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  • Male  (5)
  • 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism  (4)
  • 2005-2009  (9)
  • 1920-1924
  • 1
    Publication Date: 2017-04-03
    Description: Volcanic eruptions are characterized by intense degassing, thus it is imperative to have high quality laboratory data to constrain degassing mechanisms. In order to investigate bubble formation and growth at 1 atm, degassing experiments using a Stromboli basalt were performed on the GSECARS X-ray beamline at the Advanced Photon Source. Volatile-bearing glasses were synthesized at 1250 °C and 1000 MPa in a piston cylinder with H2O or mixtures of H2O+CO2; they were then heated in-situ on the X-ray beamline at 1 atm. Bubble growth was observed in-situ using X-ray radiography. The 3D bubble size distributions in the quenched samples and a natural Stromboli pumice were studied by synchrotron X-ray microtomography. The results show that bubble nucleation and growth in basaltic melts are volatile-concentration dependent. Bubbles can easily form in melts initially containing high volatile concentrations. The effect of CO2 on bubble nucleation and growth becomes significant at large CO2 concentrations of 880 to 1480 ppm, but is not important at lower concentrations. Multiple nucleation events occur in most of these degassing experiments, and they are more pronounced in more supersaturated melts. Bubble growth is controlled by viscosity near glass transition temperatures and by diffusion at higher temperatures. Bubbles begin to pop 10 to 20 s after a foam is developed at vesicularities of 65% to 83%. Bubble size distributions follow power–law relations at vesicularities of 1% to 65%, and bubble size distributions evolve from power–law relations to exponential relations at vesicularities of 65% to 83%. This evolution is associated with the change from far-from-equilibrium degassing to near-equilibrium degassing. During far-from-equilibrium degassing, multiple nucleation events are pronounced, and possibly account for the generation of power–law relations. When the system reaches near-equilibrium degassing, coalescence is dominant and leads to the formation of bubbles of similar size. Therefore, bubble size distributions are described by exponential relations.
    Description: NSERC
    Description: Published
    Description: 533-547
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: reserved
    Keywords: basalt ; Stromboli ; bubble size distribution ; degassing ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: The transport, degassing and atmospheric release of halogens from active volcanism on Earth have been the 12 focus of increasing interest over the last few decades, and have recently been the subject of the 1st workshop 13 on “Halogens in volcanic systems and their environmental impacts” that was held in December of 2007 at 14 Yosemite Lodge in Yosemite National Park, California. As an introduction to this Chemical Geology special 15 issue, collecting contributions from many of the participants at the workshop, we review here recent 16 advances in this field, including experimental and theoretical investigations of halogen behaviour in volcanic 17 and related magmatic systems. We discuss previous research on several aspects of halogen geochemistry, 18 including halogen abundances in the mantle and magmas on Earth; the effects of halogens on phase 19 equilibria and melt viscosities; their partitioning between melt and fluid phase(s) upon decompression, 20 cooling and crystallisation of magmas in the ^ Earth's crust; and their final atmospheric release as volcanic 21 gases. The role of halogens in the genesis of hydrothermal systems and in the transport of ore-forming metals 22 is also reviewed, and we discuss our current understanding of atmospheric processing of volcanic halogens in 23 both the troposphere and stratosphere, and their consequent impacts. In spite of these recent advancements, 24 our current understanding of halogen geochemistry at active volcanoes is still far too fragmentary, and the 25 key questions that require answers from future research are summarised in our conclusions.
    Description: PRIN 2008 and DPC-INGV 1381 2007-2009 grants; NSERC Dis- 1382 covery grant; NSF award EAR 0308866
    Description: In press
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: reserved
    Keywords: Halogens ; Volcanic gas ; Ore deposits ; Atmospheric effects ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2017-04-04
    Description: Diffusion of halogens has the potential to influence petrogenetic processes in magma chambers and conduit degassing processes. This contribution reviews our current state of knowledge concerning halogen diffusion and the influence of halogens on the diffusion of major elements in silicate melts. The addition of halogens to silicate melts at common, natural concentration levels will have little effect on the diffusion of major elements. However, the differences between the diffusivity of water, the diffusivities of halogens, and the diffusivity of sulfur are significant enough that during melt inclusion entrapment, or during rapid bubble or crystal growth, diffusive fractionation betweenwater and the halogens, and between halogens and sulfur, are expected to occur and can influence the compositions of melt inclusions, crystals and volcanic gases.
    Description: NSERC Discovery grant to D.R.B
    Description: In press
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: reserved
    Keywords: Halogens ; Diffusion ; Magmatic processes ; Volcanic gas ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2017-04-04
    Description: Fluorine and chlorine diffusion were measured in two natural phonolitic melts, from Vesuvius (Italy) and from Laacher See (Germany), at 0.5 and 1.0 GPa, between 1250 and 1450 °C at anhydrous conditions and with about 2 and 5 wt.% of dissolvedwater. The two different startingmaterials allowus to investigate the alkali effect,Na vs. K, on halogen diffusion.One compositionwas a K-rich (~10wt.%) phonoliticmelt corresponding to thewhite pumice phase of the 79ADeruption of Vesuvius, and the other aNa-rich (~10 wt.%) phonoliticmelt corresponding tomost differentiated melt of the 12,000 BC eruption of Laacher See. The diffusion-couple technique in a piston cylinder was used for the experiments. Experiments were performed with only one halogen diffusing and with the simultaneous diffusion of a halogenmixture (F, Cl, Br) in order to evaluate the interactions between the halogens during diffusion. Diffusion coefficients for F range between 2×10−11m2/s at 1250 °C and 7×10−11m2/s at 1450 °C for the Na-rich melt and between 1×10−11 m2/s at 1250 °C and 8×10−11 m2/s at 1450 °C for the K-rich melt at anhydrous conditions. Diffusion coefficients for Cl range between 2×10−12 m2/s at 1250 °C and 1×10−11 m2/s at 1450 °C for theNa-richmelt and between 7×10−12m2/s at 1250 °C and 2×10−11m2/s at 1450 °C for the K-richmelt at anhydrous conditions. Fluorine diffusivity is higher than Cl in the Na-rich-phonolitic melt by one order of magnitude,whereas in the K-rich-phonoliticmelt F and Cl diffusivities are similar. The effect ofwater is significant for Cl in both Na-rich and K-rich melts: the addition of water enhances Cl diffusivity by up to one order of magnitude, butwater does not significantly affect F diffusion. F and Cl diffusivities always differ fromone another in the same phonoliticmelt composition. F diffusivities are similar in both compositions. Conversely, Cl diffusion depends upon the dominant alkali. These results evidence that halogen diffusivitymay represent a limiting factor for their degassing during rapid syneruptive decompression and vesiculation of H2O-rich-phonolitic melts. The contrasting volatile diffusivities of F and Cl in silicate melts duringmagma vesiculation may be a key, controlling factor of the composition of the vapour phase (bubbles) produced. Such diffusion controlled degassingmodelmay explain the absence of F and Cl degassing observed during the 79AD eruption of Vesuvius.
    Description: IPGP contribution: 2364; Geotop contribution: 2008-0029.
    Description: In press
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: reserved
    Keywords: Diffusio ; Halogenes ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
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    Nature Publishing Group (NPG)
    Publication Date: 2008-03-14
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Cyranoski, David -- Baker, Monya -- England -- Nature. 2008 Mar 13;452(7184):132. doi: 10.1038/452132a.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/18337778" target="_blank"〉PubMed〈/a〉
    Keywords: Adult ; Adult Stem Cells/*cytology ; Embryonic Stem Cells/*cytology ; Endocytosis ; Genetic Vectors ; Humans ; Male ; *Nanotubes, Carbon/adverse effects ; Peer Review, Research/standards ; Pluripotent Stem Cells/*cytology ; Reproducibility of Results ; Spermatozoa/cytology ; Time Factors ; Transfection/instrumentation/*methods ; Uncertainty
    Print ISSN: 0028-0836
    Electronic ISSN: 1476-4687
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
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  • 6
    Publication Date: 2008-08-08
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Baker, Monya -- England -- Nature. 2008 Aug 7;454(7205):675. doi: 10.1038/454675b.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/18685662" target="_blank"〉PubMed〈/a〉
    Keywords: Aged, 80 and over ; Amyotrophic Lateral Sclerosis/genetics/*pathology/surgery ; Animals ; Cellular Reprogramming ; Disease Models, Animal ; Female ; Humans ; Male ; Mice ; Neurons/*cytology/metabolism/transplantation ; Pluripotent Stem Cells/*cytology/metabolism/transplantation ; Skin/*cytology/metabolism ; Stem Cell Transplantation/contraindications
    Print ISSN: 0028-0836
    Electronic ISSN: 1476-4687
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
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  • 7
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    Nature Publishing Group (NPG)
    Publication Date: 2009-02-25
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Baker, Monya -- England -- Nature. 2009 Feb 19;457(7232):941. doi: 10.1038/457941a.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/19238682" target="_blank"〉PubMed〈/a〉
    Keywords: Adolescent ; Ataxia Telangiectasia/*surgery ; Brain Neoplasms/*etiology ; Brain Tissue Transplantation/*adverse effects ; Child ; Clinical Trials as Topic/standards/trends ; Fetal Tissue Transplantation/*adverse effects ; Fetus/cytology ; Humans ; Internationality ; Male ; Moscow ; Neurons/cytology/*transplantation ; Spinal Cord Neoplasms/*etiology ; Stem Cell Transplantation/*adverse effects
    Print ISSN: 0028-0836
    Electronic ISSN: 1476-4687
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
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  • 8
    Publication Date: 2007-05-05
    Description: The global endemic of cardiovascular diseases calls for improved risk assessment and treatment. Here, we describe an association between myocardial infarction (MI) and a common sequence variant on chromosome 9p21. This study included a total of 4587 cases and 12,767 controls. The identified variant, adjacent to the tumor suppressor genes CDKN2A and CDKN2B, was associated with the disease with high significance. Approximately 21% of individuals in the population are homozygous for this variant, and their estimated risk of suffering myocardial infarction is 1.64 times as great as that of noncarriers. The corresponding risk is 2.02 times as great for early-onset cases. The population attributable risk is 21% for MI in general and 31% for early-onset cases.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Helgadottir, Anna -- Thorleifsson, Gudmar -- Manolescu, Andrei -- Gretarsdottir, Solveig -- Blondal, Thorarinn -- Jonasdottir, Aslaug -- Jonasdottir, Adalbjorg -- Sigurdsson, Asgeir -- Baker, Adam -- Palsson, Arnar -- Masson, Gisli -- Gudbjartsson, Daniel F -- Magnusson, Kristinn P -- Andersen, Karl -- Levey, Allan I -- Backman, Valgerdur M -- Matthiasdottir, Sigurborg -- Jonsdottir, Thorbjorg -- Palsson, Stefan -- Einarsdottir, Helga -- Gunnarsdottir, Steinunn -- Gylfason, Arnaldur -- Vaccarino, Viola -- Hooper, W Craig -- Reilly, Muredach P -- Granger, Christopher B -- Austin, Harland -- Rader, Daniel J -- Shah, Svati H -- Quyyumi, Arshed A -- Gulcher, Jeffrey R -- Thorgeirsson, Gudmundur -- Thorsteinsdottir, Unnur -- Kong, Augustine -- Stefansson, Kari -- New York, N.Y. -- Science. 2007 Jun 8;316(5830):1491-3. Epub 2007 May 3.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉deCODE genetics, Sturlugata 8, IS-101 Reykjavik, Iceland.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/17478679" target="_blank"〉PubMed〈/a〉
    Keywords: Age of Onset ; Aged ; Case-Control Studies ; Chromosome Mapping ; Chromosomes, Human, Pair 9/*genetics ; Coronary Artery Disease/genetics ; Female ; Genes, p16 ; *Genetic Predisposition to Disease ; *Genetic Variation ; Genotype ; Haplotypes ; Heterozygote ; Homozygote ; Humans ; Linkage Disequilibrium ; Male ; Middle Aged ; Myocardial Infarction/*genetics ; *Polymorphism, Single Nucleotide ; Risk Factors
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 9
    Publication Date: 2008-03-29
    Description: Schizophrenia is a devastating neurodevelopmental disorder whose genetic influences remain elusive. We hypothesize that individually rare structural variants contribute to the illness. Microdeletions and microduplications 〉100 kilobases were identified by microarray comparative genomic hybridization of genomic DNA from 150 individuals with schizophrenia and 268 ancestry-matched controls. All variants were validated by high-resolution platforms. Novel deletions and duplications of genes were present in 5% of controls versus 15% of cases and 20% of young-onset cases, both highly significant differences. The association was independently replicated in patients with childhood-onset schizophrenia as compared with their parents. Mutations in cases disrupted genes disproportionately from signaling networks controlling neurodevelopment, including neuregulin and glutamate pathways. These results suggest that multiple, individually rare mutations altering genes in neurodevelopmental pathways contribute to schizophrenia.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Walsh, Tom -- McClellan, Jon M -- McCarthy, Shane E -- Addington, Anjene M -- Pierce, Sarah B -- Cooper, Greg M -- Nord, Alex S -- Kusenda, Mary -- Malhotra, Dheeraj -- Bhandari, Abhishek -- Stray, Sunday M -- Rippey, Caitlin F -- Roccanova, Patricia -- Makarov, Vlad -- Lakshmi, B -- Findling, Robert L -- Sikich, Linmarie -- Stromberg, Thomas -- Merriman, Barry -- Gogtay, Nitin -- Butler, Philip -- Eckstrand, Kristen -- Noory, Laila -- Gochman, Peter -- Long, Robert -- Chen, Zugen -- Davis, Sean -- Baker, Carl -- Eichler, Evan E -- Meltzer, Paul S -- Nelson, Stanley F -- Singleton, Andrew B -- Lee, Ming K -- Rapoport, Judith L -- King, Mary-Claire -- Sebat, Jonathan -- HD043569/HD/NICHD NIH HHS/ -- M01 RR000046/RR/NCRR NIH HHS/ -- MH061355/MH/NIMH NIH HHS/ -- MH061464/MH/NIMH NIH HHS/ -- MH061528/MH/NIMH NIH HHS/ -- NS052108/NS/NINDS NIH HHS/ -- R01 HD043569/HD/NICHD NIH HHS/ -- RR000046/RR/NCRR NIH HHS/ -- RR025014/RR/NCRR NIH HHS/ -- U01 MH061355/MH/NIMH NIH HHS/ -- U01 MH061464/MH/NIMH NIH HHS/ -- U01 MH061528/MH/NIMH NIH HHS/ -- U24 NS052108/NS/NINDS NIH HHS/ -- UL1 RR025014/RR/NCRR NIH HHS/ -- Howard Hughes Medical Institute/ -- Intramural NIH HHS/ -- New York, N.Y. -- Science. 2008 Apr 25;320(5875):539-43. doi: 10.1126/science.1155174. Epub 2008 Mar 27.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Medicine, University of Washington, Seattle, WA 98195, USA.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/18369103" target="_blank"〉PubMed〈/a〉
    Keywords: Adolescent ; Adult ; Age of Onset ; Amino Acid Sequence ; Brain/cytology/*growth & development/metabolism ; Case-Control Studies ; Child ; Excitatory Amino Acid Transporter 1/chemistry/genetics/physiology ; Female ; *Gene Deletion ; *Gene Duplication ; Genetic Predisposition to Disease ; Genome, Human ; Humans ; Male ; Molecular Sequence Data ; *Mutation ; Neurons/cytology/physiology ; Oligonucleotide Array Sequence Analysis ; Polymorphism, Single Nucleotide ; Receptor, Epidermal Growth Factor/chemistry/genetics/physiology ; Receptor, ErbB-4 ; Schizophrenia/*genetics/physiopathology ; Signal Transduction
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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