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  • Articles  (102)
  • DSC  (52)
  • eutrophication  (50)
  • Springer  (102)
  • American Association for the Advancement of Science
  • American Meteorological Society
  • 1995-1999  (102)
  • 1990-1994
  • 1999  (102)
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  • Articles  (102)
Keywords
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  • Springer  (102)
  • American Association for the Advancement of Science
  • American Meteorological Society
  • Wiley-Blackwell  (1)
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  • 1995-1999  (102)
  • 1990-1994
Year
  • 1
    ISSN: 1572-8935
    Keywords: TDI-based polyurethane elastomers ; Tg ; Tglobal transition ; DSC ; TSC/RMA ; DMA
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Thermal transitions of TDI-based polyurethane elastomers with PTMO as the soft segment were characterized by the depolarization technique in TSC and by using with the thermal windowing technique on selected specimens in the RMA measurements. Results indicate that the broadened thermal transition in the glass transition region as observed in the DSC thermogram is related to the combined Tg transition and the Tglobal transition in the TSC spectrum. This Tglobal transition is associated with the macromolecular property as detected by tan δ in DMA measurement. The increase in the Tg with a high NCO content may be explained by the structural modification found on the urethanic chain with the additional linkage of the hard segment that affects the cooperative motion of the molecular chain. Data measured from DSC, TSC/RMA and DMA with simulated DEA and wide angle X-ray data are presented for the characterization of the polyurethanes. The RMA measurement leads to a compensation search on Tg transition and provides pertinent thermokinetic data that correlates the NCO content with changes in enthalpy and entropy on the relaxation behaviors in the Tg transition of polyurethane elastomers.
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  • 2
    ISSN: 1573-0417
    Keywords: diatoms ; biogenic silica ; pigments ; biomass ; trophic state changes ; eutrophication ; Lake Constance ; Germany
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract In Lake Constance, phosphorus concentrations and the seasonal development of phytoplankton communities in water samples from the pelagic zone were regularly recorded since the 1950's. Before the 1950's, there were occasional investigations of plankton communities since 1896. We compared these data with the sedimentary record in two sediment cores. Then, the eutrophication history of Lake Constance was inferred from diatoms. The record of biogenic silica in the cores is discussed with respect to diatom biomass increase. Diatom assemblages in the sediment cores precisely reflected the pelagic diatom development for the period 1971--1992. Both sediment cores and the water samples have a high interannual variability of diatom assemblages. Below a sediment depth of 27 cm (AD 1920), more than 50% of the diatoms were partly corroded, and we limited the reconstruction of trophic state changes to the interval of 1920--1993. Oligotrophic conditions of Lake Constance were indicated by the dominance of various Cyclotella taxa from 1920 to 1940. Since 1939/1940, increasing abundance of it Tabellaria fenestrata showed oligotrophic to mesotrophic conditions. Between 1953 and 1956, increasing Stephanodiscus hantzschii and disappearing Cyclotella indicated advanced eutrophication and total phosphorus values ranged between 8--10 mg m-3 during turnover in late winter. Further eutrophication was shown by disappearing T. fenestrata and increasing S. minutulus in 1963. Maximum TP concentrations of 87 mg m-3 occurred in 1979/80 and was accompanied by increasing abundances of Aulacoseira granulata. From 1986 to 1992, reoccurrence of Tabellaria fenestrata and Cyclotella indicate some recovery of Lake Constance. Biogenic silica and diatom abundances were similar among cores but indicate a 3--4 fold increase of diatom biomass only. This was far below the estimate of biomass increase from sedimentary pigment data (25 fold) and the estimate of phytoplankton data from the literature (70 fold).
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  • 3
    ISSN: 1573-0417
    Keywords: Lake Arendsee ; Germany ; freeze-core ; eutrophication ; calcite ; near-infrared reflectance
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract The present study explored whether rapid, non-destructive near-infrared reflectance spectroscopy (NIRS) could complement conventional paleolimnological and chemical analyses of sediment cores for greater efficiency and cost-effectiveness. The study used a 47-cm long freeze-core from the deepest point in Lake Arendsee, Mecklenburg Plain in northern Germany taken in 1993 to elucidate eutrophication history and to identify the pre-impact algal communities in this system. The core had been analyzed for total C, CO32-, N, P, and diatoms. Thirty-four of the 47 1-cm thick core sections were scanned by NIRS and calibrations were developed for total C, CO32-, N, P, N:P, total diatoms, and three dominant diatom species with different sedimentary profiles (Stephanodiscus binatus, Cyclotella rossii, and Fragilaria crotonensis). Total C ranged from 167-194 mg g-1 dry weight (d.w.), CO32- from 31.3-66.4 mg g-1 d. w., N from 9.9-17.4 mg g-1 d. w., and P from 0.7-6.0 mg g-1 d. w. Calibrations developed using multiple linear regression between NIR-predicted values and chemically-measured values were excellent for P (r2 〉 0.99), good for C, N, and N:P (r2 〉 0.93), and satisfactory for CO32-(r2 〉 0.8). Calibrations for total diatoms and for individual species were highly statistically significant (r2 between 0.54 and 0.69). Although the calibrations are not useful for reliable predictions of the content of diatoms in the samples, the results indicate that NIRS detects spectral properties associated with diatoms or lake conditions when they were present, and that further work is warranted to attempt to improve the results. The study demonstrated that rapid, non-destructive, simultaneous analysis of total C, CO32-, N, P, and N:P in sediment cores is feasible.
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  • 4
    ISSN: 1573-0417
    Keywords: Chrysophyceae ; Synurophyceae ; cyst ; acid deposition ; eutrophication ; cottage development ; Muskoka-Haliburton ; Canada
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Chrysophyte cysts preserved in recent and pre-industrial lake sediment samples from 54 Muskoka-Haliburton (Ontario) lakes were used in a paleolimnological study to determine the impact of acidic precipitation and cottage development on water quality. A total of 246 cyst morphotypes were identified. Ecological preferences of cyst morphotypes were determined using multivariate statistical analysis, cluster analysis, and species-environment correlations. Recent cyst assemblages were related to water chemistry and lake morphometric variables using Redundancy Analysis (RDA). The distribution of morphotypes was related to a gradient of acid neutralising capacity (ANC), expressed through the association of variables related to buffering (i.e. longitude, watershed area, and ionic concentration) with the first axis (λ1 = 0.29). Cyst assemblages were also defined, to a lesser extent (λ2 = 0.06), by a trophic status gradient, created through the combination of total nitrogen (TN), total phosphorus (TP), volume-weighted cottage density, and lake depth variables. The identification of lakewater pH and trophic status as important determinants of cyst assemblage structure allowed for the reconstruction of acidification and eutrophication related water chemistry changes using fossil cyst assemblages. The reconstruction of pre-industrial (pre-1850) water quality conditions with fossil cyst assemblages indicated that pH significantly decreased in 24.1% of the study lakes and increased in 16.7% of the lakes. Increases in pH in more alkaline drainage basins are attributed to alkalinity generation processes induced by acidic precipitation as has been shown in other studies. Total phosphorus (TP) concentrations significantly declined in 12.9% of the lakes and increased in 16.6% of lakes. Increases in [TP] were linked to cottage development. Decreases in trophic status may be due to landuse changes, the result of the acidification occurring in the area, or warmer and drier climates. A comparison of chrysophyte cyst and diatom water quality inferences show similar trends in pH changes. There is a good agreement between diatom and chrysophyte bioindicators with respect to [TP] changes in oligotrophic lakes (〈 10 μg/L); however, diatom inferences suggest that lakes with current [TP] values greater than 10 μg/L have decreased in trophic status over time, while chrysophyte reconstructions suggest that these same lakes have become more productive systems.
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  • 5
    ISSN: 1573-0417
    Keywords: Lake Gościąż ; varved sediments ; human impact ; eutrophication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract According to historical sources, the development of settlement around Lake Gości& aogon;ż during the last 330 yrs was intense at two time periods: the second half of the 1700's, and from ca. 1880 until 1944. The small farms were then abandoned, following which the lake surroundings were planted with forest trees. The presented study of human influence on the lake ecosystem and surrounding vegetation has been based on analyses of general sediment composition and its chemistry, pollen, Cyanobacteria, Chlorophyceae, Rotatoria, Cladocera, and a preliminary diatom survey. The history of human impact has been divided into four phases: 1. Phase of small local hamlets (before ca. 1770): The human impact was rather moderate then, but the cultivation of Canabis sativa, Secale cereale and later of Fagopyrum is evidenced from that time. 2. Phase of ‘Hollandii’ settlement (ca. 1770-1863). Its influence is indicated first by the recession of deciduous wood (Corylus, Carpinus) stands, which triggered drastic drop of calcium in sediments. The development of rural economy in the area, including, an extension of agriculture (Secale and other cereals, crucifers, potatoes), and animal breeding based partly on grazing in the forest, is evidenced only after 1820. 3. Phase of German colonization (1863-1944): In the early periods (before 1910) the pollen spectra do not document any essential change in the type of farming, however, a serious disturbance of the lake ecosystem and sediment chemistry is evidenced by the blooms of Araphidinae diatoms and Tetraedron minimum, a maximum frequency of Bosmina longirostris, disturbances of the regular spring blooms of Chrysophyceae, appearance of vivianite, distinct maxima of organic matter, potassium, and iron concentration in sediments and an increase of the sedimentation rate. An intensification of agricultural activities commenced around 1910; woods, including also pinewoods, were then heavily devastated, and farming extended on poor soils, what was symptomatic for the general poverty of population. Coincidently in the lake, Centriceae showed blooms, Araphidinae diatoms and Tetraedron minimum developed, and the content of potassium, iron and phosphorus increased substantially, indicating altogether rising eutrophication. 4. Phase of restoration of the natural landscape (after 1945): The farm degradation from ca. 1944 is very weakly expressed in pollen data, which show a substantial fall of farming indicators from 1953/6 only, when the whole area was used for forest plantation. It was accompanied by a certainly spontaneous development of Betula and Alnus woods, this process progressing till recent time. The gradual extinction of farming activity near Lake Gościąż was accompanied by abrupt changes in the lake ecosystem, expressed by the restored blooms of Chrysophyceae expansion of planktonic Cladocera, rapid decline of phosphorus and extinction of vivianite from sediments. As documented by the drop of Cu/Zn ratio, lake hypolimnion has been weakly oxidized since 1949, what was probably responsible for the drop of Fe and Mn content in sediments. Increasing strength of overturns affected preservation of laminae in sediments, which almost completely disappeared after 1966.
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  • 6
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    Journal of paleolimnology 21 (1999), S. 375-393 
    ISSN: 1573-0417
    Keywords: CaCO3 ; organic carbon ; iron ; manganese ; eutrophication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract The concentrations of organic carbon (OC) and CaCO3 in lake sediments are often inversely related. This relation occurs in surface sediments from different locations in the same lake, surface sediments from different lakes, and with depth in Holocene sediments. Where data on accumulation rates are available, the relation holds for organic carbon and CaCO3 accumulation rates as well. An increase of several percent OC is accompanied by a decrease of several tens of percent CaCO3 indicating that the inverse relation is not due to simple dilution of one component by another. It appears from core data that once the OC concentration in the sediments becomes greater than about 12%, the CO2 produced by decomposition of that OC and production of organic acids lowers the pH of anoxic pore waters enough to dissolve any CaCO3 that reaches the sediment-water interface. In a lake with a seasonally anoxic hypolimnion, processes in the water column also can produce an inverse relation between OC and CaCO3 over time. If productivity of the lake increases, the rain rate of OC from the epilimnion increases. Biogenic removal of CO2 and accompanying increase in pH also may increase the production of CaCO3. However, the decomposition of organic matter in the hypolimnion will decrease the pH of the hypolimnion causing greater dissolution of CaCO3 and therefore a decrease in the rain rate of CaCO3 to the sediment-water interface.
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  • 7
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    Journal of thermal analysis and calorimetry 55 (1999), S. 9-19 
    ISSN: 1572-8943
    Keywords: ARC ; DSC ; HFC ; kinetics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Isopropylnitrate (IPN) is described as a detonable material used in propellants and explosives. While there is considerable information available on its sensitivity and compatibility with other materials, very little is known about its thermochemical properties. This paper will describe the results obtained from some DSC, heat flux calorimetry (HFC) and accelerating rate calorimetry (ARC) measurements. The ASTM DSC method using a hermetic aluminum pan having a lid with a laser-produced pin hole was used to determine the vapour pressure of IPN1. Results calculated from an Antoine equation are in substantial agreement with those determined from DSC measurements. From the latter measurements, the enthalpy of vaporization was determined to be 35.32±0.62 kJ mol−1. Attempts to determine vapour pressures above about 0.8 MPa resulted in significant decomposition of IPNg. The enthalpy change for decomposition in sealed glass systems was found to be -3.43±0.09 kJ g−1 and -3.85±0.03 kJ g−1, respectively from DSC and HFC measurements on IPN1 samples loaded in air. Slightly larger exotherms were observed for the HFC results in air than those in inert gas, suggesting some oxidation occurs. In contrast, no significant difference in the observed onset temperature of about 150°C was observed for both the HFC and ARC results. From DSC measurements, an Arrhenius activation energy for decomposition of 126±4 kJ mol−1 was found. These measurements were also conducted in sealed glass systems and decomposition appeared to proceed primarily from the liquid phase.
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  • 8
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    Journal of thermal analysis and calorimetry 55 (1999), S. 67-76 
    ISSN: 1572-8943
    Keywords: activation energy ; DSC ; ethylene-vinyl acetate copolymer ; TG ; TG/IR ; thermal degradation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract When ethylene-vinyl acetate copolymer, EVA, is heated, a two-stage thermal degradation occurs following its melting. The vinyl acetate content of the copolymer was determined to be 43.8% by using TA 2950 and TA 2050 thermogravimetric instruments. TG/FTIR was used to detect the evolved gas. Acetic acid and trans-1-R-4-R'-cyclohexane were the main products evolved from EVA in the first and second stage, respectively. The apparent activation energies were determined for both stages by differential methods.
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  • 9
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    Journal of thermal analysis and calorimetry 55 (1999), S. 57-65 
    ISSN: 1572-8943
    Keywords: artificial ageing ; DSC ; dynamic crystallization ; isoconversional method
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A crystallization kinetics analysis of several polypropylene-polyethylene (PP-PE), PP-rich copolymers was made by means of differential scanning calorimetry. The crystallization was studied via calorimetric measurements at different cooling rates. Several additives were added to the base material. Some test samples were subjected to artificial ageing processes. A modified isoconversional method was used to describe the crystallization process under non-isothermal conditions. The value of the Avrami parameter was determined for primary and secondary crystallization.
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  • 10
    ISSN: 1572-8943
    Keywords: dioximine complexes of Co ; DSC ; kinetic compensation effect ; kinetic parameters of thermal decomposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract 14 mixed Co(III) dioximine chelates of the types [Co(Diox·H)2(amine)2]X (X = Br, I, NO3, ClO4) and H[Co(Diox·H)2(N3)2], respectively (Diox·H2-1,2-cyclohexane dione dioxime (nyoxime), 1,2-cycloheptane dione dioxime (heptoxime) 1,2-cyclooctane dione dioxime (octoxime) were obtained and their thermal decompositions were studied in an argon atmosphere. After the dehydration of the crystallohydrates, both types of complexes exhibit 3 decomposition stages. For the [Co(Diox·H)2(amine)2]X type complexes (X = Br, I) the first endothermal stage is the substitution of an amine molecule for the external sphere anion and this process is followed by two exothermal decomposition stages. With H[Co(Diox·H)2(N3)2] type complexes the first and third processes are relatively slow, but the second process is very fast, corresponding to a vertical portion of the TG curves. From the TG curves kinetic parameters were derived for 11 processes and the validity of a non-linear compensation law was observed.
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  • 11
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    Journal of thermal analysis and calorimetry 56 (1999), S. 51-57 
    ISSN: 1572-8943
    Keywords: DSC ; enthalpies ; NaAlF4 ; Na5Al3F14
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Beside the two well-known minerals cryolite, Na3AlF6, and chiolite, Na5Al3F14, the binary system NaF-AlF3 also contains a third compound, NaAlF4, sodium tetrafluoroaluminate. Solid NaAlF4 has been prepared from its vapour under controlled conditions. The stability of NaAlF4 has been investigated by differential scanning calorimetry. It is shown that the disproportionation of the compound: 5NaAlF4(s)=Na5Al3F14(s)+2AlF3(s) takes place at considerable rate between 700 and 900 K. The enthalpy of this reaction is calculated and found to be -66.9 kJ. Enthalpies of the two solid state transitions α-Na3AlF6 → β-Na3AlF6 and α-AlF3 → β-AlF3 have also been measured and new values are reported. The enthalpy of formation of chiolite, Na5Al3F14, at 900 K has been recalculated from enthalpy increment data obtained by drop calorimetry. A value of ΔH900 o = -7513.6±12.0 kJ mol-1 has been obtained. This value is in disagreement with the recommended value given in JANAF Thermochemical Tables given at 900 K ΔHf o = -7559.2 kJ mol-1.
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  • 12
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    Journal of thermal analysis and calorimetry 56 (1999), S. 925-929 
    ISSN: 1572-8943
    Keywords: DSC ; equilibrium ; Fe-Ni distribution ; monosulfide solid solution ; pentlandite
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Two mixtures of pentlandite and the monosulfide solid solution (mss) have been synthesized. The bulk compositions of the samples are Fe6Ni3S8 and Fe3Ni6S8. Differential scanning calorimetry detected exothermic process in the samples under heating. The process takes place in temperature range between phase transition in the mss (near 400 K) and 690 K and is governed by diffusion. X-ray powder diffraction has showed that equilibrium Fe-Ni distribution between pentlandite and the mss is achieved after short-time heating up to 670 K.
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  • 13
    ISSN: 1572-8943
    Keywords: cure kinetics ; DSC ; epoxy resin ; SAN ; thermoplastic blends
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Cure kinetics using a differential scanning calorimetry (DSC) technique were analyzed for a thermoplastic modified tetraglycidyl-4,4′-diaminodiphenylmethane (TGDDM) epoxy resin cured with diaminodiphenylsulphone (DDS), an aromatic diamine. The neat resin and its blends with the poly(styrene-co-acrylonitrile) (SAN) of various compositions were studied by applying a phenomenological model proposed by Kamal. Kinetic parameters were determined by fitting experimental data. This model gives a good description of cure kinetics up to the onset of vitrification. Diffusion control was incorporated to describe the cure in the latter stages of cure. The results showed that the addition of SAN did not alter the nature of the reaction, but the reaction rates and final conversions decreased when SAN contents increase, due to reduction of mobility of the reacting species.
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  • 14
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    Journal of thermal analysis and calorimetry 56 (1999), S. 1285-1304 
    ISSN: 1572-8943
    Keywords: amorphous state ; combined techniques ; drug design ; drug product development ; drug substance ; drug technology ; DSC ; excipients ; failure investigations ; hydrates ; MDSC ; microcalorimetry ; pharmaceuticals ; polymorphism ; polymers ; preformulation ; process optimization ; purity ; quality control ; solvates ; stability ; sub-ambient DSC ; TG ; temperature resolved X-ray diffraction ; water interactions ; thermal microscopy ; water sorption-desorption
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Modern thermal analysis, microcalorimetry and new emerging combined techniques which deliver calorimetric, microscopic and spectroscopic data offer a powerful analytical battery for the study of pharmaceuticals. These techniques are very useful in all steps of development of new drug products as well as methods for quality control in production. The characterization of raw materials enables to understand the relationships between polymorphs, solvates and hydrates and to choose the proper development of new drug products with very small amount of material in a very short time. Information on stability, purity is valuable for new entities as well as for marketed drug substances from different suppliers. Excipients which vary from single organic or inorganic entity to complexes matrixes or polymers need to be characterized and properly controlled. The thermodynamic phase-diagrams are the basis of the studies of drug-excipients interactions. They are very useful for the development of new delivery systems. A great number of new formulations need proper knowledge of the behaviour of the glass transition temperature of the components. Semi-liquid systems, interactions in aqueous media are also successfully studied by these techniques.
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  • 15
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    Journal of thermal analysis and calorimetry 57 (1999), S. 61-73 
    ISSN: 1572-8943
    Keywords: amorphous ; combined techniques for polymorphism ; DSC ; MKS 492 ; polymorphism ; purine ; quantitative determination ofamorphous and polymorphs ; solvent mediated transitions ; temperature resolved X-ray diffraction ; TG ; thermodynamic relation between polymorphs ; xanthine
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The polymorphic behaviour of the purine derivative MKS 492 was studied with investigations of suspensions of selected samples in different solvents and of samples obtained by crystallizations. The samples were analyzed by DSC, TG and X-ray diffraction. Six different crystalline modifications called A, B, B’, C, D and E and an amorphous form were identified. Four pure crystalline modifications, A, B, C and D have been manufactured and characterized by DSC, X-ray, IR, solubilities, densities, hygroscopicity and dissolution measurements. The four forms A, C, D and E are monotrop to the form B. The form B is enantiotrop to the form B’, which revealed the highest melting point of all known polymorphs. This form B’ is only stable at high temperature. Temperature resolved X-ray diffraction was very helpful for proper interpretation of the thermal events. The melting peaks of the forms A and C and the endothermic peak corresponding to the enantiotropic transition B into B’ occur in a narrow range of temperature. The form B which is the most stable one at room temperature has been chosen for further development. Quantitative methods to determine the content of the forms A, C and D in samples of form B or to determine the content of form A, B and D in form C have been developed by using X-ray diffraction. Limits of detection are 1 or 2%. For the quantitative determination of the amorphous fraction, X-ray diffraction and microcalorimetry are compared. For high amounts of the amorphous fraction, the X-ray diffraction method is preferred because it is faster. Microcalorimetry is very attractive for levels below 10% amorphous content. The lowest limit of detection is obtained by microcalorimetry, about 1%.
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  • 16
    ISSN: 1572-8943
    Keywords: crystal modifications ; DSC ; Gibbs free energy function ; molecular modelling ; solution calorimetry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The thermodynamic energy relationship between two crystal modifications of cimetidine was investigated and compared with differences in their processing properties with respect to transformation from one modification to the other. The crystal energies of the two modifications A and D were found to be almost identical and therefore the polymorphs are regarded as virtually isoenergetic crystals. This statement is based on DSC measurements of the melting points and of the enthalpies of fusion for the two crystal forms, which enable the calculation of the Gibbs free energy functions. Furthermore, the statement is supported by measurements of the enthalpies of solution in two different solvents. Both DSC and solution experiments reveal a slightly higher stability of the D modification with respect to the A form. In addition, tribomechanical treatment also indicates modification D to be the more stable one, as well as the higher density of the D form. No transformation during DSC at low heating rate was found which could be used in a stability consideration. As the explicit crystal structures of the two modifications are resolved, it was possible to calculate crystal energies theoretically as well. The theoretical results showed a remarkable difference in the crystal energies at zero degree Kelvin. Furthermore, they were just contradicting experimental findings by stating A being more stable than D. Possible reasons for this discrepancy and the feasibility of today's calculation methods with respect to prediction of stability properties are discussed.
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  • 17
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    Journal of thermal analysis and calorimetry 57 (1999), S. 631-642 
    ISSN: 1572-8943
    Keywords: DSC ; fluorocarbon chain ; polymerizability ; polymorphic behaviors ; X-ray diffraction
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The molecular aggregation of acrylic and methacrylic acid esters containing long-fluorocarbon chains: 2-(perfluoroalkyl)ethyl acrylate (FFnEA) and 2-(perfluoroalkyl)ethyl methacrylate (FFnEMA) (F(CF2)nCH2CH2OCOC(X)=CH2, where X=H, CH3 and n=6, 8, 10) was investigated by differential scanning calorimetry (DSC) and temperature controlled X-ray powder diffraction measurement. These compounds exhibited some characteristic polymorphic behaviors depending on the length of fluorocarbon chain and the α-position methyl group. The solid-state polymerization by γ-ray irradiation was studied for these compounds in the various crystal forms. In the solid-state polymerization, highest polymerizability was observed in the crystal form that exists in the highest temperature region for each compound.
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  • 18
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    Journal of thermal analysis and calorimetry 58 (1999), S. 29-38 
    ISSN: 1572-8943
    Keywords: benzoicacid ; controlled release ; DSC ; ethyl cellulose ; FTIR
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The physical state of benzoic acid (BA) and its interaction with ethyl cellulose (EC) were examined in ethyl cellulose—benzoic acid matrices by Differential Scanning Calorimetry (DSC). The glass transition temperature (Tg) of EC of various matrices having BA in solid solution form (upto 27.7%) was reduced. The BA in matrices containing more than 38.9% drug exhibited distinct melting endotherms due to crystalline form. The peak temperatures of these endotherms were lowered and they broadened as the concentration was lowered. The solubility of BA increased at its melting point as compared to ambient temperature. The melting enthalpy of BA, when plotted as a function of its concentration yielded a straight line with intercept of 330 mg g−1 of matrix. This is the solubility of BA in EC at its melting temperature. Fourier Transform Infra Red Spectroscopy (FTIR) investigations confirmed that hydrogen bonding occurred between EC and BA through hydroxyl groups.
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  • 19
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    Journal of thermal analysis and calorimetry 58 (1999), S. 363-368 
    ISSN: 1572-8943
    Keywords: DSC ; lipid ; phase behaviour ; synchrotron radiation ; X-ray diffraction
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The phase behaviour and phase stability of lipids are of importance in an understanding of the biological functions of cell membranes. Among a variety of physical techniques employed to study the phase behaviour and structural properties of polar lipids, differential scanning calorimetry and X-ray diffraction have proved to be successful and are the most frequently used methods. Applications involving a combination of the two techniques, particularly when synchrotron radiation is used as the light source of X-ray diffraction, are reviewed in this article.
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  • 20
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    Journal of thermal analysis and calorimetry 58 (1999), S. 653-662 
    ISSN: 1572-8943
    Keywords: dehydration ; DSC ; TG ; water ; zeolites
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A procedure for measurement of the heat of zeolite dehydration by scanning heating has been designed. Simultaneous data on heat flow (DSC) and mass loss (TG) are required for evaluation. The heating rate depends on the experimental conditions (point-spread function, sample mass, crucible design, and calorimetric reproducibility). Dehydration measurements have three advantages as compared with the sorption procedure: i) one can investigate samples with irreversible dehydration; ii) no approximation model is needed for calculation of the partial molar heat of dehydration; and iii) the procedure is not labor-consuming. The procedure was tested on the natural zeolites heulandite, chabazite and mordenite. The results are close to those measured by the sorption procedure. The partial molar heat of dehydration was found to depend on the water content. It increases from 50 to 87 J mol−1 K−1 for heulandite, from 53 to 81 J mol−1 K−1 for chabazite, and from 51 to 71 J mol−1 K−1 for mordenite. The approximation of the heat of sorption by linear regression was found to be wrong. Detection of a ‘phase transitioN’ after this approximation has no meaning.
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    Journal of thermal analysis and calorimetry 58 (1999), S. 725-739 
    ISSN: 1572-8943
    Keywords: DDC ; DSC ; DTA ; transformation-governed TA
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    Topics: Chemistry and Pharmacology
    Notes: Abstract The described instrumental method makes it possible that the quasi-static heating technique, well applicable to thermogravimetric measurements, (see Part I of this paper) can be used in the case of DTA and DSC examinations, too. Based on the new type of curves the characteristic transformation temperatures, the whole course of the transformation in dependence of sample temperature, the extent of the enthalpy change caused by the transformation or by its partial processes can accurately be determined. The essentially greater accuracy of the measurements — in comparison to the conventional ones — is due to the quasi-static heating technique which ensures that the transformations should take place under quasi-equilibrium conditions.
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  • 22
    ISSN: 1572-8943
    Keywords: alkylureas ; DOAB vesicles ; DSC ; gel-liquid transitions ; urea
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    Topics: Chemistry and Pharmacology
    Notes: Abstract The gel to liquid-crystal transition for vesicles in aqueous solution formed by dimethyldi-n-octadecylammonium bromide (DOAB) occurs at 44.7°C. Moreover, the shapes of the scans recorded by a sensitive DSC microcalorimeter are very similar when the vesicular solutions are prepared starting with solid DOAB and comparable amounts of either solid urea or solid alkylureas. Therefore, the DOAB vesicles in aqueous solution accommodate this class of solutes without marked changes in the melting temperature and the enthalpy of the transition. The contrast with effects of added surfactants and simple organic solutes such as THF and ethanol is particularly significant.
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  • 23
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    Journal of thermal analysis and calorimetry 55 (1999), S. 807-816 
    ISSN: 1572-8943
    Keywords: DSC ; hydrogen-bond ; IR ; lithium formate monohydrate ; Raman spectroscopy
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Differential scanning calorimetry (DSC) and thermogravimetric analysis (TG) of lithium formate monohydrate (LiHCOO·H2O) were performed in the temperature range 300–700 K. The DSC/TG measurements show that the dehydration process to anhydrous lithium formate (LiHCOO) is complex and occurs in two stages. The data are correlated to the structure and to the arrangement of the molecules in the crystal, including the hydrogen-bonding. Infrared transmittance and Raman spectra of this crystal are reported and commented on.
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  • 24
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    Journal of thermal analysis and calorimetry 55 (1999), S. 789-796 
    ISSN: 1572-8943
    Keywords: alkaline earth malonates ; DSC ; DTA ; kinetic parameters ; TG ; thermal decomposition
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    Topics: Chemistry and Pharmacology
    Notes: Abstract The thermal decomposition of strontium and barium malonates has been studied isothermally and non-isothermally employing simultaneous TG-DTG-DTA, DSC, XRD and IR spectroscopic techniques. DSC of these malonates has been recorded both in oxygen and nitrogen atmospheres. The decomposition is a single step process and the end product formed is carbonate. The energy of activation and frequency factor values for the decomposition of strontium malonate are 547 kJ mol−1 and 1041 s−1 respectively. The activation energy and frequency factor values for isothermal dehydration of barium malonate sester-hydrate are 57–111 kJ mol−1 and 107–1012 s−1 respectively and the corresponding values for decomposition from DSC are 499.5 kJ mol−1 and 1044 s−1 respectively. The higher thermal stability of strontium malonate as compared to that of barium salt is ascribed to its being anhydrous so that decomposition proceeds without restructuring. Their thermal stabilities have also been compared with that of respective oxalate salts.
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  • 25
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    Journal of thermal analysis and calorimetry 56 (1999), S. 7-15 
    ISSN: 1572-8943
    Keywords: ALE ; CVD ; DSC ; DTA ; EGA ; EL display ; solar cell ; sol-gel ; spray pyrolysis ; super-conductor ; TG ; thin films
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Processing thin films for advanced applications, for instance in electronics and optoelectronics, involves several steps starting from precursor synthesis and ending up with the devices. Especially when optimizing the first steps of this chain of processes, thermoanalytical techniques play an important role. The review will focus on the main chemical deposition methods (CVD, ALE, spray pyrolysis, sol-gel) giving selected examples of problem-solving by thermal analysis. The techniques discussed are TG, DTA/DSC, EGA and their combinations. High-temperature X-ray diffraction (HTXRD) is also a powerful tool for in situ studies of thin films. The examples are taken from solar cell, superconductor and flat panel electroluminescent display technologies.
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    Journal of thermal analysis and calorimetry 56 (1999), S. 429-435 
    ISSN: 1572-8943
    Keywords: DSC ; nickel sulphide ; TG ; toughened glass ; X-ray diffraction
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Nickel sulphide (NiS) was characterised using X-ray diffraction, thermal gravimetric analysis (TG) and differential scanning calorimetry (DSC). The 'as received' Millerite, stoichiometric NiS, observed to be slightly nickel deficient, was found to readily decompose in a nitrogen atmosphere at elevated temperatures (450°C max.) to the sulphur deficient Godlevskite, Ni7S6. DSC and X-ray measurements demonstrated that the high temperature form of the Godlevskite was readily stabilised at room temperature. The kinetics of the α-β re-transformation in Godlevskite were then investigated using DSC and were observed to be first order.
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    Journal of thermal analysis and calorimetry 56 (1999), S. 547-552 
    ISSN: 1572-8943
    Keywords: cobalt oxysalts ; DSC ; enthalpy of decomposition ; enthalpy of dehydration ; thermal decomposition
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Differential scanning calorimetry (DSC) was used to determine the molar enthalpies of dehydration and decomposition of CoC2O4·2H2O, Co(HCOO)2·2H2O and [Co(NH3)6]2(C2O4)3·4H2O. The first stage of dissociation of each compound is a single-step dehydration both in air and argon atmospheres. The next stages are decomposition processes influenced by experimental parameters. The enthalpies of dehydration and decomposition vary from compound to compound in each atmosphere. The obtained data have been related to the macromechanisms proposed for the thermal decomposition and the parallel-consecutive decomposition-oxidation processes.
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    Journal of thermal analysis and calorimetry 56 (1999), S. 783-792 
    ISSN: 1572-8943
    Keywords: complex process ; DSC ; isoconversional methods ; kinetics ; model-free kinetics ; peak maximum evolution methods ; simulations
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    Topics: Chemistry and Pharmacology
    Notes: Abstract In the case of a complex mechanism of two parallel independent reactions, peak maximum evolution methods and model-fitting methods give only a mean value of the kinetic parameters, while isoconversional methods are useful to describe the complexity of the mechanism. Isothermal and non-isothermal isoconversional methods can be used to elucidate the kinetics of the process. Nevertheless, isothermal isoconversional methods can be limited by restrictions on the temperature regions experimentally available because of duration times or detection limits.
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    Journal of thermal analysis and calorimetry 56 (1999), S. 947-951 
    ISSN: 1572-8943
    Keywords: combustion ; crude oil ; DSC ; TG/DTG
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    Topics: Chemistry and Pharmacology
    Notes: Abstract This paper investigates the minimum oil content necessary for self-sustained combustion, which is introduced as a criterion for the selection of suitable reservoirs for in-situ combustion processes. Differential scanning calorimetry was used to determine the heat values of oil-limestone mixtures. The minimum temperature required for the total consumption of the fuel was obtained by thermogravimetry (TG/DTG). The minimum amount of oil necessary to sustain combustion was calculated from these two parameters and compared with the oil content of the reservoir. Reservoirs with an oil content greater than or equal to this minimum value were considered feasible. It was seen that the fields examined are generally not suitable for in-situ combustion processes.
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    Journal of thermal analysis and calorimetry 56 (1999), S. 1155-1161 
    ISSN: 1572-8943
    Keywords: crystallisation ; DMA ; DSC ; PCL ; polymer ; temperature modulation
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Temperature modulated dynamic mechanical analysis (TMDMA) was performed in the same way as temperature modulated DSC (TMDSC) measurements. As in TMDSC TMDMA allows the investigation of reversible and non-reversible phenomena during crystallisation of polymers. The advantage of TMDMA compared to TMDSC is the high sensitivity for small and slow changes in crystallinity, e.g. during re-crystallisation. The combination of TMDMA and TMDSC yields new information about local processes at the surface of polymer crystallites. It is shown that during and after isothermal crystallisation the surface of the individual crystallites is in equilibrium with the surrounding melt.
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    Journal of thermal analysis and calorimetry 56 (1999), S. 1141-1146 
    ISSN: 1572-8943
    Keywords: crystallization ; DSC ; heavy ion irradiation ; melting ; PBT films ; poly(butyleneterephthalate) films
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    Topics: Chemistry and Pharmacology
    Notes: Abstract The influence of heavy ion-irradiation (Ar 5.5 MeV amu-1, 5·1011 ion cm-2) on the melting and crystallization of two PBT films subjected to different modes of thermal treatment was investigated. Differences were observed between the processes occurring in both initial films, due to differences in crystalline phase content. The course of melting and crystallization in heavy ion-irradiated films during first heating, cooling and second heating differs from that in the initial films. The density data and DSC results indicate a decreased crystalline phase content in the PBT films after irradiation.
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    Journal of thermal analysis and calorimetry 56 (1999), S. 1353-1357 
    ISSN: 1572-8943
    Keywords: DSC ; terpenoids ; TG ; thermal behaviour
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    Topics: Chemistry and Pharmacology
    Notes: Abstract The terpenoids acetyl sitosterol, lupeol, acetyl diosgenin and stigmasterol were studied. Comparison of the thermogravimetric curves and the activation energies of the terpenoids suggested the following sequence of thermal stability: acetyl sitosterol 〈 acetyl diosgenin 〈 lupeol 〈 stigmasterol. The DSC curves allowed determination of the melting points and the degrees of purity. Comparison of the TG and DSC curves revealed the presence of phase transitions without mass loss that were attributed to rearrangements in the terpenoid molecules.
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    Journal of thermal analysis and calorimetry 57 (1999), S. 371-375 
    ISSN: 1572-8943
    Keywords: C14E8 ; detergent ; DSC ; polyethylene glycol tetradecyl ether ; thermal transition
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    Topics: Chemistry and Pharmacology
    Notes: Abstract A narrow, reversible endothermic main transition is found in the aqueous micellar phase of octaethylene glycol tetradecyl ether (C14E8) by DSC, characterized by a transition temperature of 41°C and a ΔH value of 0.5 kcal mol−1, which is not observed by light scattering. This transition is assigned to a cooperative conformational rearrangement of the assembled amphiphilic detergent molecules and not to a micelle aggregation process. It is suggested that the detergent’s polar head group is primarily involved in this rearrangement.
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  • 34
    ISSN: 1572-8943
    Keywords: DSC ; iron(II)-oxime complexes ; kinetic parameters ; Mössbauer spectroscopy
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    Topics: Chemistry and Pharmacology
    Notes: Abstract A number of 15 [Fe(Diox#x00B7;H)2L2] type chelates and [Fe(Diox)3(BOR)2] clathrochelates (Diox#x00B7;H2 — dimethylglyoxime, glyoxime, propoxime, nyoxime, furyl-dioxime; L-pyridine, alkyl-pyridine derivatives, diethyl-phenyl-phosphine, diethyl-p-tolyl-phosphine) were obtained and characterized by means of far and middle FTIR and Mössbauer spectroscopic methods. Some structural problems were discussed on the basis of the optical data. The DSC measurements show the higher thermal stability of the clathrochelates without O—H⋯O intramolecular hydrogen bonds (with asymmetric octahedral structure), as compared to the [Fe(Diox#x00B7;H)2L2] trans, symmetric chelates containing O—H⋯O bonds. The kinetic parameters of the thermal decomposition of the complexes have been derived using the nomogram method.
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    Journal of thermal analysis and calorimetry 57 (1999), S. 745-752 
    ISSN: 1572-8943
    Keywords: confinement effects ; DSC ; dynamic light scattering ; finite-size effects ; glass transition ; o-terphenyl
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Calorimetry is the method first used by Jackson and McKenna to study the effect of finite-size on the molecular dynamics of glass-formers confined in nano-meter scale pores. It was found that the glass transition is shifted to lower temperature as pore size decreases. Since then, other spectroscopic techniques have corroborated this finding and given more information on the molecular dynamics. These results are used to compare with the predictions of several theories of glass transition, and in particular the coupling model of the author.
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    Journal of thermal analysis and calorimetry 57 (1999), S. 847-851 
    ISSN: 1572-8943
    Keywords: DSC ; linear low-density polyethylene(LLDPE) ; low density polyethylene (LDPE) ; polymer blend ; thermal properties
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    Topics: Chemistry and Pharmacology
    Notes: Abstract A forensic sample consisting of melt-recrystallized polymers that was recovered from the scene of a fire in a factory was identified by differential scanning calorimetry. The factory commonly used two kinds of film sheets, A and B, made by different manufacturers. It was necessary to decide whether the forensic sample related to material A or B. The forensic sample and reference samples of materials A and B were subjected to infrared spectroscopy and pyrolysis gas chromatograph mass spectrometry measurements, which revealed their polyethylene nature. The thermal behaviour of the samples was examined by differential scanning calorimetry (DSC) and they were found to be blends of two kinds of polyethylenes, low-density polyethylene and linear low-density polyethylene. The samples could be identified and distinguished from each other via the DSC measurements.
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    Journal of thermal analysis and calorimetry 58 (1999), S. 369-373 
    ISSN: 1572-8943
    Keywords: critical temperature ; DSC ; HNNC ; non-isothermal
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Two methods for estimating the critical temperature (Tb) of thermal explosion for the highly nitrated nitrocellulose (HNNC) are derived from the Semenov's thermal explosion theory and two non-isothermal kinetic equations, dα/dt=Af(α)e−E/RT and dα/dt=Af(α)[1+E/(RT)(1–To/T)]e−E/RT, using reasonable hypotheses. We can easily obtain the values of the thermal decomposition activation energy (E), the onset temperature (Te) and the initial temperature (To) at which DSC curve deviates from the baseline of the non-isothermal DSC curve of HNNC, and then calculate the critical temperature (Tb) of thermal explosion by the two derived formulae. The results obtained with the two methods for HNNC are in agreement to each other.
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    Journal of thermal analysis and calorimetry 55 (1999), S. 155-164 
    ISSN: 1572-8943
    Keywords: DSC ; glass ; relaxation ; structure
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    Topics: Chemistry and Pharmacology
    Notes: Abstract The enthalpic relaxation of the title glasses, studied by differential scanning calorimetry, is well described by a mathematical model based on the stretched exponential relaxation function with the relaxation time proportional to the actual viscosity. The dependence of viscosity on temperature and the fictive temperature was expressed by Mazurin's approximation. The relaxation parameters obtained correlated significantly with the glass composition, indicating the changes in the structural of the TiO2 role near a TiO2 content of 3–4 mol%.
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    Journal of thermal analysis and calorimetry 55 (1999), S. 165-172 
    ISSN: 1572-8943
    Keywords: DSC ; nickel(II) squarate ; phase transition ; TG-DTA ; triamine
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    Topics: Chemistry and Pharmacology
    Notes: Abstract [NiL2]C4O4·nH2O [where n=2 when L=diethylenetriamine(dien) and N-(3-aminopropyl)-1,3-propanediamine (dpt); n=3 when L=N-(2-aminoethyl)-1,3-propanediamine (aepn); n=0 when L=N2-methyldiethylenetriamine (medien)] and Ni(tmdien)C4O4·2H2O (where tmdien=1,4,7 trimethyl-diethylenetriamine) have been synthesised and investigated thermally in the solid state. Ni(dpt)C4O4·H2O has also been synthesised pyrolytically in the solid state from the corresponding bis complex. All the complexes possess octahedral geometry. The squarate anion takes part in coordination only in monotriamine species. [Ni(medien)2]C4O4 upon heating undergoes phase transition (270–285°C; ΔH=4.9 kJ mol−1) accompanied by colour change pink to grey. Thermal stability decreases with increase in chain length of the triamines.
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    Journal of thermal analysis and calorimetry 56 (1999), S. 305-310 
    ISSN: 1572-8943
    Keywords: amorphous palladium alloys ; DSC ; hydrogenation ; mechanical alloying ; phenylacetylene ; structural characterization ; X-ray diffractometry ; X-ray photoelectron spectroscopy
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Amorphous PdZr, PdCuZr and PdCuSi alloy ribbons and powders are characterized by DSC, XRD and XPS in the as-received state and after treatments with oxygen, hydrogen or dilute hydrogen fluoride solution. Zr-containing alloys are shown to undergo substantial structural changes resulting in palladium enrichment on their surface, whereas no apparent changes in the bulk structure are found for PdCuSi. Catalytic activity and selectivity of the pretreated samples were tested in the hydrogenation of phenylacetylene.
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    Journal of thermal analysis and calorimetry 56 (1999), S. 1203-1209 
    ISSN: 1572-8943
    Keywords: conformation of myosin ; DSC ; EPR ; spin labelling
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    Topics: Chemistry and Pharmacology
    Notes: Abstract The internal dynamics and the thermal stability of myosin in rabbit psoas muscle fibres in different intermediate states of the ATP hydrolysis cycle were studied by differential scanning calorimetry (DSC) and electron paramagnetic resonance (EPR) spectroscopy. Three overlapping endotherms were detected in rigor, in strongly binding and weakly binding state of myosin to actin. The transition at 58.4°C can be assigned to the nucleotide-binding domain. The transition at highest temperature represents the unfolding of the actin and the contributions arising from the actin-myosin interaction. The transition of 54°C reflects the interaction between the subunits of myosin. Nucleotide binding induced shifts of the melting temperatures and produced variations in the calorimetric enthalpy changes. The changes of the EPR parameters indicated local rearrangements of the internal structure in myosin heads.
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    Journal of thermal analysis and calorimetry 56 (1999), S. 1323-1327 
    ISSN: 1572-8943
    Keywords: chloramphenicol ; DSC ; quality control ; TG
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    Topics: Chemistry and Pharmacology
    Notes: Abstract The stability and thermal behaviour of chloramphenicol and various of its mixtures were investigated. The thermogravimetric and stability constant results showed that the chloramphenicol base is thermally more stable than the tablet in the studied formulation. The reduction in stability was attributed to the presence of starch in the formulation. The thermal decompositions of the chloramphenicol base and the tablet obey first-order kinetics.
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    Journal of thermal analysis and calorimetry 56 (1999), S. 1311-1316 
    ISSN: 1572-8943
    Keywords: alumina ; aluminum oxide ; compact ; DSC ; particles ; pentaerythritol tetraacetate ; pharmaceuticals ; powder ; thermal resistance ; transient state
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    Topics: Chemistry and Pharmacology
    Notes: Abstract The previously described method involving the use of transient DSC was applied to pharmaceutical powder compacts and to ceramic powder compacts. The samples were prepared by compressing powders of pentaerythritol tetraacetate and two kinds of alumina powder (differing in particle size distribution) up to a pressure of 20 MPa by using a jig. For pentaerythritol tetraacetate, a linear relationship was obtained between the parameter obtained by DSC and the compaction pressure.
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    Journal of thermal analysis and calorimetry 56 (1999), S. 1005-1010 
    ISSN: 1572-8943
    Keywords: DSC ; enthalpic relaxation ; glass transition ; physical ageing
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Enthalpic relaxation has been used to model the development of the glass transition in polymers, using kinetic parameters determined separately. For this purpose the Kohlrausch-Williams-Watt stretched exponential function, relating the extent of relaxation, Φ(t), to time t and an average relaxation time, τa, i.e. $$1 - \Phi \left( t \right) = \exp \left( { - t/ta} \right)^{\beta }$$ where β is inversely related to the breadth of the relaxation spectrum, has been adopted. The relaxation time dependence on temperature was taken to follow the modified Arrhenius relationship, $$\tau _a = A\exp \left[ {\frac{{X\Delta H}}{{RT}} + \frac{{\left( {1 - X} \right)\Delta H}}{{RT'}}} \right]$$ where T is the storage and T′ the fictive temperature, X is the structure factor and ΔH the activation enthalpy. Both have been found to describe the process of enthalpic relaxation in polymer glasses and a direct comparison has been made with the change in specific heat observed with different cooling rates in DSC experiments. The effect of variables, such as activation enthalpies, pre-exponential factors, and the non-linear factors such as X and β on the observed Tgs and the temperature range over which the transition occurred have been determined.
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    Journal of thermal analysis and calorimetry 57 (1999), S. 283-291 
    ISSN: 1572-8943
    Keywords: DSC ; fish ; general proteolytic activity ; pyloric caeca ; ripening ; salted herring product
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The thermoanalytical behaviour of pyloric caeca during salting and ripening was investigated using a Perkin Elmer DSC 7. Not only the thermal stability of the muscle proteins was influenced by salting but also that of pyloric caeca. It was recognised that the salting itself leads to a remarkable increase of the transition temperature compared with raw herring. An influence of the salt:fish ratio could be observed. The higher the salt content the higher the increase of the denaturation temperature. During ripening the transition temperature remained on a high level or showed only a slight decrease during the investigation period. The dependency from the salt content remained evident. The increase of the transition temperature was accompanied by a decrease of the transition enthalpy. The increase of thermal stability is connected with a decrease of the general proteolytic activity in pyloric caeca. Possibly, the enzymes are diffusing from the pyloric caeca into the muscle and cause there an increase of enzymatic activity observable in North Sea herring accompanied by a decrease of activity in pyloric caeca itself. Simultaneous the thermal stability of pyloric caeca is lowered. The reason for the differences in ripening could be seen in some enzyme-inhibiting factors unknown until now.
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    Journal of thermal analysis and calorimetry 57 (1999), S. 409-414 
    ISSN: 1572-8943
    Keywords: DSC ; thermal denaturation ; vegetative bacteria
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Thermal stability of vegetative cells of Listeria monocytogenes, Escherichia coli and Lactobacillus plantarum was studied by counting viable fractions and determining DSC curves of their suspensions. DSC curves in the 5–99°C range showed a series of endothermic transitions between 50 and 60°C, where the heat destruction of cells occurred. Heat denaturation of DNA required a higher temperature than cell killing. Thermal death was strongly influenced by the pH, composition and NaCl content of the suspending buffer. A mathematical model developed by us enabled comparison of DSC peak temperatures and temperatures required for loss of viability.
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    Journal of thermal analysis and calorimetry 57 (1999), S. 517-526 
    ISSN: 1572-8943
    Keywords: DSC ; humic substances ; thermal properties
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Differential Scanning Calorimetry combined with Fourier transform infrared spectroscopy, was applied to the study of a number of fulvic and humic acids extracted from soils, peat, river and seawater. The thermal patterns obtained were related to the nature and origin of samples. The low-temperature endotherms were attributed to dehydration and loss of peripheral polysaccharide chains. The endotherm at 250°C observed for soil FA was ascribed to partial decarboxylation of more labile surface COOH groups, whereas the high-temperature exotherms at about 500°C were related to the degree of polycondensation of the aromatic network of the humic molecules.
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    Journal of thermal analysis and calorimetry 58 (1999), S. 13-18 
    ISSN: 1572-8943
    Keywords: DSC ; enthalpic relaxation ; polyurethane ; TSDC
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Polyurethane acrylate resins cured by two different ways, a thermal way and a photochemical way, are investigated by means of differential scanning calorimetry (DSC) and thermally stimulated depolarization currents (TSDC). Even if both curing methods lead to the same material from a chemical point of view, we show that important differences exist between the thermocured resin and the photocured resin in terms of molecular relaxation behaviour.
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    ISSN: 1572-8943
    Keywords: DMTA ; DSC ; mechanical properties ; metallocene catalysts ; polyethylene
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A series of high density polyethylenes (HDPE) were synthesized via homogeneous polymerization with metallocene catalyst in two different reactors (glass and stainless steel). The thermal and mechanical properties of the polyethylenes, synthesized with two types of reactor and different reaction parameters, are discussed.
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  • 50
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    Journal of applied phycology 11 (1999), S. 69-78 
    ISSN: 1573-5176
    Keywords: seaweed ; algal blooms ; eutrophication ; general mechanisms ; management
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Seaweed responses to eutrophication and their role in coastal eutrophication processes were compared at 8 different sites along the European coasts from the Baltic to the Mediterranean as part of the EU-ENVIRONMENT Project Marine Eutrophication and benthic Macrophytes (EUMAC). Structural and functional changes of marine benthic vegetation typical of eutrophic waters, in particular mass development (blooms) of certain seaweeds, are not merely the result of increased nutrient loading, but must be attributed to complex interactions of primary and secondary effects during the eutrophication process. Due to species-specific physiological properties of the algae (nutrient kinetics, growth potential, light, temperature requirements), the combined effects of abiotic and biotic factors on juvenile or adult developmental stages control the development of algal blooms in different ways. In particular the role of light, temperature, water motion and oxygen depletion, as well as of grazers, on early and adult developmental stages of the algae are considered. The result are discussed in the context of coastal eutrophication control and management.
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  • 51
    ISSN: 1573-5125
    Keywords: denitrification ; eutrophication ; estuary ; nitrogen ; sediment-water exchange
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract In this review of sediment denitrification in estuaries and coastal ecosystems, we examine current denitrification measurement methodologies and the dominant biogeochemical controls on denitrification rates in coastal sediments. Integrated estimates of denitrification in coastal ecosystems are confounded by methodological difficulties, a lack of systematic understanding of the effects of changing environmental conditions, and inadequate attention to spatial and temporal variability to provide both seasonal and annual rates. Recent improvements in measurement techniques involving 15 N techniques and direct N2 concentration changes appear to provide realistic rates of sediment denitrification. Controlling factors in coastal systems include concentrations of water column NO 3 − , overall rates of sediment carbon metabolism, overlying water oxygen concentrations, the depth of oxygen penetration, and the presence/absence of aquatic vegetation and macrofauna. In systems experiencing environmental change, either degradation or improvement, the importance of denitrification can change. With the eutrophication of the Chesapeake Bay, the overall rates of denitrification relative to N loading terms have decreased, with factors such as loss of benthic habitat via anoxia and loss of submerged aquatic vegetation driving such effects.
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  • 52
    ISSN: 1573-5125
    Keywords: eutrophication ; feeding ; growth ; Mytilus edulis ; validation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract EMMY is an ecophysiological model of the growth and reproduction of a single mussel (Mytilus edulis L.). It contains feedback loops in the uptake and metabolism of food and in the partitioning of carbon and nitrogen to the internal state variables somatic tissue, storage, organic shell matrix and gametes. In this paper EMMY is used to simulate individual mussel growth in a series of mesocosm experiments with different inorganic nutrient loads (N and P). The experiments explore the impact of eutrophication reduction scenarios on mussel growth under defined and controlled conditions. In earlier studies EMMY was calibrated using expert knowledge on growth and reproduction during a period of 5 years. The resulting calibrated model was validated for system inputs and observations of three ecosystems with significantly different food and silt concentrations. EMMY reproduced the mussel growth sufficiently accurate in ecosystems with moderate or high food concentrations. In this study EMMY was adapted in order to cope with low food concentrations, then recalibrated (using the original calibration data and procedure) and applied without further calibration to 3 replicated mesocosm experiments. The EMMY simulations in this study show the ecophysiological response of mussels to different food (phytoplankton and detritus) concentrations. It is concluded that the mussels can adapt to significantly reduced food concentrations, due to inorganic nutrient load reduction, and still maintain growth.
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  • 53
    ISSN: 1573-5176
    Keywords: ecological engineering ; biofilter ; aquaculture ; seaweeds ; mariculture ; eutrophication ; Gracilaria ; shrimp farming ; mangroves ; ecological footprint
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Rapid scale growth of intensive mariculture systems can often lead to adverse impacts on the environment. Intensive fish and shrimp farming, being defined as throughput-based systems, have a continuous or pulse release of nutrients that adds to coastal eutrophication. As an alternative treatment solution, seaweeds can be used to clean the dissolved part of this effluent. Two examples of successfully using seaweeds as biofilters in intensive mariculture systems are discussed in this paper. The first example shows that Gracilaria co-cultivated with salmon in a tank system reached production rates as high as 48.9 kg m−2 a−1, and could remove 50% of the dissolved ammonium released by the fish in winter, increasing to 90–95% in spring. In the second example, Gracilaria cultivated on ropes near a 22-t fish cage farm, had up to 40% higher growth rate (specific growth rate of 7% d−1) compared to controls. Extrapolation of the results showed that a 1 ha Gracilaria culture gave an annual harvest of 34 t (d. wt), and assimilated 6.5% of the released dissolved nitrogen. This production and assimilation was more than twice that of a Gracilaria monoculture. By integrating seaweeds with fish farming the nutrient assimilating capacity of an area increases. With increased carrying capacity it will be possible to increase salmon cage densities before risking negative environmental effects like eutrophication and toxic algal blooms sometimes associated with the release of dissolved nutrients. The potential for using mangroves and/or seaweeds as filters for wastes from intensive shrimp pond farming is also discussed. It is concluded that such techniques, based on ecological engineering, seems promising for mitigating environmental impacts from intensive mariculture; however, continued research on this type of solution is required.
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  • 54
    ISSN: 1573-5125
    Keywords: eutrophication ; mesocosm ; phytoplankton ; zooplankton ; macrobenthos
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The effects of nutrient loading on phytoplankton, zooplankton and macrozoobenthos in experimental ecosystems was studied in a 7-month experiment. The mesocosms were designed to mimic the major physical characteristics (irradiance, temperature, mixing) of the Dutch coastal zone in the river Rhine plume. Three different nutrient loading scenarios were used, representing present and future conditions. The level of the spring phytoplankton bloom was determined by phosphorus loading, whereas during summer the nitrogen loading determined phytoplankton biomass. The differences in nutrient loading did not result in shifts in phytoplankton species composition. With exception of the early phase of the spring bloom, diatoms dominated phytoplankton biomass in all nutrient treatments. This was ascribed to microzooplankton grazing on smaller algal species. Microzooplankton biomass showed a positive correlation with primary production, and also significant differences between nutrient treatments. Copepod development was limited, probably due to competition with microzooplankton and predation by benthic fauna. Macrobenthos biomass correlated with primary production, and was lower in the lowest nutrient treatment.
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  • 55
    ISSN: 1573-5125
    Keywords: estuaries ; eutrophication ; resource management
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Anthropogenic nutrient enrichment of the coastal zone is now a well-established fact. However, there is still uncertainty about the mechanisms through which nutrient enrichment can disrupt biological communities and ecosystem processes in the coastal zone. For example, while some estuaries exhibit classic symptoms of acute eutrophication, including enhanced production of algal biomass, other nutrient-rich estuaries maintain low algal biomass and primary production. This implies that large differences exist among coastal ecosystems in the rates and patterns of nutrient assimilation and cycling. Part of this variability comes from differences among ecosystems in the other resource that can limit algal growth and production – the light energy required for photosynthesis. Complete understanding of the eutrophication process requires consideration of the interacting effects of light and nutrients, including the role of light availability as a regulator of the expression of eutrophication. A simple index of the relative strength of light and nutrient limitation of algal growth can be derived from models that describe growth rate as a function of these resources. This index can then be used as one diagnostic to classify the sensitivity of coastal ecosystems to the harmful effects of eutrophication. Here I illustrate the application of this diagnostic with light and nutrient measurements made in three California estuaries and two Dutch estuaries.
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  • 56
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    Hydrobiologia 408-409 (1999), S. 139-144 
    ISSN: 1573-5117
    Keywords: eutrophication ; ecological modelling ; multiple regression
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A research was made on the potential use of neural network based models in eutrophication modelling. As a result, an algorithm was developed to handle the practical aspects of designing, implementing and assessing the results of a neural network based model as a lake management tool. To illustrate the advantages and limitations of the neural network model, a case study was carried out to estimate the chlorophyll-aconcentration in Keban Dam Reservoir as a function of sampled water quality parameters (PO4phosphorus, NO3nitrogen, alkalinity, suspended solids concentration, pH, water temperature, electrical conductivity, dissolved oxygen concentration and Secchi depth) by a neural network based model. Alternatively, the same system was solved with a linear multiple regression model in order to compare the performances of the proposed neural network based model and the traditional linear multiple regression model. For both of the models, the linear correlation coefficients between the logarithms of observed and calculated chlorophyll-aconcentrations were calculated. The correlation coefficient R, the best linear fit between the observed and calculated values, was evaluated to assess the performances of the two models. R values of 0.74 and 0.71 were obtained for the neural network based model and the linear multiple regression model, respectively. The study showed that the neural network based model can be used to estimate chlorophyll-awith a performance similar to that of the traditional linear multiple regression method. However, for cases where the input and the output variables are not linearly correlated, neural network based models are expected to show a better performance.
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  • 57
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    Hydrobiologia 408-409 (1999), S. 375-387 
    ISSN: 1573-5117
    Keywords: eutrophication ; multi-lake studies ; phosphorus ; nitrogen ; chlorophyll-a ; transparency ; zooplankton ; macrophytes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Monitoring data obtained from 231 freshwater lakes and ponds in the Netherlands, covering the period 1980–1996, were used to analyse the relationships between (a) transparency and chlorophyll-a, and the effect of system characteristics on this relationship, (b) chlorophyll-aand nutrient concentrations, and the effect of biological variables and (c) nutrient concentrations and nutrient loading. (a) Chlorophyll-aimposes a maximum on water transparency, but deviations from this maximum can be large. Reducing chlorophyll-a, therefore, does not guarantee a sufficient improvement of transparency. Soil type and the average depth of a lake were shown to influence the relationship between chlorophyll-aand transparency. (b) The maximum ratios of both chlorophyll-a: total-P and chlorophyll-a: total-N were higher in systems dominated by filamentous cyanobacteria than in systems dominated by other algae, indicating the efficiency of the former group with respect to nutrients. In systems with an areal coverage with submersed macrophytes above 5%, concentrations of chlorophyll-aand nutrients were lower than in systems with lower coverages. The ratios between chlorophyll-aand nutrients were lower at coverages larger than 10%. This indicates both bottom-up and top-down control of algae by macrophytes. Grazing pressure by zooplankton was also found to lower the chlorophyll-a: nutrient ratios. (c) System specific linear relationships were found between the average concentrations of total-P and total-N in the incoming water and the summer mean concentration in the lake. This allows the assessment of admissible loads for individual lakes, with narrower confidence limits compared to traditional relationships based on combined data from many lakes. From the analysis, it is concluded that the chain of relationships from nutrient loading to transparency is complex, and depends on biological variables as well as system characteristics.
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  • 58
    ISSN: 1573-5117
    Keywords: epiphytes ; macroalgae ; Cystoseira (host plant) ; seasonality ; eutrophication ; Mediterranean
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Epiphytic macroalgal assemblages growing on Cystoseira species were examined at typical oligotrophic and eutrophic sites of the east coast of Attica (Aegean Sea, Greece) from November 1995 to September 1996. The epiphytic patterns of C. spinosa Sauvageau thriving in the oligotrophic area of Dikastika and of C. compressa (Esper) Gerloff & Nizzamudin growing in the eutrophic environment of Avlida, were compared through a cross-transplantation experiment. Seasonality effects on epiphytic assemblages were observed. The species composition was exclusive for each locality, reflecting differences in the trophic status of the two sites. No specific pattern of epiphytes' distribution was found on the hosts. The prolific epiphytic growth in the oligotrophic site resulted in a reduction of the photosynthetic tissue of both hosts (C. spinosa and the transplanted C. compressa) and the survivorship of host plants was not negatively affected by the physical drag caused by the high epiphyte densities. Cystoseira spinosa survived in oligotrophic conditions despite its heavy epiphytic load. C. compressa was also able to cope with the adverse epiphytic influence in the eutrophic conditions of Avlida; although being perennial, it sheds parts of its stipe and branches before the resting period and sprouts prior to other algae at the beginning of spring.
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  • 59
    ISSN: 1573-5117
    Keywords: phytoplankton ; eutrophication ; water quality modelling ; nutrients ; restoration
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The aim of the study was to assess the effect of nutrient loading and water level regulation of water quality in Lake Võrtsjärv. The lake is highly eutrophic and it has a high value for fisheries and recreation. A water quality model was developed in order to make predictions of the effects of the different possible restoration measures (reduction of nutrient loading, water level regulation) planned to be carried out. Two phytoplankton groups, diatoms and cyanobacteria, were included in the model. Their contribution to the total algal biomass is dominating. The other state variables of the model are concentration of soluble reactive phosphorus (SRP), concentration of inorganic nitrogen and concentration of dissolved oxygen. The ecological model was constructed using continuously stirred tank reactor (CSTR) hydraulics. The zero-dimensional approach could be used because the lake is shallow and has no thermal stratification. According to the model, external nutrient loading has a very small effect on the biomass of cyanobacteria, whereas the effect is clearer when diatoms are concerned. The contribution of water level to biomass is very significant for both diatoms and cyanobacteria.
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  • 60
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    Hydrobiologia 394 (1999), S. 219-232 
    ISSN: 1573-5117
    Keywords: restoration ; alternative stable states ; eutrophication ; macrophytes ; shallow lakes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Lake Apopka (Florida, USA) changed in 1947 from being a clear, macrophyte-dominated lake, used primarily for fishing, into a turbid algal lake with a poor fishery. The lake has resisted various efforts to reverse the change and restore the previous state. The restoration approach emphasizes the reduction in phosphorus inputs to reduce algal blooms and clear the water. We examined the question of whether a deep-lake approach with nutrient reductions is going to work on this large (area 124 km2) and shallow (mean depth 1.7 m) lake, or if techniques such as drawdowns or wind barriers developed for shallow lakes using the theory of alternative stable states are more applicable. The assumptions upon which the current restoration is based are not supported. The poor transparency is due more to resuspended sediments than plankton algae, so the current Secchi disk depth of 0.23 m is predicted to increase to 0.34 m with any reasonable reduction in algal levels. The failure of the macrophytes to become re-established probably is due more to unstable sediments than lack of light reaching the lake bed, and the marsh flow-way developed by the St Johns River Water Management District will be ineffective in removing particles from the lake. It would take more than 300 years to remove the fluid mud and more than 800 years to remove the rest of the low density sediments. We conclude that the loss of macrophytes in Lake Apopka is an example of a forward switch in the theory of alternative stable states, and that it will take more than a nutrient reduction program to bring about the reverse switch to a macrophyte state. We suggest an alternative approach using wave barriers to create refuges for plants, macroinvertebrates, and fish to restore Lake Apopka's largemouth bass fishery.
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    Hydrobiologia 404 (1999), S. 19-26 
    ISSN: 1573-5117
    Keywords: sediment ; phosphorus ; eutrophication ; biomanipulation ; fish ; Sweden
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Lake Ringsjön did not respond with decreased algal production following a substantial reduction in external phosphorus loading. This is typical of many shallow lakes which for decades have received excessive amounts of nutrients. The inertia is due to large amounts of phosphorus (P) stored in sediments and biota, causing internal phosphorus loading. Much of this phosphorus is thought to be released from the organic-rich profundal sediments. In Lake Ringsjön, only one third of the total bottom area is covered by such sediments, the rest being dominated by sand and silt. In the profundal sediments bulk P content was not exceptionally high (approximately 2 mg P·g DW−1), while the pore water phosphate concentrations, especially in Sätofta Basin, were very high, indicating large potential for phosphorus release to the water. This is also indicated by the large proportion of Fe- and Al-bound P in the sediments of Sätofta Basin. Although there are no direct quantifications of phosphorus release from the sediments in Lake Ringsjön, measurements of phosphorus concentrations in the water mass as well as budget calculations for the three basins clearly show a high capacity for internal loading. Phosphorus concentrations generally increase during summer, when external additions are minimal. Until 1980, the annual external phosphorus addition to Lake Ringsjön greatly exceeded the output, showing that the lake was an efficient phosphorus trap. Since then, input and output have been balanced, but in recent years signs that the lake is once again retaining phosphorus on an annual basis are evident. There are marked differences between the three basins, with Western Basin generally retaining phosphorus, while the upstream Eastern Basin and Sätofta Basin during the 1980s often exported phosphorus. It is not possible to evaluate the effects of the fish biomanipulation on the internal loading of phosphorus from the sediment.
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    Hydrobiologia 404 (1999), S. 19-26 
    ISSN: 1573-5117
    Keywords: sediment ; phosphorus ; eutrophication ; biomanipulation ; fish ; Sweden
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Lake Ringsjön did not respond with decreased algal production following a substantial reduction in external phosphorus loading. This is typical of many shallow lakes which for decades have received excessive amounts of nutrients. The inertia is due to large amounts of phosphorus (P) stored in sediments and biota, causing internal phosphorus loading. Much of this phosphorus is thought to be released from the organic-rich profundal sediments. In Lake Ringsjön, only one third of the total bottom area is covered by such sediments, the rest being dominated by sand and silt. In the profundal sediments bulk P content was not exceptionally high (approximately 2 mg P·g DW−1), while the pore water phosphate concentrations, especially in Sätofta Basin, were very high, indicating large potential for phosphorus release to the water. This is also indicated by the large proportion of Fe- and Al-bound P in the sediments of Sätofta Basin. Although there are no direct quantifications of phosphorus release from the sediments in Lake Ringsjön, measurements of phosphorus concentrations in the water mass as well as budget calculations for the three basins clearly show a high capacity for internal loading. Phosphorus concentrations generally increase during summer, when external additions are minimal. Until 1980, the annual external phosphorus addition to Lake Ringsjön greatly exceeded the output, showing that the lake was an efficient phosphorus trap. Since then, input and output have been balanced, but in recent years signs that the lake is once again retaining phosphorus on an annual basis are evident. There are marked differences between the three basins, with Western Basin generally retaining phosphorus, while the upstream Eastern Basin and Sätofta Basin during the 1980s often exported phosphorus. It is not possible to evaluate the effects of the fish biomanipulation on the internal loading of phosphorus from the sediment.
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  • 63
    ISSN: 1573-5117
    Keywords: eutrophication ; acidification ; macrophyte communities ; weakly mineralized streams ; France
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The Northern Vosges streams are subjected to acidification upstream and to eutrophication downstream. A bio-indicator scale of the degree of eutrophication and of the level of acidification, based on four aquatic macrophyte communities, was established in these weakly mineralized streams. Aquatic plant communities therefore begin as Group A, develop into Group B and become Group C or D downstream. The A community was characterized by bryophytes (Scapania undulata, Sphagnum sp.) and Potamogeton polygonifolius in oligotrophic, acidified to weakly acidified, and poorly buffered streams. The B community, defined by P. polygonifolius and the appearance of Ranunculus peltatus and Callitriche species (C. platycarpa, C. hamulata) was found in oligotrophic waters with a higher buffer capacity than the A community. The C community was determined by the disappearance of P. polygonifolius and the appearance of Elodea species (E. canadensis, E. nuttallii) and rare species in mesotrophic and neutral streams. The D community, with very high nutrient loading, was characterized by the abundance of Callitriche obtusangula, by the presence of Amblystegium riparium, Fissidens crassipes and the development of filamentous algae. This macrophyte sequence corresponded to an upstream to downstream zonation, which was characterized by an increase in buffer capacity and in nutrient levels and a decrease in protons and aluminium load.
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  • 64
    ISSN: 1573-5117
    Keywords: Neva Bay ; Gulf of Finland ; eutrophication ; phytoplankton ; zooplankton ; zoobenthos
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A comparative study of the long-term data (1982–1996) on the ecosystems' state in Neva Bay and the eastern Gulf of Finland showed spatial differences and temporal changes in the structure and functioning of the aquatic communities. Recent data revealed progressing eutrophication in the southern part of Neva Bay, viz. a pronounced increase of primary production and the prevalence of the production process over the decomposition of organic matter which had never been observed in Neva Bay before. At present, biomass of benthos has dramatically decreased in the eastern part but increased in the south-western areas of the bay. Structure and spatial distribution of zooplankton communities have changed both in Neva Bay and the eastern Gulf of Finland. In the latter part of the estuary, blue-green algae became a dominating group of phytoplankton indicating serious alterations in the ecosystem caused by anthropogenic stress.
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    Hydrobiologia 393 (1999), S. 117-125 
    ISSN: 1573-5117
    Keywords: microbial communities ; biomass ; biomarkers ; eutrophication ; season ; sediments
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Seasonal changes in sedimentary microbial communities were investigated using biomarker analysis from samples collected in spring and autumn 1995 from Hiroshima Bay and Suo Nada of the Seto Inland Sea of Japan. Surface sediment samples were analysed for several sediment parameters and phospholipid ester-linked fatty acids (PLFA). Total PLFA concentration, which is indicative of microbial biomass, was high in autumn and low in spring in Hiroshima Bay but no such significant seasonal difference of PLFA concentration was observed in Suo Nada. PLFA composition of the sediments were dominated by saturated PLFA, branched PLFA and monounsaturated PLFA. Regional variation in the PLFA composition was less pronounced than the seasonal variation. The presence of the characteristic polyunsaturated fatty acids (PUFA) revealed that microeukaryotes were always present in small proportions. The aerobic prokaryotes and eukaryotes group were predominant in spring, whereas in autumn, the Gram-positive bacteria group was predominant. Monounsaturated PLFA/branched PLFA ratio was high in spring and low in autumn, indicating the relative dominance of these biomarker fatty acids. Significant seasonal differences of sediment parameters, PLFA groups and microbial groups were observed in Hiroshima Bay. In Suo Nada, these parameters showed similar patterns to Hiroshima Bay but the differences of most of the parameters were insignificant. Furthermore, principal components analysis (PCA) revealed a significant shift in microbial community structure between the two seasons, indicating a clear response of microbial communities to changes in sediment parameters.
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  • 66
    ISSN: 1573-5117
    Keywords: littoral fish ; Archipelago Sea ; Baltic Sea ; eutrophication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A collapse of the littoral fish populations was found in the middle archipelago zone near the Island of Seili (northern Baltic Sea) when fish populations were studied in summer 1996 in a comparable way with earlier studies done in the early 1970s and 1980s. A similar comparison was made in the outer archipelago (the islands off the island of Utö), but no evident change was found. Reasons for the decline in littoral fish stocks are discussed, but no single-cause effect can be pointed out. Among possible explanations is a substantial increase of eutrophication in the middle archipelago together with increasing ferry traffic which both cause structural changes in the littoral environment of the study area.
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  • 67
    ISSN: 1573-5117
    Keywords: plain streams ; nutrients ; eutrophication ; organic pollution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The Argentine pampean streams exist in a traditionally agricultural region, but they also receive a supply of contaminants in the more urban zones. The objectives of this study are: 1. To analyze the physical, chemical and microbiological characteristics of the streams in the Luján river basin; and 2. To describe the annual variation of some chemical characteristics (primarily nutrients) in one of the streams. Two samplings (winter and summer) were made in 20 streams to determine some physical, chemical and microbiological variables. Topographical variables were also estimated in each stream. Additionally, in one of the streams (Las Flores), monthly measurements of current velocity, flow, and dissolved nitrogen, phosphorus and oxygen were taken during 4 years. The streams are characterized by high nutrient contents. There is no strong heterogeneity in stream chemical characteristics within the same period, however seasonal variations are important . The principal components analysis suggests the existence of two axes of variation within the basin. One reflects a pollution gradient that increases downstream; the other axis shows that waters change from high to low alkalinity and from less to more eutrophic. In Las Flores stream, nutrient concentration varied greatly between years. The concentration of soluble reactive phosphorus was significantly correlated with stream flow (P 〈 0.05). Though there was no correlation between nitrate levels and flow, some estimates indicated that these ions are in high concentrations in the groundwater. The physiognomical characteristics of pampean streams differ greatly from those described in temperate streams of the northern hemisphere, and it may be assumed that they also exhibit distinct functional characteristics.
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  • 68
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    Hydrobiologia 395-396 (1999), S. 365-378 
    ISSN: 1573-5117
    Keywords: urban lakes ; eutrophication ; wildfowl ; management ; education
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Urban lakes are very different from other lakes: they are shallow, highly artificial and often hypertrophic yet more people come into contact with them than rural, natural lakes. Our knowledge of their ecology and management is poor. This paper describes a project under the EU Life programme to understand and ecologically manage the most important urban lakes in the London Borough of Wandsworth. One main lake has been evaluated: Battersea Park Lake. The magnitude of anthropogenic impacts are quantified and remedies explored. Computer-based decision trees for urban lake management have been developed and are illustrated.
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    Hydrobiologia 395-396 (1999), S. 403-409 
    ISSN: 1573-5117
    Keywords: eutrophication ; shallow lakes ; Netherlands
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Due to the limited perspectives of the Dutch national policy and due to the unique conditions and constraints of individual lake systems, tailor-made programs are needed for the restoration of freshwater lakes. Based on an evaluation of several restoration projects, a guideline is provided to enable water managers to develop such a restoration program. This guide-line is summarized in the paper and important topics, such as the definition of targets and standards, system identification and measures, are highlighted. Targets should include a natural reference, but also the constraints imposed by other functions of the lake. Monitoring and system identification are necessary to determine the extent of remedial measures and whether they should focus on external nutrient sources, internal sources or other factors, such as the food web structure. It is advocated that for lakes which have not degraded to a green, algal-dominated, turbid state, prevention or re-establishment of its ability to self-restore are preferred to ‘intensive surgery’ on the system. Lake re-creation can be applied if the system is heavily perturbed. In that case the re-creation of a more beneficial system is a more fair-minded approach than restoration of the natural state.
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    Hydrobiologia 395-396 (1999), S. 389-401 
    ISSN: 1573-5117
    Keywords: legislation ; eutrophication ; phosphorus ; nitrogen ; wildlife conservation ; SSSI
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract There is no single piece of legislation which comprehensively addresses the problem of eutrophication of freshwater lakes. An examination is made of the extent to which national and EU laws applicable in England and Wales may be used to reduce phosphorus inputs to eutrophicated lakes. This case study is then used to outline the shortcomings of existing legislation and the future challenges for lake eutrophication control. Applicable legislation may be divided into that relating to nature conservation, to water quality and to agricultural extensification. Nature conservation laws are applicable, in that lakes designated as Sites of Special Scientific Interest (SSSIs), are theoretically safeguarded from degradation. The main limitation of the SSSI system lies in the boundary definition process under which, as a rule, no other category of legally protected land may be designated. Thus, the use of surrounding buffer land to protect water quality at the catchment level is generally precluded. The introduction of consultation areas around SSSIs of international importance under the EU Directive on Habitats is unlikely to alleviate the problem, since the area involved remains minimal compared to the extent of the majority of catchments. Intensive agricultural practices are responsible for significant nutrient enrichment of rivers and lakes, so that legislation aimed at extensification is also relevant. Examples of agricultural extensification include the Environrnentally Sensitive Areas programme and various options available for Set-Aside land. However, the prime purpose of such initiatives is the alleviation of surplus and budgetary problems and, as such, they fall short of a fully integrated approach to the ecological management of farmland. Nutrient enrichment is, essentially, a water quality issue, but policy and legislation in this area are not yet sufficiently developed to address the problem comprehensively. The current regulatory process for water quality carries the potential to work comparatively well for point sources under the system of consents to discharge. This potential is limited, however, by the paucity of information available on ecologically acceptable concentrations of phosphorus in discharges. In addition, the consents system is not constructed to deal effectively with diffuse agricultural losses of phosphorus, since, unlike point sources, these tend to arise from the cumulative effect of many activities. The main legislative challenge for lake eutrophication control lies in the area of diffuse agricultural losses of phosphorus. In this respect, experience in the U.S.A. reveals that the use of comprehensive and catchment-wide ‘Best Management Practices’ is capable of producing significant water quality improvements, providing that some degree of mandatory compliance is incorporated.
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  • 71
    ISSN: 1573-5117
    Keywords: Scotland ; lochs ; eutrophication ; acidification ; toxic substances ; classification
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The development of a national scheme for the standing waters of Scotland is described. It classifies waters along three gradients – phosphorus, loss of acid neutralising capacity and degree of contamination with toxic suubstances. A series of case studies provide examples of the application of the classification in lake management.
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  • 72
    ISSN: 1573-5117
    Keywords: Integrated lake management ; biomanipulation ; lake recovery ; phosphorus ; nitrogen ; eutrophication ; restoration
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The majority of Danish lakes are highly eutrophic due to high nutrient input from domestic sources and agricultural activities. Reduced nutrient retention, and more rapid removal, in catchments as a result of agricultural drainage of wetlands and lakes and channelisation or culverting of streams also play a role. Attempts have recently been made to reduce nutrient loading on lakes by intervening at the source level and by improving the retention capacity of catchment areas. The former measures include phosphorus stripping and nitrogen removal at sewage works, increased use of phosphate-free detergents, and regulations concerning animal fertiliser storage capacity, fertiliser application practices, fertilisation plans and green cover in winter. In order to improve nutrient retention capacity of catchments, wetlands and lakes have been re-established and channelised streams have been remeandered. In addition, cultivation-free buffer strips have been established alongside natural streams and there has been a switch to manual weed control. These measures have resulted in a 73% reduction of the mean total phosphorus concentration of point-source polluted streams since 1978; in contrast, there has been no significant change in the total nitrogen concentration. Despite the major reduction in stream phosphorus concentrations, lake water quality has often not improved. This may reflect a too high external or internal phosphorus loading or biological resistance. Various physico-chemical restoration measures have been used, including dredging and oxidation of the hypolimnion with nitrate and oxygen. Biological restoration measures have been employed in 17 Danish lakes. The methods include reducing the abundance of cyprinids, stocking with 0+ pike ( Esox lucius) to control 0+ cyprinids, and promoting macrophyte recolonization by protecting germinal submerged macrophyte beds against grazing waterfowl and transplanting out macrophyte shoots. In several lakes, marked and long-lasting improvements have been obtained. The findings to date indicate that fish manipulation has a long-term effect in shallow lakes, providing nutrient loading is reduced to a level so low as to ensure an equilibrium lake water phosphorus concentration of less than 0.05–0.1 mg phosphorus l−1. If nitrogen loading is very low, however, positive results may be obtained at higher phosphorus concentrations. Macrophyte refuges and transplantation seem to be the most successful as restoration measures in the same nutrient-phosphorus regime as fish manipulation.
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  • 73
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    Hydrobiologia 395-396 (1999), S. 13-18 
    ISSN: 1573-5117
    Keywords: interdisciplinary science ; environmental politics ; eutrophication ; broads ; environmental valuation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Restoring lakes from a degraded state is a costly and risky enterprise. It is costly partly because ‘rewinding’ the cycles of degradation involves great scientific uncertainties. Therefore, the only way forward is by careful, expensive monitoring, and much adaptation of treatment as the evidence unfolds. This process requires much patience and political commitment. Therefore, the economic challenge is to find a relationship between the ecological exploration of restoration techniques and the economic justification of the outcome. Unfortunately, the basis of that justification is an economy that creates environmental degradation. So there is a cruel circularity in the economic appraisal: the process of benefit calculation is predicted on an economy that is, at present, non sustainable. This suggests that there should be another approach to economic valuation, based more on participatory processes of involving interests with a stake in the outcome and in the gains and losses that will inevitably be incurred in reaching the outcome of lake restoration. In that process, ecological science plays a vital role of explaining possible future pathways for restoration, and the dilemma of uncertainty is handled by creating various scenarios rather than models. The real challenge, therefore, is to devise a fair and full process of bargaining over lake futures, within which both ecology and economics play important, but subsidiary roles.
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  • 74
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    Hydrobiologia 395-396 (1999), S. 19-28 
    ISSN: 1573-5117
    Keywords: eutrophication ; lake ; management ; restoration ; Wisconsin
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Lake degradation results from excessive nutrient inputs, toxic substances, habitat loss, overfishing, species invasions and extirpations. The scientific basis of lake degradation is generally well understood, although each restoration project requires some level of new site-specific research. Remediation may require management actions which are difficult to implement for social or institutional reasons. Even where large-scale remediations are attempted, it is difficult to sustain scientific assessments for long enough to evaluate success. Collaborations of scientists and managers have sometimes succeeded in overcoming limitations to lake restoration, and produced important advances in our capability to restore lakes.
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  • 75
    ISSN: 1573-5117
    Keywords: Phragmites ; eutrophication ; wetlands ; nutrient
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract In the frame of the research program EUREED (Effects of interaction between eutrophication and major environmental factors on the ecosystem stability of reed (Phragmites australis) vegetation in European land-water ecotones), three reed stands, established near Alcácer do Sal, Lagoa de Albufeira and Montargil, were studied. The stands were monitored monthly between December 1993 and December 1994 for productivity, soil and water chemistry. The relationship between the concentration of some metals in soil and water and its influence on the stability of the reed vegetation was studied. Environmental factors, such as salinity, negative redox potential on the root system and high Cu, Na and Zn concentrations in soil did not affect the normal development of reed vegetation and its capability to recover after mechanical damage.
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  • 76
    ISSN: 1572-8943
    Keywords: adducts ; cobalt complex ; DSC ; kinetics ; nickel complex ; O,O'-dialkyldithiophosphate ; pyridine ; TG-DTG
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Thermal behaviour of tri(O,O'-diisopropyldithiophosphate)cobalt(III), Co(dptp)3 and bis (O,O'-diethyldithiophosphate)nickel(II), Ni(detp)2 and its adducts with pyridine, Ni(detp)2(py)2 or 4-methylpyridine, Ni(detp)(mpy)2 in a dynamic nitrogen atmosphere was investigated by TG-DTG and DSC techniques, which showed a medium endothermic peak for the evolution process of pyridine(or 4-methylpyridine) and a strong exothermic peak for that of O,O'-diethyldithiophosphate. The thermal stability and decomposition patterns for these compounds were compared and interpreted in terms of structural features such as bond character and steric effects. The kinetic parameters and mechanisms of every decomposition stage involved for all these complexes were obtained employing the non-isothermal kinetic analysis method suggested by Malek et al., which showed the kinetics mechanism for pyrolysis of pyridine(or 4-methylpyridine) is an S-B empirical model with lower activation energy, while that of O,O'-dialkyldithiophosphate is a diffusion model. These results are in accord with the fact that two ligands are of different type.
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  • 77
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    Journal of thermal analysis and calorimetry 55 (1999), S. 85-92 
    ISSN: 1572-8943
    Keywords: DSC ; exothermic peak ; human serum albumin ; non-equilibrium state ; pyridine-n-hexane mixtures
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Human serum albumin (HSA) immersed in pyridine-n-hexane mixtures was analyzed using differential scanning calorimetry (DSC). State of the solid HSA in organic solvent mixtures is the non-equilibrium state which is seen as the exothermic peak on the DSC curves. The enthalpy change corresponding to this exothermic peak approaches zero when going from pure pyridine to pure n-hexane. Dependence of the enthalpy change on the pyridine concentration is suggestive that the non-equilibrium state of the immersed HSA results from the HSA-pyridine interactions 'frozen' at the lower temperature. Most likely the temperature-initiated exothermic peak observed on the DSC curves reflects the swelling of HSA by pyridine.
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  • 78
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    Journal of thermal analysis and calorimetry 56 (1999), S. 437-446 
    ISSN: 1572-8943
    Keywords: Al-La-Ni amorphous ribbons ; DSC ; heating rate ; non-isothermal crystallization kinetics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Crystallization kinetics of Al91La5Ni4 amorphous ribbons produced by a melt-spinning method were studied by DSC analysis and X-ray diffraction. The effect of heating rate (from 4 to 200°C min-1) was investigated in the temperature range from 298 to 700 K. Increases the heating rate from 4 to 200°C min-1 resulted in increases of the temperature difference between the two stages of the transformation process: crystallization of Al and crystallization of the Al compounds from 148.9 to 167.4 K. The apparent activation energies for the first step, related to Al crystallization, and to the second step related to crystallization of Al4La and Al3Ni, were found to be 161±9 and 199±10 kJ mol-1, respectively. The results indicate the possibility of tailoring the heating treatment to produce the required fraction of the amorphous phase.
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  • 79
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    Journal of thermal analysis and calorimetry 56 (1999), S. 1211-1216 
    ISSN: 1572-8943
    Keywords: dispersion-type processed cheese ; DSC ; ELMI
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    Topics: Chemistry and Pharmacology
    Notes: Abstract In contrast with the traditional method of cheese processing, where Ca breaks down from the protein chain and protein is peptized, a new technology has been elaborated, during which cheese is dispersed without phosphate-containing processing salt, when the gel is formed by plant hydrocolloids. Raw material of constant composition was processed with a phosphate-containing salt or in the presence of hydrocolloids. Thermodynamic processes occurring during the processing and in the end-products were examined by an ultra-sensitive micro DSC method. The structures of end-products were also investigated by electronmicroscopy. The temperature ranges of the endothermal processes indicating the transformations of protein and hydrocolloids can be distinguished: 81-90°C for peptization processing and 61-72°C for processing without peptization. The differences are less in the end-products: 75-87°C in traditional processed cheese and 68-74°C in processed cheeses made without peptization. In contrast with the spongy structure of traditional processed cheeses consisting of peptized proteins, processed cheeses made without peptization involve structure-forming elements created by the interaction of linear macromolecules of hydrocolloids and cheese proteins.
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  • 80
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    Journal of thermal analysis and calorimetry 56 (1999), S. 1317-1322 
    ISSN: 1572-8943
    Keywords: cyclodextrins ; drugs ; DSC ; excipients ; prochlorperazine
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Differential scanning calorimetry was used to examine the thermal behaviour of mixtures of the drug prochlorperazine with standard excipients, to assess potential interactions, and of mixtures with cyclodextrins, to investigate inclusion complexation which could increase the photostability of the drug. For most of the excipients (magnesium stearate, stearic acid, Explotab®, Ac-Di-Sol®, Encompress® and Ludipress®, lactose and Starch 1500) disappearance or broadening of the melting endotherm of the drug indicated interactions. Lubritab® was the only 'inert' excipient tested. Mixtures of prochlorperazine and the cyclodextrins gave incomplete inclusion complexation as shown by only partial disappearance of the melting endotherm of the drug.
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  • 81
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    Journal of thermal analysis and calorimetry 57 (1999), S. 599-605 
    ISSN: 1572-8943
    Keywords: DSC ; lead bromide ; melting ; systematic error
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The melting of PbBr2 in sealed crucibles was investigated by means of DSC. Three factors were considered to affect melting point: i) impurities, ii) the bromine pressure over the PbBr2, and iii) photolysis. Both crystals and powders were investigated. The peak of the melting changed after sample grinding. The bromine pressure over the PbBr2 was found to cause a significant error in the determination of the melting point. Lead bromide melts at 370.6±0.2°C. The heat of melting is 42.9±1.8 J g−1.
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  • 82
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    Journal of thermal analysis and calorimetry 58 (1999), S. 243-248 
    ISSN: 1572-8943
    Keywords: actin ; cisplatin ; DSC ; thiol ; transplatin
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The effects of cisplatin and its trans isomer transplatin on the thermal denaturation of G-actin were studied with a Micro DSC-III differential scanning calorimeter. The denaturation enthalpy of G-actin was found to be 12 J g−1, and the denaturation temperature was 328 K. The thermal denaturation curve showed that increasing cisplatin concentration decreased the enthalpy change. However, after the ratio of cisplatin to G-actin attained 8:1 (mol:mol), the denaturation enthalpy no longer decreased. Transplatin decreased the enthalpy change more rapidly. In contrast with cisplatin, the denaturation peak at 328 K disappeared, and a strong exothermic peak appeared at 341 K when the ratio of transplatin to G-actin was 8:1 (mol:mol). The enthalpy change was 75 J g−1, which is far in excess of the range of weak interactions. This strong exothermic phenomenon probably reflects the agglutination of protein. The effects of cisplatin and transplatin on the number of the free thiol groups of G-actin are discussed.
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  • 83
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    Journal of thermal analysis and calorimetry 58 (1999), S. 569-577 
    ISSN: 1572-8943
    Keywords: counterion effect ; DSC ; membrane ; Nafion-H ; Nafion salts ; TG
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The thermal behavior of Nafion-117 membranes was investigated by thermogravimetric analysis (TG) and differential scanning calorimetry (DSC). TG measurements revealed that the mechanism of thermal degradation of a Nafion membrane in the acid form is different from that of Nafion in the sodium form. The DSC curves for the first heating, for both acid and salt forms, display two endothermic peaks, near 120 and 230°C. The high-temperature peak was assigned to the crystalline domains melting in Nafion, and the low-temperature peak was attributed to a transition into ionic clusters, since this transition exhibits significant changes depending on the nature of the counterion and the degree of hydration.
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  • 84
    ISSN: 1573-5117
    Keywords: Seasonal riparian wetlands ; macrophytes ; ecological effects ; eutrophication ; Ecological-Economic Water Level; Lake Chao
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Experiments with replanting macrophytes in Lake Chao showed that the water quality inside an Alternathera philoxeroides Griseb.and a Phragmites australis community were better than outside. Transparency was significantly higher and the content of N and P decreased inside the communities, as did the rate of sedimentation of organic suspended matter in the Phragmites australis community. Modeling revealed that macrophyte restoration could decrease phytoplaniton biomass, increase fish biomass, exergy, structural exergy, zooplankton/phytoplankton ratio and transparency (Xu et al., 1999b). It is concluded that macrophyte restoration can purify lake water, regulate lake biological structure and control eutrophication.
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  • 85
    ISSN: 1573-5117
    Keywords: eutrophication ; Microcystis ; reservoir restoration ; phosphorus precipitation ; carbon dioxide
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract In Bautzen reservoir, a shallow, hypertrophic water in Eastern Saxony, biomanipulation led to structural changes in the phytoplankton community but did not reduce algal biomass. To supplement the top-down management, a new type of water treatment technology was tested during two seasons (May–August 1996/1997), aiming at the bottom-up control of mass developments of the cyanobacterium Microcystis aeruginosa.The technology is based on a combined lake–internal phosphorus precipitation and a transport of hypolimnetic water rich in free carbon dioxide into the upper layers. During the treatment periods, there were found both an increase of CO2concentrations in the mixed layer and an extension of the period in which free CO2was detected in the epilimnion. The concentrations of phosphorus could be lowered drastically in the whole water body. Microcystiswas almost totally suppressed (1996) or appeared with a delay (1997) compared to the regular annual pattern observed before the treatment. In contrast to the preceding year (1995), diatoms played a major role in the summer phytoplankton during the treatment years (1996/1997). The two application periods are compared with respect to the influence of meteorologically determined variables.
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  • 86
    ISSN: 1573-5117
    Keywords: phosphate ; modelling ; eutrophication ; aquatic plants ; rivers ; irrigation channels
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    Topics: Biology
    Notes: Abstract A series of models was developed using functionally-derived variables (mainly based on morphological attributes of freshwater macrophytes) to predict the trophic status of river and associated channel systems. The models were compared with an existing species-assemblage based procedure for predicting British river trophic conditions (the Macrophyte Trophic Ranking scheme, MTR). We compared sites in cooler temperate conditions (in Scotland) and warmer, sub-tropical conditions (in Egypt). In total, we made measurements of 13 traits from 〉600 individual plant specimens of 33 species growing at 42 sites (divided into independent input and test site datasets). N status (as annual mean concentration in water of total oxidised nitrogen, TON) was only very poorly predicted by this approach. However, P (as annual mean concentration in water of soluble reactive phosphate, SRP) was better predicted: both by a model based on MTR (r = −0.585, p〈0.001), and by models using functional attributes of the macrophyte vegetation. River Trophic Status Indicator (RTSI) models based on ranked plant functional group relationship to river water P concentrations (RTSIFG), or field-measured trait sets of the plants (RTSITR) could also individually explain up to about 34% of the variation in P, both for the total dataset and for subsets from Egypt or Scotland alone or for high v. low-flow sites. Combining both types of RTSI measure produced the most powerful predictive model (r = 0.72, p〈0.001), explaining just over half the variability in P.
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  • 87
    ISSN: 1573-5117
    Keywords: submerged macrophytes ; lakes ; classification ; eutrophication ; remote sensing ; transparency
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The aquatic vegetation present in lakes in the delta of the River Danube was studied using field survey data and satellite image. Based on the spectral information from satellite images, three categories of lakes were distinguished: clear / macrophyte-dominated, intermediate and turbid / poorly vegetated. The satellite-based classification was consistent with vegetation cover and water transparency measured in the field. Cluster analysis of vegetation data from 235 relevés made in 22 lakes (1996-1998, each year in June) identified ten submerged vegetation types. The lakes were characterised by the frequency of occurrence of each vegetation type and ordinated, using Principal Components Analysis (PCA). A strong relationship appeared between the composition and density of aquatic vegetation and water transparency. Isolated lakes within the extensive beds of floating reed (plaur lakes) formed a separate group. Based on the ordination analysis, connectivity of lakes in the Danube Delta was concluded to be a major factor for the development of dense macrophyte vegetation.
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  • 88
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    Hydrobiologia 393 (1999), S. 35-43 
    ISSN: 1573-5117
    Keywords: eutrophication ; modelling ; biogeochemical cycles ; nitrogen ; phosphorus ; load reduction ; Baltic Sea ; Gulf of Finland
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The entire Baltic Sea, as well as many of its different sub-regions, are subject to eutrophication due to high nutrient inputs. To plan expensive water management measures one needs a tool to quantify effects of different water management policy decisions. The tools implemented here are simulation models based on similar descriptions of biochemical interactions in the water and sediments but coupled to different hydrodynamical models. For the Baltic Proper a 1D physical model with high vertical resolution but horizontally integrated was used. Simulations for 20 years made with 50% load reduction each 5 year show that for this domain and at these scales the recovery would take decades. The most effective is reduction of phosphorus, while reduction of only nitrogen leads to a dramatic increase in cyanobacteria blooms. For the Gulf of Finland a high-resolution 3D hydrodynamic model was coupled to a more crude 3D-box biogeochemical model describing concrete conditions during August and November 1991. In the Eastern Gulf of Finland the effects of a 50% load reduction from the St. Petersburg region are pronounced even after two weeks. Here, nitrogen reduction would be more beneficial than that of phosphorus, both locally and at a larger scale. The conclusion from these simulations is that the difference in effects of nitrogen versus phosphorus reduction is dependent on scales and locations of management.
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  • 89
    ISSN: 1573-5117
    Keywords: eutrophication ; phosphorus control ; Norfolk Broads
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The Norfolk Broads are a series of shallow, man-made lakes dug in medieval times for peat extraction, in Eastern England. Their eutrophic state has been well-documented and, since the early 1980s, their restoration has been attempted using a variety of techniques. The restoration began with the removal of point sources of phosphorus from sewage treatment works, which then revealed the role of sediment release when lake phosphorus levels failed to decline following inflow phosphorus levels. Small-scale removal of sediment layers in isolated broads demonstrated the feasibility, both technical and economic, of this technique, but experience then showed that sediment removal alone could not provide long-term restoration. Biomanipulation following sediment removal now offers the most reliable route to restoration, but the mechanisms by which a stable submerged plant community can be maintained after biomanipulation are still not clear.
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  • 90
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    Hydrobiologia 395-396 (1999), S. 107-114 
    ISSN: 1573-5117
    Keywords: shallow reservoir ; eutrophication ; restoration ; ecohydrology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The ecohydrological approach is based upon understanding and integration of processes which regulate water and biota dynamics at catchment scale. Such an approach has recently been applied to the restoration programme of a eutrophic reservoir, by integrating classical methods with those of landscape ecology and recent advances in biogeochemistry at catchment scale. Restoration measures include rehabilitating buffer zones, renaturalising river channel morphology, regulating the flow regime of the incoming river as a means of modifying the nutrient supply, creating wetland systems and applying a variety of biomanipulation techniques.
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  • 91
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    Hydrobiologia 395-396 (1999), S. 117-121 
    ISSN: 1573-5117
    Keywords: rainfall ; water supply reservoirs ; eutrophication ; water treatment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Eastern England, the driest part of England, has the fastest population growth and water demand in the UK. Existing supplies taken from groundwater have to be supported by surface water, in pumped storage reservoirs supplied from highly eutrophic rivers. These reservoirs are managed primarily by technical means to produce high quality drinking water but there is recognition that intensive recreational use has to be a compatible part of their management. In the future progress towards a more sustainable, ecologically-based management is possible.
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  • 92
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    Hydrobiologia 395-396 (1999), S. 149-159 
    ISSN: 1573-5117
    Keywords: sediment ; diatoms ; phosphorus ; acidification ; eutrophication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Palaeolimnology has developed rapidly over the last two decades to deal with problems of eutrophication, and acidification. This paper reveiew the techniques for coring, dating and interpreting sediments. The applications of palaeolimnology in interpreting the past through ‘transfer functions’ calculated from biological indices are reviewed. Rates of change, the causes of change, and the restoration of lakes to some predefined target are reviewed and the direction of future developments considered.
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  • 93
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    Hydrobiologia 395-396 (1999), S. 227-238 
    ISSN: 1573-5117
    Keywords: catchment modelling ; hydrology ; eutrophication ; field survey ; remotely sensed data ; SWAT ; reliability estimation ; mollifier
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Water resource managers require catchment-scale nutrient transport models to help in the investigation and control of diffuse pollution. Many different models exist for water and pollutant movement, causing problems of selection because each model has often been constructed for specific purposes, and the choice of an appropriate one is difficult: wrongly applied models can lead to unreliable results and misleading information. The selection of a model for estimating phosphorus loss from a lowland English catchment is described. 14 models, whose underlying principles had been published, were evaluated. ‘SWAT’ was found to be the most suitable. It has several favourable qualities, but also several shortfalls which may impair its predictive ability. Their identification enables the model code to be re-written. Reliability estimation is needed to ensure that the ranges of model prediction are known.
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    Hydrobiologia 395-396 (1999), S. 265-280 
    ISSN: 1573-5117
    Keywords: Elterwater ; Lake District ; eutrophication ; continuous monitoring ; nutrients ; phytoplankton
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Continuous monitoring of physico-chemical parameters enable the determination of water quality in lakes of the English Lake District, where nutrient enrichment needs to be managed. In the case of Elterwater, severe deterioration of water quality has resulted in the prolonged deoxygenation of the whole water column of the inner basin. More specifically, the phytoplankton differed between the three basins, with progressive increases in biomass and species indicative of eutrophy, between the oligotrophic outer to the hypertrophic inner basins. Remedial action is proposed for this lake, with continual monitoring of recovery.
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    Hydrobiologia 395-396 (1999), S. 293-308 
    ISSN: 1573-5117
    Keywords: phosphorus ; sediments ; eutrophication ; Scotland
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract This paper considers the range of management techniques which are currently available for the remediation of eutrophic lakes, with respect to two lochs within southwest Scotland. Preliminary studies of sources of nutrients identified the need for the development of different management prescriptions for each. Such studies will ensure that the management is tailored to meet the specific needs of the site. The two lochs, Carlingwark Loch at Castle Douglas and Castle Loch at Lochmaben, both support algal blooms but have different nutrient sources. Carlingwark Loch appears to be receiving large quantities of nutrients from the surrounding catchment, whereas Castle Loch shows a net loss of nutrients over its surface inflows, indicating release from the sediments and/or input from overwintering wildfowl. In these cases, if preliminary studies had not been undertaken, the management programmes developed may not have used the most effective control measures.
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  • 96
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    Hydrobiologia 395-396 (1999), S. 309-323 
    ISSN: 1573-5117
    Keywords: eutrophication ; conservation ; phosphorus stripping ; biomanipulation ; Norfolk Broads
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract This paper discusses how the use of nature conservation targets can influence the practice of the management and rehabilitation of shallow lakes. It suggests that managers need to identify realistic targets, based on a sound understanding of the nature and ecological processes operating in the lakes in question. The constraints on effective management towards ecological targets are identified in the context of the rehabilitation of shallow lakes from eutrophication. It is recognised that most commonly, nature conservation is one of several objectives in lake management. Using the Norfolk Broads case study, it identifies a range of ecological and human use influences that need to be assessed in order to formthe basis of an integrated, sustainable approach to rehabilitation fromthe effects of eutrophication. The way in which nature conservation is taken account of through each stage in the planning of broads restoration projects is discussed, and the need for further specific advice for lake managers is indicated. This paper stresses the benefits of large scale experimental management, backed up by research and monitoring as a way of taking forward this applied science. The need for good communication with partner agencies and the local community when undertaking this management work, is also emphasised.
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  • 97
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    Hydrobiologia 408-409 (1999), S. 359-365 
    ISSN: 1573-5117
    Keywords: eutrophication ; trends ; lakes ; phosphorus ; nitrogen ; chlorophyll-a ; transparency
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The relation between (inter)national programs aiming at nutrient load reduction and changes in eutrophication has been studied for 231 Dutch lakes over the period 1980–1996. Trends in total-phosphorus (P) and total-nitrogen (N) were negative, as determined by analysis of both individual lakes and the complete data set. The relative trends in the nutrient concentrations as well as in the N/P ratio correspond with the significantly reduced P emission and the limited reduction of N emission in The Netherlands since the beginning of the 1980s. Negative trends in chlorophyll-aand positive trends in Secchi-disc transparency may be partly explained by reduced nutrient concentrations. Perspectives for the nearby future are discussed. Lake characteristics had only a minor impact on the trends. The improvement of the water quality was found for all subsets of average depth, surface area, hydraulic retention time and soil type. Furthermore, the effect of restoration measures and meteorological conditions on the trends were studied. Biomanipulation resulted in an additional improvement of several water quality variables compared to lakes that were only subject to (inter)national programs on nutrient load reduction. Specific measures resulting in additional P load reduction resulted only in lowered P concentrations. Severe winters resulted in lower chlorophyll-aconcentrations in the following summer and dry conditions in spring were favourable for all eutrophication variables in the following summer.
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  • 98
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    Hydrobiologia 410 (1999), S. 87-96 
    ISSN: 1573-5117
    Keywords: eutrophication ; nutrient limitation ; nitrogen ; phosphorous ; silicate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Nutrient loading by riverine input into estuarine systems has increased by 6–50 times for the N load from pristine conditions to present, whereas a 18–180 times increase has been observed in the P load. Reductions in the ratio of N to P delivery has also occurred with time. In a review of nutrient limitation in estuarine systems, it is shown that many estuarine systems display P limitation in the spring, switching to N limitation in the summer with some estuaries displaying dissolved silicate limitation of the spring diatom bloom. Historical and recent changes in nutrient loading and their effect on nutrient limitation have intensified the debate on the control of nutrient delivery to estuaries from both agricultural and point sources, and as to what nutrient (N or P) should be managed for in estuarine systems. It is hypothesized that potential reductions in P may help oxygen depletion especially in deep estuaries and reduce fast growing macrophytes such as Ulva sp., although P reductions probably will have little effect on summer chlorophyll concentrations, an important recreational management goal. Reductions in N loading should reduce summer chlorophyll concentrations and improve the conditions for submerged aquatic vegetation and thus improve ecosystem functioning. Finally, if only P reductions are pursued, that is if we are able to reduce P such that it is limiting year around in estuarine systems, it is likely that the export of N from estuarine systems would increase to the bordering N-limited marine systems, thus only exporting the problem of enhanced production with eutrophication.
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  • 99
    ISSN: 1573-5117
    Keywords: `snapshot' methodology ; spatial analysis ; nutrient fluxes ; eutrophication ; Esch-sur-Sûre basin
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The `snapshot' sampling methodology was applied to the spatial analysis of phosphorus and nitrogen concentrations and fluxes in the transnational upper Sûre watershed (Belgium–Luxembourg) during stable low discharge summer periods in 1991 and 1992. The results show clear differences in nitrogen concentrations and specific loads between agricultural and forested sub-basins, whereas for phosphorus the dependence on land use is less evident. The simultaneous measurement of stream discharge and nutrient concentrations permitted a quantitative evaluation of the input from point respectively diffuse sources and loads from the tributaries as well as the retention capacity by self-purification or sedimentation of the different phosphorus and nitrogen forms in the various sections of the Sûre river. The results illustrate the utility of the `snapshot' sampling as an important tool for an integrated watershed management.
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  • 100
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    Environmental modeling and assessment 4 (1999), S. 189-199 
    ISSN: 1573-2967
    Keywords: eutrophication ; tidal flow ; phytoplankton dynamics ; nutrient kinetics ; sediment oxygen demand ; sediment release of nutrient ; numerical modelling ; boundary-fitted coordinates
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A depth-averaged 2-D finite-difference numerical modelling for eutrophication in coastal waters, based upon a numerically generated boundary-fitted orthogonal curvilinear grid system, is developed. The present eutrophication model is run simultaneously with a hydrodynamic model to capture advection and diffusion due to tidal flow. A grid “block” technique is employed to handle the areas submerged intermittently. The model simulates the transport and transformation of up to nine water quality constituents associated with eutrophication in the waters. Some kinetic coefficients are calibrated with the measured data in Tolo Harbour, Hong Kong. Descriptive inputs for Sediment Oxygen Demand (SOD) and nutrient releases from sediment, based on relevant in situ sampling analysis, are used. The computed results are compared with other long-term field data in Tolo Harbour. It shows that the computational results by the present model agree with the field data well, i.e., the present model could reasonably describe the depth-averaged algal growth dynamics and water quality time-variations in Tolo Harbour.
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