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  • Chemistry  (14,308)
  • 551.46
  • 551.5
  • Aircraft Stability and Control
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  • 1
    Publication Date: 2021-07-20
    Description: A shell of subsiding air is generally known to develop around cumulus clouds and shield them from their environment. We seek here to improve our understanding of such shells by (a) revealing the detailed vertical and horizontal structure of shells surrounding both shallow and deeper clouds, and (b) identifying the mechanisms responsible for in‐shell subsidence generation and maintenance. To that end, a high‐resolution Cloud Resolving Model simulation of the shallow‐to‐deep convection transition over a tropical land surface is analysed with an emphasis on the cloud's near environment. Shells surrounding shallow and deep clouds are found to possess surprisingly similar characteristics. However important differences are observed near cloud top where the deepest clouds are associated with stronger subsidence and broader shells. In the convective outflow region, stronger in‐shell subsidence coincides with strong buoyancy reversal, but also with strong pressure gradients naturally generated by cloud‐top vortex dynamics. A more delicate balance between various processes takes place below, and in‐shell subsidence is only barely sustained as buoyancy reversal is largely compensated by pressure gradients. Finally, while evaporation is clearly the main source of buoyancy reversal everywhere around cloud edges, it is also shown that the downward transport of warmer air from aloft through the subsiding shells may compensate for evaporative cooling to slowly bring in‐shell buoyancy to a near‐neutral state. Overall, while it cannot be denied that evaporative cooling and buoyancy reversal play important roles in generating and sustaining in‐shell subsidence, the present results also emphasise that mechanical forcing at cloud top and downward transport within the shells should not be overlooked.
    Description: Narrow “shells” of subsiding air generally form around cumulus clouds, but the mechanisms responsible for their formation and maintenance are still debated. In this study, the dynamics of these shells is investigated using a high‐resolution simulation of idealized tropical convection. It is shown that in‐shell subsiding motions are generally driven by buoyancy reversal. However, mechanical forcing contributes at least equally at the top of all convective clouds. In addition, it is found that buoyancy reversal due to evaporative cooling may be offset by the downward transport of warmer air from aloft through the subsiding shells.
    Keywords: 551.5 ; cloud dynamics ; near‐cloud environment ; subsiding shells ; tropical convection
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  • 2
    Publication Date: 2021-07-20
    Description: Motivated by the question of whether and how wave–wave interactions should be implemented into atmospheric gravity‐wave parametrizations, the modulation of triadic gravity‐wave interactions by a slowly varying and vertically sheared mean flow is considered for a non‐rotating Boussinesq fluid with constant stratification. An analysis using a multiple‐scale WKBJ (Wentzel–Kramers–Brillouin–Jeffreys) expansion identifies two distinct scaling regimes, a linear off‐resonance regime, and a nonlinear near‐resonance regime. Simplifying the near‐resonance interaction equations allows for the construction of a parametrization for the triadic energy exchange which has been implemented into a one‐dimensional WKBJ ray‐tracing code. Theory and numerical implementation are validated for test cases where two wave trains generate a third wave train while spectrally passing through resonance. In various settings, of interacting vertical wavenumbers, mean‐flow shear, and initial wave amplitudes, the WKBJ simulations are generally in good agreement with wave‐resolving simulations. Both stronger mean‐flow shear and smaller wave amplitudes suppress the energy exchange among a resonantly interacting triad. Experiments with mean‐flow shear as strong as in the vicinity of atmospheric jets suggest that internal gravity‐wave dynamics are dominated in such regions by wave modulation. However, triadic gravity‐wave interactions are likely to be relevant in weakly sheared regions of the atmosphere.
    Description: This study explores wave–wave interactions of modulated internal gravity waves (GWs) in varying background flows using WKBJ techniques. The resulting ray‐tracing model (b) is compared to wave‐resolving LES (a). As a key result, we find that wave modulation partially suppresses the energy exchange in triadic GW interactions, and thus triadic GW interactions are likely to be relevant in weakly sheared regions of the atmosphere.
    Description: German Research Foundation (DFG) US National Science Foundation
    Keywords: 551.5 ; internal gravity waves ; parametrization ; ray‐tracing ; triadic wave–wave interaction ; wave modulation
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  • 3
    Publication Date: 2021-07-01
    Description: Subtropical seagrass meadows play a major role in the coastal carbon cycle, but the nature of air–water CO2 exchanges over these ecosystems is still poorly understood. The complex physical forcing of air–water exchange in coastal waters challenges our ability to quantify bulk exchanges of CO2 and water (evaporation), emphasizing the need for direct measurements. We describe the first direct measurements of evaporation and CO2 flux over a calcifying seagrass meadow near Bob Allen Keys, Florida. Over the 78‐d study, CO2 emissions were 36% greater during the day than at night, and the site was a net CO2 source to the atmosphere of 0.27 ± 0.17 μmol m−2 s−1 (x̅ ± standard deviation). A quarter (23%) of the diurnal variability in CO2 flux was caused by the effect of changing water temperature on gas solubility. Furthermore, evaporation rates were ~ 10 times greater than precipitation, causing a 14% increase in salinity, a potential precursor of seagrass die‐offs. Evaporation rates were not correlated with solar radiation, but instead with air–water temperature gradient and wind shear. We also confirm the role of convective forcing on night‐time enhancement and day‐time suppression of gas transfer. At this site, temperature trends are regulated by solar heating, combined with shallow water depth and relatively consistent air temperature. Our findings indicate that evaporation and air–water CO2 exchange over shallow, tropical, and subtropical seagrass ecosystems may be fundamentally different than in submerged vegetated environments elsewhere, in part due to the complex physical forcing of coastal air–sea gas transfer.
    Description: Deutscher Akademischer Austauschdienst http://dx.doi.org/10.13039/501100001655
    Description: National Science Foundation http://dx.doi.org/10.13039/100000001
    Keywords: 551.5 ; Florida ; Bob Allen Keys ; seagrass meadows ; air–water CO2 exchanges ; biometeorological measurements
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  • 4
    Publication Date: 2021-07-20
    Description: One important attribute of meteorological forecasts is their representation of spatial structures. While several existing verification methods explicitly measure a structure error, they mostly produce a single value with no simple interpretation. Extending a recently developed wavelet‐based verification method, this study separately evaluates the predicted spatial scale, orientation and degree of anisotropy. The scale component has been rigorously tested in previous work and is known to assess the quality of a forecast similar to other, established methods. However, directional aspects of spatial structure are less frequently considered in the verification literature. Since important weather phenomena related to fronts, coastlines and orography have distinctly anisotropic signatures, their representation in meteorological models is clearly of interest. The ability of the new wavelet approach to accurately evaluate directional properties is demonstrated using idealized and realistic test cases from the MesoVICT project. A comparison of precipitation forecasts from several forecasting systems reveals that errors in scale and direction can occur independently and should be treated as separate aspects of forecast quality. In a final step, we use the inverse wavelet transform to define a simple post‐processing algorithm that corrects the structural errors. The procedure improves visual similarity with the observations, as well as the objective scores.
    Description: Forecasts of precipitation fields are difficult to evaluate due to their complex, intermittent spatial structure. The SAD forecast verification method uses wavelets to compare the scale (colours in the top row), anisotropy (bottom, arrow length) and preferred direction (bottom, arrow angles) of simulated and observed fields. The new approach is successfully tested using data from the MesoVICT community project.
    Description: German Research Foundation (DFG)
    Keywords: 551.5 ; MesoVICT ; precipitation forecasts ; structure error ; verification ; wavelets
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  • 5
    Publication Date: 2021-07-03
    Description: The Southern Annular Mode (SAM) is the predominant atmospheric variability mode in the Southern Hemisphere. In this paper, we present the spatial variability results of the SAM pattern for the period 1979–2018. The SAM‐intrinsic pattern variability analysis is based on the principal component analysis (PCA), which is carried out for the ERA‐Interim 500 hPa geopotential height (GPH) data set. A spatiotemporally resolved data set of SAM pattern maps (PCA loadings) is derived by projecting monthly shifted sub‐sequences of SAM index values (PCA scores) on the corresponding GPH anomalies. The dominant SAM structure within single pattern fields is mapped automatically and can be interpreted as the Southern Hemisphere polar front. This data set allows an analysis of the geographical positions of the characteristic circumpolar SAM structure over four decades and shows considerable variability over space and time. Five different states of SAM patterns, which are associated with characteristic circulation anomalies during different phases of the study period, are identified. Station‐based Antarctic temperature anomalies can be synoptically explained by these circulation anomalies. The overall latitudinal trend of the SAM pattern indicates an intensification of the meridional structure, especially over the East Antarctic Southern Ocean. Furthermore, we show that the SAM pattern variability is significantly correlated with the Pacific Decadal Oscillation and the Atlantic Multidecadal Oscillation. Composites of 500 hPa GPH anomalies during the positive and negative phases of the respective indices indicate teleconnections with Pacific Decadal Oscillation and Atlantic Multidecadal Oscillation, and this can explain latitudinal trends of the SAM pattern.
    Description: Key Points: We present a new approach to examine the spatiotemporal Southern Annular Mode pattern variability. Station‐based Antarctic temperature anomalies are related to different structures of the Southern Annular Mode. The trend pattern shows an increasing meridional structure and correlations with Pacific and Atlantic multidecadal oscillations.
    Description: DLR Management Board: Young Investigator Group Leader Program
    Keywords: 551.5 ; Southern Annular Mode ; SAM pattern variability ; Antarctic circulation variability ; Antarctic station temperature ; PDO ; AMO
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  • 6
    Publication Date: 2021-07-03
    Description: We present a fully coupled soil‐atmosphere model that includes radiation in the energy balance of the coupling conditions between the two domains. The model is able to describe evaporation processes under the influence of turbulence, surface roughness, and soil heterogeneities and focuses specifically on the influence of radiation on the mass and energy transport across the soil‐atmosphere interface. It is shown that evaporation rates are clearly dominated by the diurnal cycle of solar irradiance. During Stage‐I evaporation maximum temperatures are regulated due to evaporative cooling, but after a transition into Stage‐II evaporation, temperatures rise tremendously. We compare two different soil types, a coarser, sandy soil and a finer, silty soil, and analyze evaporation rates, surface temperatures, and net radiation for three different wind conditions. The influence of surface undulations on radiation and evaporation is analyzed and shows that radiation can lead to different local drying patterns in the hills and the valleys of the porous medium, depending on the height of the undulations and on the direction of the Sun. At last a comparison of lysimeter measurement data to the numerical examples shows a good match for measured and calculated radiation values but evaporation rates are still overestimated in the model. Possible reasons for the discrepancy between measurement and model data are analyzed and are found to be uncertainties about the parameters close to the interface, which are decisive for determining evaporation rates.
    Description: Key Points: We demonstrate the influence of radiation on evaporation rates. The influence of surface undulations on radiation and evaporation is analyzed. Comparison with experimental data shows the importance of interface processes.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Keywords: 551.5 ; fully coupled soil‐atmosphere model ; evaporation and radiation ; turbulence
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  • 7
    Publication Date: 2021-07-03
    Description: By interacting with radiation, clouds modulate the flow of energy through the Earth system, the circulation of the atmosphere, and regional climate. We review the impact of cloud‐radiation interactions for the atmospheric circulation in the present‐day climate, its internal variability and its response to climate change. After summarizing cloud‐controlling factors and cloud‐radiative effects, we clarify the scope and limits of the Clouds On‐Off Klimate Model Intercomparison Experiment (COOKIE) and cloud‐locking modeling methods. COOKIE showed that the presence of cloud‐radiative effects shapes the circulation in the present‐day climate in many important ways, including the width of the tropical rain belts and the position of the extratropical storm tracks. Cloud locking, in contrast, identified how clouds affect internal variability and the circulation response to global warming. This includes strong, but model‐dependent, shortwave and longwave cloud impacts on the El‐Nino Southern Oscillation, and the finding that most of the poleward circulation expansion in response to global warming can be attributed to radiative changes in clouds. We highlight the circulation impact of shortwave changes from low‐level clouds and longwave changes from rising high‐level clouds, and the contribution of these cloud changes to model differences in the circulation response to global warming. The review in particular draws attention to the role of cloud‐radiative heating within the atmosphere. We close by raising some open questions which, among others, concern the need for studying the cloud impact on regional scales and opportunities created by the next generation of global storm‐resolving models. This article is categorized under: Climate Models and Modeling 〉 Knowledge Generation with Models
    Description: Clouds interact with radiation. We review the role of cloud‐radiation interactions in shaping the atmospheric circulation and thus regional climate and climate change. Figure from Blue Marble Collection of NASA Visible Earth.
    Description: U.S. Department of Energy's Office of Biological & Environmental Research
    Description: U.S. National Science Foundation
    Description: NERC CIRCULATES project
    Description: FONA: Research for Sustainable Development
    Description: German Ministry of Education and Research (BMBF) http://dx.doi.org/10.13039/501100002347
    Keywords: 551.5 ; circulation ; climate and climate change ; clouds ; global models ; radiation
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  • 8
    Publication Date: 2021-07-03
    Description: Proxy‐model comparisons show large discrepancies in the impact of volcanic aerosols on the hydrology of the Asian monsoon region (AMR). This was mostly imputed to uncertainties arising from the use of a single model in previous studies. Here we compare two groups of CMIP5 multimodel ensemble mean (MMEM) with the tree‐ring‐based reconstruction Monsoon Asia Drought Atlas (MADA PDSI), to examine their reliability in reproducing the hydrological effects of the volcanic eruptions in 1300–1850 CE. Time series plots indicate that the MADA PDSI and the MMEMs agree on the significant drying effect of volcanic perturbation over the monsoon‐dominated subregion, while disparities exist over the westerlies‐dominated subregion. Comparisons of the spatial patterns suggest that the MADA PDSI and the MMEMs show better agreement 1 year after the volcanic eruption than in the eruption year and in subregions where more tree‐ring chronologies are available. The MADA PDSI and the CMIP5 MMEMs agree on the drying effect of volcanic eruptions in western‐East Asia, South Asian summer monsoon, and northern East Asian summer monsoon (EASM) regions. Model results suggest significant wetting effect in southern EASM and western‐South Asia, which agrees with the observed hydrological response to the 1991 Mount Pinatubo eruption. Analysis on model output from the Last Millennium Ensemble project shows similar hydrological responses. These results suggest that the CMIP5 MMEM is able to reproduce the impact of volcanic eruptions on the hydrology of the southern AMR.
    Description: Key Points: Proxy and multimodel ensemble means agree (disagree) on post volcanic hydro‐responses over the Asian monsoon (westerlies)‐dominated subregion. Better agreement of spatial hydrological patterns is suggested 1 year after the eruption and in subregions with more tree‐ring data. Multimodel ensemble means can reproduce the hydrological response to volcanic perturbations in the southern Asian monsoon region.
    Keywords: 551.5 ; volcanic aerosol ; monsoon‐dominated subregion ; westerlies‐dominated subregion ; proxy data ; multimodel ensemble mean ; hydrological index
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  • 9
    Publication Date: 2021-07-03
    Description: The characterization of uncertainties in geophysical quantities is an important task with widespread applications for time series prediction, numerical modeling, and data assimilation. In this context, machine learning is a powerful tool for estimating complex patterns and their evolution through time. Here, we utilize a supervised machine learning approach to dynamically predict the spatiotemporal uncertainty of near‐surface wind velocities over the ocean. A recurrent neural network (RNN) is trained with reanalyzed 10 m wind velocities and corresponding precalculated uncertainty estimates during the 2012–2016 time period. Afterward, the neural network's performance is examined by analyzing its prediction for the subsequent year 2017. Our experiments show that a recurrent neural network can capture the globally prevalent wind regimes without prior knowledge about underlying physics and learn to derive wind velocity uncertainty estimates that are only based on wind velocity trajectories. At single training locations, the RNN‐based wind uncertainties closely match with the true reference values, and the corresponding intra‐annual variations are reproduced with high accuracy. Moreover, the neural network can predict global lateral distribution of uncertainties with small mismatch values after being trained only at a few isolated locations in different dynamic regimes. The presented approach can be combined with numerical models for a cost‐efficient generation of ensemble simulations or with ensemble‐based data assimilation to sample and predict dynamically consistent error covariance information of atmospheric boundary forcings.
    Description: Plain Language Summary: Machine learning is increasingly used for a wide range of applications in geosciences. In this study, we use an artificial neural network in the context of time series prediction. In particular, the goal is to use a neural network for learning spatial and temporal uncertainties that are associated with globally estimated wind velocities. Three well‐known wind velocity products are used for the time period 2012–2016 in different training, validation, and prediction scenarios. Our experiments show that a neural network can learn the prevailing global wind regimes and associate these with corresponding uncertainty estimates. Such a trained neural network can be used for different applications, for example, a cost‐efficient generation of ensemble simulations or for improving traditional data assimilation schemes.
    Description: Key Points: A recurrent neural network is set up to predict spatiotemporal uncertainties in wind velocity reanalyses. Global uncertainty maps can be derived from only few individual training locations. This method has benefits for time series prediction, ensemble simulations, and data assimilation.
    Keywords: 551.5 ; machine learning ; artificial neural network ; wind velocity ; atmospheric reanalysis ; ensemble simulation ; data assimilation
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  • 10
    Publication Date: 2021-04-22
    Description: Pluvial flood risk is mostly excluded in urban flood risk assessment. However, the risk of pluvial flooding is a growing challenge with a projected increase of extreme rainstorms compounding with an ongoing global urbanization. Considered as a flood type with minimal impacts when rainfall rates exceed the capacity of urban drainage systems, the aftermath of rainfall‐triggered flooding during Hurricane Harvey and other events show the urgent need to assess the risk of pluvial flooding. Due to the local extent and small‐scale variations, the quantification of pluvial flood risk requires risk assessments on high spatial resolutions. While flood hazard and exposure information is becoming increasingly accurate, the estimation of losses is still a poorly understood component of pluvial flood risk quantification. We use a new probabilistic multivariable modeling approach to estimate pluvial flood losses of individual buildings, explicitly accounting for the associated uncertainties. Except for the water depth as the common most important predictor, we identified the drivers for having loss or not and for the degree of loss to be different. Applying this approach to estimate and validate building structure losses during Hurricane Harvey using a property level data set, we find that the reliability and dispersion of predictive loss distributions vary widely depending on the model and aggregation level of property level loss estimates. Our results show that the use of multivariable zero‐inflated beta models reduce the 90% prediction intervalsfor Hurricane Harvey building structure loss estimates on average by 78% (totalling U.S.$3.8 billion) compared to commonly used models.
    Description: Key Points Recent severe pluvial flood events highlight the need to integrate pluvial flooding in urban flood risk assessment Probabilistic models provide reliable estimation of pluvial flood loss across spatial scales Beta distribution model reduces the 90% prediction interval for Hurricane Harvey building loss by U.S.$3.8 billion or 78%
    Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347
    Description: NSF GRFP
    Description: Fulbright Doctoral Program
    Keywords: 551.5 ; pluvial flooding ; loss modeling ; urban flooding ; probabilistic ; Hurricane Harvey ; climate change adaptation
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  • 11
    Publication Date: 2021-07-21
    Description: The mesosphere and lower thermosphere (MLT) region is dominated globally by dynamics at various scales: planetary waves, tides, gravity waves, and stratified turbulence. The latter two can coexist and be significant at horizontal scales less than 500 km, scales that are difficult to measure. This study presents a recently deployed multistatic specular meteor radar system, SIMONe Peru, which can be used to observe these scales. The radars are positioned at and around the Jicamarca Radio Observatory, which is located at the magnetic equator. Besides presenting preliminary results of typically reported large‐scale features, like the dominant diurnal tide at low latitudes, we show results on selected days of spatially and temporally resolved winds obtained with two methods based on: (a) estimation of mean wind and their gradients (gradient method), and (b) an inverse theory with Tikhonov regularization (regularized wind field inversion method). The gradient method allows improved MLT vertical velocities and, for the first time, low‐latitude wind field parameters such as horizontal divergence and relative vorticity. The regularized wind field inversion method allows the estimation of spatial structure within the observed area and has the potential to outperform the gradient method, in particular when more detections are available or when fine adaptive tuning of the regularization factor is done. SIMONe Peru adds important information at low latitudes to currently scarce MLT continuous observing capabilities. Results contribute to studies of the MLT dynamics at different scales inherently connected to lower atmospheric forcing and E‐region dynamo related ionospheric variability.
    Description: Plain Language Summary: The mesosphere and lower thermosphere (MLT) region is dominated by neutral wind dynamics with structure scales ranging from a few thousands of kilometers down to a few kilometers. In this work, we present a new state‐of‐the‐art ground‐based radar system using multistatic meteor scattering that allows tomographic studies of MLT wind dynamics at scales not possible before. Given the location of the radar network at the magnetic equator, its focus is on wind dynamics peculiar to equatorial latitudes. Two methods for estimating the mesospheric neutral wind field are used. One takes into account wind gradients in addition to mean wind (gradient method). The other estimates a spatially resolved wind vector field and uses an additional mathematical constraint that produces smooth wind field solutions (regularized wind field inversion method). Using the gradient method, the vertical wind estimate is improved. For the first time at MLT equatorial latitudes, parameters familiar to meteorologists, such as horizontal divergence and relative vorticity are obtained. Measurements from this new system have the potential to contribute to coupling studies of the atmosphere and the ionosphere at low latitudes.
    Description: Key Points: Measurements of horizontal wind gradients at low‐latitude mesosphere and lower thermosphere altitudes. These gradients of the horizontal winds show strong temporal and altitude variability that are not observed at high latitudes. Improved vertical winds are obtained using a gradient wind field method inherently free from horizontal divergence contamination.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: NSF, Directorate for Geosciences (GEO) http://dx.doi.org/10.13039/100000085
    Keywords: 551.5 ; low latitude mesosphere ; MLT dynamics ; MLT horizontal divergence ; MLT vorticity ; multistatic radar observations ; vertical velocity
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  • 12
    Publication Date: 2021-07-20
    Description: Cold pools originate from evaporation in precipitating downdraughts and spread as density currents at the surface. Vertical motion at the leading edge of the cold pool is an important trigger for new convective cells in organised convective storms. However, these motions are poorly resolved at the grid lengths of a kilometre or more used in convection‐permitting models. Consequently, the simulated gust fronts do not trigger enough new convection, leading to precipitation deficits and a lack of convective organization. To address these deficits, we introduce a cold pool perturbation (CPP) scheme that strengthens vertical velocity at the simulated cold pool gust fronts. This is achieved by relaxing the vertical velocity in the gust front region towards a target value derived from similarity theory. Applying the CPP scheme for simulations of a highly convective 10‐day period, we find increased precipitation amplitudes during the afternoon. There is also evidence for improvements in the location of precipitation and for stronger organization of convection, although substantial errors remain. The cold pools themselves become more frequent, larger and more intense. An additional potentially beneficial influence was found for convective initiation at sea breeze fronts.
    Description: We develop a cold pool perturbation scheme which strengthens the too weak vertical velocities at cold pool gust fronts in convection‐permitting models. In so doing, cold‐pool‐driven convective initiation is enhanced and simulated precipitation improved.
    Keywords: 551.5 ; cold pools ; convective organization ; deep convection ; density currents ; gust fronts
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  • 13
    Publication Date: 2021-07-20
    Description: The transport of trace gases by the atmospheric circulation plays an important role in the climate system and its response to external forcing. Transport presents a challenge for Atmospheric General Circulation Models (AGCMs), as errors in both the resolved circulation and the numerical representation of transport processes can bias their abundance. In this study, two tests are proposed to assess transport by the dynamical core of an AGCM. To separate transport from chemistry, the tests focus on the age‐of‐air, an estimate of the mean transport time by the circulation. The tests assess the coupled stratosphere–troposphere system, focusing on transport by the overturning circulation and isentropic mixing in the stratosphere, or Brewer–Dobson Circulation, where transport time‐scales on the order of months to years provide a challenging test of model numerics. Four dynamical cores employing different numerical schemes (finite‐volume, pseudo‐spectral, and spectral‐element) and discretizations (cubed sphere versus latitude–longitude) are compared across a range of resolutions. The subtle momentum balance of the tropical stratosphere is sensitive to model numerics, and the first intercomparison reveals stark differences in tropical stratospheric winds, particularly at high vertical resolution: some cores develop westerly jets and others easterly jets. This leads to substantial spread in transport, biasing the age‐of‐air by up to 25% relative to its climatological mean, making it difficult to assess the impact of the numerical representation of transport processes. This uncertainty is removed by constraining the tropical winds in the second intercomparison test, in a manner akin to specifying the Quasi‐Biennial Oscillation in an AGCM. The dynamical cores exhibit qualitative agreement on the structure of atmospheric transport in the second test, with evidence of convergence as the horizontal and vertical resolution is increased in a given model. Significant quantitative differences remain, however, particularly between models employing spectral versus finite‐volume numerics, even in state‐of‐the‐art cores.
    Description: The climatological and zonal mean zonal wind ū (m·s−1), as simulated by two different dynamical cores, (left) pseudospectral (GFDL‐PS) and (right) finite‐volume (CAM‐FV), with (top) 40 vertical levels and (bottom) 80 vertical levels. With higher vertical resolution, the pseudospectral core develops westerlies in the tropical stratosphere between 20 and 80 hPa, while the finite‐volume core consistently simulates easterlies at both vertical resolutions. Both cores have comparable horizontal resolution. The contour interval is 10 m·s−1.
    Description: US National Science Foundation
    Keywords: 551.5 ; age of air ; Brewer–Dobson circulation ; dynamical cores ; stratospheric dynamics ; tracer transport.
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  • 14
    Publication Date: 2021-06-27
    Description: In coastal marine environments, physical and biological forces can cause dynamic pH fluctuations from microscale (diffusive boundary layer [DBL]) up to ecosystem‐scale (benthic boundary layer [BBL]). In the face of ocean acidification (OA), such natural pH variations may modulate an organism's response to OA by providing temporal refugia. We investigated the effect of pH fluctuations, generated by the brown alga Fucus serratus' biological activity, on the calcifying epibionts Balanus improvisus and Electra pilosa under OA. For this, both epibionts were grown on inactive and biologically active surfaces and exposed to (1) constant pH scenarios under ambient (pH 8.1) or OA conditions (pH 7.7), or (2) oscillating pH scenarios mimicking BBL conditions at ambient (pH 7.7–8.6) or OA scenarios (pH 7.4–8.2). Furthermore, all treatment combinations were tested at 10°C and 15°C. Against our expectations, OA treatments did not affect epibiont growth under constant or fluctuating (BBL) pH conditions, indicating rather high robustness against predicted OA scenarios. Furthermore, epibiont growth was hampered and not fostered on active surfaces (fluctuating DBL conditions), indicating that fluctuating pH conditions of the DBL with elevated daytime pH do not necessarily provide temporal refugia from OA. In contrast, results indicate that factors other than pH may play larger roles for epibiont growth on macrophytes (e.g., surface characteristics, macrophyte antifouling defense, or dynamics of oxygen and nutrient concentrations). Warming enhanced epibiont growth rates significantly, independently of OA, indicating no synergistic effects of pH treatments and temperature within their natural temperature range.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: 551.46 ; coastal marine environments ; calcifying marine epibionts
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  • 15
    Publication Date: 2021-07-03
    Description: The use of machine learning based on neural networks for cloud microphysical parameterizations is investigated. As an example, we use the warm‐rain formation by collision‐coalescence, that is, the parameterization of autoconversion, accretion, and self‐collection of droplets in a two‐moment framework. Benchmark solutions of the kinetic collection equations are performed using a Monte Carlo superdroplet algorithm. The superdroplet method provides reliable but noisy estimates of the warm‐rain process rates. For each process rate, a neural network is trained using standard machine learning techniques. The resulting models make skillful predictions for the process rates when compared to the testing data. However, when solving the ordinary differential equations, the solutions are not as good as those of an established warm‐rain parameterization. This deficiency can be seen as a limitation of the machine learning methods that are applied, but at the same time, it points toward a fundamental ill‐posedness of the commonly used two‐moment warm‐rain schemes. More advanced machine learning methods that include a notion of time derivatives, therefore, have the potential to overcome these problems.
    Description: Plain Language Summary: In our work, we are trying to teach a computer how rain forms in clouds. We show that computer hundreds of cases in the form of data. To be honest, the data are not real data but only results of simulations with a more complicated computer model. This complicated model can track the collisions of 10,000 of droplets, and we save all that data about the growth of the droplets into larger raindrops. This is what we then give to the simpler computer model to teach it something about clouds and rain. Afterward, it can make pretty good predictions about which clouds will rain and how long it will take them to produce the first rain. Unfortunately, the current machine learning methods are still a bit stupid because they only learn from the data but do not understand the mathematics and the physics behind the data. Therefore, the new computer model is still not as good at predicting rain as some clever mathematical formulas that were developed 20 years ago. Maybe we first have to teach the computer model more about calculus before it can learn to predict rain.
    Description: Key Points: Machine learning is successfully applied to the warm‐rain parameterization problem. Training and testing data for the warm‐rain kinetic collection equation are provided using the superdroplet method. Standard training methods show some limitations for the resulting ODE system.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Keywords: 551.5 ; cloud physics ; machine learning ; autoconversion ; warm‐rain parameterization
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  • 16
    Publication Date: 2021-07-04
    Description: Mesospheric winds from three longitudinal sectors at 65°N and 54°N latitude are combined to diagnose the zonal wave numbers (m) of spectral wave signatures during the Southern Hemisphere sudden stratospheric warming (SSW) 2019. Diagnosed are quasi‐10‐ and 6‐day planetary waves (Q10DW and Q6DW, m = 1), solar semidiurnal tides with m = 1, 2, 3 (SW1, SW2, and SW3), lunar semidiurnal tide, and the upper and lower sidebands (USB and LSB, m = 1 and 3) of Q10DW‐SW2 nonlinear interactions. We further present 7‐year composite analyses to distinguish SSW effects from climatological features. Before (after) the SSW onset, LSB (USB) enhances, accompanied by the enhancing (fading) Q10DW, and a weakening of climatological SW2 maximum. These behaviors are explained in terms of Manley‐Rowe relation, that is, the energy goes first from SW2 to Q10DW and LSB, and then from SW2 and Q10DW to USB. Our results illustrate that the interactions can explain most wind variabilities associated with the SSW.
    Description: Plain Language Summary: Sudden stratospheric warming events occur typically over the winter Arctic and are well known for being accompanied by various tides and Rossby waves. A rare SSW occurred in the Southern Hemisphere in September 2019. Here, we combine mesospheric observations from the Northern Hemisphere to study the wave activities before and during the warming event. A dual‐station approach is implemented on high‐frequency‐resolved spectral peaks to diagnose the horizontal scales of the dominant waves. Diagnosed are multiple tidal components, multiple Rossby normal modes, and two secondary waves arising from nonlinear interactions between a tide component and a Rossby wave. Most of these waves do not occur in a climatological sense and occur around the warming onset. Furthermore, the evolution of these waves can be explained using theoretical energy arguments.
    Description: Key Points: Mesospheric winds from multiple longitudes in the NH are combined to diagnose zonal wave numbers of waves during the Antarctic SSW 2019. Diagnosed are Q6DW, Q10DW, M2, SW1, SW2, SW3, and LSB and USB of Q10DW‐SW2 nonlinear interactions. LSB and USB are generated asynchronously, during which their parent waves evolve following the Manley‐Rowe energy relations.
    Description: National Natural Science Foundation of China (NSFC) http://dx.doi.org/10.13039/501100001809
    Description: National Science Foundation (NSF) http://dx.doi.org/10.13039/100000001
    Description: German Research Foundation (DFG)
    Keywords: 551.5 ; sudden stratospheric warming (SSW) ; semidiurnal tides ; nonlinear interactions ; quasi‐10‐day wave ; quasi‐6‐day wave ; Manley‐Rowe relation
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  • 17
    Publication Date: 2021-07-01
    Description: Short‐term global ensemble predictions of rainfall currently have no skill over northern tropical Africa when compared to simple climatology‐based forecasts, even after sophisticated statistical postprocessing. Here, we demonstrate that 1‐day statistical forecasts for the probability of precipitation occurrence based on a simple logistic regression model have considerable potential for improvement. The new approach we present here relies on gridded rainfall estimates from the Tropical Rainfall Measuring Mission for July‐September 1998–2017 and uses rainfall amounts from the pixels that show the highest positive and negative correlations on the previous two days as input. Forecasts using this model are reliable and have a higher resolution and better skill than climatology‐based forecasts. The good performance is related to westward propagating African easterly waves and embedded mesoscale convective systems. The statistical model is outmatched by the postprocessed dynamical forecast in the dry outer tropics only, where extratropical influences are important.
    Description: Plain Language Summary: Forecasts of precipitation for the next few days based on state‐of‐the‐art weather models are currently inaccurate over northern tropical Africa, even after systematic forecast errors are corrected statistically. In this paper, we show that we can use rainfall observations from the previous 2 days to improve 1‐day predictions of precipitation occurrence. Such an approach works well over this region, as rainfall systems tend to travel from the east to the west organized by flow patterns several kilometers above the ground, called African easterly waves. This statistical forecast model requires training over a longer time period (here 19 years) to establish robust relationships on which future predictions can be based. The input data employed are gridded rainfall estimates based on satellite data for the African summer monsoon in July to September. The new method outperforms all other methods currently available on a day‐to‐day basis over the region, except for the dry outer tropics, where influences from midlatitudes, which are better captured by weather models, become more important.
    Description: Key Points: Raw and statistically postprocessed global ensemble forecasts fail to predict West African rainfall occurrence. A logistic regression model using observations from preceding days outperforms all other types of forecasts. The skill of the statistical model is mainly related to propagating African easterly waves and mesoscale convective systems.
    Description: Deutsche Forschungsgemeinschaft
    Description: Klaus Tschira Stiftung
    Keywords: 551.5 ; forecasting ; logistic regression ; postprocessing ; precipitation ; tropical convection ; West Africa
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  • 18
    Publication Date: 2021-07-03
    Description: The High Asia Refined analysis (HAR) is a regional atmospheric data set generated by dynamical downscaling of the Final operational global analysis (FNL) using the Weather Research and Forecasting (WRF) model. It has been successfully and widely utilized. A new version (HAR v2) with longer temporal coverage and extended domains is currently under development. ERA5 reanalysis data is used as forcing data. This study aims to find the optimal set‐up for the production of the HAR v2 to provide similar or even better accuracy as the HAR. First, we conducted a sensitivity study, in which different cumulus, microphysics, planetary boundary layer, and land surface model schemes were compared and validated against in situ observations. The technique for order preference by similarity to the ideal solution (TOPSIS) method was applied to identify the best schemes. Snow depth in ERA5 is overestimated in High Mountain Asia (HMA) and causes a cold bias in the WRF output. Therefore, we used Japanese 55‐year Reanalysis (JRA‐55) to correct snow depth initialized from ERA5 based on the linear scaling approach. After applying the best schemes identified by the TOPSIS method and correcting the initial snow depth, the model performance improves. Finally, we applied the improved set‐up for the HAR v2 and computed a one‐year run for 2011. Compared to the HAR, the HAR v2 has a better representation of air temperature at 2 m. It produces slightly higher precipitation amounts, but the spatial distribution of seasonal mean precipitation is closer to observations.
    Description: German Federal Ministry of Education and Research (BMBF) http://dx.doi.org/10.13039/501100002347
    Keywords: 551.5 ; cold bias ; dynamical downscaling ; ERA5 ; HAR ; High Mountain Asia ; snow depth ; WRF
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  • 19
    Publication Date: 2021-07-20
    Description: A non‐eddy‐resolving microscale model is applied to simulate convection over three different leads (elongated channels in sea ice), which were observed by aircraft over the Arctic Marginal Ice Zone in 2013. The study aims to evaluate the quality of a local and a non‐local turbulence parametrization. The latter represents a lead‐width‐dependent approach for the turbulent fluxes designed for idealised conditions of a lead‐perpendicular, near‐neutral inflow in an atmospheric boundary layer (ABL) capped by a strong inversion at around 250 to 350 m height. The observed cases considered here are also characterised by an almost lead‐perpendicular flow but, in comparison to the idealised conditions, our analysis covers effects in stable inflow conditions and a much shallower ABL. The model simulations are initialised with observed surface parameters and upwind profiles, and the results are compared with measurements obtained above and downwind of the leads. The basic observed features related to the lead‐generated convection can be reproduced with both closures, but the observed plume inclination and vertical entrainment near the inversion layer by the penetrating plume are underestimated. The advantage of the non‐local closure becomes obvious by the more realistic representation of regions with observed vertical entrainment or where the observations hint at counter‐gradient transport. It is shown by comparison with the observations that results obtained with the non‐local closure can be further improved by including the determination of a fetch‐dependent inversion height and by specifying a parameter determining the plume inclination as a function of the upwind ABL stratification. Both effects improve the representation of fluxes, boundary‐layer warming, and vertical entrainment. The model is also able to reproduce the observed vanishing of a weak low‐level jet over the lead, but its downwind regeneration and related momentum transport are not always well captured, irrespective of the closure used.
    Description: In typical springtime conditions of a cold atmospheric flow over the warm surfaces of leads, which are open‐water channels in sea ice, strong convective plumes are generated which have a large impact on atmospheric boundary‐layer characteristics. Here, a small‐scale model is applied to simulate such situations and model results obtained with different turbulence parametrizations are evaluated using airborne measurements. Based on the observations, a non‐local parametrization developed for the small‐scale modelling of the inhomogeneous convection over leads is further improved.
    Description: Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) via the Transregional Collaborative Research Center ArctiC Amplification (AC)3 (project number 268020496 TRR 172) and via the priority program SPP 1158 (grant LU 818/5‐1)
    Keywords: 551.5 ; aircraft observations ; atmospheric boundary layer ; convection over leads ; counter‐gradient transport ; entrainment ; microscale model ; sea ice ; turbulence parametrization
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  • 20
    Publication Date: 2021-07-21
    Description: The growth and decay mechanisms of barrier layers in the northwestern tropical Atlantic are studied by investigating small‐scale processes embedded in the regional circulation of the tropical Atlantic using output from an eddy‐resolving numerical simulation at 4 km resolution forced by an atmospheric reanalysis. The simulation reproduces well the temporal and spatial patterns of barrier layer thickness (BLT) estimated with Argo and CTD in situ profiles. As seen from an analysis of the salinity and temperature vertical gradient balances, localized large barrier layers form inside North Brazil Current rings during late‐June to July because of a thickening of the isothermal layer in the rings due to horizontal temperature advection, stretching of isotherms and tilting of temperature fronts. These barrier layers decay when the isothermal layer reduces again due to the above mechanisms. Further to the north, along the North Equatorial Current, the seasonal variability of BLT is highly pronounced. Thick winter (January to early March) barrier layers locally grow as the base of the mixed layer shoals mainly due to a tilting of the salinity fronts and partly due to stretching of the isohalines, horizontal salt advection and vertical turbulent mixing. The short‐term barrier layers in this case decay due to a deepening of the mixed layer, whereas they get completely eroded in spring by a shoaling of the isothermal layer due to surface temperature stratification. This work highlights that barrier layers are localized phenomena at times growing solely due to ocean dynamics, without a surface freshwater influx.
    Description: Plain Language Summary: Oceanic barrier layers exist in regions where salinity is more dominant than temperature in determining upper ocean density. Those layers lie between the bases of a constant‐density layer and a constant‐temperature layer. Barrier layers prevent vertical exchange of energy and mass between the near‐surface and the deep ocean, thus influencing air‐sea interaction. In the western tropical Atlantic, a warmer sea surface due to the presence of barrier layers can fuel hurricanes. Freshwater from the Amazon River and rainfall facilitate the growth of barrier layers, but the dynamics of their evolution are unclear. In this work, we identify/quantify the growth and decay mechanisms of barrier layers using a 4 km resolution simulation. Barrier layers grow/decay inside North Brazil Current eddies in summer because of deepening/shoaling of the constant‐temperature layer inside the eddies due to horizontal heat transport. Further north, barrier layers grow in winter as the constant‐density layer shoals mainly due to northwestward surface freshwater flow and equatorward subsurface salty water flow. Those barrier layers decay when the constant‐density layer deepens, whereas are destroyed when the constant‐temperature layer shoals in spring due to surface heating. These novel results improve the knowledge on barrier layers and help representing them in climate models.
    Description: Key Points: The North Brazil and North Equatorial Currents are two regions with quasi‐permanent barrier layers in the northwestern tropical Atlantic Large barrier layer thickness (BLT) within the rings occurs during June‐July due to a thickening of the isothermal layer within the eddies Large winter BLT in North Equatorial Current is due to tilting of salinity fronts, stretching of isohalines, advection and turbulent mixing
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Keywords: 551.46 ; northwestern tropical Atlantic ; barrier layers
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  • 21
    Publication Date: 2021-07-21
    Description: This study presents a comprehensive comparison of the impact of solar activity on forecasting the upper atmosphere through assimilation of radio occultation (RO)‐derived electron density (Ne) into a physics‐based model (TIE‐GCM) using an ensemble Kalman filter (KF). Globally abundant RO‐derived Ne offers one of the most promising means to test the effect of assimilation on the model forecasted state on a global scale. This study emphasizes the importance of understanding how the assimilation results vary with solar activity, which is one of the main drivers of thermosphere‐ionosphere dynamics. This study validates the forecast states with independent RO‐derived GRACE (Gravity Recovery and Climate Experiment mission) Ne data. The principal result of the study is that the agreement between forecast Ne and data is better during solar minimum than solar maximum. The results also show that the agreement between data and forecast is mostly better than that of the standalone TIE‐GCM driven with observed geophysical indices. The results emphasize that TIE‐GCM significantly underestimate Ne in altitudes below 250 km and the assimilation of Ne is not as effective in these lower altitudes as it is in higher altitudes. The results demonstrate that assimilation of Ne significantly impacts the neutral mass density estimates via the KF state vector—the impact is larger during solar maximum than solar minimum relative to a control case that does not assimilate Ne. The results are useful to explain the inherent model bias, to understand the limitations of the data, and to demonstrate the capability of the assimilation technique.
    Description: Key Points: Investigates the impact of solar activity on forecasting through assimilation of COSMIC‐Ne into a physics‐based upper atmosphere model. The agreement between hourly forecasted Ne and data is better during solar minimum than solar maximum. The assimilation of COSMIC‐Ne into TIE‐GCM significantly influences the neutral dynamics of the thermosphere.
    Description: National Natural Science Foundation of China (NSFC) http://dx.doi.org/10.13039/501100001809
    Description: National Science Foundation (NSF) http://dx.doi.org/10.13039/100000001
    Keywords: 551.5 ; COSMIC ; data assimilation ; ensemble Kalman filter ; ionosphere forecasts ; neutral mass density forecasts ; TIE‐GCM ; upper atmosphere ; impact of solar activity ; thermosphere-ionosphere dynamics
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  • 22
    Publication Date: 2021-07-04
    Description: We present a mechanism for self‐sustained ocean circulation changes that cause abrupt temperature changes over Greenland in a multimillennial climate model simulation with glacial CO2 concentrations representative of Marine Isotope Stage 3. The Atlantic meridional overturning circulation (AMOC) and the subpolar gyre (SPG) oscillate on millennial time scales. When the AMOC is strong, the SPG is weak and contracted; when the AMOC is weak, the SPG is strong and extensive. The coupling between the two systems via wind‐driven and density‐driven feedbacks is key to maintaining the oscillations. The SPG controls the transport of heat and salt into the deep‐water formation sites and thus controls the AMOC strength. The strength and location of the deep‐water formation affect the density‐driven part of the SPG and thus control the mean strength and extent of the SPG. This mechanism supports the hypothesis that coupled ocean‐ice‐atmosphere interactions could have triggered abrupt glacial climate change.
    Description: Plain Language Summary: Between 57.000 and 29.000 years ago, the last glacial period was marked by several abrupt warming and cooling events over Greenland and the North Atlantic. Understanding the mechanism behind these so‐called Dansgaard‐Oeschger events increases our understanding of possible tipping points that cause abrupt change in the Earth system. The role of the ocean in causing these events is still a topic of debate. We find abrupt changes in the North Atlantic circulation that resemble Dansgaard‐Oeschger events in a simulation with a state‐of‐the‐art climate model. These simulated ocean circulation changes are generated without adding external triggers such as meltwater from glaciers. Instead, the events are generated by the interaction of the two large‐scale current systems in the North Atlantic—the Atlantic meridional overturning circulation (AMOC) and the North Atlantic subpolar gyre (SPG). Both current systems are affected by changes in surface winds and the density pattern of the North Atlantic. We find that the location where the densest water is formed controls how the SPG interacts with the AMOC. Under favorable conditions, the effects of wind and density combine in such a way that changes in the SPG cause abrupt changes in the AMOC.
    Description: Key Points: Millennial‐scale, self‐sustained oscillations of the ocean circulation occur in a climate model simulation. The oscillations are driven by the interaction between the Atlantic meridional overturning circulation (AMOC) and the subpolar gyre (SPG). The AMOC‐SPG coupling is controlled by a wind‐driven and a density‐driven feedback; the coupling sign depends on the dominant feedback.
    Keywords: 551.5 ; AMOC ; subpolar gyre ; abrupt climate change ; climate modeling ; Marine Isotope Stage 3
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  • 23
    Publication Date: 2021-07-04
    Description: In order to enhance our understanding of clouds and their microphysical processes, it is crucial to exploit both observations and models. Local observations from ground‐based remote sensing sites provide detailed information on clouds, but as they are limited in dimension, there is no straightforward way to use them to guide large‐scale model development. We show that large‐eddy simulations (LES) performed on similar temporal and spatial scales as the local observations can bridge this gap. Recently, LES with realistic topography and lateral boundary conditions became feasible for domains spanning several 100 km. In this study, we show how these simulations can be linked to observations of the Jülich Observatory for Cloud Evolution (JOYCE) for a 9‐day period in spring 2013. We discuss the advantages and disadvantages of very large versus small but more constrained domains as well as the differences compared to more idealized setups. The semi‐idealized LES include time‐varying forcing but are run with homogeneous surfaces and periodic boundary conditions. These assumptions seem to be the reason why they struggle to represent the observed varying conditions. The simulations using the “realistic” setup are able to represent the general cloud structure (timing, height, phase). It seems that the smaller and more constrained domain allows for a tighter control on the synoptic situation and is the preferred choice to ensure the comparability to the local observations. These simulations together with measures as the shown Hellinger distance will allow us to gain more insights into the representativeness of column measurements in the future.
    Description: Plain Language Summary: Clouds are still a cause for uncertainty in our understanding of climate and climate feedbacks. Due to the large range of involved scales—from small droplets up to storm systems—their representation in weather and climate models is an ongoing challenge. While new and sophisticated measurements of the atmospheric column could provide new insights into important processes, their linking to models is not trivial and is ongoing research. In this study, we are presenting and exploring different approaches to combine local observations of clouds with state‐of‐the‐art high‐resolution simulations. And we are presenting a setup, which shows a promising representation of the observed clouds and is constrained enough to be applicable for long‐term statistics—one of the key requirements for improvements and evaluation clouds in of weather and climate models.
    Description: Key Points: Large‐eddy simulations including external variability can bridge the gap between ground‐based observations of clouds and large‐scale models. For comparison with local observations, it is important to take external variability (e.g., large‐scale forcing and surface) into account. ICON‐LEM offers new possibilities to simulate small scales while considering external variability.
    Keywords: 551.5 ; clouds ; heterogeneity ; ICON‐LEM ; large‐scale forcing ; LES ; remote sensing
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  • 24
    Publication Date: 2021-04-29
    Description: Visual observations from the ground and from a glider soaring in the lowermost stratosphere revealed the existence of stratospheric mother‐of‐pearl clouds above El Calafate in the lee of the Andes on 11 September 2019. The appearance of these clouds is rather unusual considering the time – end of the austral winter – and the location at about 50°S, being far away from Antarctica. This paper presents the available observations and describes the overall meteorological situation that was related to the earliest sudden stratospheric warming recorded so far in the Southern Hemisphere. By using high‐resolution numerical simulations, we show evidence of mountain waves propagating up to the stratosphere that are responsible for generating the localised cold stratospheric temperature anomalies required for ice cloud formation. Snapshots of a mother‐of‐pearl cloud from the camera installed at the PERLAN 2 aircraft's tail wing. image
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: 551.5 ; Argentina ; ice cloud formation
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  • 25
    Publication Date: 2021-06-27
    Description: Understanding groundwater–surface water (GW–SW) interactions is vital for water management in karstic catchments due to its impact on water quality. The objective of this study was to evaluate and compare the applicability of seven environmental tracers to quantify and localize groundwater exfiltration into a small, human‐impacted karstic river system. Tracers were selected based on their emission source to the surface water either as (a) dissolved, predominantly geogenic compounds (radon‐222, sulphate and electrical conductivity) or (b) anthropogenic compounds (predominantly) originating from wastewater treatment plant (WWTP) effluents (carbamazepine, tramadol, sodium, chloride). Two contrasting sampling approaches were compared (a) assuming steady‐state flow conditions and (b) considering the travel time of the water parcels (Lagrangian sampling) through the catchment to account for diurnal changes in inflow from the WWTP. Spatial variability of the concentrations of all tracers indicated sections of preferential groundwater inflow. Lagrangian sampling techniques seem highly relevant for capturing dynamic concentration patterns of WWTP‐derived compounds. Quantification of GW inflow with the finite element model FINIFLUX, based on observed in‐stream Rn activities led to plausible fluxes along the investigated river reaches (0.265 m3 s−1), while observations of other natural or anthropogenic environmental tracers produced less plausible water fluxes. Important point sources of groundwater exfiltration can be ascribed to locations where the river crosses geological fault lines. This indicates that commonly applied concepts describing groundwater–surface water interactions assuming diffuse flow in porous media are difficult to transfer to karstic river systems whereas concepts from fractured aquifers may be more applicable. In general, this study helps selecting the best suited hydrological tracer for GW exfiltration and leads to a better understanding of processes controlling groundwater inflow into karstic river systems.
    Description: Karst aquifers represent an increased complexity when aiming to measure the interaction between groundwater and river water. Combining field‐based measurements on catchment scale and modelling, the applicability of ‘classical’ environmental groundwater tracers was compared to selected organic (micro)pollutants often considered as conservative and originally arising from a wastewater treatment plant. This study demonstrates that the choice of an appropriate tracer is crucial when either aiming to quantify groundwater exfiltration into karstic river systems, or indicating hydrological processes, applying (globally) omnipresent pollutants.
    Description: German Research Foundation (DFG) http://dx.doi.org/10.13039/501100001659
    Keywords: 551.46 ; carbamazepine ; groundwater inflow ; Lagrangian sampling ; radon ; wastewater treatment plant ; water quality
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  • 26
    Publication Date: 2021-04-21
    Description: From 10 to 12 June 2019, severe thunderstorms affected large parts of Germany. Hail larger than golf ball size caused considerable damage, especially in the Munich area where losses amount to EUR 1 billion. This event thus ranks among the ten most expensive hail events in Europe in the last 40 years. Atmospheric blocking in combination with a moist, unstably stratified air mass provided an excellent setting for the development of severe, hail‐producing thunderstorms across the country. image
    Description: German Research Foundation http://dx.doi.org/10.13039/501100001659
    Keywords: 551.5 ; Germany ; thunderstorms ; hailstorm
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  • 27
    Publication Date: 2021-06-27
    Description: The general task of image classification seems to be solved due to the development of modern convolutional neural networks (CNNs). However, the high intraclass variability and interclass similarity of plankton images still prevents the practical identification of morphologically similar organisms. This prevails especially for rare organisms. Every CNN requires a vast amount of manually validated training images which renders it inefficient to train study‐specific classifiers. In most follow‐up studies, the plankton community is different from before and this data set shift (DSS) reduces the correct classification rates. A common solution is to discard all uncertain images and hope that the remains still resemble the true field situation. The intention of this North Sea Video Plankton Recorder (VPR) study is to assess if a combination of a Capsule Neural Network (CapsNet) with probability filters can improve the classification success in applications with DSS. Second, to provide a guideline how to customize automated CNN and CapsNet deep learning image analysis methods according to specific research objectives. In community analyses, our approach achieved a discard of uncertain predictions of only 5%. CapsNet and CNN reach similar precision scores, but the CapsNet has lower recall scores despite similar discard ratios. This is due to a higher discard ratio in rare classes. The recall advantage of the CNN decreases with increasing DSS. We present an alternative method to handle rare classes with a CNN achieving a mean recall of 96% by manually validating an average of 6.5% of the original images.
    Keywords: 551.46 ; North Sea ; plankton classification ; automated analyses
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  • 28
    Publication Date: 2021-07-05
    Description: The partial pressure of carbon dioxide (pCO2) in surface seawater is an important biogeochemical variable because, together with the pCO2 in the atmosphere, it determines the direction of air–sea carbon dioxide exchange. Large‐scale observations of pCO2 are facilitated by Ships‐of‐Opportunity (SOOP‐CO2) equipped with underway measuring instruments. The need for expanding the observation capacity and the challenges involving the sustainability and maintenance of traditional equilibrator systems led the community toward developing simpler and more autonomous systems. Here we performed a comparison between a membrane‐based sensor and a showerhead equilibration sensor installed on two SOOP‐CO2 between 2013 and 2018. We identified time‐ and space‐adequate crossovers in the Skagerrak Strait, where the two ship routes often crossed. We found a mean total difference of 1.5 ± 10.6 μatm and a root mean square error of 11 μatm. The pCO2 values recorded by the two instruments showed a strong linear correlation with a coefficient of 0.91 and a slope of 1.07 (± 0.14), despite the dynamic nature of the environment and the difficulty of comparing measurements from two different vessels. The membrane‐based sensor was integrated with a FerryBox system on a ship with a high sampling frequency in the study area. We showed the strength of having a sensor‐based network with a high spatial coverage that can be validated against conventional SOOP‐CO2 methods. Proving the validity of membrane‐based sensors in coastal and continental shelf seas and using the higher frequency measurements they provide can enable a thorough characterization of pCO2 variability in these dynamic environments.
    Keywords: 551.46 ; surface seawater ; carbon dioxide ; partial pressure ; measurements
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  • 29
    Publication Date: 2021-07-21
    Description: The addition of offshore wind farms (OWFs) to stratified regions of shelf seas poses an anthropogenic source of turbulence, in which the foundation structures remove power from the oceanic flow that is fed into turbulent mixing in the wake downstream. The loss of stratification within the wake of a single OWF structure is observed for the first time by means of field observations, which enable a qualitative characterization of the disturbed flow downstream. These results are complemented with high‐resolution large eddy simulations of four different stratification strengths that allow for a quantification of turbulence and mixing quantities in the wake of a foundation structure. The turbulent wake of a structure is narrow and highly energetic within the first 100 m, with the dissipation of turbulent kinetic energy well above background levels downstream of the structure. A single monopile is responsible for 7–10% additional mixing to that of the bottom mixed layer, whereby ∼10% of the turbulent kinetic energy generated by the structure is used in mixing. Although the effect of a single turbine on stratification is relatively low, large‐scale OWFs could significantly affect the vertical structure of a weakly stratified water column. Further, rough estimates show that the rate of formation of stratification in the study area is of the same order of magnitude as the additional mixing promoted by the structures, thus OWFs could modify the stratification regime and water column dynamics on a seasonal scale, depending on local conditions and farm geometries.
    Description: Plain Language Summary: Advances in the renewable energy sector have enabled the construction and operation of wind farms in bodies of water deep enough to present vertical temperature differences across the water column or thermal stratification. In coastal regions dominated by tidal motion, the presence of offshore wind farm (OWF) structures brings about additional turbulence and mixing of stratification. The present study combines field measurements and numerical simulations to characterize the wake of single OWF structures and quantify the amount of turbulence and mixing generated by them. Our results suggest that the effect of OWF structures is small compared to other naturally occurring mixing mechanisms, however can be comparable to the rate of stratification buildup. Stratification in certain regions of shelf seas could be impacted by OWFs if these are built over a large area.
    Description: Key Points: Enhanced mixing and disturbed stratification in the wake of monopiles is traceable in field and turbulence‐resolving numerical experiments Elevated turbulent dissipation and mixing are found in a narrow region downstream of monopiles, with a bulk mixing efficiency of 8–14% The enhanced mixing generated by the offshore wind farm structures could contribute to significant changes in stratification in shelf seas
    Description: Helmholtz Foundation
    Keywords: 551.46 ; stratification ; mixing ; offshore wind farms ; monopiles ; mixing efficiency ; tidal shelf seas
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  • 30
    Publication Date: 2021-07-21
    Description: Higher order upwind‐biased advection schemes are often used for potential temperature advection in dynamical cores of atmospheric models. The inherent diffusive and antidiffusive fluxes are interpreted here as the effect of irreversible sub‐gridscale dynamics. For those, total energy conservation and positive internal entropy production must be guaranteed. As a consequence of energy conservation, the pressure gradient term should be formulated in Exner pressure form. The presence of local antidiffusive fluxes in potential temperature advection schemes foils the validity of the second law of thermodynamics. Due to this failure, a spurious wind acceleration into the wrong direction is locally induced via the pressure gradient term. When correcting the advection scheme to be more entropically consistent, the spurious acceleration is avoided, but two side effects come to the fore: (i) the overall accuracy of the advection scheme decreases and (ii) the now purely diffusive fluxes become more discontinuous compared to the original ones, which leads to more sudden body forces in the momentum equation. Therefore, the amplitudes of excited gravity waves from jets and fronts increase compared to the original formulation with inherent local antidiffusive fluxes. The means used for supporting the argumentation line are theoretical arguments concerning total energy conservation and internal entropy production, pure advection tests, one‐dimensional advection‐dynamics interaction tests and evaluation of runs with a global atmospheric dry dynamical core.
    Description: Plain Language Summary: For ease of calculation, an alternative to using the internal energy equation is to consider the movement of an air parcel which maintains a constant value related to temperature and pressure (potential temperature). The pressure gradient converts the energy from internal to kinetic or vice versa, thereby influencing the direction and speed of wind. Hence, in the total energy conservation law, the pressure gradient force and the potential temperature transport equation are interdependent. Equations that simulate the movement the air parcels and its properties (advection equations) have been developed to provide accurate and consistent results. This article reviews whether contemporary advection methods for potential temperature are consistent. This means ensuring the underlying physical laws are met, in particular, the second law of thermodynamics, stating that field variables need to be diffused. However, most numerical advection methods can occasionally act in an antidiffusive way. The pressure inherits this antidiffusion from the potential temperature, if the density is held constant. Due to antidiffusion, the modeled wind direction may be incorrect. Avoiding antidiffusion prevents this effect, but leads to sudden pressure forces. These forces lead to higher gravity wave crests generated at the fronts of weather systems.
    Description: Key Points: The local antidiffusion within upwind potential temperature advection schemes leads to negative dissipation. This antidiffusion induces spurious accelerations in the wind field in one‐dimensional and full model runs. Entropically consistent schemes are less accurate and exhibit higher amplitudes of front‐generated gravity waves.
    Description: Deutsche Forschungsgemeinschaft, TRR181 “Energy Transfers in Atmosphere and Ocean”, subproject M4
    Keywords: 551.5 ; energetic and entropic consistency ; excitation of gravity waves ; upwind advection schemes
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  • 31
    Publication Date: 2021-07-25
    Description: The relationship between mesoscale convective organization, quantified by the spatial arrangement of convection, and oceanic precipitation in the tropical belt is examined using the output of a global storm-resolving simulation. The analysis uses a 2D watershed segmentation algorithm based on local precipitation maxima to isolate individual precipitation cells and derive their properties. 10° by 10° scenes are analyzed using a phase-space representation made of the number of cells per scene and the mean area of the cells per scene to understand the controls on the spatial arrangement of convection and its precipitation. The presence of few and large cells in a scene indicates the presence of a more clustered distribution of cells, whereas many small cells in a scene tend to be randomly distributed. In general, the degree of clustering of a scene (Iorg) is positively correlated to the mean area of the cells and negatively correlated to the number of cells. Strikingly, the degree of clustering, whether the cells are randomly distributed or closely spaced, to a first order does not matter for the precipitation amounts produced. Scenes of similar precipitation amounts appear as hyperbolae in our phase-space representation, hyperbolae that follow the contours of the precipitating area fraction. Finally, including the scene-averaged water vapour path (WVP) in our phase-space analysis reveals that scenes with larger WVP contain more cells than drier scenes, whereas the mean area of the cells only weakly varies with WVP. Dry scenes can contain both small and large cells, but they can contain only few cells of each category.
    Keywords: 551.5 ; convection ; object-based approaches ; organization ; precipitation ; storm-resolving modelling
    Language: English
    Type: article
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  • 32
    Publication Date: 2021-07-25
    Description: An exceptionally strong stationary planetary wave with Zonal Wavenumber 1 led to a sudden stratospheric warming (SSW) in the Southern Hemisphere in September 2019. Ionospheric data from European Space Agency's Swarm satellite constellation mission show prominent 6-day variations in the dayside low-latitude region at this time, which can be attributed to forcing from the middle atmosphere by the Rossby normal mode “quasi-6-day wave” (Q6DW). Geopotential height measurements by the Microwave Limb Sounder aboard National Aeronautics and Space Administration's Aura satellite reveal a burst of global Q6DW activity in the mesosphere and lower thermosphere during the SSW, which is one of the strongest in the record. The Q6DW is apparently generated in the polar stratosphere at 30–40 km, where the atmosphere is unstable due to strong vertical wind shear connected with planetary wave breaking. These results suggest that an Antarctic SSW can lead to ionospheric variability through wave forcing from the middle atmosphere.
    Keywords: 551.5 ; sudden stratospheric warming ; quasi-6-day wave ; planetary wave ; ionosphere ; vertical coupling ; Swarm
    Language: English
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  • 33
    Publication Date: 2021-07-21
    Description: The Etesians are the dominant synoptically driven winds observed in the Eastern Mediterranean, usually from late spring to late summer. Due to the complex topography, the Etesians can be very strong and pose significant environmental hazards, especially over wildfire incidents. This study assesses the impacts of climate change on future Etesians by analyzing the response of the most recent EURO-CORDEX regional climate simulations at the 12-km grid resolution over the twenty-first century. The mean model ensemble projects a significant increase of the Etesians' frequency and intensity under the two emission scenarios RCP4.5 and RCP8.5. This response is connected to an increase in the zonal wind at 200 hPa, a reinforcement of the midlatitude westerly flow, and a decrease in the wave amplitude. These circulation changes accelerate the mid-to-high latitude eastward propagation of the large-scale circulation systems which can favor enhanced ridges over the Balkans. A strengthening and poleward shift of the subtropical jet stream is also projected, connected with stronger subsidence over the Eastern Mediterranean. The projected changes will have profound environmental and societal implications, including the lengthening of the wildfire season and increasing air pollution risk in the region. On the other hand, the current estimate of future wind power potential in the Aegean Sea will be significantly increased by the end of the century, which might have positive impact in the regional economy.
    Keywords: 551.5 ; Etesians ; extreme winds ; Eastern Mediterranean ; midlatitude atmospheric circulation ; EURO-CORDEX ; future projections
    Language: English
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  • 34
    Publication Date: 2021-07-23
    Description: Clouds are liquid at temperature greater than 0°C and ice at temperature below −38°C. Between these two thresholds, the temperature of the cloud thermodynamic phase transition from liquid to ice is difficult to predict and the theory and numerical models do not agree: Microphysical, dynamical, and meteorological parameters influence the glaciation temperature. We temporally track optical and microphysical properties of 796 clouds over Europe from 2004 to 2015 with the space-based instrument Spinning Enhanced Visible and Infrared Imager on board the geostationary METEOSAT second generation satellites. We define the glaciation temperature as the mean between the cloud top temperature of those consecutive images for which a thermodynamic phase change in at least one pixel is observed for a given cloud object. We find that, on average, isolated convective clouds over Europe freeze at −21.6°C. Furthermore, we analyze the temporal evolution of a set of cloud properties and we retrieve glaciation temperatures binned by meteorological and microphysical regimes: For example, the glaciation temperature increases up to 11°C when cloud droplets are large, in line with previous studies. Moreover, the correlations between the parameters characterizing the glaciation temperature are compared and analyzed and a statistical study based on principal component analysis shows that after the cloud top height, the cloud droplet size is the most important parameter to determine the glaciation temperature.
    Keywords: 551.5 ; Clouds ; Glaciation temperature ; geostationary satellite ; SEVIRI ; Thermodynamic phase
    Language: English
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  • 35
    Publication Date: 2021-07-21
    Description: The intraseasonal variability of the tropical eastern boundary upwelling region in the Atlantic Ocean is investigated using multiyear mooring and satellite data. Pronounced oscillations of alongshore velocity and sea level off Angola at periods of about 90 and 120 days are observed. Similar spectral peaks are detected along the equator suggesting an equatorial forcing via equatorial and coastally trapped waves. Equatorial variability at 90 days is enhanced only in the eastern Atlantic likely forced by local zonal wind fluctuations. Variability at 120 days is generally stronger and linked to a second equatorial basin mode covering the whole equatorial basin. Besides forcing of the 120‐day variability by equatorial zonal winds, additional forcing of the resonant basin mode likely originates in the central and western tropical North Atlantic. The coastally trapped waves generated at the eastern boundary by the impinging equatorial Kelvin waves that are detected through their variations in sea level anomaly are associated with corresponding sea surface temperature anomalies delayed by about 14 days. Off Angola, those intraseasonal waves interfere with major coastal warm and cold events that occur every few years by either enhancing them as for the Benguela Niño in 1995 or damping them as for the warm event in 2001.
    Description: Plain Language Summary: The tropical Angolan upwelling system hosts a highly productive ecosystem which plays a key socioeconomic role for societal development and fisheries in Angola. The eastern boundary circulation off Angola is dominated by the warm poleward‐flowing Angola Current. During austral summer, the Angola Current transports warm tropical waters into the Benguela upwelling system. Such a transport is often linked to extreme coastal warm events the so‐called Benguela Niños. The opposite of Benguela Niños are Benguela Niñas, both affecting the marine ecosystem and climate on multiyear time scale. At intraseasonal time scale, the Angola Current variability is dominated at periods of 90 and 120 days emanating from equatorial forcing. The 120‐day variability in the equatorial basin resembles a resonance of east‐ and westward‐propagating waves. This resonant basin mode transmits part of its energy poleward as coastally trapped waves forcing the variability along the Angolan coast and at the northern boundary of the Gulf of Guinea. The impact of these intraseasonal waves on the development of the extreme coastal warm or cold events can be shown by the relation between sea level and sea surface temperature anomalies in Southern Angola: maximum sea level is leading maximum sea surface temperature by about 14 days.
    Description: Key Points: Intraseasonal variability of the Angola Current is linked to equatorial ocean dynamics and interfere with Benguela Niños and Niñas. Coastally trapped waves off Angola at 120‐day period are associated with equatorial basin‐mode resonance. Intraseasonal coastally trapped waves impact sea surface temperature off Angola and in the Gulf of Guinea via thermocline feedback.
    Description: EU H2020 TRIATLAS project
    Description: Bundesministerium für Bildung und Forschung (SACUS II)
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: 551.46 ; Angola Current ; Benguela Niños ; equatorial and coastally trapped waves ; equatorial basin mode ; intraseasonal variability ; thermocline feedback
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  • 36
    Publication Date: 2021-07-22
    Description: The Total Exchange Flow analysis framework computes consistent bulk values quantifying the estuarine exchange flow using salinity coordinates since salinity is the main contributor to density in estuaries and the salinity budget is entirely controlled by the exchange flow. For deeper and larger estuaries temperature may contribute equally or even more to the density. That is why we included potential temperature as a second coordinate to the Total Exchange Flow analysis framework, which allows gaining insights in the potential temperature-salinity structure of the exchange flow as well as to compute consistent bulk potential temperature and therefore heat exchange values with the ocean. We applied this theory to the exchange flow of the Persian Gulf, a shallow, semienclosed marginal sea, where dominant evaporation leads to the formation of hypersaline and dense Gulf water. This drives an inverse estuarine circulation which is analyzed with special interest on the seasonal cycle of the exchange flow. The exchange flow of the Persian Gulf is numerically simulated with the General Estuarine Transport Model from 1993 to 2016 and validated against observations. Results show that a clear seasonal cycle exists with stronger exchange flow rates in the first half of the year. Furthermore, the composition of the outflowing water is investigated using passive tracers, which mark different surface waters. The results show that in the first half of the year, most outflowing water comes from the southern coast, while in the second half most water originates from the northwestern region.
    Keywords: 551.46 ; Persian Gulf ; Total Exchange Flow ; inverse estuary ; General Estuarine Transport Model ; estuarine circulation
    Language: English
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  • 37
    Publication Date: 2021-07-25
    Description: Several regions worldwide have seen significant trends in anthropogenic aerosol emissions during the period of detailed satellite observations since 2001. Over Europe (EUR) and North America (NAM) there were strong declines, over China increases then declines and over India, strong increases. Regional trends in model-simulated aerosol optical depth (AOD) and cloud radiative effects in both the Fifth and Sixth Coupled Model Intercomparison Projects (CMIP5 and CMIP6) are broadly consistent with the ones from satellite retrievals in most parts of EUR, NAM and India. CMIP6 models better match satellite-derived AOD trend in western NAM (increasing) and eastern China (decreasing), where CMIP5 models failed, pointing to improved anthropogenic aerosol emissions. Drop concentration trends in both observations and models qualitatively match AOD trends. The result for solar cloud radiative effect in models, however, is due to compensating errors: Models fail to reproduce observed liquid water path trends and show, in turn, opposite trends in cloud fraction.
    Keywords: 551.5 ; aerosol emission trend ; aerosol optical depth ; cloud radiative effects ; aerosol source regions ; CDNC ; climate models
    Language: English
    Type: article
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  • 38
    Publication Date: 2021-07-23
    Description: High-resolution simulations (grid spacing 2.5 km) are performed with ICON-LEM to characterize convective organization in the Tropics during August 2016 over a large domain ranging from northeastern South America, along the tropical Atlantic to Africa (8,000×3,000 km). The degree of organization is measured by a refined version of the wavelet-based organization index (WOI), which is able to characterize the scale, the intensity and anisotropy of convection based on rain rates alone. Exploiting the localization of wavelets both in space and time, we define a localized version of the convective organization index (LWOI). We compare convection observed in satellite-derived rain rates with the corresponding processes simulated by ICON-LEM. Model and observations indicate three regions with different kinds of convective organization. Continental convection over West Africa has a predominantly meridional orientation and is more organized than over South America, because it acts on larger scales and is more intense. Convection over the tropical Atlantic is zonally oriented along the ITCZ and less intense. ICON and observations agree on the number and intensity of the African easterly waves during the simulation period. The waves are associated with strong vorticity anomalies and are clearly visible in a spatiotemporal wavelet analysis. The central speed and the wavelength of the waves is simulated well. Both the scale and intensity components of LWOI in ICON are significantly correlated with environmental variables. The scale of precipitation is related to wind shear, CAPE and its tendency, while the intensity strongly correlates with column-integrated humidity, upper-level divergence and maximum vertical wind speed. This demonstrates that the LWOI components capture important characteristics of convective precipitation.
    Keywords: 551.5 ; convective organization ; ICON-LEM ; IMERG ; LWOI ; tropical convection ; wavelet-based organization index ; WOI
    Language: English
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  • 39
    Publication Date: 2021-07-23
    Description: In this study, we present a five-member Weather Research and Forecasting (WRF) physics ensemble over the Arabian Peninsula on the convection-permitting (CP) scale and investigate the ability to simulate convection and precipitation by varying the applied cloud microphysics and planetary boundary layer (PBL) parametrizations. The study covers a typical precipitation event ocurring during summertime over the eastern part of the United Arab Emirates (UAE). Our results show that the best results are obtained by using water- and ice-friendly aerosols combined with aerosol-aware Thompson cloud microphysics and the Mellor-Yamada-Nakanishi-Niino (MYNN) PBL parametrization. The diurnal cycle of 2-m temperature over the desert is well captured by all members, although a cold bias is present during the morning and evening transition. All members are capable of simulating the correct timing of the onset of convection. Simulations with the MYNN PBL and Thompson scheme produce the highest convective available potential energy (CAPE) and convective inhibition (CIN), associated with stronger mixing inside the PBL, leading to the formation of more dense liquid water clouds. The WDM6 microphysics scheme is not a suitable option, as there are hardly any liquid water clouds; mainly ice clouds are simulated. Precipitation is best captured by applying the MYNN and Thomspon scheme. Although the ensemble size is relatively small, this allows for the provision of cloud probability maps suitable for cloud-seeding applications.
    Keywords: 551.5 ; convection ; ensemble ; PBL ; UAE ; WRF
    Language: English
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  • 40
    Publication Date: 2021-07-21
    Description: We show how changes in the global distribution of anthropogenic aerosols favor different spatial patterns in the North Atlantic sea‐surface temperature (NASST). The NASSTs largely show the expected decrease associated with the anthropogenic aerosols in the 1970s, but also an unusual warming response in the eastern sub‐polar gyre, the region of the North Atlantic warming hole. The NASST response reversed for the anthropogenic aerosols in the 2000s against 1970s. The regional reduction in anthropogenic aerosols favored as follows: (1) a strengthening of the warming hole and (2) a NASST increase at high latitudes associated with changes in the coupled atmosphere‐ocean dynamics. We found that the gyre component of the northward Atlantic heat transport in mid‐to high latitudes is an important driver for the heat convergence associated with the NASST patterns. At least two‐thirds of the NASST response in MPI‐ESM1.2 is associated with aerosol‐cloud interactions, highlighting the need to better understand them.
    Description: Plain Language Summary: The change of the North Atlantic sea‐surface temperature due to anthropogenic aerosols is not well understood. Aerosols reflect incoming solar radiation and influence clouds. Both effects are expected to cool the surface. The expected surface cooling (warming) due to more (less) aerosols is mostly seen in our experiment, but we also find an unusual warming (cooling) in a region in the North Atlantic, where observations show no clear warming trend. We identify that this area, known as the North Atlantic warming hole, is affected by circulation changes that are induced by the aerosol changes between the pre‐industrial, the 1970s and the 2000s. Changes of the heat transport in the ocean from the warming hole to the Arctic drives these changes. The magnitude of this temperature change in our experiments largely depends on the still uncertain aerosol effect on clouds.
    Description: Key Points: Anthropogenic aerosol patterns affect the coupled atmosphere‐ocean dynamical response 1970s to 2000s aerosol pattern change enhances North Atlantic warming hole through ocean meridional heat convergence by the sub‐polar gyre Most of the response to anthropogenic aerosols is associated with aerosol‐cloud interactions
    Description: Max Planck Society
    Description: German Science Foundation
    Description: German Federal Ministry for Transportation and Digital Infrastructure
    Keywords: 551.5 ; anthropogenic aerosols ; circulation ; climate response ; heat transport ; North Atlantic ; warming hole
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  • 41
    Publication Date: 2021-07-21
    Description: North‐westerly airflow and associated atmospheric rivers (ARs) have been found to profoundly influence New Zealand’s west coasts, by causing flooding, landslides and extreme ablation and accumulation on glaciers in the Southern Alps. However, the response of local glacier mass balance to synoptic‐scale circulation, including events with ARs, has typically not been investigated by considering mesoscale processes explicitly. In this study, high‐resolution atmospheric simulations from the Weather Research and Forecasting model are used to investigate the mesoscale drivers of an extreme ablation event on Brewster Glacier (Southern Alps), which occurred on February 6, 2011 during the landfall of an AR on the South Island. The following processes were found to be crucial for transferring the high temperature and water vapor contained in the AR into energy available for melt on Brewster Glacier: First, the moist‐neutral character of the air mass enabled the flow to pass over the ridge, leading to the development of orographic clouds and precipitation on the windward side of the orography, and foehn winds on the leeside. These processes fueled melt through longwave radiation and strong turbulent and rain heat fluxes within the high‐condensation environment of the orographic cloud. Second, orographic enhancement occurred due to both cellular convection within the cloud and the combined effect of multiple precipitating systems by the seeder‐feeder‐mechanism. These results indicate the potential importance of AR dynamics for New Zealand’s glaciers. They also illustrate the benefit of mesoscale atmospheric modeling for advancing process understanding of the glacier‐climate relationship in New Zealand.
    Description: Plain Language Summary: Atmospheric rivers, which are elongated, narrow structures in the atmosphere that convey large amounts of moisture through the midlatitudes, have been found to impact coastal regions worldwide, including New Zealand. Besides causing flooding and landslides, they can affect glaciers in coastal mountains such as the Southern Alps. The processes causing the high temperature and moisture in atmospheric rivers to trigger melt (or snowfall) at the glacier surface have, however, not been investigated explicitly because they operate at the size of mountain valleys and ridges which are difficult to represent in global data‐sets. We address this by using an atmospheric model with high spatial detail to simulate a case study, where an atmospheric river coincided with extreme melt on Brewster Glacier in the Southern Alps. We find that the stability characteristics of the impinging warm and moist air masses lent the air the potential to ascend the mountain instead of being directed around. This resulted in cloud and precipitation development on the windward slopes whereby rain amounts were further enhanced by internal processes within the clouds. Melt was promoted through heat released from condensation and rainfall. Conversely, on the lee slopes, downslope winds caused warm and dry conditions.
    Description: Key Points: The mass balance of Brewster Glacier is affected by an atmospheric river causing extreme melt through rain and turbulent energy transfer. Orographic enhancement and weak stability in the atmospheric river cause precipitation on windward slopes while leesides are foehn‐affected. Regional atmospheric modeling can advance the process understanding of the glacier‐climate relationship in New Zealand’s mountains.
    Description: Alexander von Humboldt‐Stiftung (Humboldt‐Stiftung) German Research Foundation (DFG): MO 2869/4‐1 http://dx.doi.org/10.13039/100005156
    Keywords: 551.5 ; Atmospheric river ; glacier ablation ; mesoscale processes ; New Zealand Southern Alps ; orographic precipitation ; WRF
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  • 42
    Publication Date: 2021-07-21
    Description: Seasonal prediction systems based on Earth System Models exhibit a lower proportion of predictable signal to unpredictable noise than the actual world. This puzzling phenomena has been widely referred to as the signal‐to‐noise paradox (SNP). Here, we investigate the SNP in a conceptual framework of a seasonal prediction system based on the Lorenz, 1963 Model (L63). We show that the SNP is not apparent in L63, if the uncertainty assumed for the initialization of the ensemble is equal to the uncertainty in the starting conditions. However, if the uncertainty in the initialization overestimates the uncertainty in the starting conditions, the SNP is apparent. In these experiments the metric used to quantify the SNP also shows a clear lead‐time dependency on subseasonal timescales. We therefore, formulate the alternative hypothesis to previous studies that the SNP could also be related to the magnitude of the initial ensemble spread.
    Description: Plain Language Summary: Comprehensive Earth System Models seem to be better at predicting the real observed climate system than expected based on their ability to predict their own modelled climate system. This puzzling phenomena is known as the signal‐to‐noise paradox (SNP) and its origin is still under intensive scientific debate with some studies pointing to deficiencies in the model formulation. In this study we investigate under which conditions the SNP can be obtained using a simple conceptual framework for a climate prediction system based on a simple dynamical model. Our results show that the SNP can be reproduced in the absence of model deficiencies if the model overestimates the observational uncertainty. We also investigate the development of the SNP on subseasonal timescales and find a clear dependency on the lead‐time of the prediction. Our results lead us to formulate an alternative hypothesis to previous studies on the origin of the SNP.
    Description: Key Points: Whether forecasts in the Lorenz Model are reliable or not depends on the ratio of initial ensemble spread to observational uncertainty Until predictability is lost in the Lorenz Model the level of over‐or underconfidence increases with increasing lead‐time
    Description: Copernicus Climate Change Service
    Description: Marine Institute and the European Regional Development fund
    Description: Deutsche Forschungsgemeinschaft (DFG, German Research Foundation)
    Keywords: 551.5 ; Lorenz Model
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  • 43
    Publication Date: 2021-07-21
    Description: Downscaling is widely used in studies of local and/or regional climate as it yields a greater spatial resolution than general circulation models (GCMs) can provide. It utilizes GCM output or reanalysis data, which is transformed using mathematical relationships or used to force the lateral boundaries of a regional climate model. However, there is no set selection technique to determine which GCM realization(s) to employ. Here, a comprehensive yet easily applicable model selection technique for studies requiring GCM data as a constraint was developed. The technique evaluates, with respect to a reanalysis product and/or observational data, the ability of GCM realizations to reconstruct the mean state of the climate and the space‐time climatic anomalies for the atmospheric state variables at three distinct pressure levels. It was applied to the region of East Africa, where GISS‐E2‐H r6i1p3 was found to perform the strongest. The top ranked realizations were found to better capture processes when evaluated for the example of the Indian Ocean Dipole. Furthermore, the surface air temperature and precipitation from three 10‐year regional climate model simulations, one forced by the Modern‐Era Retrospective Analysis for Research and Applications version 2 reanalysis, one forced by the top ranked GCM, and one by the lowest ranked one, were compared to gridded observations. Results show that using a top ranked GCM for the boundary conditions leads to a better dynamical downscaling simulation than a low‐ranked GCM, suggesting the potential of the proposed technique for future downscaling techniques.
    Description: Key Points: Creation of a comprehensive and easily applicable model selection technique for downscaling Top ranked models are better able to capture processes for Indian Ocean Dipole example Using a top ranked general circulation model (GCM) for the boundary conditions leads to a better dynamical downscaling simulation than a low‐ranked GCM
    Description: German Research Foundation (DFG)
    Keywords: 551.5 ; downscaling ; East Africa ; general circulation models ; model selection
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  • 44
    Publication Date: 2021-07-21
    Description: This paper presents for the first time results on winds, tides, gradients of horizontal winds, and momentum fluxes at mesosphere and lower thermosphere altitudes over southern Patagonia, one of the most dynamically active regions in the world. For this purpose, measurements provided by SIMONe Argentina are investigated. SIMONe Argentina is a novel multistatic specular meteor radar system that implements a Spread‐spectrum Interferometric Multistatic meteor radar Observing Network (SIMONe) approach, and that has been operating since the end of September 2019. Average counts of more than 30,000 meteor detections per day result in tidal estimates with statistical uncertainties of less than 1 m/s. Thanks to the multistatic configuration, horizontal and vertical gradients of the horizontal winds are obtained, as well as vertical winds free from horizontal divergence contamination. The vertical gradients of both zonal and meridional winds exhibit strong tidal signatures. Mean momentum fluxes are estimated after removing the effects of mean winds using a 4‐h, 8‐km window in time and altitude, respectively. Reasonable statistical uncertainties of the momentum fluxes are obtained after applying a 28‐day averaging. Therefore, the momentum flux estimates presented in this paper represent monthly mean values of waves with periods of 4 h or less, vertical wavelengths shorter than 8 km, and horizontal scales less than 400 km.
    Description: Key Points: First observations of mesosphere and lower thermosphere dynamics over one of the most dynamically active regions in the world Estimates of mean horizontal winds and their gradients are possible, thanks to the multistatic configuration Mean momentum fluxes are estimated with vertical velocity estimates free of horizontal divergence contamination
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347
    Keywords: 551.5 ; horizontal gradients ; meteor radar ; MLT ; momentum flux ; tides ; winds
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  • 45
    Publication Date: 2021-07-21
    Description: In September 2020, extremely strong wildfires in the western United States of America (i.e., mainly in California) produced large amounts of smoke, which was lifted into the free troposphere. These biomass‐burning‐aerosol (BBA) layers were transported from the US west coast toward central Europe within 3–4 days turning the sky milky and receiving high media attention. The present study characterizes this pronounced smoke plume above Leipzig, Germany, using a ground‐based multiwavelength‐Raman‐polarization lidar and the aerosol/cloud product of ESA’s wind lidar mission Aeolus. An exceptional high smoke‐AOT 〉0.4 was measured, yielding to a mean mass concentration of 8 μg m−3. The 355 nm lidar ratio was moderate at around 40–50 sr. The Aeolus‐derived backscatter, extinction and lidar ratio profiles agree well with the observations of the ground‐based lidar PollyXT considering the fact that Aeolus’ aerosol and cloud products are still preliminary and subject to ongoing algorithm improvements.
    Description: Plain Language Summary: In September 2020, extremely strong wildfires in the western USA (i.e., mainly in California) produced large amounts of smoke. These biomass burning aerosol (BBA) layers were transported from the US west coast towards central Europe within 3‐4 days. This smoke plume was observed above Leipzig, Germany, for several days turning the sky milky and receiving high media attention ‐ it was the highest perturbation of the troposphere in terms of AOT ever observed over Leipzig. The first smoke plume arrived on 11 September 2020, just in time for a regular overpass of the Aeolus satellite of the European Space Agency (ESA). Aeolus accommodates the first instrument in space that actively measures profiles of a horizontal wind component in the troposphere and lower stratosphere. Aeolus has been launched to improve weather forecasts while assimilating the Aeolus wind profile data in near–real time. But Aeolus also delivers profiles of aerosol and cloud optical properties as spin‐off products. We performed a first assessment of the aerosol profiling capabilities of Aeolus while precisely analyzing the smoke plume above Leipzig with a ground‐based multiwavelength‐Raman‐polarization lidar. But we also show the dramatic impact of fires in the western USA on atmospheric conditions over central Europe.
    Description: Key Points: Smoke from the extraordinary 2020 Californian wild fires traveled within 3–4 days toward Europe Highest Aerosol Optical Thickness ever measured in the free troposphere over Leipzig, Germany, Central Europe, with ground‐based lidar Unique opportunity for a first assessment of the aerosol optical profiles of the spaceborne wind lidar mission Aeolus
    Description: German Federal Ministry for Economic Affairs and Energy (BMWi)
    Description: German Federal Ministry for Education and Research (BMBF)
    Description: European Union’s Horizon 2020 Research and Innovation Program
    Keywords: 551.5 ; Aeolus ; biomass burning aerosol ; lidar ; remote sensing ; smoke ; wild fires
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  • 46
    Publication Date: 2021-07-24
    Description: Substantial changes have occurred in the Arctic Ocean in the last decades. Not only sea ice has retreated significantly, but also the ocean at middepth showed a warming tendency. By using simulations we identified a mechanism that intensifies the upward trend in ocean heat supply to the Arctic Ocean through Fram Strait. The reduction in sea ice export through Fram Strait induced by Arctic sea ice decline increases the salinity in the Greenland Sea, which lowers the sea surface height and strengthens the cyclonic gyre circulation in the Nordic Seas. The Atlantic Water volume transport to the Nordic Seas and Arctic Ocean is consequently strengthened. This enhances the warming trend of the Arctic Atlantic Water layer, potentially contributing to the Arctic “Atlantification.” Our study suggests that the Nordic Seas can play the role of a switchyard to influence the heat budget of the Arctic Ocean.
    Keywords: 551.46 ; Arctic Ocean ; Atlantic Water ; sea ice decline ; Nordic Seas ; Greenland Sea ; Atlantification
    Language: English
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  • 47
    Publication Date: 2021-07-23
    Description: The hydrodynamics in estuaries is mainly governed by the competition between a horizontal density gradient, friction, and wind stress. The sensitivity of the estuarine exchange flow to the wind stress increases in the absence of tides, which is investigated here using the example of the weakly tidal Warnow river estuary in the southwestern Baltic Sea—the mouth of which is characterized by strongly varying salinities of 8 to 20 g kg−1. The interaction between a volatile salinity gradient and along-estuary wind forcing is found to cause temporary inversions of the estuarine circulation. Despite the highly dynamic conditions, the applicability of recent theories for isohaline mixing, using the framework of Total Exchange Flow, and the strength of the exchange flow, using a non-dimensional parameter space, could be confirmed. By analyzing salinity fluxes at the mouth of the estuary, a mixing completeness of 84% was calculated for the estuary. Furthermore, inversion of estuarine circulation was typically found for a local Wedderburn number (ratio of non-dimensional wind stress to non-dimensional horizontal density gradient) exceeding 0.33, indicating a high sensitivity to along-estuary wind.
    Keywords: 551.46 ; estuarine circulation ; salt mixing ; wind straining ; Total Exchange Flow
    Language: English
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  • 48
    Publication Date: 2021-07-04
    Description: The effects of temporal changes in the marine geoid on estimates of the ocean dynamic topography are being investigated. Influences from mass redistribution due to changes of land hydrology, ice sheets, glacial isostatic adjustment (GIA), and ocean and atmospheric dynamics are considered, and the associated crustal deformation is included. The strongest signals are associated with the seasonal cycle caused by changes in terrestrial water storage and ice sheets as well as the redistribution of atmospheric mass. Second to this is the importance of an overall trend caused by GIA and decreasing ice sheets over Greenland and Antarctica. On long spatial scales, the amplitude of regional trends estimated for the geoid height has a sizable fraction of those from sea level anomaly (SLA) for the period 1993–2016, also after subtraction of steric height of the upper 1,000 m to analyze trends in deep ocean geostrophic currents. The estimated strong negative geoid height trend south of Greenland for the period 1993–2016 opposes changes in dynamic sea level for the same period thereby affecting past studies on changes of both the strength of the subpolar gyre based on SLA and the meridional overturning circulation on a section between Cape Farewell and Portugal applying ocean dynamic topography and hydrography. We conclude that temporal geoid height trends should be considered in studies of (multi)decadal trends in sea level and circulation on large spatial scales based on altimetry data referenced to a geoid field.
    Description: Plain Language Summary: Changes in ocean surface currents are routinely obtained from satellite altimetry data. A correction for changes in the geoid, the equipotential surface of gravity closest to sea level, is considered small and thus usually neglected. We investigate temporal geoid height changes and potential implications on ocean circulation studies using space‐borne gravity data and results from ocean and atmosphere models to discover the individual processes of mass redistribution in the climate system causing thereby changes in the geoid height. We found the largest signals in the seasonal cycle for terrestrial hydrology in the Amazone basin and in negative trends for the Greenland and West Antarctic Ice sheets. For the period 1993–2016 and on spatial scale larger than 1,000 km or so the magnitude of the negative marine geoid height trend south of Greenland is similar to the strength of the negative trend in geocentric sea level from altimetry. This outcome affects past studies on changes in the strength of the subpolar gyre and the Atlantic meridional overturning circulation that neglect geoid height variations. We conclude that temporal geoid height trends should be considered in studies of (multi)decadal trends in sea level and circulation on large spatial scales based on altimetry data.
    Description: Key Points: The strongest geoid height changes are associated with regionally pronounced seasonal signals and secular trends. In the Subpolar North Atlantic the geoid height trend biases circulation trend estimates based on altimetry. Altimetry data need correction for geoid height change when long‐term variations in ocean dynamics are studied.
    Description: German Science Foundation (DFG)
    Description: BMBF funded Verbundprojekt RACE (Regional Atlantic Circulation and Global Change)
    Description: DFG http://dx.doi.org/10.13039/100004807
    Keywords: 550.312 ; 551.46 ; geoid height ; altimetry ; ocean dynamic topography ; temporal variability ; trend
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  • 49
    Publication Date: 2021-07-04
    Description: Here, we revisit the existing concepts of the vertical structure of deep layers in the Black Sea using data from sensors deployed on profiling floats. The deep transition layer (DTL) between 700 and 1,700 m acts as an interface between the baroclinic layer and the largest bottom convective layer (BCL) of the world oceans. On top of DTL are the warm intermediate layer and deep cold intermediate layer. They both showed strong trends in the last 15 years due to warmer climate and intensification of warmer intrusions from Bosporus. A “salinity wave” was detected in 2005–2009 below ∼1,700 m, which evidenced for the first time the penetration of gravity flow from Bosporus down to the bottom. The layering of water masses was explained as resulting from the different distribution of sources of heat and salt, double diffusion, and balances between the geothermal and salinity flows in the BCL.
    Description: Plain Language Summary: A total of 5,927 profiles from 31 profiling floats deployed in the Black Sea after 2005 were used to study the thermohaline dynamic. The density ratio, which sets the conditions under which double diffusion could occur qualifies most of the depths below 600 m as a double‐diffusive environment, which was confirmed by the observed staircase structure of vertical profiles. The qualitative differences between the temperature and salinity profiles in DTL are explained by the different distributions of sources and sinks of heat and salt. This layer acts as a transition zone between the bottom convective layer and the baroclinic ocean. A deep cold intermediate layer (DCIL) occupies the top of the DTL. The former became pronounced in recent years as a consequence of the warming of upper water layers. The large salinity variations from 2005 to 2009 observed at the bottom of the DTL evidenced traces of the penetration of the Bosporus plume down to the bottom for the first time. Combining known values of geothermal flow and concepts from the theory of dynamics of salinity‐stratified tanks heated from below made it possible to quantify the mean annual volume of Bosporus water reaching the bottom.
    Description: Key Points: Profiling floats registered for the first time traces of Bosporus intrusions down to the bottom. The deep warm and cold intermediate layers are responsive to climate warming. Different sources of heat and salt dominate the transition between the baroclinic ocean and bottom convection layer.
    Keywords: 551.46 ; 551.46 ; baroclinicity ; double diffusion ; geothermal convection ; profiling floats ; sources of heat and salt ; water masses
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  • 50
    Publication Date: 2021-07-04
    Description: Cyclone Mekunu hit the southern Arabian Peninsula in late May 2018 and brought rainfall amounts that accounted for up to 6 times the mean annual precipitation. Coming from the Arabian Sea, a quite underdocumented region with regard to cyclones, the storm eye crossed the Omani coast approximately 80 km east of the border to Yemen. Using automatic samplers, rainfall samples were collected during the event at three locations along a transect almost parallel to the storm track. The stable isotope analyses show a wide range of δ values, with minimum and maximum values of −17.01‰ δ18O and −1.77‰ δ18O and −122.2‰ δ2H and −1.6‰ δ2H. On average, rainfall becomes isotopically lighter with elevation, but rather irregularly. In view of high wind speeds probably precluding a gradual rainout of ascending air masses, a “pseudo elevation effect” seems likely. Our measurements expand the known δ value range of local cyclones by about 6‰ for δ18O and by nearly 50‰ for δ2H. The isotopic composition of the annual Indian Summer Monsoon shows values of −0.93‰ δ18O to 2.21‰ δ18O and −2.1‰ δ2H to 23.7‰ δ2H. Thus, there is a clear difference in the dual isotope signatures of the two precipitation systems in the area. Our findings enable an assessment of the impact of cyclones on the hydro(geo)logical system. For the arid Najd area, we demonstrate that the isotopic signatures of groundwater samples fall between those of cyclone and (paleo)monsoon precipitation, suggesting that several rainfall types may have contributed to replenishment.
    Description: Key Points: We conducted high‐resolution sampling of a tropical cyclone from the Arabian Sea for stable isotope and hydrochemical analyses. The strong depletion in heavy isotopes and large intra‐event variations confirm observations from tropical storms elsewhere. There was no overlap with the isotopic fingerprint of local monsoon rains.
    Description: The Research Council (TRC) http://dx.doi.org/10.13039/501100004787
    Description: The Research Council of Oman
    Keywords: 551.5 ; tropical cyclone ; stable isotopes ; precipitation ; paleoclimate ; Oman ; Arabian Sea
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  • 51
    Publication Date: 2021-07-04
    Description: Processes of stratification and destratification in the German Bight region of fresh water influence (ROFI) are investigated following an extreme river discharge event in June 2013. For this purpose, a high‐resolution baroclinic ocean model is set up and validated against field data. The model results are used to study the temporal and spatial variability of stratification and the duration of persistent stratification in 2013. The relevant processes affecting stratification are investigated by analyzing the potential energy anomaly budget, with a focus on mixing and tidal straining. It is shown that the stratification in the German Bight is highly affected by the spring‐neap tidal cycle, with generally less stratification at spring tides due to dominant tidal mixing. It is also shown that the location of the river plume can modify this pattern. During spring tides, if the river plume is confined to the eastern region, stratification decreases significantly, as expected, due to the dominance of mixing over tidal straining. On the other hand, if the river plume moves toward deeper regions at spring tides, strong tidal straining becomes present. In this condition, mixing is weak, and the dominant tidal straining results in persistent stratification.
    Description: Key Points: Processes impacting the German Bight stratification are investigated using a high‐resolution baroclinic model. The position of the river plume highly affects the contribution of tidal straining and mixing to changes in stratification. Strong tidal straining can result in persistent stratification even during spring tides.
    Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347
    Description: German Research Foundation http://dx.doi.org/10.13039/501100001659
    Description: German Environment Agency http://dx.doi.org/10.13039/501100010809
    Keywords: 551.46 ; stratification ; tidal‐straining ; mixing ; extreme river discharge ; numerical model ; German Bight ROFI
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  • 52
    Publication Date: 2021-06-27
    Description: Ocean deoxygenation is a threat to marine ecosystems. We evaluated the potential of two ocean intervention technologies, that is, “artificial downwelling (AD)” and “artificial upwelling (AU),” for remedying the expansion of Oxygen Deficient Zones (ODZs). The model‐based assessment simulated AD and AU implementations for 80 years along the eastern Pacific ODZ. When AD was simulated by pumping surface seawater to the 178–457 m‐depth range of the ODZ, vertically integrated oxygen increased by up to 4.5% in the deployment region. Pumping water from 457 m depth to the surface (i.e., AU), where it can equilibrate with the atmosphere, increased the vertically integrated oxygen by 1.03%. However, both simulated AD and AU increased biological production via enhanced nutrient supply to the sea surface, resulting in enhanced export production and subsequent aerobic remineralization also outside of the actual implementation region, and an ultimate net decline of global oceanic oxygen.
    Description: Key Points: Artificial downwelling (AD) and upwelling (AU) in the eastern Pacific oxygen deficient region are simulated in a global model Both technologies can effectively mitigate local expansion of intermediate‐depth oceanic oxygen deficient zones under climate change Global deoxygenation is however enhanced due to increased export production and aerobic respiration resulting from AD and AU
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: German Research Foundation (DFG)
    Keywords: 551.46 ; deoxygenation ; geoengineering ; artificial upwelling ; artificial downwelling ; Earth system model ; marine hypoxia
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  • 53
    Publication Date: 2021-07-04
    Description: We present an application of generative adversarial networks (GANs) to reconstruct the sea level of the North Sea using a limited amount of data from tidal gauges (TGs). The application of this technique, which learns how to generate datasets with the same statistics as the training set, is explained in detail to ensure that interested scientists can implement it in similar or different oceanographic cases. Training is performed for all of 2016, and the model is validated on data from 3 months in 2017 and compared against reconstructions using the Kalman filter approach. Tests with datasets generated by an operational model (“true data”) demonstrated that using data from only 19 locations where TGs permanently operate is sufficient to generate an adequate reconstruction of the sea surface height (SSH) in the entire North Sea. The machine learning approach appeared successful when learning from different sources, which enabled us to feed the network with real observations from TGs and produce high‐quality reconstructions of the basin‐wide SSH. Individual reconstruction experiments using different combinations of training and target data during the training and validation process demonstrated similarities with data assimilation when errors in the data and model were not handled appropriately. The proposed method demonstrated good skill when analyzing both the full signal and the low‐frequency variability only. It was demonstrated that GANs are also skillful at learning and replicating processes with multiple time scales. The different skills in different areas of the North Sea are explained by the different signal‐to‐noise ratios associated with differences in regional dynamics.
    Description: Plain Language Summary: The variability of sea level is one of the most important elements of the ocean dynamics. Basin‐wide observations are due to satellite altimeters, observations in coastal stations are provided by tidal gauges. The first are not very accurate in the coastal areas, the second do not provide basin‐wide coverage. The task in the present work is to use machine learning to reconstruct the sea‐level variability in the North Sea, which is an almost enclosed ocean region, using observations only. Using data from 19 coastal stations and data from numerical models as a representation of the true ocean (synthetic observations), we demonstrated that the generative adversarial networks reconstruct almost perfectly the sea level of the North Sea. The application of this technique, which learns how to generate datasets with the same statistics as the training set, is explained in detail to ensure that interested scientists can implement it in similar or different oceanographic cases.
    Description: Key Points: Generative Adversarial Networks successfully reconstruct basin‐wide sea level in the North Sea using data from tidal gauges. Machine learning appeared successful when learning from different data sources. The proposed method is skillful at learning and replicating processes with multiple time scales.
    Keywords: 551.46 ; deep learning ; numerical models ; sea level ; tidal gauges ; tides
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  • 54
    Publication Date: 2021-07-03
    Description: Over the last years, the number of studies that investigate or utilize the electromagnetic (EM) signals generated by ocean tides is steadily growing. However, the majority of these studies focuses on the amplitudes of EM tidal signals. This study investigates the phases of EM tidal signals and their changes. Twenty‐six years of monthly observation‐based datasets of tidal velocities, geomagnetic field, and oceanic conductivity are fed into an EM induction solver to generate varying EM tidal signals. The sensitivities of the resulting EM signals are analyzed by forbidding or allowing the input datasets to vary in time. We report on the phase's sensitivities with respect to changes in the EM properties, that is, secular variation of the geomagnetic field and changes in oceanic conductivity. Distinct temporal behavior and distinct geographic pattern for the two sensitivities can be reported. In general, apart from global phase shifts of 3–5 degrees, concentrated areas with phase shifts of up to 45 degrees occur all over the globe, over the oceans, for example, Arctic and Atlantic Ocean, as well as on coastal land regions, for example, Southwest Greenland and Japan. Very locally, phase shifts of 90 degree or higher occur.
    Description: Key Points: Electromagnetic tidal signals show significant spatiotemporal phase changes. Annual and monthly phase anomalies are found to be of oceanic origin. Decadal transient phase anomalies are generated by secular variation and changing oceanic conductivity.
    Keywords: 551.46 ; climate and interannual variability ; electromagnetic fields ; ocean tides ; tidal phases
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  • 55
    Publication Date: 2021-07-21
    Description: Aerosol‐cloud interactions are an important source of uncertainty in current climate models. To understand and quantify the influence of ice‐nucleating particles in cloud glaciation, it is crucial to have a reliable estimation of the hemispheric and seasonal contrast in cloud top phase, which is believed to result from the higher dust aerosol loading in boreal spring. For this reason, we locate and quantify these contrasts by combining three different A‐Train cloud‐phase products for the period 2007–2010. These products rely on a spaceborne lidar, a lidar‐radar synergy, and a radiometer‐polarimeter synergy. We show that the cloud‐phase from the product combination is more reliable and that the estimation of the hemispheric and seasonal contrast has a lower error compared to the individual products. To quantify the contrast in cloud‐phase, we use the hemispheric difference in ice cloud frequency normalized by the liquid cloud frequency in the southern hemisphere between −42 °C and 0 °C. In the midlatitudes, from −15 to −30 °C, the hemispheric contrasts increase with decreasing temperature. At −30 °C, the hemispheric contrast varies from 29% to 39% for the individual cloud‐phase products and from 52% to 73% for the product combination. Similarly, in the northern hemisphere, we assess the seasonal contrast between spring and fall normalized by the liquid cloud frequency during fall. At −30 °C, the seasonal contrast ranges from 21% to 39% for the individual cloud‐phase products and from 54% to 75% for the product combination.
    Description: Plain Language Summary: The influence of atmospheric particles on clouds is one of the main unknowns in climate predictions. Particularly, the cloud glaciation process and its dependence on desert dust and soot particles are not well‐understood. To better understand the differences in cloud glaciation between hemispheres, we counted liquid and ice cloud tops, as observed from four different satellites, during 4 years. Combining these observations, we could confirm a higher frequency of ice cloud tops during spring in the northern hemisphere. We found that the contrast between hemispheres is higher than previously thought. These results will help to improve our understanding of cloud glaciation processes, which can be valuable for future climate predictions and for understanding the impact of aerosols on radiation and precipitation.
    Description: Key Points: A satellite product ensemble was used to locate and quantify the hemispheric and seasonal contrast in cloud top thermodynamic phase. At −30 °C, half of the liquid cloud tops observed in the southern hemisphere would glaciate in the northern hemisphere. The new product ensemble is more reliable than the individual products and suggests a previous underestimation of the cloud‐phase contrasts.
    Keywords: 551.5 ; cloud glaciation ; cloud‐phase ; hemispheric contrast ; heterogeneous freezing ; ice particles ; INP
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  • 56
    Publication Date: 2021-07-21
    Description: Mesospheric winds from two longitudinal sectors at 53°N latitude are combined to investigate quasi‐two‐day waves (Q2DWs) and their nonlinear interactions with tides. In a summer 2019 case study, we diagnose the zonal wavenumber m of spectral peaks at expected frequencies through two dual‐station approaches, a phase differencing technique (PDT) on individual spectral peaks and a least squares procedure on family batched peaks. Consistent results from the approaches verify the occurrences of Rossby‐gravity modes (m = 3 and 4 at periods T = 2.1  and 1.7 days), and their secondary waves (SWs) generated from interactions with diurnal, semi‐diurnal, ter‐diurnal, and quatra‐diurnal migrating tides. We further extend the PDT to 2012–2019, illustrating that Q2DWs exhibit significant interannual variability. Composite analysis reveals seasonal and altitude variations of the Rossby‐gravity modes and their SWs. The Rossby‐gravity modes maximize in local summer, whereas their 16‐ and 9.6‐h SWs appear more in winter.
    Description: Plain Language Summary: The quasi‐two‐day wave is the strongest and most widely studied planetary wave occurring in the mesosphere. Existing observational analyses are based on either single‐satellite or ‐station approaches, which suffer from temporal and spatial aliasing, respectively. The current study implements and develops dual‐station approaches to investigate the mesospheric quasi‐two‐day wave at 53°N latitude, in a case and a statistical study. Our approaches allow diagnosing both the frequency and zonal wavenumber. In the case study, we diagnosed two Rossby‐gravity modes and the secondary waves (SWs) of the nonlinear interactions between the Rossby‐gravity modes and the migrating tides at periods of 24, 12, 8, and 6 h. While the interactions with the 24‐ and 12‐h tides are expected, those with the 8‐ and 6‐h tides are reported for the first time. In the statistical study, we report the seasonality and altitude variation of the Rossby‐gravity modes and their most dominant SWs.
    Description: Key Points: Multi‐station approaches are developed and applied to diagnose zonal wavenumber m of near‐2‐day, ‐16‐h, ‐9.6‐h, and ‐6.9‐h spectral peaks. Diagnosed are Rossby‐gravity modes with m = 3 and 4, and their secondary waves from nonlinear interactions with 24‐, 12‐, 8‐, and 6‐h migrating tides. Seasonally, the most dominant near‐2‐day, ‐16‐h, ‐9.6‐h waves occur in summer, winter, and winter, respectively.
    Keywords: 551.5 ; atmosphere‐ionosphere coupling ; cross‐wavelet ; mesosphere ; quasi‐two‐days ; Rossby‐gravity wave ; zonal wavenumber
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  • 57
    Publication Date: 2021-07-03
    Description: A 700‐year pre‐industrial control run with the MPI‐ESM‐LR model is used to investigate the link between the summer East Atlantic (SEA) pattern and the Pacific‐Caribbean rainfall dipole (PCD), a link that has previously been shown using ERA‐Interim reanalysis data. In the model, it is found that the link between the SEA and PCD is present in some multidecadal epochs but not in others. A simple statistical model reproduces this behaviour. In the statistical model, the SEA is represented by a white noise process plus a weak influence from the PCD based on the full 700 years of the model run. The statistical model is relevant to other extratropical modes of variability, for example, the winter North Atlantic Oscillation (NAO), that are weakly influenced by the Tropics. It follows that the link between the Tropics and the winter NAO is likely to undergo modulation on multidecadal time scales, as found in some previous studies. The results suggest that any predictability of the SEA, and by implication the NAO, based on tropical rainfall may not be robust and may, in fact, be modulated on multidecadal time scales, with implications for seasonal and decadal prediction systems.
    Description: The positive phase of the SEA is associated with warm summers in Europe. The figure shows the running correlation in 51 year windows between the SEA index and the corresponding tropical rainfall index in a long pre‐industrial model run. The link between tropical rainfall and the SEA exists only in some decadal epochs, shown by the green shading, implying that predictability of the SEA based on tropical rainfall can be expected to vary on multidecadal time scales.
    Keywords: 551.5 ; nonstationarity ; seasonal prediction ; summer East Atlantic pattern
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  • 58
    Publication Date: 2021-07-21
    Description: Understanding the coupling between convective clouds and the general circulation, as well as addressing the gray zone problem in convective parameterization, requires insight into the genesis and maintenance of spatial patterns in cumulus cloud populations. In this study, a simple toy model for recreating populations of interacting convective objects as distributed over a two‐dimensional Eulerian grid is formulated to this purpose. Key elements at the foundation of the model include i) a fully discrete formulation for capturing discrete behavior in convective properties at small population sample sizes, ii) object age‐dependence for representing life‐cycle effects, and iii) a prognostic number budget allowing for object interactions and co‐existence of multiple species. A primary goal is to optimize the computational efficiency of this system. To this purpose the object birth rate is represented stochastically through a spatially aware Bernoulli process. The same binomial stochastic operator is applied to horizontal advection of objects, conserving discreteness in object number. The applicability to atmospheric convection as well as behavior implied by the formulation is assessed. Various simple applications of the BiOMi model (Binomial Objects on Microgrids) are explored, suggesting that important convective behavior can be captured at low computational cost. This includes i) subsampling effects and associated powerlaw scaling in the convective gray zone, ii) stochastic predator‐prey behavior, iii) the downscale turbulent energy cascade, and iv) simple forms of spatial organization and convective memory. Consequences and opportunities for convective parameterization in next‐generation weather and climate models are discussed.
    Description: Plain Language Summary: Convective clouds play a crucial role in Earth's climate. The way they interact with the atmospheric circulation is not well understood, and is associated with long‐standing problems in weather forecasting and climate prediction. Recent research has suggested that the spatial structure of these cloud fields is a key factor in this problem, and that improving our understanding of such convective cloud patterns is crucial for making progress. This study explores a new model framework for generating such cloud patterns, consisting of populations of convective objects on small grids. The objects are born in a random way, complete a life cycle, and can freely move around on the grid. They can also interact and form larger clusters, obeying certain rules of interaction. The way the objects behave and move around features some key innovations compared to previous ecosystem models of this kind. These are introduced to optimize the performance and reduce run time on a computer. Various experiments are conducted to explore the new model, illustrating that well‐known behavior of convective populations is reproduced. These tests also highlight opportunities created for improving convection in weather and climate models.
    Description: Key Points: A scale‐aware stochastic number generator based on a Bernoulli process is applied to model object births and advection on Eulerian grids. Discreteness in object number is conserved, while an age dimension is included to represent object life cycle effects. Population subsampling effects in the convective gray zone are reproduced, while simple applications capture well‐known convective behavior.
    Description: U.S. Department of Energy (DOE) http://dx.doi.org/10.13039/100000015
    Keywords: 551.5 ; binomial sampling ; convective clouds ; gray zone ; microgrids ; object interactions ; population modeling
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  • 59
    Publication Date: 2021-07-21
    Description: This study presents recent observations to quantify oceanic heat fluxes along the continental slope of the Eurasian part of the Arctic Ocean, in order to understand the dominant processes leading to the observed along‐track heat loss of the Arctic Boundary Current (ABC). We investigate the fate of warm Atlantic Water (AW) along the Arctic Ocean continental margin of the Siberian Seas based on 11 cross‐slope conductivity, temperature, depth transects and direct heat flux estimates from microstructure profiles obtained in summer 2018. The ABC loses on average O(108) J m−2 per 100 km during its propagation along the Siberian shelves, corresponding to an average heat flux of 47 W m−2 out of the AW layer. The measured vertical heat flux on the upper AW interface of on average 10 W m−2 in the deep basin, and 3.7 W m−2 above the continental slope is larger than previously reported values. Still, these heat fluxes explain less than 20% of the observed heat loss within the boundary current. Heat fluxes are significantly increased in the turbulent near‐bottom layer, where AW intersects the continental slope, and at the lee side of a topographic irregularity. This indicates that mixing with ambient colder water along the continental margins is an important contribution to AW heat loss. Furthermore, the cold halocline layer receives approximately the same amount of heat due to upward mixing from the AW, compared to heat input from the summer‐warmed surface layer above. This underlines the importance of both surface warming and increased vertical mixing in a future ice‐free Arctic Ocean in summer.
    Description: Plain Language Summary: Warm water from the Atlantic Ocean enters the Arctic Ocean through the Barents Sea and the Fram Strait, between Greenland and Norway, and directly influences the formation of sea ice: When the Atlantic Water (AW) is located close to the ocean's surface, as is the case shortly after its inflow in the Barents Sea, sea ice melts and new sea ice formation is hindered. This is why the Barents Sea is often ice free, even in winter. Further along the pathway, in the Laptev and East Siberian Sea study region, the AW gradually cools and dives down to deeper layers. In order to quantify the cooling and to understand how and where it happens, we measured vertical profiles of temperature and heat fluxes along a 2,500 km long part of the AW pathway. Based on these measurements, we found that the heat loss mainly occurs by mixing of warm AW with ambient cold water above the continental slope, in particular in the highly energetic region near the sea floor.
    Description: Key Points: The Atlantic Water (AW) transported in the Arctic Boundary Current loses O(108)  J m−2 per 100 km during its translation along the Siberian shelves Heat fluxes are larger than previously reported values, but too small to account for this heat loss, indicating the importance of boundary mixing The heat input from the underlying AW layer to the cold halocline is of similar magnitude to the heat input from the warm surface layer above
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: NSF | GEO | Division of Ocean Sciences http://dx.doi.org/10.13039/100000141
    Keywords: 551.46 ; Arctic Boundary Current ; Arctic Ocean ; heat flux ; Laptev Sea ; mixing ; turbulence
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  • 60
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    In:  J.Oehlenschlaeger@gmx.net | http://aquaticcommons.org/id/eprint/11132 | 1240 | 2013-04-08 18:42:57 | 11132 | Johann Heinrich von Thünen-Institut, Bundesforschungsinstitut für Ländliche Räume, Wald und Fischerei
    Publication Date: 2021-06-28
    Description: KurzfassungZahlreiche Fischereierzeugnisse aus dem Deutschen Handel wurden auf ihren Gehalt an Cholesterol hin analysiert. ZurAnalyse gelangten 38 verschiedene Dauerkonserven von acht Fischarten, 4 Produkte kalt geräucherter AtlantischerZuchtlachs in Scheiben, 10 Garnelenarten und 25 Fischstäbchenerzeugnisse von 5 Tierarten in Verbraucherpackungen. Bei den Dauerkonserven lagen die Gehalte zwischen 24 und 40 mg/100 g. Zwei Ausnahmen bildeten Sprottenkonserven mit durchschnittlich 107 mg/100 g und Oktopuskonserven mit 196 mg/100 g. Die Garnelenarten variierten zwischen 84 und 161 mg/100g. Die kalt geräucherten Lachsscheiben wiesen nur eine kleine Bandbreite im Cholesterolgehalt zwischen 38 und 43mg/100 g auf. Alle Fischstäbchen aus Magerfischen enthielten niedrige Gehalte an Cholesterol (Pangasius hypophthalmus 25, Seehecht 19, Seelachs 31 und Alaska Seehecht 28 mg/100 g), während die zwei Proben aus Tintenfischen über 100 mg/100 g lagen.AbstractNumerous fishery products from the German market have been analysed for their content of cholesterol. In total 38 different canned fishery products produced from 8 species, 4 products of sliced cold smoked Atlantic salmon, 10 species of crustacean shellfish and 25 different brands of consumer packages of fish fingers (produced from 5 species) were investigated. Canned fishery products contained amounts of cholesterol ranging from 24 to 40 mg/100 g. However, canned sprats exhibit cholesterol content as high as 107 mg/100g and canned octopus 196 mg/100 g. Crustacean shellfish was found to contain cholesterol content between 84 and 161 mg/100 g depending of species. Sliced cold smoked salmon in 200 g consumer packages showed only a little variation in cholesterol content (38-43 mg/100 g). In all fish fingers produced from lean fish species lowcholesterol content (pangasius or sutchi catfish 25, hake 19, saithe 31, and Alaska Pollack 28 mg/100 g, respectively) was found, whereas two products produced from squid exceeded 100 mg/100 g.
    Description: Johann Heinrich von Thünen-Institute, Federal Research Institute of Rural Areas, Forestry and Fisheries began publishing the Informationen aus der Fischereiforschung - Information on Fishery Research in 2010
    Keywords: Chemistry ; Fisheries ; Information Management ; fish products ; consumer protection ; chemical analysis ; nutrition advice ; healthy nutrition
    Repository Name: AquaDocs
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    Format: application/pdf
    Format: application/pdf
    Format: 71-79
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  • 61
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    In:  hartmut.rehbein@mri.bund.de | http://aquaticcommons.org/id/eprint/11167 | 1240 | 2013-05-17 07:56:42 | 11167 | Johann Heinrich von Thünen-Institut, Bundesforschungsinstitut für Ländliche Räume, Wald und Fischerei
    Publication Date: 2021-06-28
    Description: To ensure the authentication of fishery products lacking biological characters, rapid species identification methods are required. Two DNA- and protein-based methods, PCR-SSCP (polymerase chain reaction - single strand conformation polymorphism) of a 464 bp segment of the cytochrome b – gene and isoelectric focusing (IEF) of water-soluble proteins from fish fillets, were applied to identify fillets of (sub-) tropical fish species available on the European market. Among the samples analysed weretwo taxonomically identified species from the family Sciaenidae and one from Sphyraenidae. By comparison of DNA- and protein patterns of different samples, information about intra-species variability of patterns,and homogeneity of batches (e.g. fillet blocks or bags) can be obtained. PCR-SSCP and IEF may be useful for pre-checking of a large number of samples by food control laboratories.ZusammenfassungZur Sicherstellung der Authentizität von Fischerei-Erzeugnissen ohne biologische Merkmale sind schnelle Verfahren zur Speziesidentifizierung hilfreich. Zwei Methoden der DNA- bzw. Protein-Analyse wurden eingesetzt, um Filets (sub-) tropischer Fischarten, die auf dem europäischen Markt angeboten werden, zu identifizieren. Bei diesen Methoden handelt es sich um die PCR-SSCP (Polymerase-Kettenreaktion – Einzelstrang-Konformationspolymorphismus) – Analyse der PCR-Produkte und die IEF (isoelektrische Fokussierung) der wasserlöslichen Fischmuskelproteine. Unter den untersuchten Proben waren zwei taxonomisch bestimmte Arten aus der Familie Sciaenidae und eine Spezies aus der Familie Sphyraenidae. Durch Vergleich der DNA- bzw. Proteinmuster lassen sich Informationen über die intra-spezifische Variabilität solcher Muster und die Einheitlichkeit von Partien (beispielsweise Filetblöcke oder Filetbeutel) gewinnen. PCR-SSCP und IEF könnenin Laboratorien der Lebensmittelüberwachung als Vortest gerade bei hohen Probenzahlen sinnvoll eingesetzt werden.
    Description: Johann Heinrich von Thünen-Institute, Federal Research Institute of Rural Areas, Forestry and Fisheries began publishing the Informationen aus der Fischereiforschung - Information on Fishery Research in 2010
    Keywords: Chemistry ; Fisheries ; fish species identification ; PCR ; SSCP ; IEF ; Sciaenidae ; Sphyraenidae ; Fischarten-Identifizierung
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    Texas Game and Fish Commission Marine Laboratory | Rockport, TX
    In:  http://aquaticcommons.org/id/eprint/14207 | 9596 | 2020-08-23 22:50:08 | 14207 | Galveston Bay Information Collection
    Publication Date: 2021-06-24
    Description: In order to obtain information on the characteristics of water and climate that prevail in Galveston Bay, East Bay, and West Bay, established stations were sampled regularly. Information derived from samples included water temperature and salinity. Additional information of this nature was derived from other bay studies. Information on river flow, air temperature and wind were derived from publications. Water temperatures were found to follow air temperatures closely. The prevailing winds in all but two months were on-shore winds. Salinities were found to vary inversely with the volume of fresh water entering the bays from the Trinity River. West Bay, due to its locations, is affected less than the other bays by fresh water from the Trinity River. Vertical and horizontal salinity gradients were found to be the normal pattern in East Bay and Galveston Bay. West Bay, with two major passes to the Gulf of Mexico and with no major source of fresh water, normally maintained higher salinities than the other bays.
    Keywords: Chemistry ; Oceanography ; GBIC ; hydrography ; meteorology ; salinity gradients ; temperature ; salinity ; water sampling
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    South Central Environmental Center, NUS Corporation | Houston, TX
    In:  http://aquaticcommons.org/id/eprint/14172 | 9596 | 2020-08-31 20:26:12 | 14172 | Galveston Bay Information Collection
    Publication Date: 2021-06-24
    Description: In May 1979, Contract No. DACW64-79-C-0037, for performance of bioassays and bioaccumulation studies, chemical analyses of sediments, seawater and elutriate materials, and appropriate statistical analyses of samples obtained from the Galveston Harbor and Sabine-Neches Waterway Channels, was awarded to NUS Corporation by the Army Corps of Engineers, Galveston District. These studies are part of a continuing evaluation of the potential environmental effects of proposed ocean disposal of dredged materials and are required for compliance with provisions of Section 103 of the Marine Protection, Research and Sanctuaries Act of 1972 (PL 92-532). This final report presents the results of dredged material evaluations for the Galveston Harbor Channel project area.
    Keywords: Chemistry ; Limnology ; bioassay ; chemical analyses ; statistical analyses ; water quality
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    Type: monograph
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    Texas Game and Fish Commission | Rockport, TX
    In:  http://aquaticcommons.org/id/eprint/14213 | 9596 | 2020-08-23 22:33:19 | 14213 | Galveston Bay Information Collection
    Publication Date: 2021-06-24
    Description: Observations and analysis of the various features of the water of upper Galveston and Trinity Bays (Area M-2) were made using dye, thermometers, chemical tests, and other appropriate methods. Information and data were also collected from numerous publications and other sources. The distribution of marine organisms relative to pollution in the Houston Ship Channel was investigated.
    Keywords: Chemistry ; Ecology ; Pollution ; chemical analysis ; physical properties ; water analysis ; pollution ; marine organisms ; ecological distribution ; GBIC
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    In:  bill.sunda@noaa.gov | http://aquaticcommons.org/id/eprint/14910 | 403 | 2014-03-11 19:18:24 | 14910 | United States National Ocean Service
    Publication Date: 2021-06-28
    Description: Time series measurements of dimethylsulfide (DMS), particulate dimethylsulfoniopropionate (DMSPp), chlorophyll a (chl a), algal pigments, major nutrients, and the potential activity of DMSP lyase enzymes were made over a 2 yr period (6 March 2003 to 28 March 2005) near the mouth of the shallow, tidally mixed Newport River estuary, North Carolina, USA. DMSPp had a mean of 43 ± 20 nM (range = 10.5 to 141 nM, n = 85) and DMS a mean of 2.7 ± 1.2 nM (range = 0.9 to 7.0 nM). The mean DMS in Gallants Channel was not significantly different from that measured in the Sargasso Sea near Bermuda during a previous 3 yr time series study (2.4 ± 1.5 nM), despite there being a 43-fold higher mean chl a concentration (4.9 ± 2.4 µg l–1) at the coastal site. In winter, DMS was low and chl a was high in the surface waters of the Sargasso Sea, while the opposite was true at the coastal site. Consequently, DMS concentrations per unit algal chl a were on average 170 times higher in the Sargasso Sea than at the coastal site during the summer, but only 7 times higher during the winter. The much higher chl a-specific DMS concentrations at the oceanic site during the summer were linked to higher ratios of intracellular DMSP substrate and DMSP lyase enzyme per unit chl a. These differences in turn appear to be linked to large differences in nutrient concentrations and solar UV stress at the 2 sites and to associated differences in the composition of algal assemblages and physiological acclimation of algal cells.
    Keywords: Chemistry ; Ecology ; Management
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    In:  milton.levin@uconn.edu | http://aquaticcommons.org/id/eprint/14911 | 403 | 2014-03-10 20:01:03 | 14911 | United States National Ocean Service
    Publication Date: 2021-06-28
    Description: The immunotoxic potential of domoic acid (DA), a well-characterized neurotoxin, has not been fully investigated. Phagocytosis and lymphocyte proliferation were evaluated following in vitro and in vivo exposure to assay direct vs indirect effects. Mice were injected intraperitoneally with a single dose of DA (2.5 µg/g b.w.) and sampled after 12, 24, or 48 hr. In a separate experiment, leukocytes and splenocytes were exposed in vitro to 0, 1, 10, or 100 µM DA. In vivo exposure resulted in a significant increase in monocyte phagocytosis (12-hr), a significant decrease in neutrophil phagocytosis (24-hr), a significant decrease in monocyte phagocytosis (48-hr), and a significant reduction in T-cell mitogen-induced lymphocyte proliferation (24-hr). In vitro exposure significantly reduced neutrophil and monocyte phagocytosis at 1 µM. B- and T-cell mitogen-induced lymphocyte proliferation were both significantly increased at 1 and 10 µM, and significantly decreased at 100 µM. Differences between in vitro and in vivo results suggest that DA may exert its immunotoxic effects both directly and indirectly. Modulation of cytosolic calcium suggests that DA exerts its effects through ionotropic glutamate subtype surface receptors at least on monocytes. This study is the first to identify DA as an immunotoxic chemical in a mammalian species.
    Keywords: Chemistry ; Health
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    In:  http://aquaticcommons.org/id/eprint/15095 | 403 | 2014-05-28 03:30:26 | 15095 | United States National Marine Fisheries Service
    Publication Date: 2021-07-02
    Description: As nearshore fish populations decline, many commercialfishermen have shifted fishing effort to deeper continental slope habitats to target fishes for which biologicalinformation is limited. One such fishery that developed in the northeastern Pacific Ocean in the early 1980s was for the blackgill rockfish (Sebastes melanostomus), a deep-dwelling (300−800 m) species that congregates over rocky pinnacles, mainly from southern California to southernOregon. Growth zone-derived age estimates from otolith thin sections were compared to ages obtained from the radioactive disequilibria of 210Pb, in relation to its parent, 226Ra, in otolith cores of blackgill rockfish. Age estimates were validated up to 41 years, and a strong pattern of agreement supported a longevity exceeding 90years. Age and length data fitted to the von Bertalanffy growth function indicated that blackgill rockfish are slow-growing (k= 0.040 females, 0.068 males) and that females grow slower than males, but reach a greater length. Age at 50% maturity, derived from previously published length-at-maturity estimates, was 17 years for males and 21 years for females. The results of this study agree with general life history traits already recognized for many Sebastes species, such as long life, slow growth, and late age at maturation. These traits may undermine the sustainability of blackgill rockfish populations when heavy fishing pressure, such as that which occurred in the 1980s, is applied.
    Keywords: Chemistry ; Fisheries ; Management
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    In:  http://aquaticcommons.org/id/eprint/15137 | 403 | 2014-05-23 00:06:17 | 15137 | United States National Marine Fisheries Service
    Publication Date: 2021-07-03
    Keywords: Chemistry ; Fisheries
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    In:  http://aquaticcommons.org/id/eprint/15139 | 403 | 2014-05-23 00:04:39 | 15139 | United States National Marine Fisheries Service
    Publication Date: 2021-07-03
    Description: Horseshoe crabs (Limulus polyphemus) are caught by commercial fishermen for use as bait in eel and whelk fisheries (Berkson and Shuster, 1999)—fisheries with an annual economic value of $13 to $17 million (Manion et al.1). Horse-shoe crabs are ecologically important, as well (Walls et al., 2002). Migratory shorebirds rely on horseshoe crab eggs for food as they journey from South American wintering grounds to Arctic breeding grounds (Clark, 1996). Horse-shoe crabs are also essential for public health (Berkson and Shuster, 1999). Biomedical companies bleed horse-shoe crabs to extract a chemical used to detect the presence of endotoxins pathogenic to humans in injectable and implantable medical devices (Novitsky, 1984; Mikkelsen, 1988). Bled horseshoe crabs are returned to the wild, subject to the possibility of postbleeding mortality. Recent concerns of overharvesting have led to conflicts among commercial fishermen, environmentalists acting on behalf of the shorebirds, and biomedical companies (Berkson and Shuster, 1999; Walls et al., 2002).
    Keywords: Biology ; Chemistry ; Fisheries
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    In:  http://aquaticcommons.org/id/eprint/15161 | 403 | 2014-05-29 07:19:00 | 15161 | United States National Marine Fisheries Service
    Publication Date: 2021-07-03
    Description: The use of strontium-to-calcium (Sr/Ca) ratios in otoliths is becoming a standard method to describe life history type and the chronology of migrations between freshwater and seawater habitats in teleosts (e.g. Kalish, 1990; Radtke et al., 1990; Secor, 1992; Rieman et al., 1994; Radtke, 1995; Limburg, 1995; Tzeng et al. 1997; Volk et al., 2000; Zimmerman, 2000; Zimmerman and Reeves, 2000, 2002). This method provides critical information concerning the relationship and ecology of species exhibiting phenotypic variation in migratory behavior (Kalish, 1990; Secor, 1999).Methods and procedures, however, vary among laboratories because a standard method or protocol for measurement ofSr in otoliths does not exist. In this note, we examine the variations in analytical conditions in an effort to increase precision of Sr/Ca measurements. From these findings we argue that precision can be maximized withhigher beam current (although there is specimen damage) than previously recommended by Gunn et al. (1992).
    Keywords: Chemistry ; Fisheries
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    In:  http://aquaticcommons.org/id/eprint/15180 | 403 | 2014-05-29 07:50:04 | 15180 | United States National Marine Fisheries Service
    Publication Date: 2021-07-04
    Keywords: Chemistry ; Fisheries
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  • 72
    Publication Date: 2021-07-04
    Keywords: Biology ; Chemistry ; Fisheries ; Management
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    In:  http://aquaticcommons.org/id/eprint/15184 | 403 | 2014-05-29 07:55:35 | 15184 | United States National Marine Fisheries Service
    Publication Date: 2021-07-04
    Description: Otolith thermal marking is an efficient method for mass marking hatchery-reared salmon and can be used to estimate the proportion of hatchery fish captured in a mixed-stock fishery. Accuracy of the thermal pattern classification depends on the prominence of the pattern, the methods used to prepare and view the patterns, and the training and experience of the personnel who determine the presence or absence of a particular pattern. Estimating accuracy rates is problematic when no secondary marking is available and no error-free standards exist. Agreement measures, such as kappa (κ), provide a relative measure of the reliability of the determinations when independent readings by two readers are available, but the magnitude of κ can be influenced by the proportion of marked fish. If a third reader is used or if two or more groups of paired readings are examined, latent class models can provide estimates of the error rates of each reader. Applications of κ and latent class models are illustrated by a program providing contribution estimates of hatchery-reared chum and sockeye salmon in Southeast Alaska.
    Keywords: Biology ; Chemistry ; Fisheries
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    In:  http://aquaticcommons.org/id/eprint/15195 | 403 | 2014-05-30 07:14:43 | 15195 | United States National Marine Fisheries Service
    Publication Date: 2021-07-04
    Description: Skeletochronological data on growth changes in humerus diameter were used to estimate the age of Hawaiian green seaturtles ranging from 28.7 to 96.0 cm straight carapace length. Two age estimation methods, correction factor and spline integration, were compared, giving age estimates ranging from 4.1 to 34.6 and from 3.3 to 49.4 yr, respectively, for the sample data. Mean growth rates of Hawaiian green seaturtles are 4–5 cm/yr in early juveniles, decline to a relatively constant rate of about 2 cm/yr by age 10 yr, then decline again to less than 1 cm/yr as turtles near age 30 yr. On average, age estimates from the two techniques differed by just a few years for juvenile turtles, but by wider margins for mature turtles. The spline-integration method models the curvilinear relationship between humerus diameter and the width of periosteal growth increments within the humerus, and offers several advantages over the correction-factor approach.
    Keywords: Biology ; Chemistry ; Fisheries
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    In:  http://aquaticcommons.org/id/eprint/15230 | 403 | 2014-06-01 18:56:50 | 15230 | United States National Marine Fisheries Service
    Publication Date: 2021-07-05
    Description: Independent molecular markers based on mitochondrial and nuclear DNA were developed to provide positive identification of istiophorid and xiphiid billfishes (marlins, spearfishes, sailfish, and swordfish). Both classes of markers were based on amplification of short segments (〈1.7 kb) of DNA by the polymerase chain reaction and subsequent digestion with informative restriction endonucleases. Candidate markers were evaluated for their ability to discriminate among the different species and the level of intraspecific variation they exhibited. The selected markers require no more than two restriction digestions to allow unambiguous identification, although it was not possible to distinguish between white marlin and striped marlin with any of the genetic characters screened in our study. Individuals collected from throughout each species’ range were surveyed with the selected markers demonstrating low levels of intraspecific character variation within species. The resulting keys provide two independent means for the forensic identification of fillets and for specific identification of early life history stages.
    Keywords: Biology ; Chemistry ; Fisheries ; Management
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    In:  http://aquaticcommons.org/id/eprint/15228 | 403 | 2014-06-01 18:57:37 | 15228 | United States National Marine Fisheries Service
    Publication Date: 2021-07-05
    Description: Catch rates in the South African rock lobster (Jasus lalandii) fishery declined after 1989 in response to reduced adult somatic growth rates and a consequent reduction in recruitment to the fishable population. Although spatial and temporal trends in adult growth are well described, little is known about how juvenile growth rates have been affected. In our study, growth rates of juvenile rock lobster on Cape Town harbor wall were compared with those recorded at the same site more than 25 years prior to our study, and with those on a nearby natural nursery reef. We found that indices of somatic growth measured during 1996–97 at the harbor wall had declined significantly since 1971–72. Furthermore, growth was slower among juvenile J. lalandii at the harbor wall than those at the natural nursery reef. These results suggest that growth rates of juvenile and adult J. lalandii exhibit similar types of spatiotemporal patterns. Thus, the recent coastwide decline in adult somatic growth rates might also encompass smaller size classes.
    Keywords: Biology ; Chemistry ; Fisheries
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    In:  http://aquaticcommons.org/id/eprint/15236 | 403 | 2014-06-01 18:54:03 | 15236 | United States National Marine Fisheries Service
    Publication Date: 2021-07-05
    Description: Loggerhead sea turtles (Caretta caretta) are migratory, long-lived, and slow maturing. They are difficult to study because they are seen rarely and their habitats range over vast stretches of the ocean. Movements of immature turtles between pelagic and coastal developmental habitats are particularly difficult to investigate because of inadequate tagging technologies and the difficulty in capturing significant numbers of turtles at sea. However, genetic markers found in mitochondrial DNA (mtDNA) provide a basis for predicting the origin of juvenile turtles in developmental habitats. Mixed stock analysis was used to determine which nesting populations were contributing individuals to a foraging aggregation of immature loggerhead turtles (mean 63.3 cm straight carapace length [SCL]) captured in coastal waters off Hutchinson Island, Florida. The results indicated that at least three different western Atlantic loggerhead sea turtle subpopulations contribute to this group: south Florida (69%), Mexico (20%), and northeast Florida-North Carolina (10%). The conservation and management of these immature sea turtles is complicated by their multinational genetic demographics.
    Keywords: Biology ; Chemistry ; Fisheries ; Management
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    In:  http://aquaticcommons.org/id/eprint/15248 | 403 | 2014-05-30 21:15:27 | 15248 | United States National Marine Fisheries Service
    Publication Date: 2021-07-05
    Description: We used allozyme, microsatellite, and mitochondrial DNA (mtDNA) data to test for spatial and interannual genetic diversity in wall-eye pollock (Theragra chalcogramma) from six spawning aggregations representing three geographic regions: Gulf of Alaska, eastern Bering Sea, and eastern Kamchatka. Interpopulation genetic diversity was evident primarily from the mtDNA and two allozyme loci (SOD-2*, MPI*). Permutation tests ˆindicated that FST values for most allozyme and microsatellite loci were not significantly greater than zero. The microsatellite results suggested that high locus polymorphism may not be a reliable indicator of power for detecting population differentiation in walleye pollock. The fact that mtDNA revealed population structure and most nuclear loci did not suggests that the effective size of most walleye pollock populations is large (genetic drift is weak) and migration is a relatively strong homogenizing force. The allozymes and mtDNA provided mostly concordant estimates of patterns of spatial genetic variation. These data showed significant genetic variation between North American and Asian populations. In addition, two spawning aggregations in the Gulf of Alaska, in Prince William Sound, and off Middleton Island, appeared genetically distinct from walleye pollock spawning in the Shelikof Strait and may merit management as a distinct stock. Finally, we found evidence of interannual genetic variation in two of three North American spawning aggregations, similar in magnitude to the spatial variation among North American walleye pol-lock. We suggest that interannual genetic variation in walleye pollock may be indicative of one or more of the following factors: highly variable reproductive success, adult philopatry, source-sink metapopulation structure, and intraannual variation (days) in spawning timing among genetically distinct but spatially identical spawning aggregates.
    Keywords: Biology ; Chemistry ; Fisheries
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    In:  http://aquaticcommons.org/id/eprint/15239 | 403 | 2014-06-01 18:52:47 | 15239 | United States National Marine Fisheries Service
    Publication Date: 2021-07-05
    Description: Intergeneric hybridization between the epinepheline serranids Cephalopholis fulva and Paranthias furcifer in waters off Bermuda was investigated by using morphological and molecular characters. Putative hybrids, as well as members of each presumed parent species, were analyzed for 44 morphological characters and screened for genetic variation at 16 nuclear allozyme loci, two nuclear (n)DNA loci, and three mitochondrial (mt)DNA gene regions. Four of 16 allozyme loci, creatine kinase (CK-B*), fumarase (FH*), isocitrate dehydrogenase (ICDH-S*), and lactate dehydrogenase (LDH-B*), were unique in C. fulva and P. furcifer. Restriction fragments of two nuclear DNA intron regions, an actin gene intron and the second intron in the S7 ribosomal protein gene, also exhibited consistent differences between the two presumed parent species. Restriction fragments of three mtDNA regions—ND4, ATPase 6, and 12S/16S ribosomal RNA—were analyzed to identify maternal parentage of putative hybrids. Both morphological data and nuclear genetic data were found to be consistent with the hypothesis that the putative hybrids were the result of interbreeding between C. fulva and P. furcifer. Mean values of 38 morphological characters were different between presumed parent species, and putative hybrids were intermediate to presumed parent species for 33 of these characters. A principal component analysis of the morphological and meristic data was also consistent with hybridization between C. fulva and P. furcifer. Thirteen of 15 putative hybrids were heterozygous at all diagnostic nuclear loci, consistent with F1 hybrids. Two putative hybrids were identified as post-F1 hybrids based on homozygosity at one nuclear locus each. Mitochondrial DNA analysis showed that the maternal parent of all putative hybrid individuals was C. fulva. A survey of nuclear and mitochondrial loci of 57 C. fulva and 37 P. furcifer from Bermuda revealed no evidence of introgression between the parent species mediated by hybridization.
    Keywords: Biology ; Chemistry ; Fisheries
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    In:  http://aquaticcommons.org/id/eprint/15350 | 9513 | 2014-09-19 15:17:44 | 15350
    Publication Date: 2021-07-06
    Description: This study assessed the physico-chemical quality of River Ogun, Abeokuta, Ogun state, Southwestern Nigeria. Four locations were chosen spatially along the water course to reflect a consideration of all possible human activities that are capable of changing the quality of river water. The water samples were collected monthly for seven consecutive months (December 2011 – June 2012) at the four sampling stations. pH, air temperature (℃), water temperature (℃), conductivity (µs/cm) and total dissolved solids (mg/L) were conducted in-situ with the use of HANNA Combo pH and EC multi meter Hi 98129 and Mercury-in-glass thermometer while dissolved oxygen (mg/L), nitrate (mg/L), phosphate (mg/L), alkalinity (mg/L) and hardness (mg/L) were determined ex-situ using standard methods. Results showed that dissolved oxygen, hydrogen ion concentration, total hardness and nitrate were above the maximum permissible limit of National Administration for Food, Drugs and Control (NAFDAC), Standard Organization of Nigeria (SON), Federal Environmental Protection Agency (FEPA), United States Environmental Protection Agency (USEPA), European Union (EU) and World Health Organization (WHO) for drinking water during certain months of the study period. Results also showed that water temperature and conductivity were within the permissible limits of all the standards excluding FEPA. However, total dissolved solids and alkalinity were within the permissible limits of all the standards. Adejuwon and Adelakun, (2012) also reported similar findings on Rivers Lala, Yobo and Agodo in Ewekoro local government area of Ogun state, Nigeria. Since most of the parameters measured were above the maximum permissible limits of the national and international standards, it can be concluded that the water is unfit for domestic uses, drinking and aquacultural purposes and therefore needs to be treated if it is to be used at all. The low dissolved oxygen values for the first four months was too low i.e. 〈 5 mg/L. This is most likely as a result of the amount of effluents discharged into the river. To prevent mass extinction of aquatic organisms due to anoxic conditions, proper regulations should be implemented to reduce the organic load the river receives.
    Keywords: Chemistry ; Environment ; Health ; Management ; Pollution
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    In:  http://aquaticcommons.org/id/eprint/16179 | 12051 | 2015-02-09 07:35:49 | 16179 | Society of Fisheries Technologists, India
    Publication Date: 2021-06-30
    Description: The object of this study was to determine the value of physical, bacteriological and chemical tests used to find out and compare the indices of quality of prawns stored at 0°C and at 18°C. pH value, nature of drip, the total bacterial count, presence or absence of tryptophan, trimethylamine content, glycogen, lactic acid, vitamins such as thiamin, riboflavin and niacin were estimated periodically to evaluate the quality of prawns stored at 0°C, whereas in addition to organoleptic changes, pH, bacterial count, nature of growth in peptone water, soluble protein in salt solution and loss of moisture, glycogen, lactic acid, and changes in vitamin B contents were noted periodically for prawns stored at -l8°C. Riboflavin and niacin were not affected appreciably but the retention of thiamin in prawns was very low.
    Keywords: Chemistry ; Fisheries ; chemical properties ; quality control ; Penaeus indicus ; processing fishery products ; cold storage ; storage effects
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    In:  http://aquaticcommons.org/id/eprint/16190 | 12051 | 2015-02-10 07:56:55 | 16190 | Society of Fisheries Technologists, India
    Publication Date: 2021-06-30
    Description: Fresh Bombay ducks and Bombay ducks dried (a) without any pre-treatment or (b) after brining with NaCl solutions of 15% and 7.5% concentrations for 18 hours were analyzed for moisture, ash, minerals, vitamins, fat, free fatty acids, peroxide value, thiobarbituric acid value, total protein, total amino nitrogen, soluble proteins and trimethylamine contents. All the dried samples were stored in (a) tightly closed tin containers or (b) polythene bags and analyzed for the above mentioned constituents every 1½ months. It was observed that brining did not exercise any marked influence on keeping properties. Organoleptic observations showed that fish stored in tin containers kept better and longer than those stored in polythene bags.
    Keywords: Biology ; Chemistry ; chemical composition ; Harpodon nehereus ; Bombay ducks ; nutritive value ; storage methods
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  • 83
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    Louisiana Universities Marine Consortium | Chauvin, LA
    In:  http://aquaticcommons.org/id/eprint/16531 | 30 | 2015-03-30 17:02:26 | 16531 | Louisiana Universities Marine Consortium (LUMCON)
    Publication Date: 2021-07-06
    Description: This report reviews some of the natural ecological processes at work within a salt marsh as they relate to a spill of natural gas condensate - a mixture of aliphatic hydrocarbons, n-hexane, benzene, toluene, and xylene. It also reviews the environmental impacts of some of the components of natural gas condensate as well as related compounds (crude oil, higher molecular weight hydrocarbons, polycyclic aromatic hydrocarons - PAHs, linear alkyl-benzenes - LABs, etc.) on salt marsh ecosystems in southern Louisiana and elsewhere in the world. The behavior and persistence of these compounds once they have entered the environment is also considered.
    Description: A report to El Paso Energy, Inc., Houston, Texas. PDF includes front matter, 62 pages of text, 40 figures, and 9 tables.
    Keywords: Chemistry ; Ecology ; Environment ; Pollution
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    Type: monograph
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    In:  Mike.Twiner@noaa.gov | http://aquaticcommons.org/id/eprint/14901 | 403 | 2014-03-10 19:58:44 | 14901 | United States National Ocean Service
    Publication Date: 2021-06-28
    Description: Azaspiracids (AZA) are polyether marine toxins that accumulate in various shellfish species and have been associated with severe gastrointestinal human intoxications since 1995. This toxin class has since been reported from several countries, including Morocco and much of western Europe. A regulatory limit of 160 μg AZA/kg wholeshellfish flesh was established by the EU in order to protect human health; however, in some cases, AZA concentrations far exceed the action level. Herein we discuss recent advances on the chemistry of various AZA analogs, review the ecology of AZAs, including the putative progenitor algal species, collectively interpret the in vitro and in vivo data on the toxicology of AZAs relating to human health issues, and outline the European legislature associated with AZAs.
    Keywords: Chemistry ; Ecology ; Fisheries ; Health
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  • 85
    Publication Date: 2021-06-28
    Description: Ciguatoxins (CTX) are polyether neurotoxins that target voltage-gated sodium channels and are responsible for ciguatera, the most common fish-borne food poisoning in humans. This study characterizes the global transcriptional response of mouse liver to a symptomatic dose (0.26 ng/g) of the highly potent Pacific ciguatoxin-1 (P-CTX-1). At 1 h post-exposure 2.4% of features on a 44K whole genome array were differentially expressed (p ≤ 0.0001), increasing to 5.2% at 4 h and decreasing to 1.4% by 24 h post-CTX exposure. Data were filtered (|fold change| ≥ 1.5 and p ≤ 0.0001 in at least one time point) and a trend set of 1550 genes were used for further analysis. Early gene expression was likely influenced prominently by an acute 4°C decline in core body temperature by 1 h, which resolved by 8 h following exposure. An initial downregulation of 32 different solute carriers, many involved in sodium transport, was observed. Differential gene expression in pathways involving eicosanoid biosynthesis and cholesterol homeostasis was also noted. Cytochrome P450s (Cyps) were of particular interest due to their role in xenobiotic metabolism. Twenty-seven genes, mostly members of Cyp2 and Cyp4 families, showed significant changes in expression. Many Cyps underwent an initial downregulation at 1 h but were quickly and strongly upregulated at 4 and 24 h post-exposure. In addition to Cyps, increases in several glutathione S-transferases were observed, an indication that both phase I and phase II metabolic reactions are involved in the hepatic response to CTX in mice.
    Keywords: Chemistry ; Health
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    Format: application/pdf
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    In:  rikk_kvitek@csumb.edu | http://aquaticcommons.org/id/eprint/14907 | 403 | 2014-03-11 17:26:19 | 14907 | United States National Ocean Service
    Publication Date: 2021-06-28
    Description: Benthic food webs often derive a significant fraction of their nutrient inputs from phytoplankton in the overlying waters. If the phytoplankton include harmful algal species like Pseudo-nitzschia australis, a diatom capable of producing the neurotoxin domoic acid (DA), the benthic food web can become a depository for phycotoxins. We tested the general hypothesis that DA contaminates benthic organisms during local blooms of P. australis, a widespread toxin producer along the US west coast. To test for trophic transfer and uptake of DA into the benthic food web, we sampled 8 benthic species comprising 4 feeding groups: filter feeders (Emerita analoga and Urechis caupo); a predator (Citharichthys sordidus); scavengers (Nassarius fossatus and Pagurus samuelis) and deposit feeders (Neotrypaea californiensis, Dendraster excentricus and Olivella biplicata). Sampling occurred before, during and after blooms of P. australis in Monterey Bay, CA, USA during 2000 and 2001. DA was detected in all 8 species, with contamination persisting over variable time scales. Maximum DA levels in N. fossatus (674 ppm), E. analoga (278 ppm), C. sordidus (515 ppm), N. californiensis (145 ppm), P. samuelis (56 ppm), D. excentricus (15 ppm) and O. biplicata (3 ppm) coincided with P. australis blooms, while DA levels in U. caupo remained above 200 ppm (max. = 751 ppm) throughout the study period. DA in 6 species exceeded levels thought to be safe for higher level consumers (i.e. ≥20 ppm) and thus is likely to have deleterious effects on marine birds, sea lions and the endangered California sea otter, known to prey upon these benthic species.
    Keywords: Chemistry ; Fisheries ; Pollution
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  • 87
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    In:  cooperge@musc.edu | http://aquaticcommons.org/id/eprint/14914 | 403 | 2014-03-10 17:55:40 | 14914 | United States National Ocean Service
    Publication Date: 2021-06-28
    Description: The Hedgehog signaling pathway is essential for embryogenesis and for tissue homeostasis in the adult. However, it may induce malignancies in a number of tissues when constitutively activated, and it may also have a role in other forms of normal and maladaptive growth. Cyclopamine, a naturally occurring steroidal alkaloid, specifically inhibits the Hedgehog pathway by binding directly to Smoothened, an important Hedgehog response element. To use cyclopamine as a tool to explore and/or inhibit the Hedgehog pathway in vivo, a substantial quantity is required, and as a practical matter cyclopamine has been effectively unavailable for usage in animals larger than mice.
    Description: Article includes 6 pages.
    Keywords: Chemistry ; Ecology ; Fisheries
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  • 88
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    In:  http://aquaticcommons.org/id/eprint/15043 | 403 | 2014-05-27 14:14:30 | 15043 | United States National Marine Fisheries Service
    Publication Date: 2021-07-01
    Description: Twenty-six stocks of Pacific salmon and trout (Oncorhynchus spp.), representing evolutionary significant units (ESU), are listed as threatened or endangered under the Endangered Species Act (ESA) and six more stocks are currently being evaluated for listing. The ecological and economic consequences of these listings are large; therefore considerable effort has been made to understand and respond to these declining populations. Until recently, Pacific harbor seals (Phoca vitulina richardsi) on the west coast increased an average of 5% to 7% per year as a result of the Marine Mammal Protection Act of 1972 (Brown and Kohlman2). Pacific salmon are seasonally important prey for harbor seals (Roffe and Mate, 1984; Olesiuk, 1993); therefore quantifying and understanding the interaction between these two protected species is important for Morphobiologically sound management strategies. Because some Pacific salmonid species in a given area may be threatened or endangered, while others are relatively abundant, it is important to distinguish the species of salmonid upon which the harbor seals are preying. This study takes the first step in understanding these interactions by using molecular genetic tools for species-level identification of salmonid skeletal remains recovered from Pacific harbor seal scats.
    Keywords: Chemistry ; Ecology ; Fisheries
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    Format: application/pdf
    Format: 213-220
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  • 89
    Publication Date: 2021-07-01
    Description: With the global proliferation of toxic Harmful Algal Bloom (HAB) species, there is a need to identify the environmental and biological factors that regulate toxin production. One such species, Karenia brevis, forms nearly annual blooms that threaten coastal regions throughout the Gulf of Mexico. This dinoflagellate produces brevetoxins, potent neurotoxins that cause neurotoxic shellfish poisoning and respiratory illness in humans, as well as massive fish kills. A recent publication reported that a rapid decrease in salinity increased cellular toxin quotas in K. brevis and hypothesized that brevetoxins serve a role in osmoregulation. This finding implied that salinity shifts could significantly alter the toxic impacts of blooms. We repeated the original experiments separately in three different laboratories and found no evidence for increased brevetoxin production in response to low-salinity stress in any of the eight K. brevis strains we tested, including three used in the original study. Thus, we find no support for an osmoregulatory function of brevetoxins. The original publication also stated that there was no known cellular function for brevetoxins. However, there is increasing evidence that brevetoxins promote survival of the dinoflagellates by deterring grazing by zooplankton. Whether they have other as yet unidentified cellular functions is currently unknown.
    Keywords: Chemistry ; Fisheries ; Pollution
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  • 90
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    In:  http://aquaticcommons.org/id/eprint/14672 | 403 | 2014-02-26 20:33:40 | 14672 | United States National Ocean Service
    Publication Date: 2021-07-01
    Description: Dinoflagellates possess many physiological processes that appear to be under post-transcriptional control. However, the extent to which their genes are regulated post-transcriptionally remains unresolved. To gain insight into the roles of differential mRNA stability and de novo transcription in dinoflagellates, we biosynthetically labeled RNA with 4-thiouracil to isolate newly transcribed and pre-existing RNA pools in Karenia brevis. These isolated fractions were then used for analysis of global mRNA stability and de novo transcription by hybridization to a K. brevis microarray. Global K. brevis mRNA half-lives were calculated from the ratio of newly transcribed to pre-existing RNA for 7086 array features using the online software HALO (Half-life Organizer). Overall, mRNA half-lives were substantially longer than reported in other organisms studied at the global level, ranging from 42 minutes to greater than 144 h, with a median of 33 hours. Consistent with well-documented trends observed in other organisms, housekeeping processes, including energy metabolism and transport, were significantly enriched in the most highly stable messages. Shorter-lived transcripts included a higher proportion of transcriptional regulation, stress response, and other response/regulatory processes. One such family of proteins involved in post-transcriptional regulation in chloroplasts and mitochondria, the pentatricopeptide repeat (PPR) proteins, had dramatically shorter half-lives when compared to the arrayed transcriptome. As transcript abundances for PPR proteins were previously observed to rapidly increase in response to nutrient addition, we queried the newly synthesized RNA pools at 1 and 4 h following nitrate addition to N-depleted cultures. Transcriptome-wide there was little evidence of increases in the rate of de novo transcription during the first 4 h, relative to that in N-depleted cells, and no evidence for increased PPR protein transcription. These results lend support to the growing consensus of post-transcriptional control of gene expression in dinoflagellates.
    Keywords: Chemistry ; Fisheries
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  • 91
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    NOAA/National Centers for Coastal Ocean Science | Silver Spring, MD
    In:  http://aquaticcommons.org/id/eprint/14678 | 403 | 2014-02-24 20:59:15 | 14678 | United States National Ocean Service
    Publication Date: 2021-07-01
    Description: This report is the second in a series from a project to assess land-based sources of pollution (LBSP) and effects in the St. Thomas East End Reserves (STEER) in St. Thomas, USVI, and is the result of a collaborative effort between NOAA’s National Centers for Coastal Ocean Science, the USVI Department of Planning and Natural Resources, the University of the Virgin Islands, and The Nature Conservancy.Passive water samplers (POCIS) were deployed in the STEER in February 2012. Developed by the US Geological Survey(USGS) as a tool to detect the presence of water solublecontaminants in the environment, POCIS samplers were deployed in the STEER at five locations. In addition to the February 2012 deployment, the results from an earlier POCIS deployment in May 2010 in Turpentine Gut, a perennial freshwater stream which drains to the STEER, are also reported.A total of 26 stormwater contaminants were detected at least once during the February 2012 deployment in the STEER. Detections were high enough to estimate ambient water concentrations for nine contaminants using USGS sampling rate values. From the May 2010 deployment in Turpentine Gut, 31 stormwater contaminants were detected, and ambient water concentrations could be estimated for 17 compounds.Ambient water concentrations were estimated for a numberof contaminants including the detergent/surfactant metabolite 4-tert-octylphenol, phthalate ester plasticizers DEHP and DEP, bromoform, personal care products including menthol, indole, n,n-diethyltoluamide (DEET), along with the animal/plant sterol cholesterol, and the plant sterol beta-sitosterol. Only DEHP appeared to have exceeded a water quality guideline for the protection of aquatic organisms.
    Keywords: Chemistry ; Environment ; Pollution
    Repository Name: AquaDocs
    Type: monograph
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    Format: application/pdf
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    NOAA/National Centers for Coastal Ocean Science | Silver Spring, MD
    In:  http://aquaticcommons.org/id/eprint/14679 | 403 | 2014-02-24 19:16:48 | 14679 | United States National Ocean Service
    Publication Date: 2021-07-01
    Description: This report contains a chemical and biological characterization of sediments from the St. Thomas East End Reserves (STEER) in St. Thomas, U.S. Virgin Islands (USVI). The STEER Management Plan (published in 2011) identified chemical contaminants and habitat loss as high or very high threats and called for a characterization of chemical contaminants as well as an assessment of their effects on natural resources. The baseline information contained in this report on chemical contaminants, toxicity and benthic infaunal community composition can be used to assess current conditions, as well as the efficacy of future restoration activities. In this phase of the project, 185 chemical contaminants, including a number of organic (e.g., hydrocarbons and pesticides) and inorganic (e.g., metals) compounds, were analyzed from 24 sites in the STEER. Sediments were also analyzed using a series of toxicity bioassays, including amphipod mortality, sea urchin fertilization impairment, and the cytochrome P450 Human Reporter Gene System (HRGS), along with a characterization of the benthic infaunal community. Higher levels of chemical contaminants were found in Mangrove Lagoon and Benner Bay in the western portion of the study area than in the eastern area. The concentrations of polychlorinated biphenyls (PCBs), DDT (dichlorodiphenyltrichloroethane), chlordane, zinc, copper, lead and mercury were above a NOAA sediment quality guideline at one or more sites, indicating impacts may be present in more sensitive species or life stages in the benthic environment. Copper at one site in Benner Bay, however, was above a NOAA guideline indicating that effects on benthic organisms were likely. The antifoulant boat hull ingredient tributyltin, or TBT, was found at the third highest concentration in the history of NOAA’s National Status and Trends (NS&T) Program, which monitors the Nation’s coastal and estuarine waters for chemical contaminants and bioeffects. Unfortunately, there do not appear to be any established sediment quality guidelines for TBT. Results of the bioassays indicated significant sediment toxicity in Mangrove Lagoon and Benner Bay using multiple tests. The benthic infaunal communities in Mangrove Lagoon and Benner Bay appeared severely diminished.
    Keywords: Chemistry ; Environment ; Pollution
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    Type: monograph
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    NOAA/National Centers for Coastal Ocean Science | Charleston, SC
    In:  http://aquaticcommons.org/id/eprint/14710 | 403 | 2014-02-22 22:53:38 | 14710 | United States National Ocean Service
    Publication Date: 2021-07-02
    Description: Porphyrin metabolic disruption from exposure to xenobiotic contaminants such as heavy metals, dioxins, and aromatic hydrocarbons can elicit overproduction of porphyrins. Measurement of porphyrin levels, when used in conjunction with other diagnostic assays, can help elucidate an organism’s physiological condition and provide evidence for exposure to certain toxicants. A sensitive microplate fluorometric assay has been optimized for detectingtotal porphyrin levels in detergent solubilized protein extracts from symbiotic, dinoflagellate containing cnidarian tissues. The denaturing buffer used in this modified assay contains a number of potentially interfering components (e.g., sodium dodecyl sulfate (SDS), dithiothreitol (DTT), protease inhibitors, and chlorophyll from the symbiotic zooxanthellae), which required examination and validation. Examination of buffer components were validated for use in this porphyrin assay; while the use of a specific spectrofluorometric filter (excitation 400 ± 15 nm; emission 600 ± 20 nm) minimized chlorophyll interference. The detection limit for this assay is 10 fmol of total porphyrin per μg of total soluble protein and linearity is maintained up to 5000 fmol. The ability to measure total porphyrins in a SDS protein extract now allows a single extract to be used in multiple assays. This is an advantage over classical methods, particularly when tissue samples are limiting, as is often the case with coral due to availability and collection permit restrictions.
    Description: NOAA Technical Memorandum CRCP 17
    Keywords: Biology ; Chemistry ; Fisheries
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    NOAA/National Centers for Coastal Ocean Science | Charleston, SC
    In:  http://aquaticcommons.org/id/eprint/14759 | 403 | 2014-02-26 21:18:00 | 14759 | United States National Ocean Service
    Publication Date: 2021-07-03
    Description: The mucus surface layer of corals plays a number of integral roles in their overall health and fitness. This mucopolysaccharide coating serves as vehicle to capture food, a protective barrier against physical invasions and trauma, and serves as a medium to host a community of microorganisms distinct from the surrounding seawater. In healthy corals the associated microbial communities are known to provide antibiotics that contribute to the coral’s innate immunity and function metabolic activities such as biogeochemical cycling.Culture-dependent (Ducklow and Mitchell, 1979; Ritchie, 2006) and culture-independent methods (Rohwer, et al., 2001; Rohwer et al., 2002; Sekar et al., 2006; Hansson et al., 2009; Kellogg et al., 2009) have shown that coral mucus-associated microbial communities can change with changes in the environment and health condition of the coral. These changes may suggest that changes in the microbial associates not only reflect health status but also may assist corals in acclimating to changing environmental conditions. With the increasing availability of molecular biology tools, culture-independent methods are being used more frequently for evaluating the health of the animal host. Although culture-independent methods are able to provide more in-depth insights into the constituents of the coral surface mucus layer’s microbial community, their reliability and reproducibility rely on the initial sample collection maintaining sample integrity. In general, a sample of mucus is collected from a coral colony, either by sterile syringe or swab method (Woodley, et al., 2008), and immediately placed in a cryovial. In the case of a syringe sample, the mucus is decanted into the cryovial and the sealed tube is immediately flash-frozen in a liquid nitrogen vapor shipper (a.k.a., dry shipper). Swabs with mucus are placed in a cryovial, and the end of the swab is broken off before sealing and placing the vial in the dry shipper. The samples are then sent to a laboratory for analysis. After the initial collection and preservation of the sample, the duration of the sample voyage to a recipient laboratory is often another critical part of the sampling process, as unanticipated delays may exceed the length of time a dry shipper can remain cold, or mishandling of the shipper can cause it to exhaust prematurely. In remote areas, service by international shipping companies may be non-existent, which requires the use of an alternative preservation medium. Other methods for preserving environmental samples for microbial DNA analysis include drying on various matrices (DNA cards, swabs), or placing samples in liquid preservatives (e.g., chloroform/phenol/isoamyl alcohol, TRIzol reagent, ethanol). These methodologies eliminate the need for cold storage, however, they add expense and permitting requirements for hazardous liquid components, and the retrieval of intact microbial DNA often can be inconsistent (Dawson, et al., 1998; Rissanen et al., 2010).A method to preserve coral mucus samples without cold storage or use of hazardous solvents, while maintaining microbial DNA integrity, would be an invaluable tool for coral biologists, especially those in remote areas. Saline-saturated dimethylsulfoxide-ethylenediaminetetraacetic acid (20% DMSO-0.25M EDTA, pH 8.0), or SSDE, is a solution that has been reported to be a means of storing tissue of marine invertebrates at ambient temperatures without significant loss of nucleic acid integrity (Dawson et al., 1998, Concepcion et al., 2007). While this methodology would be a facile and inexpensive way to transport coral tissue samples, it is unclear whether the coral microbiota DNA would be adversely affected by this storage medium either by degradation of the DNA, or a bias in the DNA recovered during the extraction process created by variations in extraction efficiencies among the various community members. Tests to determine the efficacy of SSDE as an ambient temperature storage medium for coral mucus samples are presented here.
    Keywords: Chemistry ; Fisheries
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    Type: monograph
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    In:  melissa_snover@nps.gov | http://aquaticcommons.org/id/eprint/14838 | 403 | 2014-02-28 23:00:28 | 14838 | United States National Marine Fisheries Service
    Publication Date: 2021-06-26
    Description: Understanding the phase and timing of ontogenetic habitat shifts underlies the study of a species’ life history and population dynamics. This information is especially critical to the conservation and management of threatened and endangered species, such as the loggerhead sea turtle Caretta caretta. The early life of loggerheads consists of a terrestrial egg and hatchling stage, a posthatchlingand juvenile oceanic, pelagic feeding stage, and a juvenile neritic, primarily benthic feeding stage. In the present study, novel approaches were applied to explore the timing of the loggerhead ontogenetic shift from pelagic to benthic habitats. The most recent years of somatic growth are recorded as annual marks in humerus cross sections. A consistent growth mark pattern in benthic juvenile loggerheads was identified, with narrow growth marks in the interior of the bone transitioning to wider growth marks at the exterior, indicative of a sharp increase in growth rates at the transitional growth mark. This increase in annual growth is hypothesized to correlate with the ontogenetic shift from pelagic to benthic habitats. Stable isotopes of carbon and nitrogen just interior and exteriorto the transitional growth mark, as well as stable isotopes from pelagic and benthic flora, fauna and loggerhead stomach contents, were analyzed to determine whether this transition related to a diet shift. The results clearly indicate that a dietary shift from oceanic/pelagic to neritic/benthic feeding corresponds to a transitional growth mark. The combination of stable isotope analysis with skeletochronology can elucidate the ecology of cryptic life history stages during loggerhead ontogeny.
    Keywords: Chemistry ; Fisheries
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  • 96
    Publication Date: 2021-06-26
    Description: A competitive enzyme-linked immunosorbent assay (cELISA) was developed by using a whole-cell antigen from a marine Brucella sp. isolated from a harbor seal (Phoca vitulina). The assay was designed to screen sera from multiple marine mammal species for the presence of antibodies against marine-origin Brucella. Based on comparisons with culture-confirmed cases, specificity and sensitivity for cetacean samples tested were 73% and 100%, respectively. For pinniped samples, specificity and sensitivity values were 77% and 67%, respectively. Hawaiian monk seal (Monachus schauinslandi; n = 28) and bottlenose dolphin (Tursiops truncatus; n = 48) serum samples were tested, and the results were compared with several other assays designed to detect Brucella abortus antibodies. The comparison testing revealed the marine-origin cELISA to be more sensitive than the B. abortus tests by the detection of additional positive serum samples. The newly developed cELISA is an effective serologic method for detection of the presence of antibodies against marine-origin Brucella sp. in marine mammals.
    Keywords: Chemistry ; Fisheries ; Management
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  • 97
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    In:  http://aquaticcommons.org/id/eprint/14858 | 403 | 2014-03-07 19:40:13 | 14858 | United States National Ocean Service
    Publication Date: 2021-06-26
    Description: Marine microalgae support world fisheries production and influence climate through various mechanisms. They are also responsible for harmful blooms that adversely impact coastal ecosystems and economies. Optimal growth and survival of many bloom-forming microalgae, including climatically important dinoflagellates and coccolithophores, requires the close association of specific bacterial species, but the reasons for these associations are unknown. Here, we report that several clades of Marinobacter ubiquitously found in close association with dinoflagellates and coccolithophores produce an unusual lower-affinity dicitrate siderophore, vibrioferrin (VF). Fe-VF chelates undergo photolysis at rates that are 10–20 times higher than siderophores produced by free-living marine bacteria, and unlike the latter, the VF photoproduct has no measurable affinity for iron. While both an algal-associated bacterium and a representative dinoflagellate partner, Scrippsiella trochoidea, used iron from Fe-VF chelates in the dark, in situ photolysis of the chelates in the presence of attenuated sunlight increased bacterial iron uptake by 70% and algal uptake by 〉20-fold. These results suggest that the bacteria promote algal assimilation of iron by facilitating photochemical redox cycling of this critical nutrient. Also, binary culture experiments and genomic evidence suggest that the algal cells release organic molecules that are used by the bacteria for growth. Such mutualistic sharing of iron and fixed carbon has important implications toward our understanding of the close beneficial interactions between marine bacteria and phytoplankton, and the effect of these interactions on algal blooms and climate.
    Keywords: Chemistry ; Oceanography
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    In:  tony.pait@noaa.gov | http://aquaticcommons.org/id/eprint/14860 | 403 | 2014-03-13 22:50:39 | 14860 | United States National Ocean Service
    Publication Date: 2021-06-27
    Description: Coral ( Porites astreoides ) from eight sites in southwest Puerto Rico were analyzed for approximately 150 chemical contaminants, to provide a preliminary characterization of environmental contamination in the corals, and assess the relationships between chemical contamination in corals and adjacent sediments. Overall, the concentration of PAHs (polycyclic aromatic hydrocarbons) and PCBs (polychlorinated biphenyls) detected in the limited number of coral samples collected were comparable to concentrations found in sediments. However, the concentration of a chemical contaminant (e.g., PAHs) in the corals at a site was often different from what was found in adjacent sediments. The level of PCBs and DDT (dichlorodiphenyltrichloroethane) in the corals appeared higher just outside of Guanica Bay, and there was some evidence of a downstream concentration gradient for these two contaminant classes. The trace elements copper and zinc were frequently detected in Porites astreoides , and the concentrations were usually comparable to those found in adjacent sediments. Chromium was an exception in that it was not detected in any of the coral samples analyzed, although it was detected in all of the sediment samples.
    Keywords: Chemistry ; Management ; Pollution
    Repository Name: AquaDocs
    Type: article , TRUE
    Format: application/pdf
    Format: application/pdf
    Format: 191-203
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    NOAA/National Centers for Coastal Ocean Science | Silver Spring, MD
    In:  http://aquaticcommons.org/id/eprint/14868 | 403 | 2014-03-06 18:57:33 | 14868 | United States National Ocean Service
    Publication Date: 2021-06-27
    Description: This report presents an initial characterization of chemical contamination in coral tissues (Porites astreoides) from southwest Puerto Rico. It is the second technical report from a project to characterize chemical contaminants and assess linkages between contamination and coral condition. The first report quantified chemical contaminants in sediments from southwest Puerto Rico. This document summarizes the analysis of nearly 150 chemical contaminants in coral tissues. Although only eight coral samples were collected, some observations can be made on the correlations between observed tissue and sediment contaminant concentrations. The concentrations of polycyclic aromatic hydrocarbons (PAHs), typically associated with petroleum spills and the combustion of fossil fuels, and polychlorinated biphenyls (PCBs) in the coral tissues were comparable to concentrations found in adjacent sediments. However, the concentration of a chemical contaminant (e.g., PAHs) in the coral tissues at a particular site was not a good predictor of what was in the adjacent sediments. In addition, the types of PAHs found in the coral tissues were somewhat different (higher ratios of alkylated PAHs) than in sediments. The levels of PCBs and DDT in coral tissues appeared higher just outside of Guanica Bay, and there was evidence of a downstream concentration gradient for these two contaminant classes. The trace elements copper, zinc and nickel were frequently detected in coral tissues, and the concentration in the corals was usually comparable to that found in adjacent sediments. Chromium was an exception in that it was not detected in any of the coral tissues analyzed. Additional work is needed to assess how spatial patterns in chemical contamination affect coral condition, abundance and distribution.
    Description: National Status and Trends Program for Marine Environmental Quality
    Keywords: Chemistry ; Management ; Pollution
    Repository Name: AquaDocs
    Type: monograph
    Format: application/pdf
    Format: application/pdf
    Format: 32
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    NOAA/National Centers for Coastal Ocean Science | Charleston, SC
    In:  http://aquaticcommons.org/id/eprint/14864 | 403 | 2014-03-06 18:36:18 | 14864 | United States National Ocean Service
    Publication Date: 2021-06-27
    Description: Models that help predict fecal coliform bacteria (FCB) levels in environmental waters can be important tools for resource managers. In this study, we used animal activity along with antibiotic resistance analysis (ARA), land cover, and other variables to build models that predict bacteria levels in coastal ponds that discharge into an estuary. Photographic wildlife monitoring was used to estimate terrestrial and aquatic wildlife activity prior to sampling. Increased duck activity was an important predictor of increased FCB in coastal ponds. Terrestrial animals like deer and raccoon, although abundant, were not significant in our model. Various land cover types, rainfall, tide, solar irradiation, air temperature, and season parameters, in combination with duck activity, were significant predictors of increased FCB. It appears that tidal ponds allow for settling of bacteria under most conditions. We propose that these models can be used to test different development styles and wildlife management techniques to reduce bacterial loading into downstream shellfish harvesting and contact recreation areas.
    Keywords: Chemistry ; Ecology ; Management ; Pollution
    Repository Name: AquaDocs
    Type: monograph
    Format: application/pdf
    Format: application/pdf
    Format: 32
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