ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

Ihre E-Mail wurde erfolgreich gesendet. Bitte prüfen Sie Ihren Maileingang.

Leider ist ein Fehler beim E-Mail-Versand aufgetreten. Bitte versuchen Sie es erneut.

Vorgang fortführen?

Exportieren
Filter
  • Artikel  (1.582)
  • General Chemistry  (643)
  • Animals  (611)
  • Cell & Developmental Biology  (273)
  • 04.06. Seismology
  • Fisheries
  • 2020-2023  (55)
  • 1995-1999  (1.527)
  • 1945-1949
  • 2021  (55)
  • 1998  (1.527)
Sammlung
  • Artikel  (1.582)
Schlagwörter
Erscheinungszeitraum
Jahr
  • 1
    Publikationsdatum: 2022-03-16
    Beschreibung: In this work, we assess ground shaking in the wider Zagreb area by computing simulated seismograms at regional distances. For the purposes of the simulations, we assemble the 3D velocity and density model and test its performance. First, we compare the low-frequency simulations obtained using deterministic method for both new 3D model and a simple 1D model. We then continue the performance test by computing the full broadband seismo- grams. To do that, we apply the hybrid technique in which the low frequency (f〈1 Hz) and high frequency (f=1–10 Hz) seismograms are obtained separately using deterministic and stochastic method, respectively, and then reconciled into a single time series. We apply this method to the MW=5.3 event and four smaller (3.0〈MW〈5.0) events that occurred in the studied region. We compare simulated data with the recorded seismograms and vali- date our results by calculating the goodness of fit score for peak ground velocity and shak- ing duration. Next, to improve the understanding of the strong ground motion in this area, we simulate seismic shaking scenarios for the 1880, MW = 6.2 earthquake. From computed low-frequency waveforms, we generate shakemaps and compare the ground-motion fea- tures of the two possible sources of this event, Kašina fault and North Medvednica fault. We conduct a preliminary study to determine which fault is a more probable source of the 1880 historic event by comparing the peak ground velocities and Arias intensity with the observed intensities.
    Beschreibung: Croatian Science Foundation under the Project No. IP-2020-02-3960 European Commission, H2020 Excel- lence Science [ChEESE (Grant No. 823844)]
    Beschreibung: Published
    Beschreibung: 167–192
    Beschreibung: 1T. Struttura della Terra
    Beschreibung: 6T. Studi di pericolosità sismica e da maremoto
    Beschreibung: JCR Journal
    Schlagwort(e): Numerical simulation ; 3D ground motion ; Earthquake ; Central Croatia ; Zagreb ; Seismic wave propagation ; 3D crustal model ; 04.06. Seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 2
    Publikationsdatum: 2022-03-16
    Beschreibung: Data visualization, and to a lesser extent data sonification, are classic tools to the scientific community. However, these two approaches are very rarely combined, although they are highly complementary: our visual system is good at recognizing spatial patterns, whereas our auditory system is better tuned for temporal patterns. In this article, data representation methods are proposed that combine visualization, sonification, and spatial audio techniques, in order to optimize the user’s perception of spatial and temporal patterns in a single display, to increase the feeling of immersion, and to take advantage of multimodal integration mechanisms. Three seismic data sets are used to illustrate the methods, covering different physical phenomena, time scales, spatial distributions, and spatio-temporal dynamics. The methods are adapted to the specificities of each data set, and to the amount of information that the designer wants to display. This leads to further developments, namely the use of audification with two time scales, the switch from pure audification to time-modulated noise, and the switch from pure audification to sonic icons. First user feedback from live demonstrations indicates that the methods presented in this article seem to enhance the perception of spatio-temporal patterns, which is a key parameter to the understanding of seismically active systems, and a step towards apprehending the processes that drive this activity.
    Beschreibung: Published
    Beschreibung: 125–142
    Beschreibung: 7T. Variazioni delle caratteristiche crostali e "precursori"
    Beschreibung: JCR Journal
    Schlagwort(e): 04.06. Seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 3
    Publikationsdatum: 2022-03-25
    Beschreibung: Campi Flegrei caldera (Southern Italy) is one of the most hazardous volcanic complexes in the world since it is located inside the densely inhabited urban district of Naples-Pozzuoli. In the past, the caldera has produced devastating to moderate eruptions and periodically undergoes from strong to minor uplift episodes, named “bradyseism”, almost always accompanied by seismic swarms. Starting from 2005 Campi Flegrei has undergone an unrest crisis, characterized by ground uplift, localized gas emissions and seismicity, often occurring in seismic swarms. As a consequence, the monitoring activities have been progressively increasing, producing a huge amount of data, difficult to manage and match. GIS (Geographical Information System) represents a potent tool to manage great quantity of data, coming from different disciplines. In this study, we show two GIS technology applications to the seismic catalogue of Campi Flegrei. In the first one, a high-quality dataset is extracted from the GeoDatabase addressed to seismological studies that require high precision earthquake locations. In the second application, GIS are used to extract, visualize and analyse the typical seismic swarms of Campi Flegrei. Moreover, density and seismic moment distribution maps were generated for these swarms. In the last application, the GIS allow to highlight a clear variation in the temporal trend of the seismic swarms at Campi Flegrei.
    Beschreibung: This study has benefited from funding provided by the Italian Presidenza del Consiglio dei Ministri – Dipartimento della Protezione Civile.
    Beschreibung: Published
    Beschreibung: 131-144
    Beschreibung: 4V. Processi pre-eruttivi
    Beschreibung: 6SR VULCANI – Servizi e ricerca per la società
    Beschreibung: 1IT. Reti di monitoraggio e sorveglianza
    Beschreibung: N/A or not JCR
    Schlagwort(e): Campi Flegrei ; Seismic swams ; Seismic network ; GIS ; 04.06. Seismology ; 04.08. Volcanology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 4
    Publikationsdatum: 2021-11-29
    Beschreibung: The geological evolution of the western Mediterranean exhibits complicated interactions between orogenic processes and widespread extensional tectonics. The region is located in a convergent plate margin separating Africa and Europe, and consists of marine basins – the Alboran Sea, the Algerian- Provençal Basin, the Valencia trough, the Ligurian Sea and the Tyrrhenian Sea- which formed as back-arc basins since the Oligocene. In most reconstructions, it has been stressed that back-arc extension led to drifting of continental blocks and to large-scale block rotations. The opening of the Ligurian Sea. is in fact the result of counterclockwise rotation of Corsica and Sardinia. From the point of view of seismicity, the south western Alps and northern part of the Ligurian basin are subject to frequent earthquakes of low to moderate magnitudes. However significantly destructive events are known to have occurred in the past (e.g. 1564 and 1887). Apart from these rare large events, regional studies agree in concluding that the important local microseismicity appears to be poorly focused (e.g., COURBOULEX et alii, 2007) and that, if some tectonic lines are documented onland (COURBOULEX et alii, 2001), the active structures at sea remain unknown. It is therefore an essential prerequisite to gain better insight into the deep seismogenic structures along the North Ligurian margin and even farther offshore, in the identified oceanic domain. The fact that some of these structures can undergo ruptures of Mw~6.5, such as the 1887 event (BAKUN & SCOTTI, 2006), suggests that, at least to some extent, instrumental insufficiencies in the detection and location of microseismicity is a limit to identify active faults that have not experienced large instrumented ruptures to date. The irregular coverage provided by regional seismic networks produces a bias in the recording of local seismicity. Permanent stations are naturally limited to land areas and fail to properly constrain seismicity offshore. Taking into consideration the peculiarities of regional dynamics (low strain rates, rare large events and a regular seismic activity limited to small events with M 〈 3-4), even onshore seismicity is insufficiently covered by permanent networks and requires dense temporary instrumenting by mobile stations. Considering the potential threat of strong offshore earthquakes, it is of first importance to characterize faults that are prone to rupture in order to quantify associated seismic and tsunami hazards. Assuming some weak seismicity exists along these faults and remains undetected by onland networks, some marine stations are necessary to address instrumental remoteness and help delineate active structures. Moreover, since the velocity models used for locations are obtained by inverting seismic data and the reliability of their locations depend, in turn, from the quality of the velocity model used for their hypocentral parameters, the constraints on the seismic path provided by a more dense seismic network may contribute to a more accurate reference model. In this study, we profited from the recent developments in sea bottom seismic instrumentation to deploy OBSs above the zones of the North Ligurian to perform seismic shots and obtain the distribution of seismic velocities with 3D active tomography. We also took the opportunity of the long term (6 months) OBSs reduced array to decrease both the detection threshold and recording distances so as to obtain more complete catalogs and better localisations.
    Beschreibung: Published
    Beschreibung: 789-791
    Beschreibung: 1T. Struttura della Terra
    Beschreibung: N/A or not JCR
    Schlagwort(e): 04.01. Earth Interior ; 04.06. Seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 5
    Publikationsdatum: 2021-11-30
    Beschreibung: Historical seismic catalogs report that the Gargano Promontory (southern Italy) was affected in the past by earthquakes with medium to high estimated magnitude. From the instrumental seismicity, it can be identified that the most energetic Apulian sequence occurred in 1995 with a main shock of MW = 5.2 followed by about 200 aftershocks with a maximum magnitude of 3.7. The most energetic earthquakes of the past are attributed to right-lateral strike-slip faults, while there is evidence that the present-day seismicity occur on thrust or thrust-strike faults. In this article, we show a detailed study on focal mechanisms and stress field obtained by micro-seismicity recorded from April 2013 until the present time in the Gargano Promontory and surrounding regions. Seismic waveforms are collected from the OTRIONS Seismic Network (OSN), from the Italian National Seismic Network (RSN), and integrated with data from the Italian National Accelerometric Network (RAN) in order to provide a robust dataset of earthquake localizations and focal mechanisms. The effect of uncertainties of the velocity model on fault plane solutions (FPS) has been also evaluated indicating the robustness of the results. The computed stress field indicates a deep compressive faulting with maximum horizontal compressive stress, SHmax, trending NW-SE. The seismicity pattern analysis indicates that the whole crust is seismically involved up to a depth of 40 km and indicates the presence of a low-angle seismogenic surface trending SW-NE and dipping SE-NW, similar to the Gargano–Dubrovnik lineament. Shallower events, along the eastern sector of the Mattinata Fault (MF), are W-E dextral strike-slip fault. Therefore, we hypothesized that the seismicity is locally facilitated by preexisting multidirectional fractures, confirmed by the heterogeneity of focal mechanisms, and explained by the different reactivation processes in opposite directions over the time, involving the Mattinata shear zone.
    Beschreibung: Published
    Beschreibung: 589332
    Beschreibung: 4T. Sismicità dell'Italia
    Beschreibung: JCR Journal
    Schlagwort(e): Gargano promontory ; OTRIONS local seismic network ; focal mechanisms ; stress field ; microseismicity ; mattinata fault ; gargano-dubrovnik lineament ; 04.06. Seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 6
    Publikationsdatum: 2021-11-12
    Beschreibung: In this paper we describe the results of an experimental implementation of the recent guidelines issued by the Italian regulatory body for monitoring hydrocarbon production activities. In particular, we report about the pilot study on seismic, deformation, and pore pressure monitoring of the Mirandola hydrocarbon cultivation facility in Northern Italy. This site hosts the Cavone oil field that was speculated of possibly influencing the 2012 ML 5.8 Mirandola earthquake source. According to the guidelines, the monitoring center should analyse geophysical measurements related to seismicity, crustal deformation and pore pressure in quasi real-time (within 24–48 h). A traffic light system would then be used to regulate underground operations in case of detecting significant earthquakes (i.e., events with size and location included in critical ranges). For these 2-year period of guidelines experimentation, we analysed all different kinds of available data, and we tested the existence of possible relationship between their temporal trends. Despite the short time window and the scarce quantity of data collected, we performed the required analysis and extracted as much meaningful and statistically reliable information from the data. We discuss here the most important observations drawn from the monitoring results, and highlight the lessons learned by describing practical issues and limitations that we have encountered in carrying out the tasks as defined in the guidelines. Our main goal is to contribute to the discussion about how to better monitor the geophysical impact of this kind of anthropogenic activity. We point out the importance of a wider seismic network but, mostly, of borehole sensors to improve microseismic detection capabilities. Moreover, the lack of an assessment of background seismicity in an unperturbed situation -due to long life extraction activities- makes it difficult to get a proper picture of natural background seismic activity, which would be instead an essential reference information for a tectonically-active regions, such as Northern Italy.
    Beschreibung: “Convenzione tra il comune di San Possidonio e l’Istituto Nazionale di Geofisica e Vulcanologia -I.N.G.V.- per l’attuazione del monitoraggio nella concessione di coltivazione idrocarburi “Mirandola” finalizzata alla messa in opera di attività di monitoraggio di sperimentazione degli indirizzi e linee guida per i monitoraggi ILG ed assunzione funzioni di Struttura Preposta al Monitoraggio di cui all’art. 6 del Protocollo Operativo”
    Beschreibung: Published
    Beschreibung: 685300
    Beschreibung: 3SR TERREMOTI - Attività dei Centri
    Beschreibung: JCR Journal
    Schlagwort(e): Italian guidelines for monitoring industrial activities ; induced seismicity ; pore pressure monitoring ; deformation monitoring ; seismic monitoring ; 04.06. Seismology ; 05.09. Miscellaneous ; 04.02. Exploration geophysics ; 04.03. Geodesy
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 7
    Publikationsdatum: 2021-12-15
    Beschreibung: The analysis of how an earthquake is felt was addressed with the data provided by citizens through a website dedicated to the perception of earthquakes in Italy (Data and Resources). The analysis focused on the perception of earthquakes by observers inside both parked and moving cars. These situations were compared with outdoor ones. The felt percentage of each situation was quantified for epicentral distance ranges and European Macroseismic Scale (EMS) degree. One of the main findings was the greatest sensitivity to shaking for people inside parked cars due to resonance phenomena of the automobile–observer system. The distribution of the intensity of perception in the car was analyzed as a function of the hypocentral distance and the magnitude of the earthquake. It was possible to define the attenuation trends of these intensities. The comparison of these trends with those of the equations for estimation of response spectral ordinates allowed us to have an evaluation of the frequency values of the seismic waves that caused the vibrations felt, which were found to agree with the typical frequencies of the car–observer system, as highlighted by independent studies. The results of this analysis show the possibility to include the perception of the earthquake inside a parked and moving car among the diagnostics used in the definition of macroseismic intensity degree of the EMS.
    Beschreibung: Published
    Beschreibung: 2028–2035
    Beschreibung: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Beschreibung: 5SR TERREMOTI - Convenzioni derivanti dall'Accordo Quadro decennale INGV-DPC
    Beschreibung: JCR Journal
    Schlagwort(e): macroseismics ; questionnaires ; 04.06. Seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 8
    Publikationsdatum: 2021-12-13
    Beschreibung: Strategies for disaster risk reduction in volcanic areas are mostly driven by multidisciplinary analyses, which offer effective and complementary information on complex geomorphological and volcano-tectonic environments. For example, quantification of the offset at active faults and fissures is of paramount importance to shed light on the kinematics of zones prone to deformation and/or seismic activity. This provides key information for the assessment of seismic hazard, but also for the identification of conditions that may favor magma uprising and opening of eruptive fissures. Here we present the results of a study encompassing detailed geological, structural and seismological observations focusing on part of the NE Rift at Etna volcano (Italy). The area is situated at an elevation ranging between 2700 and 1900 m a.s.l. where harsh meteorological conditions and difficult logistics render classical field work a troublesome issue. In order to bypass these difficulties, high-resolution (2.8 cm) UAV survey has been recently completed. The survey highlights the presence of 250 extension fractures, 20 normal fault segments, and 54 eruptive fissures. The study allows us to quantify the kinematics at extensional fractures and normal faults, obtaining an extension rate of 1.9 cm/yr for the last 406 yr. With a total of 432 structural data collected by UAV along with SfM photogrammetry, this work also demonstrates the suitability of the application of such surveys for the monitoring of hazardous zone.
    Beschreibung: Published
    Beschreibung: online (vEGU21)
    Beschreibung: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Schlagwort(e): Etna ; stress and strain field ; active faults ; NE Rift ; volcano ; kinematics ; UAV survey ; multidisciplinary analysis ; 04.08. Volcanology ; 04.06. Seismology ; 04.07. Tectonophysics
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: Conference paper
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 9
    Publikationsdatum: 2021-12-15
    Beschreibung: We investigated the seismic fault structure and the rupture characteristics of the MW 6.6, 2 May 2020, Cretan Passage earthquake through tsunami data inverse modelling. Our results suggest a shallow crustal event with a reverse mechanism within the accretionary wedge rather than on the Hellenic Arc subduction interface. The study identifies two possible ruptures: a steeply sloping reverse splay fault and a back-thrust rupture dipping south, with a more prominent dip angle.
    Beschreibung: We present a source solution for the tsunami generated by the Mw 6.6 earthquake that occurred on 2 May 2020, about 80 km offshore south of Crete, in the Cretan Passage, on the shallow portion of the Hellenic Arc subduction zone (HASZ). The tide gauges recorded this local tsunami on the southern coast of Crete and Kasos island. We used Crete tsunami observations to constrain the geometry and orientation of the causative fault, the rupture mechanism, and the slip amount. We first modelled an ensemble of synthetic tsunami waveforms at the tide gauge locations, produced for a range of earthquake parameter values as constrained by some of the available moment tensor solutions. We allow for both a splay and a back-thrust fault, corresponding to the two nodal planes of the moment tensor solution. We then measured the misfit between the synthetic and the Ierapetra observed marigram for each source parameter set. Our results identify the shallow, steeply dipping back-thrust fault as the one producing the lowest misfit to the tsunami data. However, a rupture on a lower angle fault, possibly a splay fault, with a sinistral component due to the oblique convergence on this segment of the HASZ, cannot be completely ruled out. This earthquake reminds us that the uncertainty regarding potential earthquake mechanisms at a specific location remains quite significant. In this case, for example, it is not possible to anticipate if the next event will be one occurring on the subduction interface, on a splay fault, or on a back-thrust, which seems the most likely for the event under investigation. This circumstance bears important consequences because back-thrust and splay faults might enhance the tsunamigenic potential with respect to the subduction interface due to their steeper dip. Then, these results are relevant for tsunami forecasting in the framework of both the long-term hazard assessment and the early warning systems.
    Beschreibung: Published
    Beschreibung: 3713–3730
    Beschreibung: 8T. Sismologia in tempo reale e Early Warning Sismico e da Tsunami
    Beschreibung: JCR Journal
    Schlagwort(e): Tsunami, Mediterranean, Early Warning ; 04.06. Seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 10
    Publikationsdatum: 2021-12-16
    Beschreibung: A new analysis of high-resolution multibeam and seismic reflection data, collected during several oceanographic expeditions starting from 1999, allowed us to compile an updated morphotectonic map of the North Anatolian Fault below the Sea of Marmara. We reconstructed kinematics and geometries of individual fault segments, active at the time scale of 10 ka, an interval which includes several earthquake cycles, taking as stratigraphic marker the base of the latest marine transgression. Given the high deformation rates relative to sediment supply, most active tectonic structures have a morphological expression at the seafloor, even in presence of composite fault geometries and/or overprinting due to mass-wasting or turbidite deposits. In the frame of the right-lateral strike-slip domain characterizing the North Anatolian fault system, three types of deformation are observed: almost pure strike-slip faults, oriented mainly E–W; NE/SW-aligned axes of transpressive structures; NW/SE-oriented trans-tensional depressions. Fault segmentation occurs at different scales, but main segments develop alongthree major right-lateral oversteps, which delimit main fault branches, from east to west: (i) the transtensive Cinarcik segment; (ii) the Central (East and West) segments; and (iii) the westernmost Tekirdag segment. A quantitative morphometric analysis of the shallow deformation patterns observed by seafloor morphology maps and high-resolution seismic reflection profiles along the entire basin allowed to determine nature and cumulative lengths of individual fault segments. These data were used as inputs for empirical relationships, to estimate maximum expected Moment Magnitudes, obtaining values in the range of 6.8–7.4 for the Central, and 6.9–7.1 for the Cinarcik and Tekirdag segments, respectively. We discuss these findings considering analyses of historical catalogues and available paleoseismological studies for the Sea of Marmara regionto formulate reliable seismic hazard scenarios.
    Beschreibung: Published
    Beschreibung: 29–44
    Beschreibung: 6T. Studi di pericolosità sismica e da maremoto
    Beschreibung: N/A or not JCR
    Schlagwort(e): North Anatolian fault · ; Sea of Marmara ; Earthquakes ; Active fault segments ; Marine geophysics ; Seismic hazard ; 04.06. Seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 11
    Publikationsdatum: 2021-12-22
    Beschreibung: The Western Ionian Sea is characterised by an active and diffuse seismicity, directly related to the convergence of the European and African Plates and by gravitational sinking and rollback of the oceanic lithosphere. In this area, the location of earthquakes is characterised by considerable uncertainties due to large azimuthal gaps, resulting in notable location errors. This problem was partially overcome with the use of data recorded by NEMO-SN1 seafloor observatory (October 2002 - February 2003; June 2012 - May 2013). We relocated 1130 crustal and sub-crustal earthquakes using land network and NEMO-SN1 data. As most events occurred on Mt. Etna, we focused on 358 earthquakes in the offshore area and near the coasts of Sicily and Calabria. The use of the combined land-marine networks has improved the earthquake locations in terms of azimuthal GAP, as well as in horizontal and vertical errors. The comparison between locations performed with and without NEMO-SN1 data shows that differences in latitude, longitude and depths are more evident in the Western Ionian Sea and in the coast of Sicily, where values of the differences over 5 km correspond to structural heterogeneities. The increased number of seismic stations deployed on land from 2003 to 2012 did not influence the location of events occurring offshore, where NEMO-SN1 continued to be the distinctive tool in the location process. Moreover, the new 73 focal mechanisms computed with P-wave polarities from NEMO-SN1 and land stations are in agreement with the regional structural model, showing a prevalent normal, normal/oblique, and strike-slip kinematics. The similarity of two new focal solutions with the mechanisms of the main shock and aftershock of the 1990 earthquake demonstrates that the seismic structures are still active and potentially dangerous. The P-wave travel time residual analysis confirms the activity along the main structural alignments. A single point of observation in the Ionian Sea can significantly improve the quality of locations, giving an opportunity to focus on the seismogenic structures responsible for the occurrence of medium-to-high magnitude earthquakes.
    Beschreibung: Published
    Beschreibung: Se655
    Beschreibung: 1T. Struttura della Terra
    Beschreibung: JCR Journal
    Schlagwort(e): Earthquake location ; Focal mechanisms ; Tectonic and volcanic structures ; NEMO-SN1 seafloor observatory ; Ionian Sea ; 04. Solid Earth ; 04.06. Seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 12
    Publikationsdatum: 2021-12-22
    Beschreibung: Collapse of buildings, large-scale destruction and temporary abandonment of an area documented in archaeological reports provide evidence for a major earthquake in Segesta in north-western Sicily. This, and possibly a cluster of other earthquakes as recently well-documented at Selinunte (south-western), can be derived from archaeological data. These earthquakes are not included in the Italian seismic catalogues, but can be used to set constraints on the seismic risk of this area. Although western Sicily is a low seismic moment release region, characterized by sparse, low-moderate magnitude earthquakes, the occurrence of strong earthquakes in the past would instead suggest the investigated area as having a high seismic potential. The present study improves the knowledge of past earthquakes of this area, thus contributing to a more reliable characterization of seismic hazard.
    Beschreibung: Submitted
    Beschreibung: 4T. Sismicità dell'Italia
    Beschreibung: JCR Journal
    Schlagwort(e): historical earthquake ; archaeoseismology, ; buildings collapse ; western Sicily ; Segesta ; 04.06. Seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: manuscript
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 13
    Publikationsdatum: 2021-12-22
    Beschreibung: The comparison between crustal stress and surface strain azimuthal patterns has provided new insights into several complex tectonic settings worldwide. Here, we performed such a comparison for Egypt taking into account updated datasets of seismological and geodetic observations. In north-eastern Egypt, the stress field shows a fan-shaped azimuthal pattern with a WNW–ESE orientation on the Cairo region, which progressively rotated to NW–SE along the Gulf of Aqaba. The stress field shows a prevailing normal faulting regime, however, along the Sinai/Arabia plate boundary it coexists with a strike–slip faulting one (σ1 ≅ σ2 〉 σ3), while on the Gulf of Suez, it is characterized by crustal extension occurring on near-orthogonal directions (σ1 〉 σ2 ≅ σ3). On the Nile Delta, the maximum horizontal stress (SHmax) pattern shows scattered orientations, while on the Aswan region, it has a WNW–ESE strike with pure strike–slip features. The strain-rate field shows the largest values along the Red Sea and the Sinai/Arabia plate boundary. Crustal stretching (up to 40 nanostrain/yr) occurs on these areas with WSW–ENE and NE–SW orientations, while crustal contraction occurs on northern Nile Delta (10 nanostrain/yr) and offshore (~35 nanostrain/yr) with E–W and N–S orientations, respectively. The comparison between stress and strain orientations over the investigated area reveals that both patterns are near-parallel and driven by the same large-scale tectonic processes.
    Beschreibung: This research was partially funded by the Programa Operativo FEDER Andalucía 2014-2020—A call made by the University of Jaén 2018.
    Beschreibung: Published
    Beschreibung: 1398
    Beschreibung: 2T. Deformazione crostale attiva
    Beschreibung: JCR Journal
    Schlagwort(e): strain ; stress ; GNSS ; Egypt ; 04.03. Geodesy ; 04. Solid Earth ; 04.06. Seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 14
    Publikationsdatum: 2021-12-23
    Beschreibung: A comparative analysis of geodetic versus seismic moment-rate estimations makes it possible to distinguish between seismic and aseismic deformation, define the style of deformation, and also to reveal potential seismic gaps. This analysis has been performed for Egypt where the present-day tectonics and seismicity result from the long-lasting interaction between the Nubian, Eurasian, and Arabian plates. The data used comprises all available geological and tectonic information, an updated Poissonian earthquake catalog (2200 B.C.–2020 A.D.) including historical and instrumental datasets, a focal-mechanism solutions catalog (1951–2019), and crustal geodetic strains from Global Navigation Satellite System (GNSS) data. The studied region was divided into ten (EG-01 to EG-10) crustal seismic sources based mainly on seismicity, focal mechanisms, and geodetic strain characteristics. The delimited seismic sources cover the Gulf of Aqaba–Dead Sea Transform Fault system, the Gulf of Suez–Red Sea Rift, besides some potential seismic active regions along the Nile River and its delta. For each seismic source, the estimation of seismic and geodetic moment-rates has been performed. Although the obtained results cannot be considered to be definitive, among the delimited sources, four of them (EG-05, EG-06, EG-08, and EG-10) are characterized by low seismic-geodetic moment-rate ratios (〈20%), reflecting a prevailing aseismic behavior. Intermediate moment-rate ratios (from 20% to 60%) have been obtained in four additional zones (EG-01, EG-04, EG-07, and EG-09), evidencing how the seismicity accounts for a minor to a moderate fraction of the total deformational budget. In the other two sources (EG-02 and EG-03), high seismic-geodetic moment-rates ratios (〉60%) have been observed, reflecting a fully seismic deformation
    Beschreibung: This research has been partially funded in the frame of the Programa Operativo FEDER Andalucía 2014–2020-call made by the University of Jaén, 2018.
    Beschreibung: Published
    Beschreibung: 7836
    Beschreibung: 2T. Deformazione crostale attiva
    Beschreibung: JCR Journal
    Schlagwort(e): Seismicity ; GNSS ; Strain ; seismic hazard ; Egypt ; 04. Solid Earth ; 04.03. Geodesy ; 04.06. Seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 15
    Publikationsdatum: 2021-12-23
    Beschreibung: Infrasonic signals investigation plays a fundamental role for both volcano monitoring purpose and the study of the explosion dynamics. Proper and reliable detection of weak signals is a critical issue in active volcano monitoring. In particular, in volcanic acoustics, it has direct consequences in pinpointing the real number of generated events (amplitude transients), especially when they exhibit low amplitude, are close in time to each other, and/or multiple sources exist. To accomplish this task, several algorithms have been proposed in literature; in particular, to overcome limitations of classical approaches such as short-time average/long-time average and cross-correlation detector, in this paper a subspace-based detection technique has been implemented. Results obtained by applying subspace detector on real infrasound data highlight that this method allows sensitive detection of lower energy events. This method is based on a projection of a sliding window of signal buffer onto a signal subspace that spans a collection of reference signals, representing similar waveforms from a particular infrasound source. A critical point is related to subspace design. Here, an empirical procedure has been applied to build the signal subspace from a set of reference waveforms (templates). In addition, in order to determine detectors parameters, such as subspace dimension and detection threshold, even in presence of overlapped noise such as infrasonic tremor, a statistical analysis of noise has been carried out. Finally, the subspace detector reliability and performance, have been assessed by performing a comparison among subspace approach, cross correlation detector and short-time average/long-time average detector. The obtained confusion matrix and extrapolated performance indices have demonstrated the potentiality, the advantages and drawbacks of the subspace method in tracking volcanic activity producing infrasound events. This method revealed to be a good compromise in detecting low-energy and very close in time events recorded during Strombolian activity
    Beschreibung: Published
    Beschreibung: 579923
    Beschreibung: 5V. Processi eruttivi e post-eruttivi
    Beschreibung: JCR Journal
    Schlagwort(e): infrasound signal ; trigger algorithm ; infrasound volcano monitoring ; strombolian activity ; etna volcano ; infrasonic tremor ; subspace detector ; infrasound events ; solid earth ; 04.08. Volcanology ; 04.06. Seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 16
    Publikationsdatum: 2021-12-22
    Beschreibung: The earthquake of May 24th, 2008, occurred in the municipality of Quetame (Colombia), is a recent event detected by the RSNC and the World Seismological Network, which reported their seismological parameters: epicenter, depth, magnitude, scalar seismic moment and focal mechanism, among others. Based on the damages and effects caused, INGEOMINAS (Colombian Geological Survey) evaluated the macroseismic field, preparing the map of intensities with data in various populations of the departments of Cundinamarca, Tolima and Meta, mainly. Based on this macroseismic information, in this work some macroseismic analysis methods are applied to obtain the corresponding focal parameters. The results show strong correlations or similarities between instrumental and macroseismic parameters. Instrumentally reported: Epicenter 4.4°N and 73.81°W; h=14.7 km, 5.9 Mw, 5.9 Ms, 5.6 mb, 5.7 ML; M0=7.95*1024 dynes-cm. While macroseismically it was obtained: Epicenter 4.34°N and 73.86°W; 5.94 Mw, 5.5 Ms, 5.6±0.2 mb, 5.63 ML; hn=12.1 km, hl=2.23 km; E=4.57*1020 erg, M0=9.14*1024 dynes-cm; the parameters of the dimensions of the seismic focus and the seismotectonic deformation expressed by the seismic flow of the rock mass were also determined. The applied procedures show the character of complementarity between instrumental and macroseismic data.
    Beschreibung: Published
    Beschreibung: 163-184
    Beschreibung: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Beschreibung: JCR Journal
    Schlagwort(e): earthquakes ; focal parameters ; macroseismic ; 04.06. Seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 17
    Publikationsdatum: 2021-11-17
    Beschreibung: The geographic distribution of earthquake effects quantified in terms of macroseismic intensities, the so-called macroseismic field, provides basic information for several applications including source characterization of pre-instrumental earthquakes and risk analysis. Macroseismic fields of past earthquakes as inferred from historical documentation may present spatial gaps, due to the incompleteness of the available information. We present a probabilistic approach aimed at integrating incomplete intensity distributions by considering the Bayesian combination of estimates provided by intensity prediction equations (IPEs) and data documented at nearby localities, accounting for the relevant uncertainties and the discrete and ordinal nature of intensity values. The performance of the proposed methodology is tested at 28 Italian localities with long and rich seismic histories and for two well-known strong earthquakes (i.e., 1980 southern Italy and 2009 central Italy events). A possible application of the approach is also illustrated relative to a 16th-century earthquake in the northern Apennines.
    Beschreibung: Published
    Beschreibung: 2299–2311
    Beschreibung: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Beschreibung: JCR Journal
    Schlagwort(e): 04.06. Seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 18
    Publikationsdatum: 2021-12-01
    Beschreibung: Ischia is a densely inhabited and touristic volcanic island located in the northern sector of the Gulf of Naples (Italy). In 2017, the Mw 3.9 Casamicciola earthquake occurred after more than one century of seismic quiescence characterized only by minor seismicity, which followed a century with three destructive earthquakes (in 1828, 1881, and 1883). These events, despite their moderate magnitude (Mw 〈 5.5), lead to dreadful effects on buildings and population. However, an integrated catalogue systematically covering historical and instrumental seismicity of Ischia has been still lacking since many years. Here, we review and systematically re-analyse all the available data on the historical and instrumental seismicity, to build an integrated earthquake catalogue for Ischia with a robust characterization of existing uncertainties. Supported by new or updated macroseismic datasets, we significantly enriched existing catalogues, as the Italian Parametric Earthquake Catalogue (CPTI15) that, with this analysis, passed from 12 to 57 earthquakes with macroseismic parametrization. We also extended back by 6 years the coverage of the instrumental catalogue, homogenizing the estimated seismic parameters. The obtained catalogue will not only represent a solid base for future local hazard quantifications, but also it provides the unique opportunity of characterizing the evolution of the Ischia seismicity over centuries. To this end, we analyse the spatial, temporal, and magnitude distributions of Ischia seismicity, revealing for example that, also in the present long-lasting period of volcanic quiescence, is significantly non-stationary and characterized by a b-value larger than 1.
    Beschreibung: This work benefited of the agreement between Istituto Nazionale di Geofisica e Vulcanologia and the Italian Presidenza del Consiglio dei Ministri, Dipartimento della Protezione Civile (DPC).
    Beschreibung: Published
    Beschreibung: 629736
    Beschreibung: 4T. Sismicità dell'Italia
    Beschreibung: 6SR VULCANI – Servizi e ricerca per la società
    Beschreibung: 1IT. Reti di monitoraggio e sorveglianza
    Beschreibung: 4IT. Banche dati
    Beschreibung: JCR Journal
    Schlagwort(e): Ischia island ; Volcano seismicity ; Seismic catalogue ; Completeness analysis ; Ensemble modelling ; Frequency size distribution ; Poisson process ; 04.06. Seismology ; 04.08. Volcanology ; 05.02. Data dissemination ; 05.04. Instrumentation and techniques of general interest
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 19
    Publikationsdatum: 2021-12-24
    Beschreibung: This article has been accepted for publication in Geophysical Journal International ©: The Authors 2021. Published by Oxford University Press on behalf of the Royal Astronomical Society. All rights reserved. Uploaded in accordance with the publisher's self-archiving policy.
    Beschreibung: Ambient-noise records from the AlpArray network are used to measure Rayleigh wave phase velocities between more than 150,000 station pairs. From these, azimuthally anisotropic phase-velocity maps are obtained by applying the Eikonal tomography method. Several synthetic tests are shown to study the bias in the Ψ2 anisotropy. There are two main groups of bias, the first one caused by interference between refracted/reflected waves and the appearance of secondary wavefronts that affect the phase travel-time measurements. This bias can be reduced if the amplitude field can be estimated correctly. Another source of error is related to the incomplete reconstruction of the travel-time field that is only sparsely sampled due to the receiver locations. Both types of bias scale with the magnitude of the velocity heterogeneities. Most affected by the spurious Ψ2 anisotropy are areas inside and at the border of low-velocity zones. In the isotropic velocity distribution, most of the bias cancels out if the azimuthal coverage is good. Despite the lack of resolution in many parts of the surveyed area, we identify a number of anisotropic structures that are robust: in the central Alps, we find a layered anisotropic structure, arc-parallel at midcrustal depths and arc-perpendicular in the lower crust. In contrast, in the eastern Alps, the pattern is more consistently E-W oriented which we relate to the eastward extrusion. The northern Alpine forleand exhibits a preferential anisotropic orientation that is similar to SKS observations in the lowermost crust and uppermost mantle.
    Beschreibung: German Science Foundation (SPP-2017, Project Ha 2403/21-1); Swiss National Science Foundation SINERGIA Project CRSII2-154434/1 (Swiss-AlpArray); Progetto Pianeta Dinamico, finanziamento MUR-INGV, Task S2 – 2021
    Beschreibung: Published
    Beschreibung: 151–170
    Beschreibung: 1T. Struttura della Terra
    Beschreibung: JCR Journal
    Schlagwort(e): Seismic anisotropy ; Seismic interferometry ; Seismic tomography ; Wave propagation ; Continental tectonics: compressional ; 04.01. Earth Interior ; 04.06. Seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 20
    Publikationsdatum: 2021-12-14
    Beschreibung: We present results from a joint inversion of new seismic and recently compiled gravity data to constrain the structure of a prominent geophysical anomaly in the European Alps: the Ivrea Geophysical Body (IGB). We investigate the IGB structure along the West-East oriented Val Sesia profile at higher resolution than previous studies. We deployed 10 broadband seismic stations at 5 km spacing for 27 months, producing a new database of ∼1000 high-quality seismic receiver functions (RFs). The compiled gravity data yields 1 gravity point every 1–2 km along the profile. We set up an inversion scheme, in which RFs and gravity anomalies jointly constrain the shape and the physical properties of the IGB. We model the IGB’s top surface as a single density and shear-wave velocity discontinuity, whose geometry is defined by four, spatially variable nodes between far-field constraints. An iterative algorithm was implemented to efficiently explore the model space, directing the search toward better fitting areas. For each new candidate model, we use the velocity-model structures for both ray-tracing and observed-RFs migration, and for computation and migration of synthetic RFs: the two migrated images are then compared via cross-correlation. Similarly, forward gravity modeling for a 2D density distribution is implemented. The joint inversion performance is the product of the seismic and gravity misfits. The inversion results show the IGB protruding at shallow depths with a horizontal width of ∼30 km in the western part of the profile. Its shallowest segment reaches either 3–7 or 1–3 km depth below sea-level. The latter location fits better the outcropping lower crustal rocks at the western edge of the Ivrea-Verbano Zone. A prominent, steep eastward-deepening feature near the middle of the profile, coincident with the Pogallo Fault Zone, is interpreted as inherited crustal thickness variation. The found density and velocity contrasts of the IGB agree with physical properties of the main rock units observed in the field. Finally, by frequency-dependent analysis of RFs, we constrain the sharpness of the shallowest portion of the IGB velocity discontinuity as a vertical gradient of thickness between 0.8 km and 0.4 km.
    Beschreibung: The Swiss National Science Foundation (SNF) supported this research (grant numbers PP00P2_157627 and PP00P2_187199 of project OROG3NY), as well as the Grant Agency of the Czech Republic (No. 21-25710). The project CzechGeo/EPOS No. LM2015079 of the MEYS funded the MOBNET station pool.
    Beschreibung: Published
    Beschreibung: 671412
    Beschreibung: 1T. Struttura della Terra
    Beschreibung: JCR Journal
    Schlagwort(e): joint inversion ; seismic receiver functions ; gravity anomalies ; Ivrea Geophysical Body ; Ivrea-Verbano Zone ; continental crust ; intra-crustal structure ; 04.01. Earth Interior ; 04.06. Seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 21
    Publikationsdatum: 2021-12-13
    Beschreibung: The present paper describes the process of moving from a research study of most common vulnerable non-structural elements, to deliver solutions, tools and guidelines to improve understanding of and responsiveness to community concerns about seismic risk and non-structural elements. The observed damage to non-structural elements following recent earthquakes in Italy, Portugal and Iceland, were used for designing communication tools under the KnowRISK EU project for multi-stakeholders (students, business and citizens): the Practical Guide, the Students Short Guide, the KnowRISK Portfolio of Solutions, the Move, Protect and Secure video, the augmented reality apps, the maquettes, the students notebooks, videos, board games and hands-on tools. The philosophy behind these deliverables is that some risks, once identified, can be eliminated or reduced by informing people and suggesting preventive or emergency measures. These tools are devoted to improving the seismic performance of non-structural elements and to reduce the associated economic losses, loss of functionality, and potential threats to life safety. The rationale behind the selection of the information that people need to know for converting knowledge to more safety is discussed and a description of the transference of the findings of research to communication solutions is presented. The tools were planned following the engagement-model in risk communication to ensure that needs of communities and selected stakeholders were acknowledged, and that recipients are addressed in a way that appeals to them. Different media and communication channels such as print, television, online, face-to face communication and interviews were used for risk communication.
    Beschreibung: This study was co-financed by the European Commission’s Humanitarian Aid and Civil Protection (Grant agreement ECHO/SUB/2015/718655/PREV28).
    Beschreibung: Published
    Beschreibung: SE322
    Beschreibung: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Beschreibung: JCR Journal
    Schlagwort(e): Seismic risk ; seismic damage ; non-structural damage ; preventative measures ; risk awareness ; 04.06. Seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 22
    Publikationsdatum: 2021-12-15
    Beschreibung: This article has been accepted for publication in Geophysical Journal International ©: The Authors 2022. Published by Oxford University Press on behalf of the Royal Astronomical Society. All rights reserved. Uploaded in accordance with the publisher's self-archiving policy.
    Beschreibung: To understand the seismotectonics and the seismic hazard of the study sector of the Northern Apennines (Italy), one of the most important earthquakes of magnitude Mw = 6.5 which struck the Lunigiana and Garfagnana areas (Tuscany) on 7 September 1920 should be studied. Given the early instrumental epoch of the event, neither geometric and kinematic information on the fault-source nor its fault-plane solution were available. Both areas were candidates for hosting the source fault and there was uncertainty between a normal fault with Apenninic direction or an anti-Apenninic strike-slip. We retrieved 11 focal parameters (including the fault-plane solution) of the 1920 earthquake. Only macroseismic intensity information (from 499 inhabited centres) through the KF-NGA inversion technique was used. This technique uses a Kinematic model of the earthquake source and speeds up the calculation by a Genetic Algorithm with Niching. The result is a pure dip-slip focal solution. The intrinsic ambiguities of the KF-NGA method (±180° on the rake angle; choice of the fault plane between the two nodal planes) were solved with field and seismotectonic evidence. The earthquake was generated by a normal fault (rake angle = 265° ± 8°) with an Apennine direction (114° ± 5°) and dipping 38° ± 6° towards SW. The likely candidate for hosting the source-fault in 1920 is the Compione-Comano fault that borders the NE edge of the Lunigiana graben. The KF-NGA algorithm proved to be invaluable for studying the kinematics of early instrumental earthquakes and allowed us to uniquely individuate, for the first time ever, the seismogenic source of the 1920 earthquake. Our findings have implications in hazard computation and seismotectonic contexts.
    Beschreibung: Published
    Beschreibung: 1465–1477
    Beschreibung: 4T. Sismicità dell'Italia
    Beschreibung: JCR Journal
    Schlagwort(e): Inverse theory ; Body waves ; Earthquake source observations ; Seismicity and tectonics ; Dynamics: seismotectonics ; Fractures, faults, and high strain deformation zones ; 04.06. Seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 23
    Publikationsdatum: 2022-01-13
    Beschreibung: Istituto Nazionale di Geofisica e Vulcanologia
    Beschreibung: Published
    Beschreibung: 2T. Deformazione crostale attiva
    Beschreibung: 4T. Sismicità dell'Italia
    Beschreibung: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Beschreibung: 6T. Studi di pericolosità sismica e da maremoto
    Beschreibung: 4IT. Banche dati
    Schlagwort(e): Seismogenic Source ; Active Fault ; Active Fault System ; 04.04. Geology ; 04.06. Seismology ; 04.07. Tectonophysics
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: web product
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 24
    Publikationsdatum: 2021-11-26
    Beschreibung: Seismicity-based earthquake forecasting models have been primarily studied and developed over the past twenty years. These models mainly rely on seismicity catalogs as their data source and provide forecasts in time, space, and magnitude in a quantifiable manner. In this study, we presented a technique to better determine future earthquakes in space based on spatially smoothed seismicity. The improvement’s main objective is to use foreshock and aftershock events together with their mainshocks. Time-independent earthquake forecast models are often developed using declustered catalogs, where smaller-magnitude events regarding their mainshocks are removed from the catalog. Declustered catalogs are required in the probabilistic seismic hazard analysis (PSHA) to hold the Poisson assumption that the events are independent in time and space. However, as highlighted and presented by many recent studies, removing such events from seismic catalogs may lead to underestimating seismicity rates and, consequently, the final seismic hazard in terms of ground shaking. Our study also demonstrated that considering the complete catalog may improve future earthquakes’ spatial forecast. To do so, we adopted two different smoothed seismicity methods: (1) the fixed smoothing method, which uses spatially uniform smoothing parameters, and (2) the adaptive smoothing method, which relates an individual smoothing distance for each earthquake. The smoothed seismicity models are constructed by using the global earthquake catalog with Mw ≥ 5.5 events. We reported progress on comparing smoothed seismicity models developed by calculating and evaluating the joint log-likelihoods. Our resulting forecast shows a significant information gain concerning both fixed and adaptive smoothing model forecasts. Our findings indicate that complete catalogs are a notable feature for increasing the spatial variation skill of seismicity forecasts.
    Beschreibung: Published
    Beschreibung: 10899
    Beschreibung: 6T. Studi di pericolosità sismica e da maremoto
    Beschreibung: JCR Journal
    Schlagwort(e): seismic hazard ; Smoothed Seismicity Approach ; global seismic catalog ; aftershocks ; 04.06. Seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 25
    Publikationsdatum: 2021-11-25
    Beschreibung: Ambient noise polarizes inside fault zones, yet the spatial and temporal resolution of polarized noise on gas-bearing fluids migrating through stressed volcanic systems is unknown. Here we show that high polarization marks a transfer structure connecting the deforming centre of the caldera to open hydrothermal vents and extensional caldera-bounding faults during periods of low seismic release at Campi Flegrei caldera (Southern Italy). Fluids pressurize the Campi Flegrei hydrothermal system, migrate, and increase stress before earthquakes. The loss of polarization (depolarization) of the transfer and extensional structures maps pressurized fluids, detecting fluid migrations after seismic sequences. After recent intense seismicity (December 2019-April 2020), the transfer structure appears sealed while fluids stored in the east caldera have moved further east. Our findings show that depolarized noise has the potential to monitor fluid migrations and earthquakes at stressed volcanoes quasi-instantaneously and with minimum processing.
    Beschreibung: Published
    Beschreibung: 6656
    Beschreibung: 4V. Processi pre-eruttivi
    Beschreibung: JCR Journal
    Schlagwort(e): Campi Flegrei ; seismic noise ; polarization ; fluid migration ; 04.06. Seismology ; 04.08. Volcanology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 26
    Publikationsdatum: 2021-12-23
    Beschreibung: The SW Iberian margin is one of the most seismogenic and tsunamigenic areas in W-Europe, where large historical and instrumental destructive events occurred. To evaluate the sensitivity of the tsunami impact on the coast of SW Iberia and NW Morocco to the fault geometry and slip distribution for local earthquakes, we carried out a set of tsunami simulations considering some of the main known active crustal faults in the region: the Gorringe Bank (GBF), Marquês de Pombal (MPF), Horseshoe (HF), North Coral Patch (NCPF) and South Coral Patch (SCPF) thrust faults, and the Lineament South strike-slip fault. We started by considering for all of them relatively simple planar faults featuring with uniform slip distribution; we then used a more complex 3D fault geometry for the faults constrained with a large 2D multichannel seismic dataset (MPF, HF, NCPF, and SCPF); and finally, we used various heterogeneous slip distributions for the HF. Our results show that using more complex 3D fault geometries and slip distributions, the peak wave height at the coastline can double compared to simpler tsunami source scenarios from planar fault geometries. Existing tsunami hazard models in the region use homogeneous slip distributions on planar faults as initial conditions for tsunami simulations and therefore underestimate tsunami hazard. Complex 3D fault geometries and non-uniform slip distribution should be considered in future tsunami hazard updates. The tsunami simulations also support the finding that submarine canyons attenuate the wave height reaching the coastline, while submarine ridges and shallow shelves have the opposite effect.
    Beschreibung: Published
    Beschreibung: e2021JB022127
    Beschreibung: 2T. Deformazione crostale attiva
    Beschreibung: 6T. Studi di pericolosità sismica e da maremoto
    Beschreibung: 2TR. Ricostruzione e modellazione della struttura crostale
    Beschreibung: 2IT. Laboratori analitici e sperimentali
    Beschreibung: JCR Journal
    Schlagwort(e): tsunami ; earthquake ; complex fault geometry ; heterogeneous slip distribution ; tsunami numerical modeling ; seismic and tsunami hazard ; 04.04. Geology ; 04.06. Seismology ; 05.08. Risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 27
    Publikationsdatum: 2021-12-14
    Beschreibung: The Italian earthquake waveform data are collected here in a dataset suited for machine learning analysis (ML) applications. The dataset consists of nearly 1.2 million three-component (3C) waveform traces from about 50 000 earthquakes and more than 130 000 noise 3C waveform traces, for a total of about 43 000 h of data and an average of 21 3C traces provided per event. The earthquake list is based on the Italian Seismic Bulletin (http://terremoti.ingv.it/bsi, last access: 15 February 2020​​​​​​​) of the Istituto Nazionale di Geofisica e Vulcanologia between January 2005 and January 2020, and it includes events in the magnitude range between 0.0 and 6.5. The waveform data have been recorded primarily by the Italian National Seismic Network (network code IV) and include both weak- (HH, EH channels) and strong-motion (HN channels) recordings. All the waveform traces have a length of 120 s, are sampled at 100 Hz, and are provided both in counts and ground motion physical units after deconvolution of the instrument transfer functions. The waveform dataset is accompanied by metadata consisting of more than 100 parameters providing comprehensive information on the earthquake source, the recording stations, the trace features, and other derived quantities. This rich set of metadata allows the users to target the data selection for their own purposes. Much of these metadata can be used as labels in ML analysis or for other studies. The dataset, assembled in HDF5 format, is available at http://doi.org/10.13127/instance (Michelini et al., 2021).
    Beschreibung: Published
    Beschreibung: 5509–5544
    Beschreibung: 4T. Sismicità dell'Italia
    Beschreibung: JCR Journal
    Schlagwort(e): 04.06. Seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 28
    Publikationsdatum: 2022-10-26
    Beschreibung: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Kourantidou, M., Hoagland, P., Dale, A., & Bailey, M. Equitable allocations in northern fisheries: bridging the divide for Labrador Inuit. Frontiers in Marine Science, 8, (2021): 590213, https://doi.org/10.3389/fmars.2021.590213.
    Beschreibung: Canada has undertaken commitments to recognize the rights of Indigenous Peoples in fisheries through policies and agreements, including Integrated Fishery Management Plans, the Reconciliation Strategy, and Land Claim Agreements (LCAs). In addition to recognizing rights, these commitments were intended to respect geographic adjacency principles, to enhance the economic viability of Indigenous communities, and to be reflective of community dependence on marine resources. We examined the determinants of quota allocations in commercial fisheries involving Nunatsiavut, Northern Labrador, the first self-governing region for the Inuit peoples in Canada. It has been argued that current fishery allocations for Nunatsiavut Inuit have not satisfied federal commitments to recognize Indigenous rights. Indicators that measure equity in commercial allocations for the turbot or Greenland halibut (Reinhardtius hippoglossoides) and northern shrimp (Pandalus borealis) fisheries were identified and assessed. In these two cases, historical allocations continue to predominate for allocations based upon equity or other social or economic considerations. We illustrate equity-enhancing changes in the quota distribution under scenarios of different levels of inequality aversion, and we make qualitative assessments of the effects of these allocations to Nunatsiavut for socioeconomic welfare. This approach could benefit fisheries governance in Northern Labrador, where federal commitments to equity objectives continue to be endorsed but have not yet been integrated fully into quota allocations.
    Beschreibung: This research was undertaken with funding from the Canada First Research Excellence Fund through the Ocean Frontier Institute (MK and MB) and the Johnson Endowment of the Woods Hole Oceanographic Institution’s (WHOI) Marine Policy Center (PH).
    Schlagwort(e): Fisheries ; Allocations ; Equity ; Indigenous rights ; Access
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 29
    facet.materialart.
    Unbekannt
    In:  aqdchief@seafdec.org.ph | http://aquaticcommons.org/id/eprint/18569 | 2002 | 2015-11-15 16:06:30 | 18569 | Southeast Asian Fisheries Development Center, Aquaculture Department
    Publikationsdatum: 2022-08-02
    Beschreibung: This paper summarizes the results of the experiments on the induced breeding and larval rearing of milkfish (Chanos chanos) during the 1979 season. Milkfish larvae could be reared successfully without the use of trochophore larvae of oysters as feed during the first few days. In order to induce the ovulation of wild adult milkfish a higher dose of human chorionic gonadotropin hormone is required.
    Schlagwort(e): Fisheries ; Chanos chanos ; ISEW ; Philippines ; marine environment ; Brood stocks ; Fish culture ; Fish larvae ; Food organisms ; Induced breeding ; Larval development ; Sex hormones
    Repository-Name: AquaDocs
    Materialart: article
    Format: application/pdf
    Format: application/pdf
    Format: 1-3
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 30
    facet.materialart.
    Unbekannt
    In:  library@seafdec.org.ph | http://aquaticcommons.org/id/eprint/20100 | 17342 | 2016-02-24 22:18:26 | 20100 | Southeast Asian Fisheries Development Center, Aquaculture Department
    Publikationsdatum: 2022-08-02
    Beschreibung: An outline is given of aquaculture and fisheries in Asia, providing information of use to students whose work can influence laws, rules, policy and regulations on aquaculture and fisheries, with the view in mind to sustainable aquaculture. In this issue, the following countries are examined: China, Indonesia, and Bangladesh.
    Schlagwort(e): Aquaculture ; Fisheries ; Fishery management ; Aquaculture development ; Aquaculture regulations ; Marine aquaculture ; Freshwater aquaculture ; Fishery industry ; Asia ; Bangladesh ; China
    Repository-Name: AquaDocs
    Materialart: article
    Format: application/pdf
    Format: application/pdf
    Format: 7-8
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 31
    facet.materialart.
    Unbekannt
    In:  library@seafdec.org.ph | http://aquaticcommons.org/id/eprint/20067 | 2002 | 2016-03-04 15:16:24 | 20067 | Southeast Asian Fisheries Development Center, Aquaculture Department
    Publikationsdatum: 2022-08-02
    Schlagwort(e): Fisheries ; Aquaculture ; Vietnam ; Sri Lanka ; Sri Lanka ; Vietnam ; brackishwater environment ; freshwater environment ; marine environment ; Aquaculture ; Aquaculture techniques ; Brackishwater aquaculture ; Feed ; Fish culture ; Fish diseases ; Fisheries ; Fishery data ; Food organisms ; Freshwater aquaculture ; Marine aquaculture ; Marine fisheries ; Mollusc culture ; Pond culture ; Seaweed culture ; Shrimp culture
    Repository-Name: AquaDocs
    Materialart: article
    Format: application/pdf
    Format: application/pdf
    Format: pp.9-10, 27
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 32
    facet.materialart.
    Unbekannt
    In:  library@seafdec.org.ph | http://aquaticcommons.org/id/eprint/20055 | 2002 | 2016-03-03 11:33:32 | 20055 | Southeast Asian Fisheries Development Center, Aquaculture Department
    Publikationsdatum: 2022-08-02
    Schlagwort(e): Fisheries ; Aquaculture ; Asia ; Cambodia ; India ; Asia ; Cambodia ; India ; Myanmar ; Myanmar ; brackishwater environment ; freshwater environment ; marine environment ; Aquaculture ; Aquaculture development ; Aquaculture economics ; Aquaculture techniques ; Brackishwater aquaculture ; Catching methods ; Culture effects ; Environmental impact ; Fish culture ; Fisheries ; Fishery development ; Fishery resources ; Fishery statistics ; Freshwater aquaculture ; Marine aquaculture ; Shrimp culture ; Sustainability ; Trade
    Repository-Name: AquaDocs
    Materialart: article
    Format: application/pdf
    Format: application/pdf
    Format: pp.9-10, 29
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 33
    facet.materialart.
    Unbekannt
    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26291 | 23782 | 2019-04-08 09:42:05 | 26291 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publikationsdatum: 2022-08-02
    Schlagwort(e): Fisheries ; Pollution ; Indonesia ; Heavy metals ; Chemical pollution ; Pollution monitoring
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 10-19
    Format: 10
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 34
    facet.materialart.
    Unbekannt
    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26293 | 23782 | 2019-03-22 03:49:21 | 26293 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publikationsdatum: 2022-08-02
    Schlagwort(e): Fisheries ; Myanmar ; Heavy metals ; Cadmium ; Lead ; Mercury ; Biological sampling ; Fish ; Fishery products ; Seafood
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 38-46
    Format: 9
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 35
    facet.materialart.
    Unbekannt
    Secretariat, Southeast Asian Fisheries Development Center | Bangkok, Thailand
    In:  http://aquaticcommons.org/id/eprint/26259 | 2002 | 2019-03-01 05:56:06 | 26259 | Southeast Asian Fisheries Development Center, Secretariat
    Publikationsdatum: 2022-08-02
    Beschreibung: Round scad exploration by purse seine in the waters of western Philippines was conducted from April 22 to May 7, 1998 for a period of five (5) fishing days with a total catch of 7.3 tons and an average of 1.5 tons per setting. Dominant species caught were Decapterus spp. having 70.09% of the total catch, followed by Selar spp. at 12.66% and Rastrelliger spp. 10.70%. Among the Decapterus spp. caught, D. macrosoma attained the highest total catch composition by species having 68.81% followed by D. kurroides and D.russelli with 0.31% and 1.14% respectively. The round scad fishery stock was composed mainly of juvenile fish (less than 13 cm) and Age group II (13 cm to 14 cm). Few large round scad at Age group IV and V (20 cm to 28 cm) stayed at the fishery. Other fishes caught were: Auxis rochei (0.85%), A. thazard (0.12%), Caranx spp. (0.45%), Emmilichthys nitidus (0.58%), Euthynnus affinis (0.42%), Leiognathus ruconius (0.58%), Loligo sp. (0.31%), Megalaspis cordyla (0.09%), Rastrelliger spp. (10.70%), Sardinella longiceps (0.03%), Scomberoides lysan (0.24%), Selar spp. (12.66%), Sphyraena spp. (0.90%), Thunnus albacares (0.96%) and others (1.02%). Tuna and tuna like fishes such as yellowfin tuna, eastern little tuna, bullet tuna, frigate tuna and oceanic squid are distributed in the upper latitudes of the survey area. On the other hand, round scads, big-eyed scads and Indian mackerels are dominantly present in the lower latitudes of the survey area.
    Schlagwort(e): Fisheries ; Exploratory fishing ; Purse seining ; Age composition ; Catch composition ; Fishery surveys ; Carangid fisheries ; South China Sea ; Philippines ; Rastrelliger ; Decapterus
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 49-64
    Format: 16
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 36
    facet.materialart.
    Unbekannt
    Training Department, Southeast Asian Fisheries Development Center | Samut Prakarn, Thailand
    In:  http://aquaticcommons.org/id/eprint/26215 | 17342 | 2019-02-08 06:25:54 | 26215 | Southeast Asian Fisheries Development Center, Training Department
    Publikationsdatum: 2022-08-02
    Beschreibung: Presented in this paper is the status of the fishery industry in Brunei Darussalam. Specifically, it discussed the following topics: fishery management strategies, zonation scheme, licencing, the use of poisons and explosives, the minimum cod-end mesh size for trawlers, closed areas, enhancement of fishing grounds, and the enforcement activities.
    Schlagwort(e): Fisheries ; Fishery resources ; Fishery management ; Fisheries ; Ecological zonation ; Licensing ; Fish poisoning ; Catching methods ; Illegal fishing ; Explosive fishing ; Fishing gear ; Season regulations ; Fishing grounds
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 34-40
    Format: 7
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 37
    facet.materialart.
    Unbekannt
    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26295 | 23782 | 2019-03-22 08:39:12 | 26295 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publikationsdatum: 2022-08-02
    Schlagwort(e): Fisheries ; Thailand ; Cadmium ; Lead ; Mercury ; Biological sampling ; Fish ; Fishery products ; Seafood
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 53-58
    Format: 6
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 38
    facet.materialart.
    Unbekannt
    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26292 | 23782 | 2019-03-22 03:43:09 | 26292 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publikationsdatum: 2022-08-02
    Schlagwort(e): Fisheries ; Malaysia ; Cadmium ; Lead ; Mercury ; Biological sampling ; Fish ; Fishery products ; Seafood
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 20-37
    Format: 18
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 39
    facet.materialart.
    Unbekannt
    Secretariat, Southeast Asian Fisheries Development Center | Bangkok, Thailand
    In:  http://aquaticcommons.org/id/eprint/26258 | 2002 | 2019-03-01 06:00:19 | 26258 | Southeast Asian Fisheries Development Center, Secretariat
    Publikationsdatum: 2022-08-02
    Beschreibung: An exploratory tuna longline fishing survey was conducted using the research and training vessels of the Southeast Asian Fisheries Development Center, the 1,178 GT MV SEAFDEC and the Bureau of Fisheries and Aquatic Resources, the 165 GT MV MAYA-MAYA in the South China Sea Waters, West of the Philippines from April to May, 1998. A total of 3,796 hooks was set in sixteen (16) fishing stations. There were no tuna caught during the entire survey but only minor and irrelevant species like the Pacific lancetfish, sharks and an opah species, Lampris guttatus. The important fishing and oceanographic factors during the survey and other research results on longline are described and analyzed. Additional longline studies within and near the Philippines territorial waters are also presented to substantiate the research results of the joint SEAFDEC/BFAR resource exploratory.
    Schlagwort(e): Fisheries ; Exploratory fishing ; Catch composition ; Fishery surveys ; Longlining ; Tuna fisheries ; South China Sea ; Philippines
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 39-48
    Format: 10
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 40
    facet.materialart.
    Unbekannt
    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26299 | 23782 | 2019-03-27 06:00:01 | 26299 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publikationsdatum: 2022-08-02
    Schlagwort(e): Chemistry ; Fisheries ; Malaysia ; Pesticides ; Biological sampling ; Fish ; Fishery products ; Biochemical analysis ; Lethal limits
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 71-74
    Format: 4
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 41
    facet.materialart.
    Unbekannt
    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26300 | 23782 | 2019-03-27 05:58:36 | 26300 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publikationsdatum: 2022-08-02
    Schlagwort(e): Aquaculture ; Chemistry ; Fisheries ; Myanmar ; Pesticides ; Biological sampling ; Fish ; Fishery products ; Lethal limits
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 75-83
    Format: 9
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 42
    facet.materialart.
    Unbekannt
    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26307 | 23782 | 2019-03-27 03:35:56 | 26307 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publikationsdatum: 2022-08-02
    Schlagwort(e): Fisheries ; Indonesia ; Histamines ; Biological sampling ; Fish ; Fishery products ; Quality control
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 116-123
    Format: 8
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 43
    facet.materialart.
    Unbekannt
    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26303 | 23782 | 2019-03-27 05:51:15 | 26303 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publikationsdatum: 2022-08-02
    Schlagwort(e): Chemistry ; Fisheries ; Thailand ; Pesticides ; Biological sampling ; Fish ; Fishery products ; Dried products ; Lethal limits
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 100-105
    Format: 6
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 44
    facet.materialart.
    Unbekannt
    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26309 | 23782 | 2019-03-27 03:49:31 | 26309 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publikationsdatum: 2022-08-02
    Schlagwort(e): Fisheries ; Myanmar ; Histamines ; Biological sampling ; Biochemical analysis ; Fish ; Fishery products
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 129-133
    Format: 5
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 45
    facet.materialart.
    Unbekannt
    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26826 | 23782 | 2019-11-21 00:56:12 | 26826 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publikationsdatum: 2022-08-02
    Beschreibung: Presented in the paper is the standard procedure in the determination of K value which is an index to measure the enzymatic freshness of fish and squid. Specifically, reagents, apparatus and the analytical procedures needed and the calculations are presented.
    Schlagwort(e): Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Fishery products ; Fish inspection ; Fishery industry ; Food technology ; Standards ; Specifications
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: B-6.1-B-6.7
    Format: 7
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 46
    facet.materialart.
    Unbekannt
    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26825 | 23782 | 2019-11-21 00:52:35 | 26825 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publikationsdatum: 2022-08-02
    Beschreibung: Presented in the paper is the standard procedure in measuring K value in fish meat by means of the freshness testing paper technique.
    Schlagwort(e): Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Fishery products ; Fish inspection ; Fishery industry ; Food technology ; Standards ; Specifications
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: B-7.1-B-7.2
    Format: 2
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 47
    facet.materialart.
    Unbekannt
    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26802 | 23782 | 2019-11-12 05:28:20 | 26802 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publikationsdatum: 2022-08-02
    Beschreibung: Presented in the paper is the standard procedure in the measurement of pH in the fresh fish meat. Specifically, the procedures in sampling and sample preparation, apparatus and reagents required, and the analytical procedures are presented.
    Schlagwort(e): Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Microbiological analysis ; Fishery products ; Processed fishery products ; Fish inspection ; Fishery industry ; Food additives ; Food technology ; Standards ; Specifications ; pH
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: A-3.1-A-3.2
    Format: 2
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 48
    facet.materialart.
    Unbekannt
    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26842 | 23782 | 2019-11-15 07:54:48 | 26842 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publikationsdatum: 2022-08-02
    Beschreibung: Starch is commonly used in the production of fish jelly products as an extender and as binding agent. The paper provides the methodology in the determination of starch in fish jelly products. Instructions for sample preparation and the reagents needed are presented. Detailed procedures in the determination of the starch in a sample are provided.
    Schlagwort(e): Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Fishery products ; Fishery industry ; Food technology ; Standards ; Specifications ; Starch ; Additives ; Food additives
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: D-4.1-D-4.4
    Format: 4
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 49
    facet.materialart.
    Unbekannt
    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26881 | 23782 | 2019-11-05 02:46:02 | 26881 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publikationsdatum: 2022-08-02
    Beschreibung: Monitoring and investigative work undertaken in the Philippines regarding dinoflagellate blooms are described. Chronological observations of the occurrence of red tides, aerial surveys, spatial distribution of the dinoflagellate and the physical environment are discussed. Fishing and the examination of gut content of fish and mussels and bioassay tests are detailed. Incidents of paralytic shellfish poisoning in the Philippines are considered briefly.
    Schlagwort(e): Fisheries ; Health ; Environmental monitoring ; Red tides ; Public health ; Medicine ; Dangerous organisms ; Philippines
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 52-79
    Format: 28
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 50
    facet.materialart.
    Unbekannt
    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26885 | 23782 | 2019-11-05 02:23:34 | 26885 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publikationsdatum: 2022-08-02
    Beschreibung: A report is made of the first incidence occurring of paralytic shellfish poisoning in Thailand in May 1983, following an extensive bloom of Trichodesmium erythraeum. Investigations undertaken regarding the source of the toxicity are outlined.
    Schlagwort(e): Fisheries ; Health ; Biological poisons ; Public health ; Red tides ; Shellfish ; Dangerous organisms ; Thailand
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 90-91
    Format: 2
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 51
    facet.materialart.
    Unbekannt
    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26879 | 23782 | 2019-11-05 02:54:38 | 26879 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publikationsdatum: 2022-08-02
    Beschreibung: A brief account is given of recent cases of paralytic shellfish poisoning in Sabah, Malaysia, and toxicological studies undertaken. Hydrography surveys, underwater observations after the occurrence of the red tides and plankton studies and monitoring of red tides are discussed.
    Schlagwort(e): Fisheries ; Health ; Shellfish ; Toxicity tests ; Red tides ; Public health ; Dangerous organisms ; Malaysia
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 35-42
    Format: 8
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 52
    facet.materialart.
    Unbekannt
    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26852 | 23782 | 2019-11-15 07:36:44 | 26852 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publikationsdatum: 2022-08-02
    Beschreibung: Cholera is an acute specific infection caused by the organism, Vibrio cholera. Diagnosis may be confirmed by the presence of large numbers of the comma-shaped bacilli on direct microscopic examination of a fecal or vomitus smear, and by the isolation of the organism on culture. Fish and shellfish have been identified as vehicles of cholera. Large numbers of V. cholera must usually be ingested to cause cholera. Thus problems often occur when poor handling and inadequate refrigeration have allowed the organism to multiply. Presented in the paper is the methodology of determining the presence of Vibrio cholera in fish and fishery products.
    Schlagwort(e): Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Fishery products ; Fishery industry ; Food technology ; Standards ; Specifications ; Aerobic bacteria ; Microbiological analysis ; Microorganisms ; Pathogenic bacteria ; Pathogens ; Health and safety ; Public health ; Microbial contamination ; Vibrio cholerae
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: E-7.1-E-7.5
    Format: 5
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 53
    facet.materialart.
    Unbekannt
    Secretariat, Southeast Asian Fisheries Development Center | Bangkok, Thailand
    In:  http://aquaticcommons.org/id/eprint/26890 | 23782 | 2019-11-14 01:01:29 | 26890 | Southeast Asian Fisheries Development Center, Secretariat
    Publikationsdatum: 2022-08-02
    Beschreibung: Fishery statistics in Brunei Darussalam have been collected by the Department of Fisheries since the 1940s. In the early 1980s, a number of statistics were collected, such as catch and effort data of artisanal fishermen, aquaculture statistics, processing statistics as well as data from major wet markets focusing on the amount, prices of marketed fish either from the local fishermen or imported. In 1984, the collection of statistics on commercial fishing was started. The statistics have been used in the formulation of fishery management and development policies as well as for sectoral development. Following a brief account of the responsibility and statistic collections of the Department of Fisheries, an examination is made of employment in the fishery sector, fisheries production, fish marketed and the GDP for the fishery industry. Fisheries in Brunei Darussalam is a very healthy industry, where production is well below the maximum allowable harvestable limit of 20,000 tons at 30%. The Department is embarking to increase production from the capture fishery to reduce the country's dependence on imported fish; the same applies for aquaculture, in order to complement production from the capture fisheries. The processing sector is also increasing in importance, especially with the increase in the number of capture fishery licenses, and the demand for quality and value-added products.
    Schlagwort(e): Fisheries ; Marine fisheries ; Fishery statistics ; Aquaculture development ; Aquaculture statistics ; Fish catch statistics ; Marine aquaculture ; Freshwater aquaculture ; Fishery development ; Marine ; Brackish ; Freshwater
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 6-14
    Format: 9
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 54
    facet.materialart.
    Unbekannt
    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26843 | 23782 | 2019-11-15 07:52:55 | 26843 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publikationsdatum: 2022-08-02
    Beschreibung: Sodium chloride is an important additive for the production of fish jelly products. It extracts the salt soluble protein to give the gel strength of the final product. The paper provides the methodology in the determination of the amount of sodium chloride in fish jelly products. Instructions for sample preparation and the reagents needed are presented. Detailed procedures in the determination of the salt in a sample are provided.
    Schlagwort(e): Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Fishery products ; Fishery industry ; Food technology ; Standards ; Specifications ; Additives ; Food additives ; Salts ; Sodium chloride
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: D-5.1-D-5.2
    Format: 2
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 55
    facet.materialart.
    Unbekannt
    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26851 | 23782 | 2019-11-14 01:29:31 | 26851 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publikationsdatum: 2022-08-02
    Beschreibung: Food poisoning due to Vibrio parahaemolyticus is a food-borne infection resulting from the ingestion of a large number of this organism (about 106-109 viable cells). The major symptoms are diarrhea and abdominal pain with headache, fever, and vomiting also occurring. The organisms are excreted during the acute stage of the illness after which they decrease rapidly. The differentiation of V. parahaemolyticus from other pathogenic species of Vibrio is based mainly on salt tolerance, Voges-Proskauer reaction, fermentation of sucrose, and growth at 43°C. Presented in the paper is the methodology of determining the presence of Vibrio cholera in fish and fishery products.
    Schlagwort(e): Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Fishery products ; Fishery industry ; Food technology ; Standards ; Specifications ; Aerobic bacteria ; Microbiological analysis ; Microorganisms ; Pathogenic bacteria ; Pathogens ; Health and safety ; Public health ; Microbial contamination ; Vibrio parahaemolyticus ; Vibrio cholerae
    Repository-Name: AquaDocs
    Materialart: book_section
    Format: application/pdf
    Format: application/pdf
    Format: E-8.1-E-8.6
    Format: 6
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 56
    ISSN: 1434-193X
    Schlagwort(e): Photocycloaddition ; Ring opening ; Oxetanes ; 1,2-Diols ; Alkyldealkoxylation ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The ring opening of 3-isopropyl-2-phenyl-3-oxetanol (2a) by various nucleophiles has been studied. In the presence of BF3 as a Lewis acid, a clean reaction at the less substituted C-4 position was observed and the corresponding 1,2-diols 6-11 and 21-23 were isolated in diastereomerically pure form (47-97% yield). Alkyl-, aryl-, alkynyl- and alkenyllithium compounds proved to be suitable carbon nucleophiles. Deprotonated thiols were used as sulfur nucleophiles. An alkoxide derived from benzyl alcohol and an amide derived from benzylamine reacted less readily under these conditions, yielding the 1,2,3-trifunctional compounds 24 (42% yield) and 26 (54% yield). Other 2-phenyl-3-oxetanols such as 2b and 2c can also be employed as electrophiles, whereas 2-anisyl derivatives preferentially undergo rearrangement reactions, as exemplified by the conversion of oxetane 16 to the hydroxy ketone 17 (84% yield). The superior behaviour of 3-oxetanols as compared to their silyl derivatives in reactions with nucleophiles became evident from the reaction of 3-silyloxyoxetane 1a with alkyllithium reagents. A β elimination occurred upon treatment with nBuLi, which, after pericyclic ring opening and addition of nBuLi, yielded the allylic alcohol 20.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 57
    ISSN: 1434-193X
    Schlagwort(e): Azoalkanes ; DBO ; Fluorescence quenching ; Exciplexes ; Hydrogen transfer ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The fluorescence of the DBO derivatives 1-3 is efficiently quenched by olefins and arenes, exciplex formation and hydrogen transfer operate as quenching mechanisms. The electron-accepting ester groups in the azoalkanes 1-3 promote significantly more effective quenching compared to the parent DBO. Steric hindrance accounts for the differences in the quenching efficiencies, but electronic effects dominate
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 58
    ISSN: 1434-193X
    Schlagwort(e): Mannich bases ; γ-Amino alcohols ; Grob fragmentation ; (Z)-Alkenes ; Oxetanes ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Quaternized γ-amino alcohols 5 derived from ternary iminium salts 2 are stereospecifically converted into both unsaturated aldehydes/ketones 6 with a (Z)-C—C double bond in a Grob-type fragmentation and highly functionalized oxetanes 7 by intramolecular substitution.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 59
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 2201-2207 
    ISSN: 1434-193X
    Schlagwort(e): Antibiotics ; Asymmetric synthesis ; β-Lactams ; Michael additions ; Multicomponent reactions ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Lithium dialkylcuprates react either in a sequential one-pot or in a domino “three-component” fashion with chiral Michael acceptors, like Oppolzer's N-enoyl-2,10-camphorsultams 7 and 11 or ‘Evans’ N-enoyl-4-phenyl-1,3-oxazolidin-2-ones 8 and 13, and N-(methoxycarbonylmethylidene)(4-methoxyphenyl)amine 9 to afford the corresponding cis-3-alkyl-4-methoxycarbonyl-1-(4-methoxyphenyl)azetidin-2-ones 10, 14-15 in overall yields of 40-67% and enantiomeric excesses of 91-99%.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 60
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 2229-2235 
    ISSN: 1434-193X
    Schlagwort(e): 3-Nitro-ω-benzylideneacetophenone ; Carbanions ; Michael addition ; Intramolecular vicarious nucleophilic substitution of hydrogen ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: 3-Nitro-ω-benzylideneacetophenone (1) reacts with carbanions containing leaving groups to give addition products to the electrophilic side chain. As a result of conjugated addition and subsequent intramolecular vicarious nucleophilic substitution of hydrogen (VNS) in the nitroaromatic ring of 1 in the position para to the nitro group, 4-cyano-7-nitro-3-phenyl-1,2,3,4-tetrahydronaphthalen-1-one and 4-cyano-7-nitro-3-phenylnaphth-1-ol are obtained. Smooth intramolecular VNS in the position para to the nitro group was observed for 4-chloro-1-(3-nitrophenyl)-3-phenyl-4-(p-tosyl)butanol.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 61
    ISSN: 1434-193X
    Schlagwort(e): Conformation analysis ; Electrochemistry ; Nitrogen heterocycles ; Dimerization ; Mechanism ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: In aqueous media the one-electron reduction of the title compounds on a mercury pool generally gives rise to three dimers, which are distinguishable by HPL chromatography. From spectroscopic analyses it has been possible to propose a structure for these conformers and their stability has been studied. Two conformers are unstable, yielding the third conformer. A mechanism is proposed for this transformation.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 62
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 837-846 
    ISSN: 1434-193X
    Schlagwort(e): AZT ; cycloSal-pro-nucleotide ; Prodrugs ; Nucleotide delivery ; HIV chemotherapy ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The application of our cycloSaligenyl- (cycloSal) pronucleotide concept to the approved anti-HIV dideoxynucleoside 3′-azido-3′-deoxythymidine AZT (1) is reported. This pro-nucleotide concept has been designed to deliver the corresponding 3′-azido-3′-deoxythymidine monophosphate AZTMP (2) by selective chemical hydrolysis from the lipophilic precursors cycloSal-AZTMP 4a-h. All derivatives 4a-h were synthesized using differently substituted salicyl alcohols 7a-h as starting materials. In hydrolysis studies, compounds 4 decomposed selectively releasing AZTMP (2) and the salicyl alcohols 7 following the designed tandem reaction. Furthermore, due to the electronic properties introduced by substituents, the half-lives of the triesters 4 could be ajusted over a wide range. Phosphotriesters 4 exhibited considerable biological activity in HIV-1 and HIV-2 infected wild-type human T-lymphocyte (CEM/O) cells, whereas, contrary to our expectations, nearly all activity was lost in HIV-2 infected thymidine-kinase-deficient CEM cells.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 63
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 853-859 
    ISSN: 1434-193X
    Schlagwort(e): N-Alkylation ; Diketopiperazine building block ; Peptidomimetics ; RGD analogues ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: As a new scaffold for peptidomimetic synthesis, a highly constrained bifunctional diketopiperazine, 4, has been prepared by smooth N-alkylation with tert-butyl bromoacetate. As a first application, we describe herein the synthesis of new peptidomimetics of the Arg-Gly-Asp (RGD) sequence. The product 30, which shows a selective platelet-aggregation inhibiting activity, can be used as a lead for the preparation of more potent products.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 64
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 871-876 
    ISSN: 1434-193X
    Schlagwort(e): Dioxirane ; Homolysis, induced ; Aminoxyl ; Oxidation ; Spin-trapping ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: In the reactions of dimethyldioxirane (1a) and methyl(trifluoromethyl)dioxirane (1b) with 2,2,6,6-tetramethylpiperidinyl-1-oxyl (2) (TEMPO) in acetone, the corresponding methoxyamine 1-methoxy-2,2,6,6-tetramethylpiperidine (5) is produced in ≥98% yield, both in air and under N2, and in the absence or presence of a hydrocarbon (adamantane). Kinetic experiments show that aminoxyl 2 triggers the radical decomposition of the dioxirane, in addition to scavenging methyl radicals derived therefrom. The reactions of an aminoxyl less prone to oxidation, namely 1,2-dihydro-2-methyl-2-phenyl-3H-indol-3-one-1-oxyl (4), with dioxiranes 1a and 1b in acetone have also been studied. In these cases, not only is the corresponding methoxyamine 8a produced (yield 12-16%), but quinoneimine-N-oxides 10 (yield 12-21%) and 11 (yield 18-19%) are also formed. Furthermore, significant amounts (8-14%) of the amine 9 (the product of deoxygenation of 4) can be isolated. These observations provide useful information concerning the free-radical mechanism that follows the initial attack by the aminoxyl at the dioxirane.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 65
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 2373-2377 
    ISSN: 1434-193X
    Schlagwort(e): Charge-transfer fluorescence ; Fluorogenic probe ; Fluorescence labelling ; Maleimide group ; Solvatochromism ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Structural modification of the highly fluorescent donor-bridge-acceptor molecule “Fluoroprobe” (FP) is shown to extend the excitation window to longer wavelengths. The resulting “Fluorotrope” (FT) shows appreciable absorption in the 350-420-nm range, so that visible (blue) light can be used for excitation. Further functionalization with a maleimide group results in the novel fluorogenic reagent MaleimidoFluorotrope (MFT) which yields fluorescent adducts with amines, thiols and other reactive groups that add to the double bond of the maleimide. The fluorescence wavelength of these adducts is extremely sensitive to the polarity and mobility of the medium.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 66
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 2379-2387 
    ISSN: 1434-193X
    Schlagwort(e): β-Peptides ; Polylithiation of peptides ; Li-enolates of peptides ; Back-bone alkylation of β-peptides ; Diastereoselective alkylation of β-peptide enolates ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A series of N-Boc-protected β-tripeptide derivatives with or without N-methyl groups and with free or Me-ester-protected C terminus has been prepared (8-14, 16, 17). As with α-peptides (→ A), the β-peptide derivatives can be polylithiated (→ B, C). No epimerization of stereogenic centers and no β elimination (exception 17 → 24) is observed upon treatment with bases as strong as tBuLi. The C terminal ester Li-enolate moiety of tetralithio β-tripeptides (cf. C) can be selectively alkylated with methyl, benzyl and allyl halides, and with tert-butyl bromoacetate in yields ranging from 35-80% (8 → 18, 14 → 20-23).
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 67
    ISSN: 1434-193X
    Schlagwort(e): Natural products ; Steroids ; Chenodeoxycholic acid ; Brassinosteroid analogues ; Biological activity ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The synthesis and spectroscopic characterization of two new bioactive analogues of brassinosteroids with a 24-hydroxylated cholanic side chain, an A/B ring cis-junction and oxygenated functions in C-7 is described.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 68
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 2409-2416 
    ISSN: 1434-193X
    Schlagwort(e): Sulfur heterocycles ; Rearrangements ; Reductions ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The syntheses of 1,2-benzodithiino[5,4,3-cde][1,2]benzodithiin-2,7-diamine (1) and dithio-bridged benzidine 2 have been achieved. The starting material for the synthesis of 1 was 1,3-diiodo-5-nitrobenzene (15) which was transformed by conventional means into 1,2-bis[3,5-bis(ethylthio)phenyl]diazane (19). The benzidine rearrangement of 19 in the presence of HBF4 at -30 °C yielded 4,4′-diamino-2,2′,6,6′-tetraethylthiobiphenyl (20) in 50 % yield. Treatment of 20 with sodium in ammonia and work-up in the presence of air yielded 1. The latter compound could be reduced with LiAlH4 to the tetrathiol 20a. The starting material for the preparation of 2 was 3-chloro-1-iodo-5-nitrobenzene (23), a side product of the preparation of 15. It was transformed analogously to the preparation of 1 into 1,2-bis(3-ethylthiophenyl)diazane (28). The benzidine rearrangement of 28 in presence of HBF4 at -30 °C afforded 4,4′-diamino-2,2′-bis(ethylthio)biphenyl (29) in 49 % yield. Treatment of 29 with sodium in ammonia and work-up under aerobic conditions yielded 2. Quantitative reduction of 2 to the thiol 29a could be achieved with LiAlH4. The reversible electrochemical reduction of 1 on unmodified glassy carbon electrodes leads to a product to which the structure of 3 was assigned.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 69
    ISSN: 1434-193X
    Schlagwort(e): N-Heterocycles ; Porphyrins ; Radical cations ; N-Dealkylation ; Stereoelectronic effects ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Evidence for a stereoelectronic inhibition of deprotonation of the radical cation of N-benzylpiperidine is presented. This stereoelectronic effect, which is due to the cyclic structure of the precursor, provides a tool to differentiate hydrogen-atom- versus electron-transfer routes in the biomimetic oxidative N-dealkylation of tertiary amines: the electron-transfer route appears to be the operating mechanism.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 70
    ISSN: 1434-193X
    Schlagwort(e): Colchicine ; 10-Ethylthiocolchicide, diene properties of ; π-Facial diastereoselectivity ; Consecutive [4+2],[3+2] cycloadditions ; Atropisomerism ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Cycloaddition reactions of the facially dissymmetric diene moiety of (-)-(M,7S)-colchicine (5) and (-)-(M,7S)-10-ethylthiocolchicide (9) to various alkynes have been studied. With 5 and the dienophilic benzyne (3), dimethyl acetylenedicarboxylate (DMAD) (4) and cyclooctyne (6) as starting materials all cycloadditions could be realized with high regioselectivity at the 8,12-positions of the alkaloid. The approach of the dienophiles preferentially occurred toward the syn π-face of the diene. In contrast to the cycloaddition mode of 5 the ethylthiocolchicide 9 surprisingly reacted in a different manner. With benzyne as starting material a novel [3+2] cycloaddition of the thioenol ether moiety of 9 towards the dipolarophilic benzyne is supposed, affording the unexpected colchicide 10 after [1,5]H shift of the primarily formed cycloadduct followed by cleavage of the C-S linkage. With DMAD (4) and cyclooctyne (6) the reaction course is more complex. In a consecutive [4+2]/[3+2] cycloaddition (or vice versa) followed by a thermally induced cycloreversion of a not identified intermediate DMAD (4) gives rise to the polycyclic thiophene derivative 13 and the novel allocolchicinoid 14. In a similar way cyclooctyne (6) yielded three products, the thiophene-annulated homobarrelenones 18 and 19 and the tetracyclic allocolchicinoid 21. The structures of the novel colchicine derivatives were assigned on the basis of spectral data, those of the cycloadducts 1 and 19 were verified by X-ray crystallography. For the unprecedented formation of the various allocolchicinoids by consecutive [4+2]/[3+2] cycloadditions plausible reaction pathways are suggested, as far as possible. In addition the inhibitory effects on the tubulin polymerization reaction in vitro of 10, 14, and 21 are reported.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 71
    ISSN: 1434-193X
    Schlagwort(e): Paclitaxel (Taxol®) ; Paclitaxel CD-ring ; High-pressure Diels-Alder reactions ; Furan cycloadditions ; Ether cleavage in 7-oxabicyclo[2.2.1]heptanes ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The high-pressure promoted Diels-Alder reactions between several furans and citraconic anhydride have been studied and the cycloadducts obtained have been explored in new straightforward routes to the CD-ring fragment of paclitaxel. The reaction between furan and citraconic anhydride afforded the exo cycloadduct diastereoselectively, whereas a variety of 2-substituted furans afforded approximate 1:1 mixtures of exo regioisomers. Separation of both regioisomers was accomplished after either diastereoselective esterification or regioselective reduction of the anhydride function. Ether cleavage of the bicyclic compounds by either high-pressure promoted ether cleavage or Boord elimination afforded several potential CD-ring precursors which can be used in the total synthesis of paclitaxel analogues.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 72
    ISSN: 1434-193X
    Schlagwort(e): Camphoracetyl chloride ; Lactols, fused ; Lactones, fused ; Pseudoacid chlorides ; Reagents, stereoselective ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: endo-Fused lactone 3 was obtained in high yield from the camphoracetic acid 2 with thionyl chloride and a subsequent reduction of intermediate 5 with tributyltin hydride. The structure of 5 was elaborated and some aspects of the mechanism of its formation and reactivity were investigated. Lactone 3 serves as key intermediate for lactol 1 which is a useful reagent in racemate resolution and asymmetric synthesis.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 73
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 2609-2615 
    ISSN: 1434-193X
    Schlagwort(e): Supramolecular chemistry ; Domino reactions ; Bipyridines ; 1,x-Cyclohexanediones ; Mannich bases ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A one-pot reaction using 1,x-cyclohexanediones, a Mannich base (or its hydrochloride), and ammonium acetate delivers novel pyridines or 3,3′-bridged bipyridine compounds 8, 16, 18, 20, and 22. This strategy offers a great flexibility in the design of new building blocks, e.g. in supramolecular chemistry and underlines the efficiency of domino reactions.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 74
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 2603-2607 
    ISSN: 1434-193X
    Schlagwort(e): Fluoro analogs of vitamin A ; Horner-Wittig reaction ; Fluoroisoprenoid building blocks ; Stereoselectivity ; Hydrolysis of chlorofluorocyclopropanes ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: An improved method for the preparation of ethyl 2-fluoro-3-methyl-2-butenoate (3) is described. The two stereoisomers [(E)-4 and (Z)-4] obtained after γ-bromination can be separated and can be individually converted into the corresponding diethyl phosphonates. The PO-ylides generated by α-deprotonation of the latter lose their stereochemical integrity by rapid torsional equilibration of the ester tail. Thus, Horner-Wittig reactions accomplished with benzaldehyde and (Z)- or (E)-(β-ionylidene)-acetaldehyde lead inevitably to stereorandomization at the terminal, ethoxycarbonyl-bearing double bond affording (E)- and (Z)-isomers in 50:50 to 15:85 ratios, depending on the reaction conditions. The new double bond, however, is formed with perfect trans-selectivity.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 75
    ISSN: 1434-193X
    Schlagwort(e): Alkaloids ; Total synthesis/Pumiliotoxin ; PTX-C ; PTX isomers ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A method is described for the synthesis of pumiliotoxin C (1a) and related stereoisomeric compounds 1c-1f. Starting from (+)- or (-)-3-methylcyclohexanone (6a,b), the oxo esters 7a and 7b were prepared. Condensation with (+)- or (-)-3-aminohexanol (8a,b) gave the stereoisomeric 3-aminoacrylates 9a, 9b and 9c. The hydroxy group of the amino-acrylates was transformed into bromide using the tosylate method. Cyclization of the bromides led to unsaturated quinoline ring systems. Finally, decarboxylation and catalytic hydrogenation gave the different cis- and trans-fused stereoisomeric alkaloids of the pumiliotoxin C type. The structures were verified by X-ray analysis.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 76
    ISSN: 1434-193X
    Schlagwort(e): Lawesson's reagent ; Thiolation of cyclic ketones ; Anchimeric effect ; cis-Bicyclo[3.3.0]octane-3,7-diones ; 9-Thiatricyclo[3.3.1.03,7]nonane ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A simple and efficient approach to the 9-thiatricyclo[3.3.1.03,7]nonane ring system (5) has been found by treating cis-bicyclo[3.3.0]octane-3,7-diones (1) with Lawesson's reagent or phosphorus pentasulfide. When dione 1 is treated with Lawesson's reagent tetramethyl 3(4aH)oxo-1,4-dihydrophenanthro[9,10-a]pentalene-1,2,4,4a-tetracarboxylate (6) is obtained as a by-product as shown by X-ray structural analysis.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 77
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 2667-2672 
    ISSN: 1434-193X
    Schlagwort(e): Pyrazolidin-3-ones ; Optical activity ; Asymmetric synthesis ; Ring transformation ; Hydrazines ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Enantiopure α-alkylidenelactones 7 were prepared by a Wittig reaction from α-bromolactones 4 and chiral aldehydes 6. Compounds 7 react with hydrazines 9 by stereoselective Michael-like addition and ring-chain transformation affording optically active 4-(ω-hydroxyalkyl)pyrazolidin-3-ones 11.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 78
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 2673-2676 
    ISSN: 1434-193X
    Schlagwort(e): Aromatic aldehydes ; Pinacol coupling ; Radical reactions ; Reagent control ; Titanium ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A novel concept for conductingtransition-metal-catalyzed radical reactions that allows highly diastereoselective titanocene-catalyzed pinacol couplings is described.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 79
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 2677-2682 
    ISSN: 1434-193X
    Schlagwort(e): Terpenoid lactones ; Antifeedants ; Limonene ; Claisen rearrangement ; Iodolactonization ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Four enantiomeric pairs of spirolactones were obtained in a four step synthesis from (+) and (-) limonene. The Claisen rearrangement and iodolactonization were the key steps of the syntheses presented. The structures of products were confirmed by X-ray crystallography of 11, 18b, and 19.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 80
    ISSN: 1434-193X
    Schlagwort(e): Phosphole ; Phosphanorbornadiene ; Stille cross-coupling ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The reaction of alkynylstannanes with 1-phenyl-3,4-dimethylphosphole at 150 °C affords the corresponding 2-stannyl-1-phosphanorbornadienes (2a, b), in fair yield. Oxidation under mild conditions affords the corresponding phosphane oxides (3a, b), whereas more drastic conditions (H2O2, 15% in toluene at 80 °C) induce the oxidative cleavage of the P-CH2 bond of the bridge to give a bicyclic phosphinate such as 4. Treatement of 4 by iodine leads to a tin → iodine exchange. The X-ray crystal structure analysis of the resulting 1-phospha-2-oxabicyclo[2.2.2]octa-5,7-diene 1-oxide confirms the functionalisation at the α-position and the relief of ring strain taking place upon insertion of oxygen into the P-CH2 bond of the norbornadiene. The 2-stannyl-1-phosphanorbornadiene 1-oxides (3a, b) readily undergo tin → iodine exchange. The resulting 2-iodo derivatives (6a, b) can be cross-coupled with 2-furyl-, 2-thienyl-, 2-pyrrolyl-, phenylethynyl-, and vinyl-tributylstannanes to give the corresponding 2-functional 1-phosphanorbornadiene 1-oxides in excellent yields (80-95%)
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 81
    ISSN: 1434-193X
    Schlagwort(e): Asymmetric synthesis ; Density functional calculations ; Cycloadditions ; Dihydropyrans ; Enantioselective oxidations ; Sulfur heterocycles ; Sulfoxides ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The 4-benzylidene-3-oxo[1,3]oxathiolan-5-ones 13-15, which were derived from the 3-oxo[1,3]oxathiolan-5-ones 9-11 by Knoevenagel condensation with the aldehydes 12, cyclize in an intramolecular hetero Diels-Alder reaction with high yield and excellent endo/exo as well as induced diastereoselectivity to give the hetero Diels-Alder adducts 16-18. The preferred formation of the Knoevenagel products 13-15 with a (Z) configuration was predicted with DFT calculations (B3LYP-6-311+G*) using the model systems 28 and 29. In addition B3LYP-6-31G*/sB3LYP/3-21G(*) calculations on transition structures for the hetero Diels-Alder reaction of 29 and 30 allowed a good correlation with the experimental results, which show that an endo attack of the dienophile syn to the S-O group in 13-15 leads to the main products.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 82
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 2759-2767 
    ISSN: 1434-193X
    Schlagwort(e): Phosphorus phthalocyanines ; Triazatetrabenzcorroles ; Dihydroxyphosphorus(V) phthalocyanine hydroxides ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The previously reported reaction of phthalocyanines [H2(pc)] with PBr3, which was claimed to give a phosphorus(III) phthalocyanine “(PcPIII)”, has been reinvestigated in detail with both unsubstituted and alkyl-substituted phthalocyanines, 1-4. The products exhibit unusual electronic and mass spectra compared to normal phthalocyanines and have been identified as oxophosphorus(V) triazatetrabenzcorroles 5-8. The corresponding dihydroxyphosphorus(V) phthalocyanine hydroxides 9-12 have also been synthesized for the first time by insertion of phosphorus(V) into phthalocyanines and have been characterized in detail. The different reactivities of PBr3 and POX3 (X = Cl, Br) toward phthalocyanines are discussed.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 83
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 2769-2773 
    ISSN: 1434-193X
    Schlagwort(e): Rubicenes ; Cyclization ; Polycyclic aromatic hydrocarbons ; Arenes ; Synthetic methods ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The synthesis of novel disubstituted rubicenes 1a-k is described. Starting from 1,5-dichloroanthraquinone and aryllithium reagents 3, the diol adducts 4 are reduced and the resulting diarylanthracenes 5 are cyclized to afford the title compounds in fair to good overall yield.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 84
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 37-41 
    ISSN: 1434-1948
    Schlagwort(e): Tripodal P ligands ; Rhodium ; Water-soluble complexes ; Immobilization ; Biphasic hydroformylation ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The synthesis of the water-soluble tripodal phosphane ligand cis,cis-1,3,5-(PPh2)3-1,3,5-[CH2(OCH2CH2)xOCH3]C6H6 (x = 30-160) (5) has been achieved in a four-step reaction sequence. The alcohol Mo(CO)3[cis,cis-1,3,5-(PPh2)3-1,3,5-(CH2OH)3C6H6] (1) is converted to the corresponding alcoholate 2, which forms the polyethylene glycol derivative 3 in a polyaddition reaction with oxirane. After methylation of the end groups of 3, the ligand 5 is obtained by a combined photochemical/oxidative demolybdenation reaction. The water-soluble tripodal phosphane 5 and the methoxymethyl functionalized tripodal ligand 6 react with Rh(PPh3)3(CO)H to form the water-soluble and water-insoluble rhodium carbonyl hydrido complexes 5a and 6a, respectively. The catalytic activity of the rhodium complex 5a in the hydroformylation of 1-hexene was found to be comparable in a single-phase system (1-hexene/methanol) with that in the biphasic system (1-hexene/water). Only traces of alcohol were found, which demonstrates that the catalyst 5a displays higher selectivity in hydroformylation than in hydrogenation.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 85
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 55-59 
    ISSN: 1434-1948
    Schlagwort(e): Arsaalkenes ; Arsenic ligands ; Carbonyl complexes ; Chromium ; Iron ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Reaction of equimolar amounts of the metalloarsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] (1) with the carbonyl complexes [Ni(CO)4], [Fe2(CO)9], and [{(Z)-cyclooctene}Cr(CO)5], respectively, affords the adducts [(η5-C5Me5)(CO)2FeAs{M(CO)n}=C(NMe2)2] with [M(CO)n] = [Ni(CO)3] (2); [Fe(CO)4] (3), and [Cr(CO)5] (4). These feature η1 coordination of the arsaalkene ligand via the arsenic atom. The molecular structures of the complexes 3 and 4 have been determined by X-ray diffraction analyses.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 86
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 155-157 
    ISSN: 1434-1948
    Schlagwort(e): Bite angle ; Catalysis ; P ligands ; Palladium ; Cross-coupling ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The effect of the natural bite angle (βn) of diphosphane ligands on catalyst selectivity and activity in the palladium-catalyzed cross-coupling of sec-butyl magnesium chloride with bromobenzene was investigated. The calculated natural bite angles range from 78° for dppe (1,2-bisdiphenylphosphanoethane) to 110° for Xantphos. The natural bite angle of diphosphane ligands has a large effect on catalyst selectivity and activity. Both rate and selectivity of the cross-coupling reaction increase with increasing bite angle and reach a maximum value with DPEphos (βn = 102.7° ). Larger bite angles of the diphosphane ligands result in a decreased selectivity and activity.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 87
    ISSN: 1434-1948
    Schlagwort(e): Ligand field spectra ; Phosphonate complexes ; X-ray structures ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The synthesis and characterization of transition-metal coordination compounds containing the ligand diethyl 2-quinolylmethylphosphonate (2-qmpe) is described. Complexes of CoII, MnII, NiII, CdII, and ZnII were found to be mutually isomorphous according to their X-ray powder diffraction patterns and IR spectra. The new coordination compounds were identified and characterized by elemental analysis, magnetic measurements, infrared and ligand-field spectra. The crystal structures of the complexes [M(2-qmpe)4(H2O)2](ClO4)2 (M = Ni, 1; Mn, 2) reveal six-coordinate [M(2-qmpe)4(H2O)2] cations with the qmpe ligand coordinating via the oxygen rather than via the nitrogen atom, as well as lattice perchlorate anions. The metal ion is octahedrally surrounded by the four oxygen atoms of the four organic ligands. The non-participation of the pyridine nitrogen atom is unusual. The two water molecules occupy the fifth and the sixth coordination sites in a trans configuration. The coordinated water molecules are strongly hydrogen-bonded to the pyridine nitrogen atom of the 2-qmpe, further stabilizing the solid-state structure. The geometry of the metal ion can be described as distorted octahedral. For the CuII complex, a hydroxo-bridged dinuclear structure of the type [Cu(2-qmpe)2(OH)(H2O)2]2(ClO4)2 is proposed, based on its spectroscopic and magnetic properties. Ligand-field spectra of the Co and Ni compounds were found to be in agreement with the tetragonally distorted octahedral geometry.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 88
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 191-202 
    ISSN: 1434-1948
    Schlagwort(e): Polynuclear complexes ; Carbene complexes ; Bridging ligands ; Alkynyl complexes ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The sequential reaction of two equivalents of the dimethylamino(ethynyl)carbene complexes [(CO)5M=C(NMe2)C≡CH] [M = W (1a), Cr (1b)] with two equivalents of nBuLi and one equivalent of a transition metal dichloride, [Cl2M′(Ln)], affords trinuclear biscarbene complexes of the type [(CO)5M=C(NMe2)C≡C-M′(Ln)-C≡CC(NMe)2=M(CO)5] [M′(Ln) = Ni(PEt3)2 (2a, b), Pd(PEt3)2 (3a, b), Pt(PEt3)2 (4a, b), Fe(dmpe)2 (6a), Hg (8a), Ti(η5-C5H5)2 (9a, b)] [dmpe = 1,2-bis(dimethylphosphino)ethane]. Treatment of 1a with equimolar amounts of first nBuLi and then [Cl2M′(Ln)] results in the formation of the monosubstitution products [(CO)5W=C(NMe2)C≡CM′(Ln)] [M′(Ln) = trans-Pd(PEt3)2Cl (5a), trans-Fe(dmpe)2Cl (7a)]. Additionally, the synthesis of the heterobimetallicethynylcarbene complex [(CO)5W=C(NMe2)C≡CPd(PEt3)2C≡CH] (10a), starting from 1a and [ClPd(PEt3)2C≡CH], is described. When three equivalents of 1a are treated, first with three equivalents of nBuLi and then with one equivalent of the trihalides PCl3 or BBr3, the novel tris(ethynylcarbene) complexes [{(CO)5W=C(NMe2)C≡C}3E] [E = B (11a), P (12a)] are obtained. The reaction of four equivalents of 1a,b with four equivalents of nBuLi, followed by addition of one equivalent of a group 14 tetrachloride [M′Cl4], yields the novel tetrakis(ethynylcarbene) complexes [{(CO)5M=C(NMe2)C≡C}4M′] [M′ = Si (13a, b), Ge (14a), Sn (15a, b)]. The complexes 8a, 9a, 12a, and 15a were characterized by X-ray structural analyses. All spectroscopic and structural data suggest that the carbene fragments and the central transition metal or heteroatom in these new bis-, tris-, and tetrakis(ethynylcarbene) complexes interact only weakly.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 89
    ISSN: 1434-1948
    Schlagwort(e): Rhenium ; Oxacyclocarbene complexes ; Vinylidene comlexes ; Alkynols ; Tripodal ligands ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Various β-, γ-, and δ-alkynols have been reacted with the 16e- fragment [(triphos)Re(CO)2]+ generated in situ by H2 elimination from [(triphos)Re(CO)2(η2-H2)]BF4 [triphos = MeC(CH2PPh2)3]. Irrespective of the length of the alkyl chain between the C≡C and OH functional groups in the ω-alkynol, 2-oxacyclocarbene complexes are obtained. These include the 2-oxacyclopentylidene derivatives [(triphos)Re(CO)2{=CCH2CH2CH2O}]BF4 and [(triphos)Re(CO)2{=CCH2CH2CH(Me)O}]BF4, the 2-oxacyclohexylidene dervivatives [(triphos)Re(CO)2{=CCH2CH2CH2CH2O}]BF4 and[(triphos)Re(CO)2{=CCH2CH2CH2CH(Me)O}]BF4, and the 2-oxacycloheptylidene complex [(triphos)Re(CO)2{=CCH2CH2- CH2CH2CH2O}]BF4. The latter compound contains a unprecedented seven-membered oxacarbene ring. The rhenium-assisted δ-alkynol to 2-oxacyloheptylidene rearrangement proceeds via the hydroxybutylvinylidene kinetic intermediate [(triphos)Re(CO)2{C=C(H)CH2CH2CH2CH2OH}]BF4, which has been characterized in both the solid state and solution. An X-ray analysis has been carried out on a single crystal of [(triphos)Re(CO)2{=CCH2CH2CH(Me)O}]BF4. The structure of this complex consists of [(triphos)Re(CO)2{=CCH2CH2CH(Me)O}]+ cations and tetrafluoroborate anions with no interspersed solvent molecules. A facial triphos ligand, two cis-disposed carbonyl groups and a 2-oxacyclopentylidene ligand coordinate the Re centre in a slightly distorted octahedral environment.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 90
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 237-244 
    ISSN: 1434-1948
    Schlagwort(e): Titanium complexes ; Amido-cyclopentadienyl ligand ; Titanium alkyl ; Intramolecular coordination ; Ethene polymerization ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Titanium complexes containing a linked isopropyl- or benzylamido(tetramethylcyclopentadienyl) ligand C5Me4SiMe2NR (R = iPr, CH2Ph,) and one bidentate organyl group C6H4(CH2NMe2)-2, CH2C6H4(NMe2)-2, and {η5-C5H3(CH2NMe2)-2}Fe(η5-C5H5) were prepared by salt metathesis of the corresponding dichloro complex Ti(η5:η1-C5Me4SiMe2NR)Cl2 with the lithium organyl. Single crystal X-ray structural analysis of Ti(η5:η1-C5Me4SiMe2NCH2Ph)- {C6H4(CH2NMe2)-2}Cl and of Ti(η5:η1-C5Me4SiMe2NiPr){CH2C6H4(NMe2)-2}Cl revealed the presence of intramolecular coordination with square pyramidal geometry around titanium. In the ferrocenyl derivative Ti(η5:η1-C5Me4SiMe2NCH2Ph)[{η5-C5H3(CH2NMe2)-2}Fe(η5-C5H5)]Cl the NMe2 group is not bonded at the titanium atom. Ethene polymerization catalyzed by these complexes upon activation with methylaluminoxane was examined.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 91
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 271-274 
    ISSN: 1434-1948
    Schlagwort(e): Zinc complexes ; Pyrazolylborate ligands ; Hydrolytic cleavage ; Diphosphate ; Sulfonatophosphate ; Disulfonate ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Three (pyrazolylborate)zinc hydroxide complexes Tp*Zn-OH were used as hydrolytic reagents to cleave the P-O-P, P-O-S, and S-O-S linkages of organic diphosphates, sulfonatophosphates, and disulfonates. The resulting complexes of the types Tp*Zn-OPO(OR)2 and Tp*Zn-OSO2R could also be obtained by condensation reactions between Tp*Zn-OH and HO-PO(OR)2 or HO-SO2R. Two of them were characterized by structure determinations.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 92
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 283-289 
    ISSN: 1434-1948
    Schlagwort(e): Gold ; Chalcogenide ; Flux reaction ; Structure determination ; Metal-metal bonding ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The novel compounds K2AuPS4 (1), Tl2AuPS4 (2), K2AuAsS4 (3), and KAu5P2S8 (4) have been synthesized by direct reaction of the elements with a molten alkaline polythiophosphate(arsenate) flux at 550°C. The crystal structures of these compounds have been determined by single-crystal X-ray diffraction techniques. 1, 2, and 3 crystallize in the monoclinic space group P21/m. The structures of 1, 2, and 3 consist of infinite, one-dimensional anionic chains running along the crystallographic b axis. The chains are separated by potassium or thallium ions. Neighbouring Au atoms are bridged by MS43- tetrahedra (M = P, As) in a trans orientation. Compound 4 crystallizes in the space group P21/c. The anionic chains of 4 are built up from linear AuS2 dumbbell units and PS43- tetrahedra. The chains extend along the [110] and [110] direction and are separated by charge balancing K+ cations. Each of the compounds was investigated by differential thermal analysis, FT-IR, and solid-state UV/Vis diffuse reflectance spectroscopy.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 93
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 299-303 
    ISSN: 1434-1948
    Schlagwort(e): Calix[4]arenes ; Calix[4]arene complexes ; Molybdenum ; Tungsten ; Metal-metal bonding ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Addition of p-tert-butylcalix[4]arene LH4 to the dinuclear compounds M2(NMe2)6 (M = Mo, W) results in the formation of [NH2Me2]2[L2M2] 1 (M = Mo) and 2 (M = W). Both compounds have been characterized by spectroscopic methods and single-crystal X-ray diffraction. The metal-metal distances of 1 and 2, of 2.194(1) Å and 2.293(1) Å, respectively, are consistent with the retention of the M≡M triple bond. Both „ate” complexes contain a [M≡M]6+ dimetal core, supported by two bridging μ2-κ2O,κ2O-calix[4]arene ligands in the solid state. These compounds are the first examples of a formally fourfold deprotonated calix[4]arene acting as a μ2-κ2O,κ2O bridging ligand for two transition metal centres. The calix[4]arenes in 1 and 2 are distorted from a cone conformation in the uncomplexed ligand, to an elliptical cone section. 1H-NMR data at variable temperatures suggest fluxional behaviour of 1 and 2 in solution.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 94
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 331-337 
    ISSN: 1434-1948
    Schlagwort(e): Bis(pentamethylcyclopentadienyl)phosphanes ; Aminobis(pentamethylcyclopentadienyl)phosphanes ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The bis(1,2,3,4,5-pentamethyl-1,3-cyclopentadien-1-yl)phosphanes 3-7 are formed in good yields by the reaction of the halogenophosphanes 2a or 2b with the appropriate nucleophile. Following another route, the dialkylaminobis(pentamethylcyclopentadienyl)phosphanes 11a-c have been synthesized by the treatment of dichloro(dialkylamino)phosphanes with two equivalents of (pentamethylcyclopentadienyl)lithium. The compounds 3-11 have been characterized by multinuclear NMR spectroscopy and 3, 5, 6, and 11a have also been characterized by single-crystal X-ray diffraction studies. The molecular structure of 11a is governed by steric congestion, which typically would lead to a parallel arrangement of the two pentamethylcyclopentadienyl ligands at the phosphorus atom. However, surprisingly, the crystal structure of the (dimethylamino)phosphane 11a, exhibits a tilted, rather than a parallel, conformation of the pentamethylcyclopentadienyl groups [tilt angle: 130.6(1)°].
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 95
    ISSN: 1434-1948
    Schlagwort(e): Palladium ; Platinum ; Bidentate nitrogen ligands ; p-Quinone ; Alkenes ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Compounds of the type M(N∩N-κN)(nq)2 and M2(μ2-N∩N)(μ2-pbq)2, in which nq = 1,4-naphthoquinone, pbq = 1,4-benzoquinone, and N∩N is a monodentate or bridging ligand of the α-diimine type, were obtained from reactions of Pd(dba)2 in toluene with the 3,3′-annelated-2,2′-bipyridines: 4,5-diazafluoren-9-one (dafo) and 4,5-diazafluorene (dafe) in the presence of the appropriate p-quinone. In the corresponding reactions with 2,2′-bipyridine (bpy), 1,10-phenanthroline (phen), 2,2′-bipyrimidine (bpym), N,N′-dicyclohexyl-1,4-diaza-1,3-butadiene (chex-dab), bis[N-(o,o′-diisopropyl)phenylimino]acenaphthene (o,o′-iPr2-bian) and 5,6-dihydro-1,10-phenanthroline (dh-phen) only complexes of the type M(N∩N-κ2N)(Q) were formed (Q = nq, pbq). The structures of the complexes have been established by NMR in solution and by X-ray diffraction in the solid state; crystal structures of Pd(bpy-κ2N)(η2-pbq) (1) Pd(dafo-κN)(η2-nq)2 (14) and Pd2(μ2-dafo)(μ2,η2:η2-pbq)2 (16) have been determined. Of the ligands, dafo and dafe are the only ones apt to form complexes containing a monodentate or bridging N∩N ligand. This behaviour is ascribed to the geometrical constraints of dafo and dafe; the annelation by one carbon atom at the 3,3′-positions in these ligands causes an increase in bite angle from approximately 77° to 82°.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 96
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 367-373 
    ISSN: 1434-1948
    Schlagwort(e): Phthalocyanines ; Indium ; Indium-carbon bond ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The synthesis of highly soluble chloro(phthalocyaninato)indium(III) complexes RxPcInCl (3a: R1 = tert-butyl, R2 = H, x = 4 and 4a: R1 = R2 = n-pentyl, x = 8), and their reactions with R′MgBr [R′ = p-trifluoromethylphenyl- (b), m-trifluoromethylphenyl- (c), p-fluorophenyl- (d), perfluorophenyl- (e)] leading to the stable σ-bonded aryl(phthalocyaninato)indium(III) complexes 3b-e, 4b-e are described. All compounds were characterized by IR, UV/Vis, MS, 1H, 13C and 19F NMR as well as elemental analyses. Phenyl(phthalocyaninato)indium(III) (4f) was prepared by the reaction of (n-C5H11)8PcInCl (4a) with PhLi. The high solubility of the complexes 3a-e and 4a-f is, aside from the influence of the peripheral substituents, considered to be derived from the large dipole moments present which are due to the strongly electron withdrawing axial ligands, and from the lower tendency of axially substituted phthalocyaninato metal complexes to form aggregates.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 97
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 381-388 
    ISSN: 1434-1948
    Schlagwort(e): Phosphanes ; Phosphorus ylides ; Nucleophilic addition ; Structure elucidation ; NMR spectroscopy ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Chlorophosphanyl and dichlorophosphanyl alkylidene- and benzylidenephosphoranes 6 and 8 are converted by reaction with LiAlH4 to the respective phosphanes 7 and 9. The former can be isolated, but decompose on heating or on protonation to give the ylidyl diphosphane 11 and the phosphonium ylide or phosphonium salt, respectively. The final products are the cyclooligophosphanes 15-17. Only the C-tert-butyl derivative 7c is stable in both regards. The conformation of the RPH group in 7 as compared to that of the RPCl group in 6 clearly reflects their different interaction with the ylide moiety.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 98
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 407-414 
    ISSN: 1434-1948
    Schlagwort(e): Ruthenium ; Phosphorus ; Triphos complexes ; Fluxionality ; Arm-off dissociation ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Structural fluxionality is apparent in the 1H- and 31P-NMR spectra of compounds of the type [Ru(L)(MeCN)(triphos)](CF3SO3), 2-5, at 25°C, where L represents a diorganyldithiocarbamate or a heterocyclic κ2N,S coordinating thioamide. In contrast, complexes [Ru(Et2NCS2)(Y)(triphos)]n+ (6, n = 1, Y = CO; 7, n = 0, Y = CN-; 8, n = 0, Y = H-) are stereochemically rigid in solution at this temperature, indicating that MeCN dissociation must occur for the crowded octahedral coordination spheres of 2-5. Reaction of [Ru(MeCN)3(triphos)](CF3SO3)2, 1, with Na(Et2NCS2) at a 1:2 molar ratio yields [Ru(Et2NCS2-κ2S)(Et2NCS2-κS)(triphos)], 9, which slowly converts to [Ru(Et2NCS2-κ2S)2(triphosO-κ2P)], 10, on recrystallization from ethanol/acetone under air [triphosO is O=P(Ph)2CH2C(CH3)(CH2PPh2)2]. A similar κ3P→κ2P arm-off dissociation leads to the formation of [Ru(mpy-κ2N,S)2(triphosO-κ2P)] (13) and [Ru(mmim-κ2N,S)2(triphosO-κ2P)] (14) (Hmpy = 2-mercaptopyridine, Hmmim = 2-mercapto-1-methylimidazole). Crystal structures are reported for [Ru(mbt-κ2N,S)(MeCN)(triphos-κ3P)](CF3SO3) (4) (Hmbt = 2-mercaptobenzothiazole), [Ru(mpym-κ2N,S)(mpym-κS)(triphos-κ3P)] (11) (Hmpym = 2-mercaptopyrimidine) and 14, the latter of which is present as the OC-6-13 isomer.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 99
    ISSN: 1434-1948
    Schlagwort(e): Alkyne complexes ; Titanium ; Zirconium ; Coordination mode ; Metallacycles ; Cyclopentadienes ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The influence of metals, alkyne substituents, Cp substitution and additional ligands on the stability of bridged and unbridged η2-alkyne-titanocene and -zirconocene complexes has been investigated. The reduction of the complex [(η5-C5H4)-SiMe2-(η5-C5H4)]TiCl2 with magnesium in the presence of tolan (PhC2Ph) does not give the expected alkyne-titanocene complex [(η5-C5H4)-SiMe2-(η5-C5H4)]Ti(η2-PhC2Ph) but by coupling of two tolan molecules the corresponding titanacyclopentadiene [(η5-C5H4)-SiMe2-(η5-C5H4)]TiC4Ph4 (1) was obtained. In the analogous reaction with Me3SiC2SiMe3 the stable η2-alkyne complex without additional ligands [(η5-C5H4)-SiMe2-(η5-C5H4)]Ti(η2-Me3SiC2SiMe3) (2) was formed, due to the sterical influence of the alkyne substituents. The compounds without additional ligands (thi)2Ti(η2-PhC2Ph) (3) and (thi)2Ti(η2- Me3SiC2SiMe3) (5) were isolated from the unbridged titanocene complex (thi)2TiCl2 (thi = tetrahydroindenyl). Two equivalents of complex 3 reacted with one equivalent of water to yield the dimeric alkylidene-μ-oxo complex [(thi)2Ti(CPh=CHPh)]2(μ-O) (6). The reaction of the unbridged zirconocene compound (thi)2ZrCl2 gave the alkyne complex (thi)2Zr(THF)(η2-Me3- SiC2SiMe3) (7) which is stabilized by THF. At higher temperature THF was eliminated from the orange complex 7 forming the green complex (thi)2Zr(η2-Me3SiC2SiMe3). This behaviour was investigated in detail using NMR spectroscopy and compared to similar complexes such as Cp2Zr(η2-Me3SiC2SiMe3) (not stable without THF), (ebthi)2Zr(η2-Me3SiC2SiMe3) (ebthi = ethylenebistetrahydroindenyl; stable without THF) and Cp*2Zr(η2-Me3SiC2SiMe3) (Cp* = pentamethyl-Cp, stable without THF). All complexes were characterized by spectroscopic methods. X-ray structural determinations were conducted for the complexes 1, 3 and 7. Compound 3 is the first example of a structurally characterized tolan-titanocene complex without additional ligands.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 100
    ISSN: 1434-1948
    Schlagwort(e): Calixarene ; Phosphinite ; Calixphosphane ; Transition metals ; X-ray diffraction ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A cone-shaped calix[4]arene-derived monophosphinite, 25,27-di(ethoxycarbonylmethoxy)-26-hydroxy-28-(diphenylphosphinooxy)calix[4]arene (L1), has been prepared in two steps from calix[4]arene. Treatment of L1 with [AuCl(tetrahydrothiophene)] in tetrahydrofuran gave the phosphinite complex [AuClL1] (1). Reaction of [PdCl2(PhCN)2] with two equivalents of L1 gave selectively trans-[PdCl2L12] (2). Complex 2 · 2 CH2Cl2 crystallizes in the triclinic space group P1¯. The molecule is centrosymmetric, leading to a divergent array of the two calixarene moieties. The palladium atom resides outside both cones. As a result of steric interactions, the meta and para carbon atoms of the PPh2-bearing aryl ring are significantly pushed to the interior of the cavity. The related platinum complex trans-[PtCl2L122] (3), was obtained similarly from [PtCl2(PhCN)2] and presents in the solid state a structure which is isomorphous to that of 2. The diphosphinite 25,27-di(ethoxycarbonylmethoxy)-26,28-bis(diphenylphosphinoxy)calix[4]arene (cone) (L2) has also been prepared and reacts with [PtCl2(PhCN)2] to yield oligomeric material.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
Schließen ⊗
Diese Webseite nutzt Cookies und das Analyse-Tool Matomo. Weitere Informationen finden Sie hier...