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  • Articles  (109)
  • Articles: DFG German National Licenses  (109)
  • nitrogen  (67)
  • air pollution
  • 1995-1999  (109)
  • Energy, Environment Protection, Nuclear Power Engineering  (106)
  • Process Engineering, Biotechnology, Nutrition Technology  (3)
  • Ethnic Sciences  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Methods for Detecting and Estimating Population Threshold Concentrations for Air Pollution–Related Mortality with Exposure Measurement Error (1999)
    Springer
    Risk analysis 19 (1999), S. 487-496 
    Details
    ISSN: 1539-6924
    Keywords: Threshold ; measurement error ; mortality ; air pollution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The association between daily fluctuations in ambient particulate matter and daily variations in nonaccidental mortality have been extensively investigated. Although it is now widely recognized that such an association exists, the form of the concentration–response model is still in question. Linear, no threshold and linear threshold models have been most commonly examined. In this paper we considered methods to detect and estimate threshold concentrations using time series data of daily mortality rates and air pollution concentrations. Because exposure is measured with error, we also considered the influence of measurement error in distinguishing between these two completing model specifications. The methods were illustrated on a 15-year daily time series of nonaccidental mortality and particulate air pollution data in Toronto, Canada. Nonparametric smoothed representations of the association between mortality and air pollution were adequate to graphically distinguish between these two forms. Weighted nonlinear regression methods for relative risk models were adequate to give nearly unbiased estimates of threshold concentrations even under conditions of extreme exposure measurement error. The uncertainty in the threshold estimates increased with the degree of exposure error. Regression models incorporating threshold concentrations could be clearly distinguished from linear relative risk models in the presence of exposure measurement error. The assumption of a linear model given that a threshold model was the correct form usually resulted in overestimates in the number of averted premature deaths, except for low threshold concentrations and large measurement error.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1007008914354
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  • 2
    Electronic Resource
    Electronic Resource
    Pure and Binary Gas Adsorption Equilibria and Kinetics of Methane and Nitrogen on 4A Zeolite by Isotope Exchange Technique (1999)
    Springer
    Adsorption 5 (1999), S. 145-158 
    Details
    ISSN: 1572-8757
    Keywords: kinetics ; isotope-exchange ; nitrogen ; adsorption ; methane ; zeolite ; equilibria
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Abstract The Isotope Exchange Technique (IET) was used to simultaneously measure pure and binary gas adsorption equilibria and kinetics (self-diffusivities) of CH4 and N2 on pelletized 4A zeolite. The experiment was carried out isothermally without disturbing the adsorbed phase. CH4 was selectively adsorbed over N2 by the zeolite because of its higher polarizability. The multi-site Langmuir model described the pure gas and binary adsorption equilibria fairly well at three different temperatures. The selectivity of adsorption of CH4 over N2 increased with increasing pressure at constant gas phase composition and temperature. This curious behavior was caused by the differences in the sizes of the adsorbates. The diffusion of CH4 and N2 into the zeolite was an activated process and the Fickian diffusion model described the uptake of both pure gases and their mixtures. The self-diffusivity of N2 was an order of magnitude larger than that for CH4. The pure gas self-diffusivities for both components were constants over a large range of surface coverages (0 〈 θ 〈 0.5). The self-diffusivities of CH4 and N2 from their binary mixtures were not affected by the presence of each other, compared to their pure gas self-diffusivities at identical surface coverages.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1008917308002
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  • 3
    Electronic Resource
    Electronic Resource
    Soil chemistry change in a lowland english deciduous Woodland 1974–1991 (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 677-682 
    Details
    ISSN: 1573-2932
    Keywords: soils ; acidification ; ancient woodland ; nitrogen ; environmental change
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This study outlines the results of analysis of soil samples collected from fixed quadrats located in a regular pattern across Wytham Wood. Oxfordshire, England. The site contains plots of mixed deciduous ancient woodland and more recent plantations. A previous soil study was undertaken in 1974 and samples archived. Soils were resampled in 1991 and some re-analysis of the 1974 samples was undertaken. Soils were of a wide range in types from sands to gravels with a pH range of 3.0–7.0. Results showed some decline in pH in lower horizons, but most striking was a large increase in soil nitrogen for all horizons and soil types.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00476907
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  • 4
    Electronic Resource
    Electronic Resource
    Deposition gradients and foliar and soil leachate concentrations of air pollutants in Scots pine stands of S.-E. Finland and the Karelian Isthmus, N.-W. Russia (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 1263-1268 
    Details
    ISSN: 1573-2932
    Keywords: air pollution ; sulphur ; nitrogen ; base cations ; throughfall ; Scots pine ; needle elements ; soil leachate ; N.-W. Russia
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Bulk precipitation and throughfall analyses in 50–100-year-old Scots pine stands revealed decreasing sulphur, nitrogen, calcium and magnesium deposition gradients, which extend from the St. Petersburg-Leningrad region and N.-E. Estonia to S.-E. Finland. The Ca and Mg deposition alleviate the acidifying effect of sulphur and nitrogen. The Scots pine canopies acted as a sink for ammonium and nitrate, while the canopy interactions increased sulphur, calcium and magnesium content in throughfall. Foliar S, N and Ca concentrations correlated positively with the corresponding deposition loads. In contrast, low foliar magnesium concentrations were detected in the vicinity of St. Petersburg. The results indicate that the sulphur and calcium deposition may have increased soil leachate S and Ca concentrations in the most polluted Scots pine stands.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00477155
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  • 5
    Electronic Resource
    Electronic Resource
    Cost-Effective Nutrient Reductions to the Baltic Sea (1997)
    Springer
    Environmental and resource economics 10 (1997), S. 341-362 
    Details
    ISSN: 1573-1502
    Keywords: Baltic Sea ; eutrophication ; nitrogen ; phosphorus ; cost effective
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract Due to eutrophication caused by heavy loads of nitrogen and phosphorus, the biological conditions of the Baltic Sea have been disturbed: large sea bottom areas without any biological life, low stocks of cods, and toxic blue green algaes. It is recognized that the nitrogen and phosphorus loads to the Baltic Sea must be reduced by 50% in order to restore the sea. The main purpose of this paper is to calculate cost effective nitrogen and phosphorus reductions to the Baltic Sea from the nine countries surrounding the Baltic Sea. The results show a significant difference in minimum costs of decreasing nitrogen and phosphorus loads to the Sea: approximately 12 000 millions of SEK per year and 3 000 millions of SEK respectively for reductions by 50%. It is also shown that a change from a policy of cost-effective nutrient reductions to a policy where each country reduces the nutrient loads by 50% increase total costs for both nitrogen and phosphorus reductions by about 300%. The results are, however, sensitive to several of the underlying assumptions and should therefore be interpreted with much caution.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1026497515871
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  • 6
    Electronic Resource
    Electronic Resource
    The U.S. allowance trading system for sulfur dioxide: An update on market experience (1995)
    Springer
    Environmental and resource economics 5 (1995), S. 115-129 
    Details
    ISSN: 1573-1502
    Keywords: Emission trading ; United States ; sulfur dioxide ; air pollution ; costs ; cost-effectiveness
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract In 1990, the U.S. Congress passed legislation that amended the Clean Air Act to create a new program to mitigate the effects of acid deposition in the U.S. through emission reductions of sulfur dioxide (SO2) and nitrogen oxides (NOx) at electric utility plants across the country. The SO2 reductions, totalling a 40% reduction nationally from 1980 levels or a 10 million ton reduction annually, are achieved largely through an emission trading system, the largest program of its kind designed to date. This trading system has the potential to save up to half of the compliance costs associated with more traditional source-by-source emission limit programs. This paper briefly discusses background on the acid rain issue in the United States, and the principal features of the program, including: a permanent cap on utility emissions of SO2 beginning in 2010, decision to grant up-front allocation of emission credits to reduce individual approvals of trades, the use of continuous emission monitors and automatic penalties to ensure compliance, and integration of the Acid Rain program requirements with other Clean Air Act programs. The paper also discusses the development of the allowance trading market to date, including the types of compliance options chosen and quantity and type of emissions trading being conducted.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00693019
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  • 7
    Electronic Resource
    Electronic Resource
    Ordering effects in contingent valuation surveys (1996)
    Springer
    Environmental and resource economics 8 (1996), S. 485-499 
    Details
    ISSN: 1573-1502
    Keywords: contingent valuation ; ordering effects ; air pollution ; health damage
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract This paper focuses on ordering effects in CVM surveys; how the expressed value of a particular good valued in a sequence of several goods depends on where in the sequence the good is valued. We use data from a Norwegian CVM survey focusing on WTP for a 50% reduction in air pollution from car traffic to test for the existence of ordering effects and to apply a test for internal consistency. We found considerable and significant ordering effects in our data, but were not able to reject the hypothesis of internal consistency. Based on our survey, we argue that ordering effects may be a result of rational choice. These effects are problematic if a sequential valuation procedure is applied to a simultaneous problem, and/or the respondents are given imperfect information about the decision problem.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00357416
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  • 8
    Electronic Resource
    Electronic Resource
    Sulphur and nitrogen deposition in Norway, status and trends (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 623-628 
    Details
    ISSN: 1573-2932
    Keywords: monitoring ; deposition ; sulphur ; nitrogen
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The total deposition of sulphur (S) and nitrogen (N) components in Norway during the period 1988–1992 has been estimated on the basis of measurement data of air- and precipitation chemistry from the national monitoring network. There are large regional variations in depositions with highest values in the southwestern part of Norway. Time series analysis of annual mean concentrations of sulphur dioxide (SO2) and sulphate (SO4 −−) in air, non marine SO4 −−, nitrate (NO3 −) and ammonium (NH4 +) in precipitation, shows a significant reduction in the S concentrations both in air and precipitation. In precipitation the concentrations are reduced by 30–45 percent in Southern Norway and 45–55 percent in Central and Northern Norway. Even larger reductions are observed in air concentrations with 50–65 percent reduction in Southern Norway and 65–88 percent reduction further north. For N components there are generally no significant trends in concentration levels nor in precipitation or air. The observed trends are comparable with reported trends in emission.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00476898
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  • 9
    Electronic Resource
    Electronic Resource
    Effects of ambient air pollution on wheat and rice yield in Pakistan (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 1311-1316 
    Details
    ISSN: 1573-2932
    Keywords: Pakistan ; air pollution ; ozone ; nitrogen dioxide ; rice ; wheat ; filtration ; yield
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Open-top chambers ventilated with ambient or chiarcoal-filtered air were used to assess the impact of air pollution on the yield of local cultivars of wheat and rice, at a site on the outskirts of Lahore. At this location, 6-h mean O3 concentrations reach 60 ppb in certain months, and annual mean NO2 concentrations are 20–25 ppb. The experiments showed significant yield reduction in two successive seasons which ranged from 33% to 46% in wheat and from 37% to 51% in rice. The major yield parameter affected was the number of ears or panicles per plant, although there was also evidence of small effects on 1000 grain weight and on the number of grains per ear/panicle. These results have significance in terms of the maintenance of agricultural yields as pollution emissions rise in south and south-east Asia.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00477163
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  • 10
    Electronic Resource
    Electronic Resource
    Assessment of the use of principal components analysis to relate air and precipitation chemistry to climate (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 1569-1574 
    Details
    ISSN: 1573-2932
    Keywords: synoptic circulation ; principal components analysis ; air pollution ; climate change ; classification
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A classification of atmospheric circulation was derived using principal components analysis (PCA) of daily sea level pressure over a 10 year period. Correlation coefficients of up to 0.65 were obtained between the individual principal component loadings and monthly means of gas and precipitation ion concentrations for a Scottish and a Norwegian station from the European Monitoring and Evaluation Programme (EMEP) network. The mean synoptic patterns of months predicted to have high or low gas and ion concentrations from their component loadings agreed well with previous work. High concentrations occur frequently with southerly flow or anticyclonic conditions, and low concentrations with westerly and northwesterly flow. We conclude that the PCA classification is a sensible method to use to derive circulation pattern-pollutant relationships, and is an encouraging first step to use the general circulation model (GCM) projections of future climate to assess possible future air/precipitation composition patterns
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00477204
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  • 11
    Electronic Resource
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    Indirect effects of N and S deposition on a Norway spruce ecosystem. An update of findings within the Skogaby project (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 1613-1622 
    Details
    ISSN: 1573-2932
    Keywords: Deposition ; ecosystem ; nitrogen ; Norway spruce ; nutrient cycling ; production ; root function ; sulphur
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In this paper we try to interpret results from different investigations where an ecosystem with Norway spruce was manipulated with increased N and S deposition via the soil system. The site, in Skogaby in Southwest Sweden, had 1989–93 an annual deposition of 9 kg NH4-N; 7 kg NO3-N and 20 kg SO4-S ha−1. The stand was treated during 6 years with 100 kg N and 114 kg S ha− y−1 in the form of ammonium sulphate (NS treatment). The stand reacted with increased above ground production of 31% after 3 years of treatment. The uptake above ground of N was 155 kg ha−1 higher than in the control. Those trends were even stronger after 6 years of treatment. There were no decreases in the uptake of P, K, Ca or Mg (but for B) after 3 or 6 years of NS-treatment. Needle macro nutrient concentrations in relation to N decreased for several nutrients due to dilution effects. As result of the NS treatment pH increased markedly in the litter layer, and less, but significantly, in the humus layer. A decrease in pH value by about 0.3 units was found in the rest of the soil profile down to 50 cm. Dry mass of needle litter fall and litter layer both increased as a result of 6 years of NS-treatment. After three years of treatment 77–80% of all living fine roots in both control and NS treatment were found in the humus layer and the upper 10 cm of the mineral soil. The amount of living fine roots in the humus layer of NS-treated trees decreased to about one third of the control, and the amount of dead fine roots increased by 150% compared with untreated trees after 6 years of treatment. It is argued that the decreased amount of living and increased amount of dead fine roots not necessarily are indications of decreased root vitality. It can also be explained by increased root turnover rate and decreased decomposition rates of N rich new and old fine root litter. No inorganic N was leached from the control plots whereas the NS treated plots started to leach NO3 the second year of treatment. During 1989–1993 a total of 44 kg NO3-N and 30 kg NH4-N per ha was lost from the system which means that 88% of the N supplied was retained by the ecosystem. At first SO4 was adsorbed in the soil, but after five years of treatment the output was almost equal to the input.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00477211
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  • 12
    Electronic Resource
    Electronic Resource
    Ecological studies in the ratanica catchment (Carpathian foothills, S Poland) — An overview (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 1635-1640 
    Details
    ISSN: 1573-2932
    Keywords: forested catchment ; air pollution ; nutrients ; pollutants ; balance ; plant bioindicators ; forest damage
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This paper includes an overview of ecological studies conducted since 1986 in the Ratanica pine-beech forested catchment located in the polluted, high populated southern part of Poland. General characteristics of the catchment (including soil and vegetation, air pollution, input/output of nutrients and pollutants, element budget data and forest health assessment) are presented. Based on biogeochemical and bioindication results, the Ratanica catchment has been classified as a moderately to heavily deteriorated area. Predictions for this forested catchment for various deposition of anthropogenic pollutants, are also disscused.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00477214
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  • 13
    Electronic Resource
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    Forest health monitoring in Canada: How healthy is the boreal forest? (1995)
    Springer
    Water, air & soil pollution 82 (1995), S. 77-85 
    Details
    ISSN: 1573-2932
    Keywords: boreal forests ; forest health ; air pollution ; detection
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The Canadian boreal forest covers 299.2 Mha which is two-thirds of Canada's forest and runs in a continuous belt from Newfoundland north and west to the Yukon. The major species are spruce, pines, balsam fir, white birch and trembling aspen often occurring in extensive monocultures. Wildfire is the driving successional force in the boreal forest and has remained so despite fire suppression activities and extensive harvesting. Insects and diseases also cause extensive damage. In order to ensure the sustainability of forests, it is necessary for the forest manager to know the condition of the health of these forests. The CFS established in 1984 the Acid Rain National Early Warning System in order to monitor the health of the forests. National results show that mortality is generally in the normal range of 1–3% and is caused by known stresses; insects, diseases and abiotic damage. No signs of pollution damage have been yet been detected in boreal forests by the system. An early warning system to detect and monitor conditions remains an essential part of our commitment to the sustainability of Canada's forests.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01182821
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  • 14
    Electronic Resource
    Electronic Resource
    Acid deposition: Perspectives in time and space (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 15-24 
    Details
    ISSN: 1573-2932
    Keywords: Acid deposition ; global change ; Asia ; fertilizer ; nitrogen ; sulfur
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Most acid-deposition investigations have been concerned with the impact of nitrogen oxides (NOx) and sulfur dioxide (SO2) emissions on Europe and North America. This paper examines three issues beyond this central focus. Major conclusions are 1) ammonia (NH3) emissions and subsequent nitrogen (N) accumulation in terrestrial ecosystems have the potential to generate significant acidification in terrestrial and aquatic ecosystems; 2) sulfur (S) and N accumulation in environmental reservoirs will not only result in significant and extensive acidification but will also impact the earth's radiation balance, tropospheric oxidizing capacity, ecosystem nutrient balance and groundwater quality; and 3) future emissions will substantially increase in the developing world, especially in Asia. By 2020, Asian emissions of SO2, NOx and NH3 will be equal to or greater than the combined emissions from Europe and North America.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00483685
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  • 15
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    Global forest systems: An uncertain response to atmospheric pollutants and global climate change? (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 101-110 
    Details
    ISSN: 1573-2932
    Keywords: carbon ; nitrogen ; sulfur ; biogeochemistry ; mitigation ; global change
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Forest systems cover more than 4.1×109 ha of the Earth's land area. The future response and feedbacks of forest systems to atmospheric pollutants and projected climate change may be significant. Boreal, temperate and tropical forest systems play a prominent role in carbon (C), nitrogen (N) and sulfur (S) biogeochemical cycles at regional and global scales. The timing and magnitude of future changes in forest systems will depend on environmental factors such as a changing global climate, an accumulation of CO2 in the atmosphere, and increase global mineralization of nutrients such as N and S. The interactive effects of all these factors on the world's forest regions are complex and not intuitively obvious and are likely to differ among geographic regions. Although the potential effects of some atmospheric pollutants on forest systems have been observed or simulated, large uncertainty exists in our ability to project future forest distribution, composition and productivity under transient or nontransient global climate change scenarios. The potential to manage and adapt forests to future global environmental conditions varies widely among nations. Mitigation practices, such as liming or fertilization to ameliorate excess NOx or SOx or forest management to sequester CO2 are now being applied in selected nations worldwide.
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    URL: http://dx.doi.org/10.1007/BF00483692
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  • 16
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    Estimate of health impacts of acidifying air pollutants and tropospheric ozone in Europe (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 167-176 
    Details
    ISSN: 1573-2932
    Keywords: air pollution ; health effects ; risk assessment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Based on combined information available from air quality monitoring data and long-range transport models, European population exposure to SO2, NO2 and O3 has been estimated. This information has been combined with the results of epidemiological studies assessing strength of association between the exposure and health effects to estimate an impact of the pollution on health in Europe. The analysis indicates that a considerable number of health problems, ranging from mild irritation of the respiratory system to increased mortality, can be attributed to short-term peaks of pollution observed in Europe. Chronic impacts of prolonged elevated SO2 levels on lung function are estimated to occur in close to10 million people in Europe.
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    URL: http://dx.doi.org/10.1007/BF00483698
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  • 17
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    Health effects of acid aerosols (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 177-188 
    Details
    ISSN: 1573-2932
    Keywords: health ; air pollution ; acidity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Earlier in this century, a number of severe episodes clearly demonstrated that air pollution can affect human health; these included documented increases in mortality and morbidity. Although health was clearly affected during these episodes and acidity is a candidate for the responsible agent, it has been difficult to ascertain which agents were involved. In the past several years extensive research was launched to learn the significance of acidic aerosols on human health. The question of a health threat from acid aerosols was first raised by epidemiology studies, but results of the body of epidemiological evidence collected to date have been mixed. Even when a study finds evidence of a response to exposures involving high ambient acidity levels, it is usually difficult to know which agent or agents are responsible for causing the effects noted. High levels of acidic aerosols are nearly always accompanied by high levels of other air pollutants which may have known or suspected effects on the respiratory tract. For this reason, an understanding of the potential mechanisms of acid aerosol health effects needs supporting evidence from the laboratory, where exposures to various agents can be controlled. To date, this supporting evidence includes demonstration of physiological responses at acidity levels greater than those that exist in the ambient environment. A limited number of studies have considered responses at levels more characteristic of ambient exposures; these studies demonstrate little physiological response, probably due to the airways' ability to buffer acidity at low concentration. Although there is some evidence of impaired mucociliary clearance and modest changes in lung function, there is no evidence of airway inflammation or altered non-specific bronchial responsiveness as a result of acid aerosol exposure. The possibility that acid aerosols may potentiate responses to other pollutants remains a subject of interest. The potential existence of a group of individuals who are exquisitely sensitive to low acid concentrations requires further investigation. Recent epidemiology results are broadening the perspective from a focus on acidity per se to a focus on fine particulate matter, of which particulate acidity is but a subset. These studies find a consistent statistical association between various health responses, including mortality, and ambient measures of particulates, even at locations where levels of acidity are very low and at locations where current U.S. air quality standards are satisfied. There is at present no biological explanation for these associations.
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    URL: http://dx.doi.org/10.1007/BF00483699
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  • 18
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    Nutrient balance in Scots pine (Pinus sylvestris L.) forest. 2. Effects of plant growth and N-deposition on soil solution and leachate chemistry in a lysimeter experiment (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 1149-1154 
    Details
    ISSN: 1573-2932
    Keywords: forest soil ; leaching ; lysimeter ; nitrogen
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Three years of N application to a Cambic arenosol (Typic Udorthent) in two lysimeter series, one with and one without young saplings of Pinus sylvestris L. have produced significant changes in soil solution and leachate chemistry. An application of 30 kg N/ha*yr−1 significantly increased NO3 − leaching from the soil. This N load was also sufficient to significantly increase the mobility of the phyto-toxic elements Al3+ and Mn2+, likewise to increase leaching of the important plant nutrients Ca2+, Mg2+ and K+. At a N load of 90 kg N/ha*yr−1 significant increase in NH4 + leaching was observed, but total leaching of NH4 + was still very low compared to NO3 − leaching. No significant treatment effects were found for SO4 2−, Fe2+ and Cl− in the leachate. Trees grown in the lysimeters buffered the acidifying effect of N application and increased the leachate pH by 0.2 pH units compared to lysimeters without trees.
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    URL: http://dx.doi.org/10.1007/BF00477136
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  • 19
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    Effects of nitrogen load to the forest floor in sitka spruce stands (Picea sitchensis) as affected by difference in deposition and spruce aphid infestations (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 1173-1178 
    Details
    ISSN: 1573-2932
    Keywords: sitka spruce ; nitrogen ; deposition ; leaching ; proton production ; green spruce aphid
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Studies of biogeochemical cycling and soil acidification have been carried out in even aged stands of Norway spruce, sitka spruce, Douglas fir, beech and oak under the frame of “The Element Cycling Project”. Deposition of excess nitrogen to forests is important as a potential acidifying input. In Denmark, reduced vitality in Norway spruce has promoted extensive planting of sitka spruce. However, several spruce aphid infestations have caused defoliation in many sitka spruce stands. The objectives of this study were to evaluate the effects of deposition and increased litterfall due to spruce aphid infestations on nitrogen transformations in the forest floor in sitka spruce stands on different soil types. The deposition of throughfall nitrogen range from 19 to 35 kg/ha/year. Fluxes of nitrogen in litterfall ranged from 21 to 77 kg/ha/year, whereas nitrogen leaching range from 1 to 57 kg/ha/year. Leaching was lowest at the infertile sites, but increased with magnitude of deposition and aphid infestations. Proton production according to the nitrogen transformations was largest at the fertile site most often affected by infestations. Huge amounts of bird droppings, honey dew and input of easily available nutrients by canopy leaching probably induced litter decomposition and formation of NO 3 − in the soil water.
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    URL: http://dx.doi.org/10.1007/BF00477140
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    Elevational trends in the fluxes of sulphur and nitrogen in throughfall in the Southern Appalachian Mountains: Some surprising results (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 2265-2270 
    Details
    ISSN: 1573-2932
    Keywords: atmospheric deposition ; high elevation forests ; foliar uptake ; cloudwater ; nitrogen ; sulphur
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract From 1986–1989, a team of scientists measured atmospheric concentrations and fluxes in precipitation and throughfall, and modeled dry and cloudwater deposition in a spruce-fir forest of the Great Smoky Mountains National Park which is located in the Southern Appalachian Region of the United States. The work was part of the Integrated Forest Study (IFS) conducted at 12 forests in N. America and Europe. The spruce-fir forest at 1740 m consistently received the highest total deposition rates (∼2200, 1200, and 700 eq ha−1 yr−1 for SO4 2−, NO3 −, and NH4 +). During the summers of 1989 and 1990 we used multiple samplers to measure hydrologie, SO4 2−, and NO3 − fluxes in rain and throughfall events beneath spruce forests above (1940 m) and below (1720 m) cloud base. Throughfall was used to estimate total deposition using relationships determined during the IFS. Although the SO4 2− fluxes increased with elevation by a factor of ∼2 due to higher cloudwater interception at 1940 m, the NO3 − fluxes decreased with elevation by ∼30%. To investigate further, we began year round measurements of fluxes of all major ions in throughfall below spruce-fir forests at 1740 m and at 1920 m in 1993–1994. The fluxes of most ions showed a 10–50% increase with elevation due to the ∼70 cm yr−1 cloudwater input at 1920 m. However, total inorganic nitrogen exhibited a 40% lower flux in throughfall at 1920 m than at 1740 m suggesting either higher dry deposition to trees at 1740 m or much higher canopy uptake of nitrogen by trees at 1920 m. Differential canopy absorption of N by trees at different elevations would have significant consequences for the use of throughfall N fluxes to estimate deposition. We used artificial trees to understand the foliar interactions of N.
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    URL: http://dx.doi.org/10.1007/BF01186171
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    Sulphur and nitrogen input to the Ratanica forested catchment (Carpathian Foothills, southern Poland) (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 1765-1770 
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    ISSN: 1573-2932
    Keywords: nitrogen ; sulphur ; input ; forested catchment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The study covers 1991–1994 concentrations of SO2 and NO2 in the air, concentrations of sulphur and nitrogen in bulk precipitation, throughfall and stemflow as well as input of S and N to the Ratanica forested catchment (S. Poland), which is exposed to moderate anthropogenic pollution are presented. There was high input of sulphur (26 kg ha−1) and nitrogen (24 kg ha−1) to the catchment, mainly in NH4+ (18 kg ha−1). The significant contribution of NH4 + connected with intensive agriculture in surrounding fields has led to eutrophication of the ecosystem.
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    URL: http://dx.doi.org/10.1007/BF00477235
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    Response of a white clover indicator system to tropospheric ozone at eight locations in the United States (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 1373-1378 
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    ISSN: 1573-2932
    Keywords: tropospheric ozone ; white clover ; air pollution ; biomonitor
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A white clover (Trifolium repens L.) system using measured biomass to indicate effective concentrations of tropospheric ozone (O3) has been developed. The system utilizes the relative response of an O3-sensitive clone (NC-S) and an O3-resistant clone (NC-R) grown in 15-liter pots. Forage (leaves, stems and flowers) is cut, dried, and weighed at 28-day intervals. Forage dry weight ratios (NC-S/NC-R) for individual or multiple harvests indicate O3 concentrations during growth. In, 3 years of testing in open-top field chambers at Raleigh, North Carolina, O3 always decreased growth of NC-S more than that of NC-R and the NC-S/NC-R ratio routinely decreased as the O3 concentration increased. A national field test was performed in 1993 and 1994 to determine if the clover system can account for effects of climatic variables on clover growth per-se, and if climatic variables affect the relative response of the two clones to O3. Eight locations (Corvallis, Oregon; Kennedy Space Center, Florida; Delaware, Ohio; Amherst, Massachusetts; Blacksburg, Virginia; Raleigh, North Carolina; Riverside, California; San Bemardino mountains, California) provided large differences in O3 concentrations and climate. The NC-S/NC-R forage ratios for three consecutive 28-day growth periods for each year as related to the mean 12 hour per day O3 concentrations are presented in this manuscript. Ratios were generally highest where mean O3 concentrations were lowest (Oregon and Florida), lowest where mean O3 concentrations were highest (both California locations), and intermediate at other locations.
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    URL: http://dx.doi.org/10.1007/BF00477173
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    Biogeochemistry of a forested watershed in the central Adirondack Mountains: Temporal changes and mass balances (1996)
    Springer
    Water, air & soil pollution 88 (1996), S. 355-369 
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    ISSN: 1573-2932
    Keywords: atmospheric deposition ; ecosystem ; hydrology ; nitrogen ; sulfur
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Information on atmospheric inputs, water chemistry and hydrology were combined to evaluate elemental mass balances and assess temporal changes in elemental transport from 1983 through 1992 for the Arbutus Lake watershed. This watershed is located within a northern hardwood ecosystem at the Huntington Forest within the central Adirondack Mountains of New York (USA). Changes in water chemistry, including increasing NO3 − concentrations (1.1 μmol c , L−1 yr-1), have been detected during this study period. Starting in 1991 hydrological flow has been measured from Arbutus Lake and these measurements were compared with predicted flow using the BROOK2 hydrological simulation model. The model adequately (r2=0.79) simulated flow from this catchment and was used to estimate drainage for earlier periods when direct hydrological measurements were not available. Modeled drainage water losses coupled with estimates of wet and dry atmospheric deposition were used to calculate solute budgets. Export of SO4 2− (831 mol c ha−1 yr−1) from the greater Arbutus Lake watershed exceeded estimates of atmospheric deposition in an adjacent hardwood stand suggesting an additional source of S. These large drainage losses of SO4 2− also contributed to the drainage fluxes of basic cations (Ca2+, Mg2+, K+ and Na+). Most of the atmospheric inputs of inorganic N were retained (average of 74% of wet precipitation and 85% total deposition) in the watershed. There were differences among years (56 to 228 mol ha−1 yr−1) in drainage water losses of N with greatest losses occurring during a warm, wet period (1989–1991).
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    URL: http://dx.doi.org/10.1007/BF00294111
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    Chemical characteristics of leachate from pulp and paper mill residuals used to reclaim a sandy soil (1996)
    Springer
    Water, air & soil pollution 89 (1996), S. 167-187 
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    ISSN: 1573-2932
    Keywords: Pulp and paper mill sludge ; nitrogen ; DOC ; heavy metals ; water quality
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Primary sludge, secondary sludge, and wood ash from a pulp and paper mill were combined with sand to create a synthetic topsoil (C:N ratio of 18:1) to restore an abandoned gravel pit. Synthetic topsoil was applied to field microcosms at rates equivalent to 0, 2170, 4341, or 6511 kg N/ha; each was seeded with grass. Fifteen chemical constituents in leachate were measured during two field seasons. Cadmium, Ni and Zn were mobilized rapidly by soil disturbance. Chloride and SO4-S eluted rapidly from the sludge along with Na. Nitrate leached with Ca late in each field season when sludge N-mineralization and nitrification exceeded plant uptake and microbial immobilization. Ammonium elution was negligible. Dissolved organic carbon (DOC) was mobilized by decomposition of organic matter in the sludge, as were Mg and K. Copper eluted with DOC, probably as an organic ligand. Lead and ortho-P were below our detection limits. We concluded that a synthetic topsoil with a 30:1 C:N ratio applied at a rate of 2100-4300 kg N/ha should provide adequate plant nutrition while minimizing water quality hazards.
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    Sediment Accumulation of Nutrients (N, P) in the Eastern Gulf of Finland (Baltic Sea) (1997)
    Springer
    Water, air & soil pollution 99 (1997), S. 477-486 
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    ISSN: 1573-2932
    Keywords: sediment ; nitrogen ; phosphorus ; organic matter ; cluster analysis ; Gulf of Finland ; estuaries
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Dry weight (DW), ignition loss (IL) and concentrations of total nitrogen (TN) and total phosphorus (TP) of the sediment surface layer (0 to 10 cm, 1 cm slices) were analyzed from 20 sites in the eastern Gulf of Finland. The distance of the sampling sites from the mouth of the River Neva explained the nutrient concentrations of the sediments well, while the effect of water depth was negligible. The increase of TN and the decrease of TP along the transect from the river mouth towards the open Gulf were caused by the diminishing share of allochthonous material supplied from the River Neva. The mean TN concentration of the different accumulation areas was about 40 % higher in the sediment surface than in the deeper layer (9 to 10 cm). The corresponding difference for TP varied from 53 to 56 %. The results suggest considerable netflux of nutrients from sediment to water. The net sediment accumulation of nutrients were estimated as 6.0 g m-2 a-1 of N and 1.7 g m-2 a-1 of P corresponding 22 000 t a-1 of N and 6 100 t a-1 of P for the whole eastern Gulf.
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    URL: http://dx.doi.org/10.1023/A:1018399625103
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    Sulphur and heavy metal concentrations in Scots pine bark in northern Finland and the Kola peninsula (1997)
    Springer
    Water, air & soil pollution 93 (1997), S. 395-408 
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    ISSN: 1573-2932
    Keywords: air pollution ; pine bark ; sulphur ; pH ; conductivity ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Sulphur and heavy metal deposition in northern Finland (= in Lapland) and the Kola Peninsula were surveyed using Scots pine bark samples. Sulphur concentrations in bark close to the Kola smelters were on an average twice as high as on the Finnish side of the border. The Cu and Ni concentrations near the smelters were almost 100-fold the mean values in northern Finland. There was a marked decrease in the sulphur and heavy metal concentrations with increasing distance from the emission sources. The effects of emission from the Kola Peninsula were evident in Finland only close to the border, especially in the eastern parts of Inari (NE corner of Lapland) where the Cu and Ni concentrations were 2- to 6-fold those in western Lapland. The sulphur and heavy metal concentrations in most of northern Finland were low. However were the concentrations of Cr in bark in the SW corner of Lapland considerably high, due to the emissions from the Tornio refined steel plants.
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    URL: http://dx.doi.org/10.1007/BF02404769
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    Benthic fluxes of dissolved inorganic carbon, nutrients and oxygen in the Gulf of Trieste (Northern Adriatic) (1997)
    Springer
    Water, air & soil pollution 99 (1997), S. 305-314 
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    ISSN: 1573-2932
    Keywords: Adriatic Sea ; nutrients ; benthic fluxes ; carbon ; nitrogen ; silicon ; phosphorus ; budgets
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Benthic fluxes of dissolved inorganic N, Si and P nutrients, alkalinity, dissolved inorganic C (DIC), and O2 from sediments in the Gulf of Trieste (northern Adriatic, Italy) were measured monthly in the period September 1995 – August 1996 using in situ incubated light benthic chambers. The highest efluxes of DIC, NH4 +, PO4 3−, Si(OH)4, and NO3 − influxes encountered in late summer — early autumn were the consequence of degradation of benthic microalgae, and in autumn mostly of sedimented phytoplankton. High NO3 − efflux was observed in spring. Only NH4 + and Si(OH)4 fluxes were significantly correlated with temperature. This correlation suggests that the rate of downward input and the quality and quantity of sedimentary organic matter (autochthonous and allochthonous) were superimposed on the temperature fluctuations. High DIC, NH4 + and Si(OH)4 effluxes observed in July 1996 were due to the late spring — early summer degradation of sedimentary organic matter produced by benthic microalgae, while the autumn phytoplankton bloom was quickly reflected in enhanced benthic fluxes due to higher temperature. Significant correlations between NH4 +, PO4 3− and Si(OH)4 fluxes suggested their parallel regeneration and utilization at the sediment-water interface. The nutrient fluxes were linked to O2 consumption, suggesting that aerobic oxidation processes were important at the sediment-water interface in the Gulf. The N, P and Si nutrients released from sediment pore waters are probably utilized in benthic microalgal and bottom-water primary production. This indicates that pelagic and benthic communities in the central part of the Gulf of Trieste function relatively independently of each other.
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    URL: http://dx.doi.org/10.1007/BF02406870
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    Monitoring nitrogen pollution from sugarcane runoff using15N analysis (1997)
    Springer
    Water, air & soil pollution 98 (1997), S. 389-399 
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    ISSN: 1573-2932
    Keywords: fertilizer ; nitrogen ; pollution ; runoff ; stable isotopes ; sugarcane
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In many forested wetlands of Louisiana, surface water quality is being deteriorated by nutrient input from adjacent agricultural production area. This field study assesses the input of fertilizer N, applied to sugarcane fields, to forested wetlands. The potential use of natural abundance variations in15N/14N ratios for identification and tracing surface water N sources (NH 4 + - and NO 3 − -N) was evaluated. Runoff and surface water samples were collected from sugarcane fields and bordering forested wetlands (6 stations) over a 16 month period and analyzed for NH 4 + -N, NO 3 − -N, and associated NH 4 + -δ 15N and NO 3 − -δ 15N ratios. FertilizerN draining into adjacent forested wetland was estimated to be only a small fraction of the amount applied. Concentrations of NH 4 + - and NO 3 − -N in the collected water samples were low and ranged from 0.02 to 1.79 mg L−1. Isotopic analysis revealed NH 4 + -δ 15N and NO 3 − -δ 15N means were distinctive and may have the potential to be used as tracers of N contamination. The mean NH 4 + -δ 15N value was +18.6±7.1‰ and the NO 3 − -δ 15N mean was +8.3±3.1‰. Anomalously high NO 3 − -δ 15N values (〉30‰) were attributed to denitrification.
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    URL: http://dx.doi.org/10.1007/BF02047046
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    Integration of Remote Sensed and In-situ Data in an Analysis of the Air Pollution Effects on Terrestrial Ecosystems in the Border Areas between Norway and Russia (1998)
    Springer
    Environmental monitoring and assessment 49 (1998), S. 51-85 
    Details
    ISSN: 1573-2959
    Keywords: air pollution ; GIS ; lichens ; remote sensing ; SO2 ; terrestrial ecosystems
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Transboundary air pollution from industries in Nikel and Zapolyarnij has caused severe damage to the environment in Southern-Varanger in Norway and in Pechenga municipality in Russia. The work presented in this paper focuses on the integration of in-situ air pollution data with remote sensing based land cover maps. Land cover maps have been utilised to detect changes in the major land cover types within the area. The major change in the environment was the decrease of the sensitive lichen-dominated land cover types, and the increase of bilberry-dominated land cover types and finally the increase of the land cover types with the greatest air pollution stress (industrial barren, barren, and partly damaged vegetation, defoliated forests, lichen removal). A GIS based method for assessing the relationship of the remotely sensed land cover maps with the environmental condition parameters was developed and applied. By comparing the results from this analysis we observed that the land cover types with the greatest stress had the largest concentrations of SO2 in the ground air layer, while the land cover types with minor damage (the remaining lichen-dominated vegetation) had rather low concentrations of sulphur dioxide in the ground air layer. The area of the land cover types with the greatest stress (industrial barren, barren and partly damaged vegetation) has increased in the period 1973–1988, and the degradation is carried out in a such manner that sensitive mountain and lichen vegetation formations have been transformed into a more barren-like environment. The increase in the emissions has also transferred the natural barrens which also consisted of some sparse vegetation into a complete barren with little vegetation left. Also the epilitic lichens and mosses on bare rocks and stones were also removed by the high concentrations of SO2. The land cover types with minor damage (with the remaining lichen-dominated vegetation) had rather low concentrations of the contaminants (SO2, Ni and S), while the partly damaged and damaged land cover types had the highest concentrations of the contaminants. An exception was the Ni and S concentrations found in class 11 Industrial barrens which were lower than expected. Associations between the degradation and the SO2 concentration in the air were also documented. The conclusion from this analysis is that the in-situ data support the observations of damaged vegetation and industrial barrens imaged by the Landsat satellites, especially in the surroundings of Nikel and Zapolyarnij.
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    URL: http://dx.doi.org/10.1023/A:1005755706302
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    Implications of Atmospheric Change for Biodiversity of Aquatic Ecosystems in Canada (1998)
    Springer
    Environmental monitoring and assessment 49 (1998), S. 271-280 
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    ISSN: 1573-2959
    Keywords: air pollution ; atmospheric change ; atmospheric stressors ; biodiversity ; ecosystem risk
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Overall, the greatest threats to Canadian and global biodiversity are associated with conversions of natural ecosystems to anthropogenic ones, and over-exploitation of biological resources. This circumstance does not, however, trivialize the importance of atmospheric influences. Although scientific understanding of the risks is incomplete, it is nevertheless clear that anthropogenic changes in atmospheric stressors are potentially damaging to biodiversity and other ecological values over medium- and longer-term scales. It is important that greater investments be made in support of longer-term monitoring and research designed to understand the effects of atmospheric and other environmental stressors on the biodiversity and structure and function of Canadian ecosystems.
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    URL: http://dx.doi.org/10.1023/A:1005851027038
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    Multivariate imputation in cross-sectional analysis of health effects associated with air pollution (1995)
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    Environmental and ecological statistics 2 (1995), S. 191-212 
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    ISSN: 1573-3009
    Keywords: multivariate interpolation ; kriging ; respiratory morbidity ; air pollution ; sulphates ; nitrates ; ozone ; Ontario Health Study ; environmental monitoring
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract We demonstrate a recently developed spatial interpolation methodology in a study of the chronic effects of air pollution on respiratory morbidity. Our study uses data from the Ontario Health Study, a large survey of households in Ontario conducted for the province by Statistics Canada. The interpolation procedure imputes unobserved vectors of air pollution concentrations for individual Public Health Units, from those observed at a few fixed air pollution monitoring sites. We use logistic regression methods to assess the significance of air pollution levels based on the imputed values after modelling the relationship between binary health responses and assorted covariates such as measures of life style. Our findings prove negative; no significant relationship between chronic respiratory morbidity and air pollution is found. The imputation methodology is seen to be promising and might well be used in other such analyses.
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    Quantifying urban forest structure, function, and value: the Chicago Urban Forest Climate Project (1997)
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    Urban ecosystems 1 (1997), S. 49-61 
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    ISSN: 1573-1642
    Keywords: urban forests ; urban ecology ; urban climate ; hydroclimate ; air pollution ; energy conservation ; carbon removal ; benefit-cost analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This paper is a review of research in Chicago that linked analyses of vegetation structure with forest functions and values. During 1991, the regions trees removed an estimated 5575 metric tons of air pollutants, providing air cleansing worth 9.2 million. Each year they sequester an estimated 315 800 metric tons of carbon. Increasing tree cover 10% or planting about three trees per building lot saves annual heating and cooling costs by an estimated 50 to 90 per dwelling unit because of increased shade, lower summertime air temperatures, and reduced neighborhood wind speeds once the trees mature. The net present value of the services trees provide is estimated as 402 per planted tree. The present value of long-term benefits is more than twice the present value of costs.
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    Glucoamylase production in continuous cultures of Aspergillus niger with special emphasis on growth parameters (1997)
    Springer
    World journal of microbiology and biotechnology 14 (1997), S. 113-118 
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    ISSN: 1573-0972
    Keywords: Aspergillus ; continuous culture ; glucoamylase ; growth ; fungi ; nitrogen
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Abstract Maltose-limited continuous culture of Aspergillus niger was carried out with potassium nitrate to investigate growth and glucoamylase formation characteristics. Glucoamylase production was dependent on the specific growth rate. The maximal amount of glucoamylase (units/l and U/g dry weight) was obtained at μ=0.08h−1, and the maximum specific rate of production (units/g/dry weight per hour) was at μ=0.2h−1. The maintenance coefficients (ms and mATP) were higher than for some other fungi. Maximal growth yields on substrate, oxygen and ATP (Yxsm, YxO2m and Yxam) were very efficient (high) and the value of Yxam, which cannot exceed the theoretical maximal value, is obtained when a P/O ratio of 1:1 is assumed. This indicates that biomass formation is energetically inexpensive and most of the expended energy has to be invested in the process of glucoamylase excretion.
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    Changes in nitrogen resources with increases in temperature during production of mushroom compost (1996)
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    World journal of microbiology and biotechnology 12 (1996), S. 379-384 
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    ISSN: 1573-0972
    Keywords: Agaricus bisporus ; ammonia ; compost ; nitrogen ; thermophilic
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Abstract The rise in temperature is an important event during the composting of lignocellulosic materials and has to be controlled and regulated to improve the biodegradation. Phase I mushroom composts were incubated under environmentally controlled conditions. When the temperature was pre-set at 65°C and then later at around 80°C, the microbial respiration and the biodegradations were hardly affected. However residual activities due to thermoresistant bacteria were still measured after 68 h at a constant temperature of 80°C. Significant changes in nitrogen resources were observed: loss of nitrogen from microbial products, an increase in the proportion of nitrogen in non-hydrolysable and stable forms, and an increase in volatilisation of ammonia. These changes were mainly due to physico-chemical mechanisms associated with disturbances in the structure of the microbial community.
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    Effect of nitrogen and phosphorus addition on phenanthrene biodegradation in four soils (1999)
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    Biodegradation 10 (1999), S. 43-50 
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    ISSN: 1572-9729
    Keywords: biodegradation ; nitrogen ; nutrients ; phenanthrene ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Phenanthrene mineralization rates were found to vary widely among four soils; differences in soil nutrient levels was one hypothesis to explain this variation. To test this hypothesis, phenanthrene mineralization rates were measured in these soils with, and without, added nitrogen and phosphorus. Mineralization rates either remained unchanged or were depressed by the addition of nitrogen and phosphorus. Phenanthrene degradation rates remained unchanged in the soil which had the highest indigenous levels of nitrogen and phosphorus and which showed the largest increase in phosphorus levels after nutrients were added. The soils in which degradation rates were depressed had lower initial phosphorus concentrations and showed much smaller or no measurable increase in phosphorus levels after nutrients were added to the soils. To understand the response of phenanthrene degradation rates to added nitrogen and phosphorus, it may be necessary to consider the bioavailability of added nutrients and nutrient induced changes in microbial metabolism and ecology.
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    The reconstruction of environmental rights in urban South Africa (1995)
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    Human ecology 23 (1995), S. 259-284 
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    ISSN: 1572-9915
    Keywords: South Africa ; urbanization ; hazards ; flood ; air pollution ; health ; human rights
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Ethnic Sciences
    Notes: Abstract Rapid and spatially concentrated urbanization in South Africa has brought with it significant health and safety hazards. These hazards are described and analyzed through two optics: environmental rights and community participation. The rights perspective suggests that the system of apartheid led to a collapse of rural livelihoods, driving people to the cities, while apartheid's tight control over African residential location and employment ensured that high density settlement and unemployment would follow. The resulting urban environmental degradation and health and safety hazards are a violation of the human rights of the African residents of townships and informal settlements. The community participation perspective suggests that reconstruction can be linked to development and that community-based hazard identification and mitigation can be a vehicle for kick-starting urban revitalization.
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    Transpiration and hydraulic conductivity in three Scots pine (Pinus sylvestris L.) stands with different air pollution histories (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 1677-1682 
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    ISSN: 1573-2932
    Keywords: stand transpiration ; hydraulic architecture ; Pinus sylvestris L. ; air pollution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract As part of a project studying the effects of massive reductions in the output of air pollutants in eastern Germany we monitored stand transpiration rates and water stress and analyzed the hydraulic architecture of Scots pine in three stands with different air pollution histories. Sap flow densities were continuously measured in 15 trees per stand with a thermoelectric method. The sap flow densities were scaled up to the stand transpiration rate via the conductive xylem area, which was measured with computer-tomography in the same trees. Radiation (PAR), humidity and temperature were monitored at three levels in the stands, water stress is assessed by predawn water potentials. As a parameter of hydraulic architecture we studied leaf specific conductivity (LSC). The proportion of the heartwood area did not significantly vary along the gradient of air pollution. The variation of sap flow densities within the stands was large. The ratios of sap flow densities in the inner and outer xylem were site-specific and significantly different between the stands. In the stand with the highest rate of air pollution there was a sharp decline in the sap flow densities towards the heartwood. Stand transpiration in the site with the lowest pollution was significantly higher than in the two more polluted sites. LSC in 2 years old twigs was significantly higher in the low pollution stand. In the dry summer of 1994 predawn water potentials fell to extreme values of below 1.6 MPa. At that stage transpiration ceased until the next substantial rainfalls.
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    URL: http://dx.doi.org/10.1007/BF00477221
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    The effects of the emissions of the Kostomuksha mining complex on the chemical composition of deposition and soil water in the surrounding pine forests (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 1689-1694 
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    ISSN: 1573-2932
    Keywords: air pollution ; deposition ; emission ; mine industry ; precipitation ; soil water ; sulphur dioxide
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The Kostomuksha mining complex in Russian Karelia is a major emission point source surrounded by large forest areas near the Finnish border. The sulphur dioxide emissions of the complex are almost 60 000 tonnes and dust emissions about 5 000 tonnes a year. Research into the effects of emissions on the surrounding forests were started in a Finnish-Russian co-operation project in 1992. Deposition measurements during the two first years indicate that the effects of the emissions extend about 30 km to the west of the complex. The annual sulphur deposition near the mining complex has been about 300 mg/m2 in bulk precipitation and about 500 mg/m2 in throughfall. Sulphur emissions sometimes extend the eastern parts of Finland, but there the deposition is clearly smaller than near to the mining complex. The high calcium emissions neutralize the acidifying effect of sulphur near to the mine and smelter. The iron concentration in precipitation also increased near the complex. Sulphur and calcium decreased in percolation water on moving westwards.
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    URL: http://dx.doi.org/10.1007/BF00477223
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    Long term effects of enhanced nitrogen deposition on a lowland dry heath in southern Britain (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 1701-1706 
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    ISSN: 1573-2932
    Keywords: nitrogen ; heathland ; Calluna vulgaris ; critical load ; growth ; litter production
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Experimental additions of ammonium sulphate to a nitrogen-poor dry heathland have been carried out since 1989. There are four nitrogen treatments: a control (receiving artificial rain only), a low treatment which receives an additional 7.7 kg N ha−1 yr−1, a high treatment receiving 15.4 kg N ha−1 yr−1 and an alternating treatment which receives either the control or the high nitrogen additions, in alternate years. The estimated background deposition at the study site is 13–18 kg N ha−1 yr−1, a value similar to the critical load that has been suggested for the conversion of lowland heath to grassland. Over the past 5 years there have been significant stimulations in shoot growth, flowering, canopy density and litter production. Flowering, in particular, strongly reflects nitrogen additions in the alternating treatment. Current models of the response of dry Calluna heathlaud to enhanced nitrogen deposition suggest that higher tissue nitrogen levels will occur and will be accompanied by heightened sensitivity to secondary stresses. This may in turn lead to canopy breakdown and replacement by grassland. The application of nitrogen at deposition rates only slightly in excess of the critical load over five years has produced small, non-significant increases in shoot nitrogen content. However, there is clear evidence of a large positive effect on shoot growth, flowering, litter production and canopy density of Calluna. The observation of these responses at the application rates used in this study supports the current proposals for critical loads of nitrogen for lowland heaths.
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    URL: http://dx.doi.org/10.1007/BF00477225
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    Reducing the contribution of ammonia to nitrogen deposition across Europe (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 1891-1896 
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    ISSN: 1573-2932
    Keywords: emissions ; nitrogen ; ammonia ; agriculture ; integrated assessment modelling ; abatement strategies
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract European emissions of reduced nitrogen, arising principally from agriculture, are comparable with those of oxidised nitrogen from mobile and stationary combustion sources. It is therefore important to include ammonia emissions in working towards a new protocol on nitrogen under the programme of the UN Economic Commission for Europe on the control of transboundary air pollution. However the nature of the sources and the subsequent atmospheric transport and chemistry are very different from other acidifying pollutants. This paper describes work in hand under the MARACCAS project to compare agricultural activities in different European countries and to assess the applicability and efficacy of potential abatement measures. The aim is to derive abatement costs for each country relating successive emission reductions to the costs of achieving them, to be used by the UN ECE Task Force on Integrated Assessment Modelling (TFIAM) — in particular with our Abatement Strategies Assessment Model, ASAM. The paper will also address the large uncertainties involved in integrated assessment modelling with respect to ammonia, and suggest how these may be allowed for in deriving cost-effective abatement strategies.
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    URL: http://dx.doi.org/10.1007/BF01186110
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    Critical loads of acidity and nitrogen, based on multiple criteria for different swedish ecosystems (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 2375-2380 
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    ISSN: 1573-2932
    Keywords: Critical load ; acidity ; nitrogen ; Norway spruce ; Scots pine ; ground vegetation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The critical loads of acidity and nitrogen has been mapped for Swedish forest soils, using data from the Swedish Forest Inventory. The Swedish critical load map used in negotiations has been based on a number of ecological receptors. For terrestrial ecosystems criteria based on no adverse effect on growth, soil stability and groundwater quality was used. For surface waters, stream and lake biology was used as indicators for setting limits to acidification. A reduction of 75% of the acidity deposition in relation to 1988 is required in order to protect 95% of the forest resource in Sweden from effects of soil acidification. A reduction of 50% of the nitrogen deposition is required to avoid exceedance in more than 5% of the area. The mapping work was carried out by using the PROFILE model.
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    URL: http://dx.doi.org/10.1007/BF01186189
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    Calculation and mapping of critical loads of s, n and acidity on ecosystems of the Northern Asia (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 2395-2400 
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    ISSN: 1573-2932
    Keywords: critical loads ; nitrogen ; sulphur ; northern Asia
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract On the basis of modified simple steady state mass-balance equations, the critical loads for nutrient and acidifying nitrogen as well as for sulphur and acidity have been calculated for various ecosystems of northern Asia using simplified expert-modelling GIS and grid cells 150×150 km. The minimal values of critical loads of nitrogen, CL(N), (〈50eq/ha/yr) were shown for arctic and subarctic ecosystems and the maximal ones (〉300eq/ha/yr) for ecosystems of chernozemic and chernozem-like soils in southern Siberia and the Far East. The minimal values of critical loads of sulphur, CL(S), as well as acidity were shown predominantly in the northern part of east Siberia and in the Kamchatka peninsula and the maximal ones for ecosystems having neutral and alcaline soils. The corresponding exceedances were indicated for many regions of the northern part of Asia with maximal values for regions of Ural mountains, frontery of Kazakhstan, Altai, lower Yenisei river flow, Far East, Sakhalin and South-Kurilean islands.
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    URL: http://dx.doi.org/10.1007/BF01186192
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    Uncertainty analysis of critical loads for terrestrial ecosystems in Russia (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 2559-2564 
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    ISSN: 1573-2932
    Keywords: uncertainty analysis ; computed critical loads ; nitrogen ; sulpher ; acidity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The goal of this study is to give a comprehensive and quantitative estimation of the uncertainty of computed in different scale nitrogen (N) and sulphur (S) critical loads (CL) values for terrestrial ecosystems of the Northern Asia, European part and the North-Western regions of Russia. The CL values are used to set goals for future deposition rates of acidifying compounds so that the environment is protected. In this research CL values for terrestrial ecosystems are determined using the expert-modelling geoinformation system (EM GIS) approach. UNCSAM software package is used as the tool for uncertainty analysis. The analysis presented here focuses on the estimation and effect of the input source uncertainties and sensitivities on the CL values in various regions under study. In spite of the region, nitrogen uptake by vegetation, nitrogen leaching from terrestrial ecosystems and the difference between deposition and uptake by plants of base cations (BC) are the most influential factors for all terrestrial ecosystems of Russia.
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    URL: http://dx.doi.org/10.1007/BF01186219
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    Spatial variability in emissions reduction strategies for sulphur and nitrogen in the UK (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 2619-2624 
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    ISSN: 1573-2932
    Keywords: sulphur ; nitrogen ; critical loads function ; emissions reductions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The roles of sulphur (S) and nitrogen (N) in causing critical loads exceedance across the UK show considerable spatial variability at the present time. Over much of lowland Britain it appears that the environment can only be protected by reducing N deposition, whilst in upland areas (e.g. most of Scotland and Wales) reductions in S deposition are the primary requirement. Using the Hull Acid Rain Model (HARM) the effects of current and possible future emissions control legislation on critical loads exceedance can be explored. Based on HARM output, the implementation of the UNECE Sulphur Protocol (1994) will bring about a substantial reduction in the amount of S being deposited in the UK, especially in central and southern parts of the country. Some areas will remain where additional reductions in S are required. Over most of the country, however, the need to reduce N deposition will become paramount. The changing contributions and significance of non-UK sources can be estimated.
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    URL: http://dx.doi.org/10.1007/BF01186229
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    A spatial decision support system to allow the investigation of the impact of emissions from major point sources under different operating policies (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 2649-2654 
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    ISSN: 1573-2932
    Keywords: Decision support system ; optimization ; air pollution ; sulphur ; critical load
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A Spatial Decision Support System (SDSS) is being developed for Her Majesty's Inspectorate of Pollution (HMIP). It enables the investigation of the spatial implications of different operating procedures from large point sources of pollution. The environmental effect of emissions is assessed using the critical loads methodology developed at ITE and modelled deposition “footprints”. This approach allows an “effect per unit emission” or “pollution potential” to be determined for each source. Individual sources are modelled and included within the SDSS if their current emissions are above a given threshold. The SDSS provides a graphical user interface (GUI) which facilitates a fast, efficient and effective means to specify and to examine the effect of different operating policies. Mapping, statistical and optimization facilities are provided to help describe the effect of any specified strategy. Maps may be produced as deposition rates or exceedance values. Statistics may be visualised as histograms and scatter plots. The optimization facility uses linear programming to minimise the total environmental impact (estimated from emissions and critical loads) or maximise power produced within environmental limits. The SDSS has been written in the Arc/Info Macro Language (AML) and provides an invisible interface with standard GIS facilities and programmes written in “C”.
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    URL: http://dx.doi.org/10.1007/BF01186234
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    Reactions of gases on calcareous stones under dry conditions in field and laboratory studies (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 2707-2712 
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    ISSN: 1573-2932
    Keywords: Stone deterioration ; dry deposition ; air pollution ; calcareous stones ; field test ; laboratory test
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Dry deposition of gases plays an important role for the deterioration of stone materials and a better understanding of the processes involved will improve our ability to maintain stone monuments and buildings. As a part of an EU-project an investigation with four calcareous stone types have been exposed outdoor at two test sites in Norway for two years. The exposure has been carried out in sheltered position and the amount of reaction products and the penetration depth of SO2 into the stones was determined as soluble sulphate after half a year and after one and two years. Even if most of the sulphate was found in the upper 0.3 mm of the stone, there was an increase in the sulphate content in stone even down to the center of the stone sample. In laboratory tests with SO2, NO2 and changing relative humidity the synergistic effect of NO2 and the importance of the relative humidity was investigated. The uptake rates were calculated from the laboratory studies by analyzing the gas concentrations before and after the exposure chamber. By calculating the deposition velocity from the field study by using the amount of sulphate found in the stones together with the average outdoor concentration of SO2 at the test sites, the values were a magnitude higher than in the laboratory test, highest at the industrial paper mill sites with high concentrations both of SO2 and some hypochlorite and lower in urban atmosphere with fairly low values of SO2 and high values of NO2.
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    Increasing role of nitrogen in the acidification of surface waters in the Adirondack Mountains, New York (1997)
    Springer
    Water, air & soil pollution 95 (1997), S. 313-336 
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    ISSN: 1573-2932
    Keywords: nitrogen ; acidification ; Adirondack Mountains ; atmospheric deposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Assessments of the aquatic effects of acidic deposition have focused on sulfur, as have recent efforts to control the emissions of acidifying compounds. Nitrogen dynamics were excluded from most acidic deposition modeling studies because it was believed that terrestrial ecosystems strongly retain N and because modeling N is a more formidable task than modeling S due to the influence of complex biological processes on N cycling. Re-examination of available data for the Adirondack Mountains of New York suggests that N deposition may be contributing to both chronic and episodic acidification of freshwaters to a greater extent than is generally believed. Previous research concluded that N has played a limited role in acidification processes in these lakes, based on regional averages of chronic chemistry. However, it is now known that historic acidification responses have been spatially variable within the Adirondack Mountains and that the declines in lakewater pH have been less than previously believed. Lakewater NO3 − concentrations are commonly in the range of 5 to 25 μeq L−1 on a chronic basis in portions of the Adirondack region that have experienced significant chronic acidification. These NO3 − concentrations correspond in magnitude to inferred historical acidification. Furthermore, the relative importance of NO3 − as an agent of acidification increases dramatically during snowmelt when conditions are most toxic to fish. The consequence of not addressing N in formulating acidification recovery strategies for the Adirondacks includes the likelihood that we will overestimate the response of surface water to the mandated sulfur emissions reductions.
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    URL: http://dx.doi.org/10.1007/BF02406172
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    Effects of enhanced supplies of nitrogen and sulphur on rhizosphere and soil chemistry in a Norway spruce stand in SW Sweden (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 1777-1782 
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    ISSN: 1573-2932
    Keywords: aluminium ; base cations ; bulk soil ; nitrogen ; rhizosphere soil ; sulphur
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Rhizophere and bulk soil chemistry were investigated in a Norway spruce stand in SW Sweden. The rhizosphere and bulk soil chemistry in water extracts in control plots (C) and plots repeatedly treated with ammonium sulphate (NS) were compared. Treatment regime was started in 1988. Cylindrical core samples of the LFH-layer and mineral soil layers were collected in 1992 and used for water extract analyses. Samples of soil from LFH-layer and mineral soil layers were taken in 1991 and 1993 for determination of CEC and base saturation. Soil pH and NH4-N, NO3-N and SO4-S, Al, Ca, K and Mg concentrations in water extracts were measured for rhizosphere and bulk soils. The pH-values of bulk and rhizosphere soils in NS plots decreased compared with those in control plots, whereas concentrations of NH4-N, NO3-N, SO4-S, base cations and Al in water extract increased. In both bulk and rhizosphere soils the concentration of NH4-N was much higher than that of NO3-N. A significant difference in the pH and Mg concentration of bulk and rhizosphere soil between the treated and control plots was found only in the 0–10 cm layer. For all layers, there was a significant difference in NH4-N concentrations in the bulk and rhizosphere soil between the NS treatment and control plots. Concentrations of exchangeable base cations and the base saturation level in the LFH-layer decreased in the NS plots. The concentration of extractable SO4-S increased in the NS plots. The NS treatment enhanced the amount of litter in L-layer, owing to increases in needle biomass and litterfall but led to losses of base cations, mainly K and Mg, from LFH-layer. It was concluded that the NS treatment displaced cations from exchangeable sites in the LFH-layer leading to higher concentrations of these elements in both rhizosphere and bulk soil.
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    Behaviour of sulphur and nitrogen compounds measured at marine stations Lista and Säby in Scandinavia (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 2039-2044 
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    ISSN: 1573-2932
    Keywords: sulphur ; nitrogen ; Scandinavia ; long distance transport ; elemental tracers
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Long distance transport of various air pollutants has been studied at two Scandinavian coastal sites. The measuring period has covered one year divided into 4 campaigns. Seasonal variations for sulphur and nitrogen compounds as well as anthropogenically emitted metals are reported. Concentrations of Pb and Zn as well as the ratio of V/Ni concentrations have been used to trace sulphuric episodes. Covariation of anthropogenic pollutants for the two sites is demonstrated.
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    URL: http://dx.doi.org/10.1007/BF01186134
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    Long-term modelling of airborne pollution within the Northern Hemisphere (1995)
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    Water, air & soil pollution 85 (1995), S. 2051-2056 
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    ISSN: 1573-2932
    Keywords: acidification ; air pollution ; air pollution modelling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A long-term modelling (1991–1994) of oxidised sulphur, bound nitrogen and some heavy metals has been carried out by MSC-E/EMEP for the Northern Hemisphere. The transport unit of the model is an Eulerian scheme which could be classified as Pseudo-Lagrangian one. Vertical distribution described by means of Gaussian approximation and the exchange with the free troposphere are taken into account. Vertical movement is calculated proceeding from local mixing conditions, state of the surface, its height (topography) etc. The chemical unit for acid compounds contains 25 reactions and 14 compounds including sulphur and nitrogen compounds peroxyacetylnitrate, tropospheric ozone, volatile hydrocarbons (but methane) are considered as a whole via ozone creation potential. The model time step is 1 hour, meteorological data (winds, temperature, precipitation etc.) cover 6-hour intervals. The model results show that very significant part of the Arctic and West Asian acid pollution is produced by European countries. On the whole the Arctic pollution by SOx, NOx and NHx comes from sources of Old World. The main source of sulphur pollution is located in Russia and of nitrogen compound — in Central and Northern Europe. About 50% SOx, 70% NOx and 40% NHx deposition in Central Asia and Kazakhstan is-imported from external sources. A similar situation is observed in European and Asian parts of Russia.
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    Studies of precipitation contamination levels over the north-western forests of Russia subject to emissions from the two nickel smelters (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 2071-2076 
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    ISSN: 1573-2932
    Keywords: air pollution ; industrial emissions ; sulphur dioxide ; heavy metal aerosols ; contamination of precipitation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The results of investigations carried out in the forests of Kola peninsula subject to long-term air pollution by the nickel industrial enterprises are presented. Samples of rainwater from the open sites, from under the coniferous (pine) trees crowns and of the stemflow were collected at various distances from the emission sources. The highest levels in pollution of rainwater are detected over the area adjacent to the smelters. Researches of contamination of the precipitation in the vicinity of the two nickel enterprises of Kola peninsula show that concentrations of pollutants vary significantly (up to an order of magnitude) depending upon the meteorological conditions. The area of impact on forests of Kola peninsula is restricted by the radius of 30–40 km from the emission sources.
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    URL: http://dx.doi.org/10.1007/BF01186139
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    Variations in sulphur and nitrogen foliar concentration of deciduous and conifers vegetation in Slovakia (1997)
    Springer
    Water, air & soil pollution 96 (1997), S. 329-345 
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    ISSN: 1573-2932
    Keywords: beech ; biomonitoring ; nitrogen ; solid particles ; spruce ; sulphur
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The foliage contents of Stotal and Ntotal were determined in 405 Permanent monitoring plots in four National Parks and sixteen Landscape Protection Areas and were compared with 1483 Permanent monitoring plots on Slovakia. The foliage content of S ranged from 0.72 to 6.77 g kg−1 in hardwoods and from 0.98 to 4.3 g kg−1 in softwoods. A critical increase was determined in one National Park and in four Landscape Protection Areas. The foliage content of N ranged from 9.7 to 48.7 g kg−1 in softwoods, and from 7.8 to 51.4 g kg−1 in hardwoods. An insufficient level of N was determined in one Landscape Protection Area and a critical increase in four Landscape Protection Areas. The sulphur to nitrogen ratio ranged from 0.08 to 0.176 in softwoods, and from 0.078 to 0.253 in hardwoods. The foliage surface on hitherto explored four National Parks and sixteen Landscape Protection Areas in network 4×4 km was covered by all categories of rigid fallout particles. Fly-ash from coal combustion were observed each of National Parks and Landscape Protection Areas by scanning electron microscopy. Mycelia and spore, mineral matters, sand and soil particles were present on all National Parks and Landscape Protection Areas. Particles derived from aluminium production were observed at three Landscape Protection Areas. Particles derived from cement production and from lime works were observed at two National Parks and six Landscape Protection Areas. Particles derived from ferrous metals industry were observed at each of National Parks and Landscape Protection Areas and particles typical for other technologies were present in three of National Parks and twelve Landscape Protection Areas.
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    URL: http://dx.doi.org/10.1007/BF02407213
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    VARIATIONS IN SULPHUR AND NITROGEN FOLIAR CONCENTRATION OF DECIDUOUS AND CONIFERS VEGETATION IN SLOVAKIA (1997)
    Springer
    Water, air & soil pollution 96 (1997), S. 329-345 
    Details
    ISSN: 1573-2932
    Keywords: beech ; biomonitoring ; nitrogen ; solid particles ; spruce ; sulphur
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The foliage contents of Stotal and Ntotal were determined in 405 Permanent monitoring plots in four National Parks and sixteen Landscape Protection Areas and were compared with 1483 Permanent monitoring plots on Slovakia. The foliage content of S ranged from 0.72 to 6.77 g kg-1 in hardwoods and from 0.98 to 4.3 g kg-1 in softwoods. A critical increase was determined in one National Park and in four Landscape Protection Areas. The foliage content of N ranged from 9.7 to 48.7 g kg-1 in softwoods, and from 7.8 to 51.4 g kg -1 in hardwoods. An insufficient level of N was determined in one Landscape Protection Area and a critical increase in four Landscape Protection Areas. The sulphur to nitrogen ratio ranged from 0.08 to 0.176 in softwoods, and from 0.078 to 0.253 in hardwoods. The foliage surface on hitherto explored four National Parks and sixteen Landscape Protection Areas in network 4 × 4 km was covered by all categories of rigid fall-out particles. Fly-ash from coal combustion were observed each of National Parks and Landscape Protection Areas by scanning electron microscopy. Mycelia and spore, mineral matters, sand and soil particles were present on all National Parks and Landscape Protection Areas. Particles derived from aluminium production were observed at three Landscape Protection Areas. Particles derived from cement production and from lime works were observed at two National Parks and six Landscape Protection Areas. Particles derived from ferrous metals industry were observed at each of National Parks and Landscape Protection Areas and particles typical for other technologies were present in three of National Parks and twelve Landscape Protection Areas.
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    URL: http://dx.doi.org/10.1023/A:1026422606600
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    MONITORING NITROGEN POLLUTION FROM SUGARCANE RUNOFF USING 15N ANALYSIS (1997)
    Springer
    Water, air & soil pollution 98 (1997), S. 389-399 
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    ISSN: 1573-2932
    Keywords: fertilizer ; nitrogen ; pollution ; runoff ; stable isotopes ; sugarcane
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In many forested wetlands of Louisiana, surface water quality is being deteriorated by nutrient input from adjacent agricultural production areas. This field study assesses the input of fertilizer N, applied to sugarcane fields, to forested wetlands. The potential use of natural abundance variations in 15N14N ratios for identification and tracing surface water N sources (NH 4 + - and NO3 --N) was evaluated. Runoff and surface water samples were collected from sugarcane fields and bordering forested wetlands (6 stations) over a 16 month period and analyzed for NH 4 + -N, NO 3 - -N, and associated NH 4 + -δ15N and NO 3 - -δ15N ratios. Fertilizer N draining into adjacent forested wetland was estimated to be only a small fraction of the amount applied. Concentrations of NH 4 + - and NO 3 - -N in the collected water samples were low and ranged from 0.02 to 1.79 mg L-1. Isotopic analysis revealed NH 4 + -δ15N and NO 3 - -δ15N means were distinctive and may have the potential to be used as tracers of N contamination. The mean NH 4 + -δ15N value was +18.6 ± 7.1‰ and the NO 3 - -δ15N mean was +8.3 ± 3.1‰. Anomalously high NO 3 - -δ15N values (〉30‰) were attributed to denitrification.
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    Tree bark as a bioindicator of air pollution in Navarra, spain (1997)
    Springer
    Water, air & soil pollution 98 (1997), S. 381-387 
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    ISSN: 1573-2932
    Keywords: air pollution ; bioindicator ; biomonitoring ; tree bark
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract During a two year research period from 1992 to 1993, samples of different species of trees were taken in 17 forest stands located in Navarra, Spain. From these samples, bark extracts were prepared in which the pH and the conductivity were measured. The health of the sampling trees was also evaluated by determining the degree of defoliation and decoloration of the canopies. The bark tissue analysis revealed the presence of an environmental acidity gradient that decreased from NW to SE. This coincides with the location of important sources of pollution and their course of transport and dispersion. On the other hand, in the samples ofQuercus ilex a significant correlation between the pH and the defoliation levels (P≤0.01, r=0.62) was found. This fact reveals the potential usefulness of tree bark as a health bioindicator of trees.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02047045
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    Sulphur and Heavy Metal Concentrations in Scots Pine Bark in Northern Finland and the Kola Peninsula (1997)
    Springer
    Water, air & soil pollution 93 (1997), S. 395-408 
    Details
    ISSN: 1573-2932
    Keywords: air pollution ; pine bark ; sulphur ; pH ; conductivity ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Sulphur and heavy metal deposition in northern Finland (= in Lapland) and the Kola Peninsulawere surveyed using Scots pine bark samples. Sulphur concentrations in bark close to the Kolasmelters were on an average twice as high as on the Finnish side of the border. The Cu and Niconcentrations near the smelters were almost 100-fold the mean values in northern Finland. Therewas a marked decrease in the sulphur and heavy metal concentrations with increasing distancefrom the emission sources. The effects of emissions from the Kola Peninsula were evident inFinland only close to the border, especially in the eastern parts of Inari (NE corner of Lapland)where the Cu and Ni concentrations were 2- to 6-fold those in western Lapland. The sulphur andheavy metal concentrations in most of northern Finland were low. However were theconcentrations of Cr in bark in the SW corner of Lapland considerably high, due to the emissionsfrom the Tornio refined steel plants.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022160930526
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    Sediment accumulation of nutrients (N, P) in the eastern Gulf of Finland (Baltic Sea) (1997)
    Springer
    Water, air & soil pollution 99 (1997), S. 477-486 
    Details
    ISSN: 1573-2932
    Keywords: sediment ; nitrogen ; phosphorus ; organic matter ; cluster analysis ; Gulf of Finland ; estuaries
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Dry weight (DW), ignition loss (IL) and concentrations of total nitrogen (TN) and total phosphorus (TP) of the sediment surface layer (0 to 10 cm, 1 cm slices) were analyzed from 20 sites in the eastern Gulf of Finland. The distance of the sampling sites from the mouth of the River Neva explained the nutrient concentrations of the sediments well, while the effect of water depth was negligible. The increase of TN and the decrease of TP along the transect from the river mouth towards the open Gulf were caused by the diminishing share of allochthonous material supplied from the River Neva. The mean TN concentration of the different accumulation areas was about 40 % higher in the sediment surface than in the deeper layer (9 to 10 cm). The corresponding difference for TP varied from 53 to 56 %. The results suggest considerable netflux of nutrients from sediment to water. The net sediment accumulation of nutrients were estimated as 6.0 g m−2 a−1 of N and 1.7 g m−2 a−1 of P corresponding 22 000 t a− of N and 6 100 t a−1 of P for the whole eastern Gulf.
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    URL: http://dx.doi.org/10.1007/BF02406887
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    INCREASING ROLE OF NITROGEN IN THE ACIDIFICATION OF SURFACE WATERS IN THE ADIRONDACK MOUNTAINS, NEW YORK (1997)
    Springer
    Water, air & soil pollution 95 (1997), S. 313-336 
    Details
    ISSN: 1573-2932
    Keywords: nitrogen ; acidification ; Adirondack Mountains ; atmospheric deposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Assessments of the aquatic effects of acidic deposition have focused on sulfur, as have recent efforts to control the emissions of acidifying compounds. Nitrogen dynamics were excluded from most acidic deposition modeling studies because it was believed that terrestrial ecosystems strongly retain N and because modeling N is a more formidable task than modeling S due to the influence of complex biological processes on N cycling. Re-examination of available data for the Adirondack Mountains of New York suggests that N deposition may be contributing to both chronic and episodic acidification of freshwaters to a greater extent than is generally believed. Previous research concluded that N has played a limited role in acidification processes in these lakes, based on regional averages of chronic chemistry. However, it is now known that historic acidification responses have been spatially variable within the Adirondack Mountains and that the declines in lakewater pH have been less than previously believed. Lakewater NO3 - concentrations are commonly in the range of 5 to 25 μeq L-1 on a chronic basis in portions of the Adirondack region that have experienced significant chronic acidification. These NO3 - concentrations correspond in magnitude to inferred historical acidification. Furthermore, the relative importance of NO3 - as an agent of acidification increases dramatically during snowmelt when conditions are most toxic to fish. The consequence of not addressing N in formulating acidification recovery strategies for the Adirondacks includes the likelihood that we will overestimate the response of surface water to the mandated sulfur emissions reductions.
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    URL: http://dx.doi.org/10.1023/A:1026422031266
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    Tree bark as a bioindicator of air pollution in Navarra, Spain (1997)
    Springer
    Water, air & soil pollution 98 (1997), S. 381-387 
    Details
    ISSN: 1573-2932
    Keywords: air pollution ; bioindicator ; biomonitoring ; tree bark
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract During a two year research period from 1992 to 1993, samples of different species of trees were taken in 17 forest stands located in Navarra, Spain. From these samples, bark extracts were prepared in which the pH and the conductivity were measured. The health of the sampling trees was also evaluated by determining the degree of defoliation and decoloration of the canopies. The bark tissue analysis revealed the presence of an environmental acidity gradient that decreased from NW to SE. This coincides with the location of important sources of pollution and their course of transport and dispersion. On the other hand, in the samples of Quercus ilex a significant correlation between the pH and the defoliation levels (P≤0.01, r = 0.62) was found. This fact reveals the potential usefulness of tree bark as a health bioindicator of trees.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1026431211784
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    Use of formerly plowed land in New England to monitor the vertical distribution of lead, zinc and copper in mineral soil (1997)
    Springer
    Water, air & soil pollution 95 (1997), S. 75-85 
    Details
    ISSN: 1573-2932
    Keywords: Pb ; Cu ; Zn ; trace metal pollution ; air pollution ; Ap horizon ; forest soils
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In this study, we used once-plowed lands that have returned to forest for over 50 years to study the vertical distribution of meteorologically-deposited lead. These mineral soils were an essentially homogeneous 20 cm-thick layer when last plowed. As such, they were effectively a “clean slate” upon which pollutants deposited since the last plowing can be measured without the confounding aspects of well-developed natural soil horizons and the spatial heterogeneity of native forest soils. The concentration and amount of lead as well as copper and zinc, biologically active metals, were measured at five sites in New England. In the mineral soil, copper content ranged from 25 mg cm depth−1 m−2 at 0–2 cm depth to 37 mg cm depth−1 m−2 at 6–8 cm depth, but showed no consistent pattern with depth at all sites. Zinc concentrations and amounts increased with depth in the mineral soil to 14 μg g−1 and 167 mg cm depth−1 m−2, respectively. In contrast, lead showed a decrease with depth from 350 mg cm depth−1 m−2 at 0–2 cm depth to 102–108 mg cm depth−1 m−2 between 10 and 20 cm depth. At all five sites, decreases in lead concentration with depth were correlated with decreases in the amount of organic mater. Amounts of total lead deposited since the abandonment from plowing have been estimated at 1.4 g m-2 in rural sites. Thirty-five percent of this presumably anthropogenically-derived lead was in the forest floor; the remaining 65 % was in the upper mineral soil.
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    URL: http://dx.doi.org/10.1007/BF02406157
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    USE OF FORMERLY PLOWED LAND IN NEW ENGLAND TO MONITOR THE VERTICAL DISTRIBUTION OF LEAD, ZINC AND COPPER IN MINERAL SOIL (1997)
    Springer
    Water, air & soil pollution 95 (1997), S. 75-85 
    Details
    ISSN: 1573-2932
    Keywords: Pb ; Cu ; Zn ; trace metal pollution ; air pollution ; Ap horizon ; forest soils
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In this study, we used once-plowed lands that have returned to forest for over 50 years to study the vertical distribution of meteorologically-deposited lead. These mineral soils were an essentially homogeneous 20 cm-thick layer when last plowed. As such, they were effectively a “clean slate” upon which pollutants deposited since the last plowing can be measured without the confounding aspects of well-developed natural soil horizons and the spatial heterogeneity of native forest soils. The concentration and amount of lead as well as copper and zinc, biologically active metals, were measured at five sites in New England. In the mineral soil, copper content ranged from 25 mg cm depth-1 m-2 at 0–2 cm depth to 37 mg cm depth-1 m-2 at 6–8 cm depth, but showed no consistent pattern with depth at all sites. Zinc concentrations and amounts increased with depth in the mineral soil to 14 μg g-1 and 167 mg cm depth-1 m-2, respectively. In contrast, lead showed a decrease with depth from 350 mg cm depth-1 m-2 at 0–2 cm depth to 102–108 mg cm depth-1 m-2 between 10 and 20 cm depth. At all five sites, decreases in lead concentration with depth were correlated with decreases in the amount of organic mater. Amounts of total lead deposited since the abandonment from plowing have been estimated at 1.4 g m-2 in rural sites. Thirty-five percent of this presumably anthropogenically-derived lead was in the forest floor; the remaining 65% was in the upper mineral soil.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1026451710848
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    Nutrient distribution in a Norway spruce stand after long-term application of ammonium nitrate and superphosphate (1996)
    Springer
    Water, air & soil pollution 92 (1996), S. 451-467 
    Details
    ISSN: 1573-2932
    Keywords: Biomass ; calcium ; fertilization ; loss ; magnesium ; nitrogen ; nutrient ; potassium ; recovery ; soil
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The distribution of nutrients between soil layers and above-ground tree components was examined in a Norway spruce stand that had received ammonium nitrate (annually) and superphosphate (about every third year) for 22 years. Four treatments were included in the study; control (n = 4), N1P1, N2P2 and N3P2 (n = 2), which had received a total of 0, 730, 1700 and 2550 kg nitrogen (N) ha-1, 0, 130, 300 and 300 kg phosphorus (P) ha-1 and 0, 340, 784 and 784 kg calcium (Ca) ha-1, respectively. Compared with the control, stem-wood growth had been three times higher in N1P1 and three and a half times higher in N2P2 and N3P2. Amounts of N, P, Ca, potassium (K) and magnesium (Mg) in the above-ground tree biomass increased (p〈0.05) with the fertilizer dose, whereas manganese (Mn) did not. The recovery of fertilizer N and Ca in soil and above-ground tree biomass was negatively related to the fertilizer dose, although there had been a buildup of the N and Ca pools in the mor layer. This strongly indicates that at least the higher doses of N addition caused substantial nitrate leaching. Soil pools of K, Mg and Mn decreased as the fertilizer dose increased. However, the system total amounts (above-ground tree biomass plus soil) of K and Mg did not differ between treatments suggesting that no extra losses of these ions induced by nitrate leaching have occurred. Thus, in an aggrading forest ecosystem, N additions are likely to be followed by increased uptake of K, Mg and Ca. This may to some extent prevent extra leaching of these ions, which otherwise would be expected when there is an increase in nitrate leaching.
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    URL: http://dx.doi.org/10.1007/BF00283572
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    Carbon and Nitrogen Stable Isotope Fractionation in the Sediment of Lake Bled (Slovenia) (1997)
    Springer
    Water, air & soil pollution 99 (1997), S. 315-323 
    Details
    ISSN: 1573-2932
    Keywords: lake ; sediment ; carbon ; nitrogen ; stable isotope ; fractionation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Stable isotope composition of carbon and nitrogen in the sediment and pore water of a eutrophic freshwater lake was studied. Based on changes in the δ13C and δ15N values of dissolved components and sediment fraction, possible processes involved in the decomposition of sedimentary organic matter are outlined. The relative importance of acetate fermentation and CO2 reduction was estimated using known mathematical models, and ammonia assimilation by methanogenic bacteria is hypothesised to be the main process governing the isotope fractionation of dissolved nitrogen in pore water.
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    URL: http://dx.doi.org/10.1023/A:1018354415109
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    Benthic Fluxes of Dissolved Inorganic Carbon, Nutrients and Oxygen in the Gulf of Trieste (Northern Adriatic) (1997)
    Springer
    Water, air & soil pollution 99 (1997), S. 305-314 
    Details
    ISSN: 1573-2932
    Keywords: Adriatic Sea ; nutrients ; benthic fluxes ; carbon ; nitrogen ; silicon ; phosphorus ; budgets
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Benthic fluxes of dissolved inorganic N, Si and P nutrients, alkalinity, dissolved inorganic C (DIC), and O2 from sediments in the Gulf of Trieste (northern Adriatic, Italy) were measured monthly in the period September 1995 - August 1996 using in situ incubated light benthic chambers. The highest efluxes of DIC, NH4+, PO43-, Si(OH)4, and NO3- influxes encountered in late summer - early autumn were the consequence of degradation of benthic microalgae, and in autumn mostly of sedimented phytoplankton. High NO3- efflux was observed in spring. Only NH4+ and Si(OH)4 fluxes were significantly correlated with temperature. This correlation suggests that the rate of downward input and the quality and quantity of sedimentary organic matter (autochthonous and allochthonous) were superimposed on the temperature fluctuations. High DIC, NH4+ and Si(OH)4 effluxes observed in July 1996 were due to the late spring - early summer degradation of sedimentary organic matter produced by benthic microalgae, while the autumn phytoplankton bloom was quickly reflected in enhanced benthic fluxes due to higher temperature. Significant correlations between NH4+, PO43- and Si(OH)4 fluxes suggested their parallel regeneration and utilization at the sediment-water interface. The nutrient fluxes were linked to O2 consumption, suggesting that aerobic oxidation processes were important at the sediment-water interface in the Gulf. The N, P and Si nutrients released from sediment pore waters are probably utilized in benthic microalgal and bottom-water primary production. This indicates that pelagic and benthic communities in the central part of the Gulf of Trieste function relatively independently of each other.
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    URL: http://dx.doi.org/10.1023/A:1018398231038
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    Seasonal Changes in Cystoseira Myrica and Phosphorus Input at Two Sites of the Red Sea Egyptian Coast (1997)
    Springer
    Water, air & soil pollution 93 (1997), S. 199-211 
    Details
    ISSN: 1573-2932
    Keywords: Cystoseira myrica ; Red Sea ; coral reefs ; nitrogen ; phosphorus ; pollution ; eutrophication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Elevated phosphate concentrations at Safaga and Quseir, Red Sea, Egyptian coast, wererelated to some ecological and nutritional aspects of the macro-alga Cystoseira myrica during1985. The results obtained were compared with those recorded for a non-polluted control site atGhardaqa. Chemical analysis of surface seawater samples revealed that the concentrations of dissolvedphosphate at Safaga and Quseir were 3 and 20 times as much as that at Ghardaqa, respectively.The standing crop of C. myrica showed two peaks in spring and autumn. Maximum biomass yield(491 g m-2) and number of individuals (127 m-2) of C. myrica were recorded in the spring at theGhardaqa site. Quseir C. myrica samples contained significantly higher protein-N, total-N andtotal-P values but lower carbohydrate values than the Safaga and Ghardaqa samples (LSD at 1%level). Tissue N:P molar ratios for C. myrica, Laurencia papillosa and Ulva lactuca collected fromGhardaqa ranged from 68-98, compared to 30-59 for the same species collected at thephosphorus polluted sites at Safaga and Quseir. The carbon levels and the C:N ratios of C. myricaexhibited no significant variations in the three studied sites. However, the C:P ratios of Ghardaqaplants were significantly higher than those of Safaga and Quseir.
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    URL: http://dx.doi.org/10.1023/A:1022196227853
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    Holling's Figure-Eight Model: A Technical Reevaluation in Relation to Climate Change and Biodiversity (1998)
    Springer
    Environmental monitoring and assessment 49 (1998), S. 157-168 
    Details
    ISSN: 1573-2959
    Keywords: biodiversity ; carbon storage ; climate change ; conservation ; creative destruction ; ecological succession ; ecosystem stability ; Holling figure-eight ; nitrogen ; resilience
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Holling proposed a four-phase conceptual model of ecosystem dynamics that includes exploitation, conservation, and destructive and renewal components to explain the failure of many natural resource management schemes. The model is drawn as a sideways figure-eight i.e. ∞. There are two dimensions in this model, connectivity (abscissa) and the amount of capital stored in the system (ordinate). This conceptual model has been suggested as a guide to thinking about the impact of climate change on biodiversity, but the two dimensions are insufficient and the alignment of the figure-eight model is problematic when compared with actual data. Kay has adjusted the dimensions of the figure-eight model and renamed the abscissa as exergy stored and the ordinate as exergy consumed. We realign the original figure-eight model, labeling the abscissa as carbon stored and the ordinate as nutrients, such that the relative values of both axes are in qualitative agreement with data from four different studies. This new alignment is then shown to fit relatively well with Holling's original labels. This revision of the figure-eight model brings Holling's model into agreement with observations and provides insight into the linkages between biodiversity and climate change.
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    URL: http://dx.doi.org/10.1023/A:1005813702080
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    On the Assessment of Sulphur Deposition on Forests Growing Over the Areas of Industrial Impact (1997)
    Springer
    Environmental monitoring and assessment 48 (1997), S. 125-137 
    Details
    ISSN: 1573-2959
    Keywords: air pollution ; critical levels ; critical loads ; forestdamage assessment ; industrial emissions ; sulphur deposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A method of calculation of sulphur deposition values on forests subjectto long-term industrial influence is presented. Investigations wereconducted in the vicinities of nickel smelters of Kola peninsula. Sulphurdioxide (SO2) is the major phytotoxicant emitted by theseenterprises. Depositions of sulphur were calculated on the basis of ground air layer pollution. To determine it a mathematical model was applied.Field surveys of forest ecosystems response to air contamination werecarried out and areas of different forest damage degree were identified.More than 4300 km2 of the territory of Kola peninsula isunder the impact of nickel enterprises. Average SO2concentration over the area of slight damage to forests is about 20µg/m3. It corresponds to the critical level proposed for forest ecosystems (UN ECE, 1993). Sulphur deposition over thearea of slight damage varies from 0.6 to 1.0 g/m2yr-1 for coniferous forests. For deciduous forests it isabout 1.0 g/m2 yr-1. These values are close totarget loads for highly sensitive ecosystems (Nilsson et al., 1991), but they exceed critical loads for the northern regions of Europe (Downing etal., 1993).
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    URL: http://dx.doi.org/10.1023/A:1005744301889
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    Vegetation monitoring in South-Varanger, Norway – species composition of ground vegetation and its relation to environmental variables and pollution impact (1999)
    Springer
    Environmental monitoring and assessment 58 (1999), S. 1-21 
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    ISSN: 1573-2959
    Keywords: air pollution ; indirect and direct gradient analysis ; vegetation monitoring
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The area along the Norwegian-Russian border is threatened by air pollution from emission sources on the Kola Peninsula. A permanent network of 78 systematically chosen monitoring sites has been established in eastern Finnmark, Norway. Species abundance data from the ground vegetation have been recorded from 1320 systematically chosen permanent plots inside 66 of these sites, using frequency in subplots and visual estimates of percentage cover. Environmental variables were obtained for the whole site. Multivariate data analysis has been used to describe the variation in the species composition and to study its relation to environmental variables and pollution impact. The analyses show that much of the variation in the species composition, based on average species abundance at the sites, is well explained by different soil and climatic conditions. However, estimated SO2 deposition, Ni, and Cu in the soil, and Ni in Cladina tissue have also been found to be statistically significantly correlated with the variation in the species data, but they explain only a minor part of the variation. The pollution impact over several years may have lead to a reduced lichen cover in the bottom-layer vegetation. Further development in an either negative or positive direction can be detected by re-investigations of the monitoring sites.
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    URL: http://dx.doi.org/10.1023/A:1006026926667
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    Estimation of riverine loads of nitrogen and phosphorus to the Baltic Sea, 1970–1993 (1999)
    Springer
    Environmental monitoring and assessment 58 (1999), S. 173-200 
    Details
    ISSN: 1573-2959
    Keywords: Baltic Sea ; nitrogen ; phosphorous ; riverine load ; timeseries
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This article presents the results of the first critical examination of time series of riverine nutrient-load data for the entire Baltic Sea drainage area. Water quality data collected by or for the different national environmental agencies were compiled and analysed statistically to identify and remove inconsistent or obviously incorrect observations. Moreover, sampling tours were undertaken to acquire additional information about the present nutrient concentrations in the largest rivers in the study area. Gaps in the time series of approved data were then filled in by employing statistical interpolation and extrapolation methods. Thereafter, the concentration and runoff data were combined to obtain estimates of monthly nutrient loads for the time period 1970–93. The results of the calculations showed that although there had been substantial changes in land use, atmospheric deposition and wastewater treatment in many parts of the study area, the total riverine loads of nitrogen (N) and phosphorus (P) to the Baltic Sea have been fairly constant since 1980, and most likely also since 1970. Moreover, the interannual variation was clearly correlated to the runoff. The mean annual loads for the time period 1980–93 were found to be about 825 000 tonnes N and 41 000 tonnes P, respectively. This implies that (i) several other investigators have strongly underestimated the riverine loads of nutrients, especially the nitrogen, and that (ii) the riverine loads by far exceed the input to the Baltic Sea from other sources, {i.e.} atmospheric deposition, direct emissions from cities and industries along the Baltic Sea coast and nitrogen fixation by marine algae.
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    URL: http://dx.doi.org/10.1023/A:1006073015871
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    Health effects and social costs of particulate pollution – a case study for Oslo (1998)
    Springer
    Environmental modeling and assessment 3 (1998), S. 47-61 
    Details
    ISSN: 1573-2967
    Keywords: air pollution ; health effects ; social costs ; externalities ; integrated approach
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This study analyses health damages from particulate pollution and the corresponding social costs. The analyses, which are based on transferring dose–response functions to Norway, is made within an integrated approach, where the economic impacts of the health damages are handled separately from the non‐economic welfare effects. We find that the social costs of health damages in Oslo are significant, and that the non‐economic welfare effects clearly dominate the cost figure.
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    URL: http://dx.doi.org/10.1023/A:1019054604439
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    Imputing Unmeasured Explanatory Variables in Environmental Epidemiology With Application to Health Impact Analysis of Air Pollution (1998)
    Springer
    Environmental and ecological statistics 5 (1998), S. 99-105 
    Details
    ISSN: 1573-3009
    Keywords: structural measurement error ; generalized estimating equations ; longitudinal data ; environmental epidemiology ; spatial prediction ; clustered data ; nonlinear mixed-effect models ; air pollution ; respiratory morbidity ; ozone ; sulphate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This paper presents the results of a reconsideration of earlier work that finds an association between daily hospital admissions for respiratory distress and daily concentrations of sulphate (lag 1) as well as daily maximum concentrations of ozone (lags 1 and 3). These associations are found even after clustering the data by hospital of admission and accounting for the effects of temperature. We use an adaptation of their generalized estimating equation technique for clustered data, that daily data being for southern Ontario summers from 1983 to 1988. Like them, we adjust for daily maximum temperatures. However, unlike the earlier work returned to ours includes daily average humidity as a potential explanatory variable in our model. Our analysis also differs from theirs in that we cluster the data by census subdivision to reduce the risk of confounding pollutant levels with population size within regions. Moreover, we log-transform the explanatory variables and then high-pass filter the resulting data. We also deviate from the earlier analysis by taking account of measurement error incurred in using surrogate measures of the explanatory variables. To do so we use new methodology designed for our study but of potential value in other applications. That methodology requires a spatial predictive distribution for the unmeasured explanatory variables. Each day about 700 missing measurements for each of these variables can then be imputed over the geographical domain of the study. With these imputations we get a measure of imputation error through the covariance of the predictive distribution. Along with the predictive distribution we require an impact model to link-up with the predictive distribution. We describe that model and show how it uses the imputed measurements of the missing values of the explanatory variables. We also show how through that model, uncertainty about these values is reflected in our analysis and in commensurate uncertainties in the inferences made. Apart from its substantive objectives, our analysis serves to test the new methods with the earlier results serving as a foil. The reassuring qualitative agreement between our findings and the earlier results seems encouraging.
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    URL: http://dx.doi.org/10.1023/A:1009610720709
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    Spatial and Temporal Variabilities in Nitrogen and Phosphorous in the Nakdong River System, Korea (1998)
    Springer
    Water, air & soil pollution 102 (1998), S. 37-60 
    Details
    ISSN: 1573-2932
    Keywords: behavior ; distribution ; Nakdong River ; nitrogen ; phosphorus ; spatial ; temporal
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The concentrations of nitrogen (N) and phosphorous (P) species and relevant hydrographic parameters were determined in main stream and tributary waters of the Nakdong River system during the periods of May through October 1994. During the entire period, the total N (TN) and total P (TP) concentrations in surface waters were found within the ranges of 0.4–7.0 (N=241) and 0.02–1.536 mg L-1 (N=241), respectively. To help derive meaningful interpretations of temporal and geographical variabilities in the nutrient bahavior, the entire data were evaluated for each individual parameter after employing several different grouping schemes. The results of this comparative analysis can be expressed in terms of: (1) high summer/fall ratios for most of nutrient species; and (2) low summer/fall ratios for most of nutrient-to-nutrient ratios and relevant hydrographic parameters. Interestingly, while the former case was found to be more significant in tributary waters than main stream waters, such geographical dependence was not strongly evident for the latter case. A z-statistic test, conducted to check the significance of temporal (between summer and fall) and spatial (between tributary and main stream regions) differences, confirm that the observed variabilities are in most cases strong enough for most of variables studied – nutrient species, their ratios, and relevant hydrographic parameters. In addition, comparison of nutrient species between dissolved and particulate phases reveals several interesting features. Unlike dissolved nutrient species, the concentrations of particulate N or P (PN or PP) exhibited quite extraoridanry behavior. While PN appears to be rather minor component of the total N budget for the Nakdong river, PP seems to make rather strong contributions to its total P budgets with its strong input from tributary waters during rainy summer season. Through an application of correlation analysis, relationships between different parameters were investigated for both before and after the grouping of data sets. The overall picture of this analysis showed that nutrient species were strongly correlated with each other, while the strongest correlations were among such hydrographic parameters as DO, BOD, COD, and conductivity. This analysis was further conducted to more deliberately divided data groups. The results of analyses on these sub-grouped data sets indicate that the occurrences of significant corelations were common from tributary waters relative to main streams for both (1) between different nutrient species and (2) between nutrient and hydrographic parameters. Using the line of evidence gathered from the statistical tests and from the correlation analysis, we conclude that the environmental health of the Nakdong river system is affected by the combined effects of various factors and processes.
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    Leaching of Nutrients, Organic Carbon and Iron from Finnish Forestry Land (1998)
    Springer
    Water, air & soil pollution 105 (1998), S. 239-250 
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    ISSN: 1573-2932
    Keywords: Finland ; forested catchments ; iron ; leaching ; nitrogen ; nutrients ; organic carbon ; peatland ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This study provides an assessment of the spatial variability of the long-term leaching of nutrients, total organic carbon (TOC) and iron (Fetot) from 22 forested catchments (0.69-56 km2), distributed across all but the northenmost areas of Finland. The natural, unmanaged Kruunuoja catchment is located in a national park, while the other catchments represent Finnish forestry land. The average leaching of Ptot (4.2 kg km-2 yr-1) from the Kruunuoja catchment was small compared to the catchments representing forestry land (on average 10 kg km-2 yr-1). Moreover, P fertilization was the most important predictor for the spatial variation in Ptot leaching (r2=0.45). Leaching of TOC, Fetot and N compounds was not closely related to forestry practices. Median C/N ratio in the study streams was high (range 34-66). The average inorganic N proportion and leaching of Ptot were lowest in the Kruunuoja catchment (7.3 % and 2.8 kg km-2 yr-1, respectively) and highest in the southernmost Teeressuonoja catchment (54 % and 100 kg km-2 yr-1, respectively) located in the highest N deposition area. The most important forestry practices since the 1960's have affected about 2.4 % of the area of study sites per year (cf. 2% in the entire country in 1991). Moreover, the mean annual runoff from the catchments (230-430 mm yr-1) agrees with the mean annual runoff from Finland (301 mm yr-1). Consequently, the results of the study catchments can be used to estimate average total annual leaching from Finnish forestry land: 2,700 t of Ptot, 48,000 t of Ntot, 110,000 t of Fetot and 1.5 million t of TOC.
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    Reducing Ammonia Losses by Adding FeCl3 During Composting of Sewage Sludge (1999)
    Springer
    Water, air & soil pollution 112 (1999), S. 229-239 
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    ISSN: 1573-2932
    Keywords: ammonia ; composting ; iron chloride ; nitrogen ; sewage sludge ; volatilization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The release of ammonia nitrogen during composting of sewage sludge mixed with a lignocellulosic bulking agent leads to a reduction in the agronomic value of the final compost and to harmful effects on the environment. We propose adding a cheap salt FeCl3 which can be used without special precaution to reduce ammonia losses by decreasing pH conditions. An in-vessel co-composting experiment was conducted in a large reactor (100 L) in which FeCl3 was added to sludge mixed with a bulking agent (pine shavings and sawdust) and compared with a control mixture without FeCl3. Temperature, oxygen consumption and pH were monitored throughout the composting of both mixtures. The final balance of organic matter, organic and inorganic nitrogen permitted to conclude that the addition of FeCl3 reduced nitrogen loss (by a factor of 2.4 in relation to the control) and increased mineralisation of the organic nitrogen by 1.6.
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    Nitrogen Dynamics in Forest Soils after Municipal Sludge Additions (1999)
    Springer
    Water, air & soil pollution 112 (1999), S. 259-278 
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    ISSN: 1573-2932
    Keywords: forest ; municipal sludge ; nitrogen ; soil
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Nitrogen dynamics were assessed for a forested site in southern New Hampshire during the first and second growing seasons after surface application of an aerobically-digested, limed, liquid municipal sludge. Sludge was applied in June 1989, at 3.3, 6.9, and 14.5 M ha-1 (or 199, 396, and 740 kg TKN ha-1). Elevated net N mineralization (in situ buried bags) occurred in the organic and upper mineral soil horizons during the first two months after sludge application, but was similar to control levels thereafter. Net N mineralization was negligible at 30 and 60 cm soil depths. Foliar N concentration increased with sludge loading rates. Concentrations of NH4+ and NO3- in soil leachate were low, except in early fall when microbial activity was still high and plant demand was low. In trenched subplots where vegetative uptake was eliminated, NO3- concentrations in soil leachate (60 cm) rose to between 15 and 35 mg N L-1 in the first year and remained high in the second year. Other studies reported higher magnitudes of NO3- leaching from treated plots. These studies and the findings reported here shown the characteristics of the sludge being applied to land are at least as important as the physical and chemical characteristics of the site to which they are to be applied.
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    URL: http://dx.doi.org/10.1023/A:1005086413282
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    Effect of Soil Oxidants KNO3, MnO2, and Air on Methane Production in Flooded Rice Soil Suspension (1998)
    Springer
    Water, air & soil pollution 105 (1998), S. 677-684 
    Details
    ISSN: 1573-2932
    Keywords: air pollution ; global warming ; greenhouse gas ; methaneformation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract To determine effective means to reduce methane (CH4) production from flooded rice soil, laboratory measurements were made on methane (CH4) formation in a Crowley silt loam as affected by the addition of potassium nitrate (KNO3), manganese dioxide (MnO2), and air (O2) under flooded conditions. In the experiment, oxidants were added to the soil prior to flooding at the rate of 300 and 1000 ppm O2 equivalent. Methane production was measured over a 32 d incubation period. Potassium nitrate added at rates of 300 and 1000 ppm O2 equivalent reduced CH4 production by 100% and MnO_2, at 300 and 1000 ppm O2 equivalent, significantly decreased CH4 formation approximately 20% and 98-99% over the 32 d period, respectively compared to controls. Air addition did not significantly affect CH4 formation.
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    Development of forest stands in the Lusatian lignite mining district after mineral fertilization adapted to site and tree species (1996)
    Springer
    Water, air & soil pollution 91 (1996), S. 33-42 
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    ISSN: 1573-2932
    Keywords: lignite mining ; recultivation ; reafforestation ; mine soils ; fertilization ; nutrition ; nitrogen ; growth of trees and shrubs
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Based on numerous fertilization trials on mine soils of different physical and chemical properties in the Lusatian lignite mining district of northeastern Germany, optimized fertilization methods adapted to site and tree species are presented. Data for nutrition and growth of some tree species (Pinus sylvestris, Quercus rubra) are discussed.
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    URL: http://dx.doi.org/10.1007/BF00280921
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    Seasonal changes inCystoseira myrica and phosphorus input at two sites of the Red Sea Egyptian Coast (1997)
    Springer
    Water, air & soil pollution 93 (1997), S. 199-211 
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    ISSN: 1573-2932
    Keywords: Cystoseira myrica ; Red Sea ; coral reefs ; nitrogen ; phosphorus ; pollution ; eutrophication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Elevated phosphate concentrations at Safaga and Quseir, Red Sea, Egyptian coast, were related to some ecological and nutritional aspects of the macro-algaCystoseira myrica during 1985. The results obtained were compared with those recorded for a non-polluted control site at Ghardaqa. Chemical analysis of surface seawater samples revealed that the concentrations of dissolved phosphate at Safaga and Quseir were 3 and 20 times as much as that at Ghardaqa, respectively. The standing crop ofC. myrica showed two peaks in spring and autumn. Maximum biomass yield (491 g m−2) and number of individuals (127 m−2) ofC. myrica were recorded in the spring at the Ghardaqa site. QuseirC. myrica samples contained significantly higher protein-N, total-N and total-P values but lower carbohydrate values than the Safaga and Ghardaqa samples (LSD at 1% level). Tissue N:P molar ratios forC. myrica, Laurencia papillosa andUlva lactuca collected from Ghardaqa ranged from 68–98, compared to 30–59 for the same species collected at the phosphorus polluted sites at Safaga and Quseir. The carbon levels and the C:N ratios ofC. myrica exhibited no significant variations in the three studied sites. However, the C:P ratios of Ghardaqa plants were significantly higher than those of Safaga and Quseir.
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    URL: http://dx.doi.org/10.1007/BF02404756
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    Carbon and nitrogen stable isotope fractionation in the sediment of Lake Bled (Slovenia) (1997)
    Springer
    Water, air & soil pollution 99 (1997), S. 315-323 
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    ISSN: 1573-2932
    Keywords: lake ; sediment ; carbon ; nitrogen ; stable isotope ; fractionation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Stable isotope composition of carbon and nitrogen in the sediment and pore water of a eutrophic freshwater lake was studied. Based on changes in the δ11C and δ15N values of dissolved components and sediment fraction. possible processes involved in the decomposition of sedimentary organic matter are outlined. The relative importance of acetate fermentation and CO2 reduction was estimated using known mathematical models, and ammonia assimilation by methanogenic bacteria is hypothesised to be the main process governing the isotope fractionation of dissolved nitrogen in pore water.
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    URL: http://dx.doi.org/10.1007/BF02406871
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    Air Issues amd Ecosystem Protection, a Canadian National Parks Perspective (1998)
    Springer
    Environmental monitoring and assessment 49 (1998), S. 251-262 
    Details
    ISSN: 1573-2959
    Keywords: air issues ; air pollution ; Canada ; ecological integrity ; national parks
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Several case histories illustrate national park air issues and responses in Canada. These examples include: acidification studies and establishment of a multiparticipant monitoring programme at Kejimkujik; studies of smoke at campgrounds in Jasper, La Mauricie and Forillon, its effect on health, and the management of visitors and firewood supply to mitigate these risks; and estimates of emissions from through-traffic in Yoho. From these cases and from reviews of the secondary literature, we can identify air issues that affect the maintenance of ecological integrity in national parks. These issues are: forest fires and smoke management; defining goals for ecosystem restoration; representation of natural regional conditions; visitor health and amenity; acidification; pesticides; eutrophication from airborne nitrates; permafrost melting; and UV-B. In June 1995, an International Air Issues Workshop brought together representatives from Canadian and U.S. national parks and other selected agencies. They ranked the air issues affecting national parks, producing quite an eclectic list. From the most to least serious issue, they are: acidification, toxics, visibility impairment, UV-B, smoke management, oil and gas development, fugitive dust, global warming, overflights, light pollution, noise and odour. Note that atmospheric change is only one among a group of stresses affecting national parks. Of 28 stresses recognized as significant for national parks in 1992, acid precipitation ranked 8th and climate change 23rd. Petrochemicals, 17th, pesticides, 18th and heavy metals, 21st, may be partly airborne. The 1995 workshop made several recommendations applicable to Parks Canada, from which those related to research and monitoring needs have been extracted. The air monitoring needed most by national parks is of suspended particulate and visibility. This is in response to human health and amenity concerns and international treaty obligations. The long-term protection of natural sites in national parks provides opportunities for other agencies to monitor ambient air quality and ecosystem responses, for example through the installation of under-canopy monitoring towers. The air research most needed in national parks is the modelling of natural landscapes and vegetation complexes in response to climate change. This follows from the primary purpose of each national park, to maintain the ecological integrity of an area selected to represent a natural region. The principal air research opportunities for other agencies in national parks are probably intensive instrumentation and sampling over several years to examine the air-vegetation-soil transfers of nutrients, pollutants and radiation.
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    Trends in Nitrogen Transport in Swedish Rivers (1999)
    Springer
    Environmental monitoring and assessment 59 (1999), S. 47-72 
    Details
    ISSN: 1573-2959
    Keywords: flow-normalisation ; long-term trends ; monitoring ; nitrogen ; riverine load ; statistical analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Concern about nitrogen loads in marine environments has drawn attention to the existence and possible causes of long-term trends in nitrogen transport in rivers. The present study was based on data from the Swedish environmental monitoring programme for surface water quality; the continuity of these data is internationally unique. A recently developed semiparametric method was employed to study the development of relationships between runoff and river transport of nitrogen since 1971; the observed relationships were then used to produce time series of flow-normalised transports for 66 sites in 39 river basins. Subsequent statistical analyses of flow-normalised data revealed only few significant downward trends (p ≤0.05) during the time period 1971–1994, and the most pronounced of these downward trends were caused by reduced point emissions of nitrogen. The number of significant upward trends was substantially larger (15 for total-N and 18 for NO3-N). Closer examination of obtained results revealed the following: (i) the most pronounced upward trends were present downstream of lakes, and (ii) observed increases in nitrogen transport coincided in time and space with reduced point emissions of phosphorus or organic matter. This indicated that changes in the retention of nitrogen in lakes were responsible for the upward nitrogen trends. The hypothesis that nitrogen saturation of forest soils has caused a general increase in the riverine export of nitrogen from forested catchments in Sweden was not confirmed. Neither did the results indicate that improved agricultural practices have reduced the export of nitrogen from agricultural catchments.
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    The Effects of Acid Precipitation and Ozone on the Ectomycorrhizae of Red Spruce Saplings (1998)
    Springer
    Water, air & soil pollution 103 (1998), S. 263-276 
    Details
    ISSN: 1573-2932
    Keywords: air pollution ; acid rain ; forest decline ; morphotypes ; Picea rubens
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The effects of acid precipitation and ozone on the composition of the ectomycorrhizal community of red spruce saplings were evaluated. In 1986, saplings were excavated from a site in Maine that had been clear-cut in 1979. Saplings were then potted in native soil and transported to Ithaca, New York. With the exception of an ambient control treatment, trees were grown in open-top chambers. Saplings were exposed to five levels of ozone and three levels of acid precipitation beginning in July 1987. Ectomycorrhizae were sampled in 1988 and 1991 after one and four years of treatment, respectively. Although the percentage of root tips infected by ectomycorrhizal fungi was not affected by treatments, a shift in the composition of the ectomycorrhizal community occurred in response to acid precipitation treatments for both sampling years. Among the seven ectomycorrhizal morphotypes identified, the percent composition of one morphotype increased and another decreased in response to higher rain acidity. Alone, ozone treatments did not influence ectomycorrhizal composition; however, a significant interactive response to ozone and acid precipitation was observed in the organic soil horizon in 1988. Such shifts in the composition of the ectomycorrhizal community may indicate that the experimental trees were stressed by pollution treatments.
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    Reconstructing Historic Atmospheric Deposition and Nutrient Uptake from Present Day Values Using MAKEDEP (1998)
    Springer
    Water, air & soil pollution 104 (1998), S. 269-283 
    Details
    ISSN: 1573-2932
    Keywords: acidification ; air pollution ; modelling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A model, MAKEDEP, was developed for reconstructing historic atmospheric deposition and nutrient uptake for forests using present day values. Deposition is reconstructed by separation of wet deposition and throughfall into five different categories. Dry deposition is assumed to depend linearly on needle biomass. Non-marine deposition is scaled using general European emission and deposition trends for sulphur, nitrate and ammonia. Historic nutrient uptake is reconstructed using current biomass and nutrient content, a logistic forest growth curve and information on historic land use.
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    Estimation of Nutrient Atmospheric Deposition to Long Island Sound (1998)
    Springer
    Water, air & soil pollution 105 (1998), S. 521-538 
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    ISSN: 1573-2932
    Keywords: atmosperic deposition ; Long Island Sound ; modeling ; nitrogen ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Anthropogenic nutrient sources (especially nitrogen and phosphorus) released into the Long Island Sound (LIS) causes excessive phytoplankton growth resulting in hypoxic conditions. Atmospheric deposition (both wet and dry deposition) has significant effect on aquatic and terrestrial ecosystems. Two dry deposition monitoring sites were established along the north shore of LIS in February 1991. Wet and dry deposition samples were collected since then. A dry deposition velocity model, based on the characteristics of the water surface, was used to estimate the loading as well as the seasonal variability (dynamics) of nutrients in atmospheric deposition to LIS. The average nitrogen flux from each site was 6.64 kg (as-N) ha-yr-1. The total atmospheric nitrogen loading was estimated to be 2240 metric tons yr-1 which correcponds to 2.5% of the estimated total nitrogen loading to the Sound from all sources. The average phosphorus flux was 37.44 g (as-P) ha-yr-1. The total atmospheric phosphorus loading to the Sound was estimated to be 12.62 metric tons yr-1. The results show that wet deposition was the predominant source of atmospheric contribution to the Sound.
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    Soil and Minespoil Fill as Media for Renovation of Nitrogen and Phosphorus in Domestic Wastewater (1998)
    Springer
    Water, air & soil pollution 102 (1998), S. 361-375 
    Details
    ISSN: 1573-2932
    Keywords: alternative on-site wastewatertreatment and disposal systems ; fill material ; low pressuredistribution systems ; minespoil ; nitrogen ; phosphorus ; wastewater renovation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Development of Appalachian coal mining regions of the USA has been severely hampered by lack of domestic waste disposal technologies suited to fills. The suitability of on-site wastewater treatment and disposal systems (OSWTDS) in fill material is uncertain due to the effects of surface mining on soil physical properties. This research was conducted to evaluate the potential for renovation of N and P present in domestic wastewater by fills produced from mining operations. Nitrogen and P were chosen because of their potential adverse environmental impacts. Soil-fill (a mixture of Jefferson, fine-loamy, siliceous, mesic Typic Hapludult and Muskingom, fine-loamy, mixed, mesic Typic Dystrochrept soils) and minespoil (spoil)-fill (blasted rock material associated with the Taggart Marker and Low Splint Bench coal seams of the Upper Middle Wise Formation) were used in this study. Septic tank effluent (STE) and sand filter effluent (SFE) were applied to spoil-fill columns at four loading rates (0, 5.4, 10.8, and 21.6 L m-2d-1) and spoil-fill columns at one loading rate (21.6 L m-2d-1) for a period of 20 wk. Renovation of wastewater was assessed by determining the concentration of N and P present in column leachate. Reduction of inorganic N (NO3 - + NH4 +), based on N/Cl ratios, ranged from 14.9 to 32.1% after the varying application rates of STE and SFE passed through the soil columns. However, leachate NO3 --N concentrations were still above the 10 mg-1 drinking water standard. The quantity of P emerging from the spoil-fill columns (3.0 mg P L-1) was higher than anticipated and may be related to the indigenous P present in the minespoil. Sorption of P in the soil-fill column decreased with increased STE and SFE application (reductions ranged from 99.1 to 74.4%). Results from this study indicate that there is potential for renovating wastewater in OSWTDS in selected soil-fill areas in reclaimed minelands.
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    Atmospheric Deposition of Trace Metals at Three Sites Near the Great Lakes (1998)
    Springer
    Water, air & soil pollution 103 (1998), S. 423-439 
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    ISSN: 1573-2932
    Keywords: airborne particles ; air pollution ; arsenic ; cadmium ; chromium ; copper ; lead ; manganese ; nickel ; precipitation ; selenium ; vanadium ; zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The concentrations of vanadium (V), chromium (Cr), manganese (Mn), nickel (Ni), copper (Cu), zinc (Zn), arsenic (As), selenium (Se), cadmium (Cd), and lead (Pb) in precipitation and on airborne particles were measured at three Integrated Atmospheric Deposition Network (IADN) monitoring stations on Lakes Superior, Michigan and Erie during 1993 and 1994. These data were used to estimate annual wet and dry deposition fluxes at these sites. In most cases, both wet and dry deposition make an important contribution to the total atmospheric flux of trace metals. Total (wet + dry) annual loadings of Zn and Cr are higher at the Lake Erie site than at the Lake Michigan and Lake Superior sites. Atmospheric loadings of the other metals are similar at all three sites. Wet deposition of metals is more closely related to precipitation amount than to the concentration of metals in the precipitation. Dry deposition fluxes are controlled by the concentration of trace metals on large particles. Total particle mass concentrations are higher during the summer and fall at the Lake Erie site, however no seasonal trends in total particle mass at the other sites or trace metals at any of the sites were detected. The total atmospheric loadings calculated in this work are in agreement with other estimates of metals deposition to the Great Lakes.
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    Magic, Safe and Smart Model Applications at Integrated Monitoring Sites: Effects of Emission Reduction Scenarios (1998)
    Springer
    Water, air & soil pollution 105 (1998), S. 21-30 
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    ISSN: 1573-2932
    Keywords: acidification ; emission ; MAGIC ; model ; nitrogen ; SAFE ; SMART ; sulfur
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Three well-known dynamic acidification models (MAGIC, SAFE, SMART) were applied to data sets from five Integrated Monitoring sites in Europe. The calibrated models were used in a policy-oriented framework to predict the long-term soil acidification of these background forest sites, given different scenarios of future deposition of S and N. Emphasis was put on deriving realistic site-specific scenarios for the model applications. The deposition was calculated with EMEP transfer matrices and official emissions for the target years 2000, 2005 and 2010. The alternatives for S deposition were current reduction plans and maximum feasible reductions. For N, the NOx and NHy depositions were frozen at the present level. For NOx, a reduction scenario of flat 30% reduction from present deposition also was utilized to demonstrate the possible effects of such a measure. The three models yielded generally consistent results. The ‘Best prediction’-scenario (including the effects of the second UN/ECE protocol for reductions of SO2 emissions and present level for NOx-emissions), resulted in many cases in a stabilization of soil acidification, although significant improvements were not always shown. With the exception of one site, the ‘Maximum Feasible Reductions’ scenario always resulted in significant improvements. Dynamic models are needed as a complement to steady-state techniques for estimating critical loads and assessing emission reduction policies, where adequate data are available.
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    Nitrogen Deposition and Strategies for the Control of Acidification and Eutrophication across Great Britain (1998)
    Springer
    Water, air & soil pollution 107 (1998), S. 121-145 
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    ISSN: 1573-2932
    Keywords: critical loads function ; emissions reductions ; modelling ; nitrogen
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract It is now recognised that a multi-pollutant, multi-effect approach needsto be adopted to address the range of problems caused by atmosphericpollution. In this paper we use a relatively simple trajectory model (HARM)to explore the coupled behaviour of sulphur dioxide (SO2),oxides of nitrogen (NOx) and ammonia (NH3) andthe possible effects of future reductions in emissions of these pollutantson depositions of S and N across Great Britain. The performance of HARM withrespect to concentrations and depositions of NOy andNHx is assessed by comparison with data from nationalmonitoring networks. A range of emissions scenarios are modelled and theeffects of these reductions on critical loads exceedance are explored usingthe critical loads function (CLF), which allows both the acidification andeutrophication effects of S and N deposition to be explored simultaneously.Spatial variations in the reductions of deposition of S and/or N required tomeet critical loads are described. Reductions in emissions of the precursorsof strong acids (SO2 and NOx) yield benefits interms of ammonium deposition as a result of their coupled chemistry. Thedevelopment of strategies to control nitrogen deposition will need to take this non-linearity in to account.
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    URL: http://dx.doi.org/10.1023/A:1019832913817
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    Weekly Measurements over One Year of Ammonia Concentrations and Surface Exchange Fluxes at a Danish Heathland with Passive Wind-Vane Flux Samplers in an Aerodynamic Gradient Configuration (1999)
    Springer
    Water, air & soil pollution 113 (1999), S. 357-370 
    Details
    ISSN: 1573-2932
    Keywords: canopy resistance ; deposition ; emission ; micro-meterological approach ; nitrogen
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The present study aims to establish the annual NH3 deposition to an inland heathland in Denmark using a micro-meterological approach with passive wind-vane flux samplers. The integrating samplers were replaced at weekly intervals from May 1995 to May 1996. The average concentration, 2.05 μg m-3 at the heathland is at a moderate level when compared to heathlands in other parts of Europe. The average deposition velocity was 0.83 cm s-1 which is within the range of depositon velocities found for other heathlands in Europe. The average canopy resistance was found to be relatively high, 61 s -1. The measurements yielded a total NH3-N deposition of 2.4 (± 0.9) kg ha-1 yr-1 with a data coverage of 71% for 1995/1996. In 40% of this time the flux is regarded as zero because the flux is not significant different from zero. In 60% of this time the significant fluxes varied from –0.052 μg m-2 s-1 (deposition equal 16.4 kg N ha-1 yr-1) to 0.089 μg m-2 s-1 (emission equal 28.2 kg N ha-1 yr-1). The method is only able to direct measure significant fluxes down to the equivalence of 0.010 μg m-2 s-1 (approximately 3.2 kg ha-1 yr-1). Therefore the exact deposition cannot be determined by the applied method at very low deposition sites such as a coastal heathland in Denmark. In a high-deposition area as in the central Netherlands the method gave significant fluxes with a 100% data coverage for a two month period.
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    URL: http://dx.doi.org/10.1023/A:1005076200470
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  • 90
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    Nitrification and Denitrification Estimates in a Louisiana Swamp Forest Soil as Assessed by 15N Isotope Dilution and Direct Gaseous Measurements (1998)
    Springer
    Water, air & soil pollution 106 (1998), S. 149-161 
    Details
    ISSN: 1573-2932
    Keywords: denitrification ; nitrification ; nitrogen ; nitrous oxide ; wetlands ; 15 isotopes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The transformations of applied (100 kg N ha-1)15 N labelled NO3 and NH4 in Mississippi River deltaic plain swamp forest soil which receives agriculture run-off from adjacent sugarcane fields were determined. Using an isotopic dilution technique, the rates of NO3 production (nitrification) and reduction in the 15NO3 treated soil-water-columns were approximately 240 and 2,320 g N ha-1 d-1, whereas NH4 production (mineralization) and removal rates in the 15NH4 treated soil-water-columns were 270 and 2160 g N ha-1 d-1, respectively. It was shown that if nitrification and NH4 assimilation were the primary processes responsible for NH4 removal, average NH4 assimilation would be 145 g N ha-1 d-1. Based on labelled N2-emission, denitrification was 3 fold greater in the NO3 treatment compared to the NH4 treated soil water-columns with rates of 818 and 266 g N ha-1 d-1 respectively. Even though the rate was lower in the NH4 treatment, results show that nitrification-denitrification of NH4 is a significant process. Nitrogen losses determined by15 N2 emissions were 20.4 and 6.4% and N2O emissions were 0.10 and 0.03% of the applied NO3-N and NH4-N, respectively, over 32 days of incubation. Fertilizer loss through N2O emission was only of minor significance compared to the fertilizer loss through N2 evolution. Nitrous oxide fluxes from the control soil-water-columns averaged 9.4 g N ha-1 d-1. Addition of NO3-N to the columns increased N2O production 56% as compared to a 15% increase from the NH4-N addition. Results show that this wetland soil has a large capacity to process inorganic nitrogen entering the system as a result of agriculture run-off.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1004953626415
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  • 91
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    Element Concentrations in Scots Pine Needles on Radial Transects Across a Subarctic Area (1998)
    Springer
    Water, air & soil pollution 102 (1998), S. 389-405 
    Details
    ISSN: 1573-2932
    Keywords: air pollution ; heavy metals ; needle element content ; Pinus sylvestris ; XRF
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Concentrations of aluminium (Al), arsenic (As), calcium (Ca), cadmium (Cd), chlorine (Cl), chromium (Cr), copper (Cu), iron (Fe), potassium (K), magnesium (Mg), manganese (Mn), nickel (Ni), phosphorus (P), lead (Pb), sulphur (S), silicon (Si) and zinc (Zn) were measured by X-ray fluorescence spectrometry (XRF) in Scots pine needles collected from transects across Finnish Lapland and the Kola Peninsula in Russia. Ni, Cu, Fe, P and S concentrations were significantly higher in the needles collected in the vicinity of the smelters in Monchegorsk, whereas Mn and Zn decreased towards Monchegorsk. No distinct increase of S or decrease of Mn and Zn concentrations in the needles were observed when approaching Nikel. Foliar S concentrations were higher in C needles than in C+1 needles, even in plots close to the smelters. The effect of the emissions from the smelters was clearly seen in the needle chemistry up to 50 km away from smelters and was still perceivable over 100 km away.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1004940627740
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  • 92
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    Effects of Nitrogen and Phosphorus Supply on Hexadecane Biodegradation in Soil Systems (1999)
    Springer
    Water, air & soil pollution 111 (1999), S. 1-18 
    Details
    ISSN: 1573-2932
    Keywords: biodegradation ; hydrocarbon ; nitrogen ; nutrient ratios ; phosphorus ; soils
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The biodegradation of hexadecane (C as hexadecane-C) was assessed under 34 different external nitrogen (N supplied as NO3-N) and phosphorus (P supplied as PO4-3-P) supply conditions in order to determine how different nutrient formulations affected nutrient limitation conditions during degradation. CO2 production yields indicated that shifts in N and P supply levels resulted in variable biodegradation responses due to shifts in the limiting-nutrient (e.g., from N to P). For example, the estimated maximum fractional CO2 yield ratio was 0.24 (mg CO2-C produced mg-1 hexadecane-C) for P-limited nutrient formulations (P:hexadecane-C〈0.01), whereas the yield ratio was more than two times greater when the system was not P- limited. Similar effects were observed for N-limited (N:hexadecane- C〈0.15) versus non-N-limited formulations. The relative bioavailability of natural soil-N and soil-P also was examined. In the soil studied, background soil-N was 96.3% organic-N and was found to be largely nonbioavailable. In contrast, high CO2 yields were observed even when no external P was supplied. An iterative mathematical procedure indicated that the Olsen soil-P subfraction (inorganic soil-P plus soluble organic soil- P) best approximated bioavailable soil-P for this soil. Our results indicate that both N and P additions affect biodegradation yields, but that stoichiometrically inappropriate nutrient mixes produce suboptimal CO2 yields. We also found that the bioavailable fractions of soil-N and soil-P should be incorporated into estimating the most suitable nutrient formulations for a given contamination scenario.
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    URL: http://dx.doi.org/10.1023/A:1005091427942
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  • 93
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    Relationship Between Landscape Characteristics, History, and Lakewater Acidification in the Adirondack Mountains, New York (1999)
    Springer
    Water, air & soil pollution 112 (1999), S. 407-427 
    Details
    ISSN: 1573-2932
    Keywords: acidic deposition ; Adirondack mountains ; disturbance ; modeling ; nitrogen ; sulfur
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Interactions between acidic deposition and watershed characteristics were evaluated for a group of lakes in the Adirondack Mountains, New York. Landscape characteristics were compiled and examined relative to paleolimnological inferences of historical acidification. Results of estimates of acidification using the Model of Acidification of Groundwater in Catchments (MAGIC) and paleolimnological analysis were compared to physical, biological, and landscape change data, including such factors as watershed disturbance, logging, fire, and windthrow, to evaluate if inclusion of additional processes could improve model estimates. Results of bivariate and multivariate analysis confirmed that lakes that have experienced historical acidification tend to be those that receive relatively high amounts of precipitation and have short hydraulic residence times. These variables explained 58% of the diatom-inferred acidification. A combined model of long-term precipitation amount, hydraulic residence time, and recent blowdown accounted for 71% of the historic acidification in the Adirondacks. Lakes that have increased in pH since pre-industrial times tend to be those subject to substantial human disturbance and those that burned during major fires recorded after 1900. The magnitude of the discrepancy between MAGIC model and diatom-inferred hindcasts of acidification was not significantly correlated with any of the landscape change variables, suggesting that additional modifications to the MAGIC model to take into account landscape change are not likely to appreciably improve model performance.
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    URL: http://dx.doi.org/10.1023/A:1005085705318
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  • 94
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    Carbon Monoxide and Nitrogen Oxides Pollution in Moscow (1999)
    Springer
    Water, air & soil pollution 112 (1999), S. 107-131 
    Details
    ISSN: 1573-2932
    Keywords: air pollution ; carbon monoxide ; climatology ; meteorological controls ; Moscow ; nitrogen oxides ; Russia
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Major factors (emissions and meteorology) controlling pollution patterns in Moscow are discussed in the context of different types of urban land use. Nitrogen oxide pollution is one of the main air quality problems in the city. Power generation is the major source of nitrogen oxides: in 1994, it accounted for 63% of the total NOx emissions with transport contributing 30%. CO emissions are produced almost entirely by road transport. An increase in CO levels has been observed since 1990 in line with growing car ownership. Analyses of seasonal and diurnal variations in CO, NO and NO2 concentrations are presented. Meteorological conditions during an intense pollution episode are analysed in the context of the characteristics of the main sources of pollution. The occurrence of high levels of CO concentrations is associated with high pressure systems, surface-based inversions and low wind speeds. High concentrations of NO2 are caused by fumigation of the surface with pollutants emitted by power plants. The passage of warm weather fronts, the decay of elevated temperature inversions, and stronger winds are identified as meteorological condition leading to NO2 build-up.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1005043916123
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  • 95
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    Some Effects of N on Ectomycorrhizal Diversity of Scots Pine (Pinus Sylvestris L.) in Northeastern Germany (1999)
    Springer
    Water, air & soil pollution 116 (1999), S. 135-140 
    Details
    ISSN: 1573-2932
    Keywords: mycorrhiza ; Pinus sylvestris ; nitrogen ; diversity ; mycorrhizal frequency
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In the last three decades high industrial nitrogen (N) emissions have led to eutrophication of a Scots pine stand (Pinus sylvestris [L.]) near Schwedt characterized by a broad cover of Calamagrostis epigejos [L.] Roth (Poaceae). In comparison to the relatively unimpacted control site (low N site), this high N site showed a remarkably low mycorrhizal frequency (percentage of mycorrhizas on total amount of root tips) with seasonal lows down to 27 %. At the low N site the highest number of mycorrhizal root tips was found in the organic layer. At the high N site the amount of mycorrhizas per soil volume was similar in both organic and mineral soil layers, and also significantly lower when compared to the amount at the low N site. The high N site revealed only nine mycorrhizal morphotypes instead of eighteen found at each sampling date at the control site. 80 % of the coenosis at the high N site were represented by only four morphotypes resulting in a low diversity. The seasonal decrease in the mycorrhizal frequency, the small amount of mycorrhizas and the low diversity suggest that the high N deposition at this site has reduced the ability of the pine trees to withstand natural stresses such as prolonged drought or frost periods. This corresponds well with the 42 % reduction in tree stocking density at the high N site compared to the low N site.
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    URL: http://dx.doi.org/10.1023/A:1005211011835
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  • 96
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    Use of the Urease Inhibitor N-(n-BUTYL)-Thiophosphoric Triamide Decreased Nitrogen Leaching from Urea in a Fine Sandy Soil (1999)
    Springer
    Water, air & soil pollution 116 (1999), S. 587-595 
    Details
    ISSN: 1573-2932
    Keywords: groundwater ; nitrogen ; sandy soils
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Application of soluble forms of nitrogen (N) fertilizers to citrus trees in sandy soils of central Florida may cause leaching of NO 3 − below the rooting depth. A leaching column study was conducted to evaluate the leaching of urea, NH 4 + and NO3 − forms of N from calcium nitrate, urea, and urease inhibitor coated urea (Agrotain: N-(-n butyl) thiophosphoric triamide (NBPT)) applied to a Candler fine sand (hyperthermic, uncoated Typic Quartzipsamments) during six cycles of intermittent leaching with 220 mL each of water (total 1320 mL) through the soil columns (equivalent to 30 cm rainfall). The amount of NO3-N recovered in the leachate from calcium nitrate treated soil accounted for 43% of the total N applied. Leaching of N from urea and Agrotain treated soil was pronounced during the second and third leaching events. Cumulative leaching of urea form of N accounted for 12 and 8% of total N applied as urea and Agrotain, respectively. The cumulative amounts of NO3-N and NH4-N recovered in six leachate fractions from urea treated soil accounted for 14 and 21%, respectively, of the total N applied to the column. The corresponding values for the Agrotain treated soil were 8 and 17%, respectively. Soil analysis after the completion of leaching showed no urea throughout the entire depth of column in either urea or Agrotain treatments. The total recovery of N (leachate plus soil) was 48.1, 40.4, and 49.7% of total N applied as urea, Agrotain, and calcium nitrate, respectively. This study demonstrated a significant reduction in leaching of N forms from Agrotain as compared with that from urea.
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    URL: http://dx.doi.org/10.1023/A:1005116911788
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  • 97
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    Modelling the Impact of Lowered Atmospheric Nitrogen Deposition on a Nitrogen Saturated Forest Ecosystem (1998)
    Springer
    Water, air & soil pollution 104 (1998), S. 181-203 
    Details
    ISSN: 1573-2932
    Keywords: coniferous ecosystems ; Douglas fir ; 15N ; NICCCE ; NITREX ; nitrogen ; simulation model
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract For a Douglas fir forest ecosystem subjected to an experimental decrease in nitrogen (N) deposition, N dynamics were simulated using the dynamic simulation model NICCCE. Meteorological driving variables and N concentrations in throughfall were input to the model, that simulated results of a 15N tracer experiment, C and N concentrations in the soil, soil water chemistry and tree biomass. Four years of ambient N deposition, followed by four years of N deposition manipulations by means of a roof construction beneath the forest canopy, were modelled. Simulation of this second period was performed for a high-N treatment (37 kg N ha-1 yr-1) and a low-N treatment with throughfall-N at natural background level (6 kg N ha-1 yr-1). Calibration and model performance is discussed and compared to results of field experiments. The quick response of soil water chemistry after lowering N deposition and the 15N tracer signal observed in soil water at 90 cm soil depth, were simulated closely by the calibrated model. 15NH4-N data could only be simulated by accounting for bypass flow, indicating that throughfall water did not fully interact with the soil. Using the calibrated parameter set of the low-N treatment for the high-N treatment resulted in a lower model performance, although time trends were reproduced well also for this treatment. A sensitivity analysis showed model outcome of N transformations to be very sensitive to soil microbial parameters, such as the C efficiency. Use of the 15N tracer data in the calibration lowered uncertainties of these sensitive model parameters. Evaluation of the N input-output budget and microbial N transformations in the ecosystem revealed that lowering N inputs in this N saturated forest soil resulted in a more than proportional decrease of N leaching losses out of the soil system. Gross N transformations decreased under lowered N input, in particular the formation of NO3-N. Net N mineralization was not affected after four years of N manipulations. Net nitrification was decreased to about one third of the rate observed at the high-N deposition plot. Combining 15N tracer data with dynamic simulation modelling provides a powerful tool to improve model performance and process descriptions, and to evaluate impacts of atmospheric N deposition on N cycling in ecosystems.
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    URL: http://dx.doi.org/10.1023/A:1004992614988
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  • 98
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    Changes in Mass Element Fluxes and their Importance for Critical Loads: Geomon Network, Czech Republic (1998)
    Springer
    Water, air & soil pollution 105 (1998), S. 365-376 
    Details
    ISSN: 1573-2932
    Keywords: catchment ; critical loads ; Czech Republic ; element fluxes ; GEOMON network ; nitrogen ; sulfur
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Three years (1994-1996) of runoff, bulk deposition, and throughfall S and N data obtained from GEOMON, a network of 14 small forest catchments in the Czech Republic, are presented. In this paper, we assess regional differences and temporal trends in S and N fluxes under changing regional burdens. Decreases in S deposition have occurred in the emission-burdened northern and western parts of the Czech Republic, where remedial measures have been applied. For example, at the Uhlířská catchment (Jizerské hory Mtns., northern Czech Republic), throughfall S fluxes decreased from 72.7 to 48.5 kg ha-1 yr-1. In contrast, the relatively clean central and southern parts of the Czech Republic showed an increase in S deposition; for example at the Na lizu catchment (Šumava Mtns., southern Czech Republic) throughfall S fluxes increased from 9.0 to 18.8 kg ha-1 yr-1. In burdened catchments with damaged forests, high runoff of N was observed. Using fluxes of S and N measured at the GEOMON sites, we calculated critical loads and exceedances for both S and N in the catchments. The critical loads of S ranged from 505 to 3,631 mol L-1 yr-1 during 1994-1996; in about 80% of the catchments the critical loads were exceeded by atmospheric deposition; half of the catchments showed an exceedance for N.
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    URL: http://dx.doi.org/10.1023/A:1005056215068
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  • 99
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    Hydrology and Chemistry of the Choptank River Basin (1998)
    Springer
    Water, air & soil pollution 105 (1998), S. 387-397 
    Details
    ISSN: 1573-2932
    Keywords: Chesapeake Bay ; Choptank River ; iron ; nitrogen ; phosphorus ; river water chemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The Choptank River basin is a coastal plain catchment dominated by agriculture (52% of land use). We summarize an 11 year data set of discharge and chemistry from a gauged subbasin. Discharge exhibited seasonal variations driven by seasonal evapotranspiration. There were double seasonal maxima of pH, NH4 +, NO3 -, total N, Fe, and total P concentrations in late spring and fall as the saturated zone rose and fell within the soil. Significant interannual variability in discharge was the result of rainfall variation. There were positive nterannual trends in NO3 - concentrations and negative interannual trends in NH4 + and PO4 3- concentrations. These data were combined to estimate N and P export coefficients of 3-11 kg N ha-1 yr-1 and 0.14-0.66 kg P ha-1 yr-1, driven primarily by interannual variations in discharge. These export coefficients are low compared to other coastal plain watersheds dominated by agriculture and may be responsible for the small anthropogenic effects in the Choptank estuary compared to other Chesapeake drainages.
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    URL: http://dx.doi.org/10.1023/A:1005001525063
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  • 100
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    Bioindication of Different Stresses in Forest Decline Studies in Slovenia (1999)
    Springer
    Water, air & soil pollution 116 (1999), S. 377-382 
    Details
    ISSN: 1573-2932
    Keywords: forest decline ; stress ; air pollution ; bioindication ; Norway spruce ; photosynthetic pigments ; ascorbic acid ; macro nutrients ; epiphytic lichens ; Slovenia
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Determination of the stresses operating on a forest ecosystem demands the use of several bioindication methods. Air quality indicators were assessed from an inventory of forest decline based on the assessment of tree crowns and epiphytic lichens. Photosynthetic pigments, ascorbic acid and major macronutrients were studied in Norway spruce needles as indicators of physiological and biochemical stress. Analyses were carried out on selected forest plots in polluted areas (Zasavje district, vicinity of thermal power plants) and predominantly unpolluted areas (Triglav National Park, Julian Alps, Slovenia). For some bioindication methods, there was good agreement with measured air quality and climatological parameters. The best agreement was found between total foliar sulphur in needles and epiphytic lichens, especially in more polluted areas. Agreement with forest decline inventories and analyses of some needle stress physiological/biochemical parameters was less convincing. The strength of agreement was further decreased by soil characteristics and climatic parameters, influenced also by biotic parameters and forest stand history and management. It was concluded that there is no simple bioindication method available to evaluate the vitality of a forest.
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    URL: http://dx.doi.org/10.1023/A:1005274122159
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