ALBERT

Description: The Cap de Creus continental shelf and Cap de Creus canyon are located in the southern most sector of the Gulf of Lions, in the northwestern Mediterranean. The Cap de Creus continental shelf contains sandy and muddy sediments and an abrupt morpho­ logy, with rocky outcrops, relict bioherms, erosive features, and planar bedforms. The Cap de Creus canyon breaches the shelf at a depth of 110 m and denotes a marked dif­ ference in the morphology between the northern and the southern flank, reflecting a different depositional regime. The most common substrates correspond to coarse and medium sands (28%) and silty sediments (40%). The most common megabenthic assemblages of the shelf correspond to the communities of "offshore detritic" (31.95%) and "coastal terrigenous muds" (36.99%), mostly dominated by sea pens, alcyonaceans, and ceriantharians. The northern flank of the Cap de Creus canyon is predominantly depositional, whereas the southern flank is erosional. Rocky outcrops provide the sub­ stratum for cold­water coral (CWC) communities' development, in which the white coral Madrepora oculata is the most abundant species.

Description: The seasonal variation of the intrusion of the Philippine Sea Water into the South China Sea was studied by analyzing the historical hydrographic station data in the northern South China Sea and the Philippine Sea. Water masses at 150, 200, and 250 m were classified by discriminant analysis according to their temperature-salinity characteristics. At each depth, most water in the study region was classified into two groups representing the Philippine Sea Water and the South China Sea Water, respectively. The geographic distribution of water masses in the South China Sea shows that the Philippine Sea Water was present along the continental margin south of China between October and January. A westward current in the northern South China Sea in winter was inferred from the distribution of the intrusion water.

Description: Submarine groundwater discharge (SGD) into a shallow lagoon on the west coast of Mauritius Island (Flic-en-Flac) was investigated using radioactive (3H, 222Rn, 223Ra, 224Ra, 226Ra, 228Ra) and stable (2H, 18O) isotopes and nutrients. SGD intercomparison exercises were carried out to validate the various approaches used to measure SGD including radium and radon measurements, seepage rate measurements using manual and automated meters, sediment bulk conductivity and salinity surveys. SGD measurements using benthic chambers placed on the floor of the Flic-en-Flac Lagoon showed discharge rates up to 500 cm/day. Large variability in SGD was observed over distances of a few meters, which were attributed to different geomorphological features. Deployments of automated seepage meters captured the spatial and temporal variability of SGD with a mean seepage rate of 10 cm/day. The stable isotopic composition of submarine waters was characterized by significant variability and heavy isotope enrichment and was used to predict the contribution of fresh terrestrially derived groundwater to SGD (range from a few % to almost 100%). The integrated SGD flux, estimated from seepage meters placed parallel to the shoreline, was 35 m3/m day, which was in reasonable agreement with results obtained from a hydrologic water balance calculation (26 m3/m day). SGD calculated from the radon inventory method using in situ radon measurements were between 5 and 56 m3/m per day. Low concentrations of radium isotopes observed in the lagoon water reflected the low abundance of U and Th in the basalt that makes up the island. High SGD rates contribute to high nutrients loading to the lagoon, potentially leading to eutrophication. Each of the applied methods yielded unique information about the character and magnitude of SGD. The results of the intercomparison studies have resulted a better understanding of groundwater–seawater interactions in coastal regions. Such information is an important pre-requisite for the protection and management of coastal freshwater resources. Highlights ► Large fluctuations in SGD fluxes from 0 to 360 cm/day were observed. ► The integrated shoreline SGD fluxes were between 5 and 56 m3/m day. ► The groundwater contribution in SGD varied from a few % to almost 100%. ► The observed high SGD rates contributed to high nutrients loading to the lagoon.

Description: Several geochemical anomalies were observed before the Haichen, Longling, Tangshan, and Songpan earthquakes and their strong aftershocks. They included changes in groundwater radon levels; chemical composition of the groundwater (concentration of Ca++, Mg++, Cl−, SO4= and HCO3− ions); conductivity; and dissolved gases such as H2, CO2, etc. In addition, anomalous changes in water color and quality were observed before these large earthquakes. Before some events gases escaped from the surface, and there were reports of "ground odors" being smelled by local residents. The large amount of radon data can be grouped into long-term and short-term anomalies. The long-term anomalies have a radon emission build up time of from a few months to more than a year. The short-term anomalies have durations from a few hours or less to a few months.

Description: The boron isotope ratio (δ11B) of foraminifers and tropical corals has been proposed to record seawater pH. To test the veracity and practicality of this potential paleo-pH proxy in deep sea corals, samples of skeletal material from twelve archived modern Desmophyllum dianthus (D. dianthus) corals from a depth range of 274–1470 m in the Atlantic, Pacific, and Southern Oceans, ambient pH range 7.57–8.05, were analyzed for δ11B. The δ11B values for these corals, spanning a range from 23.56 to 27.88, are found to be related to seawater borate δ11B by the linear regression: δ11Bcoral=(0.76±0.28) δ11Bborate+(14.67±4.19) (1 standard error (SE)). The D. dianthus δ11B values are greater than those measured in tropical corals, and suggest substantial physiological modification of pH in the calcifying space by a value that is an inverse function of seawater pH. This mechanism partially compensates for the range of ocean pH and aragonite saturation at which this species grows, enhancing aragonite precipitation and suggesting an adaptation mechanism to low pH environments in intermediate and deep waters. Consistent with the findings of Trotter et al. (2011) for tropical surface corals, the data suggest an inverse correlation between the magnitude of a biologically driven pH offset recorded in the coral skeleton, and the seawater pH, described by the equation: ΔpH=pH recorded by coral−seawater pH=−(0.75±0.12) pHw+(6.88±0.93) (1 SE). Error analysis based on 95% confidence interval(CI) and the standard deviation of the regression residuals suggests that the uncertainty of seawater pH reconstructed from δ11Bcoral is ±0.07 to 0.12 pH units. This study demonstrates the applicability of δ11B in D. dianthus to record ambient seawater pH and holds promise for reconstructing oceanic pH distribution and history using fossil corals.

Description: Until reliable procedures have been developed to preserve the phosphorus contained in particulate matter captured by in situ pumps and sediment traps and until these procedures are applied over a wide range of locations and depths in the sea, indirect methods will have to be used to determine the C/P ratio in marine detritus. We have taken two such approaches: (1) the use of C/N ratios for particulates captured in the upper thermocline in conjunction with 02/P and N/P ratios obtained from deconvolutions of ocean chemical data and (2) regression along isopycnals in the deep‐sea waters free of fossil fuel CO2. While neither approach yields a definitive answer, both suggest that a value of 127 carbon atoms per phosphorus atom would be a more appropriate interim value than that of 106 adopted long ago by A. C. Redfield and his associates.

Description: Here we show the use of the 210Pb-226Ra excess method to determine the growth rate of two corals from the world's largest known cold-water coral reef, Røst Reef, north of the Arctic circle off Norway. Colonies of each of the two species that build the reef, Lophelia pertusa and Madrepora oculata, were collected alive at 350 m depth using a submersible. Pb and Ra isotopes were measured along the major growth axis of both specimens using low level alpha and gamma spectrometry and trace element compositions were studied. 210Pb and 226Ra differ in the way they are incorporated into coral skeletons. Hence, to assess growth rates, we considered the exponential decrease of initially incorporated 210Pb, as well as the increase in 210Pb from the decay of 226Ra and contamination with 210Pb associated with Mn-Fe coatings that we were unable to remove completely from the oldest parts of the skeletons. 226Ra activity was similar in both coral species, so, assuming constant uptake of 210Pb through time, we used the 210Pb-226Ra chronology to calculate growth rates. The 45.5 cm long branch of M. oculata was 31 yr with an average linear growth rate of 14.4 ± 1.1 mm yr−1 (2.6 polyps per year). Despite cleaning, a correction for Mn-Fe oxide contamination was required for the oldest part of the colony; this correction corroborated our radiocarbon date of 40 yr and a mean growth rate of 2 polyps yr−1. This rate is similar to the one obtained in aquarium experiments under optimal growth conditions.

Description: The purpose of this first synthesis is to summarize findings on the Yarlung Zangbo Suture Zone (YZSZ) ophiolites and discuss still remaining problems. The YZSZ studied for almost 30 years and is the youngest of the sutures recognized on Tibet Plateau. It is now acknowledged that the YZSZ is a complex assemblage of sedimentary, metamorphic and igneous rocks created during and shortly after the collision between India and Eurasia. The ages of the various lithologies span a time interval from the Jurassic to the Middle Miocene, with some Permian and Devonian exotic blocks from mélange zone. The YZSZ is characterized by ophiolitic complexes and ophiolitic mélange. The ophiolites are of two types: non dismembered and dismembered sections. The non disturbed sections, although tectonically reworked, are observed along the segment from Dazhuqu to Jiding in Xigaze area and Spontang ophiolite. The dismembered sequences are found in various locations such as Nidar, Kiogar, Jungbwa, Saga, Sangsang, Xigugabu, and Luobusa. The incomplete stratigraphic log could be connected to intraoceanic or orogenetic origins. The ophiolites are distributed into two groups of ages: the Luobusa, Zedang and Kiogar sequences being Jurassic-Lower Cretaceous whereas all other sequences are of Lower Cretaceous age. Compilation of geochronological data suggest that some ophiolite sequences might have evolved for over more than 70 My from their initial genesis to obduction which occurred around 70–90 My ago. Ophiolites differ in terms of petrological and geochemical aspects however, they were all generated in suprasubduction zone and more specifically in arc (few fore-arc) and back-arc settings. Synthesis of more than 700 geochemical analyses show variable mixing of components from N-MORB-type to IAT-CAB and to OIB end-members. The Jurassic ophiolites show the maximum of arc component while the Lower Cretaceous ones show little to strong mixing. In addition, most ophiolites were created in short lived (30 My) basins and generated close to the Eurasiatic continental margin. We propose that Ladakh–Tibet ophiolites were generated in a suprasubduction context similar to Mariana arc, interarc and back-arc or Tonga–Lau system. The variable arc signature of these ophiolites is directly related to their initial position within the suprasubduction system.

Description: Seismic techniques provide the highest-resolution measurements of the structure of the crust and have been conducted on a worldwide basis. We summarize the structure of the continental crust based on the results of seismic refraction profiles and infer crustal composition as a function of depth by comparing these results with high-pressure laboratory measurements of seismic velocity for a wide range of rocks that are commonly found in the crust. The thickness and velocity structure of the crust are well correlated with tectonic province, with extended crust showing an average thickness of 30.5 km and orogens an average of 46.3 km. Shields and platforms have an average crustal thickness nearly equal to the global average. We have corrected for the nonuniform geographical distribution of seismic refraction profiles by estimating the global area of each major crustal type. The weighted average crustal thickness based on these values is 41.1 km. This value is 10% to 20% greater than previous estimates which underrepresented shields, platforms, and orogens. The average compressional wave velocity of the crust is 6.45 km/s, and the average velocity of the uppermost mantle (Pn velocity) is 8.09 km/s. We summarize the velocity structure of the crust at 5-km depth intervals, both in the form of histograms and as an average velocity-depth curve, and compare these determinations with new measurements of compressional wave velocities and densities of over 3000 igneous and metamorphic rock cores made to confining pressures of 1 GPa. On the basis of petrographic studies and chemical analyses, the rocks have been classified into 29 groups. Average velocities, densities, and standard deviations are presented for each group at 5-km depth intervals to crustal depths of 50 km along three different geotherms. This allows us to develop a model for the composition of the continental crust. Velocities in the upper continental crust are matched by velocities of a large number of lithologies, including many low-grade metamorphic rocks and relatively silicic gneisses of amphibolite facies grade. In midcrustal regions, velocity gradients appear to originate from an increase in metamorphic grade, as well as a decrease in silica content. Tonalitic gneiss, granitic gneiss, and amphibolite are abundant midcrustal lithologies. Anisotropy due to preferred mineral orientation is likely to be significant in upper and midcrustal regions. The bulk of the lower continental crust is chemically equivalent to gabbro, with velocities in agreement with laboratory measurements of mafic granulite. Garnet becomes increasingly abundant with depth, and mafic garnet granulite is the dominant rock type immediately above the Mohorovicic discontinuity. Average compressional wave velocities of common crustal rock types show excellent correlations with density. The mean crustal density calculated from our model is 2830 kg/m3, and the average SiO2 content is 61.8%.

Description: We present a conceptual model of fluid circulation in a ridge flank hydrothermal system, the Mariana Mounds. The model is based on chemical data from pore waters extracted from piston cores and from push cores collected by deep-sea research vessel Alvin in small, meter-sized mounds situated on a local topographic high. These mounds are located within a region of heat flow exceeding that calculated from a conductive model and are zones of strong pore water upflow. We have interpreted the chemical data with time-dependent transport-reaction models to estimate pore water velocities. In the mounds themselves pore water velocities reach several meters per year to kilometers per year. Within about 100 m from these zones of focused upflow velocities decrease to several centimeters per year up to tens of centimeters per year. A larger area of low heat flow surrounds these heat flow and topographic highs, with upwelling pore water velocities less than 2 cm/yr. In some nearby cores, downwelling of bottom seawater is evident but at speeds less than 2 cm/yr. Downwelling through the sediments appears to be a minor source of seawater recharge to the basaltic basement. We conclude that the principal source of seawater recharge to basement is where basement outcrops exist, most likely a scarp about 2–4 km to the east and southeast of the study area.

Description: Aftershocks of shallow earthquakes larger than magnitude 7 in the Aleutians, southern Alaska, southeast Alaska, and offshore British Columbia from 1920 to 1970 were relocated by computer in an attempt to delineate the rupture zones of large earthquakes. Plate tectonic theory indicates that gaps in activity for large earthquakes for the past 10's to 100's of years are likely sites of future large earthquakes. Three prominent gaps of this type are delineated: one in southeast Alaska; another in southern Alaska near the epicenters of the great earthquakes of 1899 and 1900; and one in the far western Aleutians. These gaps deserve high priority for study and instrumentation. Large earthquakes appear to be much more regular than smaller shocks in their distributions with respect to space, time, and size. Aftershock zones of events since 1930 that are larger than magnitude 7.8 are longer than 250 km and those less than 7.5 are shorter than 125 km. The rupture zones of events that occurred before 1930 could not be delineated from aftershock locations. Aftershock zones of large earthquakes tend to abut without significant overlap even for rupture zones as long as 1200 km. Nearly the entire Alaska-Aleutian zone from 145°W to 171°E has broken since 1938 in a series of large earthquakes. The rupture zones of five large events appear to form a space-time sequence that progressed from 155°W in 1938 to 171°E in 1965. This sequence is much like the well-known westward progression of activity since 1939 along the North Anatolian fault. Shocks with long rupture zones tend to occur along those parts of the Alaska-Aleutian zone that are relatively simple tectonically. The ends of many aftershock zones of large earthquakes are located at the intersection of major transverse features with the Aleutian arc. Large earthquakes rarely, if ever, reoccur along the same part of a fault zone in less than several tens of years, i.e. within a time less than that for substantial strain accumulation. Events of comparable magnitude that occur soon after some great earthquakes usually involve rupture in a region adjacent to but different from that of the main shock. The March 30, 1965, earthquake of magnitude 7.5, which involved normal faulting in the Aleutian trench, appears to have been triggered by thrust faulting along the adjacent inner margin of the trench in the magnitude 7.9 earthquake of February 4, 1965. Large events of the thrust type are commonly followed within ten years by events involving normal faulting in the adjacent part of the trench. Estimates of average displacements and of the repeat times of great earthquakes from measurements of 20-sec surface waves are systematically too small and do not agree with the meager historic record of great shocks. Other estimates of repeat times vary from 30 to 850 years, but neither of these extremes appears to be typical. The aftershock zone of the April 1, 1946, Aleutian earthquake, which generated one of the largest and most widespread seismic sea waves in the Pacific during this century, was very small. A large displacement of the ocean floor may be responsible for the generation of the large sea wave. An average displacement of 2.4 to 4.1 meters was calculated from amplitudes of 100-sec waves.

Description: We measured the respiratory isotope effect ϵresp for seven representative unicellular marine organisms. The bacterium Pseudomonas halodurans, the diatom Phaeodactylum tricornutum, the phytoflagellates Cryptomonas baltica and Dunaliella tertiolecta, the heterotrophic flagellates Paraphysomonas imperforata and Bodo sp., and the ciliate Uronema sp. exhibit ϵresp values in the range 14-26‰. We also measured ϵresp for three metazoans. The ϵresp for the copepod Acartia tonsa ranged from 17 to 25‰, while two larger organisms, the mollusk Mercenaria mercenaria and the salmon Salmo salmar, respire with a smaller ϵresp of 5-10‰. The average respiratory isotope effect of the dominant marine respirers (the bacteria, microalgae and zooplankton) is about 20 ± 3‰. An ϵresp of this magnitude supports the hypothesis that the photosynthesis-respiration cycle is responsible for the 23.5‰ enrichment in the δ18O ratio of atmospheric O2 relative to seawater (the Dole effect). The large value and high variability in the average ϵresp limits the usefulness of a proposed method using the δ18O of naturally fractionated dissolved O2 in seawater as a tracer of primary production in the oligotrophic ocean.

Description: We review the current understanding of the Dole effect (the observed difference between the δ18O of atmospheric O2 and that of seawater) and its causes, extend the record of variations in the Dole effect back to 130 kyr before present using data on the δ18O of O2 obtained from studying the Vostok ice core (Sowers et al., 1993), and discuss the significance of temporal variations. The Dole effect reflects oxygen isotope fractionation during photosynthesis, respiration, and hydrologic processes (evaporation, precipitation, and evapotranspiration). Our best prediction of the present-day Dole effect, +20.8‰, is considerably lower than the observed value, +23.5‰, and we discuss possible causes of this discrepancy. During the past 130 kyr, the Dole effect has been 0.05‰ lower than the present value, on average. The standard deviation of the Dole effect from the mean has been only ±0.2‰, and the Dole effect is nearly unchanged between glacial maxima and interglacial periods. The small variability in the Dole effect suggests that relative rates of primary production in the land and marine realms have been relatively constant. Most periodic variability in the Dole effect is in the precession band, suggesting that changes in this global biogeochemical term reflects variations in low-latitude land hydrology and productivity or possibly variability in low-latitude oceanic productivity.

Description: Pore water has been analyzed from sediment cores taken from three areas on the eastern flank of the Juan de Fuca Ridge as part of FlankFlux 90, a study of hydrothermal circulation through mid-ocean ridge flanks. Seismic reflection and heat flow surveys (Davis et al., 1992a) indicate that the three areas differ in sediment thickness, basement topography, abundance of outcrops, basement temperature, and fraction of heat lost by advection versus conduction. Area 1 is on 0.6 Ma crust with nearly continuous basement outcrop, area 2 is on 1.3 Ma crust over the first buried ridge parallel to the present ridge axis, and area 3 is on 3.5–3.8 Ma crust over two axis-parallel buried ridges that penetrate the sediment cover in three locations. Each area includes a hydrothermal system in which seawater flows into basement, reacts with crustal basalt, and then exits basement either through the sediment or directly into the overlying water column. As constrained by concentrations of sulfate and lithium in the pore waters, at least some seawater enters basement in all three areas without reacting fully with the overlying sediment, even where no outcrops are known nearby. Speeds of up welling of pore water through the sediment have been estimated by fitting profiles of dissolved magnesium and chlorinity, which behave conservatively in these areas, to numerical time-dependent transport models. The estimated velocities range from 〈0.1 to 7.4 cm/yr; faster flows probably occur but were not sampled. Upwelling speed correlates positively with heat flow and basement highs and negatively with sediment thickness. The correlation with heat flow differs from area 2 to area 3 along with differences in physical properties of the turbidite sediment. We have documented pore water upwelling through sediment up to 100 m thick. We estimate that upwelling continues at decreasing speeds through sediment up to 160 m thick, corresponding to a heat flow of 0.44 W/m2 in area 2 and 0.3 W/m2 in area 3. Concentrations of magnesium and chlorinity in the altered seawater upwelling from basement are uniform within each area but differ from one area to the next. Both species remain at the bottom seawater concentration in area 1, where basement is cooled to 〈10°C at the base of the sediments mainly by advection. The concentration of magnesium decreases with increasing basement temperature in areas 2 and 3 to a minimum of 2.5 mmol/kg at about 90°C in area 3. The transition from largely advective to largely conductive heat loss occurs over only 20 km between areas 1 and 2 and corresponds to a dramatic change in the composition of fluid circulating through basement, as the uppermost basement is heated from 〈10° to 40–50°C. Chlorinity of the basement fluid increases above the present-day bottom seawater concentration in areas 2 and 3 and in nearly all other mid-ocean ridge flanks studied to date, as a result of rock hydration and the higher chlorinity of bottom seawater during the last glacial period. While chlorinity generally correlates positively with uppermost basement temperature in various ridge flank hydrothermal systems, it reaches a maximum in area 2 at only 40°C, probably because alteration there occurs at a lower water/rock ratio than elsewhere. For all mid-ocean ridge flanks studied to date, the temperature at the basement interface correlates better with the fraction of heat lost by advection versus conduction and with the average thickness of the sediment cover than with crustal age.

Description: An examination of 311 intraplate earthquakes in the Australian plate portion of the Pacific Ocean basin reported from 1918 to 1990 reveals that only 113 events are reliably intraplate, with most of the rest relocating to active trenches and transforms. The non-random distribution of the reliably intraplate events gives insight into the tectonic stresses present. The central Tasman Sea is mostly aseismic except for a swarm of activity at the predicted site of the Tasmantid hot spot. To the north, the broad regions of the Coral Sea, South Fiji Basin and Lord Howe Rise show very little intraplate seismicity, yet the narrow Norfolk Ridge and Three Kings Rise, caught between the double convergence of the New Hebrides and Tonga subduction zones, support many more earthquakes. High levels of intraplate seismicity in the southern Tasman Sea adjacent to the Macquarie Ridge Complex (MRC) indicate that this region may be undergoing internal deformation due to the unusual nature of the Australia-Pacific plate boundary. Additional support exists in the form of intraplate focal mechanisms similar to those at the plate boundary and a set of parallel gravity rolls which are observed in recent geoid maps. Some aftershocks of the Mw = 8.2 Macquarie Ridge earthquake of 1989 occurred in a fracture zone west of the Macquarie Ridge Complex [Das, 1992], but we have found several earthquakes from as early as 1924 which relocate to this feature, suggesting that its reactivation may be more significant than previously thought. This reactivation of a fossil fracture zone may be the result of the increasing amount of oblique convergence between the Australia and Pacific plates at the Macquarie Ridge Complex, formerly a spreading center, and the stresses associated with subducting recently formed Australian ocean crust beneath the older Pacific plate.

Description: The European sprat (Sprattus sprattus) was a main target species of the German GLOBEC program that investigated the trophodynamic structure and function of the Baltic and North Seas under the influence of physical forcing. This review summarizes literature on the ecophysiology of sprat with an emphasis on describing how environmental factors influence the life-history strategy of this small pelagic fish. Ontogenetic changes in feeding and growth, and the impacts of abiotic and biotic factors on vital rates are discussed with particular emphasis on the role of temperature as a constraint to life-history scheduling of this species in the Baltic Sea. A combination of field and laboratory data suggests that optimal thermal windows for growth and survival change during early life and are wider for eggs (5–17 °C) than in young (8- to 12-mm) early feeding larvae (5–12 °C). As larvae become able to successfully capture larger prey, thermal windows expand to include warmer waters. For example, 12- to 16-mm larvae can grow well at 16 °C and larger, transitional-larvae and early juveniles display the highest rates of feeding and growth at ∼18–22 °C. Gaps in knowledge are identified including the need for additional laboratory studies on the physiology and behavior of larvae (studies that will be particularly critical for biophysical modeling activities) and research addressing the role of overwinter survival as a factor shaping phenology and setting limits on the productivity of this species in areas located at the northern limits of its latitudinal range (such as the Baltic Sea). Based on stage- and temperature-specific mortality and growth potential of early life stages, our analysis suggests that young-of-the year sprat would benefit from inhabiting warmer, near-shore environments rather than the deeper-water spawning grounds such as the Bornholm Basin (central Baltic Sea). Utilization of warmer, nearshore waters (or a general increase in Baltic Sea temperatures) is expected to accelerate growth rates but also enhance the possibility for density-dependent regulation of recruitment (e.g., top-down control of zooplankton resources) acting during the late-larval and juvenile stages, particularly when sprat stocks are at high levels. Highlights ► Field, laboratory and modeling research on the ecophysiology of all sprat life stages is summarized. ► Environmental factors influencing growth and survival are revealed. ► Ontogenetic changes in thermal tolerance and prey requirements constrain life cycle scheduling. ► Gaps in knowledge are identified and future research efforts recommended on sprat recruitment dynamics. ► Exploring seasonal energy allocation will allow a mechanistic understanding of climate impacts.

Description: Throughout the last decades there has been a world-wide, general warming trend. In this study, we use the example of the Baltic Sea to resolve the overall estimated temperature trend into smaller, meso-scale spatial units. Afterwards, we investigate the spatially resolved potential impact of the temperature trend on larval survival for two important fish species, cod and sprat. We used two different sets of hydrographic data: (i) long-term temporally and depth-resolved data measured in situ originating from one geographic position and (ii) long-term horizontally resolved data, originating from a circulation model. In contrast to basin-wide integrated results, our modelling approach revealed different results related to smaller spatial scales. In shallow and coastal areas non-significant long-term temperature trends were observed. In some cases even decreasing temperature trends were found. Average distribution maps (1973–2010) of cod and sprat eggs and larvae confirmed the higher importance of central, deep basins as nursery grounds. Applying the temperature trends when calculating cod larval window of opportunity values, resulted in decreased durations of 1–3 days (~ 3–13%) in most areas. Sprat larval window of opportunity values mainly increased up to 4 days (~ 45%), indicating a potential reproduction advantage of sprat over cod under anticipated future temperature increase. Highlights ► We resolve the overall positive temperature trend in the Baltic into meso-scale spatial units and investigate the impact on larval survival for two important fish species, cod and sprat. ► In shallow and coastal areas non-significant or even negative temperature trends occurred. ► Cod larval window of opportunity values decreased by 1–3 days (~ 3–13%). ► Sprat larval window of opportunity values increased up to 4 days (~ 45%). ► Sprat will have a reproduction advantage over cod under anticipated future temperature change.

Description: Basin modeling and cross-section restoration from the northern East China Sea Shelf Basin reveal the timing of trap formation and petroleum generation. Cross-section restoration suggest that extension started in the Late Cretaceous and was interrupted by inversion at the end of Miocene that created large anticline structures, providing numerous petroleum traps. One-dimensional basin modeling of the JDZ-VII-I well show that the main phase of oil generation in the synrift fluvial shales in the Jeju Basin occurred during the Early Oligocene–middle Miocene period, predating the regional inversion. Thus, potential for large oil accumulations in the southern part of the basin is probably limited. Most of the petroleum are likely to have flowed toward the basin margin as well as basin center until the Late Miocene because no structures were available to capture them. The formation of anticline structures overlapped and/or postdated the main phase of gas generation in the Jeju Basin. This is probably why the JDZ-VII-1 is gas-prone with the gas trapped mainly in the anticlinal structures formed by the tectonic uplift. The source rocks in the southwestern part of the Domi Basin are immature for petroleum generation.

Description: Water transported by slabs into the mantle at subduction zones plays key roles in tectonics, magmatism, fluid and volatiles fluxes, and most likely in the chemical evolution of the Earth's oceans and mantle. Yet, incorporation of water into oceanic plates before subduction is a poorly understood process. Several studies suggest that plates may acquire most water at subduction trenches because the ocean crust and uppermost mantle there are intensely faulted caused by bending and/or slab pull, and display anomalously low seismic velocities. The low velocities are interpreted to arise from a combination of fluid-filled fractures associated to normal faulting and mineral transformation by hydration. Mantle hydration by transformation of nominally dry peridotite to water-rich serpentinite could potentially create the largest fluid reservoir in slabs and is therefore the most relevant for the transport of water in the deep mantle. The depth of fracturing by normal-fault earthquakes is usually not well constrained, but could potentially create deep percolation paths for water that might hydrate up to tens of kilometers into the mantle, restrained only by serpentine stability. Yet, interpretation of deep intraplate mineral alteration remains speculative because active-source seismic experiments have sampled only the uppermost few kilometers of mantle, leaving the depth-extent of anomalous velocities and their relation to faulting unconstrained. Here we use a joint inversion of active-source seismic data, and both local and regional earthquakes to map the three dimensional distribution of anomalous velocities under a seismic network deployed at the trench seafloor. We found that anomalous velocities are restrained to the depth of normal-fault micro-earthquake activity recorded in the network, and are considerably shallower than either the rupture depth of teleseismic, normal-fault earthquakes, or the limit of serpentine stability. Extensional micro-earthquakes indicate that each fault in the region slips every 2–3 months which may facilitate regular water percolation. Deeper, teleseismic earthquakes are comparatively infrequent, and possibly do not cause significant fracturing that remains open long enough to promote alteration detectable with our seismic study. Our results show that the stability field of serpentine does not constrain the depth of potential mantle hydration.

Description: The objective of the present study was to determine the action of beta-glucans as feed additives on the gene expression profile of some inflammatory-related cytokines from common carp (Cyprinus carpio L) during the early stages of a non-lethal bacterial infection with Aeromonas salmonicida. beta-glucan (MacroGard (R)), was administered daily to carp (6 mg per kg body weight) in the form of supplemented commercial food pellets for 14 days prior to infection. Control and treated fish were then intraperitoneally injected with PBS or 4 x 10(8) bacteria per fish and were sampled at time 0 and 6 h, 12 h, I day, 3 days and 5 days post-injection. Head kidney and gut were collected and the gene expression patterns for tnf alpha 1, tnf alpha 2, il1 beta, il6 and il10 were analyzed by quantitative PCR. Results obtained showed that treatment with beta-glucans generally down-regulated the expression of all measured genes when compared to their corresponding controls. After injection, highest changes in the gene expression levels were obtained at 6 h: particularly, in head kidney there was higher up-regulation of tnfa1 and tnfa2 in infected fish fed beta-glucans in comparison to control feed: however, in gut there was a significant down-regulation of tnf alpha 1, tnf alpha 2, il1 beta and il6 in infected fish fed beta-glucans. Analysis of carp specific antibodies against A. salmonicida 30 days after injection revealed their levels were reduced in the infected beta-glucan group. In conclusion, a diet supplemented with beta-glucan (MacroGard (R)) reduced the gene expression levels of some inflammation-related cytokines in common carp. Such a response appears to be dependent of organ studied and therefore the immunostimulant may be preventing an acute and potential dangerous response in gut, whilst enhancing the inflammatory response in head kidney when exposed to A. salmonicida

Description: The evolution of ridge-hotspot systems is not well understood. In this investigation, satellite-derived marine gravity data are used in conjunction with underway bathymetric and magnetic anomaly profiles to investigate the nature of ridge-hotspot interaction at four sparsely explored systems in the Southern Ocean. These systems illustrate three different stages of ridge-hotspot interaction in which a migrating spreading center approaches a hotspot (Pacific-Antarctic/Louisville), passes over or is captured by the hotspot (Mid-Atlantic/Shona-Discovery), and ultimately migrates away from the hotspot (Southeast Indian/Kerguelen). All of these systems show some evidence of discrete ridge jumps in the direction of the hotspot as the spreading center attempts to relocate toward the hotspot by asymmetric spreading. Interestingly, these ridge jumps show no evidence of propagating offsets as have been seen on many other ridge-hotspot systems. A simple model predicts that typical plume excess temperatures can weaken the lithosphere sufficiently to promote asymmetric spreading and possibly allow a discrete ridge jump. The presence of previously uncharted, obliquely oriented aseismic ridges and gravity lineations between the ridge and the hotspot supports the notion of asthenospheric flux from the plume to the spreading center both before and after the time when the hotspot is ridge centered. The azimuths of the aseismic ridges cannot be explained by plate kinematics alone; they consistently extend from the ends toward the centers of the adjacent spreading segments suggesting some interaction between plume derived asthenospheric flux and local lithospheric structure. The features discussed here also indicate that the transfer of asthenospheric material from the plume to the spreading center is influenced by the local plate boundary configuration and interaction with transform offsets.

Description: Tectonic pseudotachylytes, i.e. quenched friction-induced silicate melts, record coseismic slip along faults and are mainly reported from the brittle crust in association with cataclasites. In this study, we document the occurrence of recrystallization of quartz to ultrafine-grained (grain size 1–2 μm) aggregates along microshear zones (50–150 μm thick) in the host rock adjacent to pseudotachylytes from two different faults within quartzite (Schneeberg Normal Fault Zone, Eastern Alps), and tonalite (Adamello fault, Southern Alps) in the brittle crust. The transition from the host quartz to microshear zone interior includes: (i) formation of high dislocation densities; (ii) fine (0.3–0.5 μm) polygonization to subgrains defined by disordered to well-ordered dislocation walls; (iii) development of a mosaic aggregate of dislocation-free new grains. The crystallographic preferred orientation (CPO) of quartz towards the microshear zone shows a progressive misorientation from the host grain, by subgrain rotation recrystallization, to a nearly random CPO possibly related to grain boundary sliding. These ultrafine aggregates appear to be typically associated with pseudotachylytes in nature. We refer the crystal plastic deformation of quartz accompanied by dramatic grain size refinement to the coseismic stages of fault slip due to high differential stress and temperature transients induced by frictional heating. Microshear zones localized on precursory fractures developed during the stages of earthquake rupture propagation and the very initial stages of fault slip. Thermal models indicate that the process of recrystallization, including recovery processes, occurred in a time lapse of a few tens of seconds.

Description: The combination of the Sunda megathrust and the (strike-slip) Sumatran Fault (SF) represents a type example of slip-partitioning. However, superimposed on the SF are geometrical irregularities that disrupt the local strain field. The largest such feature is in central Sumatra where the SF splits into two fault strands up to 35 km apart. A dense local network was installed along a 350 km section around this bifurcation, registering 1016 crustal events between April 2008 and February 2009. 528 of these events, with magnitudes between 1.1 and 6.0, were located using the double-difference relative location method. These relative hypocentre locations reveal several new features about the crustal structure of the SF. Northwest and southeast of the bifurcation, where the SF has only one fault strand, seismicity is strongly focused below the surface trace, indicating a vertical fault that is seismogenic to ∼15 km depth. By contrast intense seismicity is observed within the bifurcation, displaying streaks in plan and cross-section that indicate a complex system of faults bisecting the bifurcation. In combination with analysis of topography and focal mechanisms, we propose that the bifurcation is a strike-slip duplex system with complex faulting between the two main fault branches.

Description: In this study we first evaluate the small-scale spatial variability of particulate export, using a set of synoptic thorium-234 activity observations sampled within a one-degree radius. These data show significant variability of surface thorium activity on scales of the order of 100 km (∼270–550 dpm m−3). This patchiness of export potentially affects the robustness of point observations and our interpretation of them. Motivated by these observations we subsequently couple an explicit model of thorium-234 dynamics to a coupled physical–biogeochemical basin model capable of resolving these small-scales. The model supports the observations in displaying marked thorium variability on spatial scales of the order of 100 km and smaller, with highest values in the regions of large eddy kinetic energy and large primary productivity. The model is also used to quantify the impact of small-scale variability on export estimates. Our model shows that the primary source of error associated with the presence of small-scale spatial variability is related to the standard assumptions of steady state and non-steady state (〉40% during bloom condition). The non-steady state method can misinterpret variations due to patchiness in thorium activity as temporal changes and lead to errors larger than those introduced by the simpler steady state approach. We show that the non-steady state approach could improve the flux estimates in some cases if the sampling was conducted in a Lagrangian framework. Undersampling the spatial variability results in further bias (〉20%) that can be reduced when the sampling density is increased. Finally, errors due to the dynamical transport of thorium associated with small-scale structures are relatively low (〈20%) except in regions of high eddy kinetic energy.

Description: The role of biominerals in driving carbon export from the surface ocean is unclear. We compiled surface particulate organic carbon (POC), and mineral ballast export fluxes from 55 different locations in the Atlantic and Southern Oceans. Substantial surface POC export accompanied by negligible mineral export was recorded implying that association with mineral phases is not a precondition for organic export to occur. The proportion of non-mineral associated sinking POC ranged from 0 to 80% and was highest in areas previously shown to be dominated by diatoms. This is consistent with previous estimates showing that transfer efficiency in such regions is low. However we propose that, rather than the low transfer efficiency arising from diatom blooms being inherently characterized by poorly packaged aggregates which are efficiently exported but which disintegrate readily in mid water, it is due to such environments having very high levels of unballasted organic C export.

Description: A numerical algorithm based on Fermat's Principle was developed to simulate the propagation of Global Positioning System (GPS) radio signals in the refractivity field of a numerical weather model. The unique in the proposed algorithm is that the ray-trajectory automatically involves the location of the ground-based receiver and the satellite, i.e. the posed two-point boundary value problem is solved by an implicit finite difference scheme. This feature of the algorithm allows the fast and accurate computation of the signal travel-time delay, referred to as Slant Total Delay (STD), between a satellite and a ground-based receiver. We provide a technical description of the algorithm and estimate the uncertainty of STDs due to simplifying assumptions in the algorithm and due to the uncertainty of the refractivity field. In a first application, we compare STDs retrieved from GPS phase-observations at the German Research Centre for Geosciences Potsdam (GFZ STDs) with STDs derived from the European Center for Medium-Range Weather Forecasts analyses (ECMWF STDs). The statistical comparison for one month (August 2007) for a large and continuously operating network of ground-based receivers in Germany indicates good agreement between GFZ STDs and ECMWF STDs; the standard deviation is 0.5% and the mean deviation is 0.1%.

Description: Eclogites from the Tian Shan high-pressure/low-temperature (HP/LT) metamorphic belt show evidence for successively increasing metasomatic alteration with increasing retrograde, blueschist-facies overprint. To constrain the source(s) of the metasomatizing fluid and to evaluate elemental and isotopic changes during this overprint, two sequences of eclogite-blueschist transitions were investigated: A layered transition from eclogite to blueschist (FTS 9–1 sequence) and blueschist-facies overprinted pillow metabasalts (FTS 4 samples). Geochemical trends based on the relationships of K, Ba, Rb and Th are consistent with HP metasomatism, but distinct from typical seafloor alteration trends. In contrast, oxygen isotope ratios in garnet (δ18OV-SMOW = 7.3–8.7‰) and omphacite (δ18OV-SMOW = 8.2–9.7‰) are similar to δ18OV-SMOW in bulk low-temperature altered oceanic crust (AOC), suggesting O isotopic preservation of a seafloor alteration signature. Carbonate crystallization related to the metasomatic overprint demonstrate CO2 mobility during subduction and potential C storage in HP metamorphic rocks. Carbon isotope ratios in the two sequences differ markedly: Disseminated calcite in the layered FTS 9–1 sequence has δ13CV-PDB = − 9.14 ± 0.19‰, whereas vein-forming ankerite in the pillow metabasalts has δ13CV-PDB = − 2.08 ± 0.12‰. The ankerite reflects an inorganic marine/hydrothermal signature, as observed in ophiolites, whereas the low δ13CV-PDB values from the calcite point to a contribution of organic carbon. The time when the metasomatic overprint occurred is estimated to be ~ 320 ± 11 Ma based on a Rb-Sr isochron age of six blueschist samples from the pillow metabasalts, which is in agreement with active subduction in this region. Initial (T = 320 Ma) 87Sr/86Sr ratios for all HP/LT rocks range from 0.7059 – 0.7085, and εNd320Ma varies from − 0.4 to + 10.9. Both eclogite-blueschist sequences have initial Sr isotope compositions (87Sr/86Sr ~ 0.707) that are significantly higher than those of typical oceanic mantle-derived basalts. They are thought to derive from a fluid that preserved the Sr isotopic signature of seawater by fluid-rock interaction with seawater-altered oceanic lithosphere in a subduction channel. Mixing models between eclogite and various fluids suggest that the contribution of a sediment-derived fluid was likely less than 20%. A fluid predominantly derived from seawater-altered oceanic lithosphere is also supported by the calculated O isotope composition of the fluids (10.2 – 11.2‰). It is thus evident that subduction channel fluids carry complex, mixed elemental and isotopic signatures, which reflect the composition of their source rocks modified by interaction with various other lithologies. Highlights ► Eclogites from the Tian Shan show blueschist-facies metasomatic overprint ► Fluid-induced metasomatism occurred at 320 ± 11 Ma ► Fluid predominantly derived from seawater-altered oceanic lithosphere ► Carbonates reflect C sequestration of mixture of organic and inorganic components

Description: The Southern Hemisphere winter stratosphere exhibits prominent traveling planetary-scale Rossby waves, which generally are not able to induce Stratospheric Sudden Warmings. A series of runs of a simplified general circulation model is presented, aimed at better understanding the generation of these waves. While the generation of planetary-scale traveling waves through the interaction of synoptic-scale waves is observed in a control run, when the model is truncated to permit only waves with zonal wave number 1 or 2, the long waves are found to increase in strength, leading to a considerably more active stratosphere including Sudden Warmings comparable in strength to Northern Hemisphere winter. This finding suggests that the role of tropospheric synoptic eddies is two-fold: while generating a weak planetary-scale wave flux into the stratosphere, their main effect is to suppress baroclinic instability of planetary-scale waves by stabilizing the tropospheric mean state.

Description: Cyanobacteria blooms in the Baltic Sea appear after upwelling events, which transport phosphate-rich intermediate water to the surface. The growth potential of diazotrophic cyanobacteria in upwelled water was studied in a mesocosm (tank) experiment in summer 2007. An Anabaena bloom was only induced in the tanks filled with upwelled surface water but not in those filled with surface water from outside the upwelling cell and with intermediate water. The low initial cyanobacteria biomass in the intermediate water could not grow to bloom concentrations within three weeks. It is concluded that mixing of upwelled water with surrounding surface water forms a precondition for a cyanobacteria bloom. An additional mesocosm experiment conducted in 2009 revealed that mixing of intermediate water with surface water had the same stimulating effect on nitrogen fixation and cyanobacteria growth as artificial phosphate input. Phosphate input stimulates the growth of Nodularia and Anabaena more than that of Aphanizomenon. We suggest that the upwelled phosphate-rich intermediate water has to be mixed with the surface water containing physiologically “young” cyanobacteria biomass of at least 20 mg/m3 as an inoculum in order to initiate a cyanobacteria bloom.

Description: In the Baltic Sea, excess phosphorus after the spring bloom or phosphorus input from deeper layers e.g. by upwelling are nutrient sources for the development of filamentous cyanobacteria. The objective of this study was to investigate the ability of filamentous cyanobacteria to accumulate phosphate in depths within or below the thermocline under stratified conditions in the water column. Inorganic nutrient concentrations, as well as phytoplankton composition, chlorophyll a, POC, PON and POP and the ratios between them of water samples and of isolated filamentous cyanobacteria were estimated in five horizons of the upper 30 m surface layer together with phosphorus uptake and nitrogen fixation. During the investigation period, the water column was stratified with a surface temperature of 16 °C–18 °C in the eastern Gotland Basin. Cyanobacteria surface blooms occurred and constituted between 28 and 68% of the total phytoplankton biomass in the upper 5 m surface layer. Deduced from POC:POP ratios of 264–977, cyanobacteria were phosphorus depleted here. The POC:POP ratios became lower with increasing depth. In depths below 15 m, the cyanobacteria indicated phosphorus enrichment by POC:POP ratio declining down to 75 due to a forced gross uptake of 0.62 nmol P μg−1 Chla h−1compared to an uptake rate of 0.13 nmol P μg−1 Chla h−1 measured in the surface layer. Thus, filamentous cyanobacteria can acquire phosphate in deeper layers which enables further growth when they reach the surface. However, they occurred in low abundances there. In 30 m depth, cyanobacteria accounted for only 0.3–10% of their biomass in the surface layer. This contribution to bloom formation may therefore be of minor importance compared to other sources.

Description: High-resolution sedimentary records of major and minor elements (Al, Ba, Ca, Sr, Ti), total organic carbon (TOC), and profiles of pore water constituents (View the MathML sourceSO42-, CH4, Ca2+, Ba2+, Mg2+, alkalinity) were obtained for two gravity cores (core 755, 501 m water depth and core 214, 1686 m water depth) from the northwestern Black Sea. The records were examined in order to gain insight into the cycling of Ba in anoxic marine sediments characterized by a shallow sulfate–methane transition (SMT) as well as the applicability of barite as a primary productivity proxy in such a setting. The Ba records are strongly overprinted by diagenetic barite (BaSO4) precipitation and remobilization; authigenic Ba enrichments were found at both sites at and slightly above the current SMT. Transport reaction modeling was applied to simulate the migration of the SMT during the changing geochemical conditions after the Holocene seawater intrusion into the Black Sea. Based on this, sediment intervals affected by diagenetic Ba redistribution were identified. Results reveal that the intense overprint of Ba and Baxs (Ba excess above detrital average) strongly limits its correlation to primary productivity. These findings have implications for other modern and ancient anoxic basins, such as sections covering the Oceanic Anoxic Events which Ba is frequently used as a primary productivity indicator. Our study also demonstrates the limitations concerning the use of Baxs as a tracer for downward migrations of the SMT: due to high sedimentation rates at the investigated sites, diagenetic barite fronts are buried below the SMT within a relatively short period. Thus, ‘relict’ barite fronts would only be preserved for a few thousands of years, if at all.

Description: Seismic coherency measures, such as similarity and dip of maximum similarity, were used to characterize mass transport deposits (MTDs) in the Ulleung Basin, East Sea, offshore Korea. Using 2-D and 3-D seismic data several slope failure masses have been identified near drill site UBGH1-4. The MTDs have a distinct seismic character and exhibit physical properties similar to gas hydrate bearing sediment: elevated electrical resistivity and P-wave velocity. Sediments recovered from within the MTDs show a reworked nature with chaotic assemblage of mud-clasts. Additionally, the reflection at the base of MTDs is polarity reversed relative to the seafloor, similarly to the bottom-simulating reflector commonly used to infer the presence of gas hydrates. The MTDs further show regional seismic blanking (absence of internal reflectivity), which is yet another signature often attributed to gas hydrate bearing sediments. At the drill site UBGH1-4, no gas hydrate was recovered in sediment-cores from inside a prominent MTD unit. Instead, pore-filling gas hydrate was recovered only within thin turbidite sand layers near the base of the gas hydrate stability zone. With the analysis of seismic attributes, the seismic character of the prominent MTD (Unit 3) was investigated. The base of the MTD unit exhibits deep grooves interpreted as gliding tracks from either outrunner blocks or large clasts that were dragged along the paleo-seafloor. Similar seismic features were identified on the seafloor although the length of the gliding tracks on the seafloor is much shorter (a few hundred meters to ∼1 km), compared to over 10 km long tracks at the base of the MTD. The seismic coherency attributes allowed to estimate the volume of the failed sediment as well as the direction of the flow of sediment. Tracking the MTD and extrapolating its spatial extent from the 3-D seismic volume to adjacent 2-D seismic profiles, a possible source region of this mass failure was defined ∼50 km upslope of Site UBGH1-4.

Description: Analytical challenges in obtaining high quality measurements of rare earth elements (REEs) from small pore fluid volumes have limited the application of REEs as deep fluid geochemical tracers. Using a recently developed analytical technique, we analyzed REEs from pore fluids collected from Sites U1325 and U1329, drilled on the northern Cascadia margin during the Integrated Ocean Drilling Program (IODP) Expedition 311, to investigate the REE behavior during diagenesis and their utility as tracers of deep fluid migration. These sites were selected because they represent contrasting settings on an accretionary margin: a ponded basin at the toe of the margin, and the landward Tofino Basin near the shelf's edge. REE concentrations of pore fluid in the methanogenic zone at Sites U1325 and U1329 correlate positively with concentrations of dissolved organic carbon (DOC) and alkalinity. Fractionations across the REE series are driven by preferential complexation of the heavy REEs. Simultaneous enrichment of diagenetic indicators (DOC and alkalinity) and of REEs (in particular the heavy elements Ho to Lu), suggests that the heavy REEs are released during particulate organic carbon (POC) degradation and are subsequently chelated by DOC. REE concentrations are greater at Site U1325, a site where shorter residence times of POC in sulfate-bearing redox zones may enhance REE burial efficiency within sulfidic and methanogenic sediment zones where REE release ensues. Cross-plots of La concentrations versus Cl, Li and Sr delineate a distinct field for the deep fluids (z 〉 75 mbsf) at Site U1329, and indicate the presence of a fluid not observed at the other sites drilled on the Cascadia margin. Changes in REE patterns, the presence of a positive Eu anomaly, and other available geochemical data for this site suggest a complex hydrology and possible interaction with the igneous Crescent Terrane, located east of the drilled transect.

Description: In western Canada gas hydrates have been thought to exist primarily in the Cascadia accretionary prism off southern Vancouver Island, British Columbia (BC). We present evidence for the existence of gas hydrate in folds and ridges of the Winona Basin up to 40 km seaward from the foot of the continental slope off northern Vancouver Island. The occurrence of a bottom-simulating reflector (BSR) observed in a number of vintage seismic reflection profiles is strongly correlated to faulted, and folded sedimentary ridges and buried folds. The observed tectonic structures of the Winona Basin are within the rapidly evolving Juan de Fuca – Cascadia – Queen Charlotte triple junction off BC. Re-processing of multi-channel data imaged mildly to strongly deformed sediments; the BSR is confined to sediments with stronger deformation. Changes in the amplitude character of sediment-reflections above and below the depth of the base of gas hydrate stability zone were also used as an indicator for the presence of gas hydrate. Additionally, regional amplitude and frequency reduction below some strong BSR occurrences may indicate free gas accumulations. Gas hydrate formation in the Winona Basin appears strongly constrained to folds and ridges and thus correlated to deeper-routed fluid-advection regimes. Methane production from in situ microbial activities as a source of gas to form gas hydrates, as proposed to be a major contributor for gas hydrates within the accretionary prism to the south, appears to be insufficient to produce the widespread gas hydrate occurrences in the Winona Basin. Potential reasons for the lack of sufficient in situ gas production may be that sedimentation rates are 5–100 times higher than those in the accretionary prism so that available organic carbon moves too quickly through the gas hydrate stability field. The confinement of BSRs to ridges and folds within the Winona Basin results in an areal extent of gas hydrate occurrences that is a factor of five less than what is expected from regional gas hydrate stability field mapping using water-depth (pressure) as the only controlling factor only.

Description: The Gibraltar arc, spans a complex portion of the Africa-Eurasia plate boundary marked by slow oblique convergence and intermediate and deep focus seismicity. The seemingly contradictory observations of a young extensional marine basin surrounded by an arcuate fold-and-thrust belt, have led to competing geodynamic models (delamination and subduction). Geophysical data acquired in the past decade provide a test for these models and support a narrow east-dipping, subduction zone. Seismic refraction studies indicate oceanic crust below the western Gulf of Cadiz. Tomography of the upper mantle reveals a steep, east-dipping high P-wave velocity body, beneath Gibraltar. The anisotropic mantle fabric from SKS splitting shows arc-parallel "fast directions", consistent with toroidal flow around a narrow, westward retreating subducting slab. The accompanying WSW advance of the Rif-Betic mountain belt has constructed a thick pile of deformed sediments, an accretionary wedge, characterized by west-vergent thrust anticlines. Bathymetric swath-mapping images an asymmetric embayment at the deformation front where a 2 km high basement ridge has collided. Subduction has slowed significantly since 5 Ma, but deformation of recent sediments and abundant mud volcanoes suggest ongoing activity in the accretionary wedge. Three possible origins for this deformation are discussed; gravitational spreading, overall NW-SE convergence between Africa and Iberia and finally a WSW tectonic push from slow, but ongoing roll-back subduction. In the absence of arc volcanism and shallow dipping thrust type earthquakes, evidence in favor of present-day subduction can only be indirect and remains the object of debate. Continued activity of the subduction offers a possible explanation for great (M〉8.5) earthquakes known to affect the area, like the famous 1755 Great Lisbon earthquake. Recent GPS studies show SW motion of stations in N Morocco at velocities of 3-6 mm/yr indicating the presence of an independent block, a "Rif-Betic-Alboran" microplate, situated between Iberia and Africa

Description: Mass-transport-deposits (MTDs) and hemipelagic mud interbedded with sandy turbidites are the main sedimentary facies in the Ulleung Basin, East Sea, offshore Korea. The MTDs show similar seismic reflection characteristics to gas-hydrate-bearing sediments such as regional seismic blanking (absence of internal reflectivity) and a polarity reversed base-reflection identical to the bottom-simulating reflector (BSR). Drilling in 2007 in the Ulleung Basin recovered sediments within the MTDs that exhibit elevated electrical resistivity and P-wave velocity, similar to gas hydrate-bearing sediments. In contrast, hemipelagic mud intercalated with sandy turbidites has much higher porosity and correspondingly lower electrical resistivity and P-wave velocity. At drill-site UBGH1-4 the bottom half of one prominent MTD unit shows two bands of parallel fractures on the resistivity log-images indicating a common dip-azimuth direction of about ∼230° (strike of ∼140°). This strike-direction is perpendicular to the seismically defined flow-path of the MTD to the north-east. At Site UBGH1-14, the log-data suggest two zones with preferred fracture orientations (top: ∼250°, bottom: ∼130°), indicating flow-directions to the north-east for the top zone, and north-west for the bottom zone. The fracture patterns may indicate post-depositional sedimentation that gave rise to a preferred fracturing possibly linked to dewatering pathways. Alternatively, fractures may be related to the formation of pressure-ridges common within MTD units. For the interval of observed MTD units, the resistivity and P-wave velocity log-data yield gas hydrate concentrations up to ∼10% at Site UBGH1-4 and ∼25% at Site UBGH1-14 calculated using traditional isotropic theories such as Archie's law or effective medium modeling. However, accounting for anisotropic effects in the calculation to honor observed fracture patterns, the gas hydrate concentration is overall reduced to less than 5%. In contrast, gas hydrate was recovered at Site UBGH1-4 near the base of gas hydrate stability zone (GHSZ). Log-data predict gas hydrate concentrations of 10–15% over an interval of 25 m above the base of GHSZ. The sediments of this interval are comprised of the hemipelagic mud and interbedded thin sandy turbidites, which did contain pore-filling gas hydrate as identified from pore-water freshening and core infra-red imaging. Seismically, this unit reveals a coherent parallel bedding character but has overall faint reflection amplitude. This gas-hydrate-bearing interval can be best mapped using a combination of regular seismic amplitude and seismic attributes such as Shale indicator, Parallel-bedding indicator, and Thin-bed indicator.

Description: Plant breeding and improved management options have made remarkable progress in increasing crop yields during the past century. However, climate change projections suggest that large yield losses will be occurring in many regions, particularly within sub-Saharan Africa. The development of climate-ready germplasm to offset these losses is of the upmost importance. Given the time lag between the development of improved germplasm and adoption in farmers’ fields, the development of improved breeding pipelines needs to be a high priority. Recent advances in molecular breeding provide powerful tools to accelerate breeding gains and dissect stress adaptation. This review focuses on achievements in stress tolerance breeding and physiology and presents future tools for quick and efficient germplasm development. Sustainable agronomic and resource management practices can effectively contribute to climate change mitigation. Management options to increase maize system resilience to climate-related stresses and mitigate the effects of future climate change are also discussed.

Description: Gas hydrate saturations were calculated based on Archie's relation and rock-physics modeling utilizing log measurements of electrical resistivity and P-wave velocity through the gas hydrate stability zone (GHSZ) at two sites in the Krishna Godavari (KG) basin off the East Coast of India. Acoustic impedance inversion was then performed around the well sites for regional extrapolation of the borehole data. Well-log based gas hydrate concentration estimates and core data are in general agreement with the seismic impedance inversion results at the individual well sites. However, the correlation with seismic data and thus the confidence in the extrapolation decreases with distance from the well site. To address the general problem of unknown regional confidence limits in the extrapolation and aid in regional gas hydrate assessment analyses, a new approach is introduced by calculating the running-sum of the seismic similarity attribute across the gas hydrate stability zone. The running-sum of the similarity attribute can be used locally on a 2D seismic line or 3D seismic volume for defining the limit of well-data extrapolation around a given well site. By normalizing the running-sum of the similarity attribute from all available 2D seismic data in the KG basin, a regional map was generated yielding effective confidence limits for extrapolation of well-log data. Such maps of regional confidence limits can be used strategically in basin-wide gas hydrate assessments as they provide a measure of probability to find a given gas hydrate concentration, and may also offer a guide for defining a minimum regional spacing between well-sites to address the overall structural complexity of the basin (which is reflected in the similarity of the seismic data).

Description: The recent discovery of large ionospheric disturbances associated with sudden stratospheric warmings (SSW) has challenged the current understanding of mechanisms coupling the stratosphere and ionosphere. Non-linear interaction of planetary waves and tides has been invoked as a primary mechanism for such coupling. Here we show that planetary waves may play a more complex role than previously thought. Planetary wave forcing induces a global circulation that leads to the build-up of ozone density in the tropics at 30–50 km altitude, the primary region responsible for the generation of the migrating semidiurnal tide. The increase in the ozone density reaches 25% and lasts for ∼35 days following the SSW, long after the collapse of the planetary waves. Ozone enhancements are not only associated with SSW but are also observed after other amplifications in planetary waves. In addition, the longitudinal distribution of the ozone becomes strongly asymmetric, potentially leading to the generation of non-migrating semidiurnal tides. We report a persistent increase in the variability of ionospheric total electron content that coincides with the increase in stratospheric ozone and we suggest that the ozone fluctuations affect the ionosphere through the modified tidal forcing.

Description: The eastward penetration of Atlantic-derived water (ADW) into the Eurasian Basin of the Arctic Ocean was investigated at the western Laptev Sea continental margin for the time since c. 17.6 ka. Using a high-resolution investigation of the lithology, geochemistry, planktic and benthic foraminifers, and ostracods on a sediment core from 270 m water depth major steps in the environmental evolution of the region are recognized. In general, ADW was continuously present in the study area. Between 17.6 and 15.4 ka ADW manifested itself through open-water polynyas and associated upwelling events. Comparison between the Laptev Sea and northern Svalbard shelf using Cassidulina neoteretis allows assuming an unmodified subsurface inflow of ADW within its northern branch between 15.4 and 13.2, which was strongest after 14.7-ka and in line with the overall climate amelioration. A local freshwater event at 13 ka followed by shelf flooding and the establishment of a freshened shelf water mass resulted in an off-shelf displacement of ADW from the studied site as suggested by the disappearance of C. neoteretis between 12 and 7 ka. As evidenced by an abundance peak in Nonion labradoricum, the sea-ice marginal zone was located at the site around 12–11 ka but then shifted northward during the early Holocene warming. Enhanced ADW inflow since 7 ka correlated with climate cooling and southward retreat of the seasonal drift-ice margin. The inflow of ADW during mid–late Holocene differed from deglacial times because of the combined influence of northern and eastern ADW branches.

Description: Four new cyclic lipopeptides, cyclo-(AFA-Ser-Gln-Asn-Tyr-Asn-Ser-Thr), named cyclodysidins A–D, were isolated from the broth culture of Streptomyces strain RV15 associated with the marine sponge Dysidea tupha. The sequences of the amino acid building blocks in the compounds and their structures were determined by 1D- and 2D-NMR techniques and CID-MS/MS experiments. The absolute configurations of all α-amino acids were determined by HPLC analysis after derivatization with Marfey’s reagent and comparison with commercially available reference samples, while those two of the β-amino fatty acids were determined by using racemic and enantiopure reference samples synthetically prepared.

Description: There is an association between the polar stratospheric temperature in the northern winter and the solar cycle in the winters when the 50-mb equatorial winds are westerly: The lower the sunspot number in such winters, the lower is the temperature. No major mid-winter warmings occurred in these winters when the sunspot number was below about 100. There is no such relationship in the easterly phase of the QBO. In that phase the temperatures are generally higher than in the westerly phase, and major mid-winter warmings occur regardless of the state of the solar cycle.

Description: Gridded datasets have been constructed for the physical parameters controlling the formation of gas hydrate. Simultaneous solutions to the gas hydrate phase and pressure-temperature equations were obtained for each node of these grids. The results show sub-bottom depths of potential methane hydrate BSRs. These are presented as colour contoured grids for the thickness of the hydrate stability zone for the European margins. The chart proposes that if gas hydrates exist over these areas, then this is the potential depth to the BSR. This depth is generally greater along the continental margins and also increases with increasing age of the margin. Shallowing of the BSR can be seen over areas of thinned continental crust and plateaus. The geological factors controlling gas hydrate formation determine areas of likely occurrence so the apparent paucity of identified hydrate layer BSRs off the European margins, particularly in the Mediterranean, is most notable.

Description: We present data on the burial, displacement and exhumation history of the Himalayan fold-thrust belt in eastern Bhutan. These data document the magnitude and timing of displacement of large, discrete structures and highlight temporal variability in shortening rates. Eight new40Ar/39Ar ages from white mica, 32 new zircon (U-Th)/He ages, 7 new apatite fission track ages, and 1 new U-Pb zircon (LA-MC-ICP-MS) metamorphic rim growth age are combined with published cooling ages and deformation temperatures, and incremental shortening magnitudes from restorations of two published balanced cross sections, to illustrate the kinematic and temporal development of the Bhutan thrust belt. Integrating these data from ∼23 Ma to the present illustrates rapid horizontal shortening rates (28–35 mm/yr) between 23–20 Ma and 15–10 Ma, separated by more moderate rates (10–23 mm/yr). Shortening rates decrease significantly to 7–10 mm/yr (and possibly as low as 3–4 mm/yr) from 10 to 0 Ma. This decrease is interpreted to represent the onset of strain partitioning in the eastern part of the Himalayan-Tibetan orogenic system, between shortening in the Bhutan thrust belt, uplift of the Shillong Plateau, and deformation and outward growth of the northern and eastern Tibetan Plateau. Within estimated error, horizontal shortening rates during emplacement of the Main Central thrust sheet and during construction of the upper Lesser Himalayan duplex approached India-Asia tectonic velocities. Thus, for periods of time between ∼23–20 Ma and ∼15–10 Ma, the Bhutan thrust belt may have absorbed nearly all India-Asian convergence at this longitude.

Description: Most authigenic carbonates previously recovered from the Cascadia slope have 87Sr/86Sr signatures that reflect shallow precipitation in equilibrium with coeval seawater. There is also evidence for carbonate formation supported by fluids that have been modified by reactions with the incoming Juan de Fuca plate (87Sr/86Sr = 0.7071; Teichert et al., 2005) or with terrigenous turbidites (87Sr/86Sr = 0.70975 to 0.71279; Sample et al., 1993). We report on the strontium isotopic composition of carbonates and fluids from IODP Site U1329 and nearby Barkley Canyon (offshore Vancouver Island), which have strontium isotope ratios as low as 0.70539. Whereas the strontium and oxygen isotopic compositions of carbonates from paleoseeps in the uplifted Coast Range forearc indicate formation in ambient bottom seawater, several samples from the Pysht/Sooke Fm. show a 87Sr-depleted signal (87Sr/86Sr = 0.70494 and 0.70511) similar to that of the anomalous Site U1329 and Barkley Canyon carbonates. Our data, when analyzed in the context of published elemental and isotopic composition of these carbonates (Joseph et al., 2012), point to two formation mechanisms: 1) shallow precipitation driven by the anaerobic oxidation of methane (AOM) with δ13C values as low as − 50‰ and contemporaneous 87Sr/86Sr seawater ratios, and 2) carbonate precipitation driven by fluids that have circulated through the oceanic crust, which are depleted in 87Sr. Carbonates formed from the second mechanism precipitate both at depth and at sites of deep-sourced fluid seepage on the seafloor. The 87Sr-depleted carbonates and pore fluids found at Barkley Canyon represent migration of a deep, exotic fluid similar to that found in high permeability conglomerate layers at 188 mbsf of Site U1329, and which may have fed paleoseeps in the Pysht/Sooke Fm. These exotic fluids likely reflect interaction with the 52–57 Ma igneous Crescent Terrane, which supplies fluids with high calcium, manganese and strontium enriched in the non-radiogenic nucleide. Tectonic compression and dehydration reactions then force these fluids updip, where they pick up the thermogenic hydrocarbons and 13C-enriched dissolved inorganic carbon that are manifested in fluids and carbonates sampled at Barkley Canyon and at Site U1329. The Crescent Terrane may have sourced cold seeps in this margin since at least the late Oligocene.

Description: The association between beta-glucan (MacroGard (R)) supplemented feed and apoptosis in immune-related organs of common carp (Cyprinus carpio) was studied using fluorescence microscopy and real-time PCR. In addition the effect of Aeromonas salmonicida, LPS and Poly(I:C) injections on this relationship was evaluated. Whilst acridine orange staining revealed that apoptosis levels were independent of MacroGard (R) and LPS/Poly(1:C) administration or their combination, it was shown that injection with A. salmonicida increased the percentage of apoptotic cells irrespective of the feeding regime. It was apparent that in all the treatments gene expression profiles displayed organ and time dependency. For example no effect was observed at 7 days of MacroGard (R) administration while 25 days of feeding led to increased iNOS expression and differential up-regulation of anti- or pro-apoptotic genes depending on organ. This may indicate differences in NO sensitivity. MacroGard (R) also led to an elevation of pro- as well as anti-apoptotic genes in LPS or Poly(1:C) injected fish, while LPS/Poly(I:C) alone had little effect. A. salmonicida caused enhanced iNOS expression and it is possible that the type of apoptosis pathway induced is organ dependent as Caspase 9 is induced in mid-gut but not in pronephros. These results indicate that MacroGard (R) feeding alone or in combination with other pathogenic factors did not induce significant apoptosis in immune organs

Description: This study presents results from 46 sensitivity experiments carried out with three structurally simple (2, 3, and 6 biogeochemical state variables, respectively) models of production, export and remineralization of organic phosphorus, coupled to a global ocean circulation model and integrated for 3000 years each. The models’ skill is assessed via different misfit functions with respect to the observed global distributions of phosphate and oxygen. Across the different models, the global root-mean square misfit with respect to observed phosphate and oxygen distributions is found to be particularly sensitive to changes in the remineralization length scale, and also to changes in simulated primary production. For this metric, changes in the production and decay of dissolved organic phosphorus as well as in zooplankton parameters are of lesser importance. For a misfit function accounting for the misfit of upper-ocean tracers, however, production parameters and organic phosphorus dynamics play a larger role. Regional misfit patterns are investigated as indicators of potential model deficiencies, such as missing iron limitation, or deficiencies in the sinking and remineralization length scales. In particular, the gradient between phosphate concentrations in the northern North Pacific and the northern North Atlantic is controlled predominantly by the biogeochemical model parameters related to particle flux. For the combined 46 sensitivity experiments performed here, the global misfit to observed oxygen and phosphate distributions shows no clear relation to either simulated global primary or export production for either misfit metric employed. However, a relatively tight relationship that is very similar for the different model of different structural complexity is found between the model-data misfit in oxygen and phosphate distributions to simulated meso- and bathypelagic particle flux. Best agreement with the observed tracer distributions is obtained for simulated particle fluxes that agree most closely with sediment trap data for a nominal depth of about 1000 m, or deeper.

Description: Alternative reconstructions of the Jurassic northern extent of Greater India differ by up to several thousand kilometers. We present a new model that is constrained by revised seafloor spreading anomalies, fracture zones and crustal ages based on drillsites/dredges from all the abyssal plains along the West Australian margin and the Wharton Basin, where an unexpected sliver of Jurassic seafloor (153 Ma) has been found embedded in Cretaceous (95 My old) seafloor. Based on fracture zone trajectories, this NeoTethyan sliver must have originally formed along a western extension of the spreading center that formed the Argo Abyssal Plain, separating a western extension of West Argoland/West Burma from Greater India as a ribbon terrane. The NeoTethyan sliver, Zenith and Wallaby plateaus moved as part of Greater India until westward ridge jumps isolated them. Following another spreading reorganization, the Jurassic crust resumed migrating with Greater India until it was re-attached to the Australian plate ∼95 Ma. The new Wharton Basin data and kinematic model place strong constraints on the disputed northern Jurassic extent of Greater India. Late Jurassic seafloor spreading must have reached south to the Cuvier Abyssal Plain on the West Australian margin, connected to a spreading ridge wrapping around northern Greater India, but this Jurassic crust is no longer preserved there, having been entirely transferred to the conjugate plate by ridge propagations. This discovery constrains the major portion of Greater India to have been located south of the large-offset Wallaby-Zenith Fracture Zone, excluding much larger previously proposed shapes of Greater India.

Description: The sensitivity of the El Niño–Southern Oscillation (ENSO) phenomenon to changes in the tropical Pacific mean climate is investigated with a coupled atmosphere-ocean-sea ice general circulation model (AOGCM), the Kiel Climate Model (KCM). Different mean climate states are generated by changing the orbital forcing that causes a redistribution of solar energy, which was a major driver of both the Holocene and the Eemian climates. We find that the ENSO amplitude is positively correlated with both the Equatorial Pacific sea surface temperature (SST) and the equatorial zonal SST contrast. The latter is controlled by the upwelling-induced damping of the SST changes in the Eastern Equatorial Pacific (EEP), and by the vertical ocean dynamical heating and zonal heat transport convergence in the Western Equatorial Pacific. The ENSO amplitude also correlates positively with the seasonal SST amplitude in the EEP and negatively with the strength of the easterly Trades over the Equatorial Pacific. However, the ENSO period is rather stable and stays within 3–4 years. Enhanced ENSO amplitude is simulated during the late-Holocene, in agreement with paleoproxy records. The tight positive correlation (r = 0.89) between the ENSO strength and the Western Pacific Warm Pool (WPWP) SST suggests that the latter may provide an indirect measure of the ENSO amplitude from proxy data that cannot explicitly resolve interannual variability. Key Points: - ENSO amplitude enhances as mean SST & west-east SST gradient rise in tropical Pacific - The broad range frequency peaks at periods of 3-4 years over Holocene and Eemian - The Pacific's warm pool SST is a suitable indicator to monitor ENSO variability

Description: A reconstruction of Holocene sea ice conditions in the Fram Strait provides insight into the palaeoenvironmental and palaeoceanographic development of this climate sensitive area during the past 8500 years BP. Organic geochemical analyses of sediment cores from eastern and western Fram Strait enable the identification of variations in the ice coverage that can be linked to changes in the oceanic (and atmospheric) circulation system. By means of the sea ice proxy IP25, phytoplankton-derived biomarkers and ice rafted detritus (IRD) increasing sea ice occurrences are traced along the western continental margin of Spitsbergen throughout the Holocene, which supports previous palaeoenvironmental reconstructions that document a general cooling. A further significant ice advance during the Neoglacial is accompanied by distinct sea ice fluctuations, which point to short-term perturbations in either the Atlantic Water advection or Arctic Water outflow at this site. At the continental shelf of East Greenland, the general Holocene cooling, however, seems to be less pronounced and sea ice conditions remained rather stable. Here, a major Neoglacial increase in sea ice coverage did not occur before 1000 years BP. Phytoplankton-IP25 indices (“PIP25-Index”) are used for more explicit sea ice estimates and display a Mid Holocene shift from a minor sea ice coverage to stable ice margin conditions in eastern Fram Strait, while the inner East Greenland shelf experienced less severe to marginal sea ice occurrences throughout the entire Holocene. Highlights ► Biomarker and IRD data give insight into Holocene sea ice conditions in Fram Strait. ► We find increasing sea ice coverage off West Spitsbergen throughout the Holocene. ► Oceanic/atmospheric variability caused Neoglacial sea ice fluctuations. ► Ice conditions along East Greenland shelf remain rather stable until 1000 years BP.

Description: The influence of various wind and wave conditions on the variability of downwelling irradiance Ed (490 nm) in water is subject of this study. The work is based on a two-dimensional Monte Carlo radiative transfer model with high spatial resolution. The model assumes conditions that are ideal for wave focusing, thus simulation results reveal the upper limit for light fluctuations. Local wind primarily determines the steepness of capillary-gravity waves which in turn dominate the irradiance variability near the surface. Down to 3 m depth, maximum irradiance peaks that exceed the mean irradiance Ed by a factor of more than 7 can be observed at low wind speeds up to 5 m s−1. The strength of irradiance fluctuations can be even amplified under the influence of higher ultra-gravity waves; thereby peaks can exceed 11 Ed. Sea states influence the light field much deeper; gravity waves can cause considerable irradiance variability even at 100 m depth. The simulation results show that under realistic conditions 50% radiative enhancements compared to the mean can still occur at 30 m depth. At greater depths, the underwater light variability depends on the wave steepness of the characteristic wave of a sea state; steeper waves cause stronger light fluctuations.

Description: The impacts of natural atmospheric variability and anthropogenic climate change on the spatial distribution, seasonality, structure, and productivity of North Pacific plankton groups are investigated by means of an Earth System Model (ESM) that contains a plankton model with variable stoichiometry. The ESM is forced with observed greenhouse gases for the 20th century and with the Intergovernmental Panel on Climate Change A1B Emission Scenario for the 21st century. The impacts of the two main modes of variability – connected with the Aleutian Low (AL) strength and with the North Pacific Oscillation (NPO) – are considered. When the AL is strong, primary productivity and chlorophyll concentrations are higher in the central Pacific, the seasonality of plankton is enhanced, and the classical grazing chain is stimulated, whereas in the Alaskan Gyre the model simulates a chlorophyll decrease and a shift toward smaller phytoplankton species. A stronger NPO increases productivity and chlorophyll concentration at ∼45°N. In the anthropogenic climate change scenario, simulated sea surface temperature is 4 °C higher with respect to contemporary conditions, leading to reduced mixing and nutrient supply at middle-subpolar latitudes. The seasonal phytoplankton bloom is reduced and occurs one month earlier, the flow of carbon to the microbial loop is enhanced, and phytoplanktonic stoichiometry is nutrient-depleted. Primary productivity is enhanced at subpolar latitudes, due to increased ice-free regions and possibly to temperature-related photosynthesis stimulation. This study highlights that natural climate variability may act alternatively to strengthen or to weaken the human-induced impacts, and that in the next decades it will be difficult to distinguish between internal and external climate forcing on North Pacific plankton groups. Highlights ► A plankton model with variable stoichiometry has been used in a coupled climate study. ► Natural climate variations modify North Pacific plankton biomass by 10–30% while a warming scenario decreases primary production up to 50%. ► DOC production and the microbial foodweb will be favored in a warmer North Pacific. ► Positive phases of natural fluctuations counteract the impacts of global warming. ► Natural and anthropogenic impacts are distinguishable only in the second part of the 21st century.

Description: The copepod Calanus sinicus is a common and abundant species in the shelf waters of the western North Pacific from Japan to Vietnam, and is a main food source for crucial fish species. This study examined the effect of food and light on the swimming behavior of this species. The swimming activity was assessed by using 2 approaches that focused on the dynamics of swimming states and the statistical properties of their trajectories. We discovered that the complexity of swimming paths was reduced under illuminated conditions, and intensified in the absence of food. The swimming activity in such conditions was characterized by a less tortuous shape of trajectories, a lower instantaneous swimming velocity, and a lower recurrence of extreme events. In addition, the entropy of swimming paths decreased when food was included, and the minimal entropy was reached in dark conditions and presence of food, indicating predictable behavior. A general increase in swimming activity was dominated by the slow swimming state. The variations in the swimming activity of adult females exhibited an adaptive pattern that allowed maximizing the exploitation of the three-dimensional, and generally diluted environment that the copepods inhabit, as well as limiting the risk of the predation. ⺠We used robust numerical techniques to identify behavioral patterns of C. sinicus. ⺠The light and food availability plays key role in C. sinicus. ⺠C. Sinicus exhibits an adaptive strategy for feeding success and minimize risk. ⺠Mechanistic understanding of Calanus sinicus feeding ecology.

Description: The world's oceans are warming and becoming more acidic. Both stressors, singly or in combination, impact marine species, and ensuing effects might be particularly serious for early life stages. To date most studies have focused on ocean acidification (OA) effects in fully marine environments, while little attention has been devoted to more variable coastal ecosystems, such as the Western Baltic Sea. Since natural spatial and temporal variability of environmental conditions such as salinity, temperature or pCO(2) impose more complex stresses upon organisms inhabiting these habitats, species can be expected to be more tolerant to OA (or warming) than fully marine taxa. We present data on the variability of salinity, temperature and pH within the Kiel Fjord and on the responses of the barnacle Amphibalanus improvisus from this habitat to simulated warming and OA during its early development. Nauplii and cyprids were exposed to different temperature (12, 20 and 27 degrees C) and pCO(2) (nominally 400, 1250 and 3250 mu atm) treatments for 8 and 4 weeks, respectively. Survival, larval duration and settlement success were monitored. Warming affected larval responses more strongly than OA. Increased temperatures favored survival and development of nauplii but decreased survival of cyprids. OA had no effect upon survival of nauplii but enhanced their development at low (12 degrees C) and high (27 degrees C) temperatures. In contrast, at the intermediate temperature (20 degrees C), nauplii were not affected even by 3250 mu atm pCO(2). None of the treatments significantly affected settlement success of cyprids. These experiments show a remarkable tolerance of A. improvisus larvae to 1250 mu atm pCO(2), the level of OA predicted for the end of the century

Description: Fish stocks can be considered as natural capital stocks providing harvestable fish. Fishing at low stock sizes means borrowing from the natural asset. While fishing a particular quantity generates immediate profits and income, an interest rate has to be paid in terms of foregone future fishing income, as the fish stock's reproductive capacity remains low and fishing costs stay high. In this paper we propose to apply the concept of shadowinterest rate to quantify the degree of overfishing. It incorporates the relevant biological and economic information and compares across fish stocks.We calculate the shadow interest rates for 13major European fish stocks and find these rates to range from10% tomore than 200%. The concept of the shadow interest rate can be used to make the economic consequences of overfishing transparent and to evaluate the profitability of shortterm catch reductions as investments in natural capital stocks.

Description: The tropical impact on the East Asian winter monsoon (EAWM) is examined in an ensemble of atmospheric general circulation model runs that use relaxation towards the ERA-40 reanalysis in the tropics for winters between 1960/61 and 2001/02 and performed with a recent version of the European Centre for Medium-Range Weather Forecasts model. 25% of the interannual variance of the EAWM can be reproduced in the ensemble mean by the model experiments with relaxation, even though the influence from ENSO appears to be weak. The implication is that there is the possibility of enhanced predictability for the EAWM resulting from improved forecast skill in the tropics as a whole. Prescribing observed sea surface temperature and sea ice without using relaxation cannot reproduce the interannual variability of the EAWM in our experiments, questioning the usefulness of uncoupled atmosphere models in this region, consistent with previous studies. Key Points: - Tropical impact on interannual variability of the East Asian winter monsoon. - Tropical influence and extratropical SST and sea-ice matter for the trend. - AGCMs driven only by observed SST and sea-ice give poor results.

Description: The Cenozoic tectonic evolution of the South China Sea is reflected in diverse tectonic processes including continental rifting, seafloor spreading, subduction, terrane collision and strike-slip fault movement. A continent-ocean transition zone in the northern South China Sea caused by the lithospheric extension when the continent underwent break-up, rifting and later seafloor spreading, is clearly imaged in the multi-channel seismic data presented in this study. The morphological units of the continent-ocean transition zone are the rift-depression, the volcanic zone and tilted fault blocks. The volcanic zone represents a highest extension zone within the continent-ocean transition zone and is mainly distributed in the southern slope uplift zone along the northern passive margin of the South China Sea. The large listric-normal faults bounding the Dongsha Rise and Baiyun Sag are evidenced in the seismic image. The passive margin in the northern South China Sea underwent the wide-rift to narrow-rift process in the transition zone as inferred from the relation between the surface heat flow and initial rifted crustal thickness. The continent-ocean transition zone in the continental margin of the South China Sea is consistent with high heat flow zone (average 90 mW.m(-2)) observed in the previous heat flow measurements and at ODP Site 1148, and is manifested in a sharp change of the P-wave velocity. The rifted margin of the South China Sea is a non-typical magma poor passive margin or an intermediary form between the Iberian-type non-volcanic and the Greenland-type volcanic margin compared to the world's typical passive margins

Description: The Arctic featured the strongest surface warming over the globe during the recent decades, and the temperature increase was accompanied by a rapid decline in sea ice extent. However, little is known about Arctic sea ice change during the Early Twentieth Century Warming (ETCW) during 1920–1940, also a period of a strong surface warming, both globally and in the Arctic. Here, we investigate the sensitivity of Arctic winter surface air temperature (SAT) to sea ice during 1875–2008 by means of simulations with an atmospheric general circulation model (AGCM) forced by estimates of the observed sea surface temperature (SST) and sea ice concentration. The Arctic warming trend since the 1960s is very well reproduced by the model. In contrast, ETCW in the Arctic is hardly captured. This is consistent with the fact that the sea ice extent in the forcing data does not strongly vary during ETCW. AGCM simulations with observed SST but fixed sea ice reveal a strong dependence of winter SAT on sea ice extent. In particular, the warming during the recent decades is strongly underestimated by the model, if the sea ice extent does not decline and varies only seasonally. This suggests that a significant reduction of Arctic sea ice extent may have also accompanied the Early Twentieth Century Warming, pointing toward an important link between anomalous sea ice extent and Arctic surface temperature variability.

Description: 2-D seismic data from the top and the western slope of Mergui Ridge in water depths between 300 and 2200 m off the Thai west coast have been investigated in order to identify mass transport deposits (MTDs) and evaluate the tsunamigenic potential of submarine landslides in this outer shelf area. Based on our newly collected data, 17 mass transport deposits have been identified. Minimum volumes of individual MTDs range between 0.3 km3 and 14 km3. Landslide deposits have been identified in three different settings: (i) stacked MTDs within disturbed and faulted basin sediments at the transition of the East Andaman Basin to the Mergui Ridge; (ii) MTDs within a pile of drift sediments at the basin-ridge transition; and (iii) MTDs near the edge of/on top of Mergui Ridge in relatively shallow water depths (〈 1000 m). Our data indicate that the Mergui Ridge slope area seems to have been generally unstable with repeated occurrence of slide events. We find that the most likely causes for slope instabilities may be the presence of unstable drift sediments, excess pore pressure, and active tectonics. Most MTDs are located in large water depths (〉 1000 m) and/or comprise small volumes suggesting a small tsunami potential. Moreover, the recurrence rates of failure events seem to be low. Some MTDs with tsunami potential, however, have been identified on top of Mergui Ridge. Mass-wasting events that may occur in the future at similar locations may trigger tsunamis if they comprise sufficient volumes. Landslide tsunamis, emerging from slope failures in the working area and affecting western Thailand coastal areas therefore cannot be excluded, though the probability is very small compared to the probability of earthquake-triggered tsunamis, arising from the Sunda Trench.

Description: This study investigates the controls on organic carbon and molybdenum (Mo) accumulation in sediments deposited within the Western Interior Seaway across the Cenomanian–Turonian boundary interval (94.34–93.04 Ma) including Oceanic Anoxic Event 2 (OAE2). Carbon fluxes to the sediment–water interface (reflecting changes in primary productivity) and bottom-water oxygen concentrations (reflecting preservation effects) are reconstructed from field data and used to constrain a benthic model that simulates the geochemistry of unconsolidated sediments as they were deposited. The results show that increased availability of reactive iron prevents Mo sequestration as thiomolybdate (MoS42 −) during OAE2 (O2 ~ 105 μM) by (i) inhibiting sulfate reduction, and (ii) buffering any free sulfide that becomes available. In the post-OAE2 period (O2 ~ 50 μM), Mo accumulation is favored by a large reduction in iron flux. Importantly, this occurs in parallel with oxygenated bottom waters and high rates of aerobic carbon degradation in the surface sediments, implying that elevated Mo burial fluxes in ancient marine facies do not necessarily reflect euxinic or even anoxic conditions within the water column. Our findings suggest that both an increase in production and preservation lead to enrichment in organic carbon in the Western Interior Seaway. More generally, the results demonstrate that a careful consideration of the coupling between iron, carbon and oxygen cycles during the early stages of diagenesis is critical for interpreting geochemical proxies in modern and ancient settings.

Description: The fractionation of silicon (Si) stable isotopes by biological activity in the surface ocean makes the stable isotope composition of silicon (δ30Si) dissolved in seawater a sensitive tracer of the oceanic biogeochemical Si cycle. We present a high-precision dataset that characterizes the δ30Si distribution in the deep Atlantic Ocean from Denmark Strait to Drake Passage, documenting strong meridional and smaller, but resolvable, vertical δ30Si gradients. We show that these gradients are related to the two sources of deep and bottom waters in the Atlantic Ocean: waters of North Atlantic and Nordic origin carry a high δ30Si signature of ≥+1.7‰ into the deep Atlantic, while Antarctic Bottom Water transports Si with a low δ30Si value of around +1.2‰. The deep Atlantic δ30Si distribution is thus governed by the quasi-conservative mixing of Si from these two isotopically distinct sources. This disparity in Si isotope composition between the North Atlantic and Southern Ocean is in marked contrast to the homogeneity of the stable nitrogen isotope composition of deep ocean nitrate (δ15N-NO3). We infer that the meridional δ30Si gradient derives from the transport of the high δ30Si signature of Southern Ocean intermediate/mode waters into the North Atlantic by the upper return path of the meridional overturning circulation (MOC). The basin-scale deep Atlantic δ30Si gradient thus owes its existence to the interaction of the physical circulation with biological nutrient uptake at high southern latitudes, which fractionates Si isotopes between the abyssal and intermediate/mode waters formed in the Southern Ocean. Key Points: - Deep Atlantic Ocean displays gradient in Si isotopic composition of silicic acid - The gradient is caused by quasi-conservative mixing of Si from NADW and AABW - Contrasting isotope signature of NADW and AABW due to interaction of biology and MOC

Description: Observations and model runs indicate trends in dissolved oxygen (DO) associated with current and ongoing global warming. However, a large-scale observation-to-model comparison has been missing and is presented here. This study presents a first global compilation of DO measurements covering the last 50 yr. It shows declining upper-ocean DO levels in many regions, especially the tropical oceans, whereas areas with increasing trends are found in the subtropics and in some subpolar regions. For the Atlantic Ocean south of 20° N, the DO history could even be extended back to about 70 yr, showing decreasing DO in the subtropical South Atlantic. The global mean DO trend between 50° S and 50° N at 300 dbar for the period 1960 to 2010 is –0.066 μmol kg−1 yr−1. Results of a numerical biogeochemical Earth system model reveal that the magnitude of the observed change is consistent with CO2-induced climate change. However, the pattern correlation between simulated and observed patterns of past DO change is negative, indicating that the model does not correctly reproduce the processes responsible for observed regional oxygen changes in the past 50 yr. A negative pattern correlation is also obtained for model configurations with particularly low and particularly high diapycnal mixing, for a configuration that assumes a CO2-induced enhancement of the C : N ratios of exported organic matter and irrespective of whether climatological or realistic winds from reanalysis products are used to force the model. Depending on the model configuration the 300 dbar DO trend between 50° S and 50° N is −0.027 to –0.047 μmol kg−1 yr−1 for climatological wind forcing, with a much larger range of –0.083 to +0.027 μmol kg−1 yr−1 for different initializations of sensitivity runs with reanalysis wind forcing. Although numerical models reproduce the overall sign and, to some extent, magnitude of observed ocean deoxygenation, this degree of realism does not necessarily apply to simulated regional patterns and the representation of processes involved in their generation. Further analysis of the processes that can explain the discrepancies between observed and modeled DO trends is required to better understand the climate sensitivity of oceanic oxygen fields and predict potential DO changes in the future.

Description: Active gas venting occurs on the uppermost continental slope off west Svalbard, close to and upslope from the present-day intersection of the base of methane hydrate stability (BMHS) with the seabed in about 400 m water depth in the inter-fan region between the Kongsfjorden and Isfjorden cross-shelf troughs. From an integrated analysis of high-resolution, two-dimensional, pre-stack migrated seismic reflection profiles and multibeam bathymetric data, we map out a bottom simulating reflector (BSR) in the inter-fan region and analyze the subsurface gas migration and accumulation. Gas seeps mostly occur in the zone from which the BMHS at the seabed has retreated over the recent past (1975–2008) as a consequence of a bottom water temperature rise of 1°C. The overall margin-parallel alignment of the gas seeps is not related to fault-controlled gas migration, as seismic evidence of faults is absent. There is no evidence for a BSR close to the gas flare region in the upper slope but numerous gas pockets exist directly below the predicted BMHS. While the contour following trend of the gas seeps could be a consequence of retreat of the landward limit of the BMHS and gas hydrate dissociation, the scattered distribution of seeps within the probable hydrate dissociation corridor and the occurrence of a cluster of seeps outside the predicted BMHS limit and near the shelf break indicate the role of lithological heterogeneity in focusing gas migration.

Description: Inorganic dissolved macronutrient (nitrogen, N, and phosphorus, P) supply to surface waters in the eastern tropical South Pacific is influenced by expanding oxygen minimum zones, since N loss occurs due to microbial processes under anoxic conditions while P is increasingly released from the shelf sediments. To investigate the impact of decreasing N:P supply ratios in the Peruvian Upwelling, we conducted nutrient manipulation experiments using a shipboard mesocosm setup with a natural phytoplankton community. In a first experiment, either N or P or no nutrients were added with mesozooplankton present or absent. In a second experiment, initial nutrient concentrations were adjusted to four N:P ratios ranging from 2.5 to 16 using two "high N" and two "high P" levels in combination (i.e., +N, +P, +N and P, no addition). Over six and seven days, respectively, microalgal biomass development as well as nutrient uptake was monitored. Phytoplankton biomass strongly responded to N addition, in both mesozooplankton-grazed and not grazed treatments. The developing diatom bloom in the "high N" exceeded that in the "low N" treatments by a factor of two. No modulation of the total biomass by P-addition was observed, however, species-specific responses were more variable. Notably, some organisms were able to benefit from low N:P fertilization ratios, especially Heterosigma sp. and Phaeocystis globosa which are notorious for forming blooms that are toxic or inadequate for mesozooplankton nutrition. After the decline of the diatom bloom, the relative contribution of unsaturated fatty acid to the lipid content of seston was positively correlated to diatom biomass in the peak bloom, indicating that positive effects of diatom blooms on food quality of the protist community to higher trophic levels remain even after the phytoplankton biomass was incorporated by grazers. Our results indicate an overall N-limitation of the system, especially in the case of dominating diatoms, which were able to immediately utilize the available nitrate (within two days) and develop a biomass maximum within three days of incubation. After the decline of diatom biomass, detection of the cyanobacterial marker pigment aphanizophyll indicated the occurrence of diazotrophs, especially in those enclosures initially provided with high N supply. This was surprising, as diazotrophs are thought to play a role in compensating to some extent the N deficit above OMZs in the succession of phytoplankton after an upwelling event

Description: Transport of liquid and gaseous hydrocarbons through focused fluid flow systems is a widespread process in continental margins and sedimentary basins, which is gaining increased attention in the assessment of geohazards, environment conservation, and securing fossil energy resources. Studying the abundance, distribution and drivers for this process is crucial for understanding its role in 1) the dynamics of gas hydrate accumulation and destabilization, 2) submarine slope stability and related tsunamis, 3) the plethora of chemosynthetic benthic ecosystems that develop in deep seep sites, and 4) the input of greenhouse gases (e.g. methane) into the ocean/atmosphere system, which may influence the atmospheric carbon budget and Earth's paleo- and present climate. New ocean exploration tools provide ever more data and improve our understanding of these systems. However, the subject still suffers from a lack of interdisciplinary knowledge dissemination. The ongoing international debate about the timing and the processes that control fluid expulsion in sedimentary basins is fuelled by their implications for structural and petroleum geology. Because fluids expelled at cold seeps originate at depth they represent open windows into the underlying petroleum systems and are valuable indicators for the reservoir systems. They may also help in deciphering past and predicting future climate change because worldwide release of large amounts of fluids may have an impact on the chemistry of the ocean and atmosphere. Highlights ► Special issue on hydrocarbon leakage through focused fluid flow systems. ► Imaging and interpretation of gas migration and flow structures. ► Polygonal fault systems and their implications on fluid and hydrocarbon migration. ► Ecosystems, methane-derived carbonates and geochemistry of seeps. ► Petroleum systems, thermogenic gas release, and Cenozoic hyper-thermal events.

Description: Anthropogenic CO2 emission will lead to an increase in seawater pCO(2) of up to 80-100 Pa (800-1000 mu atm) within this century and to an acidification of the oceans. Green sea urchins (Strongylocentrotus droebachiensis) occurring in Kattegat experience seasonal hypercapnic and hypoxic conditions already today. Thus, anthropogenic CO2 emissions will add up to existing values and will lead to even higher pCO(2) values 〉200 Pa (〉2000 mu atm). To estimate the green sea urchins' potential to acclimate to acidified seawater, we calculated an energy budget and determined the extracellular acid base status of adult S. droebachiensis exposed to moderately (102-145 Pa, 1007-1431 mu atm) and highly (284-385 Pa, 2800-3800 mu atm) elevated seawater pCO(2) for 10 and 45 days. A 45-day exposure to elevated pCO(2) resulted in a shift in energy budgets, leading to reduced somatic and reproductive growth. Metabolic rates were not significantly affected, but ammonium excretion increased in response to elevated pCO(2). This led to decreased O:N ratios. These findings suggest that protein metabolism is possibly enhanced under elevated pCO(2) in order to support ion homeostasis by increasing net acid extrusion. The perivisceral coelomic fluid acid-base status revealed that S. droebachiensis is able to fully (intermediate pCO(2)) or partially (high pCO(2)) compensate extracellular pH (pH(e)) changes by accumulation of bicarbonate (maximum increases 2.5 mM), albeit at a slower rate than typically observed in other taxa (10-day duration for full pH(e) compensation). At intermediate pCO(2), sea urchins were able to maintain fully compensated pH(e) for 45 days. Sea urchins from the higher pCO(2) treatment could be divided into two groups following medium-term acclimation: one group of experimental animals (29%) contained remnants of food in their digestive system and maintained partially compensated pH(e) (+2.3 mM HCO3-), while the other group (71%) exhibited an empty digestive system and a severe metabolic acidosis (-0.5 pH units, -2.4 mM HCO3-). There was no difference in mortality between the three pCO(2) treatments. The results of this study suggest that S. droebachiensis occurring in the Kattegat might be pre-adapted to hypercapnia due to natural variability in pCO(2) in its habitat. We show for the first time that some echinoderm species can actively compensate extracellular pH. Seawater pCO(2) values of 〉200 Pa, which will occur in the Kattegat within this century during seasonal hypoxic events, can possibly only be endured for a short time period of a few weeks. Increases in anthropogenic CO2 emissions and leakages from potential sub-seabed CO2 storage (CCS) sites thus impose a threat to the ecologically and economically important species S. droebachiensis.

Description: Observations indicate increasingly large and strong oxygen minimum zones (OMZs) in the tropical Pacific over recent decades. Here we report on oxygen decreases and variability within the eastern equatorial Pacific OMZ. We construct time series from historical and profiling float oxygen data and analyze data from repeat hydrographic sections at 110°W and 85°50′W. Historical data are quite sparse for constructing oxygen time series, but floats with oxygen sensors prove to be good tools to fill measurement gaps in later parts of these time series. In the region just south of the equator a time series over the last 34 years reveals that oxygen decreases from 200 to 700 m at a rate between 0.50 and 0.83 μmol kg−1 yr−1. This strong decrease seems to be related to changes in the Pacific Decadal Oscillation (PDO). Oscillations on shorter time scales (e.g., an El Niño signal in the upper 350 m) are superimposed upon this trend. In the section data, a general trend of decreasing oxygen is present below the surface layer. While velocity differences appear related to oxygen differences in the equatorial channel, there is less correlation elsewhere. Contrasting with long-term trend computations, the trends derived from two repeat sections are obscured by the influence of seasonal and longer-term variability. Multidecadal variability (e.g., PDO) has the strongest influence on long-term trends, while El Niño, isopycnal heave, current variability, seasonal cycles, and temperature changes are less important. Key points: - Oxygen decrease in the Pacific OMZ over the last 34 years in 200-700 m depth - Trends in oxygen and their relation to variability on different timescales - Relation between oxygen and velocity changes in the equatorial channel

Description: In the European Union (EU), subsidies to the fishing industry and lack of compliance and enforcement of fishing regulations have led to a chronic overcapacity and a general decline of commercial fish stocks. The entire fisheries sector (extractive fishing, fish canning and commercialization subsectors) is still affected, with all directly and indirectly employed people being impacted by the overfishing problem. However, fish populations could strongly increase and generate more economic output if they were left for only a few years under less fishing pressure. The papers published in this Special Issue are the products of recent research conducted by European fisheries scientists, economists, and lawyers. A window of opportunity for change is currently open under the current Common Fisheries Policy (CFP) reform. This Special Issue is an attempt to stimulate the debate by providing new findings and formulating new proposals to rebuild stocks, strengthen ecosystems resilience and better manage EU fisheries. The Special Issue consists of eight papers dealing with relevant biological and economic aspects of the management of European fisheries. Together these papers show that the EU fish stocks are under high fishing pressure and that their recovery will generate not only environmental or ecosystem benefits but also greater profitability for the fisheries sector. Highlights: ► Subsidies, lack of compliance and enforcement have lead to a decline of fish stocks. ► The fisheries sector is affected by the overfishing problem. ► The Special Issue provides valuable papers for the next Common Fisheries Policy reform.

Description: We describe the main differences in simulations of stratospheric climate and variability by models within the fifth Coupled Model Intercomparison Project (CMIP5) that have a model top above the stratopause and relatively fine stratospheric vertical resolution (high-top), and those that have a model top below the stratopause (low-top). Although the simulation of mean stratospheric climate by the two model ensembles is similar, the low-top model ensemble has very weak stratospheric variability on daily and interannual time scales. The frequency of major sudden stratospheric warming events is strongly underestimated by the low-top models with less than half the frequency of events observed in the reanalysis data and high-top models. The lack of stratospheric variability in the low-top models affects their stratosphere-troposphere coupling, resulting in short-lived anomalies in the Northern Annular Mode, which do not produce long-lasting tropospheric impacts, as seen in observations. The lack of stratospheric variability, however, does not appear to have any impact on the ability of the low-top models to reproduce past stratospheric temperature trends. We find little improvement in the simulation of decadal variability for the high-top models compared to the low-top, which is likely related to the fact that neither ensemble produces a realistic dynamical response to volcanic eruptions

Description: Deep crustal constraint is often carried out using deterministic inverse methods, sometimes using seismic refraction, gravity and electromagnetic datasets in a complementary or "joint" scheme. With increasingly powerful parallel computer systems it is now possible to apply joint inversion schemes to derive an optimum model from diverse input data. These methods are highly effective where the uncertainty in the system is small. However, given the complex nature of these schemes it is often difficult to discern the uniqueness of the output model given the noise in the data, and the application of necessary regularization and weighting in the inversion process means that the extent of user prejudice pertaining to the final result may be unclear. We can rigorously address the subject of uncertainty using standard statistical tools but these methods also become less feasible if the prior model space is large or the forward simulations are computationally expensive. We present a simple Monte Carlo scheme to screen model space in a fully joint fashion, in which we replace the forward simulation with a fast and uncertainty-calibrated mathematical function, or emulator. This emulator is used as a proxy to run the very large number of models necessary to fully explore the plausible model space. We develop the method using a simple synthetic dataset then demonstrate its use on a joint data set comprising first-arrival seismic refraction. MT and scalar gravity data over a diapiric salt body. This study demonstrates both the value of a forward Monte Carlo approach (as distinct from a search-based or conventional inverse approach) in incorporating all kinds of uncertainty in the modelling process, exploring the entire model space, and shows the potential value of applying emulator technology throughout geophysics. Though the target here is relatively shallow, the methodology can be readily extended to address the whole crust.

Description: The Giudicarie fault system represents the central, approximately NE–SW-trending segment of the Periadriatic fault system. Based on new fission track data the near surface evolution of the units bordering the Giudicarie fault system (GFS) is analysed. New and published zircon fission track (ZFT) data are compiled in an age-contour map of the area, and depict some first order features of cooling and exhumation pattern. Out of the three main Permian plutons located in the footwall of the GFS, the northern (Brixen pluton) and southernmost (Kreuzberg pluton) yielded ZFT ages of about 100 Ma, while the intermediate Ifinger pluton cooled through the zircon partial annealing zone only in the Miocene. The Ifinger granodiorite overthrusts the Southalpine basement and the Permian rocks of the Athesian Volcanic District along the NW dipping brittle Naif fault. Across this thrust an important age jump from Miocene to Permian ZFT ages is observed, suggesting that the deformation has jumped towards the southeast, thus deactivating the related segment of the GFS. The most eye-catching feature of the age-contour map is the corridor of young, Miocene ZFT ages from small tonalitic intrusions along the Northern Giudicarie fault. This corridor connects Early Miocene (17–23 Ma) ZFT ages of the NE-Adamello with the Middle–Late Miocene (19–9 Ma) ZFT ages of the Meran–Mauls basement and the western Tauern window and provides evidence for a polyphase deformation along the GFS. A three-step evolution model is proposed for the GFS: (a) shearing of the northern rim of the Adamello batholith along the dextral strike slip Periadriatic fault system; (b) bending of the central part of the fault to a NE direction together with the adjacent intrusive rocks; (c) Dissection of the bend part (Meran–Mauls fault) by the sinistral transpressive Northern Giudicarie fault and exhumation of small tonalitic bodies along this structure. Highlights ► Different exhumation history for Permian intrusions along the Giudicarie fault system. ► Very consistent ZFT ages of ~ 15 Ma for the entire Meran–Mauls basement. ► Corridor of Miocene zircon fission track ages along the Giudicarie fault system. ► Evidence for a polyphase deformation along the Giudicarie fault system.

Description: Dangerous climate change is best avoided by drastically and rapidly reducing greenhouse gas emissions. Nevertheless, geoengineering options are receiving attention on the basis that additional approaches may also be necessary. Here we review the state of knowledge on large-scale ocean fertilization by adding iron or other nutrients, either from external sources or via enhanced ocean mixing. On the basis of small-scale field experiments carried out to date and associated modelling, the maximum benefits of ocean fertilization as a negative emissions technique are likely to be modest in relation to anthropogenic climate forcing. Furthermore, it would be extremely challenging to quantify with acceptable accuracy the carbon removed from circulation on a long term basis, and to adequately monitor unintended impacts over large space and time-scales. These and other technical issues are particularly problematic for the region with greatest theoretical potential for the application of ocean fertilization, the Southern Ocean. Arrangements for the international governance of further field-based research on ocean fertilization are currently being developed, primarily under the London Convention/London Protocol. Highlights: ► Fertilization using iron can increase the uptake of CO2 across the sea surface. ► But most of this uptake is transient; long-term sequestration is difficult to assess. ► Unintended impacts of ocean fertilization may be far removed in space and time. ► For climate benefits, the Southern Ocean has most potential – also most problems. ► A regulatory framework for ocean fertilization research has been developed.

Description: Low-angle normal faults play a prominent role in discussions about fault strength, as they require significant weakening to remain active at low angles. The submerged Moresby Seamount detachment (MSD) is arguably the best exposed active low-angle detachment worldwide. We analyzed dredged MSD protoliths, cataclasites and mylonites to investigate deformation mechanisms and fault-weakening processes. Deformation is accompanied by important syntectonic, fluid-induced mass transfer, controlling the rheological behavior of the MSD. While the mafic protolith behaves brittlely at the onset of deformation, the metasomatic mineralogical and chemical changes cause a transition to plastic flow as the rock is progressively exhumed. Immobile elements provide a reference frame for total material gains and losses. Si, Ca and K are syntectonically enriched, while Fe, Ti, Mg, and Al are depleted. Mass increase is about 10% in the cataclasites and about 48% in the mylonites. Main mechanism is syntectonic veining, causing enrichment in calcite and quartz, thus making the mylonites capable to flow plastically. Minimum time-integrated fluid flux is calculated as 3 × 105 m3 m−2, indicating that the MSD is an important fluid conduit. The fluids have a deep crustal source, a bottom water temperature and turbidity anomaly suggests that the hydrothermal system is still active. Syntectonic veining in fault rocks and recent seismic activity both suggest that the MSD is intermittently brittle, implying a brittle-plastic transition at unusually high temperature and low differential stress. We conclude that fault zone metasomatism is crucial in forming weak detachments at passive margins, and may be a prerequisite for successful crustal breakup.

Description: In order to evaluate the influence of diagenetic and post-sampling processes on the stable oxygen and carbon isotope compositions of biogenic carbonates, we conducted a multiproxy study of organic-rich sediments from the eastern Pacific oxygen minimum zone. Core MD02-2520, which was retrieved from the Gulf of Tehuantepec (Mexico), has seasonal laminations and covers the last 40 kyr. Together with the presence of gypsum crystals and inorganic calcite aggregates, the occurrence of large excursions in the stable oxygen and carbon isotope records of both planktonic and benthic foraminifera (as large as +3‰ in d18O and -5‰ in d13C) point to significant secondary transformations. Storage-related gypsum precipitation was ruled out since it implies sulfide reoxidation by oxygen that triggers biogenic calcite dissolution, which proved to be of minor importance here. Instead, precipitation of authigenic calcite during early diagenesis appears to be the most likely process responsible for the observed isotopic excursions. The d13C composition for inorganic calcite aggregates (-5 to -7‰) suggests a major contribution from anaerobic oxidation of organic matter. The d34S composition for gypsum crystals (-10 to +15‰) suggests a major contribution from anaerobic reoxidation of authigenic sulfides, potentially involving reactions with metal oxides and sulfur disproportionation. A minor part of the gypsum might possibly have formed as a result of local pore water salinity increases induced by gas hydrate formation.

Description: The boron isotope systematics has been determined for azooxanthellate scleractinian corals from a wide range of both deep-sea and shallow-water environments. The aragonitic coral species, Caryophyllia smithii, Desmophyllum dianthus, Enallopsammia rostrata, Lophelia pertusa, and Madrepora oculata, are all found to have relatively high δ11B compositions ranging from 23.2‰ to 28.7‰. These values lie substantially above the pH-dependent inorganic seawater borate equilibrium curve, indicative of strong up-regulation of pH of the internal calcifying fluid (pHcf), being elevated by ∼0.6–0.8 units (ΔpH) relative to ambient seawater. In contrast, the deep-sea calcitic coral Corallium sp. has a significantly lower δ11B composition of 15.5‰, with a corresponding lower ΔpH value of ∼0.3 units, reflecting the importance of mineralogical control on biological pH up-regulation. The solitary coral D. dianthus was sampled over a wide range of seawater pHT and shows an approximate linear correlation with ΔpHDesmo = 6.43 − 0.71pHT (r2 = 0.79). An improved correlation is however found with the closely related parameter of seawater aragonite saturation state, where ΔpHDesmo = 1.09 − 0.14Ωarag (r2 = 0.95), indicating the important control that carbonate saturation state has on calcification. The ability to up-regulate internal pHcf, and consequently Ωcf, of the calcifying fluid is therefore a process present in both azooxanthellate and zooxanthellate aragonitic corals, and is attributed to the action of Ca2+-ATPase in modulating the proton gradient between seawater and the site of calcification. These findings also show that the boron isotopic compositions (δ11Bcarb) of aragonitic corals are highly systematic and consistent with direct uptake of the borate species within the biologically controlled extracellular calcifying medium. We also show that the relatively strong up-regulation of pH and consequent elevation of the internal carbonate saturation state (Ωcf ∼8.5 to ∼13) at the site of calcification by cold-water corals, facilitates calcification at or in some cases below the aragonite saturation horizon, providing a greater ability to adapt to the already low and now decreasing carbonate ion concentrations. Although providing greater resilience to the effects of ocean acidification and enhancing rates of calcification with increasing temperature, the process of internal pHcf up-regulation has an associated energetic cost, and therefore growth-rate cost, of ∼10% per 0.1 pH unit decrease in seawater pHT. Furthermore, as the aragonite saturation horizon shoals with rapidly increasing pCO2 and Ωarag 〈 1, increased dissolution of the exposed skeleton will ultimately limit their survival in the deep oceans.

Description: A 2-Dimensional mathematical reaction-transport model was developed to study the impact of the mud-dwelling frenulate tubeworm Siboglinum sp. on the biogeochemistry of a sediment (MUC15) at the Captain Arutyunov mud volcano (CAMV). By explicitly describing the worm in its surrounding sediment, we are able to make budgets of processes occurring in- or outside of the worm, and to quantify how different worm densities and biomasses affect the anaerobic oxidation of methane (AOM) and sulfide reoxidation (HSox). The model shows that, at the observed densities, the presence of a thin worm body is sufficient to keep the upper 10 cm of sediment well homogenised with respect to dissolved substances, in agreement with observations. By this "bio-ventilation" activity, the worm pushes the sulfate-methane transition (SMT) zone downward to the posterior end of its body, and simultaneously physically separates the sulfide produced during the anaerobic oxidation of methane from oxygen. While there is little scope for AOM to take place in the tubeworm's body, 70% of the sulfide that is produced by sulfate reduction processes or that is advected in the sediment is preferentially shunted via the organism where it is oxidised by endosymbionts providing the energy for the worm's growth. The process of sulfide reoxidation, occurring predominantly in the worm's body is thus very distinct from the anaerobic oxidation of methane, which is a diffuse process that takes place in the sediments in the methane-sulfate transition zone. We show how the sulfide oxidation process is affected by increasing densities and length of the frenulates, and by upward advection velocity. Our biogeochemical model is one of the first to describe tubeworms explicitly. It can be used to directly link biological and biogeochemical observations at seep sites, and to study the impacts of mud-dwelling frenulates on the sediment biogeochemistry under varying environmental conditions. Also, it provides a tool to explore the competition between bacteria and fauna for available energy resources.

Description: The risk and environmental impact assessments required for geological CO2 storage projects will have to rely on different types of numerical models, which will have to be calibrated and validated against measurements. Available measurements from ongoing demonstration projects are limited, hence it is necessary to turn to analog processes or laboratory experiments to estimate model parameters. In any case, parameter estimates will have uncertainties that will be important to assess when predicting future scenarios. We study a model for the rise velocity of droplets in the ocean, an important process sub-model for simulating gas seeps into marine waters. As the origin we use the parameters estimation study by Bigalke et al. (2010) based on a tank experiment. We illustrate how Linearized Covariance Analysis (LCA) can be used to assess the parameter uncertainties, and how to design a similar experiment that reduces these uncertainties. The linearity assumption underlying LCA is assessed using curvature measures. It is shown that up to ∼63% reduction in uncertainties is achieved by choosing the right droplet size distribution; by extending the range of droplet sizes to include larger droplets the uncertainties are reduced by another ∼88%.

Description: Magnesium calcites were synthesized from aqueous solutions supersaturated with respect to calcite at 25, 40, 60, and 80 °C in gas tight batch reactors for up to 35 days. Any amorphous material still present in the precipitates was removed using a partial dissolution treatment. Resulting purified Mg-calcite had Mg contents ranging from 6 to 32 mol% MgCO3. An isotopic steady-state was attained between the fluid and the precipitated solids within two weeks at 25 °C. δ18O values derived from the experiments at steady-state, depend on both temperature and the Mg content of the calcite in accord with: 1000lnαMg-calcite–H2O=18,030/T−32.42+(6×108/T3–5.47×106/T2+16,780/T−17.21)×CMg where αMg-calcite–H2O represents the calcite–water oxygen isotope fractionation factor, T refers to the temperature in °K and CMg denotes the mole percent of MgCO3 in the calcite. These results indicate that the addition of 5 mol% MgCO3 into the calcite increases 1000lnαMg-calcite–H2O by 0.88 as compared to that of pure calcite at 25 °C. This difference could lead to a 4.2 °C decrease in estimated formation temperature estimates. These results demonstrate that the accurate interpretation of oxygen isotope fractionation in magnesium calcites requires explicit provision for the effect of magnesium on oxygen isotope fractionation factors. Highlights ► The effect of Mg on calcite–aqueous fluid oxygen isotope fractionation was investigated. ► Mg incorporation is increasing the calcite–aqueous fluid oxygen isotope fractionation. ► This effect is reduced at higher temperatures. ► Obtained results are important for paleo-temperature estimation. Gadget timed out while loading

Description: Seismic oceanography is based on the passage of a regularly repeating acoustic impulsive source and an acquisition streamer along the surface of the ocean, and on summing together all signals reflected from temperature and salinity interfaces in the ocean (where there are acoustic impedance contrasts). Due to the inherent redundancy of the method, random noise is attenuated, while signal is preserved; however, if the original signal-to-noise ratio is large enough, one need not use data from the entire streamer to create a 2D profile. A processing scheme is here devised to obtain consecutive images, known as stacks, of the structure of the water column. The scheme, named Seismic Offset Groups (SOG), consists in splitting the data from the whole streamer at a given geographical position into data produced by different streamer subsets. The method is illustrated by partitioning data from a 5-km long streamer into 7 offset groups separated by 3.5 min in time, thereby imaging the same seafloor-referenced location over a period of 21 min. As the streamer passes over a fixed geographical point, motions within the water column are observed. Each stack, created with a subset of the complete streamer, can therefore be considered an image of the water column at a particular time step (animation frame). In this way each image shows a different thermohaline fabric and the animation allows us to visualize internal ocean motions.

Description: On 27 February 2010 the Mw 8.8 Maule earthquake in Central Chile ruptured a seismic gap where significant strain had accumulated since 1835. Shortly after the mainshock a dense network of temporary seismic stations was installed along the whole rupture zone in order to capture the aftershock activity. Here, we present the aftershock distribution and first motion polarity focal mechanisms based on automatic detection algorithms and picking engines. By processing the seismic data between 15 March and 30 September 2010 from stations from IRIS, IPGP, GFZ and University of Liverpool we determined 20,205 hypocentres with magnitudes Mw between 1 and 5.5. Seismic activity occurs in six groups: 1.) Normal faulting outer rise events 2.) A shallow group of plate interface seismicity apparent at 25–35 km depth and 50–120 km distance to the trench with some variations between profiles. Along strike, the aftershocks occur largely within the zone of coseismic slip but extend ~ 50 km further north, and with predominantly shallowly dipping thrust mechanisms. Along dip, the events are either within the zone of coseismic slip, or downdip from it, depending on the coseismic slip model used. 3.) A third band of seismicity is observed further downdip at 40–50 km depth and further inland at 150–160 km trench perpendicular distance, with mostly shallow dipping (~ 28°) thrust focal mechanisms indicating rupture of the plate interface significantly downdip of the coseismic rupture, and presumably above the intersection of the continental Moho with the plate interface. 4.) A deep group of intermediate depth events between 80 and 120 km depth is present north of 36°S. Within the Maule segment, a large portion of events during the inter-seismic phase originated from this depth range. 5.) The magmatic arc exhibits a small amount of crustal seismicity but does not appear to show significantly enhanced activity after the Mw 8.8 Maule 2010 earthquake. 6.) Pronounced crustal aftershock activity with mainly normal faulting mechanisms is found in the region of Pichilemu (~ 34.5°S). These crustal events occur in a ~ 30 km wide region with sharp inclined boundaries and oriented oblique to the trench. The best-located events describe a plane dipping to the southwest, consistent with one of the focal planes of the large normal-faulting aftershock (Mw = 6.9) on 11 March 2010.

Description: The south-central Chilean subduction zone has witnessed some of the largest earthquakes in history, making this region particularly important for understanding plate coupling. Here we present the results of a local earthquake tomography study from a temporary local seismic network in the Villarrica region between 39 and 40°S, where the largest coseismic displacement of the 1960 Valdivia earthquake occurred. A lowvelocity anomaly and high Vp/Vs values occur under the coastal region, indicating mantle serpentinisation and/or underthrusting of forearc material. Further east, a high-velocity anomaly is observed, interpreted as “normal” high-velocity mantle. Under the active volcanic arc a low-velocity anomaly together with high Vp/Vs ratios (1.8 and higher) likely images fluid ascent beneath the volcanoes. Close to the subducting Valdivia Fracture Zone, the coastal low-velocity anomaly extends further inland, where it interrupts and shifts the high-velocity anomalies associated with “normal” fast mantle velocities. This may indicate enhanced fluid presence along this part of the margin, probably caused by a stronger hydration of the incoming plate along the Valdivia Fracture Zone. This is consistent with geochemical fluid proxies (U/Th, Pb/Ce, Ba/Nb) in young volcanic rocks displaying peak values along the volcanic front at Llaima and Villarrica Volcanoes, and with recent GPS measurements, which suggested a local reduction in plate coupling in this region. The shift in the high-velocity anomaly underlying the central part may be caused by a north to south decrease in plate age and hydration across the Valdivia Fracture Zone, and may explain why a Central Valley is absent in this segment of the margin. The low La/Yb ratios in the volcanic rocks from Villarrica and Llaima suggest that the high slab-derived fluid flux causes elevated degrees of melting beneath these volcanoes, providing an explanation as to why these are amongst the most active volcanoes in South America.

Description: In the aftermath of an earthquake and tsunami on 11 March 2011 radioactive 137Cs was discharged from a damaged nuclear power plant to the sea off Fukushima Dai-ichi, Japan. Here we explore its dilution and fate with a state-of-the-art global ocean general circulation model, which is eddy-resolving in the region of interest. We find apparent consistency between our simulated circulation, estimates of 137Cs discharged ranging from 0.94 p Bq (Japanese Government, 2011) to 3.5 ± 0.7 p Bq (Tsumune et al., 2012), and measurements by Japanese authorities and the power plant operator. In contrast, our simulations are apparently inconsistent with the high 27 ± 15 p Bq discharge estimate of Bailly du Bois et al. (2012). Expressed in terms of a diffusivity we diagnose, from our simulations, an initial dilution on the shelf of 60 to 100 m2 s−1. The cross-shelf diffusivity is at 500 ± 300 m2 s−1 significantly higher and variable in time as indicated by its uncertainty. Expressed as an effective residence time of surface water on the shelf, the latter estimate transfers to 43 ± 16 days. As regards the fate of 137Cs, our simulations suggest that activities up to 4 mBq l−1 prevail in the Kuroshio-Oyashio Interfrontal Zone one year after the accident. This allows for low but detectable 0.1 to 0.3 m Bq l−1 entering the North Pacific Intermediate Water before the 137Cs signal is flushed away. The latter estimates concern the direct release to the sea only.

Description: A relaxation technique applied to the ECMWF model is used to analyse 11, 21 and 31 year trends in the boreal winter mean 500 hPa North Atlantic Oscillation (NAO), Pacific North America pattern (PNA) and Southern Annular Mode (SAM) indices. For the PNA, the results indicate a strong influence from the tropics on all time scales, whereas for the NAO, the stratosphere is important on time scales of 11 and 21 but with an indication of feedback from extratropical sea surface temperature and sea-ice (SSTSI) anomalies on the 11 year time scale. For the SAM, the tropics emerge as the most important influence. We find an influence from the stratosphere consistent with expectations based on ozone depletion, although no clear role for stratospheric forcing of the SAM is found in these experiments.

Description: The coelacanth, Latimeria chalumnae, occurs at the Eastern coast of Africa from South Africa up to Kenya. It is often referred to as a living fossil mainly because of its nearly unchanged morphology since the Middle Devonian. As it is a close relative to the last common ancestor of fish and tetrapods, molecular studies mostly focussed on their phylogenetic relationships. We now present a population genetic study based on 71 adults from the whole known range of the species. Despite an overall low genetic diversity, there is evidence for divergence of local populations. We assume that originally the coelacanths at the East African Coast derived from the Comoros population, but have since then diversified into additional independent populations: one in South Africa and another in Tanzania. Unexpectedly, we find a split of the Comoran coelacanths into two sympatric subpopulations. Despite its undeniably slow evolutionary rate, the coelacanth still diversifies and is therefore able to adapt to new environmental conditions.

Description: Bias correcting climate models implicitly assumes stationarity of the correction function. This assumption is assessed for regional climate models in a pseudo reality for seasonal mean temperature and precipitation sums. An ensemble of regional climate models for Europe is used, all driven with the same transient boundary conditions. Although this model-dependent approach does not assess all possible bias non-stationarities, conclusions can be drawn for the real world. Generally, biases are relatively stable, and bias correction on average improves climate scenarios. For winter temperature, bias changes occur in the Alps and ice covered oceans caused by a biased forcing sensitivity of surface albedo; for summer temperature, bias changes occur due to a biased sensitivity of cloud cover and soil moisture. Precipitation correction is generally successful, but affected by internal variability in arid climates. As model sensitivities vary considerably in some regions, multi model ensembles are needed even after bias correction. Key Points: - Bias correction in general improves future climate simulations - Cloud cover, soil moisture and albedo changes may cause temperature bias changes - Precipitation biases in arid regions are affected by internal variability

Description: Hydrocarbon seeps are ubiquitous at gas-prone Cenozoic deltas such as the Nile Deep Sea Fan (NDSF2) where seepage into the bottom water has been observed at several mud volcanoes (MVs3) including North Alex MV (NAMV4). Here we investigated the sources of hydrocarbon gases and sedimentary organic matter together with biomarkers of microbial activity at four locations of NAMV to constrain how venting at the seafloor relates to the generation of hydrocarbon gases in deeper sediments. At the centre, high upward flux of hot (70 °C) hydrocarbon-rich fluids is indicated by an absence of biomarkers of Anaerobic Oxidation of Methane (AOM) and nearly constant methane (CH4) concentration depth-profile. The presence of lipids of incompatible thermal maturities points to mixing between early-mature petroleum and immature organic matter, indicating that shallow mud has been mobilized by the influx of deep-sourced hydrocarbon-rich fluids. Methane is enriched in the heavier isotopes, with values of δ13C∼−46.6‰VPDB and δD ∼−228‰VSMOW, and is associated with high amounts of heavier homologues (C2+) suggesting a co-genetic origin with the petroleum. On the contrary at the periphery, a lower but sustained CH4 flux is indicated by deeper sulphate–methane transition zones and the presence of 13C-depleted biomarkers of AOM, consistent with predominantly immature organic matter. Values of δ13C-CH4∼−60‰VPDB and decreased concentrations of 13C-enriched C2+ are typical of mixed microbial CH4 and biodegraded thermogenic gas from Plio-Pleistocene reservoirs of the region. The maturity of gas condensate migrated from pre-Miocene sources into Miocene reservoirs of the Western NDSF is higher than that of the gas vented at the centre of NAMV, supporting the hypothesis that it is rather released from the degradation of oil in Neogene reservoirs. Combined with the finding of hot pore water and petroleum at the centre, our results suggest that clay mineral dehydration of Neogene sediments, which takes place posterior to reservoir filling, may contribute to intense gas generation at high sedimentation rate deltas. Highlights ► Extensive seepage of biodegraded gas at the periphery of North Alex mud volcano. ► At the centre seepage of deeper-sourced hot water, oil and thermogenic gas. ► At the centre, degradation of reservoired-oil to gas is most likely. ► Multivariate statistics on biomarkers show oil degradation at the centre and AOM at the periphery. ► Shallow gas production is enhanced by hot water influx from actively dewatering clays.

Description: We employed coupled 3-D biophysical models to better understand the effects of physical forcing conditions as well as differences in vertical distribution and growth performance on the spatial distribution of larval sprat (Sprattus sprattus) in the North and the Baltic Sea. Our model simulations analysed the influence of abiotic and biotic forcing variability on larval transport and the seasonal and inter-annual variability in spatial distribution of larvae originating from different spawning areas in each of the two systems. Due to strong spatial and temporal differences in temperature, drift durations differed between the two ecosystems. During cold spring and warm summer periods, drift durations in the Baltic were ∼35 and 15 days, respectively, but were somewhat shorter (30 and 10 d) in the North Sea. Changes in larval feeding rates markedly impacted larval growth rate and stage duration, and, hence, environmental histories experienced by larvae as well as their final distribution. Generally, specific spawning sites were relatively well connected to specific juvenile nursery areas in the Baltic. However, in the North Sea, considerable mixing of sprat populations occurred with frontal areas acted as convergence zones for older larvae originating from different spawning sites. The mixing and/or co-occurrence of 18-mm larvae from different source regions were greatest (least) in the early spring (summer) for larvae at colder (warmer) temperatures having longer (shorter) drift durations. Generally, such high mixing probability would not promote small- or medium-scale population distinctness of North Sea sprat. The results of our coupled hydrodynamic/trophodynamic model simulations provide a baseline in quantifying and understanding larval sprat transport in these different ecosystems and exemplify the extent to which environmental variability (e.g., differences in temperature as well as prey availability) can influence spatial distributions of larval fish.

Description: The Logatchev hydrothermal field at 14°45′N on the MAR is characterized by gas plumes that are enriched in methane and helium compared to the oceanic background. We investigated CH4 concentration and δ13C together with δ3He in the water column of that region. These data and turbidity measurements indicate that apart from the known vent fields, another vent site exists northeast of the vent field Logatchev 1. The distribution of methane and 3He concentrations along two sections were used in combination with current measurements from lowered acoustic Doppler current profilers (LADCP) to calculate the horizontal plume fluxes of these gases. According to these examinations 0.02 μmol s−1 of 3He and 0.21 mol s−1 of methane are transported in a plume that flows into a southward direction in the central part of the valley. Based on 3He measurements of vent fluid (22 ± 6 pM), we estimate a total vent flux in this region of about 900 L s−1 and a total flux of CH4 of 3.2 mol s−1.

Description: The Solar Cycle and the Quasi-Biennial Oscillation are two major components of natural climate variability. Their direct and indirect influences in the stratosphere and troposphere are subject of a number of studies. The so-called ``top-down' mechanism describes how solar UV changes can lead to a significant enhancement of the small initial signal and corresponding changes in stratospheric dynamics. How the signal then propagates to the surface is still under investigation. We continue the ``top-down' analysis further down to the ocean and show the dynamical ocean response with respect to the solar cycle and the QBO. For this we use two 110-year chemistry climate model experiments from NCAR's Whole Atmosphere Community Climate Model (WACCM), one with a time varying solar cycle only and one with an additionally nudged QBO, to force an ocean general circulation model, GFZ's Ocean Model for Circulation and Tides (OMCT). We find a significant ocean response to the solar cycle only in combination with a prescribed QBO. Especially in the Southern Hemisphere we find the tendency to positive Southern Annular Mode (SAM) like pattern in the surface pressure and associated wind anomalies during solar maximum conditions. These atmospheric anomalies propagate into the ocean and induce deviations in ocean currents down into deeper layers, inducing an integrated sea surface height signal. Finally, limitations of this study are discussed and it is concluded that comprehensive climate model studies require a middle atmosphere as well as a coupled ocean to investigate and understand natural climate variability. Key Points: - Modeled oceanic solar cycle response depends on realistically modeled stratosphe - A realistically modeled stratospheric solar cycle response requires a QBO

Description: A deliberate tracer release experiment in 2008–2010 was used to study diapycnal mixing in the tropical northeastern Atlantic. The tracer (CF3SF5) was injected on the isopycnal surface σΘ = 26.88 kg m−3, which corresponds to about 330 m depth. Three surveys, performed 7, 20, and 30 months after the release, sampled the vertically and laterally expanding tracer patch. The mean diapycnal mixing estimate over the entire region occupied by the tracer and the period of 30 months was found to be (1.19 ± 0.18) × 10−5 m2 s−1, or, alternatively, (3.07 ± 0.58) × 10−11 (kg m−3)2 s−1 as computed from the advection-diffusion equation in isopycnal coordinates with the thickness-weighted averaging. The latter method is preferable in the regions of different stratification for it yields local diapycnal mixing estimates varying less with stratification than their Cartesian coordinate counterparts. Results of this study are comparable to the results of the North Atlantic tracer release experiment (NATRE). However, the internal wave-wave interaction models predict reduced mixing from the breaking of internal waves at low latitudes. Thus, the diapycnal diffusivity found in this study is higher than parameterized by the low latitude of the site (4°N–12°N).

Description: The radiogenic isotope composition of the Rare Earth Element (REE) neodymium (Nd) is a powerful water mass proxy for present and past ocean circulation. The processes controlling the Nd budget of the global ocean are not quantitatively understood and in particular source and sink mechanisms are still under debate. In this study we present the first full water column data set of dissolved Nd isotope compositions and Nd concentrations for the Eastern Equatorial Pacific (EEP), where one of the globally largest Oxygen Minimum Zones (OMZ) is located. This region is of particular interest for understanding the biogeochemical cycling of REEs because anoxic conditions may lead to release of REEs from the shelf, whereas high particle densities and fluxes potentially remove the REEs from the water column. Data were obtained between 1°40′N and 16°S along a nearshore and an offshore transect. Near surface zonal current bands, such as the Equatorial Undercurrent (EUC) and the Subsurface Countercurrent (SSCC), which are supplying oxygen-rich water to the OMZ are characterized by radiogenic Nd isotope signatures (εNd=−2). Surface waters in the northernmost part of the study area are even more radiogenic (εNd=+3), most likely due to release of Nd from volcanogenic material. Deep and bottom waters at the southernmost offshore station (14°S) are clearly controlled by advection of water masses with less radiogenic signatures (εNd=−7) originating from the Southern Ocean. Towards the equator, however, the deep waters show a clear trend towards more radiogenic values of up to εNd=−2. The northernmost station located in the Panama basin shows highly radiogenic Nd isotope signatures in the entire water column, which indicates that particle scavenging, downward transport and release processes play an important role. This is supported by relatively low Nd concentrations in deep waters (3000–6000 m) in the EEP (20 pmol/kg) compared to locations in the Northern and Central Pacific (40–60 pmol/kg), which suggests enhanced removal of Nd in the EEP.

Description: This study is the first to directly correlate gas transfer velocity, measured at sea using the eddy-correlation (EC) technique, and satellite altimeter backscattering. During eight research cruises in different parts of the world, gas transfer velocity of dimethyl sulfide (DMS) was measured. The sample times and locations were compared with overpass times and locations of remote sensing satellites carrying Ku-band altimeters: ERS-1, ERS-2, TOPEX, POSEIDON, GEOSAT Follow-On, JASON-1, JASON-2 and ENVISAT. The result was 179 pairs of gas transfer velocity measurements and backscattering coefficients. An inter-calibration of the different altimeters significantly reduced data scatter. The inter-calibrated data was best fitted to a quadratic relation between the inverse of the backscattering coefficients and the gas transfer velocity measurements. A gas transfer parameterization based on backscattering, corresponding with sea surface roughness, might be expected to perform better than wind speed-based parameterizations. Our results, however, did not show improvement compared to direct correlation of shipboard wind speeds. The relationship of gas transfer velocity to satellite-derived backscatter, or wind speed, is useful to provide retrieval algorithms. Gas transfer velocity (cm/hr), corrected to a Schmidt number of 660, is proportional to wind speed (m/s). The measured gas transfer velocity is controlled by both the individual water-side and air-side gas transfer velocities. We calculated the latter using a numerical scheme, to derive water-side gas transfer velocity. DMS is sufficiently soluble to neglect bubble-mediated gas transfer, thus, the DMS transfer velocities could be applied to estimate water-side gas transfer velocities through the unbroken surface of any other gas Key Points: - Show relations between altimeter data and field values of air-sea gas transfer - DMS gas transfer velocity can be used to estimate direct gas transfer of any gas - Direct gas transfer velocity (for Sc = 660) is roughly double 10 m wind speed

Description: The biomarker composition of dissolved organic carbon (DOC) of the six largest Arctic rivers was studied between 2003 and 2007 as part of the PARTNERS Project. Samples were collected over seasonal cycles relatively close to the river mouths. Here we report the lignin phenol and p-hydroxybenzene composition of Arctic river DOC in order to identify major sources of carbon. Arctic river DOC represents an important carbon conduit linking the large pools of organic carbon in the Arctic/Subarctic watersheds to the Arctic Ocean. Most of the annual lignin discharge (〉75%) occurs during the two month of spring freshet with extremely high lignin concentrations and a lignin phenol composition indicative of fresh vegetation from boreal forests. The three large Siberian rivers, Lena, Yenisei, and Ob, which also have the highest proportion of forests within their watersheds, contribute about 90% of the total lignin discharge to the Arctic Ocean. The composition of river DOC is also characterized by elevated levels of p-hydroxybenzenes, particularly during the low flow season, which indicates a larger contribution from mosses and peat bogs. The lignin composition was strongly related to the average 14C-age of DOC supporting the abundance of young, boreal-vegetation-derived leachates during spring flood, and older, soil-, peat-, and wetland-derived DOC during groundwater dominated low flow conditions, particularly in the Ob and Yukon Rivers. We observed significant differences in DOC concentration and composition between the rivers over the seasonal cycles with the Mackenzie River being the most unique, the Lena River being similar to the Yenisei, and the Yukon being most similar to the Ob. The observed relationship between the lignin phenol composition and watershed characteristics suggests that DOC discharge from these rivers could increase in a warmer climate under otherwise undisturbed conditions.

Description: The global Late Pliocene/Early Pleistocene cooling (~3.0–2.0 million years ago – Ma) concurred with extremely high diatom and biogenic opal production in most of the major coastal upwelling regions. This phenomenon was particularly pronounced in the Benguela upwelling system (BUS), off Namibia, where it is known as the Matuyama Diatom Maximum (MDM). Our study focuses on a new diatom silicon isotope (δ30Si) record covering the MDM in the BUS. Unexpectedly, the variations in δ30Si signal follow biogenic opal content, whereby the highest δ30Si values correspond to the highest biogenic opal content. We interpret the higher δ30Si values during the MDM as a result of a stronger degree of silicate utilisation in the surface waters caused by high productivity of mat-forming diatom species. This was most likely promoted by weak upwelling intensity dominating the BUS during the Late Pliocene/Early Pleistocene cooling combined with a large silicate supply derived from a strong Southern Ocean nutrient leakage responding to the expansion of Antarctic ice cover and the resulting stratification of the polar ocean 3.0–2.7 Ma ago. A similar scenario is hypothesized for other major coastal upwelling systems (e.g. off California) during this time interval, suggesting that the efficiency of the biological carbon pump was probably sufficiently enhanced in these regions during the MDM to have significantly increased the transport of atmospheric CO2 to the deep ocean. In addition, the coeval extension of the area of surface water stratification in both the Southern Ocean and the North Pacific, which decreased CO2 release to the atmosphere, led to further enhanced atmospheric CO2 drawn-down and thus contributed significantly to Late Pliocene/Early Pleistocene cooling.

Description: We present the first systematic study of the silicon isotope composition in the water column (δ30SiSi(OH)4) and in diatoms (δ30Sidiatom) from the underlying surface sediments in a coastal upwelling region. The surface waters upwelling on the shelf off Peru are mainly fed by southward flowing subsurface waters along the coast, which show a mean δ30SiSi(OH)4 of +1.5‰. The concentration of dissolved silicic acid (Si(OH)4) increases towards the south in these waters and with increasing water depth, suggesting lateral mixing with water masses from the south and intense remineralisation of particulate biogenic silica (bSiO2) in the water column and in the surface sediments. Surface waters in the realm of the most intense upwelling between 5°S and 15°S have only marginally elevated δ30SiSi(OH)4 values (δ30SiSi(OH)4 = +1.7‰) with respect to the source Si isotope composition, whereas further north and south, where upwelling is less pronounced, surface waters are more strongly fractionated (δ30SiSi(OH)4 up to +2.8‰) due to the stronger utilisation of the smaller amounts of available Si(OH)4. The degree of Si(OH)4 utilisation in the surface waters along the shelf estimated from the Si(OH)4 concentration data ranges from 51% to 93%. The δ30Sidiatom values of hand-picked diatoms in the underlying surface sediments vary from +0.6‰ to +2.0‰, which is within the range of the expected fractionation between surface waters and diatoms. The fractionation signal in the surface waters produced during formation of the diatoms is reflected by the δ30Sidiatom values in the underlying sediments, with the lowest δ30Sidiatom values in the main upwelling region. The silicon isotope compositions of bSiO2 (δ30SibSiO2) from the same surface sediment samples are generally much lower than the δ30Sidiatom signatures indicating a significant contamination of the bSiO2 with biogenic siliceous material other than diatoms, such as sponge spicules. This shift towards lighter δ30SibSiO2 values by up to −1.3‰ compared to δ30Sidiatom signatures for the same surface sediment samples potentially biases the interpretation of δ30Si paleorecords from sediments with low bSiO2 concentrations, and thus the reconstruction of past Si(OH)4 utilisation in surface waters.