ISSN:
1434-1948
Keywords:
Zinc complexes
;
Pyrazolylborate ligands
;
Hydrolytic cleavage
;
Diphosphate
;
Sulfonatophosphate
;
Disulfonate
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Three (pyrazolylborate)zinc hydroxide complexes Tp*Zn-OH were used as hydrolytic reagents to cleave the P-O-P, P-O-S, and S-O-S linkages of organic diphosphates, sulfonatophosphates, and disulfonates. The resulting complexes of the types Tp*Zn-OPO(OR)2 and Tp*Zn-OSO2R could also be obtained by condensation reactions between Tp*Zn-OH and HO-PO(OR)2 or HO-SO2R. Two of them were characterized by structure determinations.
Type of Medium:
Electronic Resource