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  • Springer  (114,085)
  • Blackwell Publishing Ltd  (8,195)
  • Annual Reviews
  • 2005-2009  (47,770)
  • 1990-1994  (76,067)
  • 2007  (47,770)
  • 1994  (76,067)
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  • 2005-2009  (47,770)
  • 1990-1994  (76,067)
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  • 1
    Keywords: Biomass conversion ; Biotechnology ; Chemical Engineering ; Chemistry industry ; Industrial Chemistry ; Kent ; Riegel ; biochemical engineering
    Description / Table of Contents: Substantially revising and updating the classic reference in the field, this handbook offers a valuable overview and myriad details on current chemical processes, products, and practices. No other source offers as much data on the chemistry, engineering, economics, and infrastructure of the industry. The Handbook serves a spectrum of individuals, from those who are directly involved in the chemical industry to others in related industries and activities. It provides not only the underlying science and technology for important industry sectors, but also broad coverage of critical supporting topics. Industrial processes and products can be much enhanced through observing the tenets and applying the methodologies found in chapters on Green Engineering and Chemistry (specifically, biomass conversion), Practical Catalysis, and Environmental Measurements; as well as expanded treatment of Safety, chemistry plant security, and Emergency Preparedness. Understanding these factors allows them to be part of the total process and helps achieve optimum results in, for example, process development, review, and modification. Important topics in the energy field, namely nuclear, coal, natural gas, and petroleum, are covered in individual chapters. Other new chapters include energy conversion, energy storage, emerging nanoscience and technology. Updated sections include more material on biomass conversion, as well as three chapters covering biotechnology topics, namely, Industrial Biotechnology, Industrial Enzymes, and Industrial Production of Therapeutic Proteins.
    Pages: Online-Ressource (XIV, 1562 pages)
    ISBN: 9780387278438
    Language: English
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  • 2
    Publication Date: 2020-12-15
    Description: no abstract
    Description: Unpublished
    Description: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Description: open
    Keywords: earthquake location ; source parameters ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 3
    Publication Date: 2021-06-21
    Description: Earthquake early warning systems (EEWS), based on real-time prediction of ground motion or structural response measures, may play a role in re- ducing vulnerability and/or exposure of buildings and lifelines. Indeed, seismologists have recently developed efficient methods for real-time es- timation of an event’s magnitude and location based on limited informa- tion of the P-waves. Therefore, when an event occurs, estimates of magni- tude and source-to-site distance are available, and the prediction of the structural demand at the site may be performed by Probabilistic Seismic Hazard Analysis (PSHA) and then by Probabilistic Seismic Demand Analysis (PSDA) depending upon EEWS measures. Such an approach contains a higher level of information with respect to traditional seismic risk analysis and may be used for real-time risk management. However, this kind of prediction is performed in very uncertain conditions which may affect the effectiveness of the system and therefore have to be taken into due account. In the present study the performance of the EWWS under development in the Campania region (southern Italy) is assessed by simu- lation. The earthquake localization is formulated in a Voronoi cells ap- proach, while a Bayesian method is used for magnitude estimation. Simu- lation has an empirical basis but requires no recorded signals. Our results, in terms of hazard analysis and false/missed alarm probabilities, lead us to conclude that the PSHA depending upon the EEWS significantly improves seismic risk prediction at the site and is close to what could be produced if magnitude and distance were deterministically known.
    Description: Published
    Description: 211-232
    Description: 4.1. Metodologie sismologiche per l'ingegneria sismica
    Description: reserved
    Keywords: Earthquake Early ; Campania Region ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 4
    Publication Date: 2021-06-25
    Description: Unstructured hexahedral mesh generation is a critical part of the model- ing process in the Spectral-Element Method (SEM). We present some ex- amples of seismic wave propagation in complex geological models, automati- cally meshed on a parallel machine based upon CUBIT (Sandia Laboratory, cubit.sandia.gov), an advanced 3D unstructured hexahedral mesh genera- tor that offers new opportunities for seismologist to design, assess, and improve the quality of a mesh in terms of both geometrical and numerical accuracy. The main goal is to provide useful tools for understanding seismic phenomena due to surface topography and subsurface structures such as low wave-speed sedimentary basins. Our examples cover several typical geophysical problems: 1) “layer-cake” volumes with high-resolution topography and complex solid- solid interfaces (such as the Campi Flegrei Caldera Area in Italy), and 2) models with an embedded sedimentary basin (such as the Taipei basin in Taiwan or the Grenoble Valley in France).
    Description: Published
    Description: 3.1. Fisica dei terremoti
    Description: 4.1. Metodologie sismologiche per l'ingegneria sismica
    Description: reserved
    Keywords: meshing ; seismic wave propagation ; spectral element methond ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis ; 05. General::05.01. Computational geophysics::05.01.05. Algorithms and implementation
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 5
    Publication Date: 2020-11-30
    Description: This special issue of Journal of Seismology, dedicated to Archaeoseismology, shows the current trends of research in this young branch of seismology. The beginning of modern archaeoseismological practice during the 1980’s and the investigations made during the 1990’s were in many cases conditioned by the lack of cooperation among the spcialists from different scientific diciplines. Numerous publications resulted from the work of archaeologists, in some cases in collaboration with experts in earthquake-geology or seismology, but rarely such work included a complete and multidisciplinary approach and in situ analysis of the evidence. In many cases, archaeoseismological studies were limited to the detection of traces of past earthquakes in archaeological remains without a seismological perspective aiming to derive quantitative parameters necessary to fully describe a past earthquake (magnitude, etc.). In other cases, such investigations were limited to the analysis of archaeological reports of excavations made years or decades earlier. A step towards the quantification of seismological aspects was represented by the “territorial” approach, trying to reconstruct a picture of an earthquake by detecting its signs over a wider region. This procedure was, however, limited by the scarcity and reliability of published or unpublished archaeological material, usually adopted without a critical review.
    Description: Published
    Description: 393–394
    Description: 2TM. Divulgazione Scientifica
    Description: JCR Journal
    Description: open
    Keywords: Archaeoseismology, ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 136231 bytes
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  • 6
    Publication Date: 2020-11-23
    Description: Scattering ratios R processed from the same raw data at 353 and 532 nm by different lidar groups agree within about 10 % for high and within about 4 % for low aerosol loading. In the main layer aerosol backscatter coefficients agree within about 30 % for high and within about 40 % for low aerosol loading
    Description: Published
    Description: Berlin, Germany
    Description: 1.8. Osservazioni di geofisica ambientale
    Description: open
    Keywords: NDCS ; LIDAR ; 01. Atmosphere::01.01. Atmosphere::01.01.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 7
    Publication Date: 2017-04-04
    Description: Volcanic hazard assessment is a basic ingredient for risk-based decision-making in land-use planning and emergency management. Volcanic hazard is defined as the probability of any particular area being affected by a destructive volcanic event within a given period of time (Fournier d’Albe 1979). The probabilistic nature of such an important issue derives from the fact that volcanic activity is a complex process, characterized by several and usually unknown degrees of freedom that are often linked by nonlinear relationships (e.g. Bak et al. 1988). Except in sporadic cases, the result of this complexity is an intrinsic, and perhaps unavoidable, unpredictability of the time evolution of the volcanic system from a deterministic point of view.
    Description: Published
    Description: open
    Keywords: model ; volcanic risk ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book
    Format: 137534 bytes
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  • 8
    Publication Date: 2017-04-04
    Description: In order to empirically obtain the scaling relationships for the high-frequency ground motion in the Western Alps (NW Italy), regressions are carried out on more than 7500 seismograms from 957 regional earthquakes. The waveforms were selected from the database of 6 three-component stations of the RSNI (Regional Seismic network of Northwestern Italy). The events,MW ranging between 1.2 and 4.8, were recorded within a hypocentral distance of 200 km during the time period: 1996–2001. The peak ground velocities are measured in selected narrow-frequency bands, between 0.5 and 14 Hz. Results are presented in terms of a regional attenuation function for the vertical ground motion, a set of vertical excitation terms at the reference station STV2 (hard-rock), and a set of site terms (vertical and horizontal), all relative to the vertical component of station STV2. The regional propagation of the ground motion is modeled after quantifying the expected duration of the seismic motion as a function of frequency and hypocentral distance. A simple functional form is used to take into account both the geometrical and the anelastic attenuation: a multi-variable grid search yielded a quality factor Q( f ) = 310 f 0.20, together with a quadri-linear geometrical spreading at low frequency. A simpler, bilinear geometrical spreading seems to be more appropriate at higher frequencies (f 〉 1.0 Hz). Excitation terms are matched by using a Brune spectral model with variable, magnitude-dependent stress drop: at Mw 4.8, we used σ = 50MPa. A regional distanceindependent attenuation parameter is obtained (κ0 = 0.012 s) by modelling the average spectral decay at high frequency of small earthquakes. In order to predict the absolute levels of ground shaking in the region, the excitation/attenuation model is used through the Random Vibration Theory (RVT) with a stochastic point-source model. The expected peak-ground accelerations (PGA) are compared with the ones derived by Ambraseys et al. (1996) for the Mediterranean region and by Sabetta and Pugliese (1996) for the Italian territory.
    Description: Published
    Description: 315-333
    Description: JCR Journal
    Description: reserved
    Keywords: Attenuation ; Ground motion ; Western Alps ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 9
    Publication Date: 2017-04-04
    Description: In the study area physical and chemical factors control the composition of surface and groundwaters, which in turn determine the water quality of the “Biviere di Gela” lake. These factors combine to create diverse water types which change their compositional character spatially as rainfall infiltrates the soil zone, moves down a topographically defined flow path, and interacts with bedrock minerals. Low-salinity waters, which represent the initial stage of underground circulation, start dissolving calcium carbonate from the local rocks. The progressive increase in salinity, characterized by substantially higher Ca, SO4, Na and Cl concentrations, suggests that dissolution of CaSO4 and NaCl is an important process during water–rock interactions. The “Biviere di Gela” lake is often separated into two units (Lago Grande and Lago Piccolo). “Lago Grande” water is generally of Na-SO4-Cl-type, whereas “Lago Piccolo” water is of Na-Cl-SO4-type. Their total content of dissolved salts varies with season, the amount of rainfall, and inflow of ground and drainage water. Over time, an increasing trend towards greater salinity and also sudden changes in the relative abundances of Cl and SO4 have been recorded for the “Lago Grande.” The isotope composition of the lake water appears to be affected by inflow of ground and surface waters and also by evaporative loss. The nitrate content of waters from the recharge basin is of particular concern because it contributes to lake eutrophication. The trace element contents do not evidence the presence of any significant metal contamination of lake waters, although a future potential hazard of metals bioaccumulation by the aquatic biota must be taken into consideration. Finally, a water balance for the basin shows that a drop in precipitation of about 20% might be critical for lake survival.
    Description: Published
    Description: JCR Journal
    Description: reserved
    Keywords: wetland area ; hydrogeochemistry ; environmental geochemistry ; isotope geochemistry ; water balance ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
    Publication Date: 2017-04-04
    Description: In August 2000 and July 2001 two seismic sequences, characterized by mainshocks with Ml (local magnitude) respectively 5.1 and 4.8, occurred in the Monferrato region (Italy). The regional seismic network of North-western Italy (RSNI) recorded more than 250 foreshocks and aftershocks. The routine locations, obtained from the Hypoellipse code, show a seismic activity concentrated in a circular area, of a radius of about 15 km, located near Acqui Terme, and randomly distributed in depth. Location errors, due to an uneven azimuthal station distribution of the regional seismic network, prevent recognition of the geometry of the active zone. Waveform analysis revealed the presence of several multiplets. In order to discriminate and successively relocate them, an automatic cross-correlation procedure was applied. Normalized cross-correlation matrixes, for the RSNI stations which recorded almost 90% of considered events, on the basis of a signal to noise ratio analysis, were computed using only S wave time windows. The use of a relocation procedure, based on the double-difference method which incorporates ordinary absolute travel-time measurements and/or cross-correlation differential travel-times, allowed us to overcome the constraints of the uneven distribution of stations giving a quite different frame of seismicity. The improved locations showed that the seismic activity is mainly arranged along a NE-SW oriented volume, at a depth range of 8–20 km, involving the basement crystalline units. This orientation is confirmed by the analysis of the focal mechanisms: most focal solutions show a strike slip component with one of the nodal planes consistent with the main orientation of the seismic events.
    Description: Published
    Description: 1-22
    Description: JCR Journal
    Description: reserved
    Keywords: earthquake clusters ; waveform ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 11
    Publication Date: 2017-04-04
    Description: Measurement of effusion rate is a primary objective for studies that model lava flow and magma system dynamics, as well as for monitoring efforts during on-going eruptions. However, its exact definition remains a source of confusion, and problems occur when comparing volume flux values that are averaged over different time periods or spatial scales, or measured using different approaches. Thus our aims are to: (1) define effusion rate terminology; and (2) assess the various measurement methods and their results. We first distinguish between instantaneous effusion rate, and time-averaged discharge rate. Eruption rate is next defined as the total volume of lava emplaced since the beginning of the eruption divided by the time since the eruption began. The ultimate extension of this is mean output rate, this being the final volume of erupted lava divided by total eruption duration. Whether these values are total values, i.e. the flux feeding all flow units across the entire flow field, or local, i.e. the flux feeding a single active unit within a flow field across which many units are active, also needs to be specified. No approach is without its problems, and all can have large error (up to ∼50%). However, good agreement between diverse approaches shows that reliable estimates can be made if each approach is applied carefully and takes into account the caveats we detail here. There are three important factors to consider and state when measuring, giving or using an effusion rate. First, the time-period over which the value was averaged; second, whether the measurement applies to the entire active flow field, or a single lava flow within that field; and third, the measurement technique and its accompanying assumptions.
    Description: Published
    Description: 1-22
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: Lava ; Instantaneous effusion rate ; Time-averaged discharge rate ; Eruption rate ; Monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 12
    Publication Date: 2017-04-03
    Description: Soil-temperature measurements can provide information on the distribution of degassing fissures, their relationship to the internal structure of the volcano, and the temporal evolution of the system. At Vulcano Island (Italy) heat flux from a 〈3 km-deep magma body drives a hydrothermal system which extends across the main Fossa crater. This heat flux is also associated with variable magmatic gas flow. A high density map of soil-temperatures was made in 1996 at a constant depth of 30 cm on the central and southern inner flanks of the Fossa crater. These measurements extended over an area covering about 0.04 km2, across which the heat flux is predominantly associated with a shallow boiling aquifer. The map shows that hot zones relate to structures of higher permeability, mainly associated with a fissure system dating from the last eruptive cycle (1888-90). From 1996 to January 2005, we studied the evolution of the heat flux for the high temperature part of the map, both by repeating our measurements as part of fourteen visits, during which temperatures were measured at a constant depth, and using data from permanent stations which allowed soil-temperatures to be continuously measured for selected vertical profiles. These data allowed us to calculate the heat flux, and its variation, with good precision for values lower than about 100 W m-2, which is generally the case in the study area. Above 100 W m-2 although the heat flux value is underestimated its variations are recorded with an error less than 10%. During the period 1996-2004 two increases in the thermal flux were recorded. The first one was related to the seismic crisis of November 1998 which opened existing or new fissures. The second, in November 2004, was probably due to magma migration, and was associated with minor seismic activity.
    Description: Published
    Description: on line first
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: partially_open
    Keywords: hydrothermal flux ; soil temperature ; monitoring ; seismic activity ; Vulcano ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 13
    Publication Date: 2017-04-04
    Description: The main purpose of this paper is to introduce a Bayesian event tree model for eruption forecasting (BET EF). The model represents a flexible tool to provide probabilities of any specific event at which we are interested in, by merging all the relevant available information, such as theoretical models, a priori beliefs, monitoring measures, and any kind of past data. BET EF is based on a Bayesian procedure and it relies on the fuzzy approach to manage monitoring data. The method deals with short- and long-term forecasting, therefore it can be useful in many practical aspects, as land use planning, and during volcanic emergencies. Finally, we provide the description of a free software package that provides a graphically supported computation of short- to long-term eruption forecasting, and a tutorial application to the recent MESIMEX exercise at Vesuvius.
    Description: Published
    Description: on line first
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: partially_open
    Keywords: Eruption forecasting ; Long- and short-term volcanic hazard ; Bayesian inference ; Event tree ; Fuzzy sets ; MESIMEX ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 14
    Publication Date: 2017-04-04
    Description: Ice streams play a major role in the ice mass balance and in the reckoning of the global sea level; they have therefore been object of wide scientific interest in the last three decades. During the 21st Italian Antarctic Expedition, in the austral summer 2005-06, we deployed a joint seismographic and geodetic network in the area of the David Glacier, Southern Victoria Land. This campaign followed a similar experiment carried out in the same area during the austral summer 2003-04 with the deployment of a seismographic network that recorded significant microseismicity beneath the David Glacier, primarily occurring as a few small clusters. In the latest 2005-06 deployment, 7 seismographic stations and 3 GPS geodetic receivers operated continuously for a period of 3 months (November 2005-early February 2006) in an area of about 100x150 km2 around the David Glacier. We have carried out several analyses using the combined data sets. These included the examination of the temporal evolution in earthquake magnitude and location and also the contemporaneous observation of both seismic activity and surface kinematics of the ice stream to possibly correlate the recorded microseismicity with the movement of the glacier, affected by the Ross Sea tides. Here we present some details of the two temporary networks and preliminary results and implications.
    Description: Submitted
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: open
    Keywords: Ice dynamics ; 02. Cryosphere::02.02. Glaciers::02.02.05. Ice dynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 15
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    Springer
    Publication Date: 2017-04-04
    Description: Iron sulfides are generally quoted as minor magnetic minerals and the interest of paleomagnetists for this family of minerals progressively developed only during the last 10 – 15 years. This was due partly to the fact that their occurrence was originally believed to be restricted to peculiar geological environments (i.e. sulfidic ores, anoxic sulfate-reducing sedimentary environments) and partly to their metastability with respect to pyrite (FeS2), which is paramagnetic. Magnetic iron sulfides were therefore not expected to carry a stable remanent magnetisation and to survive over long periods of geological time in sedimentary environments. However, their occurrence as main carriers of a remanent magnetisation stable through geological times has been increasingly reported in recent years from a large variety of rock types, primarily as a result of more frequent application of magnetic methods to characterize the magnetic mineralogy in paleomagnetic samples. The recognition of the widespread occurrence of magnetic iron sulfides as stable carriers of natural remanent magnetisations in rocks propelled specific researches on their fundamental magnetic properties.
    Description: Published
    Description: 454-459
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: open
    Keywords: iron sulfides ; greigite ; pyrrhotite ; 04. Solid Earth::04.05. Geomagnetism::04.05.07. Rock magnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 16
    Publication Date: 2017-04-04
    Description: For early-warning applications in particular, the reliability and efficiency of rapid scenario generation strongly depend on the availability of reliable strong ground-motion prediction tools. If shake maps are used to represent patterns of potential damage as a consequence of large earthquakes, attenuation relations are used as a tool for predicting peak ground-motion parameters and intensities. One of the limitations in the use of attenuation relations is that these have only rarely been retrieved from data collected in the same tectonic environment in which the prediction has to be performed. As a consequence, strong ground motion can result in underestimations or overestimations with respect to the recorded data. This also holds for Italy, and in particular for the Southern Apennines, due to limitations in the available databases, both in terms of distances and magnitude. Moreover, for “real-time” early-warning applications, it is important to have attenuation models for which the parameters can be easily upgraded when new data are collected, whether this has to be done during the earthquake rupture occurrence or in the post-event, when all the strong motion waveforms are available. Here we present a strong-motion attenuation relation for early-warning applications in the Campania region (Southern Apennines), Italy. The model has a classical analytical formulation, and its coefficients were retrieved from a synthetic strong-motion database created by using a stochastic approach. The input parameters for the simulation technique were obtained through the spectral analysis of waveforms of earthquakes recorded by the Istituto Nazionale di Geofisica e Vulcanologia (INGV) network for a magnitude range Md (1.5,5.0) in the last fifteen years, and they have been extrapolated to cover a larger range. To validate the inferred relation, comparisons with two existing attenuation relations are presented. The results show that the calibration of the attenuation parameters, i.e., geometric spreading, quality factor Q, static stress drop values along with their uncertainties, are the main concern.
    Description: Published
    Description: 133-152
    Description: 4.1. Metodologie sismologiche per l'ingegneria sismica
    Description: reserved
    Keywords: A Strong Motion ; Earlywarning ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 17
    Publication Date: 2017-04-04
    Description: Igneous garnets have the potential to strongly fractionate rare earth elements (REE). Yet informations on partition coefficients are very scant, and criteria for distinguishing between hydrothermal and magmatic garnets are ambiguous. To fill this gap, we present trace element and isotopic data for two types of Ca-rich garnets from phonolites (Mt. Somma- Vesuvius). Both Ca-garnet populations are different in their style and dynamics of fractionation: one population is progressively strongly depleted in HREE from core to rim, reflecting REE fractionation in the host phonolite via earlier-crystallized garnets. Such examples for extreme changes in HREE in garnets are only known for hydrothermal grandites by REE-bearingfluids. The second garnet population is homogeneous and formed in a closed system. Near-flat patterns between Sm and Lu confirm experimental data indicating lower D(Sm)/D(Lu) for Ca-rich garnets than for e.g. pyrope-rich garnets. It follows: DGrt/PhMelt for La = 0.5, Sm = 48 and Yb = 110.
    Description: Published
    Description: 55-74
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: Grandite ; Ca-rich garnets ; Andradite ; Rare earth elements ; Fractionation ; Partition coefficient ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 18
    Publication Date: 2017-04-04
    Description: In the framework of an ongoing project financed by the Campania Region, a prototype system for seismic early and post-event warning is being developed and tested, based on a dense, wide dynamic seismic network (ISNet) and under installation in the Apennine belt region. This paper reports the characteristics of the seismic network, focussing on the required technological innovation of the different seismic network components (data-logger, sensors and data communication). To ensure a highly dynamic recording range, each station is equipped with two types of sensors: a strong-motion accelerometer and a velocimeter. Data acquisition at the seismic stations is performed using Osiris-6 model data-loggers made by Agecodagis. Each station is supplied with two (120 W) solar panels and two 130 Ah gel cell batteries, ensuring 72-h autonomy for the seismic and radio communication equipment. The site is also equipped with a GSM/GPRS programmable control/alarm system connected to several environmental sensors (door forcing, solar panel controller, battery, fire, etc) and through which the site status is known in real time. The data are stored locally on the hard-disk and, at the same time, continuously transmitted by the SeedLink protocol to local acquisition/analysis nodes (Local Control Center) via Wireless LAN bridge. At each LCC site runs a linux Earthworm system which stores and manages the acquired data stream. The real-time analysis system will perform event detection and localization based on triggers coming from data-loggers and parametric information coming from the other LCCs. Once an event is detected, the system will performs automatic magnitude and focal mechanism estimations. In the immediate post-event period, the RISSC performs shaking map calculations using parameters from the LCCs and/or data from the event database. The recorded earthquake data are stored into an event database, to be available for distribution and visualization for further off-line analyses. The seismic network will be completed in two stages: • Deployment of 30 seismic stations along the southern Apennine chain (to date almost completed) • Setting up a carrier-class radio communication system for fast and reliable data transmission, and installation of 10 additional seismic stations.
    Description: Published
    Description: 325 - 341
    Description: 4.1. Metodologie sismologiche per l'ingegneria sismica
    Description: reserved
    Keywords: Monitoring Infrastructure ; Early-warning Applications ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 19
    Publication Date: 2017-04-04
    Description: The area of Serravalle, sited in the northern part of the town of Vittorio Veneto (TV), NE Italy, has been the target of a seismic microzonation campaign. 10 seismic stations have been deployed for a 7 months period to record in continuous mode. Three stations were installed on bedrock outcrops and seven on sedimentary sites with variable cover thickness. Spectral analyses have been performed on the collected data-set using the Generalized Inversion Technique (GIT, e.g. Andrews, 1986). In particular, spectral ratios have been calculated for each station relatively to the average of the three reference, bedrock sites. The spectral ratios provide quantitative estimates of the seismic motion amplifications which occur in each of the monitored sites. Two sites show high values of amplification, 5 times larger than signal amplitude at the reference sites, in correspondence of well discernible peak frequencies of 5 Hz. Results for the other stations show smaller amounts of site amplification spreading over a broad range of frequencies. Sites where the highest amplifications were recorded all lie on the left bank of the Meschio River and in areas farther away from its outlet into the plain correlating with the presence of thick layers of Quaternary deposits.
    Description: Published
    Description: 31-49
    Description: 4.1. Metodologie sismologiche per l'ingegneria sismica
    Description: JCR Journal
    Description: reserved
    Keywords: spectral ratios ; reference sites ; site effects ; earthquake grounf motion ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 20
    Publication Date: 2017-04-04
    Description: In October and November 2002, the Molise region (southern Italy) was struck by two moderate magnitude earth- quakeswithin 24 hours followed by an onemonth long aftershocks sequence. Soon after the ?rstmainshock (October 31st, 10.32 UTC, Mw 5.7), we deployed a temporary network of 35 three-component seismic stations. At the time of occurrence of the second main event (November 1st, 15.08 UTC, Mw 5.7) the eight local stations already installed allowed us to well constrain the hypocentral parameters. We present the location of the two mainshocks and 1929 aftershocks with 2 〈 ML 〈 4.2. Earthquake distribution reveals a E-trending 15 km long fault system composed by two main segments ruptured by the two mainshocks. Aftershocks de?ne two sub-vertical dextral strike-slip fault segments in agreementwith themainshock fault plane solutions. P- and T -axes retrieved from170 aftershocks focal mechanisms show a coherent kinematics: with a sub-horizontal NW and NE-trending P and T -axes, respectively. Fora small percentage of focal mechanisms (~10%) a rotation of T axes is observed, resulting in thrust solutions. The Apenninic active normal fault belt is located about 80 km westward of the 2002 epicentral area and signi?cant seismicity occurs only 20-50 km to the east, in the Gargano promontory. Seismic hazard was thought to be small for this region because neither historical earthquake are reported in the Italian seismic catalogue or active faults were previously identi?ed. In this context, the 2002 seismic sequence highlights the existence of trans-pressional active tectonics in between the extensional Apenninic belt and the Apulian foreland.
    Description: Published
    Description: 487-494
    Description: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Description: JCR Journal
    Description: reserved
    Keywords: Molise seismic sequence ; strike slip fault system ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 21
    Publication Date: 2017-04-04
    Description: A ground magnetic study of Ustica Island was performed to provide new insights into subsurface tectonic and volcanic structures. The total-intensity anomaly field, obtained after a data-reduction procedure, shows the presence of a W–E-striking magnetic anomaly in the middle of the island and another two intense anomalies, which seem to continue offshore, in the southwestern and the northeastern sides, respectively. The detected anomalies were analyzed by a quadratic programming (QP) algorithm to obtain a 3D subsurface magnetization distribution. The volcano magnetization model reveals the presence of intensely magnetized volumes, interpreted as the feeding systems of the main eruptive centers of the island, which roughly follow the trend of the main regional structural lineaments. These findings highlight how regional tectonics has strongly affected the structural and magmatic evolution of the Ustica volcanic complex producing preferential ways for magma ascent.
    Description: Published
    Description: 869-879
    Description: JCR Journal
    Description: reserved
    Keywords: Magnetic survey ; Ustica Island ; Inverse magnetic modeling ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods
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    Type: article
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  • 22
    Publication Date: 2017-04-04
    Description: Seismicity is recognized to be a complex natural phenomenon either in space, time and energy domains: earthquakes occur as a sudden energy release after a strongly variable time period of stress accumulation, in locations not deterministically defined, with magnitude range spanning over several orders. But seismicity is certainly not a pure random process: spatial locations of events clearly display correlations with tectonic structures at all scales (from plates borders to small faults settings); on the other hand time evolution is clearly linked with strongest shocks occurrence and energy distribution displays hierarchical features. Although it is still not possible to propose deterministic models for earthquakes, well established statistical relations constrain seismicity under very specific and intriguing relations.
    Description: Published
    Description: 259-279
    Description: reserved
    Keywords: Earthquake ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability ; 05. General::05.01. Computational geophysics::05.01.04. Statistical analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 23
    Publication Date: 2017-04-04
    Description: In this article the implementation and potential of the Seismotectonic Information System of the Campania Region (SISCam) are described, in particular an application of this Web-based GIS system to the seismotectonic analysis of the Sannio area (Southern Apennines) is performed. WEB-GIS technologies greatly contribute to both the environmental monitoring and the disaster management of areas affected by high natural risks. Specifically the SISCam system has been developed with the aim of providing easy access and fast diffusion, through Internet technology, of the most significant geological, geophysical, and territorial data relative to the Campania Region. The Sannio area has been selected as our application example because it is among the most active seismic regions in Italy. This portion of the Southern Apennines which was hit by the June 5, 1688 strong earthquake (MW = 6.7, CPTI 1999) and by some low- and moderate-energy seismic sequences (1990–1992, 1997), is characterized by a complex inherited tectonic setting and low-tectonic deformation rates that hide the seismogenic sources position. Since this case study turned out to be complicated, the use of the SIScam WEB-GIS has become indispensable because it allowed us to visualize, integrate and analyze all the data available, in order to obtain an accurate and direct picture of the seismotectonic setting of the area. Moreover, a different approach of data analysis was necessary, due to the lack of up-todate neotectonic and structural data; therefore, the operation of this GIS system enabled us to process and generate some original informative layers, through image analysis, such as new structural lineaments represented on a map of the potential active faults of the area, which has been the final result of our application, as a contribution to new knowledge about the local seismic risk parameters.
    Description: Published
    Description: on line first
    Description: 5.4. TTC - Sistema Informativo Territoriale
    Description: JCR Journal
    Description: reserved
    Keywords: Web-based GIS ; Seismotectonic data ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 05. General::05.02. Data dissemination::05.02.02. Seismological data
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  • 24
    Publication Date: 2017-04-04
    Description: There is a strong movement by many universities, libraries and organizations to participate in the open access movement in order to provide fast, up-to-date, easily accessible, permanent and free-of-charge sources of information for users of scholarly research. Although many publishers and journals may allow authors to archive their work under certain conditions (there may be copyright restrictions in making an e-print freely available); other publishers are more restrictive. Open access repositories may make research available even prior to a peer-reviewed printed publication, as well as unpublished material. Here lies the challenge to discern between refereed (post-print) and non-refereed (or preprint) material.
    Description: Published
    Description: 923-926
    Description: 5.7. TTC - Biblioteche ed editoria
    Description: JCR Journal
    Description: partially_open
    Keywords: Open access repositories ; ePIC ; Earth-prints ; 05. General::05.03. Educational, History of Science, Public Issues::05.03.99. General or miscellaneous
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  • 25
    Publication Date: 2017-04-04
    Description: Microgravity observations at Mt. Etna have been routinely performed as both discrete (since 1986) and continuous (since 1998) measurements. In addition to describing the methodology for acquiring and reducing gravity data from Mt. Etna, this paper provides a collection of case studies aimed at demonstrating the potential of microgravity to investigate the plumbing system of an active volcano and detect forerunners to paroxysmal volcanic events. For discrete gravity measurements, results from 1994– 1996 and 2001 are reported. During the first period, the observed gravity changes are interpreted within the framework of the Strombolian activity which occurred from the summit craters. Gravity changes observed during the first nine months of 2001 are directly related to subsurface mass redistributions which preceded, accompanied and followed the July-August 2001 flank eruption of Mt. Etna. Two continuous gravity records are discussed: a 16-month (October 1998 to February 2000) sequence and a 48-hour (26–28 October, 2002) sequence, both from a station within a few kilometers of the volcano’s summit. The 16-month record may be the longest continuous gravity sequence ever acquired at a station very close to the summit zone of an active volcano. By cross analyzing it with contemporaneous discrete observations along a summit profile of stations, both the geometry of a buried source and its time evolution can be investigated. The shorter continuous sequence encompasses the onset of an eruption from a location only 1.5 km from the gravity station. This gravity record is useful for establishing constraints on the characteristics of the intrusive mechanism leading to the eruption. In particular, the observed gravity anomaly indicates that the magma intrusion occurred ‘‘passively’’ within a fracture system opened by external forces.
    Description: Published
    Description: 769-790
    Description: 2.6. TTC - Laboratorio di gravimetria, magnetismo ed elettromagnetismo in aree attive
    Description: JCR Journal
    Description: reserved
    Keywords: Mt. Etna ; microgravity ; 04. Solid Earth::04.03. Geodesy::04.03.05. Gravity variations
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  • 26
    Publication Date: 2017-04-04
    Description: A set of experiments forced with observed SST has been performed with the Echam4 atmospheric GCM at three different horizontal resolutions (T30, T42 and T106). These experiments have been used to study the sensitivity of the simulated Asian summer monsoon (ASM) to the horizontal resolution. The ASM is reasonably well simulated by the Echam4 model at all resolutions. In particular, the low-level westerly flow, that is the dominant manifestation of the Asian summer monsoon, is well captured by the model, and the precipitation is reasonably simulated in intensity and space appearance. The main improvements due to an higher resolution model are associated to regional aspects of the precipitation, for example the Western Ghats precipitation is better reproduced. The interannual variability of precipitation and wind fields in the Asian monsoon region appears to be less affected by an increase in the horizontal resolution than the mean climatology is. A possible reason is that the former is mainly SST-forced. Besides, the availability of experiments at different horizontal resolution realized with the Echam4 model coupled to a global oceanic model allows the possibility to compare these simulations with the experiments previously described. This analysis showed that the coupled model is able to reproduce a realistic monsoon, as the basic dynamics of the phenomenon is captured. The increase of the horizontal resolution of the atmospheric component influences the simulated monsoon with the same characteristics of the forced experiments. Some basic features of the Asian summer monsoon, as the interannual variability and the connection with ENSO, are further investigated.
    Description: Published
    Description: 273-290
    Description: 3.7. Dinamica del clima e dell'oceano
    Description: JCR Journal
    Description: reserved
    Keywords: monsoon ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate
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  • 27
    Publication Date: 2012-02-03
    Description: Archaeoseismic research contributes important data on past earthquakes. A limitation of the usefulness of archaeoseismology is due to the lack of continuous discussion about the methodology. The methodological issues are particularly important because archaeoseismological investigations of past earthquakes make use of a large variety of methods. Typical in situ investigations include: (1) reconstruction of the local archaeological stratigraphy aimed at defining the correct position and chronology of a destruction layer, presumably related to an earthquake; (2) analysis of the deformations potentially due to seismic shaking or secondary earthquake effects, detectable on walls; (3) analysis of the depositional characteristics of the collapsed material; (4) investigations of the local geology and geomorphology to define possible natural cause(s) of the destruction; (5) investigations of the local factors affecting the ground motion amplifications; and (6) estimation of the dynamic excitation, which affected the site under investigation. Subsequently, a ‘territorial’ approach testing evidence of synchronous destruction in a certain region may delineate the extent of the area struck by the earthquake. The most reliable results of an archaeoseismological investigation are obtained by application of modern geoarchaeological practice (archaeological stratigraphy plus geological–geomorphological data), with the addition of a geophysicalengineering quantitative approach and (if available) historical information. This gives a basic dataset necessary to perform quantitative analyses which, in turn, corroborate the archaeoseismic hypothesis. Since archaeoseismological investigations can reveal the possible natural causes of destruction at a site, they contribute to the wider field of environmental archaeology, that seeks to define the history of the relationship between humans and the environment. Finally, through the improvement of the knowledge on the past seismicity, these studies can contribute to the regional estimation of seismic hazard.
    Description: Published
    Description: 395-414
    Description: JCR Journal
    Description: reserved
    Keywords: archaeoseismology ; historical seismology ; geoarchaeology ; environmental archaeology ; natural catastrophes ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology
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  • 28
    Publication Date: 2017-04-04
    Description: No abstract
    Description: Published
    Description: 117-118
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: open
    Keywords: geomorphology ; tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
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  • 29
    Publication Date: 2017-04-04
    Description: The effect of climate change on the Brewer– Dobson circulation and, in particular, the large-scale seasonal-mean transport between the troposphere and stratosphere is compared in a number of middle atmosphere general circulation models. All the models reproduce the observed upwelling across the tropical tropopause balanced by downwelling in the extra tropics, though the seasonal cycle in upwelling in some models is more semi-annual than annual. All the models also consistently predict an increase in the mass exchange rate in response to growing greenhouse gas concentrations, irrespective of whether or not the model includes interactive ozone chemistry. The mean trend is 11 kt s–1 year–1 or about 2% per decade but varies considerably between models. In all but one of the models the increase in mass exchange occurs throughout the year though, generally, the trend is larger during the boreal winter. On average, more than 60% of the mean mass fluxes can be explained by the EP-flux divergence using the downward control principle. Trends in the annual mean mass fluxes derived from the EP-flux divergence also explain about 60% of the trend in the troposphere-to-stratosphere mass exchange rate when averaged over all the models. Apart from two models the interannual variability in the downward control derived and actual mass fluxes were generally well correlated, for the annual mean.
    Description: Published
    Description: 727-741
    Description: JCR Journal
    Description: reserved
    Keywords: anthropogenic change ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate
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  • 30
    Publication Date: 2017-04-04
    Description: Polar stratospheric clouds (PSC) play a major role in the process of Arctic and Antarctic ozone depletion due to heterogeneous chemical reactions responsible for chlorine acti-vation, and particle sedimentation redistributing nitrogen species in the stratosphere. Therefore the phase, size and the composition of PSCs should be known. PSC can be divided into PSC type I, observed at temperatures some degrees above the ice frostpoint, and PSC type II consisting of water ice particles occurring at temperatures below the frostpoint. PSC type I can be subdivided into aspherical (type Ia) and spherical (type Ib) particles. Measurements of gas phase HNO3 removal in presence of PSCs and labora¬tory studies led to the assumption that PSC type I consist of nitric acid trihydrate and theparticle shape depends on the cooling rate [1]. However the explanation ofPSC I based solely on the NAT-hypothesis can not explain a large amount of data [2], and other compositions like liquid supercooled ternary solu¬tions (STS) of H2O, HNO3 and H2SO 4 are discussed now [3].Multiwavelength, 2-polarization lidar measurements give information about the size distribution, refractive index and physical state of the cloud particles.
    Description: Published
    Description: Berlin, Germany
    Description: 1.8. Osservazioni di geofisica ambientale
    Description: open
    Keywords: PSC ; LIDAR ; 01. Atmosphere::01.01. Atmosphere::01.01.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 31
    Publication Date: 2017-04-04
    Description: Hydrological and geochemical studies performed on Lake Specchio di Venere on Pantelleria island (Italy) indicate that this endorheic basin has been formed through upwelling of the water table, and that it is continuously fed by the thermal springs situated on its shores. The lake is periodically stratified both thermally and in salinity, albeit this stratification is rather unstable over time since meteorological events such as strong rain or wind can determine the mixing of its waters. Periodical analyses of the lake water chemistry show large variations of the salt content due to the yearly evaporation-rain dilution cycle. These processes are also responsible for the saline stratification during steady meteorological conditions. The mineralogical characterisation of the bottom sediments shows the almost exclusive presence of neoformation minerals, mainly carbonates, formed in response to the pH gradient between spring- (pH≈6) and lake-waters (pH≈9). Finally, the CO2 partial pressures in the lake water slightly exceeding the atmospheric one, are due to the large amounts of CO2 brought to the lake through the bubbling free gas phase of the thermal springs. Nevertheless the high pH value of the lake water, its small volume and its periodical mixing prevent dangerous built up of this gas.
    Description: Published
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Pantelleria island ; volcanic lake ; gas hazard ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 32
    Publication Date: 2017-04-04
    Description: In the text
    Description: Published
    Description: 219-224
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: open
    Keywords: coda Q ; Phlegraean Fielsa ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
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  • 33
    Publication Date: 2017-04-04
    Description: On 22 September 2002, 1 month before the beginning of the flank eruption on the NE Rift, an M-3.7 earthquake struck the northeastern part of Mt. Etna, on the westernmost part of the Pernicana fault. In order to investigate the ground deformation pattern associated with this event, a multi-disciplinary approach is presented here. Just after the earthquake, specific GPS surveys were carried out on two small sub-networks, aimed at monitoring the eastern part of the Pernicana fault, and some baselines belonging to the northeastern EDM monitoring network of Mt. Etna were measured. The leveling route on the northeastern flank of the volcano was also surveyed. Furthermore, an investigation using SAR interferometry was performed and also the continuous tilt data recorded at a high precision sensor close to the epicenter were analyzed to constrain the coseismic deformation. The results of the geodetic surveys show a ground deformation pattern that affects the entire northeastern flank of the volcano, clearly shaped by the Pernicana fault, but too strong and wide to be related only to an M-3.7 earthquake. Leveling and DInSAR data highlight a local strong subsidence, up to 7 cm, close to the Pernicana fault. Significant displacements, up to 2 cm, were also detected on the upper part of the NE Rift and in the summit craters area, while the displacements decrease at lower altitude, suggesting that the dislocation did not continue further eastward. Three-dimensional GPS data inversions have been attempted in order to model the ground deformation source and its relationship with the volcano plumbing system. The model has also been constrained by vertical displacements measured by the leveling survey and by the deformation map obtained by SAR interferometry.
    Description: Published
    Description: 757-768
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: partially_open
    Keywords: Ground deformation ; Modeling ; Flank dynamics ; Volcano-tectonics ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 34
    Publication Date: 2017-04-04
    Description: A prototype system for earthquake early warning and rapid shake map evaluation is being developed and tested in southern Italy based on a dense, dynamic seismic network (accelerometers + seismometers) under installation in the Apenninic belt region (Irpinia Seismic Network). It can be classified as a regional Earthquake Early Warning System consisting of a broad-based seismic sensor network covering a portion or the entire area which is threatened by the quake's strike. The real time magnitude estimate will take advantage from the high spatial density of the network in the source region and the broad dynamic range of installed instruments. Based on the offline analysis of high quality strong-motion data bases recorded in Italy, several methods are envisaged, using different observed quantities (peak amplitude, dominant frequency, square velocity integral, …) to be measured on seismograms, as a function of time, both on P and early-S wave signals. Results from the analysis of the Italian strong motion database point out the possibility of using low-pass filtered displacement and velocity peak amplitudes measured in time windows lasting less than 3-4 sec after the first P- or S-wave arrivals. These parameters show they are robustly correlated with moment magnitude. The correlation found of 3Hz low-pass filtered PGV and PGD with magnitude is discussed and interpreted in terms of plausible dynamic models of the earthquake rupture process during its initial stage.
    Description: Published
    Description: 45-63
    Description: 4.1. Metodologie sismologiche per l'ingegneria sismica
    Description: reserved
    Keywords: Real-time Estimation ; Magnitude ; Seismic Early Warning ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 35
    Publication Date: 2017-04-04
    Description: Various authors, analysing the set of accelerograms recorded at Gubbio Piana (GBP) (central Italy), have demonstrated that strong amplification occurs at this accelerometric station, which is installed within an alluvial basin. In particular, Ambraseys et al. [(2005a), Bull Earthq Eng 3:1–53; (2005b), Bull Earth Eng 3:55–73] observed that the strong motion peaks at GBP greatly exceed the median values predicted by the attenuation relationships they derived for Europe. In this work, we analyse and discuss some characteristics of the ground motion recorded at the GBP station. We show that the ground motion parameters, such as peak-ground acceleration and peak-ground velocity, are strongly influenced by the presence of locally induced surface waves that produce both a lengthening of the significant shaking duration and an increase in the peak values with respect to a nearby bedrock site. The basin-induced surface waves are observed in the three components of motion and their effects on the peak values are particularly evident in the vertical component. In the frequency domain, the energy of the surface waves is mostly restricted to the frequency band 0.4–0.8Hz for both the horizontal and vertical components. The horizontal and vertical Fourier amplitudes are also very similar, and this indicates that the H/V spectral ratio technique is not applicable to describing the site response due to the propagation of seismic wave in a complex 2D/3D geological structure. Finally, a preliminary polarization analysis shows that the directions of polarization, as well as the degree of elliptical polarization, exhibit a strong variability with time, that may be related to a complex propagation of Love and Rayleigh waves within the basin.
    Description: Published
    Description: 27-43
    Description: 4.1. Metodologie sismologiche per l'ingegneria sismica
    Description: JCR Journal
    Description: partially_open
    Keywords: site amplification ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion
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  • 36
    Publication Date: 2017-04-04
    Description: During 1991−93 at Mount Etna, long-period (LP) events occurring in swarms characterized the evolution of the eruption. The presence of multiplets i.e. groups of events with similar waveform signatures, has been recognized within this activity. Traditional techniques for locating LP events do not allow obtaining reliable hypocenters, which have only succeeded in placing earthquakes in a roughly 1 km2 area slightly east of the Mt. Etna Northeast Crater. Hypocenters have been relocated in two steps: the absolute location has been improved using Thurber’s code and a complex 3D velocity model; a highly precise relative location has been applied on multiplets to define the source geometry. 3D locations and high precision analysis suggest that during the 1991−93 eruption the resonator producing LP events was a part of the uppermost Northeast Crater conduit, measuring 210 meters in height and 45−50 meters in diameter.
    Description: Published
    Description: 663-674
    Description: reserved
    Keywords: waveform correlation ; stacked events ; 1991−93 eruption ; conduct geometry ; Mt. Etna Northeast Crater ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
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  • 37
    Publication Date: 2017-04-04
    Description: The use of a hand-held thermal camera during the 2002–2003 Stromboli effusive eruption proved essential in tracking the development of flow field structures and in measuring related eruption parameters, such as the number of active vents and flow lengths. The steep underlying slope on which the flow field was emplaced resulted in a characteristic flow field morphology. This comprised a proximal shield, where flow stacking and inflation caused piling up of lava on the relatively flat ground of the vent zone, that fed a medial–distal lava flow field. This zone was characterized by the formation of lava tubes and tumuli forming a complex network of tumuli and flows linked by tubes. Most of the flow field was emplaced on extremely steep slopes and this had two effects. It caused flows to slide, as well as flow, and flow fronts to fail frequently, persistent flow front crumbling resulted in the production of an extensive debris field. Channel-fed flows were also characterized by development of excavated debris levees in this zone (Calvari et al. 2005). Collapse of lava flow fronts and inflation of the upper proximal lava shield made volume calculation very difficult. Comparison of the final field volume with that expecta by integrating the lava effusion rates through time suggests a loss of ~70% erupted lava by flow front crumbling and accumulation as debris flows below sea level. Derived relationships between effusion rate, flow length, and number of active vents showed systematic and correlated variations with time where spreading of volume between numerous flows caused an otherwise good correlation between effusion rate, flow length to break down. Observations collected during this eruption are useful in helping to understand lava flow processes on steep slopes, as well as in interpreting old lava–debris sequences found in other steep-sided volcanoes subject to effusive activity.
    Description: Published
    Description: JCR Journal
    Description: reserved
    Keywords: Lava flow field ; Morphology ; Tumuli ; Lava tubes ; Effusion rate ; Rheology ; Stromboli volcano ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 38
    Publication Date: 2017-04-04
    Description: The southernmost sector of the Italian peninsula is crossed by an almost continuous seismogenic belt capable of producing M ~ 7 earthquakes and extending from the Calabrian Arc, through the Messina Straits, as far as Southeastern Sicily. Though large earthquakes occurring in this region during the last Millennium are fairly well known from the historical point of view and seismic catalogues may be considered complete for destructive and badly damaging events (IX £ Io £ XI MCS), the knowledge and seismic completeness of moderate earthquakes can be improved by investigating other kinds of documentary sources not explored by the classical seismological tradition. In this paper, we present a case study explanatory of the problem, regarding the Ionian coast between the Messina Straits and Mount Etna volcano, an area of North-eastern Sicily lacking evidence of relevant seismic activity in historical times. Now, after a systematic analysis of the 18th century journalistic sources (gazettes), this gap can be partly filled by the rediscovery of a seismic sequence that took place in 1780. According to the available catalogues, the only event on record for this year is a minor shock (Io = VI MCS, Mw = 4.8) recorded in Messina on March 28, 1780. The newly discovered data allow to reinstate it as the mainshock (Io = VII–VIII MCS, Mw = 5.6) of a significant seismic period, which went on from March to June 1780, causing severe damage along the Ionian coast of North-eastern Sicily. The source responsible for this event appears located offshore, 40-km south of the previous determination, and is consistent with the Taormina Fault suggested by the geological literature, developing in the low seismic rate zone at the southernmost termination of the 1908 Messina earthquake fault.
    Description: Published
    Description: reserved
    Keywords: Historical seismology ; Macroseismic data ; MCS-EMS intensity scales ; 1780 Seismic sequence ; Seismotectonics ; NE Sicily ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology
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  • 39
    Publication Date: 2017-04-04
    Description: The catastrophic events that occurred in May 1998 in the area of Sarno (Southern Italy) highlight the destructive potential of debris flows, even when they are of relatively low magnitude. More than 130 people were killed and severe property damage took place when volcaniclastic debris flows triggered by heavy rainfall inundated various towns located in piedmont areas. This work investigates the suitability of LAHARZ, a GIS-assisted method for the automatic delineation of lahar inundation areas, for reproducing the May 1998 flows at Sarno. It was found that recalibration of the empirical relationship employed by LAHARZ is required in order to realistically hind-cast the inundation areas of considered events. The potential for further improvements in prediction outputs for this type of geomorphic setting is discussed, taking into account the observed lower mobility of these small volcaniclastic debris flows as compared to lahars of similar size.
    Description: Published
    Description: JCR Journal
    Description: reserved
    Keywords: Sarno ; LAHARZ ; Debris flows ; Lahars ; Debris flow modelling ; Hazard assessment ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 40
    Publication Date: 2017-04-04
    Description: Bulk atmospheric deposition of major cations (Na, K, Ca, Mg) and anions (Cl, F, SO4) were measured at 15 sites around an active volcano, Mount Etna, from 2001 to 2003. Their composition indicates several natural sources, among which deposition of plume-derived volcanogenic gas compounds is prevalent for F, Cl and S. Plume-derived acidic compounds are also responsible for the prevailing acidic composition of the samples collected on the summit of the volcano (pH in the 2.45–5.57 range). Cation species have complex origin, including deposition of plume volcanogenic ash and aerosols and soil-dust wind re-suspension of either volcanic or carbonate sedimentary rocks. Variation of the deposition rates during the March 2001– March 2003 period, coupled with previous measurements from 1997 to 2000 (Appl Geochem 16:985–1000, 2001), were compared with the variation of SO2 flux, volcanic activity and rainfall. The deposition rate was mainly controlled by rainfall. Commonly, about 0.1–0.9% of HF, HCl and SO2 emitted by the summit crater’s plume were deposited around the volcano. We estimate that ∼2 Gg of volcanogenic sulphur were deposited over the Etnean area during the 2002–2003 flank eruption, at an average rate of ∼24 Mg day−1 which is two orders of magnitude higher than that typical of quiescent degassing phases.
    Description: Published
    Description: 255-265
    Description: JCR Journal
    Description: open
    Keywords: Volcanic degassing ; Etna volcano ; Impact of volcanic eruptions ; S deposition rates ; Halogen deposition rates ; Bulk deposition chemistry ; Environmental volcanology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 41
    Publication Date: 2017-04-04
    Description: Forward Looking Infrared Radiometer (FLIR) cameras offer a unique view of explosive volcanism by providing an image of calibrated temperatures. In this study, 344 eruptive events at Stromboli volcano, Italy, were imaged in 2001–2004 with a FLIR camera operating at up to 30 Hz. The FLIR was effective at revealing both ash plumes and coarse ballistic scoria, and a wide range of eruption styles was recorded. Eruptions at Stromboli can generally be classified into two groups: Type 1 eruptions, which are dominated by coarse ballistic particles, and Type 2 eruptions, which consist of an optically-thick, ash-rich plume, with (Type 2a) or without (Type 2b) large numbers of ballistic particles. Furthermore, Type 2a plumes exhibited gas thrust velocities (〉15 m s−1) while Type 2b plumes were limited to buoyant velocities (〈15 m s−1) above the crater rim. A given vent would normally maintain a particular gross eruption style (Type 1 vs. 2) for days to weeks, indicating stability of the uppermost conduit on these timescales. Velocities at the crater rim had a range of 3–101 m s−1, with an overall mean value of 24 m s−1. Mean crater rim velocities by eruption style were: Type 1= 34 m s−1, Type 2a=31 m s−1, Type 2b=7 m s−1. Eruption durations had a range of 6–41 s, with a mean of 15 s, similar among eruption styles. The ash in Type 2 eruptions originates from either backfilled material (crater wall slumping or ejecta rollback) or rheological changes in the uppermost magma column. Type 2a and 2b behaviors are shown to be a function of the overpressure of the bursting slug. In general, our imaging data support a broadening of the current paradigm for strombolian behavior, incorporating an uppermost conduit that can be more variable than is commonly considered.
    Description: NSF grant no. EAR-0207734, NERC grant no. NER/B/S/2001/00707, the USGS Volcano Hazards Program and the Geophysical Institute at the University of Alaska Fairbanks
    Description: Published
    Description: 769-784
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: Stromboli volcano ; volcano monitoring ; thermal imaging ; eruption dynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 42
    Publication Date: 2017-04-04
    Description: An immersed boundary technique suitable for the solution of multiphase compressible equations of gas–particle flows of volcanic origin over complex 2D and 3D topographies has been developed and applied. This procedure combines and extends different existing methods designed for incompressible flows. Furthermore, the extension to compressible multiphase flows is achieved through a flux correction term in the mass continuity equations of the immersed cells that accounts for density variations in the partial volumes. The technique is computationally accurate and inexpensive, if compared to the use and implementation of the finite-volume technique on unstructured meshes. The first applications that we consider are the simulations of pyroclastic density currents generated by the collapse of a volcanic column in 2D axisymmetric geometry and by a dome explosion in 3D. Results show that the immersed boundary technique can significantly improve the description of the no-slip flow condition on an irregular topography even with relatively coarse meshes. Although the net effect of the present technique on the results is difficult to quantify in general terms, its adoption is recommended any time that cartesian grids are used to describe the large-scale dynamics of pyroclastic density currents over volcano topographies.
    Description: Published
    Description: 183-198
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Pyroclastic density currents ; Compressible flows ; Cartesian grids ; Finite-volume method ; Immersed boundary method ; Numerical simulation ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 43
    Publication Date: 2017-04-04
    Description: The Campania Region (southern Italy) is characterized by the frequent occurrence of volcaniclastic debris flows that damage property and loss of life (more than 170 deaths between 1996 and 1999). Historical investigation allowed the identification of more than 500 events during the last four centuries; in particular, more than half of these occurred in the last 100 years, causing hundreds of deaths. The aim of this paper is to quantify debris-flow hazard potential in the Campania Region. To this end, we compared several elements such as the thickness distribution of pyroclastic fall deposits from the last 18 ka of the Vesuvius and Phlegrean Fields volcanoes, the slopes of relieves, and the historical record of volcaniclastic debris flows from A.D. 1500 to the present. Results show that flow occurrence is not only a function of the cumulative thickness of past pyroclastic fall deposits but also depends on the age of emplacement. Deposits younger than 10 ka (Holocene eruptions) apparently increase the risk of debris flows, while those older than 10 ka (Late Pleistocene eruptions) seem to play a less prominent role, which is probably due to different climatic conditions, and therefore different rates of erosion of pyroclastic falls between the Holocene and the Late Pleistocene. Based on the above considerations, we compiled a large-scale debris-flow hazard map of the study area in which five main hazard zones are identified: very low, low, moderate, high, and very high.
    Description: Published
    Description: 157-167
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: 5.4. TTC - Sistema Informativo Territoriale
    Description: JCR Journal
    Description: reserved
    Keywords: Debris flows ; Explosive eruptions ; Hazard mapping ; Vesuvius volcano ; Erosion ; Campania region ; Southern Italy ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 44
    Publication Date: 2017-04-04
    Description: More than ca 100 km3 of nearly homogeneous crystal-poor phonolite and ca 100 km3 of slightly zoned trachyte were erupted 39 ka during the Campanian Ignimbrite super eruption, the most powerful in the Neapolitan area. Partition coefficient calculations, equilibrium mineral assemblages, glass compositions and texture were used to reconstruct compositional, thermal and pressure gradients in the pre-eruptive reservoir as well as timing and mechanisms of evolution towards magma chamber overpressure and eruption. Our petrologic data indicate that a wide sill-like trachytic magma chamber was active under the Campanian Plain at 2.5 kbar before CI eruption. Thermal exchange between high liquidus (1199 C) trachytic sill and cool country rocks caused intense undercooling, driving a catastrophic and fast (102 years) in situ fractional crystallization and crustal assimilation that produced a water oversaturated phonolitic cap and an overpressure in the chamber that triggered the super eruption. This process culminated in an abrupt reservoir opening and in a fast single-step high decompression. Sanidine phenocrysts crystal size distributions reveal high differentiation rate, thus suggesting that such a sill-like magmatic system is capable of evolving in a very short time and erupting suddenly with only short-term warning.
    Description: Published
    Description: On line First
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Campanian Ignimbrite ; Super eruption ; Crystal size distribution ; Partition coefficients ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 45
    Publication Date: 2017-04-04
    Description: We present an updated geological evolution of Mount Etna volcano based on new 40Ar/39Ar age determinations and stratigraphic data integrating the previous K/Ar ages. Volcanism began at about 500 ka ago through submarine eruptions on the Gela–Catania Foredeep basin. About 300 ka ago fissure-type eruptions occurred on the ancient alluvial plain of the Simeto River forming a lava plateau. From about 220 ka ago the eruptive activity was localised mainly along the Ionian coast where fissure-type eruptions built a shield volcano. Between 129 and 126 ka ago volcanism shifted westward toward the central portion of the present volcano (Val Calanna–Moscarello area). Furthermore, scattered effusive eruptions on the southern periphery of Etna edifice occurred until about 121 ka ago. The stabilization of the plumbing system on the Valle del Bove area is marked by the building of two small polygenic edifices, Tarderia and Rocche volcanoes. Their eruptive activity was rather coeval ending 106 and 102 ka ago, respectively. During the investigated time-span volcanism in Etna region was controlled by a main E–W extensional tectonic related to the reactivation of Malta Escarpment fault system in eastern Sicily.
    Description: Published
    Description: On line First
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: Mount Etna ; 40Ar/39Ar dating ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous
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  • 46
    Publication Date: 2017-04-03
    Description: The aim of this study is to shed light ontwo important destructive seismicsequences, about 20 years apart (1138–1139and 1156–1159), which hit the northernsector of the Dead Sea transform faultsystem (DSTFS), in the easternMediterranean region. Although some ofthese earthquakes were already known to thescholarly tradition, the interpretationsprovided until today have largely beenpartial and characterised by uncertaintiesand discrepancies among the variousauthors. Our study has developed throughresearch into the original Arabic, Syriac,Armenian and Latin texts and a criticalanalysis relating to a territory fragmentedby the presence of the Christian-Latinstates. This analysis has allowed us toshed light on the already existing, albeitoften uncertain, information and to add newelements of these two important series ofearthquake shocks to our knowledge base.As regards the first seismic sequence(October 1138–June 1139), apart from havingdefined the date with greater accuracy,eight new locations affected have beenidentified, unknown to previous studies.The shocks jolted a vast area withdestructive effects, including theterritory of Aleppo (modern Halab, Syria)and the western part of the region ofEdessa (modern Urfa, Turkey).The second seismic sequence (September1156–May 1159) was much longer anddevastating, and hit a huge area, includedbetween the present-day territories ofnorth-western Syria, northern Lebanon andthe region of Antioch (modern Antakya, insouthern Turkey). A detailed analysis ofthe primary sources has allowed toreconstruct the series of shocks withchronological detail of the effects,improving our previous knowledge. Lastly,the authors formulate an hypothesis as tothe possible seismogenic zones affected.
    Description: Published
    Description: 105-127
    Description: 3.10. Sismologia storica e archeosismologia
    Description: JCR Journal
    Description: reserved
    Keywords: Historical earthquakes ; seismic sequences ; Lebanon ; Syria ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology
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  • 47
    Publication Date: 2017-04-04
    Description: The recent seismological literature recorded three strong earthquakes in Algeria, Libya and Tunisia between 1656 and 1694 AD. The historical evidence for these derives from European sources only (gazettes, journalistic pamphlets, missionary literature). Considering the kind of sources involved, their likely biases and the geographical distances that divided their places of production from the places that they spoke about, it is possible that some of these accounts could be less than reliable, and therefore have little use as materials from which to assess earthquake parameters. To answer these doubts, we have retrieved, cross-checked and critically analysed the original historical sources quoted in previous compilations and studies.
    Description: Unpublished
    Description: 3.10. Sismologia storica e archeosismologia
    Description: open
    Keywords: Historical Seismology ; North Africa Earthquakes ; Early journalistic sources ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 48
    Publication Date: 2017-04-04
    Description: For 5 months before the 2001 Mt. Etna eruption, a progressive gravity decrease was measured along a profile of stations on the southern slope of the volcano. Between January and July 2001, the amplitude of the change reached 80 μGal, while the wavelength of the anomaly was of the order of 15 km. Elevation changes observed through GPS measurements during a period encompassing the 5-month gravity decrease, remained within 4–6 cm over the entire volcano and within 2–4 cm in the zone covered by the microgravity profile. We review both gravity and elevation changes by a model assuming the formation of new cracks, uniformly distributed in a rectangular prism. The inversion problem was formulated following a global optimization approach based on the use of Genetic Algorithms. Although it is possible to explain the observed gravity changes by means of the proposed analytical formulation, the results show that calculated elevation changes are significantly higher than those observed. Two alternative hypotheses are proposed to account for this apparent discrepancy: (1) that the assumptions behind the analytical formulation, used to invert the data, are fallacious at Etna, and thus, numerical models should be utilized; (2) that a second process, enabling a considerable mass decrease to occur without deformation, acted together with the formation of new cracks in the source volume.
    Description: Published
    Description: 553–562
    Description: 2.6. TTC - Laboratorio di gravimetria, magnetismo ed elettromagnetismo in aree attive
    Description: JCR Journal
    Description: reserved
    Keywords: Gravity ; Elastic modeling ; 04. Solid Earth::04.03. Geodesy::04.03.05. Gravity variations
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  • 49
    Publication Date: 2017-04-04
    Description: This work presents a methodology to study the interannual variability associated with summertime months in which extremely hot temperatures are frequent. Daily time series of maximum and minimum temperature fields (T max and T min, respectively) are used to define indexes of extreme months based on the number of days crossing thresholds. An empirical orthogonal function (EOF) analysis is applied to the monthly indexes. EOF loadings give information about the geographical areas where the number of days per month with extreme temperatures has the largest variability. Correlations between the EOF principal components and the time series of other fields allow plotting maps highlighting the anomalies in the large scale circulation and in the SSTs that are associated with the occurrence of extreme events. The methodology is used to construct the “climatology” of the extremely hot summertime months over Europe. In terms of both interannual and intraseasonal variability, there are three regions in which the frequency of the extremely hot days per month homogeneously varies: north-west Europe, Euro-Mediterranean and Eurasia region. Although extremes over those regions occur during the whole summer (June to August), the anomalous climatic conditions associated with frequent heatwaves present some intraseasonal variability. Extreme climate events over the north-west Europe and Eurasia are typically related to the occurrence of blocking situations. The intraseasonal variability of those patterns is related to the amplitude of the blocking, the relative location of the action centre and the wavetrain of anomalies downstream or upstream of the blocking. During June and July, blocking situations which give extremely hot climate conditions over north-west Europe are also associated with cold conditions over the eastern Mediterranean sector. The Euro-Mediterranean region is a transition area in which extratropical and tropical systems compete, influencing the occurrence of climate events: blockings tend to be related to extremely hot months during June while baroclinic anomalies dominate the variability of the climate events in July and August. We highlight that our method could be easily applied to other regions of the world, to other fields as well as to model outputs to assess, e.g. the potential change of extreme climate events in a warmer climate.
    Description: Published
    Description: 77-98
    Description: 3.7. Dinamica del clima e dell'oceano
    Description: JCR Journal
    Description: open
    Keywords: Extreme events ; Heatwaves ; Temperature anomalies ; climate variability ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate
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  • 50
    Publication Date: 2022-02-16
    Description: The role of mud volcanoes (MVs) as a source of methane(CH4) flux to the atmosphere and the ocean has been increasingly recognised in the last several years (Milkov 2000; Dimitrov 2002, 2003; Etiope and Klusman 2002; Kopf 2002, 2003; Milkov et al. 2003; Etiope and Milkov 2004). In one of the most recent papers, Kopf (2003) claims to report a reliable estimate of the global CH4 emission from MVs. However, the significance and usefulness of the estimate presented by Kopf (2003) are rather poor. The used dataset is smaller than in previous studies (although the author makes a reverse claim), and some previously published works are misquoted and misinterpreted. Numerous arithmetic mistakes made during simple calculations and data manipulations lead to confusing results and conclusions. In this comment, we highlight some of the most significant problems with the estimates published by Kopf (2003).
    Description: Published
    Description: 490-492
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Methane ; mud volcanoes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 51
    Publication Date: 2022-02-16
    Description: A new estimate of global methane emission into the atmosphere from mud volcanoes (MVs) on land and shallow seafloor is presented. The estimate, considered a lower limit, is based on 1) new direct measurements of flux, including both venting of methane and diffuse microseepage around craters and vents, and 2) a classification of MV sizes in terms of area (km2) based on a compilation of data from 120 MVs. The methane flux to the atmosphere is conservatively estimated between 6 and 9 Mt y)1. This emission from MVs is 3–6% of the natural methane sources and is comparable with ocean and hydrate sources, officially considered in the atmospheric methane budget. The total geologic source, including MVs, seepage from seafloor, microseepage in hydrocarbon-prone areas and geothermal sources, would amount to 35–45 Mt y)1. The authors believe it is time to add this parameter in the Intergovernmental Panel on Climate Change official tables of atmospheric methane sources.
    Description: Published
    Description: 997-1002
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Methane ; Mud volcanoes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
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  • 52
    Publication Date: 2022-06-09
    Description: Results of geological, geomechanical and seismometric investigations aiming at the analysis of the seismic response in a carbonate ridge of the Nera River valley (Central Apennines – Italy) are discussed. Geological and geomechanical surveys were aimed at defining the stratigraphic and structural setting of the outcropping formations and the jointing conditions of the rock mass. Velocimetric records of both ambient noise and small-magnitude earthquakes were analysed in order to identify amplification conditions. The analysis was carried out in the time domain, through directional energy evaluation, and in the frequency domain, through H/V spectral ratios and spectral ratios with respect to a reference station. A local amplification factor was estimated from Housner intensity. The study revealed a significant seismic amplification in a fault zone. This effect was observed in intensely jointed and mylonitic rock masses, located inside moderately jointed rock masses, and is the result of specific geometries and significant impedance contrasts. A map of fault zones prone to amplification of ground motion was constructed, taking into account the jointing conditions of the rock masses and the structural setting of the investigated ridge. The study relied on an integrated methodological approach, which combined the available data under union and intersection criteria.
    Description: Published
    Description: 416-449
    Description: JCR Journal
    Description: reserved
    Keywords: jointed rock masses ; velocimetric records ; seismic amplification ; trapped waves ; Central Italy ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
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  • 53
    Publication Date: 2022-05-24
    Description: Various authors, analysing the set of accelerograms recorded at Gubbio Piana (GBP) (central Italy), have demonstrated that strong amplification occurs at this accelerometric station, which is installed within an alluvial basin. In particular, Ambraseys et al. [(2005a), Bull Earthq Eng 3:1–53; (2005b), Bull Earth Eng 3:55–73] observed that the strong motion peaks at GBP greatly exceed the median values predicted by the attenuation relationships they derived for Europe. In this work, we analyse and discuss some characteristics of the ground motion recorded at the GBP station. We show that the ground motion parameters, such as peak-ground acceleration and peak-ground velocity, are strongly influenced by the presence of locally induced surface waves that produce both a lengthening of the significant shaking duration and an increase in the peak values with respect to a nearby bedrock site. The basin-induced surface waves are observed in the three components of motion and their effects on the peak values are particularly evident in the vertical component. In the frequency domain, the energy of the surface waves is mostly restricted to the frequency band 0.4–0.8Hz for both the horizontal and vertical components. The horizontal and vertical Fourier amplitudes are also very similar, and this indicates that the H/V spectral ratio technique is not applicable to describing the site response due to the propagation of seismic wave in a complex 2D/3D geological structure. Finally, a preliminary polarization analysis shows that the directions of polarization, as well as the degree of elliptical polarization, exhibit a strong variability with time, that may be related to a complex propagation of Love and Rayleigh waves within the basin.
    Description: Published
    Description: JCR Journal
    Description: reserved
    Keywords: Strong motion ; Alluvial basin effects ; Site effects ; Gubbio plain ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion
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  • 54
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
    Type: info:eu-repo/semantics/book
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  • 55
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    Springer
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
    Type: info:eu-repo/semantics/book
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  • 56
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: The intracrystalline diffusion rate of oxygen in diopside was constrained based on natural isotopic variations from a granulite facies marble from Cascade Slide, Adirondacks (New York, USA). The oxygen isotope compositions of the diopsides, measured as a function of grain size, are nearly constant (20.9 ± 0.3‰ vs. SMOW) over the entire measured size range (0.3–3.2 mm diameter). The δ18O values of the cores of calcite grains are 23.0‰. Temperature estimates based on the Δ18O(calcite-diopside) are 800d̀C, in agreement with the highest previous thermometric estimates for these rocks.The lack of isotopic variation in the diopsides as a function of grain size requires that the oxygen intracrystalline diffusion rate in diopside from the Adirondack samples was very slow. The maximum diffusion rates (D800d̀C parallel to the c-axis) were calculated with an infinite reservoir model (IRM) and a finite reservoir model (FRM) that incorporates mineral modal abundances and initial isotopic variations. For an assumed activation energy (Q) = 100 kJ/mol, the IRM diffusion rate estimate of 1.6 times 10-20cm2/s is two orders of magnitude faster than from the FRM; at Q=500kJ/mol, the D800d̀C estimate for both methods is c. 5.6 times 10-20 cm2/s. The present results require that a hydrothermal fluid significantly enhances the diffusion rate of oxygen in diopside if previous data are correct.The δ18O(SMOW) and δ13C(PDB) values of the calcite, measured in situ with a CO2 laser, are 22.9 ± 0.3, 0.1±0.3‰ in the grain cores, 22.1 ±0.3, 0.2 ±0.1‰ at the grain boundaries and 21.7 ±0.4, -0.6±0.1‰ abutting diopside grains. The δ18O and δ13δC values measured conventionally are: crystal cores, 22.96, -0.95‰; abutting diopside grains, 22.38, -0.93‰; bulk, 22.79, -0.95%. Use of the bulk δ18O(calcite) values for thermometry yields unreasonably high temperatures. The lower δ18O values at the calcite grain boundaries are not due to retrograde diffusional exchange with the diopside, they are thought to be a result of a late retrograde fluid infiltration.
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    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
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    Topics: Geosciences
    Notes: Clay mineral crystallinity and crystallite (domain) size data determined by X-ray diffraction (XRD) are methods extensively used in the characterization of very low-grade metamorphic conditions. However, the lack of sufficient interlaboratory standardization has made comparisons between different research groups unreliable due to significant variations in numerical results obtained, a consequence of the different machine conditions, measurement methods and sample preparations used during analysis. A calibration approach to the standardization of data using rock chip standards is presented, which allows data sets produced by different research groups to be directly and quantitatively compared. A standardized scale, the crystallinity index standard (CIS), is proposed, with illite crystallinity anchizonal boundary limits of 0.25d̀Δ2θ and 0.42d̀Δ2θ, and equivalent illite crystallite sizes of 52 and 23 nm, respectively, determined by the Warren-Averbach method. Calibrating both old and new data will enable more reliable comparisons between similar and contrasting geological environments, and should improve the accuracy and reliability of correlations made between XRD data and other indicators of very low-grade metamorphism, hence increasing the value of such clay mineral studies.
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  • 58
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    Journal of metamorphic geology 12 (1994), S. 0 
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  • 59
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    Journal of metamorphic geology 12 (1994), S. 0 
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    Topics: Geosciences
    Notes: The Chicago mineral-carbonate oxygen isotope fractionation curves have been combined with mineral-water fractionation data for jadeite, zoisite and rutile and new data for grossular-water to provide a set of self-consistent mineral-pair calibrations. The A coefficients in the equation 1000 In α=A× 106T-2 of the new mineral-pair fractionations areJadeite Zoisite Grossular RutileQuartz 1.69 2.00 3.03 5.02Jadeite 0.31 1.34 3.33Zoisite 1.03 3.02Grossular 1.99The isotopic fractionation properties of natural pyralspite garnet [(Ca, Fe, Mg, Mn)3Al2Si3O12] can be approximated by those of the grossular end-member. Appropriate substitutions also yield coefficients for the solid-solution minerals: sodic pyroxene and epidote, e.g. A quartz-sodic pyroxene= 2.75 - 1.06Xjd, A quartz-epidote= 2.00 + 0.75Xpswhere XJd and XPs are the mole fractions of the jadeite and pistacite components, respectively.The new data set is particularly suitable for the geothermometry of metamorphic rocks. δ18O data from minerals of the high-pressure metamorphic rocks of the Sesia Zone of Italy and Cyclades Complex of Greece yield well-constrained mean temperatures of 572 and 478d̀ C, respectively. Type III blueschist metabasalts of the Franciscan Formation of California give mean quartz-garnet temperatures of 354d̀ C.
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  • 60
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    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
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    Topics: Geosciences
    Notes: Quantitative modelling of oxygen exchange by diffusion during slow cooling has been compared to the observed oxygen isotope distributions from high-grade metamorphic and granitic rocks of the High Himalayan Crystallines, Langtang Valley, central Nepal, in order to investigate the effect of retrograde diffusional exchange on the preservation of high-temperature, oxygen isotope systematics.Modelled fractionations, using water-present diffusion data reported in the literature, predict quartz-mica fractionations to be much larger than those at peak metamorphic and igneous conditions due to low closure temperatures for micas. Quartz-feldspar fractionations may be less than those at peak conditions, and in some samples may even be slightly negative.The observed oxygen isotope fractionations in the metamorphic rocks are small and largely appear to record equilibrations close to peak conditions determined by other methods. Hence these rocks clearly do not conform to predictions of fluid-present diffusional retrograde exchange. It is suggested that their retrograde history was therefore within an anhydrous closed system in which diffusion was slow and hence mineral closure temperatures were high. The granitic rocks record rather larger quartz-biotite fractionations, approaching those predicted by the diffusion modelling. However, quartz-feldspar fractionations are large and hence, although significant retrograde exchange has clearly occurred, simple diffusion alone is not sufficient to explain the observed data and open-system exchange may be required. The presence of fluids during the retrograde history of this part of the section is supported by petrographic evidence.The different retrograde oxygen exchange histories recorded between the regional metamorphic and magmatic regimes of the Langtang section would appear to support the importance of water on the kinetics of such exchange, and suggests that in its absence, diffusional exchange may become insignificant, allowing oxygen isotope thermometry to record meaningful high-temperature data.
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  • 61
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    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
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    Topics: Geosciences
    Notes: The assemblages chlorite-pumpellyite-lawsonite-albite-quartz, chlorite-lawsonite-quartz-epidote and chlorite-epidote-albite-quartz occur in metabasaltic blocks and veins in a metamorphosed tectonic mélange in the structurally highest unit of the autochthonous and parautochthonous section underlying the Semail ophiolite in Saih Hatat, north-east Oman. The pre-Permian basement of this section contains mafic units characterized by the assemblage crossite-epidote-chlorite-quartz-albite /el actinolite. These assemblages indicate a down-section increase in metamorphic grade from ‘lawsonite-albite facies' conditions in the mélange to ‘epidote-blueschist’ facies conditions in the basement.Application of empirically and experimentally based thermobarometers as well as petrogenetic grids calculated for a model basaltic system indicates that the P-T conditions of metamorphism ranged from 3 to 6 kbar and 250 to 300d̀ C for the mélange and P 〉 6.8 kbar, T 〉 310d̀ C for the basement units. Textural relations interpreted in the context of petrogenetic grids indicate that these units followed clockwise P-T paths of evolution. The estimated P-T conditions and down-section increase in metamorphic grade in central, western and northern Saih Hatat are consistent with the hypothesis relating metamorphism to the Late Cretaceous tectonic loading of the continental margin by an ophiolite slab 〈 18 km in thickness. These results contrast with field and petrological observations documented for blueschists and eclogites exposed along the eastern coast of Saih Hatat which may have formed at an earlier stage in response to an Early Cretaceous collisional event.
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  • 62
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    Journal of metamorphic geology 12 (1994), S. 0 
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  • 63
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    Restoration ecology 2 (1994), S. 0 
    ISSN: 1526-100X
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    Topics: Biology
    Notes: Books reviewed in this article: Perspectives on Biodiversity: Case Studies of Genetic Resource Conservation and Development. Christopher S. Potter, foci 1. Cohen, and Dianne Janczewski, editors
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  • 64
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    Restoration ecology 2 (1994), S. 0 
    ISSN: 1526-100X
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    Topics: Biology
    Notes: To evaluate reclamation success on the Wooley Valley phosphate mine in southeastern Idaho, we compared vegetation structure and soil physical, chemical, and elemental properties of several different reclamation treatments with those of a nearby reference area (a native Artemisia tridentata vaseyana/Festuca idahoensis association) after 14 years. Vegetation data had been collected four years after reclamation, and we were able to compare differences in biomass and species composition between dates on the reclaimed area. Four years after reclamation there were no differences in total biomass between topsoil or spoil or between seed only, seed + mulch, or control treatments on the different soil types. Most treatments were dominated by seeded perennial grasses. Fourteen years after reclamation there were no differences in biomass or cover between spoil and topsoil plots, but on spoil plots the seeded and mulched treatment had higher total biomass and vegetation cover than on control or seed-only treatments. The seeded perennial legume Medicago sativa was codominant with the seeded forage grasses on all of the treatments. High initial fertilization rates probably facilitated the early establishment and dominance of the forage grasses; once nutrient levels, especially nitrogen, began to decline, the legume increased in abundance. Similarity between the reclaimed area and the reference or native area was low. Reclaimed treatments had higher biomass but lower species richness. The topsoil and spoil plots had similar soil texture, bulk density, pH, cation exchange capacity, electrical conductivity, and phosphorus. Differences in organic carbon, total nitrogen, carbon: nitrogen ratios, and available moisture were related more to treatments than to soil type. High biomass and, thus, litter input on the seed + mulch treatment on spoil plots resulted in both higher OC and TN than any on other soil/treatment combination. The reclaimed area had lower OC, TN, and available moisture than did the reference area on all but seed + mulch spoil plots. Bulk density was higher on reclaimed plots. The long-term differences observed between the reclaimed and reference areas parallel those obtained for other western reclamation sites. Although successional trajectories depend on the attribute measured, similarity to native reference areas depends on the initial reclamation methods. We discuss reclamation methods that would increase the structural and functional similarity of reclaimed and reference areas on the Wooley Valley phosphate mine.
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  • 65
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    Topics: Biology
    Notes: In land restoration it is imperative to study the potential role of disturbances, biotic or abiotic, that may provide sites for colonization by specific plants. Disturbances can alter community composition by removing species or allowing others to become established. In communities where animal-generated disturbances open sites for seedling establishment, animals may have important indirect effects on several aspects of plant community structure. Animal disturbances in Quercus havardii communities of western Texas appear to open sites for colonization by herbaceous species. These animal disturbances vary in spatial distribution, density, and abiotic and biotic characteristics. The abundance of herbaceous plant seedlings is positively related to bare ground and the number of distinct disturbances. Thus, the density and the spatial distribution of these disturbances may be expected to have an important influence on the abundance and dispersion of plant species. Therefore, successful restoration efforts of sand shinnery oak communities and other similar habitats must consider the effects of animal disturbances and the role of plant-animal and plant-soil microbe interactions on plant community composition and the maintenance of plant species diversity.
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    Restoration ecology 2 (1994), S. 0 
    ISSN: 1526-100X
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    Topics: Biology
    Notes: The rates of seston elimination by zooplankton and primary production were measured in Funada-ike Pond, typical of human-made impoundments in Japan, from April to September in order to evaluate various treatments of the pond aimed at improving water quality by reducing seston abundance. The treatments included draining the pond water, dredging the bottom mud, eliminating the wastewater inflow, and biomanipulation through removal of all fish. After the treatment, seston abundance was reduced from more than 10 to 0.4–2.5 mg C/liter, and large daphnid species, Daphnia similis and D. magna, occurred and predominated in the zooplankton community. Seston abundance remained at a relatively low level from June to August but increased markedly in late August, while the biomass of zooplankton became high from June to mid-August and then decreased. A decrease in seston abundance was found when the elimination rate exceeded the primary production rate. The results indicate that the development of daphnid populations was effective in keeping seston abundance at a low level. The relationship between the rate of primary production and the zoo-plankton biomass required to offset this rate, however, suggests that biomanipulation aimed at increasing zooplankton biomass alone is less effective in a pond with a high primary production. The success in improving water quality in this pond seems to depend not only on the increase in biomass of large daphnid species that resulted mainly from the removal of fish, but also on the decrease in nutrient load that was realized by the other treatments.
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    Restoration ecology 2 (1994), S. 0 
    ISSN: 1526-100X
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    Topics: Biology
    Notes: This essay reviews the recent attempts by the Northwest Power Planning and Conservation Council (NPPC) to conserve and restore wild salmon lost to hydroelectric development along the Columbia River and its tributaries. The restoration of the wild salmon is predicated on cooperation between myriad stakeholders in a planning process that includes the NPPC, 11 state and federal agencies, 13 Indian tribes, 8 utilities, and numerous interest groups. The two goals of the essay are (1) to review the recent amendments to the NPPC's fish and wildlife program, and (2) to describe the political barriers to restoration versus restocking of wild salmon in the Columbia River. The failure of political and administrative entities to deal with the problem of restoring wild salmon may result in drastic requirements being imposed by the imperatives of the Endangered Species Act.
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    Restoration ecology 2 (1994), S. 0 
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    Topics: Biology
    Notes: An environmental revolution is urgently needed that will lead to a post-industrial symbiosis between man and nature. This can be realized only if the present unrestrained biological impoverishment and neotechnological landscape degradation are replaced by the creation of healthy and attractive landscapes. Restorationists can fulfill a vital role in this process. They must broaden their scales from biodiversity restoration in small, protected nature islands to the large-scale restoration of natural and cultural landscapes. To achieve this they must restore not only the patterns of vegetation but also the processes that create these patterns, including human land uses. Their goal should be to restore the total biological, ecological, and cultural landscape diversity, or “ecodiversity,” and its intrinsic and instrumental values of highly valuable, endangered seminatural, agricultural and rural landscapes. For this purpose it is essential to maintain and restore the dynamic flow equilibrium between biodiversity, ecological, and cultural landscape heterogeneity, as influenced by human land uses, which occur at different spatial and temporal scales and intensities. Recent advances in landscape ecology should be utilized for broader assessment of ecodiversity, including proposed indices of ecodiversity, new techniques such as Intelligent Geographical Information Systems (IGIS), and Green Books for the holistic conservation and restoration of valuable endangered landscapes. Restoration ecology can make an important contribution to an urgently needed environmental revolution. This revolution should lead to a new symbiosis between man and nature by broadening the goal of vegetation restoration to ecological and cultural landscape restoration, and thereby to total landscape ecodiversity.
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  • 69
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    Topics: Biology
    Notes: A study of spider (Araneae) communities was conducted in rehabilitated bauxite mines at the Jarrahdale mine site of Alcoa of Australia Ltd. and in the nearby native jarrah (Eucalyptus marginata) forest in southwest Western Australia. The study was conducted from March to August 1993 in five rehabilitated sites of different age and method of rehabilitation and in two forest sites. A variety of collection methods was used, including pitfall trapping, litter sampling, sweep netting, tree beating, and visual searching. These methods were the same as those carried out in a previous study of some of these areas in 1983. We collected 151 spider species belonging to 102 genera and 34 families. We examined the relationship between various habitat features, including the age and method of rehabilitation, of the spider communities present. It was found that leaf litter depth and cover and vegetation density had a significant positive influence on recolonization by the various spider guilds. The age and method of rehabilitation were found to influence different vegetational and habitat features; these, in turn, influenced the spider communities. Thus, the older a rehabilitated site the greater the species richness of both plants and spiders. We compared these results with those of the 1983 study to determine the spider succession of the aging rehabilitation. The spider communities and guild composition were found to change as the vegetation matured, from a dominance of pioneer species to a community of species requiring less harsh conditions. By comparison with the pre-1983 rehabilitation, the latest method of rehabilitation increased the rate of recolonization by both plants and spiders.
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    Restoration ecology 2 (1994), S. 0 
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    Restoration ecology 2 (1994), S. 0 
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    Topics: Biology
    Notes: Peak flowering activity among woody species in the tropical dry forests of St. John, U.S. Virgin Islands, coincided with the brief spring rainy season but continued at moderate levels for six months, abating with the autumn rains. Fruit maturation showed a major peak in the long winter dry season and a minor crest during the summer dry season. Seeds of wind-dispersed species disseminated mainly during the winter dry season, while animal dispersal of seeds (74% of all woody species) followed the bimodal pattern (for wet and dry seasons) described for the community as a whole. Under shadehouse conditions, most dry forest tree species germinated well (〉 80%) and emerged promptly (within four weeks of planting) and synchronously (90% emergence within a four-week interval). Nine of 29 species tested in the shadehouse manifested dormancy of at least six weeks. Seed germinability varied among tree species, and the viability of most species began to decline following six months of dry storage. Few species retained high germinability after nine months of dry storage. The species composition of soil seed banks did not correspond closely with above-ground communities on three forested sites of varying stand age. In the youngest stand (35 years old), dominated by the weedy, arborescent legume Leucaena leucocephala, the soil seed bank was also dominated by this species, but no seeds of any other tree species were found in the soil samples. Seeds of native trees were scarcely encountered (only one indigenous species) in soil seed bank samples of three forest sites. Local seed rain from less disturbed forest may not be sufficient for prompt recovery of the dry forest community on degraded sites.
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  • 73
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    Journal of economics & management strategy 3 (1994), S. 0 
    ISSN: 1530-9134
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Economics
    Notes: I present an integrated survey of management strategy, which examines organizational design, competitive strategy, and public policy considerations. In addition, 1 offer suggestions on how economic analysis can be applied in unifying and developing management strategy as a field of study.
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    Journal of economics & management strategy 3 (1994), S. 0 
    ISSN: 1530-9134
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    Topics: Economics
    Notes: Under prospective pricing, payers for health care essentially use price regulation of hospitals as a way of indirectly regulating the provision of treatment intensity. This paper presents a theory of how a nonprofit hospital selects treatment intensities for its products given the payer's choice of prices and then determines how the payer should select prices in light of this theory. The main result is that, in equilibrium, the ratio of price to marginal cost will vary across products inversely with the elasticity of demand with respect to treatment intensity. This means that, generally, the hospital will earn positive (negative) accounting profit on products with low-(high-) intensity elasticities of demand.
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    Journal of economics & management strategy 3 (1994), S. 0 
    ISSN: 1530-9134
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    Topics: Economics
    Notes: Legislation to create optional no-fault insurance (ONFL) programs has recently been enacted in Florida and Virginia. ONFI programs provide compensation to patients when certain medical complications arise, provided the patient agrees not to sue the doctor for additional damages. The optimal design of ONFI programs is explored in this paper, focusing on the incentive effects of ONFI programs. The question of whether ONFI programs should be funded entirely by participating doctors, or whether social subsidies are optimal, is examined.
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    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
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    Topics: Geosciences
    Notes: Retrograde exchange of oxygen isotopes between minerals in igneous and metamorphic rocks by means of diffusion is explored using a finite difference computer model, which predicts both the zonation profile of δ18O within grains, and the bulk δ18O value of each mineral in the rock. Apparent oxygen isotope equilibrium temperatures that would be observed in these rocks are calculated from the δ18O values of each mineral pair within the rock. In systems which cool linearly from a sufficiently high temperature or at a low enough cooling rate, such that the final oxygen isotope values are not dependent upon the initial oxygen isotope values (‘slow cooling’), the apparent oxygen isotope temperature derived for a rock composed of a single mineral pair can be shown to be simply related to the Dodson closure temperatures (Tc) for the two phases and the mode of the rock. Adding a third phase into a system which undergoes ‘slow’ cooling will cause the apparent temperature derived for the two minerals already present to differ from the simple relationship for a two-phase system. In some systems oxygen isotope reversals can be developed. If cooling is not ‘slow’, then the mineral δ18O values resulting from cooling will be partly dependent upon the initial temperature of the system concerned. The model successfully simulates the mineral δ18O values that are often observed in granitic rocks. Application of the model will help in assessing the validity of oxygen isotope thermometry in different geological settings, and allows quantitative prediction of the oxygen isotope fractionations that are developed in cooling closed systems.
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    Journal of metamorphic geology 12 (1994), S. 0 
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    Topics: Geosciences
    Notes: The highest grade pelitic and semipelitic rocks of the Ballachulish aureole are dominantly potash feldspar + cordierite + biotite hornfelses with widely variable amounts of quartz, plagioclase, andalusite, sillimanite and corundum (together with accessory phases). On a microscopic scale these hornfelses show textural evidence of the presence of melt, whilst on a mesoscopic scale they contain a variety of leucosomes. Oxygen isotope studies have been carried out on both whole rocks and mineral separates in order to: (1) assess the sources of molten and volatile constituents and (2) determine the extents of isotopic homogenization and equilibration. Data from localities with both restricted and extensive evidence of leucosomes and melt development are compared, as well as one locality with petrographic evidence of melt incursion from the igneous complex.The whole-rock δ18O values of the leucosomes (10.5–14.9%.) are in general similar to the immediately adjacent mesosomes (9.9–14.5%.) which are typically cordierite- and feldspar-rich hornfelses. Isotopic evidence is thus consistent with an in-situ partial melt origin for the leucosomes, without the substantial addition of externally derived components. In the area of extensive melt development, the ‘chaotic zone’, it is possible there was addition of an H2O-rich fluid phase (6-13 wt%) from the igneous complex which resulted in a slight lowering of δ18O values by 0.5–1.0%.Quartz mineral separates were used to assess the degree of local isotopic homogenization. In the extensively molten area (chaotic zone) there is extensive homogenization between rock layers (quartz δ18O usually within 1.0%), whilst in less molten areas δ18O quartz has a range of c. 3.0%. The greater homogenization in the chaotic zone is attributed to the increased degree of melting and infiltration of H2O-rich fluid from the igneous complex.
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    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
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    Topics: Geosciences
    Notes: The enderbites from Tromøy in the central, granulite facies part of the Proterozoic Bamble sector of southern Norway contain dominantly CO2 and N2 fluid inclusions. CO2 from fluid inclusions in quartz segregations in enderbites was extracted by mechanical (crushing) and thermal decrepitation and the δ13C measured. Measurement was also made on samples washed in 10% HCl, oxidized with CuO at high temperatures, and step-wise extracted with progressive heating. Results between the different techniques are systematic. The main results show δ13C of -4.5±1.5% for crushing and -7±2% for thermal decrepitation. δ13C is about constant for CO2 extracted at different temperatures and points to a homogeneous isotopic composition. Due to the presence of carbonate particles and/or induced contaminations for the extraction by thermal decrepitation, the results for the crushing experiments are assumed the most reliable for fluid-inclusion CO2. Very low values of δ13C have not been found in enderbite samples and δ13C combined with δ18O of the host quartzes (8-11%) indicates juvenile values. In addition, the fluid inclusions were examined by microthermometry and Raman analysis and host quartz by acoustic emission and cathodoluminescence. CO2 fluid inclusions have varying densities with a frequency maximum of 0.92 g cm-3 and generally do not concur with trapping densities at granulite conditions. Textures show that CO2 must have been trapped in fluid inclusions in one early event, but transformed to different extents during late isothermal uplift without important fractionation of isotope compositions. The present data support a model of intrusion and crystallization of a CO2-rich enderbitic magma at granuiite conditions.
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    Journal of metamorphic geology 12 (1994), S. 0 
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: High-grade exotic blocks in the Franciscan Complex at Jenner, California, show evidence for polydeformation/metamorphism, with eight distinct stages. Two parallel sets of mineral assemblages [(E) eclogite, and (BS) laminated blueschist] representing different bulk chemistry were identified. Stage 1, recorded by parallel aligned inclusions (S1) of crossite + omphacite + epidote + ilmenite + titanite + quartz (E), and glaucophane + actinolite + epidote + titanite (BS) in the central parts of zoned garnets, represents the epidote blueschist facies. The onset of a second stage (stage 2) is represented by a weak crenulation of S1 and growth of garnet. This stage develops a well-defined S2 foliation of orientated barroisite + epidote + titanite (E), or subcalcic actinolite + epidote + titanite (BS) at c. 90d̀ to S1, with syntectonic growth of garnet, defining the (albite-)epidote-amphibolite facies. A third stage, with aligned inclusions of glaucophane + (subcalcic) actinolite + phengite parallel to S2 in the outermost rims of large garnet grains, is assigned to the transitional (albite-)epidote-amphibolite/(garnet-bearing) epidote blueschist facies. The fourth stage represents the peak metamorphism, and was identified by unorientated matrix minerals in the least retrograded samples. In this stage the mineral assemblages garnet + omphacite + glaucophane + phengite (E) and garnet + winchite + phengite + epidote (BS) both represent the eclogite facies. Stage 5 is represented by the retrogression of eclogite facies assemblages to the epidote blueschist facies assemblages crossite/glaucophane + garnet + omphacite + epidote + phengite (E), and glaucophane + actinolite + epidote + phengite (BS), with the development of an S5 foliation subparallel to S2. Stage 6 represents a crenulation of S5, with the development of a well-defined S6 crenulation cleavage wrapping around relics of the eclogite facies assemblages. This crenulation cleavage is further weakly crenulated during a D7 event. Post-D7 (stage 8) is recorded by the growth of lawsonite + chlorite ± actinolite replacing garnet, and by veins of lawsonite + pumpellyite + aragonite and phengite + apatite. The different, yet coeval, mineral parageneses observed in rock types (E) and (BS) are probably due to differences in bulk chemistry.The metamorphic evolution from stage 1 to stage 8 seems to have been broadly continuous, following an anticlockwise P-Tpath: (1) epidote blueschist (garnet-free) to (2) (albite-)epidote-amphibolite to (3) transitional epidote blueschist (garnet-bearing)/(albite-)epidote-amphibolite to (4) eclogite to (5) epidote blueschist (garnet-bearing) to (6-7) epidote blueschist (garnet-free) facies to (8) lawsonite + pumpellyite + aragonite-bearing assemblages. This anticlockwise P-T path may have resulted from a decreasing geothermal gradient with time in the Mesozoic subduction zone of California at early or pre-Franciscan metamorphism.
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  • 80
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    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Rocks within the Zermatt-Saas ophiolite of the western Alps have undergone eclogite facies metamorphism during subduction prior to the Alpine collision. The metamorphic history of these rocks is well defined, with eclogitic assemblages being followed by the limited growth of blueschist assemblages of glaucophane and paragonite. Subsequent greenschist alteration occurs adjacent to faults, veins and metasediments. Away from such sources of water, retrogression is very limited. Sm-Nd isotopic analyses of an essentially unretrogressed eclogitic metabasalt suggest that eclogite facies metamorphism occurred at 52 ± 18 Ma. The large uncertainty is due to the presence of very small amounts of Nd-rich epidote present as inclusions within garnet. As the closure temperature of garnet to Sm & Nd is thought to be 〉600d̀C, resetting due to post-high-pressure diffusion is thought to be insignificant. Given the fine-grained protolith to the sample analysed, and its extensive deformation under eclogite facies conditions, incomplete homogenization of pre-metamorphic isotopic variations is also considered unlikely to be responsible for the young age. A Tertiary age of eclogitization means that models of early Alpine evolution based on the cessation of high-pressure metamorphism in the Cretaceous need to be revised.
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  • 81
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    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Porphyroblast inclusion fabrics are consistent in style and geometry across three Proterozoic metamorphic field gradients, comprising two pluton-related gradients in central Arizona and one regional gradient in northern New Mexico. Garnet crystals contain curved ‘sigmoidal’ inclusion trails. In low-grade chlorite schists, these trails can be correlated directly with matrix crenulations of an older schistosity (S1). The garnet crystals preferentially grew in crenulation hinges, but some late crenulations nucleated on existing garnet porphyroblasts. At higher grade, biotite, staurolite and andalusite porphyroblasts occur in a homogeneous S2 foliation primarily defined by matrix biotite and ilmenite. Biotite porphyroblasts have straight to sigmoidal inclusion trails that also represent the weakly folded S1 schistosity. Staurolite and andalusite contain distinctive inclusion-rich and inclusion-poor domains that represent a relict S2 differentiated crenulation cleavage. Together, the inclusion relationships document the progressive development of the S2 fabric through six stages. Garnet and biotite porphyroblasts contain stage 2 or 3 crenulations; staurolite and andalusite generally contain stage 4 crenulations, and the matrix typically contains a homogeneous stage 6 cleavage.The similarity of inclusion relationships across spatially and temporally distinct metamorphic field gradients of widely differing scales suggests a fundamental link between metamorphism and deformation. Three end-member relationships may be involved: (1) tectonic linkages, where similar P-T-time histories and similar bulk compositions combine to produce similar metamorphic and structural signatures; (2) deformation-controlled linkages, where certain microstructures, particularly crenulation hinges, are favourable environments for the nucleation and/or growth of porphyroblasts; and (3) reaction-controlled linkages, where metamorphic reactions, particularly dehydration reactions, are associated with an increase in the rate of fabric development. A general model is proposed in which (1) garnet and biotite porphyroblasts preferentially grow in stage 2 or 3 crenulation hinges, and (2) chlorite-consuming metamorphic reactions lead to pulses in the rate of fabric evolution. The data suggest that fabric development and porphyroblast growth may have been quite rapid, of the order of several hundreds of thousands of years, in these rocks. These microstructures and processes may be characteristic of low-pressure, first-cycle metamorphic belts.
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  • 82
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    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Incipient metamorphism accompanying thrusting, folding and cleavage development has been investigated in a varied sequence of Palaeozoic sediments near the Variscan front in SW Dyfed, Wales. The aim was to evaluate a critical stage in the progression from heterogeneous sediment, whose detrital phases are neither in equilibrium with one another, nor with pore fluids, through indurated sedimentary rock to metamorphic rock comprising newly formed crystals that equilibrated with one another as they grew.Quartz veins are widely developed in the area, especially in the more psammitic lithologies, while finer grained rocks became cleaved during tectonic deformation. Mineralogical constraints and fluid inclusion measurements suggest maximum temperatures around 200-310d̀ C (slightly higher in the Marloes-Musselwick Thrust Sheet than in other parts of the structural succession) at depths of the order of 6-13 km.Quartz veins yield distinctly heavier oxygen isotopic compositions than detrital quartz grains in the adjacent wall rocks, although care must be taken in interpreting the data because slivers of detrital grains may become incorporated into veins, while matrix detrital grains may incorporate veinlets or rims of newly formed quartz. It is concluded that vein quartz grew in isotopic equilibrium with a fluid phase whose isotopic composition was primarily controlled by exchange with phyllosilicates, not detrital quartz grains. Vein and matrix quartzes from the Marloes-Musselwick Thrust Sheet are distinctly lighter (δ18Oveins=+14 to +18% and δ18Omatrix=+11 to +14%) than those from other thrust sheets (δ18O =+17 to +20% and +14 to +17%, respectively).We conclude that vein quartz and phyllosilicate grains in cleavage domains probably attained equilibrium with a locally buffered pore fluid at the peak of metamorphism, but many relict grains of different chemical and isotopic composition remained elsewhere in the rock. Local fluid migration along veins and through cleavage lamellae facilitated the attainment of equilibrium, but there is little evidence for large-scale infiltration of externally derived fluids. With further metamorphism the quartz in these rocks would attain an isotopic composition intermediate between that of the heavy vein material and light detritus which coexist here.
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  • 83
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    Restoration ecology 2 (1994), S. 0 
    ISSN: 1526-100X
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology
    Notes: Fire is a common but poorly understood disturbance in the forested ecosystems of the Sierra Madre Occidental of Mexico. In this study, fire history, forest structure (density, species composition, regeneration, forest floor fuels, herbaceous cover, and age of pines), and the dendrochronological tree-ring record were measured at two unharvested 70-ha pine-oak sites near Ojito de Camellones, Durango, Mexico. Study sites were matched in slope, aspect, elevation, slope position, and plant composition, but they differed in fire history since 1945 and in forest structure. The long-term mean fire intervals (MFI) for all fires at both sites up to 1945 were similar—4.0 years at Site 1 (1744–1945) and 4.1 years at Site 2 (1815–1945)—but Site 1 burned only three times at the site margins since 1945 while Site 2 had 9 fires that scarred two or more sample trees and 15 total fires since 1945. Density measurements and age and diameter distributions showed that Site 1 was dominated by numerous, younger, smaller trees (mean total basal area of 23.4 m2/ha and 2730 trees/ha), while Site 2 had fewer, older, larger trees (basal area of 37.2 m2/ha, 647 trees/ha). Large, rotten fuel loading and duff depth were also greater at Site 1. Because regeneration averaged 6200 stems/ha at Site 1 and 8730 stems/ha at Site 2 (no significant difference), forest density at Site 2 was not limited by regeneration capability. The distributions of overstory diameter and pine age at both sites indicate that tree establishment occurred in pulses, with the largest cohort of trees establishing at Site 1 following the 1945 fire. The dense regeneration and heavy fuel accumulation at Site 1 are likely to support a switch from the former low-intensity fire regime to a high-intensity, stand-replacing fire across the site when the next suitable combination of ignition and weather occurs. Baseline quantitative information on fire frequency and ecological effects is essential to guide conservation or restoration of Madrean forests and may prove valuable for restoration of related fire-dependent ecosystems that have experienced extended fire exclusion elsewhere in North America.
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  • 84
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    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Calc-silicate rocks occur as elliptical bands and boudins intimately interlayered with eclogites and high-pressure gneisses in the Münchberg gneiss complex of NE Bavaria. Core assemblages of the boudins consist of grossular-rich garnet, diopside, quartz, zoisite, clinozoisite, calcite, rutile and titanite. The polygonal granoblastic texture commonly displays mineral relics and reaction textures such as post kinematic grossular-rich garnet coronas. Reactions between these mineral phases have been modelled in the CaO-Al2O3-SiO2-CO2-H2O system with an internally consistent thermodynamic data base. High-pressure metamorphism in the calc-silicate rocks has been estimated at a minimum pressure of 31 kbar at a temperature of 630d̀ C with XH2, O ≥ 0.03. Small volumes of a CO2-N2-rich fluid whose composition was buffered on a local scale were present at peak-metamorphic conditions. The P-T conditions for the onset of the amphibolite facies overprint are about 10 kbar at the same temperature. XCo2 of the H2O-rich fluid phase is regarded to have been 〈0.03 during amphibolite facies conditions. These P-T estimates are interpreted as representing different stages of recrystallization during isothermal decompression. The presence of multiple generations of mineral phases and the preservation of very high-pressure relics in single thin sections preclude pervasive post-peak metamorphic fluid flow as a cause of a re-equilibration within the calc-silicates. The preservation of eclogite facies, very high-pressure relics as well as amphibolite facies reactions textures in the presence of a fluid phase is in agreement with fast, tectonically driven unroofing of these rocks.
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  • 85
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    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Mineral stable isotopic and trace element studies in 2 GPa banded eclogites of the Tauern Window, eastern Alps, record mm- to cm-scale heterogeneities that reflect compositional variations in the accompanying metamorphic fluids. A close correlation between dolomite mode and dolomite δ18O is consistent with equilibrium partitioning among coexisting minerals and fluids. Small variations in dolomite δ13C values correspond with δ18O variations, but an overall decrease in dolomite δ13C by c. 1%o across a 12-cm sample is a relict feature that pre-dates eclogite equilibration. Garnet, omphacite, and clinozoisite rims show little systematic mineral-mineral partitioning behaviour for Ti, V, Cr, Y, Sr, or Zr; major elements, however, are well equilibrated among these same minerals. Despite the apparent lack of mineral-mineral trace element equilibration, most of the trace elements vary systematically with water activity calculated in each layer. Trace element behaviour during the eclogite metamorphism thus appears to have been controlled largely by mineral-fluid interactions along grain boundaries.Shallow structural levels in other subduction complexes (c. 10-45 km) typically exhibit fracture-controlled permeability and extensive metasomatism, but there is no field or geochemical evidence for extensive fluid advection during high-pressure metamorphism in the Tauern eclogites. Because most dewatering and devolatilization during tectonic burial occurs prior to eclogite conditions, the volumetric fluid/rock ratio in eclogites should generally be low. Low fluid/rock ratios, coupled with the possible non-wetting nature of the fluids, permits the production and preservation of fine-scale chemical heterogeneities in deeply subducted eclogites and associated fluids. However, the eventual breakdown at greater depth of volatile-bearing dolomite, phengite, clinozoisite, zoisite, or amphibole could lead to renewed fracture-controlled fluid release from the subducted rocks to regions appropriate for arc magma generation.
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  • 86
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    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Metamorphism of the Gile Mountain Formation and Waits River Formation in the Strafford Dome and Townshend-Brownington Syncline in east-central Vermont records two nappe-style events, D1 and D2, followed by doming. D1 formed a muscovite + biotite ± ilmenite schistosity subparallel to compositional layering, SO, and was followed by heating to garnet grade. The temperature and pressure at the end of D1 are estimated to be c. 450d̀ C and 6-8 kbar. D2 variably crenulated and folded S1 during a nearly isothermal pressure increase of 1-2 kbar, calculated from compositions of garnet, which have inclusions trails with progressive crenulation and rotation of the S1 fabric. Similar P-T paths are computed for most of the area, suggesting that the later schistosity developed during emplacement of a regional nappe 3-6 km thick. There is a general lack of D3 (dome-stage) microstructures.Near the Strafford-Willoughby Arch, staurolite and kyanite overgrew S2 in pelites, and plagioclase with increasing XAn overgrew S2 in calcic pelites, reflecting post-D2 heating to a maximum of 550-600d̀ C. Metamorphic pressures at the end of D2 are fairly constant on the west side of the dome, indicating minor dome-stage uplift. In contrast, pressures at the thermal peak of metamorphism decrease by more than 4 kbar east of the dome. The observed pattern of isotherms and isobars is mainly the result of post-metamorphic, differential uplift and unroofing.Finally, a minor, retrograde metamorphism produced the assemblage albite + epidote + K-feldspar + muscovite + chlorite, with grade increasing east toward the Connecticut River.
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  • 87
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    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Grandite garnet-rich calcsilicate rocks from the Lower Calcsilicate Unit of the regionally metamorphosed Reynolds Range Group (central Australia) crop out along a strike-parallel section in which a transition zone from M22 amphibolite to granulite facies rocks is exposed. Across this transition the grandite-rich layers do not show systematic changes in mineral assemblages, compositions and modes, or stable isotope compositions. These layers are deformed by F22 folds that are associated with the peak of regional low-pressure/high-temperature metamorphism. Therefore, the grandite-rich layers appear to pre-date regional metamorphism and to have acted as closed chemical systems during prograde M22 metamorphism.Mineral assemblages in the grandite-rich layers are consistent with their formation through the infiltration of oxidized, water-rich fluids (Xco2 〈 0.1–0.3; log fo2 -16 to -14). The stable isotope values of calcite (Δ13C=-4.2 to -0.8%0 PDB; Δ18O = 10.5–14.0%0 V-SMOW) and bulk-silicate fractions (Δ18O = 6.1 to 10.8%) of the grandite-rich layers are most consistent with the infiltrating fluid being from a magmatic source. It is most likely that fluid infiltration occurred during the pre-M22 contact metamorphism (M21) that affected much of the Reynolds Range Group. The preservation of these assemblages is probably due to their high variance and little pervasive fluid-rock interaction having occurred during M22.The clinopyroxene- and feldspar-rich calcsilicate rocks that host the grandite-rich layers contain poikiloblastic grandite garnet that formed during prograde M22 metamorphism. Thin marbles that locally occur with the grandite-rich layers contain a third garnet generation that is post- or late M22. This grossular-rich garnet occurs in coronas around calcite, plagioclase, clinopyroxene, wollastonite and scapolite. These coronas are consistent with cooling and/or compression. However, because the marble assemblages are themselves overprinted by M21 grandite-rich layers the development of coronal garnet does not reflect a continuous P-T-t path. Rather, it more probably reflects the partial re-equilibration of M21 contact metamorphic assemblages to post-M22 conditions.
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  • 88
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    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Proterozoic granulite facies gneisses in MacRobertson Land, east Antarctica, are cut by numerous D5 mylonite-ultramylonite zones of probable Cambrian age. In garnet-absent mafic two-pyroxene gneisses and garnet-bearing charnockitic orthogneisses, the mylonite-ultramylonite zones are characterized by the growth of garnet at the expense of ilmenite, pyroxene and plagioclase. Textures within each mylonite zone can vary from protomylonitic to ultramylonitic. A range of mineral textures involving M5 garnet is developed corresponding to variations in deformation intensity. In protomylonites, garnet occurs as coronas on orthopyroxene-plagioclase and ilmenite-plagioclase boundaries, and as overgrowths on earlier garnet. In ultramylonites, fine-grained orthopyroxene-plagioclase-garnet ± quartz ± clinopyroxene intergrowths and poikilitic garnet are common. Garnet growth in all shear zones is accompanied by shifts in the compositions of neoblastic minerals occurring with garnet, consistent with local chemical equilibrium having been attained during recrystallization. Mylonitization is inferred to have occurred at P∼ 6.5 kbar. Temperature estimates for M5 vary between 550 and 797d̀ C, which may reflect variations and uncertainties associated with the calibrations used and/or partial re-equilibration during cooling. The presence of post-tectonic, coronate garnet in some mylonite zones indicates that garnet continued to form exclusively in the mylonite zones after movement had ceased and is interpreted to reflect the effects of localized strain heating.
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  • 89
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    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Transmission and scanning electron microscopy were utilized to investigate the nature and mechanisms of alteration of abundant detrital biotite of volcanic origin and progressive modification of phyllosilicate aggregates in a prograde sequence of pelitic rocks (illite crystallinity index = 0.19–0.58d̀λ2θ) from the Gaspé Peninsula in Quebec.Detrital biotite has been diagenetically altered to form corrensite and chlorite through two mechanisms; (1) layer-by-layer replacement gave rise to interstratification of packets of layers and complex mixed layering via several kinds of layer transitions between biotite and chlorite, corrensite or smectite; (2) dissolution-transport-precipitation resulted in the formation of relatively coarse-grained aggregates of randomly orientated, corrensite-rich flakes and fine-grained corrensite intergrown with chlorite and illite in the matrix.The data show that stacks consisting of alternating packets of trioctahedral and dioctahedral phyllosilicates originated during early diagenesis when lenticular fissures in strained altering biotite were filled by dioctahedral clays. Subsequent prograde evolution of dioctahedral clays occurred through deformation, dissolution and crystallization, and overgrowth. Illite evolved to muscovite, with K in part provided through biotite alteration, and corrensite/chlorite to homogeneous chlorite. The alteration of detrital biotite is closely related to the formation of titanite and magnetite in diagenetic rocks, and pyrite, calcite and anatase or rutile in the higher grade rocks.The observations demonstrate that detrital biotite of volcanic origin may be the principal precursor of chlorite in chlorite-rich metapelites originating in marginal basins. The mineral parageneses suggest that the transitions from corrensite to chlorite and illite to muscovite may be a function of local chemistry and time.
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  • 90
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    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: A fluid dynamic model for a rigid spherical porphyroblast growing in a viscous fluid matrix undergoing simple shear deformation predicts an arrangement of captured inert inclusions that is remarkably similar to the spiral pattern observed in synkinematic ‘rolled’ garnets. The model assumes only creeping (Stokes) flow of the matrix and a kinetic model for the growth of the porphyroblast of the form rm=kmΩ, where r is the crystal radius, Ω is the amount of shear-induced rotation, and m and k are kinetic parameters. For rotation less than 18d̀, J. B. Thompson and J. L. Rosenfeld's simple ring-model provides a surprisingly accurate description of the three-dimensional geometry of the central inclusion surface in the simulated porphyroblasts. Although marker planes, originally parallel to the shear plane, are deflected around the porphyroblast, their intersections with its surface remain approximately circular for much larger amounts of rotation than anticipated by Rosenfeld. The polar coordinate equation, T(r, θ), of the double spiral formed by the trace of the central inclusion surface in a section through the centre of simulated porphyroblasts, is also surprisingly simple, as follows: rm∼ (6/5k)mθ. This relationship was observed over the complete range of rotation angles investigated, 0-720d̀, and could form a reasonable basis for estimating the growth-rotation history of rolled garnets from the shape of their spiral inclusion trails. Two-dimensional sections through the simulated porphyroblasts, parallel to the rotation axis, yield ‘clamshell’ (Rosenfeld's term) inclusion geometries similar to the controversial ‘millipede’ patterns observed in many natural porphyroblasts.
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  • 91
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    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Detailed textural and chemical data for mineral assemblages on a regional scale are presented for the metaandesitic Eocene-Oligocene Taveyanne greywacke of the Glarus Alps, Eastern Switzerland. Presented data indicate an increase of metamorphic grade from zeolite facies to prehnite-pumpellyite and pumpellyite-actinolite facies. Low-grade outcrops contain laumontite, minor corrensite and pumpellyite (assemblage type 1), whereas outcrops of higher metamorphic grade contain prehnite and two populations of pumpellyite (type 2), prehnite—pumpellyite-(Al)—white mica (type 3), a single outcrop shows pumpellyite-actinolite facies (type 4). From the zeolite to prehnite-pumpellyite/pumpellyite-actinolite facies there are indications for an increase of the chemical equilibrium domain size for the critical paragenesis from a single detrital grain ≤1 mm) in type 1, to a few millimetres in type 2, and to a whole thin section in type 3. Metamorphic P-T conditions were determined by a combination of chlorite thermometry, fluid inclusion and vitrinite reflectance data. Peak temperatures range from 170-190d̀ C for zeolite facies to 270-310d̀ C for prehnite-pumpellyite and pumpellyite-actinolite facies. For the higher temperature range, pressures of 2-3 kbar are derived indicating a geothermal gradient of 24-32d̀ C km-1. The well-constrained temperature estimations derived for the assemblages provide a useful test of the different empirical calibrations of chlorite thermometers recently proposed. The best correspondence to the temperatures determined here is for the Cathelineau calibration. In addition, in the lower grade samples differences in textures and calculated temperatures provide a mean to distinguish between detrital and newly formed chlorites.
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  • 92
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    Journal of metamorphic geology 12 (1994), S. 0 
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Discordant andalusite-biotite-quartz-bearing veins occur in the contact aureole of the Vedrette di Ries pluton (Italian Eastern Alps), never outside the area of contact metamorphic andalusite development. Andalusite veins are found only within andalusite-bearing hornfelses, and vein biotite occurs wherever host-rock garnet is partially replaced by biotite. Veins formed during contact metamorphism, synchronously with the crystallization of andalusite and biotite within host rocks. Their pegmatitic structure and their orientation suggest that vein parageneses crystallized within fluid-filled cavities that opened by hydraulic fracturing.A mechanism of synmetamorphic veining is proposed to explain rock failure and subsequent mineral deposition within veins. During hydrofracturing induced by dehydration reactions in response to heating in the aureole, fissures were immediately filled with locally derived fluids. The lack of large-scale flux, together with high fluid pressures required by hydrofracturing, suggest fluid in the cavities was a virtually stagnant, passive medium, and that mass-transport toward fractures was driven by intergranular diffusion. Because temperature and Pf values within veins are similar to those in the host rock, vein assemblages are interpreted as the stable, high-T side of reactions taking place within pelitic schists, at the time when fractures opened. Once nucleation of product phases occurred, chemical components released by dissolution of reactant minerals were driven to precipitation sites by chemical potential gradients. Since nucleation was favoured at the strained grains of vein walls, andalusite and biotite simultaneously grew in vein and host rock.The proposed genetic model contrasts with generally adopted metasomatic mechanisms for the genesis of Al2SiO5-bearing veins, in not requiring large fluid/rock ratios or a highly ‘aggressive’ fluid composition. The mechanism of synmetamorphic veining may be particularly useful in the interpretation of vein occurrences in medium- and deep-crustal rocks which have undergone extensive devolatilization.
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Mineral and isotope studies were undertaken on migmatites from the Schwarzwald, Moldanubian zone of the Variscan belt. The aims of the study were to date the migmatite formation and to determine the processes involved in migmatization in order to evaluate their influence on isotopic resetting. Textural evidence and the comparison of mineral compositions from leucosomes and mesosomes of two centimetre-scale migmatite profiles, respectively, suggest that migmatitic textures and mineral assemblages were formed by metamorphic segregation (deformation-enhanced mass transport) rather than by partial melting (anatexis). The results of Rb-Sr thin-slab dating on these profiles indicate that Sr isotopes were not completely reset during migmatization. No true isochron ages, but ages of approximate isotopic homogenization were obtained on the thin slabs by calculating 87Sr/86Sr ratios back to various stages in their evolution. The coincidence of these Rb-Sr data with U-Pb ages of monazites from migmatites and non-migmatitic gneisses shows that gneisses and migmatites were formed during the same high-temperature event in the Carboniferous (330-335 Ma). The observation that high-temperature metamorphism failed to equilibrate Sr isotopes on the centimetre-scale imposes limitations on the use of conventional whole-rock isochron techniques in dating migmatites.
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  • 94
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    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
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  • 95
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: In the inner aureole of the Bufa del Diente alkali syenite (north-east Mexico), thin calcareous argillite bands horizontally embedded in impure marbles acted as contact-metamorphic aquifers for hypersaline brines of magmatic origin. Thick-bedded marbles were largely impervious. From 180 m up to the intrusion contact, argillites were completely decarbonated, resulting in melilite + wollastonite + phlogopite + perovskite-bearing parageneses. In marbles, this assemblage is confined to a narrow 7-12-m-wide infiltration zone adjacent to the contact. Up to this distance, calcite + wollastonite + diopside + alkali feldspar + titanite was stable, indicating that the fluid evolution in these marbles was internally buffered.Brine infiltration from the metaargillite aquifer into the marbles occurred perpendicular to the marble-metaargillite boundaries and was confined to a zone 4-6 cm wide above the boundaries. This is documented by the three reactionsCc + Di = Mel + CO2, (1)Cc + Kfs + Di + H2O = Phl + Wo + CO2, (2)Cc + Ttn = Prv + Wo + CO2, (3)Melilites (Ak32-45Gh13-32Sm32-40 to Ak52-72Gh0-1Sm28-48) occur as rims around diopsides and become continuously thicker towards the metaargillite beds. Fluid inclusion observations suggest that the infiltrating brine was hypersaline (NaCl + KClcq∼ 65 wt%) and that the reactions took place at the water-rich side of the H2O-CO2-salts immiscibility field at about 600d̀ C (2, 3) and 660 to 680d̀ C (1) at P∼ 1200 bar and Xco2∼ 0.02.Mass balance calculations show that the amount of brine infiltrated from the aquifer into the marble was very low and decreased continuously with increasing distance from the boundary. The maximum width of brine infiltration was about 6 cm. This confirms that brine flow was largely parallel to the aquifer, not perpendicular to it. The CO2 produced by the decarbonation reactions probably escaped as an immiscible low-density H2O-CO2 fluid of Xco2≤ 0.5 into overlying marble via grain-edge flow. The metaargillite-marble boundary acted as a semipermeable membrane 6 cm in thickness keeping back the brine in the aquifer and losing the in-situ produced low-density CO2-rich fluid.
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  • 96
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: During the Alice Springs Orogeny, deformation at Ormiston Gorge, central Australia, occurred under lower- to middle-greenschist facies conditions. Dolomites of the Bitter Springs Formation and quartzites. metagreywackes, and metapelites of the Heavitree Quartzite contain abundant early-, syn-, and post-tectonic veins. However, though vein densities locally approach 15%, the distribution of veins and the oxygen isotope geochemistry of wallrocks and veins suggest that fluid movement was on a local scale. The Heavitree Quartzite contains quartz veins that, even along the main thrust plane, have similar δ18O values (13.5–16.9%o) to those of their wallrocks (13.6–16.9%o), with Δ18O(vein-wallrock) values of -0.6 to 0.4%o. In contrast, the Bitter Springs Formation contains predominantly dolomite veins that have δ18O values of 23.4 to 27.7%o. These differences are observed even at the boundary between the Heavitree and Bitter Springs rocks, implying that significant fluid exchange between these rocks has not occurred, or that fluid flow was channelled through areas outside those sampled for this study. By contrast with the Heavitree Quartzite, δ18O values of wallrocks in individual samples of the Bitter Springs Formation are significantly higher (23.3–29.1%o) than those of the veins, with δ18O(vein-wallrock) values up to -4%o (average of -2.1%o). These systematic differences in δ18O values most likely result from oxygen isotope fractionation caused by fluid immiscibility or disequilibrium dissolution. Smaller differences in δ13C values between some dolomite veins and wallrocks [δ13C(vein-wallrock) up to -1.9%o, average of -0.5%o] are also explained by these processes. This study indicates that large volumes of veins may be produced by repeated fracturing and fluid migration within particular rock units, without involving large volumes of externally derived fluids.
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  • 97
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Calcite and quartz veins have formed, and are forming, in steeply dipping fissures in the actively rising Alpine Schist metamorphic belt of New Zealand. The fluids that deposited these minerals were mostly under hydrostatic pressure almost down to the brittle-ductile transition, which has been raised to 5-6 km depth by rapid uplift. Some fluids were trapped under lithostatic pressures. Fluids in the fissure veins were immiscible H2O + NaCl-CO2 mixtures at 200-350d̀ C. Bulk fluid composition is 15-20 mol% CO2 and 〈4.3 total mol CH4+ N2+ Ar/100mol H2O. Water hydrogen isotopic ratio δDH2O in the fissure veins spans -29 to -68‰, δ18OH2O -0.7 to 8.5‰, and bulk carbon isotopic ratio δ13C ranges from -3.7 to -11.7‰. The oxygen and hydrogen isotopic data suggest that the water has a predominantly meteoric source, and has undergone an oxygen isotope shift as a result of interaction with the host metamorphic rock. Similar fluids were present during cooling and uplift. Dissolved carbon is not wholly derived from residual metamorphic fluids; part may be generated by oxidation of graphite.
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  • 98
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: In the central Minto Block of northern Québec, the Lake Minto and Goudalie domains are dominated, respectively, by orthopyroxene-bearing plutonic suites (granite-granodiorite and diatexite) and a tonalitic gneiss complex, both of which contain scattered remnant paragneisses. Two main granulite-grade mineral assemblages are observed in the paragneiss: garnet (Grt)-orthopyroxene (Opx)-plagioclase-quartz (GOPQ) and garnet (Grt)-cordierite (Crd)-sillimanite-plagioclase-quartz (GCSPQ). These show distinct lithological associations, with the GCSPQ assemblages occurring exclusively within the diatexite in the Lake Minto domain. Petrogenetic grid considerations demonstrate that the GOPQ rocks are higher grade than the GCSPQ rocks. Maximum temperatures for GOPQ rocks, obtained from equilibria based on Al solubility in orthopyroxene in equilibrium with garnet, range from 950 to 1000d̀ C, significantly higher than garnet-orthopyroxene Fe-Mg exchange temperatures of 700 ± 50d̀ C, the latter probably representing a closure temperature below peak conditions. The Al temperatures were corrected for late cation exchange by adjusting the Fe/(Fe + Mg) ratios in garnet and orthopyroxene, to achieve internal consistency between the GOPQ thermometers and barometers. Grt-Crd thermometry records temperatures of 750±50d̀ C. Peak P-T conditions range from 5-6 kbar and 750-800d̀ C in the Goudalie and eastern Lake Minto domains, to 7-10 kbar and 950-1000d̀ C in the western and central Lake Minto domain. This variability contrasts with the uniform crustal pressures of 5 ± 1 kbar recorded by the GCSPQ assemblages in the diatexites and the hornblende granodiorites (c. 4-5 kbar) across the same area. The GOPQ rocks are inferred to record earlier P-T conditions that prevailed before the formation of GCSPQ assemblages and the intrusion of the granodiorites. Partial P-T paths in GOPQ rocks from both domains, based on net transfer equilibria corrected for Fe-Mg resetting, document cooling of 100-250d̀ C from thermal-peak conditions, concomitant with a modest pressure decrease of 2-3 kbar. Although textures diagnostic of isobaric cooling are not developed, the paths are consistent with a tectonic model in which granulite metamorphism and crustal thickening in the Minto Block were consequences of magmatic underplating. The progression from higher P-T conditions recorded by GOPQ assemblages to lower P-T conditions recorded by GCSPQ assemblages is attributed to variable amounts of synmagmatic uplift and cooling in a single, continuous thermal event in the Minto crust, associated with protracted crustal magmatism. In the Goudalie and eastern Lake Minto domains, where GOPQ and GCSPQ rocks and Hbl granodiorites have similar P-T conditions of equilibration, the crust may not have been thickened as much as further west, where GOPQ P-T conditions are significantly higher than those of the hornblende granodiorites and the GCSPQ rocks.
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  • 99
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: A sequence of regional metamorphic isograds indicating a range from prehnite-pumpellyite to lower amphibolite facies was mapped in metabasites near Flin Flon, Manitoba. The lowest grade rocks contain prehnite + pumpellyite and are cut by younger brittle faults containing epidote + chlorite + calcite. Isobaric temperature-XCO2 and pressure-temperature (constant XCO2) diagrams were calculated to quantify the effects of CO2 in the metamorphic fluid on the stability of prehnite-pumpellyite facies minerals in metabasites containing excess quartz and chlorite. Prehnite and, to a lesser extent, pumpellyite are stable only in fluids with Xco2 〈0.002. For Xco2〉0.002, epidote + chlorite + calcite assemblages are stable. Our calculated phase relations are consistent with regional metamorphism in the Flin Flon area in the presence of an H2O-rich fluid and a more CO2-rich fluid in the later fault zones. We believe that the potential effects of small amounts of CO2 in the metamorphic fluid should be assessed when considering the pressure-temperature implications of mineral assemblages in low-grade metabasites.
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  • 100
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    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: The Palghat Gap region is located near the centre of the large southern Indian granulite terrane. at the northern edge of the Kodaikanal charnockite massif. The dominant rock types in the region are hornblende-biotite ± orthopyroxene gneisses and charnockites along with minor amounts of intercalated mafic granulite, metapelite and calc-silicate. The P-T estimates from garnetiferous mafic granulites and metapelite samples are generally in the range 9-10 kbar and 800-900d̀ C using both conventional thermobarometric methods and the TWEEQU thermobarometry program. These P-T estimates, which should be taken as minimum values, are among the highest yet reported for South Indian and Sri Lankan granulites. The occurrence of orthopyroxene + plagioclase symplectites around embayed garnet grains in the mafic granulites and cordierite rims around garnet grains in metapelite suggest an isothermal decompression-type path. Similarly, a core-rim P-T trajectory indicates c. 3 and 7 kbar decompression at high temperature in the mafic granulites and metapelite, respectively. In both rock types, the key to the determination of the retrograde P-T path was the recognition of small amounts of second generation plagioclase with a more anorthitic composition than the matrix plagioclase. The preservation of high garnet-pyroxene temperatures in the mafic granulites (despite small garnet grain size) suggests rapid cooling of the terrane. Calculated minimum cooling rates range from 8 to 80d̀ C Ma-1. Such cooling rates are more rapid than those associated with normal isostatic processes and suggest that the terrane was tectonically exhumed at high temperature.
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