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  • Geological Society of America
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Years
  • 1
    Publication Date: 2024-04-22
    Description: Volcanic hazards associated with lava flows advancing on snow cover are often underrated, although sudden explosions related to different processes of lava-snow/ice contact can occur rapidly and are only preceded by small, easily underrated precursors. On 16 March 2017, during a mildly effusive and explosive eruption at Mount Etna, Italy, a slowly advancing lava lobe interacted with the snow cover to produce a sudden, brief sequence of explosions. White vapor, brown ash, and coarse material were suddenly ejected, and the products struck a group of people, injuring some of them. The proximal deposit formed a continuous mantle of ash, lapilli, and decimeter-sized bombs, while the ballistic material travelled up to 200 m from the lava edge. The deposit was estimated to have a mass of 7.1 ± 0.8 × 104 kg, which corresponds to a volume of 32.0 ± 3.6 m3 of lava being removed by the explosion. Data related to the texture and morphology of the ejected clasts were used to constrain a model of lava-snow interaction. The results suggest that the mechanism causing the explosions was the progressive build-up of pressure due to vapor accumulation under the lava flow, while no evidence was found for the occurrence of fuel-coolant interaction processes. Although these low-intensity explosions are not particularly frequent, the data set collected provides, for the first time, quantitative information about the processes involved and the associated hazard and suggests that mitigation measures should be established to prevent potentially dramatic accidents at worldwide volcanoes frequented by tourists and with fairly easy access, such as Etna.
    Description: In press
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2024-05-09
    Description: Magma convection, where low-viscosity, gas-rich magma ascends, degasses, and crystallizes before sinking down the same conduit in either annular or side-by-side flows, has been proposed for active basaltic volcanoes, where excess gas fluxes relative to erupted lava volume can be observed. Experimental studies show that convection is produced by buoyant ascending gas-rich magma and descending degassed magmas following density difference contrast, while geophysical studies point to the endogenous growth of active volcanoes through magma accumulation in plutons. However, many aspects of the convection process remain unclear, in particular, the depth to which magma ascends before overturning. Models have been proposed where overturn occurs near the surface and also at depths greater than 2 km from the top of the magma-filled conduit. The long-term monitoring of volcanic gas compositions may reveal new insights into the convection process, as each gas has a unique solubility-pressure profile. We report measurements of SO2 and HCl gas fluxes from Etna between October 2007 and May 2011, in which an ~90% collapse in halogen flux was observed together with an effusive eruption. This observation indicates that the halogen fluxes, during quiescent periods on Etna, require both magma supply to the shallowest levels and a period of residence. The lava effusion has the effect of reducing the shallow residence time, drastically reducing the halogen flux. These results provide a new interpretative framework for the degassing process and gas composition monitoring to explain subtle variations in magma supply and residence times in basaltic volcanism.
    Description: Published
    Description: 419-423
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2023-08-31
    Description: Large calderas are among the main emitters of volcanic CO2, which is mainly supplied by the deep degassing of magmatic fluids. However, other sources of non-magmatic CO2 can also occur due to the intense interaction among magmatic fluids, wide hydrothermal systems, and their host rocks. In particular, massive amounts of CO2 are released by calderas during unrest phases and have been often detected before eruptions. An accurate assessment of CO2 sources is thus fundamental to properly understand gas monitoring signals during volcanic crises. We focused on the restless Campi Flegrei caldera, in southern Italy, where CO2 fluxes at the Solfatara-Pisciarelli hydrothermal site have been progressively increasing up to 4000–5000 t/d during the ongoing unrest that started in 2005. Theoretical models of magma degassing have been able to reproduce the CO2-N2-He variations at the Solfatara fumaroles. However, a time-dependent deviation between measured and modeled N2/CO2 and He/CO2, well correlated with the temporal evolution of ground uplift and temperature of the hydrothermal system, has been observed since 2005. We show that these variations are controlled by intense physical-chemical perturbation of the hydrothermal system, which is driving the decarbonation of hydrothermal calcite stored in reservoir rocks. This process is providing large volumes of non-magmatic CO2 during the current unrest, contributing up to 20%–40% of the total fumarolic CO2.
    Description: Published
    Description: 397-401
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2022-05-27
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Waelkens, C. M., Stix, J., Monteleone, B., & Burckel, P. Efficient release of bromine by super-eruptions. Geology, 49(12), (2021): 1416–1420, https://doi.org/10.1130/G49114.1.
    Description: Bromine is a key halogen element in the quantification of volcanic volatiles, but analytical difficulties in measuring its very low abundances have prevented progress in understanding its behavior and its role in volcanic emissions. We present a new data set of bromine, chlorine, and fluorine concentrations in melt inclusions and matrix glasses for two rhyolitic super-eruptions from the Toledo and Valles calderas, New Mexico, USA. We show that before eruption, Br and Cl were efficiently partitioned from the gas-saturated magma into a separate fluid phase, and we calculate the mass of halogens in the fluid phase. We further demonstrate that syn-eruptive magma degassing was negligible during the super-eruptions, so that the main source of halogen emissions must have been the fluid phase. If the fluid phase were erupted, the large mass of Br and Cl could have severely impacted the atmospheric chemistry upon eruption.
    Description: This research was supported by a Geological Society of America grant (C. Waelkens), Natural Sciences and Engineering Research Council of Canada (NSERC) Discovery and CREATE grants (J. Stix), and Institut de Physique du Globe de Paris multidisciplinary program PARI and Paris–IdF region SESAME grant 12015908 (P. Burckel). The Northeast National Ion Microprobe Facility is subsidized by U.S. National Science Foundation (NSF) facility support grant NSF-EAR-1664308.
    Repository Name: Woods Hole Open Access Server
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  • 5
    Publication Date: 2022-08-05
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Poag, C. W. Bolide impact effects on the West Florida Platform, Gulf of Mexico: end Cretaceous and late Eocene. Geosphere, 18(3), (2022): 1077–1103, https://doi.org/10.1130/GES02472.1.
    Description: This study documents seismic reflection evidence that two different bolide impacts significantly disrupted stratigraphic and depositional processes on the West Florida Platform (Gulf of Mexico). The first impact terminated the Late Cretaceous Epoch (Chicxulub impact, Mexico; ca. 66 Ma; end-Maastrichtian age). The second took place in the late Eocene (Chesapeake Bay impact, Virginia, USA, portion of the Chesapeake Bay; ca. 35 Ma; Priabonian age). Both impacts produced far-reaching seismic shaking and ground roll followed by an impact-generated tsunami, the effects of which are evident in the seismostratigraphic record. The Chicxulub seismic shaking caused collapse and shoreward retreat of the Florida Escarpment and widely disrupted (faulting, folding, slumping) normal flat-lying shelf beds. The associated tsunami currents redistributed these shelf deposits and mixed them together with collapse debris from the escarpment to form a thick wedge of sediments along the base of the escarpment. The Chesapeake Bay impact created a mounded sedimentary deposit near the outer edge of the late Eocene ramp slope. This deposit also has a bipartite origin. A lower layer is marked by en echelon faulting created in situ by seismic shaking, whereas an upper layer represents sediments redistributed from the late Eocene shelf and upper ramp slope by tsunami-driven bottom currents (debris flows, contour currents, slumps). This is the first report of seismic effects from the Chesapeake Bay impact in the Gulf of Mexico. These results further demonstrate that large-scale marine bolide impacts have widespread effects on the stratigraphic and depositional record of Earth.
    Description: I am grateful to the following persons for their assistance in this research: Matt Arsenault for help attaining seismic data; T.J. Christian for providing samples from the Texaco 2523-1 borehole; Deborah Hutchinson, David Foster, Christian Koeberl, and an unnamed reviewer for helpful reviews of the original manuscript; and especially to the U.S. Geological Survey for supporting my continued research as a Scientist Emeritus.
    Repository Name: Woods Hole Open Access Server
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  • 6
    Publication Date: 2022-10-19
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Zhou, P., Ireland, T., Murray, R. W., & Clift, P. D. Marine sedimentary records of chemical weathering evolution in the western Himalaya since 17 Ma. Geosphere, 17(3), (2021): 824–853, https://doi.org/10.1130/GES02211.1.
    Description: The Indus Fan derives sediment from the western Himalaya and Karakoram. Sediment from International Ocean Discovery Program drill sites in the eastern part of the fan coupled with data from an industrial well near the river mouth allow the weathering history of the region since ca. 16 Ma to be reconstructed. Clay minerals, bulk sediment geochemistry, and magnetic susceptibility were used to constrain degrees of chemical alteration. Diffuse reflectance spectroscopy was used to measure the abundance of moisture-sensitive minerals hematite and goethite. Indus Fan sediment is more weathered than Bengal Fan material, probably reflecting slow transport, despite the drier climate, which slows chemical weathering rates. Some chemical weathering proxies, such as K/Si or kaolinite/(illite + chlorite), show no temporal evolution, but illite crystallinity and the chemical index of alteration do have statistically measurable decreases over long time periods. Using these proxies, we suggest that sediment alteration was moderate and then increased from 13 to 11 Ma, remained high until 9 Ma, and then reduced from that time until 6 Ma in the context of reduced physical erosion during a time of increasing aridity as tracked by hematite/goethite values. The poorly defined reducing trend in weathering intensity is not clearly linked to global cooling and at least partly reflects regional climate change. Since 6 Ma, weathering has been weak but variable since a final reduction in alteration state after 3.5 Ma that correlates with the onset of Northern Hemispheric glaciation. Reduced or stable chemical weathering at a time of falling sedimentation rates is not consistent with models for Cenozoic global climate change that invoke greater Himalayan weathering fluxes drawing down atmospheric CO2 but are in accord with the idea of greater surface reactivity to weathering.
    Description: This study was made possible by samples provided by the IODP. The work was partially funded by a grant from The U.S. Science Support Program (USSSP), as well as additional funding from the Charles T. McCord Jr. Endowed Chair in petroleum geology at LSU.
    Keywords: Alteration ; Arabian Sea ; Arid environment ; Asia ; Bengal Fan ; Chemical composition ; Chemical weathering ; Chlorite ; Chlorite group ; Clay minerals ; Climate change ; Cooling ; Crystallinity ; Emission spectra ; Erosion ; Expedition 355 ; Glaciation ; Goethite ; Grain size ; Hematite ; Himalayas ; ICP mass spectra ; Illite ; Indian Ocean ; Indus Fan ; International Ocean Discovery Program ; IODP Site U1456 ; IODP Site U1457 ; Kaolinite ; Karakoram ; Magnetic properties ; Magnetic susceptibility ; Marine environment ; Mass spectra ; Mineral assemblages ; Moisture ; Oxides ; Paleoclimatology ; Paleoenvironment ; Paleomagnetism ; Provenance ; Reactivity ; Reconstruction ; Sediment transport ; Sedimentary rocks ; Sedimentation ; Sedimentation rates ; Sheet silicates ; Silicates ; Spectra ; Terrestrial environment ; Transport ; Weathering
    Repository Name: Woods Hole Open Access Server
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  • 7
    Publication Date: 2022-05-27
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Hofig, D., Zhang, Y. G., Giosan, L., Leng, Q., Liang, J., Wu, M., Miller, B., & Yang, H. Annually resolved sediments in the classic Clarkia lacustrine deposits (Idaho, USA) during the middle Miocene Climate Optimum. Geology, 49(8), (2021): 916–920, https://doi.org/10.1130/G48901.1.
    Description: The world-renowned Miocene Clarkia paleolake in northern Idaho (USA) is closely associated with Columbia River Basalt Group volcanism. The flood basalt dammed a local drainage system to form the paleolake, which preserved a plant fossil Lagerstätte in its deposits. However, the precise age and temporal duration of the lake remain unsettled. We present the first unequivocal U-Pb zircon ages from interbedded volcanic ashes at the P-33 type location, constraining the deposition to 15.78 ± 0.039 Ma. Using micro–X-ray fluorescence and petrographic and spectral analyses, we establish the annual characteristics of laminations throughout the stratigraphic profile using the distribution of elemental ratios, mineral assemblages, and grain-size structures, as well as organic and fossil contents. Consequently, the ~7.5-m-thick varved deposit at the type location P-33 represents ~840 yr of deposition, coincident with the end of the main phase of Columbia River Basalt Group eruptions during the Miocene Climate Optimum. The timing and temporal resolution of the deposit offer a unique opportunity to study climate change in unprecedented detail during global warming associated with carbon-cycle perturbations.
    Description: This research was supported by U.S. National Science Foundation (NSF) grants EAR-1806015 to Zhang and EAR-1804511 to Yang and Leng. Zircon U-Pb analyses were made possible by the NSF-Major Research Instrumentation grant OCE-1626244 and the Texas A&M Research Development Fund award to Miller. We are grateful to the Kienbaum family for providing access to their private property to sample the P-33 site, and to Kunguang Yang from China University of Geosciences at Wuhan for the LA-ICP-MS analysis.
    Repository Name: Woods Hole Open Access Server
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  • 8
    Publication Date: 2022-05-26
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Maselli, V., Oppo, D., Moore, A. L., Gusman, A. R., Mtelela, C., Iacopini, D., Taviani, M., Mjema, E., Mulaya, E., Che, M., Tomioka, A. L., Mshiu, E., & Ortiz, J. D. A 1000-yr-old tsunami in the Indian Ocean points to greater risk for East Africa: reply. Geology, 49(1), (2021): E516-E516, https://doi.org/10.1130/G48585Y.1.
    Description: We appreciate Somerville’s (2020) interest in our work, and the opportunity to further expand the discussion about the occurrence of a trans-oceanic tsunami in the Indian Ocean generated by a megathrust earthquake ~1000 years ago. Somerville suggests a connection between the inferred tsunami deposit presented by us (Maselli et al., 2020) and a tsunami event reported to have occurred in Nagapattinam (India) in the year 900 CE and described in Kalaki Krishnamurty’s book (Rastogi and Jaiswal, 2006).
    Repository Name: Woods Hole Open Access Server
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  • 9
    Publication Date: 2022-05-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Prouty, N. G., Brothers, D. S., Kluesner, J. W., Barrie, J. V., Andrews, B. D., Lauer, R. M., Greene, H. G., Conrad, J. E., Lorenson, T. D., Law, M. D., Sahy, D., Conway, K., McGann, M. L., & Dartnell, P. Focused fluid flow and methane venting along the Queen Charlotte fault, offshore Alaska (USA) and British Columbia (Canada). Geosphere, 16(6), (2020): 1336-1357, doi:10.1130/GES02269.1.
    Description: Fluid seepage along obliquely deforming plate boundaries can be an important indicator of crustal permeability and influence on fault-zone mechanics and hydrocarbon migration. The ∼850-km-long Queen Charlotte fault (QCF) is the dominant structure along the right-lateral transform boundary that separates the Pacific and North American tectonic plates offshore southeastern Alaska (USA) and western British Columbia (Canada). Indications for fluid seepage along the QCF margin include gas bubbles originating from the seafloor and imaged in the water column, chemosynthetic communities, precipitates of authigenic carbonates, mud volcanoes, and changes in the acoustic character of seismic reflection data. Cold seeps sampled in this study preferentially occur along the crests of ridgelines associated with uplift and folding and between submarine canyons that incise the continental slope strata. With carbonate stable carbon isotope (δ13C) values ranging from −46‰ to −3‰, there is evidence of both microbial and thermal degradation of organic matter of continental-margin sediments along the QCF. Both active and dormant venting on ridge crests indicate that the development of anticlines is a key feature along the QCF that facilitates both trapping and focused fluid flow. Geochemical analyses of methane-derived authigenic carbonates are evidence of fluid seepage along the QCF since the Last Glacial Maximum. These cold seeps sustain vibrant chemosynthetic communities such as clams and bacterial mats, providing further evidence of venting of reduced chemical fluids such as methane and sulfide along the QCF.
    Description: The authors thank officers and crew of the CCGS Vector and CCGS John P. Tully; M. Baker (USGS), R. Garrison (UCSC), J. Fitzpatrick, (USGS), N. Vokhshoori (UCSC), and C. Maupin (Texas A&M University, College Station, Texas, USA) for laboratory and sample assistance; and J. Pohlman (USGS) for helpful comments. Input from two anonymous reviewers substantially improved the manuscript. The USGS Coastal and Marine Hazards and Resource Program funded this study. Any use of trade, product, or firm names is for descriptive purposes only and does not imply endorsement by the U.S. Government. Additional geochemical and geophysical data to support this project can be found in Prouty et al. (2019) and Balster-Gee et al. (2017a, 2017b), respectively.
    Repository Name: Woods Hole Open Access Server
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  • 10
    Publication Date: 2022-05-26
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Parnell-Turner, R., Sohn, R. A., Peirce, C., Reston, T. J., MacLeod, C. J., Searle, R. C., & Simao, N. M. Seismicity trends and detachment fault structure at 13 degrees N, Mid-Atlantic Ridge. Geology, 49(3), (2021): 320-324, https://doi.org/10.1130/G48420.1.
    Description: At slow-spreading ridges, plate separation is commonly partly accommodated by slip on long-lived detachment faults, exposing upper mantle and lower crustal rocks on the seafloor. However, the mechanics of this process, the subsurface structure, and the interaction of these faults remain largely unknown. We report the results of a network of 56 ocean-bottom seismographs (OBSs), deployed in 2016 at the Mid-Atlantic Ridge near 13°N, that provided dense spatial coverage of two adjacent detachment faults and the intervening ridge axis. Although both detachments exhibited high levels of seismicity, they are separated by an ∼8-km-wide aseismic zone, indicating that they are mechanically decoupled. A linear band of seismic activity, possibly indicating magmatism, crosscuts the 13°30′N domed detachment surface, confirming previous evidence for fault abandonment. Farther south, where the 2016 OBS network spatially overlapped with a similar survey done in 2014, significant changes in the patterns of seismicity between these surveys are observed. These changes suggest that oceanic detachments undergo previously unobserved cycles of stress accumulation and release as plate spreading is accommodated.
    Description: This work was funded by UK Natural Environmental Research Council (NERC) grants NE/J02029X/1, NE/J022551/1, and NE/J021741/1 and by U.S. National Science Foundation grants OCE-1458084 and OCE-1839727. OBSs were provided by NERC UK Ocean-Bottom Instrumentation Facility (Minshull et al., 2005).
    Repository Name: Woods Hole Open Access Server
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  • 11
    Publication Date: 2021-08-20
    Description: Geologic mapping in southern Death Valley, California, demonstrates Mesozoic contractional structures overprinted by two phases of Neogene extension and contemporaneous strike-slip deformation. The Mesozoic folding is most evident in the middle unit of the Noonday Formation, and these folds are cut by a complex array of Neogene faults. The oldest identified Neogene faults primarily displace Neoproterozoic units as young as the Johnnie Formation. However, in the northernmost portion of the map area, they displace rocks as young as the Stirling Quartzite. Such faults are seen in the northern Ibex Hills and con­sist of currently low- to moderate-angle, E-NE– dipping normal faults, which are folded about a SW-NE–trending axis. We interpret these low-angle faults as the product of an early, NE-SW extension related to kinematically similar deformation recognized to the south of the study area. The folding of the faults postdates at least some of the extension, indicating a component of syn-exten­sional shortening that is probably strike-slip related. Approximately EW-striking sinistral faults are mapped in the northern Saddlepeak Hills. However, these faults are kinematically incompatible with the folding of the low-angle faults, suggesting that folding is related to the younger, NW-SE extension seen in the Death Valley region. Other faults in the map area include NW- and NE-striking, high-angle normal faults that crosscut the currently low-angle faults. Also, a major N-S–striking, oblique-slip fault bounds the eastern flank of the Ibex Hills with slickenlines showing rakes of
    Electronic ISSN: 1553-040X
    Topics: Geosciences
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  • 12
    Publication Date: 2021-08-19
    Description: Four new latest Pleistocene slip rates from two sites along the northwestern half of the San Bernardino strand of the San Andreas fault suggest the slip rate decreases southeastward as slip transfers from the Mojave section of the San Andreas fault onto the northern San Jacinto fault zone. At Badger Canyon, offsets coupled with radiocarbon and optically stimulated luminescence (OSL) ages provide three independent slip rates (with 95% confidence intervals): (1) the apex of the oldest dated alluvial fan (ca. 30–28 ka) is right-laterally offset ~300–400 m yielding a slip rate of 13.5 +2.2/−2.5 mm/yr; (2) a terrace riser incised into the northwestern side of this alluvial fan is offset ~280–290 m and was abandoned ca. 23 ka, yielding a slip rate of 11.9 +0.9/−1.2 mm/yr; and (3) a younger alluvial fan (13–15 ka) has been offset 120–200 m from the same source canyon, yielding a slip rate of 11.8 +4.2/−3.5 mm/yr. These rates are all consistent and result in a preferred, time-averaged rate for the past ~28 k.y. of 12.8 +5.3/−4.7 mm/yr (95% confidence interval), with an 84% confidence interval of 10–16 mm/yr. At Matthews Ranch, in Pitman Canyon, ~13 km northwest of Badger Canyon, a landslide offset ~650 m with a 10Be age of ca. 47 ka yields a slip rate of 14.5 +9.9/−6.2 mm/yr (95% confidence interval). All of these slip rates for the San Bernardino strand are significantly slower than a previously published rate of 24.5 ± 3.5 mm/yr at the southern end of the Mojave section of the San Andreas fault (Weldon and Sieh, 1985), suggesting that ~12 mm/yr of slip transfers from the Mojave section of the San Andreas fault to the northern San Jacinto fault zone (and other faults) between Lone Pine Canyon and Badger Canyon, with most (if not all) of this slip transfer happening near Cajon Creek. This has been a consistent behavior of the fault for at least the past ~47 k.y.
    Electronic ISSN: 1553-040X
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  • 13
    Publication Date: 2021-08-19
    Description: Late Cretaceous obduction of the Semail ophiolite and underlying thrust sheets of Neo-Tethyan oceanic sediments onto the submerged continental margin of Oman involved thin-skinned SW-vergent thrusting above a thick Guadalupian–Cenomanian shelf-carbonate sequence. A flexural foreland basin (Muti and Aruma Basin) developed due to the thrust loading. Newly available seismic reflection data, tied to wells in the Gulf of Oman, suggest indirectly that the trailing edge of the Semail Ophiolite is not rooted in the Gulf of Oman crust but is truncated by an ENE-dipping extensional fault parallel to the coastline. This fault is inferred to separate the Semail ophiolite to the SW from in situ oceanic Gulf of Oman crust to the NE. It forms the basin margin to a “hinterland” basin formed atop the Gulf of Oman crust, in which 5 km of Late Cretaceous deep-water mudstones accumulated together with 4 km of Miocene and younger deep-water mudstones and sandstones. Syndepositional folding included Paleocene–Eocene folds on N-S axes, and Paleocene to Oligocene growth faults with roll-over anticlines, along the basin flank. Pliocene compression formed, or tightened, box folds whose axes parallel the modern coast with local south-vergent thrusts and reversal of the growth faults. This Pliocene compression resulted in large-scale buckling of the Cenozoic section, truncated above by an intra-Pliocene unconformity. A spectacular 60-km-long, Eocene(?) to Recent, low-angle, extensional, gravitational fault, down-throws the upper basin fill to the north. The inferred basement of the hinterland basin is in situ Late Cretaceous oceanic lithosphere that is subducting northwards beneath the Makran accretionary prism.
    Electronic ISSN: 1553-040X
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  • 14
    Publication Date: 2021-08-19
    Description: Seismic and sequence stratigraphic analyses are important methodologies for interpreting coastal and shallow-marine deposits. Though both methods are based on objective criteria, terminology for reflection/stratal stacking is widely linked to eustatic cycles, which does not adequately incorporate factors such as differential subsidence, sediment supply, and autogenic effects. To reduce reliance on model-driven interpretations, we developed a Geometrical Breakdown Approach (GBA) that facilitates interpretation of horizon-bound reflection packages by systematically identifying upward-downward and landward-seaward trajectories of clinoform inflection points and stratal ter­minations, respectively. This approach enables a rigorous characterization of stratal surfaces and depositional units. The results are captured in three-letter acronyms that provide an efficient way of recognizing repetitive stacking pat­terns through discriminating reflection packages objectively to the maximum level of resolution provided by the data. Comparison of GBA with selected sequence stratigraphic models that include three and four systems tracts and the accommodation succession approach shows that the GBA allows a greater level of detail to be extracted, identifying key surfaces with more precision and utilizing more effectively the fine-scale resolution provided by the input seismic data. We tested this approach using a synthetic analogue model and field data from the New Jersey margin. The results demonstrate that the geometric criteria constitute a reliable tool for identifying systems tracts and provide an objective and straightforward method for practitioners at all levels of experience.
    Electronic ISSN: 1553-040X
    Topics: Geosciences
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  • 15
    Publication Date: 2021-02-25
    Description: The present-day lithospheric architecture of modern and ancient orogens can be imaged by geophysical techniques. For ancient orogens, unravelling their architecture at the time of formation is hindered by later tectono-magmatic events. In this paper, we use spatial variations in radiogenic isotopic compositions of Late Triassic magmatism from the Yidun Terrane, eastern Tibetan Plateau, to establish its lithospheric architecture during the Triassic. Comprehensive geochemical and isotopic data of Late Triassic magmatic rocks from four transects across the Yidun Terrane document eastward enrichment in whole-rock Nd, Sr, and zircon Hf isotopic compositions. Mafic and felsic rocks of major plutons show coherent and nonlinear trends in the Zr and P2O5 systematics and have limited variation of isotopic compositions. This indicates that Late Triassic magmatic differentiation was dominated by fractionation of mantle-derived mafic magmas. The spatial isotopic trends result from changing mantle sources, including variable contributions of isotopically depleted asthenospheric mantle and isotopically enriched subcontinental lithospheric mantle (SCLM) to magma sources. The spatial variation of mantle sources suggests a westward thinning of the SCLM during the Triassic. We propose that this architecture is most likely associated with eastward subduction of oceanic lithosphere of the Jinshajiang Ocean located at the west of the Yidun Terrane, immediately prior to the Late Triassic magmatism.
    Print ISSN: 0016-7606
    Electronic ISSN: 1943-2674
    Topics: Geosciences
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  • 16
    Publication Date: 2021-03-01
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
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  • 17
    Publication Date: 2021-03-01
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
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  • 18
    Publication Date: 2021-02-25
    Description: Crooked Ridge and White Mesa in northeastern Arizona (southwestern United States) preserve, as inverted topography, a 57-km-long abandoned alluvial system near the present drainage divide between the Colorado, San Juan, and Little Colorado Rivers. The pathway of this paleoriver, flowing southwest toward eastern Grand Canyon, has led to provocative alternative models for its potential importance in carving Grand Canyon. The ~50-m-thick White Mesa alluvium is the only datable record of this paleoriver system. We present new 40Ar/39Ar sanidine dating that confirms a ca. 2 Ma maximum depositional age for White Mesa alluvium, supported by a large mode (n = 42) of dates from 2.06 to 1.76 Ma. Older grain modes show abundant 37–23 Ma grains mostly derived ultimately from the San Juan Mountains, as is also documented by rare volcanic and basement pebbles in the White Mesa alluvium. A tuff with an age of 1.07 ± 0.05 Ma is inset below, and hence provides a younger age bracket for the White Mesa alluvium. Newly dated remnant deposits on Black Mesa contain similar 37–23 Ma grains and exotic pebbles, plus a large mode (n = 71) of 9.052 ± 0.003 Ma sanidine. These deposits could be part of the White Mesa alluvium without any Pleistocene grains, but new detrital sanidine data from the upper Bidahochi Formation near Ganado, Arizona, have similar maximum depositional ages of 11.0–6.1 Ma and show similar 40–20 Ma San Juan Mountains–derived sanidine. Thus, we tentatively interpret the
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  • 19
    Publication Date: 2021-02-25
    Description: The southwestern margin of Laurentia transitioned from a left-lateral transform margin to a convergent margin by middle Permian time, which initiated the development of a subduction zone and subsequent Cordilleran arc along western Laurentia. The displaced Caborca block was translated several hundred kilometers from southern California, USA, to modern Sonora, Mexico, beginning in Pennsylvanian time (ca. 305 Ma). The Monos Formation, a ~600-m-thick assemblage of mixed bioclastic and volcaniclastic units exposed in northwestern Sonora, provides lithostratigraphic, petrographic, and geochronologic evidence for magmatic arc development associated with subduction by middle Permian time (ca. 275 Ma). The Monos Formation was deposited in a forearc basin adjacent to a magmatic arc forming along the southwestern Laurentian margin. Detrital zircon U-Pb geochronology suggests that Permian volcanic centers were the primary source for the Monos Formation. These grains mixed with far-traveled zircons from both Laurentia and Gondwana. Zircon age spectra in the Monos Formation are dominated by a ca. 274 Ma population that makes up 65% of all analyzed grains. The remaining 35% of grains range from 3.3 Ga to 0.3 Ma, similar to age spectra from Permian strata deposited in the Paleozoic sequences in the western continental interior. An abundance of Paleozoic through early Neoproterozoic ages suggests that marginal Gondwanan sources from Mexico and Central America also supplied material to the basin. The Monos Formation was deposited within tropical to subtropical latitudes, yet faunal assemblages are biosiliceous and heterotrophic. The lack of photozoan assemblages suggests that cold-water coastal upwelling combined with sedimentation from the Cordilleran arc and Laurentian continent promoted conditions more suitable for fauna resilient to biogeochemically stressed environments. We propose that transform faulting and displacement of the Caborca block ceased by middle Permian time and a subduction zone developed along the southwestern margin of Laurentia as early as early Permian time. The Monos basin developed along the leading edge of the continent as a magmatic arc developed, and facies indicate a consistent shoaling trend over the span of deposition.
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  • 20
    Publication Date: 2021-02-25
    Description: In 1964, the Alaska margin ruptured in a giant Mw 9.2 megathrust earthquake, the second largest during worldwide instrumental recording. The coseismic slip and aftershock region offshore Kodiak Island was surveyed in 1977–1981 to understand the region’s tectonics. We re-processed multichannel seismic (MCS) field data using current standard Kirchhoff depth migration and/or MCS traveltime tomography. Additional surveys in 1994 added P-wave velocity structure from wide-angle seismic lines and multibeam bathymetry. Published regional gravity, backscatter, and earthquake compilations also became available at this time. Beneath the trench, rough oceanic crust is covered by ~3–5-km-thick sediment. Sediment on the subducting plate modulates the plate interface relief. The imbricate thrust faults of the accreted prism have a complex P-wave velocity structure. Landward, an accelerated increase in P-wave velocities is marked by a backstop splay fault zone (BSFZ) that marks a transition from the prism to the higher rigidity rock beneath the middle and upper slope. Structures associated with this feature may indicate fluid flow. Farther upslope, another fault extends 〉100 km along strike across the middle slope. Erosion from subducting seamounts leaves embayments in the frontal prism. Plate interface roughness varies along the subduction zone. Beneath the lower and middle slope, 2.5D plate interface images show modest relief, whereas the oceanic basement image is rougher. The 1964 earthquake slip maximum coincides with the leading and/or landward flank of a subducting seamount and the BSFZ. The BSFZ is a potentially active structure and should be considered in tsunami hazard assessments.
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  • 21
    Publication Date: 2021-02-25
    Description: In this study, single-grain mineral geochemistry, detrital zircon geochronology, and conventional heavy-mineral analysis are used to elucidate sediment transport pathways that existed in the North Atlantic region during the Triassic. The presence of lateral and axial drainage systems is identified and their source regions are constrained. Axial systems are suggested to have likely delivered sediment sourced in East Greenland (Milne Land–Renland) as far south as the south Viking Graben (〉800 km). Furthermore, the data highlight the existence of lateral systems issuing from Western Norway and the Shetland Platform as well as a major east-west–aligned drainage divide positioned adjacent to the Milne Land– Renland region. This divide separated the catchments that flowed north to the Boreal Ocean from those that flowed south into a series of endoreic basins and, ultimately, the Tethys Sea. A further potential drainage divide is identified to the west of Shetland. The data presented and the conclusions reached have major implications for reservoir prediction, as well as correlation, throughout the region. Furthermore, understanding the drainage networks that existed during the Triassic can help constrain paleogeographic reconstructions and provides an important framework for the construction of facies models in the region.
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  • 22
    Publication Date: 2021-03-29
    Description: Discerning paleoclimate parameters in depositional systems of the continental interior is challenging because the system response and stratigraphic record of climate are controlled by tectonic processes and are mediated through landscape and hydrological evolution of fluvial lacustrine systems. Climate and tectonic signals cannot be deconvolved from stratigraphic patterns alone but require additional information or data sets that directly record climate or tectonic influence. The Carnian Los Rastros Formation in northwest Argentina provides an excellent case study that integrates an appropriate range of information in a system with strong climate and tectonic signals, being deposited in part during the Carnian Pluvial Episode and spanning the active rift phase of the Ischigualasto−Villa Unión Basin. We examined the stratigraphic and spatial patterns of carbon (C) and oxygen (O) stable isotopes in lacustrine carbonates from the Los Rastros Formation in multiple parts of the basin to constrain paleohydrological conditions and paleotemperatures. Practically all C and O isotope values are characterized by negative values: δ18Ocarb −11.6‰ and −15.7‰ (χ average −13.1‰; 1σ = 1.6) and δ13Ccarb −2.6‰ to −8.0‰ (χ average −5.1‰; 1σ = 2.1), reflecting the latitude, altitude, and continentality of the lake system and its vegetated and humid catchment area. Stratigraphic patterns of stable isotope data from two different localities (Cerro Bola North and Cerro Bola South) show a change from short water-residence time to long residence time and back to short residence time. This contrasts with sedimentologic, organic geochemical, and small-scale stratigraphic patterns that indicate an overfilled lake basin, which is expected to contain a completely open-hydrology isotopic signature. Paleotemperatures calculated from marginal lacustrine carbonates show a warm and quite variable paleothermal range consonant with their continental interior position and with Global Climate Model estimates for high paleolatitudes. Warmer paleotemperatures (linked to aridity, probably smaller lake size, and less thermal mass) precede the Carnian Pluvial Episode, whereas relatively cooler paleotemperatures coincide with the Carnian Pluvial Episode (linked to humidity, probably larger lake size, and more thermal mass). Carbon and oxygen stable isotope signatures integrated with sedimentologic and physiographic information allow us to propose that tectonics, specifically, half-graben tilting during the active synrift phase, dominated over climate effects as the cause of hydrological fluctuations of this system, even during the Carnian Pluvial Episode. Without appropriate stratigraphic-tectonic context, single-proxy reconstructions of continental-interior paleoclimate can be misleading. A robust interpretation of climate effects requires characterization of tectonic effects, geomorphology, paleohydrology, and sedimentary system responses.
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  • 23
    Publication Date: 2021-03-29
    Description: Normal faults are commonly segmented along strike, with segments that localize strain and influence propagation of slip during earthquakes. Although the geometry of segments can be constrained by fault mapping, it is challenging to determine seismically relevant segments along a fault zone. Because slip histories, geometries, and strengths of linkages between normal fault segments fundamentally control the propagation of rupture during earthquakes, and differences in segment slip rates result in differential uplift of adjacent footwalls, we used along-strike changes in footwall morphology to detect fault segments and the relative strength of the mechanical links between them. We applied a new geomorphic analysis protocol to the Wassuk Range fault, Nevada, within the actively deforming Walker Lane. The protocol examines characteristics of footwall morphology, including range-crest continuity, bedrock-channel long profiles, catchment area variability, and footwall relief, to detect changes in strike-parallel footwall characteristics. Results revealed six domains with significant differences in morphology that we used to identify seismically relevant fault segments and segment boundaries. We integrated our results with previous studies to determine relative strength of links between the six segments, informing seismic hazard assessment. When combined with recent geodetic studies, our results have implications for the future evolution of the Walker Lane, suggesting changes in the accommodation of strain across the region. Our analysis demonstrates the power of this method to efficiently detect along-strike changes in footwall morphology related to fault behavior, permitting future researchers to perform reconnaissance assessment of normal fault segmentation worldwide.
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  • 24
    Publication Date: 2021-03-22
    Description: Fossil melanosomes are a major focus of paleobiological research because they can inform on the original coloration, phylogenetic affinities, and internal anatomy of ancient animals. Recent studies of vertebrate melanosomes revealed tissue-specific trends in melanosome-metal associations that can persist in fossils. In some fossil vertebrates, however, melanosomes from all body regions are enriched only in Cu, suggesting diagenetic overprinting of original chemistry. We tested this hypothesis using laboratory experiments on melanosomes from skin and liver of the African clawed frog Xenopus laevis. After maturation in Cu-rich media, the metal chemistry of melanosomes from these tissues converged toward a common composition, and original differences in Cu oxidation state were lost. Elevated Cu concentrations and a pervasive Cu(II) signal are likely indicators of diagenetically altered melanosomes. These results provide a robust experimental basis for interpretating the chemistry of fossil melanosomes.
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  • 25
    Publication Date: 2021-03-22
    Description: Molecular phylogenetic data suggest that photosynthetic eukaryotes first evolved in freshwater environments in the early Proterozoic and diversified into marine environments by the Tonian Period, but early algal evolution is poorly reflected in the fossil record. Here, we report newly discovered, millimeter- to centimeter-scale macrofossils from outershelf marine facies of the ca. 950–900 Ma (Re-Os minimum age constraint = 898 ± 68 Ma) Dolores Creek Formation in the Wernecke Mountains, northwestern Canada. These fossils, variably preserved by iron oxides and clay minerals, represent two size classes. The larger forms feature unbranching thalli with uniform cells, differentiated cell walls, longitudinal striations, and probable holdfasts, whereas the smaller specimens display branching but no other diagnostic features. While the smaller population remains unresolved phylogenetically and may represent cyanobacteria, we interpret the larger fossils as multicellular eukaryotic macroalgae with a plausible green algal affinity based on their large size and presence of rib-like wall ornamentation. Considered as such, the latter are among the few green algae and some of the largest macroscopic eukaryotes yet recognized in the early Neoproterozoic. Together with other Tonian fossils, the Dolores Creek fossils indicate that eukaryotic algae, including green algae, colonized marine environments by the early Neoproterozoic Era.
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  • 26
    Publication Date: 2021-03-22
    Description: Strongly 13C-depleted authigenic carbonates (e.g., δ13CVPDB
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  • 27
    Publication Date: 2021-03-24
    Description: The widely developed black shales deposited during the early Cambrian recorded paleoenvironmental information about coeval seawater. Numerous studies have been conducted on these shales to reconstruct the paleomarine environment during this time period. However, most research has been conducted on stratigraphic sections in South China, and equivalent studies of sections from other cratons are relatively rare. Here, we report Mo isotopic compositions as well as redox-sensitive trace-element and iron (Fe) speciation data for black shales of the Lower Cambrian Yuertusi Formation from the Tarim block (i.e., a small craton). The Fe speciation data show high FeHR/FeT and Fepy/FeHR ratios, indicating roughly sustained euxinic bottom-water conditions during their deposition. Based on Mo isotopic compositions (δ98/95Mo), we further classified the euxinic black shales into two intervals: a lower interval (0−21.3 m) and an upper interval (21.3−32.3 m). The lower interval is characterized by variable Mo isotopic compositions (−2.12‰ to +0.57‰, mean = −0.52‰ ± 0.72‰), with an obvious negative excursion in its middle portion. The overlying upper interval has relatively heavy δ98/95Mo values up to +1.42‰ (mean = +0.62‰ ± 0.37‰). We ascribe δ98/95Mo differences in the lower and upper intervals to inadequate aqueous H2S concentrations for quantitative thiomolybdate formation under euxinic conditions. The most negative Mo isotope excursion may have been caused by upwelling hydrothermal inputs during a transgression, consistent with significantly elevated total organic carbon (TOC) contents, Mo and U enrichments, and Fe supply. Relatively positive δ98/95Mo values in the upper interval have roughly similar variations with other coeval sections, indicating such variations were common for early Cambrian euxinic deposits, and they were most likely caused by local differences in [H2S]aq. Compilation of Mo isotope data from the early Cambrian and earlier times further indicates relatively oxygenated seawater, especially the deep-marine areas during the early Cambrian before reaching a state like modern seawater.
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  • 28
    Publication Date: 2021-03-22
    Description: Large thermochronologic data sets enable orogen-scale investigations into spatio-temporal patterns of erosion and deformation. We present the results of a thermo-kinematic modeling study that examines large-scale controls on spatio-temporal variations in exhumation as recorded by multiple low-temperature thermochronometers in the Pyrenees mountains (France/Spain). Using 264 compiled cooling ages spanning ~200 km of the orogen, a recent model for its topographic evolution, and the thermo-kinematic modeling code Pecube, we evaluated two models for Axial Zone (AZ) exhumation: (1) thrust sheet–controlled (north-south) exhumation, and (2) along-strike (east-west) variable exhumation. We also measured the degree to which spatially variable post-orogenic erosion influenced the cooling ages. We found the best fit for a model of along-strike variable exhumation. In the eastern AZ, rock uplift rates peak at ≥1 mm/yr between 40 and 30 Ma, whereas in the western AZ, they peak between 30 and 20 Ma. The amount of post-orogenic (
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  • 29
    Publication Date: 2021-03-22
    Description: New zircon U-Pb geochronology from a peridotite suite near Ranau and the Telupid ophiolite in Sabah, eastern Malaysia, contradict previous studies, which assumed that the Sabah mafic-ultramafic rocks are largely ophiolitic and Jurassic–Cretaceous in age. We show that these rocks formed during a magmatic episode in the Miocene (9.2–10.5 Ma), which is interpreted to reflect infiltration of melts and melt-rock reaction in the Ranau subcontinental peridotites during extension, and concurrent seafloor spreading forming the Telupid ophiolite further south. Older zircons from the Ranau peridotites have Cretaceous, Devonian, and Neoproterozoic ages. Zircon Lu-Hf isotopic data suggest their derivation from a depleted mantle. However, significant proportions of crustal components have been incorporated in their genesis, as evidenced by their less-radiogenic Hf signature compared to a pristine mantle reservoir. The involvement of a crustal component is consistent with our interpreted continental setting for the Ranau peridotite and formation in a narrow backarc basin for the Telupid ophiolite. We infer that the Sulu Sea, which was expanding throughout much of the Miocene, may have extended to the southwest into central Sabah. The Telupid oceanic strand formed during the split, collapse, and rollback of the Sulu arc due to the subduction of the Celebes Sea beneath Sabah. Incorporation of the Sulu arc in the evolving Miocene oceanic basin is a potential source to explain the involvement of crustal material in the zircon evolution of the Telupid ophiolite.
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  • 30
    Publication Date: 2021-03-22
    Description: Species of burrowing animals have changed substantially over evolutionary time scales, but, surprisingly, burrows display persisting morphological patterns throughout the Phanerozoic. Deep-sea burrows are geometrically patterned, whereas shallow-marine burrows display simpler morphologies. This divergence between burrow associations is one of the central conundrums of paleontology, but it has never been quantitatively demonstrated, and the organizing principles responsible for this structure remain unknown. We show that the divergence of burrow associations has been shaped by small-world dynamics, which is proposed as a major macroevolutionary force in marine environments. Using network analysis, our study reveals that the association patterns between burrow morphotypes in 45 paleontological sites span ~500 m.y. Strong statistical support is demonstrated for a surprising association pattern, according to which the data set is optimally partitioned into two subgroups of tightly associated burrow types. These groups correspond to shallow- and deep-marine biomes. Our analysis demonstrates that across the Phanerozoic Eon, burrows did not assemble randomly nor regularly, following instead small-world assembly rules remarkably similar to those that shape human social networks. As such, small-world dynamics deeply influenced gene flow and natural variation in heritable behavior across evolutionary time.
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  • 31
    Publication Date: 2021-03-22
    Description: In the Rodinia supercontinent, Laurentia is placed at the center because it was flanked by late Neoproterozoic rifted margins; however, the conjugate margin for western Laurentia is still enigmatic. In this study, new paleomagnetic results have been obtained from 15 ca. 775 Ma mafic dikes in eastern Hebei Province, North China craton (NCC). Stepwise thermal demagnetization revealed a high-temperature component, directed northeast or southwest with shallow inclinations, with unblocking temperatures of as high as 580 °C. Rock magnetism suggests the component is carried by single-domain and pseudo-single-domain magnetite grains. Its primary origin is supported by a positive reversal test and regional remanence direction correlation test, and the paleomagnetic pole (29.0°S, 64.7°E, A95 = 5.4°) is not similar to any published younger poles of the NCC. Matching the late Mesoproterozoic to early Neoproterozoic (ca. 1110–775 Ma) apparent polar wander paths of the NCC and Laurentia suggests that the NCC could have been the conjugate margin for northwestern Laurentia in Rodinia, rather than sitting off the northeast coast of the main Rodinian landmass. Geological data indicate that breakup of the NCC and Laurentia occurred between ca. 775 and 720 Ma.
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  • 32
    Publication Date: 2021-03-22
    Description: Circum-Arctic glacial ice is melting in an unprecedented mode, and release of currently trapped geological methane may act as a positive feedback on ice-sheet retreat during global warming. Evidence for methane release during the penultimate (Eemian, ca. 125 ka) interglacial, a period with less glacial sea ice and higher temperatures than today, is currently absent. Here, we argue that based on foraminiferal isotope studies on drill holes from offshore Svalbard, Norway, methane leakage occurred upon the abrupt Eurasian ice-sheet wastage during terminations of the last (Weichselian) and penultimate (Saalian) glaciations. Progressive increase of methane emissions seems to be first recorded by depleted benthic foraminiferal δ13C. This is quickly followed by the precipitation of methane-derived authigenic carbonate as overgrowth inside and outside foraminiferal shells, characterized by heavy δ18O and depleted δ13C of both benthic and planktonic foraminifera. The similarities between the events observed over both terminations advocate for a common driver for the episodic release of geological methane stocks. Our favored model is recurrent leakage of shallow gas reservoirs below the gas hydrate stability zone along the margin of western Svalbard that can be reactivated upon initial instability of the grounded, marine-based ice sheets. Analogous to this model, with the current acceleration of the Greenland ice melt, instabilities of existing methane reservoirs below and nearby the ice sheet are likely.
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  • 33
    Publication Date: 2021-03-22
    Description: Many Archean cratons exhibit Paleoproterozoic rifted margins, implying they were pieces of some ancestral landmass(es). The idea that such an ancient continental assembly represents an Archean supercontinent has been proposed but remains to be justified. Starkly contrasting geological records between different clans of cratons have inspired an alternative hypothesis where cratons were clustered in multiple, separate “supercratons.” A new ca. 2.62 Ga paleomagnetic pole from the Yilgarn craton of Australia is compatible with either two successive but ephemeral supercontinents or two long-lived supercratons across the Archean-Proterozoic transition. Neither interpretation supports the existence of a single, long-lived supercontinent, suggesting that Archean geodynamics were fundamentally different from subsequent times (Proterozoic to present), which were influenced largely by supercontinent cycles.
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  • 34
    Publication Date: 2021-04-01
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  • 35
    Publication Date: 2021-04-01
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  • 36
    Publication Date: 2021-03-24
    Description: The Indus Fan derives sediment from the western Himalaya and Karakoram. Sediment from International Ocean Discovery Program drill sites in the eastern part of the fan coupled with data from an industrial well near the river mouth allow the weathering history of the region since ca. 16 Ma to be reconstructed. Clay minerals, bulk sediment geochemistry, and magnetic susceptibility were used to constrain degrees of chemical alteration. Diffuse reflectance spectroscopy was used to measure the abundance of moisture-sensitive minerals hematite and goethite. Indus Fan sediment is more weathered than Bengal Fan material, probably reflecting slow transport, despite the drier climate, which slows chemical weathering rates. Some chemical weathering proxies, such as K/Si or kaolinite/(illite + chlorite), show no temporal evolution, but illite crystallinity and the chemical index of alteration do have statistically measurable decreases over long time periods. Using these proxies, we suggest that sediment alteration was moderate and then increased from 13 to 11 Ma, remained high until 9 Ma, and then reduced from that time until 6 Ma in the context of reduced physical erosion during a time of increasing aridity as tracked by hematite/goethite values. The poorly defined reducing trend in weathering intensity is not clearly linked to global cooling and at least partly reflects regional climate change. Since 6 Ma, weathering has been weak but variable since a final reduction in alteration state after 3.5 Ma that correlates with the onset of Northern Hemispheric glaciation. Reduced or stable chemical weathering at a time of falling sedimentation rates is not consistent with models for Cenozoic global climate change that invoke greater Himalayan weathering fluxes drawing down atmospheric CO2 but are in accord with the idea of greater surface reactivity to weathering.
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  • 38
    Publication Date: 2021-03-12
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  • 39
    Publication Date: 2021-03-26
    Description: Sedimentary pyrite formation links the global biogeochemical cycles of carbon, sulfur, and iron, which, in turn, modulate the redox state of the planet’s surficial environment over geological time scales. Accordingly, the sulfur isotopic composition (δ34S) of pyrite has been widely employed as a geochemical tool to probe the evolution of ocean chemistry. Characteristics of the depositional environment and post-depositional processes, however, can modify the δ34S signal that is captured in sedimentary pyrite and ultimately preserved in the geological record. Exploring sulfur and iron diagenesis within the Bornholm Basin, Baltic Sea, we find that higher sedimentation rates limit the near-surface sulfidization of reactive iron, facilitating its burial and hence the subsurface availability of reactive iron for continued and progressively more 34S-enriched sediment-hosted pyrite formation (δ34S ≈ –5‰). Using a diagenetic model, we show that the amount of pyrite formed at the sediment-water interface has increased over the past few centuries in response to expansion of water-column hypoxia, which also impacts the sulfur isotopic signature of pyrite at depth. This contribution highlights the critical role of reactive iron in pyrite formation and questions to what degree pyrite δ34S values truly reflect past global ocean chemistry and biogeochemical processes. This work strengthens our ability to extract local paleoenvironmental information from pyrite δ34S signatures.
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  • 40
    Publication Date: 2021-03-26
    Description: The Chinese loess-paleosol sequences provide important archives for studying paleoenvironmental changes. However, the lack of independent and accurate time scales hinders the study between loess and other records. Asian stalagmite δ18O records indicate synchronous patterns of paleoprecipitation δ18O over large geographic regions. The record of hydrogen isotopic composition of plant wax (δDwax) in Chinese loess is also controlled by rainwater δD. Both share a common origin. The linear relationship between rainfall δ18O and δD variance provides the basis to tie together chronologies of the same climate event in different records. Here, we show a new loess chronology by correlating chronologies of marker boundaries of the prominent climate chronozones in stalagmite δ18O and summer insolation to the equivalent climate stratigraphy in the loess δDwax sequence. We first developed and tested this novel methodology with data since the last interglacial on a millennial scale, and then applied this approach to the loess δDwax sequence for the past 800 k.y. to improve the traditional chronology based on magnetic susceptibility and grain size. The new δDwax time series provides not only an improved chronology for studying paleoclimate changes during interglacial intervals, it also represents a unique database with which to better understand the links between the Asian monsoon changes in the Chinese loess and other global climate events, especially for the periods prior to 640 ka, for which stalagmite records are not available.
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  • 41
    Publication Date: 2021-03-26
    Description: The terminal Mesoproterozoic was a period of widespread tectonic convergence globally, culminating in the amalgamation of the Rodinia supercontinent. However, in Laurentia, long-lived orogenesis on its eastern margin was punctuated by short-lived extension that generated the Midcontinent Rift ca. 1110–1090 Ma. Whereas this cratonic rift basin is typically considered an isolated occurrence, a series of new depositional ages demonstrate that multiple cratonic basins in northern Laurentia originated around this time. We present a Re-Os isochron date of 1087.1 ± 5.9 Ma from organic-rich shales of the Agu Bay Formation of the Fury and Hecla Basin, which is one of four closely spaced cratonic basins spanning from northeastern Canada to northwestern Greenland known as the Bylot basins. This age is identical, within uncertainty, to ages from the Midcontinent Rift and the Amundsen Basin in northwestern Canada. These ages imply that the late Mesoproterozoic extensional episode in Laurentia was widespread and likely linked to a common origin. We propose that significant thermal anomalies and mantle upwelling related to supercontinent assembly centered around the Midcontinent Rift influenced the reactivation of crustal weaknesses in Arctic Laurentia beginning ca. 1090 Ma, triggering the formation of a series of cratonic basins.
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  • 42
    Publication Date: 2021-03-30
    Description: The mechanisms and processes by which subducted slab interacted with mantle plume remain controversial, as direct observation of such interaction is difficult to impossible. Compositional heterogeneity of large igneous provinces (LIPs) additionally makes plume-slab interaction hard to detect. Oxygen isotopes are sensitive enough to trace the source of magmas. Here we provide evidence for plume-slab interaction mainly based on in situ zircon Hf-O isotope analyses, as well as whole-rock elemental and Sr-Nd-Hf isotope analyses, on the Late Permian and Early Triassic A-type granites on the margin of the Emeishan LIP in SW China. These granites show typical A-type geochemical characters, such as high total alkali (7.93−9.68 wt%) and field strength element (HFSE, e.g., Zr and Nb) contents, and high FeOT/(FeOT+MgO) (0.87−0.98) and Ga/Al (3.67−5.06) values. The Late Permian (ca. 259 Ma) and Early Triassic (ca. 248 Ma) granites show high Nb/Th (〉3.0) and low Y/Nb (
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  • 43
    Publication Date: 2021-03-17
    Description: The paleotopographic history of the North American Cordilleran orogen holds the key to understanding mechanisms of orogenesis and subsequent orogenic collapse. It has been suggested that the orogenic front in western Montana (USA) and Alberta (Canada) was more than 4 km high during Late Cretaceous−early Eocene contractional deformation and during the initial phase of extension in the middle Eocene; however, the late Eocene−Oligocene topographic evolution during continued extensional collapse remains poorly constrained. Here we extend the paleotopographic record in the Kishenehn Basin in northwestern Montana and southeastern British Columbia (Canada) to the late Oligocene by studying δ18O values of fossil mollusks and cement and paleosol carbonates. The molluscan taxa changed from three sympatric groups with preferred habitats ranging from tropical wet, semi-arid subtropical, and temperate during the middle and late Eocene, to mainly a single group associated with temperate environment during the Oligocene, reflecting a decline in molluscan biodiversity induced by climate cooling across the Eocene−Oligocene transition. Reconstructed δ18O values of alpine snowmelt and basinal precipitation decreased by 1.4‰ and 3.8‰, respectively, from the middle to late Eocene, reflecting climate cooling and ∼1 km surface uplift of the basin floor. The reconstructed alpine snowmelt δ18O values then increased by 2.9‰ in the Oligocene suggesting a ∼0.5 km drop in elevation of the orogenic front. Collectively, the results of our new and previously published δ18O data chronicle the paleotopographic response to the change from flat-slab subduction to slab rollback over a 45 m.y. period. These data suggest that the orogenic front was characterized by high elevation (〉4 km) in the ancestral Lewis-Clark-Livingston ranges during latest Cretaceous−early Eocene (ca. 75−52 Ma) contraction. The initial phase of extension related to the Kishenehn Basin created a lowland basin with a surface elevation of only ∼1.5 km during the early middle Eocene (ca. 46−44 Ma) whereas the ranges remained 〉4 km high. The high range elevations were sustained for at least 12 m.y. in the middle to late Eocene concurrent with extension, while the basin floor elevation was uplifted to ∼2.5 km by the latest Eocene (ca. 36−34 Ma). Basin aggradation can explain at most half of the 1 km basin floor uplift. The remaining amount (at least 0.5 km) and sustained high range elevation suggest that range denudation and crustal extension was compensated by the isostatic and thermal effects of slab rollback and/or passage of a slab window and infusion of hot asthenosphere beneath the continent. The range elevation in the orogenic front decreased ∼0.5 km by the late Oligocene (ca. 28 Ma), associated with a decrease in rock uplift rate associated with extension. A post-Oligocene elevation drop of ∼1 km resulted in both the ranges and basin floor reaching modern topography in the Kishenehn Basin drainage, likely due to the regional effect of Neogene Basin and Range extension. This study, along with the previous investigation of the Kishenehn Basin by Fan et al. (2017), are the first studies that systematically investigate paleorelief of the orogenic belt by reconstructing paleoelevations of the mountains and the basin at the same time. The results highlight that the Cordilleran orogenic front of northern Montana and southern British Columbia sustained its high elevation edifice for at least 12 m.y. after the start of extension. We suggest that initial crustal extension did not result in orogenic demise because of concurrent thermal and isostatic uplift.
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  • 44
    Publication Date: 2021-03-09
    Description: Strike-slip faults form in a wide variety of tectonic settings and are a first-order control on the geometry and sediment accumulation patterns in adjacent sedimentary basins. Although the structural and depositional architecture of strike-slip basins is well documented, few studies of strike-slip basins have integrated depositional age, lithofacies, and provenance control within this context. The Chumstick basin formed in central Washington during a regional phase of dextral, strike-slip faulting and episodic magmatism associated with Paleogene ridge-trench interaction along the North America margin. The basin is bounded and subdivided by major strike-slip faults that were active during deposition of the intra-basinal, non-marine Chumstick Formation. We build on the existing stratigraphy and present new, detailed lithofacies mapping, conglomerate clast counts (N = 16; n = 1429), and sandstone detrital zircon analyses (N = 16; n = 1360) from the Chumstick Formation to document changes in sediment provenance, routing, and deposition. These data allow us to reconstruct regional Eocene paleo-drainage systems of Washington and Oregon and suggest that drainage within the Chumstick basin fed a regional river system that flowed to a forearc or marginal basin on the newly accreted Siletzia terrane. More generally, excellent age control from five interbedded tuffs and high sediment accumulation rates allow us to track the evolving sedimentary system over the Formation’s ca. 4−5 m.y. depositional history. This is the first time lithofacies and provenance variations can be constrained at high temporal resolution (0.5−1.5 m.y. scale) for an ancient strike-slip basin and permits a detailed reconstruction of sediment routing pathways and depositional environments. As a result, we can assess how varying sediment supply and accommodation space affects the depositional architecture during strike-slip basin evolution.
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  • 45
    Publication Date: 2021-03-24
    Description: The western Transverse Ranges and southern Coast Ranges of California are lithologically similar but have very different styles and rates of Quaternary deformation. The western Transverse Ranges are deformed by west-trending folds and reverse faults with fast rates of Quaternary fault slip (1–11 mm/yr) and uplift (1–7 mm/yr). The southern Coast Ranges, however, are primarily deformed by northwest-trending folds and right-lateral strike-slip faults with much slower slip rates (3 mm/yr or less) and uplift rates (
    Electronic ISSN: 1553-040X
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  • 46
    Publication Date: 2021-04-01
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  • 47
    Publication Date: 2021-03-26
    Description: Gold (Au) is largely hosted by pyrite in a variety of hydrothermal systems, but the incorporation of Au into pyrite under disequilibrium conditions remains poorly understood. We integrate synchrotron X-ray fluorescence microscopy, electron backscatter diffraction, nanoscale secondary ion mass spectrometry, and laser ablation–multicollector–inductively coupled plasma–mass spectrometry to constrain the processes that sequester Au into zoned pyrite in the hydrothermal cement of breccia ores from the world-class Daqiao orogenic Au deposit, central China. Euhedral pyrite cores with oscillatory and sector zoning, variable δ34S values, and lower Au-As contents than the mantles are attributed to crystallization during oxidation of metal-depleted ore fluids with local variation in fluid conditions. The isotopically uniform colloform mantles are formed by pyrite crystallites separated by low-angle boundaries and are characterized by unusual decoupling of Au and As. Mantle formation is attributed to rapid disequilibrium precipitation from a metal-rich FeS2-supersaturated fluid. Incorporation of Au into the pyrite mantles was facilitated by abundant lattice defects produced by rapid nucleation. Gold-As–poor pyrite rims were deposited from an evolved ore fluid or other metal-depleted fluids. These results show that chemical variations recorded by fine layering within minerals can provide valuable insights into disequilibrium mass transfer and ore formation. The decoupling between Au and As in pyrite mantles indicates that As is not always a reliable proxy for Au enrichment in rapidly crystallized porous pyrite.
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  • 48
    Publication Date: 2021-03-26
    Description: Marine terraces are widespread along California’s coastline, including on all of the Channel Islands, with the possible exception of Santa Catalina. For over a century, the origins of subhorizontal surfaces and gravel deposits on Santa Catalina have been debated, with recent suggestions that Santa Catalina has no marine terraces and is subsiding. We mapped, measured, and described terrace deposits on Santa Catalina Island, including both in situ deposits and distributed gravel float. Rounded gravels and cobbles, locally pholad-bored, are present as float across low-relief surfaces in the Little Harbor area. We also mapped and described the Eagles Nest Gravels, an ~8-m-thick package overlying a broad bedrock-cut platform at ~200 m elevation and dipping 3.2° northward. The Eagles Nest Gravels contain rounded cobbles and boulders, many of which contain pholad borings. Two other platforms are inferred from concordant gravels with similar orientations but at lower elevations. Terrace deposits on Santa Catalina truncate underlying lithological units, including a narrow band of fossiliferous Miocene to Pliocene sands. Terrace deposits and gravel lag on Santa Catalina closely resemble older terrace deposits on other California Channel Islands. The terraces on Santa Catalina Island remain undated but document at least 200 m of net uplift, similar to the elevations of undated terraces on the other Channel Islands. While the timing of uplift of Santa Catalina is unclear, analysis of terrace deposits in the Little Harbor area confirms their marine origin and settles the debate regarding the presence of marine terraces on Santa Catalina Island.
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  • 49
    Publication Date: 2021-03-26
    Description: The Longmenshan Thrust Belt in Eastern Tibet resulted from a Mesozoic orogeny and Cenozoic reworking. It is generally believed that the Cenozoic tectonics along the Longmenshan Thrust Belt are mostly inherited from the Mesozoic. Reconstructing the Mesozoic tectonics of the Longmenshan Thrust Belt is therefore important for understanding its evolutionary history. On the basis of detailed structural analysis, we recognized a Main Central Boundary that divides the Longmenshan Thrust Belt into a Southeastern Zone and a Northwestern Zone. Both zones underwent a main D1 event characterized by D1E top-to-the-SE thrusting in the Southeastern Zone and D1W top-to-the-NW/N thrusting in the Northwestern Zone. In the Southeastern Zone, a D2 top-to-the-NW/N normal faulting that cuts the D1E structures is developed along the NW boundary of the basement complexes. Newly obtained and previous geochronological data indicate that the D1E and D1W events occurred synchronously at ca. 224−219 Ma, and the D2 top-to-the-NW/N normal faulting was episodically activated at ca. 166−160 Ma, 141−120 Ma, 81−47 Ma, and 27−25 Ma. Episodic and synchronously activated top-to-the-NW normal faulting and top-to-the-SE thrusting along the northwestern and southeastern boundaries of the basement complexes, respectively, leads us to propose that the basement slices were episodically imbricated to the SE during the Late Jurassic−Early Cretaceous and Late Cretaceous−earliest Paleocene. The D1 amphibolite facies metamorphic rocks above the basement complexes recorded fast exhumation during the Late Jurassic−Early Cretaceous. We propose that the early Mesozoic northwestward basement underthrusting along a crustal “weak zone” was responsible for the D1 double-vergent thrusting and amphibolite facies metamorphism. Subsequent basement-slice imbrications reworked the Longmenshan Thrust Belt and exhumed the amphibolite facies rocks. Our results highlight the importance of basement underthrusting and imbrication in the formation and reworking of the intracontinental Longmenshan Thrust Belt in Eastern Tibet.
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  • 50
    Publication Date: 2021-02-05
    Description: A lack of precise age constraints for Neoproterozoic strata in the northwestern United States (Washington State), including the Buffalo Hump Formation (BHF), has resulted in conflicting interpretations of Rodinia amalgamation and breakup processes. Previous detrital zircon (DZ) studies identified a youngest ca. 1.1 Ga DZ age population in the BHF, interpreted to reflect mostly first-cycle sourcing of unidentified but proximal magmatic rocks intruded during the amalgamation of Rodinia at ca. 1.0 Ga. Alternatively, the ca. 1.1 Ga DZ population has been suggested to represent a distal source with deposition occurring during the early phases of Rodinia rifting, more than 250 m.y. after zircon crystallization. We combined conventional laser-ablation split-stream analyses of U-Pb/Lu-Hf isotopes in zircon with a method of rapid (8 s per spot) U-Pb analysis to evaluate these opposing models. Our study of ~2000 DZ grains from the BHF identified for the first time a minor (~1%) yet significant ca. 760 Ma population, which constrains the maximum depositional age. This new geochronology implies that the BHF records early rift deposition during the breakup of Rodinia and correlates with sedimentary rocks found in other late Tonian basins of southwestern Laurentia.
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  • 51
    Publication Date: 2021-02-26
    Description: The formation and evolution of an intracontinental basin triggered via the subduction or collision of plates at continental margins can record intracontinental tectonic processes. As a typical intracontinental basin during the Jurassic, the Qaidam Basin in western China records how this extensional basin formed and evolved in response to distant subduction or collisional processes and tectonism caused by stresses transmitted from distant convergent plate margins. The Jurassic evolution of the Qaidam Basin, in terms of basin-filling architecture, sediment dispersal pattern and basin properties, remains speculative; hence, these uncertainties need to be revisited. An integrated study of the stratigraphic succession, conglomerates, U-Pb geochronology, and Hf isotopes of detrital zircons was adopted to elucidate the Jurassic evolutionary process of the Qaidam Basin. The results show that a discrete Jurassic terrestrial succession characterized by alluvial fan, braided stream, braided river delta, and lacustrine deposits developed on the western and northern margins of the Qaidam Basin. The stratigraphic succession, U-Pb age dating, and Hf isotope analysis, along with the reconstructed provenance results, suggest small-scale distribution of Lower Jurassic sediments deposited via autochthonous sedimentation on the western margin of the basin, with material mainly originating from the Altyn Tagh Range. Lower Jurassic sediments in the western segment of the northern basin were shed from the Qilian Range (especially the South Qilian) and Eastern Kunlun Range. And coeval sediments in the eastern segment of the northern basin were originated from the Quanji massif. During the Middle-Late Jurassic, the primary source areas were the Qilian Range and Eastern Kunlun Range, which fed material to the whole basin. The Jurassic sedimentary environment in the Qaidam Basin evolved from a series of small-scale, scattered, and rift-related depressions distributed on the western and northern margins during the Early Jurassic to a larger, extensive, and unified depression occupying the whole basin in the Middle Jurassic. The Altyn Tagh Range rose to a certain extent during the Early Jurassic but lacked large-scale strike-slip tectonism throughout the Jurassic. At that time, the North Qaidam tectonic belt had not yet been uplifted and did not shed material into the basin during the Jurassic. The Qaidam Basin experienced intracontinental extensional tectonism with a northeast-southwest trend throughout the Jurassic in response to far-field effects driven by the sequential northward or northeastward amalgamation of blocks to the southern margin of the Qaidam Block and successive accretion of the Qiangtang Block and Lhasa Block onto the southern Eurasian margin during the Late Triassic−Early Jurassic and Late Jurassic−Early Cretaceous, respectively.
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  • 52
    Publication Date: 2021-01-01
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  • 53
  • 54
    Publication Date: 2021-04-15
    Description: Constraining deep-water recycling along subduction zones is a first-order problem to understand how Earth has maintained a hydrosphere over billions of years that created conditions for a habitable planet. The pressure-temperature stability of hydrous phases in conjunction with slab geotherms determines how much H2O leaves the slab or is transported to the deep mantle. Chlorite-rich, metasomatic rocks that form at the slab-mantle interface at 50–100 km depth represent an unaccounted, H2O-rich reservoir in subduction processes. Through a series of high-pressure experiments, we investigated the fate of such chlorite-rich rocks at the most critical conditions for subduction water recycling (5–6.2 GPa, 620–800 °C) using two different natural ultramafic compositions. Up to 5.7 GPa, 740 °C, chlorite breaks down to an anhydrous peridotite assemblage, and H2O is released. However, at higher pressures and lower temperatures, a hydrous Al-rich silicate (11.5 Å phase) is an important carrier to enable water transfer to the deep mantle for cold subduction zones. Based on the new phase diagrams, it is suggested that the deep-water cycle might not be in secular equilibrium.
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  • 55
    Publication Date: 2021-04-15
    Description: Unintentional encounters with silicic magma at ~2–2.5 km depth have recently occurred during drilling at three volcanoes: Kilauea (Hawaii), Menengai (Kenya), and Krafla (Iceland). Geophysical surveys had failed to warn about shallow magma before each encounter, and subsequent surveys at Krafla have been unable to resolve the size or architecture of its silicic magma body. This presents a conundrum for volcano monitoring: Do such shallow “covert” magma bodies pose an eruption risk? Here, we show that Krafla’s most recent explosive eruption, a mixed hydrothermal-magmatic event in 1724 C.E. that formed the Víti maar, involved rhyolite essentially indistinguishable in composition from magma encountered during drilling in 2009. Streaks of quenched basalt in some Víti pumices provide direct evidence for interaction between co-erupted rhyolitic and basaltic magmas, but crystals in these pumices show no evidence for late-stage heating or re-equilibration with more mafic melt, implying mixing time scales of at most several hours. Covert silicic magma thus presents an eruption risk at Krafla and may be mobilized with little warning. Difficulties in resolving magma bodies smaller than ~1 km3 with geophysical surveys mean that covert silicic magma may exist at many other volcanoes and should be considered in hazard and risk assessments.
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  • 56
    Publication Date: 2021-04-15
    Description: Deep-sea carbonate deposition is a complex process that is encapsulated in the carbonate compensation depth (CCD)—a facies boundary separating calcareous sediments from non-carbonates. Knowing how the CCD has varied over time is important for understanding and predicting the distribution of seafloor sediments and assessing their role in the global carbon cycle. We focus on the South Atlantic Ocean where the most recent CCD curve is based on Deep Sea Drilling Project (DSDP) Leg 73 sites drilled in 1980 in the South Atlantic Ocean. We compute the South and central South Atlantic CCD from the Late Cretaceous to the present day using updated age models from 45 DSDP and Ocean Drilling Program sites and backtracking with lithology-specific decompaction, eustasy, and dynamic topography. Our models extend further back in time and show more fluctuations than previous reconstructions, with the CCD varying by hundreds of meters during a span of 2–3 m.y. The addition of eustasy and dynamic topography deepens the CCD by as much as 500 m between 74 Ma and 45 Ma, and by ~200 m during the Cenozoic. The central South Atlantic CCD diverges from the average South Atlantic CCD during the Eocene and Miocene, when it was ~1 km shallower. These regional deviations may be due to changes in primary productivity and/or carbonate dissolution leading to reduced carbonate accumulation rates. Our CCD curves highlight the importance of regional processes in carbonate deposition across the South Atlantic and provide improved constraints for the modeling of geochemical cycles.
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  • 57
    Publication Date: 2021-04-15
    Description: Both the duration and severity of deep-water anoxic conditions across the Permian-Triassic mass extinction (PTME) are controversial. Panthalassa Ocean circulation models yield varying results, ranging from a well-ventilated deep ocean to rapidly developing northern-latitude, but not southern-latitude, anoxia in response to Siberian Traps–driven global warming. To address this uncertainty, we examined a southern-paleolatitude pelagic record. Trace metal and pyrite framboid data suggest bottom-water euxinic conditions developed in the southern Panthalassa Ocean at the PTME, coincident with enhanced volcanic activity indicated by Hg geochemistry. While a global ocean euxinic event at the PTME placed extraordinary stress on marine life, southern surface waters appear to have recovered more quickly as radiolarian populations returned several million years before they did in northern Panthalassa.
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  • 58
    Publication Date: 2021-04-15
    Description: Ghost-dune hollows on the eastern Snake River Plain (ESRP), Idaho, USA, are topographically inverted, crescent-shaped depressions that record the partial encasement of sand dunes by ca. 61 ka basalt lava flows. Deflation of these “ghost” sand dunes produced approximately two dozen, 5–10-m-deep ghost-dune hollows now incompletely filled with pedogenically altered eolian and colluvial sediment. Optically stimulated luminescence (OSL) and 40Ar/39Ar ages constrain a ghost-dune hollow model that illuminates the late Pleistocene to Holocene environmental and climate history of the ESRP. Detrital zircon analyses indicate sand-dune supply routes changed following the burial of Pleistocene Henrys Fork (tributary of the Snake River) alluvium by ca. 70 ka basalt flows. Removal of Henrys Fork alluvium from the eolian supply system made Lake Terreton sediment the primary source for later ESRP sand dunes. Such sediment supply changes highlight the potential impacts of effusive volcanism on sand-dune histories and landscapes. Our results support stratigraphic and sedimentary modeling of comparable ghost-dune “pit” deposits older than ca. 2 Ga on Mars that may have served as refugia for early life on that planet. Analogous ancient ghost-dune hollow deposits on Earth may also have served as early life refugia.
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  • 59
    Publication Date: 2021-04-08
    Description: Sedimentary rock deposits provide the best records of (bio)geochemical cycles in the ancient ocean. Studies of these sedimentary archives show that greenalite, an Fe(II) silicate with low levels of Fe(III), was an early chemical precipitate from the Archean ocean. To better understand the formation of greenalite, we explored controls on iron silicate precipitation through experiments in simulated Archean seawater under exclusively ferrous conditions or supplemented with low Fe(III). Our results confirm a pH-driven process promoting the precipitation of iron-rich silicate phases, and they also reveal an important mechanism in which minor concentrations of Fe(III) promote the precipitation of well-ordered greenalite among other phases. This discovery of an Fe(III)-triggering iron silicate formation process suggests that Archean greenalite could represent signals of iron oxidation reactions, potentially mediated by life, in circumneutral ancient seawater.
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  • 60
    Publication Date: 2021-04-15
    Description: The world-renowned Miocene Clarkia paleolake in northern Idaho (USA) is closely associated with Columbia River Basalt Group volcanism. The flood basalt dammed a local drainage system to form the paleolake, which preserved a plant fossil Lagerstätte in its deposits. However, the precise age and temporal duration of the lake remain unsettled. We present the first unequivocal U-Pb zircon ages from interbedded volcanic ashes at the P-33 type location, constraining the deposition to 15.78 ± 0.039 Ma. Using micro–X-ray fluorescence and petrographic and spectral analyses, we establish the annual characteristics of laminations throughout the stratigraphic profile using the distribution of elemental ratios, mineral assemblages, and grain-size structures, as well as organic and fossil contents. Consequently, the ~7.5-m-thick varved deposit at the type location P-33 represents ~840 yr of deposition, coincident with the end of the main phase of Columbia River Basalt Group eruptions during the Miocene Climate Optimum. The timing and temporal resolution of the deposit offer a unique opportunity to study climate change in unprecedented detail during global warming associated with carbon-cycle perturbations.
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  • 61
    Publication Date: 2021-05-01
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  • 62
    Publication Date: 2021-04-26
    Description: High-grade metamorphic rocks and crustal melts provide crucial evidence for growth and differentiation of the continental crust, and are widespread in collisional orogens. However, their importance in the evolution of continental arcs remains poorly understood. Metamorphism and related anatexis in the preserved continental margin of the Neo-Tethys ocean serves as a key natural laboratory to investigate this process. Along the Neo-Tethyan arc margin, the Gaoligong shear zone, Yunnan region of China, is an important locality for linking Lhasa in the north with Sibumasu and Burma in the south. Here, Late Cretaceous granulite-facies metamorphism and crustal anatexis have been identified for the first time in the Gaoligong area. Zircon and monazite U-Pb dating indicates that S-type granites formed at 87−73 Ma, granites and buried pelitic sediments were simultaneously metamorphosed at 75−70 Ma during Neo-Tethyan subduction, and all lithologies were overprinted by a younger 40−30 Ma magmatic and strike-slip event related to India-Asia collision. Phase equilibria modeling of high-grade anatectic gneiss in the MnO-Na2O-CaO-K2O-FeO-MgO-Al2O3-SiO2-H2O-TiO2 system indicates peak pressure-temperature (P−T) conditions of 780−800 °C and 6.5−7.5 kbar and defines a cooling and decompressional P−T path for the metapelites. This demonstrates that sediments within the Neo-Tethyan active continental arc were buried to 〉20 km depth at 75−70 Ma. In combination with the metamorphic record of the Lhasa, Burma, and Sibumasu blocks, an extensive Late Cretaceous metamorphic belt must have formed along the Neo-Tethyan subduction zone. This spatially correlates with coeval gabbro-diorite suites exposed in the Gangdese, Sibumasu and Burma terranes that were triggered by thinning of the lithospheric mantle. This prolonged Late Cretaceous mantle-derived magmatism and lithospheric thinning may have provided a regional-scale heat source for high-grade metamorphism and crustal anatexis along the active continental margin of the Neo-Tethys ocean.
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  • 63
    Publication Date: 2021-04-27
    Description: The Lower Permian tillites of the Beacon Supergroup, cropping out in Victoria Land (Antarctica), record climatic history during one of the Earth’s coldest periods: the Late Paleozoic Ice Age. Reconstruction of ice-extent and paleo-flow directions, as well as geochronological and petrographic data, are poorly constrained in this sector of Gondwana. Here, we provide the first detrital zircon U-Pb age analyses of both the Metschel Tillite in southern Victoria Land and some tillites correlatable with the Lanterman Formation in northern Victoria Land to identify the source regions of these glaciogenic deposits. Six-hundred detrital zircon grains from four diamictite samples were analyzed using laser ablation−inductively coupled plasma−mass spectrometry. Geochronological and petrographic compositional data of the Metschel Tillite indicate a widespread reworking of older Devonian Beacon Supergroup sedimentary strata, with minor contribution from Cambro-Ordovician granitoids and meta-sedimentary units as well as Neoproterozoic metamorphic rocks. Euhedral to subhedral Carboniferous−Devonian zircon grains match coeval magmatic units of northern Victoria Land and Marie Byrd Land. This implies, in accordance with published paleo-ice directions, a provenance from the east-southeast sectors. In contrast, the two samples from northern Victoria Land tillite reflect the local basement provenance; their geochronological age and petrographic composition indicates a restricted catchment area with multiple ice centers. This shows that numerous ice centers were present in southern Gondwana during the Late Paleozoic Ice Age. While northern Victoria Land hosted discrete glaciers closely linked with the northern Victoria Land-Tasmania ice cap, the west-northwestward flowing southern Victoria Land ice cap contributed most of the sediments comprising the Metschel Tillite.
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  • 64
    Publication Date: 2021-03-08
    Description: Assigning correct protolith to high metamorphic-grade core zone rocks of large hot orogens is a particularly important challenge to overcome when attempting to constrain the early stages of orogenic evolution and paleogeography of lithotectonic units from these orogens. The Gurla Mandhata core complex in NW Nepal exposes the Himalayan metamorphic core (HMC), a sequence of high metamorphic-grade gneiss, migmatite, and granite, in the hinterland of the Himalayan orogen. Sm-Nd isotopic analyses indicate that the HMC comprises Greater Himalayan sequence (GHS) and Lesser Himalayan sequence (LHS) rocks. Conventional interpretation of such provenance data would require the Main Central thrust (MCT) to be also outcropping within the core complex. However, new in situ U-Th/Pb monazite petrochronology coupled with petrographic, structural, and microstructural observations reveal that the core complex is composed solely of rocks in the hanging wall of the MCT. Rocks from the core complex record Eocene and late Oligocene to early Miocene monazite (re-)crystallization periods (monazite age peaks of 40 Ma, 25–19 Ma, and 19–16 Ma) overprinting pre-Himalayan Ordovician Bhimphedian metamorphism and magmatism (ca. 470 Ma). The combination of Sm-Nd isotopic analysis and U-Th/Pb monazite petrochronology demonstrates that both GHS and LHS protolith rocks were captured in the hanging wall of the MCT and experienced Cenozoic Himalayan metamorphism during south-directed extrusion. Monazite ages do not record metamorphism coeval with late Miocene extensional core complex exhumation, suggesting that peak metamorphism and generation of anatectic melt in the core complex had ceased prior to the onset of orogen-parallel hinterland extension at ca. 15–13 Ma. The geometry of the Gurla Mandhata core complex requires significant hinterland crustal thickening prior to 16 Ma, which is attributed to ductile HMC thickening and footwall accretion of LHS protolith associated with a Main Himalayan thrust ramp below the core complex. We demonstrate that isotopic signatures such as Sm-Nd should be used to characterize rock units and structures across the Himalaya only in conjunction with supporting petrochronological and structural data.
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  • 65
    Publication Date: 2021-02-05
    Description: The Kalatage inlier in the Dananhu-Haerlik arc is one of the most important arcs in the Eastern Tianshan, southern Altaids (or Central Asian orogenic belt). Based on outcrop maps and core logs, we report 16 new U-Pb dates in order to reconstruct the stratigraphic framework of the Dananhu-Haerlik arc. The new U-Pb ages reveal that the volcanic and intrusive rocks formed in the interval from the Ordovician to early Permian (445–299 Ma), with the oldest diorite dike at 445 ± 3 Ma and the youngest rhyolite at 299 ± 2 Ma. These results constrain the ages of the oldest basaltic and volcaniclastic rocks of the Ordovician Huangchaopo Group, which were intruded by granite- granodiorite-diorite plutons in the Late Ordovician to middle Silurian (445–426 Ma). The second oldest components are intermediate volcanic and volcaniclastic rocks of the early Silurian Hongliuxia Formation (S1h), which lies unconformably on the Huangchaopo Group and is unconformably overlain by Early Devonian volcanic rocks (416 Ma). From the mid- to late Silurian (S2-3), all the rocks were exhumed, eroded, and overlain by polymictic pyroclastic deposits. Following subaerial to shallow subaqueous burial at 416–300 Ma by intermediate to felsic volcanic and volcaniclastics rocks, the succession was intruded by diorites, granodiorites, and granites (390–314 Ma). The arc volcanic and intrusive rocks are characterized by potassium enrichment, when they evolved from mafic to felsic and from tholeiitic via transitional and calc-alkaline to final high-K calc- alkaline compositions with relatively low initial Sr values, (87Sr/86Sr)i = 0.70391–0.70567, and positive εNd(t) values, +4.1 to +9.2. These new data suggest that the Dananhu-Haerlik arc is a long-lived arc that consequently requires a new evolutionary model. It began as a nascent (immature) intra-oceanic arc in the Ordovician to early Silurian, and it evolved into a mature island arc in the middle Silurian to early Permian. The results suggest that the construction of a juvenile-to-mature arc, in combination with its lateral attachment to an incoming arc or continent, was an important crustal growth mechanism in the southern Altaids.
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  • 66
    Publication Date: 2021-04-28
    Description: Recent reconstructions of global plate motions suggest that the Izanagi-Pacific Ridge was subducted along the eastern margin of Eurasia at ca. 50 Ma. In the Hidaka magmatic zone (HMZ), which was located at the northeastern end of the Eurasian plate, three magmatic pulses occurred (46–45, 40–36, and 19–18 Ma). We report whole-rock geochemical and Sr-Nd-Pb isotopic data for 36 Ma high-Sr/Y (adakitic) rocks from the HMZ and show that these rocks formed by partial melting of oceanic crust and were emplaced as near-trench intrusions during ridge subduction. We reevaluate the nature of plutonic rocks in the HMZ and show that both the 46–45 and 40–36 Ma granitoids have essentially identical geochemical features. The distribution of plutons and magmatic cessation between 45 and 40 Ma are best explained by subduction of a ridge-transform intersection with a large offset of the ridge axis. The boundary between the Eocene granitoids corresponds to the position of a paleo–transform fault, and adakitic magmatism was caused by partial melting triggered by slab tearing at an overlapping spreading center. The paleoridge-transform configuration coincides with the locations of later large faults and a peridotite body.
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  • 67
    Publication Date: 2021-04-28
    Description: Fault damage zones strongly influence fluid flow and seismogenic behavior of faults and are thought to scale linearly with fault displacement until reaching a threshold thickness. Using analog modeling with different frictional layer thicknesses, we investigate damage zone dynamic evolution during normal fault growth. We show that experimental damage zone growth with displacement is not linear but progressively tends toward a threshold thickness, being larger in the thicker models. This threshold thickness increases significantly at fault segment relay zones. As the thickness threshold is approached, the failure mode progressively transitions from dilational shear to isochoric shear. This process affects the whole layer thickness and develops as a consequence of fault segment linkage as inferred in nature when the fault matures. These findings suggest that fault damage zone widths are limited both by different scales of mechanical unit thickness and the evolution of failure modes, ultimately controlled in nature by lithology and deformation conditions.
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  • 68
    Publication Date: 2021-04-28
    Description: Establishing how past climate change affected the stability of marine methane hydrate is important for our understanding of the impact of a future warmer world. As oceans shallow toward continental margins, the base of the hydrate stability zone also shallows, and this delineates the feather edge of marine methane hydrate. It is in these rarely documented settings that the base of the hydrate stability zone intersects the seabed and hydrate can crop out where it is close to being unstable and most susceptible to dissociation due to ocean warming. We show evidence for a seismically defined outcrop zone intersecting canyons on a canyon-incised margin offshore of Mauritania. We propose that climatic, and hence ocean, warming since the Last Glacial Maximum as well as lateral canyon migration, cutting, and filling caused multiple shifts of the hydrate stability field, and therefore hydrate instability and likely methane release into the ocean. This is particularly significant because the outcrop zone is longer on canyon-incised margins than on less bathymetrically complex submarine slopes. We propose considerably more hydrate will dissociate in these settings during future ocean warming, releasing methane into the world’s oceans.
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  • 69
    Publication Date: 2021-02-05
    Description: Suprasubduction zone (SSZ) ophiolites of the northern Appalachians (eastern North America) have provided key constraints on the fundamental tectonic processes responsible for the evolution of the Appalachian orogen. The central and southern Appalachians, which extend from southern New York to Alabama (USA), also contain numerous ultra- mafic-mafic bodies that have been interpreted as ophiolite fragments; however, this interpretation is a matter of debate, with the origin(s) of such occurrences also attributed to layered intrusions. These disparate proposed origins, alongside the range of possible magmatic affinities, have varied potential implications for the magmatic and tectonic evolution of the central and southern Appalachian orogen and its relationship with the northern Appalachian orogen. We present the results of field observations, petrography, bulk-rock geochemistry, and spinel mineral chemistry for ultramafic portions of the Baltimore Mafic Complex, which refers to a series of ultramafic-mafic bodies that are discontinuously exposed in Maryland and southern Pennsylvania (USA). Our data indicate that the Baltimore Mafic Complex comprises SSZ ophiolite fragments. The Soldiers Delight Ultramafite displays geochemical characteristics—including highly depleted bulk-rock trace element patterns and high Cr# of spinel—characteristic of subduction-related mantle peridotites and serpentinites. The Hollofield Ultramafite likely represents the “layered ultramafics” that form the Moho. Interpretation of the Baltimore Mafic Complex as an Iapetus Ocean–derived SSZ ophiolite in the central Appalachian orogen raises the possibility that a broadly coeval suite of ophiolites is preserved along thousands of kilometers of orogenic strike.
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  • 70
    Publication Date: 2021-02-05
    Description: The Permian marine-terrestrial system of the North China block provides an exceptional window into the evolution of northern temperate ecosystems during the critical transition from icehouse to greenhouse following the late Paleozoic ice age (LPIA). Despite many studies on its rich hydrocarbon reserves and climate-sensitive fossil flora, uncertain temporal constraints and correlations have hampered a thorough understanding of the records of geologic, biologic, and climatic change from the North China block. We present a new chronostratigraphy based on high-precision U-Pb chemical abrasion–isotope dilution–thermal ionization mass spectrometry (CA-ID-TIMS) geochronology of tuffs from a near-complete latest Carboniferous–Permian succession in North China. The results indicate that the predominance of continental red beds, climate aridification, and the disappearance of coals and characteristic tropical flora were well under way during the Cisuralian (Early Permian) in the North China block, significantly earlier than previously thought. A nearly 20 m.y. hiatus spanning the early Kungurian to the mid-Guadalupian (or later) is revealed in the northern North China block to have close temporal and spatial associations with the closure and/or subduction of the Paleo-Asian Ocean and its related tectonic convergence. This long hiatus was concomitant with the prominent loss of the highly diverse and abundant Cathaysian floras and the widespread invasion of the monotonous Angaran floras under arid climate conditions in the North China block. Similarities in the floral and climate shift histories between Euramerica and North China suggest that aside from the regional tectonic controls and continental movement, extensive volcanism during the Cisuralian may have played a major role in the global warming and aridification in the aftermath of the LPIA.
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  • 71
    Publication Date: 2021-04-08
    Description: The type and volume of sediment entering subduction zones affects the style of plate-boundary deformation and thus sedimentary and tectonic cycles. Because submarine channels significantly increase the transport efficiency of turbidity currents, their presence or absence in subduction trenches is a primary control on trench fill. To date, comprehensive architectural characterization of trench-axial channels has not been possible, undermining efforts to identify the factors controlling their initiation and evolution. Here, we describe the evolution of the Hikurangi Channel, which traverses the Hikurangi Trench, offshore New Zealand. Analysis of two- and three-dimensional seismic data reveals that the channel was present only during the last ~3.5 m.y. of the ~27 m.y. of the trench’s existence; its inception and propagation resulted from increased sediment supply to the trench following amplified hinterland exhumation. To test if the controls on the evolution of the Hikurangi Channel are universal, multivariate statistical analysis of the geomorphology of subduction trenches globally is used to investigate the formative conditions of axial channels in modern trenches. Terrigenous sediment supply and thickness of sediment cover in a trench are the dominant controls; subsidiary factors such as trench length and rugosity also contribute to the conditions necessary for trench-axial channel development. Axial channels regulate sediment distribution in trenches, and this varies temporally and spatially as a channel propagates along a trench. The presence of a trench-axial channel affects plate-boundary mechanics and has implications for the style of subduction-margin deformation.
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  • 72
    Publication Date: 2021-04-02
    Description: Continental sedimentation was widespread across the Central Anatolian Plateau in Miocene–Pliocene time, during the early stages of plateau uplift. Today, however, most sediment produced on the plateau is dispersed by a well-integrated drainage and released into surrounding marine depocenters. Residual long-term (106–107 yr) sediment storage on the plateau is now restricted to a few closed catchments. Lacustrine sedimentation was widespread in the Miocene–Pliocene depocenters. Today, it is also restricted to the residual closed catchments. The present-day association of closed catchments, long-term sediment storage, and lacustrine sedimentation suggests that the Miocene–Pliocene sedimentation also occurred in closed catchments. The termination of sedimentation across the plateau would therefore mark the opening of these closed catchments, their integration, and the formation of the present-day drainage. By combining newly dated volcanic markers with previously dated sedimentary sequences, we show that this drainage integration occurred remarkably rapidly, within 1.5 m.y., at the turn of the Pliocene. The evolution of stream incision documented by these markers and newly obtained 10Be erosion rates allow us to discriminate the respective con­tributions of three potential processes to drainage integration, namely, the capture of closed catch­ments by rivers draining the outer slopes of the plateau, the overflow of closed lakes, and the avul­sion of closed catchments. Along the southern plateau margin, rivers draining the southern slope of the Central Anatolian Plateau expanded into the plateau interior; however, only a small amount of drainage integration was achieved by this process. Instead, avulsion and/or overflow between closed catchments achieved most of the integration, and these top-down processes left a distinctive sedi­mentary signal in the form of terminal lacustrine limestone sequences. In the absence of substantial regional climate wetting during the early Pliocene, we propose that two major tectonic events triggered drainage inte­gration, separately or in tandem: the uplift of the Central Anatolian Plateau and the tectonic com­pletion of the Anatolian microplate. Higher surface uplift of the eastern Central Anatolian Plateau relative to the western Central Anatolian Plateau promoted more positive water balances in the eastern catchments, higher water discharge, and larger sediment fluxes. Overflow/avulsion in some of the eastern catchments triggered a chain of avulsions and/or overflows, sparking sweeping integration across the plateau. Around 5 Ma, the inception of the full escape of the Anatolian microplate led to the disruption of the plateau surface by normal and strike-slip faults. Fault scarps partitioned large catchments fed by widely averaged sediment and water influxes into smaller catchments with more contrasted water balances and sediment fluxes. The evolution of the Central Anatolian Plateau shows that top-down processes of integration can outcompete erosion of outer plateau slopes to reintegrate plateau interior drainages, and this is overlooked in current models, in which drainage evolution is dominated by bottom-up integration. Top-down integration has the advantage that it can be driven by more subtle changes in climatic and tectonic boundary conditions than bottom-up integration.
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  • 73
    Publication Date: 2021-04-08
    Description: The Curiosity rover is exploring Hesperian-aged stratigraphy in Gale crater, Mars, where a transition from clay-bearing units to a layered sulfate-bearing unit has been interpreted to represent a major environmental transition of unknown character. We present the first description of key facies in the sulfate-bearing unit, recently observed in the distance by the rover, and propose a model for changes in depositional environments. Our results indicate a transition from lacustrine mudstones into thick aeolian deposits, topped by a major deflation surface, above which strata show architectures likely diagnostic of a subaqueous environment. This model offers a reference example of a depositional sequence for layered sulfate-bearing strata, which have been identified from orbit in other locations globally. It differs from the idea of a monotonic Hesperian climate change into long-term aridity on Mars and instead implies a period characterized by multiple transitions between sustained drier and wetter climates.
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  • 74
    Publication Date: 2021-02-22
    Description: Sanidine dating and magnetostratigraphy constrain the timing of integration of the lower Colorado River (southwestern United States and northern Mexico) with the evolving Gulf of California. The Colorado River arrived at Cottonwood Valley (Nevada and Arizona) after 5.24 Ma (during or after the Thvera subchron). The river reached the proto–Gulf of California once between 4.80 and 4.63 Ma (during the C3n.2r subchron), not at 5.3 Ma and 5.0 Ma as previously proposed. Duplication of section across newly identified strands of the Earthquake Valley fault zone (California) probably explains the discrepancy. The data also imply the start of focused plate motion and basin development in the Salton Trough (California) at 6–6.5 Ma and relative tectonic stability of the southernmost part of the lower Colorado River corridor after its integration. After integration, the Colorado River quickly incised through sediment-filled basins and divides between them as it also likely excavated Grand Canyon (Arizona). The liberated sediment from throughout the system led to deposition of hundreds of meters of Bullhead Alluvium downstream of Grand Canyon after 4.6 Ma as the river adjusted to its lower base level.
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  • 75
    Publication Date: 2021-02-22
    Description: In an area of elevated nitrate (NO3) groundwater concentrations in the northern Chihuahuan Desert in central New Mexico (United States), a large reservoir of nitrate was found in the subsoil of an arroyo floodplain. Nitrate inventories in the floodplain subsoils ranged from 10,000 to 38,000 kg NO3-N/ha—over twice as high as any previously measured arid region. The floodplain subsoil NO3 reservoir was over 100 times higher than the adjacent desert (59–95 kg NO3-N/ha). Chloride mass balance calculations of subsoils indicate arroyo floodplain subsoils have undergone negative recharge since 2600–8600 yr ago, while the surrounding desert has had negative recharge since 13,000–17,000 yr ago. Compared to the adjacent desert, plant communities are larger and more abundant in the floodplain, though subsoil NO3 is apparently not utilized. We demonstrate that NO3 accumulates in the subsoil of the floodplain through evaporation of monsoon season precipitation funneled into the arroyo. Through a one-dimensional vadose zone model, we show that the NO3 inventories in the arroyo floodplain could be acquired 8 to 75 times faster than through atmospheric deposition through the lateral movement
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  • 76
    Publication Date: 2021-02-22
    Description: Subsurface salt movement in the absence of external tectonic forces can affect contemporaneous sediment deposition, mask allocyclic signals, and deform older strata. We used a discrete element model (DEM) to better understand salt-related modification of a sedimentary sequence with an increasing sedimentation rate. This permitted quantification of thinning rates and analysis of the lateral extent of synkinematic layers. Results show realistic evolution of salt-related faults, defining two salt-withdrawal basins, beyond which strata are undeformed. Thinning of stratigraphy is four times greater between the salt flank and crest than between the undeformed zone and flank, confirming an intense zone of halokinetic modulation adjacent to the diapir. Early, slowly aggrading layers are isolated within the salt-withdrawal basin and strongly influenced by salt growth, whereas later, quickly aggrading layers are more laterally extensive, matching inferences made from subsurface and outcrop data. Halokinetic modulation reduces up the stratigraphic section, mirroring observations around the Pierce diapirs, in the North Sea, offshore UK. Our DEM provides quantitative insights into the dynamic interplay between halokinetic and allocyclic controls on salt-stratigraphic relationships.
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  • 77
    Publication Date: 2021-02-22
    Description: Soft-bodied fossils of Cambrian age, now known as Burgess Shale–type biotas, were first described from the Parker Slate of the northwest Vermont (USA) slate belt in the late 19th century, 25 years before the discovery of the Burgess Shale in British Columbia, Canada. Here, we report the rediscovery of fossiliferous horizons at Parker’s Cobble, the site of the original quarry, which was thought to have been exhausted by excavation. New discoveries include a radiodont, multiple specimens of a new bivalved arthropod, a priapulid, and other undescribed forms. Pervasive soft-sediment deformation suggests accumulation near the toe of a steep unstable slope, similar to the setting of the Burgess Shale. Although fossils are rare, the exceptional preservation of some soft-bodied taxa suggests that recovered diversity was limited by transport into an inhospitable benthic setting rather than by decay, and this implies a potential for future discoveries of new taxa.
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  • 78
    Publication Date: 2021-02-22
    Description: The abundance of dolomitic strata in the geological record contrasts with the general rarity of locations where dolomite forms today, a discrepancy that has long posed a problem for their interpretation. Recent culture experiments show that dolomite can precipitate at room temperature, raising the possibility that many ancient dolomites may be of syngenetic origin. We compiled a large geodata set of secular variations in dolomite abundance in the Phanerozoic, coupled with compilations of genus richness of marine benthic invertebrates and sulfur-isotope variations in marine carbonates. These data show that dolomite abundance is negatively correlated to genus diversity, with four dolomite peaks occurring during mass extinctions. Dolomite peaks also correspond to the rapid increase in sulfur-isotope composition (δ34S), an indicator of enhanced sulfate reduction, in anoxic oceans. These results confirm that variations in dolomite abundance during the Phanerozoic were closely linked with changes in marine benthic diversity, with both in turn related to oceanic redox conditions.
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  • 79
    Publication Date: 2021-02-22
    Description: The sensitivity of plant carbon isotope fractionation (13Δleaf) to changes in atmospheric CO2 concentrations (Ca) is the subject of heavy debate, with some studies finding no sensitivity, while others show a strong dependency. We tested the hypothesis of photosynthetic homeostasis by using δ13C of n-alkanes, cuticles, and bulk organic matter of gymnosperm-rich rocks (Arundel Clay) from two sites deposited during the Aptian, a time that experienced significant Ca variations. Our results show no effect of Ca on 13Δleaf, and a relatively constant Ci/Ca (0.64 ± 0.04, 1σ; i—intercellular space), a value that is similar to that of modern gymnosperms. These results suggest that Aptian gymnosperms used homeostatic adjustments with rising Ca, probably involving increased carbon assimilation and/or stomatal closure, a response also found in modern gymnosperms. The similarity between Aptian and modern gymnosperms suggests that the processes responsible for regulating CO2 and water vapor exchange during photosynthesis have remained unaltered in gymnosperms for the past 128 m.y.
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  • 80
    Publication Date: 2021-02-22
    Description: Subduction erosion is important for crustal material recycling and is widespread in modern active convergent margins. However, such a process is rarely identified in fossil convergent systems, which casts doubt on the importance of subduction erosion through the geological record. We report on ca. 155 Ma Kangqiong (pluton) intrusive rocks of a Mesozoic magmatic arc in the southern Qiangtang terrane, central Tibet. These rocks mainly consist of trondhjemites and tonalites and are similar to slab-derived adakites with mantle-like zircon oxygen isotope compositions (δ18O = 5.2‰–5.6‰), they display more evolved Sr-Nd isotopes and higher Th/La relative to mid-oceanic ridge basalts from the Bangong-Nujiang suture, and they contain abundant amphibole and biotite. These characteristics indicate magma generation via H2O-fluxed melting of eroded forearc crust debris with subducted oceanic crust at 1.5–2.5 GPa and 700–800 °C. In addition, the intrusions are exposed
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  • 81
    Publication Date: 2021-02-22
    Description: River incision into bedrock drives landscape evolution and couples surface changes to climate and tectonics in uplands. Mechanistic bedrock erosion modeling has focused on plucking—the hydraulic removal of large loosened rock fragments—and on abrasion—the slower fracturing-driven removal of rock due to impacts of transported sediment—which produces sand- or silt-sized fragments at the mineral grain scale (i.e., wear). An abrasion subregime (macro-abrasion) has been hypothesized to exist under high impact energies typical of cobble or boulder transport in mountain rivers, in which larger bedrock fragments can be generated. We conducted dry impact abrasion experiments across a wide range of impact energies and found that gravel-sized fragments were generated when the impact energy divided by squared impactor diameter exceeded 1 kJ/m2. However, the total abraded volume followed the same kinetic-energy scaling regardless of fragment size, holding over 13 orders of magnitude in impact energy and supporting a general abrasion law. Application to natural bedrock rivers shows that many of them likely can generate large fragments, especially in steep mountain streams and during large floods, transporting boulders in excess of 0.6 m diameter. In this regime, even single impacts can cause changes in riverbed topography that may drive morphodynamic feedbacks.
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  • 82
    Publication Date: 2021-02-22
    Description: The Fairweather fault (southeastern Alaska, USA) is Earth’s fastest-slipping intracontinental strike-slip fault, but its long-term role in localizing Yakutat–(Pacific–)North America plate motion is poorly constrained. This plate boundary fault transitions northward from pure strike slip to transpression where it comes onshore and undergoes a 6–8 km/m.y. exhumation rates that increases in age away from the bend. We interpret this migration of rapid, transient exhumation to reflect prolonged advection of the Cenozoic–Cretaceous sedimentary cover of the eastern Yakutat microplate through a stationary restraining bend along the edge of the North America plate. Yakutat cooling ages imply a long-term strike-slip rate (54 ± 6 km/m.y.) that mimics the millennial (53 ± 5 m/k.y.) and decadal (46 mm/yr) rates. Fairweather fault slip can account for all Pacific–North America relative plate motion throughout Quaternary time and indicates stability of highly localized plate boundary strike slip on a single fault where extreme rock uplift rates are persistently localized within a restraining bend.
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  • 83
    Publication Date: 2021-04-22
    Description: The Orocopia Schist and related schists are sediments subducted during the Laramide orogeny and are thought to have been underplated as a laterally extensive layer at the base of the crust in the southwestern United States Cordillera. This concept is hard to reconcile with the existence of continental mantle lithosphere in southeastern California and western Arizona. Analytical solutions and numerical modeling suggest that the Orocopia Schist may have ascended through the mantle lithosphere as sediment diapirs or subsolidus crustal plumes to become emplaced in the middle to lower crust. Modeled time-temperature cooling paths are consistent with the exhumation history of the Orocopia Schist and explain an initial period of rapid cooling shortly after peak metamorphism. The Orocopia Schist represents a potential example of relaminated sediment observable at the surface.
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  • 84
    Publication Date: 2021-04-22
    Description: The Namche Barwa syntaxis in the eastern Himalaya is rapidly evolving in terms of its tectonics and topography. Here we constrain the exhumation history of the Yigong River to the immediate north of the syntaxis across different time scales using a multidisciplinary approach. Our new thermochronometric data reveal an acceleration of exhumation rates since 2 Ma in the downstream of the Yigong. Cosmogenic nuclides and thermoluminescence thermochronometry analyses confirm persistent rapid exhumation in the lower Yigong over the Quaternary with further increased exhumation in the last 100 ka. Together with the analysis of the morphology of the Yigong River profile, we interpret that northward expansion of the syntaxis together with capture of the Yigong by the Yarlung Tsangpo River during this expansion is responsible for the exhumation history of the Yigong River in the Quaternary.
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  • 85
    Publication Date: 2021-04-22
    Description: The Acadian and Neoacadian orogenies are widely recognized, yet poorly understood, tectono-thermal events in the New England Appalachian Mountains (USA). We quantified two phases of Paleozoic crustal thickening using geochemical proxies. Acadian (425–400 Ma) crustal thickening to 40 km progressed from southeast to northwest. Neoacadian (400–380 Ma) crustal thickening was widely distributed and varied by 30 km (40–70 km) from north to south. Doubly thickened crust and paleoelevations of 5 km or more support the presence of an orogenic plateau at ca. 380–330 Ma in southern New England. Neoacadian crustal thicknesses show a strong correlation with metamorphic isograds, where higher metamorphic grade corresponds to greater paleo-crustal thickness. We suggest that the present metamorphic field gradient was exposed through erosion and orogenic collapse influenced by thermal, isostatic, and gravitational properties related to Neoacadian crustal thickness. Geobarometry in southern New England underestimates crustal thickness and exhumation, suggesting the crust was thinned by tectonic as well as erosional processes.
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  • 86
    Publication Date: 2021-04-21
    Description: Recognition of fundamental tectonic boundaries has been extremely difficult in the (〉1000-km-wide) Proterozoic accretionary orogen of southwestern North America, where the main rock types are similar over large areas, and where the region has experienced multiple postaccretionary deformation events. Discrete ultramafic bodies are present in a number of areas that may mark important boundaries, especially if they can be shown to represent tectonic fragments of ophiolite complexes. However, most ultramafic bodies are small and intensely altered, precluding petrogenetic analysis. The 91-Mile peridotite in the Grand Canyon is the largest and best preserved ultramafic body known in the southwest United States. It presents a special opportunity for tectonic analysis that may illuminate the significance of ultramafic rocks in other parts of the orogen. The 91-Mile peridotite exhibits spectacular cumulate layering. Contacts with the surrounding Vishnu Schist are interpreted to be tectonic, except along one margin, where intrusive relations have been interpreted. Assemblages include olivine, clinopyroxene, orthopyroxene, magnetite, and phlogopite, with very rare plagioclase. Textures suggest that phlogopite is the result of late intercumulus crystallization. Whole-rock compositions and especially mineral modes and compositions support derivation from an arc-related mafic magma. K-enriched subduction-related fluid in the mantle wedge is interpreted to have given rise to a K-rich, hydrous, high-pressure partial melt that produced early magnetite, Al-rich diopside, and primary phlogopite. The modes of silicate minerals, all with high Mg#, the sequence of crystallization, and the lack of early plagioclase are all consistent with crystallization at relatively high pressures. Thus, the 91-Mile peridotite body is not an ophiolite fragment that represents the closure of a former ocean basin. It does, however, mark a significant tectonic boundary where lower-crustal arc cumulates have been juxtaposed against middle-crustal schists and granitoids.
    Electronic ISSN: 1553-040X
    Topics: Geosciences
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  • 87
    Publication Date: 2021-04-28
    Description: Titanium diffusion profiles in natural quartz crystals have become an increasingly popular tool to reconstruct the time scales of various magmatic, metamorphic, and hydrothermal processes. However, the original calibration of Ti diffusion rates in quartz has recently been challenged, and diffusivities were found to be about three orders of magnitude lower. We performed annealing experiments on crystal-crystal diffusion couples consisting of Ti-free synthetic quartz seeds over which Ti-rich quartz (100–3000 μg/g Ti) was grown hydrothermally. The annealing experiments were performed at 1000–1600 °C and 0.1 MPa to 2.0 GPa, and they lasted for 3–84 days. The resulting diffusion profiles were mapped by cathodoluminescence (CL), transmission electron microscope–energy-dispersive X-ray spectroscopy (TEM-EDXS), and, for the first time, by helium ion microscope–secondary ion mass spectrometry (HIM-SIMS). Obtained diffusion coefficients range from values similar to the lower range in previous research to values up to two orders of magnitude lower. In addition, inversely zoned quartz and sanidine phenocrysts in a natural rhyolite were studied. Comparison of the diffusion profiles suggests that at ~735 °C, the Ti diffusivity in quartz is ~1.5 and 3.0 orders of magnitude lower than that of Ba and Sr, respectively, in sanidine. The combined evidence confirms that Ti diffusion in quartz is very slow, potentially even slower than proposed earlier. Consequently, previous time scales derived from Ti diffusion profiles in quartz are likely orders of magnitude too short, and further experiments are necessary to fully clarify the issue.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
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  • 88
    Publication Date: 2021-04-28
    Description: The mechanisms and processes active during the transition from continental subduction to continental collision at the plate interface are largely unknown. Rock records of this transition are scarce, either not exposed or obliterated during subsequent events. We examine the tectono-metamorphic history of Barrovian metamorphic rocks from the western Himalayan orogenic wedge. We demonstrate that these rocks were buried to amphibolite-facies conditions from ≤47 Ma to 39 ± 1 Ma, synchronously with the formation (46 Ma) and partial exhumation (45–40 Ma) of the ultrahigh-pressure eclogites. This association indicates that convergence during continental subduction was accommodated via development of a deep orogenic wedge built through successive underplating of continental material, including the partially exhumed eclogites, likely in response to an increase in interplate coupling. This process resulted in the heating of the subduction interface (from ~7 to ~20 °C/km) through advective and/or conductive heat transfer. Rapid cooling of the wedge from 38 Ma, coeval with the formation of a foreland basin, are interpreted to result from indentation of a promontory of thick Indian crust.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
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  • 89
    Publication Date: 2021-04-28
    Description: The amount of silt and clay available to rivers reflects source-terrain composition and weathering and can be a primary control on the form and dynamics of channel networks. Fine sediment also affects the permeability of buried fluvial reservoirs. Despite this significance, there is currently a lack of methods for reconstructing how much fine sediment was transported by ancient rivers. Mud accumulations in sandy river deposits are often interpreted as indicators of variable flow conditions; however, these deposits may present an opportunity to constrain how much fine sediment was transported through ancient rivers. We report results from a series of experiments designed to evaluate how much clay and silt are preserved in sandy riverbed deposits under constant and variable discharge conditions. Our results demonstrate that (1) mud deposits, including drapes and lenses, form readily under constant, high-discharge conditions, (2) the amount of fine sediment recovered from bed-material deposits increases as fine-sediment supply increases, and (3) fine-sediment retention is higher during bed aggradation than during bypass conditions. These results indicate that the net retention of clay and silt in sandy riverbed deposits may be a simple but powerful proxy for comparing the overall amount of fine sediment supplied to ancient rivers.
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  • 90
    Publication Date: 2021-01-01
    Print ISSN: 1052-5173
    Electronic ISSN: 1943-2690
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  • 91
    Publication Date: 2021-01-01
    Print ISSN: 1052-5173
    Electronic ISSN: 1943-2690
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  • 92
    Publication Date: 2021-04-05
    Description: We present new coupled detrital zircon trace-element and U–Pb age data from Valanginian–Santonian strata of the Nacimiento forearc basin (California, USA) to enhance provenance discrimination and investigate the evolution of the late Mesozoic California margin. Our data document at least five different Jurassic–earliest Cretaceous zircon populations with variable U/Yb ratios, and zircon that displays systematically increasing U/Yb from 130 to 80 Ma. Based on the presence of a distinctive population of geochemically primitive, 168–157 Ma low-U/Yb zircon that is found in Albian–Lower Cenomanian strata but not in older Valanginian strata, we infer a period of uplift and Albian–early Cenomanian erosion of forearc basement (the Coast Range ophiolite) that was coincident with increasing Cordilleran arc magmatic flux.
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  • 93
    Publication Date: 2021-04-05
    Description: The surface of Mars contains abundant sinuous ridges that appear similar to river channels in planform, but they stand as topographic highs. Ridges have similar curvature-to-width ratios as terrestrial meandering rivers, which has been used to support the hypothesis that ridges are inverted channels that directly reflect channel geometry. Anomalously wide ridges, in turn, have been interpreted as evidence for larger rivers on Mars compared to Earth. However, an alternate hypothesis is that ridges are exhumed channel-belt deposits—a larger zone of relatively coarse-grained deposits formed from channel lateral migration and aggradation. Here, we measured landform wavelength, radius of curvature, and width to compare terrestrial channels, terrestrial channel belts, and martian ridges. We found that all three landforms follow similar scaling relations, in which ratios of radius of curvature to width range from 1.7 to 7.3, and wavelength-to-width ratios range from 5.8 to 13. We interpret this similarity to be a geometric consequence of a sinuous curved line of finite width. Combined with observations of ridge-stacking patterns, our results suggest that wide ridges on Mars could indicate fluvial channel belts that formed over significant time rather than anomalously large rivers.
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  • 94
    Publication Date: 2021-04-05
    Description: Hydrogen is an important energy source for subsurface microbial communities, but its availability beyond the flow focused through hydrothermal chimneys is largely unknown. We report the widespread export of H2 across the Atlantis Massif oceanic core complex (30°N, Mid-Atlantic Ridge; up to 44 nM), which is distinct from the circulation system feeding the Lost City Hydrothermal Field (LCHF) on the massif’s southern wall. Methane (CH4) abundances are generally low to undetectable (
    Print ISSN: 0091-7613
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  • 95
    Publication Date: 2021-04-05
    Description: Long-term relationships between climate and dust emission remain unclear, with two prevailing but opposite hypotheses for effects of climate shifts: (1) increased dust emission due to increasing aridity imposing a vegetation change, or (2) decreased dust emission due to increasing aridity which imposes less stormy climate and reduced sediment supply. Here we test these hypotheses by analyzing an ~11-m-long core archiving Holocene dust trapped in Montezuma Well, a natural sinkhole in Arizona (southwestern United States), alongside current dust sources and transport pathways. Major elements indicate that Montezuma Well sediments originate from two end members: local carbonate bedrock and external siliceous dust. Core sediments are similar to the adjacent siliceous soils accumulated atop the bedrock, pointing to their eolian origin. Particle-size distributions reveal fine dust transported during winter from the northwestern Sonoran Desert and the Mojave Desert and coarse dust transported during summer from the southwestern Sonoran Desert, similar to current climate systems and dust pathways. A survey of potential dust sources indicates that current summer and winter dust sources in the Sonoran Desert are under a supply-limited state. Dust fluxes were higher during wetter phases of the Holocene when winter sources dominated. During the middle Holocene drought, dust fluxes were minimal and dominated by summer sources until dust input ceased as drought conditions did not produce enough floods to refill sources with sediments. We propose that in the Sonoran Desert, dust emission is strongly connected with climate, increasing during humid intervals and enhanced by fluvial sediment replenishment at dust sources.
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  • 96
    Publication Date: 2021-04-05
    Description: Large impact structures with peak rings are common landforms across the solar system, and their formation has implications for both the interior structure and thermal evolution of planetary bodies. Numerical modeling and structural studies have been used to simulate and ground truth peak-ring formative mechanisms, but the shock metamorphic record of minerals within these structures remains to be ascertained. We investigated impact-related microstructures and high-pressure phases in zircon from melt-bearing breccias, impact melt rock, and granitoid basement from the Chicxulub peak ring (Yucatán Peninsula, Mexico), sampled by the International Ocean Discovery Program (IODP)/International Continental Drilling Project (IODP-ICDP) Expedition 364 Hole M0077A. Zircon grains exhibit shock features such as reidite, zircon twins, and granular zircon including “former reidite in granular neoblastic” (FRIGN) zircon. These features record an initial high-pressure shock wave (〉30 GPa), subsequent relaxation during the passage of the rarefaction wave, and a final heating and annealing stage. Our observed grain-scale deformation history agrees well with the stress fields predicted by the dynamic collapse model, as the central uplift collapsed downward-then-outward to form the peak ring. The occurrence of reidite in a large impact basin on Earth represents the first such discovery, preserved due to its separation from impact melt and rapid cooling by the resurging ocean. The coexistence of reidite and FRIGN zircon within the impact melt–bearing breccias indicates that cooling by seawater was heterogeneous. Our results provide valuable information on when different shock microstructures form and how they are modified according to their position in the impact structure, and this study further improves on the use of shock barometry as a diagnostic tool in understanding the cratering process.
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  • 97
    Publication Date: 2021-03-31
    Description: The Mesozoic tectonic evolution of the NE Asian continental margin has received much attention in recent years. However, previous studies focused mainly on the petrogenesis of igneous rocks and their relationship with Mesozoic tectonics, and there have been few studies of the Mesozoic sedimentary formations of the NE Asian continental margin. We combined zircon U-Pb ages with Hf isotopic and biostratigraphic data to reconstruct the Mesozoic paleogeography of the NE Asian continental margin. The results indicate that Mesozoic strata of the eastern Jiamusi Massif, NE China, include the Upper Triassic Nanshuangyashan Formation (Norian), Lower Jurassic volcanic rocks, and Lower Cretaceous Longzhaogou Group. The Upper Triassic Nanshuangyashan Formation consists of a suite of alternating marine and terrestrial sedimentary rocks with abundant fossils that formed in a passive continental margin setting. The Lower Jurassic strata comprise a suite of calc-alkaline volcanic rocks that include basaltic andesites, andesites, and rhyolites that formed in an active continental margin setting related to initial subduction of the Paleo-Pacific Plate beneath Eurasia. The Lower Cretaceous Longzhaogou Group belong to alternating marine and terrestrial sedimentary formations that formed in an active continental margin setting related to subduction of the Paleo-Pacific Plate. Here, we integrate these data to reconstruct the Mesozoic tectonic history of the NE Asian continental margin, which comprises a Late Triassic passive continental margin, the initiation of subduction of the Paleo-Pacific Plate in the Early Jurassic, and westward subduction and rollback of the Paleo-Pacific Plate in the Early Cretaceous.
    Print ISSN: 0016-7606
    Electronic ISSN: 1943-2674
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  • 98
    Publication Date: 2021-04-07
    Description: When and how the Yangtze Block (Yangtze) and the West Cathaysia terrane (West Cathaysia) in South China were amalgamated are critical to a better understanding of the Neoproterozoic to early Paleozoic tectonic evolution of South China and remain highly debatable. A key to this debate is the tectonic significance of the Jiangshan-Shaoxing-Pingxiang (JSP) Fault, the boundary between Yangtze and West Cathaysia. The Shenshan mélange along the JSP Fault has the typical block-in-matrix structure and is composed of numerous shear zone-bounded slivers/lenses of rocks of different types and ages that formed in different tectonic environments, including middle to late Tonian volcanic and volcanogenic sedimentary rocks (turbidite) of arc/back-arc affinity, a series of middle Tonian ultramafic to mafic plutonic rocks of oceanic island basalt affinity, a carbonaceous shale that was deposited in a deep marine environment, and a red mudstone. U-Pb zircon ages and acritarch assemblages (Leiosphaeridia-Brocholaminaria association) found in the turbidite confirm its Tonian age, and fossils from the carbonaceous shale (Asteridium-Comasphaeridium and Skiagia-Celtiberium-Leiofusa) constrains its age to the Early to Middle Cambrian. Field relationships and available age data leave no doubt that the ultramafic-mafic rocks are exotic blocks (rather than intrusions) in the younger metasedimentary rocks. We conclude that the Shenshan mélange is not an ophiolitic mélange, but rather a tectonic mélange that formed as a result of movement along the JSP Fault in the early Paleozoic. We suggest that Yangtze and West Cathaysia were two separate microcontinents, were accreted to two different parts of the northern margin of Gondwana in the early Early Paleozoic, and juxtaposed in the late Early Paleozoic through strike-slip movement along the JSP Fault. We further suggest that the ca. 820 Ma collision in the Jiangnan Orogen took place between Yangtze and a (micro)continent that is now partly preserved as the Huaiyu terrane and was not related to West Cathaysia. We compare our model for South China with the accretion of terranes in the North American Cordillera and propose a similar model for the relationship between the Avalon and Meguma terranes in the Canadian Appalachians, i.e., the two terranes were accreted to two different parts of the Laurentian margin and were later juxtaposed through margin-parallel strike slip faulting.
    Print ISSN: 0016-7606
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  • 99
    Publication Date: 2021-04-08
    Description: Recognition of a pair of pre-Neogene markers together with analysis of published data indicate ~40 km of dextral slip across the southern Death Valley fault zone, California, USA. Stratigraphic overlaps on fault rocks indicate much of the dextral slip predates the late Miocene, placing a significant fraction of the dextral slip in the same time window as regional extension and challenging interpretations that the modern strike-slip system became active post–6–3 Ma. However, these results are consistent with regional evidence that dextral transtension began by ca. 12 Ma.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
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  • 100
    Publication Date: 2021-04-08
    Description: The sources of metals enriched in Archean orogenic gold deposits have long been debated. Metasedimentary rocks, which are generally accepted as the main metal source in Phanerozoic deposits, are less abundant in Archean greenstone belts and commonly discounted as a viable metal source for Archean deposits. We report ultralow-detection-limit gold and trace-element concentrations from a suite of metamorphosed sedimentary rocks from the Abitibi belt and Pontiac subprovince, Superior Province, Canada. Systematic decreases in the Au content with increasing metamorphic grade indicate that Au was mobilized during prograde metamorphism. Mass balance calculations show that over 10 t of Au, 30,000 t of As, and 600 t of Sb were mobilized from 1 km3 of Pontiac subprovince sedimentary rock metamorphosed to the sillimanite metamorphic zone. The total gold resource in orogenic gold deposits in the southern Abitibi belt (7500 t Au) is only 3% of the Au mobilized from the estimated total volume of high-metamorphic-grade Pontiac sedimentary rock in the region (25,000 km3), indicating that sedimentary rocks are a major contributor of metals to the orogenic gold deposits in the southern Abitibi belt.
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