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  • Articles  (180)
  • Blackwell Publishing Ltd  (180)
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  • 1997  (180)
  • Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics  (180)
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  • Articles  (180)
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  • 1995-1999  (180)
  • 1990-1994
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  • 1925-1929
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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: X-ray diffraction (XRD) patterns from nominally β-SiC specimens often differ from those expected for the cubic crystal structure. These differences include the presence of additional peaks, enhanced background intensities, peak broadening, changes in relative peak heights, and shifts in peak positions. It has long been recognized that they are due to the presence of stacking faults, and models relating the experimental observations to stacking fault population have continued to evolve. The presence and relative magnitude of these features vary among different β-SiC specimens. In this work, computer simulations were used to show that the variations are closely related to differences in the type and spatial distribution of stacking faults in each specimen. In these simulations, stacking sequences were generated using a selectively activated 1-D Ising model with a Boltzmann-type probability function for specifying errors, which allows a wide variety of fault configurations to be generated. Direct correlations between different features in the XRD data to the underlying fault population are demonstrated, which are discussed in this paper. It is also shown that this computer model is general, in the sense that many of the models presented in prior work can be interpreted as limiting cases of it.
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Using the technique of fluorescence piezospectroscopy, we determine the distribution of thermal residual stresses across the edges of three laminated alumina/zirconia composites. We develop a methodology for separating the measured stress state into microstresses that result from grain-to-grain thermal mismatch and macrostresses that result from lamination-induced thermal mismatch between individual plies. Comparison between the measured edge-stress distributions and those calculated based on a simple force-superposition model shows good agreement, indicating that the laminate system is well approximated as linear elastic. Given the experimental confirmation of significant edge stresses in multi-ply laminates, the possibility of failure initiating at composite edges must be considered in the design of surface-compressed laminate structures with the aim of mediating the detrimental effect of surface flaws.
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Local laser-induced oxidation of thin titanium films on glass is shown to be self-limiting due to a decrease in the absorptivity during the reaction. Taking advantage of this confinement, stable writing of transparent oxide line structures narrower than the diffraction-limited focused spot of a continuous wave Ar ion laser (500 nm) has been accomplished. The greatest optical contrast (1:10) with the highest resolution down to 165 nm was observed if the film thickness is of the order of the light absorption length in the metal.
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Multilayered composites consisting of LaPO4 (La-monazite) layers alternating with various ZrO2-based materials were fabricated to investigate whether LaPO4 provides a weakly bonded interface suitable for promoting toughening, as previously observed in the system LaPO4/Al2O3. The following ZrO2-based materials were assessed: Y-ZrO2, Y-ZrO2/Al2O3, Ce-ZrO2, and Ce-ZrO2/Al2O3. Debonding was observed in all cases. The composites containing Y-ZrO2 and Y-ZrO2/Al2O3 were stable, with no reactions, at temperatures up to at least 1600°3C. However, in the composites containing Ce-ZrO2, interdiffusion of Ce and La occurred, resulting in formation of a pyrochlore-like phase and, in the case of the Ce-ZrO2/Al2O3 composite, a (Ce,La)Al11O18 magnetoplumbite phase.
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Copper/niobium multilayers prepared by sputtering onto Si substrates with layer thicknesses ranging from 11 to 5000 Å have been characterized by transmission electron microscopy and nanoindentation. The films are strongly textured with {110} close-packed planes of the bcc Nb parallel to the {111} close-packed planes of the fcc Cu and close-packed directions tending to be parallel as well. For the 11 Å layers, the Cu is found to grow pseudomorphically on Nb in the bcc structure. It is thought that, for thicker layers, the bcc Cu loses coherency and transforms martensitically to the fcc phase, thus resulting in the observed Kurdjumov—Sachs orientation relationship. As the layer thickness, d, decreases from 5000 to 500 Å, the hardness increases as d-1/2; i.e., it follows a Hall—Petch relationship so that hardening is due to grain boundaries and interfaces. The slope is the same as in pure Cu, but there is a large intercept which is ascribed to internal stresses and a large dislocation density. As the layer thickness decreases from 100 to 11 Å, the hardness increases as (1/d) ln (0.69d), which is a line tension formulation such as would be expected for Orowan dislocation bowing between the layers. Again there is a large intercept which is ascribed to cutting through the Cu/Nb interfaces. The interfacial energy is calculated to be 0.46 J/m2.
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  • 6
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Aqueous Zr-nitrate solutions containing appropriate amounts of Fe(NO3)3·6H2O and Al(NO3)3·6H2O were used to synthesize ZrO2-Fe2O3 compositions (up to 40 mol% Fe2O3) and one ZrO2-Al2O3-Fe2O3 composition. An amorphous phase was produced after pyrolysis, which subsequently crystallized to a single-phase Zr(Fe)O2 solid solution (or Zr(Fe,Al)O2 ss) that appeared cubic by X-ray diffraction, but tetragonal (c/a→ 1) by electron diffraction. The crystallization temperature increased with Fe2O3 content. At higher temperatures, the single phase partitioned to two phases, tetragonal-ZrO2+γ-Fe2O3. The γ- to α-Fe2O3 transformation occurred at still higher temperatures to produce a two-phase microstructure composed of two interpenetrating phases (ZrO2+α-Fe2O3), each with equiaxed grains. This microstructure was relatively stable to grain coarsening, even to temperatures just below the apparent eutectic temperature. With the exception of the lower transition temperatures and the equiaxed grains observed for both phases, these observations are similar to that previously reported for the ZrO2-Al2O3 system. The microstructure development reported here is another example for the synthesis via solution processing that involves diffusion-limited crystallization. Namely, a two-phase material can be produced where the grain size of each can be very small, and can be prevented from growing rapidly at high temperatures due to the constraint of each phase on one another.
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  • 7
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: High-temperature creep behavior of yttria fully stabilized zirconia single crystals with various yttria contents in the interval 9.4 ≤x≤ 21 mol% has been studied. The mechanical data have been collected as a function of both the temperature and the yttria concentration. The creep behavior has been explained in terms of a transition between a dislocation viscous glide and a dislocation climb controlled mechanism, making use of a generalized version of a classical model for alloys proposed by Burton. The yttria concentration dependence of the creep rate has been connected with results on cationic diffusivity, with a possible influence of impurities.
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  • 8
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The examination of natural materials at the microscopic and microchemical level from a materials science perspective can occasionally suggest advances in modern materials engineering. The present paper reports on such a case: an analytical study of the detailed structure and composition of sea urchin teeth.
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  • 9
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Compression tests of single crystals are analyzed with respect to shear due to the friction at the loaded ends. This simple approach permits an explanation of the features associated with prism plane slip in sapphire (α-Al2O3), i.e., the shape changes of the specimens and the curvature of the glide planes.
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  • 10
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The microstructure of polydomain tetragonal zirconia (t-ZrO2), i.e., a ZrO2 modification exhibiting ferroelastic behavior, is studied by high-voltage electron microscopy. This material consists of three domain variants of the tetragonal phase with their c-axes nearly orthogonal to each other. Always two variants of these platelike domains are alternately arranged, forming elongated regular colonies. Hence, in both variants the common habit plane of the domains is a {110} twin plane. The colonies are of columnar shape with a longitudinal axis. They are bound by {110} planes, too, which are twin planes for the domains in the contiguous colonies. Owing to their particular structure and the helical arrangement of the adjoining colonies, the material remains coherent and pseudocubic over large macroscopic regions, although it is formed by different tetragonal domains.
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  • 11
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The ferroelastic deformation of t-ZrO2, the microstructure of which was described in detail in Part I, was investigated by in situ deformation experiments in the high-voltage electron microscope at 1150°3C. During the experiments those two domain variants with their c-axes perpendicular to the [010] tensile direction were transformed into the third one with its c-axis parallel to the tensile direction. The subsequent ‘switching’ of the domains inside the colonies proceeds much faster than the penetration of the transformation front into a neighboring colony. Therefore, the transformed region, exhibiting a unique tetragonal structure and containing residual defects, preferentially expands into the longitudinal directions of the colonies. The transformation of single domains proceeds instantaneously within the time resolution of the video tape recording.
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  • 12
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effect of particle solubility and the dissolution rate on agglomeration was studied by drying silica and titania particles from aqueous slurries with pH values in the range of 2–12. The agglomerate strength and strength distribution were measured by a calibrated ultrasonic force, and the strength increased as the solubility and dissolution rate increased. Two silica powders of different particle size (60 nm and 500 nm) were studied, and smaller-sized particles formed stronger agglomerates. The drying rate of the powders was varied by using spray drying and tray drying, and slower drying was shown to lead to higher agglomerate strength. The agglomerate strength of titania powder (insoluble in water) was independent of pH, whereas the agglomerate strength of silica was dependent on pH. It was concluded that the solubility and dissolution rate are important parameters that govern the strength of agglomerates.
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  • 13
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    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The formation kinetics of products formed by the reaction between dense molybdenum and vapor-supplied silicon at an activity approximating that of solid silicon under open flowing gas conditions was studied at 1200°3C. An outer MoSi2 layer overlaid the much thinner Mo5Si3 that formed on the molybdenum. Both phases obeyed parabolic growth laws over a 22 h period, having parabolic rate constants of 6.8 times 10-10 cm2/s for the MoSi2 and 1.3 times 10-13 cm2/s for the Mo5Si3 phases. These results were ∼2 orders of magnitude less than prior results, mostly obtained by another processing route. Possible explanations include enhanced growth rates from chemical contamination. Gross distortion and abnormal layer thicknesses at specimen edges and the 159% volume increase during siliciding suggest that the kinetics also are strain dependent.
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  • 14
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    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An anomalous positive temperature coefficient of resistivity (PTCR) was investigated in the ZnO-NiO system. It was found that the ZnOSS (Zn0.97Ni0.03O) and NiOSS (Ni0.6Zn0.4O) constituent phases of that system exhibit negative temperature coefficient of resistivity (NTCR) character, while their combination shows a PTCR effect with a maximum at 400°3C, which coincides with a large difference in the coefficient of linear thermal expansion between the ZnOSS and NiOSS phases at that temperature. On the basis of the brick wall model microstructure, the PTCR anomaly of this system can be explained. The magnitude of the PTCR effect is governed by the difference in resistivity of the two constituent phases at the temperature where the maximum of the PTCR anomaly occurs. The predicted temperature dependence of the resistance, R(T), of a model microstructure consisting of constituent phases with different grain sizes agrees well with the experimental R(T) of the prepared composite ceramics.
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  • 15
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    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Small substitutions of BaZrO3 into Ba[(Zn,Ni)1/3Ta2/3]O3 are utilized in the commercial preparation of low-loss perovskite microwave dielectrics. The structures of a series of these phases with substitution levels ranging from 1% to 5% BaZrO3 were examined using high-resolution TEM. For ≤ 2.15% BaZrO3 the solid solutions retain the ordered “1:2” structure of the Ba[(Zn,Ni)1/3Ta2/3]O3 end-member but are comprised of small ordered domains whose size decreases as the Zr content is raised. The decrease in the size of the domains parallels a decrease in the processing time required to access a low-loss state. Although for pure Ba[(Zn,Ni)1/3Ta2/3]O3 reductions in the degree of cation order produce a large increase in the dielectric loss, the Zr-substituted ceramics retain a very low loss. We believe the low losses of the 1:2 ceramics are derived from the stabilization of the ordering-induced domain boundaries via the partial segregation of the Zr cations. For substitutions between 3% and 5% BaZrO3 the size of the ordered domains continues to decrease but the system undergoes an abrupt transformation to a cubic “1:1” ordered structure with a doubled perovskite repeat. The structures of these phases have been interpreted using a “random layer” model in which one site is occupied by Ta and the other by a random distribution of Zn, Zr, and the remaining Ta cations, i.e., Ba{[Zn(2-y)/3Ta(1–2y)/3Zry]1/2[Ta1/2]}O3. Although the ordering is confined to nano-sized domains, these ceramics also exhibit low losses, again reflecting the relative stability of the domain boundaries. In this case we believe the low losses reflect the effectiveness of the random layer in stabilizing the anti-phase boundaries.
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  • 16
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The isothermal oxidation of HfC single crystals with (100) orientation was carried out using an electromicrobalance at temperatures of 600° to 900°3C at an oxygen pressure of 2 to 8 kPa. Nonisothermal oxidation was performed by a simultaneous thermogravimetry—differential thermal analysis—mass spectrometry analysis. A polished cross section of the oxidized crystal was observed by backscattered electron imaging in a scanning electron microscope. Quantitative chemical analysis for Hf, O, and C and their elemental profiles in the HfC and oxide scale was carried out by wavelength dispersive X-ray microanalysis. It was found that the oxide scale consists of two regions, zones 1 and 2, both of which showed the existence of carbon. The carbon content at the middle point of zone 1 was about twice that in zone 2, which contained 7 to 14 at.% carbon. Zone 1 showed an almost compact and pore-free phase; its thickness remained constant (1 to 2 μm) after a prolonged time. The thickness of zone 2 increased linearly with time. The oxidation mechanism including interfacial reaction responsible for the deposition of carbon is discussed.
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  • 17
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    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Basic principles of fabricating tile glazes based on cordieritic glass-ceramics are explained. Glass compositions from the MgO-Al2O3-SiO2 three-component phase diagram have been melted with and without the nucleating agent TiO2. Additionally, a sodium borosilicate glass that is commonly used in the tile glaze industry has been wet milled, together with the previous compositions, to produce a coating slip. Studies are focused on the role of the nucleating agent and glassy formulation in the crystallization of the glass-ceramic system using differential thermal analysis, X-ray diffractometry, and scanning electron microscopy. When added to a borosilicate glass, only one composition is capable of crystallizing cordierite under a fast-firing cycle used for “monoporosa” production. The porosity of the glaze layer is sufficiently low and the crystal size is small to ensure good mechanical and chemical properties. The presence of cordierite crystals in the glaze should enhance abrasion and acid resistance, in comparison to a traditional matte glaze that contains mostly enstatite or diopside crystals.
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  • 18
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Transparent and highly oriented Ba2NaNb5O15 (BNN) thin films have been prepared by using metal alkoxides. A homogeneous precursor solution was prepared by the controlled reaction of NaOC2H5, Nb(OC2H5)5, and barium metal. The BNN precursor included a molecular-level mixture of NaNb(OC2H5)6 and Ba[Nb(OC2H5)6]2 in ethanol. The alkoxy-derived powder crystallized to a low-temperature phase, and then transformed to orthorhombic BNN (tungsten bronze) at 600°3C. BNN precursor films on substrates crystallized to orthorhombic BNN at 800°3C via the low-temperature phase. Highly (002) oriented BNN films of tungsten bronze structure were successfully prepared on MgO (100) substrates at 700°3C by using BNN underlayer.
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  • 19
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An aqueous-based system (Si-Al2O3-Y2O3-Fe2O3) for processing sintered reaction-bonded silicon nitride (SRBSN) was investigated with an emphasis on chemical control of suspension component interactions. Chemical stability and dispersion properties of a commercial silicon powder were characterized using electroacoustic, adsorption isotherm, and rheological measurements. The interactions of silicon with nitriding agent, sintering aids, dispersants, and binder were considered. The effects of pH, electrolyte, aging, particle size, and solids loading were examined. The suspension properties of the silicon powder were influenced by the native oxide film and powder treatment history. The silicon—oxide composite particles exhibit dispersion behavior similar to silica, characterized by a negative surface potential above pH 2. A method to improve the dispersion and homogeneity of suspension components based on the use of quaternary amine dispersants is proposed.
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  • 20
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The kinetics of grain growth and Ostwald ripening in Al2O3-ZrO2 two-phase composites was systematically investigated using two-dimensional (2-D) computer simulations, based on a diffuse-interface field model. Using average values for the experimentally measured ratios of the grain boundary energies to the interphase boundary energy as the input, the predicted 2-D microstructural features and their evolution are in excellent qualitative agreement with experimental observations on 2-D cross sections of 3-D Al2O3-ZrO2 two-phase composite microstructures. It was found that the coupled grain growth in Al2O3-ZrO2 composites is controlled by long-range diffusion and the average size (Rt) as a function of time (t) follows the power-growth law, Rmt - Rm0=kt with m= 3, which is independent of the initial microstructures and volume fractions of the two phases. The predicted variation of the kinetic coefficient (k) on the volume fraction follows a trend similar to that experimentally measured through the entire range of volume fractions. The scaling of grain size distributions is observed at a given volume fraction, i.e., they are time-invariant in the steady state. However, the characteristics of size distributions vary with the initial microstructures and the volume fractions. The relationship between matrix grain size and second-phase grain size is discussed.
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  • 21
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: It was observed that slurries of oxide powders in oxidized polybutene fluids can be caused to change reversibly between fluid, nearly Newtonian behavior and plastic behavior by modest changes in temperature. This phenomenon was believed to result from changes in the dispersion vs association among the particles. The rheological effects of temperature, polymer oxidation, and particle size were observed for 30 vol% slurries of TiO2, Al2O3, and ZrO2 powders in polybutene fluids. Elasticity (in oscillation) and low-shear-rate viscosity (in steady shear) were observed to increase with increasing temperature for TiO2 and Al2O3 particles in oxidized polybutene fluids. This behavior was attributed to the creation of interparticle structures. The attainment of this structure on heating was observed to be inhibited by increased oxidation of the polymer and increased particle size. It was concluded that the adsorption of oxidized molecules from the polymer liquid, along with the high viscosity of the bulk polymer, resulted in suspensions that were metastable against coagulation. Increased temperature resulted in lower viscosities of the liquid, allowing coagulation on a short time scale. The presence of the adsorbed polymer, however, prevented intimate contact among the particles so that the coagulated structure was easily destroyed upon subsequent cooling and shearing.
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  • 22
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Minimum infiltration times during isothermal chemical vapor infiltration were calculated for the formation of a silicon carbide matrix composite from methyltrichlorosilane (MTS). Several different reaction models were used to describe the SiC deposition kinetics. The results show that the nature of the reaction model has a significant effect on process optimization considerations. It is clear that a simple first-order deposition reaction does not accurately describe the infiltration process, while rate expressions that treat the effect of chlorine-containing byproduct gases provide much more accurate predictions. In theory, much shorter infiltration times can be obtained with precursor chemistries that do not produce Cl-containing gases. The results also provide guidelines for minimizing infiltration times with MTS.
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  • 23
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Cracking parallel to the fibers in off-axis plies is usually the initial form of damage in composite laminates. This cracking process has been associated with the (transverse) fracture toughness, defined by the critical strain energy release rate, GIc. The measurement of GIc provides basic information about the transverse crack resistance. In this study, the utility of the double torsion (DT) test technique to determine GIc in a glass-ceramic matrix composite (Nicalon/CAS-II) at temperatures up to 1000°3C has been demonstrated. GIc did decrease moderately with increasing temperature (as does the bulk matrix); however, no evidence of an interphase oxidizing effect on crack growth (parallel to the fibers) could be found. The inevitable misalignment of fibers in the material was not very efficient at bridging the crack in the DT specimens, in contrast to the significant matrix crack interactions with the fibers reported for other geometries such as double cantilever beam and flexure specimens.
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  • 24
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: NiAl2O4 spinel—mullite composites were prepared by simultaneous replacement of Al by Ti and/or Ni in 3:2 stoichiometric mullite. Specimens having nominal compositions 3(Al2-2xNixTixO3) · 2SiO2 (x= 0, 0.025, 0.05, 0.2) and 3(Al2-xMxO3) · 2SiO2 (M = Ni2+ or Ti4+ and x= 0.05) were synthesized by sol—gel techniques, which provide homogeneous gels in the SiO2-Al2O3 system. Gel structures investigated by infrared (IR) spectroscopy revealed the formation of Al-O-Si bonds in dried gels. The reaction sequence of gel-derived glasses, previously obtained by preheating gels at 750°3C for 3 h, was evaluated by X-ray powder diffraction (XRD) and ultraviolet—visible (UV—vis) spectroscopy. All samples crystallized at around 1000°3C from an amorphous state, but unexpectedly the first crystalline phase was Al-Si spinel in all aluminum-substituted specimens; i.e., a change in the sequence of reaction with respect to the 3:2 stoichiometric mullite was produced. NiAl2O4 spinel was almost simultaneously detected. Two processes of mullite crystallization were observed. The temperature of formation of mullite was the lowest for the higher substituted sample. The microstructure of the final NiAl2O4 spinel—mullite composites found in all Ni-containing samples after annealing for 96 h was examined by scanning electron microscopy with energy dispersive X-ray analysis (SEM/EDX), which revealed the presence of small particles of NiAl2O4 spinel dispersed in a mullite matrix. For annealed compositions with the larger Al replacement, i.e., when x= 0.2, a small amount of very small Al2TiO5 particles was also detected by XRD and transmission electron microscopy (TEM).
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  • 25
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    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The reactions of stoichiometric Y2O3, CuO, and different barium salts (BaCO3, Ba(NO3)2, BaO2, BaCuO2) for forming various compounds in the yttrium—barium—copper—oxygen system (i.e., YBa2Cu3O7–8, BaCuO2, Y2BaCuO5, and Y2Cu2O5) were systematically investigated by thermal analysis and X-ray diffractometry. In a few cases, the relevant activation energies were calculated. The reaction pathway and kinetics were significantly dependent on the physicochemical and thermal stability of the barium precursors, as well as on the crystalline size of the reagent. Binary BaO-CuO phases formed at low temperature (650°-700°3C) when in the presence of easy-to-decompose barium precursors, and then slowly transformed to ternary compounds; in contrast, when barium ions were released at temperatures of 〉900°3C, ternary phases formed directly from the components.
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  • 26
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    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A ceramic matrix for carbon-fiber-reinforced ceramic-matrix composites (CMCs) has been developed from poly-siloxane/boron mixtures. Complex geometries can be realized by using standard technologies of fiber-reinforced polymer composites. On pyrolysis, the polymer—filler mixture is converted to a ceramic matrix, consisting of silicon carbide, boron carbide, boron nitride, and a silicon oxycarbide (SiOC) glass, without reacting with the carbon fiber. Because of the large volume increase of the boron filler on nitridation (142 vol%), no multiple reinfiltration of the structure is necessary to achieve a dense matrix. Tensile strength and interlaminar shear strength exhibit maxima at a pyrolysis temperature of 1300°3C, where extensive fiber pullout is observed. Thermodynamic calculations have been used to evaluate the theoretical qualitative and quantitative phase compositions at equilibrium. Thermoanalytical (thermogravimetry—mass spectroscopy) and structural analysis (X-ray diffractometry) have shown a satisfying coherence with respect to the condensed phases, whereas deviations have been noted with respect to the composition of the gas phase.
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  • 27
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    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Carbohydrates are often key components in the formulation of extrusion pastes, yet the reasons for selection are presently empirical. The influence on paste extrusion of various types of carbohydrates, such as starch, dextrin, lactose, and glucose, have been studied and related to their water retention capacities. The bulk yield stress and the surface shear stress both decrease as the moisture content increases; however, the way in which the water that is present interacts with the carbohydrate has an important influence. The behavior of some carbohydrates can be substantially accounted for by a consideration of packing effects; however, dextrin behaves differently. The carbohydrates function not only as a binder but also as a means of retaining the liquid phase.
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  • 28
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    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Spherical indentation of thick and thin glass plates was investigated numerically and experimentally. The energy release rate at the tip of a cone crack was calculated by using finite element techniques and used to investigate the applicability in thick plates of Roesler's law relating the cone crack radius to the indentation load. Indentations of thin glass specimens resting on different substrates were also studied numerically and experimentally. The stresses in the thin specimens were calculated and correlated with the observed failures. On the basis of these results, a crack initiation mechanism map was developed for glass specimens on different substrates.
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  • 29
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    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Stereological measurements were performed to characterize the indentation crack path in a cubic zirconia—10 vol% alumina (c-ZrO2-10 vol% Al2O3) composite. Cracks were generated using Vickers indentation, and the crack propagation behavior was characterized as a function of the indentation loading/unloading rates. Cracks that were produced by Vickers indentation formed at higher crack velocities as the loading/unloading rates increased. The amount of contact between the crack and the Al2O3 particles increased as the indentation rate decreased. The total number of crack—particle interactions per unit crack length also increased as the indentation rate decreased, because of an increase in the number of particles that were fractured per unit crack length, whereas the number of particles that were debonded remained relatively constant as the indentation rate changed. These results suggest that residual thermal mismatch stresses have predominant control of the crack path at lower crack velocities (low indentation loading/unloading rate), whereas elastic mismatch stresses predominate at higher crack velocities (high indentation loading/unloading rate).
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  • 30
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    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The purpose of this study was to determine the chemical composition changes of hydroxyapatite (HA) coated titanium using surface analysis (X-ray photoemission) and bulk analysis (energy dispersive spectroscopy). The specimens examined were controls and specimens aged 30 min and 3 h at room temperature in distilled water and 0.2M sodium phosphate buffer (pH 7.2). Each X-ray photoemission cycle consisted of three scans followed by argon sputtering for 10 min for usually 20 cycles, corresponding to a sampling depth of ∼1500 Å. The energy dispersive spectroscopy analysis was on a 110 by 90 μm area for 500 s. The X-ray photoemission results indicated the oxidation effect of water on the titanium (as TiO2) and the effect of the buffer to increase the surface concentration of phosphorus. No differences in the chemical composition were observed by energy dispersive spectroscopy analysis.
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  • 31
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    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A novel in situ reaction between a ceria-doped zirconia interphase coating on Saphikon fibers and an outer alumina coating has resulted in the formation of oriented hexaaluminate platelets which can act as a low fracture energy interface barrier for crack deflection in oxide—oxide ceramic-matrix composites (CMCs). The reaction proceeds only in reducing environments where the reduction of the cerium and zirconium ions to their 3+ valent state causes a destabilization phenomenon consistent with previously reported findings. The diffusion of the cerium from the zirconia into solid solution with the alumina can stabilize the layered hexaaluminate structure. Preferred orientational growth of the hexaaluminate parallel to the coating interface was observed which is the required orientation for enhanced debonding at the fiber/matrix interface in long-fiber-reinforced CMCs.
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  • 32
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    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A layer composed of mullite and silicate glass was caused to form on the surface of a high-purity alumina ceramic in order to enhance the strength of the material. The layer was formed by exposing the specimens above a bed of SiC platelets at 1400°3C to a flowing H2 atmosphere containing ∼0.1% H2O. A reaction between the SiC platelets and the H2O in the environment resulted in the generation of SiO gas. Some of the SiO gas subsequently reacted with ambient H2O in the atmosphere, forming SiO2“smoke” which was deposited on, and reacted with, the alumina substrate. The strength of the ceramic was significantly improved by the reaction layer, which was found to be comprised of mullite and silicate glass. The increases in strength (about 60% above that of the material in the “as-polished” condition) was attributed to the blunting of surface cracks. A similar strengthening effect was observed in samples of the material which had been ground with a 220-grit diamond abrasive wheel (as had all of the samples) but not polished.
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  • 33
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    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Thin, semiconducting barium titanate (BaTiO3) ceramic bars, with a diameter of 10 to 20 μm, consisting of single grains joined together in series have been prepared to investigate the piezoresistivity in the materials, which was evaluated from their current (I)-voltage (V) characteristics under the loading condition of various bending stresses. I-V characteristics of single grain boundaries in some of the materials were found to exhibit distinct differential negative resistance (DNR) at room temperature with its feature changing with stress. The DNR appeared on the I-V curves at an electric field of several volts per one grain, and has been confirmed to be connected with the transition of current between two conduction states in the grain boundary region. The obtained results indicate that this phenomenon cannot be interpreted by a rise in the temperature of the materials up to their positive temperature coefficient of resistivity (PTCR) region above the Curie point by Joule heating due to current flow, that is their self-heating effect. This newly observed DNR phenomenon has thus been tentatively interpreted by the morphological change in the ferroelectric domain structure in the vicinity of grain boundaries under mechanical and electric stresses, on an assumption that different configurations of ferroelectric domains yield different conduction states in the grain boundary due to a difference in the degree of surface acceptor charge compensation or the anisotropic carrier mobilities in the crystal.
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  • 34
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    Journal of the American Ceramic Society 80 (1997), S. 0 
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The real part of the permittivity (ε) and the tan δ of sintered alumina (Al2O3) at about 9 GHz have been measured. The dielectric properties have been examined as a function of purity, pore volume, and sintered grain size. The tan δ is found to depend very strongly on the pore volume, purity, and grain size. ε is far less sensitive to impurities and grain size. The dependence of ε on porosity can be described by simple mixture models as expected. A model of losses in single crystals cannot be extended easily to these materials where extrinsic factors such as porosity, random crystal orientation, grain boundaries, microcracks, and impurities dominate. These factors have been studied in an attempt to describe the tan δ and ε of sintered polycrystalline alumina. In this work, the tan δ for alumina has been studied in near-theoretical density ranges between 9.1 times 10-5 and 2.4 times 10-5 depending on grain size.
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  • 35
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    Journal of the American Ceramic Society 80 (1997), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: It is well known that the undoped Pb(Mg1/3Nb2/3)O3-PbTiO3 ceramics, prepared through conventional ceramic processing, present no evident aging effect. In this paper, however, a discernible aging phenomenon was observed in an undoped, N2-H2-annealed ceramic. When this sample was later annealed again in air, this effect became negligible again just like that of a normally prepared PMN—PT ceramic. The valence states of Ti ions, which may be changeable in different annealing atmospheres, were assumed to be responsible for the different degrees of aging.
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  • 36
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    Journal of the American Ceramic Society 80 (1997), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: To test the stability of intergranular amorphous films against crystallization, a model experiment was conducted wherein a thin SiO2 film was deposited on a single-crystal TiO2 substrate, annealed to form a eutectic liquid in equilibrium with the substrate, then quenched and crystallized below the eutectic temperature. This geometry is free of residual stresses and capillary effects proposed by others as kinetic limitations to complete crystallization. Furthermore, using a binary system removes solute rejection barriers to complete crystallization. A remnant amorphous film ∼1.5 nm thick retained at the hetero-interface shows unequivocally that the amorphous film is thermodynamically preferred to a crystal/crystal interface in this system.
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  • 37
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    Journal of the American Ceramic Society 80 (1997), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Fast lithium ion conducting glass-ceramics have been successfully prepared from the pseudobinary system 2[Li1+xTi2SixP3-xO2]-AlPO4. The major phase present in the glass-ceramics was LiTi2P3O12 in which Ti4+ ions and P5+ ions were partially replaced by Al3+ ions and Si4+ ions, respectively. Increasing x resulted in a considerable enhancement in conductivity, and in a wide composition range extremely high conductivity over 10-3 S/cm was obtained at room temperature.
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  • 38
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    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Continuous-carbon-fiber-reinforced silicon carbide composites (C/SiC) were prepared by chemical vapor infiltration in which the preforms were fabricated with the three-dimensional braid method. The mechanical properties and microstructures were investigated. For the composites with no interfacial layer, flexural strength and fracture toughness increased with density of the composites, and the maximum values were 520 MPa and 16.5 MPa·m1/2, respectively. The fracture behavior was dependent on the interfacial bonding between fiber/matrix and fiber bundle/bundle which was determined by the density of the composites. Heat treatment had a significant influence on the mechanical properties and fracture behavior. The composites with pyrolysis interfacial layers exhibited characteristic fracture and relatively low strength (300 MPa).
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  • 39
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    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A test method to evaluate the fracture toughness, KIC, of thin, small, precracked ceramic specimens is described. The method is applicable for thin plates, wafers, self-supported layers, etc., especially when a large amount of material is not available for testing. The method consists of bonding a small, thin single-edge notched beam on one side of a metallic beam. A stress-free precrack with a square root singularity is achieved when the assembly is deformed in three-point bending.The fracture toughness of a thin, alumina single-edge precracked beam was evaluated experimentally using this method, and compared with that obtained for similar specimens having a 0.3-mm-wide machined notch. Comparison with previously reported fracture toughness values suggests that even a very sharp machined notch overestimates the evaluated fracture toughness.
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  • 40
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    Journal of the American Ceramic Society 80 (1997), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Dielectric depression and dispersion were observed in BaTiO3 ceramic films fabricated by electrophoretic deposition followed by sintering. The dielectric constants were depressed down to 6800-4600 around the Curie point (TC). The dielectric dispersion occurred above TC. These dielectric properties are attributable to a surface layer formed during sintering. XRD analysis indicated that the surface layer was a hexagonal-like BaTiO3 phase. A mixed solvent of acetylacetone and alcohol employed in the present work may have been responsible for the formation of the surface layer.
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  • 41
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The crystal structures of the cotunnite-type phases (space group, Pnam, Z= 4) of pure zirconia and hafnia prepared under high-temperature, high-pressure conditions in a multianvil device were refined by time-of-flight neutron powder diffraction. The structures of both compounds are very similar and the nine polyhedral metal-oxygen distances range from 2.133(1) to 2.546(1) Å in ZrO2 and from 2.121(1) to 2.535(2) Å in HfO2. The Raman spectra of both phases resemble one another strongly and are consistent with the cotunnite-type structure. These results confirm that ZrO2 and HfO2 undergo transitions to the same phase at high pressure.
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  • 42
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: We have studied the atomistic structure of a σ3 (111) grain boundary in strontium titanate by high-resolution transmission electron microscopy (HRTEM). Quantitative evaluation of HRTEM images reveals that shear stresses, which may originate from processing or external loading, have an important effect on the translation state of the two adjacent grains and on the ion positions at the grain boundary. While under low shear stress the boundary exhibits mirror symmetry with respect to the boundary plane and a comparatively large free volume, high shear stress transforms the structure to a “lock-in” configuration, which has no mirror symmetry and a smaller excess volume. These results suggest that internal or external stresses may significantly alter the charge transport properties of SrTiO3.
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  • 44
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The hardness of opposite basal faces of 4H-SiC single crystals has been measured in the temperature range 25°-1200°3C. A strong hardness anisotropy between the silicon-terminated (0001) and carbon-terminated (0001) faces of this polar crystal has been found. Transmission electron microscopy investigation of the dislocations in the plastic zone of the 1200°3C indentations shows that they lie predominantly on the basal planes parallel to the indented face, and the extra-half planes of the nonscrew dislocations originate from the indented face. It is also found that, when the (0001) Si-terminated face is indented, the dislocations are either widely dissociated, with the width of the stacking fault ribbon much larger than the equilibrium value, or else they are single leading partials, with the corresponding trailing partials absent. In this case, all the leading partials are found to have a silicon core. On the other hand, the dislocations in the plastic zone of the carbon-terminated face are in the form of dissociated dislocations, with the width of the associated stacking fault ribbons appreciably less than the equilibrium value. Moreover, the leading partials of éhese dissociated dislocations have a carbon core. The results indicate that the hardness of the polar basal faces of 4H-SiC at elevated temperatures is partly determined by the nature of the dislocation cores nucleated by the indentation process. It is argued that this is due to the influence of the core on the generation and glide of the leading partial dislocations.
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  • 45
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— Dynamic SCC (DSCC) behaviour of a Ti-6A1–4V alloy has been studied for different microstructures and orientations, in 3%NaCl solution, and the effect of crack size on crack growth behaviour was discussed. Three microstructures were prepared by heat treatment, i.e. two annealed materials (AN705 and AN850) and a solution treatment and ageing (STA) material. Tests were performed at a cyclic frequency of 10 Hz and a stress ratio of 0.9 using CT specimens for long cracks (a≥ 24 mm) and surface-cracked specimens for small cracks (a≥ 0.4 mm). The KDSCC values obtained for small cracks were considerably higher than those for long cracks in all the microstructures, that is a crack size effect in dynamic SCC behaviour was found in the Ti-6A1–4V alloy. For small cracks, the KDSCC values for AN705 and AN850 were the same in the L and T orientations, while the KDSCC value for STA was higher in the L orientation than in the T orientation. The KISCC values were almost the same as, or higher than, the KDSCC values.
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  • 46
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    ISSN: 1460-2695
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— In order to evaluate the threshold value ΔKτth for mode II fatigue crack growth, a new measurement method of mode II fatigue crack growth has been developed. This method uses a conventional closed-loop tension—compression fatigue testing machine without additional loading attachments. Mode II fatigue tests for structural steel and rail steel have been carried out. This method has proved successful and has reproduced mode II fatigue fracture surfaces similar to those found in the spalling of industrial steel-making rolls. The crack length during testing was measured by an AC potential method. The relationships between da/dN and ΔKτ and AKτth for several materials have been obtained.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    ISSN: 1460-2695
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— Stress intensity factors for quarter-elliptical corner cracks emanating from a circular hole are determined using a 3-D weight function method combined with a 3-D finite element method. The 3-D finite element method is used to analyze uncracked configurations and provide stress distributions in the region where a crack is likely to occur. Using this stress distribution as input, the 3-D weight function method is used to determine stress intensity factors. Three different loading conditions, i.e. remote tension, remote bending and wedge loading, are considered for a wide range of geometrical parameters. The significance of using 3-D uncracked stress distributions is studied. Comparisons are made with solutions available in the literature.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— This paper presents the results of an experimental testing programme to examine the uniaxial creep, low cycle fatigue and creep/fatigue interaction behaviour of a Ni-base superalloy at 700°C. The material is used in the manufacture of aeroengine turbine discs. A creep continuum damage mechanics model is shown to be capable of accurately predicting the creep and creep rupture behaviour of the material. A healing term has been incorporated into the damage mechanics model to allow the behaviour under creep/fatigue conditions to be described.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— The effect of short periods of mixed-mode overloading on the environmental hydrogen induced fracture life of 0.42%C, 0.87%Cr, 0.21%Mo steel has been studied. Tests were performed in 0.5 mol/L H2SO4 solution under continuous hydrogen charging conditions using a weight loading system. Experimental results show that the application of mixed-mode overloads can cause more severe crack growth retardation than those of mode I. Possible mechanisms responsible for the retardation of subsequent crack growth, such as crack deflection, plasticity-induced residual compression stresses, dislocation shielding and overload damage, are examined.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    ISSN: 1460-2695
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— The whole damage process in a finite sized specimen with interacting microcracks is simulated by a method combining the closed form crack solutions with boundary elements. Interactions among microcracks and boundary elements are taken into account with an explicit interaction matrix. A coalescence criterion is assumed to rule the intersection behaviour and propagation arrest. The fatal coalescence cluster resulting in the failure of the specimen, out of many intersections of propagating microcracks, is identified with a particular coalescence matrix. The numerical model proposed in this paper can be used to simulate the damage process in a brittle specimen of any shape, under arbitrary plane stress conditions.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— Creep Crack Growth (CCG) tests were performed at 405°C on specimens cut out of the cold bent extrados of five tubes of a C-Mn-Mo steel. Intergranular fracture and grain boundary cavitation was less in the C-Mn-Mo than in the C-Mn steels, in accordance with better CCG resistance of the former material. The dimensions and hardness variation across the crack tip process zone were measured by microhardness profiles performed on metallographic sections of the broken samples. TEM analysis of the dislocation patterns close to the fracture surface confirmed the presence of temperature- and stress-induced plasticity phenomena. A significant enrichment of N at grain boundaries (GB) inside the process zone was detected by Auger spectroscopy; N not only inhibits dislocation motion and stress field relaxation at the crack tip but also causes a decrease in GB cohesion ahead of the crack tip. These results help in understanding the micromechanisms which reduce the creep ductility of C-Mn-Mo and C-Mn cold bent tubes and the role of chemical composition in improving CCG resistance.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— The effect of specimen size on fracture toughness of a pipe-grade high density polyethylene has been examined using the J integral approach. It was found that the size requirements set up by common standards appear inadequate for this material. Measurements at low temperatures, at which a plane strain fracture toughness value could be obtained, turned out to be very effective in establishing a more appropriate size requirement for this material.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— Fractographic peculiarities of fatigue crack development are studied in cruciform specimens of D16T aluminium alloy under out-of-phase biaxial tension and tension-compression. In the range of the biaxial load ratios λ from −0.5 to +0.5 and an R-ratio of 0.3, fatigue striation formation took place beyond a crack growth rate near to 4 × 10−8 m/cycle. The striation spacing and the crack growth rate increase as the φ-angle of the out-of-phase biaxial loads increases in the range of φ-angles from 0° to 180°. The ratio between the increment of crack growth, da/dN, and the striation spacing, δ, is approximately 1 to 1 when da/dN is greater than 4 × 10−8 m/cycle. The relationship between the number of cycles from the beginning of a test up to the growth rate of 10−6 m/cycle (Nd), and the crack growth period, NP, from when the crack initiates up to the instant when that growth rate is reached, was determined for different λ ratios and φ angles. The value of Nd decreases as the φ angle is increased in the range from 0° to 1807deg;.Cycle loading parameters must be taken into account in order to describe the crack growth period when using a unified method that involves an equivalent stress intensity factor Ke=KIF1(λ, R)F2(φ). The values of F2(φ) were determined.The calculated fatigue crack growth period, Nc, applicable up to and including the stage of fatigue striation formation (predicted by using both of the F1(λ, R) and F2(φ) functions) is correlated with the experimental data and the error is of the order of 15%.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— The occurrence of brittle stable crack growth before unstable fracture was demonstrated with the aid of heat-tinting, for a ferritic matrix super duplex stainless steel which had been age-hardened at 475°C. The critical crack tip opening displacement for stable crack growth, i.e. the crack initiation toughness, was measured using the direct-current-potential drop crack monitoring technique. A quantitative model for the effect of temperature and age-hardening on the brittle crack initiation toughness is described.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— Fatigue crack propagation characteristics are measured by continuously determining the resonant frequency in vibrating systems, which is stabilized through a feedback control loop. The precisely controlled resonant frequency is related to the crack length by a nonlinear model based on fracture mechanics, hence crack growth can be monitored with respect to time with very high accuracy. The nonlinearity due to the opening and closing of the crack needs to be taken into account. In contrast to conventional fatigue tests, which require a long duration of time due to the high numbers of load cycles at low frequencies, the proposed technique operates at much higher frequencies, i.e. in the range of 100 Hz to 100 kHz. Thus the required time for measurements in the high cycle fatigue range is considerably reduced. The experimental setup is simple and inexpensive and does not require high energy inputs.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— Microstructure and mechanical properties of HP (Hot Pressed), HP/GP (Gas Pressed), and HP/HIP (Hot Isostatic Pressed)—Si3N4 are studied using scanning electron microscopy, bending tests and the indentation fracture method. The grain diameter distribution is analyzed to clarify the relationship between microstructure and mechanical properties; and also the bending strength and fracture toughness. It is shown that bending strength increases with decreasing grain diameter. The results also show that a Hall—Petch type of relationship is obtained between grain diameter and fracture strength. The fracture toughness shows a linear relationship with 〈inlineGraphic alt="inline image" href="urn:x-wiley:8756758X:FFE829:FFE_829_fu1" location="image_n/FFE_829_fu1.gif" extraInfo="missing"/〉, where σF= bending strength, β= a proportionality factor and da= average grain diameter, and is closely related to the aspect ratio of Si3N4 grains. It is concluded, from the morphological analysis, that a microstructure composed of Si3N4 grains, with both a small grain diameter and a large aspect ratio, is effective in improving both the fracture strength and fracture toughness.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— The random temperature fluctuation produced by the incomplete mixing of hot and cold fluid streams passing over the surface of a component or structure is known as thermal striping. This phenomenon may cause thermal fatigue to occur. It is of particular concern in various types of nuclear reactors, for rapid shut-downs of hot plant and in thermal stratification. A computer code, “TBL”, is a design tool which has been developed to assess thermal striping damage in plates. This model is further developed in this paper to assess such damage in cylindrical components. A recent, universal weight function method is examined and incorporated into TBL. Good comparisons are found between TBL and finite element results for a sinusoidally varying temperature-time-striping history. Potential thermal striping damage is assessed for a cylindrical component of material typically found in the above-core region of a fast reactor under a random temperature-time-striping history.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— The mechanical behaviour of AISI 329 steel has been investigated for ageing times up to 20,000 h at temperatures of 475, 425, 375, 325 and 275°C. The study has concentrated on the changes in the response to cyclic strains, in the low-and the high-cycle fatigue regimes, and in the resistance to fatigue crack propagation as a function of temperature and time of ageing.It is shown that ageing increases the fatigue resistance in the high-cycle fatigue regime, but the opposite occurs in the low-cycle fatigue regime. Ageing increases the LEFM threshold stress intensity factor range for fatigue crack propagation which reaches high values in these alloys, and is influenced by the fatigue load ratio. Crack closure contributes to the LEFM threshold stress intensity factor range for crack propagation only in the annealed condition of the AISI 329 steel.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— Low cycle fatigue tests under axial, torsional and combined axial-torsional loading were conducted using thin-wall tubular specimens of Ti-6A1–4V titanium alloys. Two kinds of alloys with different microstructures, the (α+β) and β alloys, were investigated in fatigue tests at room temperature. When the failure life was correlated with the equivalent plastic strain, the life in axial loading shifted toward the lower life region compared with those in other loading modes in both alloys. Dominant surface cracks propagated in mode I under axial and combined loading in the two alloys. Although growth by the mode II type was predominant under torsional loading, the growth direction of the main crack coincided with the specimen axis in the (α+β) alloy, but the circumferential direction in the β alloy. The cracking morphology depended on the microstructure, especially under the torsional mode of loading, and was simulated successfully by using the proposed model for crack initiation.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— Fracture behaviour of injection-moulded polypropylene filled with silane-treated talc was studied as a function of filler volume fraction (0–20%) and compared to that of polypropylene filled with untreated talc. High-rate tests (0.57 m/s) on SENB specimens were carried out using an instrumented Charpy impact pendulum, and linear elastic fracture mechanics (LEFM) was applied to calculate the fracture parameters, KC and GC. It was found that moderate fractions of talc which were added to the polypropylene matrix increased the fracture toughness of the composite independent of the talc surface treatment. This general improvement seems to be due to the peculiar orientation of the talc platelets in the injection-moulded specimens. The fracture behaviour of the composites was also studied at low strain rate (1 mm/min) by tests on J-integral type specimens with the same SENB geometry. In this case, the composites with silane-treated talc presented poor J-integral values compared to those of the samples with untreated talc. This was attributed to a reduction of the plastic zone at the crack tip, since the improved coupling between the talc platelets and matrix increased the yield strength of the composite. All the results are explained on a basis of morphological and microstructural details.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— Using experimentally determined data on fibre radius distributions, yarn geometry, matrix and fibre elastic moduli and frictional shear stress at the matrix/fibre interface (obtained by nano-indentation experiments), the failure probability of the composite fibre yarns (after matrix cracking) is estimated. Each fibre is divided into a fixed number of segments above and below the matrix crack. The failure probability on every segment of each fibre is computed using Weibull fibre strength statistics. A fibre is assumed to be broken when the cumulative failure probability for the complete yarn reaches a value of 0.5. The segment and fibre are then selected at “random”, according to their individual failure probabilities. After fibre failure, the broken fibre can only carry the frictional load and the load drop is transferred to its neighbours according to their distances to the broken fibre. The remote stress is then modified to match again the cumulative failure probability of 0.5 and a new fibre is broken. This procedure is repeated until all the fibres are broken. In this way, it is possible to obtain the “characteristic” load carried by the yarn and its corresponding elongation. Fibre extraction and pull-out behaviour are also considered. The roles of different load-transfer laws (from global to highly localised) are examined. The model is applied to simulate the fracture tensile behaviour of individual yarns of SiC/SiC ceramic-matrix composites. The results are compared with those obtained from tensile experiments on SiC/SiC individual yarns. The computed fracture morphology, in terms of individual pull-out lengths, is also compared to the actual SEM fractography of a woven SiC/SiC composite.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— The subject of hypersingular boundary integral equations is a rapidly developing topic due to the advantages which this kind of formulation offers compared to the standard boundary integral method. The hypersingular formulation is particularly well suited for fracture mechanics problems, where there are important gradients of the stress field and singularities. This formulation for time domain antiplane problems has been recently addressed by the authors and in the present paper, the formulation for time domain plane problems is presented and applied for the first time. A mixed Boundary Element approach based on the standard integral equation and the hypersingular integral equation is developed. The mixed formulation allows for a very simple discretization of the problem, where no subregion is needed. Conforming quadratic elements are used for the crack and the external boundaries. The hypersingular integral equation is used for collocation points within the crack elements, while the standard integral representation is used for the external boundaries. Several examples with different crack geometries are studied to illustrate the possibilities of the method. The Stress Intensity Factor (S.I.F.) is very accurately computed from the crack tip opening displacements along the crack tip element. The results show that the proposed approach for S.I.F. evaluation is simple and produces accurate solutions.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— A two-dimensional elastic-plastic finite element analysis is performed for plane stress conditions with 4-node isoparametric elements to examine closure behaviour of fatigue cracks, giving special attention to the determination of the most appropriate mesh sizes. It is found that a smaller mesh size does not always give more accurate simulation results in the fatigue crack closure analysis, unlike a conventional structural analysis. A unique, most-appropriate mesh size exists for a given loading condition that will provide numerical results which agree well with experimental data. The most appropriate mesh size can be determined approximately in terms of the theoretical reversed plastic zone size. In particular, the ratio of the most appropriate mesh size to the theoretical reversed plastic zone size is nearly constant for a given stress ratio in the so-called crack-length-fixed method proposed in this study. By using the concept of the most appropriate mesh size, the finite element analysis can predict fatigue crack closure behaviour very well.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— High strain-rate tensile tests have been carried out on pre-notched specimens of OFHC copper and Remko iron at both elevated and cryogenic temperatures. When properly expressed as a function of stress triaxiality at the centre of the notch (as predicted by numerical simulations of the experiment), the ductility of copper was found to be independent of temperature over a range from —190°C to 300°C. The specially-processed Remko iron was found to undergo a ductile-to-brittle transition at a temperature dependent on the stress triaxiality and the particular batch of the material. Otherwise the fully ductile strains-to-failure (when expressed as a function of stress triaxiality) for iron were found to decrease with increasing temperature up to 400°C; this being the maximum temperature tested.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— Fatigue crack growth experiments were carried out on cruciform specimens of D16T Al-alloy, loaded under uniaxial and biaxial loads, including a sequence of various overloads. It is shown that, for biaxial cyclic loads at stress ratios λ and various R-ratios, fracture surface development during overloads and the crack length dependences on the cyclic loads following overloads are similar to those for uniaxial loading.The aim of this investigation was to study interaction effects by analyzing the crack retardation length and associated parameters together with their relationships. These parameters’depend on the biaxial ratio (λ) and the stress ratio (R) and their uses in crack growth modelling are briefly considered.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— This paper reviews the stress intensity factor, limit load, compliance and J-integral functions for a centre cracked tensile (CCT) specimen available in the literature. Compliance and J-integral functions are derived from the optimum stress intensity factor and limit load solutions. The functions are compared with the results obtained from two-dimensional finite element analyses of the specimen.The finite element results have confirmed the accuracy of the compliance and limit load functions available in the literature and suggest that the unloading compliance technique, based on crack mouth opening displacement, could be developed for a CCT specimen. Non-linear finite element analyses have shown that J can be estimated from the measured load versus load-point displacement behaviour providing a/W≥ 0.5
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— The behaviour of fatigue cracks in an Al-alloy under cyclic compression, either with or without overloads, was studied. For constant-amplitude compressive cycling, a non-catastrophic (saturation) character of the fatigue crack behaviour was confirmed, with the final depth of a crack depending on the applied load level. Single (tensile or compressive) intermittent overloads were shown to re-activate a previously arrested crack while reversed (tensile—compressive or compressive—tensile) ones were also shown to maintain continual fatigue crack extension under otherwise fully compressive cycling.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— A new method for accelerating the collection of near-threshold corrosion fatigue crack propagation data, using local hydrogen embrittlement in the crack tip region, has been investigated for ASTM A710 HSLA steel. Fatigue tests were conducted at 10 and 0.2 Hz (stress ratio, R= 0.1) on “constant K” contoured double cantilever beam (CDCB) specimens, to establish near-threshold crack growth rates in a locally hydrogen charged region at the crack tip. Hydrogen charging was then discontinued and crack growth rates were monitored in the uncharged material. Near-threshold fatigue crack growth rates were found to be 100 times faster in the locally hydrogen charged specimens than in the uncharged material. Fatigue thresholds, ΔKth, were defined in less than one fifth the time required for load shedding tests in air at 0.2 Hz. Although demonstrated for HSLA steels, the technique is applicable to any material which can be embrittled by hydrogen.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— The objective of this work is to study the delamination growth behaviour of hybrid composite-aluminium bonded laminates. A modified Double Crack Lap Shear (DCLS) specimen was chosen for this study. An expression relating the delamination size and the compliance of a DCLS specimen was derived, and a test method for the delamination growth rate in DCLS specimens developed. The delamination sizes and the delamination growth rates of DCLS specimens were determined by monitoring the compliances of specimens during fatigue. Delamination growth rates at different stress ratios (R= 0.1, 0.3,0.5) were measured. A Walker-type equation for the delamination growth rate was obtained by a multiple linear regression analysis.It was shown that the compliance method for determining the delamination growth rate of DCLS specimens is not only convenient and practical, but also accurate. The delamination size in DCLS specimens increases linearly with cycles during fatigue, i.e. delamination growth rate is constant, independent of delamination size. The energy release rate was adopted to characterize delamination growth behaviour. Good agreement between the Walker equation and test results of the delamination growth rate was found.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— The aim of the paper is to compute the local crack face displacements of a linear elastic body containing an arbitrarily shaped plane crack. From the crack face displacements the local stress intensity factors can be derived.The boundary value problem for a plane crack of arbitrary shape, embedded in a linear elastic medium, has been treated by several authors by the singular integral equation (SIE) approach. Their computations lead to a set of hyper-singular integral equations for the Cartesian components of the unknown crack face displacements. To solve these equations the authors present a discretization procedure based on six-node triangular finite elements. A total set of 24 finite-part integrals defined over a triangular area can be developed. These 2D-finite-part integrals can be split into both a 1D-regular and a 1D-finite-part-integral by means of the polar coordinates so that they can be solved in closed form. Finally, the investigation of the SIEs is reduced to a discrete set of linear algebraic equations for the unknown nodal point values. The necessary steps will be demonstrated in detail. The derived closed-form solutions will be offered in the text and in the appendices.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— A new tool is presented to investigate cleavage fracture surfaces. It is based on the combined techniques of crystal orientation measurements using the Electron Back-Scatter Diffraction (EBSD)-technique and 3-dimensional surfaces reconstruction by an Automatic Surface Reconstruction System (ASRS).With this tool we can perform crystallographic fractometry of cleavage fracture facets of polycrystals within the limits of the resolution of a Scanning Electron Microscope (SEM), e.g. we can determine the crystallographic indices of cleavage planes and of directions on such planes.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— Ordinary ceramic refractories are used as lining material for industrial pyro-processes. A high resistance to mechanical failure from an imposed strain or thermal shock is usually termed “flexibility”. A scientific approach to enhance this property is hindered by the fact that there is a lack of understanding, definition and measurement of this parameter in relation to its physical basis.Wedge splitting tests were performed on a variety of typically shaped refractories together with standard procedures. This type of test enables stable crack propagation even for relatively large specimen dimensions that are necessary due to the size effect. High “flexibility” proved to be achievable in low brittleness materials and can be characterised by a brittleness number, the characteristic length or the thermal shock fracture resistance parameter according to Hasselman. A sufficient decrease of brittleness can be successfully achieved by the formation of precracks during the burning process which enhance the development of a fracture process zone. For a magnesia refractory (with additions of magnesia-alumina spinel) a friction bridging mechanism plays an important role in reducing brittleness.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— This paper describes the microstructure of Type 304 stainless steel after cyclic loading at room temperature under tension-torsion non-proportional strain paths. The degree of cyclic non-proportional hardening is correlated with changes in the dislocation substructure. Dislocation cells, dislocation bundles, twins and stacking faults are all observed. The type of microstructure formed and resultant stress response is dependent on the degree of non-proportional loading and strain range. Cyclic stress range was uniquely correlated with mean cell size.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— Multiple underloads and overloads with constant ΔK were carried out on centre-cracked tension specimens. It was found that when shear lips develop, underloads or overloads affect the crack growth rate da/dN and the subsequent retardation. The appearance of the shear lip fracture surfaces depends on the frequency. At higher frequencies a greater number of rough shear lip fracture surfaces will develop, while at lower frequencies there is a tendency towards smooth shear lips. The amount of crack closure differs in each case. It was found that the type of shear lip, rough or smooth, can be related to the effect on da/dN during and after underloads. The effect of rough and smooth shear lip growth was investigated in constant ΔK tests, performing these tests with and without crack closure.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— In this paper, a stress and modal analysis of an ultrasonic vibration system consisting of a notched specimen and one or two amplifying horns have been performed by using 3D finite element calculations. The stress intensity factors in ultrasonic fatigue crack propagation are evaluated by means of displacement and energy approaches. The particular advantages as well as limitations of the two approaches are briefly discussed. Two types of ultrasonic fatigue loading, with a different stress ratio, are exerted on the specimen. From a comparison of the results a conclusion is formed that the energy approach is more accurate; it also has a wide range of practicality in engineering industries.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— A number of fretting fatigue tests were carried out on CMV steel and INCO 718 alloys under closely controlled experimental conditions. A fracture mechanics-based lifing model was developed and the Paris Law employed to predict fatigue lives under a range of experimental conditions. An effective initial flaw size was used to describe initiation and early propagation of cracks. This approach was found to give good predictions of fatigue life of specimens for different values of bulk stress under the same fretting load.
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  • 79
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— The factors affecting the fatigue strength of nitrided titanium were clarified. The fatigue strength depended strongly on the fracture strength of the compound layer formed on the surface by nitriding. We found a Hall-Petch relationship between the fatigue strength of nitrided titanium and the grain size. The findings indicated that the reduction in the fatigue strength by nitriding results from both the formation of the compound layer possessing low fracture strength and grain growth occurring from ordinary nitriding. Furthermore, low-temperature nitriding (620°C, 24 h) was proposed to suppress grain growth. This treatment method improved not only the wear resistance and the corrosion resistance but also the fatigue strength of titanium.
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  • 80
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— A new technique, known as crack modelling, is used here to predict fatigue failure in a crankshaft component. The technique uses a linear elastic finite element (FE) analysis to derive a stress intensity factor (K) for the component under load. The novel feature of the technique is that K is calculated without introducing a crack into a component; the stress field around the maximum stress point is examined and compared to that for a standard centre-cracked plate. The fatigue limit for a crankshaft was successfully predicted, when compared to experimental data. The only material parameter required for this prediction was the threshold stress intensity range, ΔKth.
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  • 81
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— In this study, the relation between fracture toughness and mechanical properties, grain structure, temperature and strain rate is analysed on the basis of a thermo-activation analysis of the plastic deformation of metals.As a result of the study, the relationships obtained are of sufficient accuracy in relation to standard cracked samples of many steels.These relations can be used as a tool when designing new alloys which have a strong resistance to crack growth.This study is limited to temperatures in the range 0 ≤ T ≤ 0.2Tm and BCC metals.
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  • 82
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— A numerical model for determining the pitting resistance of gear teeth flanks is presented in this paper. The model considers the material fatigue process leading to pitting, i.e. the conditions required for crack initiation and then simulation of fatigue crack propagation. The theory of dislocation motion on persistent slip bands is used to describe the process of crack initiation, where the microstructure of a material plays a crucial role. The simulation of crack growth takes into account both short crack growth, where the modified Bilby, Cottrell and Swinden model is used for simulation of dislocation motion, and long crack growth, where the theory of linear elastic fracture mechanics is applied. The stress field in the contact area of meshing spur gear teeth and the functional relationship between the stress intensity factor and crack length are determined by the finite element method. For numerical simulations of crack initiation and crack propagation in the contact area of spur gear teeth, an equivalent model of two cylinders is used. On the basis of numerical results, and with consideration of some particular material parameters, the service life of gear teeth flanks is estimated. The developed model is applied to a real spur gear pair, which is also experimentally tested. The comparison of numerical and experimental results shows good agreement and it can be concluded that the developed model is appropriate for determining the pitting resistance of gear teeth flanks.
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  • 83
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— We consider the slow growth of normal tension cracks as quasi-brittle behaviour under hydrogen embrittlement conditions. Experiments show that the cracking resistance of a material in such cases is not a constant of the material, but is characterized by some function that relates the rate of crack growth to the stress intensity factor. We propose a numerical method for the calculation of opening mode crack growth when the kinetics are controlled by the gas diffusion into the material. The problems under consideration model the fracture phenomena inherent to structures (e.g. pressure vessels, pipelines) that operate in an aggressive medium and in particular a hydrogen environment.In such problems it is necessary to calculate the pressure variation inside a crack as a result of gas diffusion and crack growth under the action of this pressure. Hence it is necessary to solve problems of diffusion theory and elasticity theory for a cracked medium together with some additional conditions that provide the link between these two fundamental problems.We study the case of an infinite medium containing a crack which occupies a plane domain of arbitrary shape. To avoid difficulties related to the three-dimensionality of the problems, we reduce them to two-dimensional integro-differential equations for the crack domain. The integro-differential equation of the elasticity problem of the crack is solved on the basis of the Boundary Element Method (BEM). The crack kinetics are calculated using a scheme previously introduced by one of the authors and then the BEM is used to solve the integral equation for the diffusion-into-the-crack problem similar to the analogous problem of filtration of the fluid into a crack.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— An overview is presented of studies conducted at the University of Pisa on the Weight Function technique as applied to Fatigue Crack Grown analysis. The fundamental theoretical aspects of the technique are summarised, discussing some recent methods for the determination of the Weight Function. The application of the technique to non-linear (contact) problems and to the evaluation of the crack tip stress field is also discussed. It is shown that the Weight Function method allows one to efficiently consider many crack propagation problems, some examples of which are provided.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
    ISSN: 1460-2695
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— This paper analyses the validity of the fracture mechanics approach to hydrogen assisted cracking in metals on the basis of K-dominance over both the stress-strain state and the accumulation of hydrogen in the fracture process zone. Stress-strain assisted diffusion of hydrogen is considered as the rate controlling factor of hydrogen assisted cracking under sustained or quasi-static loading conditions. The discrepancy in the crack tip zone between the far-field affected diffusion and the asymptotically driven (K-controlled) process is elucidated. The far field (i.e., the stress-strain field which is not K-dominated) is shown to have a minor effect on near-tip hydrogen diffusion. It can only widen the scatter band of crack growth rates in the near-threshold portion of the crack growth kinetics curve.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— The yield criterion is interpreted as defining the metric of the stress space. Hydrostatic stresses correspond to null geodesies. The plastic strain increment represents a normal projection of the increment undergone by a certain scalar function (hardening function) which depends only on the distance between stress points. This establishes a flow rule formally equivalent to the Prandtl-Reuss equations. Consideration of un-loading processes leads to the analysis of equivalent paths and to the definition of a generalized length or separation which provides a new representation of kinematic hardening.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— An extended compact tension, EC(T), specimen has been developed for fatigue and fracture testing. The EC(T) specimen exhibits distinct advantages compared to other cracked specimen configurations, i.e., standard compact tension, single-edge crack, and middle-crack tension specimens. Documented herein are stress-intensity factor and compliance expressions for the EC(T) specimen.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— A new Dual Boundary Element formulation is presented, which allows for the analysis of mechanically fastened repairs and lap joints. The method requires only the boundaries of the problem to be discretized and the fasteners location is simply defined by a set of internal points.The technique enables the evaluation of fastener forces, sheet stresses and the stress intensity factors which are important parameters for a Damage Tolerance assessment.Examples of applications to repair designs and to a lap joint are presented to demonstrate the robustness of the new formulation that is proposed in this paper.
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  • 91
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— The effect of void shape on the mechanical behaviour of an elastic-plastic solid containing an isotropic array of aligned axisymmetric voids is examined. The mechanical response of such a material is studied by means of finite element (FE) analyses of an elementary unit cell containing an isolated void. The void shape is found to have a strong influence on both void growth rate and coalescence strain. This effect is strongest for low stress triaxialities. The numerical results are compared with analytical models of void growth, but none of the examined models give any good predictions of the results obtained numerically. A simple modification of the classical Gurson model is suggested so as to give reasonable correspondence with numerical results. Finally, some practical considerations of void shape effects are given.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— Structures made of quasibrittle materials show a marked decrease in strength as their size increases; this is the well known size effect on strength. This contribution proposes a general formula to predict with great accuracy the size effect of pre-cracked specimens. Such a formula provides the basis to determine experimentally the fracture parameters of a cohesive crack model from the measurement of the peak load in specimens with an initial crack. The formula is applicable whenever the fracture of the material can be described by a cohesive crack model with initial linear softening, as is generally accepted for concrete. Experimental evidence is presented showing that the formula is reasonably accurate also for rock.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— In this paper, the behaviour of the LEFM strip-yield model proposed by Newman and implemented in the FASTRAN II computer program is analyzed. The capabilities of the model to predict crack growth life under variable amplitude loading is considered. Special attention is paid to the effect of the constraint factors used to consider the stress condition (plane stress to plane strain), the effect of the finite length loading sequence and the effect of overloads into an irregular loading history. The results of simulation for 30 different loading histories obtained from the same stationary random process are analyzed and compared with the experimental results obtained for 2024-T351 aluminium alloy. The simulated lives present a fairly good fit with the experimental results, with a strong influence of the constraint factor selected and of the maximum peak in the loading history. Although predictions are usually good, it has been found that for any constraint factor producing good life predictions (with respect to the mean value of the Life obtained with the 30 loading histories) the results of each particular simulation may be over- or under-conservative depending on the maximum peak in the loading history used.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— The growth rate of fatigue cracks in two single crystal nickel base superalloys, CMSX-6 and SRR99, along the 〈001〉 planes are presented and rationalised in terms of two interacting crack propagation mechanisms: one attributed to crack tip plastic blunting and the other attributed to the brittle failure of the oxide scales. The role of the oxide scale is twofold as it also wedges the crack and modifies the blunting term through a crack closure effect. On the other hand, a positive effective stress intensity range is required to fracture the oxide scale. Fatigue tests were carried out at different temperatures (500 to 1050°C), frequencies (0.001 to 20 Hz), cycle waveforms and load ratios (0 to 0.9), with starter crack lengths of abut 100 μm. The model predictions match the crack growth rates obtained for both materials. Even though both materials are nickel base superalloys, they have very different oxidation behaviours. CMSX-6 has an improved oxidation resistance over SRR99, however, because of the twofold nature of the oxidation process, which material provides the better life expectancy depends on the applied test temperature and loading cycle.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— The precision with which the stress intensity factor (SIF) can be calculated from a finite element solution depends essentially on the extraction method and on the discretization error. In this paper, the influence of the discretization error in the SIF calculation was studied and a method for estimating the resulting error was developed. The SIF calculation method used is based on a shape design sensitivity analysis; this assures that the resulting error in the extracted SIF depends solely on the global discretization error present in the finite element solution. Moreover, this method allows us to extend the Zienkiewicz-Zhu discretization error estimator to the SIF calculation. The reliability of the proposed method was analysed solving a two-dimensional problem using an h-adaptive process. Also the convergence of the error with the h-adaptive refinement was studied.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— Fatigue tests conducted under fully reversed cyclic torsion, with and without superimposed axial static tension/compression loads, were carried out using hour-glass smooth specimens in laboratory air. A high strength spring steel and a 316L stainless steel, were employed to evaluate the effects of mean stress on fatigue performance. Experimental test results show that a biaxial tensile/compressive mean stress had no influence on the cyclic stress-strain response in both materials. However a biaxial tensile mean stress was found to be detrimental to fatigue life of the high strength spring steel but had no effect on the total fatigue life of 316L stainless steel. A compressive mean stress was found to be beneficial to the life of both steels. The fatigue behaviour of the two materials was investigated by experimental observations and the application of theoretical analyses of short crack growth behaviour. Based upon the analysis of surface acetate replicas it has been found that fatigue crack growth is material/stress-state dependent. A biaxial tensile static stress promoted a change in the direction of the Stage I (mode II) crack from the longitudinal direction to a plane normal to the specimen axis in the high strength steel but not in the stainless steel. Consequently a different growth behaviour of Stage I (mode II) cracks was observed for the two materials. The effect of a biaxial mean stress on fatigue crack growth behaviour of the two materials is analysed and described in some detail.
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    Fatigue & fracture of engineering materials & structures 20 (1997), S. 0 
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— Two L-notched specimens made of mild steel (average grain size =30 μm) and having root radii of 0.1 mm and 3 mm, and also a smooth surface specimen were cyclically loaded at different stress levels at R=−1 and at R= 0. A technique based on miniature strain gauges was successfully used to monitor the depth and the opening level of mechanically short cracks of depths from 0.015 mm to 0.5 mm. Three dimensional FEM computations were made to obtain appropriate calibration curves for varying crack aspect ratios and gauge eccentricities as well as notch plastic strain distributions. The fracture of L-notched specimens having a root radius of 0.1 mm was characterized by an early and multiple crack initiation phase (defined by a crack depth of 30 μm), and the short crack growth rates showed a mechanical behaviour different from that of long cracks (large discrepancies at the same ΔK-value, crack deceleration at R=−1 even beyond the notch plastic zone). For smooth surface specimens both the initiation and the propagation of a single short crack represented important fractions of the total life; the short crack growth rates were high and continuously increasing. The notch influence was highly reduced when the stress singularity is truncated by a 3 mm radius. The cracking behaviour was, in several aspects, close to that at smooth surfaces. The evolutions of crack closure were analyzed in each condition (transient decrease and stabilized value of the closure ratio U=ΔKeff/ΔK) and were shown to have a strong influence on short crack growth. Most of the short crack growth rates obtained in the various geometry/loading conditions are well consolidated with LEFM long crack growth rates using the ΔKeff parameter.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— The main object of this study is to apply the J-Q model in the transition region with emphasis on the thickness effects and the effects of constraint directly on the lower bound. If only cleavage without prior ductile growth is considered, then in the transition region the thickness effect may be small below a certain thickness. A model for predicting lower bounds from a limited number of data proposed by Stienstra and Anderson has been applied in connection with a J-Q constraint correction. The results are in good agreement with the predictions from a complete statistical analysis. A statistical analysis of the experimental data of cleavage without prior ductile growth, made after a J-Q constraint correction, shows that the latter is an appropriate procedure for evaluating small scale yielding fracture toughness of individual specimens or structures under such conditions.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— Fatigue strength, crack initiation and small crack growth behaviour in two kinds of squeeze-cast aluminium alloys, AC8A-T6 and AC4C-T6 were investigated using smooth specimens subjected to rotatary-bending fatigue at room temperature. Fatigue resistance of these alloys was almost the same as that of the wrought aluminium alloys because of their fine microstructure and of the decrease in defect size due to squeeze-casting. Fatigue crack initiation sites were at the eutectic silicon particles on the surface of specimens or at internal microporosity in the specimens. Crack initiation life, defined as a crack length of 50 μm on the specimen surface, was successfully estimated from an evaluation of initiation sites using fracture mechanics and the statistics of extrema. Small fatigue crack growth in the two kinds of alloys obeys the relation proposed by Nisitani et al., namely that d(2c)/dN = C(σa/σB)n· (2c), where C is a constant and σB is the ultimate tensile strength. It is pointed out that an improvement in fatigue strength of cast aluminium alloys can be expected by refining the eutectic silicon rather than by an increase in static strength.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract— The fatigue behaviour of polyoxymethylene (POM) of different molar mass (6.1 × 104–1.5 × 105) was studied at stress levels from 35 to 50 MPa (about 55 and 75% of the yield strength, respectively). It was found that cyclic loadings promoted bond breaking of the polymeric chains which considerably reduced the molar mass both in the crack tip region of cracked specimens and in the bulk in the case of uncracked samples. This process probably included the formation of reactive radicals which subsequently favoured the formation of microvoids that weakened the material. The static fracture toughness of fatigued samples decreased on increasing the stress level, the process accelerating as the cyclic loads approached the yield strength. As a result of material modifications during the tests the low molar mass resins did not exhibit stable crack propagation.
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