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  • General Chemistry  (3,073)
  • Chemical Engineering  (1,958)
  • 1985-1989  (3,348)
  • 1980-1984  (1,683)
  • 1975-1979
  • 1925-1929
  • 1987  (1,728)
  • 1986  (1,620)
  • 1982  (1,683)
Collection
Publisher
Years
  • 1985-1989  (3,348)
  • 1980-1984  (1,683)
  • 1975-1979
  • 1925-1929
Year
  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 1021-1034 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Equations are derived that relate the orientation of “pseudo-affine” reoriented structural units after a biaxial deformation to the degrees and the directions of the effective drawings. The connection between these drawing parameters and those externally applied is analyzed in detail. It is shown how a comparison of these two sets of drawing parameters allows conclusions regarding the distribution throughout the material of the stresses that cause the deformation, the inhomogeneity of the deformation, and the role of non-orienting flow during deformation. In particular, the orientation of biaxially drawn poly(ethylene terephthalate) films is investigated, and it is shown what general information can be obtained on the deformation behavior of this material on the basis of these considerations.
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  • 2
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 1059-1068 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Scale-up from small laboratory size extruders to large production size extruders is a procedure of great practical importance. Many scale-up rules and theories have been proposed in the past, however it is not always clear how the different scale-up methods will affect extruder performance. A basic analysis of scale-up in plasticating single screw extruders is developed from which the effect of a certain scale-up strategy on extrusion performance can be evaluated in terms of solids conveying, melting, melt conveying, mixing, residence time, heat transfer, power consumption, and specific energy consumption. Various existing scale-up theories are evaluated and compared using the basic analysis. A number of existing scale-up theories have some significant drawbacks, in particular with non-constant specific energy consumption and imbalance between melting rate and pumping rate. Conditions that are desirable to achieve in scale-up are enumerated and ranked in terms of importance. This leads to two new scale-up methods that result in constant mechanical specific energy consumption and high throughput rates. The first scale-up method keeps the specific surface area constant. This scale-up should work well for high values of the Brinkman number. However, at low values of the Brinkman number, the melting rate may be insufficient. The second scale-up method keeps the melting rate at low Brinkman number equal to the pumping rate and, thus, should be useful in cases where the first scale-up method cannot be used.
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  • 3
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 4
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 1128-1136 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The plane strain fracture toughness and fracture mechanisms of several tough engineering plastics have been studied and compared with poly(methyl methacrylate) (PMMA), a relatively brittle polymer. The tough polymers all are observed to form a multiple craze zone at the crack tip, which is shown to be the primary source of plane strain fracture toughness in these materials. The multiple craze zone is retained during slow crack growth but is metastable, and at a critical stress intensity and associated crack velocity, the system passes through a transition to a greatly accelerated single craze mode of unstable propagation.
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  • 5
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 1148-1155 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The optical properties of bisphenol-A polycarbonate resin as described by the complex index of refraction, N = n - ik, are derived by Kramers-Kronig analysis of experimental absorption and reflectance data obtained in the range 40μm ≥ λ ≥ 105 nm. Electronic absorption processes in polycarbonate are characterized by two broad absorption peaks centered at ∼200 and ∼100 nm.
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  • 6
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 1182-1186 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Three-layer coextruded blown (either blend or composite) films, made of low-density polyethylene and linear lowdensity polyethylene (1:1 ratio) of identical density, were compared. The tensile properties of both systems are nearly as high as those of the linear polyethylene while high strain rate properties including impact strength and tear resistance of the composite film are superior. Some structural insight was obtained by thermal analysis and thermoelastic measurements. Structure property relationships are discussed in light of the unique behavior, structure, and morphology of linear low-density polyethylene. The two polyethylenes are only compatible to a rather limited extent mainly affecting their blend behavior. However, a strong mutual reinforcement effect was observed.
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  • 7
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 1203-1208 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A Viton copolymer containing vinylidene fluoride (VF2) and hexafluoropropylene (HFP), and a terpolymer containing VF2, HFP, and tetrafluoroethylene (TFE) were cross linked using varying amounts of Bisphenol AF to yield two series of fluoroelastomer networks, Stress-strain isotherms in elongation were determined for these samples at several temperatures and at two degrees of swelling with phenyl acetate. Strain-induced crystallization was observed, as evidenced by upturns in the isotherms at high elongations. It appears to be more pronounced in the terpolymer samples, presumably because the TFE units not only can crystallize themselves, but can co-crystallize with the VF2 units. The crystallization was found to persist upon moderate increase in temperature, but was suppressed when the networks were swollen, Thermoelastic (force-temperature) measurements were used to obtain values of the fraction fe/f of the elastic force that is due to energetic effects. Negative values were obtained for both types of samples and, in the case of two samples studied in detail, their magnitudes increased with increase in elongation. The magnitudes were larger and the increases more pronounced in the case of the terpolymer networks, as would be expected from a greater tendency for straininduced crystallization.
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  • 8
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 1221-1228 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The transesterification reaction of molten ethylene and vinyl alcohol copolymers (EVA), in presence of paraffinic alcohols and basic catalysts, leads to high conversion of the ester groups to secondary alcohol in both discontinuous and continuous processing equipment. Various kinds of alcohols and two different catalysts were used. Sodium methoxide is a powerful catalyst for the equilibrated transesterification reaction, but we also observed side reactions, such as cross-linking with low-molecular-weight alcohols and hydrolysis of the catalyst followed by partial saponification of the EVA. Kinetic studies were performed in the presence of dibutyltin dilaurate, an efficient catalyst without any side reactions. The solubility of the main alcohol reagents was verified by diffusion measurements. The general reaction scheme and the related kinetics, corresponding to a homogeneous system, lead to a fair evaluation of the rate constants.
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  • 9
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 1252-1257 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The mechanical properties of polyurethane-unsaturated polyester interpenetrating polymer networks (IPNs) that were prepared by reaction injection molding (RIM) process were measured with variations In composition, cross-link density, and relative reaction rate. From dynamic mechanical analysis (DMA), it was found that the two component polymers had a good compatibility over the whole composition range. The tensile strengths of the blends were greater than those of the pure components and had a maximum value at 50/50 composition. The modulus of elasticity and surface hardness decreased and the impact strength increased as the polyurethane content was increased, but the changes were not high at low polyurethane content, below 50%. For higher cross-link density, the compatibility was enhanced and the mechanical properties were improved. When the reaction rates of the components were different, some extent of phase separation was found in DMA and the properties were affected adversely.
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  • 10
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1036-1038 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 11
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1049-1051 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 12
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1053-1054 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 13
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 14
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1088-1098 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A restricted diffusion model is developed to study the immobilization of enzyme in porous solid supports. Simulation studies have been carried out for various combinations of process variables and parameters of the immobilization system. The model has also been used to develop a method for estimating the intrinsic rate constant of immobilization when enzyme diffusion into the support is restricted. Results of experiments in which glucose oxidase was immobilized in porous glass supports are consistent with model simulations.
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  • 15
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1253-1262 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A universally valid formal expression for the composition dependence of solute and solvent fugacity coefficients in any dilute binary system far from criticality is derived in this paper. In the present context, dilution denotes the y1 → O limit, regardless of the mixture's molar density. The results are independent of the system under study and of the choice of equation of state. The solute fugacity coefficient is simply the product of a composition-independent term (the infinite dilution fugacity coefficient) and an exponential decay composition correction. These two parameters have important thermodynamic implications: their temperature and pressure derivatives are related to the solute's partial molar enthalpy and volume, respectively. When applied to activity coefficients, the same theoretical analysis yields universal relationships for the composition dependence of activity coefficients which can be used as consistency checks for empirical correlations. The relationship between infinite dilution activity and fugacity coefficients can be used to estimate relative solubilities of a given solute in different solvents. Excellent agreement is found when the theoretical expressions are tested with three different binary systems involving a nonvolatile solid solute and a supercritical fluid.
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  • 16
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    AIChE Journal 32 (1986), S. 1301-1311 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical model is developed to simulate the drying of hygroscopic porous media and, in particular, of wood. Drying rate experiments were performed using wood specimens and a nonhygroscopic porous ceramic solid and were simulated using the appropriate version of the drying model. Calculated model predictions are in very satisfactory agreement with experimental results. An examination of the relative impacts on drying of the transport mechanisms that comprise the model leads to meaningful interpretations of observed drying behavior. Controlling rate factors can be identified and different types of drying behavior specific to a given material or drying condition can be explained and understood through model simulation studies. Such capability can provide important guidance for drying process design and control.
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  • 17
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    AIChE Journal 32 (1986), S. 1347-1359 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The technique of distillation with intermediate heat pumps and optimal sidestream return - IHOSR distillation - is presented. IHOSR distillation allows heat to be moved between points in a distillation column with greater efficiency than several other methods of using heat pumps for distillation.
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  • 18
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Forced Rayleigh scattering, a relatively recently developed optical technique, is used to measure tracer diffusion coefficients in polymer-solvent mixtures near the system glass transition temperature, Tg. The technique has a wider range of potential application than has yet been realized, and so is presented in some detail. The objectives were to obtain data necessary to scrutinize free volume theory, and to understand so-called anomalous, non-Fickian diffusion effects observed by others in polymer-solvent mixtures near Tg. Data on dye tracer diffusion coefficients in the systems polyvinyl acetate-toluene, polystyrene-toluene, and polystyrene-tri-m-tolyl phosphate were obtained over a polymer concentration range from infinite dilution to 96 wt. %. Small molecule diffusion coefficients are seen to vary by as much as nine orders of magnitude (10-14 to 10-5 cm2/s) over this concentration range. The data are in reasonable accord with expectations based on the Duda-Vrentas version of free-volume theory.
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  • 19
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    AIChE Journal 33 (1987), S. 604-618 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Microflow calorimeter design for heats of mixing is surveyed. Precise temperature equilibration of the fluids before mixing, the elimination of frictional energy effects from the instrument response, and the absence of flow-rate and physical-property-dependent heat leaks are particularly important. A design using a differential mode of operation is based on a careful analysis of entropy generation in flows with mixing and friction. The compensation for frictional heating and the lack of dependence of measurements on flow rate and mixture physical properties other than hE represents a major advance. Measured data for the welltested cyclohexane-hexane system had an average deviation of only 0.41%. For the more viscous cyclohexane-1-hexanol system, measured data of similar precision are considered the best available.
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  • 20
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    AIChE Journal 33 (1987), S. 643-653 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Energy requirements of four different thermally coupled distillation systems were minimized for an assumed ideal ternary solution being separated. Minimum vapor flows and values of decision variables have been found in the form of analytical expressions. This enables making a quick and simple comparison of these systems. The solution method can be used for synthesis of separation systems or for screening calculations.
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  • 21
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    AIChE Journal 33 (1987), S. 628-642 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical model is presented for the codeposition of cadmium and tellurium onto a rotating-disk electrode. The treatment incorporates the equation of convective diffusion for liquid phase mass transport, Butler-Volmer expressions for charge-transfer reactions, and a thermodynamic model for individual component activities in the solid state. Because of the formation of CdTe, a compound that has a large negative free energy of formation, the cadmium deposition reaction occurs at potentials substantially positive to its standard electrode potential (Uθ = -0.40 V). This reaction, along with the deposition of tellurium (Uθ = + 0.55 V), produces an electrodeposit that contains cadmium, tellurium, and cadmium telluride. The model can be used to calculate transient current-potential relationships, ionic concentration profiles, and deposit compositions. Transport and kinetic parameters for cadmium and tellurium deposition are reported; a multidimensional optimization routine is used to evaluate physiochemical parameters from experimental data for the codeposition process.
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  • 22
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    AIChE Journal 33 (1987), S. 668-671 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 23
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    AIChE Journal 33 (1987), S. 677-680 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 24
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    AIChE Journal 33 (1987), S. 686-689 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 25
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    AIChE Journal 33 (1987), S. 694-696 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 26
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    AIChE Journal 33 (1987), S. 701-702 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 27
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    AIChE Journal 33 (1987), S. 705-710 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Studies of the attack of gel-stabilized suspensions of hydroxyapatite show dissolution at the boundary of the solid region and reprecipitation within this region. The results are apparently consistent with a theory which assumes that porous solid dissolution is diffusion-controlled but constrained by nonlinear solubility products.
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    AIChE Journal 33 (1987), S. 1829-1834 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A test has been designed and used to compare flow hydrodynamics in different thermogravimetric analysis (TGA) systems used as pulse microreactors. The test involves passing a pulse of injectant over the sample pan containing an adsorbent. Water and zeolite are used in the present case. The technique is easily performed and is insensitive to variations in temperature. A model is developed by which the fraction of gas pulse bypassing the sample pan within the TGA can be obtained. In gas/solid reactions, either catalytic or noncatalytic, the test should prove useful for comparing TGA extent-of-conversion data to similar measurements taken from other reactor configurations, carrier flow rates, and flow geometries.
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    AIChE Journal 33 (1987), S. 1835-1843 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Published models for gas-solid reactions have been used with certain modifications to interpret sulfation data for CaO, MgO, and ZnO with SO2 and SO3. None of the models evaluated gave an adequate interpretation for high solid conversions, which were found to exceed 90% in some cases. Such high conversions are inconsistent with the current models, and a new mechanism must be postulated to explain the reaction after the solid product theoretically fills the initial pores of the particle. An important factor in successfully interpreting the experimental data is the distributed nature of the pore sizes within the solid particle.
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    AIChE Journal 33 (1987), S. 1844-1849 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Contact nucleation studies were performed with the dextrose-water system. Under some conditions two crystallographic phases were formed, which were identified in situ using a laser Raman microprobe. In addition, the growth of the contact nuclei was monitored in situ using photomicroscopy. The results are discussed in the context of contact nucleation and growth models.
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    AIChE Journal 33 (1987), S. 1873-1881 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An efficient frequency domain methodology for the design of set point regulators for high-order process models involving relatively large pure time delay is presented. The unique advantage of the methodology is that it enables the designer to rapidly visualize the structure of the required controller as soon as the time and frequency domain specifications are stipulated for the closed-loop system. Optimizing the parameters of an appropriate structure improves the robustness of the controller. The method does not require order reduction of the original model, and time delay is handled directly. Also, only output feedback is utilized.
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  • 32
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    AIChE Journal 33 (1987), S. 1865-1872 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new bubble diameter correlation is derived to predict bubbling characteristics of fluidized beds of varieties of powders. The present model is founded on the postulate that the steady bubble size, which is often called the maximum stable diameter, observed in a bed of Geldart group A powder is formed as a result of an equilibrium of successive coalescence and splitting. For the cases of group B powders the present correlation automatically converges to the conventional correlation of Mori and Wen (1975), whose predictions are close to those of Rowe (1976) and Darton et al. (1977). For group A powders the present correlation is validated by comparison with experimental data in the literature. Based on this correlation a theoretical explanation is presented for the fact that the maximum bubble diameters observed were up to 50 to 100 times as large as those from the stable bubble theory of Harrison et al. (1961).
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    AIChE Journal 33 (1987), S. 1850-1864 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Global bifurcations are frequently encountered in the dynamic behavior of chemically reacting systems and their models. They cause dramatic qualitative changes in the system response, such as the birth and death of oscillations and even the onset of chaos. They involve entire regions of the system phase space, and due to their nature they are in general not predictable by standard local bifurcation methods, analytical or numerical. Special methods and algorithms must therefore be developed to locate and analyze them in parameter space. This paper presents such methods and algorithms and illustrates them through standard chemical engineering examples. Test cases include lumped chemical reactor models (homogeneous and heterogeneous, autonomous and periodically forced), a problem of compressible gas flow in porous media, and a case of two coupled oscillators. The phenomena discussed include infinite-period bifurcations, saddle connections, frequency locking, and the creation and extinction of multifrequency responses through global manifold interactions (homoclinic tangles).
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    AIChE Journal 33 (1987), S. 1882-1887 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The general collinearity conditions at phase boundaries for mixtures are proved by thermodynamic identities for density and for entropy as functions of temperature, pressure, and composition. In the case of density/temperature/pressure/composition collinearity is always found at the cricondentherm or any temperature extremum, whereas for entropy/temperature/pressure/composition collinearity is always found at the cricondenbar or any pressure extremum. Qualitative phase diagrams for a typical binary system are presented in accordance with the derived inequalities. Whether a particular slope, involving the above variables, from the homogeneous side of the phase boundary is greater or less than that from the heterogeneous side depends on location on the phase boundary with respect to cricondentherm, critical point, and cricondenbar.
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    AIChE Journal 33 (1987), S. 1899-1902 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 33 (1987), S. 1895-1898 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 33 (1987), S. 1888-1893 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Average and local heat transfer coefficients were measured for transfer from circulating fluidized beds of sand particles (mean size 188 and 356 μm) to two water-cooled membrane wall surfaces located on one face of a 152 mm square by 7.3 m tall column. The measurements cover a range of superficial gas velocities from about 4 to 7 m/s, suspension densities from about 8 to 130 kg/m3, suspension temperatures from 150 to 400°C, and secondary-to-primary air ratios of 0 to 1.5. Heat transfer coefficients, averaged over a 1.53 m length of the membrane waterwall surfaces, depend strongly on suspension density, but show almost no separate dependence on gas velocity, bed temperature, or secondary-to-primary air ratio for the conditions studied. For the surface nearest the top of the unit, the coefficient decreases with distance measured downward from the top, suggesting that particles travel downward along the surface. As a result, averaged coefficients are lower and the influence of particle size is less than for previously reported circulating fluidized bed heat transfer measurements where miniature heat transfer surfaces were employed.
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    AIChE Journal 33 (1987), S. 1903-1907 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 33 (1987), S. 1908-1911 
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    AIChE Journal 33 (1987), S. 1912-1915 
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    AIChE Journal 33 (1987), S. 1916-1920 
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    AIChE Journal 33 (1987), S. 1921-1925 
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    AIChE Journal 33 (1987), S. 1926-1929 
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    AIChE Journal 33 (1987), S. 1932-1932 
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    AIChE Journal 33 (1987), S. 1933-1933 
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    AIChE Journal 33 (1987) 
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    AIChE Journal 33 (1987), S. 1930-1932 
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    AIChE Journal 33 (1987), S. 1949-1958 
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The role of inter- and intraparticle transport resistances in the sensitivity behavior of a fixed-bed catalytic reactor is fully elucidated. The parametric sensitivity regions obtained using a heterogeneous one-dimensional plug flow model are reported for various values of the involved dimensionless parameters. Comparisons with previous sensitivity criteria and with experimental data are also presented.
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    AIChE Journal 33 (1987), S. 1937-1948 
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    Notes: A flash-evaporation technique is used to obtain vapor deposition characteristics for the binary alkali sulfates K2SO4 + Na2SO4 at 1 atm above 1, 100 K. This technique gives results of immediate engineering interest, such as dewpoint temperatures, condensate composition and rates of vapor deposition as well as useful data on the system's thermodynamic characteristics. It is concluded that alkali sulfate deposition and vaporization in combustion environments are inevitably influenced by chemical reactions such as hydroxide formation. It is also concluded that solution nonideality is important even for homologous alkali-salt mixtures.Predictions are made using convective-diffusion mass transfer theory, accounting for chemical reactions by means of effective volatilities, and assuming regular, nonideal condensate solutions. The predicted dewpoints, condensate compositions and deposition rates are quantitatively consistent with experimental observations. This approach, validated here, can be extended to more extreme conditions of engineering interest, including turbulent, high-temperature/pressure systems.
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    AIChE Journal 33 (1987), S. 1959-1970 
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    Notes: New data and analyses are presented for describing gas and solids behavior in a slurry bubble column. Axial solids concentration and bubble size distributions were measured in a 0.108 m ID slurry bubble column apparatus operated at steady state conditions. The column was operated with and without internal baffles. The slurry and gas superficial velocities ranged from 0.0077 to 0.009 m/s and from 0.031 to 0.24 m/s, respectively. The solid phase consisted of glass spheres in a narrow size range with a mean diameter of 96.5 μm; the liquid phase consisted of tap water.With a one-dimensional sedimentation-dispersion model, the data have been used to predict average solids loadings and axial distributions of the solids for specified operating conditions. Local bubble size and concentration measurements indicate that the slurry bubble column was operated in the churn-turbulent flow regime throughout the entire range of operating conditions used in this study. The impact of internal baffles and solids concentration on the gas and solids behavior is discussed.
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    AIChE Journal 33 (1987), S. 1977-1985 
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    Notes: A finite-element method is given for efficient simulation of multiphase distillation systems. Breakpoints are adaptively located to coincide with phase discontinuities. Thermodynamic criteria for the states at these discontinuities are included in the equation system. The adjustable breakpoint locations are calculated simultaneously with the other system variables by global Newton iteration. Worked examples demonstrate the accuracy and efficiency of the method.
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    AIChE Journal 33 (1987), S. 1986-1992 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: Fuzzy set theory is used to describe similarity of chemical engineering systems. The development of system similarity is given, and methods of determining a similarity relation are discussed. The system similarity relation is applied to the problems of measuring correlation confidence and quantifying modeling error. Sample problems are examined.
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    AIChE Journal 33 (1987), S. 1971-1976 
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    Notes: The oxidation of CO over aluminum-supported Ag was studied at 147°C using transient experiments. Long-time-scale dynamics were observed that could not be explained by previously postulated kinetic mechanisms for this reaction system. A model is presented with kinetic parameters estimated from steady state and transient data that is able to reproduce a variety of cycled feed stream experiments. The model incorporates a slow reversible step which forms an adsorbed oxygen species that blocks reaction sites.
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    AIChE Journal 33 (1987), S. 1993-1997 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Diffusion and chemical reaction in a catalyst pore is simulated as a Monte Carlo process. In this analysis the average diffusion distance, calculated for a large number of wall collisions, and the reaction probability are computed as two independent statistical events. This formulation yields results that compare very well with the theoretical values, yet uses minimal computer time. Results reported include typical concentration profiles and effectiveness factors for first- and second-order isothermal reactions using the method described. These results show promise of extension to more complex systems where analytical solutions are not available.
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    AIChE Journal 33 (1987), S. 1998-2002 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In turbulent flow the equations governing the development of conversion vs. distance are not closed because of the contribution of the concentration fluctuations to the average reaction rate. Toor's hypothesis permits closure from data obtained for mixing without reaction. This paper presents a critical review of the derivation of the hypothesis and discusses its validity.
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    AIChE Journal 33 (1987), S. 2003-2007 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new, unobtrusive method for liquid-liquid two-phase flow data collection was proved to be reliable in this research. Drop size distributions and concentration profiles were determined for a dilute water-inkerosene system under horizontal straight pipe flow using this technique, and the Segev model for predicting concentration profiles was tested with the data collected here.The drop size distributions were found to follow a Rosin-Rammler function for a limited droplet diameter range, and the average value of the exponent in the Rosin-Rammler equation was determined to be 2.0. The velocity where the flow regime makes a transition from stratified to adequately dispersed flow was found to be between 2.0 and 2.2 m/s. Concentration profiles predicted by the Segev model were in general agreement with the profiles determined in this work, and using the proper choice of model parameters noticeably improves the model predictions.
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    AIChE Journal 33 (1987), S. 2017-2026 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The reaction rate constant was adjusted continuously over two orders of magnitude for the unimolecular decomposition of α-chlorobenzyl methyl ether using the supercritical fluid solvent 1, 1 diffluoroethane. Activation volumes were observed as low as -6,000 cm3/mol, which is about an order of magnitude more negative than those reported previously in the literature for a homogeneous reaction. Spectral shift (solvatochromic) data were measured for phenol blue in the same fluid in order to interpret the rate data. A method is presented to predict solvent effects on rate constants at supercritical fluid conditions.
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    AIChE Journal 33 (1987), S. 2027-2036 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Pressure-drop in cocurrent gas-liquid downflow through packed beds was experimentally measured for nonfoaming, foaming Newtonian, and non-Newtonian liquids. The variables include the column diameter, packing size and shape, flow rates of the phases, and their physical properties. Unified correlations are presented for the data of the present study as well as data available in literature in terms of Lockhart-Martinelli parameters and flow variables and packing characteristics. The data were modeled using a dynamic interaction model.
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    AIChE Journal 33 (1987), S. 2037-2046 
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    Notes: To understand better the impact of gas phase reactions on chemical vapor deposition, a new experimental method has been developed to isolate and study homogeneous reactions separately from heterogeneous reactions. This new system heats reactant gases by rapidly compressing them to temperatures greater than 1,000 K; the walls of the reactor remain constant at 500 K or less. Pressure and volume measurements determine the mean temperature of the gas. Results from a series of test reactions and simple models show that this apparatus and measurement method work well. The apparatus is inexpensive and simple to use, and has advantages over shock tubes and static systems.
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    AIChE Journal 33 (1987), S. 2008-2016 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Mass transfer rates in laminar and turbulent nonseparated boundary layers are asymptotically expanded for small values of the diffusivity DAB, with a uniform state on the mass transfer surface. Results for heat transfer follow by analogy. The thermal or binary Nusselt number at small net mass transfer rates is given asymptotically by a generalized penetration expression \documentclass{article}\pagestyle{empty}\begin{document}$$ \langle Nu\rangle \, = \,a_{00} Pe^{1/2} \, + \,a_{01} Pe^0 \, + \,.\,.\,.\,{\rm (A)} $$\end{document} for short times, or for boundary layers that duplicate the surface tangential motion. For flows past rigid interfaces, the long-time average of 〈Nu〉 is given asymptotically by a generalized Chilton-Colburn relation \documentclass{article}\pagestyle{empty}\begin{document}$$ \langle \overline {Nu} \rangle \, = \,b_{00} Pe^{1/3} \, + \,b_{01} Pe^0 \, + \,.\,.\,.\,{\rm (B)} $$\end{document} in regions of nonrecirculating motion. The measurable functions aij and bij depend only on the system shape and laminar or turbulent velocity field. Formal expressions for a00 are given, and an expression for b00 in steady flows. These results agree well with data on mass transfer operations in tubes, packed beds, and fluid-fluid contactors.
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    AIChE Journal 33 (1987), S. 2057-2066 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A two-parameter, corresponding-states form for direct correlation function integrals in liquids is applied to many types of systems with one substance being supercritical. This gives a quantitative correlation for volumetric behavior, pure and mixed solvent Henry's constants, and Henry's Law deviations over wide ranges of conditions using only pure-component information and a single binary parameter. Details of the method and results are given for H2, N2, CO, CH4, and other gases in pure and mixed simple, polar, and aqueous solvents and coal oils. Because of its reliable predictive capability, the present approach can serve as a generator of data for parameter estimation by other models such as equations of state.
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    AIChE Journal 33 (1987), S. 2047-2056 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Data and finite-element simulations are presented for the blade coating of a series of Newtonian and non-Newtonian fluids. Numerical simulations for purely viscous fluids show good agreement with coating thickness data for Newtonian and relatively inelastic non-Newtonian liquids, including geometries for which lubrication theory is inaccurate. These simulations account for the shape of the free surface, with surface tension included, and incorporate realistic inflow and outflow boundary conditions. By comparing pressure distributions generated with the finite-element technique to those calculated using lubrication theory, it is shown that the simple lubrication theory analysis suffers from inadequate inflow and outflow boundary conditions. Comparison of these simulations with new experimental results for three well-characterized viscoelastic liquids, having nearly identical steady shear viscosities but different normal stress behavior, confirms speculations of earlier work with respect to the effect fluid rheology has on coating thickness.
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    AIChE Journal 33 (1987), S. 2067-2076 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A detailed kinetic model for the bulk styrene polymerization initiated by symmetrical diperoxyester bifunctional initiators is presented. When chain termination occurs via a combination termination mechanism, six distinct polymeric species are identified in accordance with the nature of the polymer end units. It is shown that the unequal thermal decomposition characteristics of the peroxides of the bifunctional initiator system lead to the formation of polymers having considerably higher molecular weight than those obtained by the monofunctional intiator systems. It has also been found that high monomer conversion, high molecular weight, and narrow molecular weight distribution can be obtained simultaneously by using the bifunctional initiators at high reaction temperatures. This is due to the reinitiation and propagation of inactive polymers carrying undecomposed peroxides. The molecular-weight-increasing effect of the bifunctional initiator is more pronounced at high reaction temperatures. The new possibilities of increasing the monomer conversion and controlling the polymer molecular weight properties more effectively through the use of bifunctional initiators are discussed.
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    AIChE Journal 33 (1987), S. 2080-2083 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 33 (1987), S. 2077-2079 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 33 (1987), S. 2084-2086 
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    AIChE Journal 33 (1987), S. 2087-2090 
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    AIChE Journal 33 (1987), S. 2091-2092 
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    AIChE Journal 33 (1987), S. 2092-2093 
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    AIChE Journal 33 (1987), S. 2092-2092 
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    AIChE Journal 33 (1987), S. 2093-2093 
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    AIChE Journal 33 (1987), S. 2094-2094 
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    AIChE Journal 33 (1987), S. 2095-2096 
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    AIChE Journal 33 (1987), S. 2096-2096 
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    AIChE Journal 33 (1987), S. 2094-2095 
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    AIChE Journal 33 (1987), S. 2096-2097 
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    AIChE Journal 33 (1987), S. 2097-2097 
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    AIChE Journal 33 (1987), S. 2098-2100 
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    AIChE Journal 32 (1986), S. 1546-1554 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Deterministic analyses applied to both velocity and concentration fluctuation data obtained in a region extremely close to air-water interface in a free-surface, unbaffled stirred tank allow estimation of the length and the velocity scales of individual eddies taking part in gas absorption. The mass transfer prediction by this method is superior to that by a statistical method using an integral length scale in the low-turbulence flow employed in this work. Eddy velocities are generally lower in the diffusion boundary layer zone compared with the bulk zone. Small eddies are generally associated with low velocity scales whereas large eddies occur at high velocity scales. Local mass transfer coefficients are high in regions where small eddies are dominant.
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    AIChE Journal 32 (1986), S. 1561-1566 
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    AIChE Journal 32 (1986), S. 1567-1569 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 32 (1986), S. 1570-1573 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: An approach to air-lift reactor analysis is presented that examines the three parts of the air-lift - the riser, downcomer, and gas-liquid separator - as three interconnected and interrelated elements. Downcomer flow configurations are described and characterized by either straight or oscillating bubble flow patterns. The downcomer gas flow rate is determined using a two-sparger system, and a correlation is presented relating the downcomer superficial gas velocity to the downcomer gas holdup. Gas recirculation is calculated and related to the geometric and operating conditions of the gas-liquid separator. It is shown that an increase in residence time in the gas-liquid separator decreases the gas recirculation rate. Correlations are presented relating gas holdup and liquid velocities to superficial gas velocity.A sparger was added near the entrance of the downcomer, in addition to the conventional placement near the entrance of the riser. Results of such a two-sparger system are discussed in relation to reactor stability and liquid velocities.
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    AIChE Journal 32 (1986), S. 1642-1654 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model for the variance σc2 of instantaneous plume concentrations, at a level corresponding to that of the Gaussian formulas for the mean field, is developed and tested against available data. Starting from the Eulerian species transport equation, theoretical and empirical information is used to estimate parameters and simplify the form of the transport equation for σc2 in a meandering frame of reference. Then, introduction of a localized production of fluctuations (LPF) scheme allows construction of analytical expressions for σc2 that provide a direct means for calculating the concentration variance inside the instantaneous boundaries of plumes resulting from continuous point emissions in turbulent flows with uniform mean velocity.
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    AIChE Journal 32 (1986), S. 1665-1676 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A procedure is presented for designing supercritical gas extraction processes using a pure solvent fluid to effect the separation. The necessary conditions for the procedure to be applicable are the existence of crossover behavior and separable crossover pressures in the fluid phase mixture. Data are presented to support the existence of such phenomena in ternary systems, and an actual separation process has been designed and operated based upon the data. For systems exhibiting this behavior, process synthesis principles are developed to illustrate the evolution of a process flowsheet for the separation of a mixture into its pure components.
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    AIChE Journal 32 (1986), S. 1677-1689 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Multiple hydrodynamic states were observed during cocurrent down-flow of air and water under trickling flow conditions in a packed bed of rectangular cross section. Although the multiplicity was exhibited by both pressure gradient and liquid holdup, the pressure gradient showed the largest variations at identical conditions. The multiplicity is interpreted as being due to the liquid flowing in two different modes, namely, film flow and rivulet flow.The characteristics of pulsing flow in a packed bed of rectangular cross section were found to be appreciably different from those reported in the literature for flow in small-diameter cylindrical columns. The most significant observation in the packed bed of rectangular cross section was that the pulses did not always span the column cross section, unlike the case in small-diameter columns. The lower pressure drop and pulse velocity in the packed bed of rectangular cross section are believed to result from the bypassing of gas around the edge of the pulses. The location of the pulses was found to depend on the quality of gas and liquid distribution at the top of the column, and the shape of the top surface of the packing. A distributor configuration in which the gas was injected directly into the bed was found to be the most desirable, and is recommended in industrial practice.
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    AIChE Journal 32 (1986), S. 1971-1979 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Bimolecular QRRK (Quantum Rice-Ramsperger-Kassel) analysis is a simple method for calculating rate constants of addition and recombination reactions, based on unimolecular quantum-RRK theory. Input parameters are readily derived, and rate constants and reaction branching can be predicted with remarkable accuracy. Such predictive power makes the method especially useful in developing mechanisms of elementary reactions. Furthermore, from the bimolecular QRRK equations, limiting forms of the rate constants in the limits of low and high pressure are developed. Addition/stabilization is pressure-dependent at low pressure but pressure-independent at high pressure, as is conventionally understood for simple decomposition, its reverse. In distinct contrast, addition with chemically activated decomposition has the opposite behavior: pressure independence at low pressure and pressure dependence [as (pressure)-1] at high pressure. The method is tested against data and illustrated by calculations for O + CO → CO2; for H + O2 → HO2 or O + OH; for H + C2H4 → C2H5 or C2H3 + H2; and for H + C2H3 → C2H4 or H2 + C2H2.
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    AIChE Journal 32 (1986), S. 2020-2027 
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical model of multicomponent permeation systems with high-flux, asymmetric hollow-fiber membranes is presented. The model takes into account the permeate pressure variation inside the fiber. In the special case of negligible permeate pressure drop, the model yields a simple analytical solution for membrane area calculation that eliminates the numerical integration step required in existing methods. Laboratory multicomponent permeation experiments have verified the mathematical model and have demonstrated the technical feasibility of using the high-flux asymmetric cellulose acetate hollow fiber for H2, CO2, and H2S separation. It is shown that the selectivity of the cellulose acetate membrane is ideally suited to the recovery of hydrogen from the purge gas of reactor recycle loops. For the separation of high-concentration CO2 or H2S, the test data show that the permeabilities of the individual components in mixed gas permeation are significantly different from those of pure gases.
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    AIChE Journal 32 (1986), S. 2067-2078 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The dew points of 40 multicomponent fluid mixtures including gas condensates, absorber oils, crude oils, synthetic aromatic heavy oils, and coal liquids were calculated using the method of continuous thermodynamics and the Patel-Teja cubic equation of state. These multicomponent mixtures were characterized by a log normal distribution function in two variables: the boiling point and specific gravity in this work. Comparisons were made with the case when a single variable distribution function is employed and also with the method of Cotterman et al. In general, the new method leads to excellent predictions of both phase equilibria and liquid densities.
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    AIChE Journal 33 (1987), S. 1187-1196 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model including the effects of diffusion and convection can be used to predict the etch rate of crystalline silicon in a plasma discharge of nitrogen trifluoride. The case of a radial flow reactor with crystalline silicon wafers located at discrete positions can be solved using a finite-element solution to a boundary value problem. Such a model is useful to predict the effects of pressure, flow rate of etchant gas, percent silicon exposed, and wafer position on both inter-and intrawafer etch rates. It was found from modeling that greater uniformity in etch rate is achieved by lowering the pressure and percent exposure of silicon, and to a lesser degree the volumetric flow rate.
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    AIChE Journal 33 (1987), S. 1207-1211 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 33 (1987), S. 1197-1206 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model of an isothermal bubble column slurry reactor for an arbitrary reaction network of R independent reactions and S reacting species has been developed. The model accounts for gas velocity variations due to a change in total number of moles during reaction, and for nonuniform catalyst distribution due to gravity settling. It is assumed that the gas phase is in plug flow and the batch liquid phase is unmixed, which is characteristic of pilot plant reactors with high aspect ratios. The minimum number of differential equations required for the complete description of the system is shown to be equal to the total number of independent reactions. A system of two series-parallel reactions, representative of Fischer-Tropsch synthesis, was used to study the effect of catalyst dispersion and model parameters on reactor performance. It was found that nonuniform catalyst distribution generally has a negative effect on conversion.
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    AIChE Journal 33 (1987), S. 1218-1221 
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    AIChE Journal 33 (1987), S. 1225-1227 
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    AIChE Journal 33 (1987), S. 1229-1230 
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    AIChE Journal 33 (1987), S. 1230-1230 
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    AIChE Journal 33 (1987), S. 173-176 
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