ALBERT

Notes: Abstract. The Skokloster and Stockholm Environmental Institute (SEI) approaches were applied to the assessment of 145 soils of the South African highveld region in terms of sensitivity to acid deposition. The critical load class calculated by variants of these methods was compared with the acid neutralizing capacity (ANC) determined by pH measurement of soil suspended in a dilute acetate buffer solution. This rapid index of ANC correlates well both with ANC determined by an established but more laborious method which involves titration and equilibration of soil with HCl, and with a number of soil properties related to base status. The correlation between Skokloster or SEI critical load classes and ANC was weak. It was concluded that ANC determination would be a preferable basis for classifying these soils in terms of their sensitivity to acid deposition, since the method is direct and integrates the contribution of various soil properties to acid sensitivity instead of requiring the relative contribution to be calculated according to somewhat arbitrary weightings given to broadly defined classes of soil properties.

Notes: Abstract. Emissions of ammonia (NH3) and nitrous oxide (N2O), and nitrate (NO-3) leaching were measured in two field experiments following application of pig slurry at rates corresponding to 83–96 kg NH4-N ha-1 before sowing. In spring and in autumn 1994, slurry was applied by four methods: trenching (T), shallow injection (S), band spreading immediately followed by harrowing (B/H) and band spreading (B). NH3 emission measurements were made during the first week after application in both experiments. In the spring experiment N2O emissions and NO-3 leaching were measured during 6 and 52 weeks after spreading respectively, and during 11 and 33 weeks after spreading in the autumn experiment. In spring, the increased N2O emissions (i.e. control subtracted) ranged from 0.27% (T) to 0.45% (B/H), and in the autumn study from 0.92% (T) to 1.14% (B/H), of applied NH4-N, although showing no statistically significant differences. In order to validate the chamber measurements, a ‘megachamber’(21 m2) was used together with an infrared spectrometer. The emissions agreed well for (B/H), while (B) resulted in lower emissions compared with the smaller chambers. Emissions of NH3 were about one order of magnitude higher. In spring, (B) gave the highest emission, reaching 19.5% of applied NH4-N, whereas (S), and (B/H) gave the lowest emissions, reaching 1.2 and 3.5% of applied NH4-N, respectively. NH3 emissions in autumn were 15–20% lower compared with spring. In spring the increased nitrate leaching ranged from 10.1 (T) to 24.9 kg ha-1 (B/H) and from 29.5 (B) to 37.8 kg ha-1 (T) in the autumn experiment, showing no statistically significant differences. Estimations of indirect N2O emissions due to ammonia deposition and nitrate leaching, suggested that the N2O contribution from NH3 deposition was relatively small, while the indirect N2O emissions from NO-3 leaching were of the same order of magnitude or higher than the direct N2O emissions.

Notes: Abstract. In a laboratory study, 15N ammonium fertilizer uptake and rice growth was determined in a non-acid sulphate marine soil (Typic Tropaquept) and an acid sulphate soil (Sulfic Tropaquept). Acid sulphate sensitive (IR 26) and acid sulphate tolerant (IR 46) rice varieties were grown in soil suspensions incubated at four Eh levels (+500, +250, +50, and -150 mV) in microcosms for three weeks. The results showed that rice grown in non-acid sulphate marine soils gave slightly better dry matter weight of 1.8g/pot, greater 15N uptake of 12.8 mg N/pot, and higher total N uptake of 38.4 mg N/pot than under acid sulphate soil conditions indicating the non-acid marine soil is more favourable to rice culture. Growth as measured by weight of dry matter was significantly reduced from 2.1g/pot under oxidized condition (+500 mV) to 0.8g/pot under highly reduced condition (-150 mV). N uptake by rice was significantly reduced from 16.9 mg/pot at + 500 mV to 4.5 mg N/pot at -150 mV Total N uptake also decreased with decreasing Eh. Growth, 15N uptake and total N uptake by acid sulphate tolerant rice, IR 46 were significantly higher than the acid sulphate sensitive rice variety, IR 26. Under highly reduced soil conditions (-150 mV), growing rice in acid sulphate soil would require additions of lime, intermittent irrigation and/or mid season drainage in order to increase soil redox potential and remove toxic substances.

Notes: Book reviewed in this articles: Take-all disease of cereals: a regional perspective. By Hornby, D., Bateman, G.L., Gutteridge, R.J., Lucas, P., Osbourn, A.E., Ward, E. & Yarham, D.H.

Notes: Abstract. This paper investigates the ways in which some bedouin in the Nubian Desert of southeastern Egypt take decisions about both the choice of site for cultivation and the subsequent management of their soils. It explores the complementarity of formal and informal sciences and how each might profitably inform the other. Results show that the bedouin understand the physical limitations and nutrient supply properties of soils, but not aspects such as pH. Decisions on the choice of cultivation site are often made with regard to other perceived risks, such as soil loss and intermittent inundation, rather than just soil quality. It is also apparent that there exists among bedouin a plurality of indigenous knowledge mediated by factors such as experience, wealth levels, household circumstances and production priorities. Understanding indigenous knowledge is essential in helping to develop better use of the soil in this area, about which little is known and which has only a short history of small scale cropping.

Notes: Book reviewed in this articles: Agroforestry for soil management. By A. Young.

Notes: Book reviewed in this articles: Biological indicators of soil health. Edited by C.E. Pankhurst, B.M. Doube & V.V.S.R. Gupta.

Notes: Abstract. Air- dried milled peat (0.45 g g-1 wet weight basis) is used as an electricity generating fuel in Ireland. It is stored on peat bogs in triangular section stockpiles. These stockpiles comprise of milled peat of varying types, classified by poured density, and are subject to rewetting during storage which incurs an economic penalty. A water applicator was constructed to study the nature of rewetting mechanisms in laboratory-scale milled peat stockpiles, and to assess some potential protection strategies. Results indicated that there were few consistent short-term mechanisms linked to milled peat type. Over a longer period, low density milled peat stored most water, high density milled peat generated most runoff from the stockpile surface, and under certain conditions, throughflow was very important in all milled peat types. The industrial implications of the findings conclude that protection strategies should focus on lower density stockpiles.

Notes: Abstract. We examined whether nitrogen (N) and phosphorus (P) export was enhanced from grassland receiving inorganic fertilizer and manures typical of intensive livestock production. Buffer strips were included in the study to determine if they could reduce nutrient export. Hillslope plots receiving granular inorganic fertilizer, liquid cattle slurry and solid cattle manure (FYM) were compared using rainfall simulation for 4 storms on consecutive days at 22 mm h-1 and 35 minutes duration. The plots were hydrologically isolated in a randomized block layout of 4 treatments × 3 replicates and measured 30 × 5m; the upper 20m received either fertilizer, slurry or FYM, while the lower 10 m acted as an unfertilized grass buffer strip. Nitrogen and P export in surface runoff from grassland receiving inorganic fertilizer exceeded that from FYM or slurry treatments; concentrations up to46mgN1--1 and 15 mgP1–1 were recorded.Sixty eight % and 62% of the N from FYM and slurry respectively, was exported in organic form. Seventy four % (FYM) and 39% (slurry) of the P was in particulate or dissolved organic form. The buffer strip reduced N export in surface runoff by 94% and P export by 98% from inorganic fertilizer plots. A 75% reduction in N export was recorded from the buffer zone below slurry plots but only a 10% reduction in P, with most P remaining in the particulate or dissolved organic fraction. There was no significant difference in N export from the buffer zone between the inorganic fertilizer treatment and the untreated control.

Notes: Abstract. The Representative Soil Sampling Scheme of England and Wales was started in 1969. During the 25 year period 1969–1993 mean soil pH values under arable and ley-arable cropping changed little, but under grassland they fell by 0.3 units. Under arable cropping, mean available phosphorus declined whilst available potassium increased fairly steeply for the first eight years then declined again to near the start value by 1993. No significant changes in soil phosphorus and potassium levels were found under ley-arable cropping, but the percentage of fields under ley-arable rotations declined from 33% to 14%. Under grassland, phosphorus and potassium levels both declined, although potassium levels rose initially before falling.For this report England and Wales were also divided into five regions. Wales and the West Country had the lowest pH values; these regions together with the Northern region were also found to have declining pH values. Phosphorus and potassium concentrations have been falling in the Northern region which stands out as having the lowest current potassium status with 20% of all fields deficient at index 0.Changes in pH and nutrients are discussed for soils sampled following the main arable crops. The largest changes found were the reductions in phosphorus and potassium in soils after potatoes. In 1993 almost one in ten sugarbeet crop soils had an excessive phosphorus level (index 5+) giving an increased risk of water pollution by this element.Under arable cropping the proportion of soils with low (〈 1.8%) organic matter declined. Average soil organic matter levels for all crops and grass have remained static during the period. It is concluded that agricultural soils in England and Wales have not contributed to an increase in the greenhouse gas carbon dioxide.

Notes: Book Reviewed in this article:Principles and Practice of Soil Science (Third Edition) By R. E. White.

Notes: Abstract. Since 1980 soil erosion by water on agricultural areas has been measured in plot experiments conducted at the Department of Soil and Water Sciences at the Agricultural University of Norway. Meltwater in spring is the most serious erosive agent but rainfall on nearly saturated soil and hare soil also has a considerable erosive effect. Erosion as a result of heavy rainfall in the growing season occurs occasionally. A high proportion of water-stable aggregates and a high content of clay and humus are characteristics of a soil with good resistance to emsion. Tillage has a strong influence on soil loss and it has been found that spring tillage reduces the annual soil loss by 90% compared with autumn ploughing.

Notes: Abstract. There is environmental concern about the increasing land application of dairy shed effluent in New Zealand. To minimize groundwater contamination by applied nutrients and pathogens it is desirable to avoid preferential flow through topsoils. Our objective was to determine an irrigation rate that retained applied effluent in the topsoil of two commonly irrigated New Zealand soils. In a field experiment, well drained Horotiu soils and poorly drained Te Kowhai soils were irrigated with a pyranine dye/KBr tracer solution at four rates (5, 10, 15, 20 mm/h) using a drip-type rainfall simulator. Twenty minutes after irrigation ceased the soil was excavated horizontally at 25 or 50 mm intervals, and photographed under UV light until no further fluorescence was vishle. Each layer was also analysed for bromide content, without subsampling. The wetting pattern was uneven in both soils as leachate moved preferentially through worm channels and structural cracks. Preferential flow was greatest in the Te Kowhai soil and increased at faster application rates. Dye fluorescence was curvilinearly related to bromide concentration. At both study sites, maintaining the irrigation rate at 〈inlineGraphic alt="leqslant R: less-than-or-eq, slant" extraInfo="nonStandardEntity" href="urn:x-wiley:02660032:SUM96:les" location="les.gif"/〉 10 mm/h minimized leachate movement into the subsoil. Pulsed irrigation at faster rates was not retained in the topsoil.

Notes: Abstract. We investigated whether a Na-K polyacrylate polymer could be used to remediate a sandy soil artificially contaminated with copper. An experiment, carried out in solution culture, showed that ionic copper was rapidly trapped within the polymer to a maximum content of c. 190mg Cu g -1 dry polymer, the proportion needed for chelation of each copper ion by four carboxylic groups present in the polymer chains. Cu-EDTA was not retained by the polymer. Growth of perennial rygrass in 10 kg pots was stimulated in the gel-amended soil, and even in the pots with the highest levels of copper, growth was much less impaired than in pots without polymer. Copper concentrations of the shoot.; were smaller in the plants cultivated in the amended soil. Water extractable copper was considerably reduced in the contaminated gel-amended soil and polymer particles removed from the soil were shown to contain high levels of copper.

Notes: Abstract. The fragile soils at the transition between semiarid and arid areas are continuously threatened by human activity, which frequently involves the elimination of plant cover. We studied the impact of vegetation removal on soil characteristics in senmiarid Mediterranean Spain using two plots (15 m ± 5 m), installed on a north facing slope of 23%. Vegetation was removed from one of the plots (disturbed plot), and changes in the soil characteristics were compared with an undisturbed control plot. Fifty-five months after vegetation removal the organic carbon content decreased by 35%, the percentage of stable aggregates by 31% and soil bulk density increased by 8%. The models that best represented the changes of these parameters with time were linear equations. There were no significant differences between the water retention capacity or saturated hydraulic conductivity of the treatments. The rapid loss of soil organic matter and the consequences in terms of physical soil properties were considered to be the main factors in soil degradation. No symptoms of natural recovery were observed in the disturbed plot and the tendency was for a steady deterioration in soil behaviour. This means that human activity or climatic change leading to less vegetation could result in irreversible soil degradation in semiarid areas.

Notes: Abstract. A field experiment was conducted over two years in one of the mountain Alfisols of the Western Himalayas to study the effects of phosphorus and mulching on phosphorus use efficiency (PUE) and productivity of wheat (cv. S-308) at difference growth stages. The source of phosphorus was single superphosphate at 0, 26, 52 and 78 kg P/ha whereas the sources of mulching materials were pine needles (Pinus longifolia), lantana weed (Lantana camara) at 8 t/ha and transparent polyethylene sheet compared with no mulch.The phosphorus use efficiency (PUE) at tillering, flowering and harvesting was greatest at the lowest dose of P and decreased as the P levels were increased. However, the increased levels of P up to 78 kg/ha, significantly improved the dry matter yield at tillering stage (30%) and flowering stage (93%) and also the grain yield (139%) and straw yield (148%) at the harvest stage. The application of mulching materials in general, and polyethylene in particular, significantly increased the phosphorus use efficiency and the productivity of wheat by 27% at tillering stage; 17% at flowering stage, and by 98 and 110% in the case of grain and straw yield at harvest stage.Although the polyethylene mulch effect was physically superior to the other materials, the latter gave greater financial returns. Consequently, the economic optimum application of P in association with 8 t/ha of lantana mulch was found to be 53 kg/ha over two years, whereas, in the absence of mulching, it was 58 kg/ha.

Notes: Abstract. An increasing proportion of P reaching surface waters appears to be derived from agricultural land; apportioning the relative contribution to particular farming systems is not straightforward. The majority of farms in the UK operate on the basis of an annual agricultural P surplus, the size of which varies across different farm types. Particularly high values (〉20kg ha-1) are commonly associated with intensive-livestock production and the lower values (〈10kg P ha-1) with arable farms. The geographical divide between the predominance of arable cropping in the east and livestock enterprises in the west of the UK should result in an uneven pattern to the distribution of annual P surplus. The expected cumulative effects of this surplus should be a noticeable increase in total and extractable soil P concentrations, but this is not readily apparent. While evidence from experimental plots suggests a relationship between the concentration of available soil P and that present in drainage waters, extrapolating this information so that it can be useful at the scale of a whole catchment is difficult. The loss of P from agricultural land is controlled by factors which are independent of the size of the annual P surplus. The pattern of P cycling, together with the dominant loss pathways, differ greatly between livestock and arable farming systems. Proportioning the contributions that either increased soil erosion arising from changing agricultural practices or the cumulative effect of a P surplus have had upon P loss is a necessary prerequisite to effective management.

Notes: Abstract. Agriculture contributes significant loads of P to surface waters. The reductions in these diffuse P inputs necessary to help prevent eutrophication problems and/or assist in the restoration of water quality will require controls over both nutrient inputs and their subsequent transport in land runoff. Specific mitigation options include nutrient budgeting, input management, soil conservation, land use management and the establishment of riparian, and other buffer zones. The variable nature of diffuse P loss suggests that the best approach to control is through integrated management at a range of scales. Critical control concepts at the farm level include targeting source areas adequately, maintaining P input loading rates within recommended limits and avoiding high-risk management actions. Since eutrophication is a natural phenomenon and with potential conflicts with the need to meet production targets and/or minimize loss of other nutrients (N), some assessment of acceptable levels of P loss, of cost effectiveness of options and some prioritization of goals are necessary to find optimal solutions. As the requirements of individual waterbodies differ, these solutions need to be site specific and their successful adoption requires an appreciation by farmers of the importance of minimizing agricultural P loss both as individuals and collectively within a catchment.

Notes: Book reviewed in this articles: Soil and Environment: Northern Ireland. By J.G. Cruickshank.

Notes: Book reviewed in this articles: Carbon and Nutrient Dynamics in Natural and Agricultural Tropical Ecosystems. Edited by L. Bergstrom & H. Kirchman.

Notes: Abstract. At present about half of the N fertilizer used in China is as urea. However, recovery of urea N in crops is often limited to 30–40%. Application of urea in combination with hydroquinone plus dicyandiamide (U-HQ-DCD) gave an improved urea-N recovery and grain yield by spring wheat in a pot experiment. The apparent total urea-N recovery was 69% and 73% of this recovered N was found in the grain. The grain yield was 32% higher than in the treatment where urea was applied without inhibitors. The application of hydroquinone and dicyandiamide also resulted in a smaller soil nitrate content, which might restrict post-harvest leaching of N. Another beneficial effect of these inhibitors was that the N2O emission from the soil—plant system was reduced by 35% compared to the treatment where only urea was applied. The use of urea in combination with hydroquinone plus encapsulated calcium carbide gave smaller beneficial effects.

Notes: Abstract. The application of gypsum to a Natraquoll under pasture was evaluated in a humid area of the ‘Flooding Pampas’ of Argentina in a randomized block field design. Gypsum was incorporated at 0, 15, 35, and 60 t ha-1. After the gypsum was mixed into the soil, the electrical conductivity of the soil solution was linearly related to the initial sodium adsorption ratio. The depth of reclamation depended on the amount of gypsum applied. Dry matter yield in all gypsum treatments was greater than the control without gypsum.

Notes: Abstract. Nitrate leaching under newly planted Miscanthus grass was measured for three years. The crop received either no fertilizer-N or an annual spring application of 60 kg or 120 kg N ha-1. During three winters soil water was collected from porous cup probes installed 90 cm deep. Nitrate leaching was calculated from the mean drain flow recorded in two drain gauges multiplied by the mean nitrate-N concentration in the soil water solutions collected. In the first year soil water nitrate concentrations were high on all treatments and N losses were 154, 187 and 228 kg ha-1 respectively on the unfertilized treatment and those that received 60 or 120 kg N ha-1. Leaching losses in the second and third years were, in turn, 8, 24 and 87 kg ha-1 and 3, 11 and 30 kg ha-1 for the unfertilized treatment and for the 60 and 120 kg N ha-1 treatments respectively. Leaching losses were closer to those recorded under extensively managed grassland than arable land. The large losses in the first year were probably due to the previous agricultural management at the site and excessive inputs of N on the fertilized plots. In the second and third year, lower drainage volumes may also have influenced losses. The results show that Miscanthus, once established, can lead to low levels of nitrate leaching and improved groundwater quality compared with growing arable crops.

Notes: Abstract. A practical and simple agro-ecological zonation of Mozambique is presented to facilitate the identification of production conditions and to serve as a basis for agricultural recommendations. The zonation is based on: FAO Major Soil Groupings, altitude and mean annual rainfall. The rationale of the zonation is evaluated by correlating these criteria with other climatic variables and the maize growth cycle. The effectiveness of the zonation was tested with maize yield data from fertilizer trials.The results show that FAO Major Soil Groupings explain a significant part of the total variation in N and organic C contents, Olsen P, exchangeable K, pH and CEC. Altitude relates significantly with temperature, maize growth cycle, radiation and rainfall reliability. Mean annual rainfall relates significantly with rainfall reliability and radiation. Grouping the maize fertilizer trials according to the zonation criteria explained 39% of the variation in unfertilized yields and yield responses to NPK fertilization, and 51% of the variation in fertilized (NPK) yields.The agro-ecological zonation on the basis of soil, altitude and mean annual rainfall proved to be a sound and practical way to identify land areas sufficiently homogeneous to be served by the same fertilizer recommendation.

Notes: Abstract. The pH of soil samples was remeasured after storage for 20 years in the laboratory. The pH decreases were minor in acid to neutral soils (-0.3), but greater in alkaline soils (-0.63). The pH differences were statistically significant only for alkaline soils. The decreases of pH with time are probably mainly due to the decomposition of organic matter, the CO2 produced, the hydroscopic water and the presence of CaCO3.

Notes: Abstract. This research aims to assess how the variability in soil morphology of Luvisols along a microtopographic sequence influences the condition of pedunculate oak (Quercus robur). The condition of 205 pedunculate oaks was observed during one growth season and related to morphological soil properties. Results show that the presence of a consolidated argillic B horizon or fragipan in Luvisols, has a negative influence on the condition of Q.robur.

Notes: Abstract. We examined the dynamics of inorganic P (Pi) and organic P (Po) pools of a savanna Alfisol under continuous cultivation complemented with nitrogen (N) and phosphorus (P) fertilizers with or without cow manure (D), using a modified Hedly fractionation. Continuous cultivation without P fertilizer decreased the concentration of Pi and Po, pools including the residual P fraction compared with an unfertilized treatment with natural vegetation. Adding P fertilizers alone or in combination with D (P, NPK, D+P, D+NP and D+NPK) increased the concentration of labile Pi pools, but decreased the concentration of Po, pools and the residual P fraction. The tendency of the residual P fraction to decrease along with Po pools suggested that the residual P fraction was largely Po. This is consistent with the correlation between the residual P fraction and total Po (r=0.74**) and the residual P fraction and organic carbon content (r=0.47**). Analysis of the relationships between plant available P, estimated by resin-extractable P, and the more stable Pi and Po, pools indicated that 85% of the variation in resin-P was atiributable to the hydroxide extractable Pi, (OH-Pi) and HCI-Pi which acted as sinks for fertilizer-P. The contribution of the residual P fraction to resin-P was indirect via bicarbonate-extractable Po (HCO3-Po) and OH-Po. These results also clarify why attempts to find P extraction methods which correlate well with response to P and to P uptake in the savanna have given inconsistent results.

Notes: Abstract. Atmospheric nitrogen (N) makes a significant contribution to the N inputs to agricultural systems and is a major eutrophying and acidifying input to natural and semi-natural ecosystems. We have estimated the nitrogen deposited to arable land at Rothamsted and at two Nitrate Vulnerable Zones (NVZs) in the UK, Lichfield and the River Waveney. Using the SUNDIAL N cycle model calibrated against measured soil mineral N and leaching losses at Rothamsted, we have calculated the contribution of deposited N to nitrate leaching under a range of crops growing on the major soil series in the NVZs. Approximately 44, 46 and 28 kg N/ha per yr are deposited to arable land around Rothamsted and in the Lichfield and Waveney NVZs, respectively. Most of this is dry-deposited in oxidized forms: nitrogen dioxide and nitric acid are the main components, arising mostly from industry, home heating and vehicle emissions. SUNDIAL predicts that current total leaching losses from arable crops average 39 kg N/ha per yr in the Lichfield NVZ anti 22 kg/ha per yr in the Waveney NVZ. Atsmospheric N contributes about 28% of the N leached from arable land in the Lichfield NVZ and 17% in the Waveney NVZ, a very significant amount. There is little variation in total leaching or the atmospheric contribution to it between soil series within each NVZ, but much variation with crop type and the weather: atmospheric N can comprise over 40% of the N leached under spring cereals in some years.

Notes: Abstract. The effect of cultivation on the P properties of whole soils and aggregate sizes separated from them was investigated for soil developed on three types of parent material. Cultivation, with associated fertilizer additions, increased both the total soil P content and extractable P of the whole soils. When the soils were separated into aggregate sizes (〈 2, 2-52, 53-150 and 151 2000 μm), total soil P and resin extractable P increased with decreasing aggregate size. Water extractable inorganic P exhibited the opposite trend, while concentrations of water extractable organic P were similar from each aggregate size. Eroded aggregates can adsorb P or release P to solution, the extent of which will be dependent upon a combination of soil attributes and the prevailing solution conditions. The resulting equilibrium P concentration (EPC) of the eroded material will be markedly different from that of the whole soil. By increasing the P content, particularly of the smaller sized aggregates it is likely that the EPC of the eroded material would favour greater P desorption.

Notes: Abstract. Phosphorus budgets have been compiled for two contrasting grassland farming systems in the UK; intensive dairy farming and extensive hill sheep production. Balance sheets of inputs, recycling of P through the soil–plant–animal pathway and outputs are presented to determine the potential rate of P accumulation in the two systems. A typical 57 ha intensive dairy farm with 129 lactating cows imports 2.48t P via fertilizer, bedding and concentrates, plus a small amount from the atmosphere, of which 0.98t are exported in milk, calves and transfer from soil to the aquatic environment. Therefore 1.5t of P are retained within the farm each year, which equates to an accumulation rate of 26 kg/ha in the plant-soil system. This surplus occurs despite a fertilizer input of only 16 kg/ha. However, a large proportion of P, equivalent to 27 kg/ha, is imported in feed concentrates.For the typical 841 ha hill sheep farm supporting 694 Blackface ewes, P inputs and outputs are 0.66 and 0.42 t/yr, respectively. Therefore, approximately 0.24t P are retained within the farm, which is equivalent to an accumulation rate of 0.28 kg/ha per yr. In comparison to the small annual inputs and outputs of P on the hill farm, much P, 2.48t, is recycled through the plant-soil and plant-animal-soil pathways on the hill sheep farm. For both farming systems there is a net input of P, although the rate of accumulation is ten times greater for the dairy farm where the annual retention of P represents 60% of the total P inputs, compared with 36% on the hill sheep farm.

Notes: Abstract. Scientific land and soil resource surveys have had only limited impacts locally on development and extension practice in the tropics. They are thought to have little relevance for subsistence farmers. Their failure to accommodate local social and cultural priorities is a factor. Soil scientists have, until recently, given little attention to others’ understanding of soil or ‘ethnopedology’. The incorporation of indigenous soil and land resource knowledge has recently been advocated to improve their relevance. But a common error is uncritically to impose a western scientific model, which may distort understanding. The ill-informed, decontextualised knowledge that results may even promote negative interventions. This paper criticises the narrow idea of ‘indigenous technical knowledge’, citing evidence from Papua New Guinea, Bangladesh and Indonesia. While we find farmers consistently use some of the same information as scientists to assess soils, their definitions of soils and land types are often at odds. Scientists identify classes by a range of technically assessed properties, whereas farmers may not. Their more holistic approach also accounts in part for the disjunction, frequently incorporating exotic social and cultural aspects. The wider use of indigenous soil notions in agrotechnology transfer may be limited too by some of their intrinsic characteristics, inclined to be location specific, and culturally relative.

Notes: Abstract. Two field trials were established in 1991 to determine the effects on crop yield, N uptake, soil moisture content and heavy metal concentration of applying de-inked paper mill sludge (DPMS) over the period 1991 to 1993. In the first year, during decomposition of the DPMS, N immobilization occurred resulting in loss of cereal yield (P 〈 0.05) at low rates of N fertilizer. Approximately 40 kg extra N fertilizer/ha was required per 100t DPMS/ha to compensate for this N immobilization. Soil volumetric moisture content was increased (P 〈 0.001) by c. 20% at both sites by 200 and 300t DPMS/ha. DPMS did not significantly increase (P 〉 0.05) soil concentrations of total Zn, Cu and Pb. Soil nitrate concentrations after harvest were reduced (P 〈 0.01) by c. 17 mg N/kg per 100t DPMS/ha with increasing rates of DPMS up to 200 t/ha. In the second year following the DPMS application, there were no significant effects on grain yield indicating that very little or no N was immobilized. By the third year, the soil N supply was 7 kg N/ha higher where a single dressing of 100t DPMS/ha had been applied compared to the control. This resulted in an overall yield increase of 7% (P 〈 0.10). Soil N supply was lower (N.S.) but crop yields were similar (P 〉 0.05) to the control where single dressings of 200 and 300t DPMS/ha had been applied.

Notes: Abstract. Nitrate leaching and pasture (Lolium perenne / Trifolium repens) yields were measured on monolith lysimeters (80 cm diam. × 120 cm depth) of a Templeton sandy loam soil (Udic Ustochrept), following repeated applications of dairy shed effluent (DSE) or ammonium fertilizer (NH4Cl), under spray (50 mm/month) or flood (100 mm/month) irrigation. Applications of DSE at 400 kg N/ha per annum resulted in significantly less nitrate leaching (8–25 kg N/ha per yr) compared with NH4Cl (28–48kg N/ha per yr) (P 〈 0.01). Over the two year period, the total mineral N (predominantly nitrate) leached was equivalent to 2.5–3.7% of the total N applied in the DSE and 8.7–9.8% of the N applied in the NH4Cl. There was a trend of slightly less nitrate leaching under the flood irrigation than under the spray irrigation, probably because of the greater potential for denitrification under the wetter conditions. Average nitrate concentrations in the leachate were generally below the drinking water standard except in the NH4Cl treatment under spray irrigation where it averaged 10 mg NO3-N/l over the two year period. DSE was equally as effective as NH4Cl in stimulating pasture dry matter production. Annual nitrogen uptakes were similar for the DSE (343 kg N/ha) and NH4Cl (332–344kg N/ha) treatments in the first year but were higher in the DSE (361–412 kg N/ha) than in the NH4Cl (324–340 kg N/ha) treatments in the second year. Pasture uptakes of phosphorus and sulphur were also higher in the DSE than in the NH4Cl treatments in the second year. The results emphasize the need to set different regulatory limits for land application of organic wastes of various types and for N fertilizers.

Notes: Abstract. Organic indices and aggregate stability were measured in soils of similar texture on two restored opencast coal sites and on adjacent, undisturbed land in South Wales, UK. The aim was to assess rates of soil change over time, to relate these changes to conditions in undisturbed land and to evaluate organic-aggregation relationships across these range of soils. Several management factors were included in the comparisons.Organic matter accumulated at the surface (0–7.5 cm) of restored soils, contents being greater than undisturbed soils after 21 years. However, this increase in total organic matter did not result in proportionate increases in carbohydrates and microbial biomass, nor did aggregate stability increase to the degree expected. Between 7.5 and 15 cm depth, rates of change were slower. Microbial metabolic quotient and respiration relative to total soil C were highest in recently (9 years) restored soils, intermediate in 21 year old restored soils and least for undisturbed soils.Sewage (100t/ha) applied at reinstatement improved clay stability but had little effect on other parameters when measured 9 years later. Drainage of soils restored in 1972 reduced total organic content but its influence on other organic indices was more complex. Carbohydrate contents had the closest association with aggregate stability and microbial biomass.Although the productivity of restored land may recover more quickly, findings suggest that rehabilitation of normal soil processes following surface mining may take much longer than the normal five year aftercare period.

Notes: Abstract. Recently, there has been interest in the occurrence of bromide (Br-) in natural waters since it has been demonstrated that Br-, in association with humic substances in raw waters, is readily incorporated into haloacetic acids in the form of organically bound bromine (Br) during water chlorination. We report results of the effects of experimentally rewetting a naturally drained gully mire on the hydrochemistry of Br-, iron (Fe) and dissolved organic carbon (DOC) in the peat water. Results obtained over a three year period showed that rewetting substantially increased the concentrations of these solutes in the pore water, with peak values of 1 mg dm-3 (Br-), 〉 60 mg dm-3 (Fe) and 〉 300 mg dm-3 (DOC) detected in some samples after rewetting, compared with typical values 〈 0.05 mg dm-3 (Br-), 〈 1 mg dm-3 (Fe) and 〈 15 mg dm-3 (DOC) under the drained conditions. Bromide, Fe and DOC release were highly seasonal, with the largest concentrations observed in late-summer to autumn. However, whereas seasonal peak concentrations of Fe and DOC have since remained at these higher levels, seasonal peak concentrations of Br- were progressively attenuated over time, suggesting the latter phenomenon is a flush effect, with no longer-term consequences for water quality.

Notes: Abstract. Experiments were set up at two sites to measure nitrogen (N) leaching loss from applications of separated pig/cattle slurry and cattle farmyard manure(FYM), during winters 1990/91–1993/94 (site A) and from broiler litter and FYM, during winters 1990/91–1992/93 (site B). The manures were applied at a target rate of 200 kg ha-1 total N during the autumn and winter to overwinter fallow or top dressed onto winter rye. The total N in leachate was calculated from leachate N concentrations, in samples collected using ceramic cups buried at 90 cm, and an estimate of drainage volume. Nitrogen losses were greatest following manure applications in September, October and November but losses following applications in December or January were not significantly elevated above those from untreated controls. Losses were consistently lower from FYM than from broiler litter or separated slurry. The presence of a cover crop (winter rye) significantly reduced overall N leaching compared with the fallow, but only reduced the manure N leaching losses at one site during one winter when a high proportion of drainage occurred late. The incorporation of a nitrification inhibitor (DCD) with manures applied in October did not significantly reduce the manure N leaching.

Notes: Book reviewed in this articles: Land Restoration and Reclamation: Principles and Practice. By J.A. Harris, P. Birch & J.P. Palmer.

Notes: Abstract. Tracts of dispersive Plio-Pleistocene clays in central and southern Italy suffer from severe erosion, which has led to the creation of badlands characterized by ‘calanchi’(unvegetated knife-edge ridges) and ‘bian-cane’(cone-shaped hummocks). In recent decades, large areas of this eroded land have been reclaimed for arable cultivation by remodelling the landscape with heavy earth moving equipment. This exposes the clay to erosive rainfall. Wet aggregate strength was used to assess those physical and chemical properties that govern the erodibility of the clays. Regression analysis demonstrated that the most significant variables in predicting soil erodibility were the % organic matter and the exchangeable sodium percentage (ESP). Threshold values of 1–2% and 3–4% organic matter were obtained, dependent on the method of pre-wetting. Reclaimed land is on the borderline of these thresholds and therefore at risk of erosion. Nevertheless, the stability of reclaimed land is significantly higher than that of the badland parent material, ascribable to a lower ESP. Careful land management is required to avoid a recurrence of erosion and the reestablishment of badlands.

Notes: Abstract. The SOILN model with a crop growth submodel for grass and cereal crops and the associated soil water and heat model SOIL were selected out of a number of similar models to simulate nitrogen cycling in a soil/crop system. The main parameter values required by the model were selected on the basis of a combination of field experiments and literature sources. Experimental data measured on grassland at Dumfries in the West of Scotland and on arable land at Bush Estate near Edinburgh were used to test the model. Simulated biomass yields and nitrogen contents of harvested biomass were in reasonable agreement with measured values for both grass and cereal crops. There were similar trends in accumulated leached nitrate between the simulations and experiments at the sites. Any discrepancy between simulated and measured nitrate leached appeared to correspond to similar discrepancies between simulated and measured water flow. The comparison between simulated and experimental results suggests that the model with the selected parameter values can simulate nitrogen and carbon cycling both in grassland and in arable land, and make convincing predictions about the effects of varying soil, crop, fertilizer and manure management practices. A basic sensitivity analysis carried out on the parameters determining the biological and biochemical processes showed the model predictions of annual N-leaching are relatively insensitive to all but two of the plant parameters. However, the model predictions of annual N-harvested and dry mass production are sensitive to numerous plant parameters.

Notes: Abstract. Nitrogen (N) is of enviromental concern if it leaches or is released as nitrous oxide (N2O,). In order to utilize N efficiently in grazed pasture systems, the fluxes of N from various sources need to be quantified. One flux is N mineralization from organic sources. Previous work has examined incubation and chemical extraction of soils as methods to determine N mineralization potential. This paper re-examines new and previously published data on net mineralization, with the aim of examining the relationships between soil thermal units, net N mineralization (measured using acetylene incubations) and dry matter production in pastures. Net N mineralization is expressed as N turnover (net N mineralization as a % of total soil N). Relationships are developed between soil thermal units, dry matter production, and N turnover. These relationships have potential in advising farmers on potential N mineralization from soil organic matter. A second use of such relationships is the modelling of N transformations in pasture systems. Further work should explore the effect of soil moisture on such relationships and examine the relationship between soil thermal units and uptake of N by pasture.

Notes: Abstract. The effect of nitrogen fertilizer inputs to cereal crops on nitrate leaching after harvest was tested on 21 experiments on sandy soils in England. At small nitrogen fertilizer rates leaching increased very little with increasing inputs, while at high rates more than half of any additional nitrogen could be accounted for as increase in nitrate leached. In many cases the response fitted two straight lines. Nitrogen offtake in grain also fitted two straight lines, with a form which complemented the leaching response. The gradient averaged 0.52 kg N in grain for every additional 1kg N applied below the break point, but only 0.05 kg/kg above. The break points were generally close to or above the economic optimum N input. The effect of inputs on leaching could he quantitatively related to nitrogen offtake in grain, assuming a constant ratio of nitrogen in grain to total nitrogen uptake. The results show that fields receiving N inputs in excess of the economic optimum cause a disproportionately large nitrate loss. However because of uncertainty in predicting the break point in advance, modest further reduction in leaching will occur by reducing inputs to somewhat below the expected economic optimum.

Notes: Book Reviewed in this article:Land resources: on the edge of the Malthusian precipice? Edited by D. J. Greenland, P. J. Gregory & P. H. Nye

Notes: Abstract. In 1996 conservation tillage was used on nearly 36% of the cropped area of the USA. This level has remained relatively unchanged over the past few years. The use of conservation tillage varied by crop and was dependent on site-specific factors including soil type, topsoil depth, and local climatic conditions. A number of economic, demographic, geographic, and policy factors have affected the adoption of conservation tillage. While it was not possible to quantify exactly the impact of these factors, it was clear that management complexities and profitability are key factors impeding an increase.

Notes: Abstract. The effects of long-term waste water irrigation on soil fertility and nutrient supply to alfalfa (Medicago sativa) have been investigated in an area near Mexico City Waste water irrigation has improved the nutrient balance of the soil in respect of total nitrogen and available phosphorus. In contrast Na has displaced Ca and diminished the Ca saturation of the soil. In consequence, Ca in alfalfa tissue has decreased and phosphorus and sodium increased after 80 years of waste water irrigation. Estimates of the N-balance suggest that substantial amounts of N are being lost, probably with consequent eutrophication of the groundwater.

Notes: Abstract. Results are presented from three years (1992-1995) of a field leaching experiment on a sandy soil in south-west Sweden. Plots of spring cereals, either with or without an undersown perennial ryegrass catch crop, were compared for nitrogen leaching and nitrogen status in soil. Both treatments were ploughed in spring, and other tillage regimes were also identical. Measurements of nitrogen leaching from drains, nitrogen uptake in crops and mineral nitrogen in the soil were made. Two coupled, simulation models, which describe water flow and nitrogen transformations and transport in soil, were used to interpret data and to calculate the nitrogen budget and nitrogen mineralization in the soil.Nitrogen leaching was 40 50% less in the catch crop treatment compared with the control during years when the establishment of the catch crop succeeded. In the third year of the experiment nitrogen leaching was actually greater in the catch crop treatment (7 kg N/ha). This increase was caused by a poorly established catch crop coinciding with enhanced mineralization of previous catch crop residues. There was no simulated change in soil organic nitrogen in either of the treatments. Simulations showed increased nitrogen mineralization during April-July after incorporation of plant material in spring, especially in the catch crop treatment. However, the increased nitrogen mineralization probably occurred too late for the released nitrogen to be fully available to the main crop.

Notes: Abstract. The effects on nitrate leaching of incorporation of paper mill waste at three cultivation depths in fields previously cropped to iceberg lettuce and calabrese are reported. In the lettuce experiment, incorporation of 40 t DM paper mill waste/ha resulted in a decrease in N leaching (measured with suction cups) from 177 to 94 kg/ha (S.E.d= 23). Deep ploughing with and without paper waste increased N leaching from 105 kg/ha (normal ploughing or surface incorporation) to 172 kg/ha (S. E. d= 27). Measurements of nitrate leaching using deep soil cores showed a less clear cut effect. Nitrous oxide (N2O) emissions were very high immediately after paper waste was ploughed in to a depth of 35 cm. Non–significant increases in biomass N content were measured in the spring following paper waste application. There was no significant reduction in plant N uptake in subsequent crops. Removal of above–ground crop residues did not have a significant effect on nitrate leaching or N2O losses. In the calabrese experiment, application of 40 t DM paper mill waste/ha followed by summer cropping with iceberg lettuce caused a decrease in N leaching (measured using deep soil cores) from 227 to 152 kg/ha (S. E.d= 22, mean of all cultivation treatments).

Notes: Abstract. In a long-term experiment, soil physical properties were studied after 20 annual cycles of maize-wheat-fodder cowpea cropping with annual application of inorganic fertilizers and farmyard manure (FYM). Weeds were controlled by hand or by the use of herbicides. The hand weeding treatment resulted in a lowering of the bulk density of the surface layer (0-15 cm) and a significant increase in the subsurface (15–30 cm) density. Application of FYM significantly increased the soil organic carbon (OC), infiltration rate, water retention, aggregation and aggregate stability in water. Application of inorganic fertilizers had small but statistically significant effect in increasing soil OC.

Notes: Book Reviewed in this article:A Place Against Time–Land and Environment in the Papua New Guinea Highlands By P. Sillitoe.

Notes: Abstract. An empirical model was developed for prediction of annual average nitrate leaching as affected by the long-term rate of N fertilization and crop type. The effect of N fertilization was estimated from annual values of nitrate leaching obtained from two Danish investigations of drainage from pipe drains with four rates of N fertilization on a loamy sand and sandy clay loam from 1973-89. The effect of crop at normal N fertilization was estimated from 147 observations of annual nitrate leaching obtained from field measurements. The nitrate leaching model consists of a relative N fertilization submodel and an absolute submodel for specific combinations of crop, soil and drainage at the normal rate of N fertilization. The relative submodel is Y/YlN= exp[0.7l(N/ N1– I)], where Y is the nitrate leaching (kg N/ha per year) at fertilization rate N, and YIN and N1 are the corresponding values at the normal rate of N fertilization. The relative submodel is valid for cereals, root crops and grass leys fertilized with mineral fertilizer at N/N1 〈 1.5, and on the prerequisite that the fertilization rate N has been constant for some years. To illustrate the use of the relative leaching submodel, estimated values of YIN corrected to mean annual drainage for 1970 to 1990 in Denmark for spring cereals and grass on sandy and loamy soils are given as input to the relative leaching submodel. The model can be used for sandy to loamy soils to estimate the mean nitrate leaching over a number of years.

Notes: Abstract. The interactions of P with soils and sediments are examined in the context of transport processes from land, through rivers to estuaries and coastal waters. In soil erosion, selective size fractionation and preferential sorption to finer solids is crucial in the transport of P to water courses. Problems in quantifying the sorption affinity and equilibrium phosphate concentration (EPC) of mixtures of different soils and sediments are identified. Riverine transport of P by suspended solids is usually very important and examples of the changes in the amount and composition of particulate P (PP) concentration during storm events are discussed. Increased P content of solids during the first autumn storms, probably reflect the resuspension of accumulated stream bed-deposits. The fate of P in estuaries and their importance as possible long-term sinks of P are discussed. The relatively high concentrations of dissolved P associated with riverine inputs are to some extent buffered by the relatively high concentrations of suspended sediments resulting from tidal flows. Phosphorus may be released during transport to the sea due to decreases in the EPC, increases in salinity and release from bottom sediments as a result of low oxygen conditions.

Notes: Abstract. Organic manures are an important source of P which can make a significant economic contribution to farm fertilizer policies. In the region of 119000 tonnes of P are returned annually to UK agricultural land in the form of manures collected and handled on farms, with an estimated 66000 tonnes of P applied to tillage land and 53000 tonnes to grassland.Previous research on the utilization of manure P has tended to indicate a lower efficiency compared to inorganic fertilizer P in the season following application, but in the longer term manure and fertilizer P can be regarded as equivalent. Failure to adequately account for manure P additions to the land may result in soil enrichment which could increase the agricultural contribution to eutrophication, as a result of surface runoff or leaching.Recent research has indicated that the current guidelines for minimizing runoff losses following the land spreading of manures are generally soundly based. However, there is a need for further research where manures are applied to cracking clay soils with underdrainage, and where rainfall soon after slurry application can increase surface runoff.The careful cycling of manures within a properly devised fertilizer plan should minimize the risk of unnecessary soil P enrichment and subsequent leaching losses by restricting topsoil extractable P levels to less than 70 mg I-1.

Notes: Abstract. Soil cores from river marginal wetlands in the UK, France and Ireland, sampled and contained within PVC piping, were flooded with nitrate-N enriched water. Half of the cores were sterilized prior to flooding to destroy the denitrifying bacteria. The change in nitrate-N concentration in the floodwater was measured over time. It is argued that the observed nitrate depletion rates (from 0.4 to 2.3 kg/ha per day) may be identified With microbially-mediated denitrification. The results show the method to be a simple and direct procedure for the assessment of spatial variation in nitrate-sink capacity. The depth of the denitrifying layer at the soil-water interface was confirmed to be of the order of a few mm.

Notes: Abstract. The stability of aggregates can be improved by amending the soil with charged synthetic polymers. We have evaluated the effects of addition of low rates of anionic polyacrylamide (PAM) on the stability of aggregates from three predominately kaolinitic soils, and investigated whether the applied PAM penetrated into the aggregates or was adsorbed onto exterior surfaces only. Aggregates (6.3–9.5 mm) from the Ap horizons of a Cecil sandy loam and a Cecil loamy sand (Typic Kanhapludult) and from the Bt horizon of a Davidson clay (Rhodic Kandiudult) were treated with a high molecular weight(2 × 107Da), negatively charged (20% hydrolysis) PAM at rates of 0, 10 or 20 kg/ha. The treated aggregate were dried and exposed to 20 mm of high kinetic energy (23.0 kJ/m3) simulated rain. Some of the PAM-treated Cecil loamy sand aggregates (5 or 10 kg/ha) were broken in half to expose untreated aggregate interiors to the rain. Percentage stable aggregates (weight/weight) in the PAM treatments ranged from 52 to 97%, vs. 20-32% in the control. PAM addition significantly increased the percentage of 〉4 mm sized aggregates compared with the untreated aggregates. PAM was more effective at stabilization in the light to medium textured Cecil soils than in the clayey Davidson. When internal surfaces of PAM treated aggregates were exposed, the percentage of stable aggregates exceeded the amount expected if the polymer was only adsorbed on to external surfaces. This suggested that some PAM had penetrated to some degree into aggregate interiors, thereby stabilizing both external and internal aggregates surfaces. Based on these results it is envisaged that use of PAM could be a viable alternative to the commonly used soil and water conservation practices (e.g. mulching, dyking, contour tillage).

Notes: Abstract. We report on a study aimed at assessing improvements in soil structure that developed when a reduced ground-pressure traffic system was introduced onto grassland previously compacted by conventional machinery traffic, and when a zero traffic system was introduced on land previously under a reduced ground-pressure system. Increases in the volume, average size, and number of macropores, measured by image analysis, together with decreases in vane shear strength indicated structural improvement in soil under the substitute traffic systems relative to the same soil in the original systems. A smaller content of organic matter in the soil of the substitute systems than in the original systems was attributed to improved aeration and greater earthworm activity in the former.

Notes: Abstract. The potential for degraded physical properties of soil to regenerate naturally after exclusion of grazing animals was examined at a long-term stocking rate trial near Armidale, New South Wales, Australia. Unsaturated hydraulic conductivity was measured before grazing was excluded, and after 7 months and 2.5 years’ grazing exclusion. These data were compared with controls grazed at 10,15 and 20 sheep/ha. After 2.5 years, there were significant increases in unsaturated hydraulic conductivity at 5 and 15 mm tension in the ungrazed treatments compared with the grazed controls. The unsaturated hydraulic conductivities and bulk density of surface soils under pasture which had been ungrazed for 2.5 years were comparable to those where the pasture had been ungrazed for 27 years. We speculate that the natural amelioration of soil physical properties in these soils was due to biological activity and wetting and drying cycles, in the absence of the compactive effect of animal treading.

Notes: Abstract. Nitrate leaching measurements in Denmark were analysed to examine the effects of husbandry factors. The data comprised weekly measurements of drainage and nitrate concentration from pipe drains in six fields from 1971 to 1991, and weekly measurements of nitrate concentration in soil water, extracted by suction cups at a depth of 1 m, from 16 fields in 1988 to 1993. The soils varied from coarse sand to sandy clay loam.The model used for analysing the data was: Y= exp (1.136–0.0628 clay+ 0.00565N +crop) D0.416, with R2= 0.54, where Y is the nitrate leaching (kg N/ha per y), clay is the % clay in 0-25 cm depth (%), N is the average N-application in the rotation (kg/ha/y) and D is drainage (mm/y). The most important factor influencing leaching was the crop type. Grass and barley undersown with grass showed low rates of leaching (17-24 kg/ha/y). Winter cereal following a grass crop, beets, winter cereals following cereals and an autumn sown catch crop following cereals showed medium rates of leaching (36-46 kg/ha/y). High rates of leaching were estimated from winter cereals following rape/peas, bare soil following cereals and from autumn applications of animal manure on bare soil (71-78 kg/ha/y). Estimates of leaching from soil of 5, 12 and 20% clay were 68, 44 and 26 kg/ha/y, respectively. Leaching was estimated to rise significantly with increasing amounts of applied N.The model is suitable for general calculations of the effects of crop rotation, soil type and N-application on nitrate leaching from sandy soil to sandy clay loarns in a temperate coastal climate.

Notes: Abstract. An examination of total phosphorus (TP) concentrations from 902 lakes in England, Scotland and Northern Ireland (NI), suggest that only Scottish lakes have a high percentage (73%) of oligotrophic waters (TP〈10 μg PI-1). The TP status of upland lakes in NI was greater than Scottish lakes particularly if lake catchments were afforested. Although lowland lakes in NI drain a predominately non-urbanized landscape, 38% of lakes below 100 m had TP concentrations 〉 100 μg PI-1 and only 29% 〈35 μg PI-1. English lakes tended to have higher TP concentrations (70% 〉 101 μg PI-1) which may reflect P inputs from sewage treatment works (STWs) although lakes draining agricultural catchments frequently produced high TP concentrations. Between 1985 and 1995, annual point source TP inputs to Loch Leven, Scotland, declined by 8 tonnes P or 40% of the 1985 TP loadings to the Loch. As point source inputs were proportionally richer in dissolved molybdate reactive phosphorus (MRP) than diffuse inputs, the MRP loading was reduced by 46%. From 1974 to 1995, TP concentrations in Lough Neagh (NI) increased despite reduced TP inputs from STWs. Partitioning of annual TP loadings from two major inflowing rivers to Lough Neagh, showed river MRP loadings from non-point sources had been increasing at annual rates of 1.9 and 2.3 kg P km-2. The remaining non-MRP river loadings had not been influenced by lower TP loads from STWs and showed no tendency to increase with time. Insufficient data is available from other lake systems in the British Isles to judge whether the increase in non-point source MRP loadings observed in the Lough Neagh catchment has been repeated elsewhere.

Notes: Abstract. Concentrations and annual loadings of molyhdate reactive P (MRP) and total (including particulate) P (TP) are reported from field drainage, catchment and erosion experiments in England. Annual losses through field drains and in catchment runoff were 0.037-0.74 kg MRP/ha and 0.37-2.64 kg TP/ha, but those in surface runoff from experimental plots measuring erosion were generally much greater (often 〉 3 kg MRP/ha and up to 32 kg TP/ha in a wet year). Amounts of TP in drainflow and catchment runoff depended upon factors influencing soil dispersibility, such as particle size distribution and calcium carbonate content. The results to date suggest that P losses in surface runoff and erosion from arable fields to water are best limited by: (a) maximizing crop cover, using minimal cultivation practices and where possible planting crop rows across rather than up and down the slope, (b) avoiding cultivation practices that result in dispersion of soil particles, and (c) avoiding application of P fertilizer to wet soils when rainfall is likely soon after application. Consideration should he given to maintaining field drains below peak efficiency to reduce subsurface P losses.

Notes: Abstract. The contribution non-point P sources make to the total P loading on water bodies in agricultural catchments has not been fully appreciated. Using data derived from plot scale experimental studies, and modelling approaches developed to simulate system behaviour under differing management scenarios, a fuller understanding of the processes controlling P export and transformations along non-point transport pathways can be achieved. One modelling approach which has been successfully applied to large UK catchments (50-350km2 in area) is applied here to a small, 1.5 km2 experimental catchment. The importance of scaling is discussed in the context of how such approaches can extrapolate the results from plot-scale experimental studies to full catchment scale. However, the scope of such models is limited, since they do not at present directly simulate the processes controlling P transport and transformation dynamics. As such, they can only simulate total P export on an annual basis, and are not capable of prediction over shorter time scales. The need for development of process-based models to help answer these questions, and for more comprehensive UK experimental studies is highlighted as a pre-requisite for the development of suitable and sustainable management strategies to reduce non-point P loading on water bodies in agricultural catchments.

Notes: Biot's poroelastic differential equations are modified for including matrix–fluid interaction mechanisms. The description is phenomenological and assumes a solid–fluid relaxation function coupling coefficient. The model satisfies basic physical properties such as, for instance, that P-wave velocities at low frequencies are lower than those predicted by Biot's theory. In many cases, the results obtained with the Biot (two-phase) modelling are equal to those obtained with single-phase elastic modelling, mainly at seismic frequencies. However, a correct equivalence is obtained with a viscoelastic rheology, which requires one relaxation peak for each Biot (P and S) mechanism. The standard viscoelastic model, which generalizes compressibility and shear modulus to relaxation functions, is not appropriate for modelling the Biot complex moduli, since Biot's attenuation is of a kinetic nature (i.e. it is not related to bulk deformations). The problem is solved by associating relaxation functions with each wave modulus. The equivalence between the two modelling approaches is investigated for a homogeneous water-filled sandstone and a periodically layered poroelastic medium, alternately filled with gas and water. The simulations indicate that, in the homogeneous case, particle velocities in the solid skeleton, caused by a source applied to the matrix, are equivalent to viscoelastic particle velocities. In a finely layered medium, viscoelastic modelling is not, in principle, equivalent to porous modelling, due to substantial mode conversion from fast wave to slow static mode. However, this effect, caused by local fluid-flow motion, can be simulated by including an additional relaxation mechanism similar to the squirt-flow.

Notes: An algorithm for modelling and migrating ground penetrating radar (GPR) data in moderately heterogeneous dispersive media is presented. The method is based on wavefield extrapolation in the frequency–wavenumber (f–k) domain, from the solution of the 2D Maxwell's equations. The wavefield is extrapolated by a phase-shift technique using a constant relative permittivity K and a quality factor Q. It is then modified by a correction term to handle the lateral K and Q variations. The spatial distribution of the K and Q-factor values, representing the given model parameters, is introduced into the algorithm by a regular grid parametrization. The radar wave dispersion and attenuation, induced by relaxation processes, are taken into account by a linear frequency-dependent Q model, and expressed by a complex wavenumber in the propagation equation.A synthetic case and a field data set illustrate the potential of the method for frequencies of 300, 500 and 900 MHz. In the first case, a typical civil engineering problem is considered. The frequency dependence of the wave velocity and attenuation is well illustrated. The synthetic data are afterwards migrated using the initial model parameters. The results show the importance of using spatially varying model parameters in the migration processes. The second case concerns an application of the method to a real data set. In order to adjust the model parameters, a forward modelling sequence is performed until the best match between the measured and the synthetic data is achieved. A depth migration is then applied to the data, and the result is compared with the initial model parameters.In conclusion, we assess the contributions of the method to industrial applications, by discussing the performance of the algorithm compared with its limitations.

Notes: Vibroseis data recorded at short source–receiver offsets can be swamped by direct waves from the source. The signal-to-noise ratio, where primary reflections are the signal and correlation side lobes are the noise, decreases with time and late reflection events are overwhelmed. This leads to low seismic resolution on the vibroseis correlogram. A new precorrelation filtering approach is proposed to suppress correlation noise. It is the ‘squeeze-filter-unsqueeze’ (SFU) process, a combination of ‘squeeze’ and ‘unsqueeze’ (S and U) transformations, together with the application of either an optimum least-squares filter or a linear recursive notch filter. SFU processing provides excellent direct wave removal if the onset time of the direct wave is known precisely, but when the correlation recognition method used to search for the first arrival fails, the SFU filtering will also fail. If the tapers of the source sweeps are badly distorted, a harmonic distortion will be introduced into the SFU-filtered trace. SFU appears to be more suitable for low-noise vibroseis data, and more effective when we know the sweep tapers exactly. SFU requires uncorrelated data, and is thus cpu intensive, but since it is automatic, it is not labour intensive.  With non-linear sweeps, there are two approaches to the S,U transformations in SFU. The first requires the non-linear analytical sweep formula, and the second is to search and pick the zero nodes on the recorded pilot trace and then carry out the S,U transformations directly without requiring the algorithm or formula by which the sweep was generated. The latter method is also valid for vibroseis data with a linear sweep. SFU may be applied to the removal of any undesired signal, as long as the exact onset time of the unwanted signal in the precorrelation domain is known or determinable.

Notes: Accurate well ties are essential to practical seismic lithological interpretation. As long as the geology in the vicinity of the reservoir is not unduly complex, the main factors controlling this accuracy are the processing of the seismic data and the construction of the seismic model from well logs. This case study illustrates how seismic data processing to a near-offset stack, quality control of logs and petrophysical modelling improved a well tie at an oil reservoir. We demonstrate the application of a predictive petrophysical model in the preparation and integration of the logs before building the seismic model and we quantify our improvements in well-tie accuracy. The data for the study consisted of seismic field data from a 3D sail line through a well in a North Sea oilfield and a suite of standard logs at the well. A swathe of fully processed 3D data through the well was available for comparison. The well tie in the shallow section from first-pass seismic data processing and a routinely edited sonic log was excellent. The tie in a deeper interval containing the reservoir was less satisfactory: the phase errors within the bandwidth of the seismic wavelet were of the order of 20°, which we consider too large for subsequent transformation of the data to seismic impedance. Reprocessing the seismic data and revision of the well-log model reduced these phase errors to less than 10° and improved the consistency of the deep and shallow well ties. The reprocessing included densely picked iterative velocity analysis, prestack migration, beam-forming multiple attenuation, stacking the near-offset traces and demigration and remigration of the near-offset data. The petrophysical model was used to monitor and, where necessary, replace the P-wave sonic log with predictions consistent with other logs and to correct the sonic log for mud-filtrate invasion in the hydrocarbon-bearing sand. This editing and correction of the P-wave transit times improved the normal-incidence well tie significantly. The recordings from a monopole source severely underestimated the S-wave transit times in soft shale formations, including the reservoir seal, where the S-wave velocity was lower than the P-wave velocity in the drilling mud. The petrophysical model predicted an S-wave log that matched the valid recordings and interpolated between them. The subsequent seismic modelling from the predicted S-wave log produced a class II AVO anomaly seen on the CDP gathers around the well.

Notes: We design a velocity–porosity model for sand-shale environments with the emphasis on its application to petrophysical interpretation of compressional and shear velocities. In order to achieve this objective, we extend the velocity–porosity model proposed by Krief et al., to account for the effect of clay content in sandstones, using the published laboratory experiments on rocks and well log data in a wide range of porosities and clay contents.The model of Krief et al. works well for clean compacted rocks. It assumes that compressional and shear velocities in a porous fluid-saturated rock obey Gassmann formulae with the Biot compliance coefficient. In order to use this model for clay-rich rocks, we assume that the bulk and shear moduli of the grain material, and the dependence of the compliance on porosity, are functions of the clay content.Statistical analysis of published laboratory data shows that the moduli of the matrix grain material are best defined by low Hashin–Shtrikman bounds. The parameters of the model include the bulk and shear moduli of the sand and clay mineral components as well as coefficients which define the dependence of the bulk and shear compliance on porosity and clay content. The constants of the model are determined by a multivariate non-linear regression fit for P- and S-velocities as functions of porosity and clay content using the data acquired in the area of interest.In order to demonstrate the potential application of the proposed model to petrophysical interpretation, we design an inversion procedure, which allows us to estimate porosity, saturation and/or clay content from compressional and shear velocities.Testing of the model on laboratory data and a set of well logs from Carnarvon Basin, Australia, shows good agreement between predictions and measurements. This simple velocity-porosity-clay semi-empirical model could be used for more reliable petrophysical interpretation of compressional and shear velocities obtained from well logs or surface seismic data.

Notes: Following a previous paper in which the principles of a 3D ground-surface tomographic processing of self-potential data were established, we extend the method to active source geoelectric surveying. The main purpose of the new tomographic approach is to obtain a physical image reconstruction of the induced electric charges distributed over buried resistivity discontinuities. The information is produced in a probabilistic sense, as the mathematical formulation underlying the method treats only the intrinsic physical nature of the generated electric field underground and the method of its ground-surface detection, independently of the geometry of the unknown structures. In practice, a 3D tomography is realized by cross-correlating a set of distributed electric-field ground-surface data with a scanning function, representing a unit positive point charge located anywhere in the lower half-space. The resolution of the method is tested on the synthetic response of a 3D structural simulation of an archaeological target, consisting of an infinitely resistive prismatic body immersed in a half-space, including surface inhomogeneities and layering. Finally, the field response of a 3D structure consisting of a hypogeal dromos-chamber tomb inside the Sabine Necropolis at Colle del Forno, close to Rome, is presented and discussed.

Notes: A guided wave along a borehole is often observed in borehole radar measurements. These guided waves deform the antenna pattern and can cause artefacts in radar measurements. A water-filled borehole or a conducting logging cable can function as a waveguide for electromagnetic waves under some conditions. We describe the theoretical characteristics of such a guided wave in a borehole and compare them with our experiments. The measured signal discussed was obtained with a directional borehole radar. This radar uses a cylindrical conformal array antenna as receiver and is a model of a conducting structure in a borehole. The induced field around the borehole was compared with the theory. The most fundamental symmetrical and asymmetrical modes were TM01 and HE11, and they were identified in the measured signals using time–frequency distribution analysis and by observation of the azimuthal field distribution of the magnetic field.

Notes: The electrical method presented is used for determining the resistivity of lake-bottom sediments and is based on the d.c. electrical sounding principles. The electrode array, called the fishing rod (FR), is of pole-pole type and is orientated vertically on a line perpendicular to the surface of the water. The technique is used for mapping resistivity anomalies located deep underwater. This paper presents an analysis of the resolution capabilities of the FR method and the results of a case study carried out in Lake Geneva, where measurements were interpreted using a one-dimensional (1D) multilayer earth model. The analysis of the uncertainty in the model parameters of a 1D multilayer earth model is carried out using the covariance matrix of the linearized inversion problem. The results of the analyses show that when the thickness and resistivity of the water layer is known, the resistivity of the sediment layer is well determined under most circumstances. The thickness of the sediment layer is well determined when resistivity contrasts are not too low. In Lake Geneva the FR method has been used to study an old depression with a resistive channel. This application shows the efficiency of the method compared with conventional electrical methods, where water depth becomes a limiting factor. The use of an automated iterative inversion scheme in this particular case is advantageous, as a joint interpretation of the three different data sets measured with the FR method can be carried out. Finally, the result of the inversion is compared with the trial-and-error interpretations of a previous study.

Notes: Minimum variance unbiased (MVU) beamforming is a type of multichannel filtering which extracts coherent signals without distortion, whilst minimizing residual noise power. Adaptive beamforming estimates signal and noise characteristics as part of the extraction process. The adaptive beamformer used here is designed from models of primary and multiple reflection signals having parametrically specified moveout and amplitude variation with offset (MVO and AVO). Phase variation with offset (PVO) can also be included but it is not usually justified in practice. The resulting analysis provides data for input into AVO and PVO schemes for obtaining lithological information. Synthetic data examples illustrate details of implementation of parametric adaptive MVU beamforming and the response characteristics of the resultant design. Real data examples show that data-adaptive beamforming is more flexible and more effective in attenuating multiples in prestack common-midpoint seismic data than Radon transform methods. In common with other prestack multichannel processes, the advantages of beamforming are shown to best effect in data with a good signal-to-noise ratio.

Notes: Known mineral occurrences in northern Vancouver Island are typically hosted in volcanic units of the Bonanza Group. At a local scale, the mineralization is associated with advanced argillic bedrock alteration and is often intimately related to porphyry intrusions. On a larger scale, faults are thought to exert the most significant control on the distribution of mineralized host rocks. Poor exposures and a complex glacial history limit the use of traditional methods of geological mapping and mineral exploration in this region and to date geophysical methods have been under-utilized. Here we present findings from four standard geophysical (gravity, magnetics, electromagnetics and seismic refraction) methods, recently deployed here to elucidate the subsurface geology, as well as to identify new targets for base metal exploration.Results at two different sites show that the integrated interpretation of geophysical data, constrained by physical rock property measurements, yields detailed images of the subsurface at a fraction of the cost of drilling. At one site, east of Rupert Inlet, the final subsurface model shows that the Bonanza Group is not nearly as extensive as previously presumed. An extension of the Holberg Fault is identified some 50 km east of the visibly mapped outcrop and an extensive zone of alteration around the fault is recognized. Furthermore, a number of the methods provide support for the existence of a porphyry dike at this site. At the second site, north of Rupert Inlet, magnetic and electromagnetic data prove effective at mapping alteration and locating shear zones beneath a relatively thin drift cover. Together, these results help outline a strategy for exploration in drift-covered terrains and show that a redirection of exploration effort is warranted in the case of northern Vancouver Island.

Notes: This study explores the use of multiple isotopic tracers to evaluate the processes involved in nitrate attenuation in ground water. δ15N and δ18O are used to provide information about the role of denitrification on nitrate attenuation, and δ34S, δ18O, and δ13C are used to evaluate the role of reduced sulfur and carbon as electron donors for nitrate reduction. The focus of this study is a zone of significant NO3−1 attenuation occurring in a sand aquifer impacted by septic system contamination. The NO3−1 pattern, the ground water flow system, and changes in other chemical parameters suggest that the NO3−1 depletion is caused by denitrification. This is supported by the nitrate δ15N and δ18O data which both show significant isotopic enrichment as NO3−1 depletion proceeds along the flow path. The increase of sulfate and dissolved inorganic carbon observed in the zone of nitrate attenuation suggests that reduced sulfur in addition to carbon is also involved in denitrification. This is supported by a trend toward depleted sulfate δ34S and δ18O values in the zone of sulfate increase, which reflects the input of sulfate formed by the oxidation of biogenic pyrite present in the aquifer sediments. The trend toward depleted δ13 values in the zone of increasing dissolved inorganic carbon reflects the input of organic carbon into this carbon pool. Chemical mass balance indicates that carbon is the dominant electron donor; however, this study demonstrates the effectiveness of using multiple isotopic tracers for providing insight into the processes affecting nitrate attenuation in ground water.

Notes: The objective of this study is to assess the effects of variable density ground water flow on capture zones for pumping wells on islands and the ability of numerical and analytical methods to account for these effects. Mathematical modeling is used to simulate variable density ground water flow for an island aquifer system. Coupled fresh water-salt water transport equations derived using sharp interface theory are solved using the finite-element method. Reverse particle tracking is used to compute the capture zone for a well. Sensitivity studies are completed using a quasi-three-dimensional model to identify the influence of variable density flow on the computed zone of contribution to a pumping well. Quantitative results indicate that the size and shape of the capture zone are sensitive to the natural geometry of the fresh water lens and the effects of fresh water-salt water upconing. This is especially true for pumping wells located close to the coastline. For the conditions considered in this study, accounting for variable density ground water flow resulted in capture zones approximately 21% larger than those predicted assuming a uniform fresh water aquifer thickness and constant hydraulic gradient. This effect of variable density flow on the predicted capture zones diminished away from the coastline. The study results serve to caution model users of the limitations inherent in using analytical methods to compute capture zone delineations for island aquifers.

Notes: In suitable cases, digital filtering of self-potential anomalies produces images of the water table. Two hypothetical cases and four field examples from New Hampshire yield images in reasonable agreement with known water tables. Filtering for a sheet of dipolar sources (that is, the water table) would be a useful addition to routine interpretation of self-potential data.

Notes: Xylene was spilled onto moist glass beads or various moist sands and water was trickled onto the columns every eight hours for periods up to 10 days. The xylene residual in the columns with water infiltration decreased compared to those of control columns, indicating a downward displacement of xylene. The extent of displacement increased with increasing size of the porous media and with increasing amounts of water infiltration.

Notes: As a well is pumped through time, concentrations of specific constituents in the water discharging from the well may change as a result of their transport within the well and the aquifer. A series of experiments conducted at a research site on Cape Cod, Massachusetts, examined the effects of transport on the chemistry of water samples obtained from a long-screened well. Analyses of time series of constituent concentrations in water pumped from the long-screened well showed persistent temporal trends during the first experiment. Iron concentrations decreased over a five-hour test (15 casing volumes), whereas the calcium and magnesium concentrations increased. In contrast, the time series of constituent concentrations of water discharging from the same well showed less change with time during a later experiment. Numerical simulations were undertaken to test the relative importance of several possible factors affecting the temporal variations of these constituents. During the process of quantitatively explaining the changes in concentrations over time observed in the two experiments, different system conceptualizations were used, including (1) flow and transport in the aquifer without wellbore transport, (2) flow and transport in the aquifer with advective flow and transport in the wellbore, and (3) flow and transport in the aquifer with advective flow and transport in the wellbore and a thin layer (skin) of water surrounding the well with constituent concentrations that had been altered by the presence of the well. The conjectured skin of wellbore water, which could have invaded the aquifer because of nearby sampling or dispersion and diffusion near the wellbore, in conjunction with flow and transport in the aquifer and advective transport within the wellbore, produced a reasonable match between the simulated and observed concentrations. The data analysis confirms the known fact that long-screened wells provide mechanisms for the redistribution of chemical constituents in the aquifer. The analysis provides new insight into the mechanisms responsible for the observed changes in concentrations during the sampling of long-screened wells. The analysis quantifies the effects of the various conceptual models of flow and transport in and around wells on the interpretation and meaning of chemical analyses of water withdrawn from long-screened wells.

Notes: The migration of a DNAPL (TCA) was demonstrated by a laboratory flow visualization experiment. The system consists of two unconfined aquifers separated by a siltstone perching layer containing a single fracture that conducts water flow downward. The TCA migrated along a tortuous path in the upper sandy aquifer and moved rapidly through the fracture. We observed no DNAPL pooling above the fracture prior to its entry into the fracture, in contrast to existing mathematical solutions of hydrostatic initial conditions and full saturation below the fracture. A multiphase flow model predicted the experimentally observed mean behavior.

Notes: The concentrations of tritium, helium isotopes, and neon have been measured in ground water from a fractured bedrock aquifer in a densely populated suburban area near New York City. Samples were obtained from heavily pumped production wells of a regional water supply company. Helium and neon concentrations exceed the values for air-saturated water, which is explained by the addition of unfractionated atmospheric air, radiogenic helium, and tritiogenic 3He. The identification of the composition of these excess components allows reliable separation of the tritiogenic 3He concentration, and hence the calculation of the 3H/3He ages of the ground water. Comparison of the combined tritium plus tritiogenic 3He concentrations with the historical record of tritium input from precipitation confirms that the 3H/3He data are self-consistent and provides constraints on the degree of mixing or helium loss. The distribution of 3H/3He ages is related to the large-scale topography of the study area and the depth of the wells. Furthermore, correlations between the 3H/3He ages and concentrations of total dissolved solids and total CO2 show that the ages contain meaningful information related to the temporal changes of the ground water chemistry.

Notes: Nitrogen isotope ratios of soil water and ground water nitrate have been used to identify or implicate sources; however, lack of data on δ15N in thick (〉12 m) vadose zones beneath the source and potential effects of denitrification on δ15N signatures have raised questions about the meaning of δ15N values measured in ground water. In this study, nitrogen isotope ratios (δ15N) were measured on nitrate extracted from 218 core samples removed from the surface to the water table below natural (soil organic matter) fertilizer, onsite sewage disposal systems (septic tank effluent), and animal sources located in Salinas and Sacramento Valleys, California. Additionally, spatial variability of δ15N in the horizontal plane was measured beneath an agricultural field, and δ15N values of native geologic materials (organic-rich shales) were determined. In general, δ15N values throughout the vadose zone were consistent with the literature and remained fairly constant with depth, indicating little denitrification during transport. The δ15N values from soil organic matter sources varied from about 0 to +4‰, and the mean was not significantly different from that of fertilizer sources. The δ15N values of animal sources varied from about +8 to +20‰ and were dependent on site and animal source. The δ15N of onsite sewage disposal sources varied from about +2 to +12‰, and the mean was significantly different from that of animal sources at a 90% confidence level. δ15N of organic-rich shales of the Panoche and Moreno Formations (Cretaceous; San Joaquin Valley) and soils derived from these rocks were generally between +4 and +8‰. Thus, it may be difficult to distinguish a geologic-N source from septic tank or commercial fertilizer sources using δ15N. Little spatial variation was found in δ15N beneath the agricultural field in the horizontal plane.

Notes: In this study, we investigate the degree to which climate-induced changes in hydraulic head can affect the stress regime and hydraulic conductivity of fractured aquifers. The effects of stress changes on conductivity are well-known, but not usually considered in the analysis of ground water systems because of the misconception that the head change necessary to make a measurable impact is beyond the range of normal head fluctuations.An empirical model relating changes in hydraulic conductivity of fractured aquifers to vertical-effective stress was used in analyzing the effects of pore pressure changes on conductivity. An analysis showed that for realistic head changes (20 to 100 m), conductivity in an unconfined system can change as much as 20 to 30%. The analysis also showed that for a given head increase, increases in conductivity are greatest at shallow depths and that conductivity is a function of both hydraulic head and the relative position of head to the land surface. Maximum conductivity changes occur when the initial pore pressure is a relatively large percentage of the total stress. Similar results were also obtained in confined systems.Field examples demonstrate that large head changes have occurred in bedrock aquifers due to climatic changes and pumping withdrawals. Thus, large head changes needed to make a measurable impact on hydraulic conductivity are quite plausible. Conductivity changes can in turn lead to changes in calculated ground water flow and solute transport rates. As a result, when significant head changes are expected, changes in conductivity should be considered in the analysis of fractured aquifer systems.

Notes: The in situ measurement of water flow and chemical transport through clay pan soils is crucial to understanding potential water contamination from agricultural sources. It is important due to the large areal extent of these soils in agricultural regions of the midwestern United States and because of preferential flow paths caused by desiccation cracks, worms burrowing, and root development. A study plot at the Missouri Management Systems Evaluation Area near Centralia, Missouri, was instrumented to determine the rate of preferential flow of water and transport of NO3−1 fertilizer in the unsaturated zone through a claypan soil using 15N-NO3−1 and Br-1 tracers. The areal distribution of preferential flow paths was between 2 and 20% in the topsoil. Gravity lysimeter flow caused by preferential flow through the claypan was as much as 150 times greater than the estimated average rate of vertical recharge. As much as 2.4% of the volume of the soil below the clay pan may be occupied by preferential flow paths.The 15N-NO3−1 concentrations in ground water indicate that substantial quantities of fertilizer-derived NO3−1 were transported to ground water through the claypan during the first recharge event following fertilizer application even though that event occurred six months after application. Hydraulic conductivity, measured at three scales, ranged from 6.2 × 10−8 to 7.5 × 10−3 cm/s. The observed increase of calculated hydraulic conductivity with each increase in scale was attributed to the inclusion of more and larger preferential flow paths within the volume over which the measurement was made, indicating hydraulic conductivity measured at one scale may not describe flow and transport at another scale.

Notes: A dipole probe (DP) for measuring vertical variations of hydraulic conductivity has been designed, constructed, and tested in field conditions. The variable-length device designed for the dipole flow test (DFT) consists of three packers separated by changeable spacer rods. The assembled DP is lowered into a well with a long screened interval. The packers are inflated, isolating two screened sections (chambers) between them. A small submersible pump, mounted on the central packer, transfers water from the upper (extraction) chamber into the lower (injection) chamber. This simultaneous injection and extraction creates a recirculatory flow within the aquifer. The chamber head responses are measured by two pressure transducers in the DP chambers. The DP can be used at discrete intervals along the entire well screen length. The DP has been successfully tested in a specially constructed well with a continuous screen in a highly conductive sand and gravel aquifer. During drilling, disturbed samples were collected using the split spoon method and the vertical profile of K was estimated from grain-size analysis. A total of 153 DFTs were performed with various DP geometries. Results indicate that the chamber head changes are sensitive to aquifer properties, reach steady state rapidly, vary linearly with redrculation pumping rate, and can be controlled by changes in DP dimensions. Vertical profiles of K compare well with grain-size analysis estimates.

Notes: An extensive drilling and testing program was undertaken at Carleton University, Ottawa, Canada, to characterize the aquifer for the design of an aquifer thermal energy storage (ATES) system. The substantial data base provides an excellent record of well yields and hydraulic responses to a series of aquifer tests in a faulted carbonate aquifer. Well yield variability is reflected in the wide range in specific capacity (1.4 to 75.8 L/s/m) and is dependent upon the proximity of a well to a major fault. Constant discharge data, available for nine pumping wells and several observation wells, reflect both the excellent hydraulic connection along major faults and the limited hydraulic connection between fault blocks. Three different flow models, including vertical fracture and vertical dyke (linear), and Theis (radial), are used to interpret constant discharge test data from nine pumping wells and several observation wells. In all tests, the duration of pumping is sufficient to identify early-time linear flow along faults and late-time pseudo-radial flow between fault blocks. This paper demonstrates the influence of fault-induced heterogeneity on the hydraulic response of a carbonate aquifer and demonstrates the application and limitation of simple radial continuum models to aquifers of this type.

Notes: This paper develops a geoelectrical and geostatistical-based methodology that can be used to screen unregulated landfills for the presence of leachate and obtain an approximation of the vertical/spatial extent of waste. The methodology uses a surface electromagnetic (EM) survey combined with indicator kriging. Indicator kriging allows for the use of EM data that have been collected over highly electrically conductive material such as that occurring within landfills. Indicator kriging maps were generated for several vertical sections cut through a landfill to establish the landfill strata. Similarly, horizontal sections were generated to evaluate the areal extent of waste and leachate in the vadose zone and saturated zones, respectively. The horizontal and vertical maps were combined to estimate the volume of solid waste and liquid within three zones: (1) waste, (2) waste and/or leachate, and (3) potential leachate. The methodology appears hold promise in providing results that can be used as part of a hazard assessment, or to assist in the placement of monitoring wells at sites requiring additional study. A case study is used to demonstrate the methodology at an unregulated landfill in eastern Nebraska.

Notes: The results of field tracer experiments performed in the Lindau fractured rock test site (southern Black Forest, Germany) and subsequent modeling are presented. A vertical, hydrothermally mineralized fault zone, with a permeability much greater than the surrounding granite mass, lies beneath a planned dam site. A dense network of boreholes and tunnels were used to investigate scaling effects of solute transport processes in fractured rock. A series of tracer experiments using deuterium and dye tracers (uranine, eosine, and pyranine) were performed over varying distances and under different testing procedures, resulting in different flow field conditions. Large-scale tracer experiments (21 to 346 m) were performed under natural flow field conditions, while small-scale tracer experiments (11 to 16 m) were performed under artificially induced radial-convergent and injection-withdrawal flow fields. The tracer concentration curves observed in all experiments were strongly influenced by the matrix diffusion. The curves were evaluated with the one-dimensional single fissure dispersion model (SFDM) (advective-dispersive transport in the fractures coupled with diffusive transport in the adjacent rock matrix) adjusted for the different flow field conditions. The fitting model parameters found determined the fracture aperture, and matrix and fissure porosities. The determined fracture aperture varied between the sections having different hydraulic conductivities (100 to 270 um and 430 to 580 um, respectively). The determined values of matrix porosity (3 to 7%) seemed to be independent of the scale of the experiment. The modeled matrix porosities agreed well with values determined in independent laboratory investigations of drill cores using mercury porosimetry. In situ fissure porosity, determined only in small-scale experiments, was independent of the applied geometry of the artificially induced flow fields. The dispersivities were found to be independent of the scale of experiment but dependent on the flow conditions. The values found in forced gradient tests lie between 0.2 and 0.3 m, while values in experiments performed under natural flow conditions were one order of magnitude higher.

Notes: Federal efforts to establish reliable natural disinfection criteria for ground water supplies require the identification of appropriate indicator viruses to represent pathogenic viruses and an understanding of parameters affecting virus survival and transport in a variety of hydrogeologic settings. A high school septic system and the associated fecal waste-impacted unconfined sand and gravel aquifer were instrumented to: (1) evaluate if the concentrations of enterovirus and coliphage in this system were sufficient to allow their use as indicator viruses; (2) establish viral transport rates, transport distances, and concentrations in a highly conductive cold water aquifer. Enteroviruses were found in only two of eight assays of the septic tank effluent (0.26 and 4.4 virus/L) and were below detection in eight ground water samples. Male-specific and somatic coliphage were detectable in both the septic tank effluent (averaging 674,000 and 466,000 coliphage/L, respectively) and in the impacted underlying ground water, decreasing to detection limits beyond 38 m of the drainfield. Virus transport parameters in this aquifer were measured by seeding high numbers of MS2 and ØX174 coliphage into the ground water and documenting their transport over 17.4 m. A portion of the seeded virus traveled at least as fast as the bromide tracer (1 to 2.9 m/d). Proposed natural disinfection criteria would not be met in this aquifer using standard 30.5 m setback distances. In addition, the virus sorption processes and long survival times resulted in presence of viable seed virus for more than nine months.

Notes: In the glacial topography of southwestern Michigan, the water table does not always conform exactly to the land surface and flow-through wetlands, those with both ground water recharge and discharge, are common. The W-l wetland in Cass County, Michigan, a flow-through system, shows a distinct contrast between upgradient and downgradient ground water quality. Ground water discharging into the wetland is oxic, has up to 40 mg/L NO3-N derived from fertilizer and hog manure application to corn fields, and has major ion concentrations typical of the shallow unconfined aquifer in the area. In contrast, shallow ground water that originates as recharge from the wetland forms a plume extending downgradient that can be identified by isotopic enrichment in 18O and deuterium resulting from evaporation in the wetland prior to recharge and by distinct chemical characteristics similar to the wetland surface water (low conductivity and alkalinity, low concentrations of sulfate, nitrate and dissolved oxygen and high concentrations of ammonia, and DOC). As the wetland surface water infiltrates into the unconfined aquifer, conductivity and alkalinity increase due to carbonate mineral dissolution and iron concentrations increase as ferric iron in the aquifer solids serves as an electron acceptor in microbially mediated reactions. The other chemical characteristics, including the lack of nitrate, persist in the flow system for significant distances downgradient from the wetland.The chemical and isotopic composition of shallow ground water around wetlands can be used to spatially delineate areas of ground-water discharge to the wetland and ground water recharge from the wetland, thereby providing a supplemental method to the use of sometimes inconclusive hydraulic head data in the determination of wetland recharge-discharge function. In this study, the chemical and isotopic data confirm that the water table does not replicate surface topography around closed depressions in the landscape.