ALBERT

Description / Table of Contents: A new freezing mechanism, called segregation freezing, is proposed to explain the generation of the suction force that draws pore water up to the freezing surface of a growing ice lens. The segregation freezing temperature is derived by applying thermodynamics to a soil mechanics concept that distinguishes the effective pressure from the neutral pressure. The frost-heaving pressure is formulated in the solution of the differential equations of the simultaneous flow of heat and water, of which the segregation freezing temperature is one of the boundary conditions.

Description / Table of Contents: The interaction of a 5.1-GHz transverse electric surface wave with a dielectric slab is experimentally investigated. The wave is initially supported by a dielectric substrate resting upon a metallic ground-plane. A slab, made of the same dielectric material as the substrate and variable in height, is then placed upon the waveguide. The results for a small slab sitting on the substrate showed that the discontinuity was a very inefficient launcher of reflected surface waves. Investigations of these reflections with a trough waveguide showed that, for values of slab height comparable to the exponential decay height of the surface wave, the reflections remain very small. However, as the slab height is increased beyond the decay height, the reflected amplitude approaches the theoretical value for a plane wave reflected from the interface between air and the same dielectric. The results are applicable to surface wave methods of microwave deicing of wings and helicopter rotors.

Description / Table of Contents: The theory of non-coaxial in-plane plastic deformation of soils that obey the Coulomb yield criterion is presented. The constitutive equations are derived by use of the geometry of the Mohr circle and the theory of characteristic lines. It is found that, for solving a boundary value problem, the non-coaxial angle must be given such values that enable us to accommodate the presupposed type of flow in the given domain satisfying the given boundary conditions. The non-coaxial angle is contained in the constitutive equations as a parameter. Therefore, the plastic material obeying the Coulomb yield criterion is a singular material whose constitutive equations are not constant with material but are variable with flow conditions.

Description / Table of Contents: The viscoelastic deflection of an infinite floating ice plate subjected to a circular load was solved, assuming the Maxwell-Voigt type four-element model. An effective method of numerical integration of the solution integrals was developed, of which each integrand contains a product of Bessel functions extending to infinity. The theoretical curve was fitted to the field data, but the material constants thus found varied with time and location.

Description / Table of Contents: Many of the technical questions relating to iceberg transport are given brief, but quantitative, consideration. These include iceberg genesis and properties, the mechanical stability of icebergs at sea, towing forces and tug characteristics, drag coefficients, ablation rates, and handling and processing the iceberg at both the pick-up site and at the final destination. In particular the paper attempts to make technical information on glaciological and ice engineering aspects of the problem more readily available to the interested planner or engineer. Specific conclusions include: (1) No unprotected iceberg, no matter how long or wide, would be likely to survive the ablation caused by a long trip to low latitudes. (2) Icebergs that have a horizontal dimension exceeding 2 km may well be prone to breakup by long wavelength swells. (3) To avoid the dangers associated with an iceberg capsizing, the width of a 200-m thick iceberg should always be more than 300 m. (4) For towing efficiency the length/width ratio of a towed iceberg should be appreciably greater than unity. (5) For a pilot project, the selected iceberg would have to be quite small, if for no other reason than the practical availability of tug power.

Description / Table of Contents: The Holocene stratigraphy in Scoresby Sund is based on climatic change as reflected by fluctuations in fjord and valley glaciers, immigration and extinction of marine molluscs, and the vegetation history recorded in pollen diagrams from five lakes. The histories are dated by C-14, and indirectly by emergence curves showing the patterns of isostatic uplift. From c. 10100-10400 to 9400 yr BP the major fjord glaciers showed oscillatory retreat with abundant moraine formation, the period of the Milne Land Moraines. The vegetation in the ice free areas was a sparse type of fell field vegetation but with thermophilous elements indicating temperatures similar to the present. From 9400 yr BP the fjord glaciers retreated rapidly in the narrow fjords, the few moraines formed are referred to the R0defjord stages and indicate topographically conditioned stillstands. At 8000 yr BP the low arctic Betula nana imigrated into the area, and in the period until 5000 yr BP dense dwarf shrub heath grew in areas where it is now absent. In the fjords the subarctic Mytilus edulis and Pecten islandica lived, suggesting a climate warmer than the present. From c. 5000 yr BP the dense dwarf shrub heath began to disappear in the coastal areas, and a 'poor' heath dominated by the high arctic Salix Arctica and Cassiope tetragona expanded. These two species, which are now extremely common, apparently did not grow in the area until c. 6000 yr BP. In lakes in the coastal area minerogenic sedimentation at c. 2800 yr BP, reflecting the general climatic deterioration.

Description / Table of Contents: Ice fog suppression experiments on the Fort Wainwright Power Plant cooling pond were conducted during the winters of 1974-76. Baseline information studies occupied a sizable portion of the available ice fog weather in 1974-75. Then hexadecanol was added to the pond and dramatically improved visibility by reducing fog generated from water vapor released by the pond at -14 C. Although this temperature was not low enough to create ice fog, the cold vapor fog created was equally as devastating to visibility in the vicinity of the pond. During the winter of 1975-76, suppression tests were continued using films of hexadecanol, mixes of hexadecanol and octadecanol, and ethylene glycol monobutyl ether (EGME). Suppression effectiveness at colder temperatures was stuided and limits to the techniques were probed. A reinforcing grid was constructed that prevented breakup of the film by wind and water currents. Lifetime tests indicated that EGME degrades much more slowly than either hexadecanol or the hexadecanol-octadecanol mix. The films were found to be very effective fog reducers at warmer temperatures but still allowed 20% to 40% of normal evaporation to occur. The vapor thus produced was sufficient to create some ice fog at lower temperatures, but this ice fog occurred less frequently and was more quickly dispersed than the thick fog that was present before application of the films.

Description / Table of Contents: The objectives of this investigation were to describe channel characteristics and geographic settings of ice jam sites from aerial photographic interpretation, to indicate which characteristics may be important in causing ice jams, and to suggest additional uses of aerial photographs. Aerial photographs were taken of 19 sites with a Zeiss RMK 15/23 aerial camera on 17, 19, and 21 April 1976. Uncontrolled photomosaics of each site were assembled and major river characteristics were delineated on the photomosaics. Characteristics described include: manmade structures, falls, rapids, changes in channel depths, channel islands, mid-channel shoals or bars, river bed material, river sinuosity, meanders, floodplain width, riparian vegetation, and types of development on the floodplain. River channel widths were measured from the photographs along rivers where ground truth data were available for comparison. Lengths of channel riffles and pools were measured along the rivers where variations in river depths were evident on the photographs. Seventy-nine percent of the sites have some form of flow control structure which causes a pool with a backwater condition of low velocity. The low flow condition in the pool allows a solid ice cover to form which impedes ice movement and initiates ice jams. Aerial photographs provide a regional perspective for evaluating channel characteristics at an ice jam site and for analyzing the geographic setting at each site during ice-free conditions. Photographs taken after ice jams have formed are useful in monitoring ice jam formation, in analyzing ice characteristics, and in documenting ice jam breakup and movement.

Description / Table of Contents: Large, simply supported beams of temperate lake ice were found, generally, to yield significantly higher flexural strengths than the same beams tested in the cantilever mode. Data support the view that a significant stress concentration may exist at the fixed corners of the cantilever beams. Maximum effects are experienced with beams of cold, brittle ice substantially free of structural imperfections; for this kind of ice the strength difference factor, here attributed to the effect of stress concentrations, may exceed 2.0; that is, simply supported beams test a factor of 2 or more stronger than the same beams tested in the cantilever mode. In ice that has undergone extensive thermal degradation, the stress concentration effect may be eliminated entirely. Simply supported beams generally yield higher strengths when the top surfaces are placed in tension. This behavior is attributed to differences in ice type; the fine-grained, crack-free top layer of snow-ice which constituted up to 50% of the ice cover in the current series of tests usually reacted more strongly in tension than the coarse-grained crack-prone bottom lake ice.

Description / Table of Contents: The use of radio-echo sounding records to indicate the presence of internal layers within large ice sheets is of interest to glaciologists because it offers a means of tracking the internal properties of the ice sheets over large distances. The interpretation of the reflections obtained in this manner is more valuable, however, if a physical property change relating to the glaciological regime can be related to the dielectric property change producing the radio-echo reflections. In this report, we use the measured physical properties of core to bedrock taken at Cape Folger, East Antarctica (66 deg 22 min s, 111 deg (E), 324-m depth), to compute a profile of dielectric properties and from this, a depth-reflection coefficient profile for comparison with observed radio-echo reflections. The measurements available on physical properties are: density variations, bubble size and shape changes, and crystal fabric variations. The depths of the strong reflections shown on the available radio-echo records are in reasonable agreement with the depths corresponding to the highest reflection coefficients computed from the combined physical property measurements. In calculations to differentiate the separate effects of different physical properties, it appears that density variations account for the primary contributions to the calculated dielectric property changes corresponding to the highest reflection coefficients. However, bubble changes alone can also account for reasonable, though lower, reflection coefficients at the appropriate depths. Crystal fabric variations correspond poorly with the reflection locations. Density variations are normally associated with depositional events in the history of the ice sheet.

Description / Table of Contents: The mathematical theory for the bearing capacity of river ice for vehicles is presented. The floating ice sheet is assumed to have simple supports at the shore line. Solutions are presented for loads uniformly distributed over circular and rectangular areas. Numerical evaluations are made for a number of vehicles and the results presented in graphical form

Description / Table of Contents: The results of axial double point-load tests on disk samples of snow and ice obtained from the area of McMurdo Sound, Antarctica, are presented. They show the effects of temperature, sample length, load point diameter and specific gravity on failure load. It was determined that 13 samples should be tested to obtain a representative mean strength index. The results show that the axial double point-load test has good possibilities as a rapid field test for determining the unconfined comrpessive strength of snow and ice but that further evaluation of the variables affecting test results must be made.

Description / Table of Contents: Uniaxial compression and tension tests were conducted on polycrystalline snow-ice to determine the effect of temperature on its strength. Test temperatures ranged from -O.1C to -54C. Two machine speeds, 0.847 mm/s and84.7 mm/s were used for the constant displacement rate tests. The compressive strength at -54C was about oneorder of magnitude higher than at -0.1C. The tensile strength at -18C was about 20% higher than at 0.1C. The initial tangent and 50% strength moduli are given for the compression tests, while the secant modulus to failure is given for the tension tests.The mode of fracture is discussed and the test results are compared with data from other investigations.

Description / Table of Contents: This volume of Reviews in Mineralogy attempts to synthesize our present understanding of certain aspects of the mineralogy and chemistry of the rock-forming carbonates. Hopefully, it reflects the presently more active areas of research. This review follows, by ten years, a major assessment of (sedimentary) carbonate minerals by Lippmann (1973). There is only minor overlap of subject material, and I hope that this difference reflects fairly how this field has developed. In some respects carbonates are unique, for they are one of the few mineral groups providing an abundant record of biological, physical, and chemical processes throughout much of geologic time. Because of their relative importance in sedimentary rocks, lowtemperature examples are given more emphasis here. Moreover, the obvious correlation with energy resources has been a significant factor contributing to the current resurgence of interest in this area. However, the broader interest in carbonates is also a reflection of their widespread occurrence in vastly different geologic environments, including metamorphic and igneous settings, as well as an appreciation of their role in both atmospheric and oceanic chemistry, both past and present. In this volume, some of the papers are general (i.e., those addressing crystal chemistry and phase relations), and they provide overviews of a fundamental nature and are of interest to many. Others are more specialized in coverage and generally reflect the different approaches used in carbonate geochemistry. The final chapter introduces transmission electron microscopy, a relatively new and powerful technique for mineralogical research that has great potential in carbonate research. Owing to the short time interval between the completion of manuscripts and publication, much of the newer material in this volume is still "fresh." The various reviewers, all gratefully acknowledged, were expeditious in their efforts. A hurried schedule, however, allows for unnoticed errors to persist; these should be brought to my attention.

Description / Table of Contents: Geochemistry is a science that is based on an understanding of chemical processes in the earth. One of the principal tools available to the chemist for understanding systems at equilibrium is thermodynamics. The awareness and application of thermodynamic techniques has increased at a very fast pace in geosciences; in fact, one may be so bold as to say that thermodynamics in geology has reached the "mature" stage, although much future thermodynamic research is certainly needed. However, the natural processes in the earth are often sluggish enough that a particular system may not reach equilibrium. This observation is being supported constantly by new experimental and field data available to the geochemist e.g. the non-applicability of the phase rule in some assemblages, the compositional inhomogeneities of mineral grains, the partial reaction rims surrounding original minerals, the lack of isotopic equilibration or the absence of minerals (e.g. dolomite), which should be present according to thermodynamics. The need to apply kinetics has produced a large number of papers dealing with kinetics in geochemistry. As an initial response to this growing field, a conference on geochemical transport and kinetics was conducted at Airlie House, VA, in 1973, sponsored by the Carnegie Institution of Washington. The papers there dealt with several kinetic topics including diffusion, exsolution, metasomatism and metamorphic layering. Since 1973 the number of kinetic papers has continued to increase greatly. Therefore, the time is ripe for a Short Course in Kinetics, which brings together the fundamentals needed to explain field observations using kinetic data. It is hoped that this book may serve, not only as a reference for researchers dealing with the rates of geochemical processes, but also as a text in courses on geochemical kinetics. One of us has found this need of a text in teaching a graduate course on geochemical kinetics at Harvard and at Penn State during the past several years. Finally, it is our hope that the book may itself further even more research into the rates of geochemical processes and into the quantification of geochemical observations. The book is organized with a rough temperature gradient in mind, i.e. low temperature kinetics at the beginning and igneous kinetics at the end (no prejudices are intended with this scheme!). However, the topics in each chapter are general enough that they can be applied often to any geochemical domain: sedimentary, metamorphic or igneous. The theory of kinetics operates at two complementary levels: the phenomenological and the atomistic. The former relies on macroscopic variables (e.g. temperature or concentrations) to describe the rates of reactions or the rates of transport; the latter relates the rates to the basic forces operating between the particular atomic or molecular species of any system. This book deals with both descriptions of the kinetics of geochemical processes. Chapter one sets the framework for the phenomenological theory of reaction rates. If any geochemical reaction is to be described quantitatively, the rate law must be experimentally obtained in a kinetically sound manner and the reaction mechanism must be understood. This applies to heterogeneous fluid-rock reactions such as those occurring during metamorphism, hydrothermal alteration or weathering as well as to homogeneous reactions. Chapter 2 extends the theory to the global kinetics of geochemical cycles. This enables the kinetic concepts of stability and feedback to be applied to the cycling of elements in the many reservoirs of the earth. Chapter 3 applies the phenomenological treatment of chapter 1 to diagenesis and weathering. The rate of dissolution of minerals as well as the chemical evolution of pore waters are discussed. The atomistic basis of rates of reaction, transition state theory, is introduced in Chapter 4. Transition state theory can be applied to relate the rate constants of geochemical reactions to the atomic processes taking place. This includes not only homogeneous reactions but also reactions that occur at the surface of minerals. Chapter 5 discusses the theory of irreversible thermodynamics and its application to petrology. The use of the second law of thermodynamics along with the expressions for the rate of entropy production in a system have been used successfully since 1935 to describe kinetic phenomena. The chapter applies the concepts to the growth of minerals during metamorphism as well as to the formation of differentiated layers (banding) in petrology. Chapter 6 describes the phenomenological theory of diffusion both in aqueous solutions and in minerals. In particular, the multicomponent nature of diffusion and its consequence in natural systems is elaborated. Chapter 7 provides the atomistic basis for the rates of reactions in minerals. Understanding of the rates of diffusion, conduction, order-disorder reactions or exsolution in minerals depends on proper description of the defects in the various mineral structures. Chapter 8 provides the kinetic theory of crystal nucleation and growth. While many of the concepts in the chapter can be applied to aqueous systems, the emphasis is on igneous processes occurring during crystallization of a melt. To fully understand both the mineral composition as well as the texture of igneous rocks, the processes whereby new crystals form and grow must be quantified by using kinetic theory. Due to space and time limitations (kinetics!) some topics have not been covered in detail. In particular, the mathematical solution of diffusion or conduction equations is discussed very well by Crank in his book, Mathematics of Diffusion, and so is not covered to a great extent here. The treatment of fluid flow (e.g. convection) is also not covered in the text.

Description / Table of Contents: A new experimental method for measuring the soil-water diffusivity of frozen soil under isothermal conditions is introduced. The theoretical justification of the method is presented and the feasibility of the method is demonstrated by experiments conducted using marine-deposited clay. The measured values of the soil-water diffusivity are found comparable to reported experimental data.

Description / Table of Contents: An analysis of ice fracture that incorporates dislocation mechanics and linear elastic fracture mechanics is discussed. The derived relationships predict a brittle to ductile transition in polycrystalline ice under tension with a Hall-Petch type dependence of brittle fracture strength on grain size. A uniaxial tensile testing technique, including specimen preparation and loading system design was developed and employed to verify the model. The tensile strength of ice in purely brittle fracture was found to vary with the square root of the reciprocal of grain size, supporting the relationship that the theory suggests. The inherent strength of the ice lattice and the Hall-Petch slope are evaluated and findings discussed in relation to previous results. Monitoring of acoustic emissions was incorporated in the tests, providing insights into the process of microfracture during ice deformation.

Description / Table of Contents: Investigations of ground radar performance over thawed and seasonally frozen silts, and sands and gravels containing artificial and natural reflectors were carried out in Alaska. The radar emitted 5-10 ns pulses, the center frequency of which was approximately 150 MHz. The artificial reflectors were metal sheets and discs and the natural reflectors were the groundwater table and interfaces between frozen and thawed material. The water table was profiled at three sites where the subsurface material was coarse-grained alluvium. Dielectric constants of 16 to 18 were measured for the thawed silts, 6 to 7 for the frozen silts and 3 to 9 for the sands and gravels. Signal penetration in the thawed high moisture content silts may be achieved only by use of a lower frequency radar, whereas in the sands and gravels greater depths may be detected with more sophisticated signal processing.

Description / Table of Contents: A sea ice model was applied to the East Greenland Sea to examine a 60-day ice advance period beginning 1 October 1979. This investigation compares model results using driving geostrophic wind fields derived from three sources. Winds calculated from sea-level pressures obtained from the National Weather Service's operational analysis system resulted in strong velocities concentrated in a narrow band adjacent to the Greenland coast, with moderate velocities elsewhere. The model showed excessive ice transport and thickness build-ups in the coastal region. The extreme pressure gradient parallel to the coast resulted partially from a pressure reduction procedure that was applied to the terrain-following sigma coordinate system to obtain sea-level pressures. Additional sea-level pressure fields were obtained from an independent optimal interpolation analysis that merged FGGE buoys drifting in the Arctic basin with high latitude land stations and from manual digitization of the NWS hand-analyzed Northern Hemisphere Surface Charts. Modeling results using winds from both of these fields agreed favorably.

Description / Table of Contents: Ice action on two cylindrical and conical structures, located side by side, was investigated in a small-scale experimental study to determine the interference on the ice forces generated during ice-structure interaction. The proximity of the two structures changes the mode of ice failure, the magnitude and direction of ice forces on the individual structure, and the dominant frequency of ice force variations. Interference effects were determined by comparing the experimental results of tests at different structure spacings.

Description / Table of Contents: Ice accreted on high-speed rotors operating in supercooled fog can be thrown off by centrifugal force, creating severe unbalance and dangerous projectiles. A simple force balance analysis indicates that the strength of accreted ice and its adhesive strength can be obtained by measuring the thickness of the accretion, the location of the separation, the rotor speed, and the density. Such an analysis was applied to field and laboratory observations of self-shedding events. The results agree reasonably well with other observations.

Description / Table of Contents: Ice sheets are formed and retained in several ways in nature, and an understanding of these factors is needed before most structures can be successfully applied. Many ice sheet retention structures float and are somewhat flexible; others are fixed and rigid or semirigid. An example of the former is the Lake Erie ice boom and of the latter, the Montreal ice control structure. Ice sheet retention technology is changing. The use of timber cribs is gradually but not totally giving way to sheet steel pilings and concrete cells. New structures and applications are being tried but with caution. Ice-hydraulic analyses are helpful in predicting the effects of structures and channel modifications on ice cover formation and retention. Often, varying the flow rate in a particular system at the proper time will make the difference between whether a structure will or will not retain ice. The structure, however, invariably adds reliability to the sheet ice retention process.

Description / Table of Contents: A literature review indicated that the effects or permafrost on streambank erodibility and stability are not yet understood because systematic and quantitative measurements are seriously lacking. Consequently, general controversy exists as to whether perennially frozen ground inhibits lateral erosion and bankline recession, or whether it increases bank recession rates. Perennially frozen streambanks erode because of modification of the bank's thermal regime by exposure to air and water, and because of various erosional processes. Factors that determine rates and locations of erosion include physical, thermal and structural properties of bank sediments, stream hydraulics and climate. Thermal and physical modification of streambanks may also induce accelerated erosion within permafrost terrain removed from the immediate river environment. Bankline or bluffline recession rates are highly variable, ranging from less than 1 m/year to over 30 m/year and, exceptionally, to over 60 m/year. Long-term observations of the physical and thermal erosion processes and systematic ground surveys and measurements of bankline-bluffline recession rates are needed.

Description / Table of Contents: A mathematical model is described that is used to determine the maximum ice conveyance capacity of a river channel. Based upon this model, computer programs were developed that enable the ice discharge to be calculated for steady-state flow conditions. For rivers that have uniform flow, the maximum ice-conveying capacity can be described with a simple function expressed in terms of the size of the ice fragments, channel geometry, and the flow of water in the river. For nonuniform flows, the computer program determines the elevation profile of the surface layer in addition to other flow characteristics, such as the velocity and surface concentration of the ice fragments. The location along this surface profile where the ice conveyance capacity becomes less than the upstream supply is determined and is considered to be the position where a surface ice jam or ice bridge will be formed.

Description / Table of Contents: Ice forces on a bridge pier in the Ottauquechee River, in Quechee, Vermont, were measured by installing fourpanels-each capable of measuring forces in the normal and tangential direction - on both sides of a vertical V-shaped pier nose. The measured forces are presented for a short period during an ice run. After the ice run, the thickness and sizes of the ice floes were measured and the compressive strength of the ice was determined in the laboratory from the ice samples collected along the river banks. The water level measurements made at several locations along theriver are also presented for the period of the ice run.