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  • Wiley-Blackwell  (113,619)
  • American Institute of Physics (AIP)  (96,077)
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  • American Meteorological Society
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  • 1
    Publication Date: 2024-04-07
    Description: PI3K biology; lymphoma; cancer
    Keywords: PI3K biology; lymphoma; cancer ; thema EDItEUR::P Mathematics and Science::PS Biology, life sciences
    Language: English
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  • 2
    Publication Date: 2024-04-03
    Description: oncogenic drivers; signaling; pathways; hematologic malignancies; cancer
    Keywords: oncogenic drivers; signaling; pathways; hematologic malignancies; cancer ; thema EDItEUR::M Medicine and Nursing
    Language: English
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  • 3
    Publication Date: 2023-06-21
    Description: Solar light/dark cycles and seasonal photoperiods underpin daily and annual rhythms of life on Earth. Yet, the Arctic is characterized by severalmonths of permanent illumination (‘‘midnight sun’’). To determine the persistence of 24h rhythms during the midnight sun, we investigated transcriptomic dynamics in the copepod Calanus finmarchicus during the summer solstice period in the Arctic, with the lowest diel oscillation and the highest altitude of the sun’s position. Here we reveal that in these extreme photic conditions, a widely rhythmic daily transcriptome exists, showing that very weak solar cues are sufficient to entrain organisms. Furthermore, at extremely high latitudes and under sea-ice, gene oscillations become re-organized to include 〈24h rhythms. Environmental synchronization may therefore be modulated to include non-photic signals (i.e. tidal cycles). The ability of zooplankton to be synchronized by extremely weak diel and potentially tidal cycles, may confer an adaptive temporal reorganization of biological processes at high latitudes.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 4
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    American Meteorological Society
    In:  EPIC3Journal of Climate, American Meteorological Society, 35(23), pp. 7811-7831, ISSN: 0894-8755
    Publication Date: 2023-06-23
    Description: Numerical simulations allow us to gain a comprehensive understanding of the underlying mechanisms of past, present, and future climate changes. The mid-Holocene (MH) and the last interglacial (LIG) were the two most recent warm episodes of Earth’s climate history and are the focus of paleoclimate research. Here, we present results of MH and LIG simulations with two versions of the state-of-the-art Earth system model AWI-ESM. Most of the climate changes in MH and LIG compared to the preindustrial era are agreed upon by the two model versions, including 1) enhanced seasonality in surface temperature that is driven by the redistribution of seasonal insolation; 2) a northward shift of the intertropical convergence zone (ITCZ) and tropical rain belt; 3) a reduction in annual mean Arctic sea ice concentration; 4) weakening and northward displacement of the Northern Hemisphere Hadley circulation, which is related to the decrease and poleward shift of the temperature gradient from the subtropical to the equator in the Northern Hemisphere; 5) a westward shift of the Indo-Pacific Walker circulation due to anomalous warming over the Eurasia and North Africa during boreal summer; and 6) an expansion and intensification of Northern Hemisphere summer monsoon rainfall, with the latter being dominated by the dynamic component of moisture budget (i.e., the strengthening of wind circulation). However, the simulated responses of the Atlantic meridional overturning circulation (AMOC) in the two models yield different results for both the LIG and the MH. AMOC anomalies between the warm interglacial and preindustrial periods are associated with changes in North Atlantic westerly winds and stratification of the water column at the North Atlantic due to changes in ocean temperature, salinity, and density.
    Repository Name: EPIC Alfred Wegener Institut
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  • 5
    Publication Date: 2023-02-25
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(11), (2022): 2841–2852, https://doi.org/10.1175/jpo-d-22-0025.1.
    Description: Prediction of rapid intensification in tropical cyclones prior to landfall is a major societal issue. While air–sea interactions are clearly linked to storm intensity, the connections between the underlying thermal conditions over continental shelves and rapid intensification are limited. Here, an exceptional set of in situ and satellite data are used to identify spatial heterogeneity in sea surface temperatures across the inner core of Hurricane Sally (2020), a storm that rapidly intensified over the shelf. A leftward shift in the region of maximum cooling was observed as the hurricane transited from the open gulf to the shelf. This shift was generated, in part, by the surface heat flux in conjunction with the along- and across-shelf transport of heat from storm-generated coastal circulation. The spatial differences in the sea surface temperatures were large enough to potentially influence rapid intensification processes suggesting that coastal thermal features need to be accounted for to improve storm forecasting as well as to better understand how climate change will modify interactions between tropical cyclones and the coastal ocean.
    Description: This research was made possible by the NOAA RESTORE Science Program (NA17NOS4510101 and NA19NOS4510194) and the NASA Physical Oceanography program (80NSSC21K0553 and WBS 281945.02.25.04.67) and NOAA IOOS program via GCOOS (NA16NOS0120018). The authors declare that they have no competing interests.
    Keywords: Seas/gulfs/bays ; Atmosphere–ocean interaction ; Currents ; Tropical cyclones ; Buoy observations ; In situ oceanic observations
    Repository Name: Woods Hole Open Access Server
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  • 6
    Publication Date: 2023-02-25
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(8), (2022): 1797–1815, https://doi.org/10.1175/JPO-D-21-0288.1.
    Description: Intruding slope water is a major source of nutrients to sustain the high biological productivity in the Gulf of Maine (GoM). Slope water intrusion into the GoM is affected by Gulf Stream warm-core rings (WCRs) impinging onto the nearby shelf edge. This study combines long-term mooring measurements, satellite remote sensing data, an idealized numerical ocean model, and a linear coastal-trapped wave (CTW) model to examine the impact of WCRs on slope water intrusion into the GoM through the Northeast Channel. Analysis of satellite sea surface height and temperature data shows that the slope sea region off the GoM is a hotspot of ring activities. A significant linear relationship is found between interannual variations of ring activities in the slope sea region off the GoM and bottom salinity at the Northeast Channel, suggesting the importance of WCRs in modulating variability of intruding slope water. Analysis of the mooring data reveals enhanced slope water intrusion through bottom-intensified along-channel flow following impingements of WCRs on the nearby shelf edge. Numerical simulations qualitatively reproduce the observed WCR impingement processes and associated episodic enhancement of slope water intrusion in the Northeast Channel. Diagnosis of the model result indicates that baroclinic CTWs excited by the ring–topography interaction are responsible for the episodically intensified subsurface along-channel inflow, which carries more slope water into the GoM. A WCR that impinges onto the shelf edge to the northeast of the Northeast Channel tends to generate stronger CTWs and cause stronger enhancement of the slope water intrusion into the GoM.
    Description: This study is supported by the National Science Foundation through Grant OCE-1634965.
    Keywords: Continental shelf/slope ; Channel flows ; Mesoscale processes ; In situ oceanic observations ; Satellite observations ; Numerical analysis/modeling
    Repository Name: Woods Hole Open Access Server
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  • 7
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    American Meteorological Society
    In:  EPIC3Journal of Climate, American Meteorological Society, pp. 1-40, ISSN: 0894-8755
    Publication Date: 2023-09-04
    Description: 〈jats:title〉Abstract〈/jats:title〉 〈jats:p〉Tipping points in the Earth system describe critical thresholds beyond which a single component, part of the system, or the system as a whole changes from one stable state to another. In the present-day Southern Ocean, the Weddell Sea constitutes an important dense-water formation site, associated with efficient deep-ocean carbon and oxygen transfer and low ice-shelf basal melt rates. Here, a regime shift will occur when continental shelves are continuously flushed with warm, oxygen-poor offshore waters from intermediate depth, leading to less efficient deep-ocean carbon and oxygen transfer and higher ice-shelf basal melt rates. We use a global ocean–biogeochemistry model including ice-shelf cavities and an eddy-permitting grid in the southern Weddell Sea to address the susceptibility of this region to such a system change for four 21〈jats:sup〉st〈/jats:sup〉-century emission scenarios. Assessing the projected changes in shelf–open ocean density gradients, bottom-water properties, and on-shelf heat transport, our results indicate that the Weddell Sea undergoes a regime shift by 2100 in the highest-emission scenario SSP5-8.5, but not yet in the lower-emission scenarios. The regime shift is imminent by 2100 in the scenarios SSP3-7.0 and SSP2-4.5, but avoidable under the lowest-emission scenario SSP1-2.6. While shelf-bottom waters freshen and acidify everywhere, bottom waters in the Filchner Trough undergo accelerated warming and deoxygenation following the system change, with implications for local ecosystems and ice-shelf basal melt. Additionally, deep-ocean carbon and oxygen transfer decline, implying that the local changes ultimately affect ocean circulation, climate, and ecosystems globally.〈/jats:p〉
    Repository Name: EPIC Alfred Wegener Institut
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  • 8
    Publication Date: 2023-04-26
    Description: Mechanisms behind the phenomenon of Arctic amplification are widely discussed. To contribute to this debate, the (AC)3 project was established in 2016 (www.ac3-tr.de/). It comprises modeling and data analysis efforts as well as observational elements. The project has assembled a wealth of ground-based, airborne, shipborne, and satellite data of physical, chemical, and meteorological properties of the Arctic atmosphere, cryosphere, and upper ocean that are available for the Arctic climate research community. Short-term changes and indications of long-term trends in Arctic climate parameters have been detected using existing and new data. For example, a distinct atmospheric moistening, an increase of regional storm activities, an amplified winter warming in the Svalbard and North Pole regions, and a decrease of sea ice thickness in the Fram Strait and of snow depth on sea ice have been identified. A positive trend of tropospheric bromine monoxide (BrO) column densities during polar spring was verified. Local marine/biogenic sources for cloud condensation nuclei and ice nucleating particles were found. Atmospheric–ocean and radiative transfer models were advanced by applying new parameterizations of surface albedo, cloud droplet activation, convective plumes and related processes over leads, and turbulent transfer coefficients for stable surface layers. Four modes of the surface radiative energy budget were explored and reproduced by simulations. To advance the future synthesis of the results, cross-cutting activities are being developed aiming to answer key questions in four focus areas: lapse rate feedback, surface processes, Arctic mixed-phase clouds, and airmass transport and transformation.
    Repository Name: EPIC Alfred Wegener Institut
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  • 9
    Publication Date: 2023-01-27
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(8), (2022): 1705-1730, https://doi.org/10.1175/jpo-d-21-0243.1.
    Description: Formation and evolution of barrier layers (BLs) and associated temperature inversions (TIs) were investigated using a 1-yr time series of oceanic and air–sea surface observations from three moorings deployed in the eastern Pacific fresh pool. BL thickness and TI amplitude showed a seasonality with maxima in boreal summer and autumn when BLs were persistently present. Mixed layer salinity (MLS) and mixed layer temperature (MLT) budgets were constructed to investigate the formation mechanism of BLs and TIs. The MLS budget showed that BLs were initially formed in response to horizontal advection of freshwater in boreal summer and then primarily maintained by precipitation. The MLT budget revealed that penetration of shortwave radiation through the mixed layer base is the dominant contributor to TI formation through subsurface warming. Geostrophic advection is a secondary contributor to TI formation through surface cooling. When the BL exists, the cooling effect from entrainment and the warming effect from detrainment are both significantly reduced. In addition, when the BL is associated with the presence of a TI, entrainment works to warm the mixed layer. The presence of BLs makes the shallower mixed layer more sensitive to surface heat and freshwater fluxes, acting to enhance the formation of TIs that increase the subsurface warming via shortwave penetration.
    Description: SK is supported by JSPS Overseas Research Fellowships. JS and SK are supported by NASA Grant 80NSSC18K1500. JTF and the mooring deployment were funded by NASA Grants NNX15AG20G and 80NSSC18K1494. DZ is supported by NASA Grant 80NSSC18K1499. This publication is partially funded by the Cooperative Institute for Climate, Ocean, and Ecosystem Studies (CICOES) under NOAA Cooperative Agreement NA20OAR4320271, Contribution 2021-1152. This is PMEL Contribution 5268.
    Description: 2023-01-27
    Keywords: Ocean ; North Pacific Ocean ; Tropics ; Entrainment ; Oceanic mixed layer ; Salinity
    Repository Name: Woods Hole Open Access Server
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  • 10
    Publication Date: 2023-02-01
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(8), (2022): 1927-1943, https://doi.org/10.1175/jpo-d-21-0124.1.
    Description: The Galápagos Archipelago lies on the equator in the path of the eastward flowing Pacific Equatorial Undercurrent (EUC). When the EUC reaches the archipelago, it upwells and bifurcates into a north and south branch around the archipelago at a latitude determined by topography. Since the Coriolis parameter (f) equals zero at the equator, strong velocity gradients associated with the EUC can result in Ertel potential vorticity (Q) having sign opposite that of planetary vorticity near the equator. Observations collected by underwater gliders deployed just west of the Galápagos Archipelago during 2013–16 are used to estimate Q and to diagnose associated instabilities that may impact the Galápagos Cold Pool. Estimates of Q are qualitatively conserved along streamlines, consistent with the 2.5-layer, inertial model of the EUC by Pedlosky. The Q with sign opposite of f is advected south of the Galápagos Archipelago when the EUC core is located south of the bifurcation latitude. The horizontal gradient of Q suggests that the region between 2°S and 2°N above 100 m is barotropically unstable, while limited regions are baroclinically unstable. Conditions conducive to symmetric instability are observed between the EUC core and the equator and within the southern branch of the undercurrent. Using 2-month and 3-yr averages, e-folding time scales are 2–11 days, suggesting that symmetric instability can persist on those time scales.
    Description: This work was supported by the National Science Foundation (Grants OCE-1232971 and OCE-1233282), the NASA Earth and Space Science Fellowship Program (Grant 80NSSC17K0443), and the Global Ocean Monitoring and Observing Program of the National Oceanographic and Atmospheric Administration (NA13OAR4830216). Color maps are from Thyng et al. (2016).
    Description: 2023-02-01
    Keywords: Currents ; In situ oceanic observations ; Instability ; Mixing ; Ocean dynamics ; Pacific Ocean ; Potential vorticity ; Tropics
    Repository Name: Woods Hole Open Access Server
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  • 11
    Publication Date: 2023-02-01
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of the Atmospheric and Oceanic Technology 39(8), (2022): 1183-1198, https://doi.org/10.1175/jtech-d-21-0068.1.
    Description: Horizontal kinematic properties, such as vorticity, divergence, and lateral strain rate, are estimated from drifter clusters using three approaches. At submesoscale horizontal length scales O(1–10)km, kinematic properties become as large as planetary vorticity f, but challenging to observe because they evolve on short time scales O(hourstodays). By simulating surface drifters in a model flow field, we quantify the sources of uncertainty in the kinematic property calculations due to the deformation of cluster shape. Uncertainties arise primarily due to (i) violation of the linear estimation methods and (ii) aliasing of unresolved scales. Systematic uncertainties (iii) due to GPS errors, are secondary but can become as large as (i) and (ii) when aspect ratios are small. Ideal cluster parameters (number of drifters, length scale, and aspect ratio) are determined and error functions estimated empirically and theoretically. The most robust method—a two-dimensional, linear least squares fit—is applied to the first few days of a drifter dataset from the Bay of Bengal. Application of the length scale and aspect-ratio criteria minimizes errors (i) and (ii), and reduces the total number of clusters and so computational cost. The drifter-estimated kinematic properties map out a cyclonic mesoscale eddy with a surface, submesoscale fronts at its perimeter. Our analyses suggest methodological guidance for computing the two-dimensional kinematic properties in submesoscale flows, given the recently increasing quantity and quality of drifter observations, while also highlighting challenges and limitations.
    Description: This research was supported by the Office of Naval Research (ONR) Departmental Research Initiative ASIRI under Grant N00014-13-1-0451 (SE and AM) and Grant N00014-13-1-0477 (VH and LC). The authors thank the captain and crew of the R/V Roger Revelle, and Andrew Lucas with the Multiscale Ocean Dynamics group at the Scripps Institution for Oceanography for providing the FastCTD data collected in 2015, which was supported by ONR Grant N00014-13-1-0489, as well as Eric D’Asaro for helpful discussions and Lance Braasch for assistance with the drifter dataset. AM and SE further thank NSF (Grant OCE-I434788) and ONR (Grant N00014-16-1-2470) for support. VH and LC were additionally supported by ONR Grants N00014-15-1-2286, N00014-14-1-0183, N00014-19-1-26-91 and NOAA Global Drifter Program (GDP) Grant NA15OAR4320071.
    Description: 2023-02-01
    Keywords: Indian Ocean ; Eddies ; Frontogenesis/frontolysis ; Fronts ; Lagrangian circulation/transport ; Ocean circulation ; Ocean dynamics
    Repository Name: Woods Hole Open Access Server
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  • 12
    Publication Date: 2023-02-01
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 35(17), (2022): 5465-5482, https://doi.org/10.1175/jcli-d-21-0671.1.
    Description: Understanding the contribution of ocean circulation to glacial–interglacial climate change is a major focus of paleoceanography. Specifically, many have tried to determine whether the volumes and depths of Antarctic- and North Atlantic–sourced waters in the deep ocean changed at the Last Glacial Maximum (LGM; ∼22–18 kyr BP) when atmospheric pCO2 concentrations were 100 ppm lower than the preindustrial. Measurements of sedimentary geochemical proxies are the primary way that these deep ocean structural changes have been reconstructed. However, the main proxies used to reconstruct LGM Atlantic water mass geometry provide conflicting results as to whether North Atlantic–sourced waters shoaled during the LGM. Despite this, a number of idealized modeling studies have been advanced to describe the physical processes resulting in shoaled North Atlantic waters. This paper aims to critically assess the approaches used to determine LGM Atlantic circulation geometry and lay out best practices for future work. We first compile existing proxy data and paleoclimate model output to deduce the processes responsible for setting the ocean distributions of geochemical proxies in the LGM Atlantic Ocean. We highlight how small-scale mixing processes in the ocean interior can decouple tracer distributions from the large-scale circulation, complicating the straightforward interpretation of geochemical tracers as proxies for water mass structure. Finally, we outline promising paths toward ascertaining the LGM circulation structure more clearly and deeply.
    Description: S.K.H. was supported by the Investment in Science Fund at WHOI and the John E. and Anne W. Sawyer Endowed Fund in Support of Scientific Staff. F.J.P. was supported by a Stanback Postdoctoral Fellowship at Caltech.
    Description: 2023-02-01
    Keywords: Diapycnal mixing ; Meridional overturning circulation ; Ocean circulation
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  • 13
    Publication Date: 2023-02-17
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of the Atmospheric and Oceanic Technology 39(10), (2022): 1525–1539, https://doi.org/10.1175/jtech-d-21-0186.1.
    Description: The static and dynamic performances of the RBRargo3 are investigated using a combination of laboratory-based and in situ datasets from floats deployed as part of an Argo pilot program. Temperature and pressure measurements compare well to co-located reference data acquired from shipboard CTDs. Static accuracy of salinity measurements is significantly improved using 1) a time lag for temperature, 2) a quadratic pressure dependence, and 3) a unit-based calibration for each RBRargo3 over its full pressure range. Long-term deployments show no significant drift in the RBRargo3 accuracy. The dynamic response of the RBRargo3 demonstrates the presence of two different adjustment time scales: a long-term adjustment O(120) s, driven by the temperature difference between the interior of the conductivity cell and the water, and a short-term adjustment O(5–10) s, associated to the initial exchange of heat between the water and the inner ceramic. Corrections for these effects, including dependence on profiling speed, are developed.
    Keywords: Data processing/distribution ; In situ oceanic observations ; Profilers ; Oceanic
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  • 14
    Publication Date: 2023-02-28
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(12),(2022): 3199-3219, https://doi.org/10.1175/jpo-d-22-0009.1.
    Description: The abyssal overturning circulation is thought to be primarily driven by small-scale turbulent mixing. Diagnosed water-mass transformations are dominated by rough topography “hotspots,” where the bottom enhancement of mixing causes the diffusive buoyancy flux to diverge, driving widespread downwelling in the interior—only to be overwhelmed by an even stronger upwelling in a thin bottom boundary layer (BBL). These water-mass transformations are significantly underestimated by one-dimensional (1D) sloping boundary layer solutions, suggesting the importance of three-dimensional physics. Here, we use a hierarchy of models to generalize this 1D boundary layer approach to three-dimensional eddying flows over realistically rough topography. When applied to the Mid-Atlantic Ridge in the Brazil Basin, the idealized simulation results are roughly consistent with available observations. Integral buoyancy budgets isolate the physical processes that contribute to realistically strong BBL upwelling. The downward diffusion of buoyancy is primarily balanced by upwelling along the sloping canyon sidewalls and the surrounding abyssal hills. These flows are strengthened by the restratifying effects of submesoscale baroclinic eddies and by the blocking of along-ridge thermal wind within the canyon. Major topographic sills block along-thalweg flows from restratifying the canyon trough, resulting in the continual erosion of the trough’s stratification. We propose simple modifications to the 1D boundary layer model that approximate each of these three-dimensional effects. These results provide local dynamical insights into mixing-driven abyssal overturning, but a complete theory will also require the nonlocal coupling to the basin-scale circulation.
    Description: We acknowledge funding support from National Science Foundation Awards 1536515, 1736109, and 2149080. This material is based upon work supported by the National Science Foundation Graduate Research Fellowship Program under Grant 174530.
    Description: 2023-05-18
    Keywords: Abyssal circulation ; Diapycnal mixing ; Meridional overturning circulation ; Topographic effects ; Upwelling/downwelling ; Bottom currents/bottom water
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  • 15
    Publication Date: 2023-02-28
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(6), (2022): 1091–1110, https://doi.org/10.1175/JPO-D-21-0068.1.
    Description: Hundreds of full-depth temperature and salinity profiles collected by Deepglider autonomous underwater vehicles (AUVs) in the North Atlantic reveal robust signals in eddy isopycnal vertical displacement and horizontal current throughout the entire water column. In separate glider missions southeast of Bermuda, subsurface-intensified cold, fresh coherent vortices were observed with velocities exceeding 20 cm s−1 at depths greater than 1000 m. With vertical resolution on the order of 20 m or less, these full-depth glider slant profiles newly permit estimation of scaled vertical wavenumber spectra from the barotropic through the 40th baroclinic mode. Geostrophic turbulence theory predictions of spectral slopes associated with the forward enstrophy cascade and proportional to inverse wavenumber cubed generally agree with glider-derived quasi-universal spectra of potential and kinetic energy found at a variety of locations distinguished by a wide range of mean surface eddy kinetic energy. Water-column average spectral estimates merge at high vertical mode number to established descriptions of internal wave spectra. Among glider mission sites, geographic and seasonal variability implicate bottom drag as a mechanism for dissipation, but also the need for more persistent sampling of the deep ocean.
    Description: This work was funded by NSF Grant 1736217 and would not have been possible without the help of Kirk O’Donnell, James Bennett, Noel Pelland, and all contributors to Deepglider development. We additionally thank the captain crew of the R/V Atlantic Explorer and the BATS team at the Bermuda Institute of Ocean Sciences, particularly Rod Johnson, as well as Seakeepers International for their professionalism, capability, and generous assistance in deploying and recovering gliders.
    Keywords: North Atlantic Ocean ; Eddies ; Mesoscale processes ; Turbulence ; Energy transport ; In situ oceanic observations ; Oceanic variability
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  • 16
    Publication Date: 2023-03-02
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(12), (2022): 3221–3240, https://doi.org/10.1175/jpo-d-22-0010.1.
    Description: Small-scale mixing drives the diabatic upwelling that closes the abyssal ocean overturning circulation. Indirect microstructure measurements of in situ turbulence suggest that mixing is bottom enhanced over rough topography, implying downwelling in the interior and stronger upwelling in a sloping bottom boundary layer. Tracer release experiments (TREs), in which inert tracers are purposefully released and their dispersion is surveyed over time, have been used to independently infer turbulent diffusivities—but typically provide estimates in excess of microstructure ones. In an attempt to reconcile these differences, Ruan and Ferrari derived exact tracer-weighted buoyancy moment diagnostics, which we here apply to quasi-realistic simulations. A tracer’s diapycnal displacement rate is exactly twice the tracer-averaged buoyancy velocity, itself a convolution of an asymmetric upwelling/downwelling dipole. The tracer’s diapycnal spreading rate, however, involves both the expected positive contribution from the tracer-averaged in situ diffusion as well as an additional nonlinear diapycnal distortion term, which is caused by correlations between buoyancy and the buoyancy velocity, and can be of either sign. Distortion is generally positive (stretching) due to bottom-enhanced mixing in the stratified interior but negative (contraction) near the bottom. Our simulations suggest that these two effects coincidentally cancel for the Brazil Basin Tracer Release Experiment, resulting in negligible net distortion. By contrast, near-bottom tracers experience leading-order distortion that varies in time. Errors in tracer moments due to realistically sparse sampling are generally small (〈20%), especially compared to the O(1) structural errors due to the omission of distortion effects in inverse models. These results suggest that TREs, although indispensable, should not be treated as “unambiguous” constraints on diapycnal mixing.
    Description: We acknowledge funding support from National Science Foundation Awards 1536515 and 1736109. This material is based upon work supported by the National Science Foundation Graduate Research Fellowship Program under Grant 174530. This research is also supported by the NOAA Climate and Global Change Postdoctoral Fellowship Program, administered by UCAR’s Cooperative Programs for the Advancement of Earth System Science (CPAESS) under Award NA18NWS4620043B.
    Description: 2023-05-18
    Keywords: Diapycnal mixing ; Diffusion ; Upwelling/downwelling ; Bottom currents/bottom water ; Tracers
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  • 17
    Publication Date: 2023-03-08
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in LeClerc, H., Tompsett, G., Paulsen, A., McKenna, A., Niles, S., Reddy, C., Nelson, R., Cheng, F., Teixeira, A., & Timko, M. Hydroxyapatite catalyzed hydrothermal liquefaction transforms food waste from an environmental liability to renewable fuel. IScience, 25(9), (2022): 104916, https://doi.org/10.1016/j.isci.2022.104916.
    Description: Food waste is an abundant and inexpensive resource for the production of renewable fuels. Biocrude yields obtained from hydrothermal liquefaction (HTL) of food waste can be boosted using hydroxyapatite (HAP) as an inexpensive and abundant catalyst. Combining HAP with an inexpensive homogeneous base increased biocrude yield from 14 ± 1 to 37 ± 3%, resulting in the recovery of 49 ± 2% of the energy contained in the food waste feed. Detailed product analysis revealed the importance of fatty-acid oligomerization during biocrude formation, highlighting the role of acid-base catalysts in promoting condensation reactions. Economic and environmental analysis found that the new technology has the potential to reduce US greenhouse gas emissions by 2.6% while producing renewable diesel with a minimum fuel selling price of $1.06/GGE. HAP can play a role in transforming food waste from a liability to a renewable fuel.
    Description: This work was funded by the DOE Bioenergy Technology Office (DE-EE0008513), a DOE DBIR (DE-SC0015784) and the MassCEC. The authors thank WenWen Yao, Department of Environmental Science at WPI, for TOC analysis, Mainstream Engineering for heating value characterization of the oil and solid samples, Wei Fan for assistance in obtaining SEM images and, Julia Martin and Ronald Grimm for their assistance in collecting XPS data, and Jeffrey R. Page for his assistance with oil upgrading and analysis. HOL was partially funded for this work by NSF Graduate Research Fellowship award number 2038257. A portion of this work was performed at the National High Magnetic Field Laboratory Ion Cyclotron Resonance user facility, which is supported by the NSF Division of Materials Research and Division of Chemistry through DMR 16-44779 and the State of Florida.
    Keywords: Chemistry ; Chemical engineering ; Catalysis
    Repository Name: Woods Hole Open Access Server
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  • 18
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    Wiley-Blackwell
    In:  EPIC3Reviews in Aquaculture, Wiley-Blackwell, ISSN: 1753-5123
    Publication Date: 2024-05-06
    Description: Mass mortality events (MMEs) are defined as the death of large numbers of fish over a short period of time. These events can result in catastrophic losses to the Atlantic salmon aquaculture industry and the local economy. However, they are challenging to understand because of their relative infrequency and the high number of potential factors involved. As a result, the causes and consequences of MMEs in Atlantic salmon aquaculture are not well understood. In this study, we developed a structural network of causal risk factors for MMEs for aquaculture and the communities that depend on Atlantic salmon aquaculture. Using the Interpretive Structural Modeling (ISM) technique, we analysed the causes of Atlantic salmon mass mortalities due to environmental (abiotic), biological (biotic) and nutritional risk factors. The consequences of MMEs were also assessed for the occupational health and safety of aquaculture workers and their implications for the livelihoods of local communities. This structural network deepens our understanding of MMEs and points to management actions and interventions that can help mitigate mass mortalities. MMEs are typically not the result of a single risk factor but are caused by the systematic interaction of risk factors related to the environment, fish diseases, feeding/nutrition and cage-site management. Results also indicate that considerations of health and safety risk, through pre- and post-event risk assessments, may help to minimize workplace injuries and eliminate potential risks of human fatalities. Company and government assisted socio-economic measures could help mitigate post-mass mortality impacts. Appropriate and timely management actions may help reduce MMEs at Atlantic salmon cage sites and minimize the physical and social vulnerabilities of workers and local communities.
    Repository Name: EPIC Alfred Wegener Institut
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  • 19
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    American Meteorological Society
    In:  EPIC3Journal of Physical Oceanography, American Meteorological Society, 54(4), pp. 1003-1018, ISSN: 0022-3670
    Publication Date: 2024-04-25
    Description: Coastal upwelling, driven by alongshore winds and characterized by cold sea surface temperatures and high upper-ocean nutrient content, is an important physical process sustaining some of the oceans’ most productive ecosystems. To fully understand the ocean properties in eastern boundary upwelling systems, it is important to consider the depth of the source waters being upwelled, as it affects both the SST and the transport of nutrients toward the surface. Here, we construct an upwelling source depth distribution for parcels at the surface in the upwelling zone. We do so using passive tracers forced at the domain boundary for every model depth level to quantify their contributions to the upwelled waters. We test the dependence of this distribution on the strength of the wind stress and stratification using high-resolution regional ocean simulations of an idealized coastal upwelling system. We also present an efficient method for estimating the mean upwelling source depth. Furthermore, we show that the standard deviation of the upwelling source depth distribution increases with increasing wind stress and decreases with increasing stratification. These results can be applied to better understand and predict how coastal upwelling sites and their surface properties have and will change in past and future climates.
    Repository Name: EPIC Alfred Wegener Institut
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  • 20
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    American Meteorological Society
    In:  EPIC3Journal of Climate, American Meteorological Society, 37(6), pp. 2059-2080, ISSN: 0894-8755
    Publication Date: 2024-04-22
    Description: Heat stress is projected to intensify with global warming, causing significant socioeconomic impacts and threatening human health. Wet-bulb temperature (WBT), which combines temperature and humidity effects, is a useful indicator for assessing regional and global heat stress variability and trends. However, the variations of European WBT and their underlying mechanisms remain unclear. Using observations and reanalysis datasets, we demonstrate a remarkable warming of summer WBT during the period 1958–2021 over Europe. Specifically, the European summer WBT has increased by over 1.08C in the past 64 years. We find that the increase in European summer WBT is driven by both near-surface warming temperatures and increasing atmospheric moisture content. We identify four dominant modes of European summer WBT variability and investigate their linkage with the large-scale atmospheric circulation and sea surface temperature anomalies. The first two leading modes of the European WBT variability exhibit prominent interdecadal to long-term variations, mainly driven by a circumglobal wave train and concurrent sea surface temperature variations. The last two leading modes of European WBT variability mainly show interannual variations, indicating a direct and rapid response to large-scale atmospheric dynamics and nearby sea surface temperature variations. Further analysis shows the role of global warming and changes in midlatitude circulations in the variations of summer WBT. Our findings can enhance the understanding of plausible drivers of heat stress in Europe and provide valuable insights for regional decision-makers and climate adaptation planning.
    Repository Name: EPIC Alfred Wegener Institut
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  • 21
    Publication Date: 2024-01-31
    Description: The response of permafrost to submergence can vary between ice-rich late Pleistocene deposits and the thermokarst basins that thawed out during the Holocene. We hypothesize that inundated Alases offshore thaw faster than submerged Yedoma. To test this hypothesis, we estimated depths to the top of ice-bearing permafrost offshore of the Bykovsky Peninsula in northeast Siberia using electrical resistivity surveys. The surveys traversed submerged lagoon deposits, drained and refrozen Alas deposits, and undisturbed Yedoma from the coastline to 373 m offshore. While the permafrost degradation rates of the submerged Yedoma were in the range of similar sites, the submerged Alas permafrost degradation rates were up to 170% faster. Given the abundance of thermokarst basins and lakes along parts of the Arctic coastline, its effect on subsea permafrost degradation must be similarly prevalent. Remote sensing analyses suggest that 54% of lagoons wider than 500 m originated in thermokarst basins.
    Repository Name: EPIC Alfred Wegener Institut
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  • 22
    Publication Date: 2024-01-31
    Description: Permafrost thaw leads to thermokarst lake formation and talik growth tens of meters deep, enabling microbial decomposition of formerly frozen organic matter (OM). We analyzed two 17-m-long thermokarst lake sediment cores taken in Central Yakutia, Russia. One core was from an Alas lake in a Holocene thermokarst basin that underwent multiple lake generations, and the second core from a young Yedoma upland lake (formed ca. 70 years ago) whose sediments have thawed for the first time since deposition. This comparison provides a glance into OM fate in thawing Yedoma deposits. We analyzed total organic carbon (TOC) and dissolved organic carbon (DOC) content, n-alkanes concentrations, and bacterial and archaeal membrane markers. Furthermore, we conducted one-year-long incubations (4 °C, dark) and measured anaerobic carbon dioxide (CO2) and methane (CH4) production. The sediments from both cores contained little TOC (0.7±0.4 wt%), but DOC values were relatively high, with highest values in the frozen Yedoma lake sediments (1620 mg L-1). Cumulative GHG production after one year was highest in the Yedoma lake sediments (226±212 μg CO2-C gdw-1, 28±36 μg CH4-C gdw-1) and 3 and 1.5 times lower in the Alas lake sediments, respectively (75±76 μg CO2-C gdw-1, 19±29 μg CH4-C gdw-1). The highest CO2 production in the frozen Yedoma lake sediments likely results from decomposition of readily bioavailable OM, while highest CH4 production in the non-frozen top sediments of this core suggests that methanogenic communities established upon thaw. The lower GHG production in the non-frozen Alas lake sediments resulted from advanced OM decomposition during Holocene talik development. Furthermore, we found that drivers of CO2 and CH4 production differ following thaw. Our results suggest that GHG production from TOC-poor mineral deposits, which are widespread throughout the Arctic, can be substantial. Therefore, our novel data are relevant for vast ice-rich permafrost deposits vulnerable to thermokarst formation.
    Repository Name: EPIC Alfred Wegener Institut
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  • 23
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    Wiley-Blackwell
    In:  EPIC3Permafrost and Periglacial Processes, Wiley-Blackwell, 32(1), pp. 59-75, ISSN: 1045-6740
    Publication Date: 2024-01-31
    Description: Thermal erosion is a major mechanism of permafrost degradation, resulting in characteristic landforms. We inventory thermo-erosional valleys in ice-rich coastal lowlands adjacent to the Siberian Laptev Sea based on remote sensing, Geographic Information System (GIS), and field investigations for a first regional assessment of their spatial distribution and characteristics. Three study areas with similar geological (Yedoma Ice Complex) but diverse geomorphological conditions vary in valley areal extent, incision depth, and branching geometry. The most extensive valley networks are incised deeply (up to 35 m) into the broad inclined lowland around Mamontov Klyk. The flat, low-lying plain forming the Buor Khaya Peninsula is more degraded by thermokarst and characterized by long valleys of lower depth with short tributaries. Small, isolated Yedoma Ice Complex remnants in the Lena River Delta predominantly exhibit shorter but deep valleys. Based on these hydrographical network and topography assessments, we discuss geomorphological and hydrological connections to erosion processes. Relative catchment size along with regional slope interact with other Holocene relief-forming processes such as thermokarst and neotectonics. Our findings suggest that thermo-erosional valleys are prominent, hitherto overlooked permafrost degradation landforms that add to impacts on biogeochemical cycling, sediment transport, and hydrology in the degrading Siberian Yedoma Ice Complex.
    Repository Name: EPIC Alfred Wegener Institut
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  • 24
    Publication Date: 2024-03-22
    Repository Name: EPIC Alfred Wegener Institut
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  • 25
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    American Meteorological Society
    In:  EPIC3Journal of Climate, American Meteorological Society, 37(8), pp. 2505-2518, ISSN: 0894-8755
    Publication Date: 2024-06-21
    Description: A fundamental statistic of climate variability is its spatiotemporal correlation function. Its complex structure can be concisely summarized by a frequency-dependent measure of the effective spatial degrees of freedom (ESDOF). Here we present, for the first time, frequency-dependent ESDOF estimates of global natural surface temperature variability from purely instrumental measurements, using the HadCRUT4 dataset (1850-2014). The approach is based on a newly developed method for estimating the frequency-dependent spatial correlation function from gappy data fields. Results reveal a multicomponent structure of the spatial correlation function, including a large-amplitude short-distance component (with weak time scale dependence) and a small-amplitude long-distance component (with increasing relative amplitude toward the longer time scales). Two frequency-dependent ESDOF measures are applied, each responding mainly to either of the two components. Both measures exhibit a significant ESDOF reduction from monthly to multidecadal time scales, implying an increase of the effective spatial scale of natural surface temperature fluctuations. Moreover, it is found that a good approximation to the global number of equally spaced samples needed to estimate the variance of global mean temperature is given, at any frequency, by the greater one of the two ESDOF measures, decreasing from ;130 at monthly to ;30 at multidecadal time scales. Finally, the multicomponent structure of the correlation function together with the detected ESDOF scaling properties indicate that the ESDOF reduction toward the longer time scales cannot be explained simply by diffusion acting on stochastically driven anomalies, as it might be suggested f rom simple stochastic-diffusive energy balance models.
    Repository Name: EPIC Alfred Wegener Institut
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  • 26
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    American Meteorological Society
    In:  EPIC3Journal of Climate, American Meteorological Society, 34(18), pp. 7373-7388, ISSN: 0894-8755
    Publication Date: 2024-06-21
    Description: Climate variability occurs over wide ranges of spatial and temporal scales. It exhibits a complex spatial covariance structure, which depends on geographic location (e.g., tropics vs extratropics) and also consists of a superposition of (i) components with gradually decaying positive correlation functions and (ii) teleconnections that often involve anticorrelations. In addition, there are indications that the spatial covariance structure depends on frequency. Thus, a comprehensive assessment of the spatiotemporal covariance structure of climate variability would require an extensive set of statistical diagnostics. Therefore, it is often desirable to characterize the covariance structure by a simple summarizing metric that is easy to compute from datasets. Such summarizing metrics are useful, for example, in the context of comparisons between climate models or between models and observations. Here we introduce a frequency-dependent version of a simple measure of the effective spatial degrees of freedom. The measure is based on the temporal variance of the global average of some climate variable, and its novel aspect consists in its frequency dependence. We also provide a clear geometric interpretation of the measure. Its easy applicability is demonstrated using near-surface temperature and precipitation fields obtained from a paleoclimate model simulation. This application reveals a distinct scaling behavior of the spatial degrees of freedom as a function of frequency, ranging from monthly to millennial scales.
    Repository Name: EPIC Alfred Wegener Institut
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  • 27
    Publication Date: 2024-05-29
    Description: NORP-SORP Workshop on Polar Fresh Water: Sources, Pathways and Impacts of Freshwater in Northern and Southern Polar Oceans and Seas (SPICE-UP) What: Up to 60 participants at a time and more than twice as many registrants in total from 20 nations and across experience levels met to discuss the current status of research on freshwater in both polar regions, future directions, and synergies between the Arctic and Southern Ocean research communities When: 19–21 September 2022 Where: Online
    Repository Name: EPIC Alfred Wegener Institut
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  • 28
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    American Meteorological Society
    In:  EPIC3Bulletin of the American Meteorological Society, American Meteorological Society, 104(9), pp. s1-s10, ISSN: 0003-0007
    Publication Date: 2024-05-29
    Description: 〈jats:title〉Abstract〈/jats:title〉 〈jats:p〉—J. BLUNDEN, T. BOYER, AND E. BARTOW-GILLIES〈/jats:p〉 〈jats:p〉Earth’s global climate system is vast, complex, and intricately interrelated. Many areas are influenced by global-scale phenomena, including the “triple dip” La Niña conditions that prevailed in the eastern Pacific Ocean nearly continuously from mid-2020 through all of 2022; by regional phenomena such as the positive winter and summer North Atlantic Oscillation that impacted weather in parts the Northern Hemisphere and the negative Indian Ocean dipole that impacted weather in parts of the Southern Hemisphere; and by more localized systems such as high-pressure heat domes that caused extreme heat in different areas of the world. Underlying all these natural short-term variabilities are long-term climate trends due to continuous increases since the beginning of the Industrial Revolution in the atmospheric concentrations of Earth’s major greenhouse gases.〈/jats:p〉 〈jats:p〉In 2022, the annual global average carbon dioxide concentration in the atmosphere rose to 417.1±0.1 ppm, which is 50% greater than the pre-industrial level. Global mean tropospheric methane abundance was 165% higher than its pre-industrial level, and nitrous oxide was 24% higher. All three gases set new record-high atmospheric concentration levels in 2022.〈/jats:p〉 〈jats:p〉Sea-surface temperature patterns in the tropical Pacific characteristic of La Niña and attendant atmospheric patterns tend to mitigate atmospheric heat gain at the global scale, but the annual global surface temperature across land and oceans was still among the six highest in records dating as far back as the mid-1800s. It was the warmest La Niña year on record. Many areas observed record or near-record heat. Europe as a whole observed its second-warmest year on record, with sixteen individual countries observing record warmth at the national scale. Records were shattered across the continent during the summer months as heatwaves plagued the region. On 18 July, 104 stations in France broke their all-time records. One day later, England recorded a temperature of 40°C for the first time ever. China experienced its second-warmest year and warmest summer on record. In the Southern Hemisphere, the average temperature across New Zealand reached a record high for the second year in a row. While Australia’s annual temperature was slightly below the 1991–2020 average, Onslow Airport in Western Australia reached 50.7°C on 13 January, equaling Australia's highest temperature on record.〈/jats:p〉 〈jats:p〉While fewer in number and locations than record-high temperatures, record cold was also observed during the year. Southern Africa had its coldest August on record, with minimum temperatures as much as 5°C below normal over Angola, western Zambia, and northern Namibia. Cold outbreaks in the first half of December led to many record-low daily minimum temperature records in eastern Australia.〈/jats:p〉 〈jats:p〉The effects of rising temperatures and extreme heat were apparent across the Northern Hemisphere, where snow-cover extent by June 2022 was the third smallest in the 56-year record, and the seasonal duration of lake ice cover was the fourth shortest since 1980. More frequent and intense heatwaves contributed to the second-greatest average mass balance loss for Alpine glaciers around the world since the start of the record in 1970. Glaciers in the Swiss Alps lost a record 6% of their volume. In South America, the combination of drought and heat left many central Andean glaciers snow free by mid-summer in early 2022; glacial ice has a much lower albedo than snow, leading to accelerated heating of the glacier. Across the global cryosphere, permafrost temperatures continued to reach record highs at many high-latitude and mountain locations.〈/jats:p〉 〈jats:p〉In the high northern latitudes, the annual surface-air temperature across the Arctic was the fifth highest in the 123-year record. The seasonal Arctic minimum sea-ice extent, typically reached in September, was the 11th-smallest in the 43-year record; however, the amount of multiyear ice—ice that survives at least one summer melt season—remaining in the Arctic continued to decline. Since 2012, the Arctic has been nearly devoid of ice more than four years old.〈/jats:p〉 〈jats:p〉In Antarctica, an unusually large amount of snow and ice fell over the continent in 2022 due to several landfalling atmospheric rivers, which contributed to the highest annual surface mass balance, 15% to 16% above the 1991–2020 normal, since the start of two reanalyses records dating to 1980. It was the second-warmest year on record for all five of the long-term staffed weather stations on the Antarctic Peninsula. In East Antarctica, a heatwave event led to a new all-time record-high temperature of −9.4°C—44°C above the March average—on 18 March at Dome C. This was followed by the collapse of the critically unstable Conger Ice Shelf. More than 100 daily low sea-ice extent and sea-ice area records were set in 2022, including two new all-time annual record lows in net sea-ice extent and area in February.〈/jats:p〉 〈jats:p〉Across the world’s oceans, global mean sea level was record high for the 11th consecutive year, reaching 101.2 mm above the 1993 average when satellite altimetry measurements began, an increase of 3.3±0.7 over 2021. Globally-averaged ocean heat content was also record high in 2022, while the global sea-surface temperature was the sixth highest on record, equal with 2018. Approximately 58% of the ocean surface experienced at least one marine heatwave in 2022. In the Bay of Plenty, New Zealand’s longest continuous marine heatwave was recorded.〈/jats:p〉 〈jats:p〉A total of 85 named tropical storms were observed during the Northern and Southern Hemisphere storm seasons, close to the 1991–2020 average of 87. There were three Category 5 tropical cyclones across the globe—two in the western North Pacific and one in the North Atlantic. This was the fewest Category 5 storms globally since 2017. Globally, the accumulated cyclone energy was the lowest since reliable records began in 1981. Regardless, some storms caused massive damage. In the North Atlantic, Hurricane Fiona became the most intense and most destructive tropical or post-tropical cyclone in Atlantic Canada’s history, while major Hurricane Ian killed more than 100 people and became the third costliest disaster in the United States, causing damage estimated at $113 billion U.S. dollars. In the South Indian Ocean, Tropical Cyclone Batsirai dropped 2044 mm of rain at Commerson Crater in Réunion. The storm also impacted Madagascar, where 121 fatalities were reported.〈/jats:p〉 〈jats:p〉As is typical, some areas around the world were notably dry in 2022 and some were notably wet. In August, record high areas of land across the globe (6.2%) were experiencing extreme drought. Overall, 29% of land experienced moderate or worse categories of drought during the year. The largest drought footprint in the contiguous United States since 2012 (63%) was observed in late October. The record-breaking megadrought of central Chile continued in its 13th consecutive year, and 80-year record-low river levels in northern Argentina and Paraguay disrupted fluvial transport. In China, the Yangtze River reached record-low values. Much of equatorial eastern Africa had five consecutive below-normal rainy seasons by the end of 2022, with some areas receiving record-low precipitation totals for the year. This ongoing 2.5-year drought is the most extensive and persistent drought event in decades, and led to crop failure, millions of livestock deaths, water scarcity, and inflated prices for staple food items.〈/jats:p〉 〈jats:p〉In South Asia, Pakistan received around three times its normal volume of monsoon precipitation in August, with some regions receiving up to eight times their expected monthly totals. Resulting floods affected over 30 million people, caused over 1700 fatalities, led to major crop and property losses, and was recorded as one of the world’s costliest natural disasters of all time. Near Rio de Janeiro, Brazil, Petrópolis received 530 mm in 24 hours on 15 February, about 2.5 times the monthly February average, leading to the worst disaster in the city since 1931 with over 230 fatalities.〈/jats:p〉 〈jats:p〉On 14–15 January, the Hunga Tonga-Hunga Ha'apai submarine volcano in the South Pacific erupted multiple times. The injection of water into the atmosphere was unprecedented in both magnitude—far exceeding any previous values in the 17-year satellite record—and altitude as it penetrated into the mesosphere. The amount of water injected into the stratosphere is estimated to be 146±5 Terragrams, or ∼10% of the total amount in the stratosphere. It may take several years for the water plume to dissipate, and it is currently unknown whether this eruption will have any long-term climate effect.〈/jats:p〉
    Repository Name: EPIC Alfred Wegener Institut
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  • 29
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    American Meteorological Society
    In:  EPIC3Bulletin of the American Meteorological Society, American Meteorological Society, 104(9), pp. s271-s321, ISSN: 0003-0007
    Publication Date: 2024-05-29
    Repository Name: EPIC Alfred Wegener Institut
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  • 30
    Publication Date: 2024-06-28
    Description: 〈jats:title〉Abstract〈/jats:title〉 〈jats:p〉This study quantifies the state-of-the-art in the rapidly growing field of seasonal Arctic sea ice prediction. A novel multi-model dataset of retrospective seasonal predictions of September Arctic sea ice is created and analyzed, consisting of community contributions from 17 statistical models and 17 dynamical models. Prediction skill is compared over the period 2001–2020 for predictions of Pan-Arctic sea ice extent (SIE), regional SIE, and local sea ice concentration (SIC) initialized on June 1, July 1, August 1, and September 1. This diverse set of statistical and dynamical models can individually predict linearly detrended Pan-Arctic SIE anomalies with skill, and a multi-model median prediction has correlation coefficients of 0.79, 0.86, 0.92, and 0.99 at these respective initialization times. Regional SIE predictions have similar skill to Pan-Arctic predictions in the Alaskan and Siberian regions, whereas regional skill is lower in the Canadian, Atlantic, and Central Arctic sectors. The skill of dynamical and statistical models is generally comparable for Pan-Arctic SIE, whereas dynamical models outperform their statistical counterparts for regional and local predictions. The prediction systems are found to provide the most value added relative to basic reference forecasts in the extreme SIE years of 1996, 2007, and 2012. SIE prediction errors do not show clear trends over time, suggesting that there has been minimal change in inherent sea ice predictability over the satellite era. Overall, this study demonstrates that there are bright prospects for skillful operational predictions of September sea ice at least three months in advance.〈/jats:p〉
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  • 31
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4546-4550 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The properties of high-resistivity InP with resistivity up to 107 Ω cm, obtained by thermal diffusion of Cu at 800 °C for over 20 h into undoped and p-type InP samples, are investigated. Hall-effect measurements showed that the compensation mechanism in the slowly cooled sample is different from that in the quickly cooled samples. Photoluminescence was quenched in the quickly cooled samples when annealed at 350 °C and the anneal temperature at which the sample resistivity and carrier mobility reached the maximum. It is shown that the electrical compensation in the slowly cooled sample could be understood by a simple deep-level compensation model. However, the semi-insulating behavior of the quickly cooled samples appears to be consistent with an internal Schottky depletion model associated with the Cu precipitates. The photoluminescence quenching is due to the Cu precipitates acting as effective nonradiative recombination centers.
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  • 32
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4551-4556 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Iron pyrite thin films prepared by flash evaporation of pyrite powder have been annealed at different temperatures in a sulfur atmosphere. We present some results on the influence of the annealing temperature (from 250 to 450 °C) on the optical and electrical properties of three groups of samples with different thicknesses ((approximately-equal-to)0.3, 0.6, and 1 μm, respectively). Sulfuration temperature has a clear influence on the optical absorption and electrical resistivity of the films, with some differences in their behavior depending on the film thickness. In light of the available present knowledge of pyrite thin films, interpretation of the obtained results is difficult, it suggests that the shape of the optical absorption curves (and their absorption edge) at low photon energies is determined by the density of point defects, which decreases on increasing the annealing temperature. On the other hand, the electrical resistivity seems to be influenced by both the film grain size and point defect density.
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  • 33
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 839-847 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Self-consistent nonequilibrium fluid models of both the two-dimension (2D) and one-dimension (1D) are presented. In the 2D simulations, the models evaluate the quantitative effects of both radial and axial flow dynamics inside a cylindrically symmetric parallel-plate geometry. The 1D model assumes that the radius of the electrode is much larger than the electrode gap and the moment distributions are uniform along the radial direction. The models are based on the first three moments of the Boltzmann equation and Poisson's equation. Radio frequency (rf) glow discharge simulations from those two fluid models are presented and compared in this study. The comparisons are presented in terms of plasma density, electric field, mean energy, and ionization rate. Results of the 1D fluid model are close to those at the center of the reactor from the 2D simulations. Nonuniform profiles along the radial direction are obtained from the 2D simulations due to the radial dynamics. Higher electron mean energy in the middle region of the radial sheath is observed. The maximum ionization rate is located in the radial sheath region and agrees with the experimental observation.
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  • 34
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 825-831 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: In this paper a model of charged particle behavior in a low-pressure oxygen plasma is developed, and compared with experimental results. Agreement is excellent. It is demonstrated that the extremely high temperature ((approximately-greater-than)1 eV) of electrons in these plasmas results in diffusion totally dominating the transport of charged species. It is also shown that charged particle recombination on the walls of a quartz reactor is insignificant. Finally, the influence of the electron temperature profile must be fully considered for accurate results. This work complements an earlier model of radical behavior in these plasmas. Both are needed to fully understand materials modification in these plasmas, which has been shown to involve a synergism between radicals and charged species.
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  • 35
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 853-861 
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    Topics: Physics
    Notes: Large particles (tens of nm to tens of μm in diameter) are problematic in low-pressure (〈1 Torr) plasma processing (etching, deposition) discharges because they can contaminate the product and can perturb electron transport. Although the source of these particles has been studied by a number of groups, a definitive explanation is still lacking. In this paper, we theoretically investigate the role of negative ions in the formation of large clusters, the precursors to particles, in low-pressure plasmas. We find that the formation of particles requires a critically large cluster. Forming the critically large cluster requires longer residence times in the plasma than is usually possible if clustering involves only neutral particles. We propose that negatively charged intermediates, which are trapped in electropositive plasmas, increase the average residence time of clusters to allow the growth of critically large clusters.
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  • 36
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 868-871 
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    Topics: Physics
    Notes: Swift heavy ion irradiation-induced defects have been studied in n-type germanium at room temperature using deep level transient spectroscopy. Several electron traps have been observed after irradiation. The corresponding energies have been determined to be at Ec−0.22, Ec−0.275, Ec−0.29, Ec−0.32, and Ec−0.465 eV. The isochronal annealing behavior of these traps has been studied in detail between room temperature and 200 °C. Comparison of our results with previously published ones allowed an identification of these defects with complexes like divacancies or associations of vacancies with impurities.
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  • 37
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 862-867 
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    Topics: Physics
    Notes: The temporal behavior of the cathode sheath in 30 kHz 0.4–1 Torr H2 discharges has been investigated by optical emission spectroscopy. Analysis of the Stark splitting of plasma-induced H Balmer delta emission was used to measure the electric field with spatial and temporal resolution in the instantaneous cathode sheath. The location of the plasma/sheath boundary was determined from the position of the maximum of the H2 d 3Πu→a 3Σg+ (0,0) Q1 emission at 622.5 nm. Both methods showed that the sheath width increases as the cathode voltage becomes more negative, whereas the width remains constant as the applied voltage drops off. Analysis of the electric-field profile provided information on the time evolution of the ion density close to the electrode during the cathode half-cycle, in agreement with recent numerical calculations. At the beginning of the anodic half-cycle an intense flash of plasma-induced emission was observed, localized within 3 mm from the electrode.
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  • 38
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 877-883 
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    Topics: Physics
    Notes: Hollow glass fibers can guide x rays because glancing-angle collisions with a smooth glass surface are highly reflective. Surface roughness decreases this reflectivity. We have developed relatively simple expressions for the effects of surface roughness on x-ray scattering, and we relate our results to the theoretical efficiency of x-ray lenses formed from bundles of hollow glass fibers.
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  • 39
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 884-890 
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    Topics: Physics
    Notes: Positron lifetime spectroscopy and two-dimensional angular correlation of annihilation radiation have been used to investigate grown-in vacancy structures in synthetic crystalline α-SiO2, synthetic fused quartz, and in a 60-μm-thick chemical-vapor-deposited amorphous SiO2 film. For α-SiO2 a ∼300 ps lifetime component suggests trapping by either silicon monovacancies or by oxygen divacancies (or both). The vacancies are neutral and present at a concentration level of 1017/cm3. The positron bulk lifetime for α-SiO2 is estimated to be ∼238 ps in good agreement with semiempirical predictions. In the fused quartz significant positronium formation is found (80%) and the remaining positrons annihilate in voids yielding a lifetime of ∼500 ps. The amorphous SiO2 film contains a mixture of small vacancy clusters and voids and ∼30% of the positrons form positronium. Heat treatment above 950 °C results in a substantial reduction in defect concentration, but up to 1100 °C a small vacancy cluster contribution persists. The positron data indicate that positronium formation in the fused quartz and in the amorphous film takes place in the voids.
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  • 40
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 872-876 
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    Topics: Physics
    Notes: X-ray photoelectron spectroscopy has been used to study the surface composition and chemistry of two perovskites: SrTiO3 and Pb(Zr,Ti)O3 (commonly known as PZT). It is seen that ion bombardment, which is a common surface modification technique, can cause substantial changes in these oxides. The PZT surface undergoes surface depletion of lead along with chemical reduction of the Pb2+ ion to its metallic state. The Zr/(Ti+Zr) ratio also changes with sputtering, but the total oxygen to cation ratio is unchanged. On the other hand, the surface stoichiometry of SrTiO3 is almost unaffected by ion bombardment. In all the perovskites, irrespective of whether the composition changes or not, a substantial amount of surface Ti is reduced to a lower valency state on sputtering. Most of this component is restored back to the original Ti4+ state when Ni is evaporated on these surfaces, indicating that the reduced state is associated with a damaged outermost surface that can be repaired with an adsorbate. The implication of these results to the bonding properties of these materials have been discussed.
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  • 41
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4102-4104 
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    Topics: Physics
    Notes: The spin pinning in the oxide surface layer has been observed directly, and it is considered a possible reason why the oxide layer leads to the decrease of the specific saturation magnetization for fine iron particles. The pinning depth has been estimated by means of a Mössbauer effect under an applied field of 6 T in a thermal-cycle process. The Debye temperature of the oxide layer and the temperature dependence of f2/f1 have been obtained, where f1 and f2 are the Mössbauer recoilless fractions for the inner α-Fe core and the oxide layer, respectively. Furthermore, the estimation for the thickness of an oxide layer has been improved.
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  • 42
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4105-4112 
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    Topics: Physics
    Notes: A theory of collective translational vibrations of 90° domain walls (DWs) in ferroelectric ceramics is presented. Vibrational motions of DWs forming a regular domain structure of a representative grain are assumed to be completely correlated but independent of DW oscillations in other grains. A dynamic mechanical stress field appearing in a ceramic because of DW vibrations is calculated. In contrast to former studies, this calculation takes into account effects due to the lagging of sound waves emitted by oscillating DWs and gives a general expression for the dynamic mechanical restoring force acting on DWs. From this expression we derive the equation of sustained forced DW vibrations in an oscillating external electric field that is valid for a wide frequency range including microwave frequencies. A general solution of this equation is found, which enables us to compute numerically the dependencies of amplitude and phase of DW vibrations on the frequency ω of the applied electric field. It is shown that in the low-frequency range ω〈ω*=ct/g (ct=velocity of transverse sound wave, g=grain size) the general equation of DW vibrations can be reduced to a simplified equation that includes the static restoring force, the inertial reaction, and the radiation reaction self-force of the DWs emitting sound waves. Analytic expressions are derived for the DW effective mass and for the factors characterizing the static restoring force and the radiation reaction. The contribution of DW vibrations to the complex dielectric constants of ferroelectric ceramics is calculated. It is predicted that at very high frequencies ω(very-much-greater-than)ω* the DW contribution to the real part of permittivity strongly decreases due to clamping of DWs. In this frequency range a peak of dielectric losses should also arise being caused by the emission of sound waves from oscillating DWs. It is emphasized that the above effects can be correctly described on the base of the general equation of DW vibrations only.
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  • 43
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    Journal of Applied Physics 74 (1993), S. 4121-4124 
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    Topics: Physics
    Notes: A phenomenological model has been applied in an attempt to explain the inability of the ordered regions in the lead magnesium niobate family of relaxor ferroelectrics to coarsen. This approach is based on the concept that the free energy is lowered by an embryonic decomposition along a non-neutral direction. It is proposed that the excess free energy associated with the formation of the non-neutral phase is offset by the distortability of the perovskite structure toward the pyrochlore. The lack of coarsening is then explained as a balance of the electrostatic energy and gradient energy terms, following an earlier published report. This model is then applied to the La-modified (donor-doped) lead magnesium niobate, to explain the dependence of the size of the ordered regions on the degree of doping as observed by other workers.
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  • 44
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    Journal of Applied Physics 74 (1993), S. 4113-4120 
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    Topics: Physics
    Notes: Charge injection leading to catastrophic breakdown has been used to study the dielectric properties of the buried oxide layer in silicon implanted with high-energy oxygen ions. Current versus gate bias, current versus time, and capacitance versus gate bias were used to characterize, at various temperatures, MOS metal-oxide-semiconductor capacitors with areas in the 1×10−4–1×10−2 cm2 range fabricated with commercially available single- or triple-implant separation by implanted oxygen silicon wafers. The data show that injected charge accumulates in the buried oxide at donorlike oxide traps ultimately leading to catastrophic breakdown. Both Poole–Frenkel and Fowler–Nordheim conduction, as well as impact-ionization mechanisms, have been identified in the oxide. The charge and field to breakdown in the best buried oxides are, respectively, near 1 C cm−2 and 10 MV cm−1, similar to the thermally grown oxide parameters. Cumulative distributions of these parameters measured over a large number of capacitors show that the frequency of breakdown events caused by extrinsic defects is scaled with the capacitor area. Intrinsic and extrinsic defect distributions are broader than with thermally grown oxides.
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  • 45
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4125-4129 
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    Notes: Zinc (Zn) is doped into GaSe single crystals grown by the Bridgman technique in a wide range from 0.005 to 0.5 at. % to the stoichiometric melt. Radiative recombination mechanisms have been investigated by using photoluminescence (PL) measurements. The PL spectra in Zn-doped samples at 77 K are dominated by three emission bands at 1.75, 1.63, and 1.27 eV. The 1.63 and 1.27 eV emission bands are enhanced with the increase in the amount of Zn. In addition to the results of Hall effect measurements, it is found that the 1.63 and 1.27 eV emission bands are associated with the acceptor levels at 0.12 and 0.3 eV above the valence band, respectively. For the 1.27 eV emission band, the temperature dependences of the PL intensity, peak energy, and half-width are characterized by the configurational coordinate model.
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  • 46
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    Journal of Applied Physics 74 (1993), S. 4598-4607 
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    Topics: Physics
    Notes: High-field effects in metal-oxide-semiconductor capacitors have been studied in detail. A comprehensive set of experiments, stressing identically fabricated capacitors on both P-type and N-type silicon, both in accumulation and in inversion, has been made to study defect generation in the oxide at high fields. There is clear experimental evidence that both bulk hole and electron traps are generated under all stress conditions. High-field prebreakdown properties depend mainly upon the dynamics of generation of traps, trapping and detrapping at these and in previously existing traps. It has been found that of several processes, some dominate, depending upon the type of silicon and polarity during stressing, and this is also true for the final breakdown mechanism. In this paper the dominant mechanisms are identified for each of the field stress conditions that have been studied.
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  • 47
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    Notes: The heavy-hole and light-hole excitons of a CdTe epilayer, pseudomorphically grown on an InSb epilayer by molecular beam epitaxy, are studied with a diamond anvil cell as a function of applied hydrostatic pressure via photoluminescence (PL) and photomodulated reflectivity (PR) spectroscopies. They are compared with the excitonic features in the simultaneously measured PL spectra of a sample of bulk CdTe. Under applied pressure, the lattice mismatch-induced splitting between the light-hole and heavy-hole related transitions increases in a continuous and reversible manner because of the additional pressure-induced compression due to the difference in the compressibilities of CdTe and InSb. The unusually large strain sustained by the CdTe epilayer under pressure is discussed in the light of various models. The PR signal vanishes after the InSb epilayer goes through a structural phase transition at approximately 20 kbar, while the PL signal persists until it is irreversibly quenched by the CdTe epilayer undergoing a structural phase transition at approximately 30 kbar. For pressures between 20 and 30 kbar, the behavior of the CdTe epilayer is similar to that of the bulk sample; the strain appears to have been relaxed due to the structural phase transition which has taken place in InSb. Values of the first- and second-order pressure coefficients for bulk CdTe and for the CdTe epilayer as well as values of the hydrostatic and shear deformation potentials are obtained at 14 and 80 K and compared with previously quoted values.
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    Notes: This article discusses a low-temperature photoluminescence (PL) and electroabsorption (EA) study of GaxIn1−xAs/Ga0.22In0.78As0.48P0.52 single quantum well (QW) samples prepared by gas-source molecular beam epitaxy. The linewidth of PL emitted from these single QW samples increases monotonically with increasing QW strain. EA measurements on the same samples reveal a multipeaked response on the high energy side of the PL spectrum. The energy separation of the EA features corresponds to that expected for differences in QW thickness of one monolayer. The observed PL broadening results from PL emanating from different regions of the same well, differing in thickness, while the Stokes shift results from migration of excitons to wider well regions. Spectral features are lost at large strain which is attributed to strain-enhanced roughening of the QW surface during the crystal deposition.
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  • 49
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    Journal of Applied Physics 74 (1993), S. 4153-4157 
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    Topics: Physics
    Notes: We report photoluminescence (PL) results obtained on p-type ZnSe epilayers grown by molecular beam epitaxy. As an acceptor dopant, we used an active nitrogen beam produced by a free radical nitrogen source. On the basis of a detailed analysis of PL data we propose a simple semiquantitative method for a quick and contactless evaluation of the net acceptor concentration in p-type ZnSe. In particular, we show that the intensity ratio of the donor–acceptor pair (DAP) emission to the acceptor-bound exciton (I1) emission strongly depends on both the excitation power and the quality of the sample, and because of that it cannot by itself be regarded as a good measure of the net acceptor concentration. On the other hand, the intensity of the DAP emission under saturation excitation shows a simple direct proportionality to the net acceptor concentration, thus providing a reliable tool for determining the relative doping level in p-type ZnSe films.
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  • 50
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4158-4162 
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    Topics: Physics
    Notes: Polymer films containing 4-alkoxy-3-chlorobenzoic acid heated to 140 °C showed two optically different states at room temperature depending on the cooling rate. If after heating the film cooled rapidly, it froze in the transparent state. In contrast, it reverted to the light scattering state when cooled slowly. Cycles between the two optical states were reproducible, therefore these films may offer potential as a rewritable recording material. The reversibility in the optical transmittance may be caused by a reversible change in the crystal size of the acid in the polymer matrix.
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  • 51
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    Journal of Applied Physics 74 (1993), S. 963-968 
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    Topics: Physics
    Notes: Ultraviolet pulsed laser induced oxidation kinetics of crystalline germanium (c-Ge) is determined from real-time optical measurements in conjunction with absolute measurements of the oxygen incorporation performed by nuclear reaction analysis. Although the oxidation process can be triggered at laser fluences initially below the melting threshold of c-Ge, it is strongly activated when surface melting occurs and therefore the fast oxidation process observed is mainly a thermally activated process. Because an optical coupling between the oxide layer and the c-Ge underneath, the growth kinetics is complex and leads to nonconstant rates. The oxygen incorporation reaches a saturation value which depends both on the laser fluence and the oxygen pressure. The results show that the oxygen incorporation is limited by an overlapped laser-induced material removal process rather than by the diffusion length of oxygen species.
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  • 52
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    Journal of Applied Physics 74 (1993), S. 4651-4659 
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    Topics: Physics
    Notes: We have investigated melt-spun Pr-Co alloys with the objective of optimizing their permanent magnet characteristics. Among a variety of elemental additives studied, carbon was found capable of significantly improving the properties, the coercivity in particular. For binary Pr-Co systems optimum values of the remanence, Br=5.7 kG, intrinsic coercivity, Hci=5.8 kOe, and energy product, (BH)max=4.7 MG Oe, were obtained from the Pr16Co84 composition. These values were enhanced to Br=5.8 kG, Hci=16.5 kOe, and (BH)max=7.4 MG Oe for Pr18Co76C6. In both cases the melt-spun ribbons were principally composed of PrCo5. The 16.5 kOe coercivity of the carbon-containing ribbons is the highest ever reported for a PrCo5-based material. Two new rare earth-cobalt phases were tentatively identified during the course of this work: PrCo7 (hexagonal TbCu7 structure) and PrCo2Cx (cubic MgCu2 structure). Survey results for other melt-spun, RCo5-based alloys are also described.
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  • 53
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    Journal of Applied Physics 74 (1993), S. 4643-4650 
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    Topics: Physics
    Notes: The microstructural origin of magnetic anisotropy in a magnetron in-line sputter-deposited CoPtCr/Cr magnetic thin-film disk was examined by mapping magnetic properties and microstructure. The film coercivity (Hc), remanence-thickness product (Mrδ), and coercivity squareness (S*) were determined as a function of radial (r) and angular (θ) co-ordinates using a transfer curve magnetometer. The observed variations in Hc, Mrδ, and S* across the disk were 85 Oe, 0.15 emu/cm2, and 0.03, respectively. The angular variation in magnetic properties showed a sinusoidal pattern with the maxima corresponding to the regions where the tracks were parallel (θ=270°) to the pallet movement direction. High-resolution scanning transmission electron microscopy showed subtle differences in the Co-alloy grain morphology and crystallographic orientation between θ=270° and θ=360° locations. The grains were equiaxed in general except for a small fraction of grains elongated in the direction of pallet movement. Lattice images clearly showed that about 45% of the Co-alloy grains had in-plane c axes and a preferred alignment of the c axes along the texture groove. A greater preference for the c axes to lie along the texture line was observed for the θ=270° location. A coherency stress-based model is proposed to explain the preferred c-axis alignment. While the crystalline anisotropy appears to be the main factor responsible for the magnetic anisotropy, both crystalline and shape anisotropies contribute to the magnetic anisotropy variations.
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    Journal of Applied Physics 74 (1993), S. 4664-4672 
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    Topics: Physics
    Notes: Insulating barium titanate films were successfully grown on Ti-deposited silicon substrates using the hydrothermal method. The film thickness was 35 and 49 nm for films treated at 200 and 250 °C, respectively, in a 0.25 M Ba(OH)2 solution for 8 h. The BaTiO3 films did not reach the Ti/Si interface. X-ray photoelectron spectroscopy revealed OH-free and nearly carbon-free films, which was corroborated using Auger electron spectroscopy (AES) depth analysis. AES revealed that the oxygen and barium concentrations are correlated throughout the film, and the existence of a diffuse BaTiO3/Ti interface. A discussion on the film growth mechanism is made using existing information on the subject.
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    Journal of Applied Physics 74 (1993), S. 4660-4663 
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    Topics: Physics
    Notes: Magnetoresistance, antiferromagnetic coupling, and crystallographic orientation of Co/Cu superlattices with intentionally mixed interfaces have been studied as a function of the thickness of the mixed region. The antiferromagnetic coupling is weakened, and spin-independent scattering of free electrons is enhanced with increasing thickness of the mixed region, although the morphology and the superlattice period remain unchanged. Saturation magnetoresistance is reduced from 27% to 4% as the result of the formation of a 0.15 nm mixed region at the interfaces. Moreover, the crystallographic orientation of Co/Cu superlattices is also found to be varied by formation of the mixed region. Giant magnetoresistance, antiferromagnetic coupling, and the crystallinity of Co/Cu superlattices are governed by the events in the thin region at the interfaces less than 1 monolayer.
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    Journal of Applied Physics 74 (1993), S. 4685-4690 
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    Notes: The effects on the reflectance spectra of zinc oxide powders, of heat treatment, and of mechanical grinding were investigated for both undoped and aluminum-doped ZnO. A broad absorptance band at 390–400 nm was induced in the undoped powders both by heating in air and by grinding. From a comparison with electron paramagnetic resonance data from the literature, the band could be related to oxygen vacancies. It was found that aluminum doping suppresses the band formation induced by grinding; however, the doping does not suppress the band formation induced by heat treatment.
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    Journal of Applied Physics 74 (1993), S. 4673-4680 
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    Topics: Physics
    Notes: Hydrogenated amorphous carbon films were prepared from CH4, H2, and Ar mixtures by plasma enhanced chemical vapor deposition. Films with various physical properties resulting from various deposition conditions were utilized for this study. The varying deposition parameters included H2 flow rates, Ar flow rates, total pressures, substrate temperatures, and power densities. A systematic study regarding the relationship between deposition conditions and the microstructures, optical, and thermal properties was conducted. Furthermore, how the optical and thermal properties related to the microstructures was analyzed. Fourier transform infrared spectroscopy was employed in this paper for determining the hydrogen concentration and the amounts of tetrahedral and trigonal bondings associated with C—H bond and their relative ratio while the optical properties were measured by optical spectrophotometer. Additionally, photothermal deflection spectroscopy was applied for the measurements of thermal diffusion length.
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    Journal of Applied Physics 74 (1993), S. 4681-4684 
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    Topics: Physics
    Notes: The relationship between the magnitude of the piezoelectric field and the degree of lattice constant mismatch is investigated via low-temperature photoluminescence measurements of the quantum-confined Stark effect for a series of (111)B Al0.15Ga0.85As-InyGa1−yAs pseudomorphic quantum well heterostructures. The experimental strain-induced electric field values agree well with theoretical calculations for indium mole fractions in the range 0.037≤y≤0.09. In addition, an anomalous saturation of the photoluminescence transition energy is observed at values of applied voltage greater than that required to nullify the piezoelectric field, despite the indication from separate electroreflectance measurements that the net electric field within the quantum well reverses polarity under similar electrical biasing conditions.
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  • 59
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    Journal of Applied Physics 74 (1993), S. 7044-7047 
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    Topics: Physics
    Notes: Laser assisted particle removal (LAPR) is an innovative laser cleaning technique which can remove various particles from solid surfaces via laser induced explosive evaporation of a chosen energy transfer medium, e.g., water. An Ar+ ion continuous-wave laser (488 nm) was used to study the CO2 laser pumped explosive evaporation of water adsorbed on a Si substrate. The probe laser beam was parallel to the sample surface at different displacements and interacted with the ejected material upon pulsed CO2 laser irradiation in analogy with the time resolved laser beam deflection experiments on laser induced vaporization of copper by Guo et al. [Opt. Commun. 77, 381 (1990)]. Using CO2 laser energies which are much greater than the LAPR thresholds, we observed the generation and propagation of a shock wave at supersonic speeds followed by a water vapor/aerosol/particle cloud at a much slower speed. From the evolution of the shock wave, the total conversion efficiency of the incident laser beam into the shock wave has been determined using a self-similar approximation.
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    Journal of Applied Physics 74 (1993), S. 2681-2685 
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    Topics: Physics
    Notes: Two types of YBa2Cu3Oy-La0.7Ca0.3MnOz-YBa2Cu3Oy (YBCO-LCMO-YBCO) coplanar-type junctions with a 0.2 μm gap were fabricated by electron-beam lithography and Ar-ion-beam milling. One is a junction in which a current flows into the a-b plane (ferromagnetic spin arrangement) of the LCMO and then passes through the channel along the c axis (antiferromagnetic arrangement), and the other is a junction in which the current only passes through the a-b plane. In the former junction the current-voltage characteristics show nonlinearity which suggests a superconductive linkage, while the latter has linear characteristics. This anisotropy of the proximity effect is attributed to anisotropy of the spin structure, because the LCMO film has a small anisotropy of the normal decay length in the a-b plane and along the c axis.
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    Journal of Applied Physics 74 (1993), S. 2701-2704 
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    Topics: Physics
    Notes: RFe2 laves phase intermetallic compounds are promising materials for magnetostrictive applications. To obtain a larger magnetostriction in a low magnetic field, the influence of boron addition on the giant magnetostriction of an amorphous (SmFe2) (1−x) at. % B (x) at. % alloy has been examined. In the amorphous alloy, the saturation magnetostriction anomalously increases, while the saturation magnetization decreases with the increase in x. The highest saturation magnetostriction of −670×10−6 at 10 kOe and its effective magnetostriction of −490×10−6 at 0.3 kOe can be obtained for amorphous (SmFe2) 99.26 at. % B 0.74 at. % alloy. This effective giant magnetostriction obtained in a low magnetic field is larger than those reported in previous researches. I attribute this anomalous giant magnetostriction in a low magnetic field to the increment of elastic energy in the amorphous (SmFe2) (1−x) at. % B (x) at. % alloy.
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  • 62
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 2725-2730 
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    Topics: Physics
    Notes: Effects of interfaces such as metal/polymer interfaces and polymer/polymer interfaces on the space-charge distribution in multiply low-density polyethylene have been investigated using a pulsed electroacoustic method. It has been found that the heterocharge was dominant in an artificial interface existing in a polyethylene sample. The time dependence of the heterocharge distribution in the interface on applied voltages and polarity was studied. From these charge distributions, the modified electrical field was calculated based on Poisson's equation. The calculated result indicated that the actual field was stronger than the applied uniform field at the artificial interface. A new data display method for a three- or two-dimensional plot is employed to display all measurement data on one plot in which the space charge becomes visible so that the results can be easily and conveniently understood.
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  • 63
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 7078-7084 
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    Topics: Physics
    Notes: The thermal diffusivity measurement through pulsed photodeflection in a modified collinear configuration is presented and discussed; comparison between theory and experiment is also shown.
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  • 64
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 7094-7100 
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    Topics: Physics
    Notes: A theory is presented to explain the observed electron emission characteristics of a hollow-cathode-based plasma source. The theory is compared with measurements made in a laboratory vacuum facility and is used to predict emission characteristics when the source plasma expands into an ambient space plasma. Crucial to understanding the observed emission current-voltage characteristic of hollow-cathode-type devices is the recognition of the role of emission current, not just the current in the main discharge circuit, in ionization of the neutral gas flowing through the device. This ionization can lead to breakdown of the sort that is familiar in many gas discharge devices. Equally crucial to understanding the low impedance capability of the device in coupling spacecraft to an ambient space plasma is recognition of the role of escaping as well as trapped source electrons in the formation of the space potential profile. The presence of these electrons, according to the theory, results in space electron emission current-voltage characteristics which are well approximated by those observed in laboratory chambers.
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  • 65
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4729-4736 
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    Topics: Physics
    Notes: The neutral and charged species emitted by pulsed-laser irradiation of polytetrafluoroethylene (PTFE) at 248 nm in vacuum have been examined. In particular, the species and properties of the emission products produced at typical fluence regimes used in the pulsed-laser deposition of PTFE thin films have been characterized. The relative intensities of the major products as well as their dependence on laser fluence are presented, and a simple model is used to fit the observed fluence dependence. Evidence that the major neutral component, the monomer (C2F4), is formed from a thermally activated unzipping reaction is presented. The ionic species are derived from the neutral decomposition products, apparently ionized by electron collisions in the weak plasma generated at the target surface.
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  • 66
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4737-4740 
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    Topics: Physics
    Notes: Impurity doping in InP layer grown by metalorganic vapor-phase epitaxy using tertiarybutylphosphine and organic doping sources is presented. Diethylzinc and diethylselenide were used as the p-type and n-type doping sources, respectively. Electrical properties and surface morphology of the impurity-doped layers together with their growth condition dependence were investigated. Good controllability and reproducibility of the doping level were confirmed. The maximum doping levels of 1.8×1018 and 1×1019 cm−3 were successfully attained for p-InP and n-InP, respectively. These results promise further safe metalorganic vapor-phase epitaxy by using organic compounds for all precursors.
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  • 67
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 3103-3110 
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    Topics: Physics
    Notes: In a previous report [G. P. Watson, D. G. Ast, T. J. Anderson, and Y. Hayakawa, Appl. Phys. Lett. 58, 2517 (1991)] we demonstrated that the motion of misfit dislocations in InGaAs, grown by organometallic vapor phase epitaxy on patterned GaAs substrates, can be impeded even if the strained epitaxial layer is continuous. Trenches etched into GaAs before growth are known to act as a barrier to misfit dislocation propagation [E. A. Fitzgerald, G. P. Watson, R. E. Proano, D. G. Ast, P. D. Kirchner, G. D. Pettit, and J. M. Woodall, J. Appl. Phys. 65, 2220 (1989)] when those trenches create discontinuities in the epitaxial layers; but even shallow trenches, with continuous strained layers following the surface features, can act as barriers. By considering the strain energy required to change the length of the dislocation glide segments that stretch from the interface to the free surface, a simple model is developed that explains the major features of the unique blocking action observed at the trench edges. The trench wall angle is found to be an important parameter in determining whether or not a trench will block dislocation glide. The predicted blocking angles are consistent with observations made on continuous 300 and 600 nm thick In0.04Ga0.96As films on patterned GaAs. Based on the model, a structure is proposed that may be used as a filter to yield misfit dislocations with identical Burgers vectors or dislocations which slip in only one glide plane.
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  • 68
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 3126-3130 
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    Topics: Physics
    Notes: Near-surface regions of Cd1−xMnxTe and Hg1−xCdxTe epilayers (down to tens of angstroms) on (001) GaAs substrates have been characterized by extremely asymmetric Bragg reflection topography (EABRT) with the laboratory x-ray source condition and a Lang camera, using x-ray grazing incidence angles less than the critical angle for total external reflection. The experimental topographs obtained in the present work illustrate the potential of the EABRT technique for nondestructive characterization of near-surface regions of crystals. The resolution of an image in EABRT is discussed in detail.
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  • 69
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 3144-3149 
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    Topics: Physics
    Notes: The enthalpies of formation of metastable fcc Ag-Cu solid solutions, produced by ball milling of elemental powders, were determined by differential scanning calorimetry. Experimental thermodynamic data for these metastable alloys and for the equilibrium phases are compared with both calculation of phase diagrams (CALPHAD) and atomistic simulation predictions. The atomistic simulations were performed using the free-energy minimization method (FEMM). The FEMM determination of the equilibrium Ag-Cu phase diagram and the enthalpy of formation and lattice parameters of the metastable solid solutions are in good agreement with the experimental measurements. CALPHAD calculations made in the same metastable regime, however, significantly overestimate the enthalpy of formation. Thus, the FEMM is a viable alternative approach for the calculation of thermodynamic properties of equilibrium and metastable phases, provided reliable interatomic potentials are available. The FEMM is also capable of determining such properties as the lattice parameter which are not available from CALPHAD calculations.
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  • 70
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 3150-3155 
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    Topics: Physics
    Notes: The diffusion of δ-function-shaped B- and Sb-dopant spikes in thin Si films grown by solid-phase-epitaxy [(SPE), growth of amorphous film by molecular-beam epitaxy (MBE) at room temperature and subsequent regrowth in situ] during annealing in vacuum is compared to diffusion in films grown by low-temperature (LT) MBE. Diffusion temperatures from 750 to 900 °C, and two-dimensional concentrations of 0.7–1.6×1014 cm−2 have been investigated. The diffusive behavior of dopants in SPE films is found to be qualitatively different from that in films grown by LTMBE. This is related to the vacancylike defects that are intrinsic to growth by SPE but not to growth by LTMBE. Dopant profiles widen significantly during SPE regrowth, making the achievement of δ-function dopant spikes impossible. After a vacuum anneal the diffusion coefficients for both n- and p-type dopants are lower in SPE films than the corresponding values in films grown by LTMBE by up to one order of magnitude. The diffused depth profile of the dopant in LTMBE films shows the characteristic deviation from a pure Gaussian that is expected due to the concentration dependence of diffusion, i.e., a flat top and steep shoulders. In contrast, dopant depth profiles of SPE-grown material show after diffusion a central spike and relatively flat shoulders. The width of the central spike is, after an initial transient that it was not possible to resolve, independent of diffusion time and temperature. This indicates that the SPE material is defective, with the defects acting as traps during diffusion.
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  • 71
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    Journal of Applied Physics 74 (1993), S. 3162-3171 
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    Topics: Physics
    Notes: Ultrathin GaAs wires as thin as 15–40 nm and about 2 μm long have been grown on a GaAs substrate by metal-organic vapor-phase epitaxy. The wires, which consist of whiskers, are grown between 380 and 550 °C using trimethylgallium and arsine (AsH3) as source materials. It is found that the wire growth direction is parallel to the [111] arsenic dangling-bond direction and can be perfectly controlled by the crystallographic orientation of the GaAs substrate surface. From transmission electron microscopic analysis it is revealed that the crystal structure of the wire coincides with the zinc-blende type for the growth temperature range of 460–500 °C, but it changes to the wurtzite type at 420 °C and temperatures higher than 500 °C. It is also found that the wires have a twin-type structure around the [111] growth axis for zinc blende and [0001] growth axis for wurtzite. Photoluminescence study of these wires shows that the luminescence peak energy shifts to a higher energy as the wire width decreases from 100 to about 35 nm. In terms of luminescence polarization it is confirmed that the luminescence intensity parallel to the wires is four times greater than that perpendicular to the wires. These results clearly indicate the quantum-size effect of carriers confined in the wire. As a preliminary application to devices, a p-n junction has been formed along the GaAs wire. Light emission by current injection to the p-n junction wires has been observed in continuous operation at room temperature.
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  • 72
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    Journal of Applied Physics 74 (1993), S. 3181-3188 
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    Topics: Physics
    Notes: The existence of partially correlated roughness in multilayer thin films is demonstrated using x-ray diffraction diffuse-intensity distribution measurements. The method is generally applicable and produces, in addition to values of magnitudes of interfacial roughness and its lateral correlation length, a measure of the cross correlation between interfaces separated by intermediate ones. A simple phenomenological model can describe roughness in W/C multilayers prepared under standard conditions. A cumulative roughness function is used to show that the wavelength range in which the interfacial roughness predominates in these layers lies between 50 A(ring) and 2000 A(ring) and that the long-wavelength roughness replicates better than the short-wavelength roughness.
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  • 73
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 3194-3203 
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    Topics: Physics
    Notes: Film-substrate interactions of YBa2Cu3O7−x (YBCO) thin films grown by pulsed laser deposition on alkaline earth fluoride substrates were investigated. X-ray photoelectron spectroscopy, atomic force microscopy, and x-ray-diffraction measurements showed that the quality of the film and amount of chemical reaction between film and substrate were dependent on the substrate material and deposition temperature. The reaction of YBCO films with CaF2 and MgF2 substrates forms BaF2 and calcium or magnesium oxide species. The reacted film is insulating and has a microscopically rough surface. No reaction was detected in films deposited on BaF2 and SrF2. Physical and thermodynamic properties which may explain the observed order of reactivity are examined.
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  • 74
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    Journal of Applied Physics 74 (1993), S. 3215-3218 
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    Topics: Physics
    Notes: We analyze the role of coherent terahertz radiation on the ultrafast electron dynamics of laser excited photoconductors. Generation of electromagnetic radiation is included within the framework of the usual hot carrier transport theory. A Monte Carlo scheme is used to study the resulting changes in the nonequilibrium electronic energy and transient drift velocity. Our results reveal a density dependent decrease in both quantities, due to reductions in the internal electric fields caused by radiative energy outflow. At densities above 2×1017 cm−3, we obtain a decrease in the transient velocity and expect delays in the onset of phonon emission.
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  • 75
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    Journal of Applied Physics 74 (1993), S. 3219-3223 
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    Notes: The steady state and transient drift velocity of holes in silicon have been investigated using Monte Carlo techniques. The valence band is modeled by warped nonparabolic heavy and light hole bands, and a spherical spin-orbit band. The nonparabolicity of the heavy and light hole bands is included using piecewise continuous functions. The calculated velocities are in better agreement with experimental steady state drift velocity values compared to previous Monte Carlo calculations using only a heavy hole band. Transient calculations show the magnitude of the velocity overshoot for holes is smaller than electrons in silicon but is significantly higher than the steady state drift velocity when high fields are applied.
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  • 76
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    Journal of Applied Physics 74 (1993), S. 7264-7268 
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    Topics: Physics
    Notes: The dc and ac conductivity of single crystal and glass of Li2B4O7 have been measured at various temperatures. It has been shown that these materials are mixed conductors in which electronic and ionic conduction coexist. In the single crystals, both the electronic conduction and ionic conduction along the c axis are much smaller than that perpendicular to the c axis. The anisotropy in the electronic conduction is considered to be due to the conduction by the π electron of the BO3 layer located on the (001) crystallographic plane. The anisotropy in the ionic conduction is also considered to be due to the diffusion of Li ions and/or protons between the BO3 layers. The thermal activation energies of the electronic conduction were 0.65 eV for glass, 1.61 eV for the crystal parallel to the c axis, and 0.78 eV for the crystal perpendicular to the c axis. The activation energy of the ionic conduction was 0.46 eV for the crystal perpendicular to the c axis.
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    Journal of Applied Physics 74 (1993), S. 2968-2970 
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    Topics: Physics
    Notes: It is shown that a combination of low-temperature photoluminescence and luminescence excitation spectroscopies together with appropriate modelization can provide the precise information needed for a thorough control of interdiffusion in quantum well structures. A fit of observed and calculated transition energies up to five energy levels, using the interdiffusion length as a unique parameter, is considered. The potentiality of this procedure to fully characterize the interdiffusion process is illustrated by considering the examples of lightly and heavily intermixed GaAs-AlGaAs multiquantum wells.
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    Journal of Applied Physics 74 (1993), S. 2977-2979 
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    Topics: Physics
    Notes: A photoluminescence study has been made on an oxygen-containing Si fine structure fabricated by a gas evaporation technique. Transmission electron micrographs have shown that the fine structure is composed of nonspherical particles aggregated together in chain-like or cluster-like structures. The luminescence from the samples after oxidation treatment is bright blue as viewed with the naked eye, the spectra having a peak at about 470 nm or shorter wavelength. A peculiar temperature dependence of the emission peak indicates that the emission is strongly correlated with some structural change in the fine structure.
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    Journal of Applied Physics 74 (1993), S. 2983-2985 
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    Topics: Physics
    Notes: Superconducting YBa2Cu3O7−δ thin films with Tc=89.5 K were deposited on MgLaAl11O19 (11¯0) substrates by pulsed laser deposition. X-ray diffraction patterns indicate that the YBa2Cu3O7−δ films were epitaxial films, with the c axis perpendicular to the substrate surfaces. Microstrip resonators of YBa2Cu3O7−δ thin films deposited on MgLaAl11O19 substrates were fabricated. The loaded quality factor of the resonator was 1007 at 77 K and 4.28 GHz. As a new substrate for high Tc oxide superconducting films, MgLaAl11O19 substrates are especially suitable for superconducting-microwave applications.
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    Journal of Applied Physics 74 (1993), S. 1469-1472 
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    Topics: Physics
    Notes: Barrier penetration is attributed to energy fluctuations expected from the uncertainty principle. Numerical simulations are made by calculating the traversal time and action for a large number of possible velocity profiles. Distributions of traversal time are determined by assuming that the probability of each velocity profile decreases exponentially with the action of the fluctuation it requires. Distributions of traversal times are reported for rectangular barriers having different sizes. For large barriers the distributions are leptokurtic and centered at the semiclassical traversal time T0 = d(square root of)m/[2(V0−E)], where d and V0 are the length and height of the barrier and m and E are the mass and energy of the particle. The kurtosis decreases and the mode shifts to shorter durations with decreasing barrier size.
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    Journal of Applied Physics 74 (1993), S. 7306-7310 
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    Topics: Physics
    Notes: We have found that a nonquantizing weakly p-doped InP/Ga0.47In0.53As/InP heterostructure exhibits a photovoltage as high as 2 V at 120 K for moderate light excitation power densities of a few mW/cm2. The back electrical contact is ohmic and the front rectifying contact is established through a thin silver layer. We have monitored as a function of reverse bias applied to the structure the internal photoemission current and also the external photoemission current, due to electrons emitted into vacuum after lowering the surface work function by cesium and oxygen adsorption. Both of these dependences exhibit strong effects of the excitation power density. The dependence of the photovoltage as a function of external bias is obtained using photoreflectance. As shown by a simple model, this gigantic photovoltage arises from accumulation of photoexcited carriers in the Ga0.47In0.53As layer because of the existence of energy barriers with the neighboring InP layers. The different electron and hole transfer probabilities across these barriers result in a strong change of the potential of the Ga0.47In0.53As layer under light excitation.
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    Journal of Applied Physics 74 (1993), S. 7315-7320 
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    Topics: Physics
    Notes: We propose a new method of making heavily doped n-type GaAs to a very shallow depth using sulfur hexafluoride (SF6) plasma treatment of the GaAs surface. Semi-insulating GaAs substrate implanted with Si was exposed to a sulfur containing SF6 plasma and capped with silicon nitride anneal cap. During a subsequent anneal step at an elevated temperature to electrically activate the implanted Si, the sulfur diffused into GaAs to a shallow depth of ∼600 A(ring) resulting in further enhancement of net carrier concentration. With this technique the carrier concentration near the surface region was almost doubled compared to samples with Si implantation only. The enhanced carrier concentration improved the wafer-scale variation of ohmic contact resistance using AuGeNi contact metals from 0.089±0.073 to 0.049±0.017 Ω mm. The surface chemistry of SF6 plasma treated GaAs surface was characterized by x-ray photoelectron spectroscopy and Auger electron spectroscopy, and the results were compared with the carrier-concentration profiles and ohmic contact resistance.
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    Journal of Applied Physics 74 (1993), S. 7329-7339 
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    Topics: Physics
    Notes: Electron coincidence spectroscopy in an ultrahigh vacuum scanning transmission electron microscope has been used to study the generation pathways for secondary (SE) and Auger electrons (AE) excited by high-energy incident electrons. Energy and momentum transfer of inelastically scattered 100 keV primary electrons have been correlated with energy selected SE and AE for both thin 〈111〉 oriented Si crystals and amorphous C films. Coincidence spectra from the valence excitation region indicate that bulk plasmon decay is not the primary production channel for SE in Si(111) and that SE result partially from the decay of ionizations from deep in the valence band. Energy deposition by the primary beam is responsible for SE production at excitation energies above the valence region. At most one SE is emitted from the entrance surface of a thin film for each inelastically scattered 100 keV primary electron. An enhancement in both the SE yield and generation probability is observed at the C K ionization edge. Correlations between energy loss electrons in the vicinity of the C K ionization edge and energy selected SE near the C KLL AE energy show a very sharp threshold in the generation probability. High-momentum transfer (spatially localized) inelastic scattering events are more efficient at creating SE than low-momentum transfer events. The high-spatial resolution obtained in SE images is explained using the Heisenberg uncertainty principle and the scattering angle dependence of the SE generation probability.
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    Journal of Applied Physics 74 (1993), S. 3061-3064 
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    Topics: Physics
    Notes: A steep plasma edge in infrared reflectivity spectra of Hg1−xCdxTe and HgSe:Fe has been observed. It is predicted that the edge is sensitive to the variation of carrier concentration, which indicates the possibility of developing a fast light-controlled switch for infrared radiation as well as a new approach of infrared modulation and detection. The modulation gain in power and detectivity limited by the generation-recombination process has been calculated and compared with the photoconductive counterpart.
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    Journal of Applied Physics 74 (1993), S. 3065-3070 
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    Notes: The transfer of energy between the plasma and the iron anode and the evaporation of metal were taken into account in modeling a short free-burning arc in argon at atmospheric pressure. The presence of metal vapor in the plasma modifies the electrical conductivity and the radiated power and leads to arc cooling in the anode region. In return, the arc cooling modifies the rate of vaporization of the anode and thus the calculated concentration of iron vapor in the arc.
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    Journal of Applied Physics 74 (1993), S. 3080-3083 
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    Notes: Six samples of congruently melting lithium niobate (∼Li0.95Nb1.01O3) have been examined by powder x-ray diffraction for the occurrence of niobium antisite defects (niobium on lithium sites). Contrary to current thinking, we have found no evidence for the occurrence of high concentrations of such defects, which also require the presence of Nb site vacancies. Rather, it was found that the number of antisite defects is close to the minimum that is required to sustain charge neutrality in a model of the type ([Li1−xNbx/5][Nb]O3), where the Nb site is fully occupied.
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    Journal of Applied Physics 74 (1993), S. 3071-3079 
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    Topics: Physics
    Notes: The plasma plume induced by pulsed CO2 laser irradiation of a Ti target at power densities up to 4×108 W cm−2 was studied by emission spectroscopy. Time- and space-resolved measurements were performed by varying laser intensity, laser temporal pulse shape, ambient gas pressure, and the nature of the ambient gas. Experimental results are discussed by comparison with usual models. We show that shock wave and plasma propagation depend critically on the ratio Ivap/Ii, Ivap being the intensity threshold for surface vaporization and Ii the plasma ignition threshold of the ambient gas. Spectroscopic diagnostics of the helium breakdown plasma show maximum values of electron temperature and electron density in the order of kTe∼10 eV and ne=1018 cm−3, respectively. The plasma cannot be described by local thermodynamic equilibrium modeling. Nevertheless, excited metal atoms appear to be in equilibrium with electrons, hence, they can be used like a probe to measure the electron temperature. In order to get information on the role of the plasma in the laser-surface interaction, Ti surfaces were investigated by microscopy after irradiation. Thus an enhanced momentum transfer from the plasma to the target due to the recoil pressure of the breakdown plasma could be evidenced.
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    Journal of Applied Physics 74 (1993), S. 3084-3090 
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    Notes: Crystallization temperatures of a-Si:H films deposited on GaAs substrates by a glow-discharge method increased with an increase in the concentration of As doped into the a-Si:H films. Crystallization of a-Si:H films with an As concentration of 2×1020 cm−3 started at a temperature of about 1050 °C. These a-Si:H films also had a large amounts of H and SiH3.
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    Journal of Applied Physics 74 (1993), S. 3091-3098 
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    Source: AIP Digital Archive
    Topics: Physics
    Notes: The conductivity and the impurity profiles of InP implanted with dopant ions (Si,Be) or non dopant ions (B,H,N,O,P) have been investigated. Experiments have been done in substrates with and without Fe doping. Low-temperature, short-time annealing of implanted Si and Be reveals an n-type distribution of carriers which cannot be accounted for on the basis of implant activation. In order to examine the contribution without the carriers originating from the dopant ions, the behavior of electrically inactive B, H, N, O, and P, implants was investigated. Implantation of these ions into semi-insulating InP introduced n-type doping in the 1×1016 cm3 range after an anneal above 450 °C. For H, O, N, and P ions, the n-type conductivity could be eliminated by annealing at higher temperatures. However, boron anneals up to 750 °C did not eliminate the n-type conductivity. The n-type carrier profiles tracked the ion profiles. The carrier profile is influenced by the redistribution of the Fe during annealing; however, the Fe motion cannot explain the n-type conductivity. This conductivity may be due to a complex formed above 450 °C.
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  • 90
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 3099-3102 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have investigated proton implantation enhanced intermixing of GaAs/AlGaAs quantum wells for H+ doses ranging from 5×1013 to 1×1016 ions/cm2. Implantation of 20 keV H+ followed by a high temperature rapid thermal anneal leads to enhanced diffusion of Al into the GaAs quantum well. Shifts of electron–heavy hole recombination energies due to compositional changes were observed using room temperature cathodoluminescence. Diffusion lengths of longer than 2 nm were calculated from energy shifts in a 5 nm well and were found to vary with both implanted dose and anneal time, as expected if the enhanced interdiffusion is caused by implantation introduced defects.
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  • 91
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 3111-3120 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The influence of various rubbing parameters on the molecular reorientation of thin polyimide orienting layers, used to align liquid-crystal (LC) molecules within liquid-crystal displays, has been studied. For this purpose the optical phase retardation in the polymer layer, explicitly induced during the rubbing treatment, was determined. The observed rubbing-induced phase retardation can directly be related to a molecular orientation within the polymer orienting layer, as could be shown by infrared dichroism studies. Furthermore, it is found that the top of the polymer layer, directly contacting the rubbing cloth during the actual rubbing process, is almost instantaneously oriented to a certain maximum value as soon as the rubbing is started. Additional or stronger rubbing has no detectable influence on the orientation within the top layer. Increasing the rubbing density or the rubbing pressure only results in an increase of the penetration depth of the rubbing process, i.e., molecular reorientation occurs deeper within the layer. Experiments show that the penetration depth can be varied from less than 10 nm to more than 60 nm by variation in rubbing conditions. These findings are supported by surface second-harmonic-generation studies of LC monolayers deposited onto rubbed orienting layers and by infrared dichroism studies.
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  • 92
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 3121-3125 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: This paper illustrates the procedure for extracting structural information available from x-ray diffraction space mapping and topography. The methods of measuring, the residual strain, macroscopic tilts, microscopic tilts and their lateral dimensions, and the strain field disruption emanating from the interfacial defects are presented. Partially relaxed thick InGaAs layers on GaAs substrates were studied and it was concluded that the relaxation and macroscopic tilting were anisotropic, the microscopic tilting reduced with thickness, and the interfacial disruption did not continue to increase with increasing relaxation. A "mosaic grain growth'' model is postulated to account for the diminishing microscopic tilt spread and increasing topographic contrast with layer thickness.
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  • 93
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 1744-1746 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Metal adhesion to polymers depends on the chemical structure at the interface. In the present work, we study the evaporation of Cr, Ti, and Au onto Teflon PFA (perfluoromethyl-vinyl-ether) substrates, and we modify the interface by post-deposition x-ray irradiation. In situ x-ray photoelectron spectroscopy shows that deposition of reactive metals such as Cr and Ti leads immediately to crosslinking and to the formation of carbide and fluoride species. Less reactive metals, such as Au, cause only small loss of fluorine without formation of any new species. The metal/PFA interface is strongly affected by x-ray irradiation in the case of Cr and Ti: remarkably enhanced crosslinking has been observed, which further increases with the metal coverage, while the carbides and fluorides remain basically unaffected. On the other hand, crosslinking increases only very slightly for pure PFA and for the Au/PFA interface, regardless of the Au thickness. These results suggest that radical recombination reactions are responsible for crosslinking at the interface between PFA and reactive metals.
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  • 94
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 1776-1780 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A method for parameter identification in grazing incidence x-ray reflectometry is presented. It is based on a nonlinear least-squares approach with on-line low-pass filtering and fits the measured reflectivity curve as a function of the incidence angle to a simulation model. The filter is applied in the (angular) frequency domain; it introduces, even for strong filtering, no bias and renders the result independent of the angular stepsize of the data. Automatic restarting helps to determine the global solution. The commonly used roughness model is generalized to non-normal distributions in order to assess data with large scattering vectors. The method is demonstrated for data from single and double film samples. Thickness and roughness can be determined with an accuracy of about 0.2 nm. However, only in special cases it is possible to determine accurately materials constants such as compositional fractions or densities. Absorption cannot be neglected, but the corresponding parameters are difficult to determine separately.
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  • 95
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 1770-1775 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The segregation and interdiffusion of In atoms in the GaAs/InAs/GaAs heterostructures were investigated by secondary-ion mass spectroscopy. When the 1-ML-thick InAs layer was grown in a layer-by-layer growth mode with no dislocations, the segregation of In atoms became marked with the increase of the growth temperature. However, the segregation was observed even at a relatively low growth temperature of 400 °C in molecular beam epitaxy. It was found that the segregation was markedly enhanced by dislocations near the heterointerface when thick InAs layers were grown in a three-dimensional island growth mode. The interdiffusion of In atoms toward the growth direction occurred after thermal annealing, which could be assisted by vacancies propagating from the film surface into the epilayer. It became apparent that the interdiffusion was effectively suppressed by a thin AlAs layer inserted in the GaAs cap layer.
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  • 96
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 1818-1821 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The results of an ensemble Monte Carlo simulation of the electron transport in gallium nitride (GaN) are presented. The calculation shows that intervalley electron transfer plays a dominant role in GaN in high electric fields leading to a strongly inverted electron distribution and to a large negative differential conductance. An analytic expression for the polar optical momentum relaxation time for phonon energies larger than the thermal energy is also derived. This expression applies to many wide-gap semiconductors, such as GaN and SiC, at room temperature since these semiconductors have large polar optical-phonon energies (on the order of 100 meV). The calculated mobility agrees well with the results of the Monte Carlo calculation.
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  • 97
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 1822-1825 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We present a theoretical investigation of the growth orientation dependence of valence-subband structures in ZnSxSe1−x/ZnyMg1−ySzSe1−z quantum wells grown in the [001], [115], [113], [112], and [111] directions. The results indicate that the in-plane effective mass of the heavy-hole subband in the [111]-oriented structure is substantially smaller than that in the [001] quantum wells. For applications to quantum-well lasers, the lighter effective mass will lead to a smaller threshold current density, and therefore a better laser performance. Our investigations should provide useful guidelines for the design of II-VI quantum-well blue lasers.
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  • 98
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 1832-1837 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We present a detailed analysis of the electronic carrier transport in silicon when subject to a nonuniform stress distribution. Such a distribution gives rise to two independent current components which can be viewed in terms of carrier generation-recombination. One component arises as a result of the nonuniform stress induced position dependent density of states, and the other due to stress induced shifts in the band edges. The various parameters and coefficients describing these phenomena are presented.
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  • 99
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 1862-1867 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The defect energy levels in metalorganic chemical vapor deposition (MOCVD) grown GaxIn1−xP/InP:Fe and GaxIn1−xP/InP:S epilayers (x≤0.24) have been studied by photoluminescence (PL) and photoconductivity (PC) measurements. To understand the origin of the observed deep levels, we have determined the temperature dependence of the intensity and half-width of the dominant deep-level PL peaks. We find that (1) the dominant deep-level peaks of the samples grown on the same substrate are related to the epilayer composition, and move to higher energies with increasing gallium content; (2) the dominant deep-level peaks of the samples with the same epilayer composition grown on different substrates are different. They are attributed to the impurity in the substrate diffusing into the epilayer during MOCVD growth, forming an impurity-vacancy complex. The following tentative assignments are proposed: the dominant deep-level peaks in GaxIn1−xP/InP:Fe and GaxIn1−xP/InP:S are attributed to the emission of a (V)P-(Fe)III complex and a (V)III-(S)P complex, respectively. Comparing the deep level with the near-band-edge emission we show that (1) all deep levels are independent of the band edge as x is varied; (2) the composition dependences of the deep levels associated with such complexes depend on the site occupied by the impurity atom.
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  • 100
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 1868-1873 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The in-well ambipolar diffusion coefficients and carrier lifetimes in ordered all-binary quantum wells, composed of (InAs)2(GaAs)5 short-period strained-layer superlattices (SPSLSs) grown on [001]-oriented GaAs substrates, are measured using picosecond optically induced transient grating and pump-probe techniques. Quantum wells containing SPSLSs may be expected to exhibit higher in-plane hole mobilities compared to InGaAs ternary alloy quantum wells because of a larger average indium content and reduced disorder scattering in the SPSLS structures. The results obtained in the SPSLSs are compared to those obtained in InGaAs alloy quantum wells of comparable well width and confinement energies. This indicates that, for a given SPSLS and its equivalent alloy, the ambipolar diffusion coefficients are comparable while the carrier lifetimes in the SPSLSs are longer. The longer carrier lifetimes in the SPSLSs suggest that these binary structures possess fewer nonradiative recombination centers than the alloys. The absence of a dramatic improvement in the transport properties, however, may indicate that imperfect interfaces in the SPSLSs may be offsetting their possible advantages, in spite of the fact that optical measurements in the SPSLSs indicate high quality and x-ray and transmission electron microscopic measurements demonstrate the binary nature of these structures.
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