ALBERT

Beschreibung / Inhaltsverzeichnis: This volume of Reviews in Mineralogy attempts to synthesize our present understanding of certain aspects of the mineralogy and chemistry of the rock-forming carbonates. Hopefully, it reflects the presently more active areas of research. This review follows, by ten years, a major assessment of (sedimentary) carbonate minerals by Lippmann (1973). There is only minor overlap of subject material, and I hope that this difference reflects fairly how this field has developed. In some respects carbonates are unique, for they are one of the few mineral groups providing an abundant record of biological, physical, and chemical processes throughout much of geologic time. Because of their relative importance in sedimentary rocks, lowtemperature examples are given more emphasis here. Moreover, the obvious correlation with energy resources has been a significant factor contributing to the current resurgence of interest in this area. However, the broader interest in carbonates is also a reflection of their widespread occurrence in vastly different geologic environments, including metamorphic and igneous settings, as well as an appreciation of their role in both atmospheric and oceanic chemistry, both past and present. In this volume, some of the papers are general (i.e., those addressing crystal chemistry and phase relations), and they provide overviews of a fundamental nature and are of interest to many. Others are more specialized in coverage and generally reflect the different approaches used in carbonate geochemistry. The final chapter introduces transmission electron microscopy, a relatively new and powerful technique for mineralogical research that has great potential in carbonate research. Owing to the short time interval between the completion of manuscripts and publication, much of the newer material in this volume is still "fresh." The various reviewers, all gratefully acknowledged, were expeditious in their efforts. A hurried schedule, however, allows for unnoticed errors to persist; these should be brought to my attention.

Beschreibung / Inhaltsverzeichnis: Geochemistry is a science that is based on an understanding of chemical processes in the earth. One of the principal tools available to the chemist for understanding systems at equilibrium is thermodynamics. The awareness and application of thermodynamic techniques has increased at a very fast pace in geosciences; in fact, one may be so bold as to say that thermodynamics in geology has reached the "mature" stage, although much future thermodynamic research is certainly needed. However, the natural processes in the earth are often sluggish enough that a particular system may not reach equilibrium. This observation is being supported constantly by new experimental and field data available to the geochemist e.g. the non-applicability of the phase rule in some assemblages, the compositional inhomogeneities of mineral grains, the partial reaction rims surrounding original minerals, the lack of isotopic equilibration or the absence of minerals (e.g. dolomite), which should be present according to thermodynamics. The need to apply kinetics has produced a large number of papers dealing with kinetics in geochemistry. As an initial response to this growing field, a conference on geochemical transport and kinetics was conducted at Airlie House, VA, in 1973, sponsored by the Carnegie Institution of Washington. The papers there dealt with several kinetic topics including diffusion, exsolution, metasomatism and metamorphic layering. Since 1973 the number of kinetic papers has continued to increase greatly. Therefore, the time is ripe for a Short Course in Kinetics, which brings together the fundamentals needed to explain field observations using kinetic data. It is hoped that this book may serve, not only as a reference for researchers dealing with the rates of geochemical processes, but also as a text in courses on geochemical kinetics. One of us has found this need of a text in teaching a graduate course on geochemical kinetics at Harvard and at Penn State during the past several years. Finally, it is our hope that the book may itself further even more research into the rates of geochemical processes and into the quantification of geochemical observations. The book is organized with a rough temperature gradient in mind, i.e. low temperature kinetics at the beginning and igneous kinetics at the end (no prejudices are intended with this scheme!). However, the topics in each chapter are general enough that they can be applied often to any geochemical domain: sedimentary, metamorphic or igneous. The theory of kinetics operates at two complementary levels: the phenomenological and the atomistic. The former relies on macroscopic variables (e.g. temperature or concentrations) to describe the rates of reactions or the rates of transport; the latter relates the rates to the basic forces operating between the particular atomic or molecular species of any system. This book deals with both descriptions of the kinetics of geochemical processes. Chapter one sets the framework for the phenomenological theory of reaction rates. If any geochemical reaction is to be described quantitatively, the rate law must be experimentally obtained in a kinetically sound manner and the reaction mechanism must be understood. This applies to heterogeneous fluid-rock reactions such as those occurring during metamorphism, hydrothermal alteration or weathering as well as to homogeneous reactions. Chapter 2 extends the theory to the global kinetics of geochemical cycles. This enables the kinetic concepts of stability and feedback to be applied to the cycling of elements in the many reservoirs of the earth. Chapter 3 applies the phenomenological treatment of chapter 1 to diagenesis and weathering. The rate of dissolution of minerals as well as the chemical evolution of pore waters are discussed. The atomistic basis of rates of reaction, transition state theory, is introduced in Chapter 4. Transition state theory can be applied to relate the rate constants of geochemical reactions to the atomic processes taking place. This includes not only homogeneous reactions but also reactions that occur at the surface of minerals. Chapter 5 discusses the theory of irreversible thermodynamics and its application to petrology. The use of the second law of thermodynamics along with the expressions for the rate of entropy production in a system have been used successfully since 1935 to describe kinetic phenomena. The chapter applies the concepts to the growth of minerals during metamorphism as well as to the formation of differentiated layers (banding) in petrology. Chapter 6 describes the phenomenological theory of diffusion both in aqueous solutions and in minerals. In particular, the multicomponent nature of diffusion and its consequence in natural systems is elaborated. Chapter 7 provides the atomistic basis for the rates of reactions in minerals. Understanding of the rates of diffusion, conduction, order-disorder reactions or exsolution in minerals depends on proper description of the defects in the various mineral structures. Chapter 8 provides the kinetic theory of crystal nucleation and growth. While many of the concepts in the chapter can be applied to aqueous systems, the emphasis is on igneous processes occurring during crystallization of a melt. To fully understand both the mineral composition as well as the texture of igneous rocks, the processes whereby new crystals form and grow must be quantified by using kinetic theory. Due to space and time limitations (kinetics!) some topics have not been covered in detail. In particular, the mathematical solution of diffusion or conduction equations is discussed very well by Crank in his book, Mathematics of Diffusion, and so is not covered to a great extent here. The treatment of fluid flow (e.g. convection) is also not covered in the text.

Beschreibung / Inhaltsverzeichnis: Although phyllosilicates are common in almost all types of rocks, their detailed study has not advanced in proportion to their importance. Books and reviews on this subject have been restricted primarily to the areas of clay mineralogy and soils. Such treatments understandably restrict coverage of the occurrences of the macroscopic-size species as well as much of their mineralogical and petrological nature. It was decided at the outset that not all phyllosilicates could be covered in a single book, and the size of this volume addressed only to the micas justifies the original decision. Kaolins, serpentines, chlorites, etc. will have to wait until some later date. This volume attempts to gather together much of our knowledge of micas, the most abundant phyllosilicate, and to indicate promising areas of future research. Chapters 1-3 lay the foundations of the classification, structures, and crystal chemistry of micas. Chapter 4 treats bonding and electrostatic modeling of micas. Chapters 5 and 6 cover spectroscopic and optical properties. Chapters 7-13, the bulk of the volume, are devoted to geochemistry and petrology. These include phase equilibria and the occurrences, chemistry, and petrology of micas in igneous, metamorphic, and sedimentary rocks, pegmatites, and certain ore deposits. Some treatments are exhaustive. All are at the forefront of our present knowledge, and indicate clearly the practical applications'of the study of micas to ascertaining various parameters of origin and crystallization history, as well as the many problems that still exist. The aim of this type of treatment is twofold -- to provide a handy reference volume for teachers and students and to enable researchers to pick more easily those directions and problems for which future research is most needed or is apt to be most productive or most challenging. X-ray powder patterns of micas in the literature are of surprisingly poor quality. The best are collated and supplemented with additional new patterns in the Appendix as an aid to identification.

Beschreibung / Inhaltsverzeichnis: A broadbanded impulse radar system was used for aerial detection of accumulated frazil and brash ice in a 9.5-km reach of the St. Lawrence River near Ogden Island. The remote sensing and data reduction system developed for the project provided data sufficient for production of a contour map having 1-ft intervals. With this contour map, the accumulation pattern of frazil and brash ice could be analyzed. Recommendations are given for improving the performance of the aerial profiling system.

Beschreibung / Inhaltsverzeichnis: This report presents experimental results on the conditions of initiation of an ice jam by a simple surface obstruction, on the equilibrium thickness of an ice jam formed by accumulation and submergence of ice floes, and on the compression strength of floating, fragmented ice cover. In the study on ice jam initiation, it was found that the minimum concentration of floes in the opening of the obstruction at which a jam occurs is nearly independent of the ratio of width of constricted passage to channel width, and is proportional to a negative power of the ratio of floe length to width of constricted passage. From energy analysis of floe submergence, a relationship relating the thickness of a jam formed by accumulation and submergence of floes to the approach flow characteristics was derived and found to fit satisfactorily the experimental data. In experiments on compression strength of floating, fragmented ice cover it was found that the compressive strength is inversely proportional to compression velocity and independent of cover length.

Beschreibung / Inhaltsverzeichnis: Ten roofs in Concord, New Hampshire, were surveyed for wet insulation using a hand-held infrared camera. Suspected wet areas were marked on the roof with spray paint and roof samples were obtained to verify wet and dry conditions. Recommendations for maintenance and repair were made based on infrared findings, water contents, and visual examinations. An incremental economic study is presented to serve as a guide in determining the most cost-effective approach.

Beschreibung / Inhaltsverzeichnis: A brief discussion is given of the ways an icebreaker breaks ice. Since the icebreaking process is so complex, the solution of a mathematical model does not appear to be feasible. As an alternative, it is suggested that physical models be used to design icebreakers. The appropriate scaling laws for physical models are developed and their practical limitation discussed.

Beschreibung / Inhaltsverzeichnis: A literature search was made for information on the accretion of ice on ocean structures and on methods for control. The bulk of the reports were in Russian, with some additional Japanese, British, American, Canadian, and Icelandic sources. Analysis of icing reports indicated that sea spray is the most important cause of ship icing, with lesser amounts due to freezing rain, snow, and fog. Icing is a potential danger whenever air temperatures are below the freezing point of water and the sea temperature is 6 C or lower. Theoretical work on the ice accretion process is discussed, and a method is suggested, based on Russian experiments, for calculating the sea spray accumulation rate for cylindrical and flat surfaces as a function of water source temperature, air temperature, and wind speed. Other factors that influence icing severity are ship size and configuration, angle between ship course and water heading, and ship speed. Icing in the north temperate latitudes generally occurs in the rear of barometric depressions. Maps showing limits of various degrees of icing severity are included. Atmospheric icing measurements on tall land-based structures are presented, and potential maximum accumulations estimated. Control measures are discussed, though no completely effective method is available. Mechanical (impaction) methods are the most common, but experiments have been conducted on heated, icephobic, and deformable surfaces, and with freezing point depressants. No device for the unequivocal measurement of ice accumulation is available, though some experimental methods are suitable for controlled testing; it is recommended that a device be developed.

Beschreibung / Inhaltsverzeichnis: Abstract: Ageneral computer model to simulate municipal snow removal has been developed. Programs which aid in the routing of snowplows are a part of this package. Once vehicle routes are created, the simulation program can be used to assess situations varying both equipment and meteorological parameters. Time for each plow to complete its route is calculated. Considerations are made for the above variable parameters plus plowing windrow, route starting depth, overlapping truck routes and intersection delay time. The effects of storm length, snowfall rate and starting depth on total plowing time are examined in a test case.

Beschreibung / Inhaltsverzeichnis: Cold weather limits the successful application of built-up roofing, but often a roof installation must be completed late in the fall or in the winter. The loose-laid protected membrane roof with a synthetic sheet membrane can be installed in the middle of the winter with complete reliability. A synthetic membrane is traditionally more expensive than built-up roofing (rising crude oil prices, however, have reversed this condition), but it has two special features besides its suitability for winter installation: it can be placed on a damp deck, if necessary, and, being losse-laid, it does not split because of deck movement. This report documents information on the installation of two roofs in Anchorage, Alaska, during January and February 1972, including a discussion of the necessary snow removal from the bare deck and the use of portable shelters for preparing the lap joints between sheets during very cold weather. The winter installation caused no special construction problems and the advantages of the synthetic membrane make it an attractive alternative to built-up roofing. The cost of loose-laid protected membrane roofs in Alaska was, in 1972, nearly $300 per square ($28/sq.m), including insulation. Prices are rising as labor costs rise and as more insulation is specified.

Beschreibung / Inhaltsverzeichnis: Tests were conducted to assess the extent of surface degradation resulting from the application of non-chloride deicing chemicals on three types of airfield pavements. The chemicals tested were proprietary mixtures of urea, formamide, and ethylene glycol; sodium chloride, distilled water, and dry specimens were used as controls and for comparison. Pavements included new and old specimens of open-graded asphaltic concrete and old specimens of dense-graded asphaltic concrete. Portland cement concrete specimens used were new and old, with and without air-entrainment. New and old tar rubber concrete specimens were also tested. Samples were subjected to up to 60 freeze-thaw cycles with deicing chemicals flooding their upper surface. Each specimen was rated on a scale of 0-5 after every five freeze-thaw cycles. All PCC specimens showed some surface degradation, whereas the dense- and open-graded asphaltic concretes were largely unaffected.

Beschreibung / Inhaltsverzeichnis: Subsurface aspects of the ore-forming process can be described in terms of standard chemical transport parameters such as T-P gradients, mineral solubilities, solvent chemistry and volume, diffusion parameters and energy flow. These necessary factors are rather easily assessed by geochemical, isotopic and structural studies. If deposition is in the surface environment, a complex array of factors will determine the success of the natural concentration process and the chances of preservation of a deposit. Basically, most large-scale ore-forming processes involve large fluid volumes and energy sources. Many environments where these requirements are met, the modern ocean ridge and the subduction environment, are still not well understood. The need for remote-sensing techniques in the submarine environment is stressed.