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  • Wiley-Blackwell  (27,398)
  • 2010-2014  (53)
  • 1980-1984  (25,305)
  • 1925-1929  (2,040)
  • 2012  (53)
  • 1983  (8,593)
  • 1981  (8,551)
  • 1980  (8,161)
  • 1928  (2,040)
Collection
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  • 2010-2014  (53)
  • 1980-1984  (25,305)
  • 1925-1929  (2,040)
Year
  • 1
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    Growth, reproduction and life span ofSepia officinalis(Cephalopoda: Mollusca) cultured through seven consecutive generations (2012)
    Wiley-Blackwell
    In:  Journal of Zoology, 233 (2). pp. 175-192.
    Details
    Publication Date: 2020-07-17
    Description: Hundreds of Sepia officinalis were hatched and cultured through the life cycle in each of 13 populations. Two genetic lines were maintained: one for an unprecedented seven generations and another presently in its fourth. All generations—save one—produced animals in excess of 1·0 kg body weight. Seven of eight generations with adequate data records had mean weights of 1–2 kg, and the largest cuttlefish reared were a male 2·6 kg and a female 2·9 kg. Fecundity levels were high, but there was a trend towards decreased fertility in later generations, with fertilization rates dropping below 10%. In the 7th generation, most mature animals failed to engage in agonistic courtship and mating behaviour. Almost no normal eggs were laid and none was fertile, thus ending the lineage. Most culture took place at 20–24°C and temperature generally explained variations in life span duration: being of shorter length at higher temperatures. Life spans were consistently longer at 20°C and sizes were greater than predicted from previously published literature. In both lines there was a trend towards larger individuals and longer life spans in subsequent generations. Survival of hatchlings typically exceeded 90% for two months post-hatching, and survival averaged 50% or higher to sexual maturity when corrected for animals removed from the populations for experimental use.
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  • 2
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    Habitat Selection and Life Cycle Characteristics of Five Species of the Amphipod Genus Gammarus in the Baltic (1981)
    Wiley-Blackwell
    In:  Oikos, 37 (2). p. 173.
    Details
    Publication Date: 2015-10-06
    Type: Article , PeerReviewed
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  • 3
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    Twenty years of invasion: a review of round goby Neogobius melanostomus biology, spread and ecological implications (2012)
    Wiley-Blackwell
    In:  Journal of Fish Biology, 80 (2). pp. 235-285.
    Details
    Publication Date: 2015-12-16
    Description: The round goby Neogobius melanostomus is one of the most wide-ranging invasive fish on earth, with substantial introduced populations within the Laurentian Great Lakes watershed, the Baltic Sea and several major European rivers. Rapid expansion and deleterious ecosystem effects have motivated extensive research on this species; here this research is synthesized. Maps of the global distribution are provided and the invasion history of N. melanostomus, which spread more rapidly at first in North America, but has undergone substantial expansion over the past decade in the Baltic Sea, is summarized. Meta-analyses comparing their size at age, diet, competitors and predators in North American and European ecosystems are provided. Size at age is region specific, with saline habitats typically supporting larger and faster growing individuals than fresh water. Neogobius melanostomus prey differs substantially between regions, demonstrating a capacity to adapt to locally abundant food sources. Neogobius melanostomus comprise at least 50% of the diet of eight taxa in at least one site or life stage; in total, 16 predator taxa are documented from the Laurentian Great Lakes v. five from Eurasia. Invasive N. melanostomus are the only common forage fish to heavily exploit mussels in the Laurentian Great Lakes and the Baltic Sea, facilitating the transfer of energy from mussels to higher trophic levels in both systems. Neogobius melanostomus morphology, life history, reproduction, habitat preferences, environmental tolerances, parasites, environmental effects, sampling strategies and management are also discussed. Neogobius melanostomus inhabit a wide range of temperate freshwater and brackish-water ecosystems and will probably continue to spread via ballast water, accidental bait release and natural dispersal worldwide. Climate change will probably enhance N. melanostomus expansion by elevating water temperatures closer to its energetic optimum of 26° C. Future research needs are presented; most pressing are evaluating the economic effects of N. melanostomus invasion, determining long-term population level effects of egg predation on game-fish recruitment and comparing several variables (density, ecological effects morphology and life history) among invaded ecosystems. This review provides a central reference as researchers continue studying N. melanostomus, often as examples for advancing basic ecology and invasion biology.
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  • 4
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    Effects of temperature and food supply on the growth of whitefishCoregonus lavaretuslarvae in an oligotrophic peri-alpine lake (2012)
    Wiley-Blackwell
    In:  Journal of Fish Biology, 81 (5). pp. 1501-1513.
    Details
    Publication Date: 2017-09-14
    Description: The relative roles of temperature and food availability on the seasonal and daily growth of whitefish Coregonus lavaretus larvae were investigated in the oligotrophic peri-alpine Lake Annecy, France. During the spring from 2004 to 2007, surface water temperature and density of potential zooplankton prey were monitored, and 2688 larvae were caught and measured. In addition, the daily growth of 130 larvae was estimated retrospectively by investigating the microstructure of their otoliths. Temperature played the predominant role in controlling both seasonal and daily growth of early larvae. In contrast, the abundance of Mesocyclops leuckarti and larval density was only slightly correlated to larval growth, suggesting no food limitation nor strong interindividual competition over the study period. Overall, these findings run counter to concerns about potential food limitation, but sound a warning about the potential impact of climate change on fish ecology and fisheries management.
    Type: Article , PeerReviewed
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  • 5
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    δ98/95Mo values and Molybdenum Concentration Data for NIST SRM 610, 612 and 3134: Towards a Common Protocol for Reporting Mo Data (2012)
    Wiley-Blackwell
    In:  Geostandards and Geoanalytical Research, 36 (3). pp. 291-300.
    Details
    Publication Date: 2017-07-21
    Description: Molybdenum concentration and δ98/95Mo values for NIST SRM 610 and 612 (solid glass), NIST SRM 3134 (lot 891307; liquid) and IAPSO seawater reference material are presented based on comparative measurements by MC-ICP-MS performed in laboratories at the Universities of Bern and Oxford. NIST SRM 3134 and NIST SRM 610 and 612 were found to have identical and homogeneous 98Mo/95Mo ratios at a test portion mass of 0.02 g. We suggest, therefore, that NIST SRM 3134 should be used as reference for the δ–Mo notation and to employ NIST SRM 610 or 612 as solid silicate secondary measurement standards, in the absence of an isotopically homogeneous solid geological reference material for Mo. The δ98/95MoJMC Bern composition (Johnson Matthey ICP standard solution, lot 602332B as reference) of NIST SRM 3134 was 0.25 ± 0.09‰ (2s). Based on five new values, we determined more precisely the mean open ocean δ98/95MoSRM 3134 value of 2.09 ± 0.07‰, which equals the value of δ98/95MoJMC Bern of 2.34 ± 0.07‰. We also refined the Mo concentration data for NIST SRM 610 to 412 ± 9 μg g−1 (2s) and NIST SRM 612 to 6.4 ± 0.7 μg g−1 by isotope dilution. We propose these concentration data as new working values, which allow for more accurate in situ Mo determination using laser ablation ICP-MS or SIMS.
    Type: Article , PeerReviewed
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  • 6
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    Process length variation of the cyst of the dinoflagellateProtoceratium reticulatumin the North Pacific and Baltic-Skagerrak region: calibration as an annual density proxy and first evidence of pseudo-cryptic speciation (2012)
    Wiley-Blackwell
    In:  Journal of Quaternary Science, 27 (7). pp. 734-744.
    Details
    Publication Date: 2017-11-14
    Description: Process length variation of cysts of the dinoflagellate Protoceratium reticulatum (Claparède et Lachmann) Bütschli in surface sediments from the North Pacific was investigated. The average process length showed a significant inverse relation to annual seawater density: σt annual = −0.8674 × average process length + 1029.3 (R2 = 0.84), with a standard error of 0.78 kg m−3. A sediment trap study from Effingham Inlet in British Columbia revealed the same relationship between average process length and local seawater density variations. In the Baltic–Skagerrak region, the average process length variation was related significantly to annual seawater density: σt annual = 3.5457 × average process length − 993.28 (R2 = 0.86), with a standard error of 3.09 kg m−3. These calibrations cannot be reconciled, which accentuates the regional character of the calibrations. This can be related to variations in molecular data (small subunit, long subunit and internal transcribed spacer sequences), which show the presence of several genotypes and the occurrence of pseudo-cryptic speciation within this species.
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  • 7
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    A heat wave and dispersal cause dominance shift and decrease biomass in experimental metacommunities (2012)
    Wiley-Blackwell
    In:  Oikos, 121 (5). pp. 721-733.
    Details
    Publication Date: 2019-01-23
    Description: In experimental metacommunities with marine benthic microalgae, we tested whether heat stress changes effects of connectivity and habitat heterogeneity on metacommunity structure and functioning, by manipulating a simulated heat wave, dispersal frequency and a light intensity gradient. We found that all measures of mean local and regional diversity and community biomass significantly declined after the heat wave and showed no sign of recovery. Additionally, dispersal decreased diversity and increased dominance in both the heat stressed and control communities. Together the heat wave and high dispersal frequency induced a dominance shift by spreading a temperature tolerant but low yielding species from its source patches with low light intensity across the metacommunity, an effect that increased with time. Although different species became dominant at high dispersal frequency with and without the heat wave, the shift towards a temperature tolerant species was not sufficient to maintain total community biomass. Thus, short-term disturbance may cause longer-term loss of ecosystem function due to dominance shifts in the composition of communities. This study illustrates the importance of employing multispecies approaches when attempting to predict responses of communities to environmental changes.
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  • 8
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    Bacterial diversity in dried colostrum and whey sold as nutraceutical products (2012)
    Wiley-Blackwell
    In:  Journal of Food Science, 77 (7). M359-M363.
    Details
    Publication Date: 2018-09-26
    Description: The microbial communities were analyzed from commercially available dried dairy nutraceutical products, including 4 brands of dried colostrum, 2 brands of dried whey, and 1 brand of nonfat dry milk. A culture‐dependent 16S rRNA sequencing approach was utilized to elucidate the identity of individual isolates recovered from each dried dairy product. Approximately 69% of all bacterial isolates were members the genus of Bacillus, while approximately 14% of all bacterial isolates were identified as members of the genus Pseudomonas. Members of the Kocuria, Microbacterium, and Enterococcus genera were identified as well.
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  • 9
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    Regional groundwater flow and interactions with deep fluids in western Apennine: the case of Narni-Amelia chain (Central Italy) (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2021-01-07
    Description: The elemental fluxes and heat flow associated with large aquifer systems can be significant both at local and at regional scales. In fact, large amounts of heat transported by regional groundwater flow can affect the subsurface thermal regime, and the amount of matter discharged towards the surface by large spring systems can be significant relative to the elemental fluxes of surface waters. The Narni-Amelia regional aquifer system (Central Italy) discharges more than 13 m3 sec)1 of groundwater characterised by a slight thermal anomaly, high salinity and high pCO2. During circulation in the regional aquifer, groundwater reacts with the host rocks (dolostones, limestones and evaporites) and mixes with deep CO2-rich fluids of mantle origin. These processes transfer large amounts of dissolved substances, in particular carbon dioxide, and a considerable amount of heat towards the surface. Because practically all the water circulating in the Narni-Amelia system is discharged by few large springs (Stifone-Montoro), the mass and energy balance of these springs can give a good estimation of the mass and heat transported from the entire system towards the surface. By means of a detailed mass and balance of the aquifer and considering the soil CO2 fluxes measured from the main gas emission of the region, we computed a total CO2 discharge of about 7.8 · 109 mol a)1 for the whole Narni-Amelia system. Finally, considering the enthalpy difference between infiltrating water and water discharged by the springs, we computed an advective heat transfer related to groundwater flow of 410 ± 50 MW.
    Description: Published
    Description: 182-196
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: carbon dioxide degassing ; heat flow ; regional aquifer ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
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    Greenland uplift and regional sea–level changes from ICESat observations and GIA modeling (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2020-12-14
    Description: We study the implications of a recently published mass balance of the Greenland ice sheet (GrIS), derived from repeated surface elevation measurements from NASA’s ice cloud and land elevation satellite (ICESat) for the time period between 2003 and 2008. To characterize the effects of this new, high-resolution GrIS mass balance, we study the time-variations of various geophysical quantities in response to the current mass loss. They include vertical uplift and subsidence, geoid height variations, global patterns of sea level change (or fingerprints), and regional sea level variations along the coasts of Greenland. Long-wavelength uplifts and gravity variations in response to current or past ice thickness variations are obtained solving the sea level equation, which accounts for both the elastic and the viscoelastic components of deformation. To capture the short-wavelength components of vertical uplift in response to current ice mass loss, which is not resolved by satellite gravity observations, we have specifically developed a high-resolution regional elastic rebound (ER) model. The elastic component of vertical uplift is combined with estimates of the viscoelastic displacement fields associated with the process of glacial-isostatic adjustment (GIA), according to a set of published ice chronologies and associated mantle rheological profiles. We compare the sensitivity of global positioning system (GPS) observations along the coasts of Greenland to the ongoing ER and GIA. In notable contrast with past reports, we show that vertical velocities obtained by GPS data from five stations with sufficiently long records and from one tide gauge at the GrIS margins can be reconciled with model predictions based on the ICE-5G deglaciation model and the ER associated with the new ICESat-derived mass balance.
    Description: Published
    Description: 1457-1474
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: Sea level change ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 11
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    BUILDING MATERIALS OF THE THEATRE OF MARCELLUS, ROME* (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2021-06-22
    Description: The building materials of the Theatre of Marcellus, 44–11 BCE, reflect Roman builders’ careful selections of tuff and travertine for dimension stone and volcanic aggregates for pozzolanic concretes. The vitric–lithic–crystal Tufo Lionato tuff dimension stone contains a high proportion of lava lithic fragments, which increase its compressive strength and decrease water sorption, enhancing durability. Sophisticated installations of travertine dimension stone reinforce the tuff masonry, which is integrated with durable concrete walls and barrel vaults. The pozzolanic mortars of the concretes contain harenae fossiciae mainly from the intermediate alteration facies of the mid-Pleistocene, scoriaceous Pozzolane Rosse pyroclastic flow. They have pervasive interpenetrating pozzolanic cements, including strätlingite, similar to highquality, imperial era mortars. Concrete walls are faced with refined Tufo Lionato opus reticulatum and tufelli, and opus testaceum of fired, greyish-yellow brick. The exploratory concrete masonry, which includes some of the earliest examples of brick facings and strätlingite cements in Rome, and the integration of these materials in complex architectural elements and internal spaces, reflect the highly skilled workmanship, rigorous work-site management and technical supervision of Roman builders trained in republican era methods and materials.
    Description: Published
    Description: 728–742
    Description: JCR Journal
    Description: restricted
    Keywords: VOLCANIC TUFF MASONRY ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 12
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    The effect of directivity in PSHA framework (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-04
    Description: We propose a method to introduce a refined representation of the ground motion in the framework of the Probabilistic Seismic Hazard Analysis (PSHA). This study is especially oriented to the incorporation of a priori information about source parameters, by focusing on the directivity effect and its influence on seismic hazard maps. Two strategies have been followed. One considers the seismic source as an extended source, and it is valid when the PSHA seismogenetic sources are represented as fault segments. We show that the incorporation of variables related to the directivity effect can lead to variations up to 30% of the hazard level, in terms of spectral acceleration response at 5 sec., exceeding probability of 10% in 50 years. The second one concerns the more general problem of the seismogenetic areas, where each point is a seismogenetic source having the same chance of enucleate a seismic event. In our proposition the point source is associated to the rupture-related parameters, defined using a statistical description. As an example, we consider a source point of an area characterized by strike slip faulting style. With the introduction of the directivity correction the modulation of the hazard map reaches values up to 100%. The introduction of directivity does not increase uniformly the hazard level, but acts more like a redistribution of the estimation that is consistent with the fault orientation. A general increase appears only when no a-priori information is available. However, nowadays good a-priori knowledge exists on style of faulting, dip and orientation of faults associated to the majority of the seismogenetic zones of the present seismic hazard maps. Following this method, all the information collected may be easily converted to obtain a more comprehensive and meaningful probabilistic Seismic Hazard formulation.
    Description: Published
    Description: 616-626
    Description: 4.1. Metodologie sismologiche per l'ingegneria sismica
    Description: JCR Journal
    Description: reserved
    Keywords: Earthquake ground motion ; Earthquake source observation ; Probabilistic Seismic Hazard ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 13
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    Microstructures of melt inclusions in anatectic metasedimentary (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-04
    Description: The occurrence of crystallized and glassy melt inclusions (MI) in high-grade, partially melted metapelites and metagraywackes has opened up new possibilities to investigate anatectic processes. The present study focuses on three case studies: khondalites from the Kerala Khondalite Belt (India), the Ronda migmatites (Spain), and the Barun Gneiss (Nepal Himalaya). The results of a detailed microstructural investigation are reported, along with some new microchemical data on the bulk composition of MI. These inclusions were trapped within peritectic garnet and ilmenite during crystal growth and are therefore primary inclusions. They are generally isometric and very small in size, mostly £15 lm, and only rarely reaching 30 lm; they occur in clusters. In most cases inclusions are crystallized ( nanogranites ) and contain a granitic phase assemblage with quartz, feldspar and one or two mica depending on the particular case study, commonly with accessory phases (mainly zircon, apatite, rutile). In many cases the polycrystalline aggregates that make up the nanogranites show igneous microstructures, e.g. granophyric intergrowths, micrographic quartz in K-feldspar and cuneiform rods of quartz in plagioclase. Further evidence for the former presence of melt within the investigated inclusions consists of melt pseudomorphs, similar to those recognized at larger scale in the host migmatites. Moreover, partially crystallized inclusions are locally abundant and together with very small (£8 lm) glassy inclusions may occur in the same clusters. Both crystallized and partially crystallized inclusions often display a diffuse nanoporosity, which may contain fluids, depending on the case study. After entrapment, inclusions underwent limited microstructural modifications, such as shape maturation, local necking down processes, and decrepitation (mainly in the Barun Gneiss), which did not influence their bulk composition. Re-homogenized nanogranites and glassy inclusions show a leucogranitic and peraluminous composition, consistent with the results of partial melting experiments on metapelites and metagraywackes. Anatectic MI should therefore be considered as a new and important opportunity to understand the partial melting processes.
    Description: Published
    Description: 303-322
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: restricted
    Keywords: garnet ; melt inclusions ; melt microstructures ; migmatites ; nanogranite ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology
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  • 14
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    Ground deformation at calderas driven by fluid injection: modelling unrest episodes at Campi Flegrei (Italy) (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-03
    Description: Campi Flegrei collapse caldera (Italy) is a high-risk volcanic area located close to Naples and includes part of the densely populated city. This area is characterised by large up and down ground displacements. The last large uplift episode caused 3.5 m of cumulative vertical displacement at the centre of the town of Pozzuoli, during the period 1969–1984. Up and down ground movements in this area often occur without intercurring eruptions and are similar to what is observed at other calderas worldwide. Here, however, they appear more evident and amplified. Understanding the mechanism of such movements is crucial for hazard assessment and eruption forecast, mainly due to this densely populated area. This paper presents a detailed model for ground displacements due to deep fluid injection in shallower layers. Such a model explains in a natural way the occurrence of uplift and subsidence without eruptions. We show that it is possible to fit observed ground deformation in this area with a thermofluid dynamical model. The model obtained is also consistent with other observations like microgravity changes, changes in CO2 flux, etc. Here, we suggest that significant uplift and subsidence at calderas can be due to effects of deep fluid injections other than magma. At Campi Flegrei, however, a partial magmatic contribution at the origin of the observed episodes cannot be excluded.
    Description: Published
    Description: 833–847
    Description: JCR Journal
    Description: restricted
    Keywords: Numerical approximations and analysis; Hydrothermal systems; Explosive volcanism; Calderas ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
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  • 15
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    Mantle viscosity inference: a comparison between Simulated Annealing and Neighbourhood Algorithm inversion methods (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-04
    Description: Two direct search methods, simulated annealing and neighbourhood algorithm, are applied to the inversion of the viscosity profile of the mantle using relative sea level time-histories for the Hudson Bay region. In problems characterized by a low-dimensional model space (Nd = 2 in this study), the two inversion methods show comparable performances. When a larger number of dimensions is involved (specifically Nd = 6), we directly show that simulated annealing is less effective than neighbourhood algorithm in overcoming the obstacles that are found in the model space when our specific data set is employed. This study confirms that modifications of the conventional Monte Carlo inversion method, such as simulated annealing and neighbourhood algorithm, are viable tools to determine the viscosity profile of the mantle, which, until recently, has been mainly tackled by means of linearized techniques.
    Description: Published
    Description: 890-900
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: mantle viscosity ; simulated annealing ; neighbourhood algorithm ; postglacial rebound ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 16
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    Some insights on the occurrence of recent volcanic eruptions of Mount Etna volcano (Sicily, Italy) (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-03
    Description: In the first part of this work, we make use of two non-parametric statistical pattern recognition algorithms and a multiple regression analysis to analyse seismic clusters occur ring around Mount Etna, Italy. The aim is to determine if the onset of flank eruptions at Mount Etna is linked to variations in the regional seismicity at a timescale of few weeks. From the analysis, we find that the discrimination between clusters preceding flank eruptions and clusters not related in time to flank activity is mainly linked to the volume output of the previous flank eruption, in some cases together with the time elapsed from its end. Instead, we do not find any difference in the seismicity features characterizing different types of clusters, except for a very small contribution of the number of seismic events in the clusters. This result does not confirm the existence, suggested in the past, of a direct link between the regional state of stress at a timescale of few weeks and the occurrence of flank eruptions on Mount Etna volcano. On the contrary, the result suggests that a prominent role in the flank eruption occur rence is played by the re-charging of the feeding system. In the second part of this study we analyse the relationship between the magma volume erupted in an eruption and the interevent time following it, finding that a ‘time-predictable model’ satisfactorily describes the occurrence of eruptions at Mount Etna in the last decades. The latter analysis is car ried out both on the flank eruption catalogue only, and on the complete catalogue of flank and summit eruptions, with comparable results.
    Description: Published
    Description: 1203–1218
    Description: JCR Journal
    Description: restricted
    Keywords: flank eruptions ; Mount Etna volcano ; regional tectonic stress ; statistical pattern recognition ; time predictability ; 05. General::05.01. Computational geophysics::05.01.04. Statistical analysis
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  • 17
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    The Italian present-day stress map (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-03
    Description: In this paper, we present a significant update of the Italian present-day stress data compilation not only to improve the knowledge on the tectonic setting of the region or to constrain future geodynamic models, but also to understand the mechanics of processes linked to faulting and earthquakes. In this paper, we have analysed, revised and collected new contemporary stress data from borehole breakouts and we have assembled earthquake and fault data. In total, 206 new quality-ranked entries complete the definition of the horizontal stress orientation and tectonic regime in some areas, and bring new information mainly in Sicily and along the Apenninic belt. Now the global Italian data set consists of 715 data points, including 499 of A–C quality, representing an increase of 37 per cent compared to the previous compilation. The alignment of horizontal stresses measured in some regions, closely matches the ∼N–S first- order stress field orientation of ongoing relative crustal motions between Eurasia and Africa plates. The Apenninic belt shows a diffuse extensional stress regime indicating a ∼NE–SW direction of extension, that we interpret as related to a second-order stress field. The horizontal stress rotations observed in peculiar areas reflect a complex interaction between first-order stress field and local effects revealing the importance of the tectonic structure orientations. In particular, in Sicily the new data delineate a more complete tectonic picture evidencing adjacent areas characterized by distinct stress regime: northern offshore of Sicily and in the Hyblean plateau the alignment of horizontal stresses is consistent with the crustal motions, whereas different directions have been observed along the belt and foredeep.
    Description: Published
    Description: 705–716
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Downhole methods; Seismicity and tectonics; Crustal structure; Europe. ; borehole breakouts, earthquakes, faults ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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    Complexity of the rupture process during the 2009 L’Aquila, Italy, earthquake (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-04
    Description: In this study, we investigate the rupture history of the April 6th 2009 (Mw 6.1) L’Aquila normal faulting earthquake by using a nonlinear inversion of strong motion, GPS and DInSAR data. Both the separate and joint inversion solutions reveal a complex rupture process and a heterogeneous slip distribution. Slip is concentrated in two main asperities: a smaller shallow patch of slip located up-dip from the hypocenter and a second deeper and larger asperity located southeastward along strike direction. The key feature of the source process emerging from our inverted models concerns the rupture history, which is characterized by two distinct stages. The first stage begins with rupture nucleation and with up-dip propagation at relatively high (∼ 4.0 km/s), but still sub-shear, rupture velocity. The second stage starts nearly 2.0÷2.5 seconds after nucleation and it is characterized by the along strike rupture propagation. The largest and deeper asperity fails during this stage of the rupture process. The rupture velocity is larger in the up-dip than in the along-strike direction. The up-dip and along-strike rupture propagation are separated in time and associated with a Mode II and a Mode III crack, respectively. The comparison between the source models inferred in this study with the Poisson ratio anomalies in the crustal volume containing the fault plane (Di Stefano et al., 2011) allows the interpretation of the delay in along-strike rupture propagation in terms of a structural control of the rupture history. Our results show that the L’Aquila earthquake featured a very complex rupture, with strong spatial and temporal heterogeneities suggesting a strong frictional and/or structural control of the rupture process.
    Description: Published
    Description: 607-621
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: restricted
    Keywords: Inverse theory;Earthquake dynamics;Earthquake ground motions;Earthquake source observations;Body waves;Rheology and friction of fault zones ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous
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    Horizontal polarization of ground motion in the Hayward fault zone (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-04
    Description: We investigate shear wave polarization in the Hayward fault zone near Niles Canyon, Fremont, CA. Waveforms of 12 earthquakes recorded by a seven-accelerometer seismic array around the fault are analysed to clarify directional site effects in the fault damage zone. The analysis is performed in the frequency domain through H/V spectral ratios with horizontal components rotated from 0◦ to 180◦, and in the time domain using the eigenvectors and eigenvalues of the covariance matrix method employing three component records. The near-fault ground motion tends to be polarized in the horizontal plane. At two on-fault stations where the local strike is N160◦, ground motion polarization is oriented N88 ± 19◦ and N83 ± 32◦, respectively. At a third on-fault station, the motion is more complex with horizontal polarization varying in different frequency bands. However, a polarization of N86 ± 7◦, similar to the results at the other two on-fault stations, is found in the frequency band 6–8 Hz. The predominantly high-angle polarization from the fault strike at the Hayward Fault is consistent with similar results at the Parkfield section of the San Andreas Fault and the Val d’Agri area (a Quaternary extensional basin) in Italy. In all these cases, comparisons of the observed polarization directions with models of fracture orientation based on the fault movement indicate that the dominant horizontal polarization is near-orthogonal to the orientation of the expected predominant cracking direction. The results help to develop improved connections between fault mechanics and near-fault ground motion.
    Description: Published
    Description: 1255–1272
    Description: JCR Journal
    Description: open
    Keywords: Earthquake ground motions. ; Interface waves ; Site effects ; Wave propagation ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion
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    Land subsidence along the Ionian coast of SE Sicily (Italy), detection and analysis via Small Baseline Subset (SBAS) multitemporal differential SAR interferometry (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-04
    Description: We present the results of a multi-temporal, differential interferometric synthetic aperture radar (DInSAR) analysis aiming to identify active surface deformation phenomena in southeastern Sicily. The study area has been chosen because of its strong seismicity, high concentration of industrial and agricultural activities, and high density of people living in the coastal area. Furthermore, the morphology, lithology and climatic feature of this sector of the Hyblean foreland are suitable for an interferometric analysis, providing a high coherence over the area. We used the Small BAseline Subset (SBAS) multitemporal DInSAR technique from Berardino et al., 2002, to calculate mean ground velocity maps and displacement time series from a large data set of European Remote Sensing Satellites (ERS 1-2) images spanning the time period 1992-2000. The reliability of the DInSAR results was tested calculating the EastSAR and UpSAR values over two permanent global positioning system (GPS) stations in the area, and comparing them with the EastGPS and UpGPS values. The residuals between GPS and DInSAR velocities were 1 and 0.6 mm/yr for the Up and East components, respectively. Four main subsiding areas, previously undetected, have been identified, in correspondence of the towns of Augusta, Siracusa, Priolo, and Villasmundo. The observed deformation phenomena are located within coastal structural basins, filled with Pleistocene and Holocence deposits, except the Villasmundo land subsidence which is located on the Hyblean plateau. The measured deformation rates reach values up to -18 mm/yr in Augusta, -6 mm/yr in Siracusa, -5 mm/yr in Villasmundo and -4.5 mm/yr in Priolo. The examination of velocity profiles, time series, and geological data allows us to relate all the detected deformation patterns primarily to groundwater over-exploitation. A multi-dimensional interpolation with kriging was performed to obtain a field subsidence map. A first order elastic deformation model was used to simulate the peculiar features of the Villasmundo subsidence
    Description: ASI-SIGRIS project. ESA Cat1 3769. MIUR Fondo per il sostegno dei giovani.
    Description: Published
    Description: 273-286
    Description: 1.10. TTC - Telerilevamento
    Description: JCR Journal
    Description: partially_open
    Keywords: subsidence ; InSAR ; 05. General::05.08. Risk::05.08.02. Hydrogeological risk
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  • 21
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    Earthquake sequences of the last millennium in L'Aquila and surrounding regions (central Italy) (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-04
    Description: We have analysed the history of seismic activity in the region of L'Aquila to compare the 2009 sequence with previous ones. Historical catalogues are exhaustive for large shocks, but not for small earthquakes and swarms. Our original compilation highlights repeated seismic sequences from 1315 ad to present. In the 20th century, at least 23 sequences affected the Abruzzi region, 8 of which were very close to L'Aquila. In previous centuries, we found evidence of at least 13 sequences around L'Aquila, with maximum magnitude ∼4 to ∼5. Only three sequences were followed by stronger shocks (1461, 1703 and 2009). However, many strong events of the region (1349, 1762, 1915, 1950) were not preceded by foreshocks. We describe here the last of these sequences (1985) showing its strong similarity with the 2009 one, except its final evolution (no large event in 1985). Our analysis suggests that seismic sequences alone cannot be considered straight forerunners of incoming strong events.
    Description: Published
    Description: 52–61
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: reserved
    Keywords: L’Aquila earthquake ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution
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    Dissolved gases in brackish thermal waters: an improved analytical method (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-04
    Description: An improved method based on equilibrium partitioning between water samples and an inert host gas, introduced after sampling, is proposed for determining multiple species of dissolved gases in brackish water. The method itself, and the most convenient equations for describing gas solubilities in brackish waters, is described in detail. The method allows the rapid characterization of several sites and represents a useful tool for geochemical surveys. A comparison between replicate samples analyzed using different procedures demonstrates the efficiency of the method and indicates that the abundances of the main dissolved gases can be obtained, which can then be used to determine underlying geochemical processes. A Microsoft Excel worksheet is provided to easily calculate the concentration of dissolved gas species.
    Description: Published
    Description: 236-244
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: brackish thermal waters ; dissolved gases ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions
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  • 23
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    Isostatic rebound following the Alpine deglaciation: impact on the sealevel variations and vertical movements in the Mediterranean region (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-04
    Description: The present-day sea level variations and geodetically observed ground deformations in the Mediterranean area are normally ascribed to the combined effect of tectonic or human-driven subsidence and postglacial uplift as a result of the melting of the major Pleistocene ice sheets. However, another potential cause of deformation, only marginally considered to date, is the melting of the glacier that covered the Alps during the last glacial maximum (LGM). The aim of this paper is to predict the long-term sea level variations induced by the melting of both the late-Pleistocene and Alpine ice sheets and compare our results with the relative sea level (RSL) observations available in the Mediterranean region. This task is accomplished solving the sea level equation (SLE) for a spherically symmetric viscoelastic Earth. Our analysis shows that the melting of the Alpine glacier has marginally affected the Holocene sea level variations in the near-field sites in southern France (Marseilles and Roussillon) and the central Tyrrhenian sea (Civitavecchia), and that the RSL predictions are significantly sensitive to the chronology of the remote ice aggregates. The computations, which are performed using a specific mantle viscosity profile consistent with global observations of RSL rise, show that the uplift rate driven by the Alpine isostatic readjustment may account for up to 1/3 of the rates observed at GPS stations in the western portion of the chain. Our results suggest that a thorough modelization of both near- and far-field ice sheets is necessary to gain a better insight into the present-day deformations and sea level variations in the Mediterranean region.
    Description: Published
    Description: 137-147
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: Alpine glacier ; glacial rebound ; mantle viscosity ; sea level variations ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 24
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    Stress-induced temperature variations in groundwater of the Monferrato area (north-western Italy) (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-04
    Description: Although characterized by low seismicity, the Monferrato area of north-western Italy was affected by earthquakes, of magnitude M5.1 and M4.8, in 2000 and 2001. At the same time, marked changes were recorded in water temperature and chemistry in several wells within the epicentral area. In May 2004, an automatic network for the continuous monitoring of groundwater was installed in selected wells to study the phenomenon. Here, we report on data collected during a 3-year period of groundwater monitoring. During the first year, episodes of water heating (by up to 20°C) were observed in one monitored well. The temporal analysis of the seismic activity recorded in the area revealed as almost all seismic events occurred during the period of elevated water temperatures. The similar timing of earthquakes and groundwater-temperature anomalies suggests that both may be triggered by the same processes acting in the crust.
    Description: Published
    Description: 142-149
    Description: JCR Journal
    Description: reserved
    Keywords: groundwater monitoring ; pore fluid pressure; ; tectonic stress ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring
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  • 25
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    Active extension in Val d’Agri area, Southern Apennines, Italy: implications for the geometry of the seismogenic belt. (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2020-02-24
    Description: Integration of geologic, geomorphologic and seismologic data sets is used to reconstruct the recent tectonic evolution and active deformation pattern in the Val d’Agri area, located in the seismically active axial sector of the Southern Apennines (Italy). The western portion of the Apennines thrust belt has been affected by Pliocene–Quaternary extension during easterly roll-back and crustal delamination of the Adriatic slab. The bulk of Quaternary extension has been accommodated bySW-dipping oblique and normal faults,which have attained mature morphologic and structural features and, nowadays, separate mountain ranges from intermontane basins. However, in the present seismogenic belt, coseismic faulting locally occurs on NE-dipping structures, which might cut the inherited Pleistocene landscape. In theVal d’Agri basin, in spite of the large Early–Middle Pleistocene, displacement occurred on SW-dipping faults bordering its eastern flank, our investigations show that the recent basin evolution has been controlled by a NE-dipping fault system (Monti della Maddalena fault system, MMFS). This fault system cuts across the Monti della Maddalena range, west of the Agri valley and has not yet created an evident tectonic landscape. Notwithstanding, fault motion since the Middle Pleistocene might explain geomorphologic and hydrographic anomalies of the Agri river and its valley, where fault-controlled subsidence has captured the river course and produced an aggrading plain within a regional uplift context. Recent and ongoing motion is documented by fault scarplets in loose deposits, 14C ages of palaeosols and the spatial relation with low to moderate instrumental seismicity. Results from fault kinematic analysis are compatible with fault-plane solutions of local and regional seismic events, and indicate ∼NE–SW oriented extension. Recognition of the MMFS as a potential seismogenic fault increases the longitudinal extent of the NE-dipping, morphologically immature seismic sources in the Southern Apennines and argues against the range-bounding fault model for active extension in the region. The regional size of the NE-dipping seismogenic belt may result from impingement of a mantle wedge beneath the Apenninic chain and possibly track the external front of crustal delamination.
    Description: Published
    Description: 591-609
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: active tectonics ; crustal deformation ; earthquakes ; geomorphology ; normal faulting ; Southern Italy ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology
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    Tsunami early warning using earthquake rupture duration and P-wave dominant period: the importance of length and depth of faulting (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2020-02-24
    Description: After an earthquake, rapid, real-time assessment of hazards such as ground shaking and tsunami potential is important for early warning and emergency response. Tsunami potential depends on seafloor displacement, which is related to the length, L, width, W, mean slip, D, and depth, z, of earthquake rupture. Currently, the primary discriminant for tsunami potential is the centroid-moment tensor magnitude, MCMT, representing the seismic potency LWD, and w estimated through an indirect, inversion procedure. The obtained MCMT and the implied LWD w value vary with the depth of faulting, assumed earth model and other factors, and is only available 30 min or more after an earthquake. The use of more direct procedures for hazard assessment, when available, could avoid these problems and aid in effective early warning. Here we present a direct procedure for rapid assessment of earthquake tsunami potential using two, simple measures on P-wave seismograms—the dominant period on the velocity records, Td, and the likelihood that the high-frequency, apparent rupture-duration, T0, exceeds 50–55 s. T0 can be related to the critical parameters L and z, while Td may be related to W, D or z. For a set of recent, large earthquakes, we show that the period-duration product T T gives more information on tsunami impact and size than MCMT and other currently used d0w discriminants. All discriminants have difficulty in assessing the tsunami potential for oceanic strike-slip and backarc or upper plate, intraplate earthquake types. Our analysis and results suggest that tsunami potential is not directly related to the potency LWD from the ‘seismic’ faulting model, as is assumed with the use of the MCMT discriminant. Instead, knowledge of w rupture length, L, and depth, z, alone can constrain well the tsunami potential of an earthquake, with explicit determination of fault width, W, and slip, D, being of secondary importance. With available real-time seismogram data, rapid calculation of the direct, period-duration discriminant can be completed within 6–10 min after an earthquake occurs and thus can aid in effective and reliable tsunami early warning.
    Description: Published
    Description: 283-291
    Description: JCR Journal
    Description: restricted
    Keywords: earthquake dynamics ; earthquake source observation ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring
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    Ocean ensemble forecasting. Part II: Mediterranean Forecast System response (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2020-02-24
    Description: This article analyzes the ocean forecast response to surface vector wind (SVW) distributions generated by a Bayesian hierarchical model (BHM) developed in Part I of this series. A new method for ocean ensemble forecasting (OEF), the socalled BHM-SVW-OEF, is described. BHM-SVW realizations are used to produce and force perturbations in the ocean state during 14 day analysis and 10 day forecast cycles of the Mediterranean Forecast System (MFS). The BHM-SVW-OEF ocean response spread is amplified at the mesoscales and in the pycnocline of the eddy field. The new method is compared with an ensemble response forced by European Centre for Medium-Range Weather Forecasts (ECMWF) ensemble prediction system (EEPS) surface winds, and with an ensemble forecast started from perturbed initial conditions derived froman ad hoc thermocline intensified random perturbation (TIRP) method. The EEPS-OEF shows spread on basin scales while the TIRP-OEF response is mesoscale-intensified as in the BHM-SVW-OEF response. TIRP-OEF perturbations fill more of the MFS domain, while the BHM-SVW-OEF perturbations are more location-specific, concentrating ensemble spread at the sites where the ocean-model response to uncertainty in the surface wind forcing is largest.
    Description: Published
    Description: 879–893
    Description: JCR Journal
    Description: embargoed_20140501
    Keywords: forecast uncertainty ; 03. Hydrosphere::03.01. General::03.01.03. Global climate models
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    Post-seismic relaxation following the 2009 April 6, L’Aquila (Italy), earthquake revealed by the mass position of a broad-band seismometer (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2020-03-16
    Description: Post-seismic relaxation is known to occur after large or moderate earthquakes, on time scales ranging from days to years or even decades. In general, long-term deformation following seismic events has been detected by means of standard geodetic measurements, although seismic instruments are only used to estimate short timescale transient processes. Albeit inertial seismic sensors are also sensitive to rotation around their sensitive axes, the recording of very slow inclination of the ground surface at their standard output channels is practically impossible, because of their design characteristics. However, modern force-balance, broad- band seismometers provide the possibility to detect and measure slow surface inclination, through the analysis of the mass position signal. This output channel represents the integral of the broad-band velocity and is generally considered only for state-of-health diagnostics. In fact, the analysis of mass position data recorded at the time of the 2009 April 6, L’Aquila (MW = 6.3) earthquake, by a closely located STS-2 seismometer, evidenced the occurrence of a very low frequency signal, starting right at the time of the seismic event. This waveform is only visible on the horizontal components and is not related to the usual drift coupled with the temperature changes. This analysis suggests that the observed signal is to be ascribed to slowly developing ground inclination at the station site, caused by post-seismic relaxation following the main shock. The observed tilt reached 1.7 × 10−5 rad in about 2 months. This estimate is in very good agreement with the geodetic observations, giving comparable tilt magnitude and direction at the same site. This study represents the first seismic analysis ever for the mass position signal, suggesting useful applications for usually neglected data.
    Description: Published
    Description: 1717-1724
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: restricted
    Keywords: Seismic cycle ; Earthquake source observations ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
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    Complex 3D Finite Element Modeling of the April 6th 2009 L'Aquila Earthquake by Inverse Analysis of Static Deformation (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-03
    Description: On 2009 April 6 a Mw = 6.3 earthquake struck the Abruzzi region (Central Italy) and caused severe destruction in L’Aquila and the surrounding area. In this work we present a Finite Element analysis of the event based on a realistic complex 3-D model, accounting for topographic relief and rheological heterogeneities deduced from local tomography. Finite Element computed Green’s functions were implemented in a linear inversion of GPS coseismic displacements, to retrieve the slip distribution on the rupture plane. The inverted slip models basically agree with previous studies carried out on homogeneous domains, but reveal the presence of a single high slip patch, whereas half-space or 1-D approaches obtain a more complex slip pattern. Our results point out that the introduction of 3-D features significantly influences the obtained source model, suggesting a trade-off between domain complexities and source details.
    Description: Published
    Description: 1339–1358
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: Numerical approximations and analysis ; Seismicity and tectonics ; Dynamics and mechanics of faulting ; L'Aquila earthquake ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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    A comprehensive approach for evaluating network performance in surface and borehole seismic monitoring (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-04
    Description: The accurate determination of locations and magnitudes of seismic events in a monitored region is important for many scientific, industrial and military studies and applications; for these purposes a wide variety of seismic networks are deployed throughout the world. It is crucial to know the performance of these networks not only in detecting and locating seismic events of different sizes throughout a specified source region, but also by evaluating their location errors as a function of the magnitude and source location. In this framework, we have developed a method for evaluating network performance in surface and borehole seismic monitoring. For a specified network geometry, station characteristics and a target monitoring volume, the method determines the lowest magnitude of events that the seismic network is able to detect (Mw detect), and locate (Mw loc) and estimates the expected location and origin time errors for a specified magnitude. Many of the features related to the seismic signal recorded at a single station are considered in this methodology, including characteristics of the seismic source, the instrument response, the ambient noise level, wave propagation in a layered, anelastic medium and uncertainties on waveform measures and the velocity model. We applied this method to two different network typologies: a local earthquake monitoring network, Irpinia Seismic Network (ISNet), installed along the Campania-Lucania Apennine chain in Southern Italy, and a hypothetic borehole network for monitoring microfractures induced during the hydrocarbon extraction process in an oil field. The method we present may be used to aid in enhancing existing networks and/or understanding their capabilities, such as for the ISNet case study, or to optimally design the network geometry in specific target regions, as for the borehole network example.
    Description: Published
    Description: 793-806
    Description: 4.1. Metodologie sismologiche per l'ingegneria sismica
    Description: JCR Journal
    Description: restricted
    Keywords: Earthquake ground motions ; Computational seismology ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques
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    Residual analysis of teleseismic P-wave energy magnitude estimates: inter- and intrastation variability (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-03
    Description: Computing the magnitude of an earthquake requires correcting for the propagation effects from the source to the receivers. This is often accomplished by performing numerical simulations using a suitable Earth model. In this work, the energy magnitude Me is considered and its determination is performed using theoretical spectral amplitude decay functions over teleseismic distances based on the global Earth model AK135Q. Since the high frequency part (above the corner frequency) of the source spectrum has to be considered in computing Me, the influence of propagation and site effects may not be negligible and they could bias the single station Me estimations. Therefore, in this study we assess the inter- and intrastation distributions of errors by considering the Me residuals computed for a large data set of earthquakes recorded at teleseismic distances by seismic stations deployed worldwide. To separate the inter- and intrastation contribution of errors, we apply a maximum likelihood approach to the Me residuals. We show that the interstation errors (describing a sort of site effect for a station) are within ±0.2 magnitude units for most stations and their spatial distribution reflects the expected lateral variation affecting the velocity and attenuation of the Earth's structure in the uppermost layers, not accounted for by the 1-D AK135Q model. The variance of the intrastation error distribution (describing the record-to-record component of variability) is larger than the interstation one (0.240 against 0.159), and the spatial distribution of the errors is not random but shows specific patterns depending on the source-to-station paths. The set of coefficients empirically determined may be used in the future to account for the heterogeneities of the real Earth not considered in the theoretical calculations of the spectral amplitude decay functions used to correct the recorded data for propagation effects.
    Description: Published
    Description: 1444-1454
    Description: JCR Journal
    Description: restricted
    Keywords: time series analysis ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring
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    Strain rate computation in Northern Victoria Land (Antarctica) from episodic GPS surveys (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-04
    Description: The monitoring of crustal motions in Northern Victoria Land (NVL) of Antarctica by means of episodic GPS stations (EGPSs) provides an accurate and dense (∼50-km spaced) velocity field. The data, gathered starting in Austral summer 1999, derive from a series of benchmarks belonging to the Victoria Land Network for DEFormation control (VLNDEF) geodetic network. The velocity uncertainties are checked on the basis of length and returning time of the episodic surveys, to obtain a meaningful strain rate field by means of a least-square computation where the contribution of a GPS station is weighted by the inverse square of its velocity error. The study shows that the NVL is characterized by a complex kinematics and that, although three subregions with different prevailing deformational behaviour can be recognized, the single blocks cannot be resolved because too few stations exist. Only features having 150–200 km size at least can be recognized. Moreover, it is demonstrated that an appropriate data processing of EGPS data can lead to an accurate evaluation of the strain rate field even in a harsh environment like Antarctica.
    Description: Published
    Description: 851-862
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: Time-series analysis ; Satellite geodesy ; Geomorphology ; Antarctica ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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    Marine Archaeogeophysical Prospection of Roman Salapia Settlement (Puglia, Italy): Detecting Ancient Harbour Remains (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-04
    Description: The Gulf of Manfredonia and the Tavoliere Plain have experienced intense human colonization since the neolithic times. There is past evidence in the study area of a Roman-age settlement historically known as Salapia, probably located close to the salt-production ponds. In particular, several portions of a partly submerged ancient pier-like structure were found close to Torre Pietra town. This structure has been interpreted as a portion of a dragged-ship channel that connected the town of Salapia to the sea. In this article we discuss the results of a high-resolution geophysical prospecting of the Margherita di Savoia offshore archaeological site (Puglia, Italy). We collected magnetic gradiometric and bathymetric data to map the submerged remains of Salapia harbour. We found evidence of an offshore projection of a Torre Pietra pier-like structure, identifying the direction of the ship channel and possibly the location of the harbour’s defensive post
    Description: Published
    Description: 89-101
    Description: 3.4. Geomagnetismo
    Description: JCR Journal
    Description: restricted
    Keywords: Marine magnetic survey; ; Manfredonia Gulf ; Roman archaeological finds ; buried ruins ; analytic signal; ; horizontal gradient ; 04. Solid Earth::04.05. Geomagnetism::04.05.04. Magnetic anomalies ; 05. General::05.01. Computational geophysics::05.01.01. Data processing
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    Volcanic deformation and flank instability due to magmatic sources and frictional rheology: the case of Mount Etna (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-04
    Description: The overall picture of Mount Etna deformation emerging since a couple of decades of geodetic surveys shows effects of magma accumulation, characterized by inflation/deflation cycle, accompanied by a sliding instability of the southeast flank, whose manifestation is an increase in the horizontal deformation away from the volcano summit. This is a very interesting case to test whether advanced models, taking into account topography, internal structure and frictional rheology, may contribute to a better understanding of the complex interplay among mechanical response, magmatic activity and gravitational load occurring in a volcanic system. Using finite element numerical models we make predictions of surface displacements associated with a simple expansion source and with a dike like vertical discontinuity. A new methodology is developed to initalize the lithostatic stress field according to the material and geometrical complexities of the models considered. Our results show that, while an amplification of the horizontal displacement can be easily obtained up to a maximum distance of 10 km from the source, we have not been able to find any onfiguration to extend further this signal. For the case of Mount Etna this suggests that the large horizontal displacements observed in the east flank along the coast cannot be directly related to magma accumulation below the volcano's summit.
    Description: Published
    Description: 939-953
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: partially_open
    Keywords: Numerical solutions ; Space geodetic surveys ; Elasticity and anelasticity ; Eruption mechanisms and flow emplacement ; Volcanic hazards and risks ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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    High-resolution shallow seismic tomography of a hydrothermal area: application to the Solfatara, Pozzuoli (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-04
    Description: The Solfatara is one of the major volcanoes of the Phlegrean Fields (Campi Flegrei) volcanic complex, and it is located in a densely populated area a few kilometres west of the city of Naples. It is an active resurgent caldera that has been characterized by a rich history of surface–ground deformation and soil diffuse degassing and fumarolic emissions, which are indications of the top of a hydrothermal plume. A seismic survey was completed in May 2009 for the characterization of the main subsurface features of the Solfatara. Using the complete data set, we have carried out surface wave inversion with high spatial resolution. A classical minimization of a least-squares objective function was first computed to retrieve the dispersion curves of the surface waves. Then, the fitting procedure between the data and a three-sedimentlayer forward model was carried out (to a depth of 7 m), using an improved version of the neighbourhood algorithm. The inversion results indicate a NE-SW fault, which is not visible at the surface. This was confirmed by a temperature survey conducted in 2010. A passive seismic experiment localized the ambient noise sources that correlate well with the areas of high CO2 flux and high soil temperatures. Finally, considering that the intrinsic attenuation is proportional to the frequency, a centroid analysis provides an overview of the attenuation of the seismic waves, which is closely linked to the petrophysical properties of the rock. These different approaches that merge complete active and passive seismic data with soil temperature and CO2 flux maps confirm the presence of the hydrothermal system plume. Some properties of the top of the plume are indicated and localized.
    Description: Published
    Description: 1725–1733
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Inverse theory ; Tomography ; Hydrothermal systems ; Europe ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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    Prismatic magnetite magnetosomes from cultivated Magnetovibrio blakemorei strain MV-1: a magnetic fingerprint in marine sediments? (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2017-04-04
    Description: The magnetic properties (first-order reversal curves, ferromagnetic resonance and decomposition of saturation remanent magnetization acquisition) of Magnetovibrio blakemorei, a cultivated marine magnetotactic bacterium, differ from those of other magnetotactic species from sediments deposited in lakes and marine habitats previously studied. This finding suggests that magnetite produced by some magnetotactic bacteria retains magnetic properties in relation to the crystallographic structure of the magnetic phase produced and thus might represent a ‘magnetic fingerprint’ for a specific magnetotactic bacterium. The use of this fingerprint is a non-destructive, new technology that might allow for the identification and presence of specific species or types of magnetotactic bacteria in certain environments such as sediments.
    Description: Published
    Description: 664-668
    Description: 1.8. Osservazioni di geofisica ambientale
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: 3.8. Geofisica per l'ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: batteri magnetotattici ; magnetite ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 04. Solid Earth::04.05. Geomagnetism::04.05.09. Environmental magnetism
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    Seismic velocity structures of southern Italy from tomographic imaging of the Ionian slab and petrological inferences (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2017-10-06
    Description: In this study we have determined detailed Vp and Vs seismic velocity models of the Ionian lithosphere subducting beneath the Tyrrhenian basin and of the surrounding mantle, by applying a post-processing technique to a large sample of local earthquake tomography studies. Our seismic velocity models permit us to infer the presence of low velocity anomalies within the slab, which we interpret as regions that are partially hydrated by fluids released during the subduction process. A petrological interpretation of the velocity anomalies gives new details on the magmatism of the volcanic Aeolian arc. Furthermore our velocity models provide a more detailed description of the boundary of the slab and its connection with the large seismically active Tindari-Letojanni strike slip system. Finally these results allow describing in detail some features of the slab as the presence of lateral and vertical tears. In conclusion, the obtained models provide some constraints for inferences on mantle circulation, and on the geodynamical evolution of the central-western Mediterranean.
    Description: Published
    Description: 751-764
    Description: 2.5. Laboratorio per lo sviluppo di sistemi di rilevamento sottomarini
    Description: JCR Journal
    Description: reserved
    Keywords: Tomography, petrology, Ionian slab ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy
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    Ocean ensemble forecasting. Part I: Ensemble Mediterranean winds from a Bayesian hierarchical model (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2020-02-24
    Description: A Bayesian hierarchical model (BHM) is developed to estimate surface vector wind (SVW) fields and associated uncertainties over the Mediterranean Sea. The BHM–SVW incorporates data-stage inputs from analyses and forecasts of the European Centre for Medium-Range Weather Forecasts (ECMWF) and SVW retrievals from the QuikSCAT data record. The process-model stage of the BHM–SVW is based on a Rayleigh friction equation model for surface winds. Dynamical interpretations of posterior distributions of the BHM–SVW parameters are discussed. Ten realizations from the posterior distribution of the BHM–SVW are used to force the data-assimilation step of an experimental ensemble ocean forecast system for the Mediterranean Sea in order to create a set of ensemble initial conditions. The sequential data-assimilation method of the Mediterranean forecast system (MFS) is adapted to the ensemble implementation. Analyses of sample ensemble initial conditions for a single data-assimilation period in MFS are presented to demonstrate the multivariate impact of the BHM–SVW ensemble generation methodology. Ensemble initial-condition spread is quantified by computing standard deviations of ocean state variable fields over the ten ensemble members. The methodological findings in this article are of two kinds. From the perspective of statistical modelling, the process-model development is more closely related tophysicalbalances than inpreviousworkwithmodels for the SVW.Fromthe ocean forecast perspective, the generation of ocean ensemble initial conditions via BHM is shown to be practical for operational implementation in an ensemble ocean forecast system. Phenomenologically, ensemble spread generated via BHM–SVW occurs on ocean mesoscale time- and space-scales, in close association with strong synoptic-scale wind-forcing events. A companion article describes the impacts of the BHM–SVW ensemble method on the ocean forecast in comparisons with more traditional ensemble methods.
    Description: Published
    Description: 858–878
    Description: JCR Journal
    Description: embargoed_20140501
    Keywords: QuikSCAT surface winds ; 03. Hydrosphere::03.01. General::03.01.05. Operational oceanography
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  • 39
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    Intensity prediction equations for Central Asia (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2020-02-24
    Description: In this study, new intensity prediction equations are derived for Central Asia, considering about 6000 intensity data points from 66 earthquakes encompassing the surface-wave magnitude range of 4.6–8.3. The suitability of the functional form used for constructing the model is assessed by comparing its predictions with those achieved through a non-parametric model. The parametric regressions are performed considering different measures of the source-to-site distance, namely the hypocentral, epicentral and the extended distance metrics. The latter is defined as the minimum distance from the site to a line crossing the epicentres, oriented along the strike of the earthquake and having a length estimated from the event’s magnitude. Although the extended distance is introduced as a preliminary attempt to improve the prediction capability of the model by considering the finiteness of the fault extension, the standard deviation of the residual distribution obtained considering the extended distance (σ = 0.734) does not show an improvement with respect to the results for the epicentral distance (σ = 0.737). The similarity of the two models in term of average residuals is also confirmed by comparing the interevent errors obtained for the two regressions, obtaining very similar values for all earthquakes but the 1911, M 8.2 Kemin event. In particular, different evidences suggest that the magnitude of this event could be overestimated by about half a magnitude unit. Regarding the variability of the residual distribution, all the three considered components (i.e. interevent, interlocation and record-to-record variances) are not negligible, although the largest contribution is related to the record-to-record variability, suggesting that both source and propagation as well as site effects not captured by the considered model influence the spatial variability of the intensity values.
    Description: Published
    Description: 327–337
    Description: JCR Journal
    Description: restricted
    Keywords: Earthquake ground motions ; 05. General::05.01. Computational geophysics::05.01.99. General or miscellaneous
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  • 40
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    Respiratory principles of oxygen-exchange in water breathing animals (2012)
    Wiley-Blackwell
    In:  EPIC3Oxidative Stress in Aquatic Ecosystems, Abele, D., Zenteno-Savin, T, Vasquez-Medina, J. (Eds) Oxidatve Stress in Aquatic Ecosystems, Blackwell-Wiley., Oxford UK, Wiley-Blackwell, 15 p., pp. 141 -156, ISBN: 978-1-4443-3548-4
    Details
    Publication Date: 2019-07-16
    Repository Name: EPIC Alfred Wegener Institut
    Type: Inbook , peerRev
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  • 41
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    The stability of European rocky shore assemblages: variation across a latitudinal gradient and the role of canopy-forming macroalgae. (2012)
    Wiley-Blackwell
    In:  EPIC3Oikos, Wiley-Blackwell
    Details
    Publication Date: 2014-04-17
    Description: Compensatory dynamics, overyielding and statistical averaging are mechanisms promoting the temporal stability of natural communities. Using the model of European intertidal rocky shore assemblages and collating 17 datasets, we investigated how the strength of these stability-enhancing mechanisms varies with latitude and how it can be altered by the loss of habitat-formers (e.g. canopy-forming macroalgae). Community stability decreased with increasing latitude, mostly as a consequence of a greater synchronization of species fluctuations. Statistical averaging and overyielding (i.e. richness effects) promoted stability, but their strength did not vary with latitude. The experimental removal of macroalgal canopies caused a strengthening of the statistical averaging effect that was consistent across the latitudinal gradient investigated. Nonetheless, the loss of canopies depressed stability by enhancing the synchronization of species fluctuations on southernmost shores, while it had weak effects on shores at higher latitudes. Variation in life-history traits among canopy-forming species and/or in prevailing environmental conditions across a gradient of latitude could underlie variable effects of habitat-formers on species fluctuations. Our study shows i) that the stability of intertidal assemblages and strength of compensatory dynamics varies with latitude, ii) that canopy-forming macroalgae, exerting a strong control on understorey species, can influence the strength of compensatory dynamics and iii) that biological forcing (i.e. facilitation) can be as important as environmental forcing in enhancing the synchronization of species fluctuations.
    Repository Name: EPIC Alfred Wegener Institut
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  • 42
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    PROVENANCING OF LIGHTWEIGHT VOLCANIC STONES USED IN ANCIENT ROMAN CONCRETE VAULTING: EVIDENCE FROM ROME (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2021-12-15
    Description: Some of the most structurally innovative concrete vaults built in imperial Rome employed lightweight volcanic rocks to reduce the lateral thrust on the supporting walls, the most famous being the Pantheon. Roman concrete (opus caementicium) was made up of mortar binding together pieces of large aggregate (caementa) usually ranging from 10 to 20 cm long, which were hand laid in the mortar (as opposed to being poured as is typical in modern concrete), so that it resembles mortared rubble. A key aspect of the development of large-scale concrete vaulting was the ability to regulate the weight of the ingredients in order to reduce the weight of the vaults and to control the forces within the structure. The volcanic environment along the west coast of Italy provided numerous stones of different weights and physical properties from which the builders could choose (Fig. 1), including pumice and scoria, which were the most common choices for the lightweight caementa of the most innovative vaulted structures. Because these materials were produced by many of the Italian volcanoes, our goal was to establish the provenance of those used in vaults in Rome in order to understand better the supply network. We first used thin sections to narrow the potential sources and then we submitted selected samples to X-ray fluorescence
    Description: Published
    Description: 707-727
    Description: JCR Journal
    Description: restricted
    Keywords: concrete vault ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
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    Traversing nature’s danger zone: getting up close with Sumatra’s volcanoes. (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2023-02-10
    Description: The Indonesian island of Sumatra, located in one of the most active zones of the Pacific Ring of Fire, is characterized by a chain of subduction-zone volcanoes which extend the entire length of the island. As a group of volcanic geochemists, we embarked upon a five-week sampling expedition to these exotic, remote, and in part explosive volcanoes (SAGE 2010; Sumatran Arc Geochemical Expedition). We set out to collect rock and gas samples from 17 volcanic centres from the Sumatran segment of the Sunda arc system, with the aim of obtaining a regionally significant sample set that will allow quantification of the respective roles of mantle versus crustal sources to magma genesis along the strike of the arc. Here we document our geological journey through Sumatra’s unpredictable terrain, including the many challenges faced when working on active volcanoes in pristine tropical climes.
    Description: Swedish Science Foundation (VR), Scripps Institution of Oceanography, Istituto Nazionale di Geofisica e Vulcanologia (INGV), Upp-sala University Centre for Natural Disaster Science (CNDS) and Otterborgska donationsfonden
    Description: Published
    Description: 64-70
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: N/A or not JCR
    Description: restricted
    Keywords: Sumatra ; Indonesia ; geochemisty ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 44
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    Do earthquake storms repeat in the Apennines of Italy? (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2022-05-24
    Description: Series of multiple main shocks that develop on adjacent faults is a typical way in which active extension is accommodated in the Apennines of Italy. This behaviour is explained by fault interaction that occurs at a scale ranging from seconds to days, yielding a space–time clustering of earthquakes, termed as earthquake storms. We show that the seismic energy released by historical earthquakes in central Apennines is clustered into two main small time periods, around 600 and 300 years ago, during which a great portion of the normal faulting belt failed. We favour the hypothesis that clustering results from sudden input of deep fluids into the brittle upper crust. The roughly 300 years periodicity and the 3–4 mm year−1 of tectonic extension suggest that earthquake storms need to be taken into account in seismic hazard scenarios.
    Description: Published
    Description: 300–306
    Description: JCR Journal
    Description: restricted
    Keywords: Apennines ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous
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  • 45
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    Predictability study on the aftershock sequence following the 2011 Tohoku-Oki, Japan, earthquake: first results (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2022-06-08
    Description: Although no deterministic and reliable earthquake precursor is known to date, we are steadily gaining insight into probabilistic forecasting that draws on space–time characteristics of earthquake clustering. Clustering-based models aiming to forecast earthquakes within the next 24 hours are under test in the global project ‘Collaboratory for the Study of Earthquake Predictability’ (CSEP). The 2011 March 11 magnitude 9.0 Tohoku-Oki earthquake in Japan provides a unique opportunity to test the existing 1-day CSEP models against its unprecedentedly active aftershock sequence. The original CSEP experiment performs tests after the catalogue is finalized to avoid bias due to poor data quality. However, this study differs from this tradition and uses the preliminary catalogue revised and updated by the Japan Meteorological Agency (JMA), which is often incomplete but is immediately available. This study is intended as a first step towards operability-oriented earthquake forecasting in Japan. Encouragingly, at least one model passed the test in most combinations of the target day and the testing method, although the models could not take account of the megaquake in advance and the catalogue used for forecast generation was incomplete. However, it can also be seen that all models have only limited forecasting power for the period immediately after the quake. Our conclusion does not change when the preliminary JMAcatalogue is replaced by the finalized one, implying that the models perform stably over the catalogue replacement and are applicable to operational earthquake forecasting. However, we emphasize the need of further research on model improvement to assure the reliability of forecasts for the days immediately after the main quake. Seismicity is expected to remain high in all parts of Japan over the coming years. Our results present a way to answer the urgent need to promote research on time-dependent earthquake predictability to prepare for subsequent large earthquakes in the near future in Japan.
    Description: Published
    Description: 653-658
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: restricted
    Keywords: Time-series analysis ; Probabilistic forecasting ; Seismicity and tectonics ; Computational seismology ; Statistical seismology ; Asia ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability
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  • 46
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    Multiproxy record for the last 4500 years from Lake Shkodra (Albania/Montenegro) (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2022-06-10
    Description: A multi-proxy record is presented for approximately the last 4500 cal a BP from Lake Shkodra, Albania/Montenegro. Lithological analyses, C/N ratio and δ13C of the organic and inorganic carbon component suggest that organic matter and bulk carbonate are predominantly authigenic. The δ18O record of bulk carbonate indicates the presence of two prominent wet periods: one at ca. 4300 cal a BP and one at ca. 2500–2000 cal a BP. The latter phase is also found in southern Spain and Central Italy, and represents a prominent event in the western and central Mediterranean. In the last 2000 years, four relatively wet intervals occurred between ca. 1800 and 1500 cal a BP (150–450 AD), 1350–1250 (600–700 AD), 1100–800 (850–1150 AD), and at ca. 90 cal a BP (1860 AD). Between ca. 4100 and 2500 cal a BP δ18O values are relatively high, with three prominent peaks indicating drier conditions at ca. 4100–4000 cal a BP, ca. 3500 and at ca. 3300 cal a BP. Four additional drier events are identified at 1850 (ca. 100 AD), 1400 (ca. 550 AD), 1150 (800 AD) and ca.750 cal a BP (1200 AD). The pollen record does not show changes in accordance with these episodes owing to the poor sensitivity of vegetation in this area, which is dominated by an orographic rainfall effect and where changes in altitudinal vegetation belts do not affect the pollen rain in the lake catchment. However, since ca. 900 cal a BP a significant decrease in the percentage arboreal pollen and in pollen concentrations suggest major deforestation produced by human activities. Copyright © 2012 John Wiley & Sons, Ltd.
    Description: Published
    Description: 780-789
    Description: 3.7. Dinamica del clima e dell'oceano
    Description: JCR Journal
    Description: reserved
    Keywords: Lake Shkodra ; late Holocene ; Mediterranean ; palaeoclimate ; stable isotopes ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology
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  • 47
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    Convective support of long-wavelength topography in the Apennines (Italy) (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2022-05-24
    Description: Two different free-air gravity datasets from the Apennines have been analysed in the frequency domain to investigate the mechanisms of support of topography. At short wavelength (λ〈150 km) the best fit between the observed and the calculated admittance gives a value of the elastic thickness of 3.7 km. The observed behaviour of the admittance at larger wavelengths (λ〉150 km) shows that such topography is not supported by elastic stresses in the lithosphere but is dynamically supported by mantle convection. The distribution of gravity anomalies and topography suggests that the mantle is rising beneath the main topographic bulge of the Apennines and that this flow is maintained by buoyancy forces, rather than being driven by movement of the subducted slab.
    Description: Published
    Description: 228-233
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: Dynamic Topography ; Gravity ; Apennines ; 04. Solid Earth::04.03. Geodesy::04.03.03. Gravity and isostasy
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  • 48
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    GPS ground deformation patterns at Mount St. Helens (Washington, USA) from 2004 to 2010 (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2022-05-24
    Description: GPS measurements on Mount St. Helens spanning the 2004.00-2010.85 time interval, encompassing the 2004-2008 dome-building eruption, were analyzed. First, a local reference frame was derived in order to isolate the volcanic ground deformation from the background tectonic pattern related to the interactions between the Pacific, Juan de Fuca and North American plates. Secondly, the resulting ground deformation patterns were modelled to constrain magmatic sources. Results suggest a vertically elongated magma chamber centred at 8 - 9 km depth beneath the summit area that deflated during the beginning of the dome growth and inflated since January 2008, evidencing that a primary magma reservoir was active both during and after the eruption in a magmatic system persistent over the time.
    Description: Published
    Description: 148-155
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: Mount St. Helens ; Ground deformation modelling ; local reference frame ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 49
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    The Palaeocene ‘‘top chron C27n’’ transient greenhouse episode: evidence from marine pelagic Atlantic and peri-Tethyan sections (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2022-05-24
    Description: The early Cenozoic, which is punctuated by several negative carbon isotope excursions (CIEs), was a time of climatic and oceanographic transition from ’Greenhouse’ to ’Icehouse’ conditions. The occurrence of a 0.5& CIE starting at the top of Chron C27n (TC27N) is reconfirmed with stable isotope data from Zumaia (Spain) and Bjala (Bulgaria) localities. Spectral analysis on respective carbonate ⁄magnetic susceptibility proxy records substantiates the orbital cyclostratigraphy allowing correlation to a high-resolution benthic foraminifera isotope record from ODP Pacific Site 1209, that indicates a coeval 2 C transient warming. The hyperthermal event lasts 200 ka, contrasting with other short-lived events from the Eocene, and displays a relatively rapid onset and a longer tailing back to pre-event values similar to the Palaeocene–Eocene Thermal Maximum (PETM), though lower in amplitude. That a causal trigger for the TC27N event may be the onset of volcanism in the North Atlantic Igneous Province (NAIP) can be inferred from a 200-m-thick lava pile erupted during C27n ⁄ C26r polarity transition in the E Greenland margin.
    Description: Published
    Description: 477-486
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: hyperthermal ; isotope excursion ; TC27N event ; Zumaia ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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    Comparison of characteristic and Gutenberg–Richter models for time-dependentM ≥ 7.9 earthquake probability in the Nankai-Tokai subduction zone, Japan (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2022-06-10
    Description: Earthquake forecasts are usually underinformed, and can be plagued by uncertainty in terms of the most appropriate model, and parameter values used in that model. In this paper, we explore the application of two different models to the same seismogenic area. The first is a renewal model based on the characteristic earthquake hypothesis that uses historical/palaeoseismic recurrence times, and fixed rupture geometries. The hazard rate is modified by the Coulomb static stress change caused by nearby earthquakes that occurred since the latest characteristic earthquake. The second model is a very simple earthquake simulator based on plate-motion, or fault-slip rates and adoption of a Gutenberg–Richter magnitude–frequency distribution. This information is commonly available even if historical and palaeoseismic recurrence data are lacking. The intention is to develop and assess a simulator that has a very limited parameter set that could be used to calculate earthquake rates in settings that are not as rich with observations of large-earthquake recurrence behaviour as the Nankai trough. We find that the use of convergence rate as a primary constraint allows the simulator to replicate much of the spatial distribution of observed segmented rupture rates along the Nankai, Tonankai and Tokai subduction zones. Although we note rate differences between the two forecast methods in the Tokai zone, we also see enough similarities between simulations and observations to suggest that very simple earthquake rupture simulations based on empirical data and fundamental earthquake laws could be useful forecast tools in information-poor settings.
    Description: Published
    Description: 1673-1688
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: restricted
    Keywords: Time series analysis ; Spatial analysis ; Probability distributions ; Seismic cycle ; Earthquake interaction ; forecasting, and prediction ; Statistical seismology. ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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    Stress effects on metabolism and energy budgets in mollusks (2012)
    Wiley-Blackwell
    In:  EPIC3Oxidative Stress in Aquatic Ecosystems, Oxidative Stress in Aquatic Ecosystems, Wiley-Blackwell, 18 p., pp. 263-280, ISBN: 978-1-4443-3548-4
    Details
    Publication Date: 2023-06-21
    Description: The chapter will summarize and critically review metabolic responses to environmental stress and stress effects on energy budgets in mollusks. Metabolic adaptations to environmental stress will be analyzed including alternative energy conserving pathways, aerobic/anaerobic transitions and metabolic arrest. Their role in the efficient use of energy substrates and in the maintenance of cellular homeostasis and redox status will be discussed. General stress effects on energy budget at different organization levels (from the cell to the whole-organism) will be analyzed including energy uptake, assimilation, conversion and expenditure, as well as the metabolic costs associated with stress resistance (including antioxidant protection, chaperone function and damage repair). We will compare metabolic responses to moderate and extreme levels of environmental stressors using temperature, ocean acidification, salinity, oxygen deficiency and toxic metal stress as examples. This chapter will also outline the future research directions to improve our understanding of the stress effects on bioenergetics in mollusks and other invertebrates. Keywords: Stress, metabolic adaptation, metabolic arrest, bioenergetics, cellular defense, energy trade-offs
    Repository Name: EPIC Alfred Wegener Institut
    Type: Inbook , peerRev
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    Oxidative Stress in Aquatic Ecosystems (2012)
    Wiley-Blackwell
    In:  EPIC3Wiley-Blackwell, ISBN: 9781444335484
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    Publication Date: 2023-06-21
    Repository Name: EPIC Alfred Wegener Institut
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    Iron in coastal marine ecosystems: role in oxidative stress (2012)
    Wiley-Blackwell
    In:  EPIC3Oxidative Stress in Aquatic Ecosystems, Oxidative Stress in Aquatic Ecosystems, Oxford, Wiley-Blackwell, 524 p., pp. 115-126, ISBN: 978 1 4443 3548 4
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    Publication Date: 2023-06-21
    Repository Name: EPIC Alfred Wegener Institut
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    Crustal structure and seismotectonics of central Sicily (southern Italy): new constraints from instrumental seismicity (2012)
    Wiley-Blackwell
    Details
    Publication Date: 2024-05-09
    Description: In this paper, we propose a new model of the crustal structure and seismotectonics for central Sicily (southern Italy) through the analysis of the depth distribution and kinematics of the instrumental seismicity, occurring during the period from 1983 to 2010, and its comparison with individual geological structures that may be active in the area. The analysed data set consists of 392 earthquakes with local magnitudes ranging from 1.0 to 4.7. We defined a new, detailed 1-D velocity model to relocate the earthquakes that occurred in central Sicily, and we calculated a Moho depth of 37 km and a mean VP/VS ratio of 1.73. The relocated seismic events are clustered mainly in the area north of Caltanissetta (e.g. Mainland Sicily) and in the northeastern sector (Madonie Mountains) of the study area; only minor and greatly dispersed seismicity is located in the western sector, near Belice, and along the southern coast, between Gela and Sciacca. The relocated hypocentral distribution depicts a bimodal pattern: 50 per cent of the events occur within the upper crust at depths less than ~16 km, 40 per cent of the events occur within the middle and depth crust, at depths between 16 and 32 km, and the remaining 10 per cent occur at subcrustal depths. The energy release pattern shows a similar depth distribution. On the basis of the kinematic analysis of 38 newly computed focal plane solutions, two major geographically distinct seismotectonic domains are distinguished: the Madonie Mountain domain, with prevalent extensional and extensional-oblique kinematics associated with upper crust Late Pliocene–Quaternary faulting, and the Mainland Sicily domain, with prevalent compressional and compressional-oblique kinematics associated with thrust faulting, at mid to deep crust depth, along the north-dipping Sicilian Basal Thrust (SBT). The stress inversion of the Mainland Sicily focal solutions integrated with neighbouring mechanisms available in the literature highlights a regional homogeneous compressional tensor, with a subhorizontal NNW–SSE-striking σ1 axis. In addition, on the basis of geodetic data, the Mainland Sicily domain may be attributed to the SSE-ward thrusting of the Mainland Sicily block along the SBT plane. Seismogenic shearing along the SBT at mid-crustal depths was responsible for the unexpected Belice 1968 earthquake (Mw 6.1), with evident implications in terms of hazard assessment.
    Description: Published
    Description: 1237-2252
    Description: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Description: 3.2. Tettonica attiva
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: 5.2. TTC - Banche dati di sismologia strumentale
    Description: JCR Journal
    Description: restricted
    Keywords: Seismicity and tectonics ; Continental tectonics: compressional ; Dynamics: seismotectonics ; Crustal structure ; Europe ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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    Reversion of the B to A transition of DNA induced by specific interaction with the oligopeptide distamycin A (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 823-831 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The effect of the DNA-binding oligopeptide distamycin A on the B to A transition of DNA in ethanol/water solutions has been studied by means of CD. (The overbars indicate that it does not matter which particular form of the corresponding families is considered.) The results show that increasing the concentration of distamycin A reverses the A conformation (in 82% ethanol) to the B conformation due to its strong binding and stabilization of the latter. In accordance with previous data for pure aqueous solutions, a site size of 3.5 base pairs is obtained from the studies in water/ethanolic solutions. From the data on the B to A transition in the presence of distamycin A, we estimated the length of the cooperativity ν0 = 10 base pairs.The results demonstrate that the oligopeptide systems of distamycin, as well as those of netropsin, are effective stabilizers of the DNA B-conformation.
    Additional Material: 6 Ill.
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    URL: http://dx.doi.org/10.1002/bip.1980.360190408
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    NMR evidence for a type I β-turn in (Pro2)-tetrapeptides and interdependence of cis:Trans isomerism, ring flexibility, and backbone conformation (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 781-804 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Tetrapeptides with proline in position 2, asparagine or leucine in position 3, and glycine in positions 1 and 4, with end groups free or blocked on the N-terminal side, were studied in their various ionic states in 2H2O and in Me2SO-d6 by 1H- and 13C-nmr. In order to clarify or refine some details, successive substitutions of the residues in these peptides with amino acids enriched to 85% in 13C, or to 85% 13C plus 97% 2H were carried out. The 1H and 13C chemical shifts as well as the 1H-1H, 13C-13C, and 13C-1H coupling constants and the signal intensities show strong similarity of behavior between the tetrapeptides of asparagine and leucine. The main conformational characteristics are (1) the almost total stabilization of the trans conformer in the type I β-turn structure when the peptide is in the zwitterion state dissolved in Me2SO. This is deduced from the 3JC3αH-N3H and the 3JC2′-H3α coupling constants, which both furnish a dihedral angle of φ3 = -90°, and from the positive value of the temperature coefficient of the glycine-4 amide protons, which suggests a type 4 → 1 hydrogen bond; (2) the evolution of cis and trans isomer fractions which change with the ionic state of the peptides in Me2SO, whereas they remain constant in aqueous solution; and (3) the conformation of the pyrrolidine ring as it follows the variations in cis:trans isomer populations together with the side-chain rotamer fractions of the residue in position 3. In the β-turn conformation the isomer cis is less abundant and the pyrrolidine ring is more flexible; this explains the perfect accommodation of the proline residue in position 2 of a bend. The interdependence of these phenomena where interactive forces play a predominant role underlines the importance of cooperative effects in the molecule. The results also suggest that the cis isomer of proline can adapt itself just as well as the trans isomer to position 2 of a type I β-turn.
    Additional Material: 3 Ill.
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    URL: http://dx.doi.org/10.1002/bip.1980.360190406
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    Transport properties of particles with segmental flexibility. II. Decay of fluorescence polarization anisotropy from hinged macromolecules (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 913-930 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An algorithm is presented for the Monte Carlo simulation of the decay of fluorescence polarization from segmentally flexible molecules. Based on the random walk model of Brownian motion, the treatment explicitly follows the stochastic changes in the diffusion coefficients as the molecule bends. It includes the effects of a linear restoring force opposing the bending and the effects of hydrodynamic coupling between the translational, rotational, and bending motions. One application is presented: the simulation of anisotropy decay curves for hinged rods. A variety of decay curves are obtained, including single- and multiexponential behavior, and the following conclusions are reached: (1) increasing the flexibility is usually, but not always, accompanied by a more rapid rate of depolarization; (2) reducing the size of the fluorescent subunit will usually, but not always, increase the rate of depolarization; and (3) the complex interplay between the effects of molecular shape, relative sizes of the subunits, restoring force, and orientation of the transition dipoles renders it unlikely that any simple method can be used to interpret anisotrophy data without simulation. In particular, it is not possible to determine the extent of bending by fitting the data with the two-exponential approximation used by some investigators in the past.
    Additional Material: 6 Ill.
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    URL: http://dx.doi.org/10.1002/bip.1980.360190414
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    13C-nmr spectroscopy of red algal galactans (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 977-990 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 13C-nmr spectra of red seaweed galactans, belonging to the agar and carrageenan groups or having the “intermediate” type of structure, were interpreted on the basis of 13C-nmr spectra of model compounds. Signal assignments have been made for most of the known extreme structures of such galactans. 13C-nmr spectroscopy was shown to be a rapid and convenient method of structural analysis, which permits one to determine the type of galactan structure, the absolute configurations of its constituents (galactose and 3,6-anhydrogalactose), and the positions of the sulfate and O-methyl groups in a polysaccharide molecule.
    Additional Material: 3 Ill.
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    Dielectric changes in hyaluronate solutions at microwave frequencies as a function of concentration, system pH, and temperature (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 931-944 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The dielectric response of human umbilical cord hyaluronic acid in various environments has been studied at microwave frquencies using a resonant microwave cavity as a probe. Both the real and imaginary parts of complex dielectric constant and the loss tangent for hyaluronate solutions are obtained by utilizing equations for perturbation of a resonant cavity. Dielectric changes at room temperature have been observed in aqueous solutions of hyaluronic acid as a function of concentration ranging from 0 to 350 mg/ml. The data indicate the existence of ordered phases in hyaluronate solutions at selective concentrations, that is, exhibiting lyotropic-type transitions. Hyaluronate solutions at 1.5 and 3 mg/ml concentrations have been studied at various pH in the range of 6-8 and at constant ionic strength 0.1. A temperature-dependent transition in hyaluronate solution of 120 mg/ml concentration has been observed at physiological temperature. It is shown that this temperature-dependent behavior can be related to the orientational polarizability term in the Debye theory of polar molecules in liquids.
    Additional Material: 8 Ill.
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    URL: http://dx.doi.org/10.1002/bip.1980.360190415
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    A quantitative test of Zimm's model for the rotor-speed-department sedimentation of linear DNA molecules (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 945-964 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In 1974, Zimm described a theory which predicts that the sedimentation coefficient of high-molecular-weight DNA will decrease as the rotor speed of measurement increases. In 1979, this theory was revised, and the new formula predicts speed-dependence effects that are substantially smaller than the predictions of the original version. This report describes the results of subjecting both the original and the revised versions of the theory to quantitative tests using a well-defined sucrose-gradient system and a DNA of known molecular weight (T4c DNA). T4c bacteriophage is a mutant, whose DNA contains the unmodified base cytosine, instead of the glucosylated hydroxymethylcytosine characteristic of the T-even bacteriophages, and has a molecular weight of 115 ± 3 × 106. The DNA of the wild-type phage (T4D+) was also used in some experiments.In addition to the quantitative tests, the experiments test for an effect first observed by Rubenstein and Leighton, which showed that the sedimentation coefficient measured for T2 DNA depended on the composition of the centrifuge tube used for the measurement (tube composition effect). It can be inferred from this observation that an interaction occurs between particle and tube wall during sedimentation, and this leads to a reduction in sedimentation velocity independent of the reduction in S described by Zimm's theory.The results show that in the range of 25,000-50,000 rpm, the original but theoretically incorrect form of the theory quite accurately describes the sedimentation behavior of both T4c and T4D+ DNA, although T4D+ was a special case in some respects. The revised (corrected) form of the theory predicts much less of a speed-dependence effect than that actually observed. The discrepancy between corrected theory and observation suggests that other factors (perhaps arising from the use of the swinging bucket rotor geometry) are causing the additional observed reduction in S20,w. However, the experiments show that the tube composition effect does not seem to be one of these.
    Additional Material: 7 Ill.
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    URL: http://dx.doi.org/10.1002/bip.1980.360190502
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    Proton NMR study of the interaction of cis-dichloro-diamine-platinum(II) with poly(I) and poly(I)·poly(C) (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 1299-1309 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The fixation of cis (NH3)2Cl2Pt(II) to poly(I)·poly(C) leads to the formation of two complexed species. One involves coordination to a single base (accounting for about 70% of the total platinum bound over the rb range 0.07-0.25) and the other to two bases which are not adjacent to each other but may be on the same strand and separated by a loop. Reaction of the platinum compound with poly(I) gives in addition to the above two species a minor one (about 15%, independent of rb over the range 0.05-0.30) in which the platinum is bound to two adjacent bases. The availability of such coordination reduces the dominance of the 1:1 species, which, however, remains the major one (ca. 55%).
    Additional Material: 3 Ill.
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    URL: http://dx.doi.org/10.1002/bip.1980.360190706
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    Heavy-atom effects associated with methylmercury (II) binding to rabbit glyceraldehyde-3-phosphate dehydrogenase (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 1329-1344 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The complex of CH3Hg(II) with the accessible cysteines of glyceraldehyde-3-phosphate dehydrogenase (GAPD, EC 1.2.1.12) from rabbit muscle has been studied by phosphorescence and optically detected magnetic resonance (ODMR) spectroscopy. The wavelength dependence of the phosphorescence decay kinetics has also been measured. Comparison of CH3Hg(II)-GAPD with GAPD by these methods shows that a specific optically resolved tryptophan site of GAPD is perturbed by the interaction with a nearby mercury atom. The perturbation on the luminescence and ODMR properties is typical of an external heavy-atom effect. Based on the x-ray diffraction structure of the lobster enzyme, it is proposed that the heavy-atom effect results from the interaction of tryptophan-310 with CH3Hg(II) bound to cysteine-281 in the rabbit muscle enzyme.
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    Interaction of spermine with different forms of DNA. A conformational study (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 1415-1434 
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    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The energy of interaction of a spermine molecule with the A- and B-forms of DNA has been calculated, assuming that the molecule of spermine is fixed in the narrow groove of the DNA helix with the formation of hydrogen bonds between the amino groups of spermine and the phosphate groups of DNA. The atom-atom potentials method was used. Optimal structures for the A-DNA-spermine and B-DNA-spermine complexes are suggested. It is shown that, in agreement with the experimental data, the interaction of the spermine molecule with the A-DNA is energetically more favorable than that with the B-DNA. Two main factors are responsible for this: (1) the distance between neighboring phosphates of the chain in A-DNA (which is about 1 Å less than that in B-DNA) corresponds better to the distance between the amino groups of the propyl part of spermine; and (2) the orientation of phosphate groups in A-DNA inside the groove is preferable for complex formation with spermine to the outside groove arrangement of the phosphates in B-DNA. These conclusions are further confirmed by the calculations for DNA-propane diamine complexes.
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    Crystal and molecular structure of isoleucinomycin, cyclo[-(D-Ile-Lac-Ile-D-Hyi)3-](C60H102N6O18) (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 1517-1534 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The crystal structure of a synthetic analog of valinomycin, cyclo[-(D-Ile-Lac-Ile-D-Hyi)3-] (C60H102N6O18), has been determined by x-ray diffraction procedures. The crystals are orthorhombic, space group P212121, with cell parameters a = 11.516, b = 15.705, c = 39.310 Å, and Z = 4. The atomic coordinates for the C, N, O atoms were refined in the anisotropic thermal motion approximation and for the H atoms in the isotropic approximation. Values of standard (R) and weighted (Rw) reliability factors after refinement are 0.073 and 0.056, respectively. The structure is completely asymmetric. The cyclic molecular backbone is stabilized by six intramolecular hydrogen bonds N—H…O=C, five bonds being of the 4→1 type and one being of the 5→1 type. The side chains are located on the molecular periphery. The conformational state of isoleucinomycin in the crystal is intermediate between the corresponding crystalline states of valinomycin and meso-valinomycin. The observed conformation suggests that complexation could proceed via entry of the ion at the face possessing the L-Lac residues, the less crowded face.
    Additional Material: 5 Ill.
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    Conformational analysis of the milk oligosaccharides (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 1555-1566 
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    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Possible conformations of lacto-N-tetraose, lacto-N-neotetraose, related disaccharides, and other milk oligosaccharides have been studied by an energy-minimization procedure using empirical potential functions. Lacto-N-tetraose favors a “curved” conformation, while lacto-N-neotetraose favors an approximately “straight” conformation. These two conformations differ mainly in the position of the terminal galactose residue with respect to the rest of the molecule. This difference explains the greater strength of lacto-N-neotetraose compared with lacto-N-tetraose in its ability to inhibit the cross-reaction of blood group P1 fractions with Type XIV pneumococcal antipolysaccharide. Although the favored conformation of lacto-N-tetraose (inactive) agrees with the model proposed by the earlier workers, that for lacto-N-neotetraose (active) differs. The favored conformations for the disaccharides galactose-β(1-4)-N-acetylglucosamine, galactose-β(1-3)-N-acetylglucosamine, and lactose are similar in overall shape, differing only in the nature and orientation of the side groups. This explains their nearly equal inhibitory activity. These theoretical models also explain the increased activity of lacto-N-fucopentaose I over that of lacto-N-tetraose and the relative activities of the substituted lactoses. The present studies suggest that it is the overall shape of the molecule which is important for activity, rather than the terminal β(1-4)-linked galactose residue alone.
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    Influence of methanol on the rotational diffusion of poly(L-lysine) in the helix-coil transition (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 1571-1585 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 13C spin-lattice relaxation times of poly(L-lysine) have been obtained at 67.9 MHz in aqueous solution and in a mixed solvent (40% methanol/60% water). A concomitant determination of the conformation by CD permits the correlation of conformation and rotational diffusion of the polymer. The dependence on pH of the spin-lattice relaxation times of the 13Cα and the side-chain carbon resonances reflects the diffusional motion in the random-coil conformation, in the helix-coil transition, and in the conformation of the α-helix. In the mixed solvent the reorientational correlation time of the Cα-Hα vector increases from τ = 0.37 nsec (random coil) to τ = 12.0 nsec (α-helix). In aqueous solution the correlation time of this vector increases from τ = 0.33 nsec (random coil) to τ ≫ 11 nsec. The reorientation rates of the side-chain methylene groups in the two solvents are markedly different. The reorientation of all methylene groups is reduced in the mixed solvent.
    Additional Material: 7 Ill.
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    Solid-state conformation of copolymers of β-benzyl-L-aspartate with L-alanine, L-leucine, L-valine, γ-benzyl-L-glutamate, or ∊-carbobenzoxy-L-lysine (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 1603-1615 
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    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The solid-state conformation of copolymers of β-benzyl-L-aspartate [L-Asp(OBzl)] with L-leucine (L-Leu), L-alanine (L-Ala), L-valine (L-Val), γ-benzyl-L-glutamate [L-Glu(OBzl)], or ∊-carbobenzoxy-L-lysine (Cbz-L-Lys) has been studied by ir spectroscopy and circular dichroism (CD). The ir spectra in the region of the amide I and II bands and in the region of 700-250 cm-1 have been determined. The results from the ir studies are in good agreement with data obtained by CD experiments. Incorporation of the amino acid residues mentioned above into poly[L-Asp(OBzl)] induces a change from the left-handed into the right-handed α-helix. This conformational change for the poly[L-Asp(OBzl)] copolymers was observed in the following composition ranges: L-Leu, 0-15 mol %; L-Ala, 0-32 mol %; L-Val, 0-8 mol %; L-Glu(OBzl), 3-10 mol %; and Cbz-L-Lys, 0-9 mol %.
    Additional Material: 7 Ill.
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    Physical aging of dry elastin (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 1667-1673 
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    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Dry purified ligamentum nuchae elastin has been investigated for physical aging. The samples were quenched from a temperature (197°C) close to the softening point to a number of measuring temperatures ranging from -20 to +180°C. At each temperature, the small-strain torsional creep properties were determined at a number of elapsed intervals after the quench. Aging effects were found over the whole temperature range, and the creep and aging behavior of elastin turned out to be very similar to that of synthetic polymers.
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    DNA backbone conformation in cis-syn pyrimidine[]pyrimidine cyclobutane dimersPresented at the American Society of Biological Chemists and Biophysical Society Meeting, June 1-5, 1980, New Orleans, Louisiana [(1980) Fed. Proc. 39, 1879]. (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 1695-1701 
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    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
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    Toroidal elastic supercoiling of DNA (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 1705-1713 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: Covalently closed circular DNA can exist in different configurations known as circular, toroidal, and interwound. Changes among these forms can be made in several ways, including the insertion of dye molecules between adjacent base pairs, which tends to untwist the double-helical structure. The aim of this paper is to discuss these configurations, and the changes among them, in the context of classical elastomechanics. The concepts of twisting, linkage and writhing are explained. Simple experiments on a twisted linear-elastic rod are described, and it is shown that although the circular and interwound forms may be modeled in this way, the toroidal form does not occur, being mechanically unstable. Theoretical energy calculations by Levitt on bent and twisted DNA show that DNA exhibits a particular kind of nonlinear elasticity in which there is an unusual coupling between bending and twisting. The aim of the paper is to show qualitatively that this special kind of elasticity can stabilize the toroidal form of closed circular DNA.
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    Physicochemical investigation of k-carrageenan in the random state (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 1357-1374 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Light-scattering, viscosity, and sedimentation experiments on aqueous solutions of k-carrageenan show that this sulfated polygalactose is an expanded flexible random coil. This expansion is due to long-range interactions that are predominantly electrostatic. Extrapolation of viscosity data to infinite ionic strength provided values for the intrinsic viscosity which were subjected to the Stockmayer-Fixman analysis, giving a value for the Mark-Houwink coefficient under theta-conditions, Kθ, of 0.27. The characteristic ratio, C∞, under these conditions is 7.8, and the conformation factor σ is 2. In a solution of 0.118 ionic strength, where a Mark-Houwink exponent aη of 0.86 is found, the radii of gyration calculated from viscosity data are lower than those found from the angular dependence of scattered light. On the other hand, the radius of gyration found from the sedimentation rate agrees well with the light-scattering radius. The relations between molecular parameters are corrected for the poly-dispersity of the sample.
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    An interaction of albumin with hyaluronic acid and chondroitin sulfate: A study of affinity chromatography and circular dichroism (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 1407-1414 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
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    Masthead (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980) 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    URL: http://dx.doi.org/10.1002/bip.1980.360190801
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    The translational friction of toroids (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 1475-1489 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An approximate analytic expression for the translational friction coefficient of a toroid modeled as a continuous shell of frictional elements is derived using the Kirkwood approximation. The accuracy of this expression was determined by comparing the friction coefficients predicted by it to those predicted by extrapolated shell-model calculations using the modified Oseen tensor. To show that these calculations do indeed yield the correct friction coefficients, actual translational friction coefficients were determined by observing settling rates of macroscopic model rings or toroids in a high-viscosity silicone fluid. Our conclusion is that the approximate expression yields friction coefficients that are about 1.5-3% low for finite rings. For thin rings, a comparison is also made with the exact result of Yamakawa and Yamaki [J. Chem. Phys. 57, 1572 (1972); 58, 2049 (1973)] for the translational friction of plane polygonal rings. This comparison shows that the approximate expression yields results which are low by 2-3% unless the rings are extremely thin, in which case the error is larger. In the limit of an infinitely thin ring the approximate expression reduces to the Kirkwood result [J. Polym. Sci. 12, 1 (1954)], which is low by 8.3%. We discuss briefly how this work may be useful in determining the structure of DNA compacted by various solvent-electrolyte systems and polyamines.
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    Dynamic light scattering studies of internal motions in DNA. II. Clean viral DNAs (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 1451-1474 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Internal Brownian motions of clean φ29 and λ-DNAs have been studied using photon-correlation techniques at both visible (λ0 = 632.8 nm) and uv (λ0 = 363.8 nm) wavelengths. The present dynamic light scattering data, which extend to K2 = 19 × 1010 cm-2, can in every case be satisfactorily simulated by a Rouse-Zimm model polymer with an appropriate choice of the three model parameters. The effects of pH, salt concentration, single-strand breaks, and molecular weight on those model parameters have also been investigated. Intact clean DNAs exhibit surprisingly little variation with pH from 7.85 to 10.25, with salt concentration from 0.01 NaCl to 5.4M NH4Cl, or with molecular weight or GC content. The single-strand breaks have no effect at pH 9.46, but produce dramatic changes in the model parameters at pH 10.0 and 10.25, indicating the introduction of titratable joints at those pHs. The failure of either single-strand breaks or a large change in GC content to alter the model parameters in the neutral pH range is a strong indication that local denaturation is not required for those flexions and torsions that dominate the relaxation of fluctuations in the scattered light. The Langevin relaxation time for the slowest internal mode of a particular Rouse-Zimm model derived from the dynamic light scattering data is compared with pertinent literature data extrapolated to the same molecular weight. The present algorithm for determining model parameters from the light-scattering Dapp vs K2 curve actually yields a Langevin time in fairly good agreement with the literature value. For unknown reasons the light-scattering D0 values generally exceed those obtained from the molecular weight and sedimentation coefficient by about 20%.
    Additional Material: 7 Ill.
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    Ultraviolet Raman spectroscopy of polyribouridylic acid: Excitation profile of the hypochromism induced by order-disorder transition (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 1507-1515 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Raman spectra of polyribouridylic acid excited in the uv region, from 363 to 290 nm, are reported. The conformational changes of the polymer from random coil to ordered structure with stacked bases at high and low temperature, respectively, are reflected by important changes in the Raman line intensities; this Raman hypochromism is itself a function of the excitation wavelength - its profile has been determined and shows negative values in the region of 290 nm (near resonance), i.e., hypochromism becomes hyperchromism. Thus the knowledge of the hypochromism excitation profile is important in following order-disorder transition of a polymer using resonance Raman spectroscopy. Theoretical attempts are proposed for explanation, involving not only the relative variations of the molar extinction coefficient on the order-disorder transition of the polymer, but also the damping factors of the vibronic levels. The theoretical curve is found to fit adequately the experimental data over the excitation range, using only the frequency of the O-O transition of uracil and a vibronic linewidth of 2200 cm-1.
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    Interaction of poly(α-L-glutamic acid) and sodium poly(α-L-glutamate) with solvent components in water-2-chloroethanol mixtures (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 2177-2190 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The preferential interaction of sodium poly(α-L-glutamate) and poly(α-L-glutamic acid) with the solvent components in water/2-chloroethanol mixtures has been determined using density-increment measurements. The degree of preferential interaction was deduced from the density increments at constant molality of 2-chloroethanol and at constant chemical potential of 2-chloroethanol. Sodium poly(α-L-glutamate) and poly(α-L-glutamic acid) are both preferentially hydrated in the whole range of solvent composition. A dehydration process occurs during the 2-chloroethanol-induced coil-to-helix transition of sodium poly(α-L-glutamate). This dehydration process was attributed to the release of some moles of water from the neighborhood of the peptide bond during the nucleation of the helix. After the conformational transition, sodium poly(α-L-glutamate) is solvated by one 2-chloroethanol molecule. The location of water and 2-chloroethanol molecules in the different parts of the residue (more polar and less polar portions) is also discussed.
    Additional Material: 5 Ill.
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    Effects of pD on ring-stacking interactions between dinucleoside phosphates and tryptamine (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 2223-2245 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Complex formation between tryptamine and mononucleotides and dinucleoside phosphates containing adenine and/or cytosine has been studied at five pD's ranging from 1.1 to 7.4 by proton magnetic resonance spectroscopy. Chemical shifts of base ring protons and the ribose anomeric proton in the nucleotides and indole ring protons in tryptamine were monitored and their changes with pD and intermolecular interactions interpreted qualitatively. Stacked complexes were found to exist at all pD's in the range studied. Complex geometries differ depending on pD. An electrostatic interaction between the tryptamine amino group and the nucleotide phosphate group contributes to complex formation above pD 4 but is not strong enough to shift the dinucleoside phosphate equilibrium towards the unstacked conformer.
    Additional Material: 5 Ill.
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    Rǒle des electrons π des fonctions amide et ester dans les peptides et depsipeptides (1981)
    New York : Wiley-Blackwell
    Biopolymers 20 (1981), S. 169-185 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The IR data for the R1 CO-O-CHR2-CO-NHR3 derivatives are interpreted in terms of a H…π interaction involving the N—H bond and the π orbitals of the ester function and giving rise to a high ν(C=O) frequency and a low ν frequency. The resulting molecular conformation corresponds to the angular values φ # -90°, ψ # 0°. The H…π interaction in MeCO-L-Lac-NHMe is highly destabilized by water and aprotic solvents but is retained in methanol. Considering the high ν(C=O) ester or amide frequency of the middle function in β-folded depsipeptide or peptide sequences, it may be supposed that the residue indexed i + 2 in β turns experiences a H…π interaction which has a stabilizing effect on β turns. Some examples concerning valinomycin and some model compounds are discussed.
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    Masthead (1981)
    New York : Wiley-Blackwell
    Biopolymers 20 (1981) 
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    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    URL: http://dx.doi.org/10.1002/bip.1981.360200201
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    Polyelectrolyte contribution to the persistence length of DNA (1981)
    New York : Wiley-Blackwell
    Biopolymers 20 (1981), S. 251-268 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The difference between the theories of Manning, on the one hand, and of Odijk and Skolnick and Fixman, on the other, for the polyelectrolyte contribution to the persistence length of DNA is shown to arise entirely from a subtle geometrical error in the theory of Manning. The corrected theory of Manning predicts a negligible polyelectrolyte contribution in 1.0M NaCl and only 33 Å in 0.01M NaCl, thus giving a change in total persistence length by a factor of only 1.07 over that range, in agreement with Odijk. Pertinent data in the literature indicate that the persistence length must change by a factor of ≤ 1.6 between 1.0 and 0.01M NaCl, and very likely by less than a factor of 1.4. Evidently, the intrinsic rigidity of the uncharged double-strand filament dominates the bending rigidity at NaCl concentrations above 0.01M.
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    Conformational studies of peptides: Crystal and molecular structures of L-3,4-dehydroproline and its t-butoxycarbonyl and acetyl amide derivatives (1981)
    New York : Wiley-Blackwell
    Biopolymers 20 (1981), S. 283-302 
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    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The crystal structures of L-3,4-dehydroproline, t-butoxycarbonyl-L-3,4-dehydroproline amide, and acetyl-L-3,4-dehydroproline amide have been determined. L-3,4-Dehydroproline is orthorhombic with a = 16.756, b = 5.870, c = 5.275 Å, and Z = 4; t-butoxycarbonyl-L-3,4-dehydroproline amide is orthorhombic with a = 6.448, b = 8.602, c = 21.710 Å, and Z = 4; acetyl-L-3,4-dehydroproline amide is monoclinic with a = 4.788, b = 10.880, c = 7.785 Å, β = 105.25°, and Z = 2. The final R value for the L-3,4-dehydroproline is 0.046 based on 529 reflections; for t-butoxycarbonyl-L-3,4-dehydroproline amide, 0.050 based on 792 reflections; and for acetyl-L-3,4-dehydroproline amide, 0.058 based on 632 reflections. The structures clearly establish that the free amino acid exists in the zwitterionic form in the crystalline state. The molecular conformations of the t-Boc and acetyl derivatives consist of two planes: one involving the primary amide and the other the remaining atoms of the molecule. The acetyl-L-3,4-dehydroproline amide contains a tertiary amide bond in the cis conformation. To the best of our knowledge, this is the first example of a cis bond in an acetyl derivative of an amino acid or peptide. At variance with the previously reported proline amides, which present φ and ψ values corresponding to those of a right-handed α-helical conformation (conformation A), the t-Boc and acetyl derivatives both have φ and ψ values corresponding to a collagenlike conformation (conformation F).
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    Physical properties of type i collagen in solution: Structure of α-Chains and β- and γ-components and two-component mixtures (1981)
    New York : Wiley-Blackwell
    Biopolymers 20 (1981), S. 359-371 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The structure of thermally denatured Type I collagen has been studied using laser light scattering. The results indicate that the diffusion coefficients of α-chains and β- and γ-components are 1.550 ± 0.08 × 10-7, 1.000 ± 0.05 × 10-7, and 0.835 ± 0.04 × 10-7 cm2/sec, respectively, at temperatures between 20 and 40°C. It is concluded from diffusion data that these species have hydrodynamic radii of about 13.8 nm (α-chain), 21.5 nm (β-component), and 25.7 nm (γ-component), consistent with previous studies of thermal denaturation by light scattering. It is also concluded, based on volume calculations, that a large volume increase occurs when the triple helix unfolds. Homodyne correlation functions for two component mixtures of α-chains and β-and γ-components appeared to decay exponentially. In all but one case discussed the correlation function could be fitted with a single component having a translational diffusion coefficient which was an intensity weighted average of the diffusion coefficient of each component present.
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    Theoretical π-π* circular dichroic spectra of helical poly(glycine) and poly(L-alanine) as functions of backbone torsion angles (1981)
    New York : Wiley-Blackwell
    Biopolymers 20 (1981), S. 387-397 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Circular dichroic spectra and oscillator strengths of the π-π transition near 190 nm are calculated for helical (Gly)6 and (Ala)6 at 30° intervals of the backbone torsion angles (φ,ψ) over the range -180° ≤ φ ≤ -60°, -60° ≤ ψ ≤ 180°, using the partially dispersive normal mode treatment of the dipole interaction model. Polarizabilities of atoms and the NC′O group are those determined semiempirically in previous studies. Calculations for (Ala)6 at (φ,ψ) angles corresponding to the α-helix, the poly(Pro) II helix, a collagen single helix, a poly-(MeAla) helix, and single β-helices are found to agree well with most of the available experimental data.
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    Interaction of the antimalarial drug fluoroquine with DNA, tRNA, and poly(A): 19F-NMR chemical-shift and relaxation, optical absorption, and fluorescence studies (1981)
    New York : Wiley-Blackwell
    Biopolymers 20 (1981), S. 435-449 
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    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The interaction of the fluorinated antimalarial drug fluoroquine [7-fluoro-4-(diethyl-amino-1-methylbutylamino)quinoline] with DNA, tRNA, and poly(A) has been investigated by optical absorption, fluorescence, and 19F-nmr chemical-shift and relaxation methods. Optical absorption and fluorescence experiments indicate that fluoroquine binds to nucleic acids in a similar manner to that of its well-known analog chloroquine. At low drug-to-base pair ratios, binding of both drugs appears to be random. Fluoroquine and chloroquine also elevate the melting temperature (Tm) of DNA to a comparable extent. Binding of fluoroquine to DNA, tRNA, or poly(A) results in a downfield shift of about 1.5 ppm for the 19F-nmr resonance. The chemical shift of free fluoroquine depends on the isotopic composition of the solvent (D2O vs H2O). The solvent isotope shift is virtually eliminated by fluoroquine binding to any one of the nucleic acids. 19F-nmr relaxation experiments were carried out to measure the spin-lattice relaxation time (T1), 19F{1H} nuclear Overhauser effect (NOE), off-resonance intensity ratio (R), off-resonance rotating-frame spin-lattice relaxation time (T1ρoff), and linewidth for fluoroquine in the nucleic acid complexes. By accounting for intramolecular proton-fluorine dipolar and chemical-shift anisotropy contributions to the fluorine relaxation, all of the relaxation parameters for the fluoroquine-DNA complex can be well described by a motional model incorporating long-range DNA bending on the order of a microsecond and an internal motion of the drug on the order of a nanosecond. Selective NOE experiments indicate that the fluorine in the drug is near the ribose protons in the RNA complexes, but not in the DNA complex. Details of the binding evidently differ for the two types of nucleic acids. This study provides the foundation for an investigation of fluoroquine in intact cells.
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    Conformational energy studies on N-methylated analogs of thyrotropin releasing hormone, enkephalin, and luteinizing hormone-releasing hormone (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 1943-1973 
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    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Empirical conformational energy calculations have been carried out for N-methyl derivatives of alanine and phenylalanine dipeptide models and N-methyl-substituted active analogs of three biologically active peptides, namely thyrotropin-releasing hormone (TRH), enkephalin (ENK), and luteinizing hormone-releasing hormone (LHRH). The isoenergetic contour maps and the local dipeptide minima obtained, when the peptide bond (ω) preceding the N-methylated residue is in the trans configuration show that (1) N-methylation constricts the conformational freedom of both the ith and (i + 1)th residues; (2), the lowest energy position for both residues occurs around φ = -135° ± 5° and ψ = 75° ± 5°, and (3) the αL conformational state is the second lowest energy state for the (i + 1)th residue, whereas for the ith residue the C5 (extended) conformation is second lowest in energy. When the peptide bond (ωi) is in the cis configuration the ith residue is energetically forbidden in the range φ = 0° to 180° and ψ = -180° to +180°. Conformations of low energy for ωi = 0° are found to be similar to those obtained for the trans peptide bond. In all the model systems (irrespective of cis or trans), the αR conformational state is energetically very high. Significant deviations from planarity are found for the peptide bond when the amide hydrogen is replaced by a methyl group. Two low-energy conformers are found for [(N-Me)His2]TRH. These conformers differ only in the φ and ψ values at the (N-Me)His2 residue. Among the different low-energy conformers found for each of the ENK analogs [D-Ala2,(N-Me)Phe4, Met5]ENK amide and [D-Ala2,(N-Me)Met5]ENK amide, one low-energy conformer was found to be common for both analogs with respect to the side-chain orientations. The stability of the low-energy structures is discussed in the light of the activity of other analogs. Two low-energy conformers were found for [(N-Me)Leu7]LHRH. These conformations differ in the types of bend around the positions 6 and 7 of LHRH. One bend type is eliminated when the active analog [D-Ala6,(M-Me)Leu7]LHRH is considered.
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    URL: http://dx.doi.org/10.1002/bip.1980.360191103
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    Interactions of molecules with nucleic acids. III. Steric and electrostatic energy contours for the principal intercalation sites, prerequisites for binding, and the exclusion of essential metabolites from intercalation (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 2067-2089 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Based on steric and electrostatic considerations, the prerequisites for binding to DNA via the intercalation mechanism are proposed. Steric contour energy curves are presented to demonstrate the region inaccessible to an intercalant. They are calculated with a 6-n (n = 14) potential. This method is a soft potential analog of an excluded-volume approach. Electrostatic contours on the steric surface illustrate the relatively positive and negative regions of the binding site. The principal intercalation sites, predicted to fit into B-DNA via a tetramer-duplex unit, and the unconstrained dimer-duplex units, obtained in crystal structures, are examined. These contours illustrate the requirements of size, conformation, and net atomic charges necessary for intercalation and optimum binding. Based on the limited space available for intercalation by the presence of the backbone and the maximum base-pair separation of 8.25 Å, an Essential Metabolite Exclusion Hypothesis is presented.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.1980.360191110
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  • 88
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    Hydrodynamic behavior and molecular conformation of poly(L-lysine HBr) in carbonate buffer solution (1981)
    New York : Wiley-Blackwell
    Biopolymers 20 (1981), S. 345-357 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In carbonate buffer at pH 10.5, a transparent solution of poly(L-lysine HBr) was obtained up to fairly high concentration of 3 g/dl at room temperature. The hydrodynamic behavior of the solution has been studied by sedimentation analyses and viscosity measurements. A dimer form for high concentrations and a monomer form for low concentrations were inferred. The dimer and monomer forms were assigned to a β-structure and α-helix, respectively, based on the CD and optical rotary dispersion spectra. Using CD spectroscopy, a reversible transition between α-helix and β-structure was observed as a function of either poly(L-lysine HBr) concentration or temperature. An aggregated form which was assigned to the antiparallel pleated sheet appeared at 50°C on the basis of its ir spectrum.
    Additional Material: 7 Ill.
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    URL: http://dx.doi.org/10.1002/bip.1981.360200207
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  • 89
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    Stability and geometry of hydrogen-bonded complexes of peptides (1981)
    New York : Wiley-Blackwell
    Biopolymers 20 (1981), S. 707-718 
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    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Observations of induced circular dichroism (CD) bands in chloroform solution demonstrate the formation of specific, asymmetric complexes of the aromatic ligands 2-pyridone and 2,6-dichlorobenzoic acid with cyclic dipeptides of the general formula cyclo(L-Pro-X). The induced CD changes sign with the configuration of X due to subtle influences of the side chain on the geometry of the complex. Computations of interaction energies suggest that a plausible model for the complex of an aromatic ligand with the -CONH- of the cis secondary amide is a nearly planar arrangement of six heavy atoms in a ring containing two hydrogen bonds. The observed CD is matched by that computed for a tilt of the aromatic ligand toward the side chain of X. Binding constants were determined from the induced CD as a function of ligand concentration. For dichlorobenzoic acid these are about 450m-1 for the secondary amide and 50m-1 for the tertiary amide. For pyridone the binding constant is about 45m-1 for either the secondary or tertiary amide. For comparison self-dimerization constants determined by vapor-pressure osmometry in chloroform solution at 25°C are 870, 350, 50, and 20m-1 for pyridone, benzoic acid, dichlorobenzoic acid, and cyclo(L-Pro-Gly), respectively.
    Additional Material: 6 Ill.
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    URL: http://dx.doi.org/10.1002/bip.1981.360200407
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  • 90
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    Proton and phosphorus nmr investigation of the conformational states of acid polyadenylic double helix (1981)
    New York : Wiley-Blackwell
    Biopolymers 20 (1981), S. 803-816 
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    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Proton and phosphorus nmr have been used to investigate the double-helical structures of polyriboadenylic acid [poly(A)] formed in acidic solutions (pH 〈 6). The results obtained at low pH (∼4.5) are consistent with the model for the acid poly(A) double helix proposed by Rich [Rich, A., Davies, D. R., Crick, F. H. C. & Watson, J. D. (1961) J. Mol. Biol. 3, 71-86]. Other models that have been proposed are inconsistent with the nmr data. The nmr measurements have also been used to examine the conformation of poly(A) helix in the half-protonated state. Although the base-stacking arrangement of this state is similar to that observed in the more extensively protonated low-pH state, the phosphate backbone conformation is different from that found in either the neutral or low-pH structures.
    Additional Material: 8 Ill.
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    URL: http://dx.doi.org/10.1002/bip.1981.360200412
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  • 91
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    The chiroptical properties of proteins. II. Near-ultraviolet circular dichroism of lysozymeTaken in part from the Ph.D. dissertation of W. J. G. (1980)
    New York : Wiley-Blackwell
    Biopolymers 19 (1980), S. 2191-2208 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A study of the near-uv CD spectrum of lysozyme was carried out in the presence and absence of the inhibitor tri-N-acetylglucosamine, and theoretical chiroptical calculations based on the tetragonal crystal structure of the enzyme and the enzyme-inhibitor complex were performed. The results of these calculations indicate that the near-uv CD spectrum of lysozyme can be adequately explained in terms of negative rotatory strengths arising from the tryptophan 1La (293-300 nm) and the disulfide n-σ* bands (250 rm), and positive rotatory strength contributions from the tryptophan 1Lb bands (291 nm) and the tyrosine 1Lb bands (275 nm). Contributions to the rotatory strength of each band were approximated in terms of specific interactions between chromophores. It was found that the rotatory strength of most of the near-uv transitions arises primarily from coupling interactions involving other side-chain chromophores and amide groups which are in close proximity. Changes which are observed in the lysozyme CD spectrum on binding of tri-N-acetylglucosamine may be explained in terms of changes in the rotatory strength which result from interactions of the 1La transitions of the active-site tryptophans with the acetamide groups of the inhibitor. The reasonable agreement which is found between the experimental and calculated rotatory strengths implies that the crystal conformation of lysozyme must resemble the solution conformation.
    Additional Material: 2 Ill.
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    URL: http://dx.doi.org/10.1002/bip.1980.360191205
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  • 92
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    Masthead (1981)
    New York : Wiley-Blackwell
    Biopolymers 20 (1981) 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.1981.360200101
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  • 93
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    Effect of some organic cosolvents on the reaction of hemoglobin with oxygen (1981)
    New York : Wiley-Blackwell
    Biopolymers 20 (1981), S. 39-51 
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    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: We studied the effects of some organic cosolvents (monohydric alcohols and amides) on the reaction of hemoglobin with oxygen. We present evidence showing that our data can be analyzed within the framework of the Monod-Wyman-Changeux model and that the main effect of cosolvents is to alter the T ⇄ R conformational equilibrium of hemoglobin, without significantly affecting the intrinsic oxygen dissociation constants. Following a previously described phenomenological approach, the overall effects have been separated into effects related to the variation of the bulk dielectric constant of the solvent and effects not related to the variation of this constant.
    Additional Material: 4 Ill.
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    URL: http://dx.doi.org/10.1002/bip.1981.360200104
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  • 94
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    XII. Conformational studies of histidine-containing peptides in solution (1981)
    New York : Wiley-Blackwell
    Biopolymers 20 (1981), S. 65-88 
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    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The spectroscopic properties (uv, CD, nmr) of histidine, glycylhistidine, histidylglycine, glycylhistidylglycine have been investigated in water and methanol in the temperature range 200-320 K in order to obtain information about their conformational equilibria. This analysis has been carried out for the different ionic forms of the compounds, in order to evaluate the influence of the ionization state of the carboxyl, histidyl, and amino groups on the rotamer distribution of the histidyl side chain (as evaluated from proton nmr analysis) and on the overall molecule (as judged from CD spectra). On the basis of certain approximations and from the temperature dependence of the proton nmr resonance, the thermodynamic parameters (ΔH° and ΔS°) characterizing the conformational equilibrium of the hystidyl side chain have been evaluated for the different structures and ionization states. Relatively large entropy differences between the rotamers are obtained in some cases. The data of the sidechain rotamer population, as determined by nmr, have been analytically correlated with the CD data, and in the case of hystidine and histidylglycine in basic solution, first-approximation values for the ellipticity of the single conformers have been evaluated. Finally, in the example of glycylhistidine and histidylglycine in basic solution, it is shown how the data obtained from the different experimental approaches (nmr and CD), as well as from theoretical energy calculations, converge to characterize the most stable conformation in solution.
    Additional Material: 6 Ill.
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    URL: http://dx.doi.org/10.1002/bip.1981.360200106
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  • 95
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    Laser light-scattering analysis of the dimerization of transfer ribonucleic acids with complementary anticodons (1981)
    New York : Wiley-Blackwell
    Biopolymers 20 (1981), S. 155-168 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Photon-correlation spectroscopy is a powerful technique for measuring the translational diffusion coefficient of particles and macromolecules in solution. In the study described here, this technique was used to analyze a specific dimerization process involving the association of two tRNA molecules through complementary anticodons. The tRNAs used in the analysis were E. coli tRNA2Glu and yeast tRNAPhe. The experimental data on the concentration dependence of the observed diffusion constants are shown to agree well with theoretical predictions. From these data, the equilibrium constant of the association reaction was determined for dimers formed over a wide range of temperatures and in several different solution conditions. In solutions of 0.1M ionic strength at 22°C, the equilibrium constants vary from 1 × 105M-1 in the absence of magnesium to 1.5 × 106M-1 in 10 mM Mg+2. The enthalpy and entropy changes for dimer formation in the absence and presence, 5 and 10 mM, of magnesium have been obtained from the temperature dependence of the equilibrium constant. The results show that both ΔH and ΔS contribute to the free energy of binding and that their relative contributions are similar for each solution condition evaluated.
    Additional Material: 2 Ill.
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    URL: http://dx.doi.org/10.1002/bip.1981.360200111
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  • 96
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    Dependence of DNA conformation on the concentration of salt (1981)
    New York : Wiley-Blackwell
    Biopolymers 20 (1981), S. 231-235 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.1981.360200116
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  • 97
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    Vibrational circular dichroism of poly(γ-benzyl-L-glutamate) (1981)
    New York : Wiley-Blackwell
    Biopolymers 20 (1981), S. 237-240 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.1981.360200117
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  • 98
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    Low-frequency modes in the raman spectrum of DNA (1981)
    New York : Wiley-Blackwell
    Biopolymers 20 (1981), S. 243-247 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.1981.360200119
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  • 99
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    Quantum-mechanical study of model molecules in relation to collagen structure. II. (Gly-Phe-Pro) and (Gly-Pro-Phe) repeating units (1981)
    New York : Wiley-Blackwell
    Biopolymers 20 (1981), S. 269-282 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A conformational quantum-mechanical study of (Gly-Phe-Pro) and (Gly-Pro-Phe) repeating tripeptide sequences has been carried out with the PCILO method. Using appropriate molecules as a model, we investigated the conformational possibilities of each in situ residue. Computations have been done taking into account the two typical pyrrolidine ring puckering and the most favorable orientations of the phenylalanyl side chain. Major conclusions drawn from this study are that the phenylalanyl can be accommodated at both second and third positions in the sequence without preventing the formation of triple-helix conformation. However, the analogy observed between the rotational possibilities around the second residue of Gly-Pro-Pro and Gly-Phe-Pro indicates that phenylalanyl in the second position favors the triple-helix formation.
    Additional Material: 7 Ill.
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    URL: http://dx.doi.org/10.1002/bip.1981.360200203
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  • 100
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    Neutron-scattering studies of the structure of chromatin core particles in solution (1981)
    New York : Wiley-Blackwell
    Biopolymers 20 (1981), S. 327-343 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The structure of the nucleosome core particle in solution has been studied by neutron scattering using the full-contrast variation technique, which reduces the experimental spectra to three fundamental scatter functions holding information on shape and structure. Systematic calculations of the fundamental scatter functions expected from proposed core-particle models have been compared with the observed functions and show that the neutron-scattering criteria severely restrict the number of models which can be valid for the structure in solution. The best model for the core particle in solution has a hydrophobic histone core about which 1.7 ± 0.1 turns of DNA are wrapped at a pitch between 3.0 and 3.5 nm. This core contains most of the histone and has an average thickness of 4 nm and diameter 6.4-7.5 nm. While solution scattering is not able to specify uniquely the actual shape of the core to high resolution, all models which are possible for the shape of the core to a resolution justified by the data have been considered. It is clear that cylindrical or wedge shapes compatible with the above dimensions are valid structures. A hole probably penetrates the histone core, but the data do not allow a diameter greater than 1 nm. Available evidence suggests that about a quarter of the total histone is outside the core.
    Additional Material: 8 Ill.
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    URL: http://dx.doi.org/10.1002/bip.1981.360200206
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