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  • Inorganic Chemistry  (3,258)
  • Aerodynamics  (145)
  • Fisheries
  • Seismology
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  • 1950-1954  (1,752)
  • 1940-1944  (1,719)
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  • 1
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    The International Collective in Support of Fishworkers (ICSF) | India
    Publication Date: 2022-02-21
    Description: Yemaya No. 63, dated May 2021, features articles from US, The Netherlands, Myanmar, Senegal, and an article on women in fisheries and human rights. The article from the US by Linda Behnken argues that a growing coalition of small-scale, community-based fishers is calling for the recognition and protection of Alaska’s invaluable coastal fisheries during COVID-19. The article from the Netherlands by Cornelie Quist looks at the challenges facing women engaged in small-scale fishing and supplying fish through retailers and how they found new ways to directly reach consumers. The conversation between Miranda Bout and Cornelie Quist focuses on how they combined new product development with the use of social media to contact their customer base during the pandemic-induced disruption of traditional marketing chains. The article by Elena Finkbeiner, Juno Fitzpatrick and Whitney Yadao-Evans looks at recent media revelations and scientific research that have brought increased attention to human-rights violations and the myriad social issues facing fisheries, but with a disproportionate focus on labour-rights violations at sea and in industrial fishing operations. The systemic inequalities combined with the effects of COVID-19 exacerbated vulnerabilities of women to health risks, food and livelihood security. The article from Senegal by Aby Dia from Lumière Synergie pour le Développement (LSD), in collaboration with WoMin African Alliance, South Africa, narrates the story of traditional women fish processors from the Bargny who have been, for more than a decade, struggling against development projects that jeopardise their environment, health and livelihoods. In order to preserve their livelihoods, women processors in Senegal have come together to oppose the Tosyali steel project. The European Network of Women in Fisheries and Aquaculture in Europe (AKTEA) urges the Office of the Commissioner for the Environment, Oceans and Fisheries to integrate gender into all aspects of European fishing policy. The Profile column looks at how Linda Behnken became a fisher in Alaska and how fishing has shaped her individuality and work. Natalie Sattler says that fishing for halibut, sablefish and salmon from the sparkling waters of the Pacific along with her children and at the same time passion for working with the Alaska Longline Fishermen’s Association and the Alaska Sustainable Fisheries Trust is an immense challenge.
    Description: Published
    Description: Refereed
    Keywords: Fishing Communities ; Women in fisheries ; Gender ; Small-scale fisheries ; Aquaculture ; Fisheries
    Repository Name: AquaDocs
    Type: Book/Monograph/Conference Proceedings
    Format: 12p.
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  • 2
    Publication Date: 2022-11-18
    Description: Seismology and Earthquake Engineering Research Infrastructure Alliance for Europe (SERA), H2020, grant agreements 730900.
    Description: Published
    Description: 2T. Deformazione crostale attiva
    Description: 6T. Studi di pericolosità sismica e da maremoto
    Description: 4IT. Banche dati
    Keywords: Geology ; Earth sciences of Europe ; Earth sciences of Africa ; Earth sciences of Asia ; Earth Sciences and Geology ; earthquakes ; hazard model ; seismogenic faults ; slip rate ; crustal fault sources ; subduction fault sources ; Seismology ; 04.04. Geology ; 04.06. Seismology ; 04.07. Tectonophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: web product
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  • 3
    Publication Date: 2022-06-28
    Description: Las pesquerías basadas en las agregaciones reproductivas pueden amenazar a especies como los pargos que tienen conductas gregarias durante el período reproductivo. Esta nota ofrece elementos que sugieren la existencia de sitios de agregación no registrados previamente y no protegidos en el Parque Nacional Cayos de San Felipe (PNCSF), región suroccidental de Cuba. La información tradicional obtenida de pescadores locales y trabajadores del parque se corroboró con muestreos cualitativos y cuantitativos de peces de arrecifes y datos de pesquerías locales del 2014. En la época de reproducción de pargos (mayo a julio) se observaron grupos de entre 40-100 ejemplares de Lutjanus cyanopterus, Lutjanus synagris y Lutjanus jocu en los arrecifes de la zona occidental del PNCSF (camellones entre 15-30 m de profundidad cerca del borde de la plataforma). Dentro de esa área, se señalan dos sitios que parecen ser utilizados para agregaciones de predesove, por lo que requieren protección y ser estudiados. Los censos cuantitativos confirmaron que en mayo y junio la zona occidental tiene densidad alta de pargos adultos. También, el pico de captura de estas especies ocurrió en la época reproductiva. Se comprobó que las pesquerías se realizaron durante las migraciones de peces hacia el borde de la plataforma en áreas de la zona occidental del PNCSF, y que más del 60% de los individuos tuvieron gónadas maduras (antes de desovar). Esta información debe incentivar el estudio de las agregaciones de desove en esta región de Cuba, la protección de especies amenazadas y áreas de alta significación ecológica y la implementación de pesquerías sostenibles.
    Description: Fisheries based on reproductive aggregations can threaten species such as snappers that have gregarious behavior during the reproductive period. This note provides evidence to support the existence of aggregation sites, not previously registered and unprotected, in the National Park San Felipe Keys (NPSFK), southwestern region of Cuba. Traditionalinformation obtained from local fishermen and from the park staff was complemented with qualitative and quantitative fish reef censuses and local fisheries data in 2014. In the reproductive season of snappers (May to July) groups of between 40-100 specimens of Lutjanus cyanopterus, Lutja- nus synagris and Lutjanus jocu were observed in the western area of the NPSFK on the reefs (spoor and grove between 20-30 m deep close to the platform edge). Within that area two sites are indicated that can be used for prespawning aggregation, so they require protection and study. Quanti- tative censuses confirmed that in May and June the western zone has high density of adult snappers. Also, the peak of capture of these snapper species occurred in the reproduc- tive season. It was found that fisheries carried out during fish migrations to the edge of the shelf in areas of the western area of the NPSFK and more than 60% of the individuals had mature gonads (before spawning). This information should promote the study of spawning aggregations in this region of Cuba, the protection of threatened species and areas of high ecological significance and the implementation of sustainable fisheries.
    Description: Published
    Description: Refereed
    Keywords: Región suroccidental de Cuba ; Desove ; Pesquerías ; Migration routes ; Spawning ; Fisheries ; Rutas migraciones
    Repository Name: AquaDocs
    Type: Journal Contribution
    Format: pp.54-65
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  • 4
    Publication Date: 2022-09-14
    Description: The ICES Workshop on ICES reference points (WKREF2) was tasked review the WKREF1 report and based on the outcome develop updated guidelines for the ICES reference points system and recommendations for ACOM consideration. The WKREF1 report has suggested 5 key recom- mendations to simplify and harmonise the ICES reference points framework representing a ma- jor change to the current guidelines. At WKREF2, we detailed discussions and four key concerns were raised about the proposed approach. The first related to the simplification of rules to define Blim. Around two thirds of category 1 stocks would end up as WKREF1 “Blim Type 2” where Blim would be set as a fraction of B0. The Allee effect or “depensation” maybe more important than previously thought and should be furthered explored for ICES stocks since it has important consequences for Blim. A number of challenges and issues around defining Blim using the current guidelines were documented. Some suggestions on improvement criteria were discussed including using classifiers to define spas- modic stocks and using change point algorithms to address non-stationary productivity regimes. However, further work is need to make these approaches operational and there was no consen- sus that the WKREF1 Blim types should replace the current guidelines. WKREF1 recommended that the FMSY proxy should be based on a biological proxies and should be less than the deterministic FMSY. It was pointed out that the stochastic FMSY estimated in EqSim for example, is lower than the deterministic FMSY and that the current guidelines ensure that the FMSY should not pose a more than 5% risk to Blim. A large amount of work described in WD 1 was carried out to develop an MSE framework to consistency and robustness test a candidate refer- ence point system for North East Atlantic stocks. However, WKREF2 recommended that further work needs to be carried out to condition and test the simulation framework before the conclu- sions could be adopted by ICES and incorporated into the guidelines. A number of considerations for defining MSY related reference points were discussed including using model validation and prediction skill to ensure that ICES provide robust and credible ad- vice. There is evidence that density dependence (DD) is important in the majority of ICES stocks (68% in recruitment and 54% in growth). The correct prediction of the shape and strength of density-dependence in productivity is key to predicting future stock development and providing the best possible long-term fisheries management advice. A suggested approach to use surplus production models (SPMs) to account for DD in FMSY was suggested and discussed but there was no consensus on whether that approach was appropriate. There was consensus that the FECO approach as a means of adapting target fishing mortality to medium-term changes in productiv- ity should be included in the guidelines subject to a benchmark and ACOM approval. While WKREF1 and 2 focused mainly on Category 1 stocks ToR c) called for a “simplified and harmonised set of guidelines for estimating MSY and precautionary reference points applicable in the advice framework across various ICES stock categories.” Ideally the ICES assessment cat- egories should provide equivalent risk across all stocks. This issue was discussed but no recom- mendations emerged. There was no consensus a revised reference point framework was proposed at WKREF2. How- ever, it was agreed that it should be presented here for further discussion at ACOM and other fora. The key feature of the suggested approach is that the stock status evaluation is treated in- dependent of the Advice Rule (AR). The main feature of the system is that the biomass trigger is not linked to a stock status evaluation, it is linked to the expected biomass when fishing at the target fishing mortality, in contrast to the current ICES approach. It also entailed that FMSY would also become an upper limit of fishing mortality and that the advised fishing mortality would be set at or lower than that level. WKREF2 did not discuss what to do in situations where SSB〈 Blim or alternative forms of HCR for the advice rule. Building community understanding and con- sensus around simplified and harmonised guidelines has yet to be achieved. A further workshop WKREF3 will be required to achieve that aim. The report includes 6 recommendations for ACOM consideration.
    Description: ICES
    Description: The main objective of the workshop was to review the recommendations of WKREF1 and con- sider how these might feed into a new reference points framework and guidelines for ICES. There were a number of presentations on the wider issues of best practice for reference points, the Allee effect, density dependence and the WKIRISH approach. The starting point was to try and develop a set of simplified and harmonised guidelines based on the WKREF1 report rather than evolving the current guidelines to include the WKREF1 conclusions. A key aspect of the meeting was to allow for discussions in order to build a shared understanding of the strengths and weakness of the current framework and of the new framework emerging from WKREF1.
    Description: Published
    Description: Non Refereed
    Keywords: ICES ; Reference points ; Management advice ; Fisheries ; Fishery management reference points
    Repository Name: AquaDocs
    Type: Report
    Format: 103pp
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  • 5
    Publication Date: 2022-10-26
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Dowd, S., Chapman, M., Koehn, L., & Hoagland, P. The economic tradeoffs and ecological impacts associated with a potential mesopelagic fishery in the California Current. Ecological Applications, 32(4), (2022): e2578, https://doi.org/10.1002/eap.2578.
    Description: The ocean's mesopelagic zone (200–1000 m) remains one of the most understudied parts of the ocean despite knowledge that mesopelagic fishes are highly abundant. Apex predators from the surface waters are known to consume these fishes, constituting an important ecological interaction. Some countries have begun exploring the potential harvest of mesopelagic fishes to supply fishmeal and fish oil markets due to the high fish abundance in the mesopelagic zone compared with overfished surface waters. This study explored the economic and ecological implications of a moratorium on the harvest of mesopelagic fishes such as lanternfish off the US West Coast, one of the few areas where such resources are managed. We adapted a bioeconomic decision model to examine the tradeoffs between the values gained from a hypothetical mesopelagic fishery with the potential values lost from declines in predators of mesopelagic fishes facing a reduced prey resource. The economic rationale for a moratorium on harvesting mesopelagics was sensitive both to ecological relationships and the scale of the nonmarket values attributed to noncommercial predators. Using a California Current-based ecological simulation model, we found that most modeled predators of mesopelagic fishes increased in biomass even under high mesopelagic harvest rates, but the changes (either increases or decreases) were small, with relatively few predators responding with more than a 10% change in their biomass. While the ecological simulations implied that a commercial mesopelagic fishery might not have large biomass impacts for many species in the California Current system, there is still a need to further explore the various roles of the mesopelagic zone in the ocean.
    Description: Sally Dowd acknowledges sponsorship from the WHOI Summer Student Fellowship and the Rausser College of Natural Resources Honors Program at UC Berkeley. This project would not have been possible without the guidance provided by Kama Thieler and Carl Boettiger. Porter Hoagland acknowledges funding from the Audacious Project, a collaborative endeavor, housed at TED and the J. Seward Johnson Fund in support of the Marine Policy Center at WHOI.
    Keywords: Bioeconomic model ; Fisheries ; Mesopelagic fishes ; Moratorium ; Nonmarket value ; Predators ; Rpath ; Willingness-to-pay values
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 6
    Publication Date: 2022-05-27
    Description: Buesseler, K., Jin, D., Kourantidou, M., Levin, D., Ramakrishna, K., Renaud, P., Ausubel, J., Baltes, K., Gjerde, K., Holland, M., Kostel, K., LaCapra, V., Martin, A., Sosik, H., Thorrold, S., Tierney, T., Joyce, K., Renier, N., Taylor, E. (2022). The Ocean Twilight Zone’s Role in Climate Change. Woods Hole Oceanographic Institution, 32 pp.
    Description: The ocean twilight zone (more formally known as the mesopelagic zone) plays a fundamental role in global climate. It is the mid-ocean region roughly 100 to 1000 meters below the surface, encompassing a half-mile deep belt of water that spans more than two-thirds of our planet. The top of the ocean twilight zone only receives 1% of incident sunlight and the bottom level is void of sunlight. Life in the ocean twilight zone helps to transport billions of metric tons (gigatonnes) of carbon annually from the upper ocean into the deep sea, due in part to processes known as the biological carbon pump. Once carbon moves below roughly 1000 meters depth in the ocean, it can remain out of the atmosphere for centuries to millennia. Without the benefits of the biological carbon pump, the atmospheric CO 2 concentration would increase by approximately 200 ppm 1 which would significantly amplify the negative effects of climate change that the world is currently trying to curtail and reverse. Unfortunately, existing scientific knowledge about this vast zone of the ocean, such as how chemical elements flow through its living systems and the physical environment, is extremely limited, jeopardizing the efforts to improve climate predictions and to inform fisheries management and ocean policy development.
    Description: Funding is: The Audacious Project housed at TED
    Keywords: Climate ; Mesopelagic ; Twilight Zone ; Fisheries ; Carbon Dioxide Removal ; Ocean ; Biological Carbon Pump ; Solubility Pump ; Carbon ; Marine Snow
    Repository Name: Woods Hole Open Access Server
    Type: Other
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  • 7
    Publication Date: 2022-08-22
    Description: Methods
    Description: The python tool "Time dependent stress response seismicity model (TDSR)" is a modified effective Coulomb failure model to calculate earthquake rates as a function of stress loading and model parameter. The theory and examples are described in Dahm and Hainzl (2022): A Coulomb Stress response model for time-dependent earthquake forecasts, accepted in Journal of Geophysical Research, Solid Earth (doi xxxxxx). The TDSR toolbox is further developed under github at https://github.com/torstendahm/tdsr . A Sphinx generated code documentation and html pages are provided after installation. Examples published in Dahm and Hainzl (2022) are provided as code examples.
    Keywords: Seismology ; Earthquake Rate Forecast ; EARTH SCIENCE 〉 HUMAN DIMENSIONS 〉 NATURAL HAZARDS 〉 EARTHQUAKES ; EARTH SCIENCE SERVICES 〉 ENVIRONMENTAL ADVISORIES 〉 GEOLOGICAL ADVISORIES 〉 EARTHQUAKES ; EARTH SCIENCE SERVICES 〉 MODELS 〉 GEOLOGIC/TECTONIC/PALEOCLIMATE MODELS
    Type: Software , Software
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  • 8
    Publication Date: 2022-10-26
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Baker, M. G., Aster, R. C., Wiens, D. A., Nyblade, A., Bromirski, P. D., Gerstoft, P., & Stephen, R. A. Teleseismic earthquake wavefields observed on the Ross Ice Shelf. Journal of Glaciology, 67(261), (2021): 58-74, https://doi.org/10.1017/jog.2020.83.
    Description: Observations of teleseismic earthquakes using broadband seismometers on the Ross Ice Shelf (RIS) must contend with environmental and structural processes that do not exist for land-sited seismometers. Important considerations are: (1) a broadband, multi-mode ambient wavefield excited by ocean gravity wave interactions with the ice shelf; (2) body wave reverberations produced by seismic impedance contrasts at the ice/water and water/seafloor interfaces and (3) decoupling of the solid Earth horizontal wavefield by the sub-shelf water column. We analyze seasonal and geographic variations in signal-to-noise ratios for teleseismic P-wave (0.5–2.0 s), S-wave (10–15 s) and surface wave (13–25 s) arrivals relative to the RIS noise field. We use ice and water layer reverberations generated by teleseismic P-waves to accurately estimate the sub-station thicknesses of these layers. We present observations consistent with the theoretically predicted transition of the water column from compressible to incompressible mechanics, relevant for vertically incident solid Earth waves with periods longer than 3 s. Finally, we observe symmetric-mode Lamb waves generated by teleseismic S-waves incident on the grounding zones. Despite their complexity, we conclude that teleseismic coda can be utilized for passive imaging of sub-shelf Earth structure, although longer deployments relative to conventional land-sited seismometers will be necessary to acquire adequate data.
    Description: This research was supported by NSF grants PLR-1142518, 1141916, 1142126, 1246151, 1246416 and OPP-1744852 and 1744856.
    Keywords: Glacier geophysics ; Ice shelves ; Seismology
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 9
    Publication Date: 2022-10-26
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Kourantidou, M., Hoagland, P., Dale, A., & Bailey, M. Equitable allocations in northern fisheries: bridging the divide for Labrador Inuit. Frontiers in Marine Science, 8, (2021): 590213, https://doi.org/10.3389/fmars.2021.590213.
    Description: Canada has undertaken commitments to recognize the rights of Indigenous Peoples in fisheries through policies and agreements, including Integrated Fishery Management Plans, the Reconciliation Strategy, and Land Claim Agreements (LCAs). In addition to recognizing rights, these commitments were intended to respect geographic adjacency principles, to enhance the economic viability of Indigenous communities, and to be reflective of community dependence on marine resources. We examined the determinants of quota allocations in commercial fisheries involving Nunatsiavut, Northern Labrador, the first self-governing region for the Inuit peoples in Canada. It has been argued that current fishery allocations for Nunatsiavut Inuit have not satisfied federal commitments to recognize Indigenous rights. Indicators that measure equity in commercial allocations for the turbot or Greenland halibut (Reinhardtius hippoglossoides) and northern shrimp (Pandalus borealis) fisheries were identified and assessed. In these two cases, historical allocations continue to predominate for allocations based upon equity or other social or economic considerations. We illustrate equity-enhancing changes in the quota distribution under scenarios of different levels of inequality aversion, and we make qualitative assessments of the effects of these allocations to Nunatsiavut for socioeconomic welfare. This approach could benefit fisheries governance in Northern Labrador, where federal commitments to equity objectives continue to be endorsed but have not yet been integrated fully into quota allocations.
    Description: This research was undertaken with funding from the Canada First Research Excellence Fund through the Ocean Frontier Institute (MK and MB) and the Johnson Endowment of the Woods Hole Oceanographic Institution’s (WHOI) Marine Policy Center (PH).
    Keywords: Fisheries ; Allocations ; Equity ; Indigenous rights ; Access
    Repository Name: Woods Hole Open Access Server
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  • 10
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    In:  aqdchief@seafdec.org.ph | http://aquaticcommons.org/id/eprint/18569 | 2002 | 2015-11-15 16:06:30 | 18569 | Southeast Asian Fisheries Development Center, Aquaculture Department
    Publication Date: 2022-08-02
    Description: This paper summarizes the results of the experiments on the induced breeding and larval rearing of milkfish (Chanos chanos) during the 1979 season. Milkfish larvae could be reared successfully without the use of trochophore larvae of oysters as feed during the first few days. In order to induce the ovulation of wild adult milkfish a higher dose of human chorionic gonadotropin hormone is required.
    Keywords: Fisheries ; Chanos chanos ; ISEW ; Philippines ; marine environment ; Brood stocks ; Fish culture ; Fish larvae ; Food organisms ; Induced breeding ; Larval development ; Sex hormones
    Repository Name: AquaDocs
    Type: article
    Format: application/pdf
    Format: application/pdf
    Format: 1-3
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  • 11
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    In:  library@seafdec.org.ph | http://aquaticcommons.org/id/eprint/20100 | 17342 | 2016-02-24 22:18:26 | 20100 | Southeast Asian Fisheries Development Center, Aquaculture Department
    Publication Date: 2022-08-02
    Description: An outline is given of aquaculture and fisheries in Asia, providing information of use to students whose work can influence laws, rules, policy and regulations on aquaculture and fisheries, with the view in mind to sustainable aquaculture. In this issue, the following countries are examined: China, Indonesia, and Bangladesh.
    Keywords: Aquaculture ; Fisheries ; Fishery management ; Aquaculture development ; Aquaculture regulations ; Marine aquaculture ; Freshwater aquaculture ; Fishery industry ; Asia ; Bangladesh ; China
    Repository Name: AquaDocs
    Type: article
    Format: application/pdf
    Format: application/pdf
    Format: 7-8
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  • 12
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    In:  library@seafdec.org.ph | http://aquaticcommons.org/id/eprint/20067 | 2002 | 2016-03-04 15:16:24 | 20067 | Southeast Asian Fisheries Development Center, Aquaculture Department
    Publication Date: 2022-08-02
    Keywords: Fisheries ; Aquaculture ; Vietnam ; Sri Lanka ; Sri Lanka ; Vietnam ; brackishwater environment ; freshwater environment ; marine environment ; Aquaculture ; Aquaculture techniques ; Brackishwater aquaculture ; Feed ; Fish culture ; Fish diseases ; Fisheries ; Fishery data ; Food organisms ; Freshwater aquaculture ; Marine aquaculture ; Marine fisheries ; Mollusc culture ; Pond culture ; Seaweed culture ; Shrimp culture
    Repository Name: AquaDocs
    Type: article
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    Format: pp.9-10, 27
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  • 13
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    In:  library@seafdec.org.ph | http://aquaticcommons.org/id/eprint/20055 | 2002 | 2016-03-03 11:33:32 | 20055 | Southeast Asian Fisheries Development Center, Aquaculture Department
    Publication Date: 2022-08-02
    Keywords: Fisheries ; Aquaculture ; Asia ; Cambodia ; India ; Asia ; Cambodia ; India ; Myanmar ; Myanmar ; brackishwater environment ; freshwater environment ; marine environment ; Aquaculture ; Aquaculture development ; Aquaculture economics ; Aquaculture techniques ; Brackishwater aquaculture ; Catching methods ; Culture effects ; Environmental impact ; Fish culture ; Fisheries ; Fishery development ; Fishery resources ; Fishery statistics ; Freshwater aquaculture ; Marine aquaculture ; Shrimp culture ; Sustainability ; Trade
    Repository Name: AquaDocs
    Type: article
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  • 14
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26291 | 23782 | 2019-04-08 09:42:05 | 26291 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Fisheries ; Pollution ; Indonesia ; Heavy metals ; Chemical pollution ; Pollution monitoring
    Repository Name: AquaDocs
    Type: book_section
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  • 15
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26293 | 23782 | 2019-03-22 03:49:21 | 26293 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Fisheries ; Myanmar ; Heavy metals ; Cadmium ; Lead ; Mercury ; Biological sampling ; Fish ; Fishery products ; Seafood
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
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    Format: 38-46
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  • 16
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    Secretariat, Southeast Asian Fisheries Development Center | Bangkok, Thailand
    In:  http://aquaticcommons.org/id/eprint/26259 | 2002 | 2019-03-01 05:56:06 | 26259 | Southeast Asian Fisheries Development Center, Secretariat
    Publication Date: 2022-08-02
    Description: Round scad exploration by purse seine in the waters of western Philippines was conducted from April 22 to May 7, 1998 for a period of five (5) fishing days with a total catch of 7.3 tons and an average of 1.5 tons per setting. Dominant species caught were Decapterus spp. having 70.09% of the total catch, followed by Selar spp. at 12.66% and Rastrelliger spp. 10.70%. Among the Decapterus spp. caught, D. macrosoma attained the highest total catch composition by species having 68.81% followed by D. kurroides and D.russelli with 0.31% and 1.14% respectively. The round scad fishery stock was composed mainly of juvenile fish (less than 13 cm) and Age group II (13 cm to 14 cm). Few large round scad at Age group IV and V (20 cm to 28 cm) stayed at the fishery. Other fishes caught were: Auxis rochei (0.85%), A. thazard (0.12%), Caranx spp. (0.45%), Emmilichthys nitidus (0.58%), Euthynnus affinis (0.42%), Leiognathus ruconius (0.58%), Loligo sp. (0.31%), Megalaspis cordyla (0.09%), Rastrelliger spp. (10.70%), Sardinella longiceps (0.03%), Scomberoides lysan (0.24%), Selar spp. (12.66%), Sphyraena spp. (0.90%), Thunnus albacares (0.96%) and others (1.02%). Tuna and tuna like fishes such as yellowfin tuna, eastern little tuna, bullet tuna, frigate tuna and oceanic squid are distributed in the upper latitudes of the survey area. On the other hand, round scads, big-eyed scads and Indian mackerels are dominantly present in the lower latitudes of the survey area.
    Keywords: Fisheries ; Exploratory fishing ; Purse seining ; Age composition ; Catch composition ; Fishery surveys ; Carangid fisheries ; South China Sea ; Philippines ; Rastrelliger ; Decapterus
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  • 17
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    Training Department, Southeast Asian Fisheries Development Center | Samut Prakarn, Thailand
    In:  http://aquaticcommons.org/id/eprint/26215 | 17342 | 2019-02-08 06:25:54 | 26215 | Southeast Asian Fisheries Development Center, Training Department
    Publication Date: 2022-08-02
    Description: Presented in this paper is the status of the fishery industry in Brunei Darussalam. Specifically, it discussed the following topics: fishery management strategies, zonation scheme, licencing, the use of poisons and explosives, the minimum cod-end mesh size for trawlers, closed areas, enhancement of fishing grounds, and the enforcement activities.
    Keywords: Fisheries ; Fishery resources ; Fishery management ; Fisheries ; Ecological zonation ; Licensing ; Fish poisoning ; Catching methods ; Illegal fishing ; Explosive fishing ; Fishing gear ; Season regulations ; Fishing grounds
    Repository Name: AquaDocs
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  • 18
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26295 | 23782 | 2019-03-22 08:39:12 | 26295 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Fisheries ; Thailand ; Cadmium ; Lead ; Mercury ; Biological sampling ; Fish ; Fishery products ; Seafood
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 53-58
    Format: 6
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26292 | 23782 | 2019-03-22 03:43:09 | 26292 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Fisheries ; Malaysia ; Cadmium ; Lead ; Mercury ; Biological sampling ; Fish ; Fishery products ; Seafood
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 20-37
    Format: 18
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  • 20
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    Secretariat, Southeast Asian Fisheries Development Center | Bangkok, Thailand
    In:  http://aquaticcommons.org/id/eprint/26258 | 2002 | 2019-03-01 06:00:19 | 26258 | Southeast Asian Fisheries Development Center, Secretariat
    Publication Date: 2022-08-02
    Description: An exploratory tuna longline fishing survey was conducted using the research and training vessels of the Southeast Asian Fisheries Development Center, the 1,178 GT MV SEAFDEC and the Bureau of Fisheries and Aquatic Resources, the 165 GT MV MAYA-MAYA in the South China Sea Waters, West of the Philippines from April to May, 1998. A total of 3,796 hooks was set in sixteen (16) fishing stations. There were no tuna caught during the entire survey but only minor and irrelevant species like the Pacific lancetfish, sharks and an opah species, Lampris guttatus. The important fishing and oceanographic factors during the survey and other research results on longline are described and analyzed. Additional longline studies within and near the Philippines territorial waters are also presented to substantiate the research results of the joint SEAFDEC/BFAR resource exploratory.
    Keywords: Fisheries ; Exploratory fishing ; Catch composition ; Fishery surveys ; Longlining ; Tuna fisheries ; South China Sea ; Philippines
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 39-48
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26299 | 23782 | 2019-03-27 06:00:01 | 26299 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Chemistry ; Fisheries ; Malaysia ; Pesticides ; Biological sampling ; Fish ; Fishery products ; Biochemical analysis ; Lethal limits
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 71-74
    Format: 4
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26300 | 23782 | 2019-03-27 05:58:36 | 26300 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Aquaculture ; Chemistry ; Fisheries ; Myanmar ; Pesticides ; Biological sampling ; Fish ; Fishery products ; Lethal limits
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 75-83
    Format: 9
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  • 23
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26307 | 23782 | 2019-03-27 03:35:56 | 26307 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Fisheries ; Indonesia ; Histamines ; Biological sampling ; Fish ; Fishery products ; Quality control
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 116-123
    Format: 8
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  • 24
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26303 | 23782 | 2019-03-27 05:51:15 | 26303 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Chemistry ; Fisheries ; Thailand ; Pesticides ; Biological sampling ; Fish ; Fishery products ; Dried products ; Lethal limits
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 100-105
    Format: 6
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26309 | 23782 | 2019-03-27 03:49:31 | 26309 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Fisheries ; Myanmar ; Histamines ; Biological sampling ; Biochemical analysis ; Fish ; Fishery products
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 129-133
    Format: 5
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  • 26
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26826 | 23782 | 2019-11-21 00:56:12 | 26826 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Presented in the paper is the standard procedure in the determination of K value which is an index to measure the enzymatic freshness of fish and squid. Specifically, reagents, apparatus and the analytical procedures needed and the calculations are presented.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Fishery products ; Fish inspection ; Fishery industry ; Food technology ; Standards ; Specifications
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: B-6.1-B-6.7
    Format: 7
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  • 27
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26825 | 23782 | 2019-11-21 00:52:35 | 26825 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Presented in the paper is the standard procedure in measuring K value in fish meat by means of the freshness testing paper technique.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Fishery products ; Fish inspection ; Fishery industry ; Food technology ; Standards ; Specifications
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: B-7.1-B-7.2
    Format: 2
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  • 28
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26802 | 23782 | 2019-11-12 05:28:20 | 26802 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Presented in the paper is the standard procedure in the measurement of pH in the fresh fish meat. Specifically, the procedures in sampling and sample preparation, apparatus and reagents required, and the analytical procedures are presented.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Microbiological analysis ; Fishery products ; Processed fishery products ; Fish inspection ; Fishery industry ; Food additives ; Food technology ; Standards ; Specifications ; pH
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: A-3.1-A-3.2
    Format: 2
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  • 29
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26842 | 23782 | 2019-11-15 07:54:48 | 26842 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Starch is commonly used in the production of fish jelly products as an extender and as binding agent. The paper provides the methodology in the determination of starch in fish jelly products. Instructions for sample preparation and the reagents needed are presented. Detailed procedures in the determination of the starch in a sample are provided.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Fishery products ; Fishery industry ; Food technology ; Standards ; Specifications ; Starch ; Additives ; Food additives
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: D-4.1-D-4.4
    Format: 4
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  • 30
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26881 | 23782 | 2019-11-05 02:46:02 | 26881 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Monitoring and investigative work undertaken in the Philippines regarding dinoflagellate blooms are described. Chronological observations of the occurrence of red tides, aerial surveys, spatial distribution of the dinoflagellate and the physical environment are discussed. Fishing and the examination of gut content of fish and mussels and bioassay tests are detailed. Incidents of paralytic shellfish poisoning in the Philippines are considered briefly.
    Keywords: Fisheries ; Health ; Environmental monitoring ; Red tides ; Public health ; Medicine ; Dangerous organisms ; Philippines
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 52-79
    Format: 28
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  • 31
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26885 | 23782 | 2019-11-05 02:23:34 | 26885 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: A report is made of the first incidence occurring of paralytic shellfish poisoning in Thailand in May 1983, following an extensive bloom of Trichodesmium erythraeum. Investigations undertaken regarding the source of the toxicity are outlined.
    Keywords: Fisheries ; Health ; Biological poisons ; Public health ; Red tides ; Shellfish ; Dangerous organisms ; Thailand
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 90-91
    Format: 2
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  • 32
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26879 | 23782 | 2019-11-05 02:54:38 | 26879 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: A brief account is given of recent cases of paralytic shellfish poisoning in Sabah, Malaysia, and toxicological studies undertaken. Hydrography surveys, underwater observations after the occurrence of the red tides and plankton studies and monitoring of red tides are discussed.
    Keywords: Fisheries ; Health ; Shellfish ; Toxicity tests ; Red tides ; Public health ; Dangerous organisms ; Malaysia
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 35-42
    Format: 8
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  • 33
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26852 | 23782 | 2019-11-15 07:36:44 | 26852 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Cholera is an acute specific infection caused by the organism, Vibrio cholera. Diagnosis may be confirmed by the presence of large numbers of the comma-shaped bacilli on direct microscopic examination of a fecal or vomitus smear, and by the isolation of the organism on culture. Fish and shellfish have been identified as vehicles of cholera. Large numbers of V. cholera must usually be ingested to cause cholera. Thus problems often occur when poor handling and inadequate refrigeration have allowed the organism to multiply. Presented in the paper is the methodology of determining the presence of Vibrio cholera in fish and fishery products.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Fishery products ; Fishery industry ; Food technology ; Standards ; Specifications ; Aerobic bacteria ; Microbiological analysis ; Microorganisms ; Pathogenic bacteria ; Pathogens ; Health and safety ; Public health ; Microbial contamination ; Vibrio cholerae
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: E-7.1-E-7.5
    Format: 5
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  • 34
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    Secretariat, Southeast Asian Fisheries Development Center | Bangkok, Thailand
    In:  http://aquaticcommons.org/id/eprint/26890 | 23782 | 2019-11-14 01:01:29 | 26890 | Southeast Asian Fisheries Development Center, Secretariat
    Publication Date: 2022-08-02
    Description: Fishery statistics in Brunei Darussalam have been collected by the Department of Fisheries since the 1940s. In the early 1980s, a number of statistics were collected, such as catch and effort data of artisanal fishermen, aquaculture statistics, processing statistics as well as data from major wet markets focusing on the amount, prices of marketed fish either from the local fishermen or imported. In 1984, the collection of statistics on commercial fishing was started. The statistics have been used in the formulation of fishery management and development policies as well as for sectoral development. Following a brief account of the responsibility and statistic collections of the Department of Fisheries, an examination is made of employment in the fishery sector, fisheries production, fish marketed and the GDP for the fishery industry. Fisheries in Brunei Darussalam is a very healthy industry, where production is well below the maximum allowable harvestable limit of 20,000 tons at 30%. The Department is embarking to increase production from the capture fishery to reduce the country's dependence on imported fish; the same applies for aquaculture, in order to complement production from the capture fisheries. The processing sector is also increasing in importance, especially with the increase in the number of capture fishery licenses, and the demand for quality and value-added products.
    Keywords: Fisheries ; Marine fisheries ; Fishery statistics ; Aquaculture development ; Aquaculture statistics ; Fish catch statistics ; Marine aquaculture ; Freshwater aquaculture ; Fishery development ; Marine ; Brackish ; Freshwater
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 6-14
    Format: 9
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  • 35
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26843 | 23782 | 2019-11-15 07:52:55 | 26843 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Sodium chloride is an important additive for the production of fish jelly products. It extracts the salt soluble protein to give the gel strength of the final product. The paper provides the methodology in the determination of the amount of sodium chloride in fish jelly products. Instructions for sample preparation and the reagents needed are presented. Detailed procedures in the determination of the salt in a sample are provided.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Fishery products ; Fishery industry ; Food technology ; Standards ; Specifications ; Additives ; Food additives ; Salts ; Sodium chloride
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: D-5.1-D-5.2
    Format: 2
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  • 36
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26851 | 23782 | 2019-11-14 01:29:31 | 26851 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Food poisoning due to Vibrio parahaemolyticus is a food-borne infection resulting from the ingestion of a large number of this organism (about 106-109 viable cells). The major symptoms are diarrhea and abdominal pain with headache, fever, and vomiting also occurring. The organisms are excreted during the acute stage of the illness after which they decrease rapidly. The differentiation of V. parahaemolyticus from other pathogenic species of Vibrio is based mainly on salt tolerance, Voges-Proskauer reaction, fermentation of sucrose, and growth at 43°C. Presented in the paper is the methodology of determining the presence of Vibrio cholera in fish and fishery products.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Fishery products ; Fishery industry ; Food technology ; Standards ; Specifications ; Aerobic bacteria ; Microbiological analysis ; Microorganisms ; Pathogenic bacteria ; Pathogens ; Health and safety ; Public health ; Microbial contamination ; Vibrio parahaemolyticus ; Vibrio cholerae
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: E-8.1-E-8.6
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  • 37
    Publication Date: 2022-04-28
    Description: On the border between Colombia and Venezuela, have occurred seismic events with important records of damage in both countries. In this paper, we study the historical earthquake that took place on May 18, 1875 between 11.15 and 11.30 in the morning (the time was the same for communities in both countries since there was no time zone difference), which is catalogued as a border earthquake due to the report of damages in the cities of both nations. The community of San José de Cúcuta, current capital of the Northern State of Santander, Colombia, registered the greatest number of deaths and damage to buildings. An inventory of the geological damage and co -seismic and postseismic effects was created based on information of previous studies and data obtained from archival primary sources from Colombia and Venezuela. The result is a bi-national database, which includes the summaries of historical descriptions with the effects in the persons and objects, the geological damages and effects observed during the seismic event. These data has led to the creation of a table of MM and EMS-98 intensities, which enables the identification and delimitation of the regions of greater damages. The maximum level intensity is I=10 in the cities of San José de Cúcuta, Villa del Rosario, Pueblo de Cúcuta (San Luis) in Colombia and San Antonio, San Juan de Ureña in Venezuela. Moreover, we formulated a table of intensities using the ESI-2007 INQUA scale, based on the information of geological observations described in historical documents. These data are related to the epicentral zone with an approximate radius of 30 km.
    Description: Published
    Description: 105-263
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: N/A or not JCR
    Keywords: historical seismicity ; destruction of communities ; Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 38
    Publication Date: 2022-10-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Baker, M. G., Aster, R. C., Anthony, R. E., Chaput, J., Wiens, D. A., Nyblade, A., Bromirski, P. D., Gerstoft, P., & Stephen, R. A. Seasonal and spatial variations in the ocean-coupled ambient wavefield of the Ross Ice Shelf. Journal of Glaciology, 65(254), (2019): 912-925, doi:10.1017/jog.2019.64.
    Description: The Ross Ice Shelf (RIS) is host to a broadband, multimode seismic wavefield that is excited in response to atmospheric, oceanic and solid Earth source processes. A 34-station broadband seismographic network installed on the RIS from late 2014 through early 2017 produced continuous vibrational observations of Earth's largest ice shelf at both floating and grounded locations. We characterize temporal and spatial variations in broadband ambient wavefield power, with a focus on period bands associated with primary (10–20 s) and secondary (5–10 s) microseism signals, and an oceanic source process near the ice front (0.4–4.0 s). Horizontal component signals on floating stations overwhelmingly reflect oceanic excitations year-round due to near-complete isolation from solid Earth shear waves. The spectrum at all periods is shown to be strongly modulated by the concentration of sea ice near the ice shelf front. Contiguous and extensive sea ice damps ocean wave coupling sufficiently so that wintertime background levels can approach or surpass those of land-sited stations in Antarctica.
    Description: This research was supported by NSF grants PLR-1142518, 1141916, 1142126, 1246151 and 1246416. JC was additionally supported by Yates funds in the Colorado State University Department of Mathematics. PDB also received support from the California Department of Parks and Recreation, Division of Boating and Waterways under contract 11-106-107. We thank Reinhard Flick and Patrick Shore for their support during field work, Tom Bolmer in locating stations and preparing maps, and the US Antarctic Program for logistical support. The seismic instruments were provided by the Incorporated Research Institutions for Seismology (IRIS) through the PASSCAL Instrument Center at New Mexico Tech. Data collected are available through the IRIS Data Management Center under RIS and DRIS network code XH. The PSD-PDFs presented in this study were processed with the IRIS Noise Tool Kit (Bahavar and others, 2013). The facilities of the IRIS Consortium are supported by the National Science Foundation under Cooperative Agreement EAR-1261681 and the DOE National Nuclear Security Administration. The authors appreciate the support of the University of Wisconsin-Madison Automatic Weather Station Program for the data set, data display and information; funded under NSF grant number ANT-1543305. The Ross Ice Shelf profiles were generated using the Antarctic Mapping Tools (Greene and others, 2017). Regional maps were generated with the Generic Mapping Tools (Wessel and Smith, 1998). Topography and bathymetry data for all maps in this study were sourced from the National Geophysical Data Center ETOPO1 Global Relief Model (doi:10.7289/V5C8276M). We thank two anonymous reviewers for suggestions on the scope and organization of this paper.
    Keywords: Antarctic glaciology ; Ice shelves ; Seismology
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 39
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 275 (1954), S. 94-97 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Das Ergebnis spektrophotometrischer Untersuchungen zeigt, daß das Zersetzungsprodukt des blauen Chromperoxyds weder Chromsäure sein kann, wie Barreswil annahm, noch Chrom(III)-chromat nach der Annahme Moissans. Die Analysenergebnisse zeigen, daß das Zersetzungsprodukt sehr wahrscheinlich Chrom(III)-dichromat Cr2(Cr2O7)3 ist. Bei der Zersetzung dieses Chrom(III)-dichromats zu Chrom(III)-oxyd betrug das Verhältnis von Chrom(III)-dichromat zu Chrom(III)-oxyd 1,22 bis 1,26 gegenüber einem theoretischen Wert von 1,23.
    Additional Material: 2 Tab.
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  • 40
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 275 (1954), S. 65-78 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1. Es wurden die Verbindungen Li5SiP3, Li5SiAs3, Li5GeP3, Li5GeAs3, Li5TiP3 und Li5TiAs3 durch Erhitzen von Silicium, Germanium oder Titan mit Lithiumphosphid und Phosphor bzw. Lithiumarsenid und Arsen hergestellt.2. Diese Verbindungen kristallisieren im Antifluoritgitter mit statistischer Verteilung des Lithiums und des Elementes der 4. Gruppe auf den Fluorpunktlagen. Die Gitterkonstanten sind in der obigen Reihenfolge 5,84, 6,04, 5,88, 6,08, 5,95, 6,13 kX.3. Die Verbindungen Li3GaP2 und Li3GaAs2 wurden durch Erhitzen von Lithiumphosphid und Galliumphosphid bzw. Lithiumarsenid und Galliumarsenid hergestellt.4. Li3GaP2, das allerdings etwas Lithiumphosphid gelöst enthält, kristallisiert in einer Überstruktur des Fluoritgitters mit der Gitterkonstante 11,74 kX. Das Li3GaAs2 kristallisiert tetragonal mit a = 11,94, c = 12,13 kX; das Bauprinzip ist offensichtlich das gleiche, wie bei den anderen Verbindungen dieser Stoffklasse.5. Es wird eine Übersicht über die bisher untersuchten ternären Nitride, Phosphide und Arsenide gegeben. Diese Verbindungen schließen sich chemisch den Verbindungen der Alkalimetalle mit den Elementen der 5. Gruppe, kristallchemisch den Verbindungen der Alkalimetalle mit den Elementen der 6. Gruppe an.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 41
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 275 (1954), S. 113-120 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Zerfallsgeschwindigkeit des Kaliumnitrosodisulfonats in 0,01 bis 10 n Essigsäure und 1 bis 4 n Natronlauge sowie in Puffergemischen von pH = 1,25 bis 2,20 wird bei verschiedenen Temperaturen kolorimetrisch gemessen. Die Reaktion verläuft in verdünnten Lösungen unimolekular. In einem pH-Bereich von etwa 2,4 bis 12,5 besitzt die Reaktion eine Induktionsperiode. In Puffergemischen ist die Zerfallsgeschwindigkeit bei 15°, 20°, 25° und 30° eine geradlinige Funktion der pH-Werte.
    Additional Material: 7 Ill.
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  • 42
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 275 (1954), S. 106-112 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird gezeigt, daß man die Isomerisation der beiden Mononitritokobalt(III)-salze [ONO · Co · (NH3)5] Cl2 und \documentclass{article}\pagestyle{empty}\begin{document}$ \left[ {\begin{array}{*{20}c} {\left( 1 \right){\rm ONO}} \\ {\left( {\rm 6} \right){\rm NCS}} \\\end{array}{\rm Co} \cdot {\rm en}_{\rm 2} } \right]{\rm ClO}_{\rm 4} $\end{document} in der Weise verfolgen kann, daß man mit angemessenen Zeitintervallen die Extinktion einer dünnen, zwischen zwei parallelen Glasplatten gepreßten Schicht des feingepulverten und mit einigen Tropfen Paraffinöl zusammengeriebenen, festen Präparates bestimmt. Die für die Umwandlung (erster Ordnung) gefundenen Geschwindigkeitskonstanten stimmen gut mit denjenigen der früheren Messungsmethode, der Auflösungsmethode, überein, bei der man die Extinktion von Probelösungen gegebener Konzentration mißt. Die Vor- und Nachteile des hier beschriebenen Verfahrens werden besprochen. Es wird für mehrere andere Umwandlungen verwendbar sein, falls diese von Extinktionsveränderungen begleitet sind.
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    Zeitschrift für anorganische Chemie 275 (1954), S. 98-105 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Kationenkonzentration verschiedener schwerlöslicher Salze bei Fällung in Gelatinelösung wurde konduktometrisch bestimmt. Es wurde festgestellt, daß die meisten der untersuchten Salze in einer andern als der dissoziierten Form vorliegen. Diese Beobachtung widerspricht der Übersättigungstheorie von Wi. Ostwald. In einigen Fällen hatte die Leitfähigkeit ein negatives Vorzeichen. Dies läßt sich aus den Versuchen dadurch erklären, daß im Verlaufe der Fällung der schwerlöslichen Salze Anteile des löslichen Reaktionsproduktes adsorbiert werden und damit dessen wirksame Konzentration herabgesetzt wird.
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  • 44
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    Zeitschrift für anorganische Chemie 275 (1954), S. 121-140 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Zur Darstellung des TiF3 werden mehrere Wege beschrieben. Das zweckmäßigste Verfahren beruht auf der Umsetzung von Titanhydrid mit Fluorwasserstoff bei 700°.Durch Hochvakuumsublimation bei ∼ 950° gelingt es, das Titantrifluorid von Verunreinigungen vollständig zu trennen. Man erhält es in blauen Kristallen, die an Luft beständig und gegenüber Säuren und Basen ungewöhnlich resistent sind.TiF3 besitzt nach magnetischen Messungen (μB = 1,75 bei einem ΘH-Wert von -10°) ein reines Ionengitter. Es ist die erste wasserfreie Verbindung des dreiwertigen Titans, die den theoretischen Wert des Ti3+-Ions ergibt.TiF3 kristallisiert rhomboedrisch, a = 5,523 Å und α = 58,88°; die Elementarzelle enthält 2 Molekeln.Die Existenz eines Difluorides ist unwahrscheinlich; die Disproportionierung des TiF3 (beginnend oberhalb 950°) erfolgt direkt in TiF4 + Ti. Die experimentellen Befunde stehen mit der Auswertung der magnetischen Messungen und mit einem Vergleich der Eigenschaften der anderen Halogenide im Einklang.
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    Zeitschrift für anorganische Chemie 275 (1954), S. 141-146 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es werden die Fällungsprodukte von HgBr2-Lösungen mit Ammoniak in Abhängigkeit von der Ammoniakkonzentration analytisch und röntgenographisch untersucht. In Bestätigung früherer Untersuchungen wird festgestellt, daß das reine HgNH2Br kubisch kristallisiert. Es bildet sich nur bei Ammoniakkonzentrationen zwischen 0,09 und 0,07 Mol/Liter.Das von Nijssen und Lipscomb beschriebene „rhombische“ HgNH2Br entsteht, wenn die Ammoniakkonzentration größer als 0,09 Mol/Liter ist. Diese rhombischen Präparate sind jedoch kein reines HgNH2Br, sondern enthalten sehr wahrscheinlich bis zu 5 Mol-% HgBr2 in fester Lösung, wodurch erst die rhombische, dem HgNH2Cl analoge Struktur stabilisiert wird.
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    Zeitschrift für anorganische Chemie 275 (1954), S. 147-151 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Wasserstoffpolysulfide selbst leicht flüchtiger Amine lassen sich bequem darstellen, wenn man in passenden möglichst dipolfreien Lösungsmitteln Amin und Schwefel löst und langsam Schwefelwasserstoff einleitet. Im allgemeinen entstehen nicht die sauren, sondern die neutralen Wasserstoffpolysulfide mit sieben oder neun Schwefelatomen.
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    Zeitschrift für anorganische Chemie 275 (1954), S. 267-272 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die RAMAN-Spektren von VOCl3 und ReO3Cl werden beschrieben. Soweit die experimentellen Daten dies zulassen, wird eine Ausdeutung der Spektren unter Heranziehung geeigneter Mustersubstanzen und mittels des WAGNERschen Modells für C3v- Molekeln versucht. Die bei VOCl3 gefundenen Frequenzen werden sämtlich zugeordnet, beim ReO3Cl gelingt nur die Zuordnung eines Teiles der Frequenzen. Die Kraftkonstanten von VOCl3 und POCl3 für das Valenzkraftmodell von WAGNER werden mitgeteilt, die sich daraus ergebenden Bindekräfte diskutiert.
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    Zeitschrift für anorganische Chemie 275 (1954), S. 283-288 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Der Dissoziationsgrad der Phosphorsäure in wäßriger Lösung wird aus der Struktur berechnet und mit den Lösungsgeschwindigkeiten von Titan und Zirkon verglichen.
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    Zeitschrift für anorganische Chemie 276 (1954) 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Zeitschrift für anorganische Chemie 276 (1954) 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Zeitschrift für anorganische Chemie 276 (1954), S. 209-226 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus einer vergleichenden Betrachtung über den Bau der Gittertypen von CaF2, Mn2O3 und La2O3 wird die Erwartung abgeleitet, daß zwischen Oxyden, die im Fluorittyp und solchen, die im Mn2O3-Typ kristallisieren, ungeachtet des verschiedenen Formeltyps unter geeigneten Bedingungen eine kontinuierliche Reihe von Mischkristallen bestehen müsse. Zur Prüfung dieser Voraussage wurden die vollständigen Phasendiagramme der binären Oxydsysteme CeO2—Y2O3, CeO2—Nd2O3, CeO2—Sm2O3, CeO2—Gd2O3, CeO2—Dy2O3, CeO2—Yb2O3, ThO2—Y2O3, ThO2—La2O3, ThO2—Ce2O3, ThO2—Nd2O3, ThO2—Sm2O3 und ThO2—Gd2O3 durch Präparation, röntgenographische und pyknometrische Untersuchungen aufgestellt. In den vier Systemen mit CeO2 und Y2O3, Sm2O3, Gd2O3 oder Dy2O3 wurde der gesuchte lückenlose Übergang zwischen den Komponenten aufgefunden. In allen übrigen Systemen besteht nur eine begrenzte Mischkristallreihe mit Fluoritstruktur, die sich über einen mehr oder weniger breiten Bereich der Zusammensetzungen erstreckt. Für das Auftreten des einen oder anderen Typus im Phasenverhalten der Systeme werden Deutungen gegeben und Regeln aufgestellt.
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    Zeitschrift für anorganische Chemie 276 (1954), S. 235-235 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Zeitschrift für anorganische Chemie 276 (1954), S. 227-235 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird ein adiabatisches Calorimeter beschrieben, das mit Säurefüllung, 4 n HCl, bei höheren Temperaturen, ungefähr 41,5° C, auf 0,001° genau arbeitet. Hiermit sind die Lösungswärmen von verschieden hergestellten pulverförmigen Nickel- und Kobalt-Metallkatalysatoren gemessen worden.Es ergibt sich eine lineare Abhängigkeit der Lösungswärme von der Größe der absoluten Oberfläche; Metallpulver, die bei niedriger Reduktionstemperatur hergestellt sind, haben eine größere Lösungswärme und eine größere Oberfläche als solche, die bei höherer Temperatur reduziert sind. Unterschiede in der Lösungswärme bis zu 0,5 kcal.Aus der Größe der absoluten Oberfläche und der Lösungswärme wird die spezifische Oberflächenenergie für Nickel und Kobalt berechnet. Anzeichen für Gitterstörungen und dadurch bedingten höheren Energieinhalt bestehen nicht.
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    Zeitschrift für anorganische Chemie 276 (1954), S. 247-266 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Auflösungsgeschwindigkeiten von Natriumchlorid, Kaliumchlorid und Kieserit wurden theoretisch und experimentell unter verschiedenen Bedingungen untersucht. Bei der Auflösung in Fremdsalzlösungen ergaben sich Kurven, aus deren Verlauf Gebiete verschieden starker Wasserbindung abgeleitet werden. Die Auflösungsgeschwindigkeit von Kieserit in seinen eigenen Lösungen ergab sich als nicht proportional der Untersättigung, was so gedeutet wird, daß in der Grenzschicht Sättigung nicht erreicht wurde. Es wird auf die Möglichkeit hingewiesen, daß bei den früheren Messungen von Auflösungsgeschwindigkeiten die Grenzschicht nicht berührt wurde, sondern lediglich ein Film anhaftender konzentrierter Lösung.
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    Zeitschrift für anorganische Chemie 276 (1954), S. 267-274 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Der Begriff Lösungsgleichgewicht wird kinetisch definiert und mit seiner Hilfe eine Methode zur Bestimmung von stabilen und metastabilen Lösungsgleichgewichten abgeleitet, die genauer arbeitet als die klassische Rührmethode.Die stabilen und metastabilen Lösungsgleichgewichte im Carnallitgebiet des Systems MgCl2—Na2Cl2—K2Cl2 —H2 wurden bei 20°C gemessen.
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    Zeitschrift für anorganische Chemie 276 (1954), S. 236-246 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Racemische Kobaltkomplexe, deren Liganden Gruppen enthalten, die mit Hydroxylresten gerne assoziieren, lassen sich leicht auf chromatographischem Wege an Stärke optisch aktivieren. Das Verfahren ist auch für die bisher nicht trennbaren Neutralkomplexe geeignet. In aktiver Form wurden erhalten: Triäthylendiamin-kobalt(III)-chlorid, α-Triglykokoll-kobalt, Kobalt-isäthinylxanthogenat, Kobalt-metholdithiocarbaminat. Die beiden letzteren Verbindungen enthalten Nebenvalenzviererringe, die aus sterischen Gründen instabil sind. Daher tritt schon bei Zimmertemperatur Racemisierung ein. Die beiden diastereomeren Formen des Kobalt-l-bornylxanthogenats ließen sich chromatographisch an Alumiumoxyd trennen.
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    Zeitschrift für anorganische Chemie 276 (1954), S. 275-288 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die binären Systeme Cr2O3—H2O, Sc2O3—H2O und Tl2O3—H2O wurden an Hand gutbekannter hydrothermaler Methoden studiert, die es ermöglichten, Gesetzmäßigkeiten innerhalb der Phasengleichgewichte zu ermitteln.Im System Cr2O3—H2O konnten die drei stabilen Phasen Cr(OH)3, CrO(OH) und Cr2O3 bestätigt und ihre Stabilitätsbereiche als eine Funktion von Druck und Temperatur bestimmt werden.Eine Verbindung der Formel Sc(OH)3 wurde nicht aufgefunden. Die Struktur des ScO(OH) ließ sich dem Diaspor-Typ zuordnen, seine Gleichgewichtskurve bei der Zersetzung zu Sc2O3 wurde festgelegt.Es konnte bestätigt werden, daß Tl2O3 keinerlei Hydrate zu bilden vermag.Die Strukturen von Oxyden, Oxydhydroxyden und Hydroxyden dreiwertiger Elemente wurden miteinander verglichen und in schematischer Form dargestellt.
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    Zeitschrift für anorganische Chemie 277 (1954) 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Zeitschrift für anorganische Chemie 276 (1954), S. 316-324 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurden Untersuchungen über die Adsorption von Solen und den Ionen eines schwerlöslichen Salzes an einem frisch gefällten Niederschlag durchgeführt, um weitere Aufschlüsse zu erhalten über die Koagulationstheorie von Dhar und Chatterji und über die Ionenadsorptions-Theorie von Bradford. Die erhaltenen Ergebnisse zeigen, daß die Adsorption von Solen durch ihre schwerlöslichen Salze in Übereinstimmung steht mit den Forderungen der Koagulationstheorie, während die Adsorption der beteiligten Ionen durch den Niederschlag, auch bei stark wechselnden Konzentrationen der Elektrolyten, sehr gering ist. Das beweist, daß die Bildung Liesegangscher Ringe nicht einer Ionenadsorption zuzuschreiben ist, sondern der Adsorption des Sols durch das schwerlösliche Salz.
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    Zeitschrift für anorganische Chemie 276 (1954), S. 325-332 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Reaktion TiCl3fest + 1/2 Cl2 = TiCl4gas wurde im Calorimeter durchgeführt. Unabhängig davon wurde ferner das Gleichgewicht \documentclass{article}\pagestyle{empty}\begin{document}$${\rm TiCl_{4 {gas}}} + {\rm Hg_{fl\ddot {u}ss}}={\rm TiCl_{3{fest}}}+ ^1\hspace{-2pt}/_2{\rm Hg_ 2} {\rm Cl_{2{fest}}} $$\end{document} untersucht. Für die Bildungswärme des violetten Titan(III)-chlorids ergab die erste Reaktion 161,1 kcal und die zweite 161,6 kcal.
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    Zeitschrift für anorganische Chemie 276 (1954), S. 289-315 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Thermodynamik geschmolzener Salze und Schlacken behandelt. Insbesondere wird dabei den speziellen Verhältnissen in derartigen Systemen Rechnung getragen und versucht, Aktivitäten und Gleichgewichte zu berechnen.Im ersten Teil werden Ionenaustausch-Gleichgewichte betrachtet. Die Gleichgewichtskonstante für den Anionenaustausch in einer aus Ionen bestehenden Salzmischung (KMisch) ist in erster Näherung durch die Gleichung gegeben: \documentclass{article}\pagestyle{empty}\begin{document}$${\rm ln}\,{\rm K}_{{\rm Misch}} \, = \,{\rm N'}_{{\rm M}_{\rm 1} } \, \cdot \,{\rm ln}\,{\rm K}_{{\rm M}_{\rm 1} } \,{\rm + }\,{\rm N'}_{{\rm M}_{\rm 2} } \, \cdot \,\ln \,{\rm K}_{{\rm M}_{\rm 2} } \,{\rm + }\, \cdot \, \cdot \, \cdot, $$\end{document} wobei KM1 die Gleichgewichtskonstante in einem System, das nur das Kation M1 enthält und N′M1 die betreffende Konzentration ist. Die Anwendung dieser Gleichung wird am Beispiel eines metallurgischen Problems, nämlich der Verteilung von Phosphor zwischen geschmolzenem Eisen und einer geschmolzenen Schlacke, diskutiert.Im zweiten Teil wird die Aktivität einer Salzkomponente in einer Mischung geschmolzener Salze berechnet. In erster Näherung ist die Aktivität der Salzkomponente (aM1X1) durch die Gleichung gegeben: \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm RT}\,\ln \,{\rm a}_{{\rm M}_{\rm 1} {\rm X}_{\rm 1} } \,{\rm = }\,{\rm RT}\,{\rm ln}\,{\rm (N}_{{\rm M}_{\rm 1} } \, \cdot \,{\rm N}_{{\rm X}_{\rm 1} })\,{\rm + }\,{\rm N'}_{{\rm M}_{\rm 2} } \,{\rm N'}_{{\rm X}_{\rm 2} } \,\Delta {\rm G}_{{\rm M}_{\rm 2} {\rm X}_{\rm 2} }^{\rm 0} + {\rm N'}_{{\rm M}_{\rm 3} } {\rm N'}_{{\rm X}_{{\rm X}_{\rm 3} } } \Delta {\rm G}_{{\rm M}_{\rm 3} {\rm X}_{{\rm X}_{\rm 3} } }^{\rm 0} +\cdot\cdot\cdot, $$\end{document} wobei ΔGM2X2° die Änderung der freien Energie bei der Reaktion \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm M}_{\rm 1} {\rm X}_{\rm 1} \,{\rm + }\,{\rm M}_{\rm 2} {\rm X}_{\rm 2} \,{\rm = }\,{\rm M}_{\rm 1} {\rm X}_{\rm 2} \,{\rm + }\,{\rm M}_{\rm 2} {\rm X}_{\rm 1} $$\end{document} ist. N und N′ sind verschiedene Konzentrationsglieder. Die Anwendbarkeit dieser Gleichung wird an einem anderen metallurgischen Problem demonstriert, der Änderung der Aktivität des FeO mit der Zusammensetzung der Schlacke.Schließlich wird die Ausbildung zweier flüssiger Phasen und Abweichungen von der statistischen Verteilung der Ionen in der Schmelzmischung kurz diskutiert.
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    Zeitschrift für anorganische Chemie 277 (1954), S. 271-273 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die tertiären aliphatischen und hydroaromatischen Phosphine können auf Grund unserer Beobachtungen aus ihren CS2-Additionsverbindungen durch Zerlegen derselben in organischen Lösungsmitteln in einfacher Weise rein dargestellt werden. Nach ihren chemischen Eigenschaften formuliert man diese CS2-Verbindungen zweckmäßig als Molekülverbindungen.
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    Zeitschrift für anorganische Chemie 277 (1954) 
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    Keywords: Chemistry ; Inorganic Chemistry
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    Zeitschrift für anorganische Chemie 277 (1954), S. 274-286 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurden weiterhin Untersuchungen im Dreistoffsystem NaF—LiF—BeF2, das durch seine Modellbeziehungen zum wichtigen Silicatsystem CaO—MgO—SiO2 von Interesse ist, durchgeführt. Dabei wurde eine Verbindung Na3Li[BeF4]2 dargestellt, die als „abgeschwächtes Modell“ des Merwinits Ca3Mg[SiO4]2 im Sinne GOLDSCHMIDTS anzusehen ist. Na3Li[BeF4]2 kristallisiert monoklin-prismatisch, das Achsenverhältnis beträgt 0,68:1:1,28, β = 126°8′, die Größe der Elementarzelle ist a0 = 6,52, b0 = 9,62, c0 = 12,26 Å. Beim Erhitzen wandelt sich Na3Li[BeF4]2 in eine andere Modifikation um. Die Umwandlung erfolgt bei 300° C und ist enantiotrop. Die Verbindung schmilzt inkongruent bei 330° C. Weiterhin werden Pulverreaktionen zwischen Na2[BeF4] und Li2[BeF4] bei höheren Temperaturen beschrieben. Es folgt eine Gegenüberstellung der Eigenschaften des Merwinits und seines Fluoridmodells Na3Li[BeF4]2.
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    Zeitschrift für anorganische Chemie 277 (1954), S. 287-296 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird eine neue dynamische Methode zur Feststellung und Untersuchung des Oberflächen-Volumen-Mechanismus bei einigen heterogenen katalytischen Reaktionen beschrieben. Es wird ein Zusammenhang zwischen dem Reaktionsgang und den Versuchsbedingungen hinter dem Katalysator beobachtet.
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    Zeitschrift für anorganische Chemie 277 (1954), S. 297-314 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Umsatz von Kaliumthoriumnitrat K2Th(NO3) 6 in flüssigem Ammoniak mit steigenden Mengen Kaliumamids wurden folgende Bodenkörper erhalten: Thoriumimido-diamid HNTh(NH2)2(A), (HN)2ThNH2K (I), HNTh(NH2)3K (II), Th2(NH)3(NH2)4K2 (III). Alle Reaktionsprodukte sind nicht kristallin und stellen mehr oder weniger hochpolymere Verbindungen dar. Das wahrscheinlich primär entstehende Thorium(IV)- amid Th(NH2)4 zerfällt unterhalb 0° C spontan in A, das bei 25° in Th2(NH)3(NH2)2 (B) übergeht. Bei 100° C bildet sich hieraus Th(NH)2 (C) und weiter bei 130° C Th3N4 (D). Auch dieses Nitrid ist röntgenamorph (Flüssigkeitsdiagramm). A reagiert mit NH4J in flüssigem NH3 unter Bildung von Th(NH3)8J4; es reagiert also mit Ammono-Säuren und Basen (Bildung der Amidosalze I, II und III; amphoteres Verhalten). Dem Amidosalz II kann durch Reaktion mit einer äquivalenten Menge NH4J alles Kalium entzogen werden. Das hierbei primär entstehende Th(NH2)4 zerfällt spontan unter NH3- Abspaltung; bei 25° C wird Dithorium-triimido-diamid (B) erhalten. Durch thermischen Abbau gehen II und III in I über; bei 270° C entsteht das Nitridosalz K3Th3N5 (IV). Bei 290-425° C zersetzt sich IV unter Bildung von röntgenamorphem ThN.
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  • 67
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    Zeitschrift für anorganische Chemie 277 (1954), S. 172-180 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung von reinstem K2MnO4 wird beschrieben. Die thermische Zersetzung von K2MnO4 im O2- und N2-Strom im Temperaturbereich 500° bis 900° wird untersucht. Durch quantitative Aufarbeitung des Reaktionsproduktes wird gezeigt, daß diese Zersetzung im Prinzip stets nach der Gl. (3) K2MnO4 = 2 K3MnO4 + MnO2 + O2 erfolgt. Ein kleiner Teil von K2MnO4 geht dabei in einer Nebenreaktion in K2MnO3 über. Das nach obiger Gleichung als primäres Zersetzungsprodukt angenommene MnO2 verliert zusätzlich Sauerstoff, so daß tatsächlich MnO1,75-MnO1,80 resultiert. Es wird eine Methode zur quantitativen Bestimmung von Manganat(VI), Manganat(V) und höherem Manganoxyd nebeneinander angegeben.
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  • 68
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    Zeitschrift für anorganische Chemie 277 (1954), S. 201-204 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bestimmung des Indium-Schmelzpunktes zu 156,17 ± 0,050 mit Platin-Widerstandsthermometer und seine Benutzung zur Eichung von Thermoelementen.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 13-18 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Kojisäure-monomethyläther läßt sich durch Oxydation mit Salpetersäure oder Luftsauerstoff i. Ggw. eines Platin-Katalysators in Komensäure-methyläther überführen. Auf einem neuen Wege wird die 5-Stellung der Oxy-Gruppe in den aus Mekonsäure und Kojisäure erhaltenen Pyron- und Pyridonderivaten bestätigt und damit eine neuerdings vertretene abweichende Auffassung widerlegt.
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  • 70
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 81-86 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Di- und Trinitro-benzolderivate lassen sich in Äthylendiamin als mehrbasige Säuren potentiometrisch titrieren. Sie verhalten sich in diesem Lösungsmittel wie organische Antibasen (Lewis-Säuren). Wegen der beim Titrieren auftretenden Farbumschläge eignen sich die Nitroverbindungen als Indikatoren für die Alkalimetrie in nichtwäßrigen Lösungsmitteln.
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  • 71
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Umsetzung der 5-Amino-1.2.4-thiodiazole mit Methyljodid oder durch Ringschluß-Synthesen werden die im Kern methylierten Imino-thiodiazoline erhalten. Die exocyclisch methylierten Amine sind über die 5-Chlor-Verbindung zugänglich, gelegentlich auch durch Umlagerung aus dem entsprechenden Thiodiazolin. Beide Klassen, von deren Hauptvertretern eine Anzahl Substitutions- und Abbauprodukte hergestellt wurden, unterscheiden sich charakteristisch in ihren Basizitäten, UV-Spektren und Polarogrammen. Aus den Befunden wird geschlossen, daß die tautomeren 5-Amino-thiodiazole als Amine vorliegen.
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  • 72
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 127-129 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Indol wird in flüssigem Ammoniak ausschließlich am Stickstoff alkyliert.
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  • 73
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 123-127 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mit verdünnter Säure (pH ∼ 1) läßt sich aus der durch Dialyse gereinigten Mucoprotein-Fraktion des Kuh-Colostrums eine schön kristallisierende, niedrigmolekulare Substanz abspalten, deren Eigenschaften mit denjenigen der Sialinsäure von G. Blix und der Methoxyverbindung der Neuraminsäure von E. Klenk verglichen werden.
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  • 74
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 282-288 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es werden die Chlorderivate der drei möglichen Methyl-chlorsilane dargestellt und beschrieben.Die Chlorierung läßt sich beim Methyl-trichlor-silan leicht bis zum Ersatz aller Wasserstoffatome treiben, ohne daß Zwischenstufen gefaßt werden konnten, beim Dimethyl-dichlor-silan bis zur Substitution von fünf Wasserstoffatomen. Beim Trimethyl-chlorsilan können maximal acht Wasserstoffatome ersetzt werden.Das Sublimationsvermögen dieser Verbindungen ist an die Anwesenheit einer Trichlormethylgruppe im Molekül gebunden.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 300-314 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird über die Darstellung von α-Chlor-äthylschwefelchlorid sowie über die mannigfaltigen, mit dieser Verbindung durchführbaren Synthesen, die u.a. auch zur Bildung von Makromolekülen durch Polykondensation und Polymerisation führen, berichtet.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 325-330 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Einige weitere Alkylschwefelchloride werden beschrieben und mit diesen sowie mit Methyl- und Äthylschwefelchlorid eine Reihe neuer organischer Schwefelverbindungen dargestellt.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 345-349 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Darstellung gemischter Phenolester von Dicarbonsäuren und deren Umlagerung in ω-Oxyphenyl-ω-oxo-carbonsäuren durch Fries'sche Verschiebung beschrieben.
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  • 78
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Als erste Verbindungen mit dem Ringsystem des Thiopheno-2'.3': 3.4-thiophens werden beschrieben: Die 2.5-Dimethyl-Verbindung und deren Maleinsäure-anhydrid Addukt; die 4'-Oxy-Verbindung und deren Thioindigo.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 396-399 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es werden einige heterocyclische o-Oxy-azomethine dargestellt, die mit Uranylacetat entsprechende Urankomplexe liefern. Während die Azomethine I und II in Übereinstimmung mit den früheren Ergebnissen mit einem Azomethin-Anion und einem Uranyl, unter Haftenbleiben einer Acetoxy-Gruppe Komplexe bilden, entsteht aus dem Azomethin V ein Komplex, der unter Verdrängung beider Acetat-Anionen aus einem Uranyl und zwei Azomethin-Anionen zusammengesetzt ist.Auch in der Formazyl-Reihe wurde ein Urankomplex beschrieben, bei dem das Uran statt sechs, nur mit fünf Liganden verknüpft und infolgedessen koordinativ ungesättigt ist.
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  • 80
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Adynerin ist ein d-Diginose-Glykosid. Als Ursache der kardiotonischen Unwirksamkeit wird eine 3-(α)-Stellung der Oxygruppe im Adynerigenin angenommen. Während im Aglykon des Adynerins und des Isoadynerins die Doppelbindung Δ8:9-Stellung hat, wird sie bei der Säurehydrolyse zur Abspaltung des Zuckers nach Δ7:8 verschoben. Die Ultrarotspektren sind mit dieser Auffassung in Einklang. Danach muß auch Scillirosid die Doppelbindung in Δ8:9 aufweisen.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 423-435 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus dem Unverseifbaren der Artischocke (Cynara scolymus) wurden die Triterpenalkohole Taraxasterol und ψ-Taraxasterol isoliert, letzteres jedoch nur im Gemisch mit Taraxasterol im Verhältnis 1:1. Das in der Literatur beschriebene „Isolactucerol” wurde als identisch mit dem Gemisch Taraxasterol-ψ-Taraxasterol 1:1 erkannt; der Name “Isolactucerol“ ist daher entbehrlich. Die Untersuchungen zur Klärung der Lage der Doppelbindung in Taraxasterol und ψ-Taraxasterol führten zu den Formeln I bzw. II für die beiden Triterpenalkohole.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 443-446 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Natrium-cyanessigsäure-äthylester und Chlor-acetylchlorid ließen sich zum Hydrat des β-Oxo-α.δ-dicyan-adipinsäure-äthylesters (I) umsetzen, aus dem der wasserfreie Ester durch Entwässerung mit Alkohol erhalten wurde. Es werden Nebenprodukte der Reaktion und Verseifungsprodukte beschrieben.
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  • 83
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Indol und Diindolyl-(3.3′)-methane mit freien α-Stellungen reagieren mit Aldehyden unter Bildung von 5.6.7.12-Tetrahydro-indolo-(2.3-b)-carbazolen, während α-substituierte Diindolyl-(3.3′)-methane unter gleichen Bedingungen eine Aufspaltung zu einkernigen Indoleninderivaten erfahren. Auch im Verhalten gegenüber Ketonen zeigt sich ein grundlegender Unterschied zwischen Diindolyl-(3.3′)-methanen mit freien und solchen mit besetzten α-Stellungen. Letztere bilden mit Ketonen asymmetrische Indolyl-indolenyl-äthan-Derivate.
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  • 84
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Peroxydasewirkungen der Oxyhämoglobine von sieben verschiedenen Tierarten wurden miteinander verglichen. Die Aktivitäten erwiesen sich als deutlich verschieden.
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  • 85
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Der aus Zimtaldehyd und Lithiumaluminiumhydrid hergestellte Komplex wird zu Synthesen herangezogen.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 668-676 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die elektrolytische Oxydation von primären und sekundären Acetylenalkoholen führte in saurer Lösung zu Acetylencarbonsäuren und Acetylenketonen. Die Reaktion wurde in Abhängigkeit von elektrochemischen Faktoren untersucht.
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  • 87
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ausgehend vom 4-Carbäthoxy-3-methyl-cyclohexen-(2)-on-(1) (Hagemann-Ester) wird eine einfache 3-Stufen-Synthese der 3-Methyl-3-carboxy-cyclohexanon-(1)-propionsäure-(2β) beschrieben. Mittels Dieckmann-Kondensation ihres Esters erhält man einen Hydrindandioncarbonsäure-ester, der durch Verseifung und Decarboxylierung in das 8-Methyl-hydrindan-dion-(1.4) überführbar ist. Über die sterischen Verhältnisse beider Verbindungen können noch keine Aussagen gemacht werden.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 700-707 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus α-Halogen-ketonen entstehen mit Ammoniumformiat in Ameisensäure oder mit Formamid unter Zusatz von konz. Schwefelsäure in 2-Stellung nicht substituierte Oxazole. Für die Synthesen von Oxazolen und Imidazolen aus Halogenketonen mittels Formamids werden Reaktionsmechanismen aufgestellt.
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  • 89
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An dem Gallenweg-Röntgenkontrastmittel - dem Dinatriumsalz des Adipinsaure-bis-[2.4.6-trijod-3-carboxy-anilids]1) (I) - und der entsprechenden freien Säure ((I)-Säure) werden einige physikochemische Untersuchungen über UV-Spektrophotometrie, Kapillar- und Kolloideigenschaften, Löslichkeiten, elektrochemische und Dissoziationsverhältnisse, Refraktometrie, Dichte usw. beschrieben, z. Tl. im Vergleich mit dem Natriumsalz der 2.4.6-Trijod-3-acetamino-benzoesäure (II), der entspr. (II)-Säure und anderen Trijodbenzolderivaten. Hierbei wurden folgende Ergebnisse erhalten: 1Die Trijod-Substitution im Benzolkern bewirkt im UV-Spektrum eine starke Erhöhung des molaren Extinktionskoeffizienten und eine Vereinfachung des Spektrums.2Trijodbenzolderivate mit einer freien NH2-Gruppe zeigen ein kleines, zusätzliches Maximum im langwelligen UV.3Durch Wasserabspaltung entstehen bei der I-Säure Molekülaggregate vom 16 fachen Mol.-Gew. (im Durchschnitt) und bedingen kolloide Eigenschaften.4Gemäß ihrer Struktur zeigt I kapillaraktive Eigenschaften (Mizellbildung) und hat somit Ähnlichkeit mit den Seifen (ausgeprägte dynamische Oberflächenspannungserniedrigung).
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 707-711 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Ketogruppe des 1-C-Phenyl-2.3.;4.5-diisopropyliden-d-glucosons kann mit Lithiumaluminiumhydrid glatt in sterisch einheitlichem Sinne zur Oxygruppe reduziert werden, wobei die d(-)-Mandelsäure-Konfiguration an C1 auftritt. Der Konfigurationsbeweis erfolgte durch Methylierung und Perjodatspaltung zu d(-)-O-Methyl-mandelsäure.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 820-824 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzung von N.N'-Diphenyl-thioharnstoff mit Malonylchlorid ohne Lösungsmittel führte zum 6-Oxy-4′-oxo-2′-thio-1′.3′-diphenyl-1′.2′.3′.4′-tetrahydro-[pyrimidino-6′.5′ :2.3-γ-pyron] sowie zu einer Reihe weiterer Reaktionsprodukte.
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  • 92
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In Erweiterung einer von B. Emmert und M. Groll angegebenen Reaktion wird gezeigt, daß bei Einwirkung von Schwefel auf ein Gemisch von methylierten Heterocyclen mit aromatischen Aminen oder Nitro-Verbindungen bisher unbekannte Thioamide, Benzthiazole und Diaryl-amidine entstehen, und zwar einzeln oder nebeneinander.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 690-691 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die optische Spaltung von racem. α-Phenyl-äthylamin gelingt mit d-Weinsäure in Methanollösung, wobei das (-)-Amin erhalten wird. Die Abscheidung des (+)-Amins aus dem Gemisch mit dem Racemat erfolgt über das Sulfat.
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  • 94
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die drei stereoisomeren Dihydro-santene werden dargestellt und optisch untersucht. Ein durch katalytische Hydrierung von Santen erhaltenes Dihydro-santen erweist sich in bezug auf die Methylgruppen als endo-cis-Verbindung. Die Anlagerung von Wasserstoff erfolgt sterisch “von der Brücke her” und stellt einen weiteren Fall von “exo-Addition” vor.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 209-211 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung von 3.3-Dimethyl-1.5-diphenyl-pentan-dion-(1.5) aus β.β-Dimethyl-glutarsäure auf zwei verschiedenen Wegen wird beschrieben.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 211-215 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 2.3.4.6-Tetraacetyl-β-d-glucose läßt sich nach der Trifluoressigsäure-anhydrid-Methode von Stacey mit Benzoesäure zu einem Gemisch von α- und β-2.3.4.6-Tetraacetyl-benzoyl-d-glucose benzoylieren. Das Verhältnis α:β-Verbindung hängt von den Versuchsbedingungen ab. Aus Benzyl-β-d-glucosid ist durch Umsetzung mit Trifluoressigsäure-anhydrid und Natriumtrifluoracetat das 2.3.4.6- Tetrakis-trifluoracetyl-benzyl-β-d-glucosid vomSchmp. 102° leicht darstellbar; die Benzyl-Gruppe konnte aber durch katalytische Hydrierung nicht entfernt werden. Falls dies gelänge, wäre es durch Veresterung mit Carbonsäuren in 1-Stellung nach Stacey und Umesterung durch Erwärmen mit Methanol möglich gewesen, in 1-Stellung beliebig veresterte Glucosen (und andere Zucker) herzustellen. Schließlich wird die Pentakis-trifluoracetyl-β-d-glucose beschrieben.
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    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 228-231 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ausgehend von m-Nitro-benzaldehyd, wird unter Verwendung der Japp-Klingemann-Reaktion und der Fischer-Cyclisierung die Synthese der Indol-diessigsäuren-(3.4) und -(3.6) beschrieben. Die Säuren lassen sich zu den entsprechenden Dimethylindolen decarboxylieren.
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  • 98
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 237-247 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Addition von Maleinsäure-anhydrid an α-Brom-styrol verläuft unter Abspaltung von Bromwasserstoff und führt in glatter Reaktion zur 1.2-Dihydro-naphthalin-dicarbonsäure-(1.2), die sich successive in die isomeren 1.4- und 3.4-Dihydro-säuren umlagern läßt. In der Literatur beschriebene und auf anderen Wegen gewonnene Präparate werden in ihrer Struktur bestätigt oder berichtigt.Durch Einwirkung von Acrylsäure auf α-Brom-styrol läßt sich auf die gleiche Weise die noch unbekannte 1.2 Dihydro-naphthoesäure-(1) darstellen.Versuche einer Addition von β-Brom-styrol, α.β-Dibrom-styrol und β.β-Dibrom-styrol an Maleinsäure-anhydrid werden beschrieben.
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  • 99
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 87 (1954), S. 272-275 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus Resorcin und N.N'-Diphenyl-formamidin läßt sich durch Schmelzen i. Vak., wobei das gebildete Anilin laufend abdestilliert, der 2.4-Dioxy-isophthaladehyd, der bisher nicht leicht zugänglich war, in Ausbeuten von 21-24% d. Th. gewinnen. Sieben Derivate des Dialdehyds werden beschrieben.
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  • 100
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 87 (1954) 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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