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  • 1
    Publication Date: 2024-04-20
    Description: This dataset includes a global compilation of new and published 14C measurements of benthic foraminifera and deep-sea corals (from 0-to 49872 years BP). We synthesized this new dataset into basin-average 14C ventilation age values over the 25,000 years, along density surfaces associated with the upper and lower cells of global ocean overturning circulation (27.5 and 28 kg m^-3, respectively). The published datasets are from all ocean basins, even those not utilized in our synthesis. We also provide the basin-average estimates for the Atlantic, Southern, and Pacific Oceans as produced by the Rafter et al. 2022 study.
    Keywords: 0050PG; 0066PG; 145-883; 145-887; 146-893A; 167-1019A; 202-1240; 202-1242A; 341-U1419; 35MF20120125, OISO_21, INDIEN SUD 2; 47396B; 50-37KL; 64-480; 90b; AII125-8-55; AII125-8-56; Akademik M.A. Lavrentiev; ALV-3887-1549-004-007; ALV-3887-1549-004-009; ALV-3887-1549-004-012; ALV-3890-1407-003-001; ALV-3891-1459-003-002; ALV-3891-1758-006-003; AMOCINT, IMAGES XVII; ANT-XI/4; ANT-XXIII/9; ANT-XXVI/2; Argentine Basin; ARK-II/5; ARK-X/2; Azores; B34-91; BC; Bering Sea; Binary Object; BO04-PC11; Box corer; Brazil Basin; Burdwood_Bank; CALYPSO; CALYPSO2; Calypso Corer; Calypso Corer II; Calypso square corer; Calypso Square Core System; Canarias Sea; Cape_Horn; Caribbean Sea; CASQ; CASQS; CD159; CD159-10; CD159-15; CD159-17; CD38-17P; Celtic Sea; Cenderawasih Bay; Central Pacific; CH84-14; Charles Darwin; CHAT_10k; CHAT_16k; CHAT-3K; CHAT-5K; Chatham Rise; COMPCORE; Composite Core; Conrad Rise; Core; CORE; Core1471; Core2088; Core21210009; Core2307; Core2631; Core2657; Core2706; Core2774; Core47396; Core654; Core660; Core936; Corner Rise; Denmark Strait; Drake Passage; DRILL; Drilling/drill rig; Eastern Equatorial Pacific; Eastern slope of Kurile Basin; East Pacific; Emperor Seamounts; EN06601; EN066-39GGC; Endeavor; Equatorial East Pacific; ESTASE1; EW0408; EW0408-26JC; EW0408-85JC; EW0408-87JC; Exp341; F2-92-P3; F8-90-G21; File content; Galapagos; Galápagos Islands; GC; GC_POI; GeoB1503-1; GeoB2104-3; GeoB7149-2; GeoB7162-6; GeoB7163-7; GeoB7167-6; GGC; GGC5; gh02-1030; Giant box corer; Giant gravity corer; Giant piston corer; GIK17940-1; GIK23243-2 PS05/431; GKG; Glomar Challenger; GPC; Gravity corer; Gravity corer (Kiel type); Gravity corer (POI); GS07-150-17/1GC-A; GS07-150-20/2A; Gulf of Alaska; Gulf of California; H209; H213; HH12-946MC; HU72-021-7; HU89038-8PC; IMAGES III - IPHIS; IMAGES IV-IPHIS III; IMAGES V; IMAGES VIII - MONA; IMAGES VII - WEPAMA; IMAGES XII - MARCO POLO; IMAGES XV - Pachiderme; Indian Ocean; INOPEX; Interim_Seamount; Japan Trench; Jean Charcot; JM-FI-19PC; Joides Resolution; JPC; JPC30; JT96-09; JT96-09PC; Jumbo Piston Core; KAL; KALMAR II; Kasten corer; KL; KN_USA; KN11002; KN159-5; Knorr; KNR073-04-003; KNR110-50; KNR110-66; KNR110-82a; KNR110-82GGC; KNR140; KNR140-01JPC; KNR140-02JPC; KNR140-12JPC; KNR140-2-12JPC; KNR140-2-22JPC; KNR140-22JPC; KNR140-2-30GGC; KNR140-2-51GGC; KNR140-26GGC; KNR140-30GGC; KNR140-37JPC; KNR140-39GGC; KNR140-43GGC; KNR140-50GGC; KNR140-51GGC; KNR140-56GGC; KNR140-66GGC; KNR159-5; KNR159-5-36GGC; KNR159-5-78GGC; KNR176-17GC; KNR178-2GC; KNR178-JPC32; KNR195-5-CDH23; KNR195-5-CDH26; KNR195-5-CDH41; KNR195-5-GGC43; KNR197-10; KNR197-10CDH42; KNR197-10-CDH42; KNR197-10-CDH46; KNR197-10-GGC17; KNR197-10-GGC36; KNR197-10-GGC5; KNR198-CDH36; KNR198-GGC15; KNR31GPC5; KNR733P; KNR734P; KNR736P; KOL; KOMEX; KOMEX II; KR02-15-PC06; Kronotsky Peninsula; KT89-18-P4; Lakshadweep Sea; Laurentian fan; Leg145; Leg146; Leg167; Leg202; Leg64; Le Suroît; LPAZ21P; LV27/GREGORY; LV27-2-4; LV29-114-3; LV29-2; M16/2; M23/2; Marion Dufresne (1972); Marion Dufresne (1995); Maurice Ewing; Mazatlan; MCSEIS; MD012378; MD01-2378; MD012386; MD01-2386; MD012416; MD01-2416; MD012420; MD01-2420; MD022489; MD02-2489; MD022519; MD02-2519; MD03-2697; MD03-2707; MD052896; MD05-2896; MD052904; MD05-2904; MD07-3076; MD07-3076Q; MD07-3088; MD08-3169; MD08-3180; MD09-3256; MD09-3256Q; MD09-3257; MD106; MD111; MD114; MD122; MD12-3396Cq; MD126; MD13; MD134; MD147; MD159; MD168; MD173; MD189; MD77-176; MD972106; MD97-2106; MD972120; MD97-2120; MD972121; MD97-2121; MD972138; MD97-2138; MD982165; MD98-2165; MD982181; MD98-2181; MD99-2334; ME0005A; ME0005A-24JC; ME0005A-43JC; Melville; Meteor (1986); ML1208-01PC; MONITOR MONSUN; MR01-K03; MR06-04_PC04A; MUC; Multichannel seismics; MultiCorer; MV99-GC38; MV99-MC17/GC32/PC10; MV99-MC19/GC31/PC08; NEMO; Nesmeyanov25-1-GGC15; Nesmeyanov25-1-GGC18; Nesmeyanov25-1-GGC20; Nesmeyanov25-1-GGC27; New_England_Seamounts; North Atlantic; North Greenland Sea; North Pacific/Gulf of California/BASIN; North Pacific Ocean; Norwegian Sea; OCE326-GGC14; OCE326-GGC26; OCE326-GGC5; off Chile; off Nova Scotia; OSIRIS III; Pacific Ocean; PALEOCINAT; PC; Philippine Sea; PICABIA; Piston corer; Piston corer (BGR type); Piston corer (Kiel type); PLDS-007G; PLDS-1; Pleiades; Polarstern; PS05; PS1243-2; PS2606-6; PS2644-2; PS30; PS30/144; PS31; PS31/160; PS69; PS69/907-2; PS69/912-3; PS69/912-4; PS75/059-2; PS75/100-4; PS75/104-1; PS75 BIPOMAC; PUCK; RAPiD-10-1P; RAPiD-15-4P; RAPiD-17-5P; RBDASS05; RC24; RC24-8GC; RC27; RC27-14; RC27-23; Remote operated vehicle; RETRO-2; RNDB-GGC15; RNDB-GGC5; RNDB-PC11; RNDB-PC13; Robert Conrad; ROV; RR0503-36JPC; RR0503-41JPC; RR0503-64JPC; RR0503-79JPC; RR0503-831C; RR0503-83GC; S67-FFC15; S794; S931; Sakhalin shelf and slope; Sars_Seamount; Scotia Sea; Sea of Okhotsk; SEDCO; Sediment corer; Shackleton_Fracture_Zone; SHAK03-6K; SHAK05-3K; SHAK06-4K; SHAK06-5K; SHAK10-10K; SHAK14-4G; Shirshov Ridge; SK129-CR2; SL; Smithsonian_48735.1; SO156/2; SO156/3; SO161/3; SO161/3_22; SO178; SO178-13-6; SO201/2; SO201-2-101; SO201-2-12KL; SO201-2-77; SO201-2-85; SO202/1; SO202/1_18-6; SO213/2; SO213/2_76-2; SO213/2_79-2; SO213/2_82-1; SO213/2_84-1; SO95; Sonne; SOPATRA; South Atlantic; South Atlantic Ocean; South China Sea; Southern Alaska Margin: Tectonics, Climate and Sedimentation; South of Iceland; South Pacific Ocean; South Tasman Rise; Southwest Pacific Ocean; SPOC; Station 6, MD189-3396; SU90-08; Thomas G. Thompson (1964); Thomas Washington; Timor Sea; TNO57-21; TR163-22; TR163-23; TR163-31; TT154-10; TTN13-18; TTXXX; U938; V34; V34-98; V35; V35-5; V35-6; Vema; Vigo; VINO19-4-GGC17; VINO19-4-GGC37; VM21-29; VM21-30; VM23-81; VM28-122; VM28-238; VNTR01; VNTR01-10GC; W8709A; W8709A-13; Wecoma
    Type: Dataset
    Format: text/tab-separated-values, 8 data points
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  • 2
    Publication Date: 2022-10-07
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Pasquier, B., Hines, S. K., Liang, H., Wu, Y., Goldstein, S. L., & John, S. G. GNOM v1.0: an optimized steady-state model of the modern marine neodymium cycle. Geoscientific Model Development, 15(11), (2022): 4625–4656. https://doi.org/10.5194/gmd-15-4625-2022.
    Description: Spatially distant sources of neodymium (Nd) to the ocean that carry different isotopic signatures (εNd) have been shown to trace out major water masses and have thus been extensively used to study large-scale features of the ocean circulation both past and current. While the global marine Nd cycle is qualitatively well understood, a complete quantitative determination of all its components and mechanisms, such as the magnitude of its sources and the paradoxical conservative behavior of εNd, remains elusive. To make sense of the increasing collection of observational Nd and εNd data, in this model description paper we present and describe the Global Neodymium Ocean Model (GNOM) v1.0, the first inverse model of the global marine biogeochemical cycle of Nd. The GNOM is embedded in a data-constrained steady-state circulation that affords spectacular computational efficiency, which we leverage to perform systematic objective optimization, allowing us to make preliminary estimates of biogeochemical parameters. Owing to its matrix representation, the GNOM model is additionally amenable to novel diagnostics that allow us to investigate open questions about the Nd cycle with unprecedented accuracy. This model is open-source and freely accessible, is written in Julia, and its code is easily understandable and modifiable for further community developments, refinements, and experiments.
    Description: This work has been supported by the Simons Foundation (grant no. 426570SP to Seth G. John), the National Science Foundation (grant no. OCE-1736896 to Seth G. John and grant no. OCE-1831415 to Steven L. Goldstein and Sophia K. V. Hines), the Investment in Science Fund at WHOI and the John E. and Anne W. Sawyer Endowed Fund in Support of Scientific Staff (Sophia K. V. Hines), and the Storke Endowment of the Department of Earth and Environmental Sciences, Columbia University (Steven L. Goldstein).
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 3
    Publication Date: 2022-10-12
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Struve, T., Wilson, D., Hines, S., Adkins, J., & van de Flierdt, T. A deep Tasman outflow of Pacific waters during the last glacial period. Nature Communications, 13(1), (2022): 3763, https://doi.org/10.1038/s41467-022-31116-7.
    Description: The interoceanic exchange of water masses is modulated by flow through key oceanic choke points in the Drake Passage, the Indonesian Seas, south of Africa, and south of Tasmania. Here, we use the neodymium isotope signature (εNd) of cold-water coral skeletons from intermediate depths (1460‒1689 m) to trace circulation changes south of Tasmania during the last glacial period. The key feature of our dataset is a long-term trend towards radiogenic εNd values of ~−4.6 during the Last Glacial Maximum and Heinrich Stadial 1, which are clearly distinct from contemporaneous Southern Ocean εNd of ~−7. When combined with previously published radiocarbon data from the same corals, our results indicate that a unique radiogenic and young water mass was present during this time. This scenario can be explained by a more vigorous Pacific overturning circulation that supported a deeper outflow of Pacific waters, including North Pacific Intermediate Water, through the Tasman Sea.
    Description: The authors acknowledge financial support from the Grantham Institute of Climate Change and the Environment (T.v.d.F. and T.S.), the Ministry for Science and Culture of the State of Lower Saxony (T.S.), Marie Curie Reintegration grant IRG 230828 (T.v.d.F.), Leverhulme Trust grant RPG-398 (T.v.d.F.), Natural Environment Research Council grants NE/F016751/1 (T.v.d.F.), NE/N001141/1 (T.v.d.F. and D.J.W.), and NE/T011440/1 (D.J.W.), and National Science Foundation grant OCE-1503129 (J.F.A. and S.K.V.H.). Open Access funding is enabled by the DFG open access publication fund and the Carl von Ossietzky University Oldenburg.
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 4
    Publication Date: 2022-05-27
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Hines, S. K. V., Bolge, L., Goldstein, S. L., Charles, C. D., Hall, I. R., & Hemming, S. R. Little change in ice age water mass structure from Cape Basin benthic neodymium and carbon isotopes. Paleoceanography and Paleoclimatology, 36(11), (2021): e2021PA004281, https://doi.org/10.1029/2021PA004281.
    Description: A common conception of the deep ocean during ice age episodes is that the upper circulation cell in the Atlantic was shoaled at the Last Glacial Maximum compared to today, and that this configuration facilitated enhanced carbon storage in the deep ocean, contributing to glacial CO2 draw-down. Here, we test this notion in the far South Atlantic, investigating changes in glacial circulation structure using paired neodymium and benthic carbon isotope measurements from International Ocean Discovery Program Site U1479, at 2,615 m water depth in the Cape Basin. We infer changes in circulation structure across the last glacial cycle by aligning our site with other existing carbon and neodymium isotope records from the Cape Basin, examining vertical isotope gradients, while determining the relative timing of inferred circulation changes at different depths. We find that Site U1479 had the most negative neodymium isotopic composition across the last glacial cycle among the analyzed sites, indicating that this depth was most strongly influenced by North Atlantic Deep Water (NADW) in both interglacial and glacial intervals. This observation precludes a hypothesized dramatic shoaling of NADW above ∼2,000 m. Our evidence, however, indicates greater stratification between mid-depth and abyssal sites throughout the last glacial cycle, conditions that developed in Marine Isotope Stage 5. These conditions still may have contributed to glacial carbon storage in the deep ocean, despite little change in the mid-depth ocean structure.
    Description: This work was supported by NSF grant OCE-1831415 (S. K. V. Hines, S. L. Goldstein., S. R. Hemming.).
    Description: 2022-04-25
    Keywords: Ocean circulation ; Neodymium isotopes ; Carbon isotopes
    Repository Name: Woods Hole Open Access Server
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  • 5
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 17 (2016): 232–240, doi:10.1002/2015GC006130.
    Description: Isotopes of the actinide elements protactinium (Pa), thorium (Th), and uranium (U), and the lanthanide element neodymium (Nd) are often used as complementary tracers of modern and past oceanic processes. The extraction of such elements from low abundance matrices, such as seawater and carbonate, is however labor-intensive and requires significant amounts of sample material. We here present a combined method for the extraction of Pa, Th, and Nd from 5 to 10 L seawater samples, and of U, Th, and Nd from 〈1 g carbonate samples. Neodymium is collected in the respective wash fractions of Pa-Th and U-Th anion exchange chromatographies. Regardless of the original sample matrix, Nd is extracted during a two-stage ion chromatography, followed by thermal ionization mass spectrometry (TIMS) analysis as NdO+. Using this combined procedure, we obtained results for Nd isotopic compositions on two GEOTRACES consensus samples from Bermuda Atlantic Time Series (BATS), which are within error identical to results for separately sampled and processed dedicated Nd samples (εNd = −9.20 ± 0.21 and −13.11 ± 0.21 for 15 and 2000 m water depths, respectively; intercalibration results from 14 laboratories: εNd = −9.19 ± 0.57 and −13.14 ± 0.57). Furthermore, Nd isotope results for an in-house coral reference material are identical within analytical uncertainty for dedicated Nd chemistry and after collection of Nd from U-Th anion exchange chromatography. Our procedure does not require major adaptations to independently used ion exchange chromatographies for U-Pa-Th and Nd, and can hence be readily implemented for a wide range of applications.
    Description: Funding that supported this work was received from the National Science Foundation (NSF 0752402), the Leverhulme Trust (RPG-398), the Natural Environmental Research Council (NE/J021636/1 and NE/N003861/1), the European Research Council (278705), and the Grantham Institute for Climate Change.
    Description: 2016-07-09
    Keywords: Deep-sea corals ; Seawater ; GEOTRACES ; Extraction methods ; Neodymium isotopes
    Repository Name: Woods Hole Open Access Server
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  • 6
    Publication Date: 2023-02-01
    Description: Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 35(17), (2022): 5465-5482, https://doi.org/10.1175/jcli-d-21-0671.1.
    Description: Understanding the contribution of ocean circulation to glacial–interglacial climate change is a major focus of paleoceanography. Specifically, many have tried to determine whether the volumes and depths of Antarctic- and North Atlantic–sourced waters in the deep ocean changed at the Last Glacial Maximum (LGM; ∼22–18 kyr BP) when atmospheric pCO2 concentrations were 100 ppm lower than the preindustrial. Measurements of sedimentary geochemical proxies are the primary way that these deep ocean structural changes have been reconstructed. However, the main proxies used to reconstruct LGM Atlantic water mass geometry provide conflicting results as to whether North Atlantic–sourced waters shoaled during the LGM. Despite this, a number of idealized modeling studies have been advanced to describe the physical processes resulting in shoaled North Atlantic waters. This paper aims to critically assess the approaches used to determine LGM Atlantic circulation geometry and lay out best practices for future work. We first compile existing proxy data and paleoclimate model output to deduce the processes responsible for setting the ocean distributions of geochemical proxies in the LGM Atlantic Ocean. We highlight how small-scale mixing processes in the ocean interior can decouple tracer distributions from the large-scale circulation, complicating the straightforward interpretation of geochemical tracers as proxies for water mass structure. Finally, we outline promising paths toward ascertaining the LGM circulation structure more clearly and deeply.
    Description: S.K.H. was supported by the Investment in Science Fund at WHOI and the John E. and Anne W. Sawyer Endowed Fund in Support of Scientific Staff. F.J.P. was supported by a Stanback Postdoctoral Fellowship at Caltech.
    Description: 2023-02-01
    Keywords: Diapycnal mixing ; Meridional overturning circulation ; Ocean circulation
    Repository Name: Woods Hole Open Access Server
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  • 7
    Publication Date: 2017-03-15
    Description: The Southern Ocean regulates the ocean’s biological sequestration of CO2 and is widely suspected to underpin much of the ice age decline in atmospheric CO2 concentration, but the specific changes in the region are debated. Although more complete drawdown of surface nutrients by phytoplankton during the ice ages is supported by some sediment core-based measurements, the use of different proxies in different regions has precluded a unified view of Southern Ocean biogeochemical change. Here, we report measurements of the 15N/14N of fossil-bound organic matter in the stony deep-sea coral Desmophyllum dianthus, a tool for reconstructing surface ocean nutrient conditions. The central robust observation is of higher 15N/14N across the Southern Ocean during the Last Glacial Maximum (LGM), 18–25 thousand years ago. These data suggest a reduced summer surface nitrate concentration in both the Antarctic and Subantarctic Zones during the LGM, with little surface nitrate transport between them. After the ice age, the increase in Antarctic surface nitrate occurred through the deglaciation and continued in the Holocene. The rise in Subantarctic surface nitrate appears to have had both early deglacial and late deglacial/Holocene components, preliminarily attributed to the end of Subantarctic iron fertilization and increasing nitrate input from the surface Antarctic Zone, respectively.
    Print ISSN: 0027-8424
    Electronic ISSN: 1091-6490
    Topics: Biology , Medicine , Natural Sciences in General
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  • 8
    Publication Date: 2019-07-01
    Print ISSN: 2572-4517
    Electronic ISSN: 2572-4525
    Topics: Geosciences
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  • 9
    Publication Date: 2013-01-01
    Description: We have developed a simple, rapid method to screen carbonates for survey applications, which provides radiocarbon dates with decreased precision at lower cost. The method is based on previous work by Longworth et al. (2011) and involves mixing pulverized CaCO3 with Fe powder, followed by pressing into aluminum target holders for direct 14C accelerator mass spectrometry (AMS) measurements. An optimum beam current averaging ∼10% of those produced by 〉0.7 mg C graphite targets was obtained for carbonate samples of 0.3–0.5 mg (0.04–0.06 mg C). The precision of the method was evaluated by measuring triplicates of 14C reference materials, as well as by comparing results from this rapid method with results from high-precision AMS measurements on graphite (typically 0.2–0.3%). Measurement reproducibility was ∼1.8% (1σ) for samples
    Print ISSN: 0033-8222
    Electronic ISSN: 1945-5755
    Topics: Archaeology , Energy, Environment Protection, Nuclear Power Engineering , Geosciences
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  • 10
    Publication Date: 2016-01-01
    Description: Isotopes of the actinide elements protactinium (Pa), thorium (Th), and uranium (U), and the lanthanide element neodymium (Nd) are often used as complementary tracers of modern and past oceanic processes. The extraction of such elements from low abundance matrices, such as seawater and carbonate, is however labor-intensive and requires significant amounts of sample material. We here present a combined method for the extraction of Pa, Th, and Nd from 5 to 10 L seawater samples, and of U, Th, and Nd from 〈1 g carbonate samples. Neodymium is collected in the respective wash fractions of Pa-Th and U-Th anion exchange chromatographies. Regardless of the original sample matrix, Nd is extracted during a two-stage ion chromatography, followed by thermal ionization mass spectrometry (TIMS) analysis as NdO+. Using this combined procedure, we obtained results for Nd isotopic compositions on two GEOTRACES consensus samples from Bermuda Atlantic Time Series (BATS), which are within error identical to results for separately sampled and processed dedicated Nd samples (εNd =-9.20 ± 0.21 and-13.11 ± 0.21 for 15 and 2000 m water depths, respectively; intercalibration results from 14 laboratories: εNd =-9.19 ± 0.57 and-13.14 ± 0.57). Furthermore, Nd isotope results for an in-house coral reference material are identical within analytical uncertainty for dedicated Nd chemistry and after collection of Nd from U-Th anion exchange chromatography. Our procedure does not require major adaptations to independently used ion exchange chromatographies for U-Pa-Th and Nd, and can hence be readily implemented for a wide range of applications. © 2015. American Geophysical Union. All Rights Reserved.
    Electronic ISSN: 1525-2027
    Topics: Chemistry and Pharmacology , Geosciences , Physics
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