ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Articles  (2,907)
  • Chemical Engineering  (2,907)
  • Animals
  • 1990-1994  (1,743)
  • 1965-1969  (1,164)
  • Process Engineering, Biotechnology, Nutrition Technology  (2,907)
Collection
  • Articles  (2,907)
Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 676-691 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A semiempirical thermodynamic method is developed to establish a framework for calculating vapor-liquid and liquid-liquid equilibria in ternary systems containing water, an organic solvent, and a salt. Careful attention is given to precise definition of standard states. Short-range ion-solvent forces are taken into account primarily by a chemical-equilibrium method based on stepwise ion solvation; however, physical contributions also contribute. Water-cosolvent nonideality is described by an extended equation of the van Laar form. Long-range electrostatic forces between ions are taken into account by an extended Debye-Hückel equation with corrections for transferring from a McMillan-Mayer to a Lewis-Randall framework.The new method is illustrated with results for several systems including saturated aqueous mixtures of LiBr or LiCl with methanol where the salt concentration exceeds 20 molal. The method developed here is of particular interest for process calculations in extractive crystallization, a low-energy operation for producing salt from aqueous solution.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 178-181 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 192-192 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 215-228 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Many experimental studies on the cross-sectional distribution of particles in vertical risers have revealed marked segregation of particles. These flows are inherently unsteady with large fluctuations in suspension density. In this article, we have analyzed the time-smoothed equations for the motion of dense suspensions to demonstrate the role of these fluctuations on the occurrence of segregation. It is shown that the particles will congregate in regions where the kinetic energy of fluctuations associated with the particles is small. In the context of transport of small particles such as FCC, a simplified model based on the mixture velocity can be constructed. A speculative K-∊ model based on this velocity is analyzed to illustrate the extent of segregation of particles afforded by unsteady fluctuations.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 269-282 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new comprehensive real-time identification/control methodology based on the concept of nonlinear autoregressive exogenous input (NARX) models and adaptive, nonlinear, model-predictive control (ANMPC) is applied to a pH neutralization process. The existing NARX model theory has been extended by incorporating measured disturbances. NARX models have shown superior predictive characteristics in comparison to linear models. The proposed real-time methodology uses a pointer vector being created during an initial identification and model structure selection procedure. Using this pointer vector, which allocates the chosen elements from the pool of all possible linear and nonlinear combinations, one needs no explicit information about the model structure for the closed-loop control. The nonlinear programming problem encountered in ANMPC is solved by a gradient-based modified Marquardt and finite difference methods. The design procedure and explicit algorithms are discussed for the multiinput/multioutput case. A pH wastewater neutralization process used illustrates and verifies the procedure by computer simulations and a real-time laboratory-scale experiments.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 321-333 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical model has been developed to predict the coupled hydrodynamics and high-molecular-weight protein transport in mammalian-cell hollow-fiber bioreactors (HFBRs). The analysis applies to reactors with isotropic ultrafiltration membranes under startup conditions when the extracapillary space (ECS) is essentially unobstructed by cells. The model confirms the experimental finding that secondary ECS flows, engendered by the primary flow in the fiber lumens, can cause significant downstream polarization of ECS proteins at typical mammalian-cell HFBR operating conditions. It also reveals that the osmotic activity of the proteins, by curtailing transmembrane fluid fluxes, can influence strongly the outcome of the polarization process. In fact, at order-of-magnitude higher protein concentrations and/or lower recycle flow rates, the secondary flow velocities can be reduced by as much as six orders-of-magnitude throughout the ECS, thereby virtually eliminating the polarization problem. This result has important implications for improved reactor startup procedures.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 349-360 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Mixing effects in protein precipitation processes are very poorly understood. They impact apparent protein solubility, protein structure in precipitates, particle size, morphology and recoverable activity. In this work, a model is proposed to describe the impact of mixing on protein solubility in precipitation processes. A series of semibatch-mode precipitation experiments were performed using bovine liver catalase and ammonium sulfate to test model predictions. The process variables studied include initial protein supersaturation, agitation rate, and rate of addition of salt solution to the initial protein solution. The mixing model parameters were estimated independently with the aid of a series-parallel dye reaction. The results showed good agreement between model and experiment. The initial protein supersaturation was the most important variable at the 1-L scale. The influence of mixing on recoverable activity was also examined. Scale-up guidelines are suggested based on model simulations and experimental results.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 369-372 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 380-381 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 395-406 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A substantial effort has been made by numerous investigators to describe droplet breakage and coalescence in turbulent dispersions. An attempt is made here to improve these models based on existing frameworks and recent advances described in the literature. Two-step mechanisms are considered for both the breakage and coalescence models. The drop breakage function is structured as the product of the drop-eddy collision frequency and breakage efficiency which reflect the energetics of turbulent liquid-liquid dispersions. The coalescence function retains the former structure of the product of drop-drop collision frequency and coalescence efficiency. The coalescence efficiency model has been modified to account for the effects of film drainage for drops with partially mobile interfaces. These models overcome several inconsistencies observed in previous efforts and are applicable for dense dispersions (about φ[0.10-0.30]). For the daughter drops produced by breakage, a probability density is proposed based on the energy requirements for the formation of daughter drops.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 11
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 419-423 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Three-dimensional Stokes flow through a thin screen which has a regular array of holes with two orthogonal axes of symmetry has been studied. The governing equation is simplified by the Roscoe potential and solved by an efficient eigenfunction expansion and collocation method. The resistance is found for circular and square holes in square arrays, and circular and hexagonal holes in triangular arrays.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 12
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 424-432 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Mixing effects are evaluated for double jet semibatch and continuous stirred precipitators by a model which gives the variation of the primary nucleation flux from the mixing conditions. The predicted trends are compared with results of various authors, including those from a new study of calcium oxalate semibatch double-jet precipitation. Satisfactory qualitative agreement is found for the different chemical systems as a function of feed rate, stirring speed and feed locations for calcium oxalate precipitation. Two types of precipitation systems are demonstrated, depending on the ratio added/tank volume, the initial supersaturations and the intrinsic stiffness factor of a given precipitation. The difference between the two types depends on the increase or reduction of the primary nucleation flux by imperfect mixing with respect to the reference primary nucleation flux obtained with perfect mixing.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 13
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 445-462 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A molecular weight distribution (MWD) estimator for batch methyl methacrylate solution polymerization is implemented experimentally for on-line control and estimation of the MWD. The estimator is based on an extended Kalman filter and provides current estimates of the entire MWD, reaction temperature, monomer conversion, and initiator conversion. It uses a detailed polymerization model, on-line monomer conversion measurements, temperature measurements, and periodic, time-delayed measurements of the MWD from an on-line size-exclusion chromatograph. The estimator is shown to perform well with several on-line MWD estimation experiments. Real-time feedback control of the molecular weight is presented by utilizing the on-line MWD information. Temperature, monomer-addition, and simultaneous temperature and monomer-addition control are investigated experimentally to achieve a specific constant weight-average molecular weight. The on-line feedback control is effective in rejecting realistic disturbances which deteriorate molecular weight control.
    Additional Material: 34 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 14
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 473-495 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This work concerns the synthesis of discrete-time feedforward/feedback control systems for general nonlinear processes with stable zero dynamics. Depending on the process under consideration, the derived feedforward/feedback controllers can completely eliminate the effect of measurable disturbances and produce a prespecified linear response with respect to a reference input, or provide integral-square error optimal response to step changes in the disturbances and a prespecified linear response with respect to a reference input. In either case, the developed feedforward/feedback controllers allow for the asymptotic rejection of unmeasurable disturbances. These controllers are derived within the globally linearizing control frame-work, first under full state information and then in the absence of state measurements. The internal stability of the closed-loop system is addressed. The derived controllers are interpreted from a model-predictive point of view, and their connections with the feedforward internal model control and the model algorithmic control are established. The theoretical results are illustrated through a continuous stirred-tank reactor example.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 15
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 506-520 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Most olefin polymerization processes produce a wide range of resin grades to suit market demand. Determining the transition policy between these grades is an important consideration that can affect process economics and safety. In this article, we compare several grade transition strategies and the relative performance of solution, slurry, bulk and gas-phase processes for the production of polypropylene, linear low-density polyethylene, high-density polyethylene and ethylene-propylene rubber. It is shown that the most important parameters that determine the grade transition performance of a process are reactor design, residence time, runtime per grade and residence time distribution of the polymer, gas and/or solution phases. Slow hydrogen dynamics severely retard grade changes involving increases in product molecular weight. The simulation results are obtained by using the dynamic simulation package “POLYRED” developed at the University of Wisconsin-Madison.
    Additional Material: 29 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 16
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 521-535 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The oxidative coupling of methane was carried out in the absence of catalyst in a continuous flow setup at total pressures up to 1,000 kPa, temperatures from 950 to 1,230 K, and inlet molar ratios of CH4/O2 down to 2.5. At constant temperature and residence time, the conversions of methane and oxygen increase drastically with increasing pressure. At oxygen conversions higher than 80%, product selectivities are comparable at different pressures. The space-time yield of the C2 products reaches a level comparable to that required for industrial operations from 400 kPa on. A radical-reaction network consisting of 38 elementary reactions allows to describe the experimental data. To describe adequately the effect of total pressure, the pressure fall-off behavior of the rate coefficients for the unimolecular reactions in the network has to be taken into account explicitly.General features of the reaction mechanism do not depend on the total pressure. Methyl and hydrogen peroxy radicals are the most abundant radicals. The total pressure increase results in a drastic increase of the concentrations of the chain carriers, particularly the hydrogen peroxy radical. Higher pressure favor the oxidative route from ethane to ethylene compared to the pyrolytic route. Increasing the total pressure leads to an increase of the primary and a decrease of the consecutive CO formation relative to the coupling. The balance between these nonselective routes determines the effect of the total pressure on the integral selectivity to C2 products at different conversions. The major contribution to the integral CO selectivity comes from the oxidation of methyl radicals.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 17
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 543-555 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Phase behavior data and FTIR spectra along with solubilities and solvatochromic shifts of ionic indicator dyes are reported for binary, ternary and quaternary systems composed of pentaethylene glycol n-octyl ether (C8E5), CO2, water, and n-pentanol as a function of temperature, pressure and composition. With the addition of n-pentanol as a cosurfactant, the water to surfactant ratio, W0, reaches values as high as 12. As water is added further, a surfactant-rich phase precipitates due to micellemicelle interactions. Ionic dyes are soluble at levels of 0.03 mM, far in excess of the negligible solubility in pure CO2.
    Additional Material: 17 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 18
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 19
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 577-585 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Diffusivities of oxygen, nitrogen and their mixtures in carbon molecular sieve are measured under conditions used for kinetic separation of air by adsorption (elevated pressures). In binary diffusion, codiffusion enhances fluxes for both components, whereas counterdiffusion has the opposite effects; for both cases, the effects are significantly more pronounced for the fast diffusing component. The multicomponent diffusion theory developed earlier in this laboratory for surface diffusion is reformulated for diffusion in molecular sieves. Multicomponent diffusivities can be predicted from the following pure-component information: concentration-dependent diffusivities and diffusional activation energies. Predicted binary diffusion results agree fairly with the experimental data for oxygen and nitrogen in carbon molecular sieve.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 20
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 594-605 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Optimum experimental conditions and column design parameters are calculated for most economical separation of binary mixtures by preparative liquid chromatography. The solvent consumption and capital costs are regarded as the two major cost contributions. Calculations were performed by using the numerical solution of the equilibrium-dispersive model of chromatography and a nonlinear simplex algorithm. Solvent consumption depends only on the column efficiency, the retention factor, and the loading factor. The production rate depends on the particle size, the column length, the mobile-phase flow velocity, the retention and the loading factors, and can be optimized with or without recovery yield constraints. A hybrid objective function was constructed to find the tradeoffs between the production rate and the solvent consumption.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 21
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 613-620 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An advanced process is developed for the separation of H2S from natural gas through an electrochemical membrane. H2S is removed from natural gas by reduction to the sulfide ion and H2 at the cathode. The sulfide ion migrates to the anode through a molten salt electrolyte suspended in an inert ceramic matrix. Once at the anode it is oxidized to elemental sulfur and swept away for condensation in an inert gas stream. The natural gas is enriched with H2. Order-of-magnitude reductions in H2S concentration have been repeatedly recorded on a single pass through the cell. This process allows removal of H2S, while producing H2 and elemental sulfur directly. No absorbents are used, and there is no need for subsequent treatment of a concetrated H2S stream as with conventional gas sweetening technology. This makes the process economically attractive, since it is much less equipment-intensive than conventional technology.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 22
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 627-646 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The Åström-Hägglund autotuner is extended to multivariable systems. The proposed multivariable automatic tuning performs the identification-design procedure in a sequential manner. Its advantages are discussed, as well as the process characteristics resulted from sequential design. One important feature is that the sequential design often leads to underdamped process characteristics. Given these characteristics, potential problems in the Ziegler-Nichols tuning are discussed and a modification is made. The sequential identification and the modified Ziegler-Nichols controller design method form the basic structure for the multivariable autotuner. The properties of convergence, the implications of tuning sequence, and the indications of undesirable pairing for the autotuner are explored. Consequently, a multivariable autotuning procedure is proposed. Two nonlinear distillation examples and a 3 × 3 linear system are used to illustrate the effectiveness of the autotuner. Simulation results show that good performance can be obtained with minimal engineering effort and the autotuner works well for very difficult processes in a very simple way.
    Additional Material: 24 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 23
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 670-675 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Vented extruder devolatilization (DV) of PS melt containing 6,000 ppm styrene was studied by scanning electron microscopy (SEM) and video photography. Vacuum DV of a polymer is accompanied by foaming, which starts instantaneously upon supersaturation of the stretched melt and is enhanced at higher speeds of the vented extruder screw. As the volatiles are removed from the melt, foaming gradually ceases, starting with the pushing flight of the screw. The experimental installation design allowed us to quench the polymer melt in the DV zone at various stages of the process. Samples taken from four areas of the channel width were investigated by SEM. Bubble nucleation in the melt appears to take place mainly in the border area adjoining the gas phase. In the shear field caused by screw rotation, large bubbles become noticeably elongated. Their surface, as well as the free surface of the melt, is covered with blisters, 1-100 μm in size. Microblisters are often concentrated in areas subjected to stretching. Calculations of cooling due to volatile evaporation and of heating due to viscous dissipation near a growing bubble shows that the process of foam-enhanced DV of a PS/styrene system can be regarded isothermal if the initial volatile concentration does not exceed approximately 1%.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 24
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1067-1081 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Protein denaturation, common in hydrophobic adsorption systems, causes misinterpretation of adsorption mechanisms, interferes with analysis in analytical chromatography, and complicates the design of large-scale adsorption processes. A detailed adsorption model isolates the effects due to denaturation from those due to mass transfer and intrinsic adsorption kinetics. The model is verified using protein gradient elution data. Simulations establish that typical symptoms of denaturation in frontal and elution chromatogrrams include sensitivity to changes in feed composition, column length, particle size, and operating conditions (feed size, flow rate, and column history). When a denatured species adsorbs irreversibly, the elution chromatogram shows decreasing peak area with increasing incubation time and apparent adsorption hysteresis over repeated cycles. In gradient elution, the peak elution order, resolution, and relative peak height depend highly on modulator properties and operating conditions. Interfering species limit solid-phase induced denaturation by competing for binding sites. Strategies for detecting and minimizing denaturation are proposed.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 25
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1418-1421 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 26
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 27
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1087-1088 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 28
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 29
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1117-1117 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 30
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1105-1117 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Pressure drops, gas holdup, and mass-transfer coefficients were measured in two concentric-tube airlift reactors of 30 and 300 L (nominal volume). The aspect ratio and the ratio of riser to downcomer cross section were the same for both reactors, but the geometry of the gas separation section was different. The influence of the bottom and top clearances was studied using water and carboxymethyl cellulose solutions and covering a range of effective viscosity from 10-3 to 25 × 10-3 Pa·s. The pressure drop results expressed as a Euler number were satisfactorily correlated with Fr, Ga, and a bubble disengagement group M. Correlations are presented also for the gas holdup in the riser, downcomer, and gas separator. The last-mentioned coincides with the correlation for the total holdup in the reactor. The gas-liquid mass-transfer coefficients for all the liquids and geometric variables in both reactors were successfully correlated as Sherwood numbers.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 31
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1156-1166 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A Semibatch gas-liquid reactor model based on a lumped kinetic schem for the liquid-phase oxidation of p-xylene to p-toluic acid catalyzed by cobalt naphtenate is developed. The model accounts for the complex nature of the involved reaction network, as well as for the interphase and intraphase mass transport processes of both reactants and products. The model reliability is tested by comparison with suitable experimental data obtained in a semibatch oxidation reactor, where the role of the composition of both the gaseous and the liquid feed has been investigated. It is shown that the model describes the reactor behavior in any of the regimes which may prevail depending upon the operating conditions and the depletion of liquid reactants in time.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 32
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1466-1478 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: As recently recognized, distillation columns, operating with reflux and boilup as independent inputs, may have multiple steady-state solutions, even in the ideal binary case. Two fundamentally different sources may cause the multiplicity, and in both cases some operating points are found to be unstable. This article provides evidence for the instability and discusses the effect of operating conditions on stability. Increasing the internal flow rates increases the probability of instability; when flows other than reflux and boilup are used as independent inputs, an operating point may become unstable if the level control is not sufficiently tight. In this case, a limit cycle, usually stable, appears as the steady state goes unstable.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 33
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1223-1237 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Heavy metals like Cu2+, Cr6+, and Hg2+ were removed successfully from wastewater and concentrated in a strip aqueous solution for recycle using the hollowfiber-contained liquid membrane (HFCLM) technique. Using cotransport, Cr6+ and Hg2+ present as anions in the feed solution were transferred individually through a liquid membrane containing tri-n-octylamine in xylene and concentrated in an alkaline solution on the strip side. The removal efficiency of each heavy metal was studied as a function of the aqueous feed flow rate in an HFCLM permeator. Copper present as cation Cu2+ was removed and concentrated by countertransport using LIX84 in n-heptane as the liquid membrane. The efficiency of copper removal was studied as a function of feed copper concentration, feed flow rate, strip flow rate, and area ratio between the feed fiber set and strip fiber set. The strip side flow rate did not affect the Cu2+ transfer rate. A theoretical model presented predicts the copper transport rate from the feed solution to the strip solution in an HFCLM permeator with a variable feed to strip-side membrane area. Both feed aqueous boundary layer and interfacial complexation reaction on the feed side dominate the observed Cu2+ removal process through LIX 84 in n-heptane for feed concentration levels used 90-500 mg/L. It was verified by providing two times larger liquid-liquid interfacial area in the feed aqueous side or in the strip aqueous side. The model can be used to design the membrane area required on the feed and strip fiber sides to remove essentially all of the copper from a given wastewater stream.
    Additional Material: 17 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 34
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1629-1638 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The physical absorption of CO2 and propene into toluene/water emulsions is studied in a stirred cell and laminar film absorber. Experimentally observed masstransfer rates are compared to an absorption model, based on Higbie's penetration theory describing physical gas absorption into an emulsion. For all absorption experiments in a stirred cell absorber (toluene fractions and stirring rates), experimentally observed mass-transfer rates are considerably higher than the rates predicted by the absorption model. Moreover, the absorption rate decreases with increasing stirring rate, whereas no influence of the stirring rate is predicted by the absorption model. In contradiction to the absorption experiments in a stirred cell absorber, the observed mass-transfer rates in the laminar film absorber agree with the model simulations. Probable existence of a very thin toluene layer is observed on top of the emulsion for the stirred cell experiments, likely due to minor phase separation. Since in the laminar film absorber gas-liquid interface and the gravity force are parallel, this phenomenon does not probably occur significantly for absorption experiments in this absorber. The observed mass-transfer phenomena can be explained, at least qualitatively, from the occurrence of a thin toluene layer.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 35
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1650-1664 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A strategy for the automatic synthesis of plant operating procedures, through the integration of artificial intelligence and mathematical modeling tools is discussed. This “predicative/numerical” modeling paradigm integrates qualitative and quantitative aspects of the problem in a same framework. It uses a “process-centered” qualitative modeling approach together with MILP optimization techniques to automatically generate operating strategies. The operation procedures network (OP-Net), formulated in terms of processes from a generic library, describes abstract (hardware-independent) processing paths leading to the desired operational goals. In this approach, the model assumptions, conservation expressions and data are described at the same level of abstraction, using the same formal representation. This permits the direct, automatic generation and modification of operation procedures in situations involving changes in basic assumptions and initial scenarios. Thus, flexibility, an essential feature of batch processing, is safeguarded.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 36
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1312-1327 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The open-loop optimal control strategy to regulate the crystal-size distribution of batch cooling crystallizers handles input, output, and final-time constraints, and is applicable to crystallization with size-dependent growth rate, growth dispersion, and fines dissolution. The objective function can be formulated to consider solid-liquid separation in subsequent processing steps.A model-based control algorithm requires a model that accurately predicts system behavior. Uncertainty bounds on model parameter estimates are not reported in most crystallization model identification studies. This obscures the fact that resulting models are often based on experiments that do not provide sufficient information and are therefore unreliable. A method for assessing parameter uncertainty and its use in experimental design are presented. Measurements of solute concentration in the continuous phase and the transmittance of light through a slurry sample allow reliable parameter estimation. Uncertainty in the parameter estimates is decreased by data from experiments that achieve a wide range of supersaturation. The sensitivity of the control policy to parameter uncertainty, which connects the model identification and control problems, is assessed. The model identification and control strategies were experimentally verified on a bench-scale KNO3-H2O system. Compared to natural cooling, increases in the weight mean size of up to 48% were achieved through implementation of optimal cooling policies.
    Additional Material: 17 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 37
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 888-898 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The design of efficient continuous sterilization equipment for flowing solid-liquid food mixtures requires that temperature and velocity distributions within the fluid are known. In electrical (ohmic) heating, electric current is passed through a two-sterilize it. This allows rapid sterilization of solid-liquid mixtures which minimizes quality loss. A computational process model simulates the effect of realistic physical property changes. The effect of variations in physical properties can have a significant effect on the temperature of the product and thus on its sterility. Realistic designs will have to cope with temperature differences between phases. Experimental data for velocities in a food flow have been incorporated into an enthalpy balance model for heat transfer in solid-liquid mixtures. The effect of inlet temperature on the length of hold tube required to give the necessary process sterility calculated shows the variation in output conditions that might results in real systems.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 38
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1769-1781 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The baffled cavity flow - the first representative of a class of chaotic flows produced by time-dependent changes of geometries - is introduced and extensions to spatially-periodic systems proposed. Both experimental and computational results are reported. The goal of the study is to put into evidence some of the steps and considerations when designing a new mixing flow; a related objective is to demonstrate the use of an efficient and accurate numerical technique (BIEM) suitable for mixing studies in time-dependent geometries. Several parameters that affect the degree of mixing are studied: the mixing protocol - how the baffles are alternated and how many baffles are used in the flow during each piecewise motion; baffle sizes and shapes; geometrical and flow parameters, such as the wall displacement per period; and details of the baffle's motions.
    Additional Material: 17 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 39
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1814-1824 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A class of models is derived for studying the effects of chemical kinetics on residue curve maps for reactive distillation. Activity-based rate and phase equilibrium expressions provide an accurate and thermodynamically consistent description of composition changes in nonideal, reacting vapor-liquid mixtures. For certain strategies of operation, which dictate the rate of product removal, the model equations are nonautonomous, leading to unusual dynamic behavior. However, for a certain special product removal policy, the effects of kinetics can be described by a single parameter, the Damköhler number, which measures the rate of reaction relative to product removal. For small values of the Damköhler number, the nonreactive simple distillation residue curve map is recovered and the singular points are the pure components and azeotropes in the nonreactive mixture. A bifurcation analysis shows the deformation and, in some cases, the disappearance of these singular points as the Damköhler number is increased until the equilibrium reactive residue curve map is recovered at large values. This bifurcation analysis reveals the limitations of the equilibrium analysis. A model problem for the reactive distillation of methyl tertbutyl ether from isobutene and methanol is solved.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 40
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1865-1875 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Recurrent neural networks are used to demonstrate the dynamic data rectification of process measurements containing Gaussin noise. The performance of these networks is compared to the traditional extended Kalman filtering approach and to published results for model-based nonlinear programming techniques for data reconciliation. The recurrent network architecture is shown to provide comparable, if not superior, results when compared to traditional methods. The networks used were trained using conventional nonlinear programming techniques in a batch fashion.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 41
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1892-1900 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The phase and chemical equilibria of flue-gas/water systems containing sour gases such as HCl, HF, SO2, SO3, NOx and volatile heavy metal compounds such as Hg, HgCl2, and SeO2 are calculated from thermodynamic standard data using the Gibbs free energy minimization method. The Pitzer/Debye/Hückel equation is used for the activity coefficients of the ions in the aqueous solution. The inhibition of certain oxidation reactions is considered by a proper formulation of the atom matrix. The comparison of the calculated equilibrium values to experimental data from a coalfired power plant show that concentrations of most pollutants at the outlet of the absorbers are close to the equilibrium values of one single theoretical stage. The extension of the Gibbs free energy minimization to multistage countercurrent absorbers gives the concentration profiles of various components.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 42
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1055-1066 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The conversion of radiant light energy into chemical affinity by microorganisms in photobioreactors is examined. The kinetics of entropy production in the system is theoretically established from entropy and energy balances for the material and photonic phases in the reactor. A negative chemical affinity term compensated for by a radiant energy term at a higher level of energy characterizes photosynthetic organisms. The local volumetric rate of radiant light energy absorbed, which appears in the dissipation function as an irreversible term, is calculated for monodimensional approximations providing analytical solutions and for general tridimensional equations requiring the solution of a new numerical algorithm. Solutions for the bluegreen alga Spirulina platensis cultivated in photoreactors with different geometries and light energy inputs are compared. Thermodynambic efficiency of the photosynthesis is calculated. The highest value of 15% found for low radiant energy absorption rates corresponds to a maximum quantum yield in the reactor.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 43
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1929-1939 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The breakup of droplets in an inhomogeneous flow is the key to emulsification. Frequently, the local flow experienced by the drops is a (quasi-) simple shear flow. The breakup of droplets in a steady, simple shear flow in the absence of emulsifiers has been studied extensively. In the presence of emulsifiers, the droplet interface may acquire viscoelastic properties, which are important in the prevention of coalescence, but their influence on droplet breakup has not been established solidly. This article reports on a phenomenological approach, which links the droplet breakup dynamics to the interfacial viscoelasticity, identifying the latter with the elasticity modulus of a deforming planar interface. Over a viscosity ratio range of three decades, the results have been found to agree with the model, which uses only independently known quantities derived from equilibrium interfacial tension properties.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 44
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1950-1960 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Liquid-phase mass-transfer coefficients are determined for the absorption of sulfur dioxide by water drops larger than 1.1 mm in dia. A local model based on the large eddy interfacial model proposed by Fortescue and Pearson (1967) is obtained by the characteristic interfacial scaling. In particular, the agitation process of the liquid phase in the interfacial region is characterized by the interfacial liquid friction velocity. Experiments of sulfur dioxide absorption and desorption from large individually free-falling water drops are also carried out in a 5-m rain shaft under various environmental conditions. These experimental results agree well with those from the local model characterizing the interfacial process in water drops greater than 1.1 mm in dia.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 45
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1982-1982 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 46
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1976-1982 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A 200-s PSA cycle involving both pressure equalization and product backfill steps has been experimentally studied on a four-bed system, where LINDE 5 A zeolites were used as the adsorbent to separate oxygen from air. This cycle is operated under a pressure ratio of 4.3. During the experiment, the pressure history and flow rates, as well as the concentration of the product stream have been continuously monitored. This is the first time detailed experimental data on a four-bed system are presented. Under favorable conditions, this system produces better than 90% oxygen at a recovery of 17%. For the low-pressure ratio, such a recovery could not have been achieved without the pressure equalization step and the reduced purge operation. Recovery and throughput, however, are not as high as one would expect from a linear local equilibrium model. The self-broadening effect of the purge wave has been identified as the major cause of underperformance.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 47
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1993-2021 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The interest in emulsion polymerization is strong because it offers the possibility of producing products with special properties not easily produced by other types of polymerization processes. Because the main reaction medium is water, not an organic solvent, its importance is steadily increasing with efforts to design environmentally benign processes. The control of emulsion polymerization is a challenging problem due to major limitations encountered in its modeling and on-line monitoring. Although emulsion polymerization has been studied and used for several decades, progress has been slow. Industrial practice relies heavily on experience while several controversial issues are still being studied. The literature related to this issue is vast and sometimes contradictory, and most deals with experimental investigation of specific emulsion polymerization systems to improve the process understanding and develop a process model. However, universally accepted conclusions are scarce. This article reviews the major issues related to control of emulsion polymerization. The latest contributions in process understanding, mathematical modeling, sensor technology, and process control techniques for emulsion polymerization are discussed. Emphasis is on contributions, which are important in resolving the control of emulsion polymerization processes.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 48
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1341-1348 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An automated distillation sequencing system (DSEQSYS) is presented, which consists of three components: a control program, a fuzzy heuristic synthesis program, and a process simulator. DSEQSYS, when applied to problems previously reported in the literature, overcomes some of the disadvantages of using heuristics or mathematical programming alone. DSEQSYS can address problems involving nonsharp separations, nonideal chemical behavior, and conflicting heuristics. A simple approach for converting the traditional separation heuristics into corresponding fuzzy heuristics is also demonstrated.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 49
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1349-1360 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The search for potential solvents for liquid extraction and extractive distillation is carried out through a group contribution molecular design of solvents (MOLDES) approach. A set of submolecular groups (UNIFAC) is used for the synthesis of molecular structures with desired solvent properties. Submolecular group combination (linking) properties are characterized to ensure the chemical feasibility of the MOLDES generated molecular structures. The size of the combinatorial problem posed by the molecular synthesis procedure is reduced by group selection and by imposing physical and molecular constraints at different stages. Criteria are developed for solvent evaluation and the reliability of the VLE and the LLE UNIFAC parameter tables for solvent screening are compared with experimental data for the recovery of oxychemicals by liquid extraction from dilute aqueous solutions.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 50
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 120-130 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Spatiotemporal patterns existing in a one-dimensional fixed-bed reactor with oscillatory or excitable kinetics are analyzed to develop the methodology of motion identification and classification. The reactor model accounts for a local (solid-phase) oscillator and a global (gas-phase) convective interaction. The local oscillator incorporates a fast and diffusing surface temperature and a localized activity as its dynamic variables. Such kinetics admit a traveling pulse solution or homogeneous oscillations in a uniform medium. In a fixed-bed reactor, the local conditions in the bed (the phase plane character) vary along the system. The response of an excitable bed to local perturbations depends on its location (at inlet or outlet) and the nature of the initial steady state ( ignite or extinguished). The main spatiotemporal-sustained patterns in the bed are: almost homogeneous oscillations that appear as parallel bands in the time-space contour map; oscillatory fronts that emerge from the reactor exit, and aperiodic motion that appears as split-bands. Pattern selection is determined by the phase planes spanned by the reactor and the ratio of the two slowest time scales: front residence time and period of oscillations.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 51
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 131-142 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Thermolysis of coal yields a complex mixture of many extract products whose molecular-weight distribution (MWD) varies with time for continuous-flow, semi-batch experiments. A laboratory flow reactor with a differential fixed bed of coal particles contacted by supercritical tert-butanol was used to provide dynamic MWD data by means of HPLC gel permeation chromatography of the extract. The experimental results, multipeaked, time-dependent MWDs of extract molecules, are interpreted by a novel mathematical model based on continuous-mixture kinetics for thermal cleavage of chemical bonds in the coal network. The parameters for the MWDs of extractable groups in the coal and the rate constants are determined from the experimental data. The effect of temperature on the kinetics of the extraction is explained in terms of one- and two-fragment reactions of the extractable groups in the coal. At lower temperatures (613 and 633 K) single-fragment reactions dominate, but at higher temperatures (653 and 673 K) more bonds in the coal are broken and the two-fragment reactions become significant. Also, the detailed MWDs are related to conventional lumped data for the thermolytic extraction process. The results yield information about the structure of coal, as well as the kinetics and mechanism of supercritical thermolytic reactions.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 52
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 143-151 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A flue gas desulfurization process being developed for coal-fired power plants removes and concentrates sulfur oxides (SOx). The key element is an electrochemical cell using a sulfur oxide selective membrane. It achieves 90% sulfur oxide removal with near 100% electric current efficiency.Recent research has focused on improving the structure of the electrochemical membrane and its interface with the electrodes. The capillary forces of the membrane and porous electrodes establish an equilibrium. To maintain electrode surface area enhancement, it is necessary to retain the electrolyte in the membrane and allow only wetting of the electrode pores. Chemically-stable matrix materials for the membrane have been identified; several fabrication techniques were used to prepare the actual membrane structure. A new electrode material, (LiO)xNiO, possesses the proper chemical stability and electrical properties in the corrosive environment. These modifications have led to an order of magnitude increase in flux and operating lifetime.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 53
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 738-739 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 54
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 55
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 56
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 726-737 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Environmental concerns have dictated the replacement of CFC-12 refrigerant with HFC-134a in automotive air-conditioning (A/C) systems. Since polyglycols are synthetic compounds compatible with HFC-134a and considered as lubricants for the A/C compressor, interations of HFC-134a with glycol-type compounds and thermodynamic properties of the solutions are important in designing an A/C system. In this work, the solubility of HFC-134a in four glycol-type compounds was measured at -5 to 80°C and 90 to 960 kPa. HFC-134a had the greatest solubility in tetraethylene glycol dimethyl ether. HFC-134a was less soluble in hexylene glycol and tetraethylene glycol and least soluble in triethylene glycol. Mixtures of HFC-134a with TRIG or TGDE showed phase separation. Solubility data were used to calculate the activity coefficient of HFC-134a in glycol solutions. An equation of the form, lnγr = (1 - xr)[A + Bxr], was found to correlate γr to the mole fraction of HFC-134a in the solution where A and B are constants which may depend on the temperature. Based on a model assuming a specific interaction between molecules and using the activity of HFC-134a, a higher degree of interaction is expected between HFC-134a and tetraethylene glycol dimethyl ether molecules than between the molecules of HFC-134a and other glycols. In general, glycols with free -OH groups may have less affinity for HFC-134a. Solubility is discussed in terms of its parameters and chemical structure of the glycols, as well as the effect of temperature on the solubility, the activity coefficient, and the thermodynamic properties of the HFC-134a/glycol solutions.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 57
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 777-785 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The desorption profiles of various organics from soil and activated carbon using dense liquid and supercritical carbon dioxide were modeled. The model accounts for effective diffusion of the organics in the solid pores, axial dispersion in the fluid phase, and external mass transfer to the fluid phase from the particle surface. This model, involving partial differential equations, is solved using the orthogonal collocation on finite elements. The model is able to predict the experimental data quite well without any adjustable parameters. The importance of each parameter depended on the system, although adsorption equilibrium and the effective pore diffusion of the organic were the most significant parameters in all the systems investigated.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 58
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 767-776 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Liquid-liquid dispersions are commonly used for separations and reaction systems, because the added interfacial area due to dispersion aids in mass transfer and chemical reaction rates. Transient coalescence experiments have been performed for a wide range of dispersed-phase fractions and impeller speeds. A similarity transformation of the experimental drop-size distribution is possible for most of the experiments. The drop-size-dependent coalescence frequency is obtained from an inverse problem procedure previously developed. Over the range of drop sizes encountered in our experiments, the coalescence frequency increases with increases in the size of the coalescing drops, the dispersed-phase fraction, and the impeller speed. For a dispersephase system of neutrally buoyant droplets of benzene/carbon tetrachloride in water, the coalescence frequency is K(v, v′)= 3.72 (10-3)φ1.42N20.52(v1/2+v′1/2) as a function of dispersed-phase fraction, φ, impeller speed, N2, and volumes of the coalescing droplets, v and v′. The results are compared with previous models for the coalescence frequency. Models predicting an eventual decrease in coalescence rates with drop size are disqualified unless this decrease occurs beyond the sizes observed in our experiments.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 59
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 756-766 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The falling liquid film has become a popular means of transferring heat and mass from a vapor to a binary liquid, especially in gas-fired heat pump systems. Ideally, the required amount of heat and mass transfer can be accomplished by using a simple cylindrical tube; however, increasingly stringent size and weight requirements for the machine prohibit use of the simple cylindrical surface, and other more complex surfaces with higher absorption capacities have been sought. In this article, absorption of a single component and condensation of a binary mixture on an axially fluted tube is considered. The solution to the problem hinges on the energy equation, although the entire energy transfer process is mass-transfer-limited. Significant mass transfer is limited to a thin layer near the liquid-vapor interface. Solutions to the energy equation are obtained for both the conduction- and convection-dominated regimes. In the latter, significant heat transfer occurs within a thin layer near the liquid-vapor interface which contains the mass transfer layer; this “boundary layer” structure does not appear to have been recognized in previous work in this area. Using the present results, the capacity of a given tube may be predicted as a function of governing geometrical and physical parameters. The principal objective of this work is to develop the theoretical tools from which computations may be carried out during a design process. The theoretical results may be applied to mixtures typical of application in the absorption heat pump industry.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 60
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 786-798 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new approach for developing fundamental equations of oxygen permeation through thin mixed-conducting oxide ceramic is presented considering both surface reactions on membrane-gas interfaces and the diffusion of charged species in the bulk oxide. The essence of this work is the coupling of surface reactions with the bulk diffusion using a novel approach which differs from the conventional Wagner. Theory applicable only to limited cases. With this approach, fundamental equations based on various permeation mechanisms can be derived for oxygen permeation through thin mixed-conducting oxide membranes, which is impossible using conventional approach. In general, the final results are a complex implicit equation correlating the oxygen permeation flux to the driving force, membrane thickness, and rate constants with physical significance in each step. Somewhat simpler theoretical oxygen permeation equations are obtained for some special cases (mixed-conducting membranes with a rate-limiting step, ionic-conducting membranes, ionic-conducting membranes with a reducing agent in permeate side). Theoretical results derived using this new approach agree excellently with the experimental oxygen permeation data. It is theoretically and experimentally shown that for ionic conductors, the surface permeation parameter measured by the dynamic permeation method is directly related to the oxygen isotope exchange rate constant measured under equilibrium conditions.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 61
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 160-165 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Water vapor pressure for cornstarch and popcorn grits at a temperature of between 100 and 180° C was determined by measuring vapor pressures generated at various moisture contents in a heated, closed system. At a higher temperature, fugacity of water increased with increasing temperature probably because of melting or partial melting of starch. The apparent heat of sorption for cornstarch changed significantly with moisture content and temperature. Noncondensible gases were produced by heating popcorn grits to temperatures above 150°C. It is not accurate to estimate vapor pressure based on the heat of sorption or extrapolation of currently used empirical isotherm equations to a temperature above 100°C. Vapor pressure inside popcorn at the instant of popping are. roughly 758 to 827 kPa (110 to 120psia).
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 62
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 849-861 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A systematic methodology applicable to the optimal design of stable process systems is presented. It is based on the formulation of a parametric problem that provides bounds on the optimal stable solution and an iterative algorithmic approach that attains convergence of the bounds in a finite number of iterations. The bounds on the optimal stable solution are based on analytical expressions of bounds on the eigenvalues of the Jacobian matrix using the concept of the measure of the matrix. When extended to the synthesis problem of reactor networks, the approach is able to couple the optimization problem with stability issues even in cases where the number of reactors is large and the reaction mechanism is described by a general complex reaction scheme. Furthermore, since at the synthesis level the reactor network represents an exhaustive superposition of the existing structural and operational alternatives, the approach fully exploits these alternatives and coordinates a weighted optimal search that improves the objective and accommodates a stable reactor network. This approach is not restricted to the synthesis of reactor networks and can be applied to the design of total process flowsheets.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 63
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 870-877 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Oxidative coupling of methane was conducted by using membrane reactors. The nonporous membrane film that consisted of PbO modified by alkaline or alkaline earth compound was supported on porous SiO2-Al2O3 tube. Higher hydrocarbons were successfully synthesized with high selectivity (about 90%). A kinetic analysis was conducted to clarify whether oxide ion transportation through PbO film participated in the oxidative coupling of methane. The evaluated value of the diffusion coefficient of oxide ion transport based on the methane oxidation agreed well with that of published data. The simulated gradient of the oxide ion concentration through the PbO membrane agreed well with that measured by electron probe X-ray microanalyzer. A transient response simulated by using kinetic parameters evaluated from steady-state analysis also agreed well with the experiment. These results prove the validity of the reaction model that consists of surface reactions of methane with oxide ion which is transferred from inside to outside of the membrane reactor. Alkali modifiers on the PbO membrane surface exhibited a promotional effect on the surface reaction of methane coupling. Another membrane reactor containing Bi2O3 showed higher activity than the PbO membrane.
    Additional Material: 17 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 64
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 908-910 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 65
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 899-907 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Optimal control strategies for maximizing the production of induced foreign protein by recombinant bacteria were sought by the optimal control theory. Nutrient and inducer feeding rates were selected as key control variables. Since the problem is linear in the control variables, the optimal control is bang-bang or singular. Singular solutions are shown to exist. The optimal control theory showed that the specific growth rate with respect to nutrient concentration must be kept in its maximum phase and that there exist both a cell growth period and a protein production periods. The optimal control theory calculates exactly the growth and production periods. The glucose concentration is controlled along a singular are to give a maximum specific growth rate. The inducer level is controlled along a separate singular arc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 66
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 911-911 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 67
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 935-943 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Equilibrium and kinetic data for adsorption of trace CF2Cl2 (Freon-12) from various carrier gases on BPL activated carbon are reported. Coadsorption of the bulk carrier gas can severely reduce the equilibrium adsorption capacity and adsorptive mass-transfer coefficient of strongly adsorbed CF2Cl2. The difference in size between CF2Cl2 and the bulk carrier gas molecules plays a major role in establishing the binary or multicomponent equilibrium adsorption properties. The multisite (single and multicomponent) Langmuir model, which accounts for differences in adsorbate sizes, provides a reasonable framework for describing the size effects. The adsorptive mass transfer of CF2Cl2 under the experimental conditions investigated is dominated by surface diffusion into the pores of the activated carbon. The surface diffusivity is a strong function of the extent of coverage and strength of adsorption of the bulk components.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 68
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 956-956 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 69
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 966-979 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The dynamic behavior of processing systems exhibits both continuous and significant discrete aspects. Process simulation is therefore a combined discrete/continuous simulation problem. In addition, there is a critical need for a declarative process modeling environment to encompass the entire range of processing system operation, from purely continuous to batch. These issues are addressed by this article.A new formal mathematical description of the combined discrete/continuous simulation problem is introduced to enhance the understanding of the fundamental discrete changes required to model processing systems. The modeling task is decomposed into two distinct activities: modeling fundamental physical behavior, and modeling the external actions imposed on this physical system. Both require significant discrete components. Important contributions include a powerful representation for discontinuities in physical behavior, and the first detailed consideration of how complex sequences of control actions may be modeled in a general manner.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 70
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 991-1004 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The spontaneous ignition of coal stockpiles is a serious economic and safety problem. This phenomenon is analyzed using the approach of modern reaction engineering, which is made challenging by the nonlinear interactions of chemical reaction, heat transfer, and buoyancy-driven flows within and around the stockpile. A model developed represents reaction and transport within a realistically-shaped stockpile and transport and flow in the surrounding air. A new methodology based on the Galerkin finite-element method (Salinger, 1993b) allows for efficient solution of flows in both porous and open domains. Bifurcation analysis is used to track steady-state model solutions of relevant parameters, such as the Damköhler number (dimensionless reaction rate), Rayleigh number (dimensionless driving force for buoyant flow), and dimensionless permeability of the stockpile. The solutions provide an understanding of the roles of various transport mechanisms on the ignition behavior and nonlinear coupling between these mechanisms. Results clearly demonstrate the need for incorporating realistic descriptions of flow and transport in the surrounding air into the model.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 71
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 361-364 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Various phenolic compounds in aqueous buffer solutions were contacted batchwise with powdered activated carbon. Relatively slow, but continual, decreases in the solution phenolic concentrations were measured over a period of several weeks. The decreases were due to oxidative coupling reactions of the phenolics which occurred on the carbon surface subsequent to adsorption. The effects of time, pH, dissolved oxygen, and the molecular nature of the phenolic were determined.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 72
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 373-377 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 73
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 378-379 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 74
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 381-382 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 75
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 76
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 385-394 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Two methods are presented for calculating the interfacial tension between two immiscible Newtonian fluids. The procedures require only two measurements of the approximate interface shape during the low-Reynold-number interfacial-tension-driven transient motion of (i) the relaxation of a modestly elongated drop back to a spherical shape or (ii) the growth of capillary wave instabilities along the surface of a thread. The interfacial tension can be estimated by comparing the time differences between the two experimental measurements with tabulated and numerically generated results for the approximate shape evolution. The numerical results are generated using boundary integral method for similar model free-boundary problems at low Reynolds numbers. The tabulated results are presented for drop to suspending fluid viscosity ratios 0.01 to 10.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 77
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 78
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1412-1417 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 79
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1426-1430 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 80
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1422-1425 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 81
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1087-1087 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 82
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1440-1448 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The forced convective heat and mass transfer to spherical-cap bubbles were investigated analytically. Potential flow was assumed outside the bubble except at the bubble surface where the boundary layer approximation was adopted. The present analytical study produced the following exact solution: \documentclass{article}\pagestyle{empty}\begin{document}$$ Nu = 2.113{\rm}\left({Pe} \right)^{1/2} $$\end{document} for the average Nusselt number where Pe is the Peclet number. The derived equation was compared with the available experimental mass-transfer results.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 83
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1449-1458 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Gel/micelle materials, comprising hydrogels containing block copolymer micelles, have the potential to be very useful in a variety of extraction and controlled release applications. It is demonstrated that block copolymer surfactants can be immobilized in calcium alginate gels and that the resulting composite material preferentially solubilizes the model hydrophobic solute naphthalene. Five different polyethylene oxide-polyropylene oxide-polyethylene oxide triblock copolymer surfactants are considered, and the qualitatively different properties exhibited are interpreted in light of the properties of these surfactants in solution. Alginate gel concentrations of 22.5 and 52.5 g/L and surfactant concentrations ranging from 20.4 to 136 g/L are considered. The data indicate that micelles can be permanently immobilized for purposes of extraction or controlled release and that the extent of solute uptake or release can be altered by varying gel and surfactant concentration and the type of surfactant employed.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 84
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1459-1465 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental studies were performed to assess the effect of salt addition on the extraction of 1-butanol, ethanol and acetone from dilute aqueous solutions using cyclopentanol, n-valeraldehyde, tert-amyl alcohol, and Adol 85NF as extractants. The liquid-liquid partitioning was examined for a few strong electrolytes in a broad range of concentrations. Results demonstrate that the distribution coefficient and selectivity in systems with reduced water activity resulting from salt addition were markedly increased. These observations can be qualitatively explained on the basis of the hydration theory. It was also determined that strong electrolytes added to the aqueous feed reduced extractant solubility in the aqueous phase, thus contributing to lower solvent losses. The results showed that the extraction efficiency was not significantly affected by increasing salt content beyond a level that reduces the water activity to a value of 0.92.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 85
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1433-1439 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It is generally believed that oil samples heat faster in a microwave oven than do water samples of the same mass. For sufficiently large and thich samples this conventional wisdom is indeed correct, but this trend can be far from true in smaller samples. In a commercially-made home microwave oven, we observed that with decreasing sample size the heating rate of a water sample increases much faster than that of an oil sample. At 50 g the heating rate of a water sample is several times greater than that of an oil sample. Additionally, in studies of cylindrical samples in a customized oven having a unidirectional microwave source, the heating rate of water samples smaller than 2.4 cm in radius is greater than that of oil samples and is a strongly oscillatory increasing function of decreasing sample radius. Combining Maxwell's theory of microwave penetration and the heat conduction equation, we show that this previously unreported oscillatory heating behavior results from the added power absorbed by samples due to resonant absorption of microwaves. The added power arises from standing waves produced by internally reflected microwaves. This effect is small for oil because only 3% of the microwave power is reflected at an oil-air interface. On the other hand, 64% is reflected at a water-air interface, which causes strong resonant heating. Our findings might prove to be useful for future consumer food product development or oven design.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 86
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 745-755 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Local heat-transfer measurements are performed using a special heat-transfer probe in gas-liquid and gas-liquid-solid systems with viscous Newtonian liquids as the continuous phase. Effects of viscosity on bubble-liquid and bubble-liquid-solid interactions affecting local heat transfer are studied through heat-transfer experiments with simultaneous flow visualization in a simplified system involving single bubbles or a chain of gas bubbles moving in viscous liquids and liquid-solid systems. Effects of viscosity on bubble wake and local heat transfer are examined with reference to heat transfer in freely-bubbling beds (bubble columns and three-phase fluidized beds). The kinematic viscosity of the fluid greatly influences the nature of flow in the wake which affects local heat transfer in the bed. The local heat transfer decreases with the viscosity due to the rapid decay in the circulation strength of the bubble wake caused by increased viscous dissipation of vorticity. Local heat transfer due to cyclic/periodic injection of bubbles is significantly enhanced due to increased bubble-wake interactions which rapidly accelerate bubbles and increase average bubble rise velocity. Heat transfer in simplified liquid and liquid-solid systems with single- and chain-bubble injections characterizes the local heat-transfer performance of freely-bubbling beds (bubble columns and three-phase fluidized beds). A mechanistic model developed accounts for the heat-transfer behavior in bubble columns and three-phase fluidized beds with viscous liquids.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 87
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 799-812 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A direct optimization method to estimate nucleation and crystal growth rate parameters from seeded batch cooling crystallization experiments is evaluated. The experimental information applied comprises the concentration of the solution and the temperature as functions of time and the final product size distribution. Parameters in kinetic equations are determined by nonlinear optimization of a dynamic model of the experiment, by which intermediate approximations of experimental data are avoided. The optimization objective function includes both solution concentration data and product size distribution data. Kinetics are estimated for succinic acid crystallizing in aqueous solutions. Results from several different cooling crystallizations are simultaneously supplied into one single optimization to determine seven parameters.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 88
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 813-825 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Reduced-order models are developed based on orthogonal collocation on finite elements for the steady-state optimization of multicomponent distillation units. The formulation divides the column sections into subdomains (finite elements) to track irregularities in the column profiles accurately and requies that plates with discontinuities in the flows introduced by feedstreams or sidestreams should be treated as discrete equilibrium stages. Application of the model formulation to a number of examples show that reduced-order models converge to the same optimal solution as the full-order, tray-by-tray model. Optimization results show that computational time can be reduced significantly using the more compact model formulation, and it is possible to converge to the optimal solution from a larger region for the initial set of variable values.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 89
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 90
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1268-1272 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 91
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1549-1557 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A “capillary condensation” in liquid phase was analyzed theoretically and experimentally, in which a solute in solvent could be separated out as a liquid into small pores by capillary effect. The “liquid-phase capillary condensation” is defined as capillary phase separation. The separated phase is counted as “adsorbed” amount on porous materials. The relation between the concentration and a critical radius of the phase separation was derived. A new method to estimate liquid-phase adsorption isotherms of adsorbates with limited solubility from pore-size distribution of solids is based on this concept. The amount absorbed consists of the separated phase and adsorption on surface expressed with a single parameter. While the surface adsorption alone could not explain measured isotherms, this model showed good agreements between experimental and estimated isotherms for adsorption of four kinds of aromatic compounds from aqueous solution onto three categories of porous solids to demonstrate the significance of the capillary phase separation. The applicability of the method to solid solutes is also discussed.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 92
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1574-1579 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A relatively simple continuous dilution method with on-line spectrophotometric measurement has been used to determine the phase transition boundaries of aqueous two-phase polymer systems. The observed range of compositions over which the phase transition occurs is dominated by the polydispersity of the polymers, but also is a function of the dilution path followed. The binodal curve obtained by the continuous dilution method agrees well with the results obtained by the traditional method of phase equilibration, separation and analysis of liquid chromatography, which is slower and requires more expensive equipment.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 93
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1594-1598 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 94
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1601-1610 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effect of imposed large-amplitude oscillations on turbulent drag is studied. The system consists of water flow through a straight 5.08-cm pipe. The velocity gradient at the wall is measured with flush-mounted electrochemical mass-transfer probes. Newly developed numerical algorithms are used to analyze the probe performance in the presence of unsteady flows. Sinusoidal oscillations are at large enough frequencies, ω+ = 0.0138-0.0506, that a pseudo-steady-state approximation cannot be made. The ratio of the time-averaged velocity gradient at the wall, with and without oscillations, S̄, varies between 1.00 and 1.03, provided flow reversal does not occur. However, two experiments in which reversed flows existed at the wall for an appreciable period of time show drag reductions of 7 and 13%.Imposed nonsinusoidal oscillations are also studied for a period of favorable pressure gradient, about twice longer than that of unfavorable, and two sudden changes in the pressure gradient. Experiments at Re = 9,700 with T0 of 2.00, 2.45, and 3.46 s, and at Re = 19,200 with T0 = 3.46 give values of S̄ = 1.04-1.08. At Re = 19,200 and T0 = 2.00, 1.50, 1.00 s, drag reductions are 10-15%. This phenomenon could be associated with the speed with which a flow adjusts to sudden changes in the pressure gradient.
    Additional Material: 17 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 95
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1618-1628 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Separating mixtures of α-amino butyric acid (ABA) and isoleucine (Ile) by displacement chromatography with a cation exchange resin and an alkaline displacer leads to the formation of a displacement train, in which only ABA is recovered as a pure component, while Ile is recovered in a mixed band with ABA. The purity of the Ile band depends on the concentration of the displacer, and essentially pure Ile is obtained when the displacer concentration is reduced to a low value. The observed behavior is explained by considering the nonideality of the equilibrium uptake of these amino acids by the resin. An equilibrium model, representing the pure component isotherms, predicts variable selectivity and the occurrence of selectivity reversal in the two-component system. Analyses using this model based on the theory of coherent waves and a numerical solution of the conservation equations for the displacement chromatography process agree with the observed behavior, predicting the formation of “azeotropic” bands during the development of the displacement train. Such analyses are used to determine under what conditions a complete separation may be obtained for a given experimental system.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 96
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1639-1649 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Elliptical basis function (EBF) networks are introduced as a new nonparametric method of estimating probability density functions for process data. Unlike Parzen window density estimators that use identical hyperspherical basis functions, the EBF method uses elliptical basis functions adapted to the local character of the data. This technique overcomes the spikiness problem associated with Parzen windows, where in high dimension, they can fail to produce smooth probability density estimates. The EBF estimator produces valid density functions that converage to the underlying distribution of the data in the limit of an infinite number of training examples. A technique based on statistical cross validation is introduced for evaluating different density estimators. The criterion is a measure of how well the density estimator estimates the density of data not used in the training. The EBF density estimation method and the evaluation technique are demonstrated using several examples of fault diagnosis.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 97
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1804-1813 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Fouling of tube surfaces from flowing solutions or suspensions is examined. A new approach to the removal aspects of this process is presented linking removal to the morphological and mechanical characteristics of deposit microstructure. A simplified description of deposit microstructure is employed, involving a collection of geometrically similar roughness elements. A dynamic situation is envisioned whereby these elements grow due to deposition and suffer breakage under the action of hydrodynamic forces. A mathematical model for the macroscopic fouling behavior based on the techniques of population balances is obtained and numerically analyzed. The behavior found is in agreement with experimental evidence.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 98
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1850-1864 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A closed-loop strategy for terpolymer composition control in semicontinuous emulsion polymerization of high solids content systems is presented. This strategy is based on a nonlinear adaptive controller that calculates the flow rate of the more reactive monomers to be added into the reactor to produce a terpolymer of a given composition. The nonlinear adaptive controller is based on a simplified mathematical model of the process that includes the on-line estimation of an adjustable parameter. The addition of a conventional feedback proportional-integral (PI) controller to the prediction of the nonlinear controller was studied by simulation. It is shown that the contribution of the PI controller is negligible. The controller was checked by computer simulation and also experimentally verified during the semicontinuous emulsion terpolymerization of high solids content (55 wt. %) of vinyl acetate, methyl methacrylate and butyl acrylate.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 99
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The mechanism of alginate droplet formation and experimental parameters for producing very small polymer microbeads (less than 100 μm dia.) using an electrostatic droplet generator studied showed that the microbead size was a function of needle diameter, charge arrangement (electrode geometry and spacing) and strength of electric field. Perfectly spherical and uniform polymer beads, 170 μm dia., for example, were obtained at a potential difference of 6 kV with a 26-gauge needle and an electrode distance of 2.5 cm. Increasing the electric field, and thus the surface charge in the vicinity of the needle, by increasing the applied potential, resulted in needle oscillation, giving a bimodal bead size distribution with a large fraction (30-40%) of microbeads with a mean diameter of 50 μm. The process of alginate droplet formation under the influence of electrostatic forces assessed with an image analysis/video system revealed distinct stages. After a voltage was applied, the liquid meniscus at the needle tip was distorted from a spherical shape into an inverted cone-like shape. Consequently, alginate solution flowed into this cone at an increasing rate causing formation of a neck-like filament. When this filament broke away, producing small droplets, the meniscus relaxed back to a spherical shape until flow of the polymer caused the process to start again. A large-scale multineedle device with a processing capacity of 0.7 L/h was also designed and produced uniform 400 ± 150 μm microbeads.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 100
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1082-1084 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...