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  • 1
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Marine Policy 9 (1985), S. 39-52 
    ISSN: 0308-597X
    Keywords: Ecology ; Fisheries ; Marine resources
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Political Science , Law
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  • 2
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Marine Policy 6 (1982), S. 43-57 
    ISSN: 0308-597X
    Keywords: Atlantic ; Fisheries ; Management
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Political Science , Law
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  • 3
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Marine Policy 9 (1985), S. 126-133 
    ISSN: 0308-597X
    Keywords: Fisheries ; Government ; USA
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Political Science , Law
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  • 4
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Marine Policy 6 (1982), S. 61-62 
    ISSN: 0308-597X
    Keywords: Fisheries ; Marketing ; UK
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Political Science , Law
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  • 5
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Marine Policy 8 (1984), S. 137-150 
    ISSN: 0308-597X
    Keywords: Fisheries ; International organizations ; Management
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Political Science , Law
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  • 6
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Marine Policy 7 (1983), S. 197-211 
    ISSN: 0308-597X
    Keywords: Fisheries ; Management ; Property rights
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Political Science , Law
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  • 7
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Marine Policy 6 (1982), S. 219-235 
    ISSN: 0308-597X
    Keywords: Canada ; Fisheries ; Foreign relations
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Political Science , Law
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  • 8
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Marine Policy 6 (1982), S. 66-68 
    ISSN: 0308-597X
    Keywords: Fisheries ; Regional government organizations ; West Africa
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Political Science , Law
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  • 9
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Marine Policy 9 (1985), S. 120-125 
    ISSN: 0308-597X
    Keywords: Exclusive Economic Zones ; Fisheries ; Law of the Sea
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Political Science , Law
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  • 10
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Marine Policy 6 (1982), S. 27-42 
    ISSN: 0308-597X
    Keywords: Fisheries ; International law ; United Nations Organization
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Political Science , Law
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  • 11
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Marine Policy 6 (1982), S. 131-139 
    ISSN: 0308-597X
    Keywords: Economic measurements ; Fisheries ; Pacific
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Political Science , Law
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  • 12
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Marine Policy 7 (1983), S. 267-278 
    ISSN: 0308-597X
    Keywords: Environment ; Fisheries ; Resource management
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Political Science , Law
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  • 13
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Marine Policy 6 (1982), S. 121-130 
    ISSN: 0308-597X
    Keywords: Atlantic ; Fisheries ; Management
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Political Science , Law
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  • 14
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Marine Policy 8 (1984), S. 239-258 
    ISSN: 0308-597X
    Keywords: Antarctica ; Fisheries ; Krill
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Political Science , Law
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  • 15
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Marine Policy 9 (1985), S. 220-236 
    ISSN: 0308-597X
    Keywords: Fisheries ; Resource economics, UK
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Political Science , Law
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  • 16
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    Springer
    Agriculture and human values 17 (2000), S. 125-139 
    ISSN: 1572-8366
    Keywords: Environment ; Fisheries ; Fordism ; Nation-State ; Regulation ; Supranational State ; Transnational corporations ; Transnational State
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract This analysis uses an analytical frameworkgrounded in political economy perspectives of theglobalization of the agro-food sector combined with acase study approach focusing on the Marine StewardshipCouncil (MSC) to inform discussions regarding thecharacteristics of societal regulation in thepost-Fordist era. More specifically, this analysisuses the case of the emergence of the MSC toinvestigate propositions regarding the existence of,and location of, nascent forms of a transnationalState. The MSC proposes to regulate the certificationof sustainable fisheries at the global level throughan eco-labeling program. The MSC was created in 1996by the transnational environmental organization theWorld Wildlife Fund and the transnational corporationUnilever. The emergence of the MSC has generatedheated discussion in fisheries management circles thatis in general divided along North/South lines. Thisanalysis indicates that the case of the MSC providesvaluable insights into the possible characteristics ofsupranational regulatory mechanisms that might emulatethe role of the nation-State in the post-Fordist era.
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  • 17
    ISSN: 1432-1009
    Keywords: Reservoir ; Fisheries ; Breeding and wintering waterbirds ; Raising water levels ; Habitat change
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A new, higher dam was installed at Kerkini Reservoir in 1982, causing habitat and landscape disruption. A decrease in the area of grassland and shallow water areas, the rapid disappearance of reedbeds, the appearance of beds ofNymphaea, and the disappearance of half the forest area were all observed between 1982 and 1991. With the new hydrological regime, a lacustrine system was created, with an extensive, rather deep (4–8 m), pelagic zone favorable for the development of coarse fish species throughout the year. After 1982, an increase in fishing effort and a change in the relative abundance of fish species in the catch, including the disappearance of eels and wels, were observed. The impact of the rise in the water level of breeding aquatic birds led to a general decline in species typical of marshy habitats in favor of species preferring deeper open water habitats. A decrease was recorded in bird species that feed largely on invertebrates and to a lesser extent fish (e.g., glossy ibis) and that require extensive shallow feeding areas. There was a decline in geese, whose nests were regularly flooded, and a major increase in piscivorous birds, particularly diving birds (e.g., cormorants), which prefer deeper open water and benefitted directly from the large increase in coarse fish biomass. The disappearance of birds breeding in flooded meadows (e.g., black-winged stilts) and of those restricted to reedbeds (e.g., marsh harrier) occurred from 1983. Over the same period, the changes in populations of wintering birds at Kerkini were different from those occurring in other wetlands in northern Greece. The changes recorded in the populations of wintering birds at Kerkini did not therefore result from overall regional trends but from the major habitat modifications that occurred to this wetland. As for breeding birds, strictly piscivorous species increased greatly as a result of the increased availability of fish, but also due to the appearance of many suitable night roosting sites (flooded trees) and to the great increase in the area of open water greater than 2 m deep. Today, Kerkini has become the most important breeding site in Greece for a majority of colonial waterbirds. In contrast, wintering shorebirds practically disappeared. The many changes recorded in the status of breeding and wintering birds at Kerkini can mostly be explained by the changes that occurred in the functioning of the ecosystem and in the habitat structure following the inauguration of the new hydrological regime. These changes did not all occur at the same time: some were immediate and others required a delay before they could be detected.
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  • 18
    ISSN: 1432-1009
    Keywords: Fisheries ; Phosphorus ; Contaminants ; Ecosystem ; Management ; Simulation model ; Great Lakes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A simulation model was developed to describe linkages among fish food web, nutrient cycling, and contaminant processes in the southern basin of Lake Michigan. The model was used to examine possible effects of management actions and an exotic zooplankter (Bythotrephes) on Lake Michigan food web and contaminant dynamics. The model predicts that contaminant concentrations in salmonines will decrease by nearly 20% ifBythotrephes successfully establishes itself in the lake. The model suggests that this decrease will result from lowered transfer efficiencies within the food web and increased flux of contaminants to the hypolimnion. The model also indicates that phosphorus management will have little effect on contaminant concentrations in salmonines. The modeling exercise helped identify weaknesses in the data base (e.g., incomplete information on contaminant loadings and on the biomass, production, and ecological efficiencies of dominant organisms) that should be corrected in order to make reliable management decisions.
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  • 19
    Electronic Resource
    Electronic Resource
    Springer
    Environmental management 7 (1983), S. 151-160 
    ISSN: 1432-1009
    Keywords: Grass carp ; Biological control ; Nuisance aquatic weeds ; Fisheries ; Aquaculture ; Reproductive requirements ; Arkansas management plan ; Sterile hybrids
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Grass carp (Ctenopharyngodon idella Val.) were introduced into the United States in 1963 as potential biological control agents for nuisance aquatic weeds. Since that time an oftentimes bitter controversy has raged over its effects on sportfishing, and its possible natural reproduction and naturalization in North America. This review considers the history, ecology, and present status of grass carp in the United States in light of the voluminous scientific research conducted since its importation. Particular attention is given to the role of grass carp in the fisheries management plans of Arkansas. Recent development of a sterile, triploid grass carp hybrid may lead to widespread use of grass carp to control nuisance aquatic weeds in culturally eutrophicated waters of the United States.
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  • 20
    ISSN: 1432-1009
    Keywords: Flushing ; Scouring ; Channel Maintenance ; Fisheries ; Trinity River
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The operation of Trinity and Lewiston Dams on the Trinity River in northern California in the United States, combined with severe watershed erosion, has jeopardized the existence of prime salmonid fisheries. Extreme streamflow depletion and stream sedimentation below Lewiston have resulted in heavy accumulation of coarse sediment on riffle gravel and filling of streambed pools, causing the destruction of spawning, nursery, and overwintering habitat for prized chinook salmon (Salmo gairdnerii) and steelhead trout (Oncorhynchus tschawytscha). Proposals to restore and maintain the degraded habitat include controlled one-time remedial peak flows or annual maintenance peak flows designed to flush the spawning gravel and scour the banks, deltas, and pools. The criteria for effective channel restoration or maintenance by streambed flushing and scouring are examined here, as well as the mechanics involved. The liabilities of releasing mammoth scouring-flushing flows approximating the magnitude that preceded reservoir construction make this option unviable. The resulting damage to fish habitat established under the postproject streamflow regime, as well as damage to human settlements in the floodplain, would be unacceptable, as would the opportunity costs to hydroelectric and irrigation water users. The technical feasibility of annual maintenance flushing flows depends upon associated mechanical and structural measures, particularly instream maintenance dredging of deep pools and construction of a sediment control dam on a tributary where watershed erosion is extreme. The cost effectiveness of a sediment dam with a limited useful economic life, combined with perpetual maintenance dredging, is questionable.
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  • 21
    Electronic Resource
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    Springer
    Environmental management 20 (1996), S. 523-539 
    ISSN: 1432-1009
    Keywords: Water control ; Floodplain ; Fisheries ; Bangladesh ; Chandpur
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Bangladesh is a very flat delta built up by the Ganges—Brahmaputra—Meghna/Barak river systems. Because of its geographical location, floods cause huge destruction of lives and properties almost every year. Water control programs have been undertaken to enhance development through mitigating the threat of disasters. This structural approach to flood hazard has severely affected floodplain fisheries that supply the major share of protein to rural Bangladesh, as exemplified by the Chandpur Irrigation Project. Although the regulated environment of the Chandpur project has become favorable for closed-water cultured fish farming, the natural open-water fishery loss has been substantial. Results from research show that fish yields were better under preproject conditions. Under project conditions per capita fish consumption has dropped significantly, and the price of fish has risen beyond the means of the poor people, so that fish protein in the diet of poor people is gradually declining. Bangladesh is planning to expand water control facilities to the remaining flood-prone areas in the next 15–20 years. This will cause further loss of floodplain fisheries. If prices for closed-water fish remain beyond the buying power of the poor, alternative sources of cheap protein will be required.
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  • 22
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    Springer
    Environmental management 3 (1979), S. 133-144 
    ISSN: 1432-1009
    Keywords: Coastal zone Management ; Fisheries ; Marshes ; Wetlands ; Louisiana
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This paper examines causes and consequences of wetland losses in coastal Louisiana. Land loss is a cumulative impact, the result of many impacts both natural and artificial. Natural losses are caused by subsidence, decay of abandoned river deltas, waves, and storms. Artificial losses result from flood-control practices, impoundments, and dredging and subsequent erosion of artificial channels. Wetland loss also results from spoil disposal upon wetlands and land reclamation projects. Total land loss in Louisiana's coastal zone is at least 4,300 ha/year. Some wetlands are converted to spoil banks and other eco-systems so that wetland losses are probably two to three times higher. Annual wetland losses in the Barataria Bay basin are 2.6% of the wetland area. Human activities are the principal determinants of land loss. The present total wetland area directly lost because of canals may be close to 10% if spoil area is included. The interrelationship between hydrology, land, vegetation, substrate, subsidence, and sediment supply are complicated; however, hydrologic units with high canal density are generally associated with higher rates of land loss and the rate may be accelerating. Some cumulative impacts of land loss are increased saltwater intrusion, loss of capacity to buffer the impact of storms, and large additions of nutrients. One measure of the impact is that roughly $8–17 × 106 (U.S.A.) of fisheries products and services are lost annually in Louisiana. Viewed at the level of the hydrologic unit, land loss transcends differences in local vegetation, substrate, geology, and hydrology. Land management should therefore focus at that level of organization. Proper guideline recommendations require an appreciation of the long-term interrelations of the wetland estuarine system.
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  • 23
    ISSN: 1573-5133
    Keywords: Chondrichthyes ; Elasmobranchs ; Fisheries ; Ageing methods ; Growth rates ; Gestation periods ; Maturity ; Vertebral bands ; Weight-length relationships ; Life histories
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis The silky shark, Carcharhinus falciformis, and scalloped hammerhead, Sphyrna lewini, represent 〉80% of the shark by-catch of the winter swordfish/tuna longline fishery of the northwestern Gulf of Mexico. This catch represents a potential supplemental fishery, yet little is known of the life histories of the two species. This report relates reproductive biology data to age and growth estimates for 135 C. falciformis and 78 S. lewini. Unlike other regional populations, C. falciformis in the Gulf of Mexico may have a seasonal 12 month gestation period. Males mature at 210–220 cm TL (6–7 yr); females at 〉225 cm TL (7–9 yr). Application of age at length data for combined sexes produced von Bertalanffy growth model parameter estimates of L∞ = 291 cm TL, K = 0.153, t0 = −2.2 yr. Adult male S. lewini outnumbered adult females in catches because of differences in the distributions of the sexually segregated population. Males mature at 180 cm TL (10 yr); females at 250 cm TL (15 yr). von Bertalanffy parameter estimates for combined sexes of this species were L∞ = 329 cm TL, K = 0.073, to = −2.2 yr.
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  • 24
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    Environmental biology of fishes 2 (1977), S. 241-259 
    ISSN: 1573-5133
    Keywords: Production ; Fisheries ; Population dynamics ; Energetics ; Fishes ; Competition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis Production rates of seven species of fishes were determined for one year in a 0.95 ha pond. Total annual production of all fishes in the pond was 209 g m−2y−1 (after the subtraction of 16.2 g m−2y−1 of negative production). Over 90% of the production occurred in the months of June through September, with young-of-the-year fishes contributing 84% of the total. When Y of Y fishes shifted to benthic diets in the spring, the small biomass of benthos available could not sustain the large biomas of fish. Severe competition for the available food then resulted in decreased production rates for the entire fish taxocene.
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  • 25
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    Environmental biology of fishes 7 (1982), S. 177-180 
    ISSN: 1573-5133
    Keywords: Temperature ; Behavior ; Ecology ; Fisheries ; Fish ; Marine juveniles
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis Sixteen yearling winter flounder, tested individually for 3-day periods in electronic shuttleboxes, voluntarily occupied an 8–27°C range of temperature, with a modal final thermal preferendum of 18.5°C (mean 18.7°C, median 19°C, midpoint 17.5°C, s.d. 1.9°C, S k + 0.33). The locomotor activity pattern of the yearling fish in the laboratory was markedly nocturnal, with mean hourly nocturnal activity exceeding mean hourly diurnal activity by a factor of 3.4. Maximum activity occurred at 0300 EST, minimum activity at 1400 EST. While activity generally increased with temperature, a local activity minimum occurred at 18.7°C, coinciding with the 24-hour mean final thermal preferendum. Comparison of these laboratory data with previously published field data suggest that behavioral responses to temperature and light play significant roles in determining age- and size-specific differences in seasonal depth stratification and onshore-offshore distributions in this species.
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  • 26
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    Environmental biology of fishes 30 (1991), S. 253-271 
    ISSN: 1573-5133
    Keywords: Rockfish ; Longevity ; Reproductive value ; Fisheries ; Scorpaenidae
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis The characteristics of lightly and heavily exploited Pacific ocean perch,Sebastes alutus, stocks are evaluated relative to the predictions of life history theory. These long-lived species (50–100 year lifespan) show limited phenotypic plasticity and have little buffering against the effects of reduced lifespan. Reduced stock abundance has generated some compensatory increase in growth rate. Length at first maturity varies only slightly with increased growth rate, although age at maturity may decrease by 1–4 years. Grooth increases yield larger (15–20%) size at age and increased reproductive effort at younger ages, but lower size-specific fecundity for these faster-growing fish. This suggests an energy allocation protocol favouring growth over reproduction in these long-lived animals. Rockfishes have late recruitment to fisheries (ages 10–15), and the detection time for results of management actions is equally long. Their vulnerability to overfishing means that indices of population changes, more representative of fishing effects than the catch rate index presently used, are required. Reproductive value indices are shown to be extremely sensitive and continuous with population abundance changes. Their incorporation into monitoring programs would permit more timely evaluation of management actions. Management policies developed for shorter-lived species are shown to be inappropriate for rockfishes. The need for an improved match in the time frame of the species' life history, and that of management strategies, is stressed.
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  • 27
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    Environmental biology of fishes 35 (1992), S. 187-203 
    ISSN: 1573-5133
    Keywords: California ; Elasmobranchs ; Exploitation ; Fisheries ; Life history ; Tagging ; Triakidae
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis The age, growth, and sexual maturation of the leopard shark, Triakis semifasciata, from central California were studied. Growth band counts in vertebral centra of 162 leopard sharks produced von Bertalanffy growth curves with L∞, K. and to parameters of 1536 mm. 0.082, and -2.31, respectively, for both sexes combined. The L8 value for females (1602 mm TL) was slightly but insignificantly higher than for males (1499 mm TL), but the K and to values were almost identical. Seasonal changes in size modes of young-of-the-year leopard sharks, centrum edge characteristics, and growth and tetracycline mark-recapture from the field were used to validate annual deposition of vertebral centrum band pairs. Sexual maturity was evaluated by the gonads and presence of sperm and eggs; males mature at 7 yr and at about 63% of asymptotic length, and females mature at 10 yr, and at about 72% of asymptotic length. This slow growth, late maturity, and relatively low fecundity may increase their susceptibility to over-exploitation.
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  • 28
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    Environmental biology of fishes 45 (1996), S. 219-235 
    ISSN: 1573-5133
    Keywords: Ecology ; Behaviour ; Evolution ; Cichlids ; Fisheries ; Conservation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis Ecological conditions in tropical lacustrine systems are considered by focusing on the evolution, maintenance, exploitation and vulnerability of fish communities in the African Great Lakes. The exceptionally high biodiversities in the littoral/sublittoral zones of the very ancient, deep, clear, permanently stratified rift lakes Tanganyika and Malawi, are contrasted with the simpler systems in their pelagic zones, also with biodiversity in the much younger, shallower Victoria, the world's largest tropical lake.
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  • 29
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    Environmental biology of fishes 23 (1988), S. 141-154 
    ISSN: 1573-5133
    Keywords: Cyanide ; Diversity ; Development ; Ecology ; Environment ; Fisheries ; Pollution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis The biological diversity and productivity of Philippine coral reefs are threatened by siltation, destructive fishing methods, coral and shell collecting and overfishing. Destructive fishing includes: the widespread, illegal use of explosives; poisons such as sodium cyanide; muro-ami and kayakas fishing; and trawling. The recent decline in catch rates threatens the livelihood of 700 000 near-shore subsistence fishermen who catch 55% of the total landings. The new government under Corazon Aquino wishes to protect the marine environment through the creation of a viable marine conservation management plan, enforcement of existing laws and through cooperation between government, non-government and international agencies to provide education and research. The Department of Agriculture, which has the authority for fisheries, has designated the International Marinelife Alliance as the lead non-government agency involved with fund raising, net-training and finding alternatives to destructive fishing methods.
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  • 30
    ISSN: 1573-5133
    Keywords: Cyprinids ; Ethiopia ; Morphotypes ; Food-niche ; Biodiversity ; Feeding ; Evolution ; Fisheries ; Resource partitioning ; Piscivory
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis In October–December 1990, the large barbs (Barbus) that contribute more than 35% of the catch in lake Tana (northern Ethiopia) were studied. Previous authors (Rüppell 1837, Boulenger 1902,1911, Bini 1940) described from 6 to 23 (sub)species for the lake. Banister (1973) lumped all of these into one subspecies: Barbus intermedius intermedius Rüppell,1837. We found that the Lake Tana Barbus could be readily categorized in at least 13 discrete morphotypes, some of which were already distinguished by local fishermen. None of the known descriptions are adequate to distinguish the barbs unambiguously, which is important for monitoring and management of developing fisheries. Intermediates between morphotypes were rare (〈 10%). By applying canonical discriminant analysis on a set of 17 morphometric characters (including some directly associated with feeding) our initial morphotype-distinction was confirmed. Also, differences between the morphotypes in distribution, related to depth and substratum were found, as well as differences in intestinal contents, a key to the food-niche. The high number of piscivorous morphotypes (8 out of 13) was striking as piscivory is relatively rare among cyprinids. Piscivory was found to be highly correlated with morphological (feeding related) characters. The presence of discrete morphotypes, that also differ in food-niche and distribution, strongly suggests that several distinct populations exist, that may be (partly or completely) reproductively segregated. Knowledge about these populations, that may represent separate units of fish stock, is of crucial importance for the management of sustainable fisheries and protection of the biodiversity in Lake Tana. It is possible that several species or even a unique cyprinid species flock are present, that urgently need protection.
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  • 31
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    Environmental biology of fishes 27 (1990), S. 303-308 
    ISSN: 1573-5133
    Keywords: Fish introductions ; Africa ; Cichlids ; Barbus ; Haplochromis ; Lake management ; Fisheries
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis Cyprinid fishes apparently constituted the major part of the original fish fauna in Lake Luhondo, Rwanda, at least until 1934. At that time only three species, all cyprinids, were known from the lake:Barbus neumayeri, a small barbel, very common in the lake (described from the lake asBarbus luhondo) and two larger cyprinid species:Barbus microbarbis andVaricorhinus ruandae. These two large species were probably not very common in the lake. Between 1935 and 1938 some youngTilapia were introduced into Lake Luhondo. Since then and certainly since 1952 the large cyprinids seem to have disappeared completely from the lake. The smallBarbus neumayeri has become extremely rare; at present it survives only in some small tributaries of the lake. In the lake itselfTilapia andHaplochromis species are now the dominant fauna. A survey of the available information is given.
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    Environmental biology of fishes 43 (1995), S. 381-391 
    ISSN: 1573-5133
    Keywords: Fisheries ; Irrigation ; Reproductive seasonality ; Sarotherodon galilaeus ; Species richness ; Water quality
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis A preliminary study of the ecology and commercial fish catches was carried out in the Toho-Todougba, Ahouangan and Dati lakes (1500 ha) in southern Benin (West Africa) over a period of 18 consecutive months. Water quality, species richness, and the reproductive biology of the dominant species, Sarotherodon galilaeus, were examined. Unlike Lagoon Toho-Todougba, lakes Ahouangan and Dati are less favourable for fish production because of their high total iron content and their relative low pH. The study revealed the existence of 19 species belonging to eleven (11) families: 16 species in Lagoon Toho-Todougba,12 in Lake Ahouangan, and 7 in Lake Dati. Lakes Ahouangan and Dati had a relatively high faunal similarity whereas Lagoon Toho-Todougba exhibited a relatively low faunal similarity with the former systems. In Lagoon Toho-Todougba, six cichlid species were the most important component of the fishery: Sarotherodon galilaeus, Tilapia guineensis, T. zillii, T. mariae, Chromidotilapia guntheri, Hemichromis fasciatus. Three catfish species Chrysichthys auratus, Clarias agboyiensis, and Clarias lazera were harvested in low abundances. Some other fish, such as Polypterus senegalus senegalus, Protopterus annectens and Heterotis niloticus were captured sporadically, with H. niloticus appearing more consistently in catches than the others. Although not abundant, Gymnarchus niloticus and the African pike, Hepsetus odoe, were almost always present in the catches. Ctenopoma kingsleyae appeared only in Ahouangan. Some predatory species, such as Notopterus afer and Xenomystus nigri, are encountered only in lakes Ahouangan and Dati. In Lagoon Toho-Todougba, Sarotherodon galilaeus had a sex ratio (♂: ♀) of 0.49:1, and size at maturation was estimated as 12.3 cm TL. The spawning period extended from May to September with the peak occurring in July. Fecundity was correlated to log-body length (r = 0.74) and log-body weight (r = 0.76). Fish catches were estimated at 389 kg ha−1 year−1; about 73% of which was Sarotherodon galilaeus. The overexploitation of juvenile fish and the use of this lagoon for the irrigation of palm tree plantations have reduced fish recruitment and mean size.
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    Environment, development and sustainability 2 (2000), S. 277-304 
    ISSN: 1573-2975
    Keywords: Systems of Knowledge ; Local Knowledge ; Fisheries ; Resource Management
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Sociology
    Notes: Abstract During the last 20 years, the existence of rich systems of local knowledge, and their vital support to resource use and management regimes, has been demonstrated in a wide range of biological, physical and geographical domains, such as agriculture, animal husbandry, forestry and agroforestry, medicine, and marine science and fisheries. Local knowledge includes empirical and practical components that are fundamental to sustainable resource management. Among coastal-marine fishers, for example, regular catches and, often, long-term resource sustainment are ensured through the application of knowledge that encompasses empirical information on fish behaviour, marine physical environments, fish habitats and the interactions among ecosystem components, as well as complex fish taxonomies. Local knowledge is therefore an important cultural resource that guides and sustains the operation of customary management systems. The sets of rules that compose a fisheries management system derive directly from local concepts and knowledge of the resources on which the fishery is based. Beyond the practical and the empirical, it is essential to recognise the fundamental socio-cultural importance of local knowledge to any society. It is through knowledge transmission and socialisation that worldviews are constructed, social institutions perpetuated, customary practices established, and social roles defined. In this manner, local knowledge and its transmission, shape society and culture, and culture and society shape knowledge. Local knowledge is of great potential practical value. It can provide an important information base for local resources management, especially in the tropics, where conventionally-used data are usually scarce to non-existent, as well as providing a shortcut to pinpoint essential scientific research needs. To be useful for resources management, however, it must be systematically collected and scientifically verified, before being blended with complementary information derived from Western-based sciences. But local knowledge should not be looked on with only a short-term utilitarian eye. Arguments widely accepted for conserving biodiversity, for example, are also applicable to the intellectual cultural diversity encompassed in local knowledge systems: they should be conserved because their utility may only be revealed at some later date or owing to their intrinsic value as part of the world's global heritage. At least in cultures with a Western liberal tradition, more than lip-service is now being paid to alternative systems of knowledge. The denigration of alternative knowledge systems as backward, inefficient, inferior, and founded on myth and ignorance has recently begun to change. Many such practices are a logical, sophisticated and often still-evolving adaptation to risk, based on generations of empirical experience and arranged according to principles, philosophies and institutions that are radically different from those prevailing in Western scientific circles, and hence all-but incomprehensible to them. But steadfastly held prejudices remain powerful. In this presentation I describe the 'design principles' of local knowledge systems, with particular reference to coastal-marine fishing communities, and their social and practical usefulness. I then examine the economic, ideological and institutional factors that combine to perpetuate the marginalisation and neglect of local knowledge, and discuss some of the requirements for applying local knowledge in modern management.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1018-1027 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei nochmaliger Untersuchung der Umsetzung von CCl4 mit Si/Cu-Gemischen werden, wie bereits bekannt, SiCl4, C2Cl4 und Si2Cl6 gefunden. Darüber hinaus lief eine direkte Synthese. Sie führte wahrscheinlich zur Bildung des allerdings dabei nicht nachgewiesenen Cl3C·SiCl3. Dagegen wurde die nach der direkten Synthese entstandene Verbindung C(SiCl3)4 erstmalig aufgefunden.  -  Die Entstehung der ebenfalls nachgewiesenen Verbindungen Cl3SiC·C⋮CC·SiCl3 und Cl3SiC·(Cl)C:C(Cl)C·SiCl3 wird durch Dechlorierungen des Cl3CC·SiCl3 mit Kupfer erklärt.  -  Für die neuen Verbindungen wurden Strukturbeweise geführt. Es wurden C2Cl4 und Cl3CC·SiCl3 mit Si/Cu-Gemischen umgesetzt. Die letzte Umsetzung ergab dieselben Reaktionsprodukte wie das CCl4, so daß auch bei diesem eine direkte Synthese über das Cl3CC·SiCl3 glaubhaft gemacht ist.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1048-1055 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Eigenschaften von tert.-Butylthionitrit, Triphenylmethylthionitrit und tert.-Butylthionitrat werden Rückschlüsse auf die Elektronenstruktur der schwefelhaltigen Gruppe gezogen.
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Als weiteres Beispiel für die präparative Überlegenheit der säurekatalysierten Aldolreaktionen des Formaldehyds gegenüber den OH⊖-katalysierten wird über die Synthese der bisher unbekannten Bisanhydro-ennea-heptose, die das Ringsystem des 3.7-Dioxa-bicyclo-[1.3.3]-nonans enthält, berichtet.  -  Bei der Untersuchung des Verhaltens der Bisanhydro-ennea-heptose gegen Alkalien machten sich in der Abspaltbarkeit der Hydroxymethylgruppen charakteristische Unterschiede geltend, deren Erklärung in den konstitutionell-konstellativen Gegebenheiten zu suchen ist.  -  Bei dem Versuch einer Ringerweiterung an der Anhydro-ennea-heptose mit Diazomethan bildet sich eine Verbindung C9H16O5, die wahrscheinlich kein Derivat des Oxa-cycloheptanons-(4), sondern ein Derivat des Tetrahydro-γ-pyrons ist.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1092-1101 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Substituierte Ammoniumsalze vom Typ I liefern mit Abkömmlingen des Phenylglyoxals in Methanol in glatter Reaktion Lactolid-Basen vom Typ II. Aus diesen lassen sich verschiedene Octa- bzw. Decahydroisochinolin-Derivate darstellen, die in 1-Stellung einen substituierten Benzylrest tragen.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1115-1117 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die jodometrische Bestimmung der Hydroperoxyde von Benzolkohlenwasserstoffen kann durch katalytische Wirkung von Kupferionen verbessert werden.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1135-1139 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzung von Tetraacetyl-α-D-glucopyranosylbromid und Tetraacetyl-6-trityl-β-D-glucopyranose mit Silberperchlorat oder Silberfluoroborat in Nitromethan liefert in guter Ausbeute Octaacetyl-β-gentiobiose. Die gleiche Umsetzung mit einem Überschuß an Tetraacetyl-α-D-glucopyranosylbromid und Silberperchlorat führt zur Octaacetyl-α-gentiobiose. Es wird eine Deutung des Reaktionsablaufs gegeben.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1126-1129 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Tachysterin2 wurde mit durch Glas gefiltertem Quecksilberdampflicht in Präcalciferol2 umgewandelt.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1152-1158 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Um eine Aussage über den Reaktionsmechanismus bei der Mercurierung des Ammonium-Ions in wäßrigen Lösungen machen zu können, wurde Quecksilber-(II)-diamminchlorid, Hg(NH3)2Cl2, mit wäßriger Ammoniumacetat-Lösung zum sog. „unschmelzbaren Präzipitat“, HgNH2Cl, umgesetzt. Die Lösung enthielt 1 Mol. 203Hg(CH3CO2)2 pro Mol. des Diammoniakates.Die beiden heterogenen Austauschreaktionen Hg(NH3)2Cl2/[203Hg(NH3)4]2⊕ und HgNH2Cl/[203Hg(NH3)4]2⊕ wurden in Abhängigkeit von der Temperatur untersucht.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1158-1163 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Von den sechs möglichen Isomeren des Decalindiols-(1.4) wurden zwei der Reihe des cis-Decalins und zwei der Reihe des trans-Decalins angehörende Diole durch Reduktion von cis- und trans-Decalindion-(1.4) sowie durch katalyt. Hydrierung von Naphthohydrochinon-(1.4) und ar-Tetralindiol-(5.8) mit Raney-Nickel im Autoklaven erhalten, eindeutig der cis- und trans-Reihe zugeordnet und durch Derivate charakterisiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1184-1188 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Einwirkung von Aryldiazoniumsalzen auf verschiedene monoalkylierte Dihydroresorcine wurde untersucht. Dabei wurden im glatten Reaktionsverlauf δ-Keto-δ-arylhydrazono-carbonsäuren erhalten. Die gleiche Reaktion führte beim 2-Acetamino-dihydroresorcin infolge einer sekundär verlaufenden Wasserabspaltung zu einem Derivat des 1.2.4-Triazols, dessen Konstitution bewiesen wurde.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1206-1212 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Umsetzung von Alkylhydroperoxyden oder Wasserstoffperoxyd mit Formaldehyd und sekundären Aminen werden nach Art der Mannich-Reaktion Aminoalkylperoxyde erhalten. In mineralsaurer Lösung gelingt auch die Umsetzung von Benzamid oder Harnstoff mit Formaldehyd und Alkylhydroperoxyden.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1216-1223 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Einführung der Carbonsäurechloridgruppe in 1- bzw. 3-Stellung des Azulensystems gelingt durch Substitution mittels Phosgens ohne Friedel-Crafts-Katalysatoren. Befindet sich in Nachbarstellung zur Carbonsäurechloridgruppe am 7-Ring kein Substituent, so lassen sich die Verbindungen zu den freien Carbonsäuren hydrolysieren, andernfalls tritt Decarboxylierung ein. Die Säurechloride lassen sich in Ester, Amide und Anilide überführen. Die spektralen Verschiebungen gegenüber den zugrunde liegenden Azulenen werden diskutiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1195-1205 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Hydrierung des Adrenalins mit Raney-Nickel liefert keine brauchbaren Ergebnisse. Das Hexahydro-adrenalin (Xb) wird deshalb synthetisch aus Tetrahydro-benzaldehyd in 5 Stufen in guter Ausbeute dargestellt. Es wird gezeigt, daß das synthetische Produkt eine sterisch weitgehend einheitliche Verbindung ist und die 3(trans).4(cis)-Konfiguration besitzt.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1212-1215 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus cyclischen Ketonen und sekundären Aminen erhältliche α.β-ungesättigte Amine addieren Wasserstoffperoxyd an der Doppelbindung und geben kristalline Peroxyde.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1237-1237 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1239-1246 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Tetrahydroxy-p-benzochinon zeigt einige Eigenschaften, die es als „doppeltes aci-Redukton“ erscheinen lassen. So erleidet es „Diazo-Spaltung“ unter Bildung von Mesoxalsäure-bis-arylhydrazid. Diazomethan verwandelt es in den Tetramethyläther, der leicht, sogar durch den Ausgangsstoff, zum entspr. Hydrochinon reduziert wird. Es werden noch Acetyl- und Aminoderivate des Tetrahydroxy-p-benzochinons und seines Dimethyläthers beschrieben sowie die UV- und IR-Spektren diskutiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1276-1287 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ausgehend von den in der ersten Veröffentlichung(1) beschriebenen Substanzen wurden Derivate der folgenden Peptide synthetisiert: Glycyl-L-glutaminsäure, Glycyl-glycyl-L-glutaminsäure, γ-L-Glutamyl-glycin, α- und γ-L-Glutamylglycyl-L-glutaminsäure, α- und γ-L-Glutamyl-α-L-glutamyl-glycin und α-L-Glutamyl-L-tyrosin. Auch einige freie Peptide konnten erhalten werden. Als interessante Nebenprodukte der Peptidsynthese über gemischte Anhydride mit Kohlensäure-halbestern wurden in zwei Fällen Diacylimide erhalten.
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Beim Behandeln von N-Benzoyl-D-glucosamin (IV) mit chlorwasserstoffhaltigem Aceton entsteht das Acetonderivat VII eines Phenyloxazolins, welches Furanosestruktur besitzt. Dieses wird mit chlorwasserstoffhaltigem Methanol in das entsprechende Aceton-β-methylfuranosid IX und anschließend in das acetonfreie β-Methylfuranosid X umgewandelt.  -  Behandeln von O-Tetraacetyl-N-carbobenzoxy-D-glucosamin (XI) mit TiCl4 oder mit AlCl3/PCl5 führt unter Abspaltung von Benzylchlorid zur Bildung eines Oxazolonderivates (XIII).
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1313-1319 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Methylphenylhydrazone der Monobenzoyl-aldosen liegen im kristallisierten und gelösten Zustand nur als Schiffsche Basen vor, sie zeigen keine Mutarotation und lassen sich zu 5-Benzoyl-2.3.4-triacetyl-pentose- bzw. 6-Benzoyl-2.3.4.5-tetraacetyl-hexose-methylphenylhydrazonen acetylieren, deren Struktur durch Synthese bewiesen wird. Die aus Monobenzoyl-aldose-phenylhydrazonen mit Phenylhydrazin darstellbaren Monobenzoyl-aldose-phenylhydrazonen werden sehr leicht zu Aldose-phenylosazonen und Benzoesäure hydrolysiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1329-1335 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung des Monobrom-, Monojod- und Trimethoxy-pivalophenons werden beschrieben. Die Halogenverbindungen erleiden bei der Einwirkung wäßriger Alkalien eine hydrolytische Spaltung. Die Methoxyverbindung ist gegen Alkalien stabil.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1363-1366 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: β-Aroyl-acrylsäuren reagieren mit Pyrrol, 1- und 2-Methyl-pyrrol nach dem Schema der substituierenden Addition.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1386-1397 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Oxydation von Tetralol-(6) und Östradiol-17-monoacetat mit Bleitetraacetat werden Tetralin-p-chinolacetat und 17β-Acetoxy-östra-p-chinol-(10ζ)-acetat dargestellt. Aus den Chinolacetaten lassen sich die Chinole durch basenkatalysierte Umesterung in Freiheit setzen. Dem aufgezeigten Weg kommt allgemeine Bedeutung zur Darstellung von p-Chinolen zu.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1472-1477 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: β-Phenyl-äthylamine lassen sich mit Cyclohexanon-(2)-essigsäure zu partiell hydrierten Oxindol-Derivaten kondensieren, die durch Ringschluß in Verbindungen der Erythrinan-Reihe übergeführt werden.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1478-1480 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Umsetzung von Chlorameisensäure-benzylester mit überschüssigem Hydrazinhydrat in absol. Chloroform ergibt Carbobenzoxy-hydrazin. In wäßrigem Medium entsteht vorwiegend N.N′-Dicarbobenzoxy-hydrazin (I), das von rauchender Salpetersäure leicht zu Azodicarbonsäure-dibenzylester (II) dehydriert wird.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1483-1500 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurden 2 Tetraphenyl-äthylene, 2 Tetraphenyl-butatriene und 2 Tetraphenyl-hexapentaene mit je 2 meta- bzw. para-ständigen Nitrogruppen dargestellt. Es gelang, die beiden Äthylene durch Kristallisation und das Butatrien mit m-ständigen NO2-Gruppen durch Chromatographie in der cis- und in der trans-Form zu gewinnen. Damit ist bei einem zweiten Beispiel die von J. H. van't Hoff 1874 vorausgesagte Isomerie an einer Verbindung verwirklicht worden, in der 4 C-Atome durch 3 Doppelbindungen verknüpft sind.  -  Die Isomeren des Triens sind lichtempfindlich. Das Mengenverhältnis cis : trans im photochemischen Gleichgewicht entspricht der Zusammensetzung des Kumulens, wie es bei der Synthese anfällt. Die thermische cis-trans-Umlagerung der Butatriene läßt sich vorzüglich IR-spektroskopisch verfolgen. Die Zuordnung der mit A und B bezeichneten isomeren Butatriene zur cis- und trans-Formel wird diskutiert.  -  Von den beiden Hexapentaenen konnte dasjenige mit 2 p-ständigen Nitrogruppen in roten Kristallen, aber nicht in cis-trans-isomeren Formen gewonnen werden. Das entsprechende Hexapentaen mit 2 m-ständigen NO2-Gruppen war in Lösung beständig, es zersetzte sich aber teilweise bei Entfernung des Lösungsmittels.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1517-1523 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzung von 1.3.5-Trinitro-benzol mit Nitrophloroglucin sowie diejenige von Pikrinsäure mit Phloroglucin führt zu polycyclischen Verbindungen. Deren adamantanartige Konstitution wird auf Grund UV-spektroskopischer Vergleiche diskutiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1559-1563 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: α.α′-Alkandialdehyde wurden durch Abbau von α.α′-Dibrom-dicarbonsäuren nach Curtius erhalten. Aus α.α′-Dibrom-korksäure bzw. α.α′-Dibrom-azelainsäure entstanden unter geeigneten Bedingungen l-Formyl-cyclopenten-(1) bzw.-cyclohexen-(1).
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1573-1578 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Der durch Säuren katalysierte Isochinolin-Ringschluß ist unter bestimmten Bedingungen auch mit Substanzen durchführbar, die eine säureempfindliche Gruppe enthalten. Auf diese Weise lassen sich Enoläther bzw. Acetale des Decahydroisochinolons herstellen (XII bzw. XIII), die durch nachfolgende Hydrolyse das freie α.β-ungesättigte Ringketon (XVI) liefern, das man durch direkten Ringschluß nicht erhalten kann.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1594-1599 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Anlagerung von Ammoniak an Δ1-Tetrahydrobenzoesäure und Cyclopenten-(1)-carbonsäure-(1) entstehen ausschließlich die trans-β-Aminosäuren. Der Nachweis der Konfiguration erfolgt bei den entsprechenden cis-Aminosäuren, die durch Hofmannschen Abbau der cis-Hexahydrophthalamidsäure (V) und des cis-Cyclopentan-dicarbonsäure-(1.2)-monoamids erhalten werden. cis-und trans-2-Amino-cyclopentan-carbonsäure-(1) wurden erstmals dargestellt.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1618-1623 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: D-Arabinose-mercaptale lassen sich mit p-Toluolsulfonsäure- und mit Methansulfonsäurechlorid in Pyridin bei tiefer Temperatur partiell zu 5-Tosyl- bzw. 5-Mesyl-D-arabinose-mercaptalen verestern. Diese werden mit Lithiumaluminiumhydrid zu 5-Desoxy-D-arabinose-mercaptalen reduziert. Daraus gewinnt man durch Abspalten von Mercaptan die 5-Desoxy-D-arabinose.
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    Berichte der deutschen chemischen Gesellschaft 91 (1958), S. 2553-2557 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus den Chloriden gesättigter, ungesättigter und aromatischer Mono- und Dicarbonsäuren lassen sich durch Umsetzen mit Kaliumfluorsulfinat die entsprechenden Säurefluoride unter milden Reaktionsbedingungen herstellen.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1550-1558 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die gleichzeitige Einwirkung von o-Phenylendiamin und Phenylhydrazin auf Dehydro-L-ascorbinsäure führt zum 2-Hydroxy-3-[1′-phenylhydrazono-L-threo-2′.3′4′-trihydroxy-butyl]-2.2′-anhydro-chinoxalin, dessen Natriumsalz beim Erhitzen in Wasser unter Ausbildung eines anellierten Pyrazolringes zum 1-Phenyl-3-[L-threo-trihydroxy-propyl]-flavazol kondensiert. Dagegen entsteht unter dem Einfluß von Hydroxylamin-hydrochlorid das 2-Hydroxy-3-[1′-phenyl-5′-hydroxymethyl-pyrazolyl-(3′)]-chinoxalin. Zu der gleichen Verbindung gelangt man auch durch alkalische Verseifung der Diacetylverbindung des Ausgangsstoffes.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1579-1586 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird der Nachweis erbracht, daß bei der Dieckmann-Kondensation des Esters IVc vorwiegend der Ketoester I entsteht. Hydrierung und Hydrolyse führt zu 3-Hydroxy-piperidin-carbonsäure-(2). Ozonspaltung und Hydrolyse ergibt Oxalsäure. Eine entsprechende Kondensation, ausgehend vom Ester IXc, ergibt den ungesättigten Piperidonester X.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1587-1593 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Anlagerung von Ammoniak an Shikimisäure (I) entstehen vorwiegend zwei stereoisomere Aminosäuren der Konstitution III und IV.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1679-1694 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: o-Substituierte Benzole mit 1. aliphatischer Amino- und aromatischer Mercaptogruppe und 2. aliphatischer Mercapto- und aromatischer Aminogruppe wurden in wäßrig-alkoholischem Medium oxydiert. In der 1. Kategorie resultierten je nach pH Sulfenamid oder Disulfid; im geeigneten Fall trat weitere Dehydrierung zum 1.2-Benzisothiazol-Derivat ein. Es wurde ein pH-abhängiges Gleichgewicht Disulfid ⇌ Sulfenamid + Aminomercaptan festgestellt. In der 2. Kategorie lief die Bildung des Sulfenamids (2.1-Benzisothiazol) und des Disulfids nebeneinander in pH-abhängigen Mengenverhältnissen. Ein übergang Disulfid → Sulfenamid konnte nur unter bestimmten oxydativen Bedingungen erzielt werden. Es wurde an diesem Beispiel gezeigt, daß auch unter günstigen sterischen Verhältnissen die aromatische Aminogruppe nicht in der Lage ist, die aliphatische Disulfid-Gruppe zu spalten.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1710-1711 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 5.5-Diphenyl-glykocyamidin wird durch Methyljodid in 3-Stellung methyliert. Durch Ammonolyse (bzw. Aminolyse) von 1-Methyl-2-methylmercapto-4.4-diphenyl-imidazolon-(5) in Gegenwart von Ammoniumsalzen wurden weitere-3-substituierte Glykocyamidine dargestellt.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959) 
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    Keywords: Chemistry ; Inorganic Chemistry
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1638-1643 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Umsetzungen von Glucuron- und Galakturonsäure und einigen ihrer Derivate mit Trimethylchlorsilan werden Substanzen erhalten, die i. Vak. gut destillieren und aus denen sich die Ausgangsverbindungen durch Alkoholyse leicht zurückgewinnen lassen. Die Eigenschaften der Trimethylsilylverbindungen werden beschrieben.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1654-1657 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: (±)-Corypalmin und (±)-Isocorypalmin wurden nach einer vereinfachten Methode zur Darstellung von Tetrahydro-protoberberinen synthetisiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1828-1834 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Carbonsäuren, Carbonsäureester und Kohlensäureester lassen sich durch Umsetzung mit Antimonpentachlorid und Chlorwasserstoff in Acidiumsalze mit Wasserstoff am Oxonium-O-Atom überführen. Diese Acidiumsalze zeigen eine gewisse Chlorwasserstofftension und bilden mit einem zweiten Mol (bzw. bei den Carbonsäuren auch mehreren Molen) der zugehörigen Base H-Brücken-Addukte. Das Dimethyl-carbonatacidium-hexachloroantimonat konnte mittels Diazomethans zum Trimethyl-carbonatacidium-Salz methyliert werden.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1858-1863 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Umsetzung von Kobalt(II)-acetylacetonat, gelöst in Methylenchlorid oder in fester Form, mit gasförmigem Stickoxyd wird ein tiefblaues, kristallines Nitrosyl-kobalt-bis-acetylacetonat rein dargestellt. Dieses ist in Äthylenbromid und anderen organischen Lösungsmitteln monomer löslich. Auf Grund von Leitfähigkeitsmessungen erweist es sich als Nichtelektrolyt und somit als ein Komplex der Koordinationszahl 5. Die aus dem magnetischen Verhalten und dem IR-Spektrum sich ergebenden Bindungsverhältnisse werden diskutiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1880-1903 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus einem Streptomyces-Stamm wurden drei kristallisierte, als ν-, ζ-und ∊-Pyrromycinon bezeichnete Farbstoffe isoliert. ν-Pyrromycinon ist ein 1.4.6-Trihydroxy-carbomethoxy-äthyl-tetracenchinon, ζ- und ∊-Pyrromycinon sind Derivate des 1.4.6-Trihydroxy-7.8.9.10-tetrahydro-tetracenchinons mit einer Carbomethoxygruppe, einer Äthylgruppe und einer bzw. zwei Hydroxygruppen. Durch Dehydrierung bzw. Wasserabspaltung lassen sie sich in ν-Pyrromycinon überführen. Für alle drei Pyrromycinone werden Konstitutionsformeln aufgestellt. Die Pyrromycinone stehen den Rhodomycinonen nahe, mit denen sie über das aus ν-Pyrromycinon dargestellte ν-Iso-pyrromycinon strukturell verknüpft werden konnten.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1918-1920 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzung von Formamid mit Methyläthylketon über Aluminiumoxyd führt bei 350-360° zu α-Amino-methyläthylacetonitril, bei 250-260° zu N-[α-Amino-isovaleryl]-N′-[2-imino-5-methyl-3.5-diäthyl-pyrrolidinyl-(3)]-harnstoff.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1944-1949 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: α-Halogen-ketone setzen sich mit Harnstoff, N-mono- und N.N-disubstituierten Harnstoffen in Dimethylformamid als Lösungsmittel zu 2-Amino-oxazolen um. Auf ihre Umwandlung in 2-Amino-imidazole wird hingewiesen.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1950-1956 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus den drei isomeren Dichloräthylenen kann mit Methyl-lithium in Äther Lithium-chloracetylenid (I) dargestellt werden, während Äthylmagnesiumbromid praktisch unwirksam ist. Die metallorganischen Eigenschaften von I werden zur Synthese organischer Chloracetylen-Derivate ausgenützt.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1982-1982 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1999-2013 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die bereits früher durchgeführten Umsetzungen von ortho-metalliertem Halogenbenzol mit tertiären Aminen, wie Triäthylamin, zu phenylierten tertiären Aminen lassen sich mit einem nucleophilen Angriff der Base auf Dehydrobenzol interpretieren. Zwingendere Argumente für ein intermediäres Auftreten von Dehydroaromaten liefert das Verhalten von orthometalliertem α- und β-Halogennaphthalin gegenüber Triäthylamin, da hierbei ein und dasselbe isomerenfreie β-Diäthylamino-naphthalin entsteht. Dafür spricht auch die Dien-Reaktion von Dehydronaphthalin mit Furan zum Endoxyd XII.  -  Orthometalliertes Halogenbenzol vermag auch mit elektrophilen Partnern wie Triäthylbor zu reagieren. Gleichzeitige Einwirkung von Triphenylbor und Triphenylphosphin führt zum Betain XV.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2022-2025 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Beim Erhitzen von Calciumhydrid mit Borsäure-trimethylester entsteht ein komplexes Hydrid, das Carbonylverbindungen sehr spezifisch zu den Alkoholen reduziert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2029-2032 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus l-Acetyl-3.3.5-trimethyl-5-benzyl-cyclohexen-(1)-ol-(2)-dion-(4.6) wird bei Hydrierung in Gegenwart von Palladium der Benzylrest als Toluol hydrogenolytisch glatt abgespalten. Analoga mit Allyl- bzw. γ.γ-Dimethyl-allyl-Gruppen anstelle des Benzylrestes werden normal hydriert zum n-Propyl- bzw. Isoamyl-Derivat.
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 2.4.6-Trisubstituierte Pyryliumsalze lassen sich mit geeigneten Carbanionen in aromatische Verbindungen überführen. In Analogie zu der früher beschriebenen Reaktion mit Metallsalzen des Nitromethans, wobei Derivate des Nitrobenzols entstehen, werden mit Benzyl-lithium Derivate des Biphenyls, mit Acetessigester substituierte Benzoesäureester, mit Acetylaceton substituierte Acetophenone und mit Cyanessigester substituierte aromatische Nitrile erhalten.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2051-2056 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung einiger Phosphorsäure-monoarylester-dichloride und Phosphorsäure-diarylester-monochloride und eines Phosphonsäure-dichlorids wird beschrieben, ebenso die Kondensation einiger dieser Chloride mit einigen Phenolen zu polymeren Phosphorsäure-phenolestern.
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzungen des Eisenpentacarbonyls mit Derivaten der Pyridinreihe, z. B. Pyridin-aldehyd-(2) und koordinativ 2-zähligen Pyridin-aldehyd-(2)-imiden, wie dem Methyl- und Äthylimid, führen zu Octacarbonyldiferraten mit hexakoordiniertem Kation, z. B. [Fe(RN=CH—NC5H4)3][Fe2(CO)8]. Mitunter verläuft die Reaktion über eine tieffarbige Additionsverbindung des betr. Amins mit Pentacarbonyl, die beim Anil als 2 Fe(CO)5·C6H5N=CH—NC5H4 gefaßt wurde. Weiterhin entstehen im letzteren Fall mit Eisentetracarbonyl, wie auch mit Pyridin-aldehyd-(2)-p-tolil, ferner mit o-Phenylendiamin oder Bipyridyl-(2.2′) und Pentacarbonyl Hendecacarbonylrifterrate, während sich mit Isochinolin, Pyrrolidon und Methylpyrrolidon und Pentacarbonyl Tridecacarbonyltetraferrate bilden, z. B. die Verbindungen [Fe(RN=CH—NC5H4)3][Fe3(CO)11] oder [Fe(C4H6ON(CH3))4][Fe4(CO)13].  -  Die für die Carbonylferrate angenommene Struktur mit 2-, 3- und 4-kernigen Anionen wird schließlich durch IR-Absorptionsspektren gestützt. Insgesamt zeigen so die Ergebnisse den spezifischen Einfluß der betr. komplexbildenden Komponente auf den Reaktionstyp.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2088-2094 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Phosphorhalogen-Verbindungen, quartäre Phosphoniumsalze, Phosphorsauerstoff- und Phosphorschwefel-Verbindungen können mit feinverteiltem Natrium zu Natriumphosphiden bzw. Phosphinen reduziert werden. Aus Natrium-phosphiden und Alkylhalogeniden sind quartäre Phosphoniumsalze leicht zugänglich.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2135-2140 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mittels der Reaktion K4[Ni2(CN)6(CO)2] + 8KC ≡CR → K6[Ni2(C≡CR)8] + 2CO + 6KCN ( R = H, CH3, C6H5) werden die gelben explosiven Octa-alkinylo-diniccolate(I) in flüssigem Ammoniak rein dargestellt. Die zweikernige Struktur dieser Verbindungen wird durch ihren Diamagnetismus, ihre Salznatur durch Leitfähigkeitsmessung bewiesen.  -  IR-Messungen an dem als Ausgangsmaterial verwendeten K4[Ni2(CN)6(CO)2] lassen das Vorliegen ketoartiger CO-Brücken im Anion erkennen.
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  • 88
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Azulen-1(bzw. 3)-glyoxylsäuren und -carbonsäuren wurden aus Azulenen und Oxalylbromid ohne Katalysatoren dargestellt. Die Reduktion von Azulenmonocarbonsäuren, -glyoxylsäuren und -dicarbonsäuren wurde untersucht. Die optischen Eigenschaften der erhaltenen Azulenderivate werden diskutiert.
    Additional Material: 4 Tab.
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  • 89
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2181-2184 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Das in der Überschrift genannte Cyclobutenderivat kann aus Butin-(2) und Chlor bei Anwesenheit von Borfluorid in 45-proz. Ausbeute gewonnen werden.
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  • 90
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2199-2205 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Umwandlung von wasserfreier Hypophosphorsäure erfolgt eine Isomerisierung zu Diphosphor(III,V)-säure. Daneben tritt Oxydoreduktion zu Pyrophosphorsäure und pyrophosphoriger Säure ein. Einige neu vermessene Raman-Spektren von Oxosäuren des Phosphors und deren Salzen werden mitgeteilt.
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  • 91
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die bei der Umsetzung von Tetraphosphor-pentasulfid, P4S5, mit flüssigem Ammoniak entstehenden Ammoniumverbindungen mit vier Phosphor- und fünf Schwefelatomen in der Molekel disproportionieren sich oberhalb von 140° in Tetraphosphor-trisulfid, P4S3, und Tetraphosphor-heptaimido-trisulfid, P4S3(NH)7. Außerdem bilden sich in Nebenreaktionen (ca. 10%) P4S7(NH)3, P4S10 und P4S7. Die Reaktionsmechanismen der Disproportionierungen, die Trennung der hierbei entstehenden Verbindungen und deren Eigenschaften werden beschrieben.
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  • 92
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2271-2277 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: cis- und trans-2.3-Dithia-decalin werden auf zwei Wegen dargestellt, ihre Eigenschaften mit denen ähnlicher cyclischer Disulfide verglichen, die Konstellationen diskutiert.
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  • 93
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2026-2029 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Pyrrol-Chinon-Farbstoffe sind auf Grund der jetzigen Erfahrungen über die Mechanismen der Pyrrolreaktionen und die Bildung von Pyrrolfarbstoffen als Dipyrrylchinone zu formulieren.
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  • 94
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2040-2042 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Schiffsche Basen des Äthylendiamins mit Imidazol-aldehyd-(4 bzw. 5) und Pyridin-aldehyd-(2) aktivieren Kobaltionen in ihrer Peroxydasewirkung. Eisenionen werden durch Chelatbildung mit 4.5-Di-[pyridyl-(2)]-imidazol katalatisch aktiviert.
    Additional Material: 2 Tab.
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  • 95
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Kondensation von 2.4.6-Triphenyl-pyryliumsalzen mit Malonsäurediester oder mit Malodinitril in Gegenwart von Kalium-tert.-butylat verläuft anders als erwartet. Im Gegensatz zu der in früheren Mitteilungen besprochenen Aromatisierungsreaktion werden hier zwei C-Atome des zugesetzten Reagenzes zur Bildung des Benzolrings verwendet; es entstehen nicht Derivate des symm. Triphenylbenzols, sondern des 2.4-Diphenyl-benzophenons.  -  Die Konstitution des mit Malonester gebildeten Stoffes wird durch eine unabhängige Synthese bewiesen.
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  • 96
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Einwirkung von wasser- und alkoholfreien ätherischen Lösungen von Diazomethan, Diazoäthan, Diazoessigsäure-äthylester bzw. Phenyl-diazomethan auf Triketo-indan erfolgt Ringerweiterung mit anschließender Enolisierung und gegebenenfalls Alkylierung der enolischen OH-Gruppe. Mit Diazomethan wurden auf diese Weise Lawson-methyläther, mit Diazoäthan Phthiocol-äthyläther in guten Ausbeuten erhalten, die sich in bekannter Weise zu den freien Hydroxy-naphthochinonen verseifen ließen.
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  • 97
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2132-2135 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An Eisenkatalysatoren mit und ohne Träger wird die Dehydrierung der Ameisensäure gemessen. Die Aktivierungsenergie der Reaktion kann systematisch durch Dotierung des als Träger dienenden Aluminiumoxyds beeinflußt werden. Auch der technisch bei der Ammoniaksynthese übliche Zusatz von Kalium läßt sich so auf eine Halbleiterdotierung zurückführen.
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  • 98
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2439-2450 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Umsetzung von D-Fructose mit optisch einheitlichen Di- und-Tripeptiden wie Glycyl-glycin, Glycyl-L-leucin, Glycyl-L-tyrosin, L-Leucyl-glycin, L-Leucyl-L-tyrosin, Glycyl-glycyl-L-leucin und Glutathion lassen sich als Hauptreaktionsprodukte „D-Glucose-Peptide“ gewinnen, die durch Umlagerung der zunächst gebildeten N-D-Fructosylpeptide entstehen.
    Additional Material: 2 Tab.
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  • 99
    Electronic Resource
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2451-2460 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Umsetzung von D-Fructose mit Gelatine in Dimethylsulfoxyd reagieren 50-60% der freien ∊-Aminogruppen der Lysinbausteine. Der Zucker wird dabei in der Art der Aldose-Aminosäuren (2-N-Aminosäure-2-desoxy-aldosen) an das Protein gebunden. In Eisessig reagieren nur 15% der Lysinbausteine.
    Additional Material: 4 Ill.
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  • 100
    Electronic Resource
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 2478-2481 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Darstellung von 1.2.4-Triazinen aus Ammoniak und Monoacylhydrazonen unsymmetrischer 1.2-Diketone können neben den erwarteten 5.6-Disubstitutionsprodukten (A) die isomeren 6.5-Derivate (B) entstehen. Der Bildungsmechanismus wird diskutiert.
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