ALBERT

Description: Non-technical summary Scenarios compatible with the Paris agreement's temperature goal of 1.5 °C involve carbon dioxide removal measures - measures that actively remove CO2 from the atmosphere - on a massive scale. Such large-scale implementations raise significant ethical problems. Van Vuuren et al. (2018), as well as the current IPCC scenarios, show that reduction in energy and or food demand could reduce the need for such activities. There is some reluctance to discuss such societal changes. However, we argue that policy measures enabling societal changes are not necessarily ethically problematic. Therefore, they should be discussed alongside techno-optimistic approaches in any kind of discussions about how to respond to climate change. Technical summary The 1.5 °C goal has given impetus to carbon dioxide removal (CDR) measures, such as bioenergy combined with carbon capture and storage, or afforestation. However, land-based CDR options compete with food production and biodiversity protection. Van Vuuren et al. (2018) looked at alternative pathways including lifestyle changes, low-population projections, or non-CO2 greenhouse gas mitigation, to reach the 1.5 °C temperature objective. Underlined by the recently published IPCC AR6 WGIII report, they show that demand-side management measures are likely to reduce the need for CDR. Yet, policy measures entailed in these scenarios could be associated with ethical problems themselves. In this paper, we therefore investigate ethical implications of four alternative pathways as proposed by Van Vuuren et al. (2018). We find that emission reduction options such as lifestyle changes and reducing population, which are typically perceived as ethically problematic, might be less so on further inspection. In contrast, options associated with less societal transformation and more techno-optimistic approaches turn out to be in need of further scrutiny. The vast majority of emission reduction options considered are not intrinsically ethically problematic; rather everything rests on the precise implementation. Explicitly addressing ethical considerations when developing, advancing, and using integrated assessment scenarios could reignite debates about previously overlooked topics and thereby support necessary societal discourse. Social media summary Policy measures enabling societal changes are not necessarily as ethically problematic as commonly presumed and reduce the need for large-scale CDR

Description: The Falkland Shelf is a highly productive ecosystem in the Southwest Atlantic Ocean. It is characterized by upwelling oceanographic dynamics and displays a wasp-waist structure, with few intermediate trophic-level species and many top predators that migrate on the shelf for feeding. One of these resident intermediate trophic-level species, the Patagonian longfin-squid Doryteuthis gahi, is abundant and plays an important role in the ecosystem. We used two methods to estimate the trophic structure of the Falkland Shelf food web, focusing on the trophic niche of D. gahi and its impacts on other species and functional groups to highlight the importance of D. gahi in the ecosystem. First, stable isotope measurements served to calculate trophic levels based on an established nitrogen baseline. Second, an Ecopath model was built to corroborate trophic levels derived from stable isotopes and inform about trophic interactions of D. gahi with other functional groups. The results of both methods placed D. gahi in the centre of the ecosystem with a trophic level of ∼ 3. The Ecopath model predicted high impacts and therefore a high keystoneness for both seasonal cohorts of D. gahi. Our results show that the Falkland Shelf is not only controlled by species feeding at the top and the bottom of the trophic chain. The importance of species feeding at the third trophic level (e.g. D. gahi and Patagonotothen ramsayi) and observed architecture of energy flows confirm the ecosystem's wasp-waist structure with middle-out control mechanisms at play.

Description: Perturbations in stratospheric aerosol due to explosive volcanic eruptions are a primary contributor to natural climate variability. Observations of stratospheric aerosol are available for the past decades, and information from ice cores has been used to derive estimates of stratospheric sulfur injections and aerosol optical depth over the Holocene (approximately 10 000 BP to present) and into the last glacial period, extending back to 60 000 BP. Tephra records of past volcanism, compared to ice cores, are less complete but extend much further into the past. To support model studies of the potential impacts of explosive volcanism on climate variability across timescales, we present here an ensemble reconstruction of volcanic stratospheric sulfur injection (VSSI) over the last 140 000 years that is based primarily on terrestrial and marine tephra records. VSSI values are computed as a simple function of eruption magnitude based on VSSI estimates from ice cores and satellite observations for identified eruptions. To correct for the incompleteness of the tephra record, we include stochastically generated synthetic eruptions assuming a constant background eruption frequency from the ice core Holocene record. While the reconstruction often differs from ice core estimates for specific eruptions due to uncertainties in the data used and reconstruction method, it shows good agreement with an ice-core-based VSSI reconstruction in terms of millennial-scale cumulative VSSI variations over the Holocene. The PalVol reconstruction provides a new basis to test the contributions of forced vs. unforced natural variability to the spectrum of climate and the mechanisms leading to abrupt transitions in the palaeoclimate record with low- to high-complexity climate models. The PalVol volcanic forcing reconstruction is available at https://doi.org/10.26050/WDCC/PalVolv1 (Toohey and Schindlbeck-Belo, 2023).

Description: Increases in ocean temperatures in the Filchner Ronne region of Antarctica are likely to result in increased ice mass loss and sea level rise. We constrain projections of the 21st century sea level contribution of this region using process-based ice-sheet modeling, with model parameters controlling ice dynamics calibrated using observed surface speeds and Markov-chain Monte Carlo sampling. We use climate forcing from Representative Concentration Pathway (RCP) scenarios as well as a set of hypothetical scenarios of deep ocean warming to evaluate the sensitivity of this region to ocean temperatures. Projected changes in regional ice mass correspond to a decrease in global mean sea level of 24±7 mm over 2015–2100 under RCP 2.6 and 28±9 mm under RCP 8.5. Increased regional inland surface accumulation related to higher warming levels in RCP 8.5 leads to more ice above flotation, offsetting increased ice shelf basal melt. The tests involving step changes in ocean temperatures with constant surface forcing show that one degree of ocean warming from present results in an additional +11 mm contribution to sea level by 2100 and 1% of the ice-covered area in the domain becomes ungrounded (23 200 km2). The rate of mass loss with temperature increases at higher temperatures.

Description: Radiocarbon (14C) concentrations in the oceans are different from those in the atmosphere. Understanding these ocean-atmospheric 14C differences is important both to estimate the calendar ages of samples which obtained their 14C in the marine environment, and to investigate the carbon cycle. The Marine20 radiocarbon age calibration curve is created to address these dual aims by providing a global-scale surface ocean record of radiocarbon from 55,000–0 cal yr BP that accounts for the smoothed response of the ocean to variations in atmospheric 14C production rates and factors out the effect of known changes in global-scale palaeoclimatic variables. The curve also serves as a baseline to study regional oceanic 14C variation. Marine20 offers substantial improvements over the previous Marine13 curve. In response to community questions, we provide a short intuitive guide, intended for the lay-reader, on the construction and use of the Marine20 calibration curve. We describe the choices behind the making of Marine20, as well as the similarities and differences compared with the earlier Marine calibration curves. We also describe how to use the Marine20 curve for calibration and how to estimate ΔR—the localized variation in the oceanic 14C levels due to regional factors which are not incorporated in the global-scale Marine20 curve. To aid understanding, illustrative worked examples are provided.

Description: The Marine20 radiocarbon (14C) age calibration curve, and all earlier marine 14C calibration curves from the IntCal group, must be used extremely cautiously for the calibration of marine 14C samples from polar regions (outside ∼ 40ºS–40ºN) during glacial periods. Calibrating polar 14C marine samples from glacial periods against any Marine calibration curve (Marine20 or any earlier product) using an estimate of , the regional 14C depletion adjustment, that has been obtained from samples in the recent (non-glacial) past is likely to lead to bias and overconfidence in the calibrated age. We propose an approach to calibration that aims to address this by accounting for the possibility of additional, localized, glacial 14C depletion in polar oceans. We suggest, for a specific polar location, bounds on the value of during a glacial period. The lower bound may be based on 14C samples from the recent non-glacial (Holocene) past and corresponds to a low-depletion glacial scenario. The upper bound, , representing a high-depletion scenario is found by increasing according to the latitude of the 14C sample to be calibrated. The suggested increases to obtain are based upon simulations of the Hamburg Large Scale Geostrophic Ocean General Circulation Model (LSG OGCM). Calibrating against the Marine20 curve using the upper and lower bounds provide estimates of calibrated ages for glacial 14C samples in high- and low-depletion scenarios which should bracket the true calendar age of the sample. In some circumstances, users may be able to determine which depletion scenario is more appropriate using independent paleoclimatic or proxy evidence.

Description: Spatially variable basal conditions are thought to govern how ice sheets behave at glacial time scales (〉1000 years) and responsible for changes in dynamics between the core and peripheral regions of the Laurentide and Fennoscandian ice sheets. Basal motion is accomplished via the deformation of unconsolidated sediments, or via sliding of the ice over an undeformable bed. We present an ice sheet sliding module for the Parallel Ice Sheet Model (PISM) that takes into account changes in sediment cover and incorporates surface meltwater. This model routes meltwater, produced at the surface and base of the ice sheet, toward the margin of the ice sheet. Basal sliding is accomplished through the deformation of water saturated sediments, or sliding at the ice-bed interface. In areas with continuous, water saturated sediments, sliding is almost always accomplished through sediment deformation. In areas with incomplete cover, sliding has a stronger dependence on the supply of water. We find that the addition of surface meltwater to the base is a more important factor for ice sheet evolution than the style of sliding. In a glacial cycle simulation, our model causes a more rapid buildup of the Laurentide Ice Sheet.

Description: Although it is generally known that a combination of abiotic and biotic drivers shapes the distribution and abundance of parasites, our understanding of the interplay of these factors remains to be assessed for most marine host species. The present field survey investigated spatial patterns of richness, prevalence and abundance of parasites in Mytilus galloprovincialis along the coast of the northern Adriatic Sea. Herein, the relationships between biotic (host size, density and local parasite richness of mussel population) and abiotic (eutrophication and salinity) drivers and parasite richness of mussel individuals, prevalence and abundance were analysed. Local parasite richness was the most relevant factor driving parasite species richness in mussel individuals. Prevalence was mainly driven by eutrophication levels in 3 out of 4 parasite species analysed. Similarly, abundance was driven mainly by eutrophication in two parasite species. Mussel size, density and salinity had only minor contributions to the best fitting models. This study highlights that the influence of abiotic and biotic drivers on parasite infections in mussels can be differentially conveyed, depending on the infection measure applied, i.e., parasite richness, prevalence or abundance. Furthermore, it stresses the importance of eutrophication as a major factor influencing parasite prevalence and abundance in mussels in the Adriatic Sea

Description: The Global Ocean Data Analysis Project (GLODAP) is a synthesis effort providing regular compilations of surface-to-bottom ocean biogeochemical bottle data, with an emphasis on seawater inorganic carbon chemistry and related variables determined through chemical analysis of seawater samples. GLODAPv2.2022 is an update of the previous version, GLODAPv2.2021 (Lauvset et al., 2021). The major changes are as follows: data from 96 new cruises were added, data coverage was extended until 2021, and for the first time we performed secondary quality control on all sulphur hexafluoride (SF6) data. In addition, a number of changes were made to data included in GLODAPv2.2021. These changes affect specifically the SF6 data, which are now subjected to secondary quality control, and carbon data measured onboard the RV Knorr in the Indian Ocean in 1994–1995 which are now adjusted using CRM measurements made at the time. GLODAPv2.2022 includes measurements from almost 1.4 million water samples from the global oceans collected on 1085 cruises. The data for the now 13 GLODAP core variables (salinity, oxygen, nitrate, silicate, phosphate, dissolved inorganic carbon, total alkalinity, pH, CFC-11, CFC-12, CFC-113, CCl4, and SF6) have undergone extensive quality control with a focus on systematic evaluation of bias. The data are available in two formats: (i) as submitted by the data originator but converted to World Ocean Circulation Experiment (WOCE) exchange format and (ii) as a merged data product with adjustments applied to minimize bias. For the present annual update, adjustments for the 96 new cruises were derived by comparing those data with the data from the 989 quality controlled cruises in the GLODAPv2.2021 data product using crossover analysis. SF6 data from all cruises were evaluated by comparison with CFC-12 data measured on the same cruises. For nutrients and ocean carbon dioxide (CO2) chemistry comparisons to estimates based on empirical algorithms provided additional context for adjustment decisions. The adjustments that we applied are intended to remove potential biases from errors related to measurement, calibration, and data handling practices without removing known or likely time trends or variations in the variables evaluated. The compiled and adjusted data product is believed to be consistent to better than 0.005 in salinity, 1 % in oxygen, 2 % in nitrate, 2 % in silicate, 2 % in phosphate, 4 μmol kg-1 in dissolved inorganic carbon, 4 μmol kg-1 in total alkalinity, 0.01–0.02 in pH (depending on region), and 5 % in the halogenated transient tracers. The other variables included in the compilation, such as isotopic tracers and discrete CO2 fugacity (fCO2), were not subjected to bias comparison or adjustments.

Description: The last 85,000 years were characterized by high climate and environmental variability on the Yucatán Peninsula. Heinrich stadials are examples of abrupt climate transitions that involved shifts in regional temperatures and moisture availability. Thus, they serve as natural experiments to evaluate the contrasting responses of aquatic and terrestrial ecosystems. We used ostracodes and pollen preserved in a 75.9-m-long sediment core (PI-6, ~85 ka) recovered from Lake Petén Itzá, Guatemala, to assess the magnitude and velocity of community responses. Ostracodes are sensitive to changes in water temperature and conductivity. Vegetation responds to shifts in temperature and the ratio of evaporation to precipitation. Ostracodes display larger and more rapid community changes than does vegetation. Heinrich Stadial 5-1 (HS5-1) was cold and dry and is associated with lower ostracode and vegetation species richness and diversity. In contrast, the slightly warmer and dry conditions during HS6 and HS5a are reflected in higher ostracode species richness and diversity. Our paleoecological study revealed the greatest ecological turnover for ostracodes occurred from 62.5 to 51.0 ka; for pollen, it was at the Pleistocene/Holocene transition. Future studies should use various climate and environmental indicators from lake and marine sediment records to further explore late glacial paleoclimate causes and effects in the northern neotropics.

Description: Trematode prevalence and abundance in hosts are known to be affected by biotic drivers as well as by abiotic drivers. In this study, we used the unique salinity gradient found in the south-western Baltic Sea to: (i) investigate patterns of trematode infections in the first intermediate host, the periwinkle Littorina littorea and in the downstream host, the mussel Mytilus edulis, along a regional salinity gradient (from 13 to 22) and (ii) evaluate the effects of first intermediate host (periwinkle) density, host size and salinity on trematode infections in mussels. Two species dominated the trematode community, Renicola roscovita and Himasthla elongata. Salinity, mussel size and density of infected periwinkles were significantly correlated with R. roscovita, and salinity and density correlated with H. elongata abundance. These results suggest that salinity, first intermediate host density and host size play an important role in determining infection levels in mussels, with salinity being the main major driver. Under expected global change scenarios, the predicted freshening of the Baltic Sea might lead to reduced trematode transmission, which may be further enhanced by a potential decrease in periwinkle density and mussel size.

Description: Radiocarbon (14C) ages cannot provide absolutely dated chronologies for archaeological or paleoenvironmental studies directly but must be converted to calendar age equivalents using a calibration curve compensating for fluctuations in atmospheric 14C concentration. Although calibration curves are constructed from independently dated archives, they invariably require revision as new data become available and our understanding of the Earth system improves. In this volume the international 14C calibration curves for both the Northern and Southern Hemispheres, as well as for the ocean surface layer, have been updated to include a wealth of new data and extended to 55,000 cal BP. Based on tree rings, IntCal20 now extends as a fully atmospheric record to ca. 13,900 cal BP. For the older part of the timescale, IntCal20 comprises statistically integrated evidence from floating tree-ring chronologies, lacustrine and marine sediments, speleothems, and corals. We utilized improved evaluation of the timescales and location variable 14C offsets from the atmosphere (reservoir age, dead carbon fraction) for each dataset. New statistical methods have refined the structure of the calibration curves while maintaining a robust treatment of uncertainties in the 14C ages, the calendar ages and other corrections. The inclusion of modeled marine reservoir ages derived from a three-dimensional ocean circulation model has allowed us to apply more appropriate reservoir corrections to the marine 14C data rather than the previous use of constant regional offsets from the atmosphere. Here we provide an overview of the new and revised datasets and the associated methods used for the construction of the IntCal20 curve and explore potential regional offsets for tree-ring data. We discuss the main differences with respect to the previous calibration curve, IntCal13, and some of the implications for archaeology and geosciences ranging from the recent past to the time of the extinction of the Neanderthals.

Description: The concentration of radiocarbon (14C) differs between ocean and atmosphere. Radiocarbon determinations from samples which obtained their 14C in the marine environment therefore need a marine-specific calibration curve and cannot be calibrated directly against the atmospheric-based IntCal20 curve. This paper presents Marine20, an update to the internationally agreed marine radiocarbon age calibration curve that provides a non-polar global-average marine record of radiocarbon from 0–55 cal kBP and serves as a baseline for regional oceanic variation. Marine20 is intended for calibration of marine radiocarbon samples from non-polar regions; it is not suitable for calibration in polar regions where variability in sea ice extent, ocean upwelling and air-sea gas exchange may have caused larger changes to concentrations of marine radiocarbon. The Marine20 curve is based upon 500 simulations with an ocean/atmosphere/biosphere box-model of the global carbon cycle that has been forced by posterior realizations of our Northern Hemispheric atmospheric IntCal20 14C curve and reconstructed changes in CO2 obtained from ice core data. These forcings enable us to incorporate carbon cycle dynamics and temporal changes in the atmospheric 14C level. The box-model simulations of the global-average marine radiocarbon reservoir age are similar to those of a more complex three-dimensional ocean general circulation model. However, simplicity and speed of the box model allow us to use a Monte Carlo approach to rigorously propagate the uncertainty in both the historic concentration of atmospheric 14C and other key parameters of the carbon cycle through to our final Marine20 calibration curve. This robust propagation of uncertainty is fundamental to providing reliable precision for the radiocarbon age calibration of marine based samples. We make a first step towards deconvolving the contributions of different processes to the total uncertainty; discuss the main differences of Marine20 from the previous age calibration curve Marine13; and identify the limitations of our approach together with key areas for further work. The updated values for ΔR, the regional marine radiocarbon reservoir age corrections required to calibrate against Marine20, can be found at the data base http://calib.org/marine/.

Description: In this Open Access book, Sander van der Leeuw examines how the modern world has been caught in a socioeconomic dynamic that has generated the conundrum of sustainability. Combining the methods of social science and complex systems science, he explores how western, developed nations have globalized their world view and how that view has led to the sustainability challenges we are now facing. Its central theme is the coevolution of cognition, demography, social organization, technology, and environmental impact. Beginning with the earliest human societies, van der Leeuw links the distant past with the present in order to demonstrate how the information and communications technology revolution is undermining many of the institutional pillars on which contemporary societies have been constructed. An original view of social evolution as the history of human information-processing, his book shows how the past offers insight into the present and can help us deal with the future.

Description: A new carbon isotope record for two high-latitude sedimentary successions that span the Jurassic–Cretaceous boundary interval in the Sverdrup Basin of Arctic Canada is presented. This study, combined with other published Arctic data, shows a large negative isotopic excursion of organic carbon (δ13Corg) of 4‰ (V-PDB) and to a minimum of −30.7‰ in the probable middle Volgian Stage. This is followed by a return to less negative values of c. −27‰. A smaller positive excursion in the Valanginian Stage of c. 2‰, reaching maximum values of −24.6‰, is related to the Weissert Event. The Volgian isotopic trends are consistent with other high-latitude records but do not appear in δ13Ccarb records of Tethyan Tithonian strata. In the absence of any obvious definitive cause for the depleted δ13Corg anomaly, we suggest several possible contributing factors. The Sverdrup Basin and other Arctic areas may have experienced compositional evolution away from open-marine δ13C values during the Volgian Age due to low global or large-scale regional sea levels, and later become effectively coupled to global oceans by Valanginian time when sea level rose. A geologically sudden increase in volcanism may have caused the large negative δ13Corg values seen in the Arctic Volgian records but the lack of precise geochronological age control for the Jurassic–Cretaceous boundary precludes direct comparison with potentially coincident events, such as the Shatsky Rise. This study offers improved correlation constraints and a refined C-isotope curve for the Boreal region throughout latest Jurassic and earliest Cretaceous time.

Description: Heinrich events are among the dominant modes of glacial climate variability. During these events, massive iceberg armadas were released by the Laurentide Ice Sheet, sailed across the Atlantic, and caused large-scale climate changes. We study these events in a fully coupled complex ice sheet–climate model with synchronous coupling between ice sheets and oceans. The ice discharges occur as internal variability of the model with a recurrence period of 5kyr, an event duration of 1–1.5kyr, and a peak discharge rate of about 50mSv, roughly consistent with reconstructions. The climate response shows a two-stage behavior, with freshwater release effects dominating the surge phase and ice-sheet elevation effects dominating in the post-surge phase. As a direct response to the freshwater discharge during the surge phase, the deepwater formation in the North Atlantic decreases and the North Atlantic deepwater cell weakens by 3.5Sv. With the reduced oceanic heat transport, the surface temperatures across the North Atlantic decrease, and the associated reduction in evaporation causes a drying in Europe. The ice discharge lowers the surface elevation in the Hudson Bay area and thus leads to increased precipitation and accelerated ice sheet regrowth in the post-surge phase. Furthermore, the jet stream widens to the north and becomes more zonal. This contributes to a weakening of the subpolar gyre, and a continued cooling over Europe even after the ice discharge. This two-stage behavior can explain previously contradicting model results and understandings of Heinrich Events.

Description: In this study, we propose a statistical method to validate sea-level reconstructions using geological records known as sea-level indicators (SLIs). SLIs are often the only available data to retrace late-glacial relative sea level (RSL). Determining the RSL from SLI height is not straight forward, the elevation at which an SLI was found usually does not represent the past RSL. In contrast, it has to be related to past RSL by investigating sample’s type, habitat and deposition conditions. For instance, water distribution at which a specific specimen is found today can be related to the indicator's depositional height range. Furthermore, the precision of dating varies between geological samples, and, in case of radiocarbon dating, the age has to be calibrated using a non-linear calibration curve. To avoid an a-priori assumption like normal-distributed uncertainties, we define likelihood functions which take into account the indicative meaning’s available error information and calibration statistics represented by joint probabilities. For this conceptional study, we restrict ourselves to one type of indicators, shallow-water shells, which are usually considered as low-grade samples giving only a lower limit of former sea level, as the depth range in which they live spreads over several tens of meters, and does not follow a normal distribution. The presented method is aimed to serve as a strategy for glacial isostatic adjustment reconstructions, in this case for the German Paleo-Climate Modelling Initiative PalMod (https://www.palmod.de/en) and by extending it to other SLI types.

Description: Dynamic vegetation models simulate global vegetation in terms of fractional coverages of a few plant functional types (PFTs). Although these models often share the same concept, they differ with respect to the number and kind of PFTs, complicating the comparability of simulated vegetation distributions. Pollen-based reconstructions are initially only available in form of time-series of individual taxa that are not distinguished in the models. Thus, to evaluate simulated vegetation distributions, the modelling results and pollen-based reconstructions have to be converted into a comparable format. The classical approach is the method of biomisation, but hitherto, PFT-based biomisation methods were only available for individual models. We introduce and evaluate a simple, universally applicable technique to harmonize PFT-distributions by assigning them into nine mega-biomes that follow the definitions commonly used for vegetation reconstructions. The method works well for all state-of the art dynamic vegetation models, independent of the spatial resolution or the complexity of the models. Large biome belts (such as tropical forest) are well represented, but regionally confined biomes (warm-mixed forest, Savanna) are only partly captured. Overall, the PFT-based biomisation is able to keep up with the conventional biomisation approach of forcing biome models (here: BIOME1) with the background climate states. The new method has, however, the advantage that it allows a more direct comparison and evaluation of the vegetation distributions simulated by Earth System Models. Thereby, the new method provides a powerful tool for the evaluation of Earth System Models in general.

Description: We have developed a new module to calculate soil organic carbon (SOC) accumulation in perennially frozen ground in the land surface model JSBACH. Running this offline version of MPI-ESM we have modelled permafrost carbon accumulation and release from the Last Glacial Maximum (LGM) to the Pre-industrial (PI). Our simulated near-surface PI permafrost extent of 16.9Miokm2 is close to observational evidence. Glacial boundary conditions, especially ice sheet coverage, result in profoundly different spatial patterns of glacial permafrost extent. Deglacial warming leads to large-scale changes in soil temperatures, manifested in permafrost disappearance in southerly regions, and permafrost aggregation in formerly glaciated grid cells. In contrast to the large spatial shift in simulated permafrost occurrence, we infer an only moderate increase of total LGM permafrost area (18.3Miokm2) – together with pronounced changes in the depth of seasonal thaw. Reconstructions suggest a larger spread of glacial permafrost towards more southerly regions, but with a highly uncertain extent of non-continuous permafrost. Compared to a control simulation without describing the transport of SOC into perennially frozen ground, the implementation of our newly developed module for simulating permafrost SOC accumulation leads to a doubling of simulated LGM permafrost SOC storage (amounting to a total of ~150PgC). Despite LGM temperatures favouring a larger permafrost extent, simulated cold glacial temperatures – together with low precipitation and low CO2 levels – limit vegetation productivity and therefore prevent a larger glacial SOC build-up in our model. Changes in physical and biogeochemical boundary conditions during deglacial warming lead to an increase in mineral SOC storage towards the Holocene (168PgC at PI), which is below observational estimates (575PgC in continuous and discontinuous permafrost). Additional model experiments clarified the sensitivity of simulated SOC storage to model parameters, affecting long-term soil carbon respiration rates and simulated active layer depths. Rather than a steady increase in carbon release from the LGM to PI as a consequence of deglacial permafrost degradation, our results suggest alternating phases of soil carbon accumulation and loss as an effect of dynamic changes in permafrost extent, active layer depths, soil litter input, and heterotrophic respiration.

Description: Climate reconstructions based on proxy records recovered from marine sediments, such as alkenone records or geochemical parameters measured on foraminifera, play an important role in our understanding of the climate system. They provide information about the state of the ocean ranging back hundreds to millions of years and form the backbone of paleo-oceanography. However, there are many sources of uncertainty associated with the signal recovered from sediment archived proxies. These include seasonal or depth habitat biases in the recorded signal, a frequency dependent reduction in the amplitude of the recorded signal due to bioturbation of the sediment, aliasing of high frequency climate variation onto a nominally annual, decadal or centennial resolution signal, and additional sample processing and measurement error introduced when the proxy signal is recovered. Here we present a forward model for sediment archived proxies that jointly models the above processes, so that the magnitude of their separate and combined effects can be investigated. Applications include the interpretation and analysis of uncertainty in existing proxy records, parameter sensitivity analysis to optimize future studies, and the generation of pseudo-proxy records that can be used to test reconstruction methods. We provide examples, such as the simulation of individual foraminifera records, that demonstrate the usefulness of the forward model for paleoclimate studies. The model is implemented as a user-friendly R package, sedproxy, the use of which we hope will contribute to a better understanding of both the limitations and potential of marine sediment proxies to inform about past climate.

Description: The Argentine margin contains important sedimentological, paleontological and chemical records of regional and local tectonic evolution, sea level, climate evolution and ocean circulation since the opening of the South Atlantic in the Late Jurassic–Early Cretaceous as well as the present-day results of post-depositional chemical and biological alteration. Despite its important location, which underlies the exchange of southern- and northern-sourced water masses, the Argentine margin has not been investigated in detail using scientific drilling techniques, perhaps because the margin has the reputation of being erosional. However, a number of papers published since 2009 have reported new high-resolution and/or multichannel seismic surveys, often combined with multi-beam bathymetric data, which show the common occurrence of layered sediments and prominent sediment drifts on the Argentine and adjacent Uruguayan margins. There has also been significant progress in studying the climatic records in surficial and near-surface sediments recovered in sediment cores from the Argentine margin. Encouraged by these recent results, our 3.5-day IODP (International Ocean Discovery Program) workshop in Buenos Aires (8–11 September 2015) focused on opportunities for scientific drilling on the Atlantic margin of Argentina, which lies beneath a key portion of the global ocean conveyor belt of thermohaline circulation. Significant opportunities exist to study the tectonic evolution, paleoceanography and stratigraphy, sedimentology, and biosphere and geochemistry of this margin.

Description: The current generation of marine biogeochemical modules in Earth system models (ESMs) considers mainly the effect of marine biota on the carbon cycle. We propose to also implement other biologically driven mechanisms in ESMs so that more climate-relevant feedbacks are captured. We classify these mechanisms in three categories according to their functional role in the Earth system: (1) "biogeochemical pumps", which affect the carbon cycling; (2) "biological gas and particle shuttles", which affect the atmospheric composition; and (3) "biogeophysical mechanisms", which affect the thermal, optical, and mechanical properties of the ocean. To resolve mechanisms from all three classes, we find it sufficient to include five functional groups: bulk phyto- and zooplankton, calcifiers, and coastal gas and surface mat producers. We strongly suggest to account for a larger mechanism diversity in ESMs in the future to improve the quality of climate projections.

Description: Recent rapid retreat of glacial front lines and the loss of land ice along the Antarctic margins may play an important role in exporting suspended particulate matter (SPM) potentially rich in bioavailable (defined as ascorbate leachable) iron (FeA) to coastal areas of the Southern Ocean. Sediment ablation is an additional source of iron for this high-nutrient low-chlorophyll region. In Potter Cove, King George Island, meltwater streams discharge up to 18 000 mg l-1 (average 283 mg l-1) of slightly weathered, finely ground bedrock particles into coastal waters during the summer. Approximately 15% of this SPM is exported within a low-salinity surface plume into Bransfield Strait. Based on our data, an estimated 12 mg m-2 yr-1 of FeA is exported from the South Shetland Island land surface (ice-free and subglacial areas) to the surrounding coastal waters. Extrapolated to an area of 2.5x104 km2, this FeA input is comparable to the contribution from icebergs and c. 240-fold higher than aeolian input via dust. An observed rise in local sediment accumulation rates suggests that glacial erosion has been increasing over recent decades and that (sub-)glacially derived SPM is becoming more important as a source of iron to the Southern Ocean.

Description: Since the Last Glacial Maximum, ice has retreated through the fjords of the South Shetland Islands leaving a valuable record of submarine landforms behind. In this study, glacial landforms and sub-bottom characteristics have been mapped to investigate the late Holocene retreat behaviour of the Fourcade Glacier and to delineate past environmental processes in Potter Cove, King George Island. The comprehensive datasets include high-resolution swath bathymetry, shallow seismic profiling and one sediment core. Moraines, moraine incisions and glacial lineations were mapped on the sea floor in the inner part of the cove, whereas pockmarks, ice scour marks and channel structures were identified in the outer part. Sub-bottom characteristics have been assigned to different acoustic facies types indicating different depositional settings. The results reveal glacial recessions as well as stillstands and potential readvances during the late Holocene. Furthermore, the sediment record indicates that the Fourcade Glacier was situated inside the inner cove during the Little Ice Age (500–100 cal yr bp).

Description: Introduction. Today, most countries have accepted a 2 degrees Celsius temperature increase above preindustrial levels as the maximum tolerable limit for global warming. An exceedance probability of below 20 percent for this limit implies an emission budget of less than 250 GtC from 2000 until 2049, however, extrapolating from current global CO2 emissions, this budget will only last until 2024. This sobering math should wake us up to the reality that all options, including climate engineering, need to be considered to address climate change. Climate engineering options can be classified broadly into two categories: solar radiation management and carbon dioxide removal measures. Solar radiation management schemes seek to decrease the incoming solar radiation or to increase the reflection of incoming solar radiation. These approaches can generate fast climate responses, but do not immediately address the cause of the problem. Carbon dioxide removal measures seek to decrease atmospheric carbon concentrations by enhancing or substituting natural carbon sinks. The terrestrial carbon sink can be enhanced by means of forestation; the oceanic sink may, in some regions, be enhanced by means of fertilization, for example by artificially enhanced upwelling of macronutrients or by purposeful addition of the micronutrient iron; the mineral carbon sink can be enhanced by means of chemically accelerated weathering. Some analysts have expressed doubts about the potential of mitigating climate change by sink enhancement, because of concerns about whether carbon can be stored permanently. Nevertheless, terrestrial vegetation sinks have entered the Kyoto Protocol (KP) as offsets for anthropogenic greenhouse gas emissions, but ocean sinks have not.

Description: Density distribution of the common infaunal bivalves, Macoma balthica and Cerastoderma edule, was studied along the Murman Coast of the Barents Sea during 2002–2010. In both species, abundance was generally higher in West Murman in contrast to East Murman. Highest density of Macoma balthica reaching 1535 ind. m−2 was observed in the Kola Inlet. Cerastoderma edule was less abundant; its density rarely exceeded 10 ind. m−2 in all but one site, where 282 ind. m−2 was registered. Reconstruction of abundance distribution across the European geographic range of Macoma balthica revealed that it does not match an ‘abundant-centre’ pattern, having features of ramped north. On the other hand, distribution of Cerastoderma edule abundance across the range generally follows an ‘abundant-centre’ pattern but southern edge populations show relatively higher abundances as compared with those at the north edge (the Barents Sea).

Description: No published information is available on the foraging ecology and choice of feeding habitat of New Zealand’s rarest breeding bird: the New Zealand Fairy Tern (NZFT) Sternula nereis davisae. To address this gap, we conducted an assessment of the largest remaining breeding population at Mangawhai Harbour, Northland, New Zealand, during the chick-rearing period of the 2010/2011 breeding season. We combined visual tracking of birds with prey surveys and stable isotope analyses, and we present the first quantitative assessment of NZFT foraging. We recorded 405 foraging dives that show NZFT foraging habitat includes the water edges, shallow channels, and pools on the tidal flats of mangrove-lined (Avicennia marina var. resinifera) parts of the estuary; tidal pools on mud- and sandflats in the mid-estuary and lower harbour; the shallow margins of the dredged main channel in the lower harbour; the oxbow lagoons on the sand spit; and coastal shallows. Our study identifies the mangrove-lined highly tidal and shallow mid-estuary and the lagoon on the sand spit as foraging hotspots for the Mangawhai breeding population of the NZFT. The prey survey employed a seine-net sampling method at identified NZFT foraging sites and yielded 4,367 prey-sized fish of 11 species, two of which had not previously been reported in Mangawhai Harbour, as well as numerous shrimps. The most abundant fish were gobies of the genus Favonigobius. Our stable isotope results highlight gobies as the most important prey for NZFT chick rearing, also indicating that flounder Rhombosolea sp. contribute to NZFT diet. We raise the possibility that shrimps may also constitute a substantial diet component for NZFT, potentially providing up to 21% of diet mass for adult birds. While our results provide a first basis to understanding the feeding ecology of NZFT during their breeding season in order to facilitate conservation planning, further research is required to address inter-annual variation and to identify key foraging grounds for this Critically Endangered bird at other breeding sites.

Description: The feeding habits of the pelagic stingray ( Pteroplatytrygon violacea ) were studied using 84 stomachs of specimens caught in the northern Adriatic Sea in the period from April 2004 to October 2005. Percentage of empty stomachs found was overall very low, being a bit bigger in smaller specimens. The diet consisted of two main taxonomic groups such as teleost fish and cephalopods, but few specimens of crustaceans were recorded as well. The main food item was represented by anchovy, while cuttlefish and red band fish represented the alternative preys. Prey size was positively correlated with the size of predator. The proportion of anchovies in the diet grew with size of predator, while the one for red band fish decreased. The stingray was confirmed to be a top predator of pelagic fish species, although the presence of benthic prey shows that it feeds also at the bottom.

Description: The schooling behaviour of the oval squid Sepioteuthis lessoniana was observed over 4 summers at 3 observation sites in the coastal waters of Okinawa Island, Ryukyu Archipelago, Japan. During this field study, 3 static appearances (belt, ball and sheet shape) and 2 transitional appearances (high and low density) were noted, recorded and described. In addition to formations, a member of S. lessoniana schools also displayed particular and repeated behavioural patterns such as vanguard and intimidating display. The 3 observation sites were tropical coral reefs near the coastline at a depth of 1 to 15 m on an average. All participating observers snorkelled and were equipped with various underwater digital video and photographic cameras. The schools observed consisted of 8 to over 100 members with a wide range of body sizes. Despite these biological and locational differences, both static and transitional appearances were consistently observed with equally consistent individual behavioural patterns. There have been studies on related species, Sepioteuthis sepioidea, at the San Blas Islands along the Caribbean coast of eastern Panama, and the same species, S. lessoniana, at a different geographical location, Casuarina Beach on Lizard Island, Australia. The findings of this study are consistent with those reported previously, with some notable differences.

Description: Age structure and hatchling dates of the squid Illex argentinus collected by bottom-trawl fishery in southern Brazilian waters were assessed by the analysis of statolith growth increments. Catches occurred between 2001 and 2002, from 23° to 32°S at depths of 100–700 m. Squid from juvenile to post-spawning stages were collected year round, with age estimated from 98 to 320 days and mantle lengths ranging from 112 to 376 mm. Duration of life cycle events based on statolith growth zones revealed that squids can spend about 14% of their lifespan as paralarva (~30 days), 70% as juvenile (~130 days), leaving maturity and spawning condition to the terminal 10–20% (~30–60 days). The results suggest that, unlike estimates available for Patagonian populations, a general 0.5 year lifespan is predicted for I. argentinus off Brazil. The wide range of size-at-ages implied that catches of shortfin squid off southern Brazil probably include squid hatched throughout the year. Mature and spawning squid caught in summer months hatched in winter and spring, while winter catches revealed mature-spawning individuals hatched both in summer/autumn (~6 months of age) and winter/spring periods (~10–11 months of age). It has been argued that such groups may combine both squid resident of Brazilian outer shelf and slope (22°–34°S) with a six months' lifespan and migrating squid originated from the northern Patagonian shelf (~42°S) with 10–11 months' lifespan.

Description: Intraspecific variation in characters such as arm sucker and gill lamellae counts in octopodids is yet to be thoroughly investigated, potentially hampering our ability to recognize species. In this study, data from 13 specimens of Muusoctopus hydrothermalis collected at four hydrothermal vents on the East Pacific Rise between 8°38′N and 12°48′N are considered. Although the northern and southern octopuses differ minimally in size, mean sucker count by arm in the northern group is 11.7 to 22.8% higher than it is in the southern group; in addition these octopuses typically have an additional gill lamella and bulkier funnel organs. The arms of each individual carry a different number of suckers. The difference is significant on nonadjacent arms, a pattern that merits examination in a broader taxonomic context. Why these differences exist among conspecifics remains unknown, the incidence of parasitic copepods is not different between the groups and the between-group variation in arm suckers seen here compares well with a previous report of variation among 18 specimens from the type locality. Increases in meristic characters (counts) in fish are attributed to lower temperatures during embryonic development following Jordan's rule. Northern and southern vents offer the octopuses a wide temperature range, but vent fluid chemistry differs. Northern vent fluids may be more toxic; if so, developing octopus embryos may survive only minimal vent fluid exposure and therefore develop at low temperatures. At the less toxic southern vents, eggs may survive greater exposure to vent fluids and thus develop at higher temperatures.

Description: The Cycladic blueschist belt, Greece, is mostly submerged below sea level and regional correlations are difficult to establish. Marbles are widespread within the belt and locally used as marker horizons to subdivide monotonous schist sequences. However, owing to the lack of distinctive petrographic characteristics, the marbles have not been used for island-to-island correlations. This study aims to investigate the potential of Sr-, C- and O-isotope compositions of marbles as a tool for unravelling the litho- and/or tectonostratigraphic relationships across the Cycladic islands, and as a proxy for the time of sediment formation. For this purpose, we have studied metamorphic carbonate rocks from the islands of Tinos, Andros, Syros, Sifnos and Naxos. Identical 87Sr/86Sr values for certain marble horizons occurring on Tinos, Andros and Sifnos are interpreted to document coeval regional carbonate precipitation. The 87Sr/86Sr values of the apparently least altered samples intersect the seawater curve multiple times within the most likely time interval of original carbonate precipitation (〈 240 Ma; as indicated by previously published ion probe U–Pb zircon data) and thus an unequivocal age assignment is not possible. Very broad temporal correlations are possible, but more subtle distinctions are not feasible. On Andros, the overlapping Sr-isotope values of marbles representing the lowest and highest parts of the metamorphic succession are in accordance with a model suggesting isoclinal folding or thrusting of a single horizon, or very fast sedimentation. In contrast, distinct 87Sr/86Sr values for samples from Tinos, representing different levels of the metamorphic succession, suggest that these rocks represent a temporal succession and not the tectonic repetition of a single horizon. Based on Sr-,O- and C-isotope characteristics alone the time equivalence ofmarbles occurring on different islands could not be documented unambiguously. However, by using various combinations of these parameters, some occurrences can be discriminated from the overall sample population. The new data further accentuate the general potential of coupled Sr-, C- and O-isotope characteristics for identification of archaeological provenance and complement existing datasets for Aegean marbles.

Description: Earthquake history shows that the Sunda subduction zone of the Indonesian margin produces great earthquakes offshore Sumatra, whereas earthquakes of comparable magnitude are lacking offshore Java and the Lesser Sunda islands. Morphological structures from multibeam bathymetric data across the forearc relate with the extent of the seismogenic zone (SZ). Off Java and the Lesser Sunda islands the Indo-Australian plate subducts almost normal underneath the oceanic plate of the Indonesian archipelago. Landward of the trench, the outer wedge of the slope break is ~50 km uniformly wide with uniform bathymetric gradients. The slope of the outer wedge is locally cut by one/two steeper ridges of ~5 km extent. The sharp slope break corresponds to the updip limit of the SZ, which is also associated with the seawardmost part of the outer arc high. Landward of the slope break we find narrow, uniform outer arc ridges. The landward termination of these ridges coincides with the downdip limit of the SZ. The intersection of the shallow upper plate mantle with the subduction thrust fault marks the downdip limit of the SZ beneath the forearc. Off Sumatra the Indo-Australian plate subducts obliquely underneath the continental part of the Indonesian Sunda margin. Landward of the trench, the outer wedge varies, being mostly ~70 km wide, in some areas narrowing to 50 km width. The lower slope bathymetric gradients are steep. The outer wedge slope is made up of several steeper ridges of ~5 km extent. The slope break is only locally sharp, and corresponds to the updip limit of the SZ. The outer arc ridges off Sumatra are, in comparison with the forearc structures off Java and the Lesser Sunda islands, wider and partly elevated above sea level forming the Mentawai forearc islands. The downdip limit of the SZ coincides with the intersection of a deeper upper plate mantle with the subduction thrust fault beneath the forearc. Sunda Strait marks a transition zone between the Sumatra and Java margins. Seafloor morphology enables the identification of the seismogenic zone (SZ) across the entire Sunda margin. The SZ is uniformly wide for the Sumatra margin and narrows off Sunda Strait. Sunda Strait is the transition between the Sumatra margin and the uniformly narrow extent of the SZ of the Java/Lesser Sunda margin. Comparing the Java and Lesser Sunda islands with the Sumatra margin we find the differences along the Sunda margin, especially the wider extent of the SZ off Sumatra, producing larger earthquakes, to result from the combination of various causes: The sediment income on the oceanic incoming plate and the subduction direction; we attribute a major role to the continental/oceanic upper plate nature of Sumatra/Java influencing the composition and deformation style along the forearc and subduction fault. Off Sumatra the SZ is up to more than twice as wide as off Java/Lesser Sunda islands, enlarging the unstable regime off Sumatra and thus the risk of sudden stress release in a great earthquake.

Description: EGU2011-407 The spatial and temporal distribution of sea ice in the subpolar North Atlantic is mainly controlled by the advection of warm Atlantic Water via the Norwegian and West Spitsbergen Current in eastern Fram Strait. Simultaneously, polar water and sea ice from the Arctic Ocean is transported southward by the East Greenland Current. Hence, variations in the strength of this oceanic circulation regime may either stimulate or reduce the sea ice extent. Based on organic geochemical studies of a high-resolution sediment core from eastern Fram Strait we provide new evidence for the highly variable character of the sea ice conditions in this area. The combination of the sea ice proxy IP25 (Belt et al., 2007) with phytoplankton derived biomarkers (e.g. brassicasterol, dinosterol; Volkman 2006) enables a reliable reconstruction of sea surface and sea ice conditions, respectively (Müller et al., 2009; 2010). By means of these biomarkers, we trace gradually increasing sea ice occurrences from the Mid to the Late Holocene – consistent with the neoglacial cooling trend. Throughout the past ca. 3,000 years (BP) we observe a significant short-term variability in the biomarker records, which points to rapid advances and retreats of the sea ice cover at the continental margin of West Spitsbergen. The co-occurrence of IP25 and phytoplankton markers, however, suggests that the primary productivity benefits from these sea ice surges. As such, higher amounts of open-water phytoplankton biomarkers together with peak abundances of IP25 indicate recurring periods of enhanced ice-edge phytoplankton blooms at the core site. To what extent a seesawing of temperate Atlantic Water may account for these sea ice fluctuations requires further investigation. Concurrent variations in Siberian river discharge (Stein et al., 2004) or Norwegian glacier extents (Nesje et al., 2001), however, strengthen that these fluctuations may be assigned to variations in the North Atlantic/Arctic Oscillation (NAO/AO) and (hence) a weakened/accelerated Atlantic Water input and Arctic sea ice export.

Description: The upwelling area in the eastern equatorial Pacific off Peru is one of the most pronounced oxygen minimum zones (OMZs) of the modern ocean. Modeling scenarios predict an expansion of the OMZs in the course of global change in the coming decades. As a consequence, the Peruvian continental margin represents a key locality for studies on biogeochemical dynamics in the future ocean. We present pore water and sediment data for redox-sensitive metals (Fe, Mn, V, Mo, and U) that have been collected along a transect across the Peruvian margin at 11°S. The results are used to evaluate the behavior of trace metals in a wide range of biogeochemical and hydrodynamic settings. In the core of the OMZ, where permanently anoxic conditions prevail, redox sensitive metals exhibit diagenetic behaviors largely consistent with previous studies. Vanadium and Mo are released from Fe oxihydroxides and subsequently recycled through diffusion across the benthic boundary or trapped through formation of authigenic V phases and sequestration of Mo by authigenic pyrite. Some U is delivered through diffusion across the benthic boundary, reduction and precipitation of UO2 and incorporation into phosphorites. The utmost part of the buried U, however, is delivered in particulate form, most likely as bioauthigenic U which cannot be recycled in the suboxic waters overlying the anoxic sediments. In contrast to sediments in the core of the OMZ, sediments on the shelf experience frequent oxygenation episodes related to the passage of internal waves and the regular recurrence of El Niño events. These oxygenation episodes lead to the re-oxidation and remobilization of authigenic U and V. In contrast to that, the authigenic accumulation of Mo is favored by the occasional occurrence of slightly oxidizing conditions. This is most likely due to enhanced formation of sulfur intermediates necessary for pyrite formation and the increased stability of pyrite, the major Mo sink, under oxidizing conditions, compared to authigenic V and U phases. Redox oscillations in the Peruvian OMZ thus lead to a discrimination of U against Mo, a mechanism that should be considered in the interpretation of U/Mo systematics in paleo redox studies. Overall our results provide valuable constraints on how trace metal inventories of marginal sediments may respond to expanding shelf anoxia and to short term perturbations of sediment redox conditions.

Description: EGU2011-12780 A temporary passive seismic network of 31 broad-band stations was deployed in the region around Talca and Constitución between 35°S to 36°S latitude and 71°W to 72.5°W longitude. The network was operated between March and October 2008. Thus, we recorded data prior the magnitude Mw=8.8 earthquake of 27 February 2010 at a latitude of the major slip and surface uplift. The experiment was conducted to address fundamental questions on deformation processes, crustal and mantle structures, and fluid flow. We present results of a teleseismic P receiver function study that covers the coastal region and reaches to the Andes. The aim is to determine the structure and thickness of the continental crust and constrain the state of hydration of the mantle wedge. The P-wave receiver function technique requires large teleseismic earthquakes from different distances and backazimuths. A few percent of the incident P-wave energy from a teleseismic event will be converted into S-wave (Ps) at significant and relatively sharp discontinuities beneath the station. A small converted S phase is produced that arrives at the station within the P wave coda directly after the direct P-wave. The converted Ps phase and their crustal multiples contain information about crustal properties, such as Moho depth and the crustal vp/vs ratio. We use teleseismic events with magnitudes mb 〉 5.5 at epicentral distances between 30° and 95° to examine P-to-S converted seismic phases. Our preliminary results provide new information about the thickness of the continental crust beneath the coastal region in Central Chile. At most of the stations we observed significant energy from P to S converted waves between 4 and 5 s after the direct P-wave within a positive phase interpreted as the Moho, occurring at 35 to 40 km. The great Maule earthquake of 27 February 2010 nucleated up-dip of the continental Moho. The rupture of this earthquake seems to have propagated down-dip of the Moho. The Moho reflection show a positive polarity, indicating that the mantle is either dry or only moderately hydrated. We observed converted energy from an intracrustal boundary at around 2 s that disappears near the coast. Further, positive polarity peaks occur that are possibly caused by the down going plate.

Description: EGU2011-8738 At present, the Arctic is responding faster to global warming than most other areas on earth, as indicated by rising air temperatures, melting glaciers and ice sheets and a decline of the sea ice cover. As part of the meridional overturning circulation which connects all ocean basins and influences global climate, northward flowing Atlantic Water is the major means of heat and salt advection towards the Arctic where it strongly affects the sea ice distribution. Records of its natural variability are critical for the understanding of feedback mechanisms and the future of the Arctic climate system, but continuous historical records reach back only ca. 150 years. To reconstruct the history of temperature variations in the Fram Strait Branch of the Atlantic Current we analyzed a marine sediment core from the western Svalbard margin. In multidecadal resolution the Atlantic Water temperature record derived from planktic foraminifer associations and Mg/Ca measurements shows variations corresponding to the well-known climatic periods of the last millennium (Medieval Climate Anomaly, Little Ice Age, Modern/Industrial Period). We find that prior to the beginning of atmospheric CO2 rise at ca. 1850 A.D. average summer temperatures in the uppermost Atlantic Water entering the Arctic Ocean were in the range of 3-4.5°C. Within the 20th century, however, temperatures rose by ca. 2°C and eventually reached the modern level of ca. 6°C. Such values are unprecedented in the 1000 years before and are presumably linked to the Arctic Amplification of global warming. Taking into account the ongoing rise of global temperatures, further warming of inflowing Atlantic Water is expected to have a profound influence on sea ice and air temperatures in the Arctic.

Description: EGU2011-1847-3 Lake Van is a lake by volume of 607 km3 and a maximum depth of 450 meters in a tectonically active zone in eastern Anatolia, Turkey. In summer 2010, Lake Van was the target of a deep drilling campaign (PaleoVan) in the frame of ICDP (International Continental Scientific Drilling Program). Two sites were drilled based on reflection seismic data collected during a seismic campaign in 2004. Here we present a first joint interpretation of the seismic and drilling data. Interpretation of seismic reflection data from lake reveals three physiographic provinces: a lacustrine shelf, a lacustrine slope, and a deep, relatively flat lake basin. The most prominent features of the lacustrine shelf and slope are prograding deltaic sequences, numerous unconformities, submerged channels, as well as closely spaced U- and/or V-shaped depressions, reflecting the variable lake level history of Lake Van. The seismic units of the shelf are dominantly composed of low-to-good continuity, variable amplitude reflections interpreted as fluvial deposits. The lake consists of three prominent basins (Tatvan, Deveboynu, and Northern Basins), separated by basement highs or ridges (Ahlat Ridge). The seismic units corresponding to these basins mainly consist of low to very high amplitude, well-stratified reflection patterns. Chaotic reflections are seen in parts of these basins. The Deveboynu Basin consists mainly of chaotic reflections. The Tatvan and Northern Basins are characterized by an alternating succession of well-stratified and chaotic reflecting layers. The chaotic seismic facies are interpreted as slump and slide deposits, which are probably the result of quick lake level fluctuations and/or earthquakes. The moderateto high amplitude, well-stratified facies seen in the deep parts of the basins away from the terrigenous sediment sources are interpreted as lacustrine deposits and tephra layers. The total sediment thickness in the deep parts of the lake is over 400 m. Prominent clinoforms indicate the initial flooding of Lake Van about 500 ka ago. The acoustic basement and the sediments lying on top of the basement in the southern part of the lake are disrupted by various intrusions and extrusions suggesting active volcanism. Synthetic seismograms calculated based on core logging, wire-line logging and check shot data will allow the correlation between seismic and drill data. This approach will allow extrapolating the stratigraphy from the wells to 3D-space by using the seismic data.

Description: EGU2011-4235 The Arctic is undergoing rapid environmental and economic transformations. Recent climate warming, which is simplifying access to oil and gas resources, enabling trans Arctic shipping, and shifting the distribution of harvestable resources, has brought the Arctic Ocean to the top of national and international political agendas. Scientific knowledge of the present status of the Arctic Ocean and the process-based understanding of the mechanics of change are urgently needed to make useful predictions of future conditions throughout the Arctic region. These are required to plan for the consequences of climate change. A step towards improving our capacity to predict future Arctic change was undertaken with the Second International Conference on Arctic Research Planning (ICARP II) meetings in 2005 and 2006, which brought together scientists, policymakers, research managers, Arctic residents, and other stakeholders interested in the future of the Arctic region. The Arctic in Rapid Transition (ART) Initiative developed out of the synthesis of the several resulting ICARP II science plans specific to the marine environment. This process started in October 2008 and has been driven by early career scientists. The ART Initiative is an integrative, international, multi-disciplinary, long-term pan-Arctic network to study changes and feedbacks with respect to physical characteristics and biogeochemical cycles in the Arctic Ocean in a state of rapid transition and its impact on the biological production. The first ART workshop was held in Fairbanks, Alaska, in November 2009 with 58 participants from 9 countries. Workshop discussions and reports were used to develop a science plan that integrates, updates, and develops priorities for Arctic Marine Science over the next decade. The science plan was accepted and approved by the International Arctic Science Committee (IASC) Marine Group, the former Arctic Ocean Science Board. The second ART workshop was held in Winnipeg, Canada, in October 2010 with 20 participants from 7 countries to develop the implementation plan. Our focus within the ART Initiative will be to bridge gaps in knowledge not only across disciplinary boundaries (e.g., biology, geochemistry, geology, meteorology, physical oceanography), but also across geographic (e.g., international boundaries, shelves, margins, and the central Arctic Ocean) and temporal boundaries (e.g., alaeo/geologic records, current process observations, and future modeling studies). This approach of the ART Initiative will provide a means to better understand and predict change, particularly the consequences for biological productivity, and ultimate responses in the Arctic Ocean system. More information about the ART Initiative can be found at http://aosb.arcticportal.org/art.html.

Description: EGU2011-13199 Images of crustal construction provide a key to understand the interplay of magmatism and tectonism while oceanic crust is build up. Bathymetric data show that the crustal construction is highly variable. Areas that are dominated by magmatic processes are adjacent to areas that are highly tectonised and where mantle rocks were found. The Mid-Atlantic Ridge at 22°N shows this high variability along the ridge axis, within the TAMMAR segment, and from segment to segment. However, this strong variability occurs also off-axis, spreading parallel, representing different times in the same area of the ridge. A fracture zone, with limited magma supply, has been replaced by a segment centre with a high magmatic budget. Roughly 4.5 million years ago, the growing magmatic active TAMMAR segment, propagated into the fracture zone, started the migration of the ridge offset to the south, and stopped the formation of core complexes. We present data from seismic refraction and wide-angle reflection profiles that surveyed the crustal structure across the ridge crest of the TAMMAR segment. These yield the crustal structure at the segment centre as a function of melt supply. The results suggest that crust is ~8 km thick near the ridge and decreases in thickness with offset to the ridge axis. Seismic layer 3 shows profound changes in thickness and becomes rapidly one kilometre thicker approx. 5 million years ago. This correlates with gravimetric data and the observed “Bull’s eye” anomaly in that region. Our observations support a temporal change from thick lithosphere with oceanic core complex formation to thin lithosphere with focussed mantle upwelling and segment growing. The formation of ‘thick-crust’ volcanic centre seems to have coincided with the onset of propagation 4.5 million years ago.

Description: EGU2011-6081 Natural stable isotopes are a powerful tool in marine sciences to investigate biological processes, such as present and past nutrient utilization. In this study we present the first dissolved silicon isotope data in the upwelling area off Peru, where one of the world’s largest Oxygen Minimum Zones (OMZ) is located. Silicon is the most important component required for phytoplankton (diatom) growth, which dominates primary productivity in this region. Stable Si isotopes are fractionated during diatom growth in that the lighter Si isotopes are preferentially incorporated into diatoms with a fractionation factor of -1.1 promille. The Si isotope composition of dissolved silicic acid of the corresponding surface waters is therefore left isotopically heavier. The Si isotope composition, 30Si/28Si, is expressed as δ30Si values, which stand forh deviations from a given standard (NBS28). Investigation of the dissolved seawater Si isotope composition thus provides a measure for the utilization and, combined with information on the Si isotope composition of the water masses upwelling off Peru, it is a measure for the supply pathways of Si to the coastal upwelling centres. Surface waters on the shelf off Peru are mainly fed by the Equatorial Undercurrent, which mainly consists of waters originating from the western and Central Pacific and which has a characteristic δ30Si of +1.5 promille. In areas and during phases of intense upwelling the fractionation of Si isotopes was observed to be weaker due to upwelling-driven supply of less fractionated Si (δ30Si = 1.7 promille, from water depths of around 100-150 m, whereas under weak upwelling conditions fractionation is higher (δ30Si ~3 promille due to a more complete utilization of the available dissolved silicate. The distribution of dissolved δ30Si correlates strongly with particulate biogenic silicate (opal) concentrations in that highest opal concentrations in the surface waters show the lowest δ30Si values thus strongest upwelling intensity. The most extreme δ30Si values in surface waters (δ30Si = 4.5 promille are observed offshore where silicic acid concentrations are nearly zero. Furthermore we compare the δ30Si data with the dissolved nitrogen isotope distribution, which in addition to nitrate utilization is mainly influenced by denitrification and annamox processes in the OMZ. Combined silicon and nitrogen isotope compositions can thus help to disentangle different fractionation processes within the nitrogen cycle.

Description: EGU2011-2455 The current interglacial has gone through a variety of warmer and colder periods. Consistent with the decreasing solar insolation during the Holocene, warmest conditions have occurred particularly within its earliest phase. We studied high-resolution sediment sequences from the Western Svalbard margin covering the last ca 10,000 years in order to reconstruct the variations of Atlantic Water advection to the Arctic, the sea ice extent, and the structure of the water column on the Westspitsbergen continental margin. The Fram Strait, often referred to as the Arctic Gateway, is the only deep-water passage for Atlantic-derived water masses to enter the Arctic Ocean. Northward advection of relatively warm and saline Atlantic Water masses keeps the eastern part of the Fram Strait ice-free all year. It therefore plays a crucial role for the heat budget of the Arctic. A multiproxy data set including geochemical, micropaleontological, and sedimentological parameters was established with centennial to multidecadal time resolution. Records of foraminiferal oxygen and carbon isotopes, planktic foraminifer assemblages, and the amount of ice rafted debris clearly reveal distinct variations between climatically warmer and colder intervals throughout this period. Planktic foraminifer assemblages reveal warmest conditions for the early Holocene period (ca 10-8 ka). A second warming pulse is detected between 5 and 6 ka. In the second half of the Holocene, increased IRD contents are indicative of a significant cooling trend. Despite of the decreasing solar insolation planktic foraminiferal assemblages suggest a return of slightly strengthened Atlantic Water advection around 3 to 2 ka and a strong warming event in the present, anthropogenically influenced period.

Description: We determined the isotopic composition of neodymium (Nd) and lead (Pb) of past seawater to reconstruct water mass exchange and erosional input between the Arctic Ocean and the Norwegian-Greenland Seas over the past 5 Ma. For this purpose, sediments of ODP site 911 (leg 151) located at 900 m water depth on the Yermak Plateau in the Fram Strait were used. The paleo-seawater variability of Nd and Pb isotopes was extracted from the sea water-derived metal oxide coatings on the sediment particles following the leaching method of Gutjahr et al. (2007). All radiogenic isotope data were acquired by Multi-Collector (MC) ICP-MS. The site 911 stratigraphy of Knies et al. (2009) was applied. Surface sediment Sr and Nd isotope data, as well as downcore Sr isotope data obtained on the same leaches are close to seawater and confirm the seawater origin of the Nd and Pb isotope signatures. The deep water Nd isotope time series extracted from site 911 was in general more radiogenic ("Nd = -7.5 to -10) than present day deep water ("Nd = -9.8 to -11.8) in the area of the Fram Strait (Andersson et al., 2008) and does not show a systematic trend with time. In contrast, the radiogenic isotope composition of Pb evolved from 206Pb/204Pb ratios around 18.7 to more radiogenic values around 19.2 between 2 Ma and today. The data indicate that mixing of water masses from the Arctic Ocean and the Norwegian-Greenland Seas has controlled the Nd isotope signatures of deep waters on the Yermak Plateau over the past 5 Ma. Prior to 1.7 Ma the Nd isotope signatures on the Yermak Plateau were less radiogenic than waters from the same depth in the central Arctic Ocean (Haley et al., 2008) pointing to a greater influence from the Norwegian-Greenland Seas. After 1.7 Ma the central Arctic and Yermak Plateau data have varied around similar values indicating water mass mixing overall similar to today. In contrast, the Pb isotope composition of deep waters in the Fram Strait appears to have been dominated by weathering inputs from glacially weathering old continental landmasses, such as Greenland or parts of Svalbard since 2 Ma. A similar control over the Pb isotope evolution of seawater since the onset of Northern Hemisphere Glaciation was recorded by ferromanganese crusts that grew from North Atlantic DeepWater in the western North Atlantic. References: Gutjahr, M., Frank, M., Stirling, C.H., Klemm, V., van de Flierdt, T. and Halliday, A.N. (2007): Reliable extraction of a deepwater trace metal isotope signal from Fe-Mn oxyhydroxide coatings of marine sediments.- Chemical Geology 242, 351-370 Haley B. A., M. Frank, R.F. Spielhagen and A. Eisenhauer (2008): Influence of brine formation on Arctic Ocean circulation over the past 15 million years. Nature Geoscience 1, 68–72 Andersson, P.S., Porcelli, D., Frank, M., Björk, G., Dahlqvist, R. and Gustafsson, Ö. (2008): Neodymium isotopes in seawater from the Barents Sea and Fram Strait Arctic- Atlantic gateways.- Geochim. Cosmochim. Acta 72, 2854-2867 Knies, J., J. Matthiessen, C. Vogt, J.S. Laberg, B.O. Hjelstuen, M.Smelror, E. Larsen, K. Andreassen, T. Eidvin and T.O. Vorren (2009): The Plio-Pleistocene glaciation of the Barents Sea–Svalbard region: a new model based on revised chronostratigraphy - Quaternary Science Reviews 28, 9-10, 812-829

Description: The midwater scorpionfish Ectreposebastes imus (Scorpaeniformes: Setarchidae) is distributed in tropical and subtropical waters of the worldwide oceans, at depths of 150–800 m. It has previously been recorded from the Gulf of Guinea in the eastern Atlantic. The present work extends the northern limit for the distribution of E. imus in the Atlantic Ocean to the area of the Canary Islands.

Description: Morphologic analyses of a large collection of coleoid cephalopods from the Lebanese Upper Cretaceous yielded a much higher diversity than previously assumed and revealed numerous extraordinarily well-preserved, soft-part characters. An analysis of the Prototeuthidina, a gladius-bearing group with a slender torpedo-shaped body, revealed two species: Dorateuthis syriaca and Boreopeltis smithi n. sp. Previously unknown soft-part characters, such as the digestive tract, the gills, and the cephalic cartilage considerably improved our knowledge of D. syriaca. Since none of the investigated specimens show more than eight arms, similarities with modern squids are regarded as superficial. Boreopeltis smithi n. sp. is erected on the basis of its comparatively wide Paraplesioteuthis- like gladius. The latter species represents the first unambiguous record of this genus in Upper Cretaceous deposits. Phylogenetic analyses indicate that the prototeuthidid clade consists of two lineages. The plesioteuthidid lineage originates from early Jurassic Paraplesioteuthis and leads to Plesioteuthis and Dorateuthis. The other lineage is morphologically more conservative and leads to Boreopeltis.

Description: EGU2011-12864 The Woodlark Basin east of Papua New Guinea represents one of the few places on Earth where a spreading axis propagates into continental crust. This special tectonic setting allows insights into the evolution of magma composition as continental extension and break-up changes to the formation of ocean crust. We report here geochemical results on samples collected in 2009 from the four segments closest to the continental breakup, from segment 1 which abuts the detachment fault responsible for continental extension on Moresby Seamount in the West, to segment 4, representing mature oceanic crust in the East. A total of 208 glass samples have been analyzed for their major (EMPA) and trace element (LA-ICPMS) compositions. The data show strong E-W variations. Samples ranging from tholeiitic basalt and basaltic andesite to andesite and rhyolite are found on Segment 1. They have generally high alkali values and a wide range of trace element contents and ratios. Segments 2 to 4 magmas in contrast only comprise tholeiitic basalt with lower alkali contents and a more restricted range of trace element chemistry. The geochemical differences between the segments cannot be attributed to differentiation processes alone, and different sources are required. High Ba/La, (La/Sm)N, Rb/Sr, and Th/La on Segment 1 suggest a derivation from an enriched mantle source, while low Nd/Pb and Nb/U suggest that some of the enrichment may also reflect the influence of continental crust during magma genesis. Whether this continental signature is present in the form of recycled material in the mantle or as rafted continental blocks in the axial region is at present unclear. In contrast to rocks from segment 1, trace element compositions of volcanic glasses from segments 2 to 4 show a stronger MORB signature, presumably reflecting more mature spreading in this part of the basin. The influence of continental material appears to be minimal, suggesting that uncontaminated asthenosphere quickly flows into the rift and/or that continental blocks are not retained in the axial region for long time periods following the rifting-spreading transition.

Description: EGU2010-13373 The frequency of volcanic activity varies on a wide rangeof spatial and temporal scales, from 〈1 yr. periodicities in single volcanic systems to periodicities of 106 yrs. in global volcanism. The causes of these periodicities are poorly understood although the long-term global variations are likely linked to plate-tectonic processes. Here we present evidence for temporal changes in eruption frequencies at an intermediate time scale (104 yrs.) using the Pleistocene to recent records of widespread tephras of sub-Plinian to Plinian, and occasionally co-ignimbrite origin, along the Pacific Ring of Fire, which accounts for about half of the global length of 44,000 km of active subduction. Eruptions at arc volcanoes tend to be highly explosive and the well-preserved tephra records from the ocean floor can be assumed to be representative of how eruption frequencies varied with time. Volcanic activity along the Pacific Ring of Fire evolved through alternating phases of high and low frequency; although there is modulation by local and regional geologic conditions, these variations have a statistically significant periodicity of 43 ka that overlaps with the temporal variation in the obliquity of the Earth’s rotation axis, an orbital parameter that also exerts a strong control on global climate changes. This may suggest that the frequency of volcanic activity is controlled by effects of global climate changes. However, the strongest physical effects of climate change occur at 100 ka periods which are not seen in the volcanic record. We therefore propose that the frequency of volcanic activity is directly influenced by minute changes in the tidal forces induced by the varying obliquity resulting in long-period gravitational disturbances acting on the upper mantle.

Description: EGU2010-10518 Seafloor compliance is the transfer function between pressure and vertical displacement at the seafloor Infragravity waves in the oceanic layer have long periods in the range of 30 – 500 s and obey a simple frequencywavenumber relation. Seafloor compliance from infragravity waves can be analyzed with single station recordings to determinate sub-seafloor shear wave velocities. Previous studies in the Pacific Ocean have demonstrated that reliable near-surface shear wave profiles can be derived from infragravity wave compliance. However, these studies indicate that, beside the water depth the compliance measurements are limited by instrument sensitivity, calibration uncertainties and possibly other effects. In this work seafloor compliance and infragravity waves are observed at two different locations in the Atlantic Ocean: the Logatchev hydrothermal field at the Mid Atlantic Ridge and the Azores (Sao Miguel Island). The data was acquired with the broadband ocean compliance station developed at the University of Hamburg as well as ocean station from the German instrument pool for amphibian seismology (DEPAS) equipped with broadband seismometers and pressure sensors. Vertical velocity and pressure data were used to calculate power spectral densities and normalized compliance along two profiles (one in each location). Power spectral densities show a dominant peak at low frequencies (0.01-0.035Hz) limited by the expected cut-off frequency, which is dependent on the water depth at each station. The peak has been interpreted as a strong infragravity wave with values between 10-14 and 10-11 (m/s2)2/Hz and 104 and 106 (Pa2)2/Hz for acceleration and pressure respectively. The results show compliance values between 10-10 and 10-8 1/Pa and its estimations take into account the coherence between seismic and pressure signals in order to confirm that the seismic signals in the infragravity waves are caused by pressure sources. Shear wave velocity models, with depth resolution from 200 to 2500 m for the deep water stations, were derived from compliance. Preliminary results indicate shear wave velocity increasing from 200 to 3500 m/s.

Description: EGU2010-9841 Active mud volcanoes, where changing salinities of pore fluids, large temperature gradients and occurrences of free gas are frequently observed, should potentially exhibit significant variability in their internal resistivity structure. This is due to the fact that the bulk resistivity is mainly determined by the porosity of sediments and the electrical resistivity of the pore filling contained therein. The resistivity variations may be derived from controlled source electromagnetic (CSEM) measurements. CSEM systems consist of an electric dipole transmitter producing a time varying source field and electric dipole receivers, which measure the earth´s response to this signal. For a RWE Dea funded investigation of fluid and gas leakages at the North Alex Mud Volcano (NAMV) - a comparatively small target with an area of about 1km2 - we have developed a new high resolution CSEM system. The system consists of several autonomous electric dipole receivers and a lightweight electric dipole transmitter, which can be mounted on a small remotely operated underwater vehicle (ROV). The use of a ROV allows for a precise placement of the transmitter, which is a necessary prerequisite for the investigation of such a small target. Furthermore, electromagnetic signals may be transmitted from different directions with respect to the stationary receivers, allowing for a 3D-style tomographic experiment. In this experiment, ten receivers were deployed over the surface of NAMV at a total of 16 receiver locations. During three successful dives with a Cherokee ROV (Ghent University, Belgium), the transmitter was deployed at a total of 80 locations. Here we present first quantitative results consisting of apparent resistivity estimations from the CSEM time domain data for each transmitter-receiver pair. The apparent resistivity map shows that the NAMV indeed has a heterogeneous resistivity structure with apparent resistivities varying by at least a factor of two: low apparent resistivities (~ 0.8Ωm) are found towards the center of the MV, whereas higher apparent resistivities (~ 1.6Ωm) prevail away from the center. In a second step, we interpret the time-domain data based on 1D inversions. Good data fits can be achieved by models containing 2-3 layers. Generally, the models indicate low resistivities at the surface, which can be associated with penetrating salt water and/or high temperatures. Toward greater depths, increasing resistivities presumably are due to a combination of compaction of sediments (i.e. reduced pore space), an increased presence of fresh water and possible occurrences of free gas. For some 1D models, the increase in resistivity exceeds a factor of 10 or more and layer interfaces are indicated down to depths of up to 70m. The derived resistivity variations observed at the NAMV will be interpreted in conjunction with temperature (Feseker, this session), fluid flow (Brückmann et al., this session) and seismic data (Bialas et al., this session) acquired. Temperature variations measured in the upper few meters are related to fluid flow, where high temperatures are indicative of upwelling fluids of low salinity and low temperature of either a downward flow of saline fluids or no flow activity. This type of surface measurement constitutes an integrative fluid flow gauge, which we can resolve vertically with our resistivity models. Seismic data yield a background structure to our resistivity model. New analysis of seismic data shows that seismic activity may also be linked to fluid flow activity, which we aim to match with resistivity variations and oscillations, which were observed in the electric and magnetic fields (Lefeldt et al., this session).

Description: Recently Hathorne et al. (2009) documented large intratest trace element (TE) variations in planktonic foraminifera from a single sediment trap sample that could not be explained by variations in water column properties. The laser ablation ICP-MS depth profiles of trace elements through the test walls revealed strong positive correlations between Li, Mg, Mn and Ba resulting from the mixing of a lower TE outer calcite with a higher TE inner calcite. In contrast Sr/Ca ratios remained relatively constant throughout the test wall. These intratest TE variations likely result from biomineralization processes and therefore should be explained by any valid biomineralization model. However, changes in calcite precipitation rate, crystal structure, or the chemical composition of the internal calcification reservoir could not, by themselves, fully account for the pattern of cation intratest variability. Here I expand on this work and investigate if a model of coral biomineralization by Sinclair and Risk (2006) can be adapted to explain the pattern of intratest TE variability in foraminifera. It is clear that the low Mg calcite secreting foraminifera must reduce the Mg/Ca ratio of the calcifying solution by at least a factor of 10 (e.g. Hathorne et al., 2009) and it has been suggested this is achieved by active removal of Mg from the calcification reservoir, although the actual mechanisms remain debatable (e.g. Bentov and Erez, 2006). However, a recent study of the calcification of a low Mg calcite species in the laboratory found a large shortcoming in the amount of Ca potentially provided by seawater transported to the site of calcification in vacuoles compared to a conservative estimate of the amount required to form the new calcite wall (de Nooijer et al., 2009a). This suggests active Ca transport to the site of calcification is required to provide sufficient Ca. If Ca specific, this Ca addition would effectively dilute the TE content (including Mg) of the calcification reservoir to varying degrees and potentially cause the positive TE correlations seen across the test wall. Sinclair and Risk (2006) used this dilution model to successfully explain some TE correlations in coral skeletons. This model can be effectively adapted to foraminifera as it accounts for recent observations of foraminiferal calcification including the transport of seawater by liquid endocytosis to the calcification site and an elevated pH at the site of calcification (Bentov et al., 2009; de Nooijer et al., 2009a, 2009b). This model therefore provides a powerful tool with which to integrate constraints from experimental observation with those from micro-analytical measurements to improve the accuracy, precision and scale of the palaepalaeoceanographic application of foraminiferal geochemistry. Bentov and Erez (2006) Geochem. Geophys. Gepsyst. 7, Q01P08. Bentov et al. (2009) PNAS 106, 21500. de Nooijer et al. (2009a) Biogeosciences 6, 2669. de Nooijer et al. (2009b) PNAS 106, 15374. Hathorne et al. (2009) Paleoceanography 24, PA4204. Sinclair and Risk (2006) Geochim. Cosmochim. Acta 70, 3855.

Description: We present Mg/Ca analyses performed via a Flow Through sequential dissolution device connected to an ICP-OES on the planktonic foraminifer Globorotalia inflata. The aim of the study is to explore the possibility to reconstruct the thermal gradient in the water column by separating non-crusted and crusted calcite phases in the tests of G. inflata using the difference between their Mg/Ca ratios as a measure of the thermal gradient. An important assumption is that the non-crusted part of the tests is calcified in shallow, warmer water than the crusted part. For analyses a range of different preparation steps were used to determine the ideal way of separating the phases. Foraminifer tests were (not) cleaned, (not) crushed, and (not) pulverized before online analysis with the FT device. To analyze samples with a FT device the foraminifer tests are placed on a filter with a mesh of 0.45 μm preventing clay minerals to wash through. A sequential dissolution protocol first rinses the samples with buffered Seralpur water before QD HNO3 is added in small steps to create a ramp of increasing acid strength. As acid is kept constant at each concentration for several minutes, dissolution of a specific calcite phase can take place. Initial results show that it is most effective to slightly crush the tests without applying standard cleaning procedures, but rather analyze them without cleaning. Samples were selected from the South Atlantic (core tops and specific downcore samples) and the Mediteterranean (plankton tows). All samples were chosen based on previous work on them to provide comparison with routinely analysed Mg/Ca ratios. The South Atlantic samples have been analyzed extensively as bulk samples separated in difference size fractions and crusted vs. non-crusted (Groeneveld and Chiessi). The Mediterranean samples were not only analyzed as bulk samples but also by Laser Ablation ICP-MS (von Raden et al.). Results show that bulk analyses are reliably reproduced by the FT method, especially for samples which are dominated by crusted calcite. Samples which were uncrusted often gave much higher Mg/Ca ratios than the bulk analyses. These higher Mg/Ca ratios mainly occur in the plankton tow samples and were also identified with Laser Ablation ICP-MS. A possible reason for this could be the presence of a high Mg amorphous calcite layer on the outside of foraminifer tests which have not completed their calcification yet as was recently also pointed out in several other studies. Identification of the crusted and uncrusted phases, and therewith a thermal gradient, seems to give the expected differences but a more rigorous statistical treatment is needed to pinpoint singular dissolution phases.

Description: EGU2010-2934 The exploration of the arctic seas require an integrated approach applying different infrastructures. In Fall 2009 German and Russian scientists performed a geo marine cruise off Kamchatka and in the western Bering Sea within the frame of the KALMAR-Project. Two main research subjects formed the scientific backbone of the cruise: The first objective focuses on the geodynamic and volcanological magmatic development of the Kuril-Kamchatka island arc system and the Kamchatka Aleutean Islands Triple-Junction. Very little is known about the composition of the mantle and the oceanic crust as well as of the seamounts including their ages. The best studied site is the Volcanologist’s Massif located between the Bering- and the Alpha Fracture Zone (Tsvetkov 1990, Volynets et al. 1992, Yogodzinsky et al. 1994), which structurally belongs to the Komandorsky Basin. The oldest rocks of the Volcanologist´s Massif show very similar trace element and isotope signatures like those rocks cropping out in the volcanoes on Kamchatka in the prolongation of the Alpha Fracture Zone (Portnyagin et al. 2005a), indicating similar conditions of magma formation. The top of the Volcanologist´s Massif is characterized by the young (〈 0.5 Ma) and hydrothermally active Piip volcano, which consists of special magnesium rich andesites ("Piip type"). Another hot site was the Meiji-Seamount which is the northernmost Seamount of the hotspot spur of the Hawaii-Emperor-Seamount chain, having an age of probably 〉 85 Ma. The only existing basement rocks from this seamount were gained during DSDP Leg 19. These are basalts with MORB like trace element and isotope signatures (Keller et al. 2000, Regelous et al. 2003). These data indicate that the Hawaii-Hotspot was at a MOR in Cretaceous time and that large volumes of depleted mantle material played a´role during the magma formation. The second objective focuses on paleo-oceanographic investigations concentrating on the sediments along the eastern continental slope of Kamchatka, in the Komandorsky Basin, and on the Shirshov Ridge in order to explore paleoclimate archives to better understand the subpolar water mass transfer and the oceanographic and climatic development in the subarctic NW-Pacific. Comparisons of Late Pleistocene and Holocene temperature changes within the near surface water masses between the NW-Pacific and the N-Atlantic resulted in a new hypothesis, the "Atlantic-Pacific seesaw" (Kiefer et al. 2001, Kim et al. 2004, Kiefer and Kienast, 2005). This Atlantic-Pacific pattern of opposite temperature variations dominates the last 60ka on millennial timescales. Modelling results of Saenko et al. (2004) support the hypothesis of the "Atlantic-Pacific seesaw" and they postulate a mechanistic connection between the two regions driven by salinity variations, which couples both regions through the thermohaline circulation. A different model relates the Holocene Atlantic-Pacific dipole to the atmospheric tele-connection between the Arctic Oscillation/N-Atlantic Oscillation and the Pacific N-American Oscillation (Kim et al. 2004). http://kalmar.ifm-geomar.de

Description: The scorpionfish Setarches guentheri (Scorpaeniformes: Setarchidae) usually dwells offshore, in soft bottom deep areas at depths of about 150 to 780 m and at bottom temperature range of 5.5°C–12.5°C. This species has the widest distribution of any known scorpaenid, although this is a rare bathydemersal scorpaenid. Setarches guentheri has a large distribution, occurring from the Indo-West Pacific (Tanzania to South Africa, India and Sri Lanka to the Bay of Bengal, Andaman Sea, north to Japan, Fiji and Hawaii, south to the Philippines, Indonesia and Western Australia), from the eastern Pacific (Chile) and from the Atlantic Ocean (in the western Atlantic, USA to Brazil, and in the eastern Atlantic). In the eastern Atlantic, it has been recorded from Morocco, Madeira and Cape Verde to South Africa and, in the Iberian Peninsula, there was only one previous record from the Algarve coast, Portugal. The present record constitutes a new extended northern limit for the distribution of S. guentheri in this area.

Description: Two species of the bobtail squid Heteroteuthis are reported from the Atlantic Ocean, H. dispar in the North Atlantic Ocean and H. dagamensis in the South Atlantic Ocean. In total 58 individuals were examined, 23 belonging to the species Heteroteuthis dispar and 35 belonging to the species H. dagamensis . All specimens were captured during the Walther Herwig Expeditions 1966, 1968, 1976 and 1982. A full description of both sexes of H. dispar and H. dagamensis is provided. These two species can only be distinguished by means of the male's enlarged suckers on arm pair III. Females are not useful for taxonomic identifications and are morphologically identical in both species. The results do not support the definition of subgenera in this genus. This is the first report for Heteroteuthis dagamensis in the South-West Atlantic Ocean.