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  • American Geophysical Union  (5,143)
  • American Institute of Physics (AIP)
  • Cambridge University Press
  • 2005-2009  (6,569)
  • 1985-1989
  • 1980-1984
  • 2005  (6,569)
Collection
Publisher
Years
  • 2005-2009  (6,569)
  • 1985-1989
  • 1980-1984
Year
  • 1
    Unknown
    Cambridge, U.K ; New York, N.Y : Cambridge University Press
    Keywords: Cellular telephone services industry ; Electronic books ; Mobile communication systems, Economic aspects ; Wireless communication systems, Economic aspects
    Pages: 1 v. (various pagings)
    ISBN: 0-511-11564-4
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  • 2
    Unknown
    Cambridge ; New York : Cambridge University Press
    Keywords: Shakespeare, William, Tragedies ; Electronic books ; Identity (Psychology) in literature ; Tragedy ; Violence in literature
    Pages: ix, 228 p.
    ISBN: 0-511-11352-8
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  • 3
    Unknown
    New York : Cambridge University Press
    Keywords: Capital market ; Electronic books ; Futures market ; Stock exchanges
    Pages: 1 v. (various pagings)
    ISBN: 0-511-11580-6
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  • 4
    Keywords: Developing countries, Economic policy. ; Federal government, Developing countries.
    Pages: xi, 276 p.
    ISBN: 0-511-11566-0
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  • 5
    Unknown
    Cambridge ; New York : Cambridge University Press
    Keywords: Dynamics. ; Kinematics.
    Pages: x, 374 p.
    Edition: 3rd ed
    ISBN: 0-511-11583-0
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  • 6
    Unknown
    Cambridge ; New York : Cambridge University Press
    Keywords: Shakespeare, William, Language ; Shakespeare, William, Romeo and Juliet ; Shakespeare, William, Stage history, 1950- ; Shakespeare, William, Stage history, England, London ; Electronic books ; English language, Pronunciation, Early modern, 1500-1700 ; Globe Theatre (London, England : 1996- )
    Pages: xviii, 188 p.
    ISBN: 0-511-11364-1
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  • 7
    Unknown
    Cambridge, U.K ; New York : Cambridge University Press
    Keywords: Electronic books ; Religion, Study and teaching (Higher) ; Theology, Study and teaching (Higher)
    Pages: xvii, 230 p.
    ISBN: 0-511-11355-2
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  • 8
    Unknown
    Cambridge [England] ; New York : Cambridge University Press
    Keywords: Engineering mathematics, Data processing. ; Numerical analysis, Data processing. ; MATLAB.
    Pages: viii, 426 p.
    ISBN: 0-511-12811-8
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  • 9
    Unknown
    New York : Cambridge University Press
    Keywords: Materials, Mechanical properties.
    Pages: xx, 425 p.
    ISBN: 0-511-11575-X
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  • 10
    Unknown
    Cambridge, UK ; New York : Cambridge University Press
    Keywords: Autonomy (Psychology) ; Electronic books ; Ethics, Modern
    Notes: Planning agency, autonomous agency / Michael E. Bratman -- Autonomy without free will / Bernard Berofsky -- Autonomy and the paradox of self-creation : infinite regresses, finite selves, and the limits of authenticity / Robert Noggle -- Agnostic autonomism revisited / Alfred R. Mele -- Feminist intuitions and the normative substance of autonomy / Paul Benson -- Autonomy and personal integration / Laura Waddell Ekstrom -- Responsibility, applied ethics, and complex autonomy theories / Nomy Arpaly -- Autonomy and free agency / Marina A.L. Oshana -- The relationship between autonomous and morally responsible agency / Michael McKenna -- Alternative possibilities, personal autonomy, and moral responsibility / Ishtiyaque Haji -- Freedom within reason / Susan Wolf -- Procedural autonomy and liberal legitimacy / John Christman -- The concept of autonomy in bioethics : an unwarranted fall from grace / Thomas May -- Who deserves autonomy, and whose autonomy deserves respect? / Tom L. Beauchamp -- Autonomy, diminished life, and the threshold for use / R.G. Frey
    Pages: ix, 350 p.
    ISBN: 0-511-08224-X
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  • 11
    Unknown
    Cambridge, UK ; New York : Cambridge University Press
    Keywords: Kant, Immanuel,, 1724-1804. ; Causation.
    Pages: xi, 451 p.
    ISBN: 0-511-08217-7
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  • 12
    Unknown
    Cambridge, UK ; New York : Cambridge University Press
    Keywords: Monte Carlo method. ; Statistical physics.
    Pages: xv, 432 p.
    Edition: 2nd ed
    ISBN: 0-511-13098-8
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  • 13
    Unknown
    Cambridge ; New York : Cambridge University Press
    Keywords: Equality. ; Minorities. ; Minorities, Civil rights. ; Multiculturalism. ; Social conflict. ; Social groups.
    Pages: xii, 390 p.
    ISBN: 0-511-08065-4
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  • 14
    Unknown
    Cambridge, UK ; New York : Cambridge University Press
    Keywords: Frege, Gottlob,, 1848-1925.
    Notes: Biography -- Function and argument -- Sense and reference -- Frege's Begriffsschrift theory of identity -- Concept and object -- Names and descriptions -- Existence -- Thought, truth value and assertion -- Indirect reference -- Through the quotation marks
    Pages: xix, 226 p.
    ISBN: 0-511-10977-6
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  • 15
    Unknown
    Cambridge : Cambridge University Press
    Keywords: Space time codes.
    Pages: 1 v. (various pagings)
    ISBN: 0-511-11562-8
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  • 16
    Publication Date: 2021-01-05
    Description: Destructive earthquakes are rare in France yet pose a sizable seismic hazard, especially when critical infrastructures are concerned. Only a few destructive events have occurred within the instrumental period, the most important being the 11 June 1909, Lambesc (Provence) earthquake. With a magnitude estimated at 6.2 [Rothé, 1942], the event was recorded by 30 observatories and produced intensity IX effects in the epicentral area, ~30 km north of Marseille. We collected 30 seismograms, leveling data and earthquake intensities to assess the magnitude and possibly the focal mechanism of this event. Following this multidisciplinary approach, we propose a source model where all relevant parameters are constrained by at least two of the input datasets. Our reappraisal of the seismological data yielded Mw 5.8-6.1 (6.0 preferred) and Ms 6.0, consistent with the magnitude from intensity data (Me 5.8) and with constraints derived from modeling of coseismic elevation changes. Hence, we found the Lambesc earthquake to have been somewhat smaller than previously reported. Our datasets also constrain the geometry and kinematics of faulting, suggesting that the earthquake was generated by reverse-right lateral slip on a WNW-striking, steeply north-dipping fault beneath the western part of the Trévaresse fold. This result suggests that the fold, located in front of the Lubéron thrust, plays a significant role in the region’s recent tectonic evolution. The sense of slip obtained for the 1909 rupture also agrees with the regional stress field obtained from earthquake focal mechanisms and microtectonic data as well as recent GPS data.
    Description: Published
    Description: 2454
    Description: partially_open
    Keywords: Lambesc earthquake ; France ; historical seismograms ; displacement modeling ; macroseismic data ; geodetic data ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 17
    Publication Date: 2021-04-07
    Description: The flow of ground water in a buried permeable paleochannel can be observed at the ground surface through its self-potential signature. We apply this method to delineate the Saint-Ferréol paleo-channel of the Rhone River located in Camargue, in the South East of France. Negative potentials, 30 mV (reference taken outside the paleochannel),are associated with ground water flow in this major sand-filled channel (500 m wide). Electrical resistivity is primarily controls by the salinity of the pore water. Electrical resistivity tomography and in situ sampling show the salinity of the water inside the paleo-channel is ten times smaller by comparison with the pore water of the surrounding sediments. Combining electrical resistivity surveys, self-potential data, and a minimum of drilling information, a 3-D reconstruction of the architecture of the paleo-channel is obtained showing the usefulness of this methodology for geomorphological reconstructions in this type of coastal environment.
    Description: - Observatoire de Recherche en Environnement (ORE)
    Description: Published
    Description: L07401
    Description: partially_open
    Keywords: Self-potential ; electrical resistivity tomography ; hydrogeology ; tomography ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 18
    Publication Date: 2017-04-04
    Description: In this paper we provide a review of chemical and isotopic data gathered over the last three decades on Etna volcano's fluid emissions and we present a synthetic framework of their spatial and temporal relationships with the volcano-tectonic structures, groundwater circulation and eruptive activity. We show that the chemistry, intensity and spatial distribution of gas exhalations are strongly controlled by the main volcano-tectonic fault systems. The emission of mantle-derived magmatic volatiles, supplied by deep to shallow degassing of alkali-hawaiitic basalts, persistently occurs through the central conduits, producing a huge volcanic plume. The magmatic derivation of the hot gases is verified by their He, C and S isotopic ratios. Colder but widespread emanations of magma-derived CO2 and He also occur through the flanks of the volcano and through aquifers, mainly concentrated within two sectors of the south-southwest (Paternò-Belpasso) and eastern (Zafferana) flanks. In these two peripheral areas, characterized by intense local seismicity and gravity highs, magma-derived CO2 and helium are variably diluted by shallower crustal-derived fluids (organically-derived carbon, radiogenic helium). Thermal and geochemical anomalies recorded in groundwaters and soil gases within these two areas prior to the 1991-1993 eruption are consistent with an input of hot fluids released by ascending magma. Magmatic fluids interacted with the shallow aquifers, modifying their physico-chemical conditions, and led to strong variations of the soil CO2 flux. In addition to routine survey of the crater plume emissions, geochemical monitoring of remote soil gases and groundwaters may thus contribute to forecasting Etna's eruptions.
    Description: Published
    Description: 129-145
    Description: partially_open
    Keywords: Mt. Etna ; Geochemical surveillance ; Groundwaters ; Volcanic gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 19
    Publication Date: 2017-04-04
    Description: The western Mediterranean subduction zone (WMSZ) extends from the northern Apennine to southern Spain and turns around forming the narrow and tight Calabrian and Gibraltar Arcs. The evolution of the WMSZ is characterized by a first phase of orogenic wedging followed, from 30 Ma on, by trench retreat and back-arc extension. Combining new and previous geological data, new tomographic images of the western Mediterranean mantle, and plate kinematics, we describe the evolution of the WMSZ during the last 35 Myr. Our reconstruction shows that the two arcs form by fragmentation of the 1500 km long WMSZ in small, narrow slabs. Once formed, these two narrow slabs retreat outward, producing back-arc extension and large scale rotation of the flanks, shaping the arcs. The Gibraltar Arc first formed during the middle Miocene, while the Calabrian Arc formed later, during the late Miocene-Pliocene. Despite the different paleogeographic settings, the mechanism of rupture and backward migration of the narrow slabs presents similarities on both sides of the western Mediterranean, suggesting that the slab deformation is also driven by lateral mantle flow that is particularly efficient in a restricted (upper mantle) style of mantle convection.
    Description: Published
    Description: 1-21
    Description: reserved
    Keywords: Mediterranean ; subduction ; arcuate belt ; tomography ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 20
    Publication Date: 2017-04-04
    Description: The recent eruption of Mount Etna (July 2001) offered the opportunity to analyze magma-derived volatiles emitted during preand syn-eruptive phases, and to verify whether their composition is affected by changes in volcanic dynamics. This paper presents the results of analyses of F, Cl and S in the volcanic plume collected by filter-packs, and interprets variations in the composition based on contrasting solubility in magmas. A Rayleigh-type degassing mechanism was used to fit the acquired data and to estimate Henryâ s solubility constant ratios in Etnean basalt. This model provided insights into the dynamics of the volcano. Abundances of sulfur and halogens in eruptive plumes may help predict the temporal evolution of an ongoing effusive eruption.
    Description: -Gruppo Nazionale per la Vulcanologia.
    Description: Published
    Description: 1559
    Description: partially_open
    Keywords: magmatic degassing ; acidic gases ; plume chemistry ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 21
    Publication Date: 2017-04-04
    Description: A high-resolution environmental magnetic study of the Massignano section, Italy (Global Stratotype Section and Point for the Eocene-Oligocene boundary), has been performed to test whether a clear magnetic signature associated with climatic change is recognizable in this record. Our results reveal the existence of alternating intervals with high and low magnetic mineral concentrations similar to the pattern of rock magnetic property variations observed from an environmental magnetic study of the CIROS-1 sediment core from Antarctica. These results suggest that an external forcing mechanism drove the sedimentary response to global climate change prior to the major Oi-1 cooling event at the Eocene-Oligocene boundary.
    Description: Published
    Description: 601-605
    Description: reserved
    Keywords: Environmental magnetism ; Massignano ; 04. Solid Earth::04.05. Geomagnetism::04.05.07. Rock magnetism
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  • 22
    Publication Date: 2017-04-04
    Description: Mud volcanoes represent the largest expression of natural methane release into the atmosphere; however, the gas flux has never been investigated in detail. Methane output from vents and diffuse soil degassing is herewith reported for the first time. Measurements were carried out at 5 mud volcano fields around Sicily (Italy). Each mud volcano is characterized by tens of vents and bubbling pools. In the quiescent phase, methane emission from single vents ranges between 0.01 and 6.8 kg/day. Diffuse soil leakage around the vents is in the order of 102–104 mg m 2 d 1. An exceptional flux of 106 mg m 2 d 1 was recorded close to an everlasting fire. Soil CH4 flux is positive even at large distances from the mud volcano fields suggesting a diffuse microseepage over wider areas. A total of at least 400 tons CH4 per year can be estimated over the area investigated alone ( 1.5 km2).
    Description: Published
    Description: 1215
    Description: partially_open
    Keywords: methane ; flux measurements ; Sicily ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
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  • 23
    Publication Date: 2017-04-04
    Description: Volcanic gas emissions from fumaroles on the rim of La Fossa crater, Vulcano Island, Italy, were measured simultaneously using direct sampling (for H2O, CO2, total sulfur, HCl and HF), filter packs (for SO2, HCl, HF) and short-path active-mode FTIR measurements (for H2O, CO2,SO2, HCl and HF) in an intercomparison study in May 2002. The results show that Cl/F ratios were in good agreement between all three methods, and that FTIR and direct sampling determined comparable proportions of CO2 and H2O. Amounts of total S observed in direct sampling data were approximately double the amounts of SO2 measured with filter packs and FTIR. This difference could be attributed either to the fact FTIR and filter packs do not measure reduced sulfur species (e.g., H2S) or to sublimation of elemental S upon exit from the fumarole, after collection by direct sampling but before detection with FTIR and filter packs.
    Description: Published
    Description: L02610
    Description: partially_open
    Keywords: volcanic gas techniques ; gas geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 24
    Publication Date: 2017-04-04
    Description: Chemical and isotopic data have been used as geochemical tracers for a genetic characterization of hydrocarbon gases from a total of eleven manifestations located in Eastern and Central-Southern Sicily (Italy). The molecular analysis shows that almost all the samples are enriched in methane (up to 93.2% Vol.), with the exception of four gas samples collected around Mt. Etna showing high mantle-derived CO2 content. Methane isotope signatures suggest that these are thermogenic gases or a mixture between thermogenic gases and microbial gases. Although samples from some mud volcanoes in Southern Sicily (Macalube di Aragona) show isotope signatures consistent with a mixing model between thermogenic and microbial, by combining the molecular compositions (C1/(C2 + C3))and the methane isotope ratios (d13C1), such a process seems to be excluded. Therefore, the occurrence of secondary post-genetic processes should be invoked. Two main hypotheses have been considered: the first hypothesis includes that the gas is produced by microbial activity and altered post-genetically by microbial oxidation of methane, while according to the second hypothesis thermogenic gas have modified their molecular ratios due to vertical migration.
    Description: Published
    Description: L06607
    Description: partially_open
    Keywords: Isotopic composition/chemistry ; Organic geochemistry ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 25
    Publication Date: 2017-04-04
    Description: We study the dynamic traction behavior within the cohesive zone during the propagation of earthquake ruptures adopting rate and state dependent constitutive relations. The resulting slip weakening curve displays an equivalent slip weakening distance (D0_eq), which is different from the parameter L controlling the state variable evolution. The adopted constitutive parameters (a, b, L) control the slip weakening behavior and the absorbed fracture energy. The dimension of the nucleation patch scales with L and not with D0_eq. We propose a scaling relation between these two lengthscale parameters which prescribes that D0_eq/L ~ 15.
    Description: Published
    Description: 1-4
    Description: open
    Keywords: Earthquake dynamics and mechanics ; Earthquake parameters ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 26
    Publication Date: 2017-04-04
    Description: Constraining fluxes of volcanic bromine and iodine to the atmosphere is important given the significant role these species play in ozone depletion. However, very few such measurements have been made hitherto, such that global volcanic fluxes are poorly constrained. Here we extend the data set of volcanic Br and I degassing by reporting the first measurements of bromine and iodine emissions from Mount Etna. These data were obtained using filter packs and contemporaneous ultraviolet spectroscopic SO2 flux measurements, resulting in time-averaged emission rates of 0.7 kt yr 1 and 0.01 kt yr 1 for Br and I, respectively, from April to October 2004, from which we estimate global Br and I fluxes of order 13 (range, 3â 40) and 0.11 (range, 0.04â 6.6) kt yr 1. Observed changes in plume composition highlight the coherent geochemical behavior of HCl, HF, HBr, and HI during magmatic degassing, and strong fractionation of these species with respect to SO2.
    Description: Published
    Description: Q08008
    Description: partially_open
    Keywords: bromine and iodine in volcanic gases ; halogen atmospheric chemistry ; volcanic degassing ; volcanic plumes ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 27
    Publication Date: 2017-04-04
    Description: A new method for extracting dissolved gases in natural waters has been developed and tested, both in the laboratory and in the field. The sampling device consists of a polytetrafluroethylene (PTFE) tube (waterproof and gas permeable) sealed at one end and connected to a glass sample holder at the other end. The device is pre-evacuated and subsequently dipped in water, where the dissolved gases permeate through the PTFE tube until the pressure inside the system reaches equilibrium. A theoretical model describing the time variation in partial gas pressure inside a sampling device has been elaborated, combining the mass balance and ‘‘Solution-Diffusion Model’’ which describes the gas permeation process through a PTFE membrane). This theoretical model was used to predict the temporal evolution of the partial pressure of each gas species in the sampling device. The model was validated by numerous laboratory tests. The method was applied to the groundwater of Vulcano Island (southern Italy). The results suggest that the new sampling device could easily extract the dissolved gases from water in order to determine their chemical and isotopic composition.
    Description: - European Social Fund.
    Description: Published
    Description: Q09005
    Description: partially_open
    Keywords: dissolved gases ; helium isotope ; PTFE membrane ; Vulcano Island ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.02. Hydrology::03.02.07. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 28
    Publication Date: 2017-04-04
    Description: Ground-based measurements of volcanic sulfur dioxide fluxes are important indicators of volcanic activity, with application in hazard assessment, and understanding the impacts of volcanic emissions upon the environment and climate. These data are obtained by making traverses underneath the volcanic plume a few kilometers from source with an ultraviolet spectrometer, measuring integrated SO2 concentrations across the plume’s cross section, and multiplying by the plume’s transport speed. However, plume velocities are usually derived from ground-based anemometers, located many kilometers from the traverse route and hundreds of meters below plume altitude, complicating the experimental design and introducing large flux (can be 〉100%) errors. Here we present the first report of a single instrument capable of (accurate) volcanic SO2 flux measurements. This device records integrated SO2 concentrations and plume heights during traverses. Between traverses, two in-plume SO2 time series are measured from underneath the plume with the instrument, corresponding to zenith and inclined (user-specified angle from vertical in the direction of the volcano) fields of view, respectively. The distance between the points of intersection of the two views with the plume is found on the basis of the determined plume height, and the two signals are cross-correlated to determine the lag between them, enabling accurate derivation of the wind speed. We present flux data (with errors ±12%) obtained in this way at Mt. Etna during July 2004.
    Description: Published
    Description: Q02003
    Description: partially_open
    Keywords: DOAS ; volcanic SO2 emissions. ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 29
    Publication Date: 2017-04-04
    Description: The main goal of this work is to provide a probability map for the next moderate to large earthquakes (M 〉= 5.5) in Italy. For this purpose we apply a new nonparametric multivariate model to characterize the spatiotemporal distribution of earthquakes. The method is able to account for tectonics/physics parameters that can potentially influence the spatiotemporal variability and tests their relative importance; moreover, it allows straightforward testing of a variety of hypothesis, such as Seismic Gap, Cluster, and Poisson hypothesis. The method has been applied to Italian seismicity of the last four centuries for earthquakes with M 〉= 5.5. Italy has been divided into 61 irregular zones representing areas with homogeneous tectonic regime resulting from active stress data. Besides the magnitude and the time of the earthquakes, the model includes information on the tectonic stress regime, the homogeneity of its orientation, the number of active faults, the dimension of the area and the homogeneity of the topography. The time distribution of the M 〉= 5.5 earthquakes appears clustered in time for a few years after an event, and then the distribution becomes similar to a memoryless Poisson process, leading to a time-dependent probability map. This map shows that the most likely regions where the next moderate to large earthquakes may occur are Friuli, Umbria- Marche, and part of Southern Apennines and the Calabrian arc.
    Description: Published
    Description: 1-15
    Description: reserved
    Keywords: earthquake probability ; Italy ; seismotectonic regionalization ; statistical modeling ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability
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  • 30
    Publication Date: 2012-02-03
    Description: Slow earthquakes and afterslips prove that the Earth does not have just two response time scales, i.e. that of tectonic loading and that of regular earthquakes. A swarm of slow earthquakes, with time constants of the order of hundreds of seconds, has been detected by a laser interferometer below the Gran Sasso massif (Italy). We analyse and model these observations to identify a very plausible source in a local fault, with no historic seismic behavior. While slow earthquakes occurring in subduction zones, and at the transition between locked and stably sliding segments of the San Andreas fault, are often associated with seismic events, in the case of the Apennines there is no correlation between local seismicity and slow earthquakes. Slow earthquakes, therefore, may also represent a specific failure behavior for a seismically locked fault, adding further complexity to the interpretation of geologic data for seismic hazard estimates.
    Description: Published
    Description: 2219
    Description: open
    Keywords: Earthquake dynamics and mechanics ; Seismic hazard assessment and prediction ; Seismicity and seismotectonics ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
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  • 31
    Publication Date: 2017-04-04
    Description: This paper reports the use of diffusive tubes in determining HF, HCl, and SO2 in the volcanic plume of Mount Etna in an attempt to highlight the potential of this method in studying volcanoes. In a first application a network of 18 diffusive tubes was installed on Etna flanks, aimed at evaluating the atmospheric dispersion of the volcanic plume on a local scale. Results showed a monotonic decrease in volatile air concentrations with distance from the craters (HF from 0.15 to 〈0.003 mmol m3, HCl from 2 to 〈0.01 mmol m3, and SO2 from 11 to 0.04 mmol m3), revealing the prevalently volcanic contribution. Matching of SO2/HCl and HCl/HF volatile ratios with contemporaneous measurements at the summit craters validated the use of diffusive tubes in tracing the chemical features of a volcanic plume from remote locations. A first tentative assessment of dry deposition rates of volcanogenic acidic gases was also made, yielding 2.5 74 t d1 (SO2), 0.6 17 t d1 (HCl), and 0.02 0.6 t d1 (HF) and revealing the potential environmental impact of gas emissions. In a second experiment, carried out during the recent October 2002 to February 2003 eruption of Etna, diffusive tubes provided a continuous record of the chemical composition of the eruptive plume from a safe distance of 1 km from the vents, thus considerably decreasing the risks involved in sampling. This highlighted a clear time decrease in SO2 concentrations and SO2/HCl ratios, which was interpreted as due to progressive exhaustion of volatile degassing and eruption energy.
    Description: Published
    Description: D21308
    Description: partially_open
    Keywords: volcanic plumes ; impact of volcanic emissions ; sulfur and halogens chemistry ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 32
    Publication Date: 2017-04-04
    Description: In the last 13 years gas emissions from both the summit and the flanks of Mount Etna volcano have been monitored using remote sensing techniques (COSPEC, and FTIR since 2000) and on-site monitoring devices. The SO2 flux variations (600 to 25,000 Mg/day) indicated: (i) low values coinciding with deep seismicity prior to eruptions or/and preceding increases in summit volcanic activity; (ii) increasing trends tracking the ascent of fresh magma within the shallow feeding system and whose rate seems proportional to the speed of magma rise; (iii) decreasing trends related to progressive degassing of magma batches; (iv) an imbalance between the amount of magma erupted and that which contributed the SO2 emission (~ 13 % of the degassing magma having been erupted during the studied period), implying that magma degassing is dominantly intrusive; (v) a seasonal component, probably due to variations in solar zenith angle, meteorological parameters and, possibly, tidal forces.FTIR monitoring allowed to recognize significant variations of SO2/HCl and SO2/HF ratios in the volcanic plume which, combined with COSPEC data, provided new insight into the dynamics of ascent and degassing of discrete magma bodies. Strong variations in CO2-rich soil degassing are interpreted as markers of gradual magma ascent from great depth (〉10 km) to the upper (〈5 km) feeding system of Mt. Etna. These changes appear to precede increases in SO2 plume flux at the craters and, so, provide additional constraints upon the interpretation of COSPEC data and the modeling of magma rise at that volcano.
    Description: Published
    Description: 111-128
    Description: partially_open
    Keywords: Gas emissions ; Mt. Etna ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 33
    Publication Date: 2017-04-04
    Description: The Neapolitan volcanic region is located within the graben structure of the Campanian Plain (CP), which developed between the western sector of the Appenine Chain and the eastern margin of the Tyrrhenian Sea. Two volcanic areas, spaced less than 10 km apart, are situated within the CP: the Somma-Vesuvius Volcano (SVV) and the Phlegraean Volcanic District (PVD). SVV is a typical stratovolcano, whereas PVD, including Campi Flegrei, Procida, and Ischia, is composed mostly of monogenetic centers. This contrast is due to different magma supply systems: a widespread fissure-type system beneath the PVD and a central-type magma supply system for the SVV. Volcanological, geophysical, and geochemical data show that magma viscosity, magma supply rate, and depth of magma storage are comparable at PVD and SVV, whereas different structural arrangements characterize the two areas. On the basis of geophysical data and magma geochemistry, an oblique-extensional tectonic regime is proposed within the PVD, whereas in the SVVarea a compressive stress regime dominates over extension. Geophysical data suggest that the area with the maximum deformation rate extends between the EW-running 41st parallel and the NE-running Magnaghi-Sebeto fault systems. The PVD extensional area is a consequence of the Tyrrhenian Sea opening and is decoupled from the surrounding areas (Roccamonfina and Somma-Vesuvius) which are still dominated by Adriatic slab dynamics. Spatially, we argue that the contribution of the asthenospheric wedge become much less important from W-NW to E-SE in the CP. The development of the two styles of volcanism in the CP reflects the different tectonic regimes acting in the area.
    Description: Published
    Description: 1-25
    Description: partially_open
    Keywords: Volcanic styles ; Tectonic setting ; Neapolitan volcanic region ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 34
    Publication Date: 2017-04-04
    Description: From December 2002 to July 2003, Stromboli volcano was characterized by a new effusive stage of eruption after a period of extraordinary strombolian activity. Signals recorded in two continuous monitoring stations during the eruption, which have already been presented in very recent papers, evidenced anomalies in the CO2 flux just before the onset of the eruption. A more detailed analysis carried out on the data subset acquired during the eruption, integrated by daily field observations of the scientific personnel working at the volcanological observatory in Stromboli, showed that CO2 flux and soil temperature are strictly related to volcanic events. Furthermore, the relative minima and maxima of the two parameters showed a strong correlation with wind speed and direction. This fact was especially true at the summit station, whereas at the coastal sites seasonal and meteorological effects masked the volcanic signal. The analysis of the wind data, particularly the relationships between wind speed and direction, air and soil temperature, and local circulation of atmospheric air masses revealed that during the eruption, in the summit area of Stromboli air movements were not only related to atmospheric circulation but were also significantly affected, and in certain cases caused, by volcanic activity. This conclusion was reached by observing several anomalies, such as the discrepancies in the wind direction between the two stations, higher air temperatures at the summit site, and inversion of direction for wind before and after the reopening of the conduit in a major explosion on 5 April 2003. The relationships found between volcanic activity, soil temperatures, CO2 fluxes, and wind speed and direction indicate that soil temperature measurements, in an open conduit volcano such as in this case, could be used to monitor the level of volcanic activity, along with CO2 flux. Furthermore, the possible volcanic origin of a peculiar type of air circulation identified in the summit area of Stromboli suggests that the separation between volcanic and atmospheric signals might not be obvious, requiring monitoring over a wide area, rather than a single location.
    Description: Published
    Description: Q12001
    Description: partially_open
    Keywords: carbon dioxide flux ; continuous monitoring ; soil temperature ; wind ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 35
    Publication Date: 2017-04-04
    Description: Marked increases of CO2, H2 and He dissolved in thermal waters and changes in the dissolved carbon isotopic composition, were observed at Stromboli before the 28 December 2002 eruption and before a violent explosive paroxysm occurred on 5 April 2003. High anomalous CO2 flux values were recorded at the crater rim since a week before the eruption onset. The first anomalies in the thermal waters (dissolved CO2 amount) appeared some months before the eruption, when magma column rose at a very high level in the conduit. High peaks of dissolved H2 and He were recorded a few days before the paroxysm. Carbon isotopic composition indicates a magmatic origin of the dissolved CO2 whose increase, together with those of H2 and He, is attributed to an increasing output of deep gases likely produced by depressurization of a rising batch of a deep gas-rich magma, whose fragments have been emitted during the explosion.
    Description: Italian Civil Protection
    Description: Published
    Description: L07620
    Description: partially_open
    Keywords: Stromboli ; geochemical precursors ; CO2 flux ; pH ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 36
    Publication Date: 2017-04-04
    Description: The Jalisco Block (JB) is a geologically and tectonically complex part of northwestern Mexico characterized by active subduction-type volcanism, rifting, and old stable structures. Thermal springs and groups of springs are widely distributed over JB. Bubbling gas from seven thermal springs located within different tectonic environments of the JB was analyzed for He, 20Ne, and N2 concentrations and d15N ratios. All gases are N2-dominant (〉84%) with the exception of one sample (Rio´ Purificacio´n), which has a significant CH4 content (about 50%). All collected gas samples are relatively high in He, up to 1500 ppm vol and with 3He/4He values ranging from 0.6 to 4.5 Ra. All measured nitrogen isotope ratios are heavier than air with d15N values ranging from 0.5 to 5.0%. The relative N2 excess with respect to air-saturated water computed on the basis of N2 and 20Ne contents indicates the contribution of a nonatmospheric N2 source. All the samples show a good correlation between d15N and the relative excess of N2 with d15N +5.3% for the maximum N2 excess of 100%. Due to a presumed lack of seafloor sediment involved in the subduction process, such a d15N positive value seems to reflect the addition to the fluids of a heavy nitrogen originating from metamorphism processes of rocks occurring within the overlying continental crust.
    Description: Published
    Description: 1-9
    Description: partially_open
    Keywords: bubbling gases ; forearc region ; Jalisco Block-Mexico ; nitrogen isotopes ; subduction-related volcanism ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 37
    Publication Date: 2017-04-04
    Description: In this paper we present the first geochemical data set regarding long-term monitoring of dissolved gases in thermal waters from a seismic area. Three sites in Umbria (Central Apennines, Italy) were studied both for the chemical and for the helium isotopic composition of the dissolved gases. Data were collected during and after the seismic crisis that struck the region in 1997â 1998. The chemical composition of the dissolved gases revealed that a CO2-rich gas phase was always mixed with an atmospheric-derived component dominated by N2. A normal faulting marked the beginning of the seismic activity enhancing the release of CO2 on a regional scale. Variations in both the chemical and isotopic compositions of the dissolved gases were also observed as preseismic, synseismic, and postseismic phenomena related to the seismic shock of March 1998. Those geochemical modifications were interpreted as being the consequence of a drop in the CO2 degassing rate, in good agreement with the compressive focal mechanism of that seismic event. Furthermore, this interpretation was also consistent with the geologic and tectonic setting of the study area and induced us to postulate that changes in the local rock permeability, due to crustal deformations (i.e., coseismic deformation and postseismic release), were responsible for the geochemical modifications observed. On the basis of the foregoing, we have concluded that the geochemistry of dissolved gases in groundwaters represents a useful tool for the investigation of the relationships between circulating fluids and seismic activity.
    Description: Published
    Description: partially_open
    Keywords: dissolved gases ; geochemistry ; seismic areas ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data
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  • 38
    Publication Date: 2017-04-04
    Description: The performance of a newly-developed portable gas analyzer, capable of real-time measurement of CO2, SO2 and H2S concentrations in volcanic gases, was tested at La Fossa Crater, Vulcano Island. The gas analyzer was used to acquire about 3000 determinations over the fumarolic field, allowing the definition of its chemical structure and heterogeneity. Our high-resolution analysis reveals that, in December 2004, the La Fossa fumarolic field was characterized by an oxidized inner core (SO2/H2S ratios of 3), and by more reducing conditions on its northern edge (SO2/H2S ratios of 1; range: 0.2–3.3). CO2/(SO2+H2S) molar ratios averaged 35 ± 21, with overlapping compositions for rim and inner crater fumaroles. S-poor compositions (CO2/(SO2+H2S) 50) characterized the field margins, probably due to deposition of native sulfur. Based on the above data and an SO2 flux of 18 ± 3 t.d-1, we estimate CO2 and H2S output rates from the volcano of 420 ± 250 and 4 ± 2 t.d-1, respectively.
    Description: Published
    Description: L13309
    Description: partially_open
    Keywords: electrochemical sensors ; fumarolic gases ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 39
    Publication Date: 2017-04-04
    Description: We present the first regional map of CO2 Earth degassing from a large area (most of central and south Italy) derived from the carbon of deep provenance dissolved in the main springs of the region. The investigation shows that a globally significant amount of deeply derived CO2 (10% of the estimated global CO2 emitted from subaerial volcanoes) is released by two large areas located in western Italy. The anomalous flux of CO2 suddenly disappears in the Apennine in correspondence to a narrow band where most of seismicity concentrates. Here, at depth, the gas accumulates in crustal traps generating CO2 overpressurized reservoirs which induce seismicity.
    Description: Published
    Description: 1-4
    Description: partially_open
    Keywords: Carbon dioxide ; Central Italy ; Southern Italy ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 40
    Publication Date: 2017-04-04
    Description: A major explosion occurred at Stromboli on April 5 2003, being the most powerful event over a period of exceptional eruptive activity lasting from December to July. Here, we describe results from a network of diffusive tubes set up on the Stromboli’s summit area, aimed at a characterisation of plume composition (SO2, HCl, HF) prior to and after April 5. Data analysis revealed anomalous sulphur degassing 2–3 days before the event, when SO2/HCl ratios (9) significantly higher than those typical of quiescent degassing (1) were recorded. We interpret this exceptional plume signature as an evidence of S-rich magmas ascending in the shallow plumbing system, and propose high SO2/HCl as a potential precursor of major explosions on the volcano. The post-April 5 phase was characterised by time-decreasing SO2/HCl and SO2/HF plume ratios, ascribed to declining magma feeding as a prelude to restoration of ‘‘normal’’ Strombolian activity.
    Description: Published
    Description: L14607
    Description: partially_open
    Keywords: magmatic degassing ; paroxysm ; Stromboli ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 41
    Publication Date: 2017-04-04
    Description: On 2nd/3rd November 2002, a huge amount of gas, mainly composed of CO2, was suddenly released from the sea bottom off the coast of Panarea, producing a ‘‘crater’’20 by 10 meters wide and 7 meters deep. The gas output was estimated to be 109 l/d, two orders of magnitude higher than that measured in the 1980s. The anomalous degassing rate lasted for some weeks, slowly decreasing to an almost constant rate of about 4 x 107 l/d after two months. The geothermo- barometric estimations revealed an increase of both the temperature and pressure in the geothermal system feeding the sampled vents. The 3He/4He ratios were similar to those measured in nearby Stromboli. We have monitored the area for the last two decades, and based on our intensive and extensive geochemical measurements, have ascertained that the geothermal reservoir has lost its steady state. We maintain that a new magmatic input caused these phenomena.
    Description: - Istituto Nazionale di Geofisica e Vulcanologia, Osservatorio Vesuviano, Naples, Italy. - Istituto Nazionale di Geofisica e Vulcanologia, Sezione di Palermo, Palermo, Italy. - Dipartimento Chimica e Fisica della Terra ed Applicazioni, Palermo, Italy.
    Description: Published
    Description: L07619
    Description: partially_open
    Keywords: Submarine degassing ; magmatic fluids ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 42
    Publication Date: 2017-04-04
    Description: Five gas discharges in the area of Mount Etna volcano (Italy) and in the near Hyblean plateau have been monitored since 1996. All the emissions displayed low contributions from crustal fluids, whereas magmatic gases were the main component. Selective dissolution of these gases into hydrothermal aquifers has been recognized and modeled, allowing us to calculate the original composition of the magma-released gases. The inferred composition of the magmatic gases exhibits synchronous variations of He/Ne and He/CO2 ratios, which are coherent with the magma degassing process. On the basis of numerical simulations of volatile degassing from Etnean basalts we have computed the initial and final pressures of the magma batches feeding the emissions. We thus can define the levels of the Etna plumbing system where magmas are stored. Pressure values were around 360 and 160 MPa for initial and final stages, respectively, meaning related depths of about 10 and 3 km below sea level, matching those obtained by geophysical investigations for the deep and shallow magma reservoirs. In addition, we have been able to recognize episodes of magma migration from the deeper reservoir toward the shallow one. An important magma injection into the shallow storage volume was detected during the onset of the 2001 eruption (17 July). No further injection had taken place during this period until September 2001, providing a possible reason for the quick exhaustion of the eruption. In view of this we suggest that the sampled emissions are a powerful geochemical tool to investigate the Etna’s plumbing system and its magma dynamics, as well as the development of eruptive events.
    Description: Published
    Description: 2463
    Description: partially_open
    Keywords: gas geochemistry ; magma degassing ; modeling ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 43
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    American Geophysical Union
    In:  Etiope G., Caracausi A., Favara R., Italiano F., Baciu C. (2002) Methane emission from the mud volcanoes of Sicily (Italy). Geoph. Res. Letters 29, 14340-14343.
    Publication Date: 2017-04-04
    Description: The paper ‘‘Methane emission from the mud volcanoes of Sicily (Italy)’’ by Etiope et al. [2002] represents the first report ever done on experimental CH4 output data from subaerial mud volcanoes (MV). A review of available CH4 flux data and detailed discussion about the global implications of mud volcanic CH4 emission has been made elsewhere [Etiope and Klusman, 2002; Morner and Etiope, 2002]. [2] The comment by Kopf [2003] contributes to open discussions and to make the readership aware on how important this subject is. In this reply we wish to clarify that precise data of CH4 flux from geologic sources are beginning to be available only now. It would be opportune that the MV-expert community could agree in using a common unit for the gas flux. We propose t y 1 and Mt y 1, and not metres cubed, consistently with the data reported for the methane sources/sinks budget by the IPCC. [3] Sicilian MVs, the first to be measured in detail, are considerably much smaller than the Azeri Ashgil MV, mentioned by Kopf [2003], and it is therefore obvious to expect a lower gas flux. Anyway the Dashgil mud volcano flux data are not based on exact measurements but only on visual estimates of the bubbles [Hovland et al., 1997]. In order to fully reply to Kopf [2003], hereafter we briefly discuss the problem of how to estimate the total number of MVs in the world and present new data from other European MVs, recently investigated. Finally, we outline the global importance of mud volcanic CH4 emission, as Kopf [2003] and recent literature is stressing.
    Description: Published
    Description: 1094
    Description: partially_open
    Keywords: methane ; mud volcanoes ; helium ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate ; 02. Cryosphere::02.03. Ice cores::02.03.02. Atmospheric Chemistry ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
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  • 44
    Publication Date: 2017-04-04
    Description: Five years of gas monitoring from selected sites suggest that Mt Etna’s plumbing system is much more extensive than previously reported. It extends at least 40 km SW from the volcano’s boundary along the NE-SW regional fault, where it discharges about 200 tons/day of gas, containing helium with mantle-type isotopic composition. Synchronous variations of 3He/4He isotopic ratios in gas sampled at sites located 60 kilometers apart have allowed us to detect pulses of ascending magma in the plumbing system, thus providing a powerful tool for eruption forecasting. Following summer 2001 eruption, the still increasing trend of the 3He/4He ratios indicates that magma storage is even now occurring at a shallow depth. Hence, the volcano maintains a high capacity to re-erupt within the next few months.
    Description: Published
    Description: 1057
    Description: partially_open
    Keywords: helium isotopes ; geochemical monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 45
    Publication Date: 2017-04-04
    Description: We report results on the measured high 3He/4He isotope ratio in western Sicily, interpreted together with the heat data. The study of this sector of the Europe-Africa interaction is crucial to a better understanding of the tectonics and the geodynamical evolution of the central Mediterranean area. The estimated mantle-derived helium fluxes in the investigated areas are up to 2–3 orders of magnitude greater than those of a stable continental area. The highest flux, found in the southernmost area near the Sicily Channel, where recent eruptions of the Ferdinandea Island occurred 20 miles out to sea off Sciacca, has been associated with a clear excess of heat flow. Our results indicate that there is an accumulation of magma below the continental crust of western Sicily that is possibly intruding and out-gassing through roughly N-S trending deep fault systems linked to the mantle, that have an extensional component. Although the identification of these faults is not sufficiently constrained by our data, they could possibly be linked to the pre-existing faults that originated during the Mesozoic extensional-transtensional tectonic phases.
    Description: Published
    Description: L04312
    Description: partially_open
    Keywords: helium isotopes ; heat production ; tectonics ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.03. Heat flow ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.03. Heat generation and transport ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 46
    Publication Date: 2017-04-04
    Description: We analyse seismograms of the slump episodes at Stromboli on December 30, 2002. Using a simple single force model, we estimate the volume involved in the individual subevents and attempt a chronological reconstruction of the whole process. Our results indicate the occurrence of two main events that could be interpreted as a submarine slump, which caused the observed tsunami, and a subaerial slump, which did not produce destructive sea waves. A total volume of about 20 106 m3 results for the submarine event, which developed over about 2 minutes with several distinct detachments, the first and largest displacing a volume of 10.8 106 m3. The second, subaerial, slump involved at least 2.5 106 m3, in about 90 s. A large long period pulse is also recognizable in the seismograms of the Stromboli station. We tentatively interpret this feature as tilt caused by the water load associated with the inundation in the Ficogrande area, on the northeastern side of the island.
    Description: Published
    Description: (L02605)
    Description: reserved
    Keywords: Stromboli Volcano ; seismological description ; Fractures and faults ; Structural Geology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology
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  • 47
    Publication Date: 2017-04-04
    Description: A field survey performed during the 1997 Umbria-Marche earthquake sequence led us to recognize ground and pavement ruptures associated with the three largest shocks (M〉= 5.7). The ruptures are concentrated in narrow bands that, in part, are on and near previously mapped high-angle normal fauts. The geometry of the ground deformation is consistent with the NE-trending extension indicated by CMT focal solutions of the mainshocks. The distribution of aftershocks suggests that the three mainshocks occurred on ~40 degree SW-dipping normal faults. Geological investigations, modelling of expected coseismic elevation changes, and seismic data, suggest that the surface deformation is not the direct result of primary rupture of faults at depth.
    Description: Published
    Description: 895-898
    Description: reserved
    Keywords: Structural geology ; Fractures and faults ; Seismology ; Seismicity and seismotectonics ; Europe ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology
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  • 48
    Publication Date: 2017-04-04
    Description: Recent examinations of the chemical fluxes through convergent plate margins suggest the existence of significant mass imbalances for many key species: only 20–30% of the to-the-trench inventory of large-ion lithophile elements (LILE) can be accounted for by the magmatic outputs of volcanic arcs. Active serpentinite mud volcanism in the shallow forearc region of the Mariana convergent margin presents a unique opportunity to study a new outflux: the products of shallow-level exchanges between the upper mantle and slab-derived fluids. ODP Leg 125 recovered serpentinized harzburgites and dunites from three sites on the crests and flanks of the active Conical Seamount. These serpentinites have U-shaped rare earth element (REE) patterns, resembling those of boninites. U, Th, and the high field strength elements (HFSE) are highly depleted and vary in concentration by up to 2 orders of magnitude. The low U contents and positive Eu anomalies indicate that fluids from the subducting Pacific slab were probably reducing in nature. On the basis of substantial enrichments of fluid-mobile elements in serpentinized peridotites, we calculated very large slab inventory depletions of B (79%), Cs (32%), Li (18%), As (17%), and Sb (12%). Such highly enriched serpentinized peridotites dragged down to depths of arc magma generation may represent an unexplored reservoir that could help balance the input-output deficit of these elements as observed by Plank and Langmuir (1993, 1998) and others. Surprisingly, many species thought to be mobile in fluids, such as U, Ba, Rb, and to a lesser extent Sr and Pb, are not enriched in the rocks relative to the depleted mantle peridotites, and we estimate that only 1–2% of these elements leave the subducting slabs at depths of 10 to 40 km. Enrichments of these elements in volcanic front and behind-the-front arc lavas point to changes in slab fluid composition at greater depths.
    Description: Published
    Description: 1-24
    Description: partially_open
    Keywords: Serpentinite ; Ocean Drilling Program ; Forearc ; Mantle ; Marianas ; Subduction ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 49
    Publication Date: 2017-04-04
    Description: We present an updated present-day stress data compilation for the Italian region and discuss it with respect to the geodynamic setting and the seismicity of the area. We collected and analyzed 190 new stress data from borehole breakouts, seismicity, and active faults and checked in detail the previous compilation [Montone et al., 1999]. Our improved data set consists of 542 data, 362 of which with a reliable quality for stress maps. The Italian region is well sampled, allowing the computation of constrained smoothed stress maps; for surrounding regions we added the World Stress Map 2003 release data. These maps depict the active stress conditions and, in the areas where the data are sparse, contribute to understand the relationship between active stress, past tectonic setting, and the seismicity of the study region. The new data are particularly representative along the northern Apennine front, from the Po Plain to offshore the Adriatic, and along the southern Tyrrhenian Sea, north of Sicily, where they point out a compressive tectonic regime. In the Alps both compressive and transcurrent regimes are observed. Our data also confirm that the whole Apenninic belt and the Calabrian arc are extending. Along the central Adriatic coast, changes from one stress regime to another are shown by abrupt variations in the minimum horizontal stress directions. Other gentler stress rotations, as, for instance, from the southern Apennines to the Calabrian arc or along the northern Apennines, follow the curvature of the arcs and are not associated to a stress regime variation.
    Description: Published
    Description: (B10410)
    Description: partially_open
    Keywords: active stress ; earthquakes ; borehole breakouts ; crust and lithosphere ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress
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  • 50
    Publication Date: 2017-04-04
    Description: We defend the two statements of ours in Michelini and Lomax [2004] about Zhang and Thurber [2003] regarded by Thurber and Zhang as incorrect and misleading.
    Description: Published
    Description: partially_open
    Keywords: earthquake location ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution
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  • 51
    Publication Date: 2017-04-04
    Description: The 1995–2004 seismicity in the Gargano Promontory (hereafter GP) foreland at the transition zone between Southern and Northern Apennine belts (Italy) is analyzed with the aim to put constraints on the present-day kinematics of this key-area of the foreland. The spatial distribution of earthquakes and 54 calculated focal mechanisms show that that the main GP ruptures develop along E-W striking, right-lateral strike-slip faults and NW- SE, normal to left-lateral second-order faults that move in response to a prevailing NW-SE compression (i.e. NE-SW extension). Tacking into account the depth of the relocated seismicity and the available geological information, we propose that the GP shear zone represents an E-W striking, major crustal discontinuity separating sectors of the foreland that move in response to the higher, northeastward propagation velocity of the thrust front of the Northern Apennines with respect to that of the Southern Apennines.
    Description: Published
    Description: open
    Keywords: Seismicity ; seismotectonics ; geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous
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  • 52
    Publication Date: 2021-05-19
    Description: The low frequency sea surface temperature (SST) variability in the North Atlantic is studied using the Center for Ocean-Land-Atmosphere Studies (COLA) anomaly coupled general circulation model. The main focus is placed on the relative roles of stable and unstable coupled feedbacks in inducing the low frequency SST variability in various regions of the North Atlantic. To examine this question, a recently developed coupling technique, interactive ensembles, is applied to reduce the strength of “weather noise” in the model and isolate the atmospheric feedback to boundary forcing.
    Description: Published
    Keywords: Sea surface temperature
    Repository Name: AquaDocs
    Type: Journal Contribution , Refereed , Article
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  • 53
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 20 (2005): PA4011, doi:10.1029/2005PA001150.
    Description: Monthly samples of stratified plankton tows taken from the slope waters off Cape Cod nearly 25 years ago are used to describe the seasonal succession of planktonic foraminifera and their oxygen isotope ratios. The 15°C seasonal cycle of sea surface temperature (SST) accounts for a diverse mixture of tropical to subpolar species. Summer samples include various Globigerinoides and Neogloboquadrina dutertrei, whereas winter and early spring species include Globigerina bulloides and Neogloboquadrina pachyderma (dextral). Globorotalia inflata lives all year but at varying water depths. Compared with the fauna in 1960–1961 (described by R. Cifelli), our samples seem warmer. Because sea surface salinity varies little during the year, δ18O is mostly a function of SST. Throughout the year, there are always species present with δ18O close to the calculated isotopic equilibrium of carbonate with surface seawater. This raises the possibility that seasonality can be estimated directly from the range of δ18O in a sediment sample provided that the δ18O-salinity relationship is the same as today.
    Description: Funding was provided by NSF grant OCE-0117149.
    Keywords: Plankton tow ; Foraminifera ; Stable isotopes
    Repository Name: Woods Hole Open Access Server
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  • 54
    Publication Date: 2022-05-25
    Description: Author Posting. © Cambridge University Press, 2000. This article is posted here by permission of Cambridge University Press for personal use, not for redistribution. The definitive version was published in Journal of Fluid Mechanics 403 (2000): 37-65, doi:10.1017/S0022112099006916.
    Description: The dynamics of expanding domes of isothermal lava are studied by treating the lava as a viscoplastic material with the Herschel–Bulkley constitutive law. Thin-layer theory is developed for radially symmetric extrusions onto horizontal plates. This provides an evolution equation for the thickness of the fluid that can be used to model expanding isothermal lava domes. Numerical and analytical solutions are derived that explore the effects of yield stress, shear thinning and basal sliding on the dome evolution. The results are briefly compared with an experimental study. It is found that it is difficult to unravel the combined effects of shear thinning and yield stress; this may prove important to studies that attempt to infer yield stress from morphology of flowing lava.
    Description: The financial support of an EPSRC Advanced Fellowship is gratefully acknowledged by R.V. C. N. J. B. was partially supported by the NSF Grant OCE-9616017 and an EPSRC Visiting Fellowship Grant GR/M50409.
    Keywords: Isothermal lava domes
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  • 55
    Publication Date: 2022-05-25
    Description: Author Posting. © Cambridge University Press, 2004. This article is posted here by permission of Cambridge University Press for personal use, not for redistribution. The definitive version was published in Parasitology 128 (2004): 577-584, doi:10.1017/S0031182004005025.
    Description: Human serum high-density lipoprotein (HDL) is necessary and sufficient for the short-term maintenance of Plasmodium falciparum in in vitro culture. However, at high concentrations it is toxic to the parasite. A heat-labile component is apparently responsible for the stage-specific toxicity to parasites within infected erythrocytes 12–42 h after invasion, i.e. during trophozoite maturation. The effects of HDL on parasite metabolism (as determined by nucleic acid synthesis) are evident at about 30 h after invasion. Parasites treated with HDL show gross abnormalities by light and electron microscopy.
    Description: Professor Hajduk was supported by NIH. Professor Day was supported by a Research Leave Fellowship from The Wellcome Trust. Dr Imrie and Ms Carter were supported by Programme Grant funding awarded to Professor Day from The Wellcome Trust. Dr Ferguson was supported by an equipment grant from The Wellcome Trust.
    Keywords: Plasmodium falciparum ; High density lipoprotein
    Repository Name: Woods Hole Open Access Server
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  • 56
    Publication Date: 2022-05-25
    Description: Author Posting. © Cambridge University Press, 2004. This article is posted here by permission of Cambridge University Press for personal use, not for redistribution. The definitive version was published in Geological Magazine 141 (2004): 195-207, doi:10.1017/S001675680400891X.
    Description: Because magmatism associated with subduction is thought to be the principal source for continental crust generation, assessing the relative contribution of pre-existing (subducted and assimilated) continental material to arc magmatism in accreted arcs is important to understanding the origin of continental crust. We present a detailed Nd isotopic stratigraphy for volcanic and volcaniclastic formations from the South Mayo Trough, an accreted oceanic arc exposed in the western Irish Caledonides. These units span an arc–continent collision event, the Grampian (Taconic) Orogeny, in which an intra-oceanic island arc was accreted onto the passive continental margin of Laurentia starting at [similar] 475 Ma (Arenig). The stratigraphy corresponding to pre-, syn- and post-collisional volcanism reveals a progression of [varepsilon]Nd(t) from strongly positive values, consistent with melt derivation almost exclusively from oceanic mantle beneath the arc, to strongly negative values, indicating incorporation of continental material into the melt. Using [varepsilon]Nd(t) values of meta-sediments that represent the Laurentian passive margin and accretionary prism, we are able to quantify the relative proportions of continent-derived melt at various stages of arc formation and accretion. Mass balance calculations show that mantle-derived magmatism contributes substantially to melt production during all stages of arc–continent collision, never accounting for less than 21% of the total. This implies that a significant addition of new, rather than recycled, continental crust can accompany arc–continent collision and continental arc magmatism.
    Keywords: Grampian Orogeny ; Western Ireland ; Continental crust ; Nd isotopes ; Laurentia ; Iapetus Ocean
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  • 57
    Publication Date: 2022-05-25
    Description: Author Posting. © Cambridge University Press, 2004. This article is posted here by permission of Cambridge University Press for personal use, not for redistribution. The definitive version was published in Journal of Fluid Mechanics 516 (2004): 83-113, doi:10.1017/S0022112004000473.
    Description: Oceanic observations indicate that abyssal mixing tends to be localized to regions of rough topography. How localized mixing interacts with the ambient fluid in a stratified, rotating system is an open question. To gain insight into this complicated process laboratory experiments are used to explore the interaction of mechanically induced boundary mixing and an interior body of linearly stratified rotating fluid. Turbulence is generated by a single vertically oscillating horizontal bar of finite horizontal extent, located at mid-depth along the tank wall. The turbulence forms a region of mixed fluid which quickly reaches a steady-state height and collapses into the interior. The mixed-layer thickness, $h_m\,{\sim}\,\gamma ({\omega}/{N})^{1/2}$, is spatially uniform and independent of the Coriolis frequency $f$. $N$ is the initial buoyancy frequency, $\omega$ is the bar oscillation frequency, and $\gamma\,{\approx}\,1$ cm is an empirical constant determined by the bar geometry. Surprisingly, the export of mixed fluid does not occur as a boundary current along the tank perimeter. Rather, mixed fluid intrudes directly into the interior as a radial front of uniform height, advancing with a speed comparable to a gravity current. The volume of mixed fluid grows linearly with time, $V\,{\propto}\,({N}/{f})^{3/2}h_m^3 \textit{ft}$, and is independent of the lateral extent of the mixing bar. Entrainment into the turbulent zone occurs principally through horizontal flows at the level of the mixing that appear to eliminate export by a geostrophic boundary flow. The circulation patterns suggest a model of unmixed fluid laterally entrained at velocity $u_e \,{\sim}\,Nh_m $ into the open sides of a turbulent zone with height $h_{m}$ and a length, perpendicular to the boundary, proportional to $L_f \,{\equiv}\,\gamma ({\omega}/{f})^{1/2}$. Here $L_{f}$ is an equilibrium length scale associated with rotational control of bar-generated turbulence. The model flux of exported mixed fluid $Q\,{\sim}\,h_m L_f u_e$ is constant and in agreement with the experiments.
    Description: This work was supported by the Ocean Ventures Fund, the Westcott Fund and the WHOI Academic Programs Office. Financial support was also provided by the National Science Foundation through grant OCE-9616949.
    Keywords: Abyssal mixing ; Stratified rotating system
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  • 58
    Publication Date: 2022-05-25
    Description: Author Posting. © Cambridge University Press, 2004. This article is posted here by permission of Cambridge University Press for personal use, not for redistribution. The definitive version was published in Journal of Fluid Mechanics 506 (2004): 217-244, doi:10.1017/S0022112004008572.
    Description: The effect of both vertical and horizontal components of the Earth's rotation on plumes during deep convection in the ocean is studied. In the laboratory, the misalignment, characterized by the angle $\alpha$, between the buoyancy force (‘effective’ free-fall acceleration ${\bm g}_e$) and the rotation axis ${\bm \Omega}$ is produced by using the centrifugal force: an experimental tank was placed at a large distance from the centre of the turntable. The mathematical analogy between the laboratory model and the oceanic environment is presented. For $\alpha\,{=}\,30^\circ$, a number of laboratory experiments spanning a wide range of the buoyancy flux parameter, and correspondingly Reynolds number, is used to illustrate the development of the convective plume from a point source in regimes ranging from weakly to highly turbulent. New features of the flow, as compared to $\alpha\,{=}\,0$, are documented and explained. The incoming heavier dyed fluid jet disintegrates into fast-sinking coherent blobs (in a low-Reynolds-number regime) or turbulent billows (in a high-Reynolds-number regime) and a more diffuse cloud of highly diluted dyed water. An analysis of the forces acting on an ellipsoid moving in a rotating fluid with the main balance including the buoyancy, Coriolis forces, and the hydrodynamic reaction due to generation of inertial waves correctly predicts the trajectory of a descending blob. It also explains the tendency of the plume to develop in the direction intermediate between ${\bm g}_e$ and ${\bm \Omega}$ and to shift ‘eastward’ (lagging the rotation of the centrifuge) if the plume is envisaged as an ensemble of blobs. The stretching of the highly diluted dyed water along the absolute vorticity tubes with simultaneous shearing by horizontal quasi-two-dimensional flow produces conspicuous tilted structures or tilted Taylor ‘ink walls’. The misalignment between ${\bm g}_e$ and ${\bm \Omega}$ enhances the turbulent mixing and development of tilted structures by breaking the symmetry and producing motions directed away from the rotation axis. We argue that the conditions at the sites of ocean deep convection are favourable for the development of tilted structures because of the smallness of the Rossby number and an extreme homogenization of the mixed layer. We hypothesize that the homogenized sublayers observed within actively convecting regions in the ocean may not be horizontal, but in fact analogous to the tilted ‘ink walls’ observed in the laboratory experiments and that they represent the internal structure of a plume on horizontal scales smaller than its depth.
    Description: This work was supported by a grant from The Andrew W. Mellon Foundation Endowed Fund for Innovative Research and by the National Science Foundation grant OCE-0116910.
    Keywords: Convective plumes
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  • 59
    Publication Date: 2022-05-25
    Description: Author Posting. © Cambridge University Press, 2000. This article is posted here by permission of Cambridge University Press for personal use, not for redistribution. The definitive version was published in Journal of Fluid Mechanics 404 (2000):117-149, doi:10.1017/S0022112099007065.
    Description: In order to gain insight into the hydraulics of rotating-channel flow, a set of initial-value problems analogous to Long's towing experiments is considered. Specifically, we calculate the adjustment caused by the introduction of a stationary obstacle into a steady, single-layer flow in a rotating channel of infinite length. Using the semigeostrophic approximation and the assumption of uniform potential vorticity, we predict the critical obstacle height above which upstream influence occurs. This height is a function of the initial Froude number, the ratio of the channel width to an appropriately defined Rossby radius of deformation, and a third parameter governing how the initial volume flux in sidewall boundary layers is partitioned. (In all cases, the latter is held to a fixed value specifying zero flow in the right-hand (facing downstream) boundary layer.) The temporal development of the flow according to the full, two-dimensional shallow water equations is calculated numerically, revealing numerous interesting features such as upstream-propagating shocks and separated rarefying intrusions, downstream hydraulic jumps in both depth and stream width, flow separation, and two types of recirculations. The semigeostrophic prediction of the critical obstacle height proves accurate for relatively narrow channels and moderately accurate for wide channels. Significantly, we find that contact with the left-hand wall (facing downstream) is crucial to most of the interesting and important features. For example, no instances are found of hydraulic control of flow that is separated from the left-hand wall at the sill, despite the fact that such states have been predicted by previous semigeostrophic theories. The calculations result in a series of regime diagrams that should be very helpful for investigators who wish to gain insight into rotating, hydraulically driven flow.
    Description: The authors have been supported by the National Science Foundation through Grants (OCE-9810599 for L.J.P. and K.R.H. and OCE-9711186 for EPC). L.J.P. also received support from the Office of Naval Research under Grant N00014-95-1-0456 and K.R.H. under grant N00014-93-1-0263.
    Keywords: Rotating-channel flow ; Hydraulically driven flow
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  • 60
    Publication Date: 2022-05-25
    Description: Author Posting. © Cambridge University Press, 2004. This article is posted here by permission of Cambridge University Press for personal use, not for redistribution. The definitive version was published in Journal of Fluid Mechanics 514 (2004): 107-119, doi:10.1017/S0022112004000126.
    Description: While acoustic scatter from oceanic turbulence is sensitive to temperature–salinity covariations, there are unfortunately no published measurements of the turbulent temperature–salinity co-spectrum. Several models have been proposed for the form of the co-spectrum of two scalars in turbulence, but they all produce unsatisfactory results when applied to the turbulent scattering equations (either predicting negative scattering cross-sections in some regimes or predicting implausible levels of correlation between temperature and salinity at some scales). A new model is proposed and shown to give physically plausible scattering predictions in all density regimes. High-frequency acoustic data illustrate the importance of the co-spectrum for acoustic scattering, but were collected in a density regime where there is little difference between the co-spectrum models.
    Description: This work was supported by NSERC and by ONR under grant #N00014-93-1-0362.
    Keywords: Oceanic turbulence ; Co-spectrum ; Temperature–salinity covariations
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  • 61
    Publication Date: 2022-05-25
    Description: Author Posting. © Cambridge University Press, 2002. This article is posted here by permission of Cambridge University Press for personal use, not for redistribution. The definitive version was published in Journal of Fluid Mechanics 452 (2002): 97-121, doi:10.1017/S0022112001006668.
    Description: Buoyancy-driven surface currents were generated in the laboratory by releasing buoyant fluid from a source adjacent to a vertical boundary in a rotating container. Different bottom topographies that simulate both a continental slope and a continental ridge were introduced in the container. The topography modified the flow in comparison with the at bottom case where the current grew in width and depth until it became unstable once to non-axisymmetric disturbances. However, when topography was introduced a second instability of the buoyancy-driven current was observed. The most important parameter describing the flow is the ratio of continental shelf width W to the width L* of the current at the onset of the instability. The values of L* for the first instability, and L*[minus sign]W for the second instability were not influenced by the topography and were 2–6 times the Rossby radius. Thus, the parameter describing the flow can be expressed as the ratio of the width of the continental shelf to the Rossby radius. When this ratio is larger than 2–6 the second instability was observed on the current front. A continental ridge allowed the disturbance to grow to larger amplitude with formation of eddies and fronts, while a gentle continental slope reduced the growth rate and amplitude of the most unstable mode, when compared to the continental ridge topography. When present, eddies did not separate from the main current, and remained near the shelf break. On the other hand, for the largest values of the Rossby radius the first instability was suppressed and the flow was observed to remain stable. A small but significant variation was found in the wavelength of the first instability, which was smaller for a current over topography than over a flat bottom.
    Description: Partial support for C.C. was provided by a TMR fellowship, MAS3-CT96-5017.
    Keywords: Buoyancy-driven currents ; Bottom topography
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  • 62
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 19 (2005): GB4006, doi:10.1029/2004GB002445.
    Description: We report iron measurements for water column and aerosol samples collected in the Sargasso Sea during July-August 2003 (summer 2003) and April-May 2004 (spring 2004). Our data reveal a large seasonal change in the dissolved iron (dFe) concentration of surface waters in the Bermuda Atlantic Time-series Study region, from ∼1–2 nM in summer 2003, when aerosol iron concentrations were high (mean 10 nmol m−3), to ∼0.1–0.2 nM in spring 2004, when aerosol iron concentrations were low (mean 0.64 nmol m−3). During summer 2003, we observed an increase of ∼0.6 nM in surface water dFe concentrations over 13 days, presumably due to eolian iron input; an estimate of total iron deposition over this same period suggests an effective solubility of 3–30% for aerosol iron. Our summer 2003 water column profiles show potentially growth-limiting dFe concentrations (0.02–0.19 nM) coinciding with a deep chlorophyll maximum at 100–150 m depth, where phytoplankton biomass is typically dominated by Prochlorococcus during late summer.
    Description: Funding for this work was provided by the U.S. National Science Foundation (OCE-0222053 to P. N. S., OCE-0222046 to T. M. C., and OCE-0241310 to D. J. M.), the U.S. National Aeronautics and Space Administration (NAG5-11265 to D. J. M.), the Australian Research Council (DP0342826 to A. R. B.), the Antarctic Climate and Ecosystems Cooperative Research Center, and the H. Unger Vetlesen Foundation.
    Keywords: Atmospheric deposition ; Iron ; Sargasso Sea
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  • 63
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 32 (2005): L19304, doi:10.1029/2005GL023457.
    Description: The effect of rheology on the evolution of the slab-tip during subduction initiation is analyzed using 2-D numerical flow models. Experimentally determined flow laws have both strong temperature- and stress-dependence, which leads to large local variations in viscosity with direct consequences for subduction initiation. We find that models with Newtonian viscosity lead to flat or coupled subduction due to hydrodynamic stresses that pull the slab-tip up towards the overriding plate. Non-Newtonian rheology reduces these hydrodynamic stresses by decreasing the wedge viscosity and the slab coupling to wedge-corner flow, rendering the small negative-slab buoyancy of the slab-tip sufficient to maintain its dip during the early stages of subduction.
    Keywords: Dynamics of lithosphere and mantle ; Plate boundary ; Rheology: mantle ; Subduction zone processes
    Repository Name: Woods Hole Open Access Server
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  • 64
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    Unknown
    American Geophysical Union
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 6 (2005): Q04009, doi:10.1029/2004GC000768.
    Description: The Hawaii-2 Observatory (H2O) is an excellent site for studying the source regions and propagation of microseisms since it is located far from shorelines and shallow water. During Leg 200 of the Ocean Drilling Program, the officers of the JOIDES Resolution took wind and wave measurements for comparison with double-frequency (DF) microseism data collected at nearby H2O. The DF microseism band can be divided into short period and long period bands, SPDF and LPDF, respectively. Comparison of the ship’s weather log with the seismic data in the SPDF band from about 0.20 to 0.45 Hz shows a strong correlation of seismic amplitude with wind speed and direction, implying that the energy reaching the ocean floor is generated locally by ocean gravity waves. Near-shore land seismic stations see similar SPDF spectra, also generated locally by wind seas. At H2O, SPDF microseism amplitudes lag sustained changes in wind speed and direction by several hours, with the lag increasing with wave period. This lag may be associated with the time necessary for the development of opposing seas for DF microseism generation. Correlation of swell height above H2O with the LPDF band from 0.085 to 0.20 Hz is often poor, implying that a significant portion of this energy originates at distant locations. Correlation of the H2O seismic data with NOAA buoy data, with hindcast wave height data from the North Pacific, and with seismic data from mainland and island stations, defines likely source areas of the LPDF signals. Most of the LPDF energy at H2O appears to be generated by high amplitude storm waves impacting long stretches of coastline nearly simultaneously, and the Hawaiian Islands appear to be a significant source of LPDF energy in the North Pacific when waves arrive from particular directions. The highest DF levels observed at mid-ocean site H2O occur in the SPDF band when two coincident nearby storm systems develop. Mid-ocean generated DF microseisms are not observed at interior continental sites, indicating high attenuation of these signals. At near-coastal seismic stations, both SPDF and LPDF microseism levels are generally dominated by local generation at nearby shorelines.
    Description: This work was supported by the U.S. Science Support Program (User Reference: 418920-BA372; Task Order F001602) associated with the Ocean Drilling Program and is sponsored by the National Science Foundation and the Joint Oceanographic Institutions, Inc. Additional support was provided by the California Energy Commission and the California Department of Boating and Waterways as part of their program to improve boating facilities, access, safety, and education. Support for Ralph Stephen was also provided by the National Science Foundation under Grant #OCE-0424633.
    Keywords: Microseisms ; Ocean gravity waves ; Seismic noise ; Rayleigh wave attenuation ; Oceanic Q ; Hawaii-2 Observatory
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  • 65
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 20 (2005): PA4005, doi:10.1029/2004PA001061.
    Description: Detailed deglacial and Holocene records of planktonic δ18O and Mg/Ca–based sea surface temperature (SST) from the Okinawa Trough suggest that at ∼18 to 17 thousand years before present (kyr B.P.), late spring/early summer SSTs were approximately 3°C cooler than today, while surface waters were up to 1 practical salinity unit saltier. These conditions are consistent with a weaker influence of the summer East Asian Monsoon (EAM) than today. The timing of suborbital SST oscillations suggests a close link with abrupt changes in the EAM and North Atlantic climate. A tropical influence, however, may have resulted in subtle decoupling between the North Atlantic and the Okinawa Trough/EAM during the deglaciation. Okinawa Trough surface water trends in the Holocene are consistent with model simulations of an inland shift of intense EAM precipitation during the middle Holocene. Millennial-scale alternations between relatively warm, salty conditions and relatively cold, fresh conditions suggest varying influence of the Kuroshio during the Holocene.
    Description: Funding for this research was provided by NSFC (grants 40106006 and 40206007), SKLLQG (grant LLQG0204), and the NSF (OCE-020776 to DWO). Y.S.'s visit to WHOI was supported via a NSF START Fellowship.
    Keywords: Okinawa Trough ; Deglaciation ; Holocene ; Kuroshio Current ; East Asian monsoon ; Mg/Ca ; Oxygen isotopes ; Foraminifera
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  • 66
    Publication Date: 2022-05-25
    Description: This paper is not subject to U.S. copyright. Published in 2005 by the American Geophysical Union. The definitive version was published in Journal of Geophysical Research 110 (2005): B06404, doi:10.1029/2004JB003459.
    Description: The Puerto Rico trench exhibits great water depth, an extremely low gravity anomaly, and a tilted carbonate platform between (reconstructed) elevations of +1300 m and −4000 m. I argue that these features are manifestations of large vertical movements of a segment of the Puerto Rico trench, its forearc, and the island of Puerto Rico that took place 3.3 m.y. ago over a time period as short as 14–40 kyr. I explain these vertical movements by a sudden increase in the slab's descent angle that caused the trench to subside and the island to rise. The increased dip could have been caused by shearing or even by a complete tear of the descending North American slab, although the exact nature of this deformation is unknown. The rapid (14–40 kyr) and uniform tilt along a 250 km long section of the trench is compatible with scales of mantle flow and plate bending. The proposed shear zone or tear is inferred from seismic, morphological, and gravity observations to start at the trench at 64.5°W and trend southwestwardly toward eastern Puerto Rico. The tensile stresses necessary to deform or tear the slab could have been generated by increased curvature of the trench following a counterclockwise rotation of the upper plate and by the subduction of a large seamount.
    Keywords: Dynamic topography ; Slab tear ; Puerto Rico trench ; Caribbean plate ; Challenger Deep ; Seamount subduction
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  • 67
    Publication Date: 2022-05-25
    Description: Author Posting. © Cambridge University Press, 2002. This article is posted here by permission of Cambridge University Press for personal use, not for redistribution. The definitive version was published in Journal of Fluid Mechanics 468 (2002): 179-204, doi:10.1017/S0022112002001520.
    Description: A similarity solution to the long-wave shallow-water equations is obtained for a density current (reduced gravity = g[prime prime or minute], Coriolis parameter = f) propagating alongshore (y = 0). The potential vorticity q = f/H1 is uniform in [minus sign][infty infinity] 〈 x [less-than-or-eq, slant] xnose(t), 0 〈 y [less-than-or-eq, slant] L(x, t), and the nose of this advancing potential vorticity front displaces fluid of greater q = f/H0, which is located at L 〈 y 〈 [infty infinity]. If L0 = L([minus sign][infty infinity], t), the nose point with L(xnose(t), t) = 0 moves with velocity Unose = [surd radical]g[prime prime or minute]H0 [phi], where [phi] is a function of H1/H0, f2L20/g[prime prime or minute]H0. The assumptions made in the similarity theory are verified by an initial value solution of the complete reduced-gravity shallow-water equations. The latter also reveal the new effect of a Kelvin shock wave colliding with a potential vorticity front, as is confirmed by a laboratory experiment. Also confirmed is the expansion wave structure of the intrusion, but the observed values of Unose are only in qualitative agreement; the difference is attributed to the presence of small-scale (non-hydrostatic) turbulence in the laboratory experiment but not in the numerical solutions.
    Description: This work is funded by National Science Foundation grants OCE-9726584 & OCE-0092504 (M. E. S.) and OCE-9810599 (K. R. H.).
    Keywords: Potential vorticity front ; Frontal intrusion ; Kelvin wave
    Repository Name: Woods Hole Open Access Server
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  • 68
    Publication Date: 2022-05-25
    Description: Author Posting. © Cambridge University Press, 2003. This article is posted here by permission of Cambridge University Press for personal use, not for redistribution. The definitive version was published in Journal of Fluid Mechanics 481 (2003): 329-353, doi:10.1017/S0022112003004051.
    Description: In this article we investigate time-periodic shear flows in the context of the two-dimensional vorticity equation, which may be applied to describe certain large-scale atmospheric and oceanic flows. The linear stability analyses of both discrete and continuous profiles demonstrate that parametric instability can arise even in this simple model: the oscillations can stabilize (destabilize) an otherwise unstable (stable) shear flow, as in Mathieu's equation (Stoker 1950). Nonlinear simulations of the continuous oscillatory basic state support the predictions from linear theory and, in addition, illustrate the evolution of the instability process and thereby show the structure of the vortices that emerge. The discovery of parametric instability in this model suggests that this mechanism can occur in geophysical shear flows and provides an additional means through which turbulent mixing can be generated in large-scale flows.
    Description: F.P.’s and G.F.’s research was supported by grants from NSF, OPP- 9910052 and OCE-0137023. J.P.’s research is supported in part by a grant from NSF, OCE-9901654.
    Keywords: Time-periodic shear flows ; Parametric instability
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  • 69
    Publication Date: 2022-05-25
    Description: Author Posting. © Cambridge University Press, 2004. This article is posted here by permission of Cambridge University Press for personal use, not for redistribution. The definitive version was published in Journal of Fluid Mechanics 515 (2004): 415-443, doi:10.1017/S0022112004000576.
    Description: The investigation involves the hydraulic behaviour of a dense layer of fluid flowing over an obstacle and subject to entrainment of mass and momentum from a dynamically inactive (but possibly moving) overlying fluid. An approach based on the use of reduced gravity, shallow-water theory with a cross-interface entrainment velocity is compared with numerical simulations based on a model with continuously varying stratification and velocity. The locations of critical flow (hydraulic control) in the continuous model are estimated by observing the direction of propagation of small-amplitude long-wave disturbances introduced into the flow field. Although some of the trends predicted by the shallow-water model are observed in the continuous model, the agreement between the interface profiles and the position of critical flow is quantitatively poor. A reformulation of the equations governing the continuous flow suggests that the reduced gravity model systematically underestimates inertia and overestimates buoyancy. These differences are quantified by shape coefficients that measure the vertical non-uniformities of the density and horizontal velocity that arise, in part, by incomplete mixing of entrained mass and momentum over the lower-layer depth. Under conditions of self-similarity (as in Wood's similarity solution) the shape coefficients are constant and the formulation determines a new criterion for and location of critical flow. This location generally lies upstream of the critical section predicted by the reduced-gravity model. Self-similarity is not observed in the numerically generated flow, but the observed critical section continues to lie upstream of the location predicted by the reduced gravity model. The factors influencing this result are explored.
    Description: M. H. N. would like to thank the Danish Natural Science Research Council for financial support. L. P. and K. H. were supported by the Office of Naval Research under grant N00014-1-01-0167 and by the National Science Foundation under grant OCE-0132903.
    Keywords: Hydraulic behaviour ; Reduced gravity model
    Repository Name: Woods Hole Open Access Server
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  • 70
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    Cambridge University Press
    Publication Date: 2022-05-25
    Description: Author Posting. © Cambridge University Press, 2001. This article is posted here by permission of Cambridge University Press for personal use, not for redistribution. The definitive version was published in Journal of Fluid Mechanics 437 (2001): 301-323, doi:10.1017/S0022112001004402.
    Description: Laboratory and numerical experiments are used to study flow of a uniform-density fluid on the [beta]-plane around a thin zonally elongated island (or ridge segment in the abyss). This orientation is chosen specifically to highlight the roles of the zonal boundary layer dynamics in controlling the circulation around the island. There are examples of deep ocean topography that fall into this category which make the work directly applicable to oceanic flows. Linear theory for the transport around the island and the flow structure is based on a modification of the Island Rule (Pedlosky et al. 1997; Pratt & Pedlosky 1999). The linear solution gives a north–south symmetric flow around the island with novel features, including stagnation points which divide the zonal boundary layers into eastward and westward flowing zones, and a western boundary layer of vanishing length, and zonal jets. Laboratory experiments agree with the linear theory for small degrees of nonlinearity, as measured by the ratio of the inertial to Munk boundary layer scales. With increasing nonlinearity the north–south symmetry is broken. The southern stagnation point (for anticyclonic forcing) moves to the eastern tip of the island. The flow rounding the eastern tip from the northern side of the island now separates from the island. Time-dependence emerges and recirculation cells develop on the northern side of the island. Mean transport around the island is relatively unaffected by nonlinearity and given to within 20% by the modified Island Rule. Numerical solutions of the shallow water equations are in close agreement with the laboratory results. The transition from zonal to meridional island orientation occurs for island inclinations from zonal greater than about 20°.
    Description: This work was supported by the National Science Foundation (Grant Number OCE96-16949).
    Keywords: Zonal boundary layer dynamics ; Island Rule
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  • 71
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    American Geophysical Union
    In:  EPIC3Tectonics, American Geophysical Union, 24(TC4020), pp. 1-19
    Publication Date: 2019-07-17
    Description: Employing surface mapping of syntectonic sediments, interpretation of industry reflection-seismic profiles, gravity data, and isotopic age dating, we reconstruct the tectonic evolution of the southern Altiplano (∼20–22°S) between the cordilleras defining its margins. The southern Altiplano crust was deformed between the late Oligocene and the late Miocene with two main shortening stages in the Oligocene (33–27 Ma) and middle/late Miocene (19–8 Ma) that succeeded Eocene onset of shortening at the protoplateau margins. Shortening rates in the southern Altiplano ranged between 1 and 4.7 mm/yr with maximum rates in the late Miocene. Summing rates for the southern Altiplano and the Eastern Cordillera, we observe an increase from Eocene times to the late Oligocene to some 8 mm/yr, followed by fluctuation around this value during the Miocene prior to shutoff of deformation at 7–8 Ma and transfer of active shortening to the sub-Andean fold and thrust belt. Shortening inverted early Tertiary graben and half graben systems and was partitioned in three fault systems in the western, central, and eastern Altiplano, respectively. The east vergent fault systems of the western and central Altiplano were synchronously active with the west vergent Altiplano west flank fault system. From these data and from section balancing, we infer a kinematically linked western Altiplano thrust belt that accumulated a minimum of 65 km shortening. Evolution of this belt contrasts with the Eastern Cordillera, which reached peak shortening rates (8 mm/yr) in between the above two stages. Hence local shortening rates fluctuated across the plateau superimposed on a general trend of increasing bulk rate with no trend of lateral propagation. This observation is repeated at the shorter length and time scales of individual growth structures that show evidence for periods of enhanced local rates at a timescale of 1–3 Myr. We interpret this irregular pattern of deformation to reflect a plateau-style of shortening related to a self-organized state of a weak crust in the central South American back arc with a fault network that fluctuated around the critical state of mechanical failure. Tuning of this state may have occurred by changes in plate kinematics, during the Paleogene, initially reactivating crustal weak zones and by thermal weakening of the crust with active magmatism mainly in the Neogene stage.
    Repository Name: EPIC Alfred Wegener Institut
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  • 72
    Publication Date: 2022-05-26
    Description: Author Posting. © Cambridge University Press, 2005. This article is posted here by permission of Cambridge University Press for personal use, not for redistribution. The definitive version was published in Journal of Fluid Mechanics 536 (2005): 253-283, doi:10.1017/S0022112005004544.
    Description: The generation of a gravity current by the release of a semi-infinite region of buoyant fluid of depth $H$ overlying a deeper, denser and quiescent lower layer in a rotating channel of width $w$ is considered. Previous studies have focused on the characteristics of the gravity current head region and produced relations for the gravity current speed $c_{b}$ and width $w_b$ as a functions of the local current depth along the wall $h_b$, reduced gravity $g^\prime$, and Coriolis frequency $f$. Here, the dam-break problem is solved analytically by the method of characteristics assuming reduced-gravity flow, uniform potential vorticity and a semigeostrophic balance. The solution makes use of a local gravity current speed relation $c_{b} \,{=}\, c_b(h_b,\ldots)$ and a continuity constraint at the head to close the problem. The initial value solution links the local gravity current properties to the initiating dam-break conditions. The flow downstream of the dam consists of a rarefaction joined to a uniform gravity current with width $w_b$ (${\le}\, w$) and depth on the right-hand wall of $h_b$, terminated at the head moving at speed $c_b$. The solution gives $h_b$, $c_b$, $w_b$ and the transport of the boundary current as functions of $w/L_R$, where $L_R \,{=}\, \sqrt{g^\prime H}/f$ is the deformation radius. The semigeostrophic solution compares favourably with numerical solutions of a single-layer shallow-water model that internally develops a leading bore. Existing laboratory experiments are re-analysed and some new experiments are undertaken. Comparisons are also made with a three-dimensional shallow-water model. These show that lateral boundary friction is the primary reason for differences between the experiments and the semigeostrophic theory. The wall no-slip condition is identified as the primary cause of the experimentally observed decrease in gravity current speed with time. A model for the viscous decay is developed and shown to agree with both experimental and numerical model data.
    Description: This work was supported by NSF Grants OCE-0095059 and OCE-0132903.
    Keywords: Gravity current ; Dam-break problem
    Repository Name: Woods Hole Open Access Server
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  • 73
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    Cambridge University Press
    Publication Date: 2022-05-26
    Description: Author Posting. © Cambridge University Press, 2003. This article is posted here by permission of Cambridge University Press for personal use, not for redistribution. The definitive version was published in Journal of Fluid Mechanics 490 (2003): 189-215, doi:10.1017/S0022112003005007.
    Description: The baroclinic instability of a zonal current on the beta-plane is studied in the context of the two-layer model when the shear of the basic current is a periodic function of time. The basic shear is contained in a zonal channel and is independent of the meridional direction. The instability properties are studied in the neighbourhood of the classical steady-shear threshold for marginal stability. It is shown that the linear problem shares common features with the behaviour of the well-known Mathieu equation. That is, the oscillatory nature of the shear tends to stabilize an otherwise unstable current while, on the contrary, the oscillation is able to destabilize a current whose time-averaged shear is stable. Indeed, this parametric instability can destabilize a flow that at every instant possesses a shear that is subcritical with respect to the standard stability threshold. This is a new source of growing disturbances. The nonlinear problem is studied in the same near neighbourhood of the marginal curve. When the time-averaged flow is unstable, the presence of the oscillation in the shear produces both periodic finite-amplitude motions and aperiodic behaviour. Generally speaking, the aperiodic behaviour appears when the amplitude of the oscillating shear exceeds a critical value depending on frequency and dissipation. When the time-averaged flow is stable, i.e. subcritical, finite-amplitude aperiodic motion occurs when the amplitude of the oscillating part of the shear is large enough to lift the flow into the unstable domain for at least part of the cycle of oscillation. A particularly interesting phenomenon occurs when the time-averaged flow is stable and the oscillating part is too small to ever render the flow unstable according to the standard criteria. Nevertheless, in this regime parametric instability occurs for ranges of frequency that expand as the amplitude of the oscillating shear increases. The amplitude of the resulting unstable wave is a function of frequency and the magnitude of the oscillating shear. For some ranges of shear amplitude and oscillation frequency there exist multiple solutions. It is suggested that the nature of the response of the finite-amplitude behaviour of the baroclinic waves in the presence of the oscillating mean flow may be indicative of the role of seasonal variability in shaping eddy activity in both the atmosphere and the ocean.
    Description: J.P.’s research is supported in part by a grant from NSF, OCE 9901654.
    Keywords: Baroclinic instability ; Baroclinic waves
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  • 74
    Publication Date: 2022-05-26
    Description: Author Posting. © Cambridge University Press, 2000. This article is posted here by permission of Cambridge University Press for personal use, not for redistribution. The definitive version was published in Zygote 8 (2000): 15-24, doi:10.1017/S0967199400000782.
    Description: The physiology of the early embryo may be indicative of embryo vitality and therefore methods for non-invasively monitoring physiological parameters from embryos could improve preimplantation diagnoses. The self-referencing electrophysiological technique is capable of non-invasive measurement of the physiology of individual cells by monitoring the movement of ions and molecules between the cell and the surrounding media. Here we use this technique to monitor gradients of calcium, potassium, oxygen and hydrogen peroxide around individual mouse preimplantation embryos. The calcium-sensitive electrode in self-referencing mode identified a region of elevated calcium concentration ([similar]0.25 pmol) surrounding each embryo. The calcium gradient surrounding embryos was relatively steep, such that the region of elevated calcium extended into the medium only 4 [mu]m from the embryo. By contrast, using an oxygen-sensitive electrode an extensive gradient of reduced dissolved oxygen concentration was measured surrounding the embryo and extended tens of micrometres into the medium. A gradient of neither potassium nor hydrogen peroxide was observed around unperturbed embryos. We also demonstrate that monitoring the physiology of embryos using the self-referencing technique does not compromise their subsequent development. Blastocysts studied with the self-referencing technique implanted and developed to term at the same frequency as did unexamined, control embryos. Therefore, the self-referencing electrode provides a valuable non-invasive technique for studying the physiology and pathophysiology of individual embryos without hindering their subsequent development.
    Description: A portion of this work was funded by an NIH R21 #RR 12718–02 to D.L.K. and P.J.S.S., KO81099 to D.L.K. and NIH P41 RR01395 to P.J.S.S.
    Keywords: Calcium ; Embryo physiology ; Embryo transfer ; Oxygen ; Preimplantation diagnosis
    Repository Name: Woods Hole Open Access Server
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  • 75
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    American Geophysical Union
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 6 (2005): Q11007, doi:10.1029/2005GC000975.
    Description: Binary mixing is one of the most common models used to explain variations in geochemical data. When the data being modeled are ratios of elements or isotopes, the mixtures follow hyperbolic trends with curvatures that depend on a cross-term representing the relative concentrations of the elements or isotopes under consideration in the mixing components. The inverse problem of estimating mixing components is difficult because of the cross-term in the hyperbolic equation, which requires the use of nonlinear methods to estimate the mixing parameters, and because the end-member ratio values are intrinsically underdetermined unless the mixing proportions of the samples are known a priori, which is not generally the case. I use maximum likelihood methods to address these issues and derive a general inversion for binary mixing model parameters from ratio-ratio data. I apply the method to synthetic test data and a global compilation of 230Th/232Th versus 87Sr/86Sr data from oceanic basalts and find that the concentration ratio parameter is well-constrained by the inversion while the end-member ratio estimates are strongly dependent on the initial guesses used to start the iterative solver, reflecting the underdetermined nature of the end-member positions on the mixing hyperbola. Monte Carlo methods that randomly perturb the initial guesses can be used to improve error estimates, and goodness-of-fit statistics can be used to assess the performance of the mixing model for explaining data variance.
    Keywords: Inverse theory ; Isotopes ; Mixing
    Repository Name: Woods Hole Open Access Server
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  • 76
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    Cambridge University Press
    Publication Date: 2022-05-26
    Description: Author Posting. © Cambridge University Press, 2005. This article is posted here by permission of Cambridge University Press for personal use, not for redistribution. The definitive version was published in Journal of Fluid Mechanics 529 (2005): 71-95, doi:10.1017/S0022112005003393.
    Description: The role of mesoscale oceanic eddies in driving large-scale currents is studied in an eddy-resolving midlatitude double-gyre ocean model. The reference solution is decomposed into large-scale and eddy components in a way which is dynamically consistent with a non-eddy-resolving ocean model. That is, the non-eddy-resolving solution driven by this eddy-forcing history, calculated on the basis of this decomposition, correctly approximates the original flow. The main effect of the eddy forcing on the large-scale flow is to enhance the eastward-jet extension of the subtropical western boundary current. This is an anti-diffusive process, which cannot be represented in terms of turbulent diffusion. It is shown that the eddy-forcing history can be approximated as a space–time correlated, random-forcing process in such a way that the non-eddy-resolving solution correctly approximates the reference solution. Thus, the random-forcing model can potentially replace the diffusion model, which is commonly used to parameterize eddy effects on the large-scale currents. The eddy-forcing statistics are treated as spatially inhomogeneous but stationary, and the dynamical roles of space–time correlations and spatial inhomogeneities are systematically explored. The integral correlation time, oscillations of the space correlations, and inhomogeneity of the variance are found to be particularly important for the flow response.
    Description: Funding for this research was provided by NSF grants OCE 0091836 and OCE 03-44094, by the Royal Society Fellowship, and by WHOI grants 27100056 and 52990035.
    Keywords: Mesoscale oceanic eddies ; Large-scale currents ; Random-forcing model
    Repository Name: Woods Hole Open Access Server
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  • 77
    Publication Date: 2022-05-26
    Description: Author Posting. © Cambridge University Press, 2002. This article is posted here by permission of Cambridge University Press for personal use, not for redistribution. The definitive version was published in Journal of Fluid Mechanics 464 (2002): 251-278, doi:10.1017/S0022112002008868.
    Description: The dynamics of buoyant gravity currents in a rotating reference frame is a classical problem relevant to geophysical applications such as river water entering the ocean. However, existing scaling theories are limited to currents propagating along a vertical wall, a situation almost never realized in the ocean. A scaling theory is proposed for the structure (width and depth), nose speed and flow field characteristics of buoyant gravity currents over a sloping bottom as functions of the gravity current transport Q, density anomaly g[prime prime or minute], Coriolis frequency f, and bottom slope [alpha]. The nose propagation speed is cp [similar] cw/ (1 + cw/c[alpha]) and the width of the buoyant gravity current is Wp [similar] cw/ f(1 + cw/c[alpha]), where cw = (2Qg[prime prime or minute] f)1/4 is the nose propagation speed in the vertical wall limit (steep bottom slope) and c[alpha] = [alpha]g/f is the nose propagation speed in the slope-controlled limit (small bottom slope). The key non-dimensional parameter is cw/c[alpha], which indicates whether the bottom slope is steep enough to be considered a vertical wall (cw/c[alpha] [rightward arrow] 0) or approaches the slope-controlled limit (cw/c[alpha] [rightward arrow] [infty infinity]). The scaling theory compares well against a new set of laboratory experiments which span steep to gentle bottom slopes (cw/c[alpha] = 0.11–13.1). Additionally, previous laboratory and numerical model results are reanalysed and shown to support the proposed scaling theory.
    Description: This research was supported by NSF grant OCE-0095059.
    Keywords: Buoyant gravity currents ; Scaling theory ; Sloping bottom
    Repository Name: Woods Hole Open Access Server
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  • 78
    Publication Date: 2022-05-26
    Description: Author Posting. © Cambridge University Press, 2003. This article is posted here by permission of Cambridge University Press for personal use, not for redistribution. The definitive version was published in Journal of the Marine Biological Association of the UK 83 (2003): 1347-1350, doi:10.1017/S0025315403008798.
    Description: Trophic positions (TP) were estimated for the blue shark (Prionace glauca), shortfin mako (Isurus oxyrinchus), thresher shark (Alopias vulpinus), and basking shark (Cetorhinus maximus) using stable isotope ratios of carbon ([delta]13C) and nitrogen ([delta]15N). The basking shark had the lowest TP (3·1) and [delta]15N value (10·4‰), whereas the thresher shark had the highest values (4·5, 15·2‰). Mako sharks showed considerable variation in TP and isotopic values, possibly due to foraging from both inshore and offshore waters. Thresher sharks were significantly more enriched in [delta]15N than blue sharks and mako sharks, suggesting a different prey base. The [delta]13C values of thresher sharks and mako sharks varied significantly, but neither was significantly different from that of blue sharks. No statistical differences were found between our TP estimations and those derived from published stomach contents analyses, indicating that stable isotope data may be used to estimate the trophic status of sharks.
    Description: This work was supported by National Marine Fisheries Service Grant NA16MF1323 to M.E.L.
    Keywords: Prionace glauca ; Isurus oxyrinchus ; Alopias vulpinus ; Cetorhinus maximus ; Trophic positions
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 79
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    Cambridge University Press
    In:  Biased embryos and evolution vol. 74, 1/2, pp. 209-211
    Publication Date: 2024-01-12
    Keywords: evolution ; natural selection ; variation ; developmental bias
    Repository Name: National Museum of Natural History, Netherlands
    Type: info:eu-repo/semantics/review
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  • 80
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    Cambridge University Press
    In:  Cambridge, UK, Cambridge University Press, vol. 10, no. 1, pp. 1-40, (ISBN 0-521-84678-1 (550 pp.))
    Publication Date: 2005
    Description: ... Overall, An Introduction to Programming with Mathematica is a useful and readable book that could serve as the text for a generic programming class, a supporting text for a class on programming for geoscientists, or an introduction for experienced geoscience programmers looking for an easily readable summary of Mathematica's programming language. Experienced Mathematica programmers may find it useful as a refresher. The book's principal drawbacks are the high price of Mathematica for those who do not already have the software (although a modestly priced student version is available) and, for geoscientists in particular, a lack of relevant example problems
    Keywords: Handbook of mathematics ; computer ; algebra ; software
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  • 81
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    Cambridge University Press
    In:  Cambridge, Cambridge University Press, vol. 7, no. Publ. No. 12, pp. 127, (ISBN: 0521839270, 520 p.)
    Publication Date: 2005
    Description: Fundamentals of Structural Geology provides a new framework for the investigation of geological structures by integrating field mapping and mechanical analysis. Assuming a basic knowledge of physical geology, introductory calculus and physics, it emphasizes the observational data, modern mapping technology, principles of continuum mechanics, and the mathematical and computational skills, necessary to quantitatively map, describe, model, and explain deformation in Earth's lithosphere. By starting from the fundamental conservation laws of mass and momentum, the constitutive laws of material behavior, and the kinematic relationships for strain and rate of deformation, the authors demonstrate the relevance of solid and fluid mechanics to structural geology. This book offers a modern quantitative approach to structural geology for advanced students and researchers in structural geology and tectonics. It is supported by a website hosting images from the book, additional colour images, student exercises and MATLAB scripts. Solutions to the exercises are available to instructors
    Keywords: Structural geology ; Textbook of geology ; MATLAB ; scripts ; Tectonics ; Lithosphere
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  • 82
    Publication Date: 2005-01-01
    Description: An assumption exists in North Alaskan archaeological literature that radiometric assays produced by the now-defunct Dicarb Radioisotope Co. (Dicarb) are “too young” or more recent when compared to those produced by other laboratories. This assumption is statistically tested by comparing radiocarbon assays produced by Dicarb to those produced by Beta Analytic, Inc.; Geochron Laboratories; and the NSF-Arizona AMS Facility. The primary data set consists of radiometric and accelerator mass spectrometry (AMS) assays produced from materials excavated at the Croxton site, Locality J, Tukuto Lake, northern Alaska. Statistical analyses demonstrate that 14C assays produced by Dicarb tend to be “younger” than assays produced by other laboratories on crosscheck samples, with differences ranging between 350 and 1440 yr.
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    Topics: Archaeology , Energy, Environment Protection, Nuclear Power Engineering , Geosciences
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  • 83
    Publication Date: 2005-12-01
    Description: This article traces the ascent of the International Accounting Standards Committee (IASC) from an obscure group with little influence in the early 1970s to a pre-eminent position as global accounting standard-setter in 2001. I argue that the rise of the IASC can be explained by several factors, including the IASC's ability to build legitimacy through technical expertise, to embed itself in a network of international organizations, and to benefit from rivalries among developed and developing countries and among European and American regulators. But the most important reason for the IASC's success is that its core values aligned strongly with the interests of the most powerful regulator-the US Securities and Exchange Commission.
    Print ISSN: 1369-5258
    Electronic ISSN: 1469-3569
    Topics: Political Science , Economics
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  • 84
    Publication Date: 2005-08-01
    Description: In recent years programs of private regulation have spread from North America and Europe to developing countries around the world. Though central to debates over public versus private international governance, little is known about the actual operations of these programs, especially in developing countries where weak state regulation has failed for decades to control environmental degradation. This paper assesses the effectiveness in Argentina of two prominent global private environmental regulatory programs'the chemical industry's Responsible Care® program and the Forest Stewardship Council. Argentina presents an intriguing country case because, despite conditions and policies that should support such programs, their implementation there has been stunted when compared against other regional cases. A focus on the demand and supply factors that shape these programs in Argentina reveals that market demand is a necessary but insufficient condition for regime effectiveness. Supply-side factors such as industry characteristics, public policies, and the institutional culture of firms significantly influence program implementation. Some transnational corporations helped export these program to Argentina; however, many others have shown opposition or disinterest, stifling program development. Also, feckless and unstable state agencies have created an institutional environment unfavorable even for private initiatives aimed at bypassing government interference.
    Print ISSN: 1369-5258
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    Topics: Political Science , Economics
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  • 85
    Publication Date: 2005-04-01
    Description: In 1998, the domestic steel industry in the United States devised and executed a complex and sophisticated effort to achieve an effective non-market response to a sudden, persistent, and damaging surge of imported steel. This campaign lasted until 2002, when President George W. Bush invoked Section 201 of the U.S. trade laws to impose tariffs on imports of most steel products. This case of the steel industry's trade policy campaign provides an opportunity to examine selected models of protection-seeking industries and lobbying to ask why and how the steel coalition achieved this extraordinary governmental response. These questions are explored though a descriptive case of the steel industry's protection-seeking campaign followed by a comparative examination of previous models of protection-seeking firms, and lobbying to achieve protectionist policies. A comparison with selected models of the determinants of protection-seeking and factors affecting lobbying strategies show that most, almost all, were present in the steel case. In fact, a meta-strategic approach that transcends the customary understanding of lobbying is suggested in a complex policy environment. Such an environment can be characterized by: the need to influence multiple governmental entities – legislative, regulatory, executive; the desire for multiple outcomes with varying levels of specificity – laws or resolutions, administrative rulings, policy choices; interactions between different levels and branches of government; employment of coordinated interrelated lobbying techniques; and simultaneity of these factors.
    Print ISSN: 1369-5258
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    Topics: Political Science , Economics
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  • 86
    Publication Date: 2005-04-01
    Description: The rentier-state literature pays little attention to the initial political conditions that shape the way an oil-rich country develops its resources. One of the key causal mechanisms linking oil wealth and regime type is the relationship between foreign investors and host governments. Especially in the developing countries that depend on international financing and expertise, the role of foreign capital in fashioning the balance of power in the political system and thereby the distribution of oil wealth becomes ever more important. As the experiences of Azerbaijan and Russia in the 1990s demonstrate, among oil-rich states in the developing world, those with authoritarian regimes tend to fare better in terms of attracting FDI in the oil sector than states with democratizing (or hybrid regimes). The durability of some authoritarian regimes in the developing world is partly a function of this external legitimation from foreign investors.
    Print ISSN: 1369-5258
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    Topics: Political Science , Economics
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  • 87
    Publication Date: 2005-12-01
    Description: We are currently witnessing the evolution of global accounting standards, as developed by the International Accounting Standards Board (IASB). This is a remarkable development, not only because accounting standards are relevant for all business operations. Whereas accounting standard-setting has previously been a task of national authorities, the process will now be managed internationally by a London-based organisation whose parent foundation is a private company incorporated in the US state of Delaware and mainly financed by the Big Four accounting firms. Furthermore, the US appear to be willing to accept foreign standards that are quite different from their own Generally Accepted Accounting Standards (GAAP). This does not only contradict a widespread perception that equals globalization with Americanization, but also offers a remarkable contrast to US unilateralism in other policy fields. Finally, we are also amidst a major change in the substance of accounting standards, as indicated by a shift from historic cost to fair value accounting within the work of the IASB. This special issue of Business and Politics is devoted to a systematic explanation of these developments, drawing on concepts from International Relations, International Political Economy and Systems Theory.
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  • 88
    Publication Date: 2005-04-01
    Description: The Federal Communications Commission rule making for low power FM radio was widely reported as an instance where Congress sharply rebuked a regulatory agency for enacting rules too favorable to entrants. Theories of bureaucratic control generally agree that when such events occur, policy differences of Congress and the agency must be large. Because rival policy positions are quantifiable in this case, the preferences of Congress and the Commission can be directly evaluated. While the distance between the policy position of the Commission and Congress appear large, they signified a negligible increment in competition when compared to a benchmark efficient policy. A financial event study supports this interpretation, as radio broadcaster's equity values were not materially affected by either events in Congress or the Commission. Thus, even marginal differences may prompt a costly intervention by Congress to ostensibly discipline an agency.
    Print ISSN: 1369-5258
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  • 89
    Publication Date: 2005-04-01
    Description: This paper applies an economic approach to empirically investigate differences in inward foreign direct investment (FDI) patterns between East Asia and Latin America and discusses the implication of regional trade arrangements. International production/distribution networks in East Asia effectively utilize the new economic logic of fragmentation, agglomeration, and optimal internalization and seem to greatly contribute to economic development. The paper examines statistical data for international trade as well as the activities of Japanese and U.S. multinational enterprises (MNEs) and argues that international production/distribution networks, particularly in machinery industries, are extensively developed in East Asia while remaining immature in Latin America. The impact of regional trade arrangements is substantially different depending on whether international production/distribution networks have already been developed or not. Our findings suggest that the impact of FTAA on FDI in Latin America by East Asian MNEs could be either positive or negative, depending on the content of FTAA and accompanying policies. If differentials between intra-regional tariffs and MFN-based tariffs are kept large, import-substituting FDI from East Asia may stagnate or even decrease. With a proper policy package to nurture international production/distribution networks, on the other hand, FDI from East Asia could be accelerated and contributed to deeper integration of Latin America.
    Print ISSN: 1369-5258
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  • 90
    Publication Date: 2005-08-01
    Description: Scholars of business associations have recently learned a great deal about how associations contribute to development, but much less about the origins of such developmental associations. This essay introduces and assesses a new political explanation for the origins of ‘developmental associations.’ Conventional wisdom holds that developmental associations must be able to rise above political and collusive pressures and establish autonomy from states. Yet, I argue that these associations' developmental capacities emerge as a result of active state support by key actors, and in response to challenges and threats posed by competitive business organizations. Developmental associations emerge and acquire their capacities as they confront internal threats from other associations, as well as utilize the opportunities presented by the national state and international channels. In this view, functional or organizational capacity is not enough, rather, developmental business associations, must exhibit political capacity'that is the ability to manage the political environment, and respond to the structure of opportunities and threats. This explanation views developmental business associations as political organizations seeking power as well as offers a historically sensitive analysis of transformation of business politics in reforming India.
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  • 91
    Publication Date: 2005-08-01
    Description: Negotiations for China's accession to the WTO provoked a debate between pessimists who believed that opening the economy would lead to a flood of imports and a de-nationalization of manufacturing industry, and those who believed that it would spur rationalization of state-owned enterprises, lock in domestic reforms, attract foreign investment, and open the way for trade expansion. The industry most frequently mentioned as endangered was motor vehicles, where an awkward combination of Stalinist central planning with localized autarky had resulted in a proliferation of inefficient producers. With the partial exception of two investments by Volkswagen, initial joint ventures in assembly operations failed miserably. China's commitments on joining the WTO banned (or at least complicated) many of the most important industrial policy tools it had used to promote the auto industry since the opening to joint ventures in the early 1980s'including performance requirements, high tariffs, and numerical quotas. After accession in 2001, tariffs fell steadily while output and foreign investment soared. The Chinese government moved towards a lighter-handed but more effective form of industrial policy that reduced top-down planning while expanding market incentives and scope for managerial freedom. Rather than destroying industrial policy for the auto industry, WTO accession constrained and disciplined it. When foreign auto firms and their governments pushed for more aggressive protection of trademarks and other intellectual property rights under the WTO, the Chinese government initially stalled. Continuing pressure then tilted the balance of state policy toward promotion of independent design, whether by state-owned enterprises testing the boundaries of their joint ventures with foreign multinationals, or by audacious smaller firms purchasing foreign designs and technology to complement inexpensive local parts and assembly, thereby creating the conditions for the emergence of a more competitive industry.
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  • 92
    Publication Date: 2005-12-01
    Description: The article takes a political economy perspective on the current harmonization of accounting standards. It argues that the process not only signals a major shift in the mode of governance (towards private authority), but also in the substance of what is being governed. In political-economic terms, the most significant change which the International Accounting Standards Board (IASB) brings to accounting is an increased reliance on market values in the form of so-called Fair Value Accounting (FVA). The FVA paradigm represents a financial perspective on business operations. This perspective is matched by the process and structure of the institutions that govern international accounting standard setting, particularly the IASB and the European Financial Reporting Advisory Group which advises the Commission of the European Union on the adoption of IASB standards. A network analysis of the different committees and working groups of these two institutions demonstrates that financial sector actors wield substantially more influence than other categories of business actors within the governance of international accounting standard setting.
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  • 93
    Publication Date: 2005-12-01
    Description: This paper examines the interplay between leading international and American accounting authorities over the span of a critical four-year period, 2001–2005. Historically, US regulators and private-sector accounting institutions have taken a cautious approach to International Financial Reporting Standards (IFRSs), citing the superior rigor and overall quality of their own Generally Accepted Accounting Principles (GAAP). During the past four years, however, the Securities and Exchange Commission (SEC) and the Financial Accounting Standards Board (FASB) have each become markedly receptive to the International Accounting Standards Board's (IASB) efforts to harmonize accounting standards worldwide based on IFRSs. Why? This paper offers an explanation that highlights the role of the high-profile American corporate scandals (2001–2002) in precipitating a shift in US accounting authorities' views of the optimal form of accounting rules, an issue that has stood in the way of trans-Atlantic accounting standard convergence. Prior to the accounting scandals, the highly-detailed rules that are characteristic of US GAAP were widely seen to be the most effective form of accounting rule. Since 2002, a normative shift has taken place such that the SEC now endorses objectives-oriented rules that are conceptually aligned with the principles-based standards promulgated by the IASB. The analysis is framed by insights from contemporary International Relations theory which emphasize the influence of scope conditions on patterns of governance.
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  • 94
    Publication Date: 2005-01-01
    Description: Recent progress in graphite target production for sub-milligram environmental samples in our facility is presented. We describe an optimized hydrolysis procedure now routinely used for the preparation of CO2 from inorganic samples, a new high-vacuum line dedicated to small sample processing (combining sample distillation and graphitization units), as well as a modified graphitization procedure. Although measurements of graphite targets as small as 35 μg C have been achieved, system background and measurement uncertainties increase significantly below 150 μg C. As target lifetime can become critically short for targets
    Print ISSN: 0033-8222
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    Topics: Archaeology , Energy, Environment Protection, Nuclear Power Engineering , Geosciences
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  • 95
    Publication Date: 2005-01-01
    Description: Dating sediments which have accumulated over the last few hundred years is critical to the calibration of longer-term paleoclimate records with instrumental climate data. We attempted to use wiggle-matched radiocarbon ages to date 2 peat profiles from northern England which have high-resolution records of paleomoisture variability over the last ∼300 yr. A total of 65 14C accelerator mass spectrometry (AMS) measurements were made on 33 macrofossil samples. A number of the age estimates were older than expected and some of the oldest ages occurred in the upper parts of the sequence, which had been dated to the late 19th and early 20th century using other techniques. We suggest that the older 14C ages are the result of contamination by industrial pollution. Based on counts of spheroidal carbonaceous particles (SCPs), the potential aging effect for SCP carbon was calculated and shown to be appreciable for samples from the early 20th century. Ages corrected for this effect were still too old in some cases, which could be a result of fossil CO2 fixation, non-SCP particulate carbon, contamination due to imperfect cleaning of samples, or the “reservoir effect” from fixation of fossil carbon emanating from deeper peat layers. Wiggle matches based on the overall shape of the depth-14C relationship and the 14C minima in the calibration curve could still be identified. These were tested against other age estimates (210Pb, pollen, and SCPs) to provide new age-depth models for the profiles. New approaches are needed to measure the impact of industrially derived carbon on recent sediment ages to provide more secure chronologies over the last few hundred years.
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    Topics: Archaeology , Energy, Environment Protection, Nuclear Power Engineering , Geosciences
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  • 96
    Publication Date: 2005-01-01
    Description: Radiocarbon dates together with geoarchaeological, soil, and lithic analyses are presented to describe archaeological site 35-CS-9 in Bandon Ocean Wayside State Park, Oregon, northwestern USA. One of the few Oregon middle-Holocene coastal sites that includes sediments and artifacts dating to the early Holocene and possibly to the late Pleistocene, it was recorded in 1951 and surface surveyed by archaeologists in 1975, 1986, and 1991, but its depth and antiquity were not tested. In February 2002, we studied the site's stratigraphy and sediments and described 8 strata from the aeolian surface to bedrock at 350 cm depth. Soil samples taken from a cut bank for texture classification, particle size analysis, pH, carbon content, and chemical analysis suggested that the site represented a complete history of Holocene deposits. Excavation of 2 test units in August 2002 uncovered substantial lithic and charcoal remains that confirm a protracted middle-Holocene occupation and suggest that human occupation began in the early Holocene. Charcoal recovered at 235–245 cm dated to 11,000 14C BP, and the deepest lithic artifact was recovered in a level at 215–225 cm. Whether the human occupation was continuous throughout the Holocene, and whether it began in the early Holocene or in the late Pleistocene, can only be determined with further excavations.
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    Topics: Archaeology , Energy, Environment Protection, Nuclear Power Engineering , Geosciences
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  • 97
    Publication Date: 2005-01-01
    Description: The South Arabian chronology has been problematic for a long time and this is also a true vexata quaestio for the ancient history of South Arabia. Three different chronologies have been suggested for the first literate phase of South Arabian cultures, which may date to the 11th century BC, the late 8th century BC, or the 5th century BC (see de Maigret 1996:157–63; de Maigret and Robin 1989: 276–8; Pirenne 1988; Robin 1997; Figure 1). At the site of Yalâ, potsherds with incised South Arabian inscriptions have been recovered in a stratum dating at least to the 8th century BC, if not earlier, and offer evidence of the existence of South Arabian culture at that time (de Maigret and Robin 1989:288–9).
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  • 98
    Publication Date: 2005-01-01
    Description: After benzene synthesis, radiocarbon dating samples are usually stored for 3–4 weeks before counting to allow an eventual radon contamination to decay to a negligible level. This paper presents a technique that can minimize, and often eliminate, this delay by using a simple single-phototube liquid scintillation counting system, specifically designed for 14C dating. Radon contamination is assessed by pulses of 214Po (a 222Rn decay product, half-life 0.16 μs), identified through pulse-time analysis. For each 214Po pulse, 0.49 beta particle pulses of 214Pb and 214Bi fall in the 14C counting window, and the 214Po pulses are used to correct the 14C count rate. A 14C sample (count rate 11.6 cpm) was measured continuously for 16 days. It was then doped with radon, which increased the first 24-hr count rate in the 14C channel by 3.8 cpm, and the sample was measured for 27 more days. Radon did not measurably affect the 14C-corrected count rate. Counting a sample for 2 min reveals whether it needs storing. If the radon concentration is low, the sample can be measured immediately without degrading accuracy.
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  • 99
    Publication Date: 2005-01-01
    Description: The chemical and isotopic compositions of long-chain (C36–C39) unsaturated ketones (alkenones), a unique class of algal lipids, encode surface ocean properties useful for paleoceanographic reconstruction. Recently, we have sought to extend the utility of alkenones as oceanic tracers through measurement of their radiocarbon contents. Here, we describe a method for isolation of alkenones from sediments as a compound class based on a sequence of wet chemical techniques. The steps involved, which include silica gel column chromatography, urea adduction, and silver nitrate-silica gel column chromatography, exploit various structural attributes of the alkenones. Amounts of purified alkenones estimated by GC/FID measurements were highly correlated with CO2 yields after sample combustion, indicating purities of greater than 90% for samples containing ≥ 100 μg C. The degree of alkenone unsaturation (U37K′) also varied minimally through the procedure. We also describe a high-performance liquid chromatography (HPLC) method to isolate individual alkenones for molecular-level structural and isotopic determination.
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  • 100
    Publication Date: 2005-01-01
    Print ISSN: 0033-8222
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    Topics: Archaeology , Energy, Environment Protection, Nuclear Power Engineering , Geosciences
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