents
    Description: Seismicity catalogue Python codes & metadata Seismicity cross-sections
    Keywords: Seismology ; Seismic Waveform Analysis ; Eastern Alps ; Earthquake ; Geophysics ; Template matching ; 4DMB ; 4D Mountain Building ; EARTH SCIENCE ; EARTH SCIENCE 〉 SOLID EARTH ; EARTH SCIENCE 〉 SOLID EARTH 〉 TECTONICS ; EARTH SCIENCE 〉 SOLID EARTH 〉 TECTONICS 〉 EARTHQUAKES ; EARTH SCIENCE 〉 SOLID EARTH 〉 TECTONICS 〉 EARTHQUAKES 〉 EARTHQUAKE MAGNITUDE/INTENSITY ; EARTH SCIENCE 〉 SOLID EARTH 〉 TECTONICS 〉 EARTHQUAKES 〉 EARTHQUAKE OCCURRENCES ; geophysics ; seismology ; surface processes ; tectonics
    Type: Dataset , Dataset
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  • 6
    Publication Date: 2023-10-18
    Description: Abstract
    Description: This data publication contains (i) a slab model of the Cascadia subduction zone, derived from receiver functions, parameterized as depth to the three interfaces: t (top), c (central) and m (Moho), in NetCDF format; (ii) the station measurements of all parameters in the model in tabular and Raysum model file format; (iii) the raw receiver functions in SAC format; and (iv) auxiliary scripts for loading and plotting the data. A total of 45,601 individual receiver functions recorded at 298 seismic stations distributed across the Cascadia forearc contributed to the slab model. For each station, 100 s recordings symmetric about the P -wave arrival (i.e. 50 s noise and 50 s signal) of earthquakes with magnitudes between 5.5 and 8, in the distance range between 30 and 100 degree, were downloaded from the Incorporated Research Institutions for Seismology (IRIS) data center, the Northern California Earthquake Data Center (NCEDC), and the Natural Resources Canada Data Center (NRCAN). After quality control, radial and transverse receiver functions were computed through frequency-domain simultaneous deconvolution, with an optimal damping factor found through generalized cross validation. The continental forearc and subducting slab were parameterized as three layers over a mantle half-space, with the subduction stratigraphy bounding interfaces labeled as t (top), c (central) and m (Moho). Synthetic receiver functions were calculated through ray-theoretical modeling of plane-wave scattering at the model interfaces. The thickness, S -wave velocity (VS) and P - to S -wave velocity ratio (VP/VS) of each layer, as well as the common strike and dip of the bottom two layers and the top of the half space (in total 11 parameters) were optimized simultaneously through a simulated annealing global parameter search scheme. The misfit was defined as the anti-correlation (1 minus the cross-correlation coefficient) between the observed and predicted receiver functions, bandpass filtered between 2 and 20 s period duration. In total, 171, 143 and 137 quality A nodes were determined to constrain the t, c and m interfaces, respectively. At the trench, 105 nodes at 3 km below the local bathymetry were inserted to constrain the t and c interfaces, and at 6.5 km deeper to constrain the m interface, representing typical sediment and igneous crustal thicknesses. A spline surface was fitted to these nodes to yield margin-wide depth models. The spline coefficients were found using singular value decomposition, with the nominal depth uncertainties supplied as weights. The solution was damped by retaining the 116, 117, and 116 largest singular values for the t, c and m interfaces, respectively, based on analysis of L-curves and the Akaike information criterion. The data set is the supplemental material to Bloch, W., Bostock, M. G., Audet, P. (2023) A Cascadia Slab Model from Receiver Functions. Geochemistry, Geophysics, Geosystems.
    Keywords: Seismology ; Cascadia ; North America ; Reveiver Functions ; Subduction ; EARTH SCIENCE 〉 SOLID EARTH 〉 TECTONICS 〉 PLATE TECTONICS ; EARTH SCIENCE 〉 SOLID EARTH 〉 TECTONICS 〉 PLATE TECTONICS 〉 PLATE BOUNDARIES ; lithosphere ; The Present
    Type: Dataset , Dataset
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  • 7
    Publication Date: 2023-06-12
    Description: Seismic events produced by block rotations about vertical axis occur in many geodynamic contexts. In this study, we show that these rotations can be accounted for using the proper theory, namely micropolar theory, and a new asymmetric moment tensor can be derived. We then apply this new theory to the Kaikōura earthquake (2016/11/14), Mw 7.8, one of the most complex earthquakes ever recorded with modern instrumental techniques. Using advanced numerical techniques, we compute synthetic seismograms including a full asymmetric moment tensor and we show that it induces measurable differences in the waveforms proving that seismic data can record the effects of the block rotations observed in the field. Therefore, the theory developed in this work provides a full framework for future dynamic source inversions of asymmetric moment tensors.
    Description: Westfälische Wilhelms-Universität Münster (1056)
    Keywords: ddc:551.22 ; Seismology ; asymmetric moment tensor ; micropolar theory ; Kaikōura earthquake
    Language: English
    Type: doc-type:article
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  • 8
    Publication Date: 2024-02-28
    Description: The AlpArray experiment and the deployment of Swath-D together with the dense permanent network in Italy allow for detailed imaging of the spatio-temporal imaging complexity of seismic wave-fields within the greater Alpine region. The distance of any point within the area to the nearest station is less than 30 km, resulting in an average inter-station distance of about 45 km. With a much denser deployment in a smaller region of the Alps (320 km in length and 140 km wide), the Swath-D network possesses an average inter-station distance of about 15 km. We show that seismogram sections with a spatial sampling of less than 5 km can be obtained using recordings of these regional arrays for just a single event. Multiply reflected body waves can be observed for up to 2 h after source time. In addition, we provide and describe animations of long-period seismic wave-fields using recordings of about 1300–1600 broadband stations for six representative earthquakes. These illustrate the considerable spatio-temporal variability of the wave-field’s properties at a high lateral resolution. Within denser station distributions like those provided by Swath-D, even shorter period body and surface wave features can be recovered. The decrease of the horizontal wavelength from P to S to surface waves, deviations from spherically symmetric wavefronts, and the capability to detect multi-orbit arrivals are demonstrated qualitatively by the presented wave-field animations, which are a valuable tool for educational, quality control, and research purposes. We note that the information content of the acquired datasets can only be adequately explored by application of appropriate quantitative methods accounting for the considerable complexity of the seismic wave-fields as revealed by the now available station configuration.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Christian-Albrechts-Universität zu Kiel (3094)
    Keywords: ddc:551.22 ; Seismology ; Wave-fields ; Animations ; Alps ; AlpArray ; Swath-D
    Language: English
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  • 9
    Publication Date: 2024-02-23
    Description: Abstract
    Description: The main aim of this project is to investigate the crustal and mantle structure beneath the Longmenshan fault zone in China, based on a very dense passive seismology profile. The Longmenshan fault zone hosted the Wenchuan earthquake of May 2008 with a magnitude (Mw) of 7.9 and the Lushan earthquake of June 2013 with a magnitude (Mw) of 6.6. It is planned to mainly use the receiver-function method, to investigate the crustal and mantle structure beneath the Longmenshan fault zone. Waveform data are available from the GEOFON data center, under network code 4O, and are embargoed until February 2024.
    Keywords: Broadband seismic waveforms ; Seismology ; temporary local seismic experiment ; Earthquake ; Receiver functions ; Crustal and mantle structure ; China ; Monitoring system ; EARTH SCIENCE 〉 SOLID EARTH ; In Situ/Laboratory Instruments 〉 Magnetic/Motion Sensors 〉 Seismometers ; In Situ Land-based Platforms 〉 GEOPHYSICAL STATIONS/NETWORKS ; In Situ Land-based Platforms 〉 GEOPHYSICAL STATIONS/NETWORKS 〉 SEISMOLOGICAL STATIONS
    Type: Dataset , Seismic Network
    Format: ~1T
    Format: .mseed
    Format: XML
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  • 10
    Publication Date: 2024-05-21
    Description: Abstract
    Description: Continuous passive seismic monitoring is carried out between September 2017 and December 2021 around the Theistareykir geothermal area located at the intersection between the active Northern Rift Zone and the active Tjörnes Fracture Zone in NE Iceland. This experiment, in addition to an extensive gravimetric monitoring survey, was conducted in the framework of the MicroGraviMoTiS project for a better understanding of the structures and behavior of the local geothermal system under exploitation and for further development of local and regional geothermal resources. 14 broadband stations (Trillium C-120s) recording at 200 Hz comprise the temporary network, that is installed to complement stations of the national seismological network of IMO and stations of Landsvirkjun, the National Power Company of Iceland. The stations were placed in and around the producing zone to primarily retrieve local natural and/or induced seismicity associated to the injection and production operations. The retrieved seismic data is also used for obtaining a representative 1D velocity model of the region, for computing a seismic ambient noise tomography, and for monitoring the system using coda wave interferometry techniques. Funding for this project is provided by the German Federal Ministry for Education and Research (MicroGraviMoTiS , BMBF, grant: 03G0858A), the Helmholtz Centre Potsdam GFZ German Research Centre for Geosciences and Landsvirkjun. Waveform data are available from the GEOFON data center, under network code 3P, and are embargoed until December 2025.
    Keywords: Broadband seismic waveforms ; Seismology ; temporary local seismic experiment ; Monitoring system ; EARTH SCIENCE 〉 SOLID EARTH ; In Situ/Laboratory Instruments 〉 Magnetic/Motion Sensors 〉 Seismometers ; In Situ Land-based Platforms 〉 GEOPHYSICAL STATIONS/NETWORKS ; In Situ Land-based Platforms 〉 GEOPHYSICAL STATIONS/NETWORKS 〉 SEISMOLOGICAL STATIONS ; Passive seismic ; Seismometers ; Velocity ; MiniSEED ; GIPP ; MESI ; Volcano
    Type: Dataset , Seismic Network
    Format: 783GB
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  • 11
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    Frontiers Media SA
    Publication Date: 2024-04-04
    Description: The Frontiers in Chemistry Editorial Office team are delighted to present the inaugural “Frontiers in Chemistry: Rising Stars” article collection, showcasing the high-quality work of internationally recognized researchers in the early stages of their independent careers. All Rising Star researchers featured within this collection were individually nominated by the Journal’s Chief Editors in recognition of their potential to influence the future directions in their respective fields. The work presented here highlights the diversity of research performed across the entire breadth of the chemical sciences, and presents advances in theory, experiment and methodology with applications to compelling problems. This Editorial features the corresponding author(s) of each paper published within this important collection, ordered by section alphabetically, highlighting them as the great researchers of the future. The Frontiers in Chemistry Editorial Office team would like to thank each researcher who contributed their work to this collection. We would also like to personally thank our Chief Editors for their exemplary leadership of this article collection; their strong support and passion for this important, community-driven collection has ensured its success and global impact.
    Keywords: Green and Sustainable Chemistry ; Analytical Chemistry ; Theoretical and Computational Chemistry ; Polymer Chemistry ; Medicinal and Pharmaceutical Chemistry ; Organic Chemistry ; Nanoscience ; Catalysis and Photocatalysis ; Supramolecular Chemistry ; Electrochemistry ; Inorganic Chemistry ; Chemical Biology ; thema EDItEUR::P Mathematics and Science::PD Science: general issues
    Language: English
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  • 12
    Publication Date: 2023-12-20
    Description: Giulia Parola’s Environmental Democracy at the Global Level: Rights and Duties for a New Citizenship can be seen as a manifesto that is both traditional and revolutionary at the same time. It calls for the construction of a new civilisation centred on the environment, while drawing on the traditional notions of democratic government. It adopts an approach that is focused on the power of individuals rather than governments, as ways to protect and improve the environment. It proposes that environmental rights and ecological duties are self-evident and inalienable, and should be treated as the cornerstones of a new democracy. Parola’s book is a thought provoking and intriguing work that will be of interest to scholars of environmental studies as well as to legal practitioners and non-specialists. Giulia Parola has studied Environmental Law at the University of Torino, at the University of René Descartes in Paris, (where she obtained PhD in Public Law) and at the University of Iceland ( LLM in Natural Resources Law and International Environmental Law). In 2011, she was appointed by the University of Laval (Canada, Quebec) as a researcher and a lecturer in Environmental Law.
    Keywords: GE1-350 ; K ; International Law ; Materials Science ; Industrial Chemistry ; Law ; Comparative Law ; Foreign Law ; Environment ; Natural Sciences ; German Civil Code ; Pollution Control ; bic Book Industry Communication::K Economics, finance, business & management::KC Economics::KCN Environmental economics
    Language: English
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  • 13
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    Taylor & Francis | CRC Press
    Publication Date: 2024-03-31
    Description: Because of many misconceptions, the biological drug manufacturing industry does not fully utilize disposable components, despite their wide availability. These misconceptions include concerns for the quality of materials, running costs, scalability, the level of automation possible, and the training of staff needed to include these components in existing bioprocessing systems. Not fully realizing the long-term benefits, many manufacturers are unwilling to discard investments made in fixed equipment and traditional stainless steel systems. Regulatory and environmental concerns, however, will eventually compel manufacturers to adopt disposable systems. Making a strong case for disposables, Disposable Bioprocessing Systems demonstrates the true potential of these systems. Written by a researcher and professor with hands-on experience in designing, establishing, and validating biological manufacturing facilities worldwide, and creating model facilities using maximum disposable technology, this book is the first comprehensive introduction to understanding disposable systems. It gives an overview of the current state of the disposable bioprocessing industry, resolves all controversial issues, and guides readers in choosing disposable components that meet their needs. An important chapter on safety addresses facts and myths about the use of plastics and elastomers—including the issue of leaching—and how to ensure regulatory compliance. Helping readers understand their choices, the book describes the equipment and systems available to prepare the starting materials for the manufacturing of biological drugs—from disposable containers to filters. The author also discusses costs, regulations, and concerns about waste disposal, and shares his predictions for the future of the disposable bioprocessing industry. A practical manual for those interested in the transition to disposable systems, this book will also interest students of bioprocessing. It offers a timely view of disposable bioprocessing technology as a "game changer" that will facilitate developing new drugs and conducting research in the emerging field of stem cells and gene therapy.
    Keywords: Biotechnology ; Pharmaceutical Science ; Industrial Chemistry ; PHARMACEUTICAL ; BIOSCIENCE ; CHEMLIB ; SCI-TECH ; BIOMEDICALSCIENCE ; CHEMICALENGINEERING ; STM ; bags ; bioreactors ; cleaning ; disposal ; downstream ; single ; stainless ; steel ; use ; validation ; thema EDItEUR::M Medicine and Nursing::MF Pre-clinical medicine: basic sciences ; thema EDItEUR::M Medicine and Nursing::MK Medical specialties, branches of medicine::MKG Pharmacology ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TD Industrial chemistry and manufacturing technologies::TDC Industrial chemistry and chemical engineering ; thema EDItEUR::M Medicine and Nursing::MQ Nursing and ancillary services::MQW Biomedical engineering
    Language: English
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  • 14
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    Taylor & Francis | CRC Press
    Publication Date: 2024-04-11
    Description: Suitable for practicing engineers and engineers in training, this book covers the most important operations involving particulate solids. Through clear explanations of theoretical principles and practical laboratory exercises, the text provides an understanding of the behavior of powders and pulverized systems. It also helps readers develop skills for operating, optimizing, and innovating particle processing technologies and machinery in order to carry out industrial operations. The author explores common bulk solids processing operations, including milling, agglomeration, fluidization, mixing, and solid-fluid separation.
    Keywords: Industrial Chemistry ; Food Chemistry ; FOOD ; CHEMLIB ; SCI-TECH ; CHEMICALENGINEERING ; CHEMISTRY ; STM ; bed ; distribution ; fluidized ; industry ; mass ; material ; particle-size ; processing ; technology ; transfer ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TD Industrial chemistry and manufacturing technologies::TDC Industrial chemistry and chemical engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TD Industrial chemistry and manufacturing technologies::TDC Industrial chemistry and chemical engineering::TDCT Food and beverage technology ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGM Materials science
    Language: English
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  • 15
    Publication Date: 2024-04-04
    Description: The Earth is an heterogeneous complex media from the mineral composition scale (10−6m) to the global scale ( 106m). The reconstruction of its structure is a quite challenging problem because sampling methodologies are mainly indirect as potential methods (Günther et al., 2006; Rücker et al., 2006), diffusive methods (Cognon, 1971; Druskin & Knizhnerman, 1988; Goldman & Stover, 1983; Hohmann, 1988; Kuo & Cho, 1980; Oristaglio & Hohmann, 1984) or propagation methods (Alterman & Karal, 1968; Bolt & Smith, 1976; Dablain, 1986; Kelly et al., 1976; Levander, 1988; Marfurt, 1984; Virieux, 1986). Seismic waves belong to the last category. We shall concentrate in this chapter on the forward problem which will be at the heart of any inverse problem for imaging the Earth. The forward problem is dedicated to the estimation of seismic wavefields when one knows the medium properties while the inverse problem is devoted to the estimation of medium properties from recorded seismic wavefields.
    Keywords: seismic wave ; geophysical imaging ; seismic wave ; geophysical imaging ; Boundary value problem ; Finite element method ; Free surface ; Frequency domain ; Seismology ; Time domain ; Velocity ; thema EDItEUR::P Mathematics and Science::PD Science: general issues
    Language: English
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  • 16
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    In:  Geofisica Pura e Applicata, Los Angeles California, 1 p., California Institute of Technology Pasadena, vol. 28, no. 6, pp. 1-10, pp. L24306, (ISBN: 0534351875, 2nd edition)
    Publication Date: 1954
    Keywords: Low velocity layer ; Seismology
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  • 17
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    In:  Bull. Geol. Soc. Am., Los Angeles California, 1 p., California Institute of Technology Pasadena, vol. 65, no. 6, pp. 1342, pp. L24306, (ISBN: 0534351875, 2nd edition)
    Publication Date: 1954
    Keywords: Seismology ; Source parameters ; Shear waves ; Polarization
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  • 18
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    California Institute of Technology Pasadena
    In:  Seismological Laboratory Bulletin, Los Angeles California, 1 p., California Institute of Technology Pasadena, vol. 1953, no. 6, pp. 98, pp. L24306, (ISBN: 0534351875, 2nd edition)
    Publication Date: 1954
    Keywords: Earthquake catalog ; Seismology ; Seismicity
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  • 19
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    In:  Bull. Geol. Soc. Am., Los Angeles California, 1 p., California Institute of Technology Pasadena, vol. 65, no. 6, pp. 337-347, pp. L24306, (ISBN: 0534351875, 2nd edition)
    Publication Date: 1954
    Keywords: Low velocity layer ; Seismology
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  • 20
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    In:  Bull. California Division of Mines San Francisco, Luxembourg, National Academy of Sciences of the USA, vol. 170, no. 3-5, pp. 19-25, pp. B05311, (ISSN: 1340-4202)
    Publication Date: 1954
    Keywords: Seismicity ; Seismology
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  • 21
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    In:  Trans. Am. Geophys. Union, Beijing, Pergamon, vol. 35, no. 3-4, pp. 979-987, pp. 1246
    Publication Date: 1954
    Keywords: Seismology ; Project report/description ; EOS
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  • 22
    facet.materialart.
    Unknown
    In:  Bull. Seism. Soc. Am., Tokyo, Railway Tech. Res. Inst., vol. 44, no. 4, pp. 39-56, pp. L06615, (ISSN: 1340-4202)
    Publication Date: 1954
    Keywords: Waves ; Seismology ; earth Core ; Travel time ; BSSA
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  • 23
    facet.materialart.
    Unknown
    Princeton Univ. Press
    In:  Princeton, New Jersey, 9 + 310 pp., Princeton Univ. Press, vol. 7, no. XVI:, pp. 385-389, (ISBN 0-12-305355-2)
    Publication Date: 1954
    Keywords: Textbook of geophysics ; Seismology ; Seismicity
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  • 24
    Publication Date: 2019-05-25
    Description: An investigation was conducted on a 35 deg swept-wing fighter airplane to determine the effects of several blunt-trailing-edge modifications to the wing and tail on the high-speed stability and control characteristics and tracking performance. The results indicated significant improvement in the pitch-up characteristics for the blunt-aileron configuration at Mach numbers around 0.90. As a result of increased effectiveness of the blunt-trailing-edge aileron, the roll-off, customarily experienced with the unmodified airplane in wings-level flight between Mach numbers of about 0.9 and 1.0 was eliminated, The results also indicated that the increased effectiveness of the blunt aileron more than offset the large associated aileron hinge moment, resulting in significant improvement in the rolling performance at Mach numbers between 0.85 and 1.0. It appeared from these results that the tracking performance with the blunt-aileron configuration in the pitch-up and buffeting flight region at high Mach numbers was considerably improved over that of the unmodified airplane; however, the tracking errors of 8 to 15 mils were definitely unsatisfactory. A drag increment of about O.OOl5 due to the blunt ailerons was noted at Mach numbers to about 0.85. The drag increment was 0 at Mach numbers above 0.90.
    Keywords: Aircraft Design, Testing and Performance
    Type: NACA-RM-A54C31
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  • 25
    Publication Date: 2019-06-28
    Keywords: AERODYNAMICS
    Type: NACA-TN-3283
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  • 26
    Publication Date: 2019-06-28
    Description: The effects of primary and runback ice formations on the section drag of a 36 deg swept NACA 63A-009 airfoil section with a partial-span leading-edge slat were studied over a range of angles of attack from 2 to 8 deg and airspeeds up to 260 miles per hour for icing conditions with liquid-water contents ranging from 0.39 to 1.23 grams per cubic meter and datum air temperatures from 10 to 25 F. The results with slat retracted showed that glaze-ice formations caused large and rapid increases in section drag coefficient and that the rate of change in section drag coefficient for the swept 63A-009 airfoil was about 2-1 times that for an unswept 651-212 airfoil. Removal of the primary ice formations by cyclic de-icing caused the drag to return almost to the bare-airfoil drag value. A comprehensive study of the slat icing and de-icing characteristics was prevented by limitations of the heating system and wake interference caused by the slat tracks and hot-gas supply duct to the slat. In general, the studies showed that icing on a thin swept airfoil will result in more detrimental aerodynamic characteristics than on a thick unswept airfoil.
    Keywords: AERODYNAMICS
    Type: NACA-RM-E53J30
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  • 27
    Publication Date: 2019-06-27
    Keywords: AERODYNAMICS
    Type: NASA-TM-79864 , NACA-TN-3062
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  • 28
    Publication Date: 2019-06-27
    Keywords: AERODYNAMICS
    Type: NASA-TM-79844 , NACA-TR-1198 , NACA-TN-3018
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  • 29
    Publication Date: 2019-08-17
    Description: Measurement of average skin-friction coefficients have been made on six rocket-powered free-flight models by using the boundary-layer rake technique. The model configuration was the NACA RM-10, a 12.2-fineness-ratio parabolic body of revolution with a flat base. Measurements were made over a Mach number range from 1 to 3.7, a Reynolds number range 40 x 10(exp 6) to 170 x 10(exp 6) based on length to the measurement station, and with aerodynamic heating conditions varying from strong skin heating to strong skin cooling. The measurements show the same trends over the test ranges as Van Driest's theory for turbulent boundary layer on a flat plate. The measured values are approximately 7 percent higher than the values of the flat-plate theory. A comparison which takes into account the differences in Reynolds number is made between the present results and skin-friction measurements obtained on NACA RM-10 scale models in the Langley 4- by 4-foot supersonic pressure tunnel, the Lewis 8- by 6-foot supersonic tunnel, and the Langley 9-inch supersonic tunnel. Good agreement is shown at all but the lowest tunnel Reynolds number conditions. A simple empirical equation is developed which represents the measurements over the range of the tests.
    Keywords: Aircraft Design, Testing and Performance
    Type: NACA-RM-L54G14
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  • 30
    Publication Date: 2019-07-12
    Description: An investigation has been conducted to determine the static stability and control and damping in roll and yaw of a 0.13-scale model of the Convair XFY-1 airplane with propellers off from 0 deg to 90 deg angle of attack. The tests showed that a slightly unstable pitch-up tendency occurred simultaneously with a break in the normal-force curve in the angle-of-attack range from about 27 deg to 36 deg. The top vertical tail contributed positive values of static directional stability and effective dihedral up to an angle of attack of about 35 deg. The bottom tail contributed positive values of static directional stability but negative values of effective dihedral throughout the angle-of-attack range. Effectiveness of the control surfaces decreased to very low values at the high angles of attack, The model had positive damping in yaw and damping in roll about the body axes over the angle-of-attack range but the damping in yaw decreased to about zero at 90 deg angle of attack.
    Keywords: Aircraft Design, Testing and Performance
    Type: NACA-RM-SL54J04
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  • 31
    Publication Date: 2019-07-12
    Description: Altitude performance characteristics of the J65-B3 turbojet engine and its components were obtained at engine-inlet conditions corresponding to Reynolds number indices from 0.2 to 0.8 over a range of corrected engine speeds from 70 to 110 percent of rated speed. Engine operational limits up to an altitude of 75,000 feet together with ignition and windmilling characteristics were also obtained. The engine and component data are presented both in graphical and in tabulated form. The operational characteristics are presented in graphical form.
    Keywords: Aircraft Design, Testing and Performance
    Type: NACA-RM-SE54H18
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  • 32
    Publication Date: 2019-07-11
    Description: An investigation was conducted in the Langley 20-foot free-spinning tunnel on a 1/23-scale model of the McDonnell F3H-1N airplane. The effects of control settings and movements upon the erect and inverted spin and recovery characteristics of the model were determined for the clean condition. Spin-recovery parachute tests were also performed. The results indicated that erect spins obtained on the airplane for the take-off or combat loadings should be satisfactorily terminated if full rudder reversal is accompanied by moving the ailerons to full with the spin (stick full right in a right spin). The spins obtained should be oscillatory in pitch, roll, and yaw. Recoveries from inverted spins should be satisfactory by full reversal of the rudder. A 16.7-foot- diameter tail parachute with a towline length of 30 feet and a drag coefficient of 0.734 should be adequate for emergency recovery from demonstration spins.
    Keywords: Aircraft Design, Testing and Performance
    Type: NACA-RM-SL55A10a
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  • 33
    Publication Date: 2019-08-14
    Description: The lift, pitching-moment, and drag characteristics of a missile configuration having a body of fineness ratio 9.33 and a cruciform triangular wing and tail of aspect ratio 4 were measured at a Mach number of 1.99 and a Reynolds number of 6.0 million, based on the body length. The tests were performed through an angle-of-attack range of -5 deg to 28 deg to investigate the effects on the aerodynamic characteristics of roll angle, wing-tail interdigitation, wing deflection, and interference among the components (body, wing, and tail). Theoretical lift and moment characteristics of the configuration and its components were calculated by the use of existing theoretical methods which have been modified for application to high angles of attack, and these characteristics are compared with experiment. The lift and drag characteristics of all combinations of the body, wing, and tail were independent of roll angle throughout the angle-of-attack range. The pitching-moment characteristics of the body-wing and body-wing- tail combinations, however, were influenced significantly by the roll angle at large angles of attack (greater than 10 deg). A roll from 0 deg (one pair of wing panels horizontal) to 45 deg caused a forward shift in the center of pressure which was of the same magnitude for both of these combinations, indicating that this shift originated from body-wing interference effects. A favorable lift - interference effect (lift of the combination greater than the sum of the lifts of the components) and a rearward shift in the center of pressure from a position corresponding to that for the components occurred at small angles of attack when the body was combined with either the exposed wing or tail surfaces. These lift and center-of-pressure interference effects were gradually reduced to zero as the angle of attack was increased to large values. The effect of wing-tail interference, which influenced primarily the pitching-moment characteristics, is dependent on the distance between the wing trailing vortex wake and the tail surfaces and thus was a function of angle of attack, angle of roll, and wing- tail interdigitation. Although the configuration at zero roll with the wing and tail in line exhibited the least center-of-pressure travel, the configuration with the wing and tail interdigitated had the least change in wing- tail interference over the angle - of-attack range. The lift effectiveness of the variable-incidence wing was reduced by more than 70 percent as a result of an increase in the combined angle of attack and wing incidence from 0 deg to 40 deg center dot The wing- tail interference (effective downwash at the tail) due to wing deflection was nearly zero as a result of a region of negative vorticity shed from the inboard portion of the wing. The lift characteristics of the configuration and its components were satisfactorily predicted by the calculated results, but the pitching moments at large angles of attack were not because of the influence of factors for which no adequate theory is available, such as the variation of the cross flow drag coefficient along the body and the effect of the wing downwash field on the after body loading.
    Keywords: Aircraft Design, Testing and Performance
    Type: NACA-RM-A54H27
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  • 34
    Publication Date: 2019-07-10
    Description: An investigation of the 1XP excitation of inclined single-rotation propellers has indicated a new concept for determining propeller shaft forces and moments of an inclined propeller. This report presents preliminary results, in particular to the counterrotating propeller.
    Keywords: Aircraft Design, Testing and Performance
    Type: NACA-RM-A54C30
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  • 35
    Publication Date: 2019-07-12
    Description: An investigation of a 1/14-scale dynamically similar model of a panto-base version of the Chase C-123 airplane was conducted to evaluate the hydrodynamic characteristics of the airplane. The resistance, longitudinal stability, and spray patterns during take-off and general behavior in calm- and rough-water landings were determined. Brief calm-water tests were made to compare the initial vertical impact accelerations of the model with and without hydro-skis. Take-off stability was satisfactory for calm-water operation. A ratio of gross load to maximum resistance of 3,6 was obtained. Heavy spray reached the propellers only during ski emergence. The landing behavior in calm water and in waves 3 feet by 150 feet (full scale) was satisfactory for a normal range of trim angles. Initial impacts in calmwater landings resulted in vertical accelerations of about 2 1/2 with the hydro-skis installed and about 4g with the hydro-skis removed,
    Keywords: Aircraft Design, Testing and Performance
    Type: NACA-RM-SL54A28
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  • 36
    Publication Date: 2019-07-12
    Description: Missions for which a rocket interceptor is suited and the effect of rocket-engine performance on interceptor performance are discussed. Flight missions for interceptors having rocket and turbojet engines are compared, and circumstances under which a combination of rocket and turbojet may be advantageous are discussed.
    Keywords: Aircraft Design, Testing and Performance
    Type: NACA-RM-E54D15
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  • 37
    Publication Date: 2019-07-12
    Description: Additional results on the static longitudinal and lateral stability characteristics of a 0.05-scale model of the Convair F2Y-1 water-based fighter airplane were obtained in the Langley high-speed 7- by 10-foot tunnel over a Mach number range of 0.50 to 0.92. The maximum angle-of-attack range (obtained at the lower Mach numbers) was from -2 degrees to 25 degrees. The sideslip-angle range investigated was from -4 degrees to 12 degrees. The investigation included effects of various arrangements of wing fences, leading-edge chord-extensions, and leading-edge notches. Various fuselage fences, spoilers, and a dive brake also were investigated. From overall considerations of lift, drag, and pitching moments, it appears that there were two modifications somewhat superior to any of the others investigated: One was a configuration that employed a full-chord fence and a partial-chord fence located at 0.63 semispan and 0.55 semispan, respectively. The second was a leading-edge chord-extension that extended from 0.68 semispan to 0.85 semispan in combination with a leading-edge notch located at 0.68 semispan. With plus or minus 10 degrees aileron, the estimated wing-tip helix angle was reduced from 0.125 at a Mach number of 0.50 to 0.088 at a Mach number of 0.92, with corresponding rates of roll of 4.0 and 5.2 radians per second. The upper aft fuselage dive brake, when deflected 30 degrees and 60 degrees, reduced the rudder effectiveness about 10 to 20 percent and about 35 to 50 percent, respectively.
    Keywords: Aircraft Design, Testing and Performance
    Type: NACA-RM-SL54H05
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  • 38
    Publication Date: 2019-07-12
    Description: Free-flight tests in the transonic speed range utilizing rocketpropelled models have been made on three pairs of 0.11-scale North American F-100 airplane wings having an aspect ratio of 3.47, a taper ratio of 0.308, 45 degree sweepback at the quarter-chord line, and thickness ratios of 31 and 5 percent to investigate the possibility of flutte r. Data from tests of two other rocket-propelled models which accidentally fluttered during a drag investigation of the North American F-100 airplane are also presented. The first set of wings (5 percent thick) was tested on a model which was disturbed in pitch by a moving tail and reached a maximum Mach number of 0.85. The wings encountered mild oscillations near the first - bending frequency at high lift coefficients. The second set of wings 9 percent thick was tested up to a maximum Mach number of 0.95 at (2) angles of attack provided by small rocket motors installed in the nose of the model. No oscillations resembling flutter were encountered during the coasting flight between separation from the booster and sustainer firing (Mach numbers from 0.86 to 0.82) or during the sustainer firing at accelerations of about 8g up to the maximum Mach number of the test (0.95). The third set of wings was similar to the first set and was tested up to a maximum Mach number of 1.24. A mild flutter at frequencies near the first-bending frequency of the wings was encountered between a Mach number of 1.15 and a Mach number of 1.06 during both accelerating and coasting flight. The two drag models, which were 0.ll-scale models of the North American F-100 airplane configuration, reached a maximum Mach number of 1.77. The wings of these models had bending and torsional frequencies which were 40 and 89 percent, respectively, of the calculated scaled frequencies of the full-scale 7-percent-thick wing. Both models experienced flutter of the same type as that experienced-by the third set of wings.
    Keywords: Aircraft Design, Testing and Performance
    Type: NACA-RM-SL54G29
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  • 39
    Publication Date: 2019-07-12
    Description: Data were obtained in an altitude test chamber for a range of altitudes from 20,000 to 58,000 feet at a flight Mach number of 0.9, and for several flight Mach numbers at an altitude of 45,000 feet. Data approximating sea-level operation are also included. Engine component performance data are presented in addition to windmilling, exhaust-nozzle, and ejector performance.
    Keywords: Aircraft Design, Testing and Performance
    Type: NACA-RM-SE54H06
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  • 40
    Publication Date: 2019-07-12
    Description: An investigation was made of the take-off characteristics of a 1/10-scale dynamic model of the Convair XF2Y-1 airplane. This airplane is a water-based, jet-propelled, delta-wing fighter incorporating a hydro-ski landing gear. Tests were made with the original configuration, with the beaching wheels removed, and with the wheels installed and fairings added in front of the wheels. Each configuration was tested at weight and balance conditions simulating 17,000 pounds gross weight with the moment due t o 7,600 pounds of thrust, 17,300 pounds gross weight with a 9,500-pound thrust condition, and 23,000 pounds gross weight with a 9,300-pound thrust condition. Constant-speed runs were made at various elevon settings and vertical ski-strut positions; and trim, rise, and resistance were measured. Accelerated runs were made with controlled elevons and scale shock struts which could be extended as desired, and the longitudinal stability and spray characteristics were observed and photographed.
    Keywords: Aircraft Design, Testing and Performance
    Type: NACA-RM-SL54G08a
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  • 41
    Publication Date: 2019-07-12
    Description: An investigation was conducted in the Langley 19-foot pressure tunnel on a 0.3-scale model of the Republic RF-84F airplane to determine modifications which would eliminate the pitch-up that occurred near maximum lift during flight tests of the airplane. The effects of high-lift and stall-control devices, horizontal tail locations, external stores, and various inlets on the longitudinal characteristics of the model were investigated. For the most part, these tests were conducted at a Reynolds number of 9.0 x 10(exp 6) and a Mach number of 0.19. The results indicated that from the standpoint of stability the inlets should possess blunted side bodies. The horizontal tail located at either the highest or lowest position investigated improved the stability of the model. Three configurations were found for the model equipped with the production tail which eliminated the pitch-up through the lift range up to the maximum lift and provided a stable static margin which did not vary more than 15% of the mean aerodynamic chord through the lift range up to 85% of maximum lift. The three configurations are as follows: the production wing-fuselage-tail combination with an inlet similar to the production inlet but smaller in plan form in conjunction with either (1) a wing fence located at 65% of the win semispan or (2) an 11.7% chord leading-edge extension extending from 65.8 to 95.8% of the wing semispan and (3) the production wing-fuselage-tail combination with the production inlet and an 11.7% chord leading-edge extension extending from 70.8 to 95.8% of the wing semispan.
    Keywords: Aircraft Design, Testing and Performance
    Type: NACA-RM-SL54B17
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  • 42
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 275 (1954) 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 43
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 275 (1954), S. 289-296 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Vorversuche mit den reinen Pentoxyden Nb2O5 und Ta2O5 lieferten die bereit von BRAUER gefundenen Modifikationen T—Nb2O5, M—Nb2O5, H—Nb2O5 und T—Ta2O5 Außerdem ergab sich, daß Ta2O5 aus dem Schmelzfluß in einer weiteren  -  vermutlich in der von LAGERGREN und MAGNÉLI schon beobachteten  -  Modifikation kristallisiert.Die Pentoxyde Nb2O5 und Ta2O5 sind im festen Zustand miteinander mischbar. Die tantalreiche Mischphase besitzt das T-Gitter; die niobreiche Mischphase liegt in der MH-Form vor. Die Grenzzusammensetzung, bei der die T—MH-Umwandlung eintritt wurde für 900, 1050 und 1200°C bei 84, 67 und 61 Mol-% Nb2O5 gefunden. Ein heterogenes Gebiet, in dem beide Phasen nebeneinander vorliegen, kann nur klein sein. Die T—MH-Umwandlung ist bei entsprechender Variation der Zusammensetzung der Pentoxydphase reversibel durchführbar. Die Existenz einer instabilen, tantalreichen MH-Phase wurde nachgewiesen. Zwischen den Phasen T—Nb2O5, T—Ta2O5, MH—Nb2O und MH—Ta2O5 besteht Isodimorphie.
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  • 44
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 275 (1954), S. 301-319 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Nach umfangreichen Untersuchungen über die Reproduzierbarkeit von Metallpotentialen gegenüber fremdionigen(2) Lösungen und die zu deren Erzielung erforderlichen Voraussetzungen wurden die Potentiale von Pt, Ag, Au, Hg, Cu und Graphit gegenüber wäßrigen Lösungen von HClO4 bzw. NaOH verschiedener Konzentrationen gemessen. Die Ergebnisse werden durch eine Potentialtheorie gedeutet, die als Primärvorgang die Adsorption von Lösungsmittelmolekeln an der Elektrodenoberfläche zugrunde legt, die dann weitere potentialbildende Sekundärvorgänge auslösen kann. Bei Vorliegen mehrerer potentialbildender Systeme entscheidet die Potentialstabilität über die Potentialbestimmung.
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  • 45
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 275 (1954) 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 46
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 275 (1954), S. 327-330 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Hydroxylamin wird durch Kaliumnitrosodisulfonat unter Bildung von Distickstoffmonoxyd, Kaliumhydroxylamindisulfonat und Wasser glatt dehydriert.Kaliumhydroxylamindisulfonat läßt sich bromatometrisch bequem und genau bestimmen.
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  • 47
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 275 (1954), S. 1-20 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch thermische Spaltung von Germaniumtetrachlorid im Abschreckrohr gelang es, ein Germaniummonochlorid der Formel (GeCl)x darzustellen. Sein Existenzbereich wurde ermittelt. Thermische Zersetzung dieses Monochlorids führt je nach Art der Reaktionsbedingungen neben Germaniumtetrachlorid zu kristallinem Germaniumdichlorid, höheren Germaniumchloriden und metallischem Germanium.  -  Es konnte ein Digermaniumhexachlorid der Formel Ge2Cl6 dargestellt werden.
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  • 48
    Electronic Resource
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 275 (1954), S. 297-300 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es werden die vorläufigen Strukturuntersuchungsergebnisse der von uns aufgefundenen 2. Modifikation des Claudetits mitgeteilt. Der Claudetit II kristallisiert in den Raumgruppen C2(2) oder Cs(2). Die Gitterabmessungen sind: a1 = 7,99 Å; a2 = 4,57 Å; a3 = 9,11 Å; α2 = 78°19′; Z = 4 Formeleinheiten As2O3; ϱr = 4,02 g/cm3. An Hand von PATTERSON-, gemischten PATTERSON- und Fourier-Synthesen kann gezeigt werden, daß die Verknüpfung der Atome in beiden Claudetitmodifikationen ähnlich ist.
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  • 49
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 275 (1954), S. 320-326 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurden Darstellungsmethode und Eigenschaften der Selenide und Telluride des Urans untersucht. USe (a = 5,739 kX) und UTe (a = 6,151 kX) besitzen NaCl-Struktur.Die Möglichkeit von Bildung von festen Lösungen der Uranmonochalkogenide mit Uranmonoverbindungen der Elemente der V. Gruppe wurde untersucht; die Gitterkonstanten der Mischkristallreihen U(As, Se) und U(Sb, Te) wurden festgestellt.U3Te4 ist kubisch, (Th3P4-Typ a0 = 9,378 kX), UTe2 tetragonal (a = 3,998 kX, c/a = 1,865), UOSe tetragonal (PbFCl-Typ, a = 3,893 kX, c/a = 1,789). Einige Synthesen des UOSe werden beschrieben.
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  • 50
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 275 (1954), S. 331-337 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurden Versuche zur Ermittlung der Konstitution des gelben Komplexes durchgeführt, der beim Zusammengießen von sauren Titansalzlösungen mit Wasserstoffperoxyd entsteht. Die Konzentration der TiO2--Ionen betrug stets 0,0005 Mole/1, die der Säure variierte von 0,1 bis 1,0 Mole/l. Das Molverhältnis [H2O2]/[TiO2+] wurde zwischen 0,1 und 8,0 geändert. Es wurden Extinktionsmessungen in verd. H2SO4, HCl, HNO3 und HClO4 ausgeführt und gefunden, daß Anionen an dem Aufbau des Komplexes in Lösung nicht beteiligt sind. Der Komplex ist positiv geladen, sein molarer Extinktionskoeffizient ist 594 für Licht von der Wellenlänge 436 mμ, die Komplexdissoziationskonstante wurde zu 5,4 · 10-5 bestimmt.
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  • 51
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 275 (1954), S. 338-348 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzung zwischen SO3 und NH3 in nichtwäßrigem und in wäßrigem Medium wurde studiert. Es zeigte sich, daß der primäre Schritt der Reaktion nicht die Bildung der Amidosulfonsäure sein kann. Primär entsteht vielmehr Sulfimid, O2SNH. Sulfimid polymerisiert sich leicht zu einem Trimeren, einem Tetrameren oder einem kettenförmig gebauten höheren Polymeren; letzteres reagiert mit SO3 und H2SO4 zu Polysulfimidsulfonsäuren. Die Hydrolyse dieser Sulfonsäuren führt zu den gleichen Produkten, die man direkt bei der Reaktion von SO3 und NH3 in wäßriger Lösung erhält.
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    Zeitschrift für anorganische Chemie 275 (1954), S. 59-64 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurden Elektrolytchrom-Präparate hergestellt. Von den in der Achatmühle gemahlenen Präparaten wurden die Suszeptibilitäten nach Gouy bestimmt. Die achatpulverkorrigierten Suszeptibilitäten, gegen den Oxydgehalt der Präparate aufgetragen, liegen auf einer Geraden. Die Extrapolation auf den Oxydgehalt Null ergibt den Wert \documentclass{article}\pagestyle{empty}\begin{document}$$ \chi _\infty = + 2,65 \cdot 10^{ - 6}\; {\rm bzw}{\rm .}\chi _{{\rm Atom}} = + 138 \cdot 10^{ - 8} $$\end{document}.
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  • 53
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    Zeitschrift für anorganische Chemie 275 (1954), S. 21-31 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurden die bei der Einwirkung von wäßrigem KF auf MoO3 und WO3 entstehenden Bodenkörper isoliert und untersucht. Im System MoO3—KF—H2O konnte die Existenz von fünf verschiedenen Verbindungen nachgewiesen werden: K3MoO3F3 (I), K2MoO3F2 · H2O (II), K3Mo4O13F · 3 H2O (III), K2MoO2F4 · H2O (IV) und K2Mo4O13 (V). Die durch Entwässern von (III) erhaltene Verbindung K3Mo4O13F ist instabil und nicht mit der im System K2Mo4O13/KF vorkommenden inkongruent schmelzenden Verbindung K3Mo4O13F identisch. (II) läßt sich entwässern; die wasserfreie Verbindung K2MoO3F2 ist instabil und zerfällt beim Schmelzen in (I) und MoO3. Im System WO3—KF—H2O konnte die Existenz nur einer Verbindung K2WO3F2 · H2O nachgewiesen werden.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 13-18 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Kojisäure-monomethyläther läßt sich durch Oxydation mit Salpetersäure oder Luftsauerstoff i. Ggw. eines Platin-Katalysators in Komensäure-methyläther überführen. Auf einem neuen Wege wird die 5-Stellung der Oxy-Gruppe in den aus Mekonsäure und Kojisäure erhaltenen Pyron- und Pyridonderivaten bestätigt und damit eine neuerdings vertretene abweichende Auffassung widerlegt.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 19-24 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Formamid und Formyl-guanidin kondensieren zu 2-Amino-1.3.5-triazin. Diese Reaktion ist jedoch nicht verallgemeinerungsfähig. Die verschiedenen anomalen Reaktionen des Aminotriazins und des 2-Amino-4.6-dimethyl-triazins führen zu dem Schluß, daß diese Verbindungen nicht die ihnen bisher zugeschriebene Struktur besitzen können, sondern als Imino-dihydro-triazine vorliegen müssen.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 46-53 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Der 5-Tosyl-1.3-benzyliden-l-arabit tauscht mit Kaliumcyanid in Methanol bei Raumtemperatur nahezu quantitativ den Tosylat-Rest gegen die Cyangruppe aus. Das entstehende Nitril läßt sich glatt zur 2-Desoxy-l-galaktonsäure verseifen. Der Reaktionsmechanismus des Tosylat-Austausches wird erörtert.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 38-45 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In der Tetramethyl-d-glucose und Tetramethyl-d-fructose konnte der Wasserstoff des Lactolhydroxyls durch Alkalimetall ersetzt werden. Konfiguration und Reaktionsfähigkeit der Alkalimetallverbindungen wurden durch Umsetzung mit Methyljodid und Dimethylsulfat, die zu den entsprechenden Glykosiden führte, ermittelt. Die Kalium-Verbindung der 2.3.4.6-Tetramethyl-d-glucose reagierte mit α-1-Tosyl-, α-1-Brom- und β-1-Chlor-2.3.4.6-Tetramethyl-d-glucose unter Bildung von Disacchariden des Trehalosetypus.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 92-108 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird durch Bromtitrationen und ultraviolett-spektroskopisch nachgewiesen, daß cyclische β-Dicarbonylverbindungen, deren beide Carbonylgruppen durch Einbau in einen 5- oder 6-Ring „trans-fixiert“ sind, so daß sie keine Enolchelate bilden können, in OH-gruppenhaltigen Lösungsmitteln vollständig enolisiert sind, in OH-gruppenfreien Lösungsmitteln aber mehr oder weniger weitgehend in die Diketoform übergehen. Die „trans-fixierten“ β-Dicarbonylverbindungen verhalten sich also bezüglich des Einflusses des Lösungsmittels auf das Keto-Enol-Gleichgewicht umgekehrt wie ihre offenkettigen oder ihre „cis-fixierten“ Analogen, bei denen das Gleichgewicht in OH-gruppenfreien Lösungsmitteln zugunsten der (chelatisierten) Enolformen und in OH-gruppenhaltigen Lösungsmitteln zugunsten nicht-enolischer Formen liegt.Am Beispiel des Dimedons wird ultrarot-spektroskopisch nachgewiesen, daß der Enolgehalt trans-fixierter β-Dicarbonylverbindungen konzentrations-abhängig ist: Verdünnte Lösungen enthalten relativ mehr Diketo-Form als konzentriertere.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 108-123 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Von einigen Cyclobutan-, Cyclopentan- und Cyclohexan-1.3-dionen werden die UV-Spektren der undissoziierten Enol-Formen, der Enolat-Anionen und der Enol-Methyläther gemessen und diskutiert. Die Enol-Formen dieser „trans-fixierten“ β-Diketone sind, da sie nicht chelatisiert sein können, relativ stark sauer (PKs = etwa 2.8 bis 5.5). Die Dissoziationskonstanten der Enole werden aus den bei verschiedenen pH-Werten gemessenen UV-Spektren berechnet. Das Enol-Enolat-Gleichgewicht ist bei vielen trans-fixierten Enolen im Bereich der bei UV-Messungen benützten Konzentrationen konzentrationsabhängig.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 127-129 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Indol wird in flüssigem Ammoniak ausschließlich am Stickstoff alkyliert.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 123-127 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mit verdünnter Säure (pH ∼ 1) läßt sich aus der durch Dialyse gereinigten Mucoprotein-Fraktion des Kuh-Colostrums eine schön kristallisierende, niedrigmolekulare Substanz abspalten, deren Eigenschaften mit denjenigen der Sialinsäure von G. Blix und der Methoxyverbindung der Neuraminsäure von E. Klenk verglichen werden.
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Dien-Synthese von Cyclopentadien mit Chlor- bzw. Brommaleinsäure-anhydrid und mit Chlor-fumarsäurechlorid wird beschrieben und strukturell und sterisch untersucht. Es wurde gefunden, daß die Addukte leicht Halogenwasserstoff abspalten und dabei in Derivate des Nor-tricyclens übergehen.
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Das noch nicht näher charakterisierte Proazulen der Schafgarbe (“M-Proazulen”) läßt sich durch alkalische Verseifung über eine Zwischenstufe in eine intensiv blaue, unbeständige Cham-Azulencarbonsäure überführen, die einen gut kristallsierenden, tiefblauen, stabilen Methylester gibt, dessen Analyse zeigte daß dem zugrundeliegenden Cham-Azulen - in Übereinstimmung mit einer kürzlich erschienen Arbeit von A. Meisels und A. Weizmann1) - die Formel C14H16 zukommt. Die Cham-Azulencarbonsäure geht unter den Bedingungen der Wasserdampfdestillation leicht in Cham-Azulen über.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 221-222 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung des α-[m-Nitro-phenyl]-äthylamins und seine Spaltung in optische Antipoden wird beschrieben. Die Rotationsdispersion des Hydrochlorids und der Acetylverbindung wird mitgeteilt.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 233-237 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Das Additionsprodukt von Phenanthrenchinon an Triacetyl-d-glucal wurde näher untersucht. Ausgehend von dieser Substanz wurde - als Modellversuch - Gentiobiose synthetisch dargestellt.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 257-261 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Reduktion von 4.8-Dimethyl-azulen-carbonsäure-(6)-äthylester mit Lithiumaluminiumhydrid werden 4.8-Dimethyl 6-oxy-methyl-azulen und hieraus 4.8-Dimethyl-azulen-aldehyd-(6) hergestellt. Die neuen Azulene werden durch Derivate und durch ihre Absorptionsspektren im Sichtbaren und im Ultrarot charakterisiert.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 282-288 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es werden die Chlorderivate der drei möglichen Methyl-chlorsilane dargestellt und beschrieben.Die Chlorierung läßt sich beim Methyl-trichlor-silan leicht bis zum Ersatz aller Wasserstoffatome treiben, ohne daß Zwischenstufen gefaßt werden konnten, beim Dimethyl-dichlor-silan bis zur Substitution von fünf Wasserstoffatomen. Beim Trimethyl-chlorsilan können maximal acht Wasserstoffatome ersetzt werden.Das Sublimationsvermögen dieser Verbindungen ist an die Anwesenheit einer Trichlormethylgruppe im Molekül gebunden.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 300-314 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird über die Darstellung von α-Chlor-äthylschwefelchlorid sowie über die mannigfaltigen, mit dieser Verbindung durchführbaren Synthesen, die u.a. auch zur Bildung von Makromolekülen durch Polykondensation und Polymerisation führen, berichtet.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 325-330 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Einige weitere Alkylschwefelchloride werden beschrieben und mit diesen sowie mit Methyl- und Äthylschwefelchlorid eine Reihe neuer organischer Schwefelverbindungen dargestellt.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 345-349 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Darstellung gemischter Phenolester von Dicarbonsäuren und deren Umlagerung in ω-Oxyphenyl-ω-oxo-carbonsäuren durch Fries'sche Verschiebung beschrieben.
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Als erste Verbindungen mit dem Ringsystem des Thiopheno-2'.3': 3.4-thiophens werden beschrieben: Die 2.5-Dimethyl-Verbindung und deren Maleinsäure-anhydrid Addukt; die 4'-Oxy-Verbindung und deren Thioindigo.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 482-488 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Einwirkung von Stickstoffwasserstoffsäure auf Succinylo-bernsteinsäure-diäthylester erhält man den Diester eines cyclischen Peptids, das aus zwei Moll. Asparaginsäure aufgebaut ist, und in dem die beiden Asparagylreste in β-Stellung miteinander verknüpft sind. Die freie Dicarbonsäure [1.5-Diaza-cyclooctan-dion-(4.8)-dicar-bonsäure-(2.6)] liefert bei der Hydrolyse Asparaginsäure. Durch Einwirkung von Acetanhydrid bei 160° wird die Dicarbonsäure in komplizierter Weise verändert. Für ein krist. Reaktionsprodukt wird die Konstitutionsformel des N-{[2.5-Dimethyl-oxazolyl-(4)]-acetyl}-d.l-asparaginsäure-anhydrids vorgeschlagen.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 488-496 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Dien-Reaktion zwischen 1-Acetoxy-butadien und 1-Methyl-cyclopenten-(1)-dion-(4.5) wurde ein Hydrindan-Derivat erhalten und dessen Konstitution aufgeklärt.
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Acetylierung von Fructoseoxim erhält man zwei isomere Hexaacetyl-fructoseoxime, Für das eine Isomere wurde die Konstitution eines Keto-fructoseoxim-bexaacetats bewiesen.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 560-566 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Fällung von Begleitstoffen mit Invertseifen lassen sich aus 1 kg Mekonium 40 bis 50 g serologisch hochwirksamer Blutgruppen-substanz gewinnen. Unter den Produkten, die bei partieller Säure-hydrolyse auftreten, findet sich ein schön kristallisierendes Disaccharid vom Sehmp. 170-171°, und [α]20D: + 51.5° → 28.5° (Wasser), das aus d-Galaktose und N-Acetyl-glucosamin aufgebaut ist. Es liefert mit Phenylhydrazin Lactosazon, woraus folgt, daß es sich um eine 2-Desoxy-2-acetamino-lactose handelt.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 581-592 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Um Bedingungen zu ermitteln, unter denen sich die Methylester von Aminosäuren und Peptiden zu mittelgroßen Polypeptiden kondensieren lassen, wurde die Kondensation der Methylester von Glycin, d.l-Alanin, d.l-Serin und Tetra-glycin untersucht. Mit geeigneten Lösungsmittel-Systemen ließ sich der Kondensationsverlauf papier-chromatographisch verfolgen.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 627-627 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Der aus Zimtaldehyd und Lithiumaluminiumhydrid hergestellte Komplex wird zu Synthesen herangezogen.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 668-676 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die elektrolytische Oxydation von primären und sekundären Acetylenalkoholen führte in saurer Lösung zu Acetylencarbonsäuren und Acetylenketonen. Die Reaktion wurde in Abhängigkeit von elektrochemischen Faktoren untersucht.
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die von van't Hoff vorausgesehene cis-trans-Isomerie bei Verbindungen, in denen 4 Kohlenstoff-Atome durch 3 Doppelbindungen verknüpft sind, ließ sich verwirklichen. Das rote Bis-[2-nitro-diphenylen]-butatrien konnte chromatographisch an Aluminiumoxyd in 2 Komponenten zerlegt werden, die kristallographisch und in den Ultrarotspektren wesentlich verschieden sind, aber im Sichtbaren praktisch gleiche Absorptionsbanden zeigen. Die als A und B bezeichneten Komponenten des Dinitro-triens, deren Rs-Werte 0.18 bzw. 0.04 betragen, lagern sich in Brombenzol als Lösungsmittel mit einer rund 200 mal größeren Geschwindigkeit als die nur 1 Doppelbindung enthaltenden Bis-[2-nitro-diphenylen]-äthylene A und B ineinander um. Die Aktivierungsenergie für die cis-trans-Umlagerung der Dinitro-triene in Brombenzol beträgt 19.5 kcal/Mol, die Halbwertszeit 850 Min. bei 0°. Das Gleichgewicht liegt bei 57% A und 43% B (0°).
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Einige Umsetzungsprodukte aus Verbindungen mit polarisierter C-C-Doppelbindung und Lithiumaluminiumhydrid dienen zur Hervon 1.4-Diolen.
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In Erweiterung einer von B. Emmert und M. Groll angegebenen Reaktion wird gezeigt, daß bei Einwirkung von Schwefel auf ein Gemisch von methylierten Heterocyclen mit aromatischen Aminen oder Nitro-Verbindungen bisher unbekannte Thioamide, Benzthiazole und Diaryl-amidine entstehen, und zwar einzeln oder nebeneinander.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 690-691 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die optische Spaltung von racem. α-Phenyl-äthylamin gelingt mit d-Weinsäure in Methanollösung, wobei das (-)-Amin erhalten wird. Die Abscheidung des (+)-Amins aus dem Gemisch mit dem Racemat erfolgt über das Sulfat.
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  • 84
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 820-824 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzung von N.N'-Diphenyl-thioharnstoff mit Malonylchlorid ohne Lösungsmittel führte zum 6-Oxy-4′-oxo-2′-thio-1′.3′-diphenyl-1′.2′.3′.4′-tetrahydro-[pyrimidino-6′.5′ :2.3-γ-pyron] sowie zu einer Reihe weiterer Reaktionsprodukte.
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  • 85
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 248-256 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus aliphatischen Aminosäuren (Glykokoll und d, l-Alanin) bilden sich mit 2 Moll. Trifluoressigsäure-anhydrid gemischte Anhydride aus N-Trifluoracetyl-aminosäure und Trifluoressigsäure. Mit l-Alanin tritt hierbei Racemisierung ein. Diese gemischten Anhydride können in die symmetrischen N-Trifluoracetyl-aminosäure-anhydride über-geführt werden, die, wie die gemischten Anhydride, mit Anilin oder Glycinäthylester N-Triflucracetyl-aminosäure-anilide bzw. N-Trifluoracetyl-peptidester geben. Nach der Säurechlorid-Methode läßt sich aus N-Trifluoracetyl-l-alanin das N-Trifluoracetyl-l-alanyl-anilid herstellen. Von der Glutaminsäure ist das innere N-Trifluoracetyl-l-glutaminsäure-anhydrid ohne Racemisierung erhältlich. Aus p-Amino-benzoesäure werden über die 4-[N-Trifluoracetylamino]-benzoesäure und das Säurechlorid 4-[N-Trifluorcetylamino]-benzoesäure-peptide gewonnen mit Glycinäthylester, l-Glutaminsäure-diäthylester und p-Aminobenzoesäure-äthylester.Auf die ziemlich leicht erfolgende alkalische Verseifbarkeit von N-Trifluoracetyl-Verbindungen ist schon hingewiesen worden1).
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  • 86
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 276-282 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ausgehend von der α-[Furyl-(2)]-benzoylglykolsäure konnte eine Reihe von Derivaten der α-[Furyl-(2)]-glykolsäure und auch die freie Säure dargestellt werden. Alle Versuche zur analogen Darstellung der α-[Chinolyl-(2)]-glykolsäure verliefen bisher wegen der großen Zersetzlichkeit dieser Verbindung negativ.
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  • 87
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 289-300 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei partieller Säurehydrolyse der Lacto-N-tetraose treten auf: 2 stickstoffhaltige Trisaccharide und 3 Disaccharide, von denen 2 stickstoffhaltig sind. Der reduzierende Baustein der Tetraose ist d-Glucose. Das stickstofffreie Disaccharid wurde als α-Lactose-hydrat identifiziert. Der Bauplan der Lacto-N-tetraose ist: 〉 d-Glucose 〉 d-Galaktose 〉 N-Acetyl-d-glucosamin 〉 d-Galaktose. Von den beiden stickstoffhaltigen Disacchariden zeichnet sich das eine, nämlich die schön kristallisierende Lacto-N-biose I, durch überraschend hohe Alkaliempfindlichkeit aus. Schon in der Kälte bei pH 9-10 erfolgt Zerfall in d-Galaktose und Anhydro-N-acetyl-d-glucosamin (AAG). Es wird erörtert, wie weit sich aus der Farbreaktion mit p-Dimethylamino-benzaldehyd (Morgan-Elson) Schlußfolgerungen auf die Konstitution von N-Acetyl-hexosamin-Derivaten ziehen lassen.Im Oligosaccharid-Gemisch der Frauenmilch nimmt die Lacto-N-tetraose eine zentrale Stellung ein, denn sie entsteht bei gelinder Säure-Einwirkung - unter Abspaltung von l-Fucose - auch aus weiteren Komponenten des Bifidus-Faktors.
    Additional Material: 4 Ill.
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  • 88
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Übertragung der Kolbeschen Nitroalkan-Synthese auf Dicarbonsäuren wurden ω-Nitro- und ω-Amino-carbonsäuren erhalten.
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  • 89
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Über die Alkalisalze des Cyclopentanon-o-carbonsäureesters werden für Ringschlüsse geeignete Substitutionsprodukte synthetisiert. Des weiteren wird die Einwirkung von Benzylamin auf Cyclopentanon-o-carbonsäureester untersucht.
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  • 90
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Synthese des polymerisierbaren und nach der Polymerisation zu Polyvinylamin verseifbaren Vinylamin-N.N-dicarbonsäure-diäthylesters über das Addukt mit Anthracen wird beschrieben.
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  • 91
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 412-417 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Synthese des 3.4'-Ace-1.2-benzfluorens (VI) wird durchgeführt, um diese Verbindung auf krebserzeugende Wirksamkeit zu prüfen. Endprodukt und Zwischenprodukte der Synthese werden durch ihre UV- und UR-Spektren charakterisiert.
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  • 92
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 439-443 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Methylierung von 2.5-Dimethoxy-3.4-dioxy-tetrahydrofuran wurden 2.3.4.5-Tetramethoxy-tetrahydrofuran und 2.3.5-Trimethoxy-4-oxy-tetrahydrofuran, die inneren Acetale des Mesoweinsäuredialdehyd-dimethyläthers und -monomethyläthers, erhalten. Kondensation dieser Aldehyde mit Methylamin und Acetondicarbonsäure nach dem Verfahren von Robinson-Schöpf führte zu den bisher noch nicht bekannten Tropanderivaten cis-6.7-Dimethoxy-tropinon und d.l-cis-6-Oxy-7-methoxy-tropinon.
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  • 93
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 35-37 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Natriumverbindung anmethylierter Saccharose reagiert in ätherischer Lösung mit Dimethylsulfat schnell und vollständig unter Bildung von Oktamethyl-saccharose.
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  • 94
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 700-707 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus α-Halogen-ketonen entstehen mit Ammoniumformiat in Ameisensäure oder mit Formamid unter Zusatz von konz. Schwefelsäure in 2-Stellung nicht substituierte Oxazole. Für die Synthesen von Oxazolen und Imidazolen aus Halogenketonen mittels Formamids werden Reaktionsmechanismen aufgestellt.
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  • 95
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 726-732 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus α-Oxy- und α-Formoxy-ketonen werden nach verschiedenen Verfahren in 2-Stellung nicht substituierte Oxazole erhalten. Die Darstellung von α-Formoxy-ketonen wird beschrieben.Aus α-Oxy-ketonen entstehen mit Formamid unter geeigneten Bedingungen α-Formamino-ketone.
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  • 96
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 764-765 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Im Gegensatz zu den Angaben der Literatur läßt sich auch Trimesinsäureester mit LiAlH4 leicht in die Trimethylol-Verbindung überführen.
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  • 97
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Eine von Y. Sakurai vorgeschlagene Formel für das Gentiopikrin wird diskutiert und eine Konstitutionsformel für den Hexahydro-gentiogenin-methyläther aufgestellt.
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  • 98
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 793-802 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Chinasäure läßt sich auf einfache Weise synthetisieren, indem man ein in 4-Stellung geeignet substituiertes Cyclohexanon-Derivat über das Cyanhydrin in die entsprechende Oxazolidon-Verbindung verwandelt, in 3-, 4- und 5-Stellung je eine Oxygruppe räumlich richtig einführt und das Reaktionsprodukt in die optischen Antipoden spaltet. Die Beobachtung, daß Chinasäure durch Erhitzen racemisierbar ist, wird theoretisch gedeutet.
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  • 99
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 712-724 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Das von W. D. Celmer und I. A. Solomons beschriebene antibiotisch wirksame Alkali-Isomerisierungsprodukt des “Mycomycins” wurde synthetisch aufgebaut. Der Methylester stimmt in allen Eigenschaften mit dem aus natürlichem Material erhaltenen “Isomycomycin-methylester” überein. Ferner wurden einige weitere Tri-ine dargestellt, die in naher Beziehung zu natürlich vorkommenden Polyinen stehen.
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  • 100
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Zahlreiche Versuche zur Darstellung von Nitrocyan scheiterten; die Verbindung bzw. das ihr isomere Cyan-nitrit entsteht aus Bromcyan und Silbernitrit in Acetonitril bei -40°, zerfällt aber schon bei -20° in Lösung quantitativ nach\documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm O}_{\rm 2} {\rm N} - {\rm CN} = {\rm CO}_{\rm 2} + {\rm N}_{\rm 2} $$\end{document}Ähnlich unbeständig sind die Reaktionsprodukte von Halogentriazinen mit Silbernitrit; aus Monochlortriazinen entstehen dabei die Silbersalze von Oxytriazinen. Die Oxydation von Amino-triazinen mit Caroscher Säure führt nur unter Schwierigkeiten bis zur Hydroxylaminostufe, in den Vordergrund tritt neben totalem oder teilweisem Abbau die Bildung von Triazin-N-oxyden. Diese Befunde werden auf Basis der Elektronentheorie gedeutet.
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