ISSN:
1434-193X
Keywords:
Enzymatic synthesis
;
Rabbit muscle aldolase
;
Branched-chain sugars
;
Anhydro sugars
;
Glycosidation
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
-The coupling of dihydroxyacetone phosphate with 3-hydroxy-2-(hydroxymethyl)propanal (1) in the presence of rabbit muscle aldolase afforded a branched-chain hexulose phosphate isolated in 64% yield as the barium salt 3.The parent, dephosphorylated sugar 4 was converted to its anhydro derivative 8 and glycoside 9.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
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