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  • Wiley-Blackwell  (17,090)
  • 1980-1984  (17,090)
  • 1925-1929
  • 1982  (8,929)
  • 1980  (8,161)
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  • 1980-1984  (17,090)
  • 1925-1929
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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 152-154 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 2
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 3
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 148-150 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 4
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 174-174 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 5
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 175-176 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 6
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 177-201 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This article reviews the major developments in the engineering and design of three-phase slurry catalytic reactors. A general theoretical analysis for predicting the overall rate of reaction in a slurry reactor for various kinetics is presented, incorporating all the transport effects. Modeling of semi-batch reactors is discussed and design procedures are indicated. Some major correlations and methods for determining gas-liquid and liquid-solid mass transfer coefficients and effective diffusivity in liquid filled pores are reviewed. Slurry reactors are compared with other three-phase reactors, such as trickle bed or packed bed reactors, and relative merits are pointed out.
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  • 7
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 201-212 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Intraparticle mass transfer in coal pyrolysis is described by ternary diffusion and viscous flow, in conjunction with a simple pore model to predict concentration profiles for gases and tar. At low pressures, product yields depend on particle size only, while at high pressures they depend on pressure and particle size. Limited experimental data from a subbituminous coal confirm these trends. Data from a bituminous coal show different trends, as expected from the drastic changes the pore structure undergoes during pyrolysis.
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  • 8
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: When primary control objectives cannot be measured directly, secondary measurements have to be selected and used in conjunction with estimators to infer the value of the unmeasurable variables. Unmeasured process disturbances (state excitation noise) are assumed to be of major importance, dominating the errors caused by measurement noise. Since the white noise assumption is generally insufficient for the persistent disturbances commonly occuring in the Chemical Engineering, environment, a nonstationary noise model has been employed, and is shown to yield superior estimations under these circumstances. New necessary and sufficient conditions have been developed for the observability of the dynamic system augmented to include the noise model.A variety of new measurement selection criteria is presented here, with the goal of minimizing estimation error. One class of criteria aims at minimizing the transient estimation error when a static estimator is used. The other class minimizes the measurement error caused by the unobservable subspace. The design of state reconstruction procedures (which are able to handle persistent unmeasured process disturbances) is explained in a stochastic and a deterministic framework. Finally, the synthesis of reduced order control schemes is discussed. The power of the selection criteria and the superiority of a Kalman filter design employing a nonstationary noise model is demonstrated in many examples.
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  • 9
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 274-281 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A three-parameter model of axial and radial dispersion in a packed tubular reactor is proposed as an alternative to the Fickian dispersion model. Though it is formulated in terms of differential equations, it requires no exit boundary condition, so it is mathematically more convenient than the Fickian model. Examples of its application to chemical reactors are given.
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  • 10
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 287-288 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 11
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 308-310 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 12
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 314-317 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 13
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 317-319 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 14
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    AIChE Journal 26 (1980), S. 325-327 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 15
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    AIChE Journal 26 (1980), S. 1-9 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This article describes a novel approach to the systematic synthesis of heat exchanger networks. For a given synthesis problem, this approach leads to a complete listing of all solutions which exist, using a prescribed degree of energy recovery, the minimum number of exchangers, heaters and coolers, and no split streams. The approach is combinatorial, with a variety of thermodynamic criteria used to minimize the problem size by preventing infeasible solutions being generated. Two examples (5SPI and 6SPI) are discussed to illustrate complete solution by hand.
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  • 16
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 24-30 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: For moving-bed solids flow in an inclined pipe leading into a fluidized bed, the pressure drop across the pipe is a retarding force while the gas leakage rate alters the flow properties of the solids. The pressure drop has been related to the pipe exit pressure, which, in turn, can be calculated by integrating the solids bulk density over the bed depth. A correlation for the rate of gas leakage in terms of the geometric features and operating conditions of the system is developed. The correlation agrees with experimental data to within ± 25%. Part II of this paper will deal with solids flow.
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  • 17
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 43-51 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Diffusion in concentrated, non-ideal liquid solutions may take place not only through motion of single molecules but also through movement of groups of molecules, or “clusters.” Analyzing this cluster diffusion leads to predictions that the diffusion coefficient can vary with the square root of the usual activity corrections to diffusion. These predictions seem consistent with experiments, particularly in highly non-ideal solutions.
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  • 18
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 60-67 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A reactor of fiour crossflow nomolithic blocks is used to approximate a cocurrent and a countercurrent reactor-heat excanger. Essentailly isothermal reaction pass profiles are produced by flowing the coolant and reactant streams cocurrent to each other according to the criteria set down in Part I of this paper. A multiplicy of steady states is shown to exist for the autothermal countercurrent mode, but not for the autothermal cocurrent mode, under identical conditions.
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  • 19
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: There are several ways to remove minral matter from coal-derived liquids: antisolvent agglomeration and subsequent sedimentation is one. Adding antisolvent to coal liquids causes asphaltenes and/or preasphaltenes in the oil to precipitate. The precipitated asphaltenes then agglomerate the paraticles, increasing the sedimentation rate. The magnitude of this increase depend no the mixing conditions used to dispers the antisolvent in the oil.This article discuss the results of sedimentation experiments performed onthe antisolvent addition to coal liquids, using an x-ray detection system. The system has the capacity of high temperature (up to 315°C) and high pressure (up to 2.75 7 × 106 Pa). The important parameters are the mixing time, the impeller speed, and the antisolvent addition rate. These are studied in detail for the antisolvent Soltrol.
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  • 20
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 132-134 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 21
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 136-139 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: NO Abstract.
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  • 22
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    AIChE Journal 26 (1980), S. 144-148 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Slugging experiments were performed in a semicircular Plexiglas column 5.6 m in height to study the effect of an expanded section on slugging. The bottom section of the column (3.05 m long) is 28.6 cm in inside diameter and the expanded section 40.6 cm. Both the bed height and the fluidizing velocity were varied during the study, and the results were successfully correlated with a theoretically derived equation. The implications in designing a bed with an expanded section to reduce the slugging effectively are also discussed.
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  • 23
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    AIChE Journal 26 (1980), S. 154-157 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 24
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 25
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 507-510 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 26
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    AIChE Journal 26 (1980), S. 510-513 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Ruthven (1976) published thermodynamic and kinetic data on the adsorption of five gases in zeolites over a wide range of temperatures and concentrations. We have described zeolite diffusivities with a model based on the discrete structure of zeolite crystals and a statistic-thermodynamic evaluation of equilibrium measurements (Fiedler and Celbin 1978). Prof. Ruthven has kindly sent us tables of results for all systems in his paper, which we analyze below.
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  • 27
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    AIChE Journal 26 (1980), S. 526-526 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 28
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 29
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    AIChE Journal 26 (1980), S. 517-521 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 30
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    AIChE Journal 26 (1980), S. 526-526 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 31
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    AIChE Journal 26 (1980), S. 527-528 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 32
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    AIChE Journal 26 (1980), S. 529-536 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Models of the role of the interstitial fluid for dispersion in a fixed bed for very high Reynolds numbers are examined in detail to determine how well they fit the physical requirements of finite speed of signal propagation, no backmixing, conservation and correct asymptotic form. It is concluded that no linear continuous partial differential equation of finite order can satisfy all of these requirements as well as the cell model, although all models for sufficiently large axial space and time variables are very good approximations to the cell model. Some new hyperbolic models are presented and their solutions obtained and compared with the standard solutions. In present day design it appears that no model has an outstanding advantage over any other.
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  • 33
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The simultaneous solution of all the equations for a general system of interlinked, multistaged separators is considered. The interlinks may be simple streams or reciprocal streams, and a particular separator may have bypassing streams (for example, pumparounds). Algorithms are developed that automatically arrange the linearized equations so that for a Newton-Raphson type of solution procedure using, for example, the Naphtali-Sandholm technique, a minimum or nearly minimum number of nonzero blocks occur outside the tridiagonal band so that computational memory and time requirements are minimized. The nonzero and nonidentity blocks are stored in a single vector of variable dimension.
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  • 34
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    AIChE Journal 26 (1980), S. 602-610 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Measurements were made of the steady state flux of sulfur dioxide through films of water and solutions of neutral and alkaline sodium salts (0.1 to 2.0 M sodium chloride, 10-3 to 3.0M sodium hydroxide, NaHSO3 or sodium sulfite) with sulfur dioxide partial pressures between 10 and 100Pa. In agreement with equilibrium theory (Part I), data from water and sodium chloride solutions show that HSO3- is responsible for 83 to 95% of the flux (facilitation factor F between 5 and 19). In alkaline solutions, HSO3- and other sulfur containing species cause F to be as large as 1 370. Equilibrium theory, however, overpredicts F by up to a factor of 7. The NEBLA (Part I) accounts for this deviation.
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  • 35
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    AIChE Journal 26 (1980), S. 635-641 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: There are many industrially important reactions in which the chemical kinetics and external diffusion govern the observed reaction rate, and the observed kinetics differ drastically from the true kinetics. This study shows that the forward stagnation flow region of a circular cylinder can be a convenient system for studying the true kinetics of a solid catalyzed reaction owing to its unique property of uniform accessibility.
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  • 36
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    AIChE Journal 26 (1980), S. 663-669 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A five plate distillation column, 100 mm in diameter, has been used to study both fluid mixing and the mass transfer separations of mixtures of methylcyclohexane and n-heptane under periodically cycled conditions. Both the fluid mixing and mass transfer could be successfully analyzed using the (2S) model to describe the liquid movement in the column. Previously reported results by McWhirter and Lloyd could not be reproduced. Only moderate improvements in separating ability can be obtained with sieve plates and packed sieve plate columns operated in the cycled mode.
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  • 37
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    AIChE Journal 26 (1980) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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  • 38
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In an earlier article, a Corresponding States Method was presented for predicting the saturated liquid densities of both pure components and mixtures. The method is based on the known saturated liquid densities of two reference fluids and requires the critical properties and acentric factors of the pure components as input parameters. We use the method here to calculate the swelling factors of CO2-crude oil mixtures using CO2 and n-dodecane as the reference fluids. The critical properties and acentric factors of the crude oils were estimated from their API gravities and Watson K-factors. Using only one adjustable coefficient to characterize each CO2-crude oil system, swelling factors were calculated to within 0.5% of their experimental values. The single, adjustable coefficient is linearly related to the boiling point of the crude.
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  • 39
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    AIChE Journal 26 (1980), S. 372-378 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A cubic perturbed, hard sphere equation of state which combines the hard sphere expression of Scott and the empirical attractive term of Redlich and Kwong with two temperature dependent parameters has been successfully applied to the calculation of pure component properties and vapor-liquid equilibrium values.
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  • 40
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    AIChE Journal 26 (1980), S. 390-398 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Trajectories of bubbles and entrained particles in the rotating fluidized bed were obtained from equations expressing a balance among inertial, centrifugal, Coriolis, gravity and drag forces. The solutions led to information on the behavior of isolated bubbles, bubbles swarms and the elutriation characteristics of the rotating fluidized bed.
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  • 41
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    AIChE Journal 26 (1980), S. 411-419 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: We identify dispersion approximations to the transverse average of the solution of the convective diffusion equation on exacting equality of a finite number of axial Hermite moments. The method unifies the dispersion of chemically active and passive solutes and generalizes dispersion theory to arbitrary transverse averages. We emphasize the importance of the scalar results via their application to the dispersion of a system of chemical isomers.
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  • 42
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    AIChE Journal 26 (1980), S. 443-454 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: When an aerocolloidal suspension flows through a fibrous filter, particles deposit on the fibers and form dendrites. Similar phenomena are observed with collectors other than fibers, provided that the characteristic dimension of the collector does not exceed that of the particles by more than one to two orders of magnitude. This deposition pattern leads to marked increases in capture efficiency and pressure drop, as particles accumulate within the filter. In previous publications, theoretical models of this process were developed for the cases of deposition by interception alone and of deposition by combined inertial impaction and interception. Consequently, those works apply to aerosol particles with diameters of 1 μm or larger. Here we extend the model to the case of submicron particles, where the main transport mechanism is Brownian diffusion. To keep things specific, we consider fine fibers as collectors, but the model can be easily converted to other geometries. We present solutions for the cases of nonslip flow around the fiber and nonslip, slip and free molecular flow around particles. Unlike deposition by inertial impaction and/or interception, convective Brownian diffusion forms dendrites over the entire fiber surface.
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  • 43
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    AIChE Journal 26 (1980), S. 471-477 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The performances of cylindrical and conical thickeners are compared by means of calculations, using published data on the properties of a suspension. Experimental data on the operation of cylindrical thickeners indicate that sludge funneling at the bottom of such thickeners has a large effect and is a possible cause of observed discrepancies between theory and experiment.
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    AIChE Journal 26 (1980), S. 487-496 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model is developed for the gasification of a single-char particle in an environment of water, hydrogen, carbon dioxide, carbon monoxide and methane, existing in the gasification zone of a reactor. The model, consisting of the mass and energy conservation equations, together with the Stefan-Maxwell relations includes the intraparticle effects and the change in internal surface area. It is found that the intraparticle effects and the surface area effects are significant and hence cannot be neglected, and the situation becomes more acute with increasing particle size and high temperatures. Comparisons with other models and existing empirical relations show that the model agrees well when diffusional effects are minimal, but at higher temperature and large pariticle size there is a significant difference. The model may be used to discriminate among various idealized models such as the homogeneous and the shrinking core model. The conyective terms in the Stefan-Maxwell relations have negligible influence. The analysis can be directly used in the modeling studies of gasification reactors and will be so applied in a later paper.
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    AIChE Journal 26 (1980), S. 496-504 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study of the identification of the dynamics of a pilot scale absorption-desorption system and the subsequent design of a multivariable control scheme are reported. A multivariable transfer function model was obtained from experimental input-output data in which the inputs (steam supply and liquid circulation rate) were perturbed simultaneously using uncorrelated pseudo random sequences. A two-step, least-squares estimator was employed for the identification of the model.A multivariable controller was then designed on the basis of the direct Nyquist array method. The implementation of the controller design indicated the utility of the design procedure as compared to independent single input, single output control loops; there is, however, some scope for additional tuning.
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    AIChE Journal 26 (1980), S. 513-517 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 26 (1980), S. 828-832 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new numerical method is proposed for the one-dimensional melting problem. Unlike many of the existing numerical techniques which either immobilize the moving interface by a suitable coordinate transformation or search for the moving interface under a fixed grid, fixed-time-step finite-difference formulation, the present method was a fixed grid, variable time-step approach. Each time step in the computation is determined iteratively by requiring that the interface be located at a mesh point, one grid space from the previous interface location.Results of two sample calculations show that the present method is superior to the conventional finite-difference method both in its accuracy and computational efficiency. The formulation is mathematically simple and can be applied with no difficulty to problems with nonplanar geometry and initial subcooling. The present method is applied to the analysis of the melting of a finite slab subjected to a constant heat flux boundary condition. Some interesting effects of initial subcooling on the physics of melting are illustrated and discussed.
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    AIChE Journal 26 (1980), S. 850-852 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 26 (1980), S. 869-872 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Goodman's integral heat and mass balance method is applied to the problem of a moving boundary in a spherical particle. The moving boundary was fixed by a suitable transformation for ease in solution. The mean value theorem was used to treat the nonlinearities when they occurred. Relations for the heat and mass boundary positions are obtained for the most general conditions. These expressions reduce in their limiting cases to known results.
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    AIChE Journal 26 (1980), S. 876-876 
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    Keywords: Chemistry ; Chemical Engineering
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  • 51
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    AIChE Journal 26 (1980), S. 876-876 
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    AIChE Journal 26 (1980), S. 891-901 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Multistage permeation cascades have been designed for the removal of radioactive krypton and xenon from nuclear reactor atmospheres. These cascades could serve for the decontamination of the atmosphere within a reactor containment dome following a nuclear accident and for other applications of interest to the nuclear industry. The stages of the cascades are assumed to consist of permeator modules using silicone rubber capillaries as separation membranes. All stages are to be operated in a countercurrent mode with shell-side feed.It is shown that it is possible to design an ideal cascade for the separation of multicomponent mixtures by matching the concentrations of a suitable key component in interstage streams that are mixed. This procedure minimizes the cascade volume and power requirement. It is also possible to design a cascade with constant stage cuts in its enriching and stripping sections that approximates the performance of an ideal cascade. The krypton and xenon content of a feed mixture containing about 1 × 10-3 mol% Kr and 1 × 10-2 mol% Xe in air can be lowered by factors of 103 and 108 respectively in a 27-stage permeation cascade. Methods of reducing the number of stages and the effects of irradiation on the membrane performance are also discussed.
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    AIChE Journal 26 (1980), S. 881-890 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The objective of this investigation was to study the separation of krypton and xenon from nuclear reactor atmospheres by selective permeation through silicone rubber capillaries. Effective permeability coefficients for pure krypton xenon, nitrogen, and oxygen were determined between 0 and 40°C and at pressure differences across the capillary walls (Δp) of up to 3.45 × 105 N/m2 (50 psi). The silicone rubber capillaries had an O.D. of 635 μm (0.025 in.) and an I.D. of 305 μm (0.012 in.), and were pressurized externally. The effective permeability coefficients decreased with increasing Δp, due to the elastic deformation of the capillaries, in general agreement with a deformation analysis of thick-walled elastic tubes.Gas separation studies were made with a Kr-Xe-N2-O2 mixture in a permeator containing a bundle of silicone rubber capillaries. The permeator had an effective permeation area of 0.480 m2 (5.165 ft2) at a packing density of 4132 m2m3 permeator volume (1260 ft2/ft3), and was operated in a countercurrent mode. The separation studies were conducted at -10 and 20°C and at three Δp values. The separation achieved in the permeator at Δp's of 1.38 × 105 N/m2 (20 Ib/in.2) and 2.07 × 105 N/m2 (30 Ib/in.2) was in good agreement with that predicted from a theoretical model of a permeation stage with countercurrent flow. At 3.45 × 105 N/m2 (50 Ib/in.2), the separation approached that predicted from a “perfect mixing” model. This behavior probably was due to local collapses of the capillaries at weak spots in their walls, as was evidenced also by a sharp increase in the axial pressure drop inside the capillaries.
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    AIChE Journal 26 (1980), S. 916-928 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Due to rising energy costs, there is an increasing need to include the goal of energy conservation as an integral part of process synthesis. This paper discusses the problem of finding the optimum sequence of distillation columns for separating a multicomponent mixture, when heat exchange is permitted between the columns. The major difficulties are associated with the nonserial nature of the problem, the large combinatorial variety and the size of the optimization task. The synthesis strategy presented here overcomes these problems by the use of a bounding technique together with the Lagrangian theory from nonlinear programming. Accurate lower bounds on the optimal costs permit the elimination of nonoptimal sequences with minimal computational effort.
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    Notes: Numerical bifurcation techniques are used to predict multiple steady states for a nonadiabatic, premixed hydrogen flame stabilized on a flat-flame burner. It is found that predicted conditions for burnout and ignition vary remarkably as rival chemical niodels are selected, while conditions for a well-stabilized flame are much less sensitive to chemical and kinetic assumptions. It is concluded that multiplicity theory can help define the chemical behavior of realistic, complex reaction-diffusion systems.
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    Notes: An experimental investigation of an impinging water jet freezing on a melting solid surface has been carried out. Attention was focused on the stagnation region of an axisymmetric jet. In the experiment, a water jet was directed upward against the lower end of a meltable rod, having a diameter about twice that of the jet orifice. Solid octane (m.p. - 56.5°C) and solid mercury (m.p. - 38.9°C) served as the meltable materials. A laminar-axisymmetric flow model was developed to describe melting heat transfer in the presence of jet solidification within the impingement region. Measurements of the melting rate and conditions for the onset of jet solidification were found to agree quite well with the values predicted with this model.
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    AIChE Journal 26 (1980), S. 779-787 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: An analytical solution is obtained to the extended Graetz problem with prescribed wall flux, based on a selfadjoint formalism resulting from a decomposition of the convective diffusion equation into a pair of first-order partial differential equations. The solution obtained is simple, computationally efficient and in striking contrast with incomplete numerical efforts in the past.
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    AIChE Journal 26 (1980), S. 802-816 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Structural relationships between the numbers of the various types of steady states exhibited by a mixed culture of microorganisms growing in a chemostat have been obtained. The analysis is based on the degree theory and utilizes Hopf's index theorem. Useful information concerning the culture growth and general conclusions pertaining to the nature of the possible steady states are obtained from these relationships. An alternate method of stability analysis, based on the above results, has also been developed and applications to several cases of growth of indirectly interacting populations which demonstrate the efficiency of the method are presented.
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    AIChE Journal 26 (1980), S. 832-839 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: For gas absorption accompanied by two consecutive second-order reactions, the reaction factors of the film and penetration theories were solved by the orthogonal collocation method. For equivalent definition of the other physico-chemical parameters, the reaction factors from the two theories differ only slightly. In film theory, it is shown that the film-bulk boundary condition is of importance only for small values of M. It is also shown that the difference between the point yields of the film and penetration theories is generally small, although it is larger than the difference in reaction factors for the two theories.
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    AIChE Journal 26 (1980), S. 858-862 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 26 (1980), S. 865-868 
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    Notes: Diametrically different influences of small moisture contents upon strength are often measured in beds of different kinds of particles. Here we explain such opposing trends in terms of capillary forces exerted by condensed liquid rings at the points of particle contact. The effects of such rings are opposite for different particle shapes at the point of contact, namely, at spherical or at sharp angular contact points. In addition to the theoretical development, data are given for two different illustrative types of particles.
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    AIChE Journal 26 (1980), S. 876-876 
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    AIChE Journal 26 (1980), S. 876-879 
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    AIChE Journal 26 (1980) 
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    AIChE Journal 26 (1980), S. 910-916 
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    Notes: A number of approaches to the optimal selection of sensor locations are presented, and some of these are applied to determine optimal thermocouple positions in a packed bed tubular reactor. As expected, the optimal locations were found to be those surrounding the hot spot location. The theory also revealed that for good state estimation and for goodlinear quadratic control of the reactor, only one or two well located temperature measurements are necessary rather than the entire temperature profile.
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    AIChE Journal 26 (1980), S. 935-943 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A detailed mathematical model of a single catalyst pellet has been developed to describe its behavior under transient conditions encountered during the warmup period of automobile exhaust catalytic converters. In contrast to the converter models previously reported in the literature, this model is capable of describing the time-dependent behavior of a composite catalyst pellet, and thus provides a convenient means of examining the effects of poison penetration and various noble metal impregnation strategies in the activity-time (rather than activity-temperature) domain.Extensive calculations were carried out to investigate the effects of various catalyst design parameters and converter operating conditions on the lightoff behavior of a spherical, platinum-alumina catalyst pellet. Due to the complex kinetics of the CO and hydrocarbon oxidation reactions, catalyst lightoff was found to exhibit interesting behavior with respect to variations of the system's design parameters and operating conditions. Graphs are presented to illustrate the parameteric sensitivity of these effects.
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    AIChE Journal 26 (1980), S. 954-964 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: We have obtained values for interaction second viral coefficients of the helium-carbon dioxide system in the range 230 ≤ T/K ≤ 300. Our experimental technique is essentially the Burnett mixing method described by Hall and Eubank (1973, 1974). We have modified the analysis to account for higher-order effects and to detect significant systematic errors. We also report virial coefficients for the pure components: helium in the range 100 ≤ T/K ≤ 300 and carbon dioxide at 300 K.
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    Notes: The design of the steady-state optimizing control for a single unit is formulated within the framework of the nonlinear mathematical programming theory. Alternative implementational strategies are developed and a multilevel screening procedure is proposed to arrive at the best optimizing control configuration. Numerical examples on a fluid catalytic cracking unit and a distillation column demonstrate the systematic design and the synthesis of the most promising optimizing control structures for these systems.
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    AIChE Journal 26 (1980), S. 1013-1019 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A time lag method is described for use with a membrane-covered, rotated disc electrode that allows determination of the partitioning and diffusivity of small molecules in hydrophilic gel membranes and membrane permeability from a single measurement. This new technique takes into account the concentration boundary layer in the solution adjacent to the membrane and reaction at the electrode surface of solutes that are diffusion- or kinetic-limited. Examples are given of the use of this method for characterizing mass transfer in a commercial cellulosic membrane with oxygen, hydroquinone, ferrocyanide, and glucose as solutes.
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    AIChE Journal 28 (1982), S. 1-6 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experiments on the separation of hydrogen isotopes were conducted using vanadium hydride in a temperature swing process. Process behavior followed trends predicted by an equilibrium theory of process operation, but was modified by a kinetic isotope effect and by finite rates of hydrogen absorption and isotope exchange.
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    AIChE Journal 28 (1982), S. 20-30 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The statistical behavior of some common parameter estimation methods is investigated by simulation. The methods based on the maximum likelihood principle give the best estimates of parameters in a given model. An analysis of the possibilities for detecting systematic errors by means of the maximum likelihood method showed that this method gives at best the same information as other well known tests.
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    AIChE Journal 28 (1982), S. 49-55 
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An approximate method is developed for the simulation of three-phase, multistaged multicomponent separators in which one of the two liquid phases can be regarded as being constituted of almost one component only.Comparisons with the complete three-phase model shows a large reduction of the required computation time and a satisfactory agreement of the obtained results.
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    Notes: A new process for purification of phenolic wastewaters by parametric pumping is presented.An equilibrium (linear) model for nonmixed dead volumes thermal direct mode parametric pumping is developed and the influence of bottom and top dead volume magnitudes on transient separation is analyzed.Analytical solutions for batch, continuous and semicontinuous operations are presented.Experimental data on the system phenol/water-Duolite ES861 include equilibrium isotherms at 20°C and 60°C and parapump runs for the cases mentioned above.
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    AIChE Journal 28 (1982), S. 103-111 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: A high-temperature molten carbonate electrochemical cell has been tested for use as a carbon dioxide concentrator in a manned spacecraft. Carbon dioxide is removed from a stream of cabin air supplied to the cathode of the bench scale cell. It is then concentrated through the molten carbonate electrolyte to the anode. The anode is fed either hydrogen (energy producer) or nitrogen (substance producer). Performance variation with gas flow rate, cell temperature, carbon dioxide partial pressure, and current are presented and analyzed.
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    Notes: P-V-T-x data for the propane-perfluorocyclobutane system are reported in this paper. The data cover a temperature range from 329.4 to 397.7°K and a pressure range from 60 to 6920 kPa. The low pressure compressibility measurements were used to determine second virial coefficients of pure propane and pure perfluorocyclobutane and for seven of their mixtures. The prediction of second virial coefficients using an extended corresponding states principle is also reported. Excellent predictions of the second virial coefficients of both pure components and mixtures have been obtained using, in the case of mixtures, a binary interaction coefficient obtained from a study of the critical states of the system.
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    AIChE Journal 28 (1982), S. 208-214 
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model for packed-bed reactors with dispersion is derived rigorously via the volume averaging approach. Though it is quantitatively more consistent with experimental data, it requires less computational efforts than the prevalent Fickian model. The adverse effects of dispersion on conversion are demonstrated both numerically and analytically using the new model.
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    AIChE Journal 28 (1982), S. 173-173 
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    AIChE Journal 28 (1982), S. 174-174 
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    AIChE Journal 28 (1982), S. 182-190 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An analysis is presented to described the dynamics of fluidized bed adsorption columns. A microbial film model (recently proposed by the authors) is used to characterize the bacterial activity and its interaction with adsorption and solids mixing. Solids mixing and mixing in the liquid phase are included in the analysis, as is the effect of microbial film growth on the settling velocity of the adsorbent particles. The interplay of film growth, bed stratification and solids mixing is discussed in detail.
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    AIChE Journal 28 (1982), S. 11-20 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A fast and accurate method was developed for the integration of large sparse systems of stiff initial value ordinary differential equations. The system is ordered, decoupled and, if necessary, torn into subsystems (also called blocks) which are then solved by orthogonal collocation on finite elements. The size of these elements, or steps, is different for each subsystem and is a function of the stiffness of the set of equations constituting the subsystem. The steps are overlapped for maximum computational efficiency.
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    AIChE Journal 28 (1982), S. 39-49 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical model for simulating particulate removal in gas-solid fluidized beds is developed based on bubble assemblage concepts and particulate collection mechanisms. The importance of fluidization mechanics on the overall fluidized bed filtration performance is emphasized in the present study. Model predictions of fluidized bed filtration efficiencies are shown to compare favorably to the experimental results of various investigations. Because of the general formulation of the proposed model, it is believed to be applicable in the design of fluidized bed filtration operations.
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    AIChE Journal 28 (1982), S. 392-396 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The results of batch settling tests with various coal powders in model oils indicated that the viscosity and the aromatic/paraffinic nature of the oil influences the sedimentation and the aggregation rate of the particles. Oxidation of paraffin oil may result in the generation of surface active agents which retards the sedimentation of certain coals.
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    AIChE Journal 28 (1982), S. 405-410 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A general expression for the time-dependence of the activity of a catalyst pellet affected by both chemical deactivation and diffusion is developed. Specific results are given for both uniform and pore-mouth poisoning, with parallel and series poisoning mechanisms. Comparisons show a satisfactory agreement between theoretical and experimental results. A pellet effectiveness representing the combined effect of deactivation and diffusion is also developed in a form suitable for direct inclusion in reactor conservation equations.
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    AIChE Journal 28 (1982), S. 117-128 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model describing the entrainment of solid particles in the freeboard region of a fluidized bed is proposed. Published experimental data have been used to correlate the entrainment rate near the bed surface and the elutriation rate above the bed. It has been shown that the column diameter can have an important influence on the amount of fines elutriated.
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    AIChE Journal 28 (1982), S. 134-138 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The volumetric and phase behavior of propane-perfluorocyclobutane mixtures has been determined in the critical region. This system exhibits a minimum temperature point in its critical locus curve and forms a positive critical azeotrope. The measured critical points in this system and their correlation using an extended corresponding states principle are reported in this paper.
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    AIChE Journal 28 (1982), S. 147-156 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: When a small drop or bubble approaches a solid surface, a thin liquid film forms between them, drains, until an instability forms and coalescence occurs. A hydrodynamic theory is developed for the first portion of this coalescence process: the drainage of the thin liquid film while it is still sufficiently thick that the effects of London-van der Waals forces and electrostatic forces can be ignored. This theory describes the time rate of change of the film profile, given only the drop radius and the required physical properties. Predictions are compared with profiles measured by Platikanov (1964) for gas bubbles. It is concluded that, even with only a trace of surfactant present, the liquid-gas interface may be nearly immobile (tangential components of velocity are zero) and the surface viscosities will have little effect upon the drainage rate.
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    AIChE Journal 28 (1982), S. 173-173 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 28 (1982), S. 175-175 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 28 (1982), S. 177-182 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model is presented in which damaged pores are distributed throughout a network of undamaged pores within a spherical particle. The differential equations are solved according to the numerical procedure of Haynes, Jr. (1975). The model is intended to simulate more highly skewed chromatographic response curves than the two-zone model recently proposed by Chou and Hegedus (1978).Pulse chromatographic measurements in fresh NaMgA zeolites using i-butane as a tracer which only enters the macropores yield response curves with relatively low skew, which are readily fitted by a system of equations accounting for diffusion in a monodisperse pore system. For hydrothermally treated zeolites effective diffusivities and Henry constants are considerably lower and the skew higher than in fresh samples.Curve fitting with the model proposed below is quite satisfactory, and the characteristic parameters determined are approximately constant at the flowrates studied. Application of the model should not be restricted to hydrothermally treated zeolites, but may be extended to catalysts or adsorbents with macroporous structures damaged by other forms of ageing.
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    AIChE Journal 28 (1982), S. 547-557 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Aqueous solutions of drag-reducing polymers were injected into turbulent water flow in a pipe. The injection point was situated where the flow was well-developed. Thus, subsequent steamwise variations in pressure drop were due to the injected polymer spreading out across the pipe. The axial development of local drag reduction was monitored by a series of closely-spaced pressure tappings. The corresponding radial dispersion of the injected polymer, as it travelled downstream, was assessed by sampling the flow at various points.Local drag reduction, due to either point injection at the centerline or injection through a slot in the wall, was found to increase with distance downstream. This increase was related to the streamline increase of polymer concentration in a narrow annulus near the pipe wall. It was tentatively concluded that the effective annulus was bounded by 15 ≤ y + ≤ 100, in agreement with previous deductions from less direct evidence.
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    AIChE Journal 28 (1982), S. 573-580 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Concentrations of NO, NH3, and HCN, together with coal particle burnout and gas composition, were measured during combustion of a bituminous coal. Control of incoming secondary gas swirl level and overall stoichiometric ratio led to significant reductions in nitrogen oxide pollutant concentration. In-situ measurements showed that coal particles were confined near the reactor center during rapid particle reaction. This took place in a locally fuel-rich environment, producing near-quantitative conversion of fuel-nitrogen to NH3 and HCN, with some NO. Subsequent gas phase reactions of these nitrogen species were identified as important in establishing the ultimate NO concentration.
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    AIChE Journal 28 (1982), S. 597-603 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: High-quality (95%) steam-water critical flow through a straight pipe was studied using high-speed photographic and holographic techniques. The results indicate that most of the water exists as a discontinuous or continuous thin film which flows along the wall with a speed much slower than that of the steam. This results in slip ratios higher than those reported before. Although a separated flow model would seem to describe the actual flow situation more closely than other models, the assumption of thermal equilibrium between phases and the fact that the flow is not separated except close to the exit plane are probably explanations for differences in slip ratios obtained in this study from those predicted.
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    AIChE Journal 28 (1982), S. 279-285 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A revised version of a recently proposed free-volume theory of polymer-solvent diffusion is introduced and evaluated using experimental diffusivity data collected over wide temperature and concentration ranges. The theory accurately predicts the large temperature and concentration variations typically observed for polymer-solvent diffusion coefficients.
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    AIChE Journal 28 (1982), S. 302-311 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical model of nitric oxide (NO) formation during pulverized coal combustion was developed from a proposed kinetic mechanism involving 12 overall chemical reactions. Most significantly, the model describes the complex conversion of coal bound nitrogen compounds to NO during combustion. The predictions of the model compare favorably with literature data obtained in well defined laboratory combustors firing gaseous fuels doped with organic nitrogen additives, as well as with data obtained in laboratory coal combustors. The predictions of the model are in qualitative agreement with trends observed in practical coal combustors.
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    AIChE Journal 28 (1982), S. 333-338 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Aqueous solutions of p-nitrobenzoic acid were hydrogenated in the presence of Pt/C and Pd/C catalysts in a slurry reactor. External as well as internal mass transport steps were studied using a membrane H2-electrode and a metal probe electrode. After the influence of the mass transport effects was corrected for, it was possible to obtain corrected values of the kinetic characteristics of the overall chemical reaction. The mechanism was studied using potential and polarization methods.
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    AIChE Journal 28 (1982), S. 344-346 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 28 (1982), S. 349-349 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    AIChE Journal 28 (1982), S. 700-702 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 28 (1982), S. 703-703 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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