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  • Elsevier  (178)
  • Frontiers Media  (101)
  • Wiley  (66)
  • American Association of Petroleum Geologists (AAPG)
  • American Institute of Physics (AIP)
  • Annual Reviews
  • 2020-2023  (344)
  • 2015-2019  (2)
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  • 1940-1944
  • 2022  (225)
  • 2020  (123)
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  • 1
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Physics Letters B 294 (1992), S. 466-478 
    ISSN: 0370-2693
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Physics Letters B 317 (1993), S. 474-484 
    ISSN: 0370-2693
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 2022-01-07
    Description: The Q10 temperature coefficient, which is widely used in scientific literature, is a measure of the temperature sensitivity of chemical reaction rates or biological processes. However, the conclusions drawn from applying this coefficient to experimental data obtained from biological processes are not universal. In many biological processes, Q10 values are often discordant with the results predicted by the Arrhenius law. The hypothesis tested in the present study is that this problem arises mainly from the fact that the Q10 coefficient is defined by the ratio between rates described by exponential laws instead of power laws. Considering this hypothesis and the need to review the mathematical laws and models currently used to describe rates and Q10 coefficients, we propose a model beyond the usual Arrhenius theory or exponential decay law herein. The proposed mathematical model is based on the theory of deformed exponential functions, with the ordinary Q10 model representing the conventional exponential function. Therefore, all results following the standard model remain valid. Moreover, we include a Q10 free open-source code, written in Python, and compatible with Windows, Linux and macOS platforms. The validation of the proposed model and confirmation of the given hypothesis were performed based on the following temperature-dependent biological processes: soil organic carbon (SOC) decomposition (which is essential to forecast the impact of climate change on terrestrial ecosystems); the metabolism of Arctic zooplankton; physiological processes of the respiratory and cardiovascular systems; rate of oxygen consumption in mitochondria of the eurythermal killifish Fundulus heteroclitus, and leaf respiration.
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  • 4
    Publication Date: 2022-01-07
    Description: Since 2010, the Soil Moisture and Ocean Salinity (SMOS) satellite mission monitors the earth emission at L-Band. It provides the longest time series of Sea Surface Salinity (SSS) from space over the global ocean. However, the SSS retrieval at high latitudes is a challenge because of the low sensitivity L-Band radiometric measurements to SSS in cold waters and to the contamination of SMOS measurements by the vicinity of continents, of sea ice and of Radio Frequency Interferences. In this paper, we assess the quality of weekly SSS fields derived from swath-ordered instantaneous SMOS SSS (so called Level 2) distributed by the European Space Agency. These products are filtered according to new criteria. We use the pseudo-dielectric constant retrieved from SMOS brightness temperatures to filter SSS pixels polluted by sea ice. We identify that the dielectric constant model and the sea surface temperature auxiliary parameter used as prior information in the SMOS SSS retrieval induce significant systematic errors at low temperatures. We propose a novel empirical correction to mitigate those sources of errors at high latitudes. Comparisons with in-situ measurements ranging from 1 to 11 m depths spotlight huge vertical stratification in fresh regions. This emphasizes the need to consider in-situ salinity as close as possible to the sea surface when validating L-band radiometric SSS which are representative of the first top centimeter. SSS Standard deviation of differences (STDD) between weekly SMOS SSS and in-situ near surface salinity significantly decrease after applying the SSS correction, from 1.46 pss to 1.28 pss. The correlation between new SMOS SSS and in-situ near surface salinity reaches 0.94. SMOS estimates better capture SSS variability in the Arctic Ocean in comparison to TOPAZ reanalysis (STDD between TOPAZ and in-situ SSS = 1.86 pss), particularly in river plumes with very large SSS spatial gradients.
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  • 5
    Publication Date: 2022-01-07
    Description: The exhumation of peridotite rocks in oceanic transform zones passes by the rheological transition between the ductile and brittle deformation until the complete emplacement in the oceanic lithosphere. The São Pedro and São Paulo Archipelago (SPSPA), in the Equatorial Atlantic, records the deformational products of ductile, brittle and the rocks/fluid interaction generating specific structures in each domain. The deformational stages are related to the transpressional and transtensional geodynamics of São Paulo Transform Fault. Firstly, during transpression, exhumation occurs associated with the ductile domain causing intense mylonitization in temperatures between ~700° and 800 °C, defined by olivine and orthopyroxene recrystallization. The interaction with fluids initially originated from the mantle generates amphibole and oxide-rich layers marking the passage to a semi-brittle deformation. The continuation of peridotite exhumation, associated with an NW-SE shortening and transpressional led to a higher availability of hydrothermal fluids. As a consequence, four serpentinization episodes are recorded, which are associated with semi-brittle to brittle transition under temperatures between 300° and 400 °C. Finally, the complete exhumation and establishment of brittle mechanisms led to carbonatation phase near the surface, with temperatures ranging from 300° to 150 °C. The active NW-SE tectonic stress generated E-W strike-slip faults that were filled by carbonates recording the final exhumation stage.
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  • 6
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    Elsevier
    In:  Environmental Technology & Innovation, 17 . Art.-Nr.: 100567.
    Publication Date: 2022-01-07
    Description: The present state of constantly increasing plastic pollution is the major concern of scientific researchers. The conventional techniques applied (i.e., burning and landfilling) to get plastic degraded from the environment are inadequate due to harmful byproducts and limited to its recycling. In this review, we have recapitulated recent biotechnological approaches, including synthetic microbial consortia, systems biology tools, and genetic engineering techniques which can pave the path towards the plastic bioremediation and degradation. Moreover, potential plastic degrader microbes and their degradation pathways are also summarized. Lastly, this review focuses on enhancing the understanding of the degradation ability of microorganisms using contemporary biotechnological tools.
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  • 7
    Publication Date: 2022-01-07
    Description: Atmospheric deposition of aerosols to the ocean provides an important pathway for the supply of vital micronutrients, including trace metals. These trace metals are essential for phytoplankton growth, and therefore their delivery to marine ecosystems can strongly influence the ocean carbon cycle. The solubility of trace metals in aerosols is a key parameter to better constrain their potential impact on phytoplankton growth. To date, a wide range of experimental approaches and nomenclature have been used to define aerosol trace metal solubility, making data comparison between studies difficult. Here we investigate and discuss several laboratory leaching protocols to determine the solubility of key trace metals in aerosol samples, namely iron, cobalt, manganese, copper, lead, vanadium, titanium and aluminium. Commonly used techniques and tools are also considered such as enrichment factor calculations and air mass back-trajectory projections and recommendations are given for aerosol field sampling, laboratory processing (including leaching and digestion) and analytical measurements. Finally, a simple 3-step leaching protocol combining commonly used protocols is proposed to operationally define trace metal solubility in aerosols. The need for standard guidelines and protocols to study the biogeochemical impact of atmospheric trace metal deposition to the ocean has been increasingly emphasised by both the atmospheric and oceanographic communities. This lack of standardisation currently limits our understanding and ability to predict ocean and climate interactions under changing environmental conditions.
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  • 8
    Publication Date: 2022-01-07
    Description: Highlights • Regional brain iron concentrations are heterogenous. • Regional distribution of iron is most consistent with ferritin mRNA expression. • SEC-ICP-MS reveals the protein masses that cytosolic iron is associated with. • More than 50 % of cytosolic iron is associated with ferritin. Iron is essential for brain development and health where its redox properties are used for a number of neurological processes. However, iron is also a major driver of oxidative stress if not properly controlled. Brain iron distribution is highly compartmentalised and regulated by a number of proteins and small biomolecules. Here, we examine heterogeneity in regional iron levels in 10 anatomical structures from seven post-mortem human brains with no apparent neuropathology. Putamen contained the highest levels, and most case-to-case variability, of iron compared with the other regions examined. Partitioning of iron between cytosolic and membrane-bound iron was generally consistent in each region, with a slightly higher proportion (55 %) in the ‘insoluble’ phase. We expand on this using the Allen Human Brain Atlas to examine patterns between iron levels and transcriptomic expression of iron regulatory proteins and using quantitative size exclusion chromatography-inductively coupled plasma-mass spectrometry to assess regional differences in the molecular masses to which cytosolic iron predominantly binds. Approximately 60 % was associated with ferritin, equating to approximately 25 % of total tissue iron essentially in storage. This study is the first of its kind in human brain tissue, providing a valuable resource and new insight for iron biologists and neuroscientists, alike.
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  • 9
    Publication Date: 2022-01-07
    Description: The aim of this study was to investigate the syntrophic methanogenesis from the perspective of energy transfer and competition. Effects of redox materials and redox potential on direct interspecies electron transfer (DIET) were examined through thermodynamic analysis based on the energy distribution principle. Types of redox materials could affect the efficiency of DIET via changing the total energy supply of the syntrophic methanogenesis. Decreasing system redox potential could facilitate DIET through increasing the total available energy. The competition between hydrogenotrophic methanogens and DIET methanogens might be the reason for the low proportion of the DIET pathway in the syntrophic methanogenesis. A facilitation mechanism of DIET was proposed based on the energy distribution. Providing sufficient electrons, inhibiting hydrogenotrophic methanogens and adding more competitive redox couples to avoid hydrogen generation might be beneficial for the facilitation of DIET.
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  • 10
    Publication Date: 2022-01-07
    Description: Highlights • NH4NO3, Tris-HCl, and NH4CH3COO are optimal buffers for use in SEC-ICP-MS metalloprotein analyses. • Optimal range of buffer concentration is 50–200 mM in SEC-ICP-MS. • 100 mM concentration reduces both protein column interactions and ICP-MS maintenance. • Dextran-based columns are best suited for the analysis of apo-copper proteins. The correct identification of the metalloproteins present in human tissues and fluids is essential to our understanding of the cellular mechanisms underpinning a host of health disorders. Separation and analysis of biological samples are typically done via size exclusion chromatography hyphenated with inductively coupled plasma-mass spectrometry (SEC-ICP-MS). Although this technique can be extremely effective in identification of potential metalloproteins, the choice of mobile phase may have a marked effect on results, results by adversely affecting metal-protein bonds of the metalloproteins of interest. To assess the choice of mobile phase on SEC-ICP-MS resolution and the resulting metalloproteome pattern, we analysed several different sample types (brain homogenate; Cu/Zn-superoxide dismutase (SOD1); a molecular weight standard mix containing ferritin (Ft), ceruloplasmin (Cp), cytochrome c (CytC), vitamin B12 (B12) and thyroglobulin (Tg) using six different mobile phase conditions (200 mM, pH 7.5 solutions of ammonium salts nitrate, acetate, and sulfate; HEPES, MOPS and Tris-HCl). Our findings suggest that ammonium nitrate, ammonium acetate and Tris-HCl are optimal choices for the mobile phase, with the specific choice being dependent on both the number of samples and method of detection that is hyphenated with separation. Furthermore, we found that MOPS, HEPES and ammonium sulfate mobile phases all caused significant changes to peak resolution, retention time and overall profile shape. MOPS and HEPES, in particular, produced additional Fe peaks that were not detected with any of the other mobile phases that were investigated. As well as this, MOPS and HEPES both caused significant concentration dependent matrix suppression of the internal standard.
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  • 11
    Publication Date: 2022-01-07
    Description: Symbiotic relationships range from parasitic to mutualistic, yet all endosymbionts face similar challenges, including evasion of host immunity. Many symbiotic organisms have evolved similar mechanisms to face these challenges, including manipulation of the host's transforming growth factor-beta (TGFβ) pathway. Here we investigate the TGFβ pathway in scelaractinian corals which are dependent on symbioses with dinoflagellates from the family Symbiodiniaceae. Using the Caribbean coral, Orbicella faveolata, we explore the effects of enhancement and inhibition of the TGFβ pathway on host gene expression. Following transcriptomic analyses, we demonstrated limited effects of pathway manipulation in absence of immune stimulation. However, manipulation of the TGFβ pathway significantly affects the subsequent ability of host corals to mount an immune response. Enhancement of the TGFβ pathway eliminates transcriptomic signatures of host coral immune response, while inhibition of the pathway maintains the response. This is, to our knowledge, the first evidence of an immunomodulatory role for TGFβ in a scelaractinian coral. These findings suggest variation in TGFβ signaling may have implications in the face of increasing disease prevelance. Our results suggest that the TGFβ pathway can modulate tradeoffs between symbiosis and immunity. Further study of links between symbiosis, TGFβ, and immunity is needed to better understand the ecological implications of these findings.
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  • 12
    Publication Date: 2022-01-07
    Description: Highlights • Microplastics act as anthropogenic vectors of trace metals in freshwaters. • Adsorption capacity of microplastics is enhanced by biofilms but is not strong as natural substrates. • Biofilms alter the adsorption kinetics and mechanisms of trace metals onto microplastics. • Microplastics enhance exchange rates of trace metals between water and solid materials. • Anthropogenic substrate is necessary in evaluation of migration and fate of trace metals. Microplastics (MPs) are ubiquitous in freshwater environments, and represent an emerging anthropogenic vector for contaminants, such as trace metals. In this study, virgin expanded polystyrene (PS) particles were placed in a eutrophic urban lake and a reservoir serving as the resource of domestic water for 4 weeks, to develop biofilms on the surface. For comparison, natural adsorbents in the form of suspended particles and surficial sediment were also sampled from these waterbodies. The trace metal adsorption properties of anthropogenic (virgin and biofilm covered microplastics) and natural substrates were investigated and compared via batch adsorption experiments. The adsorption isotherms fitted the Langmuir model, revealed that biofilms could enhance the trace metal adsorption capacity of MPs. However, natural substrates still had a greater adsorption capacity. Biofilms also alter the adsorption kinetics of trace metals onto MPs. The process of adsorption onto virgin MPs was dominated by intraparticle diffusion, whereas film diffusion governed adsorption onto biofilm covered microplastics and natural substrates. The trace metal adsorption of all the substrates was significantly dependent on pH and ionic strength. The adsorption mechanisms were further analyzed by SEM-EDS and FT-IR. The enhancement of adsorption was mainly attributed to complexation with functional groups contained in the biofilms, including carboxyl, amino, and phenyl-OH. Collectively, biofilm development intensifies the role of MPs in the migration and fate of trace metals in freshwater, since it does not give MPs an edge over natural substrates in adsorption.
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  • 13
    Publication Date: 2022-01-07
    Description: Highlights • New insights of CH4 and CO2 hydrates are explored using MD strategy. • The bubble evolution appears to be important over dissociation process. • RDF, MSD, AOP, and diffusion coefficient can be used to examine hydrate stability. • The most stable structure of CH4 and CO2 molecules in the gas hydrate is found. • A promising match is noticed between the MD and literature findings. A comprehensive knowledge and precise estimation of the dynamic, structural, and thermodynamic characteristics of hydrates are needed to assess the stability of gas hydrates. Thermodynamic model and experimental studies can be utilized to compute the physical and dynamic properties of hydrate structures. The use of molecular dynamic (MD) simulation is a well-established approach in gas hydrate studies at the atomic level where the properties of interest are obtained from the numerical solution of Newtonian equations. The present work uses MD simulations by employing the constant temperature-constant pressure (NPT), constant temperature-constant volume (NVT) conditions, and the consistent valence force field (CVFF) to monitor the stability and decomposition of methane and carbon dioxide gas hydrates with different compositions. The effects of temperature and composition on the hydrate stability are investigated. In this study, we also compute the radial distribution function, mean square displacement, diffusion coefficient, lattice parameter, potential energy, dissociation enthalpy as well as the density of methane and carbon dioxide under various thermodynamic and process conditions. The formation of methane and carbon dioxide bubbles is studied to investigate bubble evolution during hydrate dissociation. The sizes of methane and carbon dioxide bubbles are not the same due to different solubility conditions of methane and carbon dioxide in liquid water. In addition, the influences of pressure and temperature on the lattice parameter and density of clathrate hydrates are discussed. The obtained results are consistent with previous theoretical and experimental findings, implying that the methodology followed in this work is reliable. The most stable arrangement of methane and carbon dioxide molecules in the gas hydrate is found. The insights/findings of this study might be useful to further understand detailed transport phenomena (e.g., molecular interactions, gas production rate, carbon dioxide replacement, and carbon dioxide capture) involved in the process of carbon dioxide injection into gas hydrate reservoirs.
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  • 14
    Publication Date: 2022-01-07
    Description: Deep-ocean islands have long been associated with the generation of oceanic eddies in their wakes. However, their interaction with incoming eddies has seldom been considered. This study focuses on the characterization of background and locally generated mesoscale eddies in the Cabo Verde archipelago between 2003 and 2014. Special attention is given to the interaction of incoming eddies with the bathymetry of the islands, along with their impacts on the local generation of eddies. Island-induced wind-shear effects are also considered. In addition, some examples of the biological response to background and locally generated eddies are discussed. This is achieved by combining remote-sensing satellite observations for wind, sea surface height, and chlorophyll-a (Chla) surface concentrations. The results show that the interaction between incoming background eddies and the archipelago is a recurrent phenomenon, which results in eddy deflection, splitting, merging, intensification, and termination (sorted by highest to lowest number of occurrences). Local island-induced disturbances are also significant, mainly due to atmospheric effects. Such processes result in the generation of island-induced eddies and in wind-mediated eddy intensification and confinement, more often observed in the leeward group. Nonetheless, it is strongly suggested that many of the locally generated eddies are a direct product or by-product of the interaction of background eddies with the islands. With respect to the biological realm, a locally generated cyclonic eddy is observed to originate a pronounced phytoplankton bloom in the vicinity of the tallest island. Nonetheless, background eddies generated off the African coast are often associated with enhanced Chla concentrations when they intersect the archipelago. Such observations challenge the idea that local biological productivity in deep oceanic islands is exclusively driven by island-induced mechanisms.
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  • 15
    Publication Date: 2022-01-07
    Description: In an era of electronics, recovering the precious metal such as gold from ever increasing piles of electronic-wastes and metal-ion infested soil has become one of the prime concerns for researchers worldwide. Biological mining is an attractive, economical and non-hazardous to recover gold from the low-grade auriferous ore containing waste or soil. This review represents the recent major biological gold retrieval methods used to bio-mine gold. The biomining methods discussed in this review include, bioleaching, bio-oxidation, bio-precipitation, bio-flotation, bio-flocculation, bio-sorption, bio-reduction, bio-electrometallurgical technologies and bioaccumulation. The mechanism of gold biorecovery by microbes is explained in detail to explore its intracellular mechanistic, which help it withstand high concentrations of gold without causing any fatal consequences. Major challenges and future opportunities associated with each method and how they will dictate the fate of gold bio-metallurgy from metal wastes or metal infested soil bioremediation in the coming future are also discussed. With the help of concurrent advancements in high-throughput technologies, the gold bio-exploratory methods will speed up our ways to ensure maximum gold retrieval out of such low-grade ores containing sources, while keeping the gold mining clean and more sustainable.
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  • 16
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    Wiley
    In:  In: Bergey's Manual of Systematics of Archaea and Bacteria. Wiley, Chichester, p. 1.
    Publication Date: 2022-01-14
    Description: Rho.do.mi.cro' bi.um. Gr. neut. n. rhodon the rose; Gr. masc. adj. micros small; Gr. masc. n. bios life; N.L. neut. n. Rhodomicrobium red microbe. Proteobacteria / Alphaproteobacteria / Rhizobiales / Hyphomicrobiaceae / Rhodomicrobium Most characteristic for Rhodomicrobium species is the polar cell growth and the characteristic vegetative growth cycle which includes the formation of peritrichously flagellated swarmer cells and nonmotile “mother cells,” which form prosthecae from one to several times the length of the mother cell. Daughter cells originate as spherical buds at the end of the prosthecae and may undergo differentiation in various ways. They are Gram-negative ovoid to elongate-ovoid bacteria belonging to the Alphaproteobacteria. Internal photosynthetic membranes are of the lamellar type. Photosynthetic pigments are bacteriochlorophyll a and carotenoids of the spirilloxanthin series. The predominant cellular fatty acid is C18:1, which comprises more than 80% of the membrane-bound fatty acids. Ubiquinone and rhodoquinone with 10 isoprene units are present, and the lipopolysaccharides are characterized by a glucosamine-containing, phosphate-free lipid A with amide-bound C16:0 3 OH. DNA G + C content (mol%): 61.8–63.8. Type species: Rhodomicrobium vannielii Duchow and Douglas 1949.
    Type: Book chapter , NonPeerReviewed
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  • 17
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    Wiley
    In:  In: Bergey's Manual of Systematics of Archaea and Bacteria. Wiley, Chichester, p. 1.
    Publication Date: 2022-01-17
    Description: Proteobacteria Alphaproteobacteria Rhizobiales Hyphomicrobiaceae Blas.to.chlo'ris. Gr. masc. n. blastos bud shoot; Gr. masc. adj. chloros green; N.L. fem. n. Blastochloris green bud shoot. Proteobacteria / Alphaproteobacteria / Rhizobiales / Hyphomicrobiaceae / Blastochloris Blastochloris species are anoxygenic phototrophic Alphaproteobacteria that have bacteriochlorophyll b in their photosynthetic reaction centers. Crystals of the photosynthetic reaction centers of Blastochloris viridis were the first that have been studied in high-resolution structure analysis at 3 Å resolution. Internal photosynthetic membranes are present as lamellae underlying and parallel to the cytoplasmic membrane. Cells are rod shaped to ovoid and exhibit polar growth, budding, and asymmetric cell division and form rosette-like cell aggregates. They are motile by means of subpolar flagella and stain Gram-negative. Straight-chain monounsaturated C18:1 is the predominant component of cellular fatty acids. Ubiquinones and menaquinones are present, and the lipopolysaccharides are characterized by a 2,3-diamino-2,3-deoxy-d-glucose (DAG)-containing, phosphate-free lipid A with amide-bound C14:0 3OH. DNA G + C content (mol%): 63.8–68.3. Type species: Blastochloris viridis (Drews and Giesbrecht 1966) Hiraishi 1997 (Rhodopseudomonas viridis Drews and Giesbrecht 1966).
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  • 18
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    Wiley
    In:  In: Bergey's Manual of Systematics of Archaea and Bacteria (BMSAB). , ed. by Brenner, D. J., Krieg, N. R. and Staley, J. T. Wiley, New York, USA, pp. 506-507. ISBN 978-1-118-96060-8
    Publication Date: 2022-01-17
    Description: Rho.do.mi.cro' bi.um. Gr. neut. n. rhodon the rose; Gr. masc. adj. micros small; Gr. masc. n. bios life; N.L. neut. n. Rhodomicrobium red microbe. Proteobacteria / Alphaproteobacteria / Rhizobiales / Hyphomicrobiaceae / Rhodomicrobium Most characteristic for Rhodomicrobium species is the polar cell growth and the characteristic vegetative growth cycle which includes the formation of peritrichously flagellated swarmer cells and nonmotile “mother cells,” which form prosthecae from one to several times the length of the mother cell. Daughter cells originate as spherical buds at the end of the prosthecae and may undergo differentiation in various ways. They are Gram‐negative ovoid to elongate‐ovoid bacteria belonging to the Alphaproteobacteria. Internal photosynthetic membranes are of the lamellar type. Photosynthetic pigments are bacteriochlorophyll a and carotenoids of the spirilloxanthin series. The predominant cellular fatty acid is C18:1, which comprises more than 80% of the membrane‐bound fatty acids. Ubiquinone and rhodoquinone with 10 isoprene units are present, and the lipopolysaccharides are characterized by a glucosamine‐containing, phosphate‐free lipid A with amide‐bound C16:0 3 OH. DNA G + C content (mol%): 61.8–63.8. Type species: Rhodomicrobium vannielii Duchow and Douglas 1949.
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  • 19
    Publication Date: 2022-04-25
    Description: Wildfires are natural or anthropogenic phenomena increasing at alarming rates globally due to land-use alterations, droughts, climatic warming, hunting and biological invasions. Whereas wildfire effects on terrestrial ecosystems are marked and relatively well-studied, ash depositions into aquatic ecosystems have often remained overlooked but have the potential to significantly impact bottom-up processes. This study assessed ash-water-phytoplankton biomass dynamics using six plant species [i.e., three natives (apple leaf Philenoptera violacea, Transvaal milk plum Englerophytum magalismontanum, quinine tree Rauvolfia caffra) and three aliens (lantana Lantana camara, gum Eucalyptus camaldulensis, guava Psidium guajava)] based on a six-week mesocosm experiment with different ash concentrations (1 and 2 g L-1). We assessed concentrations of chemical elements, i.e., N, P, K, Ca, Mg, Na, Mn, Fe, Cu, Zn and B from ash collected, and we have observed significant differences among the species. High concentrations of P, K, Mn, Fe, Cu, Zn and B were recorded from Transvaal milk plum ash and low concentrations of P, K, Ca, Mg, Cu and Zn were recorded from apple leaf. An increase in phytoplankton biomass (using chlorophyll-a concentration as a proxy) for all treatments i.e., 1 and 2 g L-1 for all plant species ash was observed a week after, followed by decreases in the following weeks, with the exception of 2 g L-1 for lantana, gum and control. Silicate concentrations (i.e., used as a proxy for diatom abundance) showed increasing patterns among all ash treatments, with exception of controls. However, no clear patterns were observed between native and alien plant ash on both chl-a and silicate concentrations. We found that ash has notable effects on water chemistry, particularly nitrate, which increased throughout the weeks, whereas, pH and conductivity were high at low ash concentrations. The impacts of ash on water chemistry, chl-a and silicate concentrations vary with individual species and the amount of ash deposited into the system.
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  • 20
    Publication Date: 2022-05-31
    Description: One of the best-known greenhouse gases, CO2, has been increasing in the last decade of about 1.7%. To overcome the well-known global problems related to this gas, researchers of all over the world are working very hard in order to develop any strategies to seriously solve this issue. In this chapter, the authors focus their attention on one of the possible solutions to the problem: bacteria that are CO2 capture cells which have carried out this task since ancient times. In our work we make an excursus on all the biochemical processes of CO2 capture carried out by bacteria, ending with a detailed comparison of the most studied enzymes. One of the alternatives will be to genetically modify the organisms known to date to speed up their conversion process.
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  • 21
    Publication Date: 2022-07-22
    Description: Phytoplankton form the base of the pelagic food web in inland waters. Unlike rooted plants with access to nutrients in the sediment, phytoplankton depend on the open water as their sole direct source of minerals. Phytoplankton comprise cyanobacteria and phylogenetically diverse eukaryotic algae that convert light energy and mineral nutrients into organic matter. Many species also exploit the elements and energy within dissolved organic compounds and particles produced in the catchment or within the water. Here, we describe the nutrient requirements of phytoplankton, their different modes of nutrition, the mechanisms they employ to acquire nutrients and the ecological consequences of their varying ability to exploit an often scarce and spatially and temporally variable resource. When nutrients are abundant, often as a result of human disruption of nutrient cycles, phytoplankton productivity, and often biomass, increases to the point that it causes a range of ecological consequences that reduce the value of the water resource for mankind.
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  • 22
    Publication Date: 2022-07-24
    Description: The availability of dissolved iron (dFe) exerts an important control on primary production. Recent ocean observation programs have provided information on dFe in many parts of the ocean, but knowledge is still limited concerning the rates of processes that control the concentrations and cycling of dFe in the ocean and hence the role of dFe as a determinant of global primary production. We constructed a three-dimensional gridded dataset of oceanic dFe concentrations by using both observations and a simple model of the iron cycle, and estimated the difference of processes among the ocean basins in controlling the dFe distributions. A Green's function approach was used to integrate the observations and the model. The reproduced three-dimensional dFe distribution indicated that iron influx from aeolian dust and from shelf sediment were 7.6 Gmol yr and 4.4 Gmol yr in the Atlantic Ocean and 0.4 Gmol yr and 4.1 Gmol yr in the Pacific Ocean. The residence times were estimated to be 12.2 years in the Atlantic and 80.4 years in the Pacific. These estimates imply large differences in the cycling of dFe between the two ocean basins that would need to be taken into consideration when projecting future iron biogeochemical cycling under different climate change scenarios. Although there is some uncertainty in our estimates, global estimates of iron cycle characteristics based on this approach can be expected to enhance our understanding of the material cycle and hence of the current and future rates of marine primary production.
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  • 23
    Publication Date: 2022-10-05
    Description: Quantification of phthalates or phthalic acid esters (PAEs) might be problematic due to matrix overlap, auto-self absorbance and background scattering noise by the plastic lab materials although plastics have been reported in the release of PAEs. These materials (ambient air, reagents bottles, sampling devices, and various analytical instruments), are ubiquitous in the laboratory environment, thereby making it more difficult to reliably analyze of trace concentration of PAEs. Thus, in the current study, a straight forward and reliable protocol has been established for the analysis of PAEs including control of blank contamination, and the experimental conditions such as extraction time and temperature were optimized. The mass of PAEs in blank tests of selected materials ranged from 3±0.7 to 35±6 ng for liquid-liquid extraction (LLE) and from 5±1.8 to 63±15 ng for solid-phase extraction (SPE). For both extraction methods, higher blank values were measured for dibutyl phthalate (DBP) (35±6 ng, 12±3 ng), and DEHP (63±12 ng, 23±5 ng) in LLE and SPE, respectively. Average recoveries of PAEs in LLE were 90-97% and obtained with successive aliquots of 2 mL, 1 mL, and 1 mL dichloromethane (DCM). For SPE, recoveries up to 86-90% were achieved with successive aliquots of 5, 3, and 2 mL DCM at a sample flow rate of 5 mL min -1 . Under the optimized conditions, the method quantification limits (MQL) for PAEs was 10-20 ng L -1 for LLE and 10-35 ng L -1 for SPE. Moreover, the dissolved concentrations of PAEs from LDPE measured by the LLE method ranged 〈 1.5 to 5.83 ng cm -2, and those measured by SPE ranged from 1.0to256ngL -1 , in seawater samples of Sharm Obhur. The method has lower MQL values for LLE and SPE than average reported values of 10-100 ng L -1 and 30-100 ng L -1 , respectively.
    Type: Article , NonPeerReviewed
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  • 24
    Publication Date: 2022-12-02
    Description: A key requirement for geological CO2 storage is site integrity management and monitoring during operation through to the post decommissioning period. This paper focuses on monitoring deformation of the ground surface and seabed as a proxy for overall deformation in the reservoir and surrounding layers. The objective is to inform, based on deformation data, on how the reservoir is responding to CO2 injection and to ensure any issues with regard to storage integrity are rapidly detected. The magnitude and pattern of deformation at the surface reveals geomechanical/hydromechanical processes that occur in reservoir due to CO2 injection. We acquired deformation data from the In Salah CO2 injection site and from four additional study cases during the course of this study; one in the onshore UK, the other a combined campaign onshore Norway and offshore Germany, and the third in onshore Japan. Significant developments in measurement techniques, processing tools and interpretation algorithms were developed through this project. Models were then developed to simulate the observed data and to couple surface deformation to displacement in the subsurface. The results show millimeter-scale deformations in the subsurface have a signature at the surface that can be captured by the tools and workflows developed in this project. These deformations, particularly the patterns, are important factors to consider when monitoring a CO2 storage site.
    Type: Article , NonPeerReviewed
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  • 25
    Publication Date: 2022-12-19
    Description: New sedimentological data of facies and diagenesis as well as chronological data including strontium (87Sr/86Sr)-isotope ratios and uranium (U)-series dating, radiocarbon (14C) accelerator mass spectrometry (AMS) dating and biostratigraphy from elevated reef terraces (makatea) in the southern Cook Islands of Mangaia, Rarotonga and Aitutaki contribute to controversial discussions regarding age and sea-level relationships of these occurrences during the Neogene and Quaternary. The oldest limestones of the uplifted makatea island of Mangaia include reef-related facies which are mid-Miocene in age, based on new Sr-isotope and biostratigraphical data. In between these older deposits and the lowest coastal reef terrace of marine isotope stage (MIS) 5e, various older Pleistocene reef-related facies were identified. Based on Sr-isotope ratios, these were deposited during earlier Pleistocene highstands (as old as 2.28 Ma). Rare reef terraces on Rarotonga belong to the Plio-Pleistocene and the late Miocene, according to 87Sr/86Sr ratios. The late Miocene age is enigmatic as it exceeds the age of subaerially exposed volcanic rocks of Rarotonga island. The fossil reef could have formed on an older submarine volcanic high that was later displaced by younger volcanism to its present position, or the Sr-age could be too old due to diagenetic resetting. The Plio-Pleistocene Rarotonga reef terraces are overlain irregularly by Holocene reef deposits that are interpreted as storm rubble. Reef terraces on Aitutaki represent evidence of a higher-than-present (up to 1 m) sea-level during the late Holocene, based on 14C AMS age data. They are very similar to elevated late Holocene reefs of adjacent French Polynesia with regard to composition, elevation and age.
    Type: Book chapter , NonPeerReviewed
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  • 26
    Publication Date: 2022-04-01
    Description: Volcanic hazard assessment relies on the accurate knowledge of the eruptive style and recurrence of volcanic eruptions in the past. At El Hierro (Canary Islands) historical and prehistorical records are still poorly defined, and although the island was the location of one of the most recent eruptions (La Restinga, 2011 CE) of the Canarian archipelago, the recent subaerial volcanism is still poorly studied. Information about the age of Holocene volcanic activity as well as the stratigraphy of the deposits is scarce: few eruptions are dated so far, whereas the others are classified as pre-or Holocene events considering lava flow characteristics along the coast. Here, we report on the dating of eleven (M˜na Chamuscada, M˜na del Tesoro, Orchilla, Las Calcosas, M˜na Negra, Lomo Negro, Below Lomo Negro, Cuchillo del Roque, Malpaso Member, and M˜na del Guanche) Holocene subaerial eruptions, distributed along the three rift zones, combining paleomagnetic and 14C methods. We also provide geochemical analyses for nine of them. Results indicate that M˜na Chamuscada and M˜na del Tesoro occurred more recently than previously considered, setting them within the last two thousand years. Conversely, paleomagnetic and 14C ages found for Lomo Negro eruption are consistent with literature data (Villasante- Marcos and Pav´on-Carrasco, 2014) and constrain the occurrence of this event in the XVI century CE. Finally, for Malpaso Member deposits, the two 14C datings obtained by charcoals found below and above the trachytic layer set the eruption during the Holocene epoch, between ~7300 BCE and ~4700 BCE. For the other eruptions, in two cases (Orchilla and Las Calcosas) many possible time windows during the last 14 ka have been found, whereas a few possible ages have been obtained for the others. On the whole, the resulting chronological reconstruction of the recent activity of El Hierro indicates that eruptions occurred unevenly along the three main rifts, with nine eruptions in the WNW rift, six in the NE rift, and four in the SSE rift. We document at least two periods characterized by high eruptive frequency: an old one, between 8000 BCE and 1000 BCE, with eight eruptions, three of which characterized by more evolved compositions (phonotephrite and trachyte), and a recent one, between 1000 BCE and present day, with at least seven eruptions, mainly showing basanite compositions. The new data yield a significant improvement of Holocene eruption chronology, thus are instrumental for a correct evaluation of the volcanic hazard at El Hierro.
    Description: Published
    Description: 107526
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
    Keywords: Paleomagnetism ; El Hierro ; 04.05. Geomagnetism ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 27
    Publication Date: 2022-04-01
    Description: The Gutenberg–Richter law and the Omori law are both characterized by a scaling behavior. However, their relation is still an open question. Although several hypotheses have been formulated, a comprehen- sive geophysical mechanism is still missing to explain the observed variability of the scaling exponents b-value and p-value, e.g., correlating the seismic cycle to statistical seismology and tectonic processes. In this work, a model for describing the size-frequency scaling and the temporal evolution of seismicity is proposed starting from simple assumptions. The parameter describing how the number of earthquakes decreases after a major seismic event, p, turns out to be positively correlated to the exponent of the frequency-size distribution of seismicity, b, and related to tectonics. Our findings suggest that p ≈ 23 (b + 1). It implies that a relationship between fracturing regimes, “efficiency” of the seismic process, duration of the seismic sequences and geodynamic setting exists, with outstanding potential impact on seismic hazard. On the other hand, the Gutenberg–Richter law simply reflects the tendency of the segments of the Earth’s crust to reach mechanical stability via constrained energy-budget optimization. Each perturbation has a probability of growing an earthquake or not, depending on disorder within the fault zone and the energy accumulated in the adjoining volume, mainly controlling the evolution of seismic sequences. The results are consistent with the different energy sources related to the tectonic settings, i.e., gravitational in extensional regimes, having higher b and p values, and generating lower maximum magnitude earthquakes with respect to strike-slip and contractional settings, which are rather fueled by elastic energy, showing lower b and p values, and they may generate higher magnitude events.
    Description: Published
    Description: 117511
    Description: 3T. Fisica dei terremoti e Sorgente Sismica
    Description: JCR Journal
    Keywords: Gutenberg–Richter distribution ; fracturing and fault disorder ; Omori–Utsu law ; earthquake triggering ; tectonic setting ; 04.06. Seismology ; 04.07. Tectonophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 28
    Publication Date: 2022-04-13
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 29
    Publication Date: 2022-03-11
    Description: As the Arctic coast erodes, it drains thermokarst lakes, transforming them into lagoons and, eventually, integrates them into subsea permafrost. Lagoons represent the first stage of a thermokarst lake transition to a marine setting and possibly more saline and colder upper boundary conditions. In this research, borehole data, electrical resistivity surveying, and modelling of heat and salt diffusion were carried out at Polar Fox Lagoon on the Bykovsky Peninsula, Siberia. Polar Fox Lagoon is a seasonally isolated water body connected to Tiksi Bay through a channel, leading to hypersaline waters under the ice cover. The boreholes in the centre of the lagoon revealed floating ice and a saline cryotic bed underlain by a saline cryotic talik, a thin ice‐bearing permafrost layer, and unfrozen ground. The bathymetry showed that most of the lagoon was ice‐grounded in spring. In bedfast ice areas, the electrical resistivity profiles suggest that an unfrozen saline layer was underlain by a thick layer of refrozen talik. The modelling suggests thermokarst lake taliks refreeze when submerged in saltwater with mean annual bottom water temperatures below or slightly above 0 °C. This occurs, because the top‐down chemical degradation of newly formed ice‐bearing permafrost is slower than the cooling of the talik. Hence, lagoons may pre‐condition taliks with a layer of ice‐bearing permafrost before encroachment by the sea and this frozen layer may act as a cap on gas migration out of the underlying talik.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev , info:eu-repo/semantics/article
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  • 30
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    Unknown
    Wiley
    In:  EPIC3Journal of Geophysical Research-Atmospheres, Wiley, 127(3), pp. 1-18, ISSN: 0148-0227
    Publication Date: 2022-02-28
    Description: Fram Strait in the northern North Atlantic is a key region for marine cold air outbreaks (MCAOs), southward discharges of polar air under northerly air flow, which have a strong impact on air-sea heat fluxes, boundary layer processes and severe weather. This study investigates climatologies and decadal trends of Fram Strait MCAOs of different intensity classes based on the ERA5 reanalysis product for 1979–2020. Among striking interannual variability, it is shown that the main MCAO season is December through March, when MCAOs occur around 2/3 of the time. We report on significant decadal MCAO decreases in December and January, and a significant increase in March. While the mid-winter decrease is mainly related to the different paces of warming between the surface and the lower atmosphere, the increase in March can be related to changes in synoptic circulation patterns. As an explanation for the latter, a possible feedback between retreating Barents Sea sea ice, enhanced cyclonic activity and Fram Strait MCAOs is postulated. Exemplifying the trend toward stronger MCAOs during March, the study details the recordbreaking MCAO season in early 2020, and an observational case study of an extreme MCAO event in March 2020 is conducted. Thereby, radiosonde observations are combined with kinematic air back-trajectories to provide rare observational evidence for the diabatic cooling and drying during the MCAO preconditioning phase.
    Repository Name: EPIC Alfred Wegener Institut
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  • 31
    Publication Date: 2022-03-02
    Description: The continental margin of the Ross Sea has been consistently sensitive to the advance and retreat of the Ross Ice Sheet (RIS) between the interglacial and glacial periods. This study examines changes of the glaciomarine sedimentation on the continental slope and rise to the eastern side of Hillary Canyon in the central Ross Sea, using three gravity cores collected at increasing water depths. Besides older AMS 14C ages of bulk sediments, based on the analytical results, sediment lithology was divided into units A, B1, and B2, representing Holocene, deglacial, and glacial periods, respectively. The sedimentation rate decreased as the water depth increased, with a higher sedimentation rate in the deglacial period (unit B1) than the Holocene (unit A). Biological productivity proxies were significantly higher in glacial unit B2 than in interglacial unit A, with transitional values observed in deglacial unit B1. Biological productivity generally decreased in the Antarctic continental margin during the glacial period because of extensive sea ice coverage. The higher biogenic contents in unit B2 are primarily attributed to the increased transport of eroded and reworked shelf sediments that contained abundant biogenic components to the continental slope and rise beneath the advancing RIS. Thus, glacial sedimentation on the continental slope and rise of the central Ross Sea was generally governed by the activity of the RIS, which generated melt-water plumes and debris flows at the front of the grounding line, although the continental rise might have experienced seasonally open conditions and lateral effects due to the bottom current.
    Repository Name: EPIC Alfred Wegener Institut
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  • 32
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    Unknown
    Elsevier
    In:  EPIC3Science for the Protection of Indonesian Coastal Ecosystems (SPICE), Science for the Protection of Indonesian Coastal Ecosystems (SPICE), Amsterdam, Netherlands, Elsevier, 457 p., pp. 143-199, ISBN: 978-0-12-815050-4
    Publication Date: 2022-03-04
    Description: Abstract Ecological and social processes of the Spermonde Archipelago, South Sulawesi, Indonesia, have been intensively studied during the Science for the Protection of Indonesian Coastal Ecosystems (SPICE) program. The archipelago is of specific interest to better understand how intensive exploitation of marine resources results in the degradation of reef systems. The projects specifically targeted (1) ecological processes in coral reefs, (2) genetic structure of populations, and (3) social–ecological dynamics relating to resource use, social networks, and governance structures. A modeling component emphasized (4) the integration of different ecological, social, and environmental components. Results indicated that reef resources in the Spermonde Archipelago are intensively exploited and further stressed by pollution effluents from hinterland processes. The lack of alternative livelihoods perpetuates dependencies within the patron–client system of the artisanal fisheries and supports high exploitation and also destructive resource uses. Greater inclusion of local stakeholders in the governance may result in better conservation practices, sustainable resource use, and improved livelihoods for the people. Abstrak Selama proyek SPICE, aspek ekologis dan sosial di perairan Kepulauan Spermonde, Sulawesi Selatan, Indonesia, dipelajari secara intensif. Kepulauan dan perairan ini mengundang banyak perhatian untuk lebih memahami bagaimana tingkat pemanfaatan sumber daya laut yang intensif berakibat pada degradasi sistem terumbu karang. Kerangka kerja proyek penelitian SPICE, secara khusus, menargetkan kajian-kajian mengenai (a) proses ekologis dalam sistem terumbu karang, (b) struktur genetik populasi untuk menentukan konektifitasnya, dan (c) dinamika sosial-ekologi yang berkaitan dengan penggunaan sumber daya, jejaring sosial dan struktur tata kelola. Komponen pemodelan juga dimasukkan kedalam kajian mengenai (d) integrasi berbagai komponen ekologi, sosial dan lingkungan dalam karakterisasi sistem sosial-ekologis. Hasil-hasil penelitian menunjukkan bahwa sumber daya terumbu karang di Kepulauan Spermonde sangat tereksploitasi dan terancam juga oleh limbah polusi dari proses di daratan. Kurangnya mata pencaharian alternatif memperkuat ketergantungan para nelayan tradisional pada sistem patron-klien dan meningkatkan penggunaan sumber daya yang tidak berkelanjutan dan merusak. Keikutsertaan pemangku kepentingan lokal yang lebih erat dalam tata kelola sumber daya alam Kepulauan Spermonde sangat memungkinkan hasil praktik konservasi yang lebih baik, penggunaan sumber daya berkelanjutan, dan peningkatan mata pencaharian bagi masyarakat.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Inbook , peerRev
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  • 33
    Publication Date: 2022-03-03
    Description: The Monte San Nicola area (Southern Sicily) offers a spectacular exposure of open-marine sediments that were employed in 1998 for defining the Global Stratotype Section and Point (GSSP) of the Gelasian Stage (Upper Pliocene). After the lowering of the Pliocene/Pleistocene boundary to ca. 2.6 Ma in 2010, the Gelasian GSSP has been redefined as the base of both the Pleistocene Series and the Quaternary Period, which increased its importance and visibility within the scientific community. However, documentation on the Monte San Nicola reference section is still sparse. In the light of its renewed status, we decided to undertake a complete revision of the Gelasian Stage in its type area, in order to evaluate whether the succession of bio- and magnetostratigraphic events that are expected to occur in the interval of relevance are represented adequately in the local record. The results of our investigation demonstrate that the Monte San Nicola succession spans continuously from the upper Piacenzian to the lower Calabrian, and is therefore suitable to host the Unit Stratotype, or even the Astronomical Unit Stratotype, of the Gelasian Stage.
    Description: Published
    Description: 107367
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 34
    Publication Date: 2022-03-07
    Description: The investigation of the role played by CO2 circulating within the mantle during partial melting and metasomatic/refertilization processes, together with a re-consideration of its storage capability and re-cycling in the lithospheric mantle, is crucial to unravel the Earth's main geodynamic processes. In this study, the combination of petrology, CO2 content trapped in bulk rock- and mineral-hosted fluid inclusions (FI), and 3D textural and volumetric characterization of intra- and inter-granular microstructures was used to investigate the extent and modality of CO2 storage in depleted and fertile (or refertilized) Sub-Continental Lithospheric Mantle (SCLM) beneath northern Victoria Land (NVL, Antarctica). Prior to xenoliths entrainment by the host basalt, the Antarctic SCLM may have stored 0.2 vol% melt and 1.1 vol% fluids, mostly as FI trails inside mineral phases but also as inter-granular fluids. The amount of CO2 stored in FI varies from 0.1 μg(CO2)/g(sample) in olivine from the anhydrous mantle xenoliths at Greene Point and Handler Ridge, up to 187.3 μg/g in orthopyroxene from the highly metasomatized amphibole-bearing lherzolites at Baker Rocks, while the corresponding bulk CO2 contents range from 0.3 to 57.2 μg/g. Irrespective of the lithology, CO2 partitioning is favoured in orthopyroxene and clinopyroxene-hosted FI (olivine: orthopyroxene = 0.10 ± 0.06 to 0.26 ± 0.09; olivine: clinopyroxene = 0.10 ± 0.05 to 0.27 ± 0.14). The H2O/(H2O + CO2) molar ratios obtained by comparing the CO2 contents of FI to the H2O amount retained in pyroxene lattices vary between 0.72 ± 0.17 and 0.97 ± 0.03, which is well comparable with the values measured in olivine-hosted melt inclusions from Antarctic primary lavas and assumed as representative of the partition of volatiles at the local mantle conditions. From the relationships between mineral chemistry, thermo-, oxybarometric results and CO2 contents in mantle xenoliths, we speculate that relicts of CO2-depleted mantle are present at Greene Point, representing memory of a CO2-poor tholeiitic refertilization related to the development of the Jurassic Ferrar large magmatic event. On the other hand, a massive mobilization of CO2 took place before the (melt-related) formation of amphibole veins during the alkaline metasomatic event associated with the Cenozoic rift-related magmatism, in response to the storage and recycling of CO2-bearing materials into the Antarctica mantle likely induced by the prolonged Ross subduction.
    Description: Published
    Description: 106643
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 4V. Processi pre-eruttivi
    Description: 2TR. Ricostruzione e modellazione della struttura crostale
    Description: JCR Journal
    Keywords: CO2 storage ; Sub-Continental Lithospheric Mantle ; Alkaline metasomatism ; Fluid inclusions ; Synchrotron X-ray microtomography ; Inter-granular fluids ; 04.01. Earth Interior ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 35
    Publication Date: 2022-03-07
    Description: Understanding the sources of potentially toxic elements (PTEs) in soils is a worldwide challenge that requires effective discrimination between geogenic and anthropogenic contributions, particularly in areas with certain geological complexity. This study aims to examine the chemical contents of 23 topsoil samples collected from the surroundings of a fossil fuel power plant in the village of Puerto Libertad (Sonoran Desert, Mexico). The study did not exclusively focus on the source identification of the priority PTEs to evaluate soil pollution. Furthermore, major oxides and immobile trace element (Zr, Hf, and REE: La→Lu) data were provided for a reliable assessment of the provenance of the soils. The relatively high SiO2 contents (65.26–75.42 wt%, anhydrous basis), the Post-Archean Australian Shale (PAAS)-normalized REE patterns, and the uniformity of the values of the Index of Compositional Variability (ICV = 1.11–2.72) and the Chemical Index of Alteration (CIA = 31.65–51.79) suggest that the soils were derived from intermediate to felsic source rocks, controlled by the local weathering of the parent bedrocks, under a low degree of chemical weathering conditions. The PTE data were treated following a robust workflow, which included the use of the enrichment factor (EF), the Spearman rank correlation (ρ), and multivariate statistical analyses allowed the generation of significant elemental associations and the identification of pools related either to the geological background or to anthropogenic activities. The results suggesting that Mo and Zn concentrations present a moderate anthropogenic influence while the concentrations of Pb, Sn, Cu, Cd, As, Cr, and Co are predominantly of geogenic origin. Vanadium (avg. EFV = 3.4) and Ni (avg. EFNi = 4.6) were the most enriched elements in the soils. Moreover, the highest values of the integrated Nemerow Pollution Index (PIN〉3) were recorded at the sampling stations closer to the village, suggesting point-source pollution by the emissions of the power station. Finally, in this paper is traced the extent of the particulate released into the atmosphere, which can be dispersed in a wide area into the Sonoran Desert.
    Description: Published
    Description: 105158
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Environmental geochemistry ; Geogenic sources ; Anthropogenic impact ; Provenance ; Power plant pollution ; Puerto libertad ; PTEs ; Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 36
    Publication Date: 2022-03-07
    Description: Comprehensive hydrogeochemical studies have been conducted in the Campi Flegrei volcanic aquifer since late 20th century due to the volcanic unrest. In the last decade, groundwater samples were grouped based on the dominant anion species (i.e. bicarbonate, sulfate and chloride) to explain the general hydrogeochemical processes. In this article, 44 groundwater samples are collected from Campi Flegrei aquifer to geochemically and spatially capture the main characteristics of the groundwater body. The hierarchical clustering algorithm is then performed on proportion of bicarbonate, sulfate and chloride, and the optimum number of clusters are determined regarding the results of deep hydrogeochemical investigations published in the past. The collected samples are categorized in the following groups: (1) bicarbonate-rich groundwater; (2) chlorine-rich groundwater; (3) sulfate-rich groundwater; and (4) mixed groundwater. The first group (As = 158.2 ± 169 μg/l, electric conductivity = 1,732.1 ± 1,086 μS/cm and temperature = 25.6 ± 8 ◦C) is mainly derived from poor arsenic meteoric water, but there is significant thermal/seawater contribution in the second one (As = 1,457.8 ± 2,210 μg/l, electric conductivity = 20,118.3 ± 11,139 μS/cm and temperature = 37.1 ± 20 ◦C). Interaction of the bicarbonate-rich groundwater and hydrothermal vapors gives rise to the sulfate-rich groundwater (As = 847.2 ± 679 μg/l, electric conductivity = 3,940.0 ± 540 μS/cm and temperature = 82.8 ± 3 ◦C) around Solfatara volcano. The mixed groundwater (As = 451.4 ± 388 μg/l, electric conductivity = 4,482.9 ± 4,027 μS/cm and temperature = 37.1 ± 16 ◦C) is observed where the three main groundwater groups undergo a mixing process, depending on the hydrogeology of the volcanic aquifer. Contrary to the bicarbonate- and sulfate-rich groundwater, the chlorine-rich and mixed groundwater generally occurs at low piezometric levels (approximately 〈1 m above sea level) near the coastline. The hierarchical cluster analysis provides more information about the volcanic aquifer, particularly when compositional data analysis is applied to study hydrogeochemistry of the homogeneous groundwater groups and to uncover the relationships between variables. Addressing compositional nature of data is recommended in the future studies for developing new tools that help deeper understanding of groundwater evolution in volcanic aquifers and identifying promising precursors of volcanic eruption.
    Description: Published
    Description: 106922
    Description: 4V. Processi pre-eruttivi
    Description: 2IT. Laboratori analitici e sperimentali
    Description: JCR Journal
    Keywords: Hierarchical cluster analysis ; Groundwater evolution ; Hydrothermal system ; Precursors of volcanic eruption ; 03.02. Hydrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 37
    Publication Date: 2022-04-24
    Description: Hillaire‐Marcelet al. bring forward several physical and geochemical arguments against our finding of an Arctic glaciolacustrine system in the past. In brief, we find that a physical approach to further test our hypothesis should additionally consider the actual bathymetry of the Greenland–Scotland Ridge (GSR), the density maximum of freshwater at 3–4°C, the sensible heat flux from rivers, and the actual volumes that are being mixed and advected. Their geochemical considerations acknowledge our original argument, but they also add a number of assumptions that are neither required to explain the observations, nor do they correspond to the lithology of the sediments. Rather than being additive in nature, their arguments of high particle flux, low particle flux, export of 230Th and accumulation of 230Th, are mutually exclusive. We first address the arguments above, before commenting on some misunderstandings of our original claim in their contribution, especially regarding our dating approach.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 38
    Publication Date: 2022-05-02
    Description: We assess about 20 years of onshore and offshore subsidence along a sector of the Upper Adriatic Sea (Italy) coastal areas affected by natural soil compaction and intense anthropogenic activities such as aquifers exploitation and hydrocarbons extraction. Our approach is based on the synergistic use of independent remote sensing and in-situ geodetic data to detect and spatially characterise the deformation pattern by cross-validating the different available measurements. We collect extensive datasets from i) SAR images provided by Envisat, Cosmo- SkyMed and Sentinel-1 missions, ii) GNSS measurements from continuous stations managed by public institutions, local authorities and private companies and iii) Leveling surveys. The cross-validation analysis shows good agreement among all the independent datasets, thus providing a reliable assessment of the ongoing deformation. We detect an onshore and offshore subsidence peak of about 1/-1.5 cm/yr in the proximity of the coastline, close to Lido di Dante and Fiumi Uniti villages, and at the present offshore platform. The outcomes highlight how the integration of different remote sensing and in situ geodetic techniques is successful to retrieve deformation history in time and space in complex areas, where different natural and anthropogenic sources concur to the overall deformation pattern. Moreover, such approach provides a robust support to modelling studies for hazard assessment in both inland and shoreline areas.
    Description: Published
    Description: 102756
    Description: 1TR. Georisorse
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 39
    Publication Date: 2022-04-29
    Description: We carried out new geological, morphotectonic, geophysical and paleoseismological investigations on the Meduno Thrust that belongs to the Pliocene-Quaternary front of the eastern Southern Alps in Friuli (NE Italy). The study area is located in the Carnic Prealps, where a series of alluvial terraces, linked to both climatic and tectonic pulses characterises the lower reach of the Meduna Valley. In correspondence of the oblique ramp of the Meduno Thrust, the Late Pleistocene Rivalunga terrace shows a set of scarps perpendicular to the Meduno valley, often modified by human activity. In order to reconstruct the tectonic setting of the area and identify the location for digging paleoseismological trenches, integrated geophysical investigations including electrical resistivity tomography, seismic refraction and reflection, ground penetrating radar and surface wave analyses (HVSR, ReMi and MASW), were carried out across the scarps of the Rivalunga terrace. Geophysical surveys pinpointed that in correspondence of the oblique ramp, stress is accommodated by a transpressive thrust system involving all the seismo-stratigraphic horizons apart from the ploughed soil. Trenching illustrated the Meduno Thrust movements during Late Pleistocene-Holocene. Trenches exhibited both shear planes and extrados fracturing, showing deformed alluvial and colluvial units. 14C datings of the colluvial units show that the most recent fault movements occurred after 1360 CE and 1670 CE. The age of the deformed stratigraphic units compared with the earthquakes listed in current catalogues, suggests that the 1776 earthquake (Mw 5.8, Io = 8–9 MCS) could represent the last seismic event linked to the Meduno thrust activity. This study provided new quantitative constraints improving seismic hazard assessment for Carnic prealpine area.
    Description: The research developed in the framework of the agreement between the Regione Autonoma Friuli Venezia Giulia - Direzione Centrale Ambiente ed Energia - Servizio Geologico, the Istituto Superiore per la Protezione e la Ricerca Ambientale (I.S.P.R.A.) and the University of Udine. The project was funded by the Regione Autonoma Friuli Venezia Giulia, Direzione Centrale Ambiente ed Energia, Servizio Geologico (C.I. G.: Z0E0C5EF75, p.i. Maria Eliana Poli).
    Description: Published
    Description: 229071
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Active fault ; Paleoseismology ; Morphogenic earthquake ; Eastern Southern Alps ; Applied geophysics ; NE Italy ; 04.04. Geology ; 04.07. Tectonophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 40
    Publication Date: 2022-05-03
    Description: Shallow seabed depressions attributed to focused fluid seepage, known as pock- marks, have been documented in all continental margins. In this study, we dem- onstrate how pockmark formation can be the result of a combination of multiple factors— fluid type, overpressures, seafloor sediment type, stratigraphy and bot- tom currents. We integrate multibeam echosounder and seismic reflection data, sediment cores and pore water samples, with numerical models of groundwa- ter and gas hydrates, from the Canterbury Margin (off New Zealand). More than 6800 surface pockmarks, reaching densities of 100 per km2, and an undefined number of buried pockmarks, are identified in the middle to outer shelf and lower continental slope. Fluid conduits across the shelf and slope include shal- low to deep chimneys/pipes. Methane with a biogenic and/or thermogenic origin is the main fluid forming flow and escape features, although saline and fresh- ened groundwaters may also be seeping across the slope. The main drivers of fluid flow and seepage are overpressure across the slope generated by sediment loading and thin sediment overburden above the overpressured interval in the outer shelf. Other processes (e.g. methane generation and flow, a reduction in hydrostatic pressure due to sea- level lowering) may also account for fluid flow and seepage features, particularly across the shelf. Pockmark occurrence coin- cides with muddy sediments at the seafloor, whereas their planform is elongated by bottom currents.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , peerRev
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  • 41
    Publication Date: 2022-05-25
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Romagnoni, G., Kvile, K. o., Dagestad, K., Eikeset, A. M., Kristiansen, T., Stenseth, N. C., & Langangen, O. Influence of larval transport and temperature on recruitment dynamics of North Sea cod (Gadus morhua) across spatial scales of observation. Fisheries Oceanography, (2020): 1-16, doi:10.1111/fog.12474.
    Description: The survival of fish eggs and larvae, and therefore recruitment success, can be critically affected by transport in ocean currents. Combining a model of early‐life stage dispersal with statistical stock–recruitment models, we investigated the role of larval transport for recruitment variability across spatial scales for the population complex of North Sea cod (Gadus morhua ). By using a coupled physical–biological model, we estimated the egg and larval transport over a 44‐year period. The oceanographic component of the model, capable of capturing the interannual variability of temperature and ocean current patterns, was coupled to the biological component, an individual‐based model (IBM) that simulated the cod eggs and larvae development and mortality. This study proposes a novel method to account for larval transport and success in stock–recruitment models: weighting the spawning stock biomass by retention rate and, in the case of multiple populations, their connectivity. Our method provides an estimate of the stock biomass contributing to recruitment and the effect of larval transport on recruitment variability. Our results indicate an effect, albeit small, in some populations at the local level. Including transport anomaly as an environmental covariate in traditional stock–recruitment models in turn captures recruitment variability at larger scales. Our study aims to quantify the role of larval transport for recruitment across spatial scales, and disentangle the roles of temperature and larval transport on effective connectivity between populations, thus informing about the potential impacts of climate change on the cod population structure in the North Sea.
    Description: G.R. was supported by the Norden Top‐level Research Initiative sub‐programme “Effect Studies and Adaptation to Climate Change” through the Nordic Centre for Research on Marine Ecosystems and Resources under Climate Change (NorMER). K.Ø.K. was supported by the WHOI John H. Steele Post‐doctoral Scholar award and VISTA – a basic research program in collaboration between The Norwegian Academy of Science and Letters, and Equinor. We thank an anonymous referee for valuable comments that substantially improved the article.
    Keywords: Atlantic cod ; biophysical model ; larval transport ; North Sea ; populations ; stock–recruitment ; temperature
    Repository Name: Woods Hole Open Access Server
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  • 42
    Publication Date: 2022-05-25
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Yoshii, A., & Green, W. N. Editorial: role of protein palmitoylation in synaptic plasticity and neuronal differentiation. Frontiers in Synaptic Neuroscience, 12(27), (2020), doi:10.3389/fnsyn.2020.00027.
    Description: Protein palmitoylation, the reversible addition of palmitate to proteins, is a dynamic post-translational modification. Both membrane (e.g., channels, transporters, and receptors) and cytoplasmic proteins (e.g., cell adhesion, scaffolding, cytoskeletal, and signaling molecules) are substrates. In mammals, palmitoylation is mediated by 23-24 palmitoyl acyltransferases (PATs), also called ZDHHCs for their catalytic aspartate-histidine-histidine-cysteine (DHCC) domain. PATs are integral membrane proteins found in cellular membranes. In the palmitoylation cycle, palmitate is removed by the depalmitoylation enzymes, acyl palmitoyl transferases (APT1 and 2), and α/β Hydrolase domain-containing protein 17 (ABHD17A-C). These are cytoplasmic proteins that are targeted to membranes where they are substrates for PATs. The second class of depalmitoylating enzymes are palmitoyl thioesterases, PPT1 and 2, discovered through their association with infantile neuronal ceroid lipofuscinosis. These are secreted proteins found in the lumen of intracellular organelles, primarily lysosomes, where their function as depalmitoylating enzymes is unclear.
    Description: This work was supported by University of Illinois start-up fund (to AY) and NIH/NIDA (grant DA044760 to WG).
    Keywords: palmitoylation and depalmitoylation ; synaptic plasticity ; axonal growth ; lysosome ; neurodegenerative disease ; neuronal ceroid lipofuscinoses (NCL) ; Huntington disease
    Repository Name: Woods Hole Open Access Server
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  • 43
    Publication Date: 2022-05-25
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Beam, J. P., Becraft, E. D., Brown, J. M., Schulz, F., Jarett, J. K., Bezuidt, O., Poulton, N. J., Clark, K., Dunfield, P. F., Ravin, N. V., Spear, J. R., Hedlund, B. P., Kormas, K. A., Sievert, S. M., Elshahed, M. S., Barton, H. A., Stott, M. B., Eisen, J. A., Moser, D. P., Onstott, T. C., Woyke, T., & Stepanauskas, R. Ancestral absence of electron transport chains in Patescibacteria and DPANN. Frontiers in Microbiology, 11, (2020): 1848, doi:10.3389/fmicb.2020.01848.
    Description: Recent discoveries suggest that the candidate superphyla Patescibacteria and DPANN constitute a large fraction of the phylogenetic diversity of Bacteria and Archaea. Their small genomes and limited coding potential have been hypothesized to be ancestral adaptations to obligate symbiotic lifestyles. To test this hypothesis, we performed cell–cell association, genomic, and phylogenetic analyses on 4,829 individual cells of Bacteria and Archaea from 46 globally distributed surface and subsurface field samples. This confirmed the ubiquity and abundance of Patescibacteria and DPANN in subsurface environments, the small size of their genomes and cells, and the divergence of their gene content from other Bacteria and Archaea. Our analyses suggest that most Patescibacteria and DPANN in the studied subsurface environments do not form specific physical associations with other microorganisms. These data also suggest that their unusual genomic features and prevalent auxotrophies may be a result of ancestral, minimal cellular energy transduction mechanisms that lack respiration, thus relying solely on fermentation for energy conservation.
    Description: This work was funded by the USA National Science Foundation grants 1441717, 1826734, and 1335810 (to RS); and 1460861 (REU site at Bigelow Laboratory for Ocean Sciences). RS was also supported by the Simons Foundation grant 510023. TW, FS, and JJ were funded by the U.S. Department of Energy Joint Genome Institute, a DOE Office of Science User Facility supported under Contract No. DE-AC02-05CH11231. NR group was funded by the Russian Science Foundation (grant 19-14-00245). SS was funded by USA National Science Foundation grants OCE-0452333 and OCE-1136727. BH was funded by NASA Exobiology grant 80NSSC17K0548.
    Keywords: Bacteria ; Archaea ; evolution ; genomics fermentation ; respiration ; oxidoreductases
    Repository Name: Woods Hole Open Access Server
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  • 44
    Publication Date: 2022-05-25
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Jacox, M. G., Alexander, M. A., Siedlecki, S., Chen, K., Kwon, Y., Brodie, S., Ortiz, I., Tommasi, D., Widlansky, M. J., Barrie, D., Capotondi, A., Cheng, W., Di Lorenzo, E., Edwards, C., Fiechter, J., Fratantoni, P., Hazen, E. L., Hermann, A. J., Kumar, A., Miller, A. J., Pirhalla, D., Buil, M. P., Ray, S., Sheridan, S. C., Subramanian, A., Thompson, P., Thorne, L., Annamalai, H., Aydin, K., Bograd, S. J., Griffis, R. B., Kearney, K., Kim, H., Mariotti, A., Merrifield, M., & Rykaczewski, R. Seasonal-to-interannual prediction of North American coastal marine ecosystems: forecast methods, mechanisms of predictability, and priority developments. Progress in Oceanography, 183, (2020): 102307, doi:10.1016/j.pocean.2020.102307.
    Description: Marine ecosystem forecasting is an area of active research and rapid development. Promise has been shown for skillful prediction of physical, biogeochemical, and ecological variables on a range of timescales, suggesting potential for forecasts to aid in the management of living marine resources and coastal communities. However, the mechanisms underlying forecast skill in marine ecosystems are often poorly understood, and many forecasts, especially for biological variables, rely on empirical statistical relationships developed from historical observations. Here, we review statistical and dynamical marine ecosystem forecasting methods and highlight examples of their application along U.S. coastlines for seasonal-to-interannual (1–24 month) prediction of properties ranging from coastal sea level to marine top predator distributions. We then describe known mechanisms governing marine ecosystem predictability and how they have been used in forecasts to date. These mechanisms include physical atmospheric and oceanic processes, biogeochemical and ecological responses to physical forcing, and intrinsic characteristics of species themselves. In reviewing the state of the knowledge on forecasting techniques and mechanisms underlying marine ecosystem predictability, we aim to facilitate forecast development and uptake by (i) identifying methods and processes that can be exploited for development of skillful regional forecasts, (ii) informing priorities for forecast development and verification, and (iii) improving understanding of conditional forecast skill (i.e., a priori knowledge of whether a forecast is likely to be skillful). While we focus primarily on coastal marine ecosystems surrounding North America (and the U.S. in particular), we detail forecast methods, physical and biological mechanisms, and priority developments that are globally relevant.
    Description: This study was supported by the NOAA Climate Program Office’s Modeling, Analysis, Predictions, and Projections (MAPP) program through grants NA17OAR4310108, NA17OAR4310112, NA17OAR4310111, NA17OAR4310110, NA17OAR4310109, NA17OAR4310104, NA17OAR4310106, and NA17OAR4310113. This paper is a product of the NOAA/MAPP Marine Prediction Task Force.
    Keywords: Prediction ; Predictability ; Forecast ; Ecological forecast ; Mechanism ; Seasonal ; Interannual ; Large marine ecosystem
    Repository Name: Woods Hole Open Access Server
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  • 45
    Publication Date: 2022-03-16
    Description: © 〈2021〉. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/
    Description: In this paper we explore the efficiency of various machine learning techniques to determine the volcano source,the eruptive formation and the eruption period of volcanic rocks when their chemical contents are known. Withthis aim, we assembled a data set of 9800 volcanic rocks from the open-access literature. The rocks belong toeruptive formations from Somma-Vesuvius, Campi Flegrei, Ischia and Procida volcanoes, in the Neapolitan regionof Italy.The data set includes content of majoroxidesand trace elements,aswell asSrand Nd isotope ratios,erup-tive periods, eruption formations and volcano source. Some discrete numerical variables are missing in certainsamples resulting in data exclusion and measurement inhomogeneity. Our results indicate that, despite such is-sues, some machine learning algorithms have a very high prediction ability, i.e., at 〉70%. The achieved resultsare interesting in order to facilitate the managing of new data for volcanological reconstruction andtephrostratigraphic studies
    Description: Published
    Description: 107254
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 46
    Publication Date: 2022-03-16
    Description: In this study we present the compositional changes of clinopyroxene (cpx), plagioclase (plg), spinel (sp), and glass experimentally solidified from an Icelandic MORB melt. The starting material was cooled at Patm and fO2 of air, in the thermal range of cooling (ΔTc) between 1300 °C (superliquidus) to 800 °C (solidus) with rates (ΔT/Δt) of 1, 7, 60, 180, 1800, and 9000 °C/h. The run products obtained at 1, 7 and 60 °C/h are holocrystalline, whilst between 60 and 180 °C/h plg disappears, and texture of cpx + sp. shifts from faceted to dendritic. As cooling rate increases, we observe that Fe2O3 decreases and Al2O3 increases in sp. and Al2O3 + Fe2O3 increase and CaO + MgO decrease in cpx. These measured variations mirror changes induced by cooling rate in cation (atoms per formula unit, a.p.f.u.) and molecular abundances of these two crystalline phases. Plg composition shows clear linear trends versus cooling rate. The chemistry of sp., cpx and, to a minor extent, plg solidified from this basaltic liquid is thus strictly related to the cooling rate condition and is similar to those observed in previous investigations on alkaline and evolved basaltic systems. In particular, cpx is the only mineral phase profusely present at all the cooling rates, showing the greatest chemical variations in terms of oxides, cations, and components. The intra-crystalline glass (≤ 50 μm from crystal rims) obtained at 180–1800 °C/h shows compositional variations related to the surrounding crystal growth, evidencing strong supersaturation phenomena (such as dendritic texture) due to the establishment of a diffusion-controlled growth regime. Chemical attributes of mineral phases are also quantitatively related with the maximum (Gmax) and average (GCSD) growth rates of sp., cpx, and plg. When compared with the starting melt composition, the chemistry of cpx suggests the attainment of near-equilibrium crystallization conditions at cooling rate ≤ 60 °C/h, whereas disequilibrium effects are found at cooling rate 〉 60 °C/h. In contrast, plg is in disequilibrium with the initial melt chemistry in all experiments. By using thermometric models, the calculated crystallization of plg takes place at temperatures much lower than those of cpx, when the crystal content is high and the diffusion of cations in the melt is slow due to the higher (residual) melt viscosity. Under such conditions and due to the effect of cooling, the system cannot return to homogeneous concentrations and, consequently, plg more effectively records the disequilibrium partitioning of cations between the growing crystal surface. The data-set reported here captures the entire (superliquidus to solidus) and intrinsic (heterogeneous site-free silicate liquid) solidification behavior from an actual MORB melt from very rapid to extremely sluggish cooling rate. Finally, all analytical relationships found in this work enable careful reconstruction of the solidification conditions of MORB melts, providing novel geo-speedometers for them at high fO2.
    Description: Published
    Description: 120765
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 47
    Publication Date: 2022-03-16
    Description: Volcano seismology, while its value for surveillance of an active volcano is undebatable, is a very demanding field when it comes to station deployment, maintenance, and finally interpreting the measurements. Most valuable in the past was the deployment of arrays of sensors to evaluate the properties of the entire wavefield in order to classify, locate, and estimate the dominant mechanism of the corresponding sources. While very beneficial, an array of seismographs is very hard to maintain in a permanent installation at an active volcano. With the advent of new instrumentation based on fiber optic technology such as Distributed Acoustic Sensing (DAS) with fiber optic cables as well as Fiber-Optic Gyroscopes (FOG) the measurement of deformation and rotation, i.e., the gradient of the wavefield is feasible. The advantage of the FOG instrumentation with respect to DAS lies in the portability and ease of deployment, which is very similar to standard deployments of traditional seismometers. During a field campaign in summer 2018 we were able to install three FOGs together with classical broadband seismometers in close proximity to the active vents of Stromboli volcano (Italy). We show that with this new six-degrees-of-freedom (6DOF) measurement we are able to analyze the wavefield composition, a property normally reserved for array(s) of seismic sensors. As a first result, we can support earlier array-derived findings that a large portion of the wavefield at Stromboli volcano is formed by SV- and SH- type waves. We also present first locations of these signals facilitating the polarization properties of the combined measurement of gyroscopes and seismometers. They emphasize the benefit of recording wavefield gradients. In addition to these array-like results, the 6DOF recordings show a clear separation of at least three distinct groups of volcanic events of which two are already known and one represents a jetting event that appears nearly invisible for classical seismometers. However, rotational motions - or more general - gradients of the wavefield experience severe distortions by local velocity fluctuations and topography significantly complicating the application of 6DOF techniques at activate volcanoes.
    Description: Published
    Description: 107499
    Description: 3T. Fisica dei terremoti e Sorgente Sismica
    Description: JCR Journal
    Keywords: 6 DOF ; rotational seismology ; volcanoseismology ; Stromboli ; 04.06. Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 48
    Publication Date: 2022-03-16
    Description: Tectono-stratigraphic interpretation and sequential restoration modelling was performed over two high-resolution seismic profiles crossing the Western Ionian Basin of southern Italy. This analysis was undertaken in order to provide greater insights and a more reliable assessment of the deformation rate affecting the area. Offshore seismic profiling illuminates the sub-seafloor setting where a belt of active normal faults slice across the foot of the Malta Escarpment, a regional-scale structural boundary inherited from the Permo-Triassic palaeotectonic setting. A sequential restoration workflow was established to back-deform the entire investigated sector with the primary aim of analysing the deformation history of the three major normal faults affecting the area. Restoration of the tectono-stratigraphic model reveals how deformation rates evolved through time. In the early stage, the studied area experienced a significant deformation with the horizontal component prevailing over the vertical element. In this context, the three major faults contribute to only one third of the total deformation. The overall throw and extension then notably reduced through time towards the present day and, since the middle Pliocene, ongoing crustal deformation is accommodated almost entirely by the three major normal faults. Unloading and decompaction indicate that when compared to the unrestored seismic sections, a revision and a reduction of roughly one third of the vertical displacement of the faults offset is required. This analysis ultimately allows us to better understand the seismic potential of the region.
    Description: Published
    Description: 321-341
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
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  • 49
    Publication Date: 2022-03-15
    Description: Single rainwater samples were collected in the city of Goma (~1,1 million inhabitants), eastern Democratic Republic of the Congo, from January to June 2013 to draw a baseline for rainwater chemical composition and quality as influenced by the permanent plume of Nyiragongo volcano. This was a better period for a baseline as the neighboring Nyamulagira volcano, only 15 km apart, had no important degassing from its central crater, and hence the recorded volcanic influence on the rainwater chemistry was solely from Nyiragongo's lava lake which has been active since May 2002. The baseline for the rainwater chemistry and quality is important for this highly populated region where rainwater is the unique potable water source for the inhabitants of many villages surrounding the volcanoes, and for some of the inhabitants of the city of Goma. Our results show that samples collected at the crater rim of Nyiragongo were more acidic with pH ranging from 3.70 to 3.82, while the majority of rainwater samples collected in downtown Goma city and to the northeastern zone of the volcano had pH close to 5.7; which represents the value for rainwater from unpolluted continental areas (Berner and Berner, 2012). However, the pH was as low as 3.93 to the west of Nyiragongo volcano because the volcanic plume is directed westward by the dominant local wind direction. The western part of the city of Goma as well as the small town of Sake and many villages (e.g. Rusayo, Mubambiro, Kingi, …) are located in this zone, and experience endemic fluorosis caused by high fluoride in the available water. The mean F- in this zone was 0.38 mg/L, while the southern and northeastern zones had mean F- concentrations on 0.44 and 0.01 mg/L respectively; even though concentrations higher than the WHO guidelines were found in few samples from the western zone (1.69 mg/L) and from the southern zone (3.44 mg/L). Compared to data from Cuoco et al. (2012) obtained during the Nyamulagira 2010 eruption, and from Balagizi et al.2017 and Liotta et al., 2017 obtained during the intense degassing of both Nyiragongo and Nyamulagira lava lakes; we have noted similarity in the spatial variation of the pH, but samples from the present study showed notable lower concentrations of major elements. This is the case for fluoride which is strictly of volcanic origin. For the other major elements, anthropogenic sources, mainly the traffic and wind-blown dust; or other non-volcanic natural sources influenced their concentrations. Thus, the anions (Cl- and SO42-) and cations (Na+, K+, Mg2+, and Ca2+) from the present study are either lower compared to that previously reported in the literature for the Virunga, or are both comparable for the zones impacted by anthropogenic activities.
    Description: Published
    Description: 130859
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Endemic dental fluorosis; Nyamulagira volcano; Nyiragongo volcanic plume; Rainwater chemistry; Rainwater quality baseline
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 50
    Publication Date: 2022-03-15
    Description: The origin of magmatic fluids along the East African Rift System (EARS) is a long-lived field of debate in the scientific community. Here, we investigate the chemical composition of the volcanic gas plume and fumaroles at Nyiragongo and Nyamulagira (Democratic Republic of Congo), the only two currently erupting volcanoes set on the Western Branch of the rift. Our results are in line with earlier conceptual models proposing that volcanic gas emissions along the EARS mainly reflect variable contributions of either a Sub-Continental Lithospheric Mantle (SCLM) component or a Depleted Morb Mantle (DMM) component, and deeper fluid. At Nyiragongo and Nyamulagira, our study discards a major contribution of a high 3He/4He mantle plume component in the genesis of volcanic fluids beneath the area. High CO2/3He in fumaroles of both volcanoes is thought to reflect carbonate metasomatism in the lithospheric mantle source. As inferred by previous results obtained on the lava chemistry, this carbonate metasomatism would be more pronounced beneath Nyiragongo. This supports the idea of the presence of distinct metasomes within the lithospheric mantle beneath the Western Branch of the rift.
    Description: Published
    Description: 120811
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: East African Rift System ; Volcano ; Gas chemistry ; 04.08. Volcanology ; 04.01. Earth Interior
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  • 51
    Publication Date: 2022-03-17
    Description: Coccolithophores were collected at 21 stations during summer 2016, from coastal and offshore areas of the Central Mediterranean Sea, to describe the ecology of the coccolithophore community integrating information on their abundance, environmental parameters (salinity, temperature, dissolved oxygen, and fluorescence) and oceanographic data. Emiliania huxleyi dominated the assemblage from surface to intermediate layers, while Florisphaera profunda was more abundant in the deep photic zone. Principal Component Analysis revealed that the distribution of coccolithophore taxa was influenced by environmental parameters: K-strategist taxa were related to warm surface waters, whereas lower photic zone taxa were influenced by the development of a Deep Chlorophyll Maximum and high salinity values, well below the thermocline. These results confirmed that a vertical species zonation, as a typical feature of low-middle latitude, characterizes the Central Mediterranean during summer. The distribution of F. profunda once again confirmed its use as a proxy of Deep Chlorophyll Maximum development and paleoproductivity estimates. Gephyrocapsa spp. (=total Gephyrocapsa), and in particular G. oceanica, were more abundant along the Atlantic Water pathway. Finally, the high concentration value of Helicosphaera carteri, recorded in the Ligurian Sea at an offshore station, suggested an expansion of the opportunist nature of this taxon from coastal environments to the offshore areas characterized by high turbidity and high productivity.
    Description: Published
    Description: 101995
    Description: 4A. Oceanografia e clima
    Description: JCR Journal
    Keywords: Living coccolithophores ; Helicosphaera carteri ; Oceanography ; Ecology ; Central Mediterranean Sea ; coccolithophore ecology and oceanography
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  • 52
    Publication Date: 2022-03-17
    Description: A high resolution study of calcareous nannofossils has been performed on samples from the Sapropel S1interval deposited in the North Ionian Sea, with the aim to assess the paleoenvironmental changes in the photic zone during this crucial interval in Mediterranean circulation. Calcareous nannofossil data have been integrated with planktonic foraminiferal data recently published from which the paleoclimatic curve has been constructed. Placoliths (namely Emiliania huxleyi) and Florisphaera profunda distributions, along with that of planktonic foraminifer Globigerinoides ruber white, evidence that, after a progressive weakening of surface water mixing, a deep chlorophyll maximum developed just prior to the sapropel deposition. We suggest that these changes took place as a response to enhanced precipitation conditions and riverine discharge as testified by increasing trend of reworked coccoliths and the occurrence of lower salinity taxon Braarudosphaera bigelowii. Calcareous nannofossils also point out that the oceanographic (water column stratification, reduced bottom water ventilation) and biogeochemical (increased primary production) processes that occurred during the S1 formation were particularly dominant during the earliest part of the older S1 warm phase (S1a). Our results support than some reventilation events of the shallow depth of studied site (665 m) occurred to some extent, particularly during the final phases of S1a. The distribution of holococcoliths, more abundant during the cold interruption phase S1i, seems confirm that the preservation of these tiny and delicate coccoliths, highly susceptible to dissolution, is enhanced under seafloor re-ventilation conditions. Finally, we tentatively suggest that preservation also plays a significant role in the distribution of the warm upper photic zone taxa, particularly during the warm S1b interval.
    Description: Published
    Description: 103599
    Description: 4A. Oceanografia e clima
    Description: JCR Journal
    Keywords: Sapropel S1 ; Calcareous nannofossils ; Planktonic foraminifera ; North Ionian Sea ; Mediterranean ; Hydrosphere
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  • 53
    Publication Date: 2022-03-17
    Description: The understanding of fault-slip behaviour in carbonates has an important societal impact due to the widespread occurrence and propagation of earthquakes in these rocks. Fault rock variations in carbonates are systematically controlled by the lithology of the faulted protolith: cataclasis and hydraulic fracturing with evidence of past seismic slip commonly affect fault rocks in competent limestone formations whereas widespread pressure-solution and sliding along clay foliation are observed in marly rocks. We performed a series of friction experiments on carbonatic fault rocks sampled from mature thrusts (〉2km displacement) in the Apennines of Italy. We sheared both intact wafers and powdered fault materials at low (10MPa) and in situ(53MPa) normal stress under room-humidity and water-saturated conditions. We used velocity steps (1 to 300μm/s) and slide–hold–slide (3–1000 s holds) to assess the frictional stability and healing behaviour of these rocks. We observe that cataclastic fault rocks derived from competent limestones are characterized by high friction coefficients coupled with significant post-slip restrengthening and velocity-weakening behaviour. Conversely, intact foliated marly tectonites, sheared under the same conditions, show low friction, null post-slip healing and stable velocity-strengthening behaviour suggesting that these rocks deform aseismically. To extrapolate these opposite mechanical behaviours to the entire fault surface we developed a fault model integrating our mechanical data, field observations and balanced geological cross-sections. The mechanical heterogeneities highlighted in the model provide constraints for the distribution of fault patches with higher seismogenic potential.
    Description: Published
    Description: 307–318
    Description: 3T. Fisica dei terremoti e Sorgente Sismica
    Description: JCR Journal
    Keywords: friction carbonates earthquakes fault
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 54
    Publication Date: 2022-03-29
    Repository Name: EPIC Alfred Wegener Institut
    Type: Inbook , peerRev
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  • 55
    Publication Date: 2022-03-21
    Description: Changbaishan, an intraplate volcano, is characterized by an approximately 6 km wide summit caldera and last erupted in 1903. Changbaishan experienced a period of unrest between 2002 and 2006. The activity developed in three main stages, including shield volcano (basalts), cone-construction (trachyandesites to trachytes with minor basalts), and caldera-forming stages (trachytes to comendites). This last stage is associated with one of the more energetic eruptions of the last millennium on Earth, the 946 CE, VEI 7 Millennium Eruption (ME), which emitted over 100 km3 of pyroclastics. Compared to other active calderas, the plumbing system of Changbaishan and its evolution mechanisms remain poorly constrained. Here, we merge new whole-rock, glass, mineral, isotopic, and geobarometry data with geophysical data and present a model of the plumbing system. The results show that the volcano is characterized by at least three main magma reservoirs at different depths: a basaltic reservoir at the Moho/lower crust depth, an intermediate reservoir at 10–15 km depth, and a shallower reservoir at 0.5–3 km depth. The shallower reservoir was involved in the ME eruption, which was triggered by a fresh trachytic melt entering a shallower reservoir where a comenditic magma was stored. The trachytes and comendites originate from fractional crystallization processes and minor assimilation of upper crust material, while the less evolved melts assimilate lower crust material. Syn-eruptive magma mingling occurred during the ME eruption phase. The magma reservoirs of the caldera-forming stage partly reactivate those of the cone-construction stage. The depth of the magma storage zones is controlled by the layering of the crust. The plumbing system of Changbaishan is vertically extensive, with crystal mush reservoirs renewed by the replenishment of new trachytic to trachyandesitic magma from depth. Unlike other volcanoes, evidence of a basaltic recharge is lacking. The interpretation of the signals preceding possible future eruptions should consider the multi-level nature of the Changbaishan plumbing system. A new arrival of magma may destabilize a part of or the entire system, thus triggering eruptions of different sizes and styles. The reference model proposed here for Changbaishan represents a prerequisite to properly understand periods of unrest to potentially anticipate future volcanic eruptions and to identify the mechanisms controlling the evolution of the crust below volcanoes.
    Description: National Natural Science Foundation of China (Grant Nos. 41972313 and 41790453), Engineering Research Center of Geothermal Resources Development Technology and Equipment, Ministry of Education, Jilin University, China, INGV Ricerca Libera.
    Description: Published
    Description: 101171
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 56
    Publication Date: 2022-03-21
    Description: The presence of weak phyllosilicates in mature carbonate fault zones has been invoked to explain weak faults. However, the relation between frictional strength, fault stability, mineralogical composition, and fabric of fault gouge, composed of strong and weak minerals, is poorly constrained. We used a biaxial apparatus to systematically shear different mixtures of shale (68% clay, 23% quartz and 4% plagioclase) and calcite, as powdered gouge, at room temperature, under constant normal stresses of 30, 50, 100 MPa and under room-dry and pore fluid-saturated conditions, i.e. CaCO3-equilibrated water. We performed 30 friction experiments during which velocity-stepping and slide-hold-slide tests were employed to assess frictional stability and to measure frictional healing, respectively. Our frictional data indicate that the mineralogical composition of fault gouges significantly affects frictional strength, stability, and healing as well as the presence of CaCO3-equilibrated water. Under room-dry condition, the increasing shale content determines a reduction in frictional strength, from μ = 0.71 to μ = 0.43, a lowering of the healing rates and a transition from velocity-weakening to velocity-strengthening behavior. Under wet condition, with increasing shale content we observe a more significant reduction in frictional strength (μ = 0.65–0.37), a near-zero healing and a velocity strengthening behavior. Microstructural investigations evidence a transition from localized deformation promoted by grain size reduction, in calcite-rich samples, to a more distributed deformation with frictional sliding along clay-enriched shear planes in samples with shale content greater than 50%. For faults cutting across sedimentary sequences composed of carbonates and clay-rich sediments, our results suggest that clay concentration and its ability to form foliated and interconnected networks promotes important heterogeneities in fault strength and slip behavior.
    Description: Published
    Description: 228811
    Description: 1T. Struttura della Terra
    Description: JCR Journal
    Keywords: Carbonate faults ; Fault slip behavior ; 04.02. Exploration geophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 57
    Publication Date: 2022-03-21
    Description: The 2016 Central Italy earthquake sequence is characterized by remarkable rupture complexity, including highly heterogeneous slip across multiple faults in an extensional tectonic regime. The dense coverage and high quality of geodetic and seismic data allow us to image intriguing details of the rupture kinematics of the largest earthquake of the sequence, the Mw 6.5 October 30th, 2016 Norcia earthquake, such as an energetically weak nucleation phase. Several kinematic models suggest multiple fault planes rupturing simultaneously, however, the mechanical viability of such models is not guaranteed. Using 3D dynamic rupture and seismic wave propagation simulations accounting for two fault planes, we constrain “families” of spontaneous dynamic models informed by a high-resolution kinematic rupture model of the earthquake. These families differ in their parameterization of initial heterogeneous shear stress and strength in the framework of linear slip weakening friction. First, we dynamically validate the kinematically inferred two-fault geometry and rake inferences with models based on only depth-dependent stress and constant friction coefficients. Then, more complex models with spatially heterogeneous dynamic parameters allow us to retrieve slip distributions similar to the target kinematic model and yield good agreement with seismic and geodetic observations. We discuss the consistency of the assumed constant or heterogeneous static and dynamic friction coefficients with mechanical properties of rocks at 3-10 km depth characterizing the Italian Central Apennines and their local geological and lithological implications. We suggest that suites of well-fitting dynamic rupture models belonging to the same family generally exist and can be derived by exploiting the trade-offs between dynamic parameters. Our approach will be applicable to validate the viability of kinematic models and classify spontaneous dynamic rupture scenarios that match seismic and geodetic observations as well as geological constraints.
    Description: T.U., T., D.L., and A.-A. Gabriel are supported by the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme (TEAR, agreement No. 852992 and ChEESE, grant no. 823844), the German Research Foundation (DFG project grants no. GA 2465/2-1 and GA 2465/3-1) and by KAUST-CRG (grant no. ORS-2017-CRG6 3389.02). E.T. was supported by Progetti di Ricerca Sapienza (RM120172A2EAC019). Computing resources were provided by the Leibniz Supercomputing Centre (LRZ, project no. pr63qo on SuperMUC-NG).
    Description: Published
    Description: 117237
    Description: 3T. Fisica dei terremoti e Sorgente Sismica
    Description: JCR Journal
    Keywords: earthquake source ; dynamic rupture ; high-performance computing ; frictional heterogeneity ; 04.06. Seismology ; 05.05. Mathematical geophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 58
    Publication Date: 2022-03-22
    Description: Crustal seismicity is in general confined within the seismogenic layer, which is bounded at depth by processes related to the brittle-ductile transition (BDT) and in the shallow region by fault zone consolidation state and mineralogy. In the past 10-15 years, high resolution seismological and geodetic data have shown that faulting within and around the traditional seismogenic zone occurs in a large variety of slip modes. Frictional and structural heterogeneities have been invoked to explain such differences in fault slip mode and behaviour. However, an integrated and comprehensive picture remains extremely challenging because of difficulties to properly characterize fault rocks at seismogenic depths. Thus, the central-northern Apennines provide a unique opportunity because of the integration of deep-borehole stratigraphy and seismic reflection profiles with high resolution seismological data and outcrop studies. These works show that seismic sequences are limited within the sedimentary cover (depth 〈 9-10 km), suggesting that the underlaying basement plays a key-role in dictating the lower boundary of the seismogenic zone. Here we integrate structural data on exhumed outcrops of basement rocks with laboratory friction data to shed light on the mechanics of the Apenninic basement. Structural data highlight heterogeneous and pervasive deformation where foliated and phyllosilicate-rich rocks surround more competent quartz-rich lenses up to hundreds of meters in thickness. Phyllosilicate horizons deform predominantly by folding and foliation-parallel frictional sliding whereas quartz-rich lenses are characterized by brittle signatures represented by extensive fracturing and minor faulting. Laboratory experiments revealed that quartz-rich lithologies have relatively high friction, μ ≈ 0.51, velocity-strengthening to neutral behaviour, and elevated healing rates. On the contrary, phyllosilicate-rich (muscovite and chlorite) lithologies show low friction, 0.23 〈 μ 〈 0.31, a marked velocity strengthening behaviour that increases with increasing sliding velocity and negligible rates of frictional healing. Our integrated approach suggests that in the Apenninic basement deformation occurs along shear zones distributed on thickness up-to several kilometres, where the frictionally stable, foliated, and phyllosilicate-rich horizons favour aseismic deformation and therefore confine the depth of major earthquake ruptures and the seismogenic zone.
    Description: Published
    Description: 117444
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 59
    facet.materialart.
    Unknown
    Wiley
    In:  EPIC3Limnology and Oceanography Letters, Wiley, 7(2), pp. 167-174, ISSN: 2378-2242
    Publication Date: 2022-03-25
    Description: The end of the polar night with the concurrent onset of photosynthetic biomass production ultimately leads to the spring bloom, which represents the most important event of primary production for the Arctic marine ecosystem. This dataset shows, for the first time, significant in situ biomass accumulation during the dark–light transition in the high Arctic, as well as the earliest recorded positive net primary production rates together with constant chlorophyll a-normalized potential for primary production through winter and spring. The results indicate a high physiological capacity to perform photosynthesis upon re-illumination, which is in the same range as that observed during the spring bloom. Put in context with other data, the results of this study indicate that also active cells originating from the low winter standing stock in the water column, rather than solely resting stages from the sediment, can seed early spring bloom assemblages.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 60
    Publication Date: 2022-02-28
    Description: Leucititic rocks, K-foiditic in composition are volumetrically important in the Colli Albani (also known as Alban Hills) volcanic district (Central Italy) especially during the most explosive phases of activity (〉200 km3). The Colli Albani tephra in distal (〉500 km) deposits indicates that K-foiditic magma chambers fed large explosive eruptions (i.e., tens of km3 of pyroclastic rocks). Major oxides, trace elements and Raman spectra were measured on the glasses and minerals occurring in the K-foiditic scoria clasts of the ~530 kyr-old Tufo del Palatino, erupted in the Colli Albani volcanic district. The Colli Albani pre-eruptive magmatic system is characterized by the aH2O 〈 1 and high CO2 activ- ity in the melt, as testified by the CO3 in the clinopyroxene melt inclusions, by the early crystallization of CO3-bearing apatite and by the high CO2 activity in the free volatile phase that led to crystallization of calcium carbonate in the scoria clast vesicles. The K-foiditic magmas plot on the Cpx + Lc + melt divariant surface of the Ol-Cpx-Lc-Mel- H2O-CO2, P ≥ 0.2 GPa and T ≤ 1100 °C. The assimilation of cold carbonate by hot magmas is an important open- system process allowing the establishment of aH20 〈 1 condition in the volatile-rich, Colli Albani magma chambers where the stability fields of the olivine and phlogopite are reduced in favor of clinopyroxene and leucite. Trace ele- ment modelling indicates large amount of carbonate assimilation (~12.4 wt%) involved in the differentiation process that origins the K-foiditic magmas starting from a K-rich, phonotephritic parental magma. The large amount of as- similate carbonate is consistent with the peculiar distribution of the latent heat across the crystallization interval of the phonotephritic parental magma. The isenthalpic assimilation process is very efficient in the phonotephritic magma because the crystallization of clinopyroxene and leucite in equilibrium with a K-foiditic melt proceeds over a relatively large temperature interval (〉200 °C) and the K-foiditic melt shows low viscosity (104Pa·s at 1000 °C). Actually, the low melt viscosity, that increases the growth rate, and the large temperature interval of crys- tallization are intrinsic factors that increase the release of the latent heat of crystallization from the phonotephritic parental magma. Extrinsic factors enhancing the assimilation process efficiency are the thickness (〉4 km) and the depth (down to 5–7 km) of the carbonate substrate in the Colli Albani volcanic district.
    Description: Published
    Description: 106239
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 61
    Publication Date: 2022-02-28
    Description: New analyses of marine terraces in the Tyrrhenian Sea margin of Basilicata - northern Calabria (southern Italy) have been carried out. In the study area, c. 25 km in length, an impressive flight of marine terraces occurs, with the highest terraces reaching ~160 m a.s.l. Detailed geomorphological-stratigraphical analyses on remnants of paleoshorelines located within 60 m a.s.l. have shown that the rocky coast of the investigated coastal stretch has been affected by multiple relative sea-level fluctuations, during which reworking of older shorelines has occurred. Dating of the coral Cladocora caespitosa and speleothems, either predating or postdating single paleoshorelines, has allowed the construction of a chronological framework for the identified relative sea-level markers, and their correlation with MIS 7, MIS 6e and distinct peaks of MIS 5. A mean uplift rate of c. 0.25 mm/y since the Last Interglacial has been quantified, one order of magnitude larger than previous estimates. The uplift rate value has been used to infer the elevations of MIS 5a, 5c and 6e sea level peaks, which are higher than those reported in most sea level curves worldwide, although consistent with several findings from the western Mediterranean. Our results demonstrate that a mere sequential correlation may be misleading in the interpretation of flights of marine terraces and indicates that multiple age controls are crucial to unravelling the complex interaction between uplift and sea-level fluctuations in uplifted coastal areas. The reconstructed MIS 5a, 5c and 6e sea level paleo-elevations, besides contributing to the assessment of late Quaternary sea-level fluctuations in the Mediterranean Sea, may contribute to constrain coeval ice sheets volume variations.
    Description: Published
    Description: 107978
    Description: 7SR AMBIENTE – Servizi e ricerca per la società
    Description: JCR Journal
    Keywords: Marine terraces ; morpho-stratigraphy ; Geochronological dating ; MIS 5 ; MIS 6e ; Tyrrhenian margin
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 62
    Publication Date: 2022-02-28
    Description: The behaviour of dry and wet volcanic granular flows is one of the main research topics in present day geophysics and volcanology. It involves various disciplines (e.g. sedimentology, geophysics, fluid dynamics) and investigation techniques (e.g. field studies, laboratory experiments, computational fluid dynamics). The vast interest is justified by the complex nature of these flows and their very dangerous nature that threaten millions of people around the world. In the last decade, computational fluid dynamics has become one of the main instruments used to reproduce past events of volcanic granular flows or to predict their behaviour and potential hazard. In this study, we tested two of the most used codes for simulating volcanic granular flows, TITAN2D and FLO2D, against well studied natural cases (the 1998 wet granular flows in the Sarno area and the 2005 block and ash flows at Colima volcano) and large-scale experiments on granular flows. Comparison between simulated parameters and real ones were carried out in order to evaluate strengths and weaknesses of the two numerical codes. TITAN2D results showed how the basal friction angle is fundamental to control numerical simulations and its dependence on the topographic complexities, DEM resolution and slope-angle ratio. Simulation of large scale experiments offered a good relationship between slope angle ratio at break in slope and basal friction angle, which is useful for application to small drainage basins with not complex channel morphology. FLO2D suffers the lack of rheometric parameters for volcaniclastic material, but is less sensitive of DEM resolution with respect to TITAN2D.
    Description: Published
    Description: 107146
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 63
    Publication Date: 2022-02-28
    Description: Glacial-interglacial variations in ice volume and sea level are essential components of the Pleistocene global climate evolution. Deciphering the timing of change of these key climate parameters with respect to the insolation forcing is central to understanding the processes controlling glacial terminations. Here we exploit the sensitivity of the Paleo Tiber River (central Italy) to sea-level forced changes in the base level and the frequent occurrence of datable tephra layers in its sedimentary successions to reconstruct the timing of the relative sea-level (RSL) change between 450 and 403 ka, i.e., across the glacial termination (T-V) that marks the transition between Marine Isotope Stage (MIS) 12 and MIS 11. The analysis hinges on new stratigraphic data, tephra geochemical fingerprinting, and 40Ar/39Ar dating from a fluvial section that represents the inland counterpart of the near mouth, coastal aggradational succes- sions of the San Paolo Formation (SPF). Tephra correlation indicates that the morpho-stratigraphic record of the inland section is as sensitive to the sea-level change as its coastal counterparts, which makes it ideal to complement previous RSL reconstructions from the Tiber River catchment basin, thereby providing a more detailed picture of the sea-level history across T-V. Combined sedimentological and morphological proxies of the composed inland-coastal SPF record document the occurrence of two phases of relatively rapid sea-level rise, here interpreted as meltwater pulse (MWP) events. The earlier MWP occurred between ~450 and ~445 ka and matches a relatively minor episode of the sea-level rise documented in an existing RSL record, while the younger MWP at ~430 ka corresponds to the high amplitude sea-level rise that marks T-V. We find that both MWPs coincide with episodes of ice-rafted debris deposition in the North Atlantic (Heinrich-like events) and with attendant Southern Hemi- sphere warming, plausibly associated with the bipolar seesaw.
    Description: Published
    Description: 106976
    Description: 5A. Ricerche polari e paleoclima
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 64
    facet.materialart.
    Unknown
    Elsevier
    Publication Date: 2022-02-10
    Description: The airborne magnetic method was established a few decades ago, as a strong tool in mining and petroleum exploration. Several economically relevant discoveries are often credited to aeromagnetism. Geological reconnaissance and mapping, deep crustal and upper mantle studies, environmental characterization, and national and international security issues can greatly benefit from the aeromagnetic method, as compared with other geophysical prospecting schemes. The rapid rate of coverage and the low cost per unit area explored represent just a few among the many advantages of the technique. Consequently, large-scale airborne magnetic surveys have been carried out in various parts of the globe. The amount of direct discoveries of ore bodies by means of aeromagnetism is impressive. Large magnetic iron deposits found in the early 1960s are in Southern California, Missouri, Nevada, Pennsylvania, Quebec, Ontario, and elsewhere. In the field of petroleum exploration, the method has also been used, although with less direct application. Depth to magnetic basement estimation in sedimentary basins narrows down areas of interest where to conduct exploration surveys in detail by means of more costly methods. The most relevant use of airborne magnetic results is crustal imaging and characterization. Nowadays, geology is interpreted in three dimensions using a digital aeromagnetic map.
    Description: Published
    Description: 675-688
    Description: 1T. Struttura della Terra
    Description: 4T. Sismicità dell'Italia
    Description: 6T. Studi di pericolosità sismica e da maremoto
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: 3A. Geofisica marina e osservazioni multiparametriche a fondo mare
    Description: 5A. Ricerche polari e paleoclima
    Description: 7A. Geofisica per il monitoraggio ambientale
    Description: 1TR. Georisorse
    Description: 2TR. Ricostruzione e modellazione della struttura crostale
    Description: 6SR VULCANI – Servizi e ricerca per la società
    Description: 7SR AMBIENTE – Servizi e ricerca per la società
    Keywords: aeromagnetism ; potential fields ; magnetic anomaly ; 04.02. Exploration geophysics ; 04.05. Geomagnetism ; 04.07. Tectonophysics ; 04.08. Volcanology ; 04.06. Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 65
    Publication Date: 2022-02-18
    Description: Unravelling the physical state and properties of mantle rocks is crucial for understanding both plate tectonics, seismic activity, and volcanism. In this context, the knowledge of accurate elastic parameters of constituent mineral phases, and their variations with pressure (P) and temperature (T), is an essential requirement, that coupled with the thermal state of the lithosphere can provide a better understanding of its petrophysics and thermochemical structure. In this paper, we present an assessment of the thermoelastic parameters [in the form of P–V–T–K Equations of State (EoS)] of orthopyroxene, clinopyroxene, spinel and garnet based on X-Ray diffraction data and direct elastic measurements available in literature. The newly developed EoS are appropriate to describe the elastic behaviour of these phases under the most relevant P–T conditions and bulk compositions of the Earth’s mantle. In combination with the published EoS for mantle olivine and magnesiochromite, these EoS are suitable to calculate the physical properties of mantle peridotites and their variation with P and T. Thanks to these EoS, we can evaluate how the variations in bulk composition and thermal regimes affect the density structure of the lithospheric mantle. Accordingly, the density structure of fertile and depleted peridotitic systems was calculated along the 35, 45 and 60 mWm􀀀 2 geothermal gradients at P comprised between 1 and 8 GPa. Under very cold geothermal gradients, the density of both fertile and depleted peridotitic systems progressively increases with depth, whereas under relatively hot conditions a first downwards decrease from 1 to ca 3 GPa is observed, followed by an increase downward. In mantle sections characterized by intermediate geotherms (45 mWm􀀀 2), the behaviour of the two systems differs up to ca 4 GPa, as the density of the depleted system remains nearly constant down to this depth whereas it moderately increases in the fertile system. The results of our simplified parameterisation, in agreement with classical thermodynamic modelling, indicate that the density structure of the lithospheric mantle is predominantly controlled by the P – T gradient variations, with some compositional control mostly arising at cold-intermediate thermal conditions. Integrated by geophysical and thermodynamic modelling, the newly developed and selected EoS could provide an alternative strategy to infer the elastic properties of mineral phases and peridotite rocks, under the most relevant P–T conditions and compositions of the Earth’s mantle, without requiring sets of end-member properties and solution models.
    Description: Published
    Description: 106483
    Description: 3T. Fisica dei terremoti e Sorgente Sismica
    Description: 4T. Sismicità dell'Italia
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 66
    Publication Date: 2022-02-18
    Description: Plutons in crustal shear zones may exploit inherited structures, interfere with strain localizing or be deformed passively. To constrain the relative timing of such tectono-magmatic relationships in natural settings is not always straight-forward. We here present sandbox-type analogue model experiments simulating magma emplacement into simple and transtensional crustal shear zones to test the diagnostic potential of pluton shape with respect to timing and setting. Observations based on surface deformation and intrusion shape exemplify the interplay between evolving and inherited tectonic structures and magma uprising. We observe markedly asymmetric intrusions in association with dikes reflecting the regional stresses, fault pattern and finite strain field. At the same time, the presence of an intrusion modifies the tectonic evolution, but only transiently, resulting in short-lived faults, reactivation and inversion. Diagnostic attributes include the pluton’s aspect ratio, its orientation and amplitude as well as dike association. Accordingly, syn-tectonic intrusions show the highest pluton amplitudes, but only intermediate elongation compared to other scenarios. They are oriented parallel to Riedel shears in simple shear, respectively to the compression direction in transtension. Post-tectonic intrusions are least elongated, have medium amplitudes and exploit Riedel shears. Pre-tectonic intrusions are characterized by lowest amplitudes but the highest aspect ratios and are parallel to the finite elongation direction. Intrusions in transtensional shear zones are generally of less elongate than those in simple shear zones. Experimental results are tested against observations from natural examples validating the diagnostic potential of pluton shape for the timing and the tectonic setting of the emplacement.
    Description: Published
    Description: 104417
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 67
    Publication Date: 2022-02-16
    Description: On September 6, 2017, the solar active region AR 2673 emitted two solar flares: the first at 08:57 UT (X2.2) and the second at 11:53 UT (X9.3); both were powerful enough to black-out high and low frequency radio waves (where UT is universal time). The X9.3 was the strongest solar flare event in the past decade. In this study, we took the advantage of these two extreme flare events to investigate corresponding effects on the ionosphere using multi-instrument observations from magnetometers, Global Positioning System – Total Electron content (GPS-TEC) receivers, ionosondes and Swarm satellites over a large geographical extent covering South American, African and European sectors. During the X2.2 flare, European and African sectors were sunlit and during X9.3 European, African, and South American sectors were sunlit and exposed to the solar flare radiation. During the X2.2 flare, there was an ionosonde blackout for a duration of about 45 min, while during the X9.3 flare this blackout lasted for 1 h and 30 min. The blackout are seen over a large global extent which demonstrates the severity of solar flare events in disrupting the radio communication. The horizontal component of Earth’s geomagnetic field has shown ripples and enhancements during these flare events. The ionospheric Vertical Total Electron Content (VTEC) showed a positive phase along with an intensification of the Equatorial Ionization Anomaly (EIA) over the South American and African sectors. The dynamical and physical processes associated with the TEC and EIA variabilities due to solar flare are discussed.
    Description: Published
    Description: 1775-1791
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: 2A. Fisica dell'alta atmosfera
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 68
    Publication Date: 2022-02-16
    Description: In seismic modelling, fault planes are normally assumed to be flat due to the lack of data which can constrain fault morphology. However, incorporating 3D fault morphology is important for modelling several phenomena, for example calculating mainshock induced stress changes. We utilize a data-analytical method to unveil the 3D rupture morphology of faults using unsupervised clustering techniques applied to earthquake hypocenters in seismic sequences. We apply this method to the 2009 L’Aquila seismic sequence which involved a MW 6.1 mainshock on April 6th. We use a dataset of about 50,000 relocated events, mostly microearthquakes, reaching magnitude of completeness equal to 0.7. Clustering distinguishes the earthquakes as occurring in three main clusters along with other minor fault segments. We then represent the morphology of the main Paganica fault system (responsible for the largest mainshock) using splines. This method shows promise as a step toward robustly and quickly obtaining 3D rupture morphologies where earthquake sequences have been monitored. The 3D model is presented interactively online, and the processing is presented in an interactive Jupyter Notebook (https://bit.ly/2MnCFdj).
    Description: Published
    Description: 228756
    Description: 3T. Fisica dei terremoti e Sorgente Sismica
    Description: JCR Journal
    Keywords: Fault morphology Clustering L’Aquila earthquake sequence ; Clustering ; L’Aquila earthquake sequence
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 69
    Publication Date: 2022-02-17
    Description: Free access at https://onlinelibrary.wiley.com/doi/10.1111/1755-6724.14824
    Description: Earthquake is a sudden release of energy due to fault motions. The severity of the damages can be minimized by development of a culture of prevention which includes the Seismic Hazard Assessment, microzonation studies and appropriate building codes. Earthquake risk assessment methods require seismo tectonic information usually organized in earthquake catalogues utilized in Probabilistic Seismic Hazard Assessment (PSHA) based on initial work by Cornell (1968), where probability distributions for magnitudes and source site distances reported in earthquake catalogues were utilized for the first time. In following years the method furtherly improved reporting an upper bound on the earthquake magnitude in each region avoiding the inclusion of unrealistically big earthquakes. A different approach has been followed in Countries characterized by significant incompletenesses in available earthquake catalogues. In these places the Deterministic Seismic Hazard Assessment (DSHA) methods have been often utilized. In particular the DSHA takes into account the maximum possible earthquake to evaluate the intensity of seismic ground motion distribution at a site by taking account the seismotectonic setup of the area. A deepening in the knowledge of seismotectonics and of morphostructural features of the studied area has been carried out in pattern recognition studies (Gelfand et al., 1976 and references therein). More updated applications named Neo-Deterministic Seismic Hazard Assessment (NDSHA) proposed by Wang et al. (2021) also consider morphostructural zoning which, in turn, considers nodes (fractured areas), lineaments and topographical features like the maximal elevation and the minimal elevation of the studied area. The steepness of topographic surfaces and sharp variations in morphostructural parameters indicate high tectonic activity. Some geological features are also presently utilized in PSHA methods in some Countries and considers basic parameters like the top and the bottom of seismogenic layers deduced by faults geometry within the frame of the Earthquake Rupture Forecasting (Bird and Liu, 2007).
    Description: Published
    Description: 31-33
    Description: 9T. Geochimica dei fluidi applicata allo studio e al monitoraggio di aree sismiche
    Description: JCR Journal
    Keywords: probabilistic seismic hazard assessment, deterministic seismic hazard assessment, helium isotopes, geochemical prospection, earthquake precursors ; seismic hazard estimation by geochemical methods
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 70
    Publication Date: 2022-02-22
    Description: The westernmost Mediterranean hosts part of the plate boundary between the European and African tectonic plates. Based on the scattered instrumental seismicity, this boundary has been traditionally interpreted as a wide zone of diffuse deformation. However, recent seismic images and seafloor mapping studies support that most of the plate convergence may be accommodated in a few tectonic structures, rather than in a broad region. Historical earthquakes with magnitudes Mw 〉 6 and historical tsunamis support that the low-to-moderate instrumental seismicity might also have led to underestimation of the seismogenic and tsunamigenic potential of the area. We evaluate the largest active faults of the westernmost Mediterranean: the reverse Alboran Ridge, and the strike-slip Carboneras, Yusuf and Al-Idrissi fault systems. For the first time, we use a dense grid of modern seismic data to characterize the entire dimensions of the main fault systems, accurately describe the geometry of these structures and estimate their seismic source parameters. Tsunami scenarios have been tested based on 3D-surfaces and seismic source parameters, using both uniform and heterogeneous slip distributions. The comparison of our results with previous studies, based on limited information on the fault geometry and kinematics, indicates that accurate fault geometries and heterogeneous slip distributions are needed to properly assess the seismic and tsunamigenic potential in this area. Based on fault scaling relations, the four fault systems have a large seismogenic potential, being able to generate earthquakes with Mw 〉 7. The reverse Alboran Ridge Fault System has the largest tsunamigenic potential, being able to generate a tsunami wave amplitude greater than 3 m in front of the coasts of Southern Spain and Northern Africa.
    Description: Published
    Description: 106749
    Description: 6T. Studi di pericolosità sismica e da maremoto
    Description: JCR Journal
    Keywords: Western Mediterranean ; Seismogenic potential ; Tsunamigenic potential ; Numerical modelling ; Active faults ; Active seismic data ; 04.04. Geology ; 04.07. Tectonophysics ; 04.06. Seismology ; 05.08. Risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 71
    Publication Date: 2022-02-21
    Description: Relative sea‐level (RSL) evolution during Marine Isotopic Stage (MIS) 5 in the Mediterranean basin is still not fully understood despite a plethora of morphological, stratigraphic and geochronological studies carried out on highstand deposits of this area. In this review we assembled a database of 323 U/Th‐dated samples (e.g. corals, molluscs, speleothems) which were used to chronologically constrain RSL evolution within MIS 5. The application of strict geochemical criteria to the U/Th samples indicates that only ~33% of data available for the Mediterranean Sea can be considered ‘reliable’. Most of these data (~65%) refer to the MIS 5e highstand, while only ~17% could be related to the MIS 5a. No attribution to MIS 5c can be unequivocally supported. Nevertheless, the resulting framework does not allow us to define a satisfactory RSL trend during the MIS 5e highstand and subsequent MIS 5 substages. Overall, the proposed selection of reliable/unreliable data would be useful for detecting areas where MIS 5 substage attributions are not supported by confident U/Th chronological data and thus the related reconstructions need to be revised. In this regard, the resulting framework calls for a reappraisal and re‐examination of the Mediterranean records with advanced geochronological methodologies.
    Description: Published
    Description: 1174-1189
    Description: 5A. Ricerche polari e paleoclima
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 72
    Publication Date: 2022-02-21
    Description: This work presents hydrochemical results for groundwater and dissolved gas samples collected from a thermal and cold aquifer in the Juchipila Basin, in southern Sierra Madre Occidental, central Mexico. Thermal springs in the Juchipila Basin reach temperatures of 60 ◦C, these manifestations are not related to recent or active volcanism as are all the known geothermal fields in Mexico. The thermal waters (〉32 ◦C) are Na-HCO3 and Na-SO4 type, with an anomalous concentration of F, B, Li, and As. Their chemistry likely results from water-rock interaction processes. The cold waters (〈32 ◦C) have a Ca-HCO3 composition typical of recent infiltration and shallow flow, but they have an anomalous concentration of NO3. The δ2H and δ18O indicate a common meteoric source for the warm and cold water plotting along an evaporation line. The waters have higher CO2 and He concentrations than the air-saturated water. The helium composition is mainly atmospheric and terrigenous with a mantle helium contribution of up to 14%. This suggests that faults affecting the region are deeply rooted, permitting mantle helium uprise. Geothermometry gives mean reservoir temperatures of 58–102 ◦C. Based on these results, we propose a model of hydrothermal circulation in the Juchipila Basin, in which rainwater infiltrates deeply through the graben edges fault system, dissolves ions and crustal helium, incorporates mantle helium, while heated by the geothermal gradient, and eventually surges and mixes with the cold, shallow aquifer along faults cutting the whole succession within the graben.
    Description: Published
    Description: 102076
    Description: 1TR. Georisorse
    Description: JCR Journal
    Keywords: Hydrogeochemical processes ; Helium isotopes ; Water stable isotopes ; Unconventional geothermal system ; Mexico
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 73
    Publication Date: 2022-02-21
    Description: Unmanned aerial systems (UAS, aka drones) are being used to map macro-litter on the environment. Sixteen qualified researchers (operators), with different expertise and nationalities, were invited to identify, mark and categorize the litter items (manual image screening, MS) on three UAS images collected at two beaches. The coefficient of concordance (W) among operators varied between 0.5 and 0.7, depending on the litter parameter (type, material and colour) considered. Highest agreement was obtained for the type of items marked on the highest resolution image, among experts in litter surveys (W = 0.86), and within territorial subgroups (W = 0.85). Therefore, for a detailed categorization of litter on the environment, the MS should be performed by experienced and local operators, familiar with the most common type of litter present in the target area. This work provides insights for future operational improvements and optimizations of UAS-based images analysis to survey environmental pollution.
    Description: Published
    Description: 112542
    Description: 5A. Ricerche polari e paleoclima
    Description: JCR Journal
    Keywords: Coastal pollution; Plastics; Remote sensing; Unmanned aerial vehicle (UAV); Waste management
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 74
    Publication Date: 2022-02-24
    Description: We investigated the late Quaternary throw distribution of the main normal fault that ruptured during the Mw 6.5 2016 earthquake in central Italy by means of a high-resolution structure-from-motion (SfM)-derived Digital Surface Model (DSM). We focused on a key area along the Cordone del Vettore fault (CDV), which is part of the Vettore-Bove fault system (VBFS). The CDV displays a prominent compound post-glacial scarp that allowed the reconstruction of the along-strike cumulative throw distribution. We propose a geometric approach to calculate the CDV fault throw distribution from the reconstruction of a displaced glaciation-related erosional surface, used as a geomorphic marker, and a series of closely spaced cross profiles. The proposed calculation accounts for both the slip vector direction and the degraded scarp top, including field data on fault dip angles. Following this approach, we recognized two scarps with a minimum average fault throw of ~21 m and ~35 m for this section of the investigated fault strand. The correlation with the possible post-LGM (Last Glacial Maximum) deglaciation phases of the erosional surface suggests a minimum scarp age of 25–27 ka cal BP. Such an age provides a reasonable CDV fault throw rate of ~0.8 mm/a, comparable with known long-term throw rates of the VBFS and active Apennines normal faults. By comparing the reconstructed long-term Cordone del Vettore throw distribution with the 2016 coseismic one, ~24 2016-like surface faulting events are required to generate the main cumulative scarp, under the assumption of constant slip per event. This, along with the age of the scarp, yields an average earthquake recurrence time interval of ~1100 a. These results suggest the presence of multiple regional markers that correlates with different LGM (if not pre-LGM) major glacial phases, whose erosional processes allow the preservation of pre-existing bedrock fault scarp remnants.
    Description: Published
    Description: 107784
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: earthquake ; surface rupture ; active tectonics ; geomorphology ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 75
    Publication Date: 2022-02-24
    Description: Dissolution of clinopyroxene (cpx) in a K-basaltic melt from the Campi Flegrei Volcanic District (Italy) has been investigated through dissolution and dissolution-crystallization experiments at pressure of 0.8 GPa, superliquidus temperature of 1350 ◦C, and dwell times between 0.5 and 1 h. The obtained dissolution rates range from 7.9⋅10− 6 cm s− 1 to 6.1⋅10− 6 cm s− 1 as a function of dwell time. In the dissolution-crystallization experiment (1300 ◦C; 0.8 GPa; 2 h), the formation of overgrowth rims accompanied by new cpx crystals suggests that the injection of recharge magmas in basaltic reservoir may lead to inverse or oscillatory zonation. The interaction between cpx and K-basaltic melt at ~1570 ◦C was studied by in situ radiography using synchrotron radiation combined with the Paris-Edinburgh press. This resulted in cpx resorption to occur depending on the temperature conditions with respect to the liquidus temperature of the cpx (TcpxL). The calculated cpx dissolution rates are ~5⋅10− 3 cm s− 1 at T ≤ TcpxL and ~ 3⋅10− 2 cm s− 1 at T ≥ TcpxL. The role of crystal dissolution in the estimation of magma residence times has been also tested for a natural magmatic system by interpolating the dissolution rates (~10− 5–10− 6 cm s− 1) with the textural data of cpx phenocrysts from the Agnano-Monte Spina pyroclastic deposit at Campi Flegrei caldera (Campanian region, Italy). Results from calculations indicate that the time required for partial or complete resorption of phenocrysts varies from ~0.5 to ~40 h, and that the effect of crystal dissolution may be relevant to estimate magma residence times whether signifcant dissolution occurs during magma mixing processes.
    Description: Published
    Description: 120533
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 76
    Publication Date: 2022-02-25
    Description: During the 2016–2017 Central Italy earthquake sequence, a series of moderate to large earthquakes M 〉 5 occurred near the Amatrice and Norcia towns. These events are recorded on a dense seismic network, providing relevant observational evidence of complex earthquakes in time and space. In this work, we used this substantial data set to study the ground-motion characteristics of the Norcia earthquake M6.5 on October 30, 2016, through a broadband ground-motion simulation. Three-component broadband seismograms are generated to cover the entire frequency band of engineering interest. Low and high frequencies are computed considering the heterogeneous slip rupture model of Scognamiglio et al. (2018) [1]. High frequencies are calculated using a stochastic approach including P, SV, and SH waves, while low frequencies are obtained through a forward simulation of the kinematic model at the various stations. To predict earthquake-induced ground motions in the area, we adopted region-specific attenuation and source scaling parameters derived by Malagnini et al. (2011) [2]. Ground-motion parameters, including peak ground acceleration (PGA), peak ground velocity (PGV) and spectral amplitudes, are calculated at the selected sites adopting physics-based parameters to understand better the earthquake fault rupture, the wave propagation, and their impacts on the seismic hazard assessment in the region. We showed that combining the fault rupture history over the entire frequency spectrum of engineering interest, the attenuation characteristics of the seismic wave propagation, and the properly defined site responses can improve the prediction of ground motions and time histories, especially in near seismic sources.
    Description: Published
    Description: 106866
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: JCR Journal
    Keywords: Ground-motion simulation ; Hybrid Method ; 30 October 2016 Norcia earthquake ; Site effects ; 04.06. Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 77
    Publication Date: 2022-02-25
    Description: Gypsum plasterboards are nowadays very appreciated in buildings, mainly due to their lightness, thermal insulation and suitable sound transmission loss when used in double walls. However thermal and acoustic features of gypsum plasterboard can be enhanced. In the present study an innovative method, consisting in the direct addition of a pre-manufactured foam to gypsum pastes is used to increase the gypsum porosity improving sound absorption, lightness and thermal insulation features. In this aim, the role of both different amounts and dilutions of a vegetal foaming agent on the main physical, mechanical and microstructural characteristics of the gypsum was experimentally investigated. Moreover, also X-ray computed micro tomography technique (Micro- CT) was carried out in order to investigate the 3D internal microstructure of the materials. The results confirmed the effectiveness of the foaming agent in increasing the gypsum porosity, with a linear correlation between densities and mechanical strengths. Moreover, the presence of large bubbles, mainly connected each other, involved in a strong reduction of the thermal coefficient (λ), from 0.57 W/m∙K of REF sample to 0.25 W/m∙K of LG10_5% sample, and in a strong increase of the normal sound absorption coefficient (α0), from 0.06 of REF sample to 0.20 of LG10_5% sample. Finally, in the light of the results obtained by the present research, the use of a pre-whipped vegetal foaming agent represents a suitable way to obtain lightweight gypsum-based materials with enhanced thermal and acoustic properties.
    Description: Published
    Description: 124948
    Description: 7A. Geofisica per il monitoraggio ambientale
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 78
    Publication Date: 2022-02-25
    Description: The coastal vulnerability along the Mediterranean coasts is increasing, especially in response to the occurrence of tropical-like cyclones, known as Medicanes, which have become more intense than in the past. A peculiar case was the impact of Medicane Zorbas in September 2018 along the coasts of south-eastern Sicily, where it caused inland flooding and damages to the socio-economic activities. Here, Zorbas effects are reconstructed through post-event geomorphological surveys, interviews with direct witness and analyses of video recorded by surveillance systems or found in social media. These data allowed us to assess the flooding extent on seven coastal sectors located between Thapsos Peninsula and Marzamemi. Flooding caused by Zorbas appears to be greater than those produced by the main seasonal storms affecting the areas from 2015 to 2019; nevertheless, it is comparable with the flooding generated by Medicane Qendresa that impacted south-eastern Sicily in 2014. Wave propagation and extreme water level modelling, performed for the main storm events that occurred in the area since 2005, and analyses of data recorded by tide gauges of Catania, Porto Palo di Capo Passero and Malta since 2008, showed that Medicanes generate greater flooding than seasonal storms because they can induce higher and longer surge along the coastline. Collected data indicated that the surge generated by Zorbas reached a maximum value between about 0.8 m and 1.2 m above mean sea level (msl) along the coast of south-eastern Sicily. Results highlighted the need to better evaluate the coastal hazard related to the propagation of Medicanes, especially in the context of future climate change when these events will probably be characterized by longer duration and greater intensity than at the present.
    Description: Published
    Description: 106556
    Description: 4A. Oceanografia e clima
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 79
    Publication Date: 2022-02-25
    Description: In the last decades, investigating geochemistry of sea sediments has been challenging in the eastern sector of Pozzuoli Bay, source of the metal(loid)s has been a matter of debate and the proposed origin of potentially toxic elements (PTEs) has been occasionally inconsistent. In this study, compositional data analysis (CoDA) was used because the results are independent of the measurement unit, the selected subgroup of elements and the order of chemicals in the dataset. The robust variant of principal component analysis (PCA) indicated that Hg, Cd, Cu, Pb and Zn were positively correlated with mud and organic matter in the sediments deposited in front of the former industrial site. Concentrations of these metals decrease along the cores and in the distal zone. Nevertheless, Al, As, V, Fe, Cr, Ni and sand form an association along the coast which strengthens with increasing distance from fumaroles in the proximal zone. It suggests that arsenic was mainly originated from the pyroclastic deposits of Campi Flegrei and some of the seepages with hydrothermal component, supported by low contribution of the variables in robust PCA of the sediments from distal zone. Therefore, this pioneering article suggests CoDA as a powerful tool for answering the long-lasting questions over sediment geochemistry in polluted areas.
    Description: Published
    Description: 129955
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Bagnoli industrial site; Campi Flegrei; Fractal analysis; Isometric log-ratio; Robust principal component analysis; Symmetric coordinate
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 80
    Publication Date: 2022-02-25
    Description: In our original paper (Buono et al., 2020), we investigated the dynamics of degassing (e.g., bubble nucleation and growth, degassing styles and regimes) of H2O-, CO2- and H2O-CO2-rich evolved alkaline melts over a wide range of variables (final pressures, decompression rates, volatile compositions and contents, temperatures) through a comprehensive review of previous and new HP (high pressure)-HT (high temperature) decompression experiments. The criticism of Allabar and Nowak regards a restricted part of our results, i.e., those concerning homogeneous bubble nucleation from our new experiments on H2O-rich melts. Their aim is refusing the classical nucleation theory (CNT), widely accepted in literature to explain homogeneous bubble nucleation in magmas, for evolved alkaline melts in favour of the spinodal decomposition. We found that the Authors of the Comment do not provide any new evidence in support of their thesis, but they keep only arbitrary and erroneous conjectures of our new experimental data. As we stated in our original paper, the evaluation of the specific bubble nucleation mechanism (CNT vs. spinodal decomposition) is beyond the scope of our research, as appropriate studies on both experimental and natural products would be necessary to shed light on this complex issue.
    Description: Published
    Description: 103654
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 81
    Publication Date: 2022-02-25
    Description: Bagnoli Coroglio is an urban district of the City of Naples (South Italy), which fronts the Tyrrhenian Sea for nearly 3 km. It is part of the Campi Flegrei caldera, one of the most explosive volcanic areas in Europe. The need for redeveloping the site after the intense industrial activities of the twentieth century has prompted a remarkable research effort to investigate the pollution's degree, nature, and extent at both the land and seafloor. This article focuses on releasing thermal waters from a natural channel as a source of arsenic contamination in the Bagnoli marine sediments; the thermal waters originate from the nearby Agnano hot-springs and have been conveying artificially to the track since the mid-XIX century. As a first part of the outcomes, the work describes the flow regime that characterizes the marine area. The analysis has been conducted via numerical simulations carried out with the software package Delft3D, developed by Deltares, which employs dynamically interfacing modules to account for wave propagation, generation of currents, and presence of coastal structures. Climatic inputs to the software (waves, winds, and tide) have specifically been gathered and analyzed within this research. The numerical study has permitted to furnish, for the first time, a clear and systematic view of the hydrodynamic forcings that characterize the area under investigation. In particular, a leading role in the transport of pollutants could be played by rip current systems, whose characteristics vary with climate intensity (waves and wind) and coastal structures characteristics. Due to its inherently dynamic nature, the proposed approach seems especially desirable in situations where different contamination sources are compared. As such, it could be successfully applied to other sites also.
    Description: Published
    Description: 146811
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Anthropogenic contamination sources; Marine circulation; Numerical modeling; Pollutants advection; Rip currents; Seabed contamination by arsenic
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 82
    Publication Date: 2022-02-25
    Description: The Apennines are a retreating collisional belt where the foreland basin system, across large domains, is floored by a subaerial forebulge unconformity developed due to forebulge uplift and erosion. This unconformity is overlain by a diachronous sequence of three lithostratigraphic units made of (a) shallow-water carbonates, (b) hemipelagic marls and shales and (c) siliciclastic turbidites. Typically, the latter two have been interpreted regionally as the onset of syn-orogenic deposition in the foredeep depozone, whereas little attention has been given to the underlying unit. Accordingly, the rate of migration of the central-southern Apennine fold-thrust beltforeland basin system has been constrained, so far, exclusively considering the age of the hemipelagites and turbidites, which largely post-date the onset of foredeep depozone. In this work, we provide new high-resolution ages obtained by strontium isotope stratigraphy applied to calcitic bivalve shells sampled at the base of the first syn-orogenic deposits overlying the Eocene-Cretaceous pre-orogenic substratum. Integration of our results with published data indicates progressive rejuvenation of the strata sealing the forebulge unconformity towards the outer portions of the foldthrust belt. In particular, the age of the forebulge unconformity linearly scales with the pre-orogenic position of the analysed sites, pointing to an overall constant migration velocity of the forebulge wave in the last 25 Myr.
    Description: Published
    Description: 2817-2836
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: central-southern Apennines (Italy) ; fold-thrust belt ; forebulge ; foredeep
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 83
    Publication Date: 2022-02-25
    Description: We investigated the calcareous nannofossil biostratigraphy and magnetostratigraphy of middle Eocene – lower Oligocene sediments from ODP Hole 709 C, equatorial Indian Ocean. The new bio-magnetostratigraphic analyses have resulted in an accurate biochronology of the interval span- ning Chrons C20r (middle Eocene) to C12r, in which 29 bioevents were investigated, in a 12 myr interval. The magnetostratigraphic signal is less clear across the Eocene-Oligocene transition (EOT) but becomes more reliable at the top of Chron C13n to Chron C12r (early Oligocene). Quantitative analyses of calcareous nannofossil as- semblages allowed recognition of the Middle Eocene Climatic Optimum (MECO) and the long cooling trend leading to the glacial state starting in the early Oligocene. We identify two hiatuses, in the lower middle Eocene and across the Eocene-Oligocene Transition (EOT). Across the latter unconformity, a major transition from oligotrophic to eutrophic favoring nannofossil taxa highlights the enhanced sea surface nutrient availability during the transition to the early Oligocene glacial system. Finally, a late Oligocene warming event is recorded at this site by the increase in calcareous nannofossil taxa that preferred warm water.
    Description: Published
    Description: 102051
    Description: 5A. Ricerche polari e paleoclima
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 84
    Publication Date: 2022-01-07
    Description: Palaeoenvironmental reconstructions with temporal coverages extending beyond Marine Isotope Stage (MIS) three are scarce within the data sparse region of Chukotka, Far East Russia. The objective of this paper is to infer palaeoenvironmental variability from a 10.76 m long, OSL- and 14C- dated sediment core from Lake Ilirney, Chukotka (67°21′N, 168°19′E). We analysed high-resolution sediment-geochemistry (XRF), sedimentology (TC, TN, TOC, grain-size), mineralogy (XRD) and preliminary micropalaeontological data (diatoms and pollen) from the core as well as acoustic sub-bottom profiling data from the lake basin. Our results affirm the application of XRF-based sediment-geochemical proxies as effective tracers of palaeoenvironmental variability within arctic lake systems. Our study reveals that a lake formed during MIS3 from 51.8 (±4.1) ka BP, following extensive MIS4 glaciation. Catchment palaeoenvironmental conditions during this time remained harsh associated with the continued presence of a catchment glacier until 36.2 (±2.6) ka BP. Partial amelioration reflected by increased diatom, catchment vegetation and lake organic productivity and clastic sediment input from mixed sources from 36.2 (±2.6) ka BP resulted in a lake high-stand ∼15 m above present and is interpreted as evidence of a more productive palaeoenvironment coincident with the MIS3 interstadial optimum. A transitional period of deteriorating palaeoenvironmental conditions occurred ∼30–27.9 ka BP and was superseded by periglacial-glacial conditions from 27.9 (±0.8) ka BP, during the last glacial maximum. Deglaciation as marked by sediment-geochemical proxies commenced at 20.2 (±0.8) ka BP. Our findings are compared with lacustrine, Yedoma and river-bluff records from across Beringia and potentially yield limited support for a marked Younger Dryas cooling in the study area.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 85
    Publication Date: 2022-02-11
    Description: This investigation presents for the first time the seasonal and solar cycle variations of the daytime F-layer multiple stratifications (F3 and F4 layers) near the southern crest of the EIA in two different longitudinal sectors of South America. To perform the study, the ionograms recorded from 2007 to 2015 at Sao Jose dos Campos (23.2° S, 45.9° W), Brazil (eastern sector), and at Tucuman (26.9° S, 65.4° W), Argentina (western sector), are considered. Both sites present a frequency of occurrence of the F3 and F4 layers which is directly proportional to the solar activity, and an annual variation with a maximum in spring/summer and a minimum in autumn/winter. The main result that came out from the analysis is that the frequency of occurrence of the F3 and F4 layers is higher in the western sector than in the eastern sector, and this could be attributed to a different gravity waves activity characterizing the two longitudinal sectors.
    Description: Published
    Description: 59-70
    Description: 2A. Fisica dell'alta atmosfera
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 86
    Publication Date: 2022-02-07
    Description: We address the potential for methane to exist in the subsurface of Mars, focusing on its generation, accumulation in sealed traps, and seepage to the atmosphere. We discuss two abiotic processes that could have produced subsurface methane, even if life never developed on the planet. Compared to Earth, accumulations of methane on Mars are likely to be limited, and those that are present may be better sealed by the thick and planetwide cryosphere. Releases are thus expected to be minor and episodic. We emphasize the importance of long-term, continuous monitoring of predicted release sites, as limited, episodic releases could be easy to miss. Moreover, we note that numerous scenarios of methane fluxes from terrestrial analogs may explain non-detections by the ExoMars Trace Gas Orbiter (TGO), as they can produce atmospheric concentrations below the TGO limit of detection. Our work does not negate the potential for meteoric/cometary sources of methane, but it does illustrate the strength of the case for subsurface sourcing. Finally, we provide a map of potential locations of release and discuss remaining uncertainties and a path forward.
    Description: Published
    Description: 149-174
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 87
    Publication Date: 2022-02-14
    Description: East Java is characterised by a complex interaction of volcanic and tectonic processes and it is marked by isolated eruptive centres scattered across the back-arc sedimentary basins. In 2006 a large sediment hosted geothermal system named Lusi, pierced the Kendeng basin in East Java and since then it continues in a relentless eruption of mud breccia. To investigate the spatial and structural relationships between the volcanic arc and the back-arc domains, we perform a local earthquake tomography. The inversion of regional earthquakes recorded by our seismic network (for about two years) shows sharp Vp and Vp/Vs transitions. We observe a marked reduction of P-wave velocities and a high Vp/Vs ratio in the back-arc basins. Our study highlights a clear connection between the plumbing system of the volcanic arc and the northern sedimentary province. We propose a conceptual model suggesting that magmas and hydrothermal fluids may migrate from the middle to the upper crust into the sedimentary basins capitalising on existing thrust faults. Such low angle faults, promoted by the compressional regime of the region, link the magmatic domain to the northern sedimentary provinces. This process may represent the early phase of volcanic arc migration when magma-derived fluids are focused into fractured and permeable geological structures. Our conceptual model would not only help to understand the occurrence of the abundant mantle-derived fluids sampled across the back-arc, but it is also consistent with the occurrence of isolated magmatic and hybrid systems piercing across sedimentary environments in the back-arc of Java.
    Description: Published
    Description: 117258
    Description: 1T. Struttura della Terra
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 88
    Publication Date: 2022-02-14
    Description: Archaeological sites are extremely vulnerable to the impacts of weather-related events, which may lead to irreparable damages to cultural heritage. Here an assessment of the debris-flow hazard for the UNESCO site of Roman Villa del Casale (Italy) is carried out, through a combination of historical analyses, field surveys, geomorphological and hydrological investigations and two-dimensional hydraulic numerical modelling, all performed at river catchment scale. Historical analyses reveal that the site has been hit by several landslides in the far and recent past. This is presently confirmed by the high level of exposure to the impact of rain-triggered debris-flow events, due to the position of the Villa at a closure section of the related river basin and to the hydro- geomorphological characteristics of the basin itself. By applying the proposed approach, a scenario analysis is carried out. Results allow one to highlight the dynamics of the impact of debris flows, thanks to space and time- dependent maps about deposition areas, water depth and speed values, and to identify the most vulnerable archaeological elements within the study site. The numerical simulations are also used to test the efficiency of the existing hydraulic defense systems and to support the implementation of an early warning system for the site protection. Here, we also synthetize the design of the architecture of the wireless monitoring network, the sensor technology adopted to develop an effective real time environmental monitoring system and management plat-form, to construct a Wireless Sensor Network (WSN) - early warning and reporting system, which can be applied as a prevention measure.
    Description: Published
    Description: 102509
    Description: 7A. Geofisica per il monitoraggio ambientale
    Description: JCR Journal
    Keywords: Hydraulic risk, Archaeological excavation, Cultural heritage, WSN Monitoring, EWS Scenario analysis ; 03.02. Hydrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 89
    Publication Date: 2022-02-14
    Description: Como historic centre, located at the SW branch of Lake Como (northern Italy), is prone to subside because of a thick sequence of late Pleistocene to Holocene glacio-lacustrine, palustrine and alluvial sediments in the subsoil. After the 1950s, the combination of natural causes and anthropogenic activities amplified subsidence-induced differential settlements at building foundation depths, resulting in damage on the superstructures. This work presents the first subsidence vulnerability analysis of the historic buildings in Como city centre by combining hydrogeological and stratigraphic features, in situ damage investigations, and remote sensing Synthetic Aperture Radar (SAR) data acquired by Cosmo-SkyMed mission. First, the relationships between local hydrogeological features and vertical displacements retrieved by SAR Interferometry (InSAR) analysis were qualitatively assessed. This highlighted that cumulative vertical InSAR-derived settlements have a stronger linear correlation with the groundwater level rather than the thickness of compressible soil units at the city scale. The largest vertical displacements are located in the NW sector of the city centre and along the shore of Lake Como, where they remark the pre-Roman shoreline. Then, the cause-effect relationships between building damage severity and Subsidence-Related Intensity (SRI) parameters were investigated using a probabilistic approach based on empirical fragility curves. To this aim, two InSAR-derived SRI parameters were tested for both masonry and reinforced concrete buildings: differential settlements and relative rotations. The former resulted to relate better to distinct damage levels in Como historic centre. The analyses performed can contribute to the management of the inestimable architectural and cultural heritage of Como historic centre.
    Description: Published
    Description: 102115
    Description: 5IT. Osservazioni satellitari
    Description: JCR Journal
    Keywords: Subsidence of Como urban area
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 90
    Publication Date: 2022-02-14
    Description: Microplastic presence in benthic marine systems is a widely discussed topic. The influence of the natural matrix on microplastic distribution within the sedimentary matrix is often overlooked. Marine sediments from the western inner Oslofjord, Norway, were investigated for temporal trends, with a particular focus on the relationship between sediment grain-sizes and microplastic distribution. Density separation, optical microscopy and chemical validation were used to categorize microplastics. Microplastic concentrations ranged from 0.02 to 1.71 MPs g − 1 dry weight (dw). Fibres were the most common (76%), followed by fragments and films (18%, 6%). Common polymers were polyesters (50%), polypropylene (18%), polymethylmethacrylate (9%), rayon and viscose (5%) and elastane (4%). Microplastics appear to accumulate preferentially according to their morphology and polymer type in certain sediment grain-sizes. Microplastics inputs to the Oslofjord appear to derive from a wastewater treatment plant in the vicinity. Although, the redistribution of microplastics within the fjord needs further investigation.
    Description: This project was supported by the Norwegian Institute for Water Research (NIVA) and the Erasmus+ Programme (EU).
    Description: Published
    Description: 113076
    Description: 7SR AMBIENTE – Servizi e ricerca per la società
    Description: JCR Journal
    Keywords: Accumulation ; Plastic pollution ; Canonical correspondence analysis (CCA) ; Wastewater treatment plant (WWTP) ; Sediment core ; FT-IR ; Microplastics ; Marine sediments
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 91
    Publication Date: 2022-02-14
    Description: Magnetic skyrmions are emerging as key elements of unconventional operations having unique properties such as small size and low current manipulation. In particular, it is possible to design skyrmion-based neurons and synapses for neuromorphic computing in devices where skyrmions move along the current direction (zero skyrmion Hall angle). Here, we show that, for a given graph, skyrmions can be used in optimization problems facing the calculation of the shortest path. Our tests show a solution with the same path length as computed with Algorithm. In addition, we also discuss how skyrmions act as positive feedback on this type of problem giving rise to a self-reinforcement of the path which is a possible solution.
    Description: Published
    Description: 167977
    Description: 7A. Geofisica per il monitoraggio ambientale
    Description: 7SR AMBIENTE – Servizi e ricerca per la società
    Description: JCR Journal
    Keywords: Physics - Mesoscopic Systems and Quantum Hall Effect; Physics - Mesoscopic Systems and Quantum Hall Effect
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 92
    Publication Date: 2022-02-11
    Description: In this study we present a procedure for the topographic classification of Italy, taking advantage of existing high resolution digital elevation models (DEM), with the support of routines embedded in Geographic Information Systems. The proposed method is based on morphometric analyses of a DEM, allowing for hilltop ridge detection, slope computation, identification of reliefs with potential topographic site effects, and topographic classification according to the indications of the current European and Italian seismic codes. The developed procedure can be applied worldwide and has a potential engineering interest for a fast and accurate topographic classification of a site, for both scientific and application purposes. The topographic classification of Italy is tested on several well known cases of topographic amplification and it is adopted for the topographic classification of Italian accelerometric stations.
    Description: The study has partially benefited from funding provided by the Italian Presidenza del Consiglio dei Ministri–Dipartimento della Protezione Civile (DPC)—Agreement B2, DPC-INGV. This paper does not necessarily represent DPC official opinions and policies.
    Description: Published
    Description: 106848
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: JCR Journal
    Keywords: DEM ; Topographic classification ; EC8 ; NTC18 ; GIS ; Morphometric analyses
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 93
    Publication Date: 2022-02-11
    Description: Fluids supplied by stored magma at depth are causal factors of volcanic unrest, as they can cause pressurization/ heating of hydrothermal systems. However, evidence for links between hydrothermal pressurization, CO2 emission and volcano seismicity have remained elusive. Here, we use recent (2010−2020) observations at Campi Flegrei caldera (CFc) to show hydrothermal pressure, gas emission and seismicity at CFc share common source areas and well-matching temporal evolutions. We interpret the recent escalation in seismicity and surface gas emissions as caused by pressure-temperature increase at the top of a vertically elongated (0.3–2 km deep) gas front. Using mass (steam) balance considerations,we showhydrothermal pressurization is causing energy transfer from the fluids to the host rocks, ultimately triggering low magnitude earthquakes within a seismogenetic volume containing the hydrothermal system. This mechanism is probably common to other worldwide calderas in similar hydrothermal activity state.
    Description: MIUR project n. PRIN2017-2017LMNLAW“Connect4Carbon”
    Description: Published
    Description: 107245
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: CO2 emission ; Campi Flegrei ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 94
    Publication Date: 2022-02-03
    Description: This work presents the first 3D geological model of the Rome coastal area that integrates available subsurface geological, stratigraphic and geophysical data with surface geochemical data obtained both from the literature and new surveys. The model provides new insights into the stratigraphic and tectonic setting of the area and the geological factors controlling both natural and human-induced gas emissions. This sector of the Italian Tyrrhenian margin has been historically affected by natural emissions of deep CO2 and thermogenic CH4, stored in permeable layers but with local migration to the surface along buried normal faults. In addition to natural processes, human activities can also cause leakage and serious health risks, such as the abrupt gas release in August 2013, that was triggered by borehole drillings near the Rome international airport. The presented 3D reconstruction unveils the link between faults, stratigraphy, lithology and the distribution of the soil gas anomalies. It provides information about the depth of the reservoir that can potentially trap endogenous gases, and the location and geometry of the main faults along which the gas migrates towards the surface. Furthermore, reconstruction of the distribution and thickness of important clay layers better constrains the low permeable areas that prevent gas escape. The 3D model, coupled with the geochemical information, can serve as a useful tool for the local administration to perform land-use planning and manage the local geological and degassing hazards that affect this highly urbanized area near Rome. Furthermore, we estimate that the large amount of CO2 broadly released in the area also provides a contribution to the budget of natural greenhouse gases in the atmosphere.
    Description: Published
    Description: 106527
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: 3D geological model ; Soil gas ; Active faults ; Surface degassing ; Geological hazards ; Tiber delta ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 95
    Publication Date: 2022-02-02
    Description: Ion temperature data recorded by Millstone Hill incoherent scatter radar (42.61 N, 288.51 E) over four full solar cycles (from 1970 to 2018) are analyzed to depict its climatological behavior in the range of altitudes between 100 and 550 km. The ion temperature dependencies on altitude, local time, month of the year, and solar activity level are studied through a climatological analysis based on binning and boxplot representation of statistical values. Binned observations of ion temperature are compared with International Reference Ionosphere (IRI) modeled values (IRI-2016 version). This comparison reveals several shortcomings in the IRI modeling of the ion temperature at ionosphere altitudes, in particular for the altitudinal, diurnal, seasonal, and solar activity description. The main finding of this study is that the overall IRI overestimation of the ion temperature can be probably ascribed to the long-term ionosphere cooling. Moreover, the study suggests that the IRI ion temperature model needs to implement the seasonal and solar activity dependence, and introduce a more refined diurnal description to allow multiple diurnal maxima seen in observations. The IRI ion temperature anchor point at 430 km is investigated in more detail to show how also a better description of the altitude dependence is desirable for modeling purposes. Some hints and clues are finally given to improve the IRI ion temperature model.
    Description: Published
    Description: 2186-2203
    Description: 2A. Fisica dell'alta atmosfera
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 96
    Publication Date: 2022-02-02
    Description: TITIPy (Topside Ionosphere Turbulence Indices with Python) is a stand-alone Python tool developed for the calculation and mapping of RODI, ROTI, and ROTEI indices, for the characterization of the turbulent state of the topside ionosphere. Data gathered by Langmuir Probes and Precise Orbit Determination antennas on-board ESA Swarm satellites constellation are used to calculate topside ionosphere indices with a high time rate and a global coverage. From the study of these topside indices, information on physical mechanisms involved in the formation of small-scale irregularities (both spatial and temporal) can be drawn, particularly at high and low latitudes. TITIPy provides outputs as time series of calculated indices in text files, and figures as maps in geographic and magnetic coordinates. TITIPy is particularly suited for the investigation of the topside ionosphere irregularities, and for the identification of peculiar spatial and temporal patterns. The paper describes the TITIPy design and code workflow along with a detailed explanation of RODI, ROTI, and ROTEI indices calculation. Furthermore, an example of application based on data collected during the St. Patrick 2015 geomagnetic storm is also shown. TITIPy is open-source and freely downloadable at https://github.com/pignalberi/TITIPy.
    Description: Published
    Description: 104675
    Description: 2A. Fisica dell'alta atmosfera
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 97
    Publication Date: 2022-01-11
    Description: Mt Etna has made headlines over the last weeks and months with spectacular eruptions, some of them highly explosive. This type of paroxysmal eruptive behaviour is characteristic of Etna’s activity over the past few decades and so it is no surprise that Etna is among the most active volcanoes worldwide. Etna is well-known for its extraordinary geology and due to its repeated eruptive activity it provides a continuous supply of new scientific opportunities to understand the inner workings of large basaltic volcanic systems. In addition to its scientific value, Etna is also a world famous tourist attraction and has been listed as a UNESCO World Heritage site in 2013 for its geological and cultural value and not least for its fine agricultural products. Etna’s status as an iconic volcano is not a recent phenomenon; in fact, Etna has been a literary fixture for at least 3000 years, giving rise to many ancient myths and legends that mark it as a special place, deserving of human respect. From the ancient eruptions to the latest events in February–April 2021, people try to explain and understand the processes that occur within and beneath the volcano. In this article, we briefly summarize the recent eruptive activity of Etna as well as the ancient myths and legends that surround this volcano, from the underground forge of Hephaestus to the adventures of Odysseus, all the way to the benefits and dangers the volcano provides to those living on its flanks today.
    Description: Published
    Description: 141-149
    Description: 2TM. Divulgazione Scientifica
    Description: N/A or not JCR
    Keywords: Etna, mythology, 2021 paroxysms, economy ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 98
    Publication Date: 2022-02-11
    Description: Prior to the 2018 lower East Rift Zone (ERZ) eruption and summit collapse of Kīlauea Volcano, Hawai‘i, continuous gravimeters operated on the vent rims of ongoing eruptions at both the summit and Pu‘u ‘Ō‘ō. These instruments captured the onset of the 2018 lower ERZ eruption and the effects of lava withdrawal from both locales, providing constraints on the timing and style of activity and the physical properties of the lava lakes at both locations. At the summit, combining gravity, lava level, and a three-dimensional model of the vent indicates that the upper ∼200 m of the lava lake had a density of about 1700 kg m−3, slightly greater than estimates from 2011–2015 and possibly indicating a gradual densification over time. At Pu‘u ‘Ō‘ō, gravity and vent geometry were used to model both the density and the rate of crater collapse, which was unknown owing to a lack of visual observations. Results suggest the withdrawal of at least m3 of lava over the course of two hours, and a material density of 1800–1900 kg m−3. In addition, gravity data at Pu‘u ‘Ō‘ō captured a transient decrease and increase about an hour prior to crater collapse and that was probably related to a small, short-lived fissure eruption on the west flank of the cone and possibly to dike intrusion beneath Pu‘u ‘Ō‘ō. The fissure was the first event in the subsequent cascade that ultimately led to the extrusion of over 1 km3 of lava from lower ERZ vents, collapse of the summit caldera floor by more than 500 m, and the destruction of over 700 homes and other structures. These results emphasize the importance of continuous gravity in operational monitoring of active volcanoes.
    Description: Published
    Description: 117003
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 99
    Publication Date: 2022-02-11
    Description: Extensive geophysical and geodetic measurements were carried out to evaluate the groundwater aquifer, trace the basement relief, as well as detect the igneous intrusions and structural elements (mainly faults) that affect the occurrence of groundwater in the study area. The fieldwork included resistivity sounding, a geomagnetic survey, and Global Positioning System measurements. The magnetic results showed the presence of a group of main faults in East-west trend at the western part of the area and major fault at the northern part of the area of NW-SW trend. The findings also showed the presence of two igneous rock intrusions located in the middle of the eastern part of the valley. Pronounced differences in the depths of basement rocks have been identified, ranging between 0 and 900 m from the surface. Both high horizontal movements and high shear strain rates have been found to be concentrated at the southeast of the study area and it was noted that high stress was accumulated along the main observed faults and at the main groundwater aquifers. The geoelectrical results confirmed the presence of two aquifers; a shallow aquifer (Quaternary aquifer) that narrows northwards and a Nubian sandstone aquifer, which considered the main aquifer. The Nubian sandstone aquifer carries groundwater in the region, which overlies the last geoelectric unit represented by the basement complex layer and geological structures affecting the potential availability of groundwater in the study area, as proved by the geomagnetic survey and stress accumulation.
    Description: Researchers Supporting Project number (RSP-2021/351), King Saud University, Riyadh, Saudi Arabia
    Description: Published
    Description: 101549
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: GPS ; stress ; strain ; geomagnetic ; geoelectric ; groundwater ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 100
    Publication Date: 2022-02-11
    Description: This work describes the data used in the EPSL research article "Quantifying strong seismic propagation effects in the upper volcanic edifice using sensitivity kernels". The dataset is generated in order to investigate to what extent the seismic signals recorded on volcanoes are affected by near surface velocity structure. Data were calculated using the computational spectral elements scheme SPECFEM2D, where the wave propagation beneath Mount Etna volcano, Italy, was simulated in both homogeneous and heterogeneous models. The heterogeneous model comprises a low-velocity superficial structure (top several hundred meters) based on the previously published studies. Several different source mechanisms and locations were used in the simulations. The seismic wavefield was "recorded" by 15 surface receivers distributed along the surface of the volcano. The associated sensitivity kernels were also computed. These kernels highlight the region of the velocity model that affects the recorded seismogram within a desired time window. The text files describing the velocity models used in the simulations are also provided. The data may be of interest to volcano seismologists, as well as earthquake seismologists studying path effects and wave propagation through complex media.
    Description: European Union Seventh Framework Programme (FP7/2007 2013) under the project NEMOH, grand agreement no. 289976.
    Description: Published
    Description: 106673
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Near surface velocity structure; Numerical simulations; Sensitivity kernels; Specfem2d; Volcanic edifice; Volcano seismic sources
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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