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  • Chemistry  (72,968)
  • 2020-2024  (45)
  • 1980-1984  (33,715)
  • 1960-1964  (20,531)
  • 1935-1939  (8,266)
  • 1925-1929
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  • 1
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-05
    Description: Mineralogy includes thirteen chapters that discuss the methodology of specific mineralogical methods, the composition of minerals from different igneous rocks, and the composition of minerals from different sedimentary rocks.It contains detailed mineralogical studies from Africa, Asia, and Europe. Chapters present different scientific mineralogical methods and detailed descriptions of minerals from different magmatic and sedimentary rocks.
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNV Chemistry of minerals, crystals and gems
    Language: English
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  • 2
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-05
    Description: Benzimidazole is a comprehensive survey of the known and new methods of benzimidazole synthesis, the spectral and theoretical aspects of existing benzimidazole derivatives, and the anticancer properties of a new class of benzimidazole derivatives. This book examines aspects and newer mechanisms of benzimidazoles containing heterocyclic moiety. Chapters report on anticancer properties of benzimidazole derivatives, novel methods of synthesis of benzimidazoles, versatile nature of the benzimidazoles, spectral and theoretical studies of benzimidazole derivatives, and medicinal importance and pharmacological aspects of benzimidazole derivatives.
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry
    Language: English
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  • 3
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-05
    Description: Green Chemistry - New Perspectives is at the frontiers of this continuously evolving interdisciplinary science, and publishes research that attempts to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. The book covers all aspects of green chemistry, including chemical synthesis, nano synthesis, eco-friendly processes, biomass, extraction techniques, environmental remediation, and energy, making it a unique reference resource. This will continue to encourage scientists around the world to develop novel synthetic methods or improve the existing ones to circumvent some of the problems and favours all aspects of green chemistry. This book is intended for academia, professionals, scientists, as well as graduate and undergraduate students without any geographical limitations.
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry
    Language: English
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  • 4
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    EDP SCIENCES
    Publication Date: 2024-04-05
    Description: Chemistry
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry::PNNP Polymer chemistry
    Language: French
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  • 5
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    EDP SCIENCES
    Publication Date: 2024-04-05
    Description: Chemistry
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry::PNNP Polymer chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry::PNNP Polymer chemistry
    Language: French
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  • 6
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-05
    Description: This book consists of several selected chapters on important subjects in modern high-performance liquid chromatography (HPLC) and ultra-performance liquid chromatography (UPLC). The content addresses aspects related to both improvements in the mainstream HPLC/UPLC technology and utilization, as well as developments of exploratory new materials and equipment. The book presents useful details about the presented subjects as well as describes new applications and/or relevant case studies for each subject. It is addressed to a large audience of analytical chemists involved in separation science. Each chapter is authored by scientists with considerable field and academic experience.
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNF Analytical chemistry
    Language: English
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  • 7
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    EDP SCIENCES
    Publication Date: 2024-04-07
    Description: Chemistry
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry::PNNP Polymer chemistry
    Language: French
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  • 8
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-05
    Description: Recent Advances in Chemical Kinetics provides a comprehensive overview of several types of chemical reactions. It includes six chapters that discuss solvent catalysis, customized flow reactors, p-conjugation in kinetics, kinetics of autoxidation, molecular chameleon for cations and anions, and internal clocks of atoms.
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNR Physical chemistry
    Language: English
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  • 9
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    Taylor & Francis | CRC Press
    Publication Date: 2024-03-31
    Description: Hydroxyapatite coatings are of great importance in the biological and biomedical coatings fields, especially in the current era of nanotechnology and bioapplications. With a bonelike structure that promotes osseointegration, hydroxyapatite coating can be applied to otherwise bioinactive implants to make their surface bioactive, thus achieving faster healing and recovery. In addition to applications in orthopedic and dental implants, this coating can also be used in drug delivery. Hydroxyapatite Coatings for Biomedical Applications explores developments in the processing and property characterization and applications of hydroxyapatite to provide timely information for active researchers and newcomers alike. In eight carefully reviewed chapters, hydroxyapatite experts from the United States, Japan, Singapore, and China present the latest on topics ranging from deposition processes to biomedical applications in implants and drug delivery. This book discusses: Magnetron sputtering and electrochemical deposition The modification of hydroxyapatite properties by sol–gel deposition to incorporate other elements found in natural bones, such as zinc, magnesium, and fluorine The use of pure hydroxyapatite in drug delivery applications The growth or self-assembly of hydroxyapatite on shape memory alloy Hydroxyapatite composite coatings—with carbon nanotubes, titanium dioxide (TiO2), and others—on the titanium alloy Offering valuable insights and a wealth of data, including numerous tables and figures, this is a rich source of information for research on hydroxyapatite coatings. Each chapter also covers material that provides an accessible stepping stone for those who are new to the field.
    Keywords: Pre-clinical medicine: basic sciences ; Chemistry ; Materials science ; thema EDItEUR::M Medicine and Nursing::MF Pre-clinical medicine: basic sciences ; thema EDItEUR::P Mathematics and Science::PN Chemistry ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGM Materials science
    Language: English
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  • 10
    Publication Date: 2024-04-05
    Description: Chemiebezogene Kompetenzen werden bereits im Sachunterricht der Grundschule entwickelt und sollen im Chemieunterricht der Sekundarstufe I aufgegriffen und weiterentwickelt werden. Ziel dieser Studie war es, die chemiebezogenen Kompetenzen der Schülerinnen und Schüler in der Übergangsphase zwischen Sachunterricht und Chemieunterricht zu analysieren. In einer Ergänzungsstudie wurden zusätzlich sowohl die Auswirkungen der Schulschließungen aufgrund der SARS-CoV-II Pandemie auf die Kompetenzen der Schülerinnen und Schüler als auch der Einfluss einer veränderten Testadministration untersucht. Insgesamt wurden die Kompetenzen von 2262 Lernenden der Jahrgangsstufen 5 bis 9 zu drei Messzeitpunkten analysiert. Die Ergebnisse zeigen, dass die chemiebezogenen Kompetenzen sowohl zum Ende der Grundschulzeit als auch zu Beginn des Chemieunterrichts über alle Kompetenzbereiche hinweg sehr heterogen ausfallen. Dennoch sind sie zu Beginn des Chemieunterrichts in einigen Kompetenzbereichen höher ausgeprägt als zum Ende der Grundschulzeit. Nach den pandemiebedingten Schulschließungen waren die Kompetenzen ähnlich ausgeprägt wie in den gleichen Jahrgangsstufen vor den Schulschließungen. Eine während der Schulschließungen notwendige Bearbeitung der Testhefte von zu Hause aus führte vor allem bei den jüngeren Schülerinnen und Schülern zu besseren Testergebnissen als die Bearbeitung in der Schule. Um die Entwicklung chemiebezogener Kompetenzen in der Übergangsphase zu optimieren, sollte der Erwerb dieser Kompetenzen bereits im Sachunterricht einheitlicher gestaltet werden.
    Keywords: Science ; Chemistry ; Education ; thema EDItEUR::P Mathematics and Science::PN Chemistry ; thema EDItEUR::J Society and Social Sciences::JN Education
    Language: German
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  • 11
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-05
    Description: Redox reactions are involved in biochemistry, energy, corrosion, and much more. In both biology and electrochemistry, the redox reaction is complex and varied. For example, redox shuttles in supercapacitors show aspects of molecular electrochemistry applied to electrode porosity. In pseudocapacitors, the formalism associated with their electrochemical response requires investigation and formalism. Similarly, the simple definition of redox potential opens fundamental questions about its measurement in solutions without supporting salts. This book illustrates the variety of redox reactions in its examination of the importance of redox molecules in the development of new electrical energy storage devices.
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNR Physical chemistry::PNRH Electrochemistry and magnetochemistry
    Language: English
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  • 12
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    Logos Verlag Berlin | Logos Verlag Berlin
    Publication Date: 2024-04-05
    Description: In 2005, the hybrid model was published by Prof. H.-D. Alber and Prof. P. Zhu as an alternative to the Allen-Cahn model for the description of phase field transformations. With low interfacial energy, it is more efficient, since the resolution of the diffuse interface is numerically broader for the same solution accuracy and allows coarser meshing. The solutions of both models are associated with energy minimisation and in this work the error terms introduced in the earlier publications are discussed and documented using one and two dimensional numerical simulations. In the last part of this book, phase field problems, initially not coupled with material equations, are combined with linear elasticity and, after simple introductory examples, a growing martensitic inclusion is simulated and compared with literature data. In addition to the confirmed numerical advantage, another phenomenon not previously described in the literature is found: with the hybrid model, in contrast to the examples calculated with the Allen-Cahn model, an inclusion driven mainly by curvature energy does not disappear completely. The opposite problem prevents inclusions from growing from very small initial configurations, but this fact can be remedied by a very finely chosen diffuse interface width and by analysing and adjusting the terms that generate the modelling errors. The last example shows that the hybrid model can be used with numerical advantages despite the above mentioned peculiarities.
    Keywords: Science ; Chemistry ; Mathematics ; Science ; Physics ; thema EDItEUR::P Mathematics and Science::PN Chemistry ; thema EDItEUR::P Mathematics and Science::PB Mathematics ; thema EDItEUR::P Mathematics and Science::PH Physics
    Language: English
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  • 13
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-05
    Description: We are living in a critical time, both for humanity and the planet, which has led us to look for more sustainable formulas to interact with the environment. One of the important changes in the design and operation of chemical processes is the search for environmentally friendly technologies. Supercritical carbon dioxide has been revealed as a promising environmentally friendly solvent that is energy efficient, selective and capable of reducing waste, making it a promising alternative to conventional organic solvents. However, reliable and versatile mathematical models of phase equilibrium thermodynamics are needed for the use of supercritical carbon dioxide in process design and viability studies. This book reviews experimental procedures for obtaining high-pressure phase equilibria data and describes the phase diagrams of binary mixtures and some thermodynamic models capable of determining the conditions of phase equilibria at high pressures. These concepts are applied to the components of the transesterification reaction of rac-2-pentanol with a vinyl ester, which is important in the pharmaceutical industry because (S)-2-pentanol can be obtained as a reaction product. This product is a key intermediate in the synthesis of drugs against Alzheimer’s disease.
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNR Physical chemistry
    Language: English
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  • 14
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    MDPI - Multidisciplinary Digital Publishing Institute
    Publication Date: 2024-04-05
    Description: Nanofibers, particularly those of a carbonaceous content, have received increased interest in the past two decades due to their outstanding physico-chemical characteristics and their possibility to form and contribute towards a plethora of potentially advantageous materials for consumer, industrial and medical applications. Despite this, and together with the numerous research studies and published articles that have sought to investigate these aspects, the potential impact of CNTs is still not understood. Whether or not nanofibers may be able to provide a sophisticated alternative to conventional materials is still debatable, whilst their effects upon both environmental and human health are highly equivocal. How nanofibers are conceived can determine how they may interact with different environments, such as the human body. Understanding each key step of the synthesis and production of nanofibers to their use within potential applications is therefore essential in gaining an insight into how they may be perceived by any biological system and environment. Thus, obtaining such information will enable all scientific communities to begin to realize the potential advantages posed by nanofibers. The aim of this Special Issue therefore, was to provide a collective overview of nanofibers; ‘from synthesis to application’. The Issue particularly focuses upon carbon-based nanofibers, but also highlights alternative nanofiber types. Emphasis is given holistically, with articles discussing the production routes of nanofibers, their plight during their life-cycle (origin to applied form and effects over time), as well as how nanofibers could either incite conflict, or provide aid to human and environmental health.
    Keywords: QD1-999 ; Toxicology ; Chemistry ; Biology ; Material Science ; Nanofibers ; Nanotechnology ; thema EDItEUR::P Mathematics and Science::PN Chemistry
    Language: English
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  • 15
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-05
    Description: In recent decades, artificial porous structures have attracted increasing enthusiasm from researchers inspired by the fascinating molecular pores in nature and their unique biological functions. Although substantial achievements in porous materials have been realized, the construction of topologically designed pores is still challenging. Recently, the emergence of covalent organic frameworks (COFs), which are constructed based on organic and polymer chemistry, has made it possible to design artificial pores with controlled pore size, topology and interface properties. COFs are crystalline porous materials constructed by the precise reticulation of organic building blocks via dynamic covalent bonds. Distinct from non-covalent interactions which tend to produce isostructures, covalent bonds enable accurate pore design owing to their predetermined reaction pathways. In addition, the appropriate polycondensation of organic building units enables the formation of extended two-dimensional (2D) and three-dimensional (3D) polymer architectures with periodically ordered skeletons and well-defined pores. With their large surface area, tailorable structures, and tunable chemistry, COFs are regarded as potentially superior candidates for various applications including catalysis, energy storage and conversion, mass transport and biotechnology. This book examines the historic achievement of COFs, providing clear and comprehensive guidance for researchers on their structural design, synthetic protocols and functional exploration.
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry
    Language: English
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  • 16
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-05
    Description: Fluoride covers a continuum of topics that are frequently studied in the broad area of fluoride (F) research. It provides an overview of the primary sources of environmental fluoride in typical high-fluoride environments and demonstrates the transitions and transformations that emerge and culminate in hydro-geochemical interactions that result in fluoride-fouling of large portions of the world’s water and agricultural resources. This way, the book pinpoints the connection between F enrichment of water sources and the prevalence of endemic fluorosis in certain areas of the world. In order to contribute to a better understanding of the global fluoride problem, new fluoride detection and quantification technologies are proposed with an in-depth analysis of emerging trends in the use of portable user-friendly devices in point-of-use measurements of water fluoride. This has been presented against the backdrop of a robust overview of traditional fluoride quantification methodologies that are still in wide application among the scientific communities. In addressing fluoride toxicities, which are not limited to dental and skeletal dilapidations, the authors have explored the role of natural antioxidants in ameliorating physiological fluoride-induced noxious effects in mammalian systems. Nonetheless, since community dependence on high-fluoride water due to a lack of alternative clean water sources remains to be the principal pathway of human fluoride over-exposure, a review chapter on F mitigation techniques applied all over the world is incorporated aiming at providing a succinct overview of water defluoridation techniques and strategies being used to combat the impacts of human F overexposure around the globe. Since every cloud has a silvery lining, the possibility of using ammonium fluorides as a novel reagent in mineral processing has been considered convenient industrial fluorinating agents, which present the possibility of complete regeneration that is not afforded by the reagents presently used in decomposing silicon component of the ores.
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNK Inorganic chemistry
    Language: English
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  • 17
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-05
    Description: This book discusses the chemistry and applications of pyridine derivatives. The library of pyridine derivatives is growing steadily with numerous synthetic analogues already described and the identification of new, naturally occurring pyridine-based compounds. The book includes ten chapters organized into two parts. The first part focuses on the numerous types of reactions that arise from pyridine derivatives. The second part examines the pharmaceutical applications of pyridine derivatives as well as their usefulness as sensors for metal cations and extracting agents for platinum group metals.
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry
    Language: English
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  • 18
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-05
    Description: The book discusses multiple issues associated with modern dosimetry in physics and treatment planning and how investigators from diverse world centers and institutions approach problem-solving in these important areas. It examines topics including pretreatment validation and factors affecting reference dosimetry. It also addresses unique issues affecting pediatric populations as well as the modern role of thermoluminescence validation. Several chapters discuss intensity modulation, including defining modern problems associated with both treatment planning and the definition of tumor and normal tissue contours. Furthermore, the book examines the role of imaging as both a vehicle to define tumor targets and normal tissue as well as a tool for dose validation.
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNR Physical chemistry::PNRL Nuclear chemistry, photochemistry and radiation
    Language: English
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  • 19
    Publication Date: 2024-04-05
    Description: Das selbstgesteuerte Experimentieren ist laut den nationalen Bildungsstandards sowie den Lehrplänen im Fach Chemie ein wichtiger Bestandteil der naturwissenschaftlichen Schulbildung. Offene Experimentierformen sind jedoch wenig etabliert. Um das selbstgesteuerte Experimentieren in die Unterrichtspraxis zu implementieren, wurde im Rahmen dieses Forschungsprojekts eine eintägige Lehrkräftefortbildung zur Konzeption von selbstgesteuerten Experimenten im Chemieunterricht durchgeführt. Dazu wurde ein literaturbasiertes Strukturierungskonzept entwickelt, mit dem die Lehrkräfte kochbuchartige Schulversuche zu selbstgesteuerten und kompetenzorientierten Experimenten mit beliebigen Öffnungsgraden modifizieren können. Begleitend zur Fortbildung wurde im Prä-Post-Follow-Up-Design das fachdidaktische Wissen der Teilnehmenden hinsichtlich der Planung von selbstgesteuerten Experimenten empirisch überprüft. Zur Erfassung dieses Konstrukts wurde ein neues Messinstrument literaturbasiert entwickelt und die Güte des Messinstruments evaluiert. Die Auswertungen zeigen, dass die Fortbildung hinsichtlich des fachdidaktischen Wissens der Lehrkräfte kurz- sowie langfristig lernförderlich ist und die Fortbildung von den Teilnehmenden positiv bewertet wird. Die Reliabilitätsanalyse sowie die Validierungsstudie zeigen, dass der Test sowohl reliabel als auch valide ist. In Folgestudien könnte die langfristige Verhaltensänderung der Lehrkräfte bezüglich der Implementierung des selbstgesteuerten Experimentierens in den Unterricht untersucht werden.
    Keywords: Science ; Chemistry ; Science ; Education ; thema EDItEUR::P Mathematics and Science::PN Chemistry ; thema EDItEUR::P Mathematics and Science::PD Science: general issues ; thema EDItEUR::J Society and Social Sciences::JN Education
    Language: German
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  • 20
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-05
    Description: The book comprises 14 chapters covering all the issues related to water desalination. These chapters emphasize the relationship between problems encountered with the use of feed water, the processes developed to address them, the operation of the required plants and solutions actually implemented. This compendium will assist designers, engineers and investigators to select the process and plant configuration that are most appropriate for the particular feed water to be used, for the geographic region considered, as well as for the characteristics required of the treated water produced. This survey offers a comprehensive, hierarchical and logical assessment of the entire desalination industry. It starts with the worldwide scarcity of water and energy, continues with the thermal - and membrane-based processes and, finally, presents the design and operation of large and small desalination plants. As such, it covers all the scientific, technological and economical aspects of this critical industry, not disregarding its environmental and social points of view. One of InTech's books has received widespread praise across a number of key publications. Desalination, Trends and Technologies (Ed. Schorr, M. 2011) has been reviewed in Corrosion Engineering, Science & Technology – the official magazine for the Institute of Materials, Minerals & Mining, and Taylor & Francis's Desalination Publications. Praised for its “multi-faceted content [which] contributes to enrich it,” and described as “an essential companion...[that] enables the reader to gain a deeper understanding of the desalination industry,” this book is testament to the quality improvements we have been striving towards over the last twelve months.
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNF Analytical chemistry
    Language: English
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  • 21
    Publication Date: 2024-04-05
    Description: The Global Methane Initiative (GMI) is a voluntary international partnership that promotes methane recovery and reuse activities in developing and transition economies. The U.S. Department of State requested an evaluation of the activities and outcomes supported in whole or in part by its contributions to GMI to gauge its value added to the program.
    Keywords: Physics ; Environmental Science ; Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TQ Environmental science, engineering and technology ; thema EDItEUR::R Earth Sciences, Geography, Environment, Planning::RB Earth sciences::RBP Meteorology and climatology
    Language: English
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  • 22
    Publication Date: 2024-04-04
    Description: This volume, occasioned by the centenary of the Fritz Haber Institute, formerly the Institute for Physical Chemistry and Electrochemistry, covers the institute's scientific and institutional history from its founding until the present. The institute was among the earliest established by the Kaiser Wilhelm Society, and its inauguration was one of the first steps in the development of Berlin-Dahlem into a center for scientific research. Its establishment was made possible by an endowment from Leopold Koppel, granted on the condition that Fritz Haber, well-known for his discovery of a method to synthesize ammonia from its elements, be made its director. The history of the institute has largely paralleled that of 20th-century Germany. It undertook controversial weapons research during World War I, followed by a "Golden Era" during the 1920s, in spite of financial hardships.
    Keywords: Chemistry ; Chemistry ; Fritz Haber Institute ; thema EDItEUR::P Mathematics and Science::PD Science: general issues::PDX History of science
    Language: English
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  • 23
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-05
    Description: Progress in agricultural, biomedical and industrial applications' is a compilation of recent advances and developments in gas chromatography and its applications. The chapters cover various aspects of applications ranging from basic biological, biomedical applications to industrial applications. Book chapters analyze new developments in chromatographic columns, microextraction techniques, derivatisation techniques and pyrolysis techniques. The book also includes several aspects of basic chromatography techniques and is suitable for both young and advanced chromatographers. It includes some new developments in chromatography such as multidimensional chromatography, inverse chromatography and some discussions on two-dimensional chromatography. The topics covered include analysis of volatiles, toxicants, indoor air, petroleum hydrocarbons, organometallic compounds and natural products. The chapters were written by experts from various fields and clearly assisted by simple diagrams and tables. This book is highly recommended for chemists as well as non-chemists working in gas chromatography.
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNF Analytical chemistry
    Language: English
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  • 24
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-05
    Description: This book discusses electrocatalysis and electrocatalysts for energy, water electrolysis, water treatment, CO2 conversion, and green chemistry. It reviews various electrocatalysts and their properties and electrochemical performances. The first section of the book covers topics in direct alcohol fuel cells including Pt-based electrocatalysts as non-carbon electrode support materials and the development of electrocatalysts for direct methanol fuel cells. The second section of the book covers various topics in electrocatalysis and electrocatalysts for a cleaner environment, including electrocatalysts for the conversion of CO2 to valuable products and SYNGAS, electrocatalysts for water electrolysis, and much more.
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNR Physical chemistry::PNRH Electrochemistry and magnetochemistry
    Language: English
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  • 25
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    transcript Verlag | transcript Verlag
    Publication Date: 2024-04-04
    Description: Die Chemie büßt zugunsten physikalischer und lebenswissenschaftlicher Konzeptionen zunehmend an Deutungsmacht über die molekulare Welt ein. Sandra Lang untersucht, inwiefern die Ausdifferenzierung der chemischen Wissenschaften mit sich ebenfalls ausdifferenzierenden Zugriffen auf das Molekulare zusammenhängt. Anhand der vier exemplarischen Grenzfelder Materialwissenschaften, Biomedizin, Pharmazie und Quantenchemie und deren Narrative zur molekularen Eigenschaft der Chiralität veranschaulicht sie die transformative Phase der Chemie angesichts sich wandelnder Innovationsdispositive.
    Keywords: Chemie ; Chiralität ; Molekülkonzept ; Naturwissenschaften ; Grenzarbeit ; Interdisziplinarität ; Hybridität ; Wissenschaft ; Technik ; Wissenschaftssoziologie ; Techniksoziologie ; Wissenssoziologie ; Wissenschaftsgeschichte ; Soziologie ; Chemistry ; Chirality ; Molecule Concept ; Natural Sciences ; Border Work ; Interdisciplinarity ; Hybridity ; Science ; Technology ; Sociology of Science ; Sociology of Technology ; Sociology of Knowledge ; History of Science ; Sociology ; thema EDItEUR::P Mathematics and Science::PD Science: general issues::PDR Impact of science and technology on society ; thema EDItEUR::J Society and Social Sciences::JH Sociology and anthropology::JHB Sociology
    Language: German
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  • 26
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-05
    Description: Surfactants are ubiquitous and have applications in diverse areas, including food, cosmetics, detergents, lubricants, enhanced oil recovery (EOR), and targeted drug delivery systems. Their wide diversity of applications owes to their unique structure, namely, a hydrophilic and a hydrophobic group present in the same molecule. Although most surfactants used industrially are synthetic, there is a growing need for natural surfactants, as the latter is obtainable from renewable sources and are less toxic and highly biodegradable in contrast to their synthetic counterparts. This book is a compilation of interesting articles by various experts that cover various applications of both synthetic and natural surfactants.
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNR Physical chemistry::PNRC Colloid chemistry
    Language: English
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  • 27
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-05
    Description: The chemical sensor plays an essential role in the fields of environmental conservation and monitoring, disaster and disease prevention, and industrial analysis. A typical chemical sensor is a device that transforms chemical information in a selective and reversible way, ranging from the concentration of a specific sample component to total composition analysis, into an analytically useful signal. Much research work has been performed to achieve a chemical sensor with such excellent qualities as quick response, low cost, small size, superior sensitivity, good reversibility and selectivity, and excellent detection limit. This book introduces the latest advances on chemical sensors. It consists of 15 chapters composed by the researchers active in the field of chemical sensors, and is divided into 5 sections according to the classification following the principles of signal transducer. This collection of up-to-date information and the latest research progress on chemical sensor will provide valuable references and learning materials for all those working in the field of chemical sensors.
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNF Analytical chemistry
    Language: English
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    EDP SCIENCES
    Publication Date: 2024-04-05
    Description: Chemistry
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry::PNNP Polymer chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry::PNNP Polymer chemistry
    Language: French
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  • 29
    Publication Date: 2024-04-05
    Description: Chemistry
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry::PNNP Polymer chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry::PNNP Polymer chemistry
    Language: French
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    De Gruyter | De Gruyter
    Publication Date: 2024-04-11
    Description: Presents technologies and key concepts to produce suitable smart materials and intelligent structures for sensing, information and communication technology, biomedical applications (drug delivery, hyperthermia therapy), self-healing, flexible memories and construction technologies. Novel developments of environmental friendly, cost-effective and scalable production processes are discussed by experts in the field.
    Keywords: Science ; Chemistry ; Industrial & Technical ; Technology & Engineering ; Textiles & Polymers ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TD Industrial chemistry and manufacturing technologies::TDC Industrial chemistry and chemical engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGM Materials science
    Language: English
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-05
    Description: Distillation is an important separation technique that has been used for many centuries to exploit the volatility differences between components in a mixture. The distillation process has many variations and applications. This book includes two sections on desalination and reactive distillation. It discusses desalination in the processes of solar and membrane distillation, with a focus on the reduction of energy costs to obtain potable water. It also discusses reactive distillation, which can be used in some cases to reduce the power duty in the separation process by using the reaction heat directly in the separation. The book includes cases of mathematical modeling, simulation, and optimization of the distillation process.
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNF Analytical chemistry
    Language: English
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    Logos Verlag Berlin | Logos Verlag Berlin
    Publication Date: 2024-04-05
    Description: Konsumgüter werden beispielsweise mit Slogans wie "Gut in Bio. Schlecht in Chemie." beworben. Dabei wird intendiert, sich gezielt von "Chemie" abzugrenzen und sich das positive Bild von "Natur" zu Nutze zu machen. Dies prägt die öffentliche Meinung und trägt zu einer antagonistisch-wertenden Sicht von "Chemie" und "Natur" bei. Dass Chemie als Naturwissenschaft der Beschreibung der Natur dient, um deren Stoffe und Stoffumwandlungen zu erklären, ist dem Laien selten bewusst. Chemie findet überall statt, insbesondere in der Natur! Genau an diesem Punkt setzt das Unterrichtskonzept "Chemie Pur - Unterrichten in der Naturglqq an. Ziel ist es, im Freiland, mit direkt vor Ort gewonnenen Naturstoffen, Umweltprozesse experimentell zu erarbeiten. Die projektbegleitende Evaluationsstudie stellte sich der Forschungsfrage, wie sich das Unterrichtskonzept auf das Fach- und Sachinteresse, auf die Naturverbundenheit sowie auf die Einstellung zu Chemie und Natur von Schülerinnen und Schülern der Sekundarstufe II auswirkt. Die Auswertung der Fragebogenergebnisse mit latenten Veränderungsmodellen haben gezeigt, dass die Intervention im Freiland das inhaltsbezogene Sachinteresse steigert und die Einstellung zu Chemie und Natur positiv beeinflusst sowie ein erhöhten Fachwissenszuwachs ermöglicht. Die gewonnenen Erkenntnisse können die Grundlage für die Entwicklung und Evaluation von good-practice-Ansätzen naturwissenschaftlicher Lernsituationen bilden. Das Unterrichtskonzept Chemie Pur leistet zudem einen Beitrag im Bereich Outdoor Education, um den Antagonismus von Chemie und Natur zu verringern.
    Keywords: Science ; Chemistry ; Science ; Education ; thema EDItEUR::P Mathematics and Science::PN Chemistry ; thema EDItEUR::P Mathematics and Science::PD Science: general issues ; thema EDItEUR::J Society and Social Sciences::JN Education
    Language: German
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    De Gruyter | De Gruyter
    Publication Date: 2024-04-05
    Description: Comprise definition of 1500 terms. Innovation from A to Z presents a glossary, including: Terms, older terms whose meanings have changed, acronyms, synonyms, famous names, selected abbreviations, and cross-references. A highly interdisciplinary approach incorporating strategy and entrepreneurship with technology and engineering sciences, economics, marketing, organizational behavior and theory. Ideal for engineers, managers, sales people and economists. Innovation Technology from A to Z Glossary of terms, including acronyms, synonyms, abbreviations, cross-references 1500 terms supplemented by figures and tables that clearly demonstrate the state-of-the-art in Innovation Technology
    Keywords: Science ; Chemistry ; Technology & Engineering ; Agriculture ; thema EDItEUR::P Mathematics and Science::PN Chemistry ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TV Agriculture and farming
    Language: English
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    EDP SCIENCES
    Publication Date: 2024-04-08
    Description: Chemistry
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry::PNNP Polymer chemistry
    Language: French
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  • 35
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-05
    Description: Cyclodextrins (CDs) have attracted great interest from the research community as well as industries in an array of sectors because of their unique structural features. This book provides a comprehensive overview of CDs, beginning with their historical background. Chapters address such topics as the structure and physiochemical properties of CDs, advancements in the field, and potential applications of these materials in fields such as drug delivery and sensing. This book reveals new frontiers in the CD world and is a useful resource for organic, analytical, and supramolecular chemists as well as scientists engaged in biological and material sciences.
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry::PNNP Polymer chemistry
    Language: English
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  • 36
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-05
    Description: The book presents a comprehensive overview of sorption, which is a multi-parametric separation process. It is extensively used in the removal of various pollutants from the tertiary stage of wastewater treatment, from leachates, etc. It discusses fundamental points of the technique as well as kinetic theories and isotherms. It also examines the synthesis and characterizations of all studied adsorbent materials to find their paths of sorption. Finally, it highlights the importance of having a cost-estimation plan for the synthesis of sorbent materials as well as predictions for their reusability.
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNR Physical chemistry::PNRX Surface chemistry and adsorption
    Language: English
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  • 37
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    EDP SCIENCES
    Publication Date: 2024-04-05
    Description: Chemistry;Materials science
    Keywords: Chemistry ; Materials science ; thema EDItEUR::P Mathematics and Science::PN Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry::PNNP Polymer chemistry
    Language: French
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  • 38
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    The MIT Press | The MIT Press
    Publication Date: 2024-03-27
    Description: The original 1818 text of Mary Shelley's classic novel, with annotations and essays highlighting its scientific, ethical, and cautionary aspects. Mary Shelley's Frankenstein has endured in the popular imagination for two hundred years. Begun as a ghost story by an intellectually and socially precocious eighteen-year-old author during a cold and rainy summer on the shores of Lake Geneva, the dramatic tale of Victor Frankenstein and his stitched-together creature can be read as the ultimate parable of scientific hubris. Victor, “the modern Prometheus,” tried to do what he perhaps should have left to Nature: create life. Although the novel is most often discussed in literary-historical terms—as a seminal example of romanticism or as a groundbreaking early work of science fiction—Mary Shelley was keenly aware of contemporary scientific developments and incorporated them into her story. In our era of synthetic biology, artificial intelligence, robotics, and climate engineering, this edition of Frankenstein will resonate forcefully for readers with a background or interest in science and engineering, and anyone intrigued by the fundamental questions of creativity and responsibility. This edition of Frankenstein pairs the original 1818 version of the manuscript—meticulously line-edited and amended by Charles E. Robinson, one of the world's preeminent authorities on the text—with annotations and essays by leading scholars exploring the social and ethical aspects of scientific creativity raised by this remarkable story. The result is a unique and accessible edition of one of the most thought-provoking and influential novels ever written. Essays by Elizabeth Bear, Cory Doctorow, Heather E. Douglas, Josephine Johnston, Kate MacCord, Jane Maienschein, Anne K. Mellor, Alfred Nordmann
    Keywords: science fiction ; gothic ; horror ; European ; British ; literature ; fiction ; cautionary tale ; STEM ; science ; bioethics ; classic ; bicentennial ; Josephine Johnston ; Cory Doctorow ; Jane Maienschein ; Kate MacCord ; Alfred Nordmann ; Elizabeth Bear ; Anne K. Mellor ; Heather E. Douglas ; Frankenstein ; Creature ; Monster ; Mary Shelley ; Makers ; women in science ; science and anti-science ; values in science ; responsible innovation ; Industrial Revolution ; Mary Wollstonecraft ; William Godwin ; Percy Bysshe Shelley ; Galvanism ; Mount Tambora ; Myths ; Two Cultures ; epistolary novel ; Victor Frankenstein ; Geneva ; Prometheus ; Arctic ; Lord Byron ; John Polidori ; ghost stories ; Revisions ; Electricity ; Lightning ; Vitalism ; Chemistry ; Extinction ; Magnetism ; Moral responsibility ; Legal responsibility ; Social responsibility ; Consequences ; Obligations ; Ethics ; Maker Culture ; DIY ; Technology Adjacent Possible ; Facebook ; Surveillance ; Aristotle ; Fetal development ; Epigenesis ; Embryo ; Person ; Technoscience ; Alchemy ; uncanny valley ; animation ; complexity ; Morality ; Monstrosity ; Christianity ; Otherness ; Gender ; Nature ; Domestic Affections ; Women ; Sexuality ; Technical Sweetness ; Los Alamos ; Trinity Test ; Scientific Responsibility ; Nuclear Weapons ; adjacent possible ; synthetic biology ; robotics ; thema EDItEUR::F Fiction and Related items::FB Fiction: general and literary::FBC Classic fiction: general and literary ; thema EDItEUR::F Fiction and Related items::FL Science fiction::FLC Classic science fiction
    Language: English
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    Coimbra University Press
    Publication Date: 2022-01-31
    Description: This work brings together various contributions from experts in very diverse areas of knowledge, to discuss the theme ‘Light’ from various points of view. The subjects gathered in this work come from the areas of Physics, Philosophy, Transcendence, Chemistry, Optics, Literature, History of Sciences, History, Geography, International Relations, Biology, Psychology, Art, Cinema and Photography, Medicine and Museology. The texts partially reflect the contents presented at the interdisciplinary colloquium ‘Visões da Luz’ held in October 2015, on the occasion of the International Year of Light 2015, under the aegis of III-UC and open to academia and society, to teachers of the Basic and Secondary Education.
    Keywords: Geography ; Chemistry ; Literature ; Geology ; Light ; Optics ; Biology ; History ; Physics
    Language: Portuguese
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-05
    Description: Carotenoids are natural and versatile secondary metabolites, most of them showing colours that vary from yellow to red. They are widespread among living beings where they are involved in many biological roles reporting beneficial actions. To date, more than 750 carotenoids have been described in nature. Humans cannot synthesize carotenoids de novo, thus they are mainly obtained through diet. In fact, carotenoids are consistently found in tissues or biological fluids where they play a beneficial decreasing the risk of developing some diseases.During the last half-century, significant advances in carotenoids research have been made. This book highlights new perspectives and applications of carotenoids including characterization and isolation of new compounds (including rare carotenoids), their production at a mid-large scale (involving new innovative approaches), and uses of carotenoids in different biotechnological fields like food science, biomedicine, and cosmetics.
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry
    Language: English
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    EDP SCIENCES
    Publication Date: 2024-04-05
    Description: Chemistry
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNN Organic chemistry::PNNP Polymer chemistry
    Language: French
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    IntechOpen | IntechOpen
    Publication Date: 2024-04-05
    Description: Infrared Spectroscopy - Perspectives and Applications is a compendium of contributions from experts in the field of infrared (IR) spectroscopy. This assembly of investigations and reviews provides a comprehensive overview of the fundamentals as well as the groundbreaking applications in the field. Chapters discuss IR spectroscopy applications in the food and biomedicine sectors and for measuring transport through polymer membranes, characterizing lignocellulosic biomasses, detecting adulterants, and characterizing enamel surface advancements. This book is an invaluable resource and reference for students, researchers, and other interested readers.
    Keywords: Chemistry ; thema EDItEUR::P Mathematics and Science::PN Chemistry::PNF Analytical chemistry::PNFS Spectrum analysis, spectrochemistry, mass spectrometry
    Language: English
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    Logos Verlag Berlin | Logos Verlag Berlin
    Publication Date: 2024-04-05
    Description: When auralizing moving sound sources in Virtual Reality (VR) environments, the two main input parameters are the location and radiated signal of the source. An array measurement-based model is developed to characterize moving sound sources regarding the two parameters in this thesis. This model utilizes beamforming, i.e. delay and sum beamforming (DSB) and compressive beamforming (CB) to obtain the locations and signals of moving sound sources. A spiral and a pseudorandom microphone array are designed for DSB and CB, respectively, to yield good localization ability and meet the requirement of CB. The de-Dopplerization technique is incorporated in the time-domain DSB to address moving source problems. Time-domain transfer functions (TDTFs) are calculated in terms of the spatial locations within the steering window of the moving source. TDTFs then form the sensing matrix of CB, thus allowing CB to solve moving source problem. DSB and CB are further extended to localize moving sound sources, and the reconstructed signals from the beamforming outputs are investigated to obtain the source signals. Moreover, localization and signal reconstruction are evaluated through varying parameters in the beamforming procedures, i.e. steering position, steering window length and source speed for a moving periodic signal using DSB, and regularization parameter, signal to noise ratio (SNR), steering window length, source speed, array to source motion trajectory and mismatch for a moving engine signal using CB. The parameter studies show guidelines of parameter selection based on the given situations in this thesis for modeling moving source using beamforming. Both algorithms are able to reconstruct the moving signals in the given scenarios. Although CB outperforms DSB in terms of signal reconstruction under particular conditions, the localization abilities of the two algorithms are quite similar. The practicability of the model has been applied on pass-by measurements of a moving loudspeaker using the designed arrays, and the results can match the conclusions drawn above from simulations. Finally, a framework on how to apply the model for moving source auralization is proposed.
    Keywords: Science ; Chemistry ; Technology & Engineering ; Construction ; Technology & Engineering ; thema EDItEUR::P Mathematics and Science::PN Chemistry ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TN Civil engineering, surveying and building::TNK Building construction and materials ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues
    Language: English
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  • 44
    Publication Date: 2024-04-05
    Description: Neuere Erkenntnisse zum Umsatzverhalten an Dieseloxidationskatalysatoren (DOCs) zeigen, dass das Umsatzverhalten von Schadstoffen vom Oxidationsgrad der verwendeten Edelmetallkatalysatoren abhängen kann. Dabei wird deutlich, dass sich der Oxidationsgrad bei typischen Abgaszusammensetzungen langsam und reversibel mit der Katalysatortemperatur ändert. Das kann bei periodischen Katalysatortemperaturänderungen zu einem ausgeprägten Hystereseverhalten führen. Bisherige Ergebnisse liegen insbesondere zum Verhalten der NO-Oxidation an Platin-Katalysatoren vor. Ziel der vorliegenden Arbeit ist es daher, die Untersuchungen auf seriennahe Pd- und PtPd-Mischkatalysatoren sowie auf andere abgastypische Schadstoffe, wie CO und Kohlenwasserstoffe, zu erweitern und dabei auch den Einfluss der Katalysatoralterung zu erfassen. Es wurde ein globalkinetisches Modell entwickelt und an die experimentellen Befunde angepasst. Dabei zeigte sich, dass es in der Regel möglich ist, das Umsatzverhalten bei reinen Pt- und Pd-Katalysatoren mit diesem örtlich eindimensionalen, makrokinetischen Zweiphasenmodell zutreffend zu beschreiben, wohingegen das Verhalten auf Pt/Pd-Mischkatalysatoren weniger gut simuliert werden kann. Dies ist vermutlich auf die heterogene Struktur der Pt/Pd-legierten Partikel zurückzuführen.
    Keywords: Science ; Chemistry ; Technology & Engineering ; Chemical & Biochemical ; thema EDItEUR::P Mathematics and Science::PN Chemistry ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TD Industrial chemistry and manufacturing technologies::TDC Industrial chemistry and chemical engineering
    Language: German
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  • 45
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 118 (1980), S. 128-151 
    ISSN: 1420-9136
    Keywords: Galactic cosmic rays ; Solar proton events ; Particle precipitation ; Chemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract An assessment is made of the relative contribution of certain classes of energetic particle precipitation to the chemical composition of the middle atmosphere with emphasis placed on the production of odd nitrogen and odd hydrogen species and their subsequent role in the catalytic removal of ozone. Galactic cosmic radiation is an important source of odd nitrogen in the lower stratosphere but since the peak energy deposition occurs below the region where catalytic removal of O3 is most effective, it is questionable whether this mechanism is important in the overall terrestrial ozone budget. The precipitation of energetic solar protons can periodically produce dramatic enhancement in upper stratospheric NO. The long residence time of NO in this region of the atmosphere, where catalytic interaction with O3 is also most effective, mandates that this mechanism be included in future modelling of the global distribution of O3. Throughout the mesosphere the precipitation of energetic electrons from the outer radiation belt (60°≲Λ≲70°) can sporadically act as a major local source of odd hydrogen and odd nitrogen leading to observable O3 depletion. Future satellite studies should be directed at simultaneously measuring the precipitation flux and the concomitant atmosphere modification, and these results should be employed to develop more sophisticated models of this important coupling.
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  • 46
    Electronic Resource
    Electronic Resource
    Springer
    Journal of molecular evolution 15 (1980), S. 79-101 
    ISSN: 1432-1432
    Keywords: Molecules ; Interstellar ; Chemistry ; Isotopes ; Solar system
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Summary The study of interstellar molecules broadly includes two areas of interest. One area uses the unique ability of molecules to act as probes of the physical conditions in the cold, dense, visually opaque component of the interstellar medium. The physical properties of this and other components of the interstellar medium are summarized. The other area deals with the chemistry of interstellar molecules, recent aspects of which are emphasized in this review. Gas-phase chemistry, shock chemistry, and grain surface chemistry are discussed in the context of recent observations. No present observations suggest that surface reactions are relevant, but neither can they be ruled out. Ion-molecule reactions are clearly operative, at least for the simpler species. Chemical isotope fractionation is reviewed, andd it is concluded that the complexities of the chemistry allow no cosmological conclusions to be drawn from observations of deuterium in interstellar molecules, while the presence of13C in interstellar molecules permits an estimate of the12C/13C ratio which is consistent with the current concepts of the nucleosynthesis history of the Galaxy. Possible connections between interstellar molecules and the early molecular history of the solar system are discussed.
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  • 47
    ISSN: 1432-0827
    Keywords: Bacterial amphophile ; Purification ; Chemistry ; Resorption ; Ca influx ; Cyclic AMP
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine , Physics
    Notes: Summary The bone resorptive factor and amphipathic antigen (AcA) previously identified by us in preparations fromActinomyces viscosus have been partially purified, characterized chemically, and compared. They elute at the same location on chromatography with Ac 22. The fatty acid composition of AcA and the bone resorptive factor is the same. Some differences in carbohydrate composition are observed. TheActinomyces factor does not affect calcium influx or cyclic AMP in isolated bone cells. Therefore it is concluded that AcA stimulates resorption either by gaining entrance into bone cells or by way of a yet undetermined second messenger.
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  • 48
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    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 49
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    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960), S. 1-1 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 50
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960), S. 3-8 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Maximum stable droplet size in nonuniform dispersoids may be ignored or treated as a statistical-limiting parameter or as a physically significant quantity. In this paper the author shows that treatment as a physically significant quantity is always permissible and in most cases advantageous. It is found that maximum stable droplet size as well as a mean droplet size can be calculated in some cases from theory and in other cases from correlated experimental data; this is illustrated with examples involving sprays and emulsions.
    Additional Material: 9 Ill.
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  • 51
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960), S. 9-23 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study was made of the evaporation from single drops containing solids. By means of a specially designed sensitive balance, drops were suspended over a hot-air stream and their drying behavior was observed. Weight changes were measured during evaporation. Experimental data are presented on the time of appearance of the first solid phase and the formation of a solid crust for a wide range of drying conditions and materials. A theory is advanced for predicting the formation of a solid phase in drying a droplet containing a dissolved solid. This theory shows reasonable agreement with the experimental results. A tentative proposal for the application of the results to spray-dryer performance is suggested.
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  • 52
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960), S. 364-368 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The mathematical equations describing the kinetic behavior of ion exchange processes have been solved analytically for systems having linear equilibrium relationships of the type q* = K1 + K2C*. The concentration ratios of the effluent to the influent solution for these cases are found to depend on parameters involving time, position, and relative resistances of the liquid and resin phases. Numerical results have been obtained and are presented in tabular and graphical forms. Furthermore expressions for the constant pattern breakthrough curve for two special cases have also been worked out.
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  • 53
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    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960), S. 390-393 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This work presents initial information useful to concurrent gas-absorption design. Data are reported on the variation of pressure drop and liquid holdup obtained with various flow rates, packings, and liquids.
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  • 54
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960), S. 168-170 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In 1954 Becker found that the components of a gas mixture could be separated by allowing a jet of the gas mixture to expand in a low-pressure chamber. The heavier molecules would concentrate near the center of the jet and the lighter ones near the edge. Thus the jet could be split into two streams, one containing more of the heavy component and one containing more of the light component. In this paper it will be shown that this effect can be predicted from the kinetic theory of gases and that the predicted magnitude of the effect agrees favorably with the experimental data of Becker.
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960), S. 174-175 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 56
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    AIChE Journal 6 (1960), S. 3M 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: No abstracts.
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    AIChE Journal 6 (1960), S. 5M 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: No abstracts.
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    AIChE Journal 6 (1960), S. 176 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: The Chemical Engineering Progress Symposium Series is composed of papers on specific subjects conveniently bound in individual books, which are published at intervals. The books are 8 1/2 by 11 inches, paper covered, and cost as follows: “Adsorption, Dialysis, and Ion Exchange,” $3.50 to members, $4.50 to nonmembers; “Nuclear Engineering Part VI,” $3.50 to members, $4.50 to nonmembers. They may be ordered from the Secretary's Office, the American Institute of Chemical Engineers, 25 West 45 Street, New York 36, New York.The A. I. Ch. E. Journal will publish, from time to time, abstracts of the articles appearing in the Symposium Series volumes.
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    AIChE Journal 6 (1960) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 6 (1960), S. 177-177 
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    Keywords: Chemistry ; Chemical Engineering
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  • 61
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  • 62
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    AIChE Journal 6 (1960), S. 505-509 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In stirred beakers the interfacial area between xylene containing a scintillator and tritiated water was measured as a function of stirrer speed by a scintillation counting technique. Because of the 6 μ average range of the tritium betas the rate at which flashes are detected by a phototube is a function of the interfacial area. A calibration curve of count rate against known interfacial area for unstirred phases in containers of various diameters gave a numerical estimate of the interfacial area for ten configurations.
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    AIChE Journal 6 (1960), S. 179-183 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Accurate solutions to the Graetz equation and to the similar equation for flow between two parallel plates are presented including the first ten or eleven eigenvalues and important derivatives. The first six eigenfunctions are also presented at intervals of 0.05 from y = 0 to y = 1.
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  • 64
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    AIChE Journal 6 (1960), S. 606-611 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: An investigation has been made of transient heat transfer and water removal on an unfelted cylinder dryer. This investigation has included the development of a theory for describing conduction of heat in the drying material and an experimental testing of the adequacy of the theory.The theory describes the heat transfer and evaporation of water in terms of a second-order partial-differential equation and appropriate boundary conditions. Numerical solutions obtained on a digital computer are presented.The experimental work, performed on a specially constructed laboratory dryer, included measurements of temperatures at internal points in a drying sheet and also measurements of water removed during drying.Good agreement was found between theory and experiment, and the usefulness of the theory is demonstrated in the analysis of water removal in some drying experiments.Although the work was primarily concerned with a description of the paper drying process, the methods should apply equally well to the drying of other materials on heated cylinders.
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    AIChE Journal 7 (1961) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    AIChE Journal 7 (1961), S. 17-19 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    Notes: The problem of defining an average diffusion coefficient of a gas arises in the application of the film resistance model for mass transfer to systems involving multicomponent mixtures of simultaneously diffusing gases and in the application of mass, momentum, and heat transfer analogies in such systems. It is shown that, in some cases, integration of the diffusion equation with an average value of the diffusion coefficient will not be valid. An approximate solution of the diffusion equation is obtained with the concentration dependence of the diffusion coefficient taken into account. Some numerical examples are constructed for comparison of this method and several methods for defining an average diffusion coefficient with an exact solution of the Stefan-Maxwell relations.
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  • 67
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    AIChE Journal 7 (1961), S. 13-16 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: The phase-equilibria data of the propane-hydrogen sulfide system has been previously investigated from 32°F. to the critical locus. Since this represents about one-half of the phase data, the primary purposes of the present study were to complete the data to the solid-liquid-vapor region which starts about  - 125°F. and to verify the results of other investigators at the higher temperatures.Five mixtures of propane-hydrogen sulfide were studied, ranging from 8.6 to 78.3% propane, with the dew- and bubble-point method. A temperature-composition diagram for six isobars from 400 to 20 lb./sq. in. abs. presents most of the essential data. Vaporization equilibrium constants are tabulated together with the x-y data for these isobars. The data of Kay and Rambosek (3) and Steckel (4) were verified to within 2% except near the vicinity of the azeotrope.A new method was used to fix the temperature of the azeotrope for two of the five mixtures and a sixth mixture. The determination of the azeotropic temperatures was made by a graphical method in which the differences between the dew- and the bubble-point pressures for each mixture were plotted against the temperature. The minimum value of the curve corresponds to the temperature of the azeotrope. The application of this method to the data of Kay and Rambosek (3) gave results which were in agreement with this study, while the original results by these authors as determined by an indirect method were in poor agreement.A measure of the reliability of the composition, temperature, and pressure data of the solid-liquid-vapor region was indicated when checks within 5% were found with Dalton's law of partial pressures.
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    AIChE Journal 7 (1961), S. 26-28 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: This study deals with boundary-layer flow on continuous solid surfaces. Flow of this type represents a new class of boundary-layer problems, with solutions substantially different from those for boundary-layer flow on surfaces of finite length. In this paper the boundary-layer behavior on continuous surfaces is examined, and the basic differential and integral momentum equations of boundary-layer theory are derived for such surfaces. In subsequent papers these equations will be solved for the boundary layer on a moving continuous flat surface and a moving continuous cylindrical surface, for both laminar and turbulent flow in the boundary layer.
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    AIChE Journal 7 (1961), S. 20-25 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Drag coefficients were determined at low Reynolds numbers for cylinders (0.1 ≤ Re ≤ 1.0) and flat plates (0.05 ≤ Re ≤ 2.0) moving through a viscous medium. The drag coefficient was calculated from the force required to move the immersed body through the fluid, and preliminary work on spheres was used to calibrate the apparatus. For all bodies studied the drag coefficient was inversely proportional to the Reynolds number. The data were analyzed by a least-squares method to obtain the relationship between drag coefficient and Reynolds number.The diameter of the tank containing the viscous fluid had a very definite effect upon the drag coefficient of the various cylinders and flat plates studied. In the range of DT/D (tank diameter/cylinder diameter) studied the relationships recommended by White involving the wall effect and the end correction agree with experimental data for values of L/D (cylinder length/cylinder diameter) greater than 16. At L/D ratios less than this drag coefficients are lower than those predicted by White's equations, and the experimental curves are recommended for these ratios.For flat plates in perpendicular flow no effect of the W/L (plate width/plate length) was detected in the range studied. The tank diameter however had a considerable effect, and a curve is proposed to predict drag coefficients for flat plates in perpendicular flow in the range of experimental conditions studied.
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    AIChE Journal 7 (1961), S. 329-335 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The principles involved in designing a process for the production of fixed nitrogen by the direct use of fission fragment recoil energy are reviewed. The problems concerned with the radiation chemistry, development of fuel element, reactor design, and chemical process design are pointed out. Possible solutions to these problems incorporated in a complete plant design are presented. An economic evaluation, comparing the chemonuclear process with other conventional processes, is made. The conclusion is reached that at the present state of knowledge there does not seem to be any clear-cut advantage over conventional processes, even based on a nuclear economy. However moderate research efforts should continue for further evaluation of this process.
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    AIChE Journal 7 (1961), S. 336-337 
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    Notes: A modified Edwards density balance was used to measure compressibility of carbon dioxide and nitrous oxide at pressures under 2.0 atm. and over a temperature range of -30° to 75°C. Second virial coefficients were calculated for the temperatures covered in this investigation and compared with data presented in the literature for both gases. The compressibility data are estimated to be accurate within ±0.10% of the actual compressibility factor.
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    AIChE Journal 7 (1961), S. 346-347 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 7 (1961), S. 337-342 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: The effect of mass transfer resistance in reducing the effectiveness of porous catalysts has been known since the publication of Thiele's classical paper in 1939. The variation in temperature caused by resistance to heat transfer may bring about equally significant changes in effectiveness in some cases. An extension of Thiele's treatment to take exact account of heat transfer resistance leads to a set of nonlinear differential equations that can only be solved numerically.This paper presents an approximate treatment of the simulataneous effects of resistances to mass and heat transfer. With the limitations imposed by linearizing the equations the formulas derived give the activity and selectivity for any combination of reactions. The use of the results is illustrated by three examples. It is shown that the principal effects are associated with the variation of concentration within the pellet of catalyst and with the difference in temperature between the surface of the pellet and the bulk fluid.
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    AIChE Journal 7 (1961), S. 343-345 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: The P-V-T-x properties of binary gas mixtures and their dependence on reduced temperature and pressure have been reviewed in detail.A modified form of Kay's original method for estimating P-V-T-x properties of mixtures is suggested for purposes of engineering calculations.
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    AIChE Journal 7 (1961), S. 243-249 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: From the equations expressing mass and energy transfer in the solid and void regions of a catalyst of micropores, conversion and temperature profiles are evaluated as a function of the properties of the particle and the reaction system. The method developed is illustrated with numerical calculations for a first-order, irreversible reaction. Microeffectiveness factors Ec are derived from these profiles for several distribution functions for the size (radius) of the micropores.The results indicate that the nature of the pore-size distribution cannot affect Ec more than about 10%. However effectiveness factors greater than unity are possible for exothermic reactions with high heats of reaction and particles of reasonable size.To treat pelletted catalysts, equations are also developed for determining conversion and temperature profiles in pellets formed by compressing the microporous particles These results are interpreted in terms of macroeffectiveness factors Es, with values of Ec applicable at various positions in the pellet. To illustrate the method of solution numerical values of Es are determined for a limited range of parameters. The results indicate that in pelletted catalysts large temperature gradients may exist. For an exothermic reaction this can lead to a significant increase in macroeffectiveness factor.
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    AIChE Journal 6 (1960), S. 469-472 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: Air-carbon tetrachloride gas streams were dehumidified with cold liquid carbon tetrachloride in a short 4.0-in. diameter column packed with 0.5-in. Raschig rings in an attempt to explain reported unsuccessful attempts to correlate dehumidification data obtained at high solute concentration.The data were in satisfactory agreement with a previously presented correlation if the Schmidt number was evaluated at average film conditions and interfacial conditions were employed with regorous calculation methods to evaluate the mass transfer coefficients.
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    AIChE Journal 6 (1960), S. 473-481 
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    Notes: The transient response of a gas phase as it flows through an irrigated packed column can be interpreted as a distribution of time spent by the elements of gas as they flow through the bed.A step function in helium concentration was introduced in the entering air stream of a column packed with Raschig rings, and the outlet concentration was recorded with time. Water was used as the liquid phase. Size of Raschig rings, depth of bed, water and gas flow rates were the main variables investigated.The response curve for the gas reveals an increasing departure from uniform flow of the gas stream as liquid and gas rates are increased to flooding. The first and second moments of the time distribution give directly the porosity and the axial dispersion of the gas. These quantities have been found to be mainly dependent on liquid flow rates. The skewness which characterizes the weight that the various gas elements have on the dispersion about the average residence time has been found to give a convenient measurement of the uniformity of gas flow through the bed.
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    AIChE Journal 7 (1961), S. 29-34 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: Experimental heat transfer studies were carried out in beds of unconsolidated glass beads and sand through which fluids were flowing. The scope of the measurements included four fluids, helium, air, carbon dioxide, and water liquid at atmospheric pressure in beds packed with four sizes of glass beads, 110, 370, 570, and 1,020 μ and with two sizes of sand, 110 and 240 μ. Flow rates ranged form 1 to 26 lb./(hr. sq.ft.) in a direction parallel and countercurrent to energy flow.The data were interpreted in terms of apparent, effective thermal conductivities of the bed. The values of ke increase significantly with mass velocity of fluid.By considering the mechanism of heat transfer in porous media a relationship was developed between ke and the heat transfer coefficient between fluid and particle. Treatment of the experimental data in this fashion, combined with available information for larger particles, results in a correlation of Nusselt and Reynolds numbers for air that covers the range NRem = 10-1 to 104.
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    AIChE Journal 7 (1961), S. 38-41 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: An experimental study of superposed free and forced convection for air in a horizontal tube is reported. The laminar Nusselt number, based on the log mean temperature difference, ranged from 29.9 to 15.2; the laminar flow Graetz number, based on the bulk or average temperature of the air, ranged from 33 to 1,300, the Grashof-Prandtl modulus based on properties of air at the wall temperature ranged from 1.1 × 106 to 2.2 × 106. The Grashof number utilized the log mean temperature difference. An analysis of the system from a macroscopic viewpoint led to the determination of an equation which fits the laminar flow experimental data in the range of Graetz numbers from 60 to 1,300. An equation was also found for the turbulent data.
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    AIChE Journal 7 (1961), S. 41-45 
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    Notes: In recent years there have been quite a few experimental studies on turbulent flow in annuli. In this paper a Prandtl mixing-length approach is applied to give a friction factor vs. Reynolds number expression for annuli [see Equation (22) and Table 1]; this expression describes tube flow and slit flow as special cases. No new adjustable constants appear in the final result other than those determined earlier for tube flow. The final expression is found to predict friction factors within the accuracy of the existing experimental data. The mixing-length friction-factor expression is thus substantially more accurate than the usual hydraulic-radius procedure and of comparable accuracy to other recent annulus friction-factor treatments.
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    AIChE Journal 7 (1961), S. 46-48 
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    Notes: In a previous publication it has been shown that for the case of liquid droplets moving through a second quiescent liquid the holdup vs. slip-velocity ratio could be predicted on the basis of analogous rigid sphere fluidization data. The present paper extends these results to cover the countercurrent flow of both liquid phases. As long as the system is operated below the flooding point, the behavior of the spray column can be predicted from the corresponding solids fluidized data.
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    AIChE Journal 7 (1961), S. 48-52 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: Mass transfer coefficients have been measured for air flowing through a bed of naphthalene pellets. Results were obtained for ⅜-in. spheres and for ½, ⅜, and ¼-in. cylinders in a bed 4 in. in diameter and packed to heights varying from 5 to 10 in. Radial concentration profiles were obtained for some conditions, from which the radial variation of the mass transfer coefficient was determined. The point-values of kg follow an equation of the form kg = a Gb. From mixed outlet concentrations, values of kgav and jd, corrected for the effect of axial diffusion, have been obtained for all the pellet sizes as functions of mass velocity and Reynolds number, respectively.
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    AIChE Journal 7 (1961), S. 61-63 
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    Notes: A continuous velocity distribution is derived which is based on an arbitrary modification of Prandtl's mixing length expression. The resulting velocity distribution agrees well with experiments for transition and fully developed turbulent flow throughout the entire cross section of the conduit. Furthermore the mixing length expression applies to parallel flow in smooth circular tubes and between infinite parallel plates with the same set of constants.
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    AIChE Journal 7 (1961), S. 437-441 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: A solution for the problem of incompressible laminar boundary-layer flow and heat transfer with variable viscosity is presented. Because of the variation of viscosity with temperature the velocity and temperature fields interact mutually. This necessitates the simultaneous solution of the momentum and energy equations. The analysis is carried out for the case where heating begins at the leading edge of the plate. The results show the effect of the important variable property parameters on the friction factor and the heat transfer coefficient. These parameters are seen to be the temperature difference between wall and free stream, the viscosity temperature variation law, and the Prandtl number at the wall. The results are applicable to liquids.
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    AIChE Journal 7 (1961), S. 431-437 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: The turbulent heat, mass, and momentum transport characteristics of suspensions of particles with near-colloidal dimensions have previously been shown to be related to the non-Newtonian laminar-flow properties of the suspension. However the laminar-flow properties were not studied systematically. The present study showed that the principal factors affecting the magnitude of the laminar-flow properties of flocculated suspensions were the concentration and particle diameter of the solid phase. The range of variables included concentrations from 0.02 to 0.23 volume fraction solids and particle sizes from 0.35 to 13 μ. Materials tested included thorium oxide, kaolin, titanium oxide, aluminum oxide, graphite, magnesium, and uranium dioxide.At high rates of shear the data were fitted satisfactorily with the Bingham plastic model. With the use of this model, the yield stress was directly proportional to the cube of the volume fraction solids and inversely proportional to the first or second power of the particle diameter, depending on the particle shape. The logarithm of the ratio of the coefficient of rigidity of the suspension to the viscosity of the suspending medium was directly proportional to the volume fraction solids over the complete range of concentrations studied. Although specific electrolytes (such as oxalate or pyrophosphate) deflocculated the suspensions even at low concentrations, the suspensions remained flocculated both in the presence of up to 0.1 M of 1:1 electrolyte and over a pH range of 4 to 12. This is consistent with present theories of the stability of colloidal and near-colloidal particles.Although the concentration-dependence relationships of the yield stress and coefficient of rigidity have been proposed previously and have been shown to apply to specific systems, this is the first time they have been shown to apply to a broad class of materials. In addition it is the first time that the laminar-flow properties used in the particle-size and concentration correlations have been determined over a shear-rate range which permits application of the results in correlations of turbulent heat, mass, and momentum transfer data obtained in systems of commercial interest.
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    AIChE Journal 7 (1961), S. 606-610 
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    Keywords: Chemistry ; Chemical Engineering
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    Notes: Mechanical and dynamical characteristics of semifluidized beds of single-size particles in solid-liquid system were investigated. A semifluidized bed is a type of fluidized bed in which the bed expansion is partially restricted. The emphasis was placed on the study of packed bed formation and pressure drop increase when the semifluidized beds were formed by the compression of fluidized beds. The data showed good agreement with the theoretical and semiempirical equations based on a simple model of fluidized beds.The results of this investigation would also contribute to the understanding of fluidized beds.
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    AIChE Journal 7 (1961), S. 615-619 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Drag coefficients of aerodynamically smooth spheres having a density variation of from 0.252 to 1.91 g./cc. and a diameter variation from 1.56 to 3.21 mm. were obtained for acceleration rates varying from 103.5 ft./sec.2 to -30 ft./sec.2 and for relative intensities of up to 45%. The particle-to-Eulerian macroscale ratios varied from 0.50 to 0.16, and the diameter-to-Eulerian microscale ratios varied from 10 to 2.The drag coefficients were found to be a function of the particle Reynolds number and of the relative intensity but not of the acceleration and relative macro-and-microscale variations.A transition theory for the system investigated is presented, which predicts that the product of the critical Reynolds number and the square of the relative intensity should be a constant; it is supported by the experimental results obtained.
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    AIChE Journal 7 (1961), S. 631-634 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The liquid film coefficient is related to bubble diameter and velocity in pure water and to the physical properties of the liquid. The addition to water of organic substances which influence the surface tension and viscosity will decrease the size of the air bubble released from a diffuser and reduce the transfer of oxygen into the solution. The maximum reduction in oxygen transfer occurs in the region of maximum surface tension change. The effect of the addition of several organic substances on the oxygen transfer characteristics are shown.
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    AIChE Journal 7 (1961), S. 625-631 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental viscosity, thermal conductivity, and self-diffusivity data available in the literature for carbon dioxide have been critically reviewed and used to develop reduced state correlations of the transport properties for this substance. These correlations should apply to nonpolar compounds having critical compressibility factors approximately equal to that of carbon dioxide, zc = 0.275.In order to establish the dependence of these transport properties in the high pressure and liquid state regions, use has been made of relationships between the residual properties, μ-μ*, k-k*, and (PD)*-(PD) and density. These residual quantities represent the differences between the values of the properties at any pressure and temperature and those at atmospheric pressure and the same temperature. These relationships also allow the determination of the values of the transport properties at the critical point. The resulting critical values along with the residual relationships enabled the construction of reduced state correlations for viscosity, thermal conductivity, and the product of self-diffusivity and pressure for carbon dioxide.These correlations extend from the saturated vapor and liquid states to reduced temperatures of TR = 10 and reduced pressures of PR = 50. Comparisons made between values resulting from these correlations and corresponding experimental values, including the region of high pressure for both the gaseous and liquid states and the vicinity of the critical point, produced an average deviation of 2.0% for viscosity, 1.4% for thermal conductivity, and 5.9% for self-diffusivity.
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  • 90
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    AIChE Journal 7 (1961), S. 641-649 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: There has been considerable doubt as to the manner in which the productivity of solar stills is affected by many of the designs and operating variables. To assist in designing solar stills of improved performance, theoretical equations are derived to describe the complete energy and mass transfer relationships involved in the operation of the basin type of solar still. These are supplemented with data from field operation of a 2,500-sq. ft. still. With these relationships and the aid of a digital computer, the effects of variations of design parameters on the performance of solar stills is predicted. Distiller productivity is correlated with atmospheric temperature, wind velocity, solar radiation, absorptivity and slope of transparent cover, and other variables. Curves showing the magnitude of the effects of design changes on cover temperature, brine temperature, and productivity are presented.
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  • 91
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    AIChE Journal 7 (1961), S. 650-652 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In experimental investigations of the transient behavior of batch thermogravitational thermal diffusion columns it is expedient to obtain more than one sample from the column during a single run. Such sampling modifies the true batch nature of the column and thereby influences the experimental measurements to some degree. A combined theoretical and experimental investigation was carried out to determine the extent of the influence of sampling rate and thereby provide a means of predetermining a suitable sampling rate.The theoretical analysis was made by approximating the intermittent sampling as a continuous flow through the column. The transport equation of Furry, Jones, and Onsager was applied in the analysis, and an analytical solution was obtained for small separations of equicomposition binary solutions. The series solution is presented in the form of a graph. Experimental data were obtained in two thermogravitational columns with different plate spacings to test the theory. The effect of sampling rate was investigated, and theory and experiments were found to be in good agreement. It is concluded that the theory is entirely adequate to permit the prediction of sampling rates which will yield the maximum number of samples without disturbing the true batch behavior of the column.
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  • 92
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    AIChE Journal 7 (1961), S. 663-665 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In predicting interfacial area in liquid-liquid systems there are several published reports which give different results. Differences in methods of measurement of interfacial area and impeller design and location account for some of these discrepancies.For one pair of liquids, 40 parts by volume of ethylhexanol and 60 parts water, it was found that over wide ranges of impeller size to tank size ratio (0.27 to 0.67) that equal power per unit volume gave equal interfacial area per unit volume.
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  • 93
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    AIChE Journal 7 (1961), S. 672-676 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Diffusivities and equilibrium absorption of sodium chloride and glycerol in cation exchange resin Dowex-50 were determined by making a two-constant fit of experimental data to a diffusion model. The variables studied were: resin cross linkage - 2% to 12% divinylbenzene, temperature - 25° to 80°C, concentrations in the equilibrating solution, resin particle size, flow rate of the eluting distilled water. Diffusivities increase with decrease in cross linkage and with increase in temperature. The ratio of the diffusivities of sodium chloride or glycerol in the resin to that in water is between 0.2 and 0.35 for 2% DVB and between 0.025 and 0.1 for 12% DVB. Diffusivities were found to be independent of the third, fourth, and fifth variables. The amounts of solutes absorbed at equilibrium also increased with a decrease in cross linkage and an increase in temperature.
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  • 94
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    AIChE Journal 7 (1961), S. 682-687 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Low-pressure solubility data have been correlated for eleven gases in nine solvents over a wide temperature range by considering the dissolution process in two steps. First the gas is condensed isothermally to a hypothetical liquid at 1 atm. pressure, and then this hypothetical liquid is dissolved in the solvent. The free energy of the first step depends only on the properties of the solute, which in the case of nonpolar gases can be adequately described by the theorem of corresponding states. The second step depends on the properties of both solute and solvent and, in the case of nonpolar systems, can be described by the theory of regular solutions. The correlation depends on three solute parameters: the solubility parameter, the molar volume, and the fugacity of the hypothetical liquid; the last of these has been plotted as a generalized function for the reduced temperature range of 0.7 to 3.2. A separate plot is given for hydrogen. These parameters may be used to make good estimates of low-pressure gas solubilities (or K values) in nonpolar solvents over a wide range of temperature.A semiempirical method for correlating the solubilities of gases in polar solvents is also described and illustrated for several cases.Since the correlation presented in this paper covers a wide temperature range, it is possible to make estimates of the heats of solution of gases in liquids. These may be useful in enthalpyblance calculations as required in certain phase-separation operations.
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  • 95
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 96
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    AIChE Journal 7 (1961), S. 704 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 7 (1961), S. 5D-6D 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 98
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    AIChE Journal 7 (1961), S. 705-707 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 7 (1961), S. 707-707 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 7 (1961), S. 709-710 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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