ISSN:
0947-3440
Keywords:
Mannich bases
;
Quaternization
;
Grob fragmentation
;
Alkenes
;
Nucleophilic attack
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Quaternary β-amino aldehydes and β-amino ketones are cleaved in a Grob-type fragmentation induced by nucleophilic attack of NH2- on the carbonyl group of 3, to yield new carbonyl derivatives 4 and alkenes 5, and unsaturated amides 6, respectively.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.199719970820
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