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  • 1
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 73 (1998), S. 1571-1573 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have analyzed the perturbations produced by recombination at surface, trapping at impurities, and stress fields on the room-temperature migration properties of point defects in Si. A stack consisting of a Si oxide (or a Si nitride) and a polycrystalline Si layer, deposited on Si samples, was patterned to open 2-μm-wide, 10-μm-spaced stripes. A 40-keV Si implantation to fluences of 1×1012–5×1013/cm3, performed through this mask at room temperature, was used to inject point defects into the bulk of the wafer. After implants, defect-induced dopant deactivation, in the cross section orthogonal to the direction of the stripes, has been monitored using two-dimensional spreading resistance profilometry. It has been found that, in highly pure epitaxial Si samples, dopant deactivation extends in depth to several microns beyond the region (∼0.4 μm) directly modified by the ions. Furthermore, the two-dimensional deactivation profiles exhibit a strong recess at the surface and a significant anisotropy, being markedly elongated in the lateral direction. Analysis of the data shows that long-range migration of defects is interrupted by trapping at impurities (C and O) or recombination at the surface, characterized by a coefficient of ∼100 μm−1. Moreover, the lateral elongation of the profiles is tentatively explained assuming an anisotropy in the defect diffusivity tensor produced by the strain field under the mask. © 1998 American Institute of Physics.
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  • 2
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 64 (1994), S. 354-356 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The selective chemical etching of silicon containing an impurity profile was used to obtain surface topography related to the local carrier concentration. Atomic force microscopy (AFM) was then used to image this topography. Through a calibration curve of etched depth versus carrier concentration, established by etching uniformly doped epitaxial silicon layers, it is possible to convert the AFM topographical data into carrier concentration. The technique was applied to measure directly the carrier distribution in submicron devices.
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 2370-2377 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: P and B ions with energies of 400 keV and 1 MeV were implanted in a random direction and along the [100] axis of single-crystal Si samples patterned with oxide stripes. The lateral spread of the implants was determined by using two-dimensional spreading resistance measurements. The lateral distribution of ions implanted in a random direction is always broader than that of ions implanted with the same energy along the [100] axis. With increasing dose the lateral penetration for channeled implants increases too due to the disorder introduced in the samples. The experimental results are discussed and then compared with Monte Carlo simulations obtained by the marlowe code.
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 3464-3469 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have investigated the electrical characteristics of p+–n Si junction diodes implanted with 300 keV C ions at fluences of 0.5 and 1×1015 cm−2 and annealed at 900 or 1100 °C. In all cases cross-sectional transmission electron microscopy shows an excellent crystalline quality, with no extended defects, and the C-rich region is characterized by an n-type doping. In the material annealed at 900 °C the C-rich region shows a low electron mobility and the presence of deep donor levels, and, as a consequence, the diode characteristics are nonideal. These effects can be attributed to the formation of C–Si self-interstitial-type complexes after the 900 °C anneal. At 1100 °C part of the C–Si complexes dissolve and the electrical characteristics of the materials noticeably improve. © 1996 American Institute of Physics.
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 195-200 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The diffusion of ion-implanted Au, Pt, and Zn in crystalline Si has been investigated. The implantation was performed in photolithographically defined areas of the wafer and a spreading resistance technique was used to measure the three-dimensional concentration profiles of the metal atoms after high temperature diffusion anneals. We found that the lateral spread under the mask is larger than the vertical diffusion, especially on the sample side opposite to the implanted diffusion source. All the significant features of the measured profiles can be explained as a consequence of the kick-out mechanism of diffusion for these transition metals. In fact, the peculiar shape of the concentration profiles is determined by the interplay between the influx of interstitial metal atoms and the outflux of silicon self-interstitials generated by the kick-out reaction. Despite the high lateral diffusion, it will be shown that by a suitable combination of implantation fluence and annealing temperature it is possible to limit this lateral spread inside ∼200 μm, while maintaining a high metal concentration in the region under the implanted area. This demonstrates the possibility of using transition metal diffusion to control minority carrier lifetime in a selected area of a semiconductor device.
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 69 (1991), S. 726-731 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The diffusion into a p-type Si substrate of arsenic ions implanted into TiSi2 layers has been investigated for several thermal diffusion treatments in the 900–1100 °C temperature range. The drive-in was performed using either a rapid thermal annealing system or a traditional furnace. Shallow (20–80-nm depth) junctions were obtained with a high (1019–1020/cm3) dopant concentration at the silicide-silicon interface. The amount of diffused arsenic atoms measured by Rutherford backscattering spectrometry increases linearly with the square root of the annealing time. A similar relation was found for the amount of electrically active arsenic, as measured by Van der Pauw structure in combination with anodic oxidation. The two quantities differ and the inactive dopants precipitate in the diffused layer as seen by transmission electron microscopy. This behavior might be associated to the high tensile stress induced by the silicide layer on the surface silicon region and to its influence on the solid solubility and clustering of arsenic atoms. Precipitates are easily dissolved after thermal annealing in the absence of the TiSi2 layer.
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 67 (1990), S. 7174-7176 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The matter transport of arsenic ions implanted into titanium silicide layers has been investigated after thermal diffusion treatment in the 800 °C–1100 °C temperature range. The arsenic atoms redistribute between TiSi2 and Si with a segregation coefficient depending on temperature. The diffused amount increases linearly with the square root of annealing time at 1100 °C. The n-doped shallow Si layer has a quite good electrical activity with a mean resistivity of about 1.2 MΩ cm. The leakage current of the reverse-biased n+/p junction is instead quite high. Stacking faults are observed in the diffused layer.
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 88 (2000), S. 1299-1306 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: In this paper an extensive characterization of the electrical activation of ultra-low energy implanted boron in silicon is reported. The Spreading Resistance Profiling technique has been used, in a suitable configuration, for measuring doped layers shallower than 100 nm, in order to extract the carrier concentration profiles. The dependence on the implant energy, dose, and annealing temperature allowed us to gain more insight into the mechanisms responsible for the electrical activation at implant energies below 1 keV. By measuring the electrical activation as a function of time for several annealing temperatures, the thermal activation energy for the electrical activation of the dopant was achieved. It slightly depends on the implant dose and it is in the range of 2–3 eV. In particular, for an implant dose of 1×1014/cm2 it is 2.0 eV, close therefore to the 1.7 eV activation energy found [Napolitani et al., Appl. Phys. Lett. 75, 1869 (1999)] for the enhanced diffusion of ultra-low energy implanted boron. The best conditions to maximize electrical activation, while minimizing diffusion, are identified and junction depths of ∼50 nm with sheet resistance below 500 Ω reported. These data are reported and their implication for the fabrication of future generation devices is discussed. © 2000 American Institute of Physics.
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 89 (2001), S. 5381-5385 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have investigated and modeled the B diffusion in Si following ultralow energy implantation. Secondary ion mass spectrometry measurements revealed that B diffusion is transient enhanced. For the simulation we have used a kick-out model which requires only two uncorrelated parameters able to describe the microscopical processes involved. By optimizing the parameters, an excellent agreement between the simulated and the experimental profile broadening is achieved. Moreover, an extension of the previous model that accounts for interstitial cluster formation and dissolution was implemented in order to achieve a better description of B diffusion. The extracted parameters are discussed and compared with published values. © 2001 American Institute of Physics.
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 3873-3878 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Arsenic implants performed in Si at ultralow energy have been extensively studied with structural, chemical, and electrical analysis. The near-surface damage annealing and its influence on the electrical activation of ultrashallow As in Si as a function of the anneal ambient has been investigated. Double alignment medium energy ion scattering, high resolution transmission electron microscopy, and low energy secondary ion mass spectrometry have been used to assess the dopant behavior and crystal recovery in the near-surface regions. The electrical activation of As in Si has been measured with spreading resistance profiling, four point probe, and van der Pauw methods. Major redistribution of the dopant into the SiO2–Si interface region occurred during crystal regrowth of the damaged Si layer. An inactive meta-stable As solid solution was formed in the near-surface region after amorphous layer regrowth. Electrical activation of the dopant occurred upon dissociation of the As solid solution, when the dopant concentration fell to the steady state level. The As diffusion observed has been shown to be enhanced for short (10 s) anneal times at 1100 °C. When annealing at high temperature in an oxidizing ambient the dopant is retained at a high concentration in the solid and a higher level of electrical activation is observed. Significant outdiffusion of the dopant is observed during high temperature annealing in nonoxidizing conditions which reduced the level of activation. © 2001 American Institute of Physics.
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