ALBERT

Description: Efforts to date have not advanced Indigenous participation, capacity building and knowledge in Arctic environmental science in Canada because Arctic environmental science has yet to acknowledge, or truly practice decolonizing research. The expanding literature on decolonizing and Indigenous research provides guidance towards these alternative research approaches, but less has been written about how you do this in practice and the potential role for non-Indigenous research partners in supporting Inuit self-determination in research. This paper describes the decolonizing methodology of a non-Indigenous researcher partner and presents a co-developed approach, called the Sikumiut model, for Inuit and non-Indigenous researchers interested in supporting Inuit self-determination. In this model the roles of Inuit and non-Indigenous research partners were redefined, with Inuit governing the research and non-Indigenous research partners training and mentoring Inuit youth to conduct the research themselves. The Sikumiut model shows how having Inuit in decision-making positions ensured Inuit data ownership, accessibility, and control over how their Inuit Qaujimajatuqangit is documented, communicated, and respected for its own scientific merit. It examines the benefits and potential to build on the existing research capacity of Inuit youth and describes the guidance and lessons learned from a non-Indigenous researcher in supporting Inuit self-determination in research. Pinasuktaujut maannamut pivaallirtittisimangimmata nunaqarqaarsimajunik ilautitauninginnik, pijunnarsivallianirmik ammalu qaujimajaujunik ukiurtartumi avatilirinikkut kiklisiniarnikkut kanata pijjutigillugu ukiurtartumi avatilirinikkut kiklisiniarnikkut ilisarsisimangimmata, uvaluunniit piliringimmata issaktausimangittunik silataanit qaujisarnirmut. Uqalimaagait issaktausimangittunit silataanit ammalu nunaqarqaarsimajut qaujisarningit piviqartittikmata tukimuagutaujunnarlutik asiagut qaujisarnikkut, kisiani titirartauqattanginnirsaukmat qanuq pilirigajarmangaata ammalu ilautitauningit nunaqarqaarsimangittut qaujisarnirmut ikajurtuilutik Inuit nangminiq qaujisaqattarnirmut. Taanna titirarsimajuq uqausiqartuq issaktausimangillutik iliqusiujumik nunaqarqaarsimangittut qaujisartiujut ammalu saqittillutik ikajurtigiiklutik pigiartittinirmik, taijaujuq sikumiut aturtanga, inungnut ammalu nunaqarqaarsimangittunut qaujisartinut pijumajunut ikajurtuilutik Inuit nangminiq qaujisarnirmut. Tavani aturtaujumi piliriaksangit Inuit ammalu nunaqarqaarsimangittut qaujisartiujut tukisinarsititaullutik, Inuit aulattillutik qaujisarnirmik ammalu nunaqarqaarsimangittut qausartit ilinniartittillutik ammalu pilimmaksaillutik makkuktunik inungnik nangminiq qaujisarunnarniarmata. Sikumiunut aturtaujuq takuksaujuq qanuq Inuit aaqiksuijiullutik Inuit pisimajiuniarlutik tinngirartaujunik, takujaujunnarningit ammalu aulatauningit qanuq inuit qaujimajatuqangit titirartaukmangaata, tusaumajjutaukmangaata ammaluikpigijaulutik kiklisiniarnikkut atuutiqarninginnik. Takunangniujuq pivaalliutaujunnartunik ammalu pirurpalliagajartunik maanna qaujisarniujumik pijunnarsiqullugit makkuktut Inuit ammalu uqausiulluni tukimuagutaujunnartut ammalu ilitausimajut nunaqarqaarsimangittunit qausartinit ikajurtuilutik inuit nangminiq qaujisarnirmut.

Description: A total of 344 soil cores were taken in annually cropped fields of Alberta, Saskatchewan, Manitoba, and Ontario from 2011 to 2013 in areas where the field shapes, or obstacles within fields, required the driving pattern of farm operations to overlap. Soil nitrate-N concentrations in overlapping areas were 60% greater, soil Olsen-P concentrations were 23% greater, and pH was 0.5 units greater at 0–15 cm depth compared with non-overlapping areas, suggesting smaller nutrient use efficiency and potential for greater nutrient loss.

Description: Differences in soil water retention (SWR) characteristics between soil types and the factors driving those differences provide important information for land management, particularly in regions such as the Colombian Andes, which have limited water-storage infrastructure and where soils provide plant-available water and other ecosystem services. The objective of this study was to explore relationships between SWR and physical, chemical, and mineralogical properties of Andisols and Inceptisols through a case study of two watersheds in the Colombian Andes. This study identified a complex relationship between total carbon (TC), short-range order (SRO) minerals, and SWR. Both soil types had high SWR, with volumetric water content at permanent wilting point between 39% and 53%. Principal component analysis showed association of SWR with TC, SRO minerals, and % clay in both soil types. The Andisols of this study were coarse textured, allophanic (rich in allophane and imogolite — up to 17% in the B horizon), and with up to 15% TC in the A horizon. In contrast, the Inceptisols were fine textured (〉30% clay) and higher in ferrihydrite than the Andisols. The formation of organo-metallic complexes was observed in A horizons; however, TC was lower under pasture than forest in both soil types. The addition of organic matter to soils with SRO minerals, such as the soils of this study, may foster the formation of organo-metallic complexes, stabilize soil C, and enhance SWR. Consequently, both study sites may benefit from management practices that increase soil organic matter.

Description: The paper describes the architecture for a data repository and distribution system to be used in the case of a SETI detection event. This system is conceptually modelled after the Deep Space Network, although the hardware and infrastructure involved are different and substantially less expensive to operate. The system is designed to accommodate a large number of users from a variety of fields who wish to contribute to the analysis and comprehension effort that would follow the detection of an information-bearing signal.

Description: Under the potential to reconstruct the past climatic and atmospheric conditions from a deep ice core in the coastal Antarctic site (Styx Glacier), an 8.84 m long firn core (73°50.975′ S, 163°41.640′ E; 1623 m a.s.l.) was initially studied to propose a reliable age scale for the local estimation of snow accumulation rate. The seasonal variations of δ18O, methanesulfonic acid (MSA) and non-sea-salt sulfate (nssSO42–) were used for the firn core dating and revealed 25 annual peaks (from 1990 to 2014) with volcanic sulfate signal. The observed declining trend in annual accumulation rate with a mean value of 146 ± 60 kg m–2 a–1 is likely to be linked to the changes of sea-ice extent in the Ross Sea region. Moreover, the temporal variation of the annual mean δ18O, an annual flux of MSA and nssSO42– also likely to be under the influence of ice-covered and open water area. This study suggests a potential to recover past changes in an oceanic environment and will be useful for the interpretation of the long ice core drilled at the same site.

Description: Clouds play an important role in the Arctic surface radiative budget, impacting the seasonal evolution of Arctic sea-ice cover. We explore the large-scale impacts of springtime and early summer (March through July) cloud and radiative fluxes on sea ice by comparing these fluxes to seasonal ice volume losses over the central Arctic basin, calculated for available observational years 2004–2007 (ICESat) and 2011–2017 (CryoSat-2). We also supplement observation data with sea-ice volume computed from the Pan-Arctic Ice–Ocean Modeling and Assimilation System (PIOMAS) during summer months. We find that the volume of sea ice lost over the melt season is most closely related to observed downwelling longwave radiation in March and early summer (June and July) longwave cloud radiative forcing, which together explain a large fraction of interannual variability in seasonal sea-ice volume loss (R2 = 0.71, p = 0.007). We show that downwelling longwave fluxes likely impact the timing of melt onset near the sea-ice edge, and can limit the magnitude of ice thickening from March to April. Radiative fluxes in June and July are likely critical to seasonal volume loss because modeled data show the greatest ice volume reductions occur during these months.

Description: In severely deficit soil, lentil (Lens culinaris Medic) crop requires micronutrients for increased production. Micronutrient management is, therefore, very important for lentil productivity but mostly ignored. This study was carried out from 2014–2015 to 2016–2017 to understand the effects of zinc (Zn), boron (B), and molybdenum (Mo) on lentil productivity, nodulation, and nutrient uptake and how these elements improve soil micronutrient fertility. The experiment was laid out in randomized complete block design, and the treatments were replicated thrice. Different combinations of Zn, Mo, and B were contrasted with no application of micronutrients. The treatments were Zn alone (Zn), B alone (B), Mo alone (Mo), Zn combined with B (ZnB), Zn with Mo (ZnMo), B with Mo (BMo), and Zn combined with B and Mo (ZnBMo). Doses of Zn, B, and Mo were 3, 2, and 1 kg ha−1, respectively. In this trial, the highest average seed yield (1807 kg ha−1) and yield increment (44%) was obtained in ZnBMo combined application with macronutrients. Single, dual, and combined application of Zn, B, and Mo had significant effects on yield parameters and yield of lentil (P 

Description: There is a need to provide quantitative relationships that will allow agronomists to estimate accurately the nitrogen-supplying power of soils while taking into account both temperature and soil moisture variations. The procedure for estimating net nitrogen mineralization proposed by Stanford and co-workers was used to determine Arrhenius relationships between the rate constants (k) and absolute temperature (°K) for 33 virgin and cultivated Western Canadian prairie surface (0–15 cm) soils. There was no significant difference in Arrhenius relationship between soils within each soil zone; thus, a single average Arrhenius equation was calculated per soil zone. Average Q10 for the Brown chernozemic soils was 2.75, for the Dark Brown, thin Black and thick Black chernozems, 2.18, and for the Gray luvisols, 2.0. These Q10 values are as high or higher than those reported in other parts of the world and may be related to the degree of degradation of the soil organic matter in these various soils. Culture had no marked effect on Q10 but sandy soils had higher Q10 than loams and clays. An equation for estimating net nitrogen mineralization for the Wood Mountain loam (a Brown chernozem) was tested using data from a previous study. The results were quite satisfactory, especially when the test data were derived under laboratory conditions where moisture was well controlled. The temperature functions presented herein can be used together with moisture functions and potentially mineralizable nitrogen results published earlier to make first estimates of net nitrogen mineralized during the growing season in the soils tested. Key words: Q10, Arrhenius relationship, potentially mineralizable nitrogen

Description: The use of commercially available porous cup soil water samplers for soil solution extraction was evaluated. Ortho-P, (NO3 + NO2)-N and potassium (K) were adsorbed by the porous cup during extraction of soil water samples, but the retention of (NO3 + NO2)-N was minimal. The screening of NO3− by the cup was not obvious. The retention of ortho-P and K was a function of solution concentration and the time of contact between soil solution and the cup. A rest period between extractions, during which samplers remained in contact with solution at zero tension, appeared to enhance phosphorus sorption capacity of the ceramic cup. Furthermore, phosphorus sorption was reversible in nature. The porous cup subjected to high solution concentration initially, released phosphorus when flushed with soilsolution of low concentration. It is recommended that several consecutive soil water extractions be carried out at high (0.6 bar) tension, using high flow rate porous cups. The sample collected in the last extraction should be used to determine true soil water quality.

Description: The distribution of lipid S (sulpholipids) in 27 soils was examined in relation to factors which influence its abundance in different soil environments. Lipid S was found in all soils examined, but at levels varying from 1.6 to 291 ppm S. Lipid S content was higher in organic horizons than in mineral horizons, and poorly drained soils had higher lipid S than freely drained soils. Highest levels were observed in poorly drained organic soils. Lipid S accounted for a small proportion of total S (0.5–3.5%) and of total lipid (0.03–1.7%). Lipid S levels were on average three times higher than lipid P. Lipid S was significantly correlated with total S, HI-reducible S and organic C. In a regression analysis, 89% of the variation in soil content of lipid S was accounted for by total lipid and total S contents. The distribution of total lipids confirmed previous reports that higher levels were associated with soils having restricted biological activity.

Description: Content of mercury in organic soil horizons was monitored to ascertain seasonal changes in background levels. L, F, and H horizons were relatively enriched in mercury in early spring. Levels then diminished and reached seasonal low values in August. Content of mercury then increased twofold during September after which levels declined to summer values. F horizons had the highest content of mercury and H horizons had the lowest. Key words: Mercury cycling, mercury dynamics, heavy metal

Description: The sulfur status of rapeseed (Brassica napus and Brassica campestris) plants grown in field studies was assessed using a variety of plant indices; percent sulfur, percent hydriodic acid reducible sulfur (HI-S in plant dry matter), HI-S:total S ratio, and total N:total S ratios. Of these, HI-S:total S determined at the rosette growth stage was the most accurate and consistent index of seed yield. A growth chamber study indicated that the HI-S:total S ratio would not be affected by nitrogen fertilizer application at normal field rates. Key words: Sulfur, deficiency, rapeseed (Brassica spp.), plant analysis

Description: The objective of this study was to compare the effects of various pretreatments on the X-ray identification and quantification of clay-sized minerals from some podzolic B horizons. After soil samples were treated with H2O2 to remove organic matter, clay fractions were dispersed, separated, and freeze-dried. A portion of each clay sample was subjected to the following pretreatments: ultrasonic bath, extraction by citrate-dithionite, extraction by 0.5 N NaOH, and extraction by Tiron. Oriented slides were used for identification and quantification of clay minerals after each pretreatment. The X-ray patterns for ultrasonically dispersed samples were used as a basis for evaluating the effectiveness of the three chemical pretreatments. Tiron pretreatment was found to be the most suitable method for removal of amorphous material from clay separates of podzolic B horizons. The traditional citrate-dithionite method was not effective in removing amorphous Si from clays. The 0.5 N NaOH method is not recommended because it resulted in significant destruction of phyllosilicates and it was not effective in removing amorphous Fe.

Description: A study designed to assess gaseous losses of N as N2O and N2 from soils of conventional till fields seeded to wheat in the Chernozemic soil region of Saskatchewan, together with limited supporting laboratory investigations, has confirmed that for the May-November period losses were in the vicinity of 3 kg N∙ha−1 or less. In contrast, total losses from a summer-fallowed field were approximately 300% higher. Comparisons at one site were made of N losses from a conventionally tilled and zero-tilled Dark Brown Chernozemic soil seeded to wheat; the total losses of N were twice as high for the zero till as the conventional till treatments. The N2O fluxes were shown to be the result of both reductive (denitrification) and oxidative (nitrification) processes and generally, under the conditions of these field experiments, both occurred simultaneously. This experiment also confirmed that C2H2 inhibited nitrification in a manner very similar to N-serve, a well-known nitrification inhibitor.

Description: The effects of surface mining for coal on soil respiration (CO2), microbial biomass C, ATP levels, bacterial and actinomycete numbers, bacterial taxa, hyphal lengths, fungal taxa, N2 fixation and decomposition potential were determined for a short-grass prairie site in southern Alberta, Canada. Soil respiration, microbial biomass C, ATP, actinomycete numbers, hyphal lengths and N2-fixing potential were significantly lower in the mined soil particularly when compared to the undisturbed topsoil. Bacterial numbers were, however, greater in the mined soil than in the unmined soil. The bacteria isolated from the undisturbed soil were dominated by Bacillus spp., coryneforms and non-pigmented Gram-negative rods, while those from the disturbed soil belonged mainly to the coryneform group. Mining also caused the fungal community to shift from one dominated by Chrysosporium-Pseudogymnoascus and sterile dark organisms to one dominated by Alternaria spp., Cladosporium spp., sterile dark forms and yeasts. Decomposition of filter paper, 24 mo after their placement in the field, was significantly faster on the disturbed site than on the undisturbed site. Key words: Surface mining, microbiology, prairie soil

Description: Interest in composting as a means of handling the large volumes of manure generated by southern Alberta beef cattle feedlots has increased in recent years. We measured concentrations of 19 elements (C, N, P, Na, Ca, Mg, K, S, Al, Fe, Mn, Zn, Cu, Cr, Ni, P b , Co, Mo and Cd) in fresh manure, interim-composted manure and finished compost, at four commercial feedlots. Thirteen elements showed increased concentrations (by 26–73%) with composting, while four (C, Cr, Ni and Mo) showed concentration declines. Of the remaining two, the trend in N concentration was feedlot dependent, while Pb was largely unaffected. Total mass loss during composting averaged 54%, which represents a substantial decrease in haulage requirements. Overall average C losses were 61% and N losses 33%. On an equivalent wet weight basis ("as-is"), composting allowed haulage of 56% more N, 84% more P, 91% more Zn, and 76% more Cu than fresh manure, which is advantageous in terms of moving nutrients and trace elements from high to low-loading areas. Our study quantifies nutrient and trace element behaviour during composting, provides comparative data with fresh manure, and helps tailor end-use decisions (e.g., haulage distance, application rate) on the compost product. Key words: Manure, compost, beef cattle feedlots, nutrients, trace elements

Description: Estimation of fertilizer N requirements of crops remains a challenge. Numerous field studies have been carried out to calibrate soil tests against yield response to applied fertilizer N. Synthesis and identification of common crop fertilizer N response across large data sets (years, sites) will allow maximum use of this past work and a framework for comparison of future work. The objective of this paper is to define macro-relationships between the economically optimum fertilizer N rate (EONR) and the yield increase at the EONR defined as the delta yield, ΔYec , for large data sets of 2nd- and 3rd-order estimates of fertilizer N response functions with both 0th and 1st-order rate relationships between fertilizer nitrogen use efficiency and applied fertilizer N. The derived macro-relationships are curvilinear, depend on the price ratio R = the ratio of the (price per kilogram of fertilizer N)/(price per kilogram grain), and are similar to measurements from data sets of corn fertilizer N response functions spanning decades (+20 yr) and representing areas in both the United States and Canada. The macro-relationships appear to be robust and therefore useful for quantifying (post-harvest analysis) soil fertility, crop fertilizer N requirement, and comparison/classification of N response functions.Key words: Response function, prediction, efficiency, economic N rate, corn

Description: The morphological expression of podzolization in four Humo-Ferric Podzols increased in a northerly direction over a distance of approximately 74 km from the north shore of Lake Huron. The transect coincided with changes in both geology and vegetation. All the soils were developed in coarse-textured acid tills whose composition was not significantly different to explain the observed variations in soil morphology. Using quartz as an internal standard, the order of mobility from surface horizons was found to be Mg 〉 Fe = Ca 〉 Na = Al 〉 K 〉 Ti. Pyroxenes, amphiboles, chlorite and albite were the most easily weathered minerals. Protocatechuic, p-coumaric, gentisic and gallic acids were found to be the major phenolic acids in water extracts of soil surface horizons. The content of both phenolic acids and carbohydrates in surface horizons increased as the morphological expression of podzolization increased.

Description: Two separate field experiments were conducted on several crops to determine the effect of selenium (Se) applied to soils with pH levels between 5.7 and 6.6. Tissue Se levels after a single application of Se and lime, were monitored for up to six cropping years or until the tissue Se fell below 0.1 ppm, the level considered to be necessary for animal nutrition. For applications of 1.12 and 2.24 kg Se/ha, the minimal tissue Se concentration (〉 0.1 ppm) was maintained in barley (Hordeum vulgare L.) for two cropping years, but with a very sharp decrease for the first 3 yr. In the case of timothy (Phleum pratense L.), tissue levels greater than 0.1 ppm were maintained for 3 yr at the higher rate of Se without lime and up to 5 yr at high soil pH levels. At the applied rates of 0.28 and 0.56 kg Se/ha, the tissue Se levels above 0.1 ppm in timothy, red clover (Trifolium pratense L.), and alfalfa (Medicago sativa L.) were maintained for one and two cropping years, respectively. In spite of the sharp decrease in plant tissue Se levels, little decrease in total soil Se was noted at rates of 1.12 and 2.24 kg Se/ha after successive croppings of barley and timothy. Although not always significant, liming, in general, increased the plant Se concentration. The Se concentration (log ppm) for tissues (or depletion of Se availability) in the Se-applied plots decreased linearly for at least the first three cropping seasons.

Description: A single batch application of phosphorus once in several years might be a more economical practice for wheat production in Western Canada than the traditional annual application at seeding time. Annual phosphorus applications and batch applications once every 8 yr were compared. Response functions were estimated for annual applications for two locations in Saskatchewan and two in Manitoba. The response functions were used to determine the optimum application rates at each location. These optimums were compared with the profitability of the batch application to determine the economic optimum phosphorus application strategy. Three wheat/fertilizer price ratios were used in the analysis to examine the effect of changes in relative prices. The 100-kg batch application was economically preferred to annual applications for all three price ratios at three of the four locations. Only at Swift Current, Saskatchewan was the batch application not economically justified. The 100-kg batch application was economically superior to the 200-kg application at all locations studied.

Description: The effect of labile inorganic phosphate (Pi) status of the soil on the decomposition of added cellulose and on the immobilization, mineralization, and redistribution of native and added P in soils was studied in a greenhouse incubation experiment. Cellulose was added at 765 μg C∙g−1 soil with and without P (9 μg∙g−1 soil) every 30 days under adequate N, H2O, and constant tempreature to two soils of different available P status. Lack of P eventually slowed down decomposition of added C, but this effect was partially compensated for by increased mineralization of organic P (Po) forms. Added P was redistributed to both P, (58–69%) and Po (42–31%) forms; higher amounts of Po were found in the soil with the highest Pi status. The correlation between microbial P uptake and solution P values was significant, and microbial C:P ratios ranged from 12:1 under high available P conditions to 45:1 where P was in low supply.

Description: A field study was conducted to measure the effect of soil salinity on barley grown under irrigated conditions in Alberta. Salinity was measured by the saturated paste extract, 1:2 soil-to-water extract, vertical probe and horizontal surface array methods. Correlation coefficients were determined between salinity measurements and the yield of barley to establish the suitability of these methods for predicting the growth of barley. Nineteen fields over 2 yr were monitored and soil salinity and the yield of barley were determined at a number of sites in each field. All methods of measuring salinity were significantly correlated (P = 0.01) with the yield of barley. At an EC of 7.8, yields of barley were reduced by 50%. Sodium concentration and sodium adsorption ratio were closely correlated with yield of barley and with saturated-paste-extract salinity. Soil moisture and pH were not as effective as salinity and sodium measurements in predicting the yield of barley. The saturated-paste-extract salinity was more closely correlated with the 1:2 soil-to-water extract than with the vertical probe or the horizontal surface array. The latter three methods were effective for rapid determination of the yield reductions which would occur on saline soils. No difference in tolerance to salinity was found between Klages (two-row) and Galt (six-row) cultivars of barley. Key words: Salinity tolerance of barley, methods of measuring salinity, vertical probe EC, horizontal array EC, saturated paste EC, 1:2 soil-to-water extract EC

Description: An earlier study indicated that cereal straw may be removed after harvest without affecting crop production, soil organic matter and microbial biomass. Further measurements of early indicators of changes in soil organic matter, viz., the light fraction and mineralizable C and N, confirm that straw removal is superior to straw incorporation with moldboard ploughing, and comparable to straw incorporation by disking, in C and N retention and turnover. Key words: Carbon, light fraction, mineralization, nitrogen, straw management

Description: A theory is presented for the distribution of load pressures over the different phases in an unsaturated soil. It provides differential and integral relations between the equilibrium liquid pressure, the equilibrium solid pressure and the load pressure. Mechanical and thermodynamic models are presented by which the effective stress in unsaturated soils is defined. The value of the effective stress is then calculated for a certain state of a clay soil.

Description: Soils cultivated for 60 yr were compared with uncultivated forested soils at 10 sites in Appalachian Quebec. All soils belonged to the Humo-Ferric Podzol Great Group, five sets of comparisons being located on the Ascot soil series and five on the Greensboro. Comparisons were made between corresponding soil horizons, analytical data being derived from the bulking and analysis of six sample cores per horizon. Cultivation increased weight of soil in the solum and in the whole profile of both the Greensboro and the two soil series combined; bulk density was slightly affected. Field capacity, permanent wilting point and available water of the surface and sub-surface layers, in the solum and in the whole profile, were significantly increased by cultivation. The increase of available water was accompanied by a corresponding decrease in gravitational water. The content fine clay was significantly decreased in the surface layer and in the solum, while it was increased significantly in the C horizon by cultivation which also decreased the acidity of the surface and sub-surface in both series. There was a marked increase in organic matter content, but the level of fulvic acid was relatively unaffected by cultivation, indicating that the increased H/F ratio was primarily due to an increase in humic acid. Generally, Al content was not significantly changed, while significant increases in Fe and Mn were observed in the surface and solum of cultivated profiles. A deduction is made that cultivation has regraded podzol profiles into Dystric Brunisol ones which have started to evolve already toward kinds of Luvisolic profiles.

Description: Using previous years’ yield patterns may be one method of breaking a field into management zones for the purpose of site-specific management. For this method to be useful there must be temporal stability of yield patterns and there must be a sound method of assessing the spatial-temporal stability of yield in a field. To this end, a method was developed to give a non-biased estimate of the within-field spatial-temporal stability of yield. The method determined the probability that the normalized yield for all years available at a given location in the field fit within the accuracy limits of the combine. Combine accuracies of ± 2.5%, 5% and 10% of the field mean yield and gridded data of 3 m, 6 m, and 9 m cell sizes, as well as crop choice were all included in the model to assess its sensitivity to changes in these factors. The resulting spatial-temporal stability maps were well correlated with visual estimations of the spatial yield patterns. The model results were highly influenced by the inputted combine accuracy, but grid size and crop choice had little affect on the proportion of the field or the spatial pattern of temporal stability in the two field sites examined. The sensitivity of the model to changes in the input value for the combine accuracy indicated that a good estimate of this value is required for the determination of the stable patterns in a field. Key words: Spatial-temporal stability, yield

Description: Increasing use of animal manures in Saskatchewan requires information on the effect of manure addition on the availability of soil K, Ca and Mg and their concentrations in plant tissue. To address these issues, we examined the effects of repeated application of liquid swine and solid cattle manure at low and high rates on extractable K, Ca and Mg in soils from three different long-term field trials in Saskatchewan, and on plant K, Ca and Mg concentrations in cereal straw grown on the soils. After 5 to 7 yr of manure application, extractable potassium in the soils was significantly increased, while extractable Ca and Mg tended to remain similar, or was decreased with swine manure addition. In the cereal straw, concentrations of K, Ca, and Mg were all increased by repeated swine manure application, such that there was no significant increase in the K/(Ca + Mg) ratio. However, the K/(Ca + Mg) ratio in the cereal straw grown on soil amended with the high rate of cattle manure was increased. These findings suggest that increased risk of tetany potential from manure application would mainly be associated with excessive application rates of cattle manure in these soils, but should be monitored in feeds grown on all manured soils.Key words:Soil extractable K, Ca, Mg and Na; cereal K, Ca and Mg concentrations, K/(Ca + Mg) ratio, tetany potential, urea, swine manure, cattle manure

Description: There is a need to develop verifiable algorithms that can be easily applied to estimate carbon sequestration in soils. A simple process-based empirical model, driven primarily by soil texture and crop residue input, was developed to account for changes in soil organic carbon (SOC) in Chernozemic soils on the Canadian prairies. The model was used to estimate SOC change under no-till and continuous cropping compared with conventional tillage and rotations with fallow. Using this model, C sequestration due to continuous cropping compared with fallow-containing rotations was determined to be 0.09 Mg C ha-1yr-1 for the Brown and Dark Brown, and 0.05 Mg C ha-1 yr-1 for the Black and Dark Gray/Gray soil zones. The rate of C sequestration as a result of continuous cropping was positively related to the frequency of fallow, which decreases on the prairies from the Brown, Dark Brown, and Black to the Dark Gray/Gray soil zones. Using this model average C sequestration when conventional tillage was converted to no-till, was 0.13, 0.23, 0.34, and 0.25 Mg C ha-1 yr-1 for the same soil zones, respectively. Combined gains due to no-till and continuous cropping in comparison with conventional tillage and fallow-containing rotations were determined to be 0.22, 0.32, 0.39, and 0.30 Mg C ha-1 yr-1 for the Brown, Dark Brown, Black and Dark Gray/Gray soil zones, respectively. Based on Agricultural Census of Canada data in 1996 and 2001, the amount of “C sequestered” due to the adoption of no-till was estimated to be 1.23 million Mg of C in 1996 and 1.72 million Mg of C in 2001, which is approximately 10% of the total greenhouse gas emissions from the agricultural sector in Canada. This simple process-based empirical model could serve as a useful tool for soil scientists to use in assessing soil sustainability and C sequestration in the Canadian prairies. It would also assist policy makers in understanding how various scenarios of improved management will influence future greenhouse gas emissions on agricultural soils. Key words: Soil organic carbon, no-till, fallow, crop rotation

Description: Selected surface horizons of grassland and forest soils formed under a cold, semi-arid climate were investigated to evaluate the formation of secondary minerals within the White River tephra, a Late Holocene rhyolitic tephra (~115014C yr BP) veneer that overlies the soil landscapes of central Yukon. Concentrations of extractable Fe (〈 0.48%), Al (〈 0.26%) and Si (〈 0.082%) concentrations in surface tephra-contaning horizons of grassland and forest pedons are low. The high amount of exchangeable calcium in grassland soils is likely due to cycling by vegetation and perhaps, aeolian inputs of Ca and Mg carbonates. Al is incorporated into Al-humus complexes in forest pedons and allophane in grassland pedons. Allophane content is low (〈 0.56%) in all soils as is ferrihydrite (〈 0.34%). Mineral composition of the sand fraction from tephra horizons is dominated by volcanic glass, plagioclase feldspars, amphiboles, epidote, pyroxenes and very limited quantities of quartz and primary Fe oxides. Chlorite and an expanding phyllosilicate were also detected and are assumed to be of detrital origin. Clay mineralogy is dominated by volcanic glass, quartz, feldspars and minimal quantities of kaolinite and dehydrated halloysite in surficial horizons. Kaolinite is assumed to be of detrital origin while dehydrated halloysite is a product of a low leaching and dry environment where limited resilication occurs. Scanning electronmicroscopy (SEM) investigation indicates the presence of opaline silica in surface horizons from forest pedons which has likely formed due to freezing of the soil solution in combination with dehydration and resilication. Overall, the soil horizons formed within the veneer of White River tephra have experienced minimal weathering and very little silicate clay mineral development. Key words: Tephra, glass, Yukon, minerals (secondary), weathering

Description: The potential for sustainable agricultural practices to sequester C is substantial. The economic feasibility and competitiveness of soil C sequestration depends on the opportunity cost per tonne of C stored. The key issue is whether the cost is competitive with alternative methods of reducing greenhouse gas emissions. The high spatial variability in land productivity means that the soil characteristics are important when designing public policies to address this issue. Empirical evidence suggests that the opportunity cost per tonne of C stored can be as low as US$10 to US$25 t-1 (Can$12–30), but that for the majority of temperate agriculture it exceeds US$50 t-1 (Can$60). The final monetary value placed on a tonne reduction of C will emerge either from the establishment of a fully functioning market or from government payment schemes. Estimates of the value of stored C have ranged from US$100 t-1 (Can$120) to a low of less than US$5 t-1 (Can$6). Current evidence suggests a likely price in the lower region of this range. Key words: Carbon farming, carbon sequestration, soil organic carbon, soil sustainability

Description: It is becoming common for soil surveys to be made of the same area at different intensities and published at different scales. The principles of cartographic generalization are discussed that control the relationships between the map units and delineations on maps made from such surveys. A study of two sets of maps showed that almost no lines were coincident. Up to 20% of the small scale delinations could be ’inliers’ of different soils and about 15% of the large scale delineations would be outside their small scale equivalents. The same discrepancies are to be expected between large scale soil maps and the smaller scale maps of physiography or vegetation that are often used to stratify soils. Reasons for these discrepancies are discussed under the headings of simplification and classification. Recommendations arc made to guide the preparation of maps and legends for different intensities and scales of survey in the same area. These recommendations have practical implications for the planning of surveys and the designs of computer-based autocartography systems.

Description: Supplementing irrigation water with effluents could reduce the need for potable water for irrigation and promote nutrient recycling, but may require additional amendments to deal with Na. In a growth chamber experiment, winter wheat was seeded into a control soil and to soil amended with either gypsum or wood ash applied at an equivalent rate of 15 dry t ha-1. Wheat was irrigated at a rate of 6 mm d-1 with distilled water (DW), kraft pulp mill effluent (KPME) and waste-activated sludge (WAS), and three KPME/WAS combinations. This included two KPME/WAS combinations diluted with DW to 25 and 50% (KPME/WAS:DW) to evaluate the effect on the nutrient uptake and biomass and the impact on soluble ions in the soil. Effluent applications increased wheat biomass up to 70%, and increases of 97 and 140% were observed in soils amended with gypsum and ash, respectively. Effluent applications increased soluble Na, Ca, and SO4, but only on the gypsum-amended soils, except those irrigated with WAS, had lower sodium adsorption ratio (SAR) than control soils by 0.7 to 3 units. Effluent combinations at the lower dilutions in combination with gypsum could be used to provide supplemental water with moderate increases in electrical conductivity (ECe) and SAR that would still be within tolerable limits of many crops.Key words: Effluent irrigation, electrical conductivity, gypsum, sodium adsorption ratio, wood ash

Description: The variability of forest floor properties over short distances and the number of samples required to achieve desired levels of precision for estimation of property means have received little attention. The importance of the forest floor for forest management is well known and increasingly forest floor characteristics are being used to classify forest sites. Highly variable forest floor properties require more intensive sampling and often have less predictive value for characterization and classification purposes. A study site at Port Hardy was used to characterize forest floors for selected physical and chemical properties. The three sites chosen represented xeric, mesic and hygric positions along a hygrotopic gradient. A stratified random sampling procedure was used to obtain 15 samples at each site. Fifteen samples were adequate to characterize the means at 10% allowable error with a 95% confidence level for total nitrogen, organic carbon, pH and cation exchange capacity. Greater than 15 samples were required for exchangeable bases and forest floor thickness for the same level of accuracy and confidence. Even at 25% allowable error and 90% confidence, 40 samples and 16 samples, respectively, were required for exchangeable Ca and Mg.

Description: Most soil C sequestration research has focused on organic C stabilization, while carbonate precipitation has received little attention. Mineral colloids can accelerate abiotic humification reactions of biomolecules such as amino acids, sugars, and polyphenols, derived from the breakdown of biological residues and metabolites. During these reactions CO2 is produced as a result of the oxidation of biomolecules. However, the biomolecule-induced formation of carbonate during abiotic humification remained to be uncovered. Here we demonstrate using X-ray diffraction, Fourier transform infrared spectroscopy and C K-edge and Mn L-edge near edge X-ray absorption fine structure spectroscopy that the Maillard reaction (glucose and glycine) and the integrated polyphenol-Maillard reaction pathway (catechol, glucose and glycine), in the presence of birnessite (δ-MnO2) produce MnCO3 (rhodochrosite). Increasing the molar ratio of catechol to glucose and glycine dramatically hampered carbonate formation, which is attributed to the enhanced formation of humic polymers, which increased proton generation and perturbed rhodochrosite crystallization through Mn(II)-humic complexation in the reaction systems. Thus, rhodochrosite formation was a competing reaction with humic substance formation. Our findings are of fundamental significance in understanding the vital role of the nature and relative abundance of biomolecules in abiotic carbonate formation, which merits close attention in understanding and regulating C sequestration in natural environments.Key words: Abiotic humification, polyphenol-Maillard reaction, rhodochrosite, birnessite, C K-edge and Mn L-edge NEXAFS

Description: Leaching of water-soluble contaminants has resulted in degradation of groundwater quality. This research project examined the long-term spatial variability of leaching processes within two hummocky, agricultural landscapes near Bittern Lake, in central Alberta. Analysing the distribution of soil profiles within a landscape, we created a leaching potential index based on a soil profile index (SPI) and plan curvature measurements. The index accurately differentiated locations of very high and high leaching potential from low and very low leaching potential. This index may become a useful tool to determine the variability of leaching within an agricultural landscape, to identify areas of high leaching potential, to determine agricultural best management practices, and to minimize contamination of groundwater. Key words: Soil-landscape, soil horizon, soil classification, sulphate, electrical conductivity, leaching

Description: Land application of swine manure can result in a loss of nitrogen (N) through ammonia (NH3) volatilization. Accurate NH3 loss assessments are essential to support the development of regional and global emission factors and identify best management strategies for reducing losses. The objectives of this study were to simultaneously assess the reliability and applicability of three simple NH3 flux measurement techniques and their effectiveness and usefulness for the measurement of emissions from surface-applied swine manure. Ammonia losses from two chamber systems were compared: (i) static and (ii) wind tunnel chamber, as well as the (iii) micrometeorological theoretical profile shape (TPS) method. A series of field tests was performed at the Agriculture and Agri-Food Canada (AAFC) Research Farm in Harrington, Prince Edward Island (PE) on a sandy loam, stubble field that was surface applied with 100 kg NH4-N ha-1 of liquid swine manure. After application the three NH3 emission techniques were established and measurements were performed over a 5-d period. Ammonia losses from the wind tunnels were comparable with those from the TPS method. The static chambers were found to underestimate NH3 emissions (by ~95–99%), compared with both the wind tunnel and TPS methods. It is therefore recommended that either the TPS or wind tunnel approaches be used to more accurately quantify NH3 losses for field systems. Key words: Ammonia volatilization, flux measurements, swine manure, micrometeorology, static chambers, wind tunnel

Description: Perennial legumes in crop rotations increase soil C sequestration from greater productivity with N2 fixation. Here, we corroborated increases in soil organic carbon (SOC) and harvests modelled in 5 yr wheat–oats–barley–alfalfa/brome–alfalfa/brome (5Y) vs. 2 yr wheat–fallow (WF) rotations with those measured from 1929 to 2018. Harvest and SOC gains of 100–150 g C m−2 yr−1 and 15–25 g C m−2 yr−1 were modelled and measured in 5Y vs. WF rotations with different fertilizer and manure amendments. Modelled gains were closely related to annualized rates of N2 fixation by alfalfa of 8–10 g N m−2 yr−1. However, N2 fixation also drove increases in modelled N2O emissions of ca. 0.06 g N m−2 yr−1, which partially offset gains in SOC. Gains in harvest, SOC, and N2O emissions of 60–90 g C m−2 yr−1, 15 g C m−2 yr−1, and 0.05 g N m−2 yr−1 were modelled and measured in both rotations with amendments of N + P relative to unamended treatments. Harvest and SOC gains were smaller, and leaching and N2O losses larger, with amendments of N without P. After 100 yr of RCP 8.5 climate change, harvests in WF changed little from those in baseline runs, whereas those in 5Y rose with N + P because of increased N2 fixation. SOC declined in WF with all amendments and could only be raised in 5Y with N + P amendments. These model findings indicated the importance of N2 fixation and P amendments in determining responses of agroecosystem productivity and C sequestration to climate change.

Description: Tillage influences the retention and storage of organic matter (OM) in soil. We used a sequential density and particle-size fractionation to evaluate the total quantity and distribution of organic carbon (C) and nitrogen (N) in the profile of soils under mouldboard ploughing and no-till. Cores (0-60 cm) from four long-term tillage studies (in Prince Edward Island, Quebec, and two sites in Ontario) on soils of different textures, from sandy loam to clay were collected and divided into six depth increments. Four soil OM fractions were isolated on the basis of size and density from each sample. At two sites the standing stocks of C and N were larger in tilled than in no-till soil profiles at depths slightly greater than plough depth; tillage effects were also evident at a third site, where the mass of C in a layer close to the depth of ploughing was greater in tilled soils. Ploughing also had a substantial and consistent positive effect in all four soils on the quantity of C (and in some cases N) protected within aggregates, particularly at or near the bottom of the plough layer, and sometimes in surface soil layers. We attribute differences observed in whole soil C and N due to tillage mostly to differences in mineral-associated OM, particularly in soils with heavier textures, but the other size and density fractions could, together, account for as much as 25% of the difference. Because the C capacity level was not reached in heavy-textured soils, these soils show greater potential for further accumulation of C in the soil profile than coarse-textured soils, especially near the bottom of the plough layer.Key words: Light fraction, soil organic matter, soil tillage, physically-protected organic matter, no-till, soil texture

Description: The objectives of this study were to find ways to improve the accuracy of soil fertilizer recommendations by taking into account the variation in bulk density (BD) of organic soils. To achieve this end, field BD values of 30 organic soils (0.100–0.504 g/mL) were used to evaluate methods of measuring the BD in the laboratory by means of correlation and regression techniques. A simple and rapid procedure using the reconstituted BD of field-moist soils was the most accurate means of determining the average field BD in the laboratory, as indicated by the correlation coefficient obtained between the BD values obtained by this method and those in the field (r = 0.975**). The second most accurate method relied upon the exponential relationship between the water content of soils and their BD (R2 = 91.1 %). The least exact method of correcting for BD variations was to scoop a volume of dried (65 °C) and sieved (2-mm) soils, as is done in some soil test laboratories. Although the values obtained by this method were related (r = 0.502**) to the field data, drying caused shrinkage of soils, thereby increasing their BD about twofold. Soil pH (r = 0.716**) and percentage ash contents (r = 0.851**) were also related to the field BD of soils. These tests could be used to estimate the BD of soils when the preferred method cannot be used. Regression equations are provided for relating appropriate test values to the BD of organic soils.

Description: In response to Kyoto Protocol commitments, countries can elect agricultural carbon sinks to offset emissions from other sectors, but they need to verify soil organic carbon (SOC) stock change. We summarize issues we see as barriers to obtaining accurate measures of SOC change, including: soil depth, bulk density and equivalent soil mass, representation of landscape components, experimental design, and the equilibrium status of the SOC. If the entire plow depth is not considered, rates of SOC storage under conservation compared with conventional tillage can be overstated. Bulk density must be measured to report SOC stock on an area basis. More critical still is the need to report SOC stock on an equivalent mass basis to normalize the effects of management on bulk density. Most experiments comparing SOC under differing management have been conducted in small, flat research plots. Although results obtained from these long-term experiments have been useful to develop and validate SOC prediction models, they do not adequately consider landscape effects. Traditional agronomic experimental designs can be inefficient for assessing small changes in SOC stock within large spatial variability. Sampling designs are suggested to improve statistical power and sensitivity in detecting changes in SOC stocks over short time periods. Key words: Soil organic carbon change, agroecosystems, experimental design, sampling depth

Description: This paper deals with predicting flow accumulation, drainage class, and soil and vegetation type within small headwater catchments (

Description: Sustainability of forest ecosystems and climate change are two critical issues for boreal forest ecosystems in Canada that require an understanding of the links and balance between productivity, soil processes and their interaction with natural and anth ropogenic disturbances. Forest ecosystem models can be used to understand and predict boreal forest ecosystem dynamics. EFIMOD 2 is an individual tree model of the forest-soil ecosystem capable of modelling nitrogen feedback to productivity in response to changes in soil moisture and temperature. It has been successfully applied in Europe, but has not been calibrated for any forest ecosystem in Canada. The objective of this study was to parameterize and validate EFIMOD 2 for jack pine in Canada. Simulated and measured results agreed for changes in tree biomass carbon and soil carbon and nitrogen with increasing stand age and across a climatic gradient from the southern to northern limits of the boreal forest. Preliminary results from scenario testing indicate that EFIMOD 2 can be successfully applied to predict the impacts of forest management practices and climate change in the absence of natural disturbances on jack pine in the boreal forest of Canada. Model development is underway to represent the effects of natural disturbances. Key words: EFIMOD 2, forest soil, carbon, nitrogen, model, jack pine

Description: It is recognized that volatilized ammonia (NH3) from intensive livestock production can be a significant pathway for nitrogen (N) pollution to land and water, and can contribute to poor air quality. The objectives of our study were to document NH3 emissions from a dairy lagoon and to assess the influence of meteorology on NH3 emissions. Ammonia emissions were determined using a backward Lagrangian Stochastic approach using WindTrax software, an open-path NH3 laser and a sonic anemometer. Results indicate that an average 5.1 ± 1.6 g NH3 m-2 d-1 was released over the summer; however, the emission varied typically over 24 h between 3.6 and 8.6 g NH3 m-2 d-1. Wind speed and surface temperature of the lagoon had similar influences on the magnitude of the release, where their direct impact on NH3 emission accounted for 28 and 31% of the variability, respectively. The main implication of this study is that NH3 losses are significant from dairy lagoons, contributing to the issue of N pollution. As well, NH3 emissions are a loss of valuable N for manure used as fertilizer, which in our study amounted to approximately 13% of the total ammoniacal N content of the manure in the lagoon. Key words: Ammonia, dairy, manure, cattle, dispersion model

Description: Potassium deficiency in grapes, as well as in other fruit crops grown on soils in the Niagara peninsula, is a common and often serious problem. Ap horizon samples from 12 of these soils and grape petiole samples from nine of the soil locations were analyzed to elucidate the behavior of the soil K and its availability to grapes. The soils ranged in texture from sandy loam to silty clay and their clay mineralogy was relatively uniform with mica as the main layer silicate. Vermiculite was quantified by potential K fixation methods and was concentrated in the clay. Up to 5.8% vermiculite was present in the soils which seemed to be sufficient to reduce K availability by K fixation. Amounts of exchangeable K extracted with NaCl or NH4Cl were relatively high (0.46–2.09 meq/100 g) but were not correlated with K uptake by grapes. Energies of K exchange obtained from immiscibly displaced soil solutions were closely related to vermiculite contents and amounts of K fixed after air drying. Energies of K exchange and ratios of exchangeable K over exchangeable Ca + Mg were highly correlated with K uptake by grapes. Soils with energies of K exchange less than or equal to −2800 cal/equiv. or K exch./(Ca + Mg) exch. equal to or more than 7% appeared to have adequate amounts of available K for grapes. These two analyses therefore show promise for predicting K availability to grapes. Key words: Exchangeability of K, energy of K exchange, fixation of K, soil mineralogy, availability of K to grapes

Description: Using a revised Intergovernmental Panel on Climate Change (IPCC) methodology and the process-based model DeNitrification and DeComposition (DNDC), we estimated N2O emissions from agroecosystems in Canada for each census year from 1981 to 2001. Based on the IPCC methodology, direct emissions of N2O ranged from 12.9 to 17.3 with an average of 15.1 Tg CO2 equivalents, while the DNDC model predicted values from 16.0 to 24.3 with an average of 20.8 Tg CO2 equivalents over the same period, and showed a large interannual variation reflecting weather variability. On a provincial basis, emissions estimated by IPCC and DNDC methods were highest in Alberta, Saskatchewan and Ontario, intermediate for Manitoba and Quebec and lowest in British Columbia and the Atlantic provinces. The greatest source of emissions estimated by the IPCC method was from N fertilizer (avg. 6.32 Tg CO2 equiv. in Canada), followed by crop residues (4.24), pasture range and paddocks (PRP) (2.77), and manure (1.65). All sources of emissions, but especially those from fertilizers, increased moderately over time. Monte Carlo Simulation was used to determine the uncertainty associated with the 2001 emission estimates for both IPCC and DNDC methodologies. The simulation generated most likely values of 19.2 and 16.0 Tg CO2 equivalents for IPCC and DNDC, respectively, with uncertainties of 37 and 41%, respectively. Values for the IPCC estimates varied between 28% for PRP and manure and 50% for N fertilizer and crop residues. At the provincial level, uncertainty ranged between 15 and 47% with higher values on the prairies. Sensitivity analyses for IPCC estimates showed crop residues as the most important source of uncertainty followed by synthetic N-fertilizers. Our analysis demonstrated that N2O emissions can be effectively estimated by both the DNDC and IPCC methods and that their uncertainties can be effectively estimated by Monte Carlo Simulation. Key words: Nitrous oxide, IPCC, DNDC model, Uncertainty analysis, Monte Carlo Simulation

Description: Environment and management effects on the N supply to crops are not well understood. We assessed the influence of tillage system (conventional tillage or no-till), N fertilizer (0 or 60 kg N ha-1) and year on N sources and supply of a Dark Brown Chernozem loam soil, and N utilization by spring wheat (Triticum aestivum L.) in 2 yr. The main N source was mineralized N; only 14–23% of wheat N was derived from fertilizer, and non-exchangeable ammonium made no measurable contribution. Soil NO3 and exchangeable NH4 content at sowing and net N mineralization during the growing season (Nmin) were influenced more by year than by N addition and tillage. Nmin was 90–100 kg N ha-1 in 1999, a moist growing season but only 21–39 kg N ha-1 in 2000, a drier year. In both years, soil inorganic N to 60 cm at sowing averaged about 60 kg N ha-1 of which half was N mineralized since the previous harvest. Year accounted for 65–81% of the variation in N uptake. Fertilization increased N uptake and wheat yields, especially in 2000, but fertilization and tillage had no effect on post-heading N uptake and N translocation. Nitrogen use efficiency (NUE) and N recovery were lower with N applied and not affected by tillage. Our study indicated that available N was affected more by environment than management. In dry conditions, when Nmin is low, N application may be more effective in increasing yield and N uptake than in wet years, an observation that may merit further attention. Key words: Available N, N mineralization, N recovery, N use efficiency, non-exchangeable ammonium, tillage

Description: The recent development of low-cost controlled-release urea (CRU) may provide additional options for N fertilization of winter wheat (Triticum aestivum L.). Two field experiments were conducted over 3 yr at three locations in southern Alberta to evaluate different options of applying CRU to winter wheat. In the first experiment, three N fertilizers (20-day CRU, 40-day CRU and urea) were seed-placed and side-banded at the time of seeding at 0, 30, 60, 90 and 120 kg N ha-1. Stand densities were substantially reduced by seedrow application of urea at rates greater than 30 kg N ha-1, but were unaffected by seedrow application of CRU, even at the highest rate of N application. When N fertilizer was sidebanded, stand densities were unaffected by fertilizer type or N rate. Yield gains due to N application were reduced by application of high rates of seed-placed urea, but similar for other treatments. Grain protein concentration and N uptake were also similar for CRU and seed-placed urea. In the second experiment, three N fertilizers (CRU, urea and ammonium nitrate) were broadcast at 30 kg N ha-1 in early spring on plots that had received 0, 30 or 60 kg N ha-1 of CRU at the time of seeding. Inadequate release of spring broadcast CRU was indicated by reduced grain protein concentrations relative to conventional N fertilizers. Under the conditions experienced in our study, CRU substantially increased the maximum safe rate of seed-placed urea, provided minimal benefits to N response relative to side-banded urea, and was less effective than conventional N fertilizers when broadcast in early spring. Key words: N fertilizer use efficiency, slow release, winter survival

Description: Intermediate wheatgrass [Thinopyrum intermedium (Host) Barkw. & D.R. Dewey subsp. intermedium] is a productive, high-quality perennial forage that lacks persistence under grazing. A study was conducted to evaluate the effects of three grazing times on soil bulk density, soil pH, and soil organic C under intermediate wheatgrass. Treatment effects on the three soil attributes were negligible, implying grazing time did not negatively impact intermediate wheatgrass beyond a threshold whereby critical soil functions were impaired. Findings from this study are important in the context of sustainable forage and cropping system management, where maintaining or improving critical soil functions are essential for enhancing agroecosystem sustainability. Key words: Seeded perennial forages, Northern Great Plains, soil organic C

Description: Hydrological models require the determination of fitting parameters that are tedious and time consuming to acquire. A rapid alternative method of estimating the fitting parameters is to use pedotransfer functions. This paper proposes a reliable method to estimate soil moisture at -33 and -1500 kPa from soil texture and bulk density. This method reduces the saturated moisture content by multiplying it with two non-linear functions depending on sand and clay contents. The novel pedotransfer function has no restrictions on the range of the texture predictors and gives reasonable predictions for soils with bulk density that varies from 0.25 to 2.16 g cm-3. These pedotransfer functions require only five parameters for each pressure head. It is generally accepted that the introduction of organic matter as a predictor improves the outcomes; however it was found by using a porosity based pedotransfer model, using organic matter as a predictor only modestly improves the accuracy. The model was developed employing 18 559 samples from the IGBP-DIS soil data set for pedotransfer function development (Data and Information System of the International Geosphere Biosphere Programme) database that embodies all major soils across the United States of America. The function is reliable and performs well for a wide range of soils occurring in very dry to very wet climates. Climatical grouping of the IGBP-DIS soils was proposed (aquic, tropical, cryic, aridic), but the results show that only tropical soils require specific grouping. Among many other different non-climatical soil groups tested, only humic and vitric soils were found to require specific grouping. The reliability of the pedotransfer function was further demonstrated with an independent database from Northern Italy having heterogeneous soils, and was found to be comparable or better than the accuracy of other pedotransfer functions found in the literature. Key words: Pedotransfer functions, soil moisture, soil texture, bulk density, organic matter, grouping

Description: The objectives of this study were to evaluate if zero tillage had significantly altered the distribution of certain soil properties formally developed under the shallow cultivation (conventional tillage) soil management systems used on the Canadian prairies. To this end, concentration gradients of available plant nutrients, microbial biomass and mineralizable C and N, were determined in the Ap soil horizon from four locations representing zero and conventional (shallow) tillage systems of 2-, 4-, 12- and 16-yr duration. No significant change coud be detected in total soil organic C and N between tillages systems. Concentrations of plant-available P and K were slightly increased in the surface 0- to 2-cm depth after 16 yr of zero tillage. Except for the 2-yr tillage site, concentration gradients of potential microbial biomass C and N, and potential net mineralizable C and N were significantly greater in the surface soil under zero tillage in comparison to conventional tillage. The reverse situation was observed at the lower depth. The percentage of soil organic C and N that was in the microbial biomass also reflected the above trends. Accumulation of mineral N and calculated N mineralization potentials were closely correlated to both the initial microbial biomass N and the decrease in size of the latter during mineralization. The possible relationships of tillage induced change and redistribution in potential biological activity to N availability were discussed.

Description: Adequate nitrogen (N) fertilization is crucial to optimize yield and quality of potato and also to minimize N environmental losses. Effects of rates and timing of N fertilizer on residual soil nitrate (RSN) [NO3-N, 0-0.7 m], soil solution nitrate (SWN) concentrations and apparent fertilizer nitrogen recovery (Nrec) by potato (Solanum tuberosum L.) tubers were evaluated from 1999 to 2001. Two sites representative of the management zones (MZ) previously delineated by apparent soil electrical conductivity and differing in soil water availability were selected. The MZ differed primarily with depth to a clayey substratum, with average values of 1.06 m and 1.34 m in the shallow MZ (SMZ) and in the deep MZ (DMZ), respectively. At each site, a trial with 21 treatments including five rates of ammonium nitrate (0–200 kg N ha-1 in 1999; 0–240 kg N ha-1 in 2000 and 2001) was conducted. Each N rate was applied according to five application timings (100, 75, 50, 25 or 0% of N applied at planting with the remainder at hilling). The effects of N rates and timing on Nrec, RSN and SWN sometimes differed between sites. The Nrec was less responsive to N rates and timing in the SMZ site compared with the DMZ site. Application of the same rate of fertilizer N generally resulted in higher values of RSN at harvest in the SMZ site compared with the DMZ site. Measured SWN was higher in the DMZ than in the SMZ on several occasions in 1999 and 2001, indicating greater nitrate (NO3) leaching in the DMZ site compared with the SMZ site. Different site-specific N management regimes could thus be used at the two sites to improve N use efficiency and to limit the risk of NO3 leaching. However, the temporal variability in the measured parameters, influenced mainly by climatic conditions, was greater than the spatial N variability and this emphasizes the fact that a dynamic model of the N status based on the soil and/or the plant is a prerequisite to help growers to adjust the N fertilizer application within fields and seasons. Key words: Solanum tuberosum, apparent soil electrical conductivity, suction lysimeter

Description: Containerized jack pine (Pinus banksiana Lamb.) seedlings were planted in 10 paired slash-pile-burn and control plots established on a recent clearcut in north eastern Ontario to assess early impacts of intensive fire on soils and plant growth and nutrition. Root zone soil and seedlings were sampled one growing season after planting. The control seedlings exhibited modest growth without gain in N content, indicating reliance on internal nutrient reserves for growth on this low-fertility site. Slash-pile burning reduced seedling mortality, and markedly increased height, rootcollar diameter, and biomass growth, as well as uptake of N, P, K, Ca and Mg. The response was attributed to greatly improved soil fertility following fire, characterized by increased pH, extractable NO3- and NH4+ , available P, and exchangeable K, Ca and Mg. Significant correlations between corresponding soil tests and seedling nutrient composition indicated that laboratory extractions effectively reflected nutrient availability to plants. The highest correlations were associated with N. Vector diagnosis identified N as the most limiting nutrient constraining growth on the burns, even though base cation increases (mainly from ash) were relatively larger than extractable N in the soil. These early responses in soils and plants to intensive fire may have long-term effects on plantation development. Key words: Slash pile, prescribed fire, soil fertility, seedling nutrition

Description: In 1982, six crop rotation treatments that were initiated in 1967 on a Orthic Brown Chernozemic loam were sampled for soil NO3-N and moisture to a depth of 240 cm. Soil samples were taken on 18 May and 10 June from all treatments, on 2 Sept. on fallow treatments only, and on 14 Oct. from cropped treatments. Precipitation during the sampling period was about 23% above the long-term average. It was estimated that at least 123 kg NO3-N∙ha−1 were leached from the top 240 cm of fallow soils. Leaching appeared to result from a portion of the precipitation moving through macro soil pores. There was evidence that water and NO3-N might also move upwards from below the 240-cm depth. Of the six rotations examined, the 2-yr and 3-yr spring wheat (Triticum aestivum L.) rotations lost the most NO3-N. The presence of fall rye (Secale cereale L.) in a fallow-rye-wheat rotation was very effective in reducing NO3-N losses. Spring wheat, when grown continuously, was also very effective in reducing NO3-N losses but even here there was some evidence of leaching beyond the root zone. Application of fertilizer N and P at amounts based on soil test recommendations reduced NO3-N leached. It was estimated from long-term precipitation data, that over the past 100 yr about 20% of the soil organic N that was present at the time of breaking the land has been lost from the soil via leaching. It was concluded that leaching losses of N from the soils on the Canadian prairies had been greatly underestimated and were partly responsible for losses attributed to the more visible wind erosion. Key words: Nitrate movement, crop rotations, fertilizer and leaching, summerfallow and leaching, bimodal leaching

Description: Despite the seriousness of the erosion problem in the Nakhla watershed, there are still only limited data on the rates of soil loss on cultivated land on steep slopes. Thus, there is a need for more information for optimizing strategies for soil conservation. Recent concern over problems of soil degradation and the off-site impacts of accelerated erosion has highlighted the need for improved methods of estimating rates and patterns of soil erosion by water. In this paper, soil erosion and deposition rates have been studied using the 137Cs technique in upstream part in the Nakhla watershed on cultivated soils (Larbaa Beni Hassan area), which is known to suffer soil erosion. Multiple transect sampling was established parallel to the slope, and 137Cs inventories were determined for the sampling points. After establishing the local reference inventory (3073 Bq m-2), soil erosion and deposition rates were estimated using the 137Cs inventories on all the transects with three calibration models: proportional model (PM), mass balance model 1 (MBM1) and mass balance model 2 (MBM2). The magnitude of the soil erosion rates depends on many factors, including the location of sampling, the local topography, and the soil properties. Estimated soil erosion rates for the study area varied from 0.4 to 28.9 t ha-1 yr-1 using PM; from 0.5 to 66.9 t ha-1 yr-1 using MBM1; and from 0.4 to 56.4 t ha-1 yr-1 using MBM2. The deposition ranged, respectively, from 0.3 to 8.0 t ha-1 yr-1 for PM, from 0.4 to 14.5 t ha-1 yr-1 for MBM1, and from 0.3 to 11.5 t ha-1 yr-1 for MBM2. The sediment delivery ratio is about 98%. For one selected plot, L11, the erosion rates show a clear relationship with the range of slopes in its three different horizontal parts. Estimates of soil redistribution rates were interpolated by means of kriging, using Surfer 7.0 software. Two representative transects were selected to identify the contribution of tillage on 137Cs redistribution by using mass balance model 3. It is observed that the pattern of 137Cs redistribution is dominated by water erosion and that the contribution of tillage redistribution remain is smaller. Key words: 137Cs method, soil erosion, erosion rate, soil redistribution, conversion models

Description: The overall objective of this study was to measure the major nitrogen pools and fluxes in nutrient- and peat-rich, vegetated marshes and fens surrounding shallow ponds in the Western Boreal Plain (WBP) of Canada. Within the same peatland-pond complex, marshes and fens did not differ from each other in major N fluxes and pool sizes; however, significant differences in N dynamics were measured between different peatland-ponds. Specifically, N cycling rates (gross and net mineralization) were much greater in a floating peatland than in a non-floating peatland. Gross N mineralization rates were 59 and 453 mg N m-2 d-1 in the non-floating and floating peatlands, respectively. Gross ammonification rates were approximately 4–10 times net rates while gross nitrification rates were 500–800 times net rates, indicating rapid turnover of extractable inorganic N pools. Increased moisture and carbon in the floating peat supported higher microbial biomass and activity, however net primary production values were lower, presumably due to competition by microbes for available inorganic N. Monthly measurements of N fluxes were combined to provide an estimate of annual internal N cycling within marshes and fens surrounding shallow ponds in the WBP. Key words: Gross mineralization, microbial biomass, nitrogen, peatland

Description: Experiments were done to characterize the hydrolyzed solutions of aluminum nitrate, aluminum chloride and aluminum sulfate. The hydrolysis of the dilute solutions (10−3M) was accomplished under reflux process at 92 °C. The results showed that anions associated with Al have an effect on hydrolysis of aluminum and the order of ease of hydrolysis for similar concentrations of Al was NO3 〉 Cl 〉 SO4. The average composition of the hydroxyaluminum cation (Aln(OH)m) was calculated as [Formula: see text] and [Formula: see text] for hydrolyzed solutions of Al(NO3)3, AlCl3, and Al2(SO4)3, respectively. The infrared spectra of the hydrolyzed species of aluminum were obtained by a subtraction technique and infrared peaks at 1410 cm−1 and 1085 cm−1 in the AlCl3 system and at 1435 cm−1 and 1070 cm−1 in the Al2(SO4)3 system were assigned to polynuclear hydroxyaluminum species having been formed due to reflux process.

Description: Core aeration, a management practice originally developed for soil-based putting greens, is still commonly used on sand-based greens. The study objective was to determine the effects of core aeration on soil properties of sand-based putting greens in the Lower Fraser Valley of British Columbia. The experiment was laid out as a randomized complete block design with three replications. The study treatments were regular management practices, including core aeration (CA) carried out in spring and late summer, and regular management practices, but no core aeration (NCA). Each core aeration event impacted 5% of the surface area. Treatments with and without core aeration had similar soil organic matter content, root weight density, and soil bulk density. The CA treatment was generally drier than NCA. Water infiltration was greater on CA than NCA, but only for 1 mo following core aeration. Core aeration generally reduced soil penetration resistance within the mat layer relative to treatment without this practice. On both treatments, soil penetration resistance consistently exceeded 4000 kPa below about 13 cm depth preventing deeper root growth. The limited benefits of the low-surface-area-impact core aeration on the maturing sand-based putting greens in a humid maritime climate suggest that this practice might not be worth doing (at a low surface area impact); however, additional, more detailed studies are needed to confirm this. Key words: Turf management, golf course management, soil penetration resistance, water infiltration

Description: Soil phosphorus (P), which is potentially a risk for environmental contamination, is currently interpreted using soil P saturation in North America. Our objective was to assess the ratio of P to aluminum (Al) in the Mehlich-III (M-III) soil test to build P requirement models for corn and soybean. We analyzed 129 corn and 19 soybean P fertilizer trials. For corn, the (P/Al)M-III ratio improved soil fertility classification compared with PM-III alone. The critical PM-III value as determined by the Cate-Nelson procedure was found to be 31.5 mg PM-III kg-1, close to published values. The critical (P/Al)M-III ratios of 0.025 for 〉 300 g clay kg-1 soils and 0.040 for ≤ 300 g clay kg-1 soils differed significantly between the two soil groups. For (P/Al)M-III ratios above 0.214, there was no positive response to added P for all soils regardless of texture. Using published critical environmental (P/Al)M-III ratios of 0.076 for 〉 300 g clay kg-1soils and 0.131 for ≤ 300 g clay kg-1 soils as benchmarks values, agri-environmental P requirement models were built using conditional expectations of 50 to 80% of computed optimum P values within a soil class. A validation study supported the low critical (P/Al)M-III ratios and the 50% conditional expectation model except for a high carbon soil which was outside the application range of the models. However, banded P decreased corn yield at four validation sites although the model predicted positive response to P. Soybean did not respond to P except at extremely low fertility levels ((P/Al)M-III ≤ 0.02) and behaved as a P-mining crop even in low-P soils. Corn-soybean rotations can reduce soil P to low (P/Al)M-III ratios with minimal agronomic risk. Key words: Soil phosphorus saturation, Mehlich-III soil extraction method, soil fertility classification, soil texture, fertilizer P requirement model, corn, soybean

Description: The distribution of NO3-N in the soil, and N uptake by the crop during the first 12 yr of a long-term rotation study at Swift Current, Saskatchewan were studied. A considerable amount of NO3-N appeared to be leached beyond the rooting zone of the cereal crop in years of above average precipitation and also in some relatively dry years with heavy spring rains. Thus, leaching of NO3-N seemed to occur even under continuous wheat rotations. At all times there was considerable NO3-N situated at the 60- to 120-cm depth. In wet years N uptake by the plants reduced the amount of NO3-N located in the subsoil, but in dry years the amount of NO3-N in the subsoil remained higher throughout the growing season. The latter could result in groundwater pollution, especially if such a soil was fallowed the next year. Fall rye (Secale cereale L.) made more efficient use of mineral N than spring-sown crops. In dry years more NO3-N persisted in the root zone of N-fertilized wheat than in the root zone of unfertilized wheat, but in wet and average years there was little difference due to N application. The average rate of net NO3-N production in fallow land from spring thaw to freeze-up (166 days) was 107 kg∙ha−1. Values ranged from about 60 to 175 kg∙ha−1 with the lowest values being obtained during very dry or very wet years. The quantity of N mineralized (kg∙ha−1) between spring thaw and freeze-up was related to precipitation (mm) by the equation Nmin = 29.0 + 0.20 precipitation for the 0- to 60-cm depth (R2 = 0.65*). Key words: Nitrate leaching, N uptake, crop rotations, N mineralization rate

Description: Organic matter can sorb P in acid soils through metal-organic matter-phosphate complexes. The pyrophosphate extractable Al and Fe and soil C contents were hypothetized to influence P partitioning in Ferro-Humic Podzols. Reaction of added P may be mitigated by adding lime or organic matter as dry swine manure (DSM) together with mineral P fertilizers. Three soils had 40 to 50 g kg-1 of soil organic matter (SOM) content, and 76 to 140 mmol (Al + Fe)pyro kg-1. A peaty soil phase had 200 g SOM kg-1, and 58 mmol (Al + Fe)pyro kg-1. Rates of monoammonium phosphate were 0, 27, 69, and 144 kg P ha-1 in a simulated fertilizer band. Rates of DSM and lime were 800 and 185–369 mg per 35 mL of soil, respectively. After 6 wk of incubation, soil P was fractionated sequentially into aluminium bound P (Al-P), iron bound P (Fe-P), and loosely bound P. Total P, desorbed P and organic P were determined in separate subsamples. A proportion of 79–92% of added P was recovered as Al-P and Fe-P in the three low SOM soils, compared to 51–61% in the high SOM soil. The DSM increased loosely bound P from 25 to 34% in the high SOM soil and from 4.8 to 5.9% in low SOM soils. With DSM, the proportion of desorbed P was much higher in the high (70%) than in low SOM (22%) soils. Compared to the non-amended treatment, lime showed no significant effect on any P fraction but desorbed P. The DSM increased P availability in the fertilizer band considerably more in the soil having the lowest (Al + Fe)pyro/C ratio. Key words: P fractionation, organic ligand, P sorption, fertilizer band

Description: Field spectroscopy and other efficient hyperspectral techniques have been widely used to measure soil properties, including soil organic carbon (SOC) content. However, reflectance measurements based on field spectroscopy are quite sensitive to uncontrolled variations in surface soil conditions, such as moisture content; hence, such variations lead to drastically reduced prediction accuracy. The goals of this work are to (i) explore the moisture effect on soil spectra with different SOC levels, (ii) evaluate the selection of optimal parameter for external parameter othogonalization (EPO) in reducing moisture effect, and (iii) improve SOC prediction accuracy for semi-arid soils with various moisture levels by combing the EPO with machine learning method. Soil samples were collected from grassland regions of Inner Mongolia in North China. Rewetting laboratory experiments were conducted to make samples moisturized at five levels. Visible and near-infrared spectra (350–2500 nm) of soil samples rewetted were observed using a hand-held SVC HR-1024 spectroradiometer. Our results show that moisture influences the correlation between SOC content and soil reflectance spectra and that moisture has a greater impact on the spectra of samples with low SOC. An EPO algorithm can quantitatively extract information of the affected spectra from the spectra of moist soil samples by an optimal singular value. A SOC model that effectively couples EPO with random forest (RF) outperforms partial least-square regression (PLSR)-based models. The EPO–RF model generates better results with R2 of 0.86 and root-mean squared error (RMSE) of 3.82 g kg−1, whereas a PLSR model gives R2 of 0.79 and RMSE of 4.68 g kg−1.

Description: Organic matter with high C:N ratios accumulated on mineral soil retards cycling of nutrients in semi-mature jack pine (Pinus banksiana Lamb.) ecosystems. To test whether N as ammonium sulfate or as urea stimulates organic matter decomposition, 200 kg N∙ha−1 were applied to mixed L and F horizon material in Warburg respirometer flasks. Soils were incubated at 13 °C and constant 0.3 bar (340%) moisture; O2 consumption was measured as an index of microbial activity. In urea-treated soil, O2 uptake was much higher than with unamended soil over a 7-wk incubation period, and this indicated a marked effect of urea on microbial activity. The fact that ammonium sulfate depressed respiration rates was evidence that stimulation of microbial respiration by urea was not initially related to added N, but rather to an increase in soil-soluble C resulting from soil pH changes during hydrolysis. In the presence of a C source (ethanol), a 5-fold increase in respiration was noted, whereas C and urea together produced a 15-fold increase in activity. These results suggest that readily available energy for microbial growth, rather than N, limits the initial decomposition of L and F materials in this pine stand. Once microbial demand for C is satisfied, a further increase in microbial activity is produced by N addition.

Description: From the solubility equilibrium data of basic aluminite at three temperatures, the standard free energy change (ΔG°), enthalpy change (ΔH°), and entropy change (ΔS°) were determined as 160.02 kcal∙mole−1, 65.48 kcal∙mole−1 and 317.1 cal∙deg−1]mole−1, respectively. From these values the free energy of formation (ΔGf°) and the heat of formation (ΔHf°) of basic aluminite was also computed and was 1465.25 kcal∙mole−1 and 1682.08 kcal∙mole−1, respectively.

Description: Vegetated buffer strips (VBS) are often recommended as a management practice that farmers can use to help mitigate the environmental effects of runoff from agricultural fields. Previous research has shown that VBS can be effective at trapping phosphorus (P) and other farm-sourced environmental contaminants. This project measured the effectiveness of established vegetated strips at decreasing P in runoff from agricultural fields in Manitoba. Paired samples of runoff, taken at the field edge and in the vegetated strip, indicated that in 11 of the 22 cases sampled (50%), P concentrations in the runoff decreased (on average 30%) as the flow passed through the vegetated strip. In 7 of the 22 case (32%) there was no difference; however, in four of the 22 cases (18%), runoff P concentrations increased, indicating the vegetated strip had become a source of runoff P. Soil samples from the VBS showed high available P concentrations at positions within the vegetated strip along the runoff flow path, and in 7 of 10 cases these concentrations were higher (33% on average) than in the field soil. Although the observations and numerical results suggest that VBS can be effective at removing P in runoff, perhaps the major limitation in this flat-land region is that runoff tends to flow through rather small portions of the VBS, and these may not have sufficient capacity to retain the runoff P in the longer term. Key words: Vegetated filter strips, VBS, VFS, manure, soluble, particulate, ortho, riparian

Description: New legislation to reduce the amount of fertilizer leached into the environment by horticultural growers and the need to implement water-saving irrigation systems require an understanding of salt build-up and of nutrient cycles in order to develop efficient water-use strategies for growers. Solute transport in growing media is central to this process, but has received little attention thus far. The objectives of this study were to determine how solutes behave in sub-irrigated growing media and to assess a solute transport model for these media. A steady state evaporation (upward water flow) experiment was carried out with three different growing media in packed columns in the laboratory. Bromide, potassium and copper concentrations were determined using in-column pore water solution samplers and by sectioning the columns at the end of the experiment to obtain concentration profiles. The Hydrus-1D model was fitted to the solution sampler data assuming non-linear Freundlich adsorption, and then used to obtain favorable predictions of the measured concentration profiles. Independent adsorption isotherm results from batch experiments were found to be inadequate when used to predict solute movement and the results indicate that the preferred approach is an in-column evaluation of the transport parameters.Key words: Solute transport, sub-irrigation, peat, growing media

Description: A modular approach is presented to assess terrain-specific soil trafficability in terms of soil resistance to penetration and machine-specific rut depths. These modules address: (1) soil resistance to cone penetration (cone index, or CI) as affected by soil moisture, texture and pore space (Module 1), (2) machine-induced rut depths (single-pass and multi-cycles) as affected by wheel loads, tire specifications and CI (accounting for depth of compactable soil, Module 2), (3) temporal variations in hydrothermal conditions, CI, and potential rut depths due to daily soil moisture and temperature variations (Module 3), and (4) spatial variations in CI and rut depth across terrain due to corresponding changes in soil moisture, depth of compactable soil, bulk density, texture, frost depth, organic matter and coarse fragments (Module 4). The approach is applied to off-road wood-forwarding operations. Modules 1 and 2 were calibrated to apply to a wide range of soil conditions. Modules 3 and 4 were initialized for a wood-forwarding case study at CFB Gagetown, New Brunswick, Canada. Model results should be most applicable for flat to near-flat terrain, with insignificant wheel obstructions, and no organic matter accumulations on top of the mineral soil. Key words: Forest harvesting, soil penetration resistance, cone index, soil rut depth, soil disturbance, soil trafficability, soil compaction, terrain modelling

Description: Current irrigation water criteria for boron (B) are based upon the B concentration of either the irrigation water or the soil saturation extract. The effects of the leaching fraction (LF) and the boron adsorption capacity (BAC) of the soil upon the soil solution concentration have not been considered. The objectives of this paper were (i) to develop a predictive model relating soil solution B concentration at equilibrium to the B concentration in irrigation water and the LF, and (ii) to show how the relationship between the B concentration of the soil solution under field conditions and the B concentration of the soil saturation extract can be modelled. The predictive model, derived from the mass balance concept, indicated that at equilibrium the value of the soil solution B in well-drained soil would be close to that of irrigation water, at the soil surface and will increase with depth with the highest value being near the bottom of the root zone where its magnitude is determined primarily on the degree of leaching. For irrigation water concentrations between 0.5 and 10 mg B/L, the weighted average B concentration of the soil solution in the profile of an alfalfa field would be about 1.9–2.7 times the irrigation water concentration at a LF of 0.1; it would be 1.4–1.9 times for a LF of 0.25; and 1.3–1.5 times for a LF of 0.4. The model of the relationship between soil solution B at field capacity and saturation extract B indicates the importance of the BAC of the soil. Without considering BAC, the ratio between the two would be 2. However, the model indicates that the ratio ranges from 1.0 to 1.8 depending upon the B concentration in the solution and the BAC of the soil. This suggests that the B concentration of the soil saturation extract does not provide a true representation of the soil solution B. In assessing B toxicity, the saturation extract concentration should be converted to the soil solution concentration at the actual water content of the soil.

Description: A preliminary field study was conducted to investigate the influence of fall applications of nitrogen and phosphorus on winter survival of winter wheat on zero-tilled and conventionally tilled land. Nitrogen fertilization tended to decrease winter survival while phosphorus fertilization tended to increase survival. A N-P interaction was observed, with the decrease in survival in response to added N being more evident in the absense of applied P. Balanced N-P fertilization may therefore result in highest winter survival in both conventionally tilled and zero-tilled winter wheat. Key words: Zero-tillage, winter survival, nitrogen, phosphorus, winter wheat

Description: Regression and covariance analysis of a 13-yr rotation experiment of corn on Brookston clay soil showed that grain yield of corn could be related to each of nine other plant and soil measurements. Soil compaction as measured by bulk density was negatively associated with the level of leaf K in the plants, as well as available soil moisture. The major part of the yield difference between fertilized continuous corn and fertilized corn following alfalfa could be accounted for by multiple regression of grain yield on leaf N and K nutrient levels, soil compaction and soil moisture. Soil compaction was not affected or modified by fertilizer treatment. Response of corn grain yield to soil conditions, moisture and plant nutrient level appears to vary with rotation and fertilizer input.

Description: The dynamics of fixation and release of NH4+ in soils were studied using tracer N under field and laboratory conditions. Field data showed that release of fixed NH4+ was relatively slow after an initial moderately fast release. Forty months of field weathering of Bainsville soil left 3.48 kg 15N/ha in the 75-cm profile of the 13.5 kg 15N/ha applied and most (76%) of this recovered 15N was fixed NH4+–N. The relative quantitative importance of recently fixed NH4+ in the various particle size fractions was not in the same order as the native fixed NH4+. The fine silt fraction (2–5 μm) fixed a larger amount (whole soil basis) than the fine clay fraction (

Description: Increased use of sulphur (S) fertilizers in southern Alberta led to a series of field and phytotron experiments to investigate the importance of S fertilizers and the role of subsoil reserves of sulphate sulphur (SO4-S) for barley (Hordeum vulgare) and rapeseed (Brassica napus). Two types of experiments were conducted. In the field-plot studies, barley was grown on dryland soils low in surface SO4-S but underlain by subsoil high in SO4-S. Neither elemental nor SO4 forms of S significantly increased barley yields in a series of 10 experiments on those soils. The comparisons were made at three levels of N fertilizers. In a series of lysimeter studies, three successive crops were grown in soil low in inorganic S (2.0 μg SO4-S∙g−1), or soil supplemented with 25 μg 35SO4-S∙g−1 soil at specified depths in the lysimeters. Barley was adequately supplied with S from SO4-S at a depth of 54–72 cm. It obtained 55% of its S from a high SO4-S (25 μg∙g−1) layer of soil at that depth, although 40 days growth were required before the S was effectively utilized. Five times as much S was taken up by the barley when the entire soil received an additional 25 μg SO4-S∙g−1 as when only the 54- to 72-cm depth was supplemented; however, the yields were unaffected. Most of the excess S was retained in the straw. Rapeseed took up an increasing amount of SO4-S as the proportion of the lysimeters that initially contained SO4-S was increased. Rapeseed was also able to utilize SO4-S from a depth of 54–72 cm. Rapeseed showed deficiency symptoms when most of the added and soil reserves of S had been depleted by previous crops; its growth habit became indeterminate and seeds did not develop. Although total dry matter yield was not greatly affected, seed yield was markedly reduced in S-deficient rapeseed. Rapeseed took up 10 times as much S as did barley when the S supply was just adequate for seed production. Although rapeseed had a much higher S requirement than barley, both crops were adequately supplied by subsoil reserves of SO4-S under the field and controlled environment conditions studied. The studies suggest that fertilizer recommendations should be based on soil analysis to a depth of at least 60 cm. Key words: Sulphur fertilizer, sulphates, 35S, barley, rapeseed, nutrient uptake

Description: A 2-yr study was conducted to investigate the effects of application date, landscape position and a urease and nitrification inhibited formulation of urea on the efficiency of fall-banded N fertilizer under Manitoba conditions. To date, no studies have investigated how these factors interact to influence the efficiency of fall-banded N in western Canada. The effects of landscape position were apparent at three of the four sites, with significantly greater grain yields, straw yields and total recovery of N in the high landscape positions than in the low landscape positions. In the high landscape positions, there were no significant differences in crop response or recovered N among application dates in the fall and spring. However, in the low landscape positions, grain yields, grain yield increases and apparent recovered fertilizer N in the aboveground portion of the crop and in the soil (0–120 cm) were significantly greater for spring and late fall applications, when compared with early and mid-fall applications. At one site in the first year of the study, early fall-banded N with the urease and nitrification inhibitors produced greater increases in grain yield than early fall-banded N without the inhibitors in the low landscape positions. However, overall there was little agronomic benefit to the use of the additives, as there were few significant differences in crop yields or N uptake by the crop with the inhibitors than without, in either year or landscape position. The results demonstrate that selection of suitable timing for application of fertilizer N to optimize crop yields is much more critical for poorly drained areas within a field, or for poorly drained fields, than for better drained land. Key words: Fall-banded N, spring-banded N, landscape position, N-(n-butyl) thiophosphoric triamide (NBPT), Dicyandiamide (DCD), wheat (Triticum aestivum)

Description: Volumetric water content (θv) was estimated from time domain reflectometry (TDR) measurementsof apparent dielectric permittivity (Ka) in an organic soil (Humisol). The goals of this study were: (i) to test the accuracy of existing θv-Ka relationships in this soil and if found insufficient (ii) to develop alternative θv-Ka relationships for this organic soil. The Ka values were measured over a wide range of θv in intact soil cores taken from three horizons (Ohp, Of, Oco). Empirical θv-Ka relationships found in the literature for organic porous media could not accurately describe the θv-Ka relationships of any horizon of this Humisol, probably because of the its very large organic matter content (〉 75%) of this soil. New θv-Ka relationships for each horizon were consequently developed. Key words: Organic soil, TDR, coprogenic soil, volumetric water content, apparent dielectric permittivity

Description: A study was conducted to examine the effect of tillage on soil conditions and crop growth at three long-term (〉 10 yr) no-till sites, one in each of the Brown, Black, and Gray soil zones of Saskatchewan. The four tillage treatments consisted of one cycle of tillage at three levels of intensity: spring cultivation only, fall + spring cultivation, and fall + spring + disc cultivation, all applied to no-till and also a no-till control. Total and particulate soil organic carbon, soil pH, and soil aggregation were not affected by the tillage operations. Tillage decreased the bulk density in the 5- to 10-cm soil depth, but did not affect soil water content (0-10 cm) or spring soil temperature (0-5 cm). Tillage decreased stratification of available phosphorus to some extent, but there appeared to be no associated effect on crop P uptake. Tillage did not effect crop production in any of the 3 yr following its imposition, except at one site where, in the first year, apparent tillage-induced nutrient immobilization resulted in lower yields. Overall, the imposition of one cycle of tillage on long-term no-till soils appears to have little effect on soil properties or crop growth.Key words: No-till, nutrient stratification, soil organic carbon, tillage

Description: Ridge-tilled corn (Zea mays L.) could benefit from arbuscular mycorrhizal (AM) fungi. Under low soil disturbance, AM hyphal networks are preserved and can contribute to corn nutrition. A 2-yr study was conducted in the St. Lawrence Lowlands (Quebec, Canada) to test the effects of indigenous AM fungi on corn P nutrition, growth, and soil P in field cropped for 8 yr under ridge-tillage. Phosphorus treatments (0, 17, 35 kg P ha-1) were applied to AM-inhibited (AMI) (fungicide treated) and AM non-inhibited (AMNI) plots. Plant tissue and soil were sampled 22, 48 and 72 days after seeding (DAS). P dynamics was monitored in situ with anionic exchange membranes (PAEM) from seeding to the end of July. AMNI plants showed extensive AM colonization at all P rates. At 22 DAS, AMI plants had decreased growth in the absence of P inputs, while AMNI plants had higher dry mass (DM) and P uptake in unfertilized plots. The PAEM was lower in the AMNI unfertilized soils in 1998 and at all P rates in 1999, indicating an inverse relationship between P uptake and PAEM. At harvest, grain P content of AMNI plants was greater than that of AMI plants. In 1998, only AMI plants had decreased yield in the absence of P fertilization. In 1999, AMNI plants produced greater grain yield than AMI plants at all P rates. AM fungi improve the exploitation of soil P by corn thereby maintaining high yields while reducing crop reliance on P inputs in RT. Key words: Arbuscular mycorrhizae, ridge-tillage, soil P dynamics, corn, P nutrition

Description: The effect of 10, 15, 20 and 25 °C soil temperatures on the extractability of soil and fertilizer phosphorus (P) was examined in two soils, one containing free carbonate (pH 7.8) and the other non-carbonated (pH 6.9). The time course of fixation and desorption reactions were monitored. The extractability of P was also assessed using sodium bicarbonate (NaHCO3) extractions, desorption curves, and short-term uptake by wheat seedlings. Phosphorus-32 was used throughout. Opposing effects of temperature were found. An increase in incubation temperature from 10 to 25 °C decreased the amount of applied P extracted probably due to accelerated fixation reactions. This effect was established 1 day after the P was applied and persisted for 57 days. An increase in extraction temperature over the corresponding incubation temperature increased the extractability of P, indicating endothermic desorption reactions. This effect was established 1 h after the extraction began and persisted for 48 h. Hence, the net effect of temperature on the extractability of P will depend upon the balance of these opposing processes. The time course of these processes had two phases. The effects of temperature were established during the initial phase (

Description: The sensitivity of soil organic matter decomposition to temperature change is critical tothe global carbon balance and to whether soils will respond with positive feedback to climate change. Forest cover determines litter composition, which controls to a large extent soil organic matter quality and its sensitivity to temperature. The effect of temperature on soil organic matter decomposition was studied along a latitudinal gradient encompassing sugar maple, balsam fir and black spruce forest types. Long-term laboratory soil incubations conducted at four different temperatures were used to discriminate the effect of temperature from that of organic matter quality on decomposition rates. The specific C mineralization rate of the humus layer was highest for balsam fir sites, intermediate for one sugar maple site and lowest for black spruce sites and the other sugar maple site. However, considering the total C pools of the FH layer and of the top 20 cm of mineral soil, it was estimated that coniferous sites exhibit a higher C efflux than sugar maple soils at any given temperature. Estimated C mineralization rates in the field using the temperature records for each individual site showed the same trends despite cooler temperature regimes for the coniferous sites. The Q10 respiration rates of the humus layer of all sites increased as the temperature got warmer. A significant effect of temperature on the pool size of labile C in the mineral soil was detected for some sites suggesting a potential long-term loss of C upon warming. The low estimated C evolution rates of sugar maple soils were perhaps due to the greater decomposition activity within the L layer, before the litter C enters underlying soil pools. These observations suggest that coniferous soils are not more resistant than deciduous forests to increasing their specific rates of soil heterotrophic respiration upon warming. Key words: Soil organic carbon, forest type, forest composition, warming, long-term incubation, labile carbon

Description: The sustainability of organic dairying in Canada, with respect to nutrients, remains unexamined. To assess how management affects nutrient status, we documented whole farm nutrient (NPK) budgets over 2 yr (2003 to 2005) and soil (0 to 15 cm) P and K status on 15 long-term Ontario organic dairy farms. Farm size, livestock density and herd productivity averaged 110 ha, 1.00 livestock units ha-1 and 5656 kg milk cow-1 yr-1, respectively. Annual farm nutrient surpluses of 75 (N), 1 (P) and 11 (K) kg ha-1 yr-1 were lower than those reported for confinement-based dairy farms in the United States, pointing to possible environmental benefits from reduced off farm impacts on air and water quality. Weighted average soil test P levels were low (〈 10 mg kg-1) on approximately 50% of farms, while exchangeable K levels were moderate to high (76 to 160 mg kg-1) on all farms. Four farms adopting a "self-sufficient" approach, producing most feed on-farm, imported little P as feed (1.37 to 1.90 kg P ha-1 yr-1) and had negative average farm P balances (avg. -1.54 kg P ha-1 yr-1). An integrated nutrient management approach, along with a flexible feed import strategy, fosters the sustainability of organic dairying systems. Key words: Organic dairying, nutrient budget, nitrogen, potassium, phosphorus, soil fertility

Description: Functional relationships between soil water content and water suction were examined and related to textural and organic carbon content data. Soil water retention curves between 5 and 10 000 kPa were determined on disturbed samples of 18 soils representing various soil Great Groups in the Canadian prairies. The best fit was obtained with a two-straight-line regression model. Correlation and regression analysis showed that texture was the main soil property influencing the shape and position of the water retention curve. Organic matter influenced primarily the water content at which a break in the curve occurred. Soil zone and cultivation history had little effect on water retention. Key words: Water retention, texture, organic matter, two-straight-line regression

Description: Field investigations between 1970 and 1980 revealed frequent carry-over residues of atrazine (2-chloro-4-ethylamino-6-isopropylamino-s-triazine) and its major metabolite, N-de-ethyl atrazine (2-chloro-4-amino-6-isopropylamino-s-triazine) in soils and many were associated with visible crop damage. Susceptible crops in rotation with corn appeared to tolerate a carry-over of 0.1 mg/kg Σ-atrazine (atrazine plus metabolite) under field conditions. Where the carry-over residues were above 0.1 mg/kg the severity of injury appeared to be related to the amount of residue, the soil type, the crop species, and the weather conditions. A growth cabinet experiment was designed to study the response of five susceptible crop species to simulated carry-over levels of atrazine between 0.05 and 0.70 mg/kg active ingredient added to a sandy loam, a loam and an organic loam soil, that contained 1.0, 3.5 and 10% organic matter (OM), respectively. Additions of as little as 0.10 mg/kg atrazine to soils with 1.0 and 3.5% OM caused visible injury to develop on the foliage of all five crop species. Alfalfa (Medicago sativa L.) appeared to be the most sensitive crop species, being affected by atrazine at 0.05 mg/kg. On soils with 10% OM the phytotoxic effects of atrazine were considerably reduced and all five crops tolerated residue levels up to 0.70 mg/kg without serious injury. Key words: Atrazine, N-de-ethyl atrazine, residue, crops, field, growth chamber

Description: Soil N supply is an important contributor of N to crop production; however, there is a lack of practical methods for routine estimation of soil N supply under field conditions. This study evaluated sampling just prior to topkill of whole potato plants that received no fertilizer N as a field bioassay of soil N supply. Three experiments were performed. In exp. 1, field trials were conducted to test if P and K fertilization, with no N fertilization, influenced plant biomass and N accumulation at topkill. In exp. 2, plant N accumulation at topkill in unfertilized plots was compared with mineral N accumulation in vegetation-free plots. In exp. 3, estimates of soil N supply were obtained from 56 sites from 1999 to 2003 using a survey approach where plant N accumulation at topkill, and soil mineral N content to 30-cm depth at planting and at tuber harvest were measured. Application of P and K fertilizer had no significant effect on plant N accumulation in two trials, and resulted in a small increase in plant N accumulation in a third trial. Zero fertilizer plots, which can be more readily established in commercial potato fields, can therefore be used instead of zero fertilizer N plots to estimate soil N supply. In exp. 2, estimates of soil N supply were generally comparable between plant N accumulation at topkill and maximum soil NO3-N accumulation in vegetation-free plots; therefore, the plant bioassay approach is a valid means of estimation of plant available soil N supply. Plant N accumulation at topkill in exp. 3 averaged 86 kg N ha-1, and ranged from 26 to 162 kg N ha-1. Plant N accumulation was higher for sites with a preceding forage crop compared with a preceding cereal or potato crop. Plant N accumulation was generally higher in years with warmer growing season temperatures. Soil NO3-N content at harvest in exp. 3 was less than 20 kg N ha-1, indicating that residual soil mineral N content was low at the time of plant N accumulation measurement. Soil NO3-N content at planting was generally small relative to plant N accumulation, indicating that soil N supply in this region is controlled primarily by growing season soil N mineralization. Use of a plant bioassay approach provides a practical means to quantify climate, soil and management effects on plant available soil N supply in potato production. Key words: Solanum tuberosum, nitrate, ammonium, N mineralization, plant N accumulation

Description: Cutans that coat and link sand grains in cemented podzolic B horizons (ortstein) of well and poorly drained podzolic soils from Nova Scotia and New Brunswick were described in thin sections and analyzed by energy dispersive spectrometry (EDS). The principal type of cutan was brown and weakly to moderately anisotropic; it included numerous silt and fine sand grains. X-ray spectra showed this type to be composed dominantly of Al and Si with lesser amounts of K and Fe, and minor amounts of P, S, and other elements. The silt and clay particles of these cutans were apparently impregnated with Al, Fe-organic complexes. Another common type of cutan was dark reddish brown, monomorphic and isotropic; it consisted mainly of Al and organic matter as indicated by dominant Al and weak P and S peaks. In a few samples such cutans were composed mainly of Fe and organic matter. Rarer black cutans contained Mn in various proportions. The dominant cementing material of these ortstein horizons was shown to be organic complexes of Al and, less commonly, of Fe. The genesis of soils with ortstein is discussed.

Description: International initiatives such as the United Nations Framework Convention on Climate Change and the Kyoto Protocol require that countries calculate national inventories of their greenhouse gas emissions. The objective of the present study was to develop a country-specific (Tier II) methodology to calculate the inventory of N2O emissions from agricultural soils in Canada. Regional fertilizer-induced emission factors (EFreg) were first determined using available field experimental data. Values for EFreg were 0.0016 kg N2O-N kg-1 N in the semi-arid Brown and 0.008 kg N2O-N kg N-1 in the sub-humid Black soil zones of the Prairie region, and 0.017 kg N2O-N kg-1 N in the humid provinces of Quebec and Ontario. A function relating EFreg to the "precipitation to potential evapotranspiration" ratio was determined to estimate annual emission factors (EFeco) at the ecodistrict scale (≈ 150 000 ha) in all agricultural regions of Canada. Country-specific coefficients were also developed to account for the effect of several additional factors on soil N2O emissions. Emissions from fine-textured soils were estimated as being 50% greater than from coarse- and medium-textured soils in eastern Canada; emissions during winter and spring thaw corresponded to 40% of emissions during the snow-free season in eastern Canada; increased emissions from lower (wetter) sections of the landscape and irrigated areas were accounted for; emissions from no-till soils were 10% greater in eastern, but 20% lower in western Canada than from those under conventional tillage practices; emissions under summerfallow were estimated as being equal to those from soils under annual cropping. This country-specific methodology therefore accounts for regional climatic and land use impacts on N2O emission factors, and includes several sources/offsets that are not included in the Intergovernmental Panel on Climate Change (IPCC) default approach. Key words: Nitrous oxide, soils, greenhouse gases, inventory

Description: Forest landings are areas located adjacent to haul roads where harvested trees that were skidded from the cutblock are processed and loaded onto trucks. Soils on landings are often excessively compacted by heavy timber harvesting machinery and may take many years to recover from such disturbance. This study examined soil properties and tree growth on unrehabilitated landings (with and without natural regeneration) and adjacent naturally regenerated clearcuts in the central interior of British Columbia (BC), 23 yr after landing construction. Landings (both with and without natural regeneration) had less favorable conditions for tree growth than did clearcuts, including significantly greater surface soil bulk density and mechanical resistance (on some dates) and lower total porosity and concentrations of C and N. Landings without natural regeneration had the least favorable soil conditions, which may account for the lack of natural regeneration. Lodgepole pine (Pinus contorta Dougl. ex Loud. var. latifolia Engelm.) growing on portions of the landings did not differ in height from those growing in adjacent clearcuts. Site index, as estimated using the growth intercept method, did not differ between naturally regenerated landings (21.7 m) and clearcuts (22.0 m), suggesting that the soils may be equally capable of supporting productive forests. Key words: Forest soil disturbance, soil mechanical resistance, soil productivity, soil water content, natural regeneration

Description: Growth chamber and field studies were conducted to assess the relative utilization of placed and broadcast 15N-urea by spring wheat. The field studies were conducted on zero and conventional (shallow) tillage systems, of 4-yr duration, located on Chernozemic soils at two locations in Saskatchewan. Placement below the seeding depth in comparison to broadcast application, generally reduced fertilizer N immobilization and increased fertilizer N uptake, recovery, and efficiency. Under moisture stress, placed applications were effective in enhancing dry matter yield and total N uptake. It is concluded that fertilizer N placement for these two contrasting tillage systems should be identical, thus some soil disturbance under zero tillage may be necessary to achieve optimum crop use of applied fertilizer N. The dominant N transformation processes and possible tillage induced differences, in regard to methods of N application, are discussed. Key words: Placed and broadcast N application, N efficiency, N utilization, 15N-urea, zero tillage, soil moisture

Description: The forest floor of a mature, naturally regenerated conifer stand on a well-drained podzolic soil in the Central Uplands of New Brunswick was sampled systematically. The forest-floor properties measured were: oven-dried mass per unit area, depth, moisture content, pH, potassium-chloride-extractable NH4-N and NO3-N, water-soluble phosphate, and ammonium-acetate-extractable K, Mg, and Ca. Total elemental C, N, P, K, Mg, Ca, Al, Fe concentrations were also determined. Coefficients of variation varied from 0.066 (total C) to 1.78 (2 N KCl-extractable NO3-N). Concentrations (measured in ppm or percent) were in each case less variable than absolute amounts (measured in kilograms per hectare). Frequency distributions were positively skewed (except for total C and N) and appeared to follow a gamma or Weibull distribution pattern. Key words: Ferro-Humic-Podzol, forest floor, lateral variability, spruce-fir forest, systematic sampling

Description: Regulation of manure application in Manitoba has raised the question of whether or not biosolids application should be regulated in the same way. This study examined the effects of biosolids (BIO) applications on P sorption characteristics of a Vertisol in comparison with dairy cattle (DAIRY) and hog (HOG) manures, and monoammonium phosphate (MAP) fertilizer using the classical sorption isotherm and single point sorption index. Pertinent chemical properties and degree of P saturation (DPS) were also determined. The sorption maximum (Smax) in the control was reduced from 655 mg kg-1, to a range of 536–655 mg kg-1 with BIO, 559–650 mg kg-1 with MAP, 402–568 mg kg-1 with DAIRY, and 350–587 mg kg-1 with HOG depending upon the rate of P added. The lower DPS in the soil amended with BIO suggests a lower risk of P loss with biosolids compared with manures. The higher P sorption capacity of biosolids-amended soils compared with soils amended with manures suggest that Ca added with BIO increased the number of P sorption sites by a similar proportion to the amount of P added. Key words: Biosolids, P sorption isotherm, degree of P saturation, labile P, non-labile P

Description: A descriptive system is outlined for characterizing, in thin sections, the micromorphology of organic soils and organic layers. In each thin section, distinct regions of morphology, fabric zones, can be recognized. Each fabric zone may be composed of various combinations of organic constituents. These constituents are designated as basic morphologic units and four main types are defined: particulate material, granular units, discrete compound particles, and massive-appearing fabric. The fabric zone and basic morphologic units can be coded in a fabric description symbol of the following simple general form [Fabric Unit]1 …[Fabric Unit]n, where [Fabric Unit] represents a particular fabric zone and its basic morphologic units. For example, [PpGa] [Ma] is a fabric description symbol indicating that two fabric zones are identified in the thin section. The first [PpBa] is the dominant fabric zone in the thin section (areal proportion) and is composed of two basic morphologic units, mainly recognizable plant fragments, Pp, and a lesser occurrence of amorphous granular material, Ga. The second fabric unit [Ma] indicates a fabric zone composed of one basic morphologic unit: amorphous massive-appearing fabric, Ma. The system is applied to the micromorphological characterization of a Typic Mesisol from Keswick, Ontario. Key words: Microcorphology, organic soils, descriptive method, characterization

Description: Forested peatlands store significant amounts of soil carbon (C) compared with upland forests and are strongly influenced by climatic parameters. Carbon stocks at peatland margins, although likely to be most sensitive to changes in climate, have not been well quantified, making it difficult to predict their response to climate change. The purpose of this study was to characterize the physical environment and associated changes in C stocks across the forested margins of two boreal fens. Peat depth increased and water table depth decreased toward the peatland centre, and these parameters acted as the controlling environmental variables. Above-ground biomass C was primarily derived from tree biomass and decreased from upland to peatland, despite an opposite trend in understorey (herbaceous and shrubby) biomass stocks. Leaf area index was related to peat depth through a negative power function and increased linearly with above-ground tree biomass. Total ecosystem C increased from upland to peatland, with minimum and maximum values of 270 and 2100 Mg C ha-1, respectively, and was largely dominated by soil C stocks, even at the upland end of the gradient. Although numerous small trees toward the peatland interior might allow a rapid increase in tree biomass C with lowering water tables, it seems likely that this would be a limited response, overshadowed in the long term by declines in the more substantial soil C stocks. Key words: Peatlands, carbon stocks, biomass, soil, leaf area index, peat depth

Description: Conservation tillage (CT) for potato crop land has been increasing in Atlantic Canada, but producers are concerned that fields managed in this way may be wet, slow to warm in spring, have increased debris at harvest, exhibit higher soil compaction and result in reduced yield. The objective of this study was to compare the effects of four tillage practices on potato yield, soil properties and weed growth over a 3-yr period. The four tillage practices were: (1 ) conventional autumn mouldboard plowing followed by spring secondary tillage; (2) spring mouldboard plowing followed by secondary tillage; (3) autumn chisel plowing followed by spring secondary tillage; and (4) spring CT. Tillage practices significantly affected soil water content (at both the 0- to 15-cm and 15- to 30-cm soil depths) with CT generally showing a greater soil water content prior to spring tillage in comparison to the other treatments. Soil temperature (at the 2- to 5-cm soil depth) prior to spring tillage was not influenced by tillage differences. Conservation tillage increased soil compaction at the 10- to 30-cm soil depth, but not to a level considered detrimental to root growth. Tillage treatments had no effect on amount of soil clods and plant debris passing over the harvester. Potato yield (range of 43 to 51 Mg ha-1) and quality were not adversely influenced by tillage practices. There were few treatment effects on individual weed species or groupings of annual, perennial and total weeds. Overall, CT can be a viable management alternative to conventional tillage because this practice does not negatively affect field management, potato yield, or soil quality. Key words: Conservation tillage, residue management, potato, soil temperature, soil moisture, tillage methods

Description: Water loss from soil minerals has been known to cause errors in the determination of soil organic matter when the loss on ignition (LOI) method is used. Unfortunately, no known published studies reliably quantify the range of structural water in the soil. To do this, 15 common reference minerals were analyzed by LOI to obtain their individual water loss. In addition, 14 upland, loamy soil samples and 3 wetland/hydric soil samples with varied mineral contents were analyzed to collect their X-ray powder diffraction spectra. Based upon X-ray spectra peak intensities, the modal abundance of minerals in each soil sample was determined using the RockJock computer program. The resultant modal weight percentages of all identified minerals in each soil sample were then multiplied by the LOI value for each mineral to obtain the mineral structural water loss (SWL) of that soil sample. For the 17 soil samples analyzed, the range of mineral water loss is 0.56 to 2.45%. Depending on the LOI values of the soil samples, the SWL:LOI ratios range from 0.04 to around 1.00. The SWL:LOI ratios are particularly low for top wetland soil when the LOI value is higher. The ratios are lower for surface soil samples than for subsurface soil samples because of the high LOI values in surface soil samples. Understanding soil mineral water loss and its relation to the LOI patterns from various environments is important for the accurate evaluation of soil organic matter when the LOI method is used. Key words: Mineral, structural water, loss on ignition

Description: Modelling soil organic carbon (SOC) stock changes in agroecosystems can be performed with different approaches depending on objectives and available data. Our objective in this paper is to describe a scheme for developing a dynamic SOC algorithm for calculating net greenhouse gas emissions from Canadian farms as a function of management and local conditions. Our approach is flexible and emphasizes ease of use and the integration of available knowledge. Using this approach, we assessed the performance of several SOC models having two or more compartments for some common agroecosystems in Canada. Analysis of long-term data for conventional management practices at different sites (n = 36) in Canada, including recent model applications in the literature on some of those data, indicated that the results obtained with two-compartment models, such as the Introductory Carbon Balance Model (ICBM) and Modified Woodruff Model (MWM), yielded results comparable to those of a multi-compartment model (CENTURY). The analysis also showed that a model such as ICBM need stuning to be applied to management and conditions across Canada. Two-compartment models programmable in a simple spreadsheet format, though they may not supplant more complex models in allapplications, offer advantages of simplicity and transparency in whole-farm analyses of greenhouse gas emissions. Key words: Virtual Farm, soil organic carbon, soil disturbance, C inputs, Introductory Carbon Balance Model (ICBM), CENTURY, Modified Woodruff Model (MWM).

Description: Agroclimatic indices (heat units and water deficits) were determined for the Atlantic region of Canada for a baseline climate (1961 to 1990 period) and for two future time periods (2010 to 2039 and 2040 to 2069). Climate scenarios for the future periods were primarily based on outputs from the Canadian General Circulation Model (GCM) that included the effects of aerosols (CGCMI-A), but variability introduced by multiple GCM experiments was also examined. Climatic data for all three periods were interpolated to a grid of about 10 to 15 km. Agroclimatic indices were computed and mapped based on the gridded data. Based on CGCMI-A scenarios interpolated to the fine grid, average crop heat units (CHU) would increase by 300 to 500 CHU for the 2010 to 2039 period and by 500 to 700 CHU for the 2040 to 2069 period in the main agricultural areas of the Atlantic region. However, increases in CHU for the 2040 to 2069 period typically varied from 450 to 1650 units in these regions when variability among GCM experiments was considered, resulting in a projected range of 2650 to 4000 available CHU. Effective growing degree-days above 5°C (EGDD) typically increased by about 400 units for the 2040 to 2069 period in the main agricultural areas, resulting in available EGDD from 1800 to over 2000 units. Uncertainty introduced by multiple GCMs increased the range from 1700 to 2700 EGDD. A decrease in heat units (cooling) is anticipated along part of the coast of Labrador. Anticipated changes in water deficits (DEFICIT), defined as the amount by which potential evapotranspiration exceeded precipitation over the growing season, typically ranged from +50 to −50 mm for both periods, but this range widened from +50 to −100 mm when variability among GCM experiments was considered. The greatest increases in deficits were expected in the central region of New Brunswick for the 2040 to 2069 period. Our interpolation procedures estimated mean winter and summer temperature changes that were 1.4°C on average lower than a statistical downscaling procedure (SDSM) for four locations. Increases in precipitation during summer and autumn averaged 20% less than SDSM. During periods when SDSM estimated relatively small changes in temperature or precipitation, our interpolation procedure tended to produce changes that were larger than SDSM. Additional investigations would be beneficial that explore the impact of a range of scenarios from other GCM models, other downscaling methods and the potential effects of change in climate variability on these agroclimatic indices. Potential impacts of these changes on crop yields and production in the region also need to be explored. Key words: Crop heat units, effective growing degree-days, water deficits, climate change scenarios, statistical downscaling, spatial interpolation