ALBERT

Description: No abstract available

Description: We present a spherical harmonic solution of the static gravity field of Mars to degree and order 120, GMM-3, that has been calculated using the Deep Space Network tracking data of the NASA Mars missions, Mars Global Surveyor (MGS), Mars Odyssey (ODY), and the Mars Reconnaissance Orbiter (MRO). We have also jointly determined spherical harmonic solutions for the static and time-variable gravity field of Mars, and the Mars k 2 Love numbers, exclusive of the gravity contribution of the atmosphere. Consequently, the retrieved time-varying gravity coefficients and the Love number k 2 solely yield seasonal variations in the mass of the polar caps and the solid tides of Mars, respectively. We obtain a Mars Love number k 2 of 0.1697 +/-0.0027 (3- sigma). The inclusion of MRO tracking data results in improved seasonal gravity field coefficients C 30 and, for the first time, C 50 . Refinements of the atmospheric model in our orbit determination program have allowed us to monitor the odd zonal harmonic C 30 for approx.1.5 solar cycles (16 years). This gravity model shows improved correlations with MOLA topography up to 15% larger at higher harmonics ( l = 6080) than previous solutions.

Description: The Mars Reconnaissance Orbiter (MRO) entered Mars orbit on March 10, 2006. After five months of aerobraking, a series of propulsive maneuvers were used to establish the desired low-altitude science orbit. The spacecraft has been on station in its 255 x 320 km, sun-synchronous (~3 am-pm), primary science orbit since September 2006 performing both scientific and Mars programmatic support functions. This paper will provide a summary of the major achievements of the mission to date and the major flight activities planned for the remainder of its third Extended Mission (EM3). Some of the major flight challenges the flight team has faced are also discussed.

Description: No abstract available

Description: The Lunar Reconnaissance Orbiter (LRO) launched in 2009 to collect the dataset required for future surface missions and to answer key questions about the lunar surface environment. In the first seven years of operations, the Lunar Reconnaissance Orbiter Camera (LROC) acquired over a million images of the lunar surface and collected key stereo observations for the production of meter-scale digital terrain models. Due to the configuration of the LRO orbit, LROC and the other onboard instruments have the opportunity to acquire observations at or near the poles every two hours. The lunar south polar region is an area of interest for future surface missions due to the benign thermal environment and areas of near-continuous illumination. These persistently illuminated regions are also adjacent to permanently shadowed areas (e.g. floors of craters and local depressions) that are of interest to both scientists and engineers prospecting for cold-trapped volatiles on or near the surface for future in situ resource utilization. Using a terramechanics model based on surface properties derived during the Apollo and Luna missions, we evaluated the accessibility of different science targets and the optimal traverse paths for a given set of waypoints. Assuming a rover that relies primarily on solar power, we identified a traverse that would keep the rover illuminated for 94.43% of the year between 1 January 2021 and 31 December 2021. Throughout this year-long period, the longest eclipse endured by the rover would last only 101 hours and the rover would move a total of 22.11 km with an average speed of 2.5 m/hr (max speed=30 m/hr). During this time the rover would be able to explore a variety of targets along the connecting ridge between Shackleton and de Gerlache craters. In addition to the southern polar regions, we are also examining traverses around other key exploration sites such as Marius Hills, Ina-D, Rima Parry, and the Mairan Domes in efforts to aid future mission planners and assess the requirements for future roving prospectors (e.g., maximum speed, maximum slope, etc.).

Description: Since early 2015, the Mars Exploration Rover Opportunity has been exploring the break in the rim of Endeavour Crater dubbed Marathon Valley by the rover team. Marathon Valley was identified by orbital hyperspectral data from the MRO CRISM as having a relatively strong spectral feature in the 2.3 micrometer region indicative of an Mg or Fe-OH combination overtone absorption band indicative of smectite clay. Earlier in its mission, Opportunity examined the Matijevic Hill region on the more northerly Cape York crater rim segment and found evidence for smectite clays in a stratigraphically lower, pre-impact formed unit dubbed the Matijevic formation. However, the smectite exposures in Marathon Valley appear to be associated with the stratigraphically higher Shoemaker formation impact breccia. Evidence for alteration in this unit in Marathon Valley is provided by Pancam multispectral observations in the 430 to 1010 nm visible/near infrared (VNIR) spectral range. Sinuous troughs ("red zones") contain fragmented cobbles and pebbles displaying higher blue-to-red slopes, moderately higher 535 nm band depths, elevated 754 to 934 nm, and negative 934 to 1009 nm slopes. The lack of an absorption at 864 to 904 nm indicates the lack of crystalline red hematite in these red zones, but likely an enrichment in nanophase ferric oxides. The negative 934 to 1009 nm slope is potentially indicative of the presence of adsorbed or structurally bound water. A scuff in a red zone near the southern wall of Marathon Valley uncovered light-toned soils and a pebble with an 803 to 864 nm absorption resembling that of light-toned Fe-sulfate bearing soils uncovered by the Spirit rover in the Columbia Hills of Gusev crater. APXS chemical measurements indicated enrichments of Mg and S in the scuff soils and the pebble, Joseph Field, with the strongest 803 nm band- consistent with Mg and Fe sulfates. The presence of Fe and Mg sulfates can be interpreted as evidence of a potentially later episode of aqueous alteration with an earlier, neutral to alkaline pH episode forming the Fe/Mg smectites and a later acid pH episode forming the Fe and Mg sulfates.

Description: Mars Exploration Rover Opportunity is exploring the rim of 22 km diameter, Noachian-aged Endeavour crater. Marathon Valley cuts through the central region of the western rim providing a window into the local lower rim stratigraphic record. Spectra from the Compact Reconnaissance Imaging Spectrometer for Mars show evidence for the occurrence of Fe-Mg smectite in this valley, indicating areally extensive and distinct lithologic units and/or styles of aqueous alteration. The Alpha Particle X-ray Spectrometer has determined the compositions of 59 outcrop targets on untreated, brushed and abraded surfaces. Rocks in the Marathon Valley region are soft breccias composed of mm- to cm-sized darker clasts set in a lighter-toned, finegrained matrix. They are basaltic in non-volatile-element composition and compositionally similar to breccias investigated elsewhere on the rim. Alteration styles recorded in the rocks include: (1) Enrichments in Si, Al, Ti and Cr in more reddish-colored rock, consistent with leaching of more soluble cations and/or precipitation of Si +/- Al, Ti, Cr from fluids. Coprecipitation of Ge-rich phases with Si occurred in the western area only; high water:rock is indicated. Pancam multispectral observations indicate higher nanophase ferric oxide contents, but the rocks have lower Fe contents. The highly localized nature of the red zones indicate they cannot be the source of the widespread smectite signature observed from orbit. (2) Outcrops separated by approximately 65 m show common compositional changes between brushed and abraded (approximately 1 mm deep) targets: increases in S and Mg; decreases in Al, Cl and Ca. These changes are likely due to relatively recent, surface-related alteration of valley rocks and formation of surface coatings under low water:rock. (3) One target, from the center of a region of strong CRISM smectite signature, shows modest differences in composition (higher Si, K; lower Mn) compared to most Marathon Valley rocks, while another target approximately 40 cm away on the same outcrop does not; a change towards smectite bulk compositions is not observed. The smectite signature likely resulted from alteration under low water:rock such that primary minerals were partially altered to phyllosilicates, but wholesale leaching of cations by fluids did not occur.

Description: The petrographic study of Itokawa particle, RA-QD02-0127 has been performed by SEM-EDS and optical microscope observations. The purpose of this study is to understand better the metamorphic and impact shock history of asteroid Itokawa, and other S-class asteroids.

Description: This year marks the 40th year anniversary for the Antarctic Search for Meteorite (ANSMET) program. In 1976, the ANSMET program led the first expedition to Antarctica. The ANSMET program is a US-led field-based science project that recovers meteorite samples from Antarctica. Once a year from late November to late January, a field team consisting of 8 to 12 people, spends 6-8 weeks camping on the ice and collecting meteorites. Since 1976, more than 22,000 meteorite samples have been recovered. These meteorites come from asteroids, planets and other bodies of the solar system. Once collected, the Antarctic meteorites are shipped to NASA/Johnson Space Center (JSC) Houston, TX. in a refrigerated truck and are kept frozen to minimize oxidation until they are ready for initial processing. In Antarctica each meteorite is given a field tag which consists of numbers, once in the lab, this is replaced by an official tag, consisting of the Antarctic field location and year collected. The types and numbers of meteorites that have been classified include 849 carbonaceous chondrites, 135 enstatites, 512 achondrites, 64 stony, 115 irons, 48 others (27 R chondrites, 7 ungrouped), 6,161 H chondrites, 7,668 L chondrites, and 4,589 LL chondrites. Although 80-85 percent of the collected meteorites fall in the ordinary chondrite group, the other approximately 15 percent represent rare types of achondrites and carbonaceous chondrites. These rare meteorites include 25 lunar meteorites, 15 Martian meteorites, scores of various types of carbonaceous chondrites, and unique achondrites. The Antarctic meteorites that have been collected are processed in the Meteorite Processing Lab at JSC in Houston, TX. Initial processing of the meteorites begins with thawing/drying the meteorites in a nitrogen glove box for 24 to 48 hours. The meteorites are then photographed, measured, weighed and a description of the interior and exterior of each meteorite is written. The meteorite is broken and a representative sample, either a 1-3 gram chip or thin section is sent to the Smithsonian Institution for classification. After Antarctic meteorites have been classified and approved by the Nomenclature Committee of the Meteoritical Society, they are announced in the Antarctic Meteorite Newsletter, which is published twice per year (fall and spring) so that scientists may review which meteorites are available to study. Requests for Antarctic Meteorite samples are welcomed from research scientists, regardless of their current state of funding for meteorite studies. Since its inception over 3,300 requests have been made for pieces of these meteorites and over 400 investigators worldwide are active in the study of meteorites.. Research on these samples has been published in more than1500 peer reviewed articles; a listing of papers for any meteorite sample can be generated by accessing http://curator.jsc.nasa.gov/antmet/referencesearch.cfm. Antarctic meteorite samples requested by scientists are prepared several different ways. Most samples are prepared as chips, either using a rock splitter or using a chisel and chipping bowl. In special situations, a researcher may request a meteorite slab in which case the samples are cut using a diamond-bladed bandsaw inside of a dry nitrogen glove box. The meteorites are always cut in a 100 percent liquid-free environment. Additionally, thin/thick sections of Antarctic meteorites are also prepared at JSC. The meteorite thin section lab at JSC can prepare standard 30-micron thin sections, thick sections of variable thickness (100 to 200 microns), or demountable sections using superglue, all section are prepared without using water. Although many of the techniques used back in the '70's are still used today, advances in computers, software, databases, available tools and instrumentation have helped to streamline and shorten the duration of the classification process. In conjunction with present day missions to asteroids and other planets, meteorite studies have not only led to a better understanding of the complex histories of these bodies but have also tied certain meteorite groups to particular asteroid bodies. New meteorite discoveries by the ANSMET program provide a cost effective method for obtaining samples of previously unsampled bodies, allowing scientists to learn more about the origin, composition, and evolution of the solar system. Preservation in our cleanrooms at NASA allows material to be archived for future generations and advances in instrumentation and analysis.

Description: The Mars Science Laboratory rover, Curiosity, landed at Gale crater in August 2012 and has been investigating a sequence of dominantly fluviolacustrine sediments deposited 3.6-3.2 billion years ago. Curiosity collects quantitative mineralogical data with the CheMin XRD/XRF instrument and quantitative chemical data with the APXS and ChemCam instruments. These datasets show stratigraphic mineralogical and geochemical variability that suggest a complex aqueous history. The Murray Formation, primarily composed of fine-laminated mudstone, has been studied in detail since the arrival at the Pahrump Hills in September 2014. CheMin data from four samples show variable amounts of iron oxides, phyllosilicates, sulfates, amorphous and crystalline silica, and mafic silicate minerals. Geochemical data throughout the section show that there is significant variability in Zn, Ni, and Mn concentrations. Mineralogical and geochemical trends with stratigraphy suggest one of possibly several aqueous episodes involved alteration in an open system under acidic pH, though other working hypotheses may explain these and other trends. Data from the Murray Formation contrast with those collected from the Sheepbed mudstone located approximately 60 meters below the base of the Murray Formation, which showed evidence for diagenesis in a closed system at circumneutral pH. Ca-sulfates filled late-stage veins in both mudstones.

Description: I will describe water we have found in 4.5 billion year old extraterrestrial salt, and the organics that are also present. We hypothesize that organics being carried through the parent body of the halite have been deposited adjacent to the fluid inclusions, where they have been preserved against any thermal metamorphism. We are making bulk compositional, carbon and hydrogen isotopic measurements of solid organic phases associated with the aqueous fluid inclusions in the meteorites. We will compare these organics with those found in chondrites and Wild-2 comet coma particles to determine whether these classes of organics had an origin within aqueous solutions.

Description: Atmospheric aerosols on Mars are critical in determining the nature of its thermal structure, its large-scale circulation, and hence the overall climate of the planet. We conduct multi-annual simulations with the latest version of the NASA Ames Mars global climate model (GCM), gcm2.3+, that includes a modernized radiative-transfer package and complex water-ice cloud microphysics package which permit radiative effects and interactions of suspended atmospheric aerosols (e.g., water ice clouds, water vapor, dust, and mutual interactions) to influence the net diabatic heating. Results indicate that radiatively active water ice clouds profoundly affect the seasonal and annual mean climate. The mean thermal structure and balanced circulation patterns are strongly modified near the surface and aloft. Warming of the subtropical atmosphere at altitude and cooling of the high latitude atmosphere at low levels takes place, which increases the mean pole-to-equator temperature contrast (i.e., "baroclinicity"). With radiatively active water ice clouds (RAC) compared to radiatively inert water ice clouds (nonRAC), significant changes in the intensity of the mean state and forced stationary Rossby modes occur, both of which affect the vigor and intensity of traveling, synoptic period weather systems. Such weather systems not only act as key agents in the transport of heat and momentum beyond the extent of the Hadley circulation, but also the transport of trace species such as water vapor, water ice-clouds, dust and others. The northern hemisphere (NH) forced Rossby waves and resultant wave train are augmented in the RAC case: the modes are more intense and the wave train is shifted equatorward. Significant changes also occur within the subtropics and tropics. The Rossby wave train sets up, combined with the traveling synoptic-period weather systems (i.e., cyclones and anticyclones), the geographic extent of storm zones (or storm tracks) within the NH. A variety of circulation features will be presented which indicate contrasts between the RAC and nonRAC cases, and which highlight key effects radiatively-active clouds have on physical and dynamical processes active in the current climate of Mars.

Description: The CO2 cycle is one of the three controlling climate cycles on Mars. One aspect of the CO2 cycle that is not yet fully understood is the existence of a residual CO2 ice cap that is offset from the south pole. Previous investigations suggest that the atmosphere could control the placement of the south residual cap (e.g., Colaprete et al., 2005). These investigations show that topographically forced stationary eddies in the south during southern hemisphere winter produce colder atmospheric temperatures and increased CO2 snowfall over the hemisphere where the residual cap resides. Since precipitated CO2 ice produces higher surface albedos than directly deposited CO2 ice, it is plausible that CO2 snowfall resulting from the zonally asymmetric atmospheric circulation produces surface ice albedos high enough to maintain a residual cap only in one hemisphere. Our current work builds on these initial investigations with a version of the NASA Ames Mars Global Climate Model (GCM) that includes a sophisticated CO2 cloud microphysical scheme. Processes of cloud nucleation, growth, sedimentation, and radiative effects are accounted for. Simulated results thus far agree well with the Colaprete et al. studythe zonally asymmetric nature of the atmospheric circulation produces enhanced snowfall over the residual cap hemisphere throughout much of the winter season. However, the predicted snowfall patterns vary significantly with season throughout the cap growth and recession phases. We will present a detailed analysis of the seasonal evolution of the predicted atmospheric circulation and snowfall patterns to more fully evaluate the hypothesis that the atmosphere controls the placement of the south residual cap.

Description: Wintertime transient baroclinic eddies in the northern midlatitudes of Mars were identified in Viking Lander 2 (VL2, 48.3N, 134.0E) surface pressure data back in the early 1980s. Here we report the results of an analysis of REMS surface pressure data acquired by the Curiosity Rover in Gale Crater (4.5S, 137.4E) that suggests the meridional scale of these eddies is so large that the disturbances in the surface pressure fields they create extend across the equator and into the southern hemisphere. A power spectrum analysis of the seasonally detrended REMS pressure data from Ls=240-280 shows dominant periods of ~ 6 sols and ~2.2 sols (though with greatly reduced power) which are close the dominant periods of the transient eddies observed by VL2 at this season. Analysis of the surface pressure fields from the Ames Mars GCM for the same season also shows dominant periods at the grid points closest to VL2 and Gale Crater similar to those observed. In the model, the disturbances responsible for these oscillations are eastward traveling baroclinic eddies whose amplitudes are greatest at northern mid latitudes at this season, but whose meridional extent does indeed extend into the low latitudes of the southern hemisphere. REMS appears to be seeing the signature of these eddies, not only for this season but for the early fall and late winter seasons as well. While orbital images of the so called flushing storms, which more closely correspond to the shorter period waves, show dust-lifting frontal systems that cross the equator, REMS data - even though acquired at a longitude of comparatively weak storm activity - provide the first in-situ evidence that northern hemisphere transient eddies can be detected at the surface in low latitudes of the southern hemisphere.

Description: NASA's Resource Prospector (RP) project intends to characterize the 3D distribution of volatiles in permanently shadowed regions at the lunar poles. One RP remote sensing instrument is a near-infrared spectrometer with an associated camera and radiometer, called the Near-InfraRed Volatile Spectrometer System (NIRVSS). In May 2016, NIRVSS, a Honeybee Robotics drill, and an Inficon mass spectrometer were placed in a vacuum chamber at Glenn Research Center. Also inside was a tube (1.2 m high x 25 cm diameter) filled with lunar simulant NU-LHT-3M, initially doped with a homogeneous water abundance of ~5%, chilled to cryogenic temperatures and exposed to a vacuum (~10e-6 Torr). During drilling, the NIRVSS instruments observed the cuttings pile as subsurface materials were emplaced on the surface. Spectral features associated with water ice, near 2000 and 3000 nm, were measured by the spectrometer during drilling. The spectral data documents development of a desiccated soil layer in the tube down to ~25-30 cm (confirmed by post-test soil analyses), formed during the initial pump down to vacuum. Drilling occurred in 10 cm segments, with the drill stem extracted and flutes brushed after each 10 cm depth. One exception to this was the 40 cm depth segment where the soil was delivered to a sample capture mechanism, and sealed for post-test analyses. To ~30 cm depth the greatest 2000 and 3000 nm signatures were associated with brushing of the drill flutes above the surface. At depths 〉40 cm the strongest ice signatures were associated with the drill clearing soil from the existing hole, or beginning to encounter new material. For these greater depths, brushing the flutes after extraction produced much weaker ice signatures than for shallower depths. This suggests that the soil may remain trapped in the exit funnel and is not emplaced on the surface. After each event creating strong ice signatures, these signatures decreased to near background levels in 5 minutes or less, due to surface exposure to vacuum.

Description: Develop and incorporate a liquid water cycle into the NASA Ames Research Center (ARC) Mars Global Climate Model (GCM).

Description: No abstract available

Description: No abstract available

Description: No abstract available

Description: Planetary rovers navigate in extreme environments for which a Global Positioning System (GPS) is unavailable, maps are restricted to relatively low resolution provided by orbital imagery, and compass information is often lacking due to weak or not existent magnetic fields. However, an accurate rover localization is particularly important to achieve the mission success by reaching the science targets, avoiding negative obstacles visible only in orbital maps, and maintaining good communication connections with ground. This paper describes a horizon solution for precise rover orientation estimation. The detected horizon in imagery provided by the on board navigation cameras is matched with the horizon rendered over the existing terrain model. The set of rotation parameters (roll, pitch yaw) that minimize the cost function between the two horizon curves corresponds to the rover estimated pose.

Description: Data from NASA's New Horizons encounter with Pluto in July 2015 revealed an astoundingly complex world. The surface seen on the encounter hemisphere ranged in age from ancient to recent. A vast craterless plain of slowly convecting solid nitrogen resides in a deep primordial impact basin, reminiscent of young enigmatic deposits in Mars' Hellas basin. Like Mars, regions of Pluto are dominated by valleys, though the Pluto valleys are thought to be carved by nitrogen glaciers. Pluto has fretted terrain and halo craters. Pluto is cut by tectonics of several different ages. Like Mars, vast tracts on Pluto are mantled by dust and volatiles. Just as on Mars, Pluto has landscapes that systematically vary with latitude due to past and present seasonal (and mega-seasonal) effects on two major volatiles. On Mars, those volatiles are H2O and CO2; on Pluto they are CH4 and N2. Like Mars, some landscapes on Pluto defy easy explanation. In the Plutonian arctic there is a region of large (approx. 40 km across) deep (approx. 3-4 km) pits that probably could not be formed by sublimation, or any other single process, alone. Equally bizarre is the Bladed terrain, which is composed of fields of often roughly aligned blade-like ridges covering the flanks and crests of broad regional swells. Topping the unexpected are two large mounds approximately150 km across, approx. 5-6 km high, with great central depressions at their summits. The central depressions are almost as deep as the mounds are tall. These mounds have many of the characteristics of volcanic mountains seen on Mars and elsewhere in the inner solar system. Hypotheses for the formation of these Plutonian mounds so far all have challenges, principally revolving around the need for H2O ice to support their relief and the difficulty imagining mechanisms that would mobilize H2O. From the perspective of one year after the encounter, our appreciation of the extent of Pluto's diversity and complexity is quite reminiscent of the perspective the science community had of Mars, with similar quality data sets, soon after the early reconnaissance of that planet in the late 1960s and early 70s. So certainly in this sense, Pluto is the new Mars.

Description: A multi-discipline team of experts from the National Aeronautics and Space Administration (NASA) developed Mars surface power system point design solutions for two conceptual missions to Mars using In-situ resource utilization (ISRU). The primary goal of this study was to compare the relative merits of solar- versus fission-powered versions of each surface mission. First, the team compared three different solar-power options against a fission power system concept for a sub-scale, uncrewed demonstration mission. This pathfinder design utilized a 4.5 meter diameter lander. Its primary mission would be to demonstrate Mars entry, descent, and landing techniques. Once on the Martian surface, the landers ISRU payload would demonstrate liquid oxygen propellant production from atmospheric resources. For the purpose of this exercise, location was assumed to be at the Martian equator. The three solar concepts considered included a system that only operated during daylight hours (at roughly half the daily propellant production rate of a round-the-clock fission design), a battery-augmented system that operated through the night (matching the fission concepts propellant production rate), and a system that operated only during daylight, but at a higher rate (again, matching the fission concepts propellant production rate). Including 30% mass growth allowance, total payload masses for the three solar concepts ranged from 1,128 to 2,425 kg, versus the 2,751 kg fission power scheme. However, solar power masses increase as landing sites are selected further from the equator, making landing site selection a key driver in the final power system decision. The team also noted that detailed reliability analysis should be performed on daytime-only solar power schemes to assess potential issues with frequent ISRU system on/off cycling.

Description: C-class asteroids frequently exhibit reflectance spectra consistent with thermally metamorphosed carbonaceous chondrites, or a mixture of phyllosilicate-rich material along with regions where they are absent. One particularly important example appears to be asteroid 162173 Ryugu, the target of the Hayabusa 2 mission, although most spectra of Ryugu are featureless, suggesting a heterogeneous regolith. Here we explore an alternative cause of dehydration of regolith of C-class asteroids - impact shock melting. Impact shock melting has been proposed to ex-plain some mineralogical characteristics of CB chondrites, but has rarely been considered a major process for hydrous carbonaceous chondrites.

Description: A variety of processes have been considered possibly contributing the volatiles including noble gases to the atmospheres of the terrestrial planets (e.g., [1-3]). Special consideration has been given to the concept of accretion of volatile-rich materials by the forming planets. This might include infalling planetesimals and dust, and could include material from the outer asteroid belt, as well as cometary material from the outer solar system. Currently, the dominant source of extraterrestrial material accreted by the Earth is represented by micrometeorites (MMs) with sizes mostly in the 100-300 micron range [3, 4]). Their role has been assessed by [3], who conclude that accretion of early micrometeorites played a major role in the formation of the terrestrial atmosphere and oceans. We have therefore set out to investigate in more detail the inventory of noble gases in MMs. Here we summarize some of our results obtained on MMs collected in micrometeorite traps of the Transantarctic Mountains [5].

Description: No abstract available

Description: No abstract available

Description: No abstract available

Description: No abstract available

Description: Lunar Polar Volatiles: Permanently shadowed craters at the lunar poles contain water, 5 wt according to LCROSS. Interest in water for ISRU applications. Desire to ground truth water using surface prospecting e.g. Resource Prospector and RESOLVE. How to access subsurface water resources and accurately measure quantity. Excavation operations and exposure to lunar environment may affect the results. Volatile capture tests: A series a ground based dirty thermal vacuum tests are being conducted to better understand the subsurface sampling operations. Sample removal and transfer. Volatiles loss during sampling operations. Concept of operations, Instrumentation. This presentation is a progress report on volatiles capture results from these tests with lunar polar drill prototype hardware.

Description: Mars Design Reference Architecture 5.0:Lists in-situ resource utilization (ISRU) as enabling for robust human Mars missionsLO2LCH4 ascent propulsion 25,000 kg oxygen from atmosphere for ascent and life support Atmospheric based ISRU processes less operationally complex than surface based limited concept evaluation to date and Mars surface water property and distribution uncertainty would not allow [Mars soil water processing] to be base lined at this time Limited Concept Evaluation to Date Lunar regolith O2 extraction processing experience Lunar regolith is fluidized and heated to high temperatures with H2 to produce H2O from iron-bearing minerals Mars similarity concept: Soil placed in fluidized bed reactor Heated to moderate temperatures Inert gas flow used to fluidize the bed and help with water desorption Challenges: High-temperature dusty seals Working gas requires downstream separation and recycling to reduce consumables loss Batch process heating thermally inefficient.

Description: Seismicity estimates play an important role in creating regional geological characterizations, which are useful for understanding a planet's formation and evolution, and are of key importance to site selection for landed missions. Here we investigate the regional effects of seismicity in planetary environments with the goal of determining whether such surface features on the Moon, could be triggered by fault motion.

Description: Introduction: Seismicity estimates play an important role in creating regional geological characterizations, which are useful for understanding a planet's formation and evolution, and of key importance to site selection for landed missions. Here we investigate the regional effects of lunar seismicity with the goal of determining whether surface features such as landslides and boulder trails on the Moon are triggered by fault motion.

Description: When planet-hosting stars evolve off the main sequence and go through the red-giant branch, the stars become orders of magnitudes more luminous and, at the same time, lose mass at much higher rates than their main sequence counterparts. Accordingly, if planetary companions exist around these stars at orbital distances of a few au, they will be heated up to the level of canonical hot Jupiters and also be subjected to a dense stellar wind. Given that magnetized planets interacting with stellar winds emit radio waves, such "Red-Giant Hot Jupiters" (RGHJs) may also be candidate radio emitters. We estimate the spectral auroral radio intensity of RGHJs based on the empirical relation with the stellar wind as well as a proposed scaling for planetary magnetic fields. RGHJs might be intrinsically as bright as or brighter than canonical hot Jupiters and about 100 times brighter than equivalent objects around main-sequence stars. We examine the capabilities of low-frequency radio observatories to detect this emission and find that the signal from an RGHJ may be detectable at distances up to a few hundred parsecs with the Square Kilometer Array.

Description: A variety of mineralogical and geochemical indicators for aqueous alteration on Mars have been identified by a combination of surface and orbital robotic missions, telescopic observations, characterization of Martian meteorites, and laboratory and terrestrial analog studies. Acid sulfate alteration has been identified at all three landing sites visited by NASA rover missions (Spirit, Opportunity, and Curiosity). Spirit landed in Gusev crater in 2004 and discovered Fe-sulfates and materials that have been extensively leached by acid sulfate solutions. Opportunity landing on the plains of Meridiani Planum also in 2004 where the rover encountered large abundances of jarosite and hematite in sedimentary rocks. Curiosity landed in Gale crater in 2012 and has characterized fluvial, deltaic, and lacustrine sediments. Jarosite and hematite were discovered in some of the lacustrine sediments. The high elemental abundance of sulfur in surface materials is obvious evidence that sulfate has played a major role in aqueous processes at all landing sites on Mars. The sulfate-rich outcrop at Meridiani Planum has an SO3 content of up to 25 wt.%. The interiors of rocks and outcrops on the Columbia Hills within Gusev crater have up to 8 wt.% SO3. Soils at both sites generally have between 5 to 14 wt.% SO3, and several soils in Gusev crater contain around 30 wt.% SO3. After normalization of major element compositions to a SO3-free basis, the bulk compositions of these materials are basaltic, with a few exceptions in Gusev crater and in lacustrine mudstones in Gale crater. These observations suggest that materials encountered by the rovers were derived from basaltic precursors by acid sulfate alteration under nearly isochemical conditions (i.e., minimal leaching). There are several cases, however, where acid sulfate alteration minerals (jarosite and hematite) formed in open hydrologic systems, e.g., in Gale crater lacustrine mudstones. Several hypotheses have been suggested for the aqueous formation of sulfate-bearing phases under acidic conditions on the surface of Mars including (1) sulfuric acid weathering of basaltic materials; (2) oxidative weathering of ultramafic igneous rocks containing sulfides; (3) acid fog weathering of basaltic materials, and (4) near-neutral pH subsurface solutions rich in Fe2(+) that were rapidly oxidized to Fe3(+), which produced excess acidity as iron was oxidized on exposure to O2 or photo-oxidized by ultraviolet radiation at the martian surface. Next, we briefly describe evidence for these hypothesis.

Description: At the time of publication of New Views of the Moon, it was thought that the Moon was bone dry with less than about 1 ppb H2O. However in 2007, initial reports at the 38th Lunar and Planetary Science Conference speculated that H-species were present in both apatites and pyroclastic volcanic lunar glasses. These early reports were later confirmed through peer-review, which motivated many subsequent studies on magmatic volatiles in and on the Moon within the last decade. Some of these studies have cast into question the post-Apollo view of lunar formation, the distribution and sources of volatiles in the Earth-Moon system, and the thermal and magmatic evolution of the Moon. The mineral apatite has been one of the pillars of this new field of study, and it will be the primary focus of this abstract. Although apatite has been used both to understand the abundances of volatiles in lunar systems as well as the isotopic compositions of those volatiles, the focus here will be on the abundances of F, Cl, and H2O. This work demonstrates the utility of apatite in advancing our understanding of lunar volatiles, hence apatite should be among the topics covered in the endogenous lunar volatile chapter in NVM II. Truncated ternary plot of apatite X-site occupancy (mol%) from highlands apatite and mare basalt apatite plotted on the relative volatile abundance diagram from. The solid black lines delineate fields of relative abundances of F, Cl, and H2O (on a weight basis) in the melt from which the apatite crystallized. The diagram was constructed using available apatite/melt partitioning data for fluorine, chlorine, and hydroxyl.

Description: The leading hypothesis for the origin of the Moon is the giant impact model, which grew out of the post-Apollo science community. The hypothesis was able to explain the high E-M system angular momentum, the small lunar core, and consistent with the idea that the early Moon melted substantially. The standard hypothesis requires that the Moon be made entirely from the impactor, strangely at odds with the nearly identical oxygen isotopic composition of the Earth and Moon, compositions that might be expected to be different if Moon came from a distinct impactor. Subsequent geochemical research has highlighted the similarity of both geochemical and isotopic composition of the Earth and Moon, and measured small but significant amounts of volatiles in lunar glassy materials, both of which are seemingly at odds with the standard giant impact model. Here we focus on key geochemical measurements and spacecraft observations that have prompted a healthy re-evaluation of the giant impact model, provide an overview of physical models that are either newly proposed or slightly revised from previous ideas, to explain the new datasets.

Description: The Moon contains broad and isolated areas of plains that have been recognized as mare, cryptomare, impact ejecta, or impact melt. These deposits have been extensively studied on the lunar nearside by remote sensing via telescopes and numerous spacecraft, and in some cases, in situ robotically and by astronauts. Only recently have the deposits on the entire farside been able to be observed and evaluated to the same degree. There are spatially extensive plains deposits located throughout the lunar farside highlands whose formation has remained ambiguous. Many of the plains deposits in the lunar farside highlands display higher albedos than mare materials. Some deposits are located in close proximity to relatively younger impact craters suggesting that plains could be composed of cryptomare or ejecta materials. Some deposits are within the range in which ejecta from large basin-forming events (e.g., SPA and Orientale) likely distributed large amounts of ejecta across the surface. Here we are conducting a series of observations and models in order to resolve the nature and origin of lunar farside plains deposits. Understanding these plains is important for understanding the volcanic and impact histories of the lunar farside, and is important for future mapping and thermal modeling studies.

Description: The Resource Prospector is an in-situ resource utilization (ISRU) technology demonstration mission, planned for a 2021 launch to search for and analyze volatiles at the Lunar South Pole. The mission poses unique operational challenges. Operating at the Lunar South Pole requires navigating a surface with lighting, shadow and regolith characteristics unlike those of previous missions. The short round trip communications time enables reactive surface operations for science and engineering. Navigation of permanently shadowed regions with a solar powered rover creates risks, including power and thermal management, and requires constant real time decision making for safe entry, path selection and egress. The mission plan requires a faster rover egress from the lander than any previous NASA rover mission.

Description: The FINESSE (Field Investigations to Enable Solar System Science and Exploration) team of NASA's Solar System Exploration Research Virtual Institute (SSERVI) is focused on a science and exploration field-based research program aimed at generating strategic knowledge in preparation for the human and robotic exploration of the Moon, Near Earth Asteroids, and the moons of Mars. The FINESSE science program is infused with leading edge exploration concepts since "science enables exploration and exploration enables science." The FINESSE education and public outreach program leverages the team's field investigations and educational partnerships to share the excitement of lunar, Near Earth Asteroid, and martian moon science and exploration locally, nationally, and internationally. The FINESSE education plan is in line with all of NASA's Science Mission Directorate science education objectives, particularly to enable STEM (science, technology, engineering, and mathematics) education and leverage efforts through partnerships.

Description: No abstract available

Description: Recent reflectance data from LRO instruments suggest water ice and other volatiles may be present on the surface in lunar permanently shadowed regions, though the detection is not yet definitive. Understanding the composition, quantity, distribution, and form of water and other volatiles associated with lunar permanently shadowed regions (PSRs) is identified as a NASA Strategic Knowledge Gap (SKG) for Human Exploration. These polar volatile deposits are also scientifically interesting, having the potential to reveal important information about the delivery of water to the Earth-Moon system.

Description: Since these techniques are very new and as they have never been used or this purpose. they will need to be replicated by several independent studies. These techniques may be very important if the optical imaging encounters difficulties, for example, if a sample is made of very dark or monochromatic material and in the case of very deep pits (〉500 microns) Based on the preliminary results, the LIBS continuum technique is more appropriate to the large pits produced by long ablations The relationship may work best homogeneous samples, but the continuum is collected with every LIBS analysis so does not require any addition to the experimental suite of techniques. The integration of a QCMB in the ablation chamber may be a very interesting solution to determine the ablated mass. Even if it only measures a fraction of the total mass, its sensitivity should be able to weigh hundreds of nanograms accumulated on the crystal during ablation and relate it to the actual ablated mass. In the future. these options may help in situ K-Ar dating to give the age of the rock with the best accuracy and precision.

Description: No abstract available

Description: The Dhofar 961 lunar meteorite was found in 2003 in Oman. It is texturally paired with Dhofar 925 and Dhofar 960 (though Dhofar 961 is more mafic and richer in incompatible elements). Several lines of reasoning point to the South Pole-Aitken Basin (SPA) basin as a plausible source (Figure 2): Mafic character of the melt-breccia lithic clasts consistent the interior of SPA, rules out feldspathic highlands. Compositional differences from Apollo impact-melt groups point to a provenance that is separated and perhaps far distant from the Procellarum KREEP Terrane SPA "hot spots" where Th concentrations reach 5 ppm and it has a broad "background" of about 2 ppm, similar to lithic clasts in Dhofar 961 subsamples If true, impact-melt lithologies in this meteorite may be unaffected by the Imbrium-forming event that is pervasively found in our Apollo sample collection, and instead record the early impact history of the Moon.

Description: The origin of the martian moons Phobos and Deimos is obscure and enigmatic. Hypotheses include the capture of small bodies originally from the outer main belt or beyond, residual material left over from Mars' formation, and accreted ejecta from a large impact on Mars, among others. Measurements of reflectance spectra indicate a similarity to low-albedo, red D-type asteroids, but could indicate a highly space-weathered veneer. Here we suggest a way of constraining the near-surface composition of the two moons, for comparison with known meteoritic compositions. Neutron spectroscopy, particularly the thermal and epithermal neutron flux, distinguishes clearly between various classes of meteorites and varying hydrogen (water) abundances. Perhaps most surprising of all, a rendezvous with Phobos or Deimos is not necessary to achieve this. Multiple flybys suffice.

Description: Apatite is a common mineral in terrestrial, planetary, and asteroidal materials. It is commonly used for geochronology (U-Pb), sensing volatiles (H, F, Cl, S), and can concentrate rare earth elements (REE) during magmatic fractionation and in general. Some recent studies have shown that some kinds of phosphate may fractionate Hf and W and that Mn may be redox sensitive. Experimental studies have focused on REE and other lithophile elements and at simplified or not specified oxygen fugacities. There is a dearth of partitioning data for chalcophile, siderophile and other elements between apatite and melt. Here we carry out several experiments at variable fO2 to study the partitioning of a broad range of trace elements. We compare to existing data and then focus on several elements that exhibit redox dependent partitioning behavior.

Description: Germanium is a moderately volatile and siderophile element that follows silicon in its compatibility during partial melting of planetary mantles. Despite its obvious usefulness in planetary geochemistry germanium is not analyzed routinely, with there being only three prior studies reporting germanium abundances in Martian meteorites. The broad range (1-3 ppm) observed in Martian igneous rocks is in stark contrast to the narrow range of germanium observed in terrestrial basalts (1.5 plus or minus 0.1 ppm). The germanium data from these studies indicates that nakhlites contain 2-3 ppm germanium, while shergottites contain approximately 1 ppm germanium, a dichotomy with important implications for core formation models. There have been no reliable germanium abundances on chassignites. The ancient meteoritic breccia, NWA 7533 (and paired meteorites) contains numerous clasts, some pristine and some impact melt rocks, that are being studied individually. Because germanium is depleted in the Martian crust relative to chondritic impactors, it has proven useful as an indicator of meteoritic contamination of impact melt clasts in NWA 7533. The germanium/silicon ratio can be applied to minerals that might not partition nickel and iridium, like feldspars. We report germanium in minerals from the 3 known chassignites, 2 nakhlites and 5 shergottites by LAICP- MS using a method optimized for precise germanium analysis.

Description: Highly siderophile elements (HSE = Au, Re, and the Pt-group elements) are tracers of silicate / metal interactions during planetary processes. Since most core-formation models involve some state of equilibrium between liquid silicate and liquid metal, understanding the partioning of highly siderophile elements (HSE) between silicate and metallic melts is a key issue for models of core / mantle equilibria and for core formation scenarios. However, partitioning models for HSE are still inaccurate due to the lack of sufficient experimental constraints to describe the variations of partitioning with key variable like temperature, pressure, and oxygen fugacity. In this abstract, we describe a self-consistent set of experiments aimed at determining the valence of platinum, one of the HSE, in silicate melts. This is a key information required to parameterize the evolution of platinum partitioning with oxygen fugacity.

Description: Numerical models of differentiation of a global-scale lunar magma ocean (LMO) have raised as many questions as they have answered. Recent orbital missions and sample studies have provided new context for a large range of lithologies, from the comparatively magnesian "purest anorthosite" reported by to Si-rich domes and spinel-rich clasts with widespread areal distributions. In addition, the GRAIL mission provided strong constraints on lunar crustal density and average thickness. Can this increasingly complex geology be accounted for via the formation and evolution of the LMO? We have in recent years been conducting extensive sets of petrologic experiments designed to fully simulate LMO crystallization, which had not been attempted previously. Here we review the key results from these experiments, which show that LMO differentiation is more complex than initial models suggested. Several important features expected from LMO crystallization models have yet to be reproduced experimentally; combined modelling and experimental work by our group is ongoing.

Description: The South Pole-Aitken (SPA) basin is the stratigraphically oldest identifiable lunar basin and is therefore one of the most important targets for absolute age-dating to help understand whether ancient lunar bombardment history smoothly declined or was punctuated by a cataclysm. The SPA basin also has another convenient property, a geochemically distinct interior, unobscured by extensive mare basalt fill. A case has been made for the possible origin of the Dhofar 961 lunar meteorite in the South Pole-Aitken (SPA) basin, based on comparing its composition with Lunar Prospector gamma-ray data for the interior of the SPA basin. Dhofar 961 contains several different impact-melt (IM) lithologies. Jolliff et al. described two classes of mafic impact-melt lithologies, one dominated by olivine (Lithology A) and the other by plagioclase (An 95-96.5) (Lithology B). Broad-beam analyses of these lithologies yielded (is) approximately 14.0 wt% FeO, 11.7 wt% MgO, and 15.4 wt% Al2O3. Lithologies A and B differ by approximately 2.5% Al2O3, 1.5% FeO and 1.5% MgO, consistent with the occurrence of olivine phenocrysts in A and plagioclase clasts in B. Both lithologies are considerably more mafic than the Apollo mafic impact-melt breccias, corresponding to olivine gabbronorite. Joy et al. used U-Pb dating to investigate phosphate fragments in the Dhofar 961 matrix and impact-melt clasts. Matrix phosphates have 4.34 to 4 Ga ages, consistent with ancient KREEP-driven magmatic episodes and Pre-Nectarian ((is) greater than 3.92 Ga). Phosphates found within Dhofar 961 crystalline impact melt breccia clasts range from 4.26 to 3.89 Ga, potentially recording events throughout the basin forming epoch of lunar history. The youngest reset ages in the Dhofar 961 sample represent an upper limit for the time of formation of the meteorite. Joy et al suggested this age represents the final impact that mixed and consolidated several generations of precursor rocks into the Dhofar meteorite group, although they note that further age dating of all the stones is required to test this hypothesis. We received a split of Dhofar 961 from R. Zeigler consisting of a large clast of IM Lithology B, with some light-colored, friable matrix clinging to the external margins of the impact-melt clast. This lithology was not present in the samples investigated by Joy et al. and thus does not have corresponding U-Pb ages on it. We created multiple subsplits of both the IM and matrix lithologies, each weighing several tens of micrograms. We conducted Ar-40 Ar-39 dating of this candidate SPA material by high-resolution step heating and comparing it with the regolith that surrounds it.

Description: Geochronology is a fundamental measurement for planetary samples, providing the ability to establish an absolute chronology for geological events, including crystallization history, magmatic evolution, and alteration events, and providing global and solar system context for such events. The capability for in situ geochronology will open up the ability for geochronology to be accomplished as part of lander or rover complement, on multiple samples rather than just those returned. An in situ geochronology package can also complement sample return missions by identifying the most interesting rocks to cache or return to Earth. The K-Ar radiometric dating approach to in situ dating has been validated by the Curiosity rover on Mars as well as several laboratories on Earth. Several independent projects developing in situ rock dating for planetary samples, based on the K-Ar method, are giving promising results. Among them, the Potassium (K)-Argon Laser Experiment (KArLE) at MSFC is based on techniques already in use for in planetary exploration, specifically, Laser-induced Breakdown Spectroscopy (LIBS, used on the Curiosity Chemcam), mass spectroscopy (used on multiple planetary missions, including Curiosity, ExoMars, and Rosetta), and optical imaging (used on most missions).

Description: Recent reflectance data from LRO instruments suggest water ice and other volatiles may be present on the surface in lunar permanentlyshadowed regions, though the detection is not yet definitive. Understanding the composition, quantity, distribution, and form of water and other volatiles associated with lunar permanently shadowed regions (PSRs) is identified as a NASA Strategic Knowledge Gap (SKG) for Human Exploration. These polar volatile deposits are also scientifically interesting, having the potential to reveal important information about the delivery of water to the Earth- Moon system.

Description: Mesosiderites (MES) are a group of enigmatic stony-iron meteorites exhibiting fragmental matrix breccias and irregular textures; e.g. [1-3]. Mesosiderites contain roughly equal volumes metal (Fe-Ni) and silicates often intimately mixed together (Fig.1). The silicates mostly consist of basaltic, gabbroic, and pyroxenitic components, and appear similar to eucrites and howardites; [4-8]. But unlike HEDs - and other differentiated parent body meteorite groups e.g. ureilites - mesosiderites contain high metal abundances. Several studies have been published to reveal the processes leading to the formation of mesosiderites and attempt to classifiy them [1], [2], [10-15]. Because the silicate inclusions in mesosiderites are often strongly metamorphosed after formation, it is difficult to assess the origin of the silicates and implications for the differentiation process of their parent body [15-17]. Several workers have advanced a formation hypothesis for the mesosiderites where an impact between differentiated bodies occurred prior to 4.47 Ga ago (e.g. [13,18], which could explain the possible incomplete dispersal of the colliding bodies due to their low cosmic ray exposure ages and their special thermal history. However, [13] discuss and favor the model for formation of mesosiderites with the collision of two differentiated bodies, along with disruption events and gravitational re-assembly. The mesosiderites have numerous gabbroid melt clasts with anomalous rare-earth- element (REE) - especially positive Eu - values [19, 20]. HEDs do not show the same. However, the heating mechanisms of both mesosiderites and HED's are puzzling. Mesosiderites are remarkable, they consist of a mix of basalts, which are only found on or near planetary surfaces and undifferentiated metal [1,2]. The probable model is that an asteroid containing a metallic magma impacted onto a second asteroid covered with basalt [18,21]. The mix was then buried under an insulating regolith, and cooled slowly. During cooling and at low temperatures the redox reactions continued to occur and proceed (J.T. Wasson; in pers. comm. 2015).

Description: A wide diversity of planetary surfaces in the solar system represent high priority targets for in situ compositional and contextual analysis as part of future missions. The planned mission portfolio will inform our knowledge of the chemistry at play on Mars, icy moons, comets, and primitive asteroids, which can lead to advances in our understanding of the interplay between inorganic and organic building blocks that led to the evolution of habitable environments on Earth and beyond. In many of these environments, the presence of water or aqueously altered mineralogy is an important indicator of habitable environments that are present or may have been present in the past. As a result, the search for complex organic chemistry that may imply the presence of a feedstock, if not an inventory of biosignatures, is naturally aligned with targeted analyses of water-rich surface materials. Here we describe the two-step laser mass spectrometry (L2MS) analytical technique that has seen broad application in the study of organics in meteoritic samples, now demonstrated to be compatible with an in situ investigation with technique improvements to target high priority planetary environments as part of a future scientific payload. An ultraviolet (UV) pulsed laser is used in previous and current embodiments of laser desorption/ionization mass spectrometry (LDMS) to produce ionized species traceable to the mineral and organic composition of a planetary surface sample. L2MS, an advanced technique in laser mass spectrometry, is selective to the aromatic organic fraction of a complex sample, which can provide additional sensitivity and confidence in the detection of specific compound structures. Use of a compact two-step laser mass spectrometer prototype has been previously reported to provide specificity to key aromatic species, such as PAHs, nucleobases, and certain amino acids. Recent improvements in this technique have focused on the interaction between the mineral matrix and the organic analyte. The majority of planetary targets of astrobiological interest are characterized by the presence of water or hydrated mineral phases. Water signatures can indicate a history of available liquid water that may have played an important role in the chemical environment of these planetary surfaces and subsurfaces. The studies we report here investigate the influence of water content on the detectability of organics by L2MS in planetary analog samples.

Description: The Lunar Atmosphere and Dust Environment Explorer (LADEE) was an orbital lunar science mission designed to address the goals of the 2003 National Research Council decadal survey, the Lunar Exploration Analysis Group Roadmap, and the "Scientific Context for Exploration of the Moon" (SCEM) report, and has been recommended for execution by the 2011 Planetary Missions Decadal Survey. The LADEE mission goal was to determine the composition of the lunar atmosphere and investigate the processes that control its distribution and variability, including sources, sinks, and surface interactions. It will monitor variations in known gasses, such as sodium, potassium, argon and helium, and will search for other, as-yet-undetected gasses of both lunar and extra-lunar origin. Another goal of LADEE was to determine whether dust is present in the lunar exosphere, and reveal the processes that contribute to its sources and variability.

Description: Phyllosilicates on Mars are thought to have formed during Mars' earliest Noachian geologic era (approx. 4.1-3.7 Ga). Sulfate formation, on the other hand, requires more acidic conditions which are thought to have occurred later during Mars' Hesperian era (approx. 3.7-3.0 Ga). Therefore, regions on Mars where phyllosilicates and sulfates are found in close proximity to each other provide evidence for the aqueous conditions during this global transition. Both phyllosilicates and sulfates form in the presence of water and thus give clues to the aqueous history of Mars and its potential for habitability. Phyllosilicates that formed during the Noachian era would have been weathered by the prevailing acidic conditions that define the Hesperian. Therefore, the purpose of this study is to characterize the alteration products of acid-sulfate weathered phyllosilicates in laboratory experiments, focusing on the Fe/Mg-smectites commonly identified on Mars. We also compare our results to observations of phyllosilicates and sulfates on Mars in regions such as Endeavour Crater and Mawrth Vallis to understand the formation process of sulfates and constrain the aqueous history of these regions.

Description: The Mars rover Curiosity has encountered silica-enriched bedrock (as strata and as veins and associated halos of alteration) in the largely basaltic Murray Fm. of Mt. Sharp in Gale Crater. Alpha Particle X-ray Spectrometer (APXS) investigations of the Murray Fm. revealed decreasing Mg, Ca, Mn, Fe, and Al, and higher S, as silica increased (Fig. 1). A positive correlation between SiO2 and TiO2 (up to 74.4 and 1.7 wt %, respectively) suggests that these two insoluble elements were retained while acidic fluids leached more soluble elements. Other evidence also supports a silica-retaining, acidic alteration model for the Murray Fm., including low trace element abundances consistent with leaching, and the presence of opaline silica and jarosite determined by CheMin. Phosphate stability is a key component of this model because PO4 3- is typically soluble in acidic water and is likely a mobile ion in diagenetic fluids (pH less than 5). However, the Murray rocks are not leached of P; they have variable P2O5 (Fig. 1) ranging from average Mars (0.9 wt%) up to the highest values in Gale Crater (2.5 wt%). Here we evaluate APXS measurements of Murray Fm. bedrock and veins with respect to phosphate stability in acidic fluids as a test of the acidic alteration model for the Lower Mt. Sharp rocks.

Description: Meteorites falling in Antarctica are captured in ice and stored until the glacial flow transports them to the surface where they can be collected. Prior to collection, they are altered during interactions between the rock, the cryosphere, and the hydrosphere. The purpose of this study is to characterize the stable isotope values of terrestrial, secondary carbonate minerals from Ordinary Chondrite (OC) meteorites collected in Antarctica. This facilitates better understanding of terrestrial weathering in martian meteorites as well as mechanisms for weathering in cold, arid environments as an analog to Mars. OC samples were selected for analysis based upon size and collection proximity to known martian meteorites. They were also selected based on petrologic type (3+) such that they were likely to be carbonate-free before falling to Earth.

Description: Howardites are polymict breccias that, together with eucrites and diogenites (HED), likely originate from the vestan surface (regolith/ megaregolith), and display a heterogeneous distribution of eucritic and diogenitic material. Melt clasts are also present alongside other regolithic features within howardites, and are noteworthy for their compositional variability and appearance. Melt clasts formed by impact events provide a snapshot of the timings and conditions of surface gardening and bombardment on the vestan surface. By dating such clasts, we aim to better constrain the timings of impact events on Vesta, and to establish whether the impact flux in the asteroid belt was similar to that on the Moon. As the Moon is used as the basis for characterising impact models of the inner solar system, it is necessary to verify that apparent wide-scale events are seen in other planetary bodies. In particular, the observed clustering of Apollo melt clast ages between 3.8-4.0 Ga has led to two hypotheses: 1) The Moon was subjected to a sudden event - 'Lunar Cataclysm' or period of 'Late Heavy Bombardment' (LHB), 2) The age cluster represents the end of an epoch of declining bombardment or 'Heavy Bombardment. No consensus has emerged regarding one or other hypothesis. We are testing these hypotheses by seeking evidence for such events in materials other than those derived from the Moon.

Description: The origin of the martian moons Phobos and Deimos is obscure and enigmatic. Hypotheses include the capture of asteroids originally from the outer main belt or beyond, residual material left over from Mars' formation, and accreted ejecta from a large impact on Mars, among others. Measurements of reflectance spectra indicate a similarity to dark, red D-type asteroids, but could indicate a highly space-weathered veneer. Here we suggest a way of constraining the near-surface composition of the two moons, for comparison to known meteoritic compositions. Neutron spectroscopy, particularly the thermal and epithermal neutron flux, distinguishes clearly between various classes of meteorites and varying hydrogen (water) abundances. Perhaps most surprising of all, a rendezvous with Phobos or Deimos is not necessary to achieve this.

Description: Determining the composition of apatites is important to understand the behavior of volatiles during planetary differentiation. Apatite is an ubiquitous magmatic mineral in the SNC meteorites. It is a significant reservoir of halogens in these meteorites and has been used to estimate the halogen budget of Mars. Apatites have been identified in sandstones and pebbles at Gale crater by ChemCam, a Laser-Induced Breakdown Spectroscometer (LIBS) instrument onboard the Curiosity rover. Their presence was inferred from correlations between calcium, fluorine (using the CaF molecular band centered near 603 nm, whose detection limit is much lower that atomic or ionic lines and, in some cases, phosphorus (whose detection limit is much larger). An initial quantification of fluorine, based on fluorite (CaF2)/basalt mixtures and obtained at the LANL laboratory, indicated that the excess of F/Ca (compared to the stoichiometry of pure fluorapatites) found on Mars in some cases could be explained by the presence of fluorite. Chlorine was not detected in these targets, at least above a detection limit of 0.6 wt% estimated from. Fluorapatite was later also detected by X-ray diffraction (with CheMin) at a level of approx.1wt% in the Windjana drill sample (Kimberley area), and several points analyzed by ChemCam in this area also revealed a correlation between Ca and F. The in situ detection of F-rich, Cl-poor apatites contrasts with the Cl-rich, F-poor compositions of apatites found in basaltic shergottites and in gabbroic clasts from the martian meteorite NWA 7034, which were also found to be more Cl-rich than apatites from basalts on Earth, the Moon, or Vesta. The in situ observations could call into question one of the few possible explanations brought forward to explain the SNC results, namely that Mars may be highly depleted in fluorine. The purpose of the present study is to refine the calibration of the F, Cl, OH and P signals measured by the ChemCam LIBS instrument, initiated for F, for Cl in soils, for P, and estimate their limit of detection. For this purpose, different types of apatites and mixtures of basalt powder and apatites were analyzed using ChemCam Engineering Qualification Model (EQM) at IRAP, Toulouse. The present abstract presents the initial results from the laboratory analyses. Differences between the response function of the EQM and the Flight Model of ChemCam are still to be refined to apply these new results to the Martian dataset.

Description: According to Lunar Magma Ocean (LMO) theory, lunar samples that fall into the ferroan anorthosite (FAN) category represent the only samples we have of of the primordial crust of the Moon. Modeling indicates that plagioclase crystallizes after 〉70% LMO crystallization and formed a flotation crust, depending upon starting composition. The FAN group of highlands materials has been subdivided into mafic-magnesian, mafic-ferroan, anorthositic- sodic, and anorthositic-ferroan, although it is not clear how these subgroups are related. Recent radiogenic isotope work has suggested the range in FAN ages and isotopic systematics are inconsistent with formation of all FANs from the LMO. While an insulating lid could have theoretically extend the life of the LMO to explain the range of the published ages, are the FAN compositions consistent with crystallization from the LMO? As part of a funded Emerging Worlds proposal (NNX15AH76G), we examine this question through analysis of FAN samples. We compare the results with various LMO crystallization models, including those that incorporate the influence of garnet.

Description: In recent years, methane in the martian atmosphere has been detected by Earth-based spectroscopy, the Planetary Fourier Spectrometer on the ESA Mars Express mission, and the NASA Mars Science Laboratory. The methane's origin remains a mystery, with proposed sources including volcanism, exogenous sources like impacts and interplanetary dust, aqueous alteration of olivine in the presence of carbonaceous material, release from ancient deposits of methane clathrates, and/or biological activity. An additional potential source exists: meteor showers from the emission of large comet dust particles could generate martian methane via UV pyrolysis of carbon-rich infall material. We find a correlation between the dates of Mars/cometary orbit encounters and detections of methane on Mars. We hypothesize that cometary debris falls onto Mars during these interactions, generating methane via UV photolysis.

Description: The Sample Analysis at Mars (SAM) and Chemistry and Mineralogy (CheMin) instruments on the Mars Science Laboratory (MSL) have analyzed several subsamples of 〈150 micron fines from ten sites at Gale Crater. Three were in Yellowknife Bay: the Rocknest aeolian bedform (RN) and drilled Sheepbed mudstone from sites John Klein (JK) and Cumberland (CB). One was drilled from the Windjana (WJ) site on a sandstone of the Kimberly formation. Four were drilled from sites Confidence Hills (CH), Mojave (MJ), Telegraph Peak (TP) and Buckskin (BK) of the Murray Formation at the base of Mt. Sharp. Two were drilled from sandstones of the Stimson formation targeting relatively unaltered (Big Sky, BY) and then altered (Greenhorn, GH) material associated with a light colored fracture zone. CheMin analyses provided quantitative sample mineralogy. SAM's evolved gas analysis mass spectrometry (EGA-MS) detected H2O, CO2, O2, H2, SO2, H2S, HCl, NO, and other trace gases. This contribution will focus on evolved SO2. All samples evolved SO2 above 500 C. The shapes of the SO2 evolution traces with temperature vary between samples but most have at least two "peaks' within the wide high temperature evolution, from approx. 500-700 and approx. 700-860 C (Fig. 1). In many cases, the only sulfur minerals detected with CheMin were Ca sulfates (e.g., RN and GH), which should thermally decompose at temperatures above those obtainable by SAM (〉860 C). Sulfides or Fe sulfates were detected by CheMin (e.g., CB, MJ, BK) and could contribute to the high temperature SO2 evolution, but in most cases they are not present in enough abundance to account for all of the SO2. This additional SO2 could be largely associated with x-ray amorphous material, which comprises a significant portion of all samples. It can also be attributed to trace S phases present below the CheMin detection limit, or to reactions which lower the temperatures of SO2 evolution from sulfates that are typically expected to thermally decompose at temperatures outside the SAM temperature range (e.g., Ca and Mg sulfates). Here we discuss the results of SAM-like laboratory analyses targeted at understanding this last possibility, focused on understanding if reactions of HCl or an HCl evolving phase (oxychlorine phases, chlorides, etc.) and Ca and Mg sulfates can result in SO2 evolution in the SAM temperature range.

Description: Yellowknife Bay (YKB; sol 124-198) is the second site that the Mars Science Laboratory Rover Curiosity investigated in detail on its mission in Gale Crater. YKB represents lake bed sediments from an overall neutral pH, low salinity environment, with a mineralogical composition which includes Ca-sulfates, Fe oxide/hydroxides, Fe-sulfides, amorphous material, and trioctahedral phyllosilicates. We investigate whether sulfide alteration could be associated with ancient habitable microenvironments in the Gale mudstones. Some textural evidence for such alteration may be pre-sent in the nodules present in the mudstone.

Description: Angrites represent some of the earliest stages of planetesimal differentiation. Not surprisingly, there is no simple petrogenetic model for their origin. Petrogenesis has been linked to both magmatic and impact processes. Studies demonstrated that melting of chondritic material (e.g. CM, CV) at redox conditions where pure iron metal is unstable (e.g., IW+1 to IW+2) produced angrite-like melts. Alternatively, angrites were produced at more reducing conditions (〈IW) with their exotic melt compositions resulting from carbonates in the source or from nebular condensation. Clearly, understanding what role fO2 plays in producing angrite magmas is critical for deciphering their petrogenesis and extending our understanding of primordial melting of asteroids. Calculations for the fO2 conditions of angrite crystallization are limited, and only preliminary attempts been made to understand the changes in fO2 that occurred during petrogenesis. Many of the angrites have phase assemblages which provide conflicting signals about redox conditions during crystallization (e.g., Fe metal and a Fe-Ti oxide with potential Fe3+. There have been several estimates of fO2 for angrites. Most notably, experiments examined the variation of DEu/DGd with fO2, between plagioclase and fassaitic pyroxene in equilibrium with an angrite melt composition. They used their observations to estimate the fO2 of crystallization to be approximately IW+0.6 for angrite LEW 86010. This estimate is only a "snapshot" of fO2 conditions during co-crystallization of plagioclase and pyroxene. Preliminary XANES analyses of V redox state in pyroxenes from D'Orbigny reported changes in fO2 from IW-0.7 during early pyroxene crystallization to IW+0.5 during latter episodes of pyroxene crystallization [15]. As this was a preliminary report, it presented limited information concerning the effects of pyroxene orientation and composition on the V valence measurements, and the effect of melt composition on valence and partitioning behavior of V. A closer examination of fO2 as recorded by Cr valence state in olivine will allow us to test models for primordial melting of chondritic material to produce the angrite parent melts. Here, we report the our initial stages of examining the origin and conditions of primordial melting on the angrite parent body and test some of the above models by integrating an experimental study of Cr and V valence partitioning between olivine [OL] and an angrite melt, with micro-scale determinations of Cr and V oxidation state in OL in selected "volcanic" angrites.

Description: The (f)O2 [oxygen fugacity] of crystallization for martian basalts has been estimated in various studies to range from IW-1 to QFM+4 [1-3]. A striking geochemical feature of the shergottites is the large range in initial Sr isotopic ratios and initial epsilon(sup Nd) values. Studies by observed that within the shergottite group the (f)O2 [oxygen fugacity] of crystallization is highly correlated with these chemical and isotopic characteristics with depleted shergottites generally crystallizing at reduced conditions and enriched shergottites crystallizing under more oxidizing conditions. More recent work has shown that (f)O2 [oxygen fugacity] changed during the crystallization of these magmas from one order of magnitude in Y980459 (Y98) to several orders of magnitude in Larkman Nunatak 06319. These real or apparent variations within single shergottitic magmas have been attributed to mixing of a xenocrystic olivine component, volatile loss-water disassociation, auto-oxidation during crystallization of mafic phases, and assimilation of an oxidizing crustal component (e.g. sulfate). In contrast to the shergottites, augite basalts such as NWA 8159 are highly depleted yet appear to be highly oxidized (e.g. QFM+4). As a first step in attempting to unravel petrologic complexities that influence (f)O2 [oxygen fugacity] in martian magmas, this study explores the effect of (f)O2 [oxygen fugacity] on the liquid line of descent (LLD) for a primitive shergottite liquid composition (Y98). The results of this study will provide a fundamental basis for reconstructing the record of (f)O2 [oxygen fugacity] in shergottites and other martian basalts, its effect on both mineral chemistries and valence state partitioning, and a means for examining the role of crystallization (and other more complex processes) on the petrologic linkages between olivine-phyric and pyroxene-plagioclase shergottites.

Description: The Potassium (K) - Argon (Ar) Laser Experiment (KArLE) will make in situ noble-gas geochronology measurements aboard planetary robotic landers and roverss. Laser-Induced Breakdown Spectroscopy (LIBS) is used to measure the K abun-dance in a sample and to release its noble gases; the evolved Ar is measured by mass spectrometry (MS); and rela-tive K content is related to absolute Ar abundance by sample mass, determined by optical measurement of the ablated volume. KArLE measures a whole-rock K-Ar age to 10% or better for rocks 2 Ga or older, sufficient to resolve the absolute age of many planetary samples. The LIBS-MS approach is attractive because the analytical components have been flight proven, do not require further technical development, and provide complementary measurements as well as in situ geochronology.

Description: The Curiosity rover landed on Mars in August 2012 to explore the sedimentary history and to assess the habitability of Gale Crater. After 1200 sols of surface operations and over 12 km of traverse distance, the mineralogy of 10 samples has been determined by the CheMin X-ray diffractometer (XRD) and the chemical composition of nearly 300 targets has been established by the Alpha Particle X-ray Spectrometer (APXS). Light-toned fracture zones containing elevated concentrations of silica have been studied by Curiosity's instruments to determine the nature of the fluids that resulted in the enrichment of SiO2. Multiple fluid exposures are evident, and the chemistry and mineralogy data indicate at least two aqueous episodes may have occurred under acidic conditions.

Description: The possibility for multiple parent bodies, instead of a common parent body of Vesta, for eucrites has been suggested based on the variable oxygen isotopic composition observed in some eucrites.. Recently, we added an extra dimension to the discussion based on the (epsilon)54Cr composition of the same eucrites with known (delta)17O to compare with the normal eucrites. The combined (delta)17O and (epsilon)54Cr isotope systematics for Pasamonte, PCA 91007, A-881394, and Ibitira indicate their likely origin from multiple different parent bodies than the normal eucrites. Often the qualifier anomalous is used to identify HEDs with (delta)17O values that deviate significantly (〉3(sigma)) from the mean HED (delta)17O. However, variations in eucrites and diogenites also include unique geochemical characteristics such as bulk composition, trace element abundances, or volatile concentrations, in addition to (delta)17O. Here, we investigate three such geochemically anomalous HEDs: Elephant Moraine (EET) 92023, Graves Nunataks (GRA) 98098, and Dhofar 700. In addition, to verify the homogeneity of (epsilon)54Cr observed for normal HEDs thus far, a set of seven eucrites and diogenites considered normal samples were also investigated.

Description: Although the current cold, dry environment of Mars extends back through much of its history, its earliest periods experienced significant water- related surface activity. Both geomorphic features (e.g., paleolakes, deltas, and river valleys) and hydrous mineral detections (e.g., clays and salts) have historically been interpreted to imply a "warm and wet" early Mars climate. More recently, atmospheric modeling studies have struggled to produce early climate conditions with temperatures above 0degC, leading some studies to propose a "cold and icy" early Mars dominated by widespread glaciation with transient melting. However, the alteration mineralogy produced in subglacial environments is not well understood, so the extent to which cold climate glacial weathering can produce the diverse alteration mineralogy observed on Mars is unknown. This summer, we will be conducting a field campaign in a glacial weathering environment in the Cascade Range, OR in order to determine the types of minerals that these environments produce. However, we must first disentangle the effects of glacial weathering from other significant alteration processes. Here we attempt a first understanding of glacial weathering by differentiating rocks and sediments weathered by hydrothermal, pedogenic, and glacial weathering processes in the Cascades volcanic range.

Description: Over the past 40 years, estimates of the total outgassed inventory of water on Mars have ranged from a global equivalent layer (GEL) approximately 7-1000 m deep. However, Carr and Head have recently argued that it is not the total inventory of outgassed water that is important, but the amount that exists in climatically exchangeable surface and near surface reservoirs - suggesting that any exchange with water in the deep subsurface is precluded by the existence of a thick cryosphere, at least during the Amazonian and Hesperian. Based on this assumption and their estimate of the present day near-surface inventory of H2O (approximately 34 m GEL, stored as ice in the polar layered deposits (PLD), lobate debris aprons, ice-rich latitude dependent mantles, and as shallow ground ice), they extrapolate the evolution of this inventory backward in time, taking into account the introduction of new water by volcanism, outflow channel activity, and the loss of water by exospheric escape. They conclude that, at the end of the Noachian, Mars had a near-surface water inventory of approximately 24 m and approximately 62 m by the end of the Hesperian - inventories that Carr and Head argue were incompatible with the existence of a former ocean.

Description: Mars is the "horizon goal" for human space flight [1]. Towards that endeavor, one must consider several factors in regards to choosing a landing site suitable for a human-rated mission including: entry, descent, and landing (EDL) characteristics, scientific diversity, and possible insitu resources [2]. Selecting any one place is a careful balance of reducing risks and increasing scientific return for the mission.

Description: The Strata-1 experiment will study the evolution of asteroidal regolith through long-duration exposure of simulant materials to the microgravity environment on the International Space Station (ISS). Many asteroids feature low bulk densities, which implies high values of porosity and a mechanical structure composed of loosely bound particles, (i.e. the "rubble pile" model), a prime example of a granular medium. Even the higher-density, mechanically coherent asteroids feature a significant surface layer of loose regolith. These bodies are subjected to a variety of forces and will evolve in response to very small perturbations such as micrometeoroid impacts, planetary flybys, and the YORP effect. Our understanding of this dynamical evolution and the inter-particle forces involved would benefit from long-term observations of granular materials exposed to small vibrations in microgravity. A detailed understanding of asteroid mechanical evolution is needed in order to predict the surface characteristics of as-of-yet unvisited bodies, to understand the larger context of samples collected by missions such as OSIRIS-REx and Hayabusa 1 and 2, and to mitigate risks for both manned and unmanned missions to asteroidal bodies. Understanding regolith dynamics will inform designs of how to land and set anchors, safely sample/move material on asteroidal surfaces, process large volumes of material for in situ resource utilization (ISRU) purposes, and, in general, predict behavior of large and small particles on disturbed asteroid surfaces.

Description: Human exploration of microgravity bodies is being investigated as a precursor to a Mars surface mission. Asteroids, comets, dwarf planets, and the moons of Mars all fall into this microgravity category and some are being discussed as potential mission targets. Obtaining geological samples for return to Earth will be a major objective for any mission to a small body. Currently, the knowledge base for geology sampling in microgravity is in its infancy. Humans interacting with non-engineered surfaces in microgravity environment pose unique challenges. In preparation for such missions a team at the NASA Johnson Space Center has been working to gain experience on how to safely obtain numerous sample types in such an environment. This paper describes the type of samples the science community is interested in, highlights notable prototype work, and discusses an integrated geology sampling solution.

Description: NASA Johnson Space Center's (JSC's) Astromaterials Research and Exploration Science (ARES) Division, part of the Exploration Integration and Science Directorate, houses a unique combination of laboratories and other assets for conducting cutting edge planetary research. These facilities have been accessed for decades by outside scientists, most at no cost and on an informal basis. ARES has thus provided substantial leverage to many past and ongoing science projects at the national and international level. Here we propose to formalize that support via an ARES/JSC Plane-tary Sample Analysis and Mission Science Laboratory (PSAMS Lab). We maintain three major research capa-bilities: astromaterial sample analysis, planetary process simulation, and robotic-mission analog research. ARES scientists also support planning for eventual human ex-ploration missions, including astronaut geological training. We outline our facility's capabilities and its potential service to the community at large which, taken together with longstanding ARES experience and expertise in curation and in applied mission science, enable multi-disciplinary planetary research possible at no other institution. Comprehensive campaigns incorporating sample data, experimental constraints, and mission science data can be conducted under one roof.

Description: The Mars Science Laboratory (MSL) Curiosity rover began investigating the rocks of Mt. Sharp in September 2014. The Murray formation is the lowermost unit, which is mostly comprised of finely laminated mudstones, suggesting these sediments were deposited in a lacustrine environment. It is important to characterize the geochemical and mineralogical trends throughout the Murray Fm to interpret the aqueous conditions of the ancient lake, the sources of the lake sediments, and post-depositional alteration processes. Four samples have been drilled from the Murray Fm so far: Confidence Hills, Mojave 2, and Telegraph Peak were collected from the Pahrump Hills member - the basal portion of the Murray Fm, and Buckskin was collected in the Marias Pass region (Fig. 1). The drill fines were delivered to the instruments inside the rover, including the CheMin instrument, a combination X-ray diffractometer and X-ray fluorescence spectrometer. Rietveld refinements and FULLPAT analyses of 1D CheMin XRD patterns were performed to determine quantitative abundances of minerals and amor-phous phases and the unit cell parameters of minerals present in abundances greater than 4-5 wt.%.

Description: The MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft orbited Mercury for four years until April 2015, revealing its structure, chemical makeup, and compositional diversity. Data from the mission have confirmed that Mercury is a compositional end-member among the terrestrial planets. The X-Ray Spectrometer (XRS) and Gamma-Ray Spectrometer (GRS) on board MESSENGER provided the first detailed geochemical analyses of Mercury's surface. These instruments have been used in conjunction with the Neutron Spectrometer and the Mercury Dual Imaging System to classify numerous geological and geochemical features on the surface of Mercury that were previously unknown. Furthermore, the data have revealed several surprising characteristics about Mercury's surface, including elevated S abundances (up to 4 wt%) and low Fe abundances (less than 2.5 wt%). The S and Fe abundances were used to quantify Mercury's highly reduced state, i.e., between 2.6 and 7.3 log10 units below the Iron-Wustite (IW) buffer. This fO2 is lower than any of the other terrestrial planets in the inner Solar System and has important consequences for the thermal and magmatic evolution of Mercury, its surface mineralogy and geochemistry, and the petrogenesis of the planet's magmas. Although MESSENGER has revealed substantial geochemical diversity across the surface of Mercury, until now, there have been only limited efforts to understand the mineralogical and petrological diversity of the planet. Here we present a systematic and comprehensive study of the potential mineralogical and petrological diversity of Mercury.

Description: Northwest Africa (NWA) 7034 and its pairings comprise a regolith breccia with a basaltic bulk composition [1] that yields a better match than any other martian meteorite to visible-infrared reflectance spectra of the martian surface measured from orbit [2]. The composition of the fine-grained matrix within NWA 7034 bears a striking resemblance to the major element composition estimated for the martian crust, with several exceptions. The NWA 7034 matrix is depleted in Fe, Ti, and Cr and enriched in Al, Na, and P [3]. The differences in Al and Fe are the most substantial, but the Fe content of NWA 7034 matrix falls within the range reported for the southern highlands crust [6]. It was previously suggested by [4] that NWA 7034 was sourced from the southern highlands based on the ancient 4.4 Ga ages recorded in NWA 7034/7533 zircons [4, 5]. In addition, the NWA 7034 matrix material is enriched in incompatible trace elements by a factor of 1.2-1.5 [7] relative to estimates of the bulk martian crust. The La/Yb ratio of the bulk martian crust is estimated to be approximately 3 [7], and the La/Yb of the NWA 7034 matrix materials ranges from approximately 3.9 to 4.4 [3, 8], indicating a higher degree of LREE enrichment in the NWA 7034 matrix materials. This elevated La/Yb ratio and enrichment in incompatible lithophile trace elements is consistent with NWA 7034 representing a more geochemically enriched crustal terrain than is represented by the bulk martian crust, which would be expected if NWA 7034 represents the bulk crust from the southern highlands. Given the similarities between NWA 7034 and the martian crust, NWA 7034 may represent an important sample for constraining the composition of the martian crust, particularly the ancient highlands. In the present study, we seek to constrain the H isotopic composition of the martian crust using Cl-rich apatite in NWA 7034. Usui et al., [9] recently proposed that a H isotopic reservoir exists within the martian crust that has a H-isotopic composition that is intermediate (D of 1000-2000per mille) between an isotopically light mantle (Delta D is less than 275per mille [10]) and an isotopically heavy atmosphere (D of 2500-6100per mille [11, 12]). Apatites in NWA 7034 occur in a number of lithologic domains, however apatites across all lithologic domains have been affected by a Pb-loss event at about 1.5 Ga before present [5], so they are unlikely to have retained a primary composition and are more likely to have equilibrated with fluids within the martian crust that may or may not have exchanged with the martian atmosphere. Equilibration of apatite with crustal fluids is further supported by the chlorine-rich compositions exhibited by apatites in NWA 7034 in comparison to apatites from other martian meteorites (Figure 1; [13]). Cl is more hydrophilic than F, which promotes formation of Cl-rich apatite compositions in fluid-rich systems [e.g., 14, 15-17].

Description: The Astromaterials Acquisition and Curation Office (henceforth referred to herein as NASA Curation Office) at NASA Johnson Space Center (JSC) is responsible for curating all of NASA's extraterrestrial samples. Under the governing document, NASA Policy Directive (NPD) 7100.10E "Curation of Extraterrestrial Materials", JSC is charged with "...curation of all extra-terrestrial material under NASA control, including future NASA missions." The Directive goes on to define Curation as including "...documentation, preservation, preparation, and distribution of samples for research, education, and public outreach." Here we describe some of the past, present, and future activities of the NASA Curation Office.

Description: The partitioning behavior of rare earth elements (REE) between minerals and melts is widely used to interpret the petrogenesis and geologic context of terrestrial and extra-terrestrial samples. REE are important tools for modelling the evolution of the lunar interior. The ubiquitous negative Eu anomaly in lunar basalts is one of the main lines of evidence to support the lunar magma ocean (LMO) hypothesis, by which the plagioclase-rich lunar highlands were formed as a flotation crust during differentiation of a global-scale magma ocean. The separation of plagioclase from the mafic cumulates is thought to be the source of the Eu depletion, as Eu is very compatible in plagioclase. Lunar basalts and volcanic glasses are commonly depleted in light REEs (LREE), and more enriched in heavy REEs (HREE). However, there is very little experimental data available on REE partitioning between lunar minerals and melts. In order to interpret the source of these distinctive REE patterns, and to model lunar petrogenetic processes, REE partition coefficients (D) between lunar minerals and melts are needed at conditions relevant to lunar processes. New data on D(sub REE) for plagioclase, and pyroxenes are now available, but there is limited available data for olivine/melt D(sub REE), particularly at pressures higher than 1 bar, and in Fe-rich and reduced compositions - all conditions relevant to the lunar mantle. Based on terrestrial data, REE are highly incompatible in olivine (i.e. D much less than 1), however olivine is the predominant mineral in the lunar interior, so it is important to understand whether it is capable of storing even small amounts of REE, and how the REEs might be fractionatied, in order to understand the trace element budget of the lunar interior. This abstract presents results from high-pressure and temperature experiments investigating REE partitioning between olivine and melt in a composition relevant to lunar magmatism.

Description: Details of the differentiation of a global-scale lunar magma ocean (LMO) remain enigmatic, as the Moon is not simply composed of highlands anorthosite and a suite of mare basalts as inferred from early studies. Results from recent orbital missions, and the increasingly detailed study of lunar samples, have revealed a much larger range of lithologies, from relatively MgO-rich and "purest anorthosite" discovered on the lunar far side by the M3 instrument on Chandraayan-1 to more exotic lithologies such as Si-rich domes and spinel-rich clasts distributed globally. To understand this increasingly complex geology, we must understand the initial formation and evolution of the LMO, and the composition of the cumulates this differentiation could have produced. Several attempts at modelling such a crystallization sequence have been made, and have raised as many questions as they have answered. We present results from our ongoing experimental simulations of magma ocean crystallization, investigating two end-member bulk compositions (TWM and LPUM) under fully fractional crystallization conditions. These simulations represent melting of the entire silicate portion of the Moon, as an end-member starting point from which to begin assessing the evolution of the lunar interior and formation of the lunar crust.

Description: Recent results obtained from the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft showed the surface of Mercury has high S abundances (approximately 4 wt%) and low Iron(II) Oxide abundances (less than 2 wt%). Based on these extreme values, the oxygen fugacity of Mercury's surface materials was estimated to be approximately 3 to 7 log(sub 10) units below the IW buffer (Delta IW-3 to Delta IW-7). This highly reducing nature of the planet has resulted in a large core and relatively thin mantle, extending to only approximately 420 km depth (corresponding to a core-mantle boundary pressure of approximately 4-7 GPa) within the planet. Furthermore, MESSENGER results have suggested the presence of carbon on the surface of the planet. Previous experimental results from have also suggested the possibility of a primary floatation crust on Mercury composed of graphite, produced after a global magma ocean event. With these exotic conditions of this compositional end-member planet, it begs the question, what is the core composition of Mercury? Although no definitive conclusion has been reached, previous studies have made advances towards answering this question. Riner et al. and Chen et al. looked at iron sulfide systems and implemented various crystallization and layered core scenarios to try and determine the composition and structure of Mercury's core. Malavergne et al. examined core crystallization scenarios in the presence of sulfur and silicon. Hauck et al. used the most recent geophysical constraints from the MESSENGER spacecraft to model the internal structure of Mercury, including the core, in a iron-sulfur-silicon system. More recently, Chabot et al. conducted a series of metal-silicate partitioning experiments in a iron-sulfur-silicon system. These results showed the core of Mercury has the potential to contain more than 15 wt% silicon. However, with the newest results from MESSENGER's low altitude campaign, carbon is another potential light element that could be incorporated into Mercury's core. The goal of this study is to determine the carbon concentration at graphite saturation in various silicon-iron bearing metals relevant to possible mercurian core compositions. Future experiments will include the addition of sulfur into these metals.

Description: The Sample Analysis at Mars (SAM) instrument aboard the Mars Science Laboratory rover has analyzed 10 samples from Gale Crater. All SAM evolved gas analyses have yielded a multitude of volatiles (e.g, H2O, SO2, H2S, CO2, CO, NO, O2, HC1). The objectives of this work are to 1) Characterize the evolved H2O, SO2, CO2, and O2 gas traces of sediments analyzed by SAM through sol 1178, 2) Constrain sediment mineralogy/composition based on SAM evolved gas analysis (SAM-EGA), and 3) Discuss the implications of these results releative to understanding the geochemical history of Gale Crater.

Description: Carbonates comprise the second most abundant class of carbon-bearing phases in carbonaceous chondrites after organic matter (approximately 2 wt.%), followed by other C-bearing phases such as diamond, silicon carbide, and graphite. Therefore, understanding the abundances of carbonates and the associated organic matter provide critical insight into the genesis of major carbonaceous components in chondritic materials. Carbonates in CM chondrites mostly occur as calcite (of varying composition) and dolomite. Properly performed, Raman spectroscopy provides a non-destructive technique for characterizing meteorite mineralogy and organic chemistry. It is sensitive to many carbonaceous phases, allows the differentiation of organic from inorganic materials, and the interpretation of their spatial distribution. Here, with the use of Raman spectroscopy, we determine the structure of the insoluble organic matter (IOM) in the matrix and carbonate phases in five CM chondrites: Jbilet Winselwan, Murchison, Nogoya, Santa Cruz, and Wisconsin Range (WIS) 91600, and interpret the relative timing of carbonate precipitation and the extent of the associated alteration events.

Description: Recent reports of the DAWN spacecraft's observations of the surface of Ceres indicate that there are bright areas, which can be explained by large amounts of the Mg sulfate hexahydrate (MgSO46(H2O)), although the identification appears tenuous. There are preliminary indications that water is being evolved from these bright areas, and some have inferred that these might be sites of contemporary hydro-volcanism. A heat source for such modern activity is not obvious, given the small size of Ceres, lack of any tidal forces from nearby giant planets, probable age and presumed bulk composition. We contend that observations of chondritic materials in the lab shed light on the nature of the bright spots on Ceres

Description: GEMS and ultrafine grained polyphase units (UFG-PU) in anhydrous IDPs are probably some of the most primitive materials in the solar system. UFG-PUs contain nanocrystalline silicates, oxides, metals and sulfides. GEMS are rounded approximately 100 nm across amorphous silicates containing embedded iron-nickel metal grains and sulfides. GEMS are one of the most abundant constituents in some anhydrous CPIDPs, often accounting for half the material or more. When NASA's Stardust mission returned with samples from comet Wild 2 in 2006, it was thought that UFG-PUs and GEMS would be among the most abundant materials found. However, possibly because of heating during the capture process in aerogel, neither GEMS nor UFG-PUs have been clearly found.

Description: Meteorites provide us with valuable insights into the conditions of the early solar system. Collisions often occur in our solar system that can result in materials accreting to other bodies as foreign clasts. These foreign pieces may have multiple origins that can sometimes be easily identified as a particular type of meteorite. It is important to interpret the origins of these clasts in order to understand dynamics of the solar system, especially throughout its early history. The Nice Model, as modified, proposes a reordering of planetary orbits that is hypothesized to have triggered the Late Heavy Bombardment. Clasts found within meteorites that came from objects in the solar system not commonly associated as an impactor could be indicative of such an event suggested by the Nice Model. Impacts also redistribute material from one region of an asteroid to another, and so clasts are found that reveal portions of the geological history of a body that are not recorded by typical samples. These would be cognate clasts. The goal of this investigation was to examine meteorites that had particularly interesting foreign and cognate clasts enclosed in them. We focus here on an unusual clast located in the ordinary chondrite, NWA 6925. This is one of three clasts analyzed during the LPI summer internship of Jessica Johnson.

Description: The surface geology and geomorphology of Mars indicate that it was once warm enough to maintain a large body of liquid water on its surface, though such a warm environment might have been transient. This study reports the hydrogen, carbon, and oxygen isotope compositions of the ancient atmosphere/hydrosphere of Mars based on in situ ion microprobe analyses of approximately 4 Ga-old carbonates in Allan Hills (ALH) 84001. The ALH 84001 carbonates are the most promising targets because they are thought to have formed from fluid that was closely associated with the Noachian atmosphere. While there are a number of carbon and oxygen isotope studies of the ALH 84001 carbonates, in situ hydrogen isotope analyses of these carbonates are limited and were reported more than a decade ago. Well-documented coordinated in situ analyses of carbon, oxygen and hydrogen isotopes provide an internally consistent dataset that can be used to constrain the nature of the Noachian atmosphere/hydrosphere and may eventually shed light on the hypothesis of ancient watery Mars.

Description: In its 12th year of exploration and 1600 sols since arrival at the rim of the 22 km-diameter Noachian Endeavour impact crater, Mars Exploration Rover Opportunity traversed from the summit of the western rim segment "Cape Tribulation" to "Marathon Valley", a shallow trough dissecting the rim and the site of strong orbital detection of smectites. In situ analysis of the exposures within Marathon Valley is establishing some of the geologic and geochemical controls on the aqueous alteration responsible for smectite detection known to occur in crater rims throughout Noachian terrains of Mars.

Description: The Mars Exploration Rover Opportunity has been exploring the western rim of the 22 km diameter Endeavour crater since August, 2011. Recently, Opportunity has reached a break in the Endeavour rim that the rover team has named Mara-thon Valley. This is the site where orbital observations from the MRO CRISM imaging spectrometer indicated the presence of iron smectites. On the outer western portion of Marathon Valley, Opportunity explored the crater-form feature dubbed Spirit of St. Louis (SoSL) crater. This presentation describes the 430 to 1009 nm (VNIR) reflectance, measured by the rover's Pancam, of rock units present both at Spirit of St. Louis and within Marathon Valley.

Description: Mars Exploration Rover Opportunity has been exploring Mars for 12+ years, and is presently investigating the geology of a western rim segment of 22 kilometers diameter, Noachian- aged Endeavour crater. The Alpha Particle X-ray Spectrometer has determined the compositions of a pre-impact lithology, the Matijevic fm., and polymict impact breccias ejected from the crater, the Shoemaker fm. Opportunity is now investigating a region named Marathon Valley that cuts southwest-northeast through the central portion of the rim segment and provides a window into the lower stratigraphic record. (Geographic names used here are informal.) At the head of Marathon Valley, referred to here as Upper Marathon Valley, is a shallow, ovoid depression approximately 2535 millimeters in size, named Spirit of Saint Louis. Layering inside Spirit of Saint Louis appears continuous with the Upper Marathon Valley rocks outside, indicating they are coeval. Spirit of Saint Louis is partly bounded by approximately 10-20 centimeters wide zone containing reddish altered rocks (red zone). Red zones also form prominent curvilinear features in Marathon Valley. Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) spectra provide evidence for a really extensive Fe-Mg smectite in the Marathon Valley region, indicating distinct styles of aqueous alteration. The CRISM detections of smectites are based on metal-OH absorptions at approximately 2.3 and 2.4 micron that are at least two times the background noise level.

Description: The Sample Analysis at Mars (SAM) instrument on board the Curiosity Rover has detected oxygen and HCl gas releases from all analyzed Gale Crater sediments. The presence of perchlorate ClO4(sup-) and/or chlorates ClO3(sup-) are potential sources of the aforementioned O2 releases. The detections of O2 and HCl gas releases and chlorinated hydrocarbons by SAM coupled with the detection of perchlorates by Phoenix Lander's 2008 Wet Chemistry Laboratory all suggest that perchlorates, and possibly chorates, may be present in the Gale Crater sediments. Previous laboratory studies have attempted to replicate these O2 releases by heating perchlorates and chlorates in instruments operated similarly to those in the SAM instrument. Early studies found that pure perchlorates release O2 at temperatures higher than those observed in SAM data. Subsequently, studies were done to test the effects of mixing iron-phase minerals, analogous to those detected on Mars by ChemMin, with perchlorates. The iron in these minerals acts as a catalyst and causes O2 to be released from the perchlorate at a lower temperature. These studies found that perchlorate solutions mixed with either Hawaii palagonite or ferrihydrite produce O2 releases at temperatures similar to the Rocknest (RN) windblown deposit and the John Klein (JK) drill sample from the Sheepbed mudstone. The study also determined that perchlorate mixtures with magnetite, hematite, fayalite-magnetite, ilmentite, and pyrrhotite produce O2 releases at temperatures similar to the Confidence Hills (CH) drill sample from the Murray mudstone. Oxygen re-leases from pure chlorates were recently compared with the SAM data. Laboratory analyses determined that Ca-chlorate produces O2 and HCl peaks that are similar to those detected in RN and JK materials. Currently, no perchlorate/chlorate mixture with iron-phase minerals can explain the O2 releases from either the Cumberland (CB) drill sample from the Sheepbed mudstone or Windjana (WJ) drill sample from the Kimberly sandstone. Mixtures of chlorate solutions with iron-phase minerals may produce O2 peaks at temperatures that match those from CB and WJ materials. The goal of this work is to determine if heating chlorate solutions mixed with iron-phase minerals will produce O2 and HCl peak temperatures similar to O2 and HCl peak temperatures of sediments analyzed by SAM, particularly the WJ and CB materials.

Description: The Sample Analysis at Mars (SAM) instrument onboard Curiosity can perform pyrolysis of martian solid samples, and analyze the volatiles by direct mass spectrometry in evolved gas analysis (EGA) mode, or separate the components in the GCMS mode (coupling the gas chromatograph and the mass spectrometer instruments). In addition, SAM has a wet chemistry laboratory designed for the extraction and identification of complex and refractory organic molecules in the solid samples. The chemical derivatization agent used, N-methyl-N-tert-butyldimethylsilyl- trifluoroacetamide (MTBSTFA), was sealed inside seven Inconel metal cups present in SAM. Although none of these foil-capped derivatization cups have been punctured on Mars for a full wet chemistry experiment, an MTBSTFA leak was detected and the resultant MTBSTFA vapor inside the instrument has been used for a multi-sol MTBSTFA derivatization (MD) procedure instead of direct exposure to MTBSTFA liquid by dropping a solid sample directly into a punctured wet chemistry cup. Pyr-EGA, Pyr-GCMS and Der-GCMS experiments each led to the detection and identification of a variety of organic molecules in diverse formations of Gale Crater.

Description: NASA's New Horizons spacecraft has revealed the complex geology of Pluto and Charon. Pluto shows ongoing surface geological activity centered on a vast basin containing a thick layer of volatile ices that is involved in convection and advection, with a crater retention age no greater than 10 Ma. Surrounding terrains show active glacial flow, apparent transport and rotation of large buoyant water-ice crustal blocks, and pitting by sublimation erosion and/or collapse. More enigmatic features include tall mounds with central depressions that are conceivably cryovolcanic, and ridges with complex bladed textures. Pluto also has ancient cratered terrains up to 4 Ga old that are extensionally fractured and extensively mantled and eroded by glacial or other processes. Charon is not currently active, but experienced major extensional tectonism and resurfacing (probably cryovolcanic) nearly 4 billion years ago. Impact crater populations on Pluto and Charon are not consistent with the steepest proposed impactor size-frequency distributions.

Description: This study represents the first metagenomic interrogation of Antarctic permafrost and polar cryptoendolithic microbial communities. The results underlie two different habitability conditions in the same location under extreme cold and dryness: the permafrost habitat where viable microbial life and activity is questionable, and the cryptoendolithic habitat which contains organisms capable of growth under the extreme conditions of the Antarctic Dry Valleys.

Description: Sublimation of the polar CO2 ice caps on Mars is an ongoing phenomenon that may be contributing to secular climate change on Mars. The transfer of CO2 between the surface and atmosphere via sublimation and deposition may alter atmospheric mass such that net atmospheric mass is increasing despite seasonal variations in CO2 transfer. My study builds on previous studies by Kahre and Haberle that analyze and compare data from the Phoenix and Viking Landers 1 and 2 to determine whether secular climate change is happening on Mars. In this project, I use two years worth of temperature, pressure, and elevation data from the MSL Curiosity rover to create a program that allows for successful comparison of Curiosity pressure data to Viking Lander pressure data so a conclusion can be drawn regarding whether CO2 ice cap sublimation is causing a net increase in atmospheric mass and is thus contributing to secular climate change on Mars.

Description: Ceres has only a small spin axis tilt (4 deg), and craters near its rotational poles can experience permanent shadow and trap volatiles, as is the case on Mercury and on Earth's Moon. Topography derived from stereo imaging by the Dawn spacecraft is used to calculate direct solar irradiance that defines the extent of the permanently shadowed regions (PSRs). In the northern polar region, PSRs cover approximately 1800 sq km or 0.13% of the hemisphere, and most of the PSRs are cold enough to trap water ice over geological time periods. Based on modeling of the water exosphere, water molecules seasonally reside around the winter pole and ultimately an estimated 0.14% of molecules get trapped. Even for the lowest estimates of the amount of available water, this predicts accumulation rates in excess of loss rates, and hence, there should be fresh ice deposits in the cold traps.