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  • Institute of Physics  (377,302)
  • American Institute of Physics (AIP)  (77,901)
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  • 1
    Publication Date: 2020-09-07
    Description: This study presents and discusses horizontal and vertical geodetic velocities for a low strain rate region of the south Alpine thrust front in northeastern Italy obtained by integrating GPS, interferometric synthetic aperture radar (InSAR) and leveling data. The area is characterized by the presence of subparallel, south-verging thrusts whose seismogenic potential is still poorly known. Horizontal GPS velocities show that this sector of the eastern Southern Alps is undergoing ∼1 mm a−1 of NW–SE shortening associated with the Adria–Eurasia plate convergence, but the horizontal GPS velocity gradient across the mountain front provides limited constraints on the geometry and slip rate of the several subparallel thrusts. In terms of vertical velocities, the three geodetic methods provide consistent results showing a positive velocity gradient, of ∼ 1.5 mm a−1, across the mountain front, which can hardly be explained solely by isostatic processes. We developed an interseismic dislocation model whose geometry is constrained by available subsurface geological reconstructions and instrumental seismicity. While a fraction of the measured uplift can be attributed to glacial and erosional isostatic processes, our results suggest that interseismic strain accumulation at the Montello and the Bassano–Valdobbiadene thrusts it significantly contributing to the measured uplift. The seismogenic potential of the Montello thrust turns out to be smaller than that of the Bassano–Valdobbiadene fault, whose estimated parameters (locking depth equals 9.1 km and slip rate equals 2.1 mm a−1) indicate a structure capable of potentially generating a Mw〉6.5 earthquake. These results demonstrate the importance of precise vertical ground velocity data for modeling interseismic strain accumulation in slowly deforming regions where seismological and geomorphological evidence of active tectonics is often scarce or not conclusive.
    Description: Published
    Description: 1681–1698
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Southern Alps ; Vertical Velocities ; GPS and InSAR integration ; Interseismic Deformation ; Dislocation Model ; Seismic Potential ; 04.03. Geodesy ; 04.07. Tectonophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2021-06-07
    Description: The diagnosis of the conservation state of monumental structures from constraints to the spatial distribution of their physical properties on shallow and inner materials represents one of the key objectives in the application of non-invasive techniques. In situ, CRP and 3D ultrasonic tomography can provide an effective coverage of stone materials in space and time. The intrinsic characteristics of the materials that make up a monumental structure and affect the two properties (i.e., reflectivity, longitudinal velocity) through the above methods substantially differ. Consequently, the content of their information is mainly complementary rather than redundant. In this study we present the integrated application of different non-destructive techniques i.e., Close Range Photogrammetry (CRP), and low frequency (24 KHz) ultrasonic tomography complemented by petrographycal analysis based essentially on Optical Microscopy (OM). This integrated methodology has been applied to a Carrara marble column of the Basilica of San Saturnino, in Byzantine-Proto-Romanesque style, which is part of the Paleo Christian complex of the V-VI century. This complex also includes the adjacent Christian necropolis in the square of San Cosimo in the city of Cagliari, Sardinia, Italy. The column under study is made of bare material dating back probably to the first century A.D., it was subjected to various traumas due to disassembly and transport to the site, including damage caused by the close blast of a WWII fragmentation bomb. High resolution 3D modelling of the studied artifact was computed starting from the integration of proximal sensing techniques such as CRP based on Structure from Motion (SfM), with which information about the geometrical anomalies and reflectivity of the investigated marble column surface was obtained. On the other hand, the inner parts of the studied body were successfully inspected in a non-invasive way by computing the velocity pattern of the ultrasonic signal through the investigated materials using 3D ultrasonic tomography. This technique gives information on the elastic properties of the material related with mechanical properties and a number of factors, such as presence of fractures, voids, and flaws. Extracting information on such factors from the elastic wave velocity using 3D tomography provides a non-invasive approach to analyse the property changes of the inner material of the ancient column. The integrated application of in situ CRP and ultrasonic techniques provides a full 3D high resolution model of the investigated artifact. This model enhanced by the knowledge of the petrographic characteristics of the materials, improves the diagnostic process and affords reliable information on the state of conservation of the materials used in the construction processes of the studied monumental structure. The integrated use of the non-destructive techniques described above also provides suitable data for a possible restoration and future preservation.
    Description: Copernicus
    Description: Published
    Description: On line
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Keywords: Cultural Heritage ; Monumental Structures ; Non-Destructive Testing ; Close Range Photogrammetry ; 3D Ultrasonic Tomography ; High resolution 3D modelling ; Restoration ; Conservation ; 05.04. Instrumentation and techniques of general interest
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Abstract
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  • 3
    Publication Date: 2020-08-10
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev , info:eu-repo/semantics/article
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  • 4
    Publication Date: 2021-02-16
    Description: A range of future climate scenarios are projected for high atmospheric CO2 concentrations, given uncertainties over future human actions as well as potential environmental and climatic feedbacks. The geological record offers an opportunity to understand climate system response to a range of forcings and feedbacks which operate over multiple temporal and spatial scales. Here, we examine a single interglacial during the late Pliocene (KM5c, ca. 3.205±0.01 Ma) when atmospheric CO2 exceeded pre-industrial concentrations, but were similar to today and to the lowest emission scenarios for this century. As orbital forcing and continental configurations were almost identical to today, we are able to focus on equilibrium climate system response to modern and near-future CO2. Using proxy data from 32 sites, we demonstrate that global mean sea-surface temperatures were warmer than pre-industrial values, by ∼2.3°C for the combined proxy data (foraminifera Mg∕Ca and alkenones), or by ∼3.2–3.4°C (alkenones only). Compared to the pre-industrial period, reduced meridional gradients and enhanced warming in the North Atlantic are consistently reconstructed. There is broad agreement between data and models at the global scale, with regional differences reflecting ocean circulation and/or proxy signals. An uneven distribution of proxy data in time and space does, however, add uncertainty to our anomaly calculations. The reconstructed global mean sea-surface temperature anomaly for KM5c is warmer than all but three of the PlioMIP2 model outputs, and the reconstructed North Atlantic data tend to align with the warmest KM5c model values. Our results demonstrate that even under low-CO2 emission scenarios, surface ocean warming may be expected to exceed model projections and will be accentuated in the higher latitudes.
    Repository Name: EPIC Alfred Wegener Institut
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  • 5
    Publication Date: 2020-09-28
    Description: Reconstructions of global hydroclimate during the Common Era (CE; the past ∼2000 years) are important for providing context for current and future global environmental change. Stable isotope ratios in water are quantitative indicators of hydroclimate on regional to global scales, and these signals are encoded in a wide range of natural geologic archives. Here we present the Iso2k database, a global compilation of previously published datasets from a variety of natural archives that record the stable oxygen (δ18O) or hydrogen (δ2H) isotopic compositions of environmental waters, which reflect hydroclimate changes over the CE. The Iso2k database contains 759 isotope records from the terrestrial and marine realms, including glacier and ground ice (210); speleothems (68); corals, sclerosponges, and mollusks (143); wood (81); lake sediments and other terrestrial sediments (e.g., loess) (158); and marine sediments (99). Individual datasets have temporal resolutions ranging from sub-annual to centennial and include chronological data where available. A fundamental feature of the database is its comprehensive metadata, which will assist both experts and nonexperts in the interpretation of each record and in data synthesis. Key metadata fields have standardized vocabularies to facilitate comparisons across diverse archives and with climate-model-simulated fields. This is the first global-scale collection of water isotope proxy records from multiple types of geological and biological archives. It is suitable for evaluating hydroclimate processes through time and space using large-scale synthesis, model–data intercomparison and (paleo)data assimilation. The Iso2k database is available for download at https://doi.org/10.25921/57j8-vs18 (Konecky and McKay, 2020) and is also accessible via the NOAA/WDS Paleo Data landing page: https://www.ncdc.noaa.gov/paleo/study/29593 (last access: 30 July 2020).
    Repository Name: EPIC Alfred Wegener Institut
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  • 6
    Publication Date: 2021-07-23
    Description: Originating from the boreal forest and often transported over large distances, driftwood characterises many Arctic coastlines. Here we present a combined assessment of radiocarbon (14C) and dendrochronological (ring width) age estimates of driftwood samples to constrain the progradation of two Holocene beach-ridge systems near the Lena Delta in the Siberian Arctic (Laptev Sea). Our data show that the 14C ages obtained on syndepositional driftwood from beach deposits yield surprisingly coherent chronologies for the coastal evolution of the field sites. The dendrochronological analysis of wood from modern driftlines revealed the origin and recent delivery of the wood from the Lena River catchments. This finding suggests that the duration transport lies within the uncertainty of state-of-the-art 14C dating and thus substantiates the validity of age indication obtained from driftwood. This observation will help to better understand changes in similar coastal environments, and to improve our knowledge about the response of coastal systems to past climate and sea-level changes.
    Repository Name: EPIC Alfred Wegener Institut
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  • 7
    Publication Date: 2020-11-16
    Description: The Northeast Greenland Ice Stream (NEGIS) extends around 600 km upstream from the coast to its onset near the ice divide in interior Greenland. Several maps of surface velocity and topography of interior Greenland exist, but their accuracy is not well constrained by in situ observations. Here we present the results from a GPS mapping of surface velocity in an area located approximately 150 km from the ice divide near the East Greenland Ice-core Project (EastGRIP) deep-drilling site. A GPS strain net consisting of 63 poles was established and observed over the years 2015–2019. The strain net covers an area of 35 km by 40 km, including both shear margins. The ice flows with a uniform surface speed of approximately 55 m a^−1 within a central flow band with longitudinal and transverse strain rates on the order of 10−4 a^−1 and increasing by an order of magnitude in the shear margins. We compare the GPS results to the Arctic Digital Elevation Model and a list of satellite-derived surface velocity products in order to evaluate these products. For each velocity product, we determine the bias in and precision of the velocity compared to the GPS observations, as well as the smoothing of the velocity products needed to obtain optimal precision. The best products have a bias and a precision of ∼0.5 m a^−1. We combine the GPS results with satellite-derived products and show that organized patterns in flow and topography emerge in NEGIS when the surface velocity exceeds approximately 55 m a−1 and are related to bedrock topography.
    Repository Name: EPIC Alfred Wegener Institut
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  • 8
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    Copernicus
    In:  EPIC3Climate of the Past, Copernicus, 16(6), pp. 2275-2323, ISSN: 1814-9332
    Publication Date: 2021-07-01
    Description: We present the Alfred Wegener Institute's contribution to the Pliocene Model Intercomparison Project Phase 2 (PlioMIP2) wherein we employ the Community Earth System Models (COSMOS) that include a dynamic vegetation scheme. This work builds on our contribution to Phase 1 of the Pliocene Model Intercomparison Project (PlioMIP1) wherein we employed the same model without dynamic vegetation. Our input to the PlioMIP2 special issue of Climate of the Past is twofold. In an accompanying paper we compare results derived with COSMOS in the framework of PlioMIP2 and PlioMIP1. With this paper we present details of our contribution with COSMOS to PlioMIP2. We provide a description of the model and of methods employed to transfer reconstructed mid-Pliocene geography, as provided by the Pliocene Reconstruction and Synoptic Mapping Initiative Phase 4 (PRISM4), to model boundary conditions. We describe the spin-up procedure for creating the COSMOS PlioMIP2 simulation ensemble and present large-scale climate patterns of the COSMOS PlioMIP2 mid-Pliocene core simulation. Furthermore, we quantify the contribution of individual components of PRISM4 boundary conditions to characteristics of simulated mid-Pliocene climate and discuss implications for anthropogenic warming. When exposed to PRISM4 boundary conditions, COSMOS provides insight into a mid-Pliocene climate that is characterised by increased rainfall (+0.17 mm d−1) and elevated surface temperature (+3.37 ∘C) in comparison to the pre-industrial (PI). About two-thirds of the mid-Pliocene core temperature anomaly can be directly attributed to carbon dioxide that is elevated with respect to PI. The contribution of topography and ice sheets to mid-Pliocene warmth is much smaller in contrast – about one-quarter and one-eighth, respectively, and nonlinearities are negligible. The simulated mid-Pliocene climate comprises pronounced polar amplification, a reduced meridional temperature gradient, a northwards-shifted tropical rain belt, an Arctic Ocean that is nearly free of sea ice during boreal summer, and muted seasonality at Northern Hemisphere high latitudes. Simulated mid-Pliocene precipitation patterns are defined by both carbon dioxide and PRISM4 paleogeography. Our COSMOS simulations confirm long-standing characteristics of the mid-Pliocene Earth system, among these increased meridional volume transport in the Atlantic Ocean, an extended and intensified equatorial warm pool, and pronounced poleward expansion of vegetation cover. By means of a comparison of our results to a reconstruction of the sea surface temperature (SST) of the mid-Pliocene we find that COSMOS reproduces reconstructed SST best if exposed to a carbon dioxide concentration of 400 ppmv. In the Atlantic to Arctic Ocean the simulated mid-Pliocene core climate state is too cold in comparison to the SST reconstruction. The discord can be mitigated to some extent by increasing carbon dioxide that causes increased mismatch between the model and reconstruction in other regions.
    Repository Name: EPIC Alfred Wegener Institut
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  • 9
    Publication Date: 2021-01-04
    Repository Name: EPIC Alfred Wegener Institut
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  • 10
    Publication Date: 2021-07-05
    Description: Earth system and climate modelling involves the simulation of processes on a wide range of scales and within and across various compartments of the Earth system. In practice, component models are often developed independently by different research groups, adapted by others to their special interests and then combined using a dedicated coupling software. This procedure not only leads to a strongly growing number of available versions of model components and coupled setups but also to model- and high-performance computing (HPC)-system-dependent ways of obtaining, configuring, building and operating them. Therefore, implementing these Earth system models (ESMs) can be challenging and extremely time consuming, especially for less experienced modellers or scientists aiming to use different ESMs as in the case of intercomparison projects. To assist researchers and modellers by reducing avoidable complexity, we developed the ESM-Tools software, which provides a standard way for downloading, configuring, compiling, running and monitoring different models on a variety of HPC systems. It should be noted that ESM-Tools is not a coupling software itself but a workflow and infrastructure management tool to provide access to increase usability of already existing components and coupled setups. As coupled ESMs are technically the more challenging tasks, we will focus on coupled setups, always implying that stand-alone models can benefit in the same way. With ESM-Tools, the user is only required to provide a short script consisting of only the experiment-specific definitions, while the software executes all the phases of a simulation in the correct order. The software, which is well documented and easy to install and use, currently supports four ocean models, three atmosphere models, two biogeochemistry models, an ice sheet model, an isostatic adjustment model, a hydrology model and a land-surface model. Compared to previous versions, ESM-Tools has lately been entirely recoded in a high-level programming language (Python) and provides researchers with an even more user-friendly interface for Earth system modelling. ESM-Tools was developed within the framework of the Advanced Earth System Model Capacity project, supported by the Helmholtz Association.
    Repository Name: EPIC Alfred Wegener Institut
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  • 11
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    Copernicus
    In:  EPIC3Climate of the Past, Copernicus, 16(4), pp. 1643-1665, ISSN: 1814-9332
    Publication Date: 2021-02-16
    Description: We compare results obtained from modeling the mid-Pliocene warm period using the Community Earth System Models (COSMOS, version: COSMOS-landveg r2413, 2009) with the two different modeling methodologies and sets of boundary conditions prescribed for the two phases of the Pliocene Model Intercomparison Project (PlioMIP), tagged PlioMIP1 and PlioMIP2. Here, we bridge the gap between our contributions to PlioMIP1 (Stepanek and Lohmann, 2012) and PlioMIP2 (Stepanek et al., 2020). We highlight some of the effects that differences in the chosen mid-Pliocene model setup (PlioMIP2 vs. PlioMIP1) have on the climate state as derived with COSMOS, as this information will be valuable in the framework of the model–model and model–data comparison within PlioMIP2. We evaluate the model sensitivity to improved mid-Pliocene boundary conditions using PlioMIP's core mid-Pliocene experiments for PlioMIP1 and PlioMIP2 and present further simulations in which we test model sensitivity to variations in paleogeography, orbit, and the concentration of CO2. Firstly, we highlight major changes in boundary conditions from PlioMIP1 to PlioMIP2 and also the challenges recorded from the initial effort. The results derived from our simulations show that COSMOS simulates a mid-Pliocene climate state that is 0.29°C colder in PlioMIP2 if compared to PlioMIP1 (17.82°C in PlioMIP1, 17.53°C in PlioMIP2; values based on simulated surface skin temperature). On the one hand, high-latitude warming, which is supported by proxy evidence of the mid-Pliocene, is underestimated in simulations of both PlioMIP1 and PlioMIP2. On the other hand, spatial variations in surface air temperature (SAT), sea surface temperature (SST), and the distribution of sea ice suggest improvement of simulated SAT and SST in PlioMIP2 if employing the updated paleogeography. Our PlioMIP2 mid-Pliocene simulation produces warmer SSTs in the Arctic and North Atlantic Ocean than those derived from the respective PlioMIP1 climate state. The difference in prescribed CO2 accounts for 0.5°C of temperature difference in the Arctic, leading to an ice-free summer in the PlioMIP1 simulation, and a quasi ice-free summer in PlioMIP2. Beyond the official set of PlioMIP2 simulations, we present further simulations and analyses that sample the phase space of potential alternative orbital forcings that have acted during the Pliocene and may have impacted geological records. Employing orbital forcing, which differs from that proposed for PlioMIP2 (i.e., corresponding to pre-industrial conditions) but falls into the mid-Pliocene time period targeted in PlioMIP, leads to pronounced annual and seasonal temperature variations. Our result identifies the changes in mid-Pliocene paleogeography from PRISM3 to PRISM4 as the major driver of the mid-Pliocene warmth within PlioMIP and not the minor differences in forcings.
    Repository Name: EPIC Alfred Wegener Institut
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  • 12
    Publication Date: 2021-07-01
    Description: Palaeoclimate simulations improve our understanding of the climate, inform us about the performance of climate models in a different climate scenario, and help to identify robust features of the climate system. Here, we analyse Arctic warming in an ensemble of 16 simulations of the mid-Pliocene Warm Period (mPWP), derived from the Pliocene Model Intercomparison Project Phase 2 (PlioMIP2). The PlioMIP2 ensemble simulates Arctic (60–90 °N) annual mean surface air temperature (SAT) increases of 3.7 to 11.6 °C compared to the pre-industrial period, with a multi-model mean (MMM) increase of 7.2 °C. The Arctic warming amplification ratio relative to global SAT anomalies in the ensemble ranges from 1.8 to 3.1 (MMM is 2.3). Sea ice extent anomalies range from −3.0 to −10.4×106 km2, with a MMM anomaly of −5.6×106 km2, which constitutes a decrease of 53 % compared to the pre-industrial period. The majority (11 out of 16) of models simulate summer sea-ice-free conditions (≤1×106 km2) in their mPWP simulation. The ensemble tends to underestimate SAT in the Arctic when compared to available reconstructions, although the degree of underestimation varies strongly between the simulations. The simulations with the highest Arctic SAT anomalies tend to match the proxy dataset in its current form better. The ensemble shows some agreement with reconstructions of sea ice, particularly with regard to seasonal sea ice. Large uncertainties limit the confidence that can be placed in the findings and the compatibility of the different proxy datasets. We show that while reducing uncertainties in the reconstructions could decrease the SAT data–model discord substantially, further improvements are likely to be found in enhanced boundary conditions or model physics. Lastly, we compare the Arctic warming in the mPWP to projections of future Arctic warming and find that the PlioMIP2 ensemble simulates greater Arctic amplification than CMIP5 future climate simulations and an increase instead of a decrease in Atlantic Meridional Overturning Circulation (AMOC) strength compared to pre-industrial period. The results highlight the importance of slow feedbacks in equilibrium climate simulations, and that caution must be taken when using simulations of the mPWP as an analogue for future climate change.
    Repository Name: EPIC Alfred Wegener Institut
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  • 13
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    Copernicus
    In:  EPIC3The Cryosphere, Copernicus, 14(11), pp. 3843-3873, ISSN: 1994-0424
    Publication Date: 2020-11-11
    Description: Antarctic geothermal heat flow (GHF) affects the temperature of the ice sheet, determining its ability to slide and internally deform, as well as the behaviour of the continental crust. However, GHF remains poorly constrained, with few and sparse local, borehole-derived estimates and large discrepancies in the magnitude and distribution of existing continent-scale estimates from geophysical models. We review the methods to estimate GHF, discussing the strengths and limitations of each approach; compile borehole and probe-derived estimates from measured temperature profiles; and recommend the following future directions. (1) Obtain more borehole-derived estimates from the subglacial bedrock and englacial temperature profiles. (2) Estimate GHF from inverse glaciological modelling, constrained by evidence for basal melting and englacial temperatures (e.g. using microwave emissivity). (3) Revise geophysically derived GHF estimates using a combination of Curie depth, seismic, and thermal isostasy models. (4) Integrate in these geophysical approaches a more accurate model of the structure and distribution of heat production elements within the crust and considering heterogeneities in the underlying mantle. (5) Continue international interdisciplinary communication and data access.
    Repository Name: EPIC Alfred Wegener Institut
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  • 14
    Publication Date: 2020-12-07
    Description: Northwestern Alaska has been highly affected by changing climatic patterns with new temperature and precipitation maxima over the recent years. In particular, the Baldwin and northern Seward peninsulas are characterized by an abundance of thermokarst lakes that are highly dynamic and prone to lake drainage like many other regions at the southern margins of continuous permafrost. We used Sentinel-1 synthetic aperture radar (SAR) and Planet CubeSat optical remote sensing data to analyze recently observed widespread lake drainage. We then used synoptic weather data, climate model outputs and lake ice growth simulations to analyze potential drivers and future pathways of lake drainage in this region. Following the warmest and wettest winter on record in 2017/2018, 192 lakes were identified as having completely or partially drained by early summer 2018, which exceeded the average drainage rate by a factor of ∼ 10 and doubled the rates of the previous extreme lake drainage years of 2005 and 2006. The combination of abundant rain- and snowfall and extremely warm mean annual air temperatures (MAATs), close to 0 ∘C, may have led to the destabilization of permafrost around the lake margins. Rapid snow melt and high amounts of excess meltwater further promoted rapid lateral breaching at lake shores and consequently sudden drainage of some of the largest lakes of the study region that have likely persisted for millennia. We hypothesize that permafrost destabilization and lake drainage will accelerate and become the dominant drivers of landscape change in this region. Recent MAATs are already within the range of the predictions by the University of Alaska Fairbanks' Scenarios Network for Alaska and Arctic Planning (UAF SNAP) ensemble climate predictions in scenario RCP6.0 for 2100. With MAAT in 2019 just below 0 ∘C at the nearby Kotzebue, Alaska, climate station, permafrost aggradation in drained lake basins will become less likely after drainage, strongly decreasing the potential for freeze-locking carbon sequestered in lake sediments, signifying a prominent regime shift in ice-rich permafrost lowland regions.
    Repository Name: EPIC Alfred Wegener Institut
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  • 15
    Publication Date: 2020-07-08
    Description: The ESA Earth Explorer CryoSat-2 was launched on 8 April 2010 to monitor the precise changes in the thickness of terrestrial ice sheets and marine floating ice. To do that, CryoSat orbits the planet at an altitude of around 720 km with a retrograde orbit inclination of 92∘ and a quasi repeat cycle of 369 d (30 d subcycle). To reach the mission goals, the CryoSat products have to meet the highest quality standards to date, achieved through continual improvements of the operational processing chains. The new CryoSat Ice Baseline-D, in operation since 27 May 2019, represents a major processor upgrade with respect to the previous Ice Baseline-C. Over land ice the new Baseline-D provides better results with respect to the previous baseline when comparing the data to a reference elevation model over the Austfonna ice cap region, improving the ascending and descending crossover statistics from 1.9 to 0.1 m. The improved processing of the star tracker measurements implemented in Baseline-D has led to a reduction in the standard deviation of the point-to-point comparison with the previous star tracker processing method implemented in Baseline-C from 3.8 to 3.7 m. Over sea ice, Baseline-D improves the quality of the retrieved heights inside and at the boundaries of the synthetic aperture radar interferometric (SARIn or SIN) acquisition mask, removing the negative freeboard pattern which is beneficial not only for freeboard retrieval but also for any application that exploits the phase information from SARIn Level 1B (L1B) products. In addition, scatter comparisons with the Beaufort Gyre Exploration Project (BGEP; https://www.whoi.edu/beaufortgyre, last access: October 2019) and Operation IceBridge (OIB; Kurtz et al., 2013) in situ measurements confirm the improvements in the Baseline-D freeboard product quality. Relative to OIB, the Baseline-D freeboard mean bias is reduced by about 8 cm, which roughly corresponds to a 60 % decrease with respect to Baseline-C. The BGEP data indicate a similar tendency with a mean draft bias lowered from 0.85 to −0.14 m. For the two in situ datasets, the root mean square deviation (RMSD) is also well reduced from 14 to 11 cm for OIB and by a factor of 2 for the BGEP. Observations over inland waters show a slight increase in the percentage of good observations in Baseline-D, generally around 5 %–10 % for most lakes. This paper provides an overview of the new Level 1 and Level 2 (L2) CryoSat Ice Baseline-D evolutions and related data quality assessment, based on results obtained from analyzing the 6-month Baseline-D test dataset released to CryoSat expert users prior to the final transfer to operations.
    Repository Name: EPIC Alfred Wegener Institut
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  • 16
    Publication Date: 2020-08-10
    Description: The Global Ocean Data Analysis Project (GLODAP) is a synthesis effort providing regular compilations of surface to bottom ocean biogeochemical data, with an emphasis on seawater inorganic carbon chemistry and related variables determined through chemical analysis of water samples. GLODAPv2.2020 is an update of the previous version, GLODAPv2.2019. The major changes are: data from 106 more cruises added, extension of time coverage until 2019, and the inclusion of available discrete fugacity of CO2 (fCO2) values in the merged product files. GLODAPv2.2020 includes measurements from more than 1.2 million water samples from the global oceans collected on 946 cruises. The data for the 12 GLODAP core variables (salinity, oxygen, nitrate, silicate, phosphate, dissolved inorganic carbon, total alkalinity, pH, CFC-11, CFC-12, CFC-113, and CCl4) have undergone extensive quality control, especially systematic evaluation of bias. The data are available in two formats: (i) as submitted by the data originator but updated to WOCE exchange format and (ii) as a merged data product with adjustments applied to minimize bias. These adjustments were derived by comparing the data from the 106 new cruises with the data from the 840 quality-controlled cruises of the GLODAPv2.2019 data product. They correct for errors related to measurement, calibration, and data handling practices, while taking into account any known or likely time trends or variations in the variables evaluated. The compiled and adjusted data product is believed to be consistent to better than 0.005 in salinity, 1 % in oxygen, 2 % in nitrate, 2 % in silicate, 2 % in phosphate, 4 μmol kg−1 in dissolved inorganic carbon, 4 μmol kg−1 in total alkalinity, 0.01–0.02, depending on region, in pH, and 5 % in the halogenated transient tracers. The other variables included in the compilation, such as isotopic tracers and discrete fCO2 were not subjected to bias comparison or adjustments. The original data, their documentation and doi codes are available at the Ocean Carbon Data System of NOAA NCEI (https://www.nodc.noaa.gov/ocads/oceans/GLODAPv2_2020/, last access: 22 June 2020). This site also provides access to the merged data product, which is provided as a single global file and as four regional ones – the Arctic, Atlantic, Indian, and Pacific oceans – under https://doi.org/10.25921/2c8h-sa89 (Olsen et al., 2020). The bias corrected product files also include significant ancillary and approximated data. These were obtained by interpolation of, or calculation from, measured data. This living data update documents the GLODAPv2.2020 methods and provides a broad overview of the secondary quality control procedures and results.
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  • 17
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    Copernicus
    In:  EPIC3Geochemical evidence of a floating Arctic ice sheet and underlying freshwater in the Arctic Mediterranean in glacial periods, EGU General Assembly 2021, Copernicus, pp. EGU21-12910
    Publication Date: 2021-05-01
    Description: Numerous studies have addressed the possible existence of large floating ice sheets in the glacial Arctic Ocean from theoretical, modelling, or seafloor morphology perspectives. Here, we add evidence from the sediment record that support the existence of such freshwater ice caps in certain intervals, and we discuss their implications for possible non-linear and rapid behaviour of such a system in the high latitudes. We present sedimentary activities of 230Th together with 234U/238U ratios, the concentrations of manganese, sulphur and calcium in the context of lithological information and records of microfossils and their isotope composition. New analyses (PS51/038, PS72/396) and a re-analysis of existing marine sediment records (PS1533, PS1235, PS2185, PS2200, amongst others) in view of the naturally occurring radionuclide 230Thex and, where available, 10Be from the Arctic Ocean and the Nordic Seas reveal the widespread occurrence of intervals with a specific geochemical signature. The pattern of these parameters in a pan-Arctic view can best be explained when assuming the repeated presence of freshwater in frozen and liquid form across large parts of the Arctic Ocean and the Nordic Seas. Based on the sedimentary evidence and known environmental constraints at the time, we develop a glacial scenario that explains how these ice sheets, together with eustatic sea-level changes, may have affected the past oceanography of the Arctic Ocean in a fundamental way that must have led to a drastic and non-linear response to external forcing. This concept offers a possibility to explain and to some extent reconcile contrasting age models for the Late Pleistocene in the Arctic Ocean. Our view, if adopted, offers a coherent dating approach across the Arctic Ocean and the Nordic Seas, linked to events outside the Arctic.
    Repository Name: EPIC Alfred Wegener Institut
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  • 18
    Publication Date: 2020-02-17
    Description: Glacial isostatic adjustment (GIA) is a major source of uncertainty for ice and ocean mass balance estimates derived from satellite gravimetry. In Antarctica the gravimetric effect of cryospheric mass change and GIA are of the same order of magnitude. Inverse estimates from geodetic observations hold some promise for mass signal separation. Here, we investigate the combination of satellite gravimetry and altimetry and demonstrate that the choice of input data sets and processing methods will influence the resultant GIA inverse estimate. This includes the combination that spans the full GRACE record (April 2002–August 2016). Additionally, we show the variations that arise from combining the actual time series of the differing data sets. Using the inferred trends, we assess the spread of GIA solutions owing to (1) the choice of different degree-1 and C20 products, (2) viable candidate surface-elevation-change products derived from different altimetry missions corresponding to different time intervals, and (3) the uncertainties associated with firn process models. Decomposing the total-mass signal into the ice mass and the GIA components is strongly dependent on properly correcting for an apparent bias in regions of small signal. Here our ab initio solutions force the mean GIA and GRACE trend over the low precipitation zone of East Antarctica to be zero. Without applying this bias correction, the overall spread of total-mass change and GIA-related mass change using differing degree-1 and C20 products is 68 and 72 Gt a−1, respectively, for the same time period (March 2003–October 2009). The bias correction method collapses this spread to 6 and 5 Gt a−1, respectively. We characterize the firn process model uncertainty empirically by analysing differences between two alternative surface mass balance products. The differences propagate to a 10 Gt a−1 spread in debiased GIA-related mass change estimates. The choice of the altimetry product poses the largest uncertainty on debiased mass change estimates. The spread of debiased GIA-related mass change amounts to 15 Gt a−1 for the period from March 2003 to October 2009. We found a spread of 49 Gt a−1 comparing results for the periods April 2002–August 2016 and July 2010–August 2016. Our findings point out limitations associated with data quality, data processing, and correction for apparent biases.
    Repository Name: EPIC Alfred Wegener Institut
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  • 19
    Publication Date: 2021-03-25
    Description: Landfast sea ice (fast ice) attached to Antarctic (near-)coastal elements is a critical component of the local physical and ecological systems. Through its direct coupling with the atmosphere and ocean, fast-ice properties are also a potential indicator of processes related to a changing climate. However, in situ fast-ice observations in Antarctica are extremely sparse because of logistical challenges and harsh environmental conditions. Since 2010, a monitoring program observing the seasonal evolution of fast ice in Atka Bay has been conducted as part of the Antarctic Fast Ice Network (AFIN). The bay is located on the northeastern edge of Ekström Ice Shelf in the eastern Weddell Sea, close to the German wintering station Neumayer III. A number of sampling sites have been regularly revisited each year between annual ice formation and breakup to obtain a continuous record of sea-ice and sub-ice platelet-layer thickness, as well as snow depth and freeboard across the bay. Here, we present the time series of these measurements over the last 9 years. Combining them with observations from the nearby Neumayer III meteorological observatory as well as auxiliary satellite images enables us to relate the seasonal and interannual fast-ice cycle to the factors that influence their evolution. On average, the annual consolidated fast-ice thickness at the end of the growth season is about 2 m, with a loose platelet layer of 4 m thickness beneath and 0.70 m thick snow on top. Results highlight the predominately seasonal character of the fast-ice regime in Atka Bay without a significant interannual trend in any of the observed variables over the 9-year observation period. Also, no changes are evident when comparing with sporadic measurements in the 1980s and 1990s. It is shown that strong easterly winds in the area govern the year-round snow distribution and also trigger the breakup of fast ice in the bay during summer months. Due to the substantial snow accumulation on the fast ice, a characteristic feature is frequent negative freeboard, associated flooding of the snow–ice interface, and a likely subsequent snow ice formation. The buoyant platelet layer beneath negates the snow weight to some extent, but snow thermodynamics is identified as the main driver of the energy and mass budgets for the fast-ice cover in Atka Bay. The new knowledge of the seasonal and interannual variability of fast-ice properties from the present study helps to improve our understanding of interactions between atmosphere, fast ice, ocean, and ice shelves in one of the key regions of Antarctica and calls for intensified multidisciplinary studies in this region.
    Repository Name: EPIC Alfred Wegener Institut
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  • 20
    Publication Date: 2021-07-01
    Description: The Pliocene epoch has great potential to improve our understanding of the long-term climatic and environmental consequences of an atmospheric CO2 concentration near ∼400 parts per million by volume. Here we present the large-scale features of Pliocene climate as simulated by a new ensemble of climate models of varying complexity and spatial resolution based on new reconstructions of boundary conditions (the Pliocene Model Intercomparison Project Phase 2; PlioMIP2). As a global annual average, modelled surface air temperatures increase by between 1.7 and 5.2 °C relative to the pre-industrial era with a multi-model mean value of 3.2 °C. Annual mean total precipitation rates increase by 7 % (range: 2 %–13 %). On average, surface air temperature (SAT) increases by 4.3 °C over land and 2.8 °C over the oceans. There is a clear pattern of polar amplification with warming polewards of 60°N and 60°S exceeding the global mean warming by a factor of 2.3. In the Atlantic and Pacific oceans, meridional temperature gradients are reduced, while tropical zonal gradients remain largely unchanged. There is a statistically significant relationship between a model's climate response associated with a doubling in CO2 (equilibrium climate sensitivity; ECS) and its simulated Pliocene surface temperature response. The mean ensemble Earth system response to a doubling of CO2 (including ice sheet feedbacks) is 67 % greater than ECS; this is larger than the increase of 47 % obtained from the PlioMIP1 ensemble. Proxy-derived estimates of Pliocene sea surface temperatures are used to assess model estimates of ECS and give an ECS range of 2.6–4.8°C. This result is in general accord with the ECS range presented by previous Intergovernmental Panel on Climate Change (IPCC) Assessment Reports.
    Repository Name: EPIC Alfred Wegener Institut
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  • 21
    Publication Date: 2021-06-16
    Description: In the last decades, changing climate conditions have had a severe impact on sea ice at the western Antarctic Peninsula (WAP), an area rapidly transforming under global warming. To study the development of spring sea ice and environmental conditions in the pre-satellite era we investigated three short marine sediment cores for their biomarker inventory with a particular focus on the sea ice proxy IPSO25 and micropaleontological proxies. The core sites are located in the Bransfield Strait in shelf to deep basin areas characterized by a complex oceanographic frontal system, coastal influence and sensitivity to large-scale atmospheric circulation patterns. We analyzed geochemical bulk parameters, biomarkers (highly branched isoprenoids, glycerol dialkyl glycerol tetraethers, sterols), and diatom abundances and diversity over the past 240 years and compared them to observational data, sedimentary and ice core climate archives, and results from numerical models. Based on biomarker results we identified four different environmental units characterized by (A) low sea ice cover and high ocean temperatures, (B) moderate sea ice cover with decreasing ocean temperatures, (C) high but variable sea ice cover during intervals of lower ocean temperatures, and (D) extended sea ice cover coincident with a rapid ocean warming. While IPSO25 concentrations correspond quite well to satellite sea ice observations for the past 40 years, we note discrepancies between the biomarker-based sea ice estimates, the long-term model output for the past 240 years, ice core records, and reconstructed atmospheric circulation patterns such as the El Niño–Southern Oscillation (ENSO) and Southern Annular Mode (SAM). We propose that the sea ice biomarker proxies IPSO25 and PIPSO25 are not linearly related to sea ice cover, and, additionally, each core site reflects specific local environmental conditions. High IPSO25 and PIPSO25 values may not be directly interpreted as referring to high spring sea ice cover because variable sea ice conditions and enhanced nutrient supply may affect the production of both the sea-ice-associated and phytoplankton-derived (open marine, pelagic) biomarker lipids. For future interpretations we recommend carefully considering individual biomarker records to distinguish between cold sea-ice-favoring and warm sea-ice-diminishing environmental conditions.
    Repository Name: EPIC Alfred Wegener Institut
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  • 22
    Publication Date: 2021-07-01
    Description: The modeling of paleoclimate, using physically based tools, is increasingly seen as a strong out-of-sample test of the models that are used for the projection of future climate changes. New to the Coupled Model Intercomparison Project (CMIP6) is the Tier 1 Last Interglacial experiment for 127 000 years ago (lig127k), designed to address the climate responses to stronger orbital forcing than the midHolocene experiment, using the same state-of-the-art models as for the future and following a common experimental protocol. Here we present a first analysis of a multi-model ensemble of 17 climate models, all of which have completed the CMIP6 DECK (Diagnostic, Evaluation and Characterization of Klima) experiments. The equilibrium climate sensitivity (ECS) of these models varies from 1.8 to 5.6 ∘C. The seasonal character of the insolation anomalies results in strong summer warming over the Northern Hemisphere continents in the lig127k ensemble as compared to the CMIP6 piControl and much-reduced minimum sea ice in the Arctic. The multi-model results indicate enhanced summer monsoonal precipitation in the Northern Hemisphere and reductions in the Southern Hemisphere. These responses are greater in the lig127k than the CMIP6 midHolocene simulations as expected from the larger insolation anomalies at 127 than 6 ka. New synthesis for surface temperature and precipitation, targeted for 127 ka, have been developed for comparison to the multi-model ensemble. The lig127k model ensemble and data reconstructions are in good agreement for summer temperature anomalies over Canada, Scandinavia, and the North Atlantic and for precipitation over the Northern Hemisphere continents. The model–data comparisons and mismatches point to further study of the sensitivity of the simulations to uncertainties in the boundary conditions and of the uncertainties and sparse coverage in current proxy reconstructions. The CMIP6–Paleoclimate Modeling Intercomparison Project (PMIP4) lig127k simulations, in combination with the proxy record, improve our confidence in future projections of monsoons, surface temperature, and Arctic sea ice, thus providing a key target for model evaluation and optimization.
    Repository Name: EPIC Alfred Wegener Institut
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  • 23
    Publication Date: 2017-04-04
    Description: Volcanoes represent an important natural source of several trace elements to the atmosphere. For some species (e.g., As, Cd, Pb and Se) they may be the main natural source and thereby strongly influencing geochemical cycles from the local to the global scale. Mount Etna is one of the most actively degassing volcanoes in the world, and it is considered to be, on the long-term average, the major atmospheric point source of many environmental harmful compounds. Their emission occurs either through continuous passive degassing from open-conduit activity or through sporadic paroxysmal eruptive activity, in the form of gases, aerosols or particulate. To estimate the environmental impact of magma-derived trace metals and their depositions processes, rainwater and snow samples were collected at Mount Etna area. Five bulk collectors have been deployed at various altitudes on the upper flanks around the summit craters of the volcano; samples were collected every two week for a period of one year and analyzed for the main chemical-physical parameters (electric conductivity and pH) and for major and trace elements concentrations. Chemical analysis of rainwater clearly shows that the volcanic contribution is always prevailing in the sampling site closest to the summit crater (about 1.5 km). In the distal sites (5.5-10 km from the summit) and downwind of the summit craters, the volcanic contribution is also detectable but often overwhelmed by anthropogenic or other natural (seawater spray, geogenic dust) contributions. Volcanic contribution may derive from both dry and wet deposition of gases and aerosols from the volcanic plume, but sometimes also from leaching of freshly emitted volcanic ashes. In fact, in our background site (7.5 km in the upwind direction) volcanic contribution has been detected only following an ash deposition event. About 30 samples of fresh snow were collected in the upper part of the volcano, during the winters 2006 and 2007 to estimate deposition processes at high altitude during cold periods. Some of the samples were collected immediately after a major explosive event from the summit craters to understand the interaction between snow and fresh erupted ash. Sulphur, Chlorine and Fluorine, are the major elements that prevailingly characterize the volcanic contribution in atmospheric precipitation on Mount Etna, but high concentrations of many trace elements are also detected in the studied samples. In particular, bulk deposition samples display high concentration of Al, Fe, Ti, Cu, As, Rb, Pb, Tl, Cd, Cr, U and Ag, in the site most exposed to the volcanic emissions: median concentration values are about two orders of magnitude higher than those measured in our background site. Also in the snow samples the volcanic signature is clearly detectable and decreases with distance from the summit craters. Some of the analysed elements display very high enrichment values with respect to the average crust and, in the closest site to the summit craters, also deposition values higher than those measured in polluted urban or industrial sites.
    Description: Published
    Description: Vienna, Austria
    Description: 4.5. Degassamento naturale
    Description: open
    Keywords: Mt. Etna ; trace elements ; rainwater ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 24
    Publication Date: 2017-04-04
    Description: Improving the constraints on the atmospheric fate and depletion rates of acidic compounds persistently emitted by non-erupting (quiescent) volcanoes is important for quantitatively predicting the environmental impact of volcanic gas plumes. Here, we present new experimental data coupled with modelling studies to investigate the chemical processing of acidic volcanogenic species during tropospheric dispersion. Diffusive tube samplers were deployed at Mount Etna, a very active open-conduit basaltic volcano in eastern Sicily, and Vulcano Island, a closed-conduit quiescent volcano in the Aeolian Islands (northern Sicily). Sulphur dioxide (SO2), hydrogen sulphide (H2S), hydrogen chloride (HCl) and hydrogen fluoride (HF) concentrations in the volcanic plumes (typically several minutes to a few hours old) were repeatedly determined at distances from the summit vents ranging from 0.1 to ~10 km, and under different environmental conditions. At both volcanoes, acidic gas concentrations were found to decrease exponentially with distance from the summit vents (e.g., SO2 decreases from ~10,000 μg/m3 at 0.1 km from Etna’s vents down to ~7 _μg/m3 at ~10km distance), reflecting the atmospheric dilution of the plume within the acid gas-free background troposphere. Conversely, SO2/HCl, SO2/HF, and SO2/H2S ratios in the plume showed no systematic changes with plume aging, and fit source compositions within analytical error. Assuming that SO2 losses by reaction are small during short-range atmospheric transport within quiescent (ash-free) volcanic plumes, our observations suggest that, for these short transport distances, atmospheric reactions for H2S and halogens are also negligible. The one-dimensional model MISTRA was used to simulate quantitatively the evolution of halogen and sulphur compounds in the plume of Mt. Etna. Model predictions support the hypothesis of minor HCl chemical processing during plume transport, at least in cloud-free conditions. Larger variations in the modelled SO2/HCl ratios were predicted under cloudy conditions, due to heterogeneous chlorine cycling in the aerosol phase. The modelled evolution of the SO2/H2S ratios is found to be substantially dependent on whether or not the interactions of H2S with halogens are included in the model. In the former case, H2S is assumed to be oxidized in the atmosphere mainly by OH, which results in minor chemical loss for H2S during plume aging and produces a fair match between modelled and measured SO2/H2S ratios. In the latter case, fast oxidation of H2S by Cl leads to H2S chemical lifetimes in the early plume of a few seconds, and thus SO2 to H2S ratios that increase sharply during plume transport. This disagreement between modelled and observed plume compositions suggests that more in-detail kinetic investigations are required for a proper evaluation of H2S chemical processing in volcanic plumes.
    Description: Published
    Description: 1441-1450
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: open
    Keywords: Mt. Etna ; volcanic gas plumes ; tropospheric processing ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 25
    Publication Date: 2017-04-04
    Description: After some short test surveys, during the 2004–2005 summer expedition in Antarctica, a geomagnetic French-Italian observatory was installed on the plateau (geographic coordinates: 75.1 S, 123.4 E; corrected geomagnetic coordinates: 88.9 S, 54.3 E; UT=LT−8) very close to the geomagnetic pole. In this paper we present some peculiarities of the daily variation as observed at this polar cap observatory during the years 2005 and 2006, taking into account the different Loyd seasons and different interplanetary magnetic field conditions. Some interesting results emerge from the analysis, confirming the dependence of the daily variation (and of the associated polar current systems) on the IMF Bz and By components. In particular the analysis showed that different Bz conditions correspond to different contribution to daily variation of ionospheric and field aligned currents, while particular By conditions lead to a time shift of the diurnal variation, indicating an asymmetry with respect to the noon meridian.
    Description: Published
    Description: 2045–2051
    Description: 3.9. Fisica della magnetosfera, ionosfera e meteorologia spaziale
    Description: 1.6. Osservazioni di geomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Geomagnetism and paleomagnetism (Time variations, diurnal to secular) ; Magnetospheric physics (Polar cap phenomena; Solar wind-magnetosphere interactions) ; 01. Atmosphere::01.03. Magnetosphere::01.03.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 26
    Publication Date: 2022-05-25
    Description: Author Posting. © Annual Reviews, 2003. This article is posted here by permission of Annual Reviews for personal use, not for redistribution. The definitive version was published in Annual Review of Environment and Resources 28 (2003): 521-558, doi:10.1146/annurev.energy.28.011503.163443.
    Description: Agriculture and industrial development have led to inadvertent changes in the natural carbon cycle. As a consequence, concentrations of carbon dioxide and other greenhouse gases have increased in the atmosphere and may lead to changes in climate. The current challenge facing society is to develop options for future management of the carbon cycle. A variety of approaches has been suggested: direct reduction of emissions, deliberate manipulation of the natural carbon cycle to enhance sequestration, and capture and isolation of carbon from fossil fuel use. Policy development to date has laid out some of the general principles to which carbon management should adhere. These are summarized as: how much carbon is stored, by what means, and for how long. To successfully manage carbon for climate purposes requires increased understanding of carbon cycle dynamics and improvement in the scientific capabilities available for measurement as well as for policy needs. The specific needs for scientific information to underpin carbon cycle management decisions are not yet broadly known. A stronger dialogue between decision makers and scientists must be developed to foster improved application of scientific knowledge to decisions. This review focuses on the current knowledge of the carbon cycle, carbon measurement capabilities (with an emphasis on the continental scale) and the relevance of carbon cycle science to carbon sequestration goals.
    Description: The National Center for Atmospheric Research is supported by the National Science Foundation.
    Keywords: Carbon sequestration ; Measurement techniques ; Climate ; Kyoto protocol
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 27
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    Unknown
    Annual Reviews
    Publication Date: 2022-05-25
    Description: Author Posting. © Annual Reviews, 2006. This article is posted here by permission of Annual Reviews for personal use, not for redistribution. The definitive version was published in Annual Review of Fluid Mechanics 38 (2006): 395-425, doi:10.1146/annurev.fluid.38.050304.092129.
    Description: Over the past four decades, the combination of in situ and remote sensing observations has demonstrated that long nonlinear internal solitary-like waves are ubiquitous features of coastal oceans. The following provides an overview of the properties of steady internal solitary waves and the transient processes of wave generation and evolution, primarily from the point of view of weakly nonlinear theory, of which the Korteweg-de Vries equation is the most frequently used example. However, the oceanographically important processes of wave instability and breaking, generally inaccessible with these models, are also discussed. Furthermore, observations often show strongly nonlinear waves whose properties can only be explained with fully nonlinear models.
    Description: KRH acknowledges support from NSF and ONR and an Independent Study Award from the Woods Hole Oceanographic Institution. WKM acknowledges support from NSF and ONR, which has made his work in this area possible, in close collaboration with former graduate students at Scripps Institution of Oceanography and MIT.
    Keywords: Solitary waves ; Nonlinear waves ; Stratified flow ; Physical Oceanography
    Repository Name: Woods Hole Open Access Server
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  • 28
    Publication Date: 2022-05-25
    Description: First published online as a Review in Advance on October 24, 2005. (Some corrections may occur before final publication online and in print)
    Description: Author Posting. © Annual Reviews, 2005. This article is posted here by permission of Annual Reviews for personal use, not for redistribution. The definitive version was published in Annual Review of Physiology 68 (2006): 22.1-22.29, doi:10.1146/annurev.physiol.68.040104.105418.
    Description: Superfast muscles of vertebrates power sound production. The fastest, the swimbladder muscle of toadfish, generates mechanical power at frequencies in excess of 200 Hz. To operate at these frequencies, the speed of relaxation has had to increase approximately 50-fold. This increase is accomplished by modifications of three kinetic traits: (a) a fast calcium transient due to extremely high concentration of sarcoplasmic reticulum (SR)-Ca2+ pumps and parvalbumin, (b) fast off-rate of Ca2+ from troponin C due to an alteration in troponin, and (c) fast cross-bridge detachment rate constant (g, 50 times faster than that in rabbit fast-twitch muscle) due to an alteration in myosin. Although these three modifications permit swimbladder muscle to generate mechanical work at high frequencies (where locomotor muscles cannot), it comes with a cost: The high g causes a large reduction in attached force-generating cross-bridges, making the swimbladder incapable of powering low-frequency locomotory movements. Hence the locomotory and sound-producing muscles have mutually exclusive designs.
    Description: This work was made possible by support from NIH grants AR38404 and AR46125 as well as the University of Pennsylvania Research Foundation.
    Keywords: Parvalbumin ; Ca2+ release ; Ca2+ uptake ; Cross-bridges ; Adaptation ; Sound production ; Whitman Center
    Repository Name: Woods Hole Open Access Server
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  • 29
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    Copernicus
    In:  EPIC3A global monthly climatology of oceanic total dissolved inorganic carbon: a neural network approach, Earth System Science Data Discussions, Copernicus, pp. 1-30
    Publication Date: 2020-03-17
    Repository Name: EPIC Alfred Wegener Institut
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  • 30
    Publication Date: 2021-09-20
    Description: In order to investigate the impact of spatial resolution on the discrepancy between simulated δ18O and observed δ18O in Greenland ice cores, regional climate simulations are performed with the isotope-enabled regional climate model (RCM) COSMO_iso. For this purpose, isotope-enabled general circulation model (GCM) simulations with the ECHAM5-wiso general circulation model (GCM) under present-day conditions and the MPI-ESM-wiso GCM under mid-Holocene conditions are dynamically downscaled with COSMO_iso for the Arctic region. The capability of COSMO_iso to reproduce observed isotopic ratios in Greenland ice cores for these two periods is investigated by comparing the simulation results to measured δ18O ratios from snow pit samples, Global Network of Isotopes in Precipitation (GNIP) stations and ice cores. To our knowledge, this is the first time that a mid-Holocene isotope-enabled RCM simulation is performed for the Arctic region. Under present-day conditions, a dynamical downscaling of ECHAM5-wiso (1.1◦ × 1.1◦) with COSMO_iso to a spatial resolution of 50km improves the agreement with the measured δ18O ratios for 14 of 19 observational data sets. A further increase in the spatial resolution to 7km does not yield substantial improvements except for the coastal areas with its complex terrain. For the mid-Holocene, a fully coupled MPI-ESM-wiso time slice simulation is downscaled with COSMO_iso to a spatial resolution of 50km. In the mid-Holocene, MPI-ESM-wiso already agrees well with observations in Greenland and a downscaling with COSMO_iso does not further improve the model–data agreement. Despite this lack of improvement in model biases, the study shows that in both periods, observed δ18O values at measurement sites constitute isotope ratios which are mainly within the subgrid-scale variability of the global ECHAM5-wiso and MPI-ESM-wiso simulation results. The correct δ18O ratios are consequently not resolved in the GCM simulation results and need to be extracted by a refinement with an RCM. In this context, the RCM simulations provide a spatial δ18O distribution by which the effects of local uncertainties can be taken into account in the comparison between point measurements and model outputs. Thus, an isotope-enabled GCM–RCM model chain with realistically implemented fractionating processes constitutes a useful supplement to reconstruct regional paleo-climate conditions during the mid-Holocene in Greenland. Such model chains might also be applied to reveal the full potential of GCMs in other regions and climate periods, in which large deviations relative to observed isotope ratios are simulated.
    Repository Name: EPIC Alfred Wegener Institut
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  • 31
    Publication Date: 2021-09-20
    Description: Proxy climate records are an invaluable source of information about the earth’s climate prior to the instrumental record. The temporal- and spatial-coverage of records continues to increase, however, these records of past climate are associated with significant uncertainties due to non-climate processes that influence the recorded and measured proxy values. Generally, these uncertainties are timescale-dependent and correlated in time. Accounting for structure in the errors is essential to providing realistic error estimates for smoothed or stacked records, detection of anomalies and identifying trends, but this structure is seldom accounted for. In the first of these companion articles we outlined a theoretical framework for handling proxy uncertainties by deriving the power spectrum of proxy error components from which it is possible to obtain timescale-dependent error estimates. Here in part II, we demonstrate the practical application of this theoretical framework using the example of marine sediment cores. We consider how to obtain estimates for the required parameters and give examples of the application of this approach for typical marine sediment proxy records. Our new approach of estimating and providing timescale-dependent proxy errors overcomes the limitations of simplistic single value error estimates. We aim to provide the conceptual basis for a more quantitative use of paleo-records for applications such as model-data comparison, regional and global synthesis of past climate states and data assimilation.
    Repository Name: EPIC Alfred Wegener Institut
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  • 32
    Publication Date: 2021-09-06
    Description: The mid-Pliocene warm period (mPWP; ∼3.2 million years ago) is seen as the most recent time period characterized by a warm climate state, with similar to modern geography and ∼400 ppmv atmospheric CO2 concentration, and is therefore often considered an interesting analogue for near-future climate projections. Paleoenvironmental reconstructions indicate higher surface temperatures, decreasing tropical deserts, and a more humid climate in West Africa characterized by a strengthened West African Monsoon (WAM). Using model results from the second phase of the Pliocene Modelling Intercomparison Project (PlioMIP2) ensemble, we analyse changes of the WAM rainfall during the mPWP by comparing them with the control simulations for the pre-industrial period. The ensemble shows a robust increase in the summer rainfall over West Africa and the Sahara region, with an average increase of 2.5 mm/d, contrasted by a rainfall decrease over the equatorial Atlantic. An anomalous warming of the Sahara and deepening of the Saharan Heat Low, seen in 〉90 % of the models, leads to a strengthening of the WAM and an increased monsoonal flow into the continent. A similar warming of the Sahara is seen in future projections using both phase 3 and 5 of the Coupled Model Intercomparison Project (CMIP3 and CMIP5). Though previous studies of future projections indicate a west–east drying–wetting contrast over the Sahel, PlioMIP2 simulations indicate a uniform rainfall increase in that region in warm climates characterized by increasing greenhouse gas forcing. We note that this effect will further depend on the long-term response of the vegetation to the CO2 forcing.
    Repository Name: EPIC Alfred Wegener Institut
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  • 33
    Publication Date: 2021-12-15
    Description: Due to its dryness, the subtropical free troposphere plays a critical role in the radiative balance of the Earth's climate system. But the complex interactions of the dynamical and physical processes controlling the variability in the moisture budget of this sensitive region of the subtropical atmosphere are still not fully understood. Stable water isotopes can provide important information about several of the latter processes, namely subsidence drying, turbulent mixing, and dry and moist convective moistening. In this study, we use high-resolution simulations of the isotope-enabled version of the regional weather and climate prediction model of the Consortium for Small-Scale Modelling (COSMOiso) to investigate predominant moisture transport pathways in the Canary Islands region in the eastern subtropical North Atlantic. Comparison of the simulated isotope signals with multi-platform isotope observations (aircraft, ground- and space-based remote sensing) from a field campaign in summer 2013 shows that COSMOiso can reproduce the observed variability of stable water vapour isotopes on timescales of hours to days, thus allowing us to study the mechanisms that control the subtropical free-tropospheric humidity. Changes in isotopic signals along backward trajectories from the Canary Islands region reveal the physical processes behind the synoptic-scale isotope variability. We identify four predominant moisture transport pathways of mid-tropospheric air, each with distinct isotopic signatures: - air parcels originating from the convective boundary layer of the Saharan heat low (SHL) – these are characterised by a homogeneous isotopic composition with a particularly high δD (median mid-tropospheric δD=−122‰), which results from dry convective mixing of low-level moisture of diverse origin advected into the SHL; - air parcels originating from the free troposphere above the SHL – although experiencing the largest changes in humidity and δD during their subsidence over West Africa, these air parcels typically have lower δD values (median δD=−148‰) than air parcels originating from the boundary layer of the SHL; - air parcels originating from outside the SHL region, typically descending from tropical upper levels south of the SHL, which are often affected by moist convective injections from mesoscale convective systems in the Sahel – their isotopic composition is much less enriched in heavy isotopes (median δD=−175‰) than those from the SHL region; - air parcels subsiding from the upper-level extratropical North Atlantic – this pathway leads to the driest and most depleted conditions (median δD=−255‰) in the middle troposphere near the Canary Islands. The alternation of these transport pathways explains the observed high variability in humidity and δD on synoptic timescales to a large degree. We further show that the four different transport pathways are related to specific large-scale flow conditions. In particular, distinct differences in the location of the North African mid-level anticyclone and of extratropical Rossby wave patterns occur between the four transport pathways. Overall, this study demonstrates that the adopted Lagrangian isotope perspective enhances our understanding of air mass transport and mixing and offers a sound interpretation of the free-tropospheric variability of specific humidity and isotope composition on timescales of hours to days in contrasting atmospheric conditions over the eastern subtropical North Atlantic.
    Repository Name: EPIC Alfred Wegener Institut
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  • 34
    Publication Date: 2021-12-21
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev , info:eu-repo/semantics/article
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  • 35
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4546-4550 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The properties of high-resistivity InP with resistivity up to 107 Ω cm, obtained by thermal diffusion of Cu at 800 °C for over 20 h into undoped and p-type InP samples, are investigated. Hall-effect measurements showed that the compensation mechanism in the slowly cooled sample is different from that in the quickly cooled samples. Photoluminescence was quenched in the quickly cooled samples when annealed at 350 °C and the anneal temperature at which the sample resistivity and carrier mobility reached the maximum. It is shown that the electrical compensation in the slowly cooled sample could be understood by a simple deep-level compensation model. However, the semi-insulating behavior of the quickly cooled samples appears to be consistent with an internal Schottky depletion model associated with the Cu precipitates. The photoluminescence quenching is due to the Cu precipitates acting as effective nonradiative recombination centers.
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  • 36
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4551-4556 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Iron pyrite thin films prepared by flash evaporation of pyrite powder have been annealed at different temperatures in a sulfur atmosphere. We present some results on the influence of the annealing temperature (from 250 to 450 °C) on the optical and electrical properties of three groups of samples with different thicknesses ((approximately-equal-to)0.3, 0.6, and 1 μm, respectively). Sulfuration temperature has a clear influence on the optical absorption and electrical resistivity of the films, with some differences in their behavior depending on the film thickness. In light of the available present knowledge of pyrite thin films, interpretation of the obtained results is difficult, it suggests that the shape of the optical absorption curves (and their absorption edge) at low photon energies is determined by the density of point defects, which decreases on increasing the annealing temperature. On the other hand, the electrical resistivity seems to be influenced by both the film grain size and point defect density.
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  • 37
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 839-847 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Self-consistent nonequilibrium fluid models of both the two-dimension (2D) and one-dimension (1D) are presented. In the 2D simulations, the models evaluate the quantitative effects of both radial and axial flow dynamics inside a cylindrically symmetric parallel-plate geometry. The 1D model assumes that the radius of the electrode is much larger than the electrode gap and the moment distributions are uniform along the radial direction. The models are based on the first three moments of the Boltzmann equation and Poisson's equation. Radio frequency (rf) glow discharge simulations from those two fluid models are presented and compared in this study. The comparisons are presented in terms of plasma density, electric field, mean energy, and ionization rate. Results of the 1D fluid model are close to those at the center of the reactor from the 2D simulations. Nonuniform profiles along the radial direction are obtained from the 2D simulations due to the radial dynamics. Higher electron mean energy in the middle region of the radial sheath is observed. The maximum ionization rate is located in the radial sheath region and agrees with the experimental observation.
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  • 38
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 825-831 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: In this paper a model of charged particle behavior in a low-pressure oxygen plasma is developed, and compared with experimental results. Agreement is excellent. It is demonstrated that the extremely high temperature ((approximately-greater-than)1 eV) of electrons in these plasmas results in diffusion totally dominating the transport of charged species. It is also shown that charged particle recombination on the walls of a quartz reactor is insignificant. Finally, the influence of the electron temperature profile must be fully considered for accurate results. This work complements an earlier model of radical behavior in these plasmas. Both are needed to fully understand materials modification in these plasmas, which has been shown to involve a synergism between radicals and charged species.
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  • 39
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 853-861 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Large particles (tens of nm to tens of μm in diameter) are problematic in low-pressure (〈1 Torr) plasma processing (etching, deposition) discharges because they can contaminate the product and can perturb electron transport. Although the source of these particles has been studied by a number of groups, a definitive explanation is still lacking. In this paper, we theoretically investigate the role of negative ions in the formation of large clusters, the precursors to particles, in low-pressure plasmas. We find that the formation of particles requires a critically large cluster. Forming the critically large cluster requires longer residence times in the plasma than is usually possible if clustering involves only neutral particles. We propose that negatively charged intermediates, which are trapped in electropositive plasmas, increase the average residence time of clusters to allow the growth of critically large clusters.
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  • 40
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 868-871 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Swift heavy ion irradiation-induced defects have been studied in n-type germanium at room temperature using deep level transient spectroscopy. Several electron traps have been observed after irradiation. The corresponding energies have been determined to be at Ec−0.22, Ec−0.275, Ec−0.29, Ec−0.32, and Ec−0.465 eV. The isochronal annealing behavior of these traps has been studied in detail between room temperature and 200 °C. Comparison of our results with previously published ones allowed an identification of these defects with complexes like divacancies or associations of vacancies with impurities.
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  • 41
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 862-867 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The temporal behavior of the cathode sheath in 30 kHz 0.4–1 Torr H2 discharges has been investigated by optical emission spectroscopy. Analysis of the Stark splitting of plasma-induced H Balmer delta emission was used to measure the electric field with spatial and temporal resolution in the instantaneous cathode sheath. The location of the plasma/sheath boundary was determined from the position of the maximum of the H2 d 3Πu→a 3Σg+ (0,0) Q1 emission at 622.5 nm. Both methods showed that the sheath width increases as the cathode voltage becomes more negative, whereas the width remains constant as the applied voltage drops off. Analysis of the electric-field profile provided information on the time evolution of the ion density close to the electrode during the cathode half-cycle, in agreement with recent numerical calculations. At the beginning of the anodic half-cycle an intense flash of plasma-induced emission was observed, localized within 3 mm from the electrode.
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  • 42
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 877-883 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Hollow glass fibers can guide x rays because glancing-angle collisions with a smooth glass surface are highly reflective. Surface roughness decreases this reflectivity. We have developed relatively simple expressions for the effects of surface roughness on x-ray scattering, and we relate our results to the theoretical efficiency of x-ray lenses formed from bundles of hollow glass fibers.
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  • 43
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 884-890 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Positron lifetime spectroscopy and two-dimensional angular correlation of annihilation radiation have been used to investigate grown-in vacancy structures in synthetic crystalline α-SiO2, synthetic fused quartz, and in a 60-μm-thick chemical-vapor-deposited amorphous SiO2 film. For α-SiO2 a ∼300 ps lifetime component suggests trapping by either silicon monovacancies or by oxygen divacancies (or both). The vacancies are neutral and present at a concentration level of 1017/cm3. The positron bulk lifetime for α-SiO2 is estimated to be ∼238 ps in good agreement with semiempirical predictions. In the fused quartz significant positronium formation is found (80%) and the remaining positrons annihilate in voids yielding a lifetime of ∼500 ps. The amorphous SiO2 film contains a mixture of small vacancy clusters and voids and ∼30% of the positrons form positronium. Heat treatment above 950 °C results in a substantial reduction in defect concentration, but up to 1100 °C a small vacancy cluster contribution persists. The positron data indicate that positronium formation in the fused quartz and in the amorphous film takes place in the voids.
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  • 44
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 872-876 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: X-ray photoelectron spectroscopy has been used to study the surface composition and chemistry of two perovskites: SrTiO3 and Pb(Zr,Ti)O3 (commonly known as PZT). It is seen that ion bombardment, which is a common surface modification technique, can cause substantial changes in these oxides. The PZT surface undergoes surface depletion of lead along with chemical reduction of the Pb2+ ion to its metallic state. The Zr/(Ti+Zr) ratio also changes with sputtering, but the total oxygen to cation ratio is unchanged. On the other hand, the surface stoichiometry of SrTiO3 is almost unaffected by ion bombardment. In all the perovskites, irrespective of whether the composition changes or not, a substantial amount of surface Ti is reduced to a lower valency state on sputtering. Most of this component is restored back to the original Ti4+ state when Ni is evaporated on these surfaces, indicating that the reduced state is associated with a damaged outermost surface that can be repaired with an adsorbate. The implication of these results to the bonding properties of these materials have been discussed.
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  • 45
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4102-4104 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The spin pinning in the oxide surface layer has been observed directly, and it is considered a possible reason why the oxide layer leads to the decrease of the specific saturation magnetization for fine iron particles. The pinning depth has been estimated by means of a Mössbauer effect under an applied field of 6 T in a thermal-cycle process. The Debye temperature of the oxide layer and the temperature dependence of f2/f1 have been obtained, where f1 and f2 are the Mössbauer recoilless fractions for the inner α-Fe core and the oxide layer, respectively. Furthermore, the estimation for the thickness of an oxide layer has been improved.
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  • 46
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4105-4112 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A theory of collective translational vibrations of 90° domain walls (DWs) in ferroelectric ceramics is presented. Vibrational motions of DWs forming a regular domain structure of a representative grain are assumed to be completely correlated but independent of DW oscillations in other grains. A dynamic mechanical stress field appearing in a ceramic because of DW vibrations is calculated. In contrast to former studies, this calculation takes into account effects due to the lagging of sound waves emitted by oscillating DWs and gives a general expression for the dynamic mechanical restoring force acting on DWs. From this expression we derive the equation of sustained forced DW vibrations in an oscillating external electric field that is valid for a wide frequency range including microwave frequencies. A general solution of this equation is found, which enables us to compute numerically the dependencies of amplitude and phase of DW vibrations on the frequency ω of the applied electric field. It is shown that in the low-frequency range ω〈ω*=ct/g (ct=velocity of transverse sound wave, g=grain size) the general equation of DW vibrations can be reduced to a simplified equation that includes the static restoring force, the inertial reaction, and the radiation reaction self-force of the DWs emitting sound waves. Analytic expressions are derived for the DW effective mass and for the factors characterizing the static restoring force and the radiation reaction. The contribution of DW vibrations to the complex dielectric constants of ferroelectric ceramics is calculated. It is predicted that at very high frequencies ω(very-much-greater-than)ω* the DW contribution to the real part of permittivity strongly decreases due to clamping of DWs. In this frequency range a peak of dielectric losses should also arise being caused by the emission of sound waves from oscillating DWs. It is emphasized that the above effects can be correctly described on the base of the general equation of DW vibrations only.
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  • 47
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4121-4124 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A phenomenological model has been applied in an attempt to explain the inability of the ordered regions in the lead magnesium niobate family of relaxor ferroelectrics to coarsen. This approach is based on the concept that the free energy is lowered by an embryonic decomposition along a non-neutral direction. It is proposed that the excess free energy associated with the formation of the non-neutral phase is offset by the distortability of the perovskite structure toward the pyrochlore. The lack of coarsening is then explained as a balance of the electrostatic energy and gradient energy terms, following an earlier published report. This model is then applied to the La-modified (donor-doped) lead magnesium niobate, to explain the dependence of the size of the ordered regions on the degree of doping as observed by other workers.
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  • 48
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4113-4120 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Charge injection leading to catastrophic breakdown has been used to study the dielectric properties of the buried oxide layer in silicon implanted with high-energy oxygen ions. Current versus gate bias, current versus time, and capacitance versus gate bias were used to characterize, at various temperatures, MOS metal-oxide-semiconductor capacitors with areas in the 1×10−4–1×10−2 cm2 range fabricated with commercially available single- or triple-implant separation by implanted oxygen silicon wafers. The data show that injected charge accumulates in the buried oxide at donorlike oxide traps ultimately leading to catastrophic breakdown. Both Poole–Frenkel and Fowler–Nordheim conduction, as well as impact-ionization mechanisms, have been identified in the oxide. The charge and field to breakdown in the best buried oxides are, respectively, near 1 C cm−2 and 10 MV cm−1, similar to the thermally grown oxide parameters. Cumulative distributions of these parameters measured over a large number of capacitors show that the frequency of breakdown events caused by extrinsic defects is scaled with the capacitor area. Intrinsic and extrinsic defect distributions are broader than with thermally grown oxides.
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  • 49
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4125-4129 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Zinc (Zn) is doped into GaSe single crystals grown by the Bridgman technique in a wide range from 0.005 to 0.5 at. % to the stoichiometric melt. Radiative recombination mechanisms have been investigated by using photoluminescence (PL) measurements. The PL spectra in Zn-doped samples at 77 K are dominated by three emission bands at 1.75, 1.63, and 1.27 eV. The 1.63 and 1.27 eV emission bands are enhanced with the increase in the amount of Zn. In addition to the results of Hall effect measurements, it is found that the 1.63 and 1.27 eV emission bands are associated with the acceptor levels at 0.12 and 0.3 eV above the valence band, respectively. For the 1.27 eV emission band, the temperature dependences of the PL intensity, peak energy, and half-width are characterized by the configurational coordinate model.
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  • 50
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4598-4607 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: High-field effects in metal-oxide-semiconductor capacitors have been studied in detail. A comprehensive set of experiments, stressing identically fabricated capacitors on both P-type and N-type silicon, both in accumulation and in inversion, has been made to study defect generation in the oxide at high fields. There is clear experimental evidence that both bulk hole and electron traps are generated under all stress conditions. High-field prebreakdown properties depend mainly upon the dynamics of generation of traps, trapping and detrapping at these and in previously existing traps. It has been found that of several processes, some dominate, depending upon the type of silicon and polarity during stressing, and this is also true for the final breakdown mechanism. In this paper the dominant mechanisms are identified for each of the field stress conditions that have been studied.
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  • 51
    ISSN: 1089-7550
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    Topics: Physics
    Notes: The heavy-hole and light-hole excitons of a CdTe epilayer, pseudomorphically grown on an InSb epilayer by molecular beam epitaxy, are studied with a diamond anvil cell as a function of applied hydrostatic pressure via photoluminescence (PL) and photomodulated reflectivity (PR) spectroscopies. They are compared with the excitonic features in the simultaneously measured PL spectra of a sample of bulk CdTe. Under applied pressure, the lattice mismatch-induced splitting between the light-hole and heavy-hole related transitions increases in a continuous and reversible manner because of the additional pressure-induced compression due to the difference in the compressibilities of CdTe and InSb. The unusually large strain sustained by the CdTe epilayer under pressure is discussed in the light of various models. The PR signal vanishes after the InSb epilayer goes through a structural phase transition at approximately 20 kbar, while the PL signal persists until it is irreversibly quenched by the CdTe epilayer undergoing a structural phase transition at approximately 30 kbar. For pressures between 20 and 30 kbar, the behavior of the CdTe epilayer is similar to that of the bulk sample; the strain appears to have been relaxed due to the structural phase transition which has taken place in InSb. Values of the first- and second-order pressure coefficients for bulk CdTe and for the CdTe epilayer as well as values of the hydrostatic and shear deformation potentials are obtained at 14 and 80 K and compared with previously quoted values.
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  • 52
    ISSN: 1089-7550
    Source: AIP Digital Archive
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    Notes: This article discusses a low-temperature photoluminescence (PL) and electroabsorption (EA) study of GaxIn1−xAs/Ga0.22In0.78As0.48P0.52 single quantum well (QW) samples prepared by gas-source molecular beam epitaxy. The linewidth of PL emitted from these single QW samples increases monotonically with increasing QW strain. EA measurements on the same samples reveal a multipeaked response on the high energy side of the PL spectrum. The energy separation of the EA features corresponds to that expected for differences in QW thickness of one monolayer. The observed PL broadening results from PL emanating from different regions of the same well, differing in thickness, while the Stokes shift results from migration of excitons to wider well regions. Spectral features are lost at large strain which is attributed to strain-enhanced roughening of the QW surface during the crystal deposition.
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  • 53
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4153-4157 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report photoluminescence (PL) results obtained on p-type ZnSe epilayers grown by molecular beam epitaxy. As an acceptor dopant, we used an active nitrogen beam produced by a free radical nitrogen source. On the basis of a detailed analysis of PL data we propose a simple semiquantitative method for a quick and contactless evaluation of the net acceptor concentration in p-type ZnSe. In particular, we show that the intensity ratio of the donor–acceptor pair (DAP) emission to the acceptor-bound exciton (I1) emission strongly depends on both the excitation power and the quality of the sample, and because of that it cannot by itself be regarded as a good measure of the net acceptor concentration. On the other hand, the intensity of the DAP emission under saturation excitation shows a simple direct proportionality to the net acceptor concentration, thus providing a reliable tool for determining the relative doping level in p-type ZnSe films.
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  • 54
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4158-4162 
    ISSN: 1089-7550
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    Topics: Physics
    Notes: Polymer films containing 4-alkoxy-3-chlorobenzoic acid heated to 140 °C showed two optically different states at room temperature depending on the cooling rate. If after heating the film cooled rapidly, it froze in the transparent state. In contrast, it reverted to the light scattering state when cooled slowly. Cycles between the two optical states were reproducible, therefore these films may offer potential as a rewritable recording material. The reversibility in the optical transmittance may be caused by a reversible change in the crystal size of the acid in the polymer matrix.
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  • 55
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 963-968 
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    Topics: Physics
    Notes: Ultraviolet pulsed laser induced oxidation kinetics of crystalline germanium (c-Ge) is determined from real-time optical measurements in conjunction with absolute measurements of the oxygen incorporation performed by nuclear reaction analysis. Although the oxidation process can be triggered at laser fluences initially below the melting threshold of c-Ge, it is strongly activated when surface melting occurs and therefore the fast oxidation process observed is mainly a thermally activated process. Because an optical coupling between the oxide layer and the c-Ge underneath, the growth kinetics is complex and leads to nonconstant rates. The oxygen incorporation reaches a saturation value which depends both on the laser fluence and the oxygen pressure. The results show that the oxygen incorporation is limited by an overlapped laser-induced material removal process rather than by the diffusion length of oxygen species.
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  • 56
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4651-4659 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have investigated melt-spun Pr-Co alloys with the objective of optimizing their permanent magnet characteristics. Among a variety of elemental additives studied, carbon was found capable of significantly improving the properties, the coercivity in particular. For binary Pr-Co systems optimum values of the remanence, Br=5.7 kG, intrinsic coercivity, Hci=5.8 kOe, and energy product, (BH)max=4.7 MG Oe, were obtained from the Pr16Co84 composition. These values were enhanced to Br=5.8 kG, Hci=16.5 kOe, and (BH)max=7.4 MG Oe for Pr18Co76C6. In both cases the melt-spun ribbons were principally composed of PrCo5. The 16.5 kOe coercivity of the carbon-containing ribbons is the highest ever reported for a PrCo5-based material. Two new rare earth-cobalt phases were tentatively identified during the course of this work: PrCo7 (hexagonal TbCu7 structure) and PrCo2Cx (cubic MgCu2 structure). Survey results for other melt-spun, RCo5-based alloys are also described.
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  • 57
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4643-4650 
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    Topics: Physics
    Notes: The microstructural origin of magnetic anisotropy in a magnetron in-line sputter-deposited CoPtCr/Cr magnetic thin-film disk was examined by mapping magnetic properties and microstructure. The film coercivity (Hc), remanence-thickness product (Mrδ), and coercivity squareness (S*) were determined as a function of radial (r) and angular (θ) co-ordinates using a transfer curve magnetometer. The observed variations in Hc, Mrδ, and S* across the disk were 85 Oe, 0.15 emu/cm2, and 0.03, respectively. The angular variation in magnetic properties showed a sinusoidal pattern with the maxima corresponding to the regions where the tracks were parallel (θ=270°) to the pallet movement direction. High-resolution scanning transmission electron microscopy showed subtle differences in the Co-alloy grain morphology and crystallographic orientation between θ=270° and θ=360° locations. The grains were equiaxed in general except for a small fraction of grains elongated in the direction of pallet movement. Lattice images clearly showed that about 45% of the Co-alloy grains had in-plane c axes and a preferred alignment of the c axes along the texture groove. A greater preference for the c axes to lie along the texture line was observed for the θ=270° location. A coherency stress-based model is proposed to explain the preferred c-axis alignment. While the crystalline anisotropy appears to be the main factor responsible for the magnetic anisotropy, both crystalline and shape anisotropies contribute to the magnetic anisotropy variations.
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4664-4672 
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    Source: AIP Digital Archive
    Topics: Physics
    Notes: Insulating barium titanate films were successfully grown on Ti-deposited silicon substrates using the hydrothermal method. The film thickness was 35 and 49 nm for films treated at 200 and 250 °C, respectively, in a 0.25 M Ba(OH)2 solution for 8 h. The BaTiO3 films did not reach the Ti/Si interface. X-ray photoelectron spectroscopy revealed OH-free and nearly carbon-free films, which was corroborated using Auger electron spectroscopy (AES) depth analysis. AES revealed that the oxygen and barium concentrations are correlated throughout the film, and the existence of a diffuse BaTiO3/Ti interface. A discussion on the film growth mechanism is made using existing information on the subject.
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4660-4663 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Magnetoresistance, antiferromagnetic coupling, and crystallographic orientation of Co/Cu superlattices with intentionally mixed interfaces have been studied as a function of the thickness of the mixed region. The antiferromagnetic coupling is weakened, and spin-independent scattering of free electrons is enhanced with increasing thickness of the mixed region, although the morphology and the superlattice period remain unchanged. Saturation magnetoresistance is reduced from 27% to 4% as the result of the formation of a 0.15 nm mixed region at the interfaces. Moreover, the crystallographic orientation of Co/Cu superlattices is also found to be varied by formation of the mixed region. Giant magnetoresistance, antiferromagnetic coupling, and the crystallinity of Co/Cu superlattices are governed by the events in the thin region at the interfaces less than 1 monolayer.
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4685-4690 
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    Topics: Physics
    Notes: The effects on the reflectance spectra of zinc oxide powders, of heat treatment, and of mechanical grinding were investigated for both undoped and aluminum-doped ZnO. A broad absorptance band at 390–400 nm was induced in the undoped powders both by heating in air and by grinding. From a comparison with electron paramagnetic resonance data from the literature, the band could be related to oxygen vacancies. It was found that aluminum doping suppresses the band formation induced by grinding; however, the doping does not suppress the band formation induced by heat treatment.
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  • 61
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4673-4680 
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    Topics: Physics
    Notes: Hydrogenated amorphous carbon films were prepared from CH4, H2, and Ar mixtures by plasma enhanced chemical vapor deposition. Films with various physical properties resulting from various deposition conditions were utilized for this study. The varying deposition parameters included H2 flow rates, Ar flow rates, total pressures, substrate temperatures, and power densities. A systematic study regarding the relationship between deposition conditions and the microstructures, optical, and thermal properties was conducted. Furthermore, how the optical and thermal properties related to the microstructures was analyzed. Fourier transform infrared spectroscopy was employed in this paper for determining the hydrogen concentration and the amounts of tetrahedral and trigonal bondings associated with C—H bond and their relative ratio while the optical properties were measured by optical spectrophotometer. Additionally, photothermal deflection spectroscopy was applied for the measurements of thermal diffusion length.
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  • 62
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4681-4684 
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    Topics: Physics
    Notes: The relationship between the magnitude of the piezoelectric field and the degree of lattice constant mismatch is investigated via low-temperature photoluminescence measurements of the quantum-confined Stark effect for a series of (111)B Al0.15Ga0.85As-InyGa1−yAs pseudomorphic quantum well heterostructures. The experimental strain-induced electric field values agree well with theoretical calculations for indium mole fractions in the range 0.037≤y≤0.09. In addition, an anomalous saturation of the photoluminescence transition energy is observed at values of applied voltage greater than that required to nullify the piezoelectric field, despite the indication from separate electroreflectance measurements that the net electric field within the quantum well reverses polarity under similar electrical biasing conditions.
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  • 63
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 7044-7047 
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    Topics: Physics
    Notes: Laser assisted particle removal (LAPR) is an innovative laser cleaning technique which can remove various particles from solid surfaces via laser induced explosive evaporation of a chosen energy transfer medium, e.g., water. An Ar+ ion continuous-wave laser (488 nm) was used to study the CO2 laser pumped explosive evaporation of water adsorbed on a Si substrate. The probe laser beam was parallel to the sample surface at different displacements and interacted with the ejected material upon pulsed CO2 laser irradiation in analogy with the time resolved laser beam deflection experiments on laser induced vaporization of copper by Guo et al. [Opt. Commun. 77, 381 (1990)]. Using CO2 laser energies which are much greater than the LAPR thresholds, we observed the generation and propagation of a shock wave at supersonic speeds followed by a water vapor/aerosol/particle cloud at a much slower speed. From the evolution of the shock wave, the total conversion efficiency of the incident laser beam into the shock wave has been determined using a self-similar approximation.
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  • 64
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 2681-2685 
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    Topics: Physics
    Notes: Two types of YBa2Cu3Oy-La0.7Ca0.3MnOz-YBa2Cu3Oy (YBCO-LCMO-YBCO) coplanar-type junctions with a 0.2 μm gap were fabricated by electron-beam lithography and Ar-ion-beam milling. One is a junction in which a current flows into the a-b plane (ferromagnetic spin arrangement) of the LCMO and then passes through the channel along the c axis (antiferromagnetic arrangement), and the other is a junction in which the current only passes through the a-b plane. In the former junction the current-voltage characteristics show nonlinearity which suggests a superconductive linkage, while the latter has linear characteristics. This anisotropy of the proximity effect is attributed to anisotropy of the spin structure, because the LCMO film has a small anisotropy of the normal decay length in the a-b plane and along the c axis.
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  • 65
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 2701-2704 
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    Notes: RFe2 laves phase intermetallic compounds are promising materials for magnetostrictive applications. To obtain a larger magnetostriction in a low magnetic field, the influence of boron addition on the giant magnetostriction of an amorphous (SmFe2) (1−x) at. % B (x) at. % alloy has been examined. In the amorphous alloy, the saturation magnetostriction anomalously increases, while the saturation magnetization decreases with the increase in x. The highest saturation magnetostriction of −670×10−6 at 10 kOe and its effective magnetostriction of −490×10−6 at 0.3 kOe can be obtained for amorphous (SmFe2) 99.26 at. % B 0.74 at. % alloy. This effective giant magnetostriction obtained in a low magnetic field is larger than those reported in previous researches. I attribute this anomalous giant magnetostriction in a low magnetic field to the increment of elastic energy in the amorphous (SmFe2) (1−x) at. % B (x) at. % alloy.
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 2725-2730 
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    Topics: Physics
    Notes: Effects of interfaces such as metal/polymer interfaces and polymer/polymer interfaces on the space-charge distribution in multiply low-density polyethylene have been investigated using a pulsed electroacoustic method. It has been found that the heterocharge was dominant in an artificial interface existing in a polyethylene sample. The time dependence of the heterocharge distribution in the interface on applied voltages and polarity was studied. From these charge distributions, the modified electrical field was calculated based on Poisson's equation. The calculated result indicated that the actual field was stronger than the applied uniform field at the artificial interface. A new data display method for a three- or two-dimensional plot is employed to display all measurement data on one plot in which the space charge becomes visible so that the results can be easily and conveniently understood.
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    Journal of Applied Physics 74 (1993), S. 7078-7084 
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    Topics: Physics
    Notes: The thermal diffusivity measurement through pulsed photodeflection in a modified collinear configuration is presented and discussed; comparison between theory and experiment is also shown.
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    Journal of Applied Physics 74 (1993), S. 7094-7100 
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    Notes: A theory is presented to explain the observed electron emission characteristics of a hollow-cathode-based plasma source. The theory is compared with measurements made in a laboratory vacuum facility and is used to predict emission characteristics when the source plasma expands into an ambient space plasma. Crucial to understanding the observed emission current-voltage characteristic of hollow-cathode-type devices is the recognition of the role of emission current, not just the current in the main discharge circuit, in ionization of the neutral gas flowing through the device. This ionization can lead to breakdown of the sort that is familiar in many gas discharge devices. Equally crucial to understanding the low impedance capability of the device in coupling spacecraft to an ambient space plasma is recognition of the role of escaping as well as trapped source electrons in the formation of the space potential profile. The presence of these electrons, according to the theory, results in space electron emission current-voltage characteristics which are well approximated by those observed in laboratory chambers.
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 4729-4736 
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    Topics: Physics
    Notes: The neutral and charged species emitted by pulsed-laser irradiation of polytetrafluoroethylene (PTFE) at 248 nm in vacuum have been examined. In particular, the species and properties of the emission products produced at typical fluence regimes used in the pulsed-laser deposition of PTFE thin films have been characterized. The relative intensities of the major products as well as their dependence on laser fluence are presented, and a simple model is used to fit the observed fluence dependence. Evidence that the major neutral component, the monomer (C2F4), is formed from a thermally activated unzipping reaction is presented. The ionic species are derived from the neutral decomposition products, apparently ionized by electron collisions in the weak plasma generated at the target surface.
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    Journal of Applied Physics 74 (1993), S. 4737-4740 
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    Notes: Impurity doping in InP layer grown by metalorganic vapor-phase epitaxy using tertiarybutylphosphine and organic doping sources is presented. Diethylzinc and diethylselenide were used as the p-type and n-type doping sources, respectively. Electrical properties and surface morphology of the impurity-doped layers together with their growth condition dependence were investigated. Good controllability and reproducibility of the doping level were confirmed. The maximum doping levels of 1.8×1018 and 1×1019 cm−3 were successfully attained for p-InP and n-InP, respectively. These results promise further safe metalorganic vapor-phase epitaxy by using organic compounds for all precursors.
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    Journal of Applied Physics 74 (1993), S. 3103-3110 
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    Notes: In a previous report [G. P. Watson, D. G. Ast, T. J. Anderson, and Y. Hayakawa, Appl. Phys. Lett. 58, 2517 (1991)] we demonstrated that the motion of misfit dislocations in InGaAs, grown by organometallic vapor phase epitaxy on patterned GaAs substrates, can be impeded even if the strained epitaxial layer is continuous. Trenches etched into GaAs before growth are known to act as a barrier to misfit dislocation propagation [E. A. Fitzgerald, G. P. Watson, R. E. Proano, D. G. Ast, P. D. Kirchner, G. D. Pettit, and J. M. Woodall, J. Appl. Phys. 65, 2220 (1989)] when those trenches create discontinuities in the epitaxial layers; but even shallow trenches, with continuous strained layers following the surface features, can act as barriers. By considering the strain energy required to change the length of the dislocation glide segments that stretch from the interface to the free surface, a simple model is developed that explains the major features of the unique blocking action observed at the trench edges. The trench wall angle is found to be an important parameter in determining whether or not a trench will block dislocation glide. The predicted blocking angles are consistent with observations made on continuous 300 and 600 nm thick In0.04Ga0.96As films on patterned GaAs. Based on the model, a structure is proposed that may be used as a filter to yield misfit dislocations with identical Burgers vectors or dislocations which slip in only one glide plane.
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    Journal of Applied Physics 74 (1993), S. 3126-3130 
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    Topics: Physics
    Notes: Near-surface regions of Cd1−xMnxTe and Hg1−xCdxTe epilayers (down to tens of angstroms) on (001) GaAs substrates have been characterized by extremely asymmetric Bragg reflection topography (EABRT) with the laboratory x-ray source condition and a Lang camera, using x-ray grazing incidence angles less than the critical angle for total external reflection. The experimental topographs obtained in the present work illustrate the potential of the EABRT technique for nondestructive characterization of near-surface regions of crystals. The resolution of an image in EABRT is discussed in detail.
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    Journal of Applied Physics 74 (1993), S. 3144-3149 
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    Topics: Physics
    Notes: The enthalpies of formation of metastable fcc Ag-Cu solid solutions, produced by ball milling of elemental powders, were determined by differential scanning calorimetry. Experimental thermodynamic data for these metastable alloys and for the equilibrium phases are compared with both calculation of phase diagrams (CALPHAD) and atomistic simulation predictions. The atomistic simulations were performed using the free-energy minimization method (FEMM). The FEMM determination of the equilibrium Ag-Cu phase diagram and the enthalpy of formation and lattice parameters of the metastable solid solutions are in good agreement with the experimental measurements. CALPHAD calculations made in the same metastable regime, however, significantly overestimate the enthalpy of formation. Thus, the FEMM is a viable alternative approach for the calculation of thermodynamic properties of equilibrium and metastable phases, provided reliable interatomic potentials are available. The FEMM is also capable of determining such properties as the lattice parameter which are not available from CALPHAD calculations.
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    Journal of Applied Physics 74 (1993), S. 3150-3155 
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    Topics: Physics
    Notes: The diffusion of δ-function-shaped B- and Sb-dopant spikes in thin Si films grown by solid-phase-epitaxy [(SPE), growth of amorphous film by molecular-beam epitaxy (MBE) at room temperature and subsequent regrowth in situ] during annealing in vacuum is compared to diffusion in films grown by low-temperature (LT) MBE. Diffusion temperatures from 750 to 900 °C, and two-dimensional concentrations of 0.7–1.6×1014 cm−2 have been investigated. The diffusive behavior of dopants in SPE films is found to be qualitatively different from that in films grown by LTMBE. This is related to the vacancylike defects that are intrinsic to growth by SPE but not to growth by LTMBE. Dopant profiles widen significantly during SPE regrowth, making the achievement of δ-function dopant spikes impossible. After a vacuum anneal the diffusion coefficients for both n- and p-type dopants are lower in SPE films than the corresponding values in films grown by LTMBE by up to one order of magnitude. The diffused depth profile of the dopant in LTMBE films shows the characteristic deviation from a pure Gaussian that is expected due to the concentration dependence of diffusion, i.e., a flat top and steep shoulders. In contrast, dopant depth profiles of SPE-grown material show after diffusion a central spike and relatively flat shoulders. The width of the central spike is, after an initial transient that it was not possible to resolve, independent of diffusion time and temperature. This indicates that the SPE material is defective, with the defects acting as traps during diffusion.
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    Journal of Applied Physics 74 (1993), S. 3162-3171 
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    Topics: Physics
    Notes: Ultrathin GaAs wires as thin as 15–40 nm and about 2 μm long have been grown on a GaAs substrate by metal-organic vapor-phase epitaxy. The wires, which consist of whiskers, are grown between 380 and 550 °C using trimethylgallium and arsine (AsH3) as source materials. It is found that the wire growth direction is parallel to the [111] arsenic dangling-bond direction and can be perfectly controlled by the crystallographic orientation of the GaAs substrate surface. From transmission electron microscopic analysis it is revealed that the crystal structure of the wire coincides with the zinc-blende type for the growth temperature range of 460–500 °C, but it changes to the wurtzite type at 420 °C and temperatures higher than 500 °C. It is also found that the wires have a twin-type structure around the [111] growth axis for zinc blende and [0001] growth axis for wurtzite. Photoluminescence study of these wires shows that the luminescence peak energy shifts to a higher energy as the wire width decreases from 100 to about 35 nm. In terms of luminescence polarization it is confirmed that the luminescence intensity parallel to the wires is four times greater than that perpendicular to the wires. These results clearly indicate the quantum-size effect of carriers confined in the wire. As a preliminary application to devices, a p-n junction has been formed along the GaAs wire. Light emission by current injection to the p-n junction wires has been observed in continuous operation at room temperature.
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    Journal of Applied Physics 74 (1993), S. 3181-3188 
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    Topics: Physics
    Notes: The existence of partially correlated roughness in multilayer thin films is demonstrated using x-ray diffraction diffuse-intensity distribution measurements. The method is generally applicable and produces, in addition to values of magnitudes of interfacial roughness and its lateral correlation length, a measure of the cross correlation between interfaces separated by intermediate ones. A simple phenomenological model can describe roughness in W/C multilayers prepared under standard conditions. A cumulative roughness function is used to show that the wavelength range in which the interfacial roughness predominates in these layers lies between 50 A(ring) and 2000 A(ring) and that the long-wavelength roughness replicates better than the short-wavelength roughness.
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    Journal of Applied Physics 74 (1993), S. 3194-3203 
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    Topics: Physics
    Notes: Film-substrate interactions of YBa2Cu3O7−x (YBCO) thin films grown by pulsed laser deposition on alkaline earth fluoride substrates were investigated. X-ray photoelectron spectroscopy, atomic force microscopy, and x-ray-diffraction measurements showed that the quality of the film and amount of chemical reaction between film and substrate were dependent on the substrate material and deposition temperature. The reaction of YBCO films with CaF2 and MgF2 substrates forms BaF2 and calcium or magnesium oxide species. The reacted film is insulating and has a microscopically rough surface. No reaction was detected in films deposited on BaF2 and SrF2. Physical and thermodynamic properties which may explain the observed order of reactivity are examined.
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    Journal of Applied Physics 74 (1993), S. 3215-3218 
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    Topics: Physics
    Notes: We analyze the role of coherent terahertz radiation on the ultrafast electron dynamics of laser excited photoconductors. Generation of electromagnetic radiation is included within the framework of the usual hot carrier transport theory. A Monte Carlo scheme is used to study the resulting changes in the nonequilibrium electronic energy and transient drift velocity. Our results reveal a density dependent decrease in both quantities, due to reductions in the internal electric fields caused by radiative energy outflow. At densities above 2×1017 cm−3, we obtain a decrease in the transient velocity and expect delays in the onset of phonon emission.
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    Journal of Applied Physics 74 (1993), S. 3219-3223 
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    Notes: The steady state and transient drift velocity of holes in silicon have been investigated using Monte Carlo techniques. The valence band is modeled by warped nonparabolic heavy and light hole bands, and a spherical spin-orbit band. The nonparabolicity of the heavy and light hole bands is included using piecewise continuous functions. The calculated velocities are in better agreement with experimental steady state drift velocity values compared to previous Monte Carlo calculations using only a heavy hole band. Transient calculations show the magnitude of the velocity overshoot for holes is smaller than electrons in silicon but is significantly higher than the steady state drift velocity when high fields are applied.
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    Journal of Applied Physics 74 (1993), S. 7264-7268 
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    Topics: Physics
    Notes: The dc and ac conductivity of single crystal and glass of Li2B4O7 have been measured at various temperatures. It has been shown that these materials are mixed conductors in which electronic and ionic conduction coexist. In the single crystals, both the electronic conduction and ionic conduction along the c axis are much smaller than that perpendicular to the c axis. The anisotropy in the electronic conduction is considered to be due to the conduction by the π electron of the BO3 layer located on the (001) crystallographic plane. The anisotropy in the ionic conduction is also considered to be due to the diffusion of Li ions and/or protons between the BO3 layers. The thermal activation energies of the electronic conduction were 0.65 eV for glass, 1.61 eV for the crystal parallel to the c axis, and 0.78 eV for the crystal perpendicular to the c axis. The activation energy of the ionic conduction was 0.46 eV for the crystal perpendicular to the c axis.
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    Journal of Applied Physics 74 (1993), S. 2968-2970 
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    Topics: Physics
    Notes: It is shown that a combination of low-temperature photoluminescence and luminescence excitation spectroscopies together with appropriate modelization can provide the precise information needed for a thorough control of interdiffusion in quantum well structures. A fit of observed and calculated transition energies up to five energy levels, using the interdiffusion length as a unique parameter, is considered. The potentiality of this procedure to fully characterize the interdiffusion process is illustrated by considering the examples of lightly and heavily intermixed GaAs-AlGaAs multiquantum wells.
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    Journal of Applied Physics 74 (1993), S. 2977-2979 
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    Topics: Physics
    Notes: A photoluminescence study has been made on an oxygen-containing Si fine structure fabricated by a gas evaporation technique. Transmission electron micrographs have shown that the fine structure is composed of nonspherical particles aggregated together in chain-like or cluster-like structures. The luminescence from the samples after oxidation treatment is bright blue as viewed with the naked eye, the spectra having a peak at about 470 nm or shorter wavelength. A peculiar temperature dependence of the emission peak indicates that the emission is strongly correlated with some structural change in the fine structure.
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    Journal of Applied Physics 74 (1993), S. 2983-2985 
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    Topics: Physics
    Notes: Superconducting YBa2Cu3O7−δ thin films with Tc=89.5 K were deposited on MgLaAl11O19 (11¯0) substrates by pulsed laser deposition. X-ray diffraction patterns indicate that the YBa2Cu3O7−δ films were epitaxial films, with the c axis perpendicular to the substrate surfaces. Microstrip resonators of YBa2Cu3O7−δ thin films deposited on MgLaAl11O19 substrates were fabricated. The loaded quality factor of the resonator was 1007 at 77 K and 4.28 GHz. As a new substrate for high Tc oxide superconducting films, MgLaAl11O19 substrates are especially suitable for superconducting-microwave applications.
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    Journal of Applied Physics 74 (1993), S. 1469-1472 
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    Topics: Physics
    Notes: Barrier penetration is attributed to energy fluctuations expected from the uncertainty principle. Numerical simulations are made by calculating the traversal time and action for a large number of possible velocity profiles. Distributions of traversal time are determined by assuming that the probability of each velocity profile decreases exponentially with the action of the fluctuation it requires. Distributions of traversal times are reported for rectangular barriers having different sizes. For large barriers the distributions are leptokurtic and centered at the semiclassical traversal time T0 = d(square root of)m/[2(V0−E)], where d and V0 are the length and height of the barrier and m and E are the mass and energy of the particle. The kurtosis decreases and the mode shifts to shorter durations with decreasing barrier size.
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    Journal of Applied Physics 74 (1993), S. 7306-7310 
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    Topics: Physics
    Notes: We have found that a nonquantizing weakly p-doped InP/Ga0.47In0.53As/InP heterostructure exhibits a photovoltage as high as 2 V at 120 K for moderate light excitation power densities of a few mW/cm2. The back electrical contact is ohmic and the front rectifying contact is established through a thin silver layer. We have monitored as a function of reverse bias applied to the structure the internal photoemission current and also the external photoemission current, due to electrons emitted into vacuum after lowering the surface work function by cesium and oxygen adsorption. Both of these dependences exhibit strong effects of the excitation power density. The dependence of the photovoltage as a function of external bias is obtained using photoreflectance. As shown by a simple model, this gigantic photovoltage arises from accumulation of photoexcited carriers in the Ga0.47In0.53As layer because of the existence of energy barriers with the neighboring InP layers. The different electron and hole transfer probabilities across these barriers result in a strong change of the potential of the Ga0.47In0.53As layer under light excitation.
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    Journal of Applied Physics 74 (1993), S. 7315-7320 
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    Source: AIP Digital Archive
    Topics: Physics
    Notes: We propose a new method of making heavily doped n-type GaAs to a very shallow depth using sulfur hexafluoride (SF6) plasma treatment of the GaAs surface. Semi-insulating GaAs substrate implanted with Si was exposed to a sulfur containing SF6 plasma and capped with silicon nitride anneal cap. During a subsequent anneal step at an elevated temperature to electrically activate the implanted Si, the sulfur diffused into GaAs to a shallow depth of ∼600 A(ring) resulting in further enhancement of net carrier concentration. With this technique the carrier concentration near the surface region was almost doubled compared to samples with Si implantation only. The enhanced carrier concentration improved the wafer-scale variation of ohmic contact resistance using AuGeNi contact metals from 0.089±0.073 to 0.049±0.017 Ω mm. The surface chemistry of SF6 plasma treated GaAs surface was characterized by x-ray photoelectron spectroscopy and Auger electron spectroscopy, and the results were compared with the carrier-concentration profiles and ohmic contact resistance.
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  • 87
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 7329-7339 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Electron coincidence spectroscopy in an ultrahigh vacuum scanning transmission electron microscope has been used to study the generation pathways for secondary (SE) and Auger electrons (AE) excited by high-energy incident electrons. Energy and momentum transfer of inelastically scattered 100 keV primary electrons have been correlated with energy selected SE and AE for both thin 〈111〉 oriented Si crystals and amorphous C films. Coincidence spectra from the valence excitation region indicate that bulk plasmon decay is not the primary production channel for SE in Si(111) and that SE result partially from the decay of ionizations from deep in the valence band. Energy deposition by the primary beam is responsible for SE production at excitation energies above the valence region. At most one SE is emitted from the entrance surface of a thin film for each inelastically scattered 100 keV primary electron. An enhancement in both the SE yield and generation probability is observed at the C K ionization edge. Correlations between energy loss electrons in the vicinity of the C K ionization edge and energy selected SE near the C KLL AE energy show a very sharp threshold in the generation probability. High-momentum transfer (spatially localized) inelastic scattering events are more efficient at creating SE than low-momentum transfer events. The high-spatial resolution obtained in SE images is explained using the Heisenberg uncertainty principle and the scattering angle dependence of the SE generation probability.
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  • 88
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 3061-3064 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A steep plasma edge in infrared reflectivity spectra of Hg1−xCdxTe and HgSe:Fe has been observed. It is predicted that the edge is sensitive to the variation of carrier concentration, which indicates the possibility of developing a fast light-controlled switch for infrared radiation as well as a new approach of infrared modulation and detection. The modulation gain in power and detectivity limited by the generation-recombination process has been calculated and compared with the photoconductive counterpart.
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  • 89
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 3065-3070 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The transfer of energy between the plasma and the iron anode and the evaporation of metal were taken into account in modeling a short free-burning arc in argon at atmospheric pressure. The presence of metal vapor in the plasma modifies the electrical conductivity and the radiated power and leads to arc cooling in the anode region. In return, the arc cooling modifies the rate of vaporization of the anode and thus the calculated concentration of iron vapor in the arc.
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  • 90
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 3080-3083 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Six samples of congruently melting lithium niobate (∼Li0.95Nb1.01O3) have been examined by powder x-ray diffraction for the occurrence of niobium antisite defects (niobium on lithium sites). Contrary to current thinking, we have found no evidence for the occurrence of high concentrations of such defects, which also require the presence of Nb site vacancies. Rather, it was found that the number of antisite defects is close to the minimum that is required to sustain charge neutrality in a model of the type ([Li1−xNbx/5][Nb]O3), where the Nb site is fully occupied.
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  • 91
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 3071-3079 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The plasma plume induced by pulsed CO2 laser irradiation of a Ti target at power densities up to 4×108 W cm−2 was studied by emission spectroscopy. Time- and space-resolved measurements were performed by varying laser intensity, laser temporal pulse shape, ambient gas pressure, and the nature of the ambient gas. Experimental results are discussed by comparison with usual models. We show that shock wave and plasma propagation depend critically on the ratio Ivap/Ii, Ivap being the intensity threshold for surface vaporization and Ii the plasma ignition threshold of the ambient gas. Spectroscopic diagnostics of the helium breakdown plasma show maximum values of electron temperature and electron density in the order of kTe∼10 eV and ne=1018 cm−3, respectively. The plasma cannot be described by local thermodynamic equilibrium modeling. Nevertheless, excited metal atoms appear to be in equilibrium with electrons, hence, they can be used like a probe to measure the electron temperature. In order to get information on the role of the plasma in the laser-surface interaction, Ti surfaces were investigated by microscopy after irradiation. Thus an enhanced momentum transfer from the plasma to the target due to the recoil pressure of the breakdown plasma could be evidenced.
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  • 92
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 3084-3090 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Crystallization temperatures of a-Si:H films deposited on GaAs substrates by a glow-discharge method increased with an increase in the concentration of As doped into the a-Si:H films. Crystallization of a-Si:H films with an As concentration of 2×1020 cm−3 started at a temperature of about 1050 °C. These a-Si:H films also had a large amounts of H and SiH3.
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  • 93
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 3091-3098 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The conductivity and the impurity profiles of InP implanted with dopant ions (Si,Be) or non dopant ions (B,H,N,O,P) have been investigated. Experiments have been done in substrates with and without Fe doping. Low-temperature, short-time annealing of implanted Si and Be reveals an n-type distribution of carriers which cannot be accounted for on the basis of implant activation. In order to examine the contribution without the carriers originating from the dopant ions, the behavior of electrically inactive B, H, N, O, and P, implants was investigated. Implantation of these ions into semi-insulating InP introduced n-type doping in the 1×1016 cm3 range after an anneal above 450 °C. For H, O, N, and P ions, the n-type conductivity could be eliminated by annealing at higher temperatures. However, boron anneals up to 750 °C did not eliminate the n-type conductivity. The n-type carrier profiles tracked the ion profiles. The carrier profile is influenced by the redistribution of the Fe during annealing; however, the Fe motion cannot explain the n-type conductivity. This conductivity may be due to a complex formed above 450 °C.
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  • 94
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 3099-3102 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have investigated proton implantation enhanced intermixing of GaAs/AlGaAs quantum wells for H+ doses ranging from 5×1013 to 1×1016 ions/cm2. Implantation of 20 keV H+ followed by a high temperature rapid thermal anneal leads to enhanced diffusion of Al into the GaAs quantum well. Shifts of electron–heavy hole recombination energies due to compositional changes were observed using room temperature cathodoluminescence. Diffusion lengths of longer than 2 nm were calculated from energy shifts in a 5 nm well and were found to vary with both implanted dose and anneal time, as expected if the enhanced interdiffusion is caused by implantation introduced defects.
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  • 95
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 3111-3120 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The influence of various rubbing parameters on the molecular reorientation of thin polyimide orienting layers, used to align liquid-crystal (LC) molecules within liquid-crystal displays, has been studied. For this purpose the optical phase retardation in the polymer layer, explicitly induced during the rubbing treatment, was determined. The observed rubbing-induced phase retardation can directly be related to a molecular orientation within the polymer orienting layer, as could be shown by infrared dichroism studies. Furthermore, it is found that the top of the polymer layer, directly contacting the rubbing cloth during the actual rubbing process, is almost instantaneously oriented to a certain maximum value as soon as the rubbing is started. Additional or stronger rubbing has no detectable influence on the orientation within the top layer. Increasing the rubbing density or the rubbing pressure only results in an increase of the penetration depth of the rubbing process, i.e., molecular reorientation occurs deeper within the layer. Experiments show that the penetration depth can be varied from less than 10 nm to more than 60 nm by variation in rubbing conditions. These findings are supported by surface second-harmonic-generation studies of LC monolayers deposited onto rubbed orienting layers and by infrared dichroism studies.
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  • 96
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 3121-3125 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: This paper illustrates the procedure for extracting structural information available from x-ray diffraction space mapping and topography. The methods of measuring, the residual strain, macroscopic tilts, microscopic tilts and their lateral dimensions, and the strain field disruption emanating from the interfacial defects are presented. Partially relaxed thick InGaAs layers on GaAs substrates were studied and it was concluded that the relaxation and macroscopic tilting were anisotropic, the microscopic tilting reduced with thickness, and the interfacial disruption did not continue to increase with increasing relaxation. A "mosaic grain growth'' model is postulated to account for the diminishing microscopic tilt spread and increasing topographic contrast with layer thickness.
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  • 97
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 1744-1746 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Metal adhesion to polymers depends on the chemical structure at the interface. In the present work, we study the evaporation of Cr, Ti, and Au onto Teflon PFA (perfluoromethyl-vinyl-ether) substrates, and we modify the interface by post-deposition x-ray irradiation. In situ x-ray photoelectron spectroscopy shows that deposition of reactive metals such as Cr and Ti leads immediately to crosslinking and to the formation of carbide and fluoride species. Less reactive metals, such as Au, cause only small loss of fluorine without formation of any new species. The metal/PFA interface is strongly affected by x-ray irradiation in the case of Cr and Ti: remarkably enhanced crosslinking has been observed, which further increases with the metal coverage, while the carbides and fluorides remain basically unaffected. On the other hand, crosslinking increases only very slightly for pure PFA and for the Au/PFA interface, regardless of the Au thickness. These results suggest that radical recombination reactions are responsible for crosslinking at the interface between PFA and reactive metals.
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  • 98
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 1776-1780 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A method for parameter identification in grazing incidence x-ray reflectometry is presented. It is based on a nonlinear least-squares approach with on-line low-pass filtering and fits the measured reflectivity curve as a function of the incidence angle to a simulation model. The filter is applied in the (angular) frequency domain; it introduces, even for strong filtering, no bias and renders the result independent of the angular stepsize of the data. Automatic restarting helps to determine the global solution. The commonly used roughness model is generalized to non-normal distributions in order to assess data with large scattering vectors. The method is demonstrated for data from single and double film samples. Thickness and roughness can be determined with an accuracy of about 0.2 nm. However, only in special cases it is possible to determine accurately materials constants such as compositional fractions or densities. Absorption cannot be neglected, but the corresponding parameters are difficult to determine separately.
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  • 99
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 1770-1775 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The segregation and interdiffusion of In atoms in the GaAs/InAs/GaAs heterostructures were investigated by secondary-ion mass spectroscopy. When the 1-ML-thick InAs layer was grown in a layer-by-layer growth mode with no dislocations, the segregation of In atoms became marked with the increase of the growth temperature. However, the segregation was observed even at a relatively low growth temperature of 400 °C in molecular beam epitaxy. It was found that the segregation was markedly enhanced by dislocations near the heterointerface when thick InAs layers were grown in a three-dimensional island growth mode. The interdiffusion of In atoms toward the growth direction occurred after thermal annealing, which could be assisted by vacancies propagating from the film surface into the epilayer. It became apparent that the interdiffusion was effectively suppressed by a thin AlAs layer inserted in the GaAs cap layer.
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  • 100
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    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 1818-1821 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The results of an ensemble Monte Carlo simulation of the electron transport in gallium nitride (GaN) are presented. The calculation shows that intervalley electron transfer plays a dominant role in GaN in high electric fields leading to a strongly inverted electron distribution and to a large negative differential conductance. An analytic expression for the polar optical momentum relaxation time for phonon energies larger than the thermal energy is also derived. This expression applies to many wide-gap semiconductors, such as GaN and SiC, at room temperature since these semiconductors have large polar optical-phonon energies (on the order of 100 meV). The calculated mobility agrees well with the results of the Monte Carlo calculation.
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