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  • Inorganic Chemistry  (83,665)
  • ddc:330
  • ddc:600
  • Wiley-Blackwell  (83,665)
  • Stockholm : Europ. Council for an Energy Efficient Economy  (29)
  • Cheltenham : Elgar  (21)
  • Stuttgart : Hirzel  (14)
Collection
Language
Years
  • 1
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    Cheltenham : Elgar | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2018-04-30
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 2
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    Cheltenham : Elgar | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-08-23
    Keywords: ddc:330
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  • 3
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    Stuttgart : Hirzel | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2018-04-30
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 4
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    Cheltenham : Elgar | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2019-04-01
    Keywords: ddc:330
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    Language: English
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  • 5
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    Cheltenham : Elgar | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2014-08-15
    Keywords: ddc:330
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    Language: English
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  • 6
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    Stuttgart : Hirzel | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2014-08-15
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 7
    Publication Date: 2014-08-15
    Description: Das Zauberwort der Ökoeffizienz hat längst die Chefetagen der Wirtschaft erreicht und immer mehr Unternehmen sehen in der Aufgabe, aktiven Klimaschutz zu betreiben, eine Chance für neue Geschäftsfelder. Mit der Ausschreibung des Wuppertaler Energie- und Umweltpreises suchte das Wuppertal Institut umsetzbare Ideen aus dem Umwelt- und Energiebereich, die den Ressourcen- und Energieverbrauch deutlich reduzieren und so maßgeblich zur Verbesserung der Ökoeffizienz beitragen. Dieses Buch von Ernst Ulrich von Weizsäcker und Peter Hennicke (Herausgeber) stellt zwanzig Projekte vor, die von der Jury des Wettbewerbs prämiert oder belobigt wurden.
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 8
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    Stockholm : Europ. Council for an Energy Efficient Economy | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2018-04-18
    Keywords: ddc:330
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    Language: English
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  • 9
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    Stockholm : Europ. Council for an Energy Efficient Economy | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2018-04-18
    Keywords: ddc:330
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  • 10
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    Stuttgart : Hirzel | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:330
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    Language: German
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  • 11
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    Cheltenham : Elgar | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2019-04-01
    Keywords: ddc:330
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  • 12
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    Cheltenham : Elgar | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-08-23
    Keywords: ddc:330
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  • 13
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    Cheltenham : Elgar | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-08-23
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  • 14
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    Cheltenham : Elgar | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-08-23
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  • 15
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    Cheltenham : Elgar | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2014-08-15
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  • 16
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    Cheltenham : Elgar | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
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  • 17
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    Cheltenham : Elgar | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:600
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  • 18
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    Stuttgart : Hirzel | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2018-04-30
    Keywords: ddc:330
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    Language: German
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  • 19
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    Stockholm : Europ. Council for an Energy Efficient Economy | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:330
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  • 20
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    Stockholm : Europ. Council for an Energy Efficient Economy | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2018-04-18
    Keywords: ddc:330
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  • 21
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    Stuttgart : Hirzel | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-08-23
    Description: Wir wollen auf den Mars und sollten doch zuerst einmal auf der Erde landen. Hier warten ungelöste ökologische und ökonomische Probleme auf Lösungen. Stefan Bringezu lässt seine Leser gedanklich auf dem Planeten Erde neu landen. Dabei tauchen Fragen auf: Wie viel Verbrauch verträgt der Planet? Wo greift die Menschheit in natürliche Stoffströme ein, welche zusätzlichen Stoffströme setzt sie in Bewegung und welche Folgen haben diese? Menschliche Gesellschaft und Natur werden zu zwei komplexen Systemen, von denen das eine - die Gesellschaft - an das andere auf Gedeih und Verderb gekoppelt ist. Der Mensch ist in der Lage, seinen "Stoffwechsel" mit der Natur zu optimieren. Wie dieser gemessen werden kann und welche Lösungsansätze es bereits gibt, zeigt dieses Buch. Auch künftig wird es uns möglich sein, gut zu leben und zu wirtschaften, wenn wir den Verbrauch natürlicher Ressourcen nachhaltig gestalten.
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 22
    Publication Date: 2016-08-23
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 23
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    Cheltenham : Elgar | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2019-04-01
    Keywords: ddc:330
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  • 24
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    Stuttgart : Hirzel | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2018-04-30
    Keywords: ddc:330
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  • 25
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    Cheltenham : Elgar | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:600
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  • 26
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    Cheltenham : Elgar | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
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  • 27
    Publication Date: 2014-08-15
    Description: Ideen von heute prägen die Welt von morgen. Um diese Zukunft verantwortungsvoll zu gestalten, müssen technische Innovationen ökonomische, ökologische und soziale Aspekte in Einklang bringen. Die hier dokumentierten fünfzehn Arbeiten zeigen auf anschauliche und praxisnahe Weise, wie Umweltschutz, Wirtschaftlichkeit und soziale Verantwortung effizient miteinander verbunden werden können. Durch den alle zwei Jahre vom Wuppertal Institut für Klima, Umwelt, Energie ausgelobten Ideenwettbewerb sollen vor allem junge Forscher, Entwickler und Innovatoren gefördert und motiviert werden. Dieses Buch dokumentiert ausführlich alle preisgekrönten und belobigten Projekte des Wuppertaler Energie- und Umweltpreises 2002.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 28
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    Stuttgart : Hirzel | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:330
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  • 29
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    Stuttgart : Hirzel | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
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  • 30
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    Stuttgart : Hirzel | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
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  • 31
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    Cheltenham : Elgar | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2019-04-01
    Description: This book presents important new research on applied eco-efficiency concepts throughout Europe. The aim of eco-efficiency is to achieve market-based measures of environmental protection, in order to enhance the prospects for sustainable development and achieve positive economic and ecological benefits. The distinguished authors discuss a number of themes surrounding eco-efficiency including the necessary conditions for technological dissemination and ecological modernization, and the role of government in enabling businesses and society to participate actively in this process. In particular, they highlight the application of existing European-based policies concerning material flows and energy. The authors also investigate some new concepts of sustainable development and provide a useful introduction to material flows analysis. In further chapters they study the emerging regulatory policies for eco-efficiency, and examine the issues of sustainable business and consumption strategies.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 32
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    Stockholm : Europ. Council for an Energy Efficient Economy | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2019-04-01
    Keywords: ddc:600
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  • 33
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    Stuttgart : Hirzel | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2018-04-11
    Keywords: ddc:330
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    Language: German
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  • 34
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    Cheltenham : Elgar | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2019-04-01
    Keywords: ddc:330
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  • 35
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    Cheltenham : Elgar | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-08-23
    Keywords: ddc:330
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  • 36
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    Cheltenham : Elgar | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2018-04-30
    Keywords: ddc:330
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  • 37
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    Stockholm : Europ. Council for an Energy Efficient Economy | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2014-08-15
    Keywords: ddc:330
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  • 38
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    Stuttgart : Hirzel | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-08-23
    Keywords: ddc:330
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    Language: German
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  • 39
    Publication Date: 2016-04-28
    Keywords: ddc:330
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  • 40
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    Stockholm : Europ. Council for an Energy Efficient Economy
    Publication Date: 2021-05-04
    Keywords: ddc:600
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  • 41
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    Stockholm : Europ. Council for an Energy Efficient Economy | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2018-04-18
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  • 42
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    Stuttgart : Hirzel | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2018-11-19
    Keywords: ddc:330
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    Language: German
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  • 43
    Publication Date: 2018-11-19
    Keywords: ddc:600
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  • 44
    Publication Date: 2019-04-01
    Keywords: ddc:600
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  • 45
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    Stockholm : Europ. Council for an Energy Efficient Economy | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2022-02-18
    Description: Energy labelling for household appliances has become an established instrument to promote energy efficiency. For heating systems, however, this approach has not been successfully implemented yet. This is partially due to the reluctance of industry. To find ways to motivate industry to participate in a labelling scheme, we carried out a survey among producers of heating systems. Respondents to our questionnaire and personal interviews cover together more than 30 percent of the EU market for heating systems. Thus the results provide a solid basis for conclusions. Our survey helps to draw a much better picture of the attitudes and expectations of the manufacturers with regard to a labelling scheme. The paper covers: Attitudes regarding potential effects of a label; Opinions on possible design of a label; Perceived effects of the labels for the companies; Perceived advantages and disadvantages of a label; And, as a conclusion, the potential effects on the companies and their probable relevance. As a result, industry representatives expect that customers will be able to make sounder purchasing decisions because of the availability of a label. Therefore they believe that energy savings will be achieved. What is more, respondents expect that a label could improve integration of the European market for heating systems and would rather improve their individual economic performance. The survey results in a clearer identification of industry's problems, needs and interests. It thus will help policy-makers to get industry to support energy efficiency labels and activities.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 46
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    Stockholm : Europ. Council for an Energy Efficient Economy | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2022-02-18
    Description: The general conditions for local authorities in Germany have changed fundamentally during the last decades. Not only do municipalities compete with each other for employment, prestige and competitive advantages, they also face increasingly higher demands by their citizens, for instance in the area of climate protection. Therefore, every municipality has to consider various economic, social and ecological determinants in its decision-making processes. With respect to public buildings, an economically-oriented cost-benefit-analysis alone is not adequate due to a municipality's role as "consumer and role model". To identify measures with a broader benefit, a multicriteria analysis (MCA) has been used to analyze energy efficiency measures in public buildings for the city of Dortmund. For several years Dortmund has committed itself to implement energy efficiency measures and improve the energy performance of its building stock. Nevertheless, a benchmark analysis still shows a high energy saving potential that cannot be tapped with the existing measures and instruments. Therefore, a package of measures has been developed in close cooperation with the city of Dortmund, ranging broadly from measures of energetic retrofitting and green IT to behavioral change of building occupants. In the MCA these measures have been assessed according to ten different criteria such as innovativeness, cost effectiveness, external costs, CO2 reduction potential, local value or effort of implementation. Three different scenarios ("City as Role Model", "City as Homo Oeconomicus", "City as Climate Protector") show different municipal perspectives. The analysis has shown that the greatest benefit for municipalities, regardless of the municipal perspective, is yielded by measures such as voluntarily enhanced minimum standards for new or for energetic retrofitting of public buildings, the procurement of energy-efficient office equipment, the expansion of heat generation from renewable energies and the usage of private capital in participatory projects like "Solar&Save".
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 47
    Publication Date: 2022-02-18
    Description: The electric utility sector in Australia, Germany and the U.S. are all going through major changes driven by declining sales, increasing use of distributed energy sources and policy responses to global climate change. This paper discusses efforts in each of these countries to reform their electric industries, address climate change and promote energy efficiency. Going forward, we see a role for government, utilities and private market energy efficiency efforts in all three countries, although the emphasis will vary by country and will evolve over time. Where all three parties can work together with a common vision, reform efforts are likely to be more successful and more sustained. In all three countries the future is uncertain. In the face of this uncertainty, energy efficiency supporters need to keep abreast of these changes, and find more flexible and nimble policy strategies for energy efficiency to prosper, as the future is likely to unfold in unexpected ways.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 48
    Publication Date: 2022-02-18
    Description: Following the decisions of the Paris climate conference at the end of 2015 as well as similar announcements e.g. from the G7 in Elmau (Germany) in the summer of 2015, long-term strategies aiming at (almost) full decarbonisation of the energy systems increasingly move into the focus of climate and energy policy. Deep decarbonisation obviously requires a complete switch of energy supply towards zero GHG emission sources, such as renewable energy. A large number of both global as well as national climate change mitigation scenarios emphasize that energy efficiency will likewise play a key role in achieving deep decarbonization. However, the interdependencies between a transformation of energy supply on the one hand and the role of and prospects for energy efficiency on the other hand are rarely explored in detail. This article explores these interdependencies based on a scenario for Germany that describes a future energy system relying entirely on renewable energy sources. Our analysis emphasizes that generally, considerable energy efficiency improvements on the demand side are required in order to have a realistic chance of transforming the German energy system towards 100 % renewables. Efficiency improvements are especially important if energy demand sectors will continue to require large amounts of liquid and gaseous fuels, as the production of these fuels are associated with considerable energy losses in a 100 % renewables future. Energy efficiency on the supply side will therefore differ considerably depending on how strongly the use of liquid and gaseous fuels in the various demand sectors can be substituted through the direct use of electricity. Apart from a general discussion of the role of energy efficiency in a 100 % renewable future, we also look at the role of and prospects for energy efficiency in each individual demand sector.
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  • 49
    Publication Date: 2022-02-18
    Description: Energy intensive industries are one of the fields in which strong increases of energy efficiency and deep decarbonisation strategies are particularly challenging. Although European energy intensive industries have already achieved significant energy and greenhouse gas reductions in the past, much remains to be done to make a significant contribution to achieving European as well as national climate mitigation targets of greenhouse gas emission reductions by -80% or more (compared to the baseline of 1990). North Rhine-Westphalia (NRW) is a European hotspot for coping with this challenge, accommodating more than 10% of the energy intensive industries of the EU28. It is also the first German state to have adopted its own Climate Law, enacting state-wide CO2 emission reductions by 80% until 2050 compared to 1990. The state government initiated the project "Platform Climate Protection and Industry North-Rhine Westphalia" to identify and develop the necessary far-reaching low carbon innovation strategies for energy intensive industries. Heart of the project was a dialogue process, which involved a broad spectrum of stakeholders from steel, chemical, aluminium, cement, glass and paper producing industries. Besides enhancing and broadening the knowledge on high efficiency and low-carbon technologies within industries, the aim was to explore possible pathways and preconditions for the application of these technologies in energy intensive industries as well as to strengthen the motivation of companies for initiatives and investments in technologies with lower CO2 emissions. The results of the dialogue shall provide a basis for a possible low-carbon industry roadmap NRW and may also serve as an example for other industrialized regions in the EU and globally. The paper sketches the structured dialogue process with the stakeholders from companies as well as industrial associations and presents the learnings regarding the engagement of energy intensive industries into ambitious climate policies on a regional level. These include existing limitations as well as chances in the respective sectors on the state level, regarding their economic and technical structures as well as their innovation systems. The findings are based on more than a dozen stakeholder workshops with industry companies and more than 150 individual representatives of NRW's energy intensive industries as well as on background research in the initial phase of the project.
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  • 50
    Publication Date: 2022-02-18
    Description: One of the most pressing issues of climate policy is how to get building owners to invest in the energy efficiency of their homes. The German federal government has set the goal of decreasing the energy demand of buildings by 80 to 95 percent until 2050. One pillar of the strategy to support building owners in this task is the provision of targeted energy advice, to both motivate owners to implement an energy efficiency refurbishment and help them to choose the most efficient measures. In this paper we analysed the demand for energy advice in three German cities of the Ruhr area finding the number of energy consulting provided to be extremely low compared to the stated goals. Based on the approach of joint knowledge production we invited stakeholders from the three cities to participate in a series of workshops in order to develop ideas how to more effectively bring homeowners and energy advisors together. As a result, different energy advice experiments were co-operatively developed for each city targeting different groups by using tailored channels for outreach. The evaluation of both the process as well as the outcome of the experiments indicates that while joint knowledge production is a suitable approach to enable knowledge transfer and formation of new networks between different stakeholders in science and practice, it does not necessarily lead to superior approaches with regard to effectively addressing a policy issue at hand. Apart from the experiment in which the window of opportunity change of building ownership was taken advantage of, participation of target groups in the experiments has been soberingly low, underlining the value of so-called trigger points when designing effective outreach strategies to building owners.
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  • 51
    Publication Date: 2022-02-18
    Description: Energy efficiency improvements have numerous benefits/impacts additional to energy and greenhouse gas savings, as has been shown and analysed e.g. in the 2014 IEA Report on "Multiple Benefits of Energy Efficiency". This paper presents the Horizon 2020-project COMBI ("Calculating and Operationalising the Multiple Benefits of Energy Efficiency in Europe"), aiming at calculating the energy and non-energy impacts that a realisation of the EU energy efficiency potential would have in 2030. The project covers the most relevant technical energy efficiency improvement actions and estimates impacts of reduced air pollution (and its effects on human health, eco-systems/crops, buildings), improved social welfare (incl. disposable income, comfort, health, productivity), saved biotic and abiotic resources, and energy system, energy security, and the macroeconomy (employment, economic growth and public budget). This paper explains how the COMBI energy savings potential in the EU 2030 is being modelled and how multiple impacts are assessed. We outline main challenges with the quantification (choice of baseline scenario, additionality of savings and impacts, context dependency and distributional issues) as well as with the aggregation of impacts (e.g. interactions and overlaps) and how the project deals with them. As research is still ongoing, this paper only gives a first impression of the order of magnitude for additional multiple impacts of energy efficiency improvements may have in Europe, where this is available to date. The paper is intended to stimulate discussion and receive feedback from the academic community on quantification approaches followed by the project.
    Keywords: ddc:600
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  • 52
    Publication Date: 2022-02-18
    Description: Heat integration and industrial symbiosis have been identified as key strategies to foster energy efficient and low carbon manufacturing industries (see e.g. contribution of Working Group III in IPCC's 5th assessment report). As energy efficiency potentials through horizontal and vertical integration are highly specific by site and technology they are often not explicitly reflected in national energy strategies and GHG emission scenarios. One of the reasons is that the energy models used to formulate such macro-level scenarios lack either the necessary high technical or the spatial micro-level resolution or both. Due to this lack of adequate tools the assumed huge existing potentials for energy efficiency in the energy intensive industry cannot be appropriately appreciated by national or EU level policies. Due to this background our paper describes a recent approach for a combined micro-macro energy model for selected manufacturing industries. It combines national level technical scenario modelling with a micro-modelling approach analogous to total site analysis (TSA), a methodology used by companies to analyse energy integration potentials on the level of production sites. Current spatial structures are reproduced with capacity, technical and energy efficiency data on the level of single facilities (e.g. blast furnaces) using ETS data and other sources. Based on this, both, the investments in specific technologies and in production sites are modelled and the evolvement of future structures of (interconnected) industry sites are explored in scenarios under different conditions and with different objectives (microeconomic vs. energy efficiency optimization). We further present a preliminary scenario that explores the relevance of these potentials and developments for the German steel industry.
    Keywords: ddc:600
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  • 53
    Publication Date: 2022-02-18
    Description: The German federal state of North Rhine-Westphalia (NRW) is home to important clusters of energy-intensive basic materials industries. 15% of the EU's primary steel as well as 15% of high-value base chemicals are produced here. Together with refinery fuels, cement, lime and paper production (also overrepresented in NRW) these are the most carbon-intensive production processes of the industrial metabolism. To achieve the ambitious regional and national climate goals without relocating these clusters, carbon-neutral production will have to become standard by mid-century. We develop and evaluate three conceptual long-term scenarios towards carbon-neutral industry systems for NRW for 2050 and beyond: * a first scenario depending on carbon capture and storage or use for heavy industries (iCCS), * a second scenario sketching the direct electrification of industrial processes (and transport) and * a third scenario relying on the import of low carbon energies (e.g. biomass, and synthetic fuels (like methanol) for the use in industries and transport. All scenarios share the assumption that electricity generation will be CO2-neutral by 2050. For all three scenarios energy efficiency, primary energy demand for energy services and feedstock as well as the carbon balance are quantified. We apply a spatial-explicit analysis of production sites to allow for discussion of infrastructure re-use and net investment needs. Possible symbiotic relations between sectors are also included. The robustness of the three conceptualised future carbon-neutral industry systems is then analysed using a multi-criteria approach, including e.g. energy security issues and lock-ins on the way to 2050.
    Keywords: ddc:600
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  • 54
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    Stockholm : Europ. Council for an Energy Efficient Economy | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2022-02-18
    Description: Iran is one of the largest oil producers and natural gas owners globally. However, it has to struggle with domestic energy shortages, economic losses through energy subsidisation and inefficient energy infrastructures. Furthermore, GHG and other energy related emissions are rapidly increasing and posing a growing threat to local environment as well as global climate. With current trends prevailing, Iran may even become a net energy importer over the next decades. Resource allocation is therefore a crucial challenge for Iran: domestic consumption stands versus exports of energy. The energy transformation sector clarifies Iran's dilemma: soaring electricity demand leads to blackouts, and power plant new builds are far from using most efficient technologies (e. g. CHP), therefore keeping energy intensive structures. But fossil fuels could be sold on international markets if spared by having more efficient energy infrastructures. As shown by the high energy intensity of its economy, Iran has large potentials for energy saving and efficiency. In order to highlight and better identify this potential the paper contrasts a high efficiency scenario in all sectors of energy transformation and consumption with a possible "business as usual" development. Using a bottom-up approach, the analysis provides a sector-by-sector perspective on energy saving potentials. These can be utilised on the demand side especially in the transport sector (fuels) and in households (electricity for appliances, natural gas for heating). Electricity generation bears efficiency potentials as well. We conclude that Iran, but also the international community, would benefit on various levels from a more energy-efficient Iranian economy: Energy exports could increase, generating more foreign currency and reducing the pressures on international oil and gas prices; energy consumption would decrease, leading to lower needs for nuclear energy and for subsidies to Iranian people, as well as to a reduction of the high external costs entailed by fossil fuels combustion (smog in cities, environmental stress).
    Keywords: ddc:330
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  • 55
    Publication Date: 2022-02-18
    Description: The role of cities in mitigating GHG emissions and thus tackling global warming has gained importance over the last years.Many cities have developed climate action plans, primarily to achieve long-term "low-carbon" mitigation goals set by national governments or (inter)national agreements. A mere adoption of high level targets, however, raises the question whether these targets are applicable for cities with very different framework conditions. We argue that it is crucial to understand the socio-economic, geophysical, spatial, infrastructural and political framework of a city - a broad approach, which is generally missing in climate action plans. Thus, determining drivers and barriers for future development paths is neglected by local policies, which leads to a gap between ambition (target) and reality (implementation). We exemplarily examine this hypothesis for the shrinking city of Oberhausen (Germany). Oberhausen, located in the Ruhr area,is a typical old industrial region, which has seen a decline of its industrial basis over the last decades. We analysed historical data and developed scenarios until 2030. Both show a significant decrease in CO2 emissions. A closer look, however, reveals that the reduction is primarily due to the economic transformation (less manufacturing, more service industry, accompanied by a decrease in population) and general energy efficiency developments following the implementation of national and EU policies. Although the city has implemented–and will further implement - many instruments and policies to reduce CO2 emissions, local barriers such as unemployment, low rents, low income, high per capita debts, etc. dramatically reduce the city's capacity for action. The results show that Oberhausen's emission reductions do not reflect active energy policies but are mainly driven by an economic decline. To reach ambitious reduction targets, however, the city needs to be enabled to take action in achieving appropriate and reasonable targets.
    Keywords: ddc:600
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  • 56
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    Stockholm : Europ. Council for an Energy Efficient Economy
    Publication Date: 2022-02-18
    Description: Conventional new buildings in OECD countries with a history of building codes save about 50 % of energy compared to average buildings in the building stock. This improvement, however, is not enough to create a building standard with low lifetime costs nor to reach long-term climate protection targets. Much higher energy savings can already be achieved through proven high-efficiency building concepts bringing net economic benefits among other advantages. A strategic approach to integrated building design is the key to achieving these high-energy savings at low or no extra cost in residential buildings. In our paper we describe the "Easy Efficiency Approach", which can reduce primary energy consumption by 40 to 60 % compared to conventional new building standards, or by 70% to 80% when compared to the primary energy consumption of the existing building stock, and should be regarded as the minimum. This strategy focuses on low-cost options, mainly passive options. Although it can already significantly reduce energy consumption, this first step will not be sufficient to reach long-term climate protection goals. It is thus necessary to implement and support what we call an "Advanced Efficiency Approach", with savings up to 90% , as compared to new building standards, as soon as possible to avoid lock-in effects. Further improvements, especially through the active use of renewable energies, reduce the net primary energy demand to 0 % and beyond. According to the chosen strategy clearly defined energy performance ranges, with reference to possible savings, for different climate zones worldwide are given. In verifying this approach simulations with BAT (Best Available Technologies) buildings of different types (single family, multi family, high rise) were carried out in close cooperation with project partners. This data has also been verified through an empirical database of built examples both for energy consumption as well their economic soundness.
    Keywords: ddc:600
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  • 57
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    Stockholm : Europ. Council for an Energy Efficient Economy | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2022-02-18
    Description: The cement industry is one of the major energy consuming and CO2 emitting sectors in China. In 2010, 1,868 million tons of cement has been produced, which accounted for 56.1% of the world's total cement production. The 11th Five-Year Plan (FYP) (2006-2010) included policy measures for CO2 emission abatement in cement production. Based on the main governmental framework of CO2 mitigation policies at national level in the cement sector, key policies and technologies used during this period are identified and their effects on CO2 reduction are assessed. This paper calculates the reduction of CO2 emissions related to four main policies and technologies for efficient cement production in the 11th and the 12th FYP (2011-2015) with 2005 as a reference year. These are waste heat recovery, closing outdated facilities, substitution for clinker production and other technologies aiming to increase energy efficiency. Due to these measures, we estimate that a total CO2 emission reduction during the 11th FYP of 397 million tonnes could be saved, which is considerably different to 185.75 million tonnes estimated by Zeng (2008) and 303 million tonnes by the NDRC by using different calculation methods. Of the four technologies, the 4th group of energy efficiency increasing techniques was the most important policy and avoided the largest amount of CO2 emissions. Previous energy intensity reduction was mainly due to the outdated production closing and energy efficiency improving. Based on the assessment of technology performance, it appears that there is still a large emission reduction potential in cement production processes. The paper calculates this potential for the 12th FYP period (2011-2015) based on these four identified policy measures. The result is compared to the Chinese government targets in the 12th FYP and promising future CO2 mitigation policies and technologies are proposed, such as the use of alternative energy.
    Keywords: ddc:600
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  • 58
    Publication Date: 2022-02-18
    Description: Several low-carbon energy roadmaps and scenarios have recently been published by the European Commission and the International Energy Agency (IEA) as well as by various stakeholders such as Eurelectric, ECF and Greenpeace. Discussions of these studies mainly focus on technology options available on the electricity supply side and mostly omit the significant challenges that all of the scenarios impose on the energy demand side. A comparison of 5 decarbonisation scenarios from 4 of the most relevant recent scenario studies for the EU shows that all of them imply significant efficiency improvements in traditional appliances, usually well above levels historically observed over longer periods of time. At the same time they assume substantial electrification of transportation and heating. The scenarios suggest that both of these challenges need to be tackled successfully for decarbonising the energy system. With shares of renewable electricity reaching at least 60 % of supply in 2050 in almost all of the decarbonisation scenarios, the adaptation of demand to variable supply becomes increasingly important. This aspect of demand side management should therefore be part of any policy mix aiming for a low-carbon power system. Based on a quantitative analysis of 5 decarbonisation scenarios and a comparison with historical evidence we derive the (implicit) new challenges posed by the current low-carbon roadmaps and develop recommendations for energy policy on the electricity demand side.
    Keywords: ddc:600
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  • 59
    Publication Date: 2022-02-18
    Description: This chapter discusses the question of ecologically differentiated value added taxes (VAT) as a tool to overcome tax-related cognitive barriers by connecting to an existing tax system. This is elaborated along several aspects: (a) The role indirect of consumption taxes for the economy, (b) the legal issues of the VAT system, (c) the EU harmonization efforts in this context, (d) the distributional implications of value added taxes. Following this, the chapter develops a proposal for a VAT reform (e). To this end, it looks at potential and existing differentiations between sectors, products and services, and product and service groups and turns to those consumption areas that are widely identified as particularly resource and carbon intensive and sets out how a harmonization of the overall system and an ecological differentiation in single consumption areas could be brought together. Potential impacts and effects are briefly discussed (f) and some conclusions are drawn (g). The subject addressed in the chapter is relevant from a policy perspective but mainly descriptive: It does not use innovative qualitative and quantitative tools.
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  • 60
    Publication Date: 2022-02-18
    Description: There is an increasing pressure that enhanced and novel energy technologies are swiftly adopted by the market to ensure meeting the energy and climate targets. An important issue with such novel developments is their risk to be stuck in the "valley of death", i.e. that their transition to the market is delayed or unsuccessful. Publicly supported demonstration projects could help to bridge the valley of death by reducing barriers to the adoption caused by missing information and perceived risks. A challenge for technology demonstrations in the industrial context is their often high investments that are required to prove their real-world benefits. Given the magnitude of such investments, it becomes crucial that public funding focuses on the most promising demonstration proposals. Structured evaluation processes can help to facilitate the identification of promising proposals and to improve the quality and transparency of decisions. This paper deals with a corresponding multi-staged multi-criteria decision support system (DSS) suggested to the German Federal Ministry for Economic Affairs and Energy. It deals with the evaluation of demonstration proposals across three stages: The first stage represents a filtering stage to identify those proposals relevant for further considerations. The second stage comprises a multi-criteria scoring method drawing on an evaluation against nineteen criteria. The final third stage serves to critically review the need for public funding of well-scored proposals. This contribution outlines the development of the DSS and its design and thus provides insights on proposal evaluating in energy research.
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  • 61
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    Stockholm : Europ. Council for an Energy Efficient Economy | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2022-02-18
    Description: International consensus is growing that a transition towards a low carbon society (LCS) is needed over the next 40 years. The G8, the Major Economies Forum on Energy and Climate, as well as the Ad Hoc Working Group on Long-term Cooperative Action under the United Nations Framework Convention on Climate Change, have concluded that states should prepare their own Low-emission Plans or Low-emission Development Plans and such plans are in development in an increasing number of countries. An analysis of recent long-term low emission scenarios for Germany shows that all scenarios rely heavily on a massive scale up of energy efficiency improvements based on past trends. However, in spite of the high potential that scenario developers assign to this strategy, huge uncertainty still exists in respect of where the efficiency potentials really lie, how and if they can be achieved and how much their successful implementation depends on more fundamental changes towards a more sustainable society (e.g. behavioural changes). In order to come to a better understanding of this issue we specifically examine the potential for energy efficiency in relation to particular demand sectors. Our comparative analysis shows that despite general agreement about the high importance of energy efficiency (EE), the perception on where and how to achieve it differ between the analysed scenarios. It also shows that the close nexus between energy efficiency and non-technical behavioural aspects is still little understood. This leads us to the conclusion that in order to support energy policy decisions more research should be done on energy efficiency potential. A better understanding of its potential would help energy efficiency to fulfil its role in the transition towards a LCS.
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  • 62
    Publication Date: 2022-02-18
    Description: Renewable energy plays a key role in the sustainable pathway towards a low carbon future and, despite new supply capacities, the transformation of the energy system also requires the adoption of a method which allows for the integration of increasing amounts of renewable energy. This requires a transition to more flexible processes at an industrial level and demand side management (DSM) is one possible way of achieving this transition. Currently, increased shares of variable renewable energy can cause the electricity supply to become more volatile and result in changes to the electricity market. In order to develop a new dynamic equilibrium to balance supply and demand, sufficient flexibility in demand is required. As adequate storage systems are not available in the short to medium term, the potential for large electricity consumers to operate flexibly is an attractive, pragmatic and feasible option. Recent studies in Germany suggest that there is significant potential for DSM in so-called "energy-intensive industries". However, the figures (which fall in the approximate range of 1,250-2,750 MW positive and 400-1,300 MW negative shiftable load) should be interpreted with caution. The range of industrial processes considered are diverse and vary from plant to plant, with the result that it is difficult to provide accurate calculations of the accumulated potential for Germany or the EU as a whole. Based on extensive surveys and panel discussions with representatives from energy-intensive industries (aluminum, cement, chemicals, iron & steel, pulp & paper), which together account for approximately one third of the industrial electricity demand in Germany, our paper provides an overview of both the opportunities and the barriers faced by DSM. One of the key findings is the possible loss in energy efficiency due to DSM: in order to decrease or increase production depending on the stability needs of the electricity system, plants and processes may no longer operate at their optimum levels. The effects on downstream production must also be taken into account in order to gain a more complete understanding of the overall effects of industrial DSM.
    Keywords: ddc:600
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  • 63
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    Stockholm : Europ. Council for an Energy Efficient Economy
    Publication Date: 2022-02-18
    Description: Converting electricity into heat offers the opportunity to make of use large scales of renewable (surplus) energy in the long run in order to reduce shut-downs of renewable power plants and to substitute fossil fuels. Electrification seems to be also very promising for industrial heat applications, as it enables high process temperatures to be achieved in a tailor-made and efficient way and enables the utilisation of other energy sources like waste heat, geothermal or ambient heat (via heat pumps). This article analyses theoretical and technical electrification potentials of Steam Generation and Other Process Heat Generation in the following energy-intensive branches: iron & steel, non-ferrous metal, iron foundries, refineries, base chemicals, glass, cement clinker and paper industry in Germany. Literature research, expert interviews as well as own modelling were conducted to determine potentials and their implementation barriers. Based on these methods, market potential to electrify industrial steam generation was estimated. On the basis of two climate protection scenarios, the effects of both a monovalent and a hybrid industrial power-to-heat strategy were quantified with regard to greenhouse gas reduction and energy efficiency (primary energy saving). The pathway towards electrification will be reflected by criteria such as path dependency, dependency of infrastructure and system compatibility. Recommendations for research and development as well as policies are derived from the overall analysis. The article shows that electrification can be an important option to achieving high CO2-savings in the industrial heating sector in a long-term perspective. However, the scenario calculations show that electrification does not in itself guarantee reduction of greenhouse gases or savings of primary energy. To reach these goals, it is essential to further develop industrial heat pumps and to map electrification and further development of renewable energy (including infrastructure such as power networks and storage facilities) in a concerted strategy.
    Keywords: ddc:600
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  • 64
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    Stockholm : Europ. Council for an Energy Efficient Economy
    Publication Date: 2022-02-18
    Description: The efficiency strategy to exploit the potential for energy savings in buildings still is applied rather slowly in most countries. In addition, there are indications that energy savings are partly compensated particularly by wealth but also rebound effects, the "empty nest" (persistence of elderly people and couples in family homes), and cohort effects (e.g. vintages of people or buildings). In Germany, as in other European countries, the existing trend in housing is a continuously growing floor space per capita. Over the last decades it expanded from about 20 m2 in 1960 to currently 45 m2 per person. Forecasts expect a further increase to more than 50 m2 per person. Obviously, more floor space needs more energy for space heating and cooling, ventilation, and lighting, but it also allows the household to operate more and or bigger appliances, all of which increase energy consumption. On the other hand, housing projects emerge offering relatively small private living spaces in combination with various shared spaces to use. Many of them are based on private initiatives. But what is the motivation behind it? And is there a higher need for new living concepts in the future? The proposed paper presents main drivers of increasing floor space per capita in Germany and discusses the question if more space is necessary for higher comfort. It presents different examples of housing concepts that strive to achieve good living with less space and suggests a "building typology of sufficiency". Finally, the paper discusses qualitatively to which extent these housing concepts can lead to less energy use and emissions. In this way sufficiency could be best friend with efficiency and tackle wealth, rebound, and other effects that counter-act efficiency progress. But therefore, as the paper concludes, politics and policies should recognise sufficiency as a field of action instead of referring to individual decisions and lifestyles.
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  • 65
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1018-1027 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei nochmaliger Untersuchung der Umsetzung von CCl4 mit Si/Cu-Gemischen werden, wie bereits bekannt, SiCl4, C2Cl4 und Si2Cl6 gefunden. Darüber hinaus lief eine direkte Synthese. Sie führte wahrscheinlich zur Bildung des allerdings dabei nicht nachgewiesenen Cl3C·SiCl3. Dagegen wurde die nach der direkten Synthese entstandene Verbindung C(SiCl3)4 erstmalig aufgefunden.  -  Die Entstehung der ebenfalls nachgewiesenen Verbindungen Cl3SiC·C⋮CC·SiCl3 und Cl3SiC·(Cl)C:C(Cl)C·SiCl3 wird durch Dechlorierungen des Cl3CC·SiCl3 mit Kupfer erklärt.  -  Für die neuen Verbindungen wurden Strukturbeweise geführt. Es wurden C2Cl4 und Cl3CC·SiCl3 mit Si/Cu-Gemischen umgesetzt. Die letzte Umsetzung ergab dieselben Reaktionsprodukte wie das CCl4, so daß auch bei diesem eine direkte Synthese über das Cl3CC·SiCl3 glaubhaft gemacht ist.
    Additional Material: 2 Ill.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1048-1055 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Eigenschaften von tert.-Butylthionitrit, Triphenylmethylthionitrit und tert.-Butylthionitrat werden Rückschlüsse auf die Elektronenstruktur der schwefelhaltigen Gruppe gezogen.
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    Keywords: Chemistry ; Inorganic Chemistry
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    Notes: Als weiteres Beispiel für die präparative Überlegenheit der säurekatalysierten Aldolreaktionen des Formaldehyds gegenüber den OH⊖-katalysierten wird über die Synthese der bisher unbekannten Bisanhydro-ennea-heptose, die das Ringsystem des 3.7-Dioxa-bicyclo-[1.3.3]-nonans enthält, berichtet.  -  Bei der Untersuchung des Verhaltens der Bisanhydro-ennea-heptose gegen Alkalien machten sich in der Abspaltbarkeit der Hydroxymethylgruppen charakteristische Unterschiede geltend, deren Erklärung in den konstitutionell-konstellativen Gegebenheiten zu suchen ist.  -  Bei dem Versuch einer Ringerweiterung an der Anhydro-ennea-heptose mit Diazomethan bildet sich eine Verbindung C9H16O5, die wahrscheinlich kein Derivat des Oxa-cycloheptanons-(4), sondern ein Derivat des Tetrahydro-γ-pyrons ist.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1092-1101 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Substituierte Ammoniumsalze vom Typ I liefern mit Abkömmlingen des Phenylglyoxals in Methanol in glatter Reaktion Lactolid-Basen vom Typ II. Aus diesen lassen sich verschiedene Octa- bzw. Decahydroisochinolin-Derivate darstellen, die in 1-Stellung einen substituierten Benzylrest tragen.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1115-1117 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die jodometrische Bestimmung der Hydroperoxyde von Benzolkohlenwasserstoffen kann durch katalytische Wirkung von Kupferionen verbessert werden.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1135-1139 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzung von Tetraacetyl-α-D-glucopyranosylbromid und Tetraacetyl-6-trityl-β-D-glucopyranose mit Silberperchlorat oder Silberfluoroborat in Nitromethan liefert in guter Ausbeute Octaacetyl-β-gentiobiose. Die gleiche Umsetzung mit einem Überschuß an Tetraacetyl-α-D-glucopyranosylbromid und Silberperchlorat führt zur Octaacetyl-α-gentiobiose. Es wird eine Deutung des Reaktionsablaufs gegeben.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1126-1129 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Tachysterin2 wurde mit durch Glas gefiltertem Quecksilberdampflicht in Präcalciferol2 umgewandelt.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1152-1158 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Um eine Aussage über den Reaktionsmechanismus bei der Mercurierung des Ammonium-Ions in wäßrigen Lösungen machen zu können, wurde Quecksilber-(II)-diamminchlorid, Hg(NH3)2Cl2, mit wäßriger Ammoniumacetat-Lösung zum sog. „unschmelzbaren Präzipitat“, HgNH2Cl, umgesetzt. Die Lösung enthielt 1 Mol. 203Hg(CH3CO2)2 pro Mol. des Diammoniakates.Die beiden heterogenen Austauschreaktionen Hg(NH3)2Cl2/[203Hg(NH3)4]2⊕ und HgNH2Cl/[203Hg(NH3)4]2⊕ wurden in Abhängigkeit von der Temperatur untersucht.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1158-1163 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Von den sechs möglichen Isomeren des Decalindiols-(1.4) wurden zwei der Reihe des cis-Decalins und zwei der Reihe des trans-Decalins angehörende Diole durch Reduktion von cis- und trans-Decalindion-(1.4) sowie durch katalyt. Hydrierung von Naphthohydrochinon-(1.4) und ar-Tetralindiol-(5.8) mit Raney-Nickel im Autoklaven erhalten, eindeutig der cis- und trans-Reihe zugeordnet und durch Derivate charakterisiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1184-1188 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Einwirkung von Aryldiazoniumsalzen auf verschiedene monoalkylierte Dihydroresorcine wurde untersucht. Dabei wurden im glatten Reaktionsverlauf δ-Keto-δ-arylhydrazono-carbonsäuren erhalten. Die gleiche Reaktion führte beim 2-Acetamino-dihydroresorcin infolge einer sekundär verlaufenden Wasserabspaltung zu einem Derivat des 1.2.4-Triazols, dessen Konstitution bewiesen wurde.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1206-1212 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Umsetzung von Alkylhydroperoxyden oder Wasserstoffperoxyd mit Formaldehyd und sekundären Aminen werden nach Art der Mannich-Reaktion Aminoalkylperoxyde erhalten. In mineralsaurer Lösung gelingt auch die Umsetzung von Benzamid oder Harnstoff mit Formaldehyd und Alkylhydroperoxyden.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1216-1223 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Einführung der Carbonsäurechloridgruppe in 1- bzw. 3-Stellung des Azulensystems gelingt durch Substitution mittels Phosgens ohne Friedel-Crafts-Katalysatoren. Befindet sich in Nachbarstellung zur Carbonsäurechloridgruppe am 7-Ring kein Substituent, so lassen sich die Verbindungen zu den freien Carbonsäuren hydrolysieren, andernfalls tritt Decarboxylierung ein. Die Säurechloride lassen sich in Ester, Amide und Anilide überführen. Die spektralen Verschiebungen gegenüber den zugrunde liegenden Azulenen werden diskutiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1195-1205 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Hydrierung des Adrenalins mit Raney-Nickel liefert keine brauchbaren Ergebnisse. Das Hexahydro-adrenalin (Xb) wird deshalb synthetisch aus Tetrahydro-benzaldehyd in 5 Stufen in guter Ausbeute dargestellt. Es wird gezeigt, daß das synthetische Produkt eine sterisch weitgehend einheitliche Verbindung ist und die 3(trans).4(cis)-Konfiguration besitzt.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1212-1215 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus cyclischen Ketonen und sekundären Aminen erhältliche α.β-ungesättigte Amine addieren Wasserstoffperoxyd an der Doppelbindung und geben kristalline Peroxyde.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1237-1237 
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    Keywords: Chemistry ; Inorganic Chemistry
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    Topics: Chemistry and Pharmacology
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1239-1246 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Tetrahydroxy-p-benzochinon zeigt einige Eigenschaften, die es als „doppeltes aci-Redukton“ erscheinen lassen. So erleidet es „Diazo-Spaltung“ unter Bildung von Mesoxalsäure-bis-arylhydrazid. Diazomethan verwandelt es in den Tetramethyläther, der leicht, sogar durch den Ausgangsstoff, zum entspr. Hydrochinon reduziert wird. Es werden noch Acetyl- und Aminoderivate des Tetrahydroxy-p-benzochinons und seines Dimethyläthers beschrieben sowie die UV- und IR-Spektren diskutiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1276-1287 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ausgehend von den in der ersten Veröffentlichung(1) beschriebenen Substanzen wurden Derivate der folgenden Peptide synthetisiert: Glycyl-L-glutaminsäure, Glycyl-glycyl-L-glutaminsäure, γ-L-Glutamyl-glycin, α- und γ-L-Glutamylglycyl-L-glutaminsäure, α- und γ-L-Glutamyl-α-L-glutamyl-glycin und α-L-Glutamyl-L-tyrosin. Auch einige freie Peptide konnten erhalten werden. Als interessante Nebenprodukte der Peptidsynthese über gemischte Anhydride mit Kohlensäure-halbestern wurden in zwei Fällen Diacylimide erhalten.
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    Keywords: Chemistry ; Inorganic Chemistry
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    Topics: Chemistry and Pharmacology
    Notes: Beim Behandeln von N-Benzoyl-D-glucosamin (IV) mit chlorwasserstoffhaltigem Aceton entsteht das Acetonderivat VII eines Phenyloxazolins, welches Furanosestruktur besitzt. Dieses wird mit chlorwasserstoffhaltigem Methanol in das entsprechende Aceton-β-methylfuranosid IX und anschließend in das acetonfreie β-Methylfuranosid X umgewandelt.  -  Behandeln von O-Tetraacetyl-N-carbobenzoxy-D-glucosamin (XI) mit TiCl4 oder mit AlCl3/PCl5 führt unter Abspaltung von Benzylchlorid zur Bildung eines Oxazolonderivates (XIII).
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1313-1319 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Methylphenylhydrazone der Monobenzoyl-aldosen liegen im kristallisierten und gelösten Zustand nur als Schiffsche Basen vor, sie zeigen keine Mutarotation und lassen sich zu 5-Benzoyl-2.3.4-triacetyl-pentose- bzw. 6-Benzoyl-2.3.4.5-tetraacetyl-hexose-methylphenylhydrazonen acetylieren, deren Struktur durch Synthese bewiesen wird. Die aus Monobenzoyl-aldose-phenylhydrazonen mit Phenylhydrazin darstellbaren Monobenzoyl-aldose-phenylhydrazonen werden sehr leicht zu Aldose-phenylosazonen und Benzoesäure hydrolysiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1329-1335 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung des Monobrom-, Monojod- und Trimethoxy-pivalophenons werden beschrieben. Die Halogenverbindungen erleiden bei der Einwirkung wäßriger Alkalien eine hydrolytische Spaltung. Die Methoxyverbindung ist gegen Alkalien stabil.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1363-1366 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: β-Aroyl-acrylsäuren reagieren mit Pyrrol, 1- und 2-Methyl-pyrrol nach dem Schema der substituierenden Addition.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1386-1397 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Oxydation von Tetralol-(6) und Östradiol-17-monoacetat mit Bleitetraacetat werden Tetralin-p-chinolacetat und 17β-Acetoxy-östra-p-chinol-(10ζ)-acetat dargestellt. Aus den Chinolacetaten lassen sich die Chinole durch basenkatalysierte Umesterung in Freiheit setzen. Dem aufgezeigten Weg kommt allgemeine Bedeutung zur Darstellung von p-Chinolen zu.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1472-1477 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: β-Phenyl-äthylamine lassen sich mit Cyclohexanon-(2)-essigsäure zu partiell hydrierten Oxindol-Derivaten kondensieren, die durch Ringschluß in Verbindungen der Erythrinan-Reihe übergeführt werden.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1478-1480 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Umsetzung von Chlorameisensäure-benzylester mit überschüssigem Hydrazinhydrat in absol. Chloroform ergibt Carbobenzoxy-hydrazin. In wäßrigem Medium entsteht vorwiegend N.N′-Dicarbobenzoxy-hydrazin (I), das von rauchender Salpetersäure leicht zu Azodicarbonsäure-dibenzylester (II) dehydriert wird.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1483-1500 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurden 2 Tetraphenyl-äthylene, 2 Tetraphenyl-butatriene und 2 Tetraphenyl-hexapentaene mit je 2 meta- bzw. para-ständigen Nitrogruppen dargestellt. Es gelang, die beiden Äthylene durch Kristallisation und das Butatrien mit m-ständigen NO2-Gruppen durch Chromatographie in der cis- und in der trans-Form zu gewinnen. Damit ist bei einem zweiten Beispiel die von J. H. van't Hoff 1874 vorausgesagte Isomerie an einer Verbindung verwirklicht worden, in der 4 C-Atome durch 3 Doppelbindungen verknüpft sind.  -  Die Isomeren des Triens sind lichtempfindlich. Das Mengenverhältnis cis : trans im photochemischen Gleichgewicht entspricht der Zusammensetzung des Kumulens, wie es bei der Synthese anfällt. Die thermische cis-trans-Umlagerung der Butatriene läßt sich vorzüglich IR-spektroskopisch verfolgen. Die Zuordnung der mit A und B bezeichneten isomeren Butatriene zur cis- und trans-Formel wird diskutiert.  -  Von den beiden Hexapentaenen konnte dasjenige mit 2 p-ständigen Nitrogruppen in roten Kristallen, aber nicht in cis-trans-isomeren Formen gewonnen werden. Das entsprechende Hexapentaen mit 2 m-ständigen NO2-Gruppen war in Lösung beständig, es zersetzte sich aber teilweise bei Entfernung des Lösungsmittels.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1517-1523 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzung von 1.3.5-Trinitro-benzol mit Nitrophloroglucin sowie diejenige von Pikrinsäure mit Phloroglucin führt zu polycyclischen Verbindungen. Deren adamantanartige Konstitution wird auf Grund UV-spektroskopischer Vergleiche diskutiert.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1559-1563 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: α.α′-Alkandialdehyde wurden durch Abbau von α.α′-Dibrom-dicarbonsäuren nach Curtius erhalten. Aus α.α′-Dibrom-korksäure bzw. α.α′-Dibrom-azelainsäure entstanden unter geeigneten Bedingungen l-Formyl-cyclopenten-(1) bzw.-cyclohexen-(1).
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1573-1578 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Der durch Säuren katalysierte Isochinolin-Ringschluß ist unter bestimmten Bedingungen auch mit Substanzen durchführbar, die eine säureempfindliche Gruppe enthalten. Auf diese Weise lassen sich Enoläther bzw. Acetale des Decahydroisochinolons herstellen (XII bzw. XIII), die durch nachfolgende Hydrolyse das freie α.β-ungesättigte Ringketon (XVI) liefern, das man durch direkten Ringschluß nicht erhalten kann.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1594-1599 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Anlagerung von Ammoniak an Δ1-Tetrahydrobenzoesäure und Cyclopenten-(1)-carbonsäure-(1) entstehen ausschließlich die trans-β-Aminosäuren. Der Nachweis der Konfiguration erfolgt bei den entsprechenden cis-Aminosäuren, die durch Hofmannschen Abbau der cis-Hexahydrophthalamidsäure (V) und des cis-Cyclopentan-dicarbonsäure-(1.2)-monoamids erhalten werden. cis-und trans-2-Amino-cyclopentan-carbonsäure-(1) wurden erstmals dargestellt.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1618-1623 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: D-Arabinose-mercaptale lassen sich mit p-Toluolsulfonsäure- und mit Methansulfonsäurechlorid in Pyridin bei tiefer Temperatur partiell zu 5-Tosyl- bzw. 5-Mesyl-D-arabinose-mercaptalen verestern. Diese werden mit Lithiumaluminiumhydrid zu 5-Desoxy-D-arabinose-mercaptalen reduziert. Daraus gewinnt man durch Abspalten von Mercaptan die 5-Desoxy-D-arabinose.
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    Berichte der deutschen chemischen Gesellschaft 91 (1958), S. 2553-2557 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus den Chloriden gesättigter, ungesättigter und aromatischer Mono- und Dicarbonsäuren lassen sich durch Umsetzen mit Kaliumfluorsulfinat die entsprechenden Säurefluoride unter milden Reaktionsbedingungen herstellen.
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    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1550-1558 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die gleichzeitige Einwirkung von o-Phenylendiamin und Phenylhydrazin auf Dehydro-L-ascorbinsäure führt zum 2-Hydroxy-3-[1′-phenylhydrazono-L-threo-2′.3′4′-trihydroxy-butyl]-2.2′-anhydro-chinoxalin, dessen Natriumsalz beim Erhitzen in Wasser unter Ausbildung eines anellierten Pyrazolringes zum 1-Phenyl-3-[L-threo-trihydroxy-propyl]-flavazol kondensiert. Dagegen entsteht unter dem Einfluß von Hydroxylamin-hydrochlorid das 2-Hydroxy-3-[1′-phenyl-5′-hydroxymethyl-pyrazolyl-(3′)]-chinoxalin. Zu der gleichen Verbindung gelangt man auch durch alkalische Verseifung der Diacetylverbindung des Ausgangsstoffes.
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  • 97
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1579-1586 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird der Nachweis erbracht, daß bei der Dieckmann-Kondensation des Esters IVc vorwiegend der Ketoester I entsteht. Hydrierung und Hydrolyse führt zu 3-Hydroxy-piperidin-carbonsäure-(2). Ozonspaltung und Hydrolyse ergibt Oxalsäure. Eine entsprechende Kondensation, ausgehend vom Ester IXc, ergibt den ungesättigten Piperidonester X.
    Additional Material: 1 Ill.
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  • 98
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1587-1593 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Anlagerung von Ammoniak an Shikimisäure (I) entstehen vorwiegend zwei stereoisomere Aminosäuren der Konstitution III und IV.
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  • 99
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1679-1694 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: o-Substituierte Benzole mit 1. aliphatischer Amino- und aromatischer Mercaptogruppe und 2. aliphatischer Mercapto- und aromatischer Aminogruppe wurden in wäßrig-alkoholischem Medium oxydiert. In der 1. Kategorie resultierten je nach pH Sulfenamid oder Disulfid; im geeigneten Fall trat weitere Dehydrierung zum 1.2-Benzisothiazol-Derivat ein. Es wurde ein pH-abhängiges Gleichgewicht Disulfid ⇌ Sulfenamid + Aminomercaptan festgestellt. In der 2. Kategorie lief die Bildung des Sulfenamids (2.1-Benzisothiazol) und des Disulfids nebeneinander in pH-abhängigen Mengenverhältnissen. Ein übergang Disulfid → Sulfenamid konnte nur unter bestimmten oxydativen Bedingungen erzielt werden. Es wurde an diesem Beispiel gezeigt, daß auch unter günstigen sterischen Verhältnissen die aromatische Aminogruppe nicht in der Lage ist, die aliphatische Disulfid-Gruppe zu spalten.
    Additional Material: 2 Tab.
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  • 100
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 92 (1959), S. 1710-1711 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 5.5-Diphenyl-glykocyamidin wird durch Methyljodid in 3-Stellung methyliert. Durch Ammonolyse (bzw. Aminolyse) von 1-Methyl-2-methylmercapto-4.4-diphenyl-imidazolon-(5) in Gegenwart von Ammoniumsalzen wurden weitere-3-substituierte Glykocyamidine dargestellt.
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